JP2611603B2 - Manufacturing method of hot rolled steel sheet with excellent corrosion resistance - Google Patents

Manufacturing method of hot rolled steel sheet with excellent corrosion resistance

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Publication number
JP2611603B2
JP2611603B2 JP12026992A JP12026992A JP2611603B2 JP 2611603 B2 JP2611603 B2 JP 2611603B2 JP 12026992 A JP12026992 A JP 12026992A JP 12026992 A JP12026992 A JP 12026992A JP 2611603 B2 JP2611603 B2 JP 2611603B2
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JP
Japan
Prior art keywords
corrosion resistance
steel
steel sheet
less
strength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP12026992A
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Japanese (ja)
Other versions
JPH05311234A (en
Inventor
東成 福山
修二 中居
信一郎 勝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
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Priority to JP12026992A priority Critical patent/JP2611603B2/en
Publication of JPH05311234A publication Critical patent/JPH05311234A/en
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  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、耐食性低合金鋼板の製
造方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a corrosion-resistant low alloy steel sheet.

【0002】[0002]

【従来の技術】近年、種々の産業分野で用いられる鋼板
は、より安価で、しかも施工性、耐久性、成形性に優れ
るものがますます求められている。特に、自動車用鋼板
においては、高強度付与による板厚の減少とともに、安
価にして表面防錆性を維持するという高性能化を図るた
め、表面処理鋼板および合金鋼板の使用が指向されてい
る。
2. Description of the Related Art In recent years, there has been an increasing demand for steel sheets used in various industrial fields which are cheaper and have excellent workability, durability and formability. In particular, the use of surface-treated steel sheets and alloy steel sheets has been pursued in automotive steel sheets in order to reduce the thickness by imparting high strength, and at the same time to improve the performance by maintaining the surface rust resistance at a low cost.

【0003】表面処理鋼板の一つとして、亜鉛メッキ鋼
板がある。しかし、このメッキ鋼板では溶接時に亜鉛が
蒸発し、ブローホールを形成する。そのため、溶接後の
疲労強度低下が懸念されている。
[0003] As one of the surface-treated steel sheets, there is a galvanized steel sheet. However, in this plated steel sheet, zinc evaporates during welding to form blow holes. Therefore, there is a concern that the fatigue strength after welding is reduced.

【0004】これに対応すべく、表面無処理の鋼板で耐
穴明き腐食性に優れるものが開発されている。例えば、
特開平3−253541号公報に示される高耐食性低合金鋼板
は、主としてCu、Niの同時添加とPの添加によって耐食
性向上を図るものであるが、Cuとほぼ同量のNiを添加し
なければならないので、鋼板のコスト上昇は避けられな
い。
[0004] In order to cope with this, a steel sheet having no surface treatment and excellent in perforated corrosion resistance has been developed. For example,
Japanese Patent Laid-Open Publication No. 3-253541 discloses a high corrosion-resistant low-alloy steel sheet mainly intended to improve corrosion resistance by simultaneous addition of Cu and Ni and addition of P, but it is necessary to add approximately the same amount of Ni as Cu. Therefore, an increase in the cost of the steel sheet is inevitable.

【0005】特開昭64−79347 号公報に示される高強度
熱延鋼板は、Cuを 1.0重量%以上固溶させることにより
高成形性を保ち、加工後の熱処理によりε−Cuを析出さ
せて強度を向上させるものである。したがって、加工後
の熱処理工程やそのための設備を新規に追加することが
必要である。
A high-strength hot-rolled steel sheet disclosed in JP-A-64-79347 maintains high formability by dissolving 1.0% by weight or more of Cu, and precipitates ε-Cu by heat treatment after processing. It is to improve the strength. Therefore, it is necessary to newly add a heat treatment step after processing and equipment for the heat treatment step.

【0006】特開平3−82708 号公報に示される高強度
熱延鋼板は、Cu、Niを同等添加することで、疲労特性お
よび加工性を確保するものである。しかし、この場合で
は、Cu添加量を比較的低値に抑えた上でCu−Ni間化合物
を形成させ、スラブの熱間脆化を防止しているので、熱
間圧延後の鋼板の表面と内部とのCu濃度の差が少なくな
る。そのため、Cu添加の耐食性向上に対する寄与は少な
い。
A high-strength hot-rolled steel sheet disclosed in Japanese Patent Application Laid-Open No. 3-82708 secures fatigue characteristics and workability by adding Cu and Ni equally. However, in this case, the Cu-added amount is suppressed to a relatively low value and the Cu-Ni intermetallic compound is formed to prevent hot embrittlement of the slab. The difference in Cu concentration from the inside is reduced. Therefore, the contribution of Cu addition to the improvement of corrosion resistance is small.

【0007】[0007]

【発明が解決しようとする課題】本発明の目的は、Ni含
有量を低減してコストを低下させた、耐食性に優れる熱
延鋼板の製造方法を提供することにある。
SUMMARY OF THE INVENTION An object of the present invention is to provide a method for producing a hot-rolled steel sheet excellent in corrosion resistance, in which the Ni content is reduced and the cost is reduced.

【0008】[0008]

【課題を解決するための手段】本発明の要旨は、下記
(1)、(2) の製造方法にある。
The gist of the present invention is as follows.
(1) and (2).

【0009】(1) 重量%で、C: 0.10%未満、Si:1.5%
以下、Mn:2.0%以下、P: 0.02〜0.10%、 Cu: 0.2〜1.
0 %未満、Ni:Cuの 1/4%未満、残部がFeおよび不可避
的不純物からなる鋼を1070〜1200℃で30〜75分間加熱保
持した後、熱間圧延を施すことを特徴とする耐食性に優
れる熱延鋼板の製造方法。
(1) By weight%, C: less than 0.10%, Si: 1.5%
Mn: 2.0% or less, P: 0.02 to 0.10%, Cu: 0.2 to 1.
Corrosion resistance characterized in that steel containing less than 0%, less than 1/4% of Ni: Cu, and the balance being Fe and unavoidable impurities is heated and maintained at 1070 to 1200 ° C for 30 to 75 minutes, and then subjected to hot rolling. Method for producing hot rolled steel sheet with excellent heat resistance.

【0010】(2) 上記の鋼が更に、重量%で、 Cr: 0.3
〜1.0 %、Ti: 0.01〜0.03%、Nb: 0.01〜0.03%、V:
0.01〜0.03%および Mo: 0.1〜0.5 %の中の1種または
2種以上を含有する鋼であることを特徴とする上記 (1)
に記載の方法。
(2) The above steel further contains Cr: 0.3% by weight.
~ 1.0%, Ti: 0.01 ~ 0.03%, Nb: 0.01 ~ 0.03%, V:
(1) characterized in that the steel contains one or more of 0.01 to 0.03% and Mo: 0.1 to 0.5%.
The method described in.

【0011】なお、上記 (1)、(2) の鋼においては、Si
は 0.1〜1.5 %、Mnは 0.3〜2.0 %の範囲とすることが
望ましい。
Incidentally, in the steels (1) and (2), Si
Is preferably in the range of 0.1 to 1.5%, and Mn is preferably in the range of 0.3 to 2.0%.

【0012】本発明の方法は、上記の目的を達成するた
めに、Ni含有量をCuのそれの 1/4%未満に抑え、スラブ
加熱温度を1070〜1200℃で30〜75分間加熱保持すること
により、Fe−Cuの液相をスラブ表面にのみ形成させて圧
延し、Cu、Pの同時濃化層が鋼板の表面部に存在するよ
うにして、鋼板の耐食性を向上させる製造方法である。
In order to achieve the above object, the method of the present invention suppresses the Ni content to less than 1/4% of that of Cu and heats and maintains the slab at a temperature of 1070 to 1200 ° C. for 30 to 75 minutes. This is a production method in which the liquid phase of Fe-Cu is formed only on the slab surface and rolled, so that a simultaneously concentrated layer of Cu and P is present on the surface of the steel sheet, thereby improving the corrosion resistance of the steel sheet. .

【0013】錆の形成に伴い、添加されたCu、Pは、Cu
2+およびPO4 3- イオンとして錆と金属との界面に濃化
し、Fe(II) −水酸化物錯体が酸化して非晶質δ−FeOO
H になる際に触媒として働き、その結果、耐食性が向上
することは周知である。図1は、この概念を説明するた
めの、鋼表面の錆の組織を示す模式的断面図である。最
外表面には、α−FeOOH 1とγ−FeOOH 2からなる錆の
層3が形成され、この層中にFe3O4 4が塊状で、しかも
その一部は最表面に露出する状態で点在する。錆の層3
と母材鋼6の間の第二層には、非晶質の緻密なδ−FeOO
H 層5があり、ここに上記のようにCu、Pが濃化し、耐
食的に作用する。
[0013] With the formation of rust, added Cu and P are Cu
2+ and PO 4 3- ions are concentrated at the interface between rust and metal, and the Fe (II) -hydroxide complex is oxidized to form amorphous δ-FeOO
It is well known that when it becomes H, it acts as a catalyst, resulting in improved corrosion resistance. FIG. 1 is a schematic cross-sectional view showing the structure of rust on a steel surface for explaining this concept. A rust layer 3 composed of α-FeOOH 1 and γ-FeOOH 2 is formed on the outermost surface, and Fe 3 O 4 4 is formed in a lump in this layer, and a part thereof is exposed to the outermost surface. Dotted. Rust layer 3
And a second layer between the base metal 6 and the amorphous dense δ-FeOO
There is an H layer 5 in which Cu and P are concentrated as described above and act corrosion-resistant.

【0014】しかし、本発明者らが鋼板表面近傍のこれ
らの元素の濃度分布を精密に調査したところ、図2に概
略図として示すように、「Cu、Ni、Pを同時添加した成
分系の薄鋼板では、Pのみが表面側に濃化しているの
で、Pの耐食性への寄与は大きいが、Cuの表面濃度は逆
に減少しているので、耐食性向上をCuに頼る場合には、
その多量添加が必要である」ことがわかった。
However, when the present inventors examined the concentration distribution of these elements in the vicinity of the steel sheet surface in detail, as shown in a schematic diagram in FIG. In thin steel sheets, only P is concentrated on the surface side, so the contribution of P to corrosion resistance is large, but the surface concentration of Cu is conversely reduced, so when relying on Cu for corrosion resistance improvement,
It is necessary to add a large amount thereof ”.

【0015】そこで、意図的に表面にCuを濃化させるた
めに、Cu、Pを同時添加した成分系で、スラブ表層にの
みFe−Cu液相が形成するようなスラブの加熱条件で鋼板
を試作したところ、図3に概略図として示すように、
「ある特定の条件下では、CuとPをともに表面側に濃化
させることができ、したがって、Cu添加量の低減が可能
であり、これらの濃化状況では、Fe−Cu液相の形成によ
る熱間脆化を回避するためのNiの多量添加は必ずしも必
要がない」こともわかった。
Therefore, in order to intentionally enrich Cu on the surface, the steel sheet is heated under a slab heating condition such that a Fe-Cu liquid phase is formed only on the slab surface layer with a component system in which Cu and P are simultaneously added. When a prototype was made, as shown in FIG. 3 as a schematic diagram,
"Under certain conditions, both Cu and P can be concentrated on the surface side, so that the amount of Cu added can be reduced, and in these concentrated situations, the formation of the Fe-Cu liquid phase It is not always necessary to add a large amount of Ni to avoid hot embrittlement. "

【0016】[0016]

【作用】本発明の方法の対象となる鋼の化学組成範囲お
よび本発明の方法の熱間圧延条件を、上記のように定め
た理由を説明する。
The reasons for determining the chemical composition range of the steel to be subjected to the method of the present invention and the hot rolling conditions of the method of the present invention as described above will be described.

【0017】C:鋼板の強度を確保するために必要な成
分である。本発明の方法の対象となる鋼では、0.10%未
満で所要の強度が得られる。0.10%以上になると成形
性、耐食性が共に低下する。
C: A component necessary for ensuring the strength of the steel sheet. For steels subject to the method of the invention, the required strength is obtained at less than 0.10%. If it is 0.10% or more, both the moldability and corrosion resistance decrease.

【0018】Si:鋼の強度確保、耐食性向上のために必
要な成分である。 0.1%未満では強度確保、耐食性向上
の効果が乏しいから、 0.1%以上含有させることが望ま
しい。しかし、 1.5%を超えると成形性が劣化する。
Si: A component necessary for securing the strength of the steel and improving the corrosion resistance. If it is less than 0.1%, the effect of securing strength and improving corrosion resistance is poor, so it is desirable to contain 0.1% or more. However, when the content exceeds 1.5%, the formability deteriorates.

【0019】Mn:鋼の強度確保のために必要な成分であ
る。しかし、 2.0%を超えると延性が低下し、さらにMn
S系介在物が生じやすくなって成形性も低下する。Mnが
0.3%未満では、強度を上げる効果が小さいから、 0.3
%以上含有させるのが望ましい。
Mn: A component necessary for ensuring the strength of steel. However, if it exceeds 2.0%, ductility decreases, and Mn
S-based inclusions are likely to be generated, and the moldability also decreases. Mn
If it is less than 0.3%, the effect of increasing the strength is small.
% Is desirably contained.

【0020】P:鋼の耐食性を向上させるとともに、成
形性、溶接性に影響を与える成分である。0.02%未満で
は耐食性向上に寄与しない。0.10%を超えると成形性、
溶接性が共に劣化する。
P: A component that improves the corrosion resistance of steel and affects the formability and weldability. If it is less than 0.02%, it does not contribute to improving corrosion resistance. If it exceeds 0.10%, moldability,
Both weldability deteriorates.

【0021】Cu:鋼の強度とともに耐食性向上に寄与す
る成分であり、 0.2%未満ではその効果がなく、一方、
1.0%以上になると耐食性向上効果が飽和し不経済とな
る。
Cu: a component that contributes to the improvement of corrosion resistance as well as the strength of steel. If it is less than 0.2%, it has no effect.
If it is 1.0% or more, the effect of improving corrosion resistance is saturated, which is uneconomical.

【0022】Ni:Cu−Ni金属間化合物の形成による、Cu
−Fe化合物の融点上昇を防止するために含有させる。し
たがって、Niの含有量はCuのそれと関連があり、Cu−Fe
化合物の融点上昇の防止効果は、Cuの1/4 %未満の含有
量でも十分である。
Ni: Cu, formed by the formation of Cu-Ni intermetallic compound
-Included to prevent an increase in melting point of Fe compound. Therefore, the content of Ni is related to that of Cu, Cu-Fe
The effect of preventing the rise of the melting point of the compound is sufficient even if the content is less than 1/4% of Cu.

【0023】Ni含有量の下限については特に定める必要
はないが、後述するスラブ加熱温度は、通常の熱間圧延
ではその経済性の面から、1200〜1250℃の範囲が選択さ
れることが多いので、スラブ加熱温度が1200℃に達して
も、より確実にスラブ内部からのFe−Cuの液相の形成を
防止するために、例えば0.05%程度の極く少量のNiを含
有させることが好ましい。
Although there is no particular need to set the lower limit of the Ni content, the slab heating temperature described later is usually selected from the range of 1200 to 1250 ° C. in ordinary hot rolling in view of its economic efficiency. Therefore, even if the slab heating temperature reaches 1200 ° C., in order to more reliably prevent the formation of a liquid phase of Fe—Cu from inside the slab, it is preferable to contain a very small amount of Ni, for example, about 0.05%. .

【0024】本発明の方法の対象となる鋼は、更に下記
の成分の1種以上を含有することができる。
The steel subject to the method of the present invention may further contain one or more of the following components:

【0025】Cr:鋼の強度確保のために含有させる。
0.3%未満ではその効果がなく、 1.0%を超えると、そ
の効果が飽和するので不経済となる。
Cr: contained to ensure the strength of the steel.
If it is less than 0.3%, the effect will not be obtained, and if it exceeds 1.0%, the effect will be saturated and uneconomical.

【0026】Ti:オーステナイト結晶粒またはフェライ
ト結晶粒の微細化、あるいは、TiCの析出による強度向
上の作用を利用する場合に含有させる。0.01%未満では
その効果がなく、一方、0.03%を超えるとその効果が飽
和するので不経済となる。
Ti: Included when utilizing the effect of refining austenite crystal grains or ferrite crystal grains or improving the strength by precipitation of TiC. If it is less than 0.01%, the effect will not be obtained, while if it exceeds 0.03%, the effect will be saturated and uneconomical.

【0027】Nb、V:共に鋼の強度確保に寄与する成分
である。いずれも0.01%未満では強度上昇に寄与しな
い。一方、いずれも0.03%を超えると強度上昇効果が飽
和し不経済となる。
Nb, V: Both components contribute to ensuring the strength of steel. In any case, less than 0.01% does not contribute to the increase in strength. On the other hand, if any of them exceeds 0.03%, the effect of increasing the strength is saturated and uneconomical.

【0028】Mo:鋼の強度確保および溶接後のHAZ
(熱影響部)の軟化防止に寄与する成分である。 0.1%
未満では強度上昇効果がなく、一方、 0.5%を超えると
これらの効果が飽和し不経済となる。
Mo: HAZ after securing steel strength and welding
(Heat-affected zone) It is a component that contributes to prevention of softening. 0.1%
If it is less than 0.5%, there is no strength-increasing effect, while if it exceeds 0.5%, these effects are saturated and uneconomical.

【0029】スラブ加熱温度:スラブの表層のみにCu−
Fe液相を形成させ、Cuをスラブ表面のみに濃化させるた
めには、1070℃以上とする必要がある。一方、1200℃を
超えるとCu−Fe液相はスラブ内質の粒晶粒界にも形成さ
れ、スラブの熱間加工性が劣化する。
Slab heating temperature: Cu-only in the surface layer of the slab
In order to form the Fe liquid phase and concentrate Cu only on the slab surface, the temperature needs to be 1070 ° C. or higher. On the other hand, when the temperature exceeds 1200 ° C., the Cu—Fe liquid phase is also formed at the grain boundaries in the slab, and the hot workability of the slab deteriorates.

【0030】加熱保持時間:スラブの表層のみにCu−Fe
液相を形成させるには、前記の加熱温度と共に保持時間
を規定しなければならない。30分未満ではスラブの表面
全体にこの液相を形成するのに不十分である。75分を超
えると表層のみでなく、内質の粒界にもCu−Fe液相が形
成されるので熱間加工性が劣化する。
Heat holding time: Cu-Fe only on the surface of slab
In order to form a liquid phase, the holding time must be specified together with the heating temperature. Less than 30 minutes is insufficient to form this liquid phase over the entire surface of the slab. If the heating time exceeds 75 minutes, the Cu-Fe liquid phase is formed not only on the surface layer but also on the grain boundaries of the inner material, so that the hot workability deteriorates.

【0031】熱間圧延についての仕上温度や巻取温度の
条件は、特にその範囲を定める必要はない。しかし、成
形性(伸び+孔拡性)を向上させることを考慮して、仕
上温度はAr3 点〜940 ℃、巻取温度は 400〜550 ℃とす
ることが望ましい。
The conditions of the finishing temperature and the winding temperature for hot rolling do not need to be particularly defined. However, in consideration of improving the moldability (elongation + hole expansion), it is desirable that the finishing temperature be 3 points to 940 ° C and the winding temperature be 400 to 550 ° C.

【0032】[0032]

【実施例】表1に示す化学組成の鋼A〜Nを転炉にて溶
製して連続鋳造したスラブを表2に示す熱延条件で熱間
圧延し、 2.9mm厚の鋼板を製造した。仕上温度および巻
取温度は、それぞれAr3 点以上 940℃以下、 550℃以下
とした。これらの鋼板から作製したJIS 5号試験片を用
いて引張試験を行った。この機械的試験の結果を表2に
示す。耐穴明き性調査のための耐食性試験は、これらの
鋼板から作製したサンプルを用いて、図4に示す条件に
従い、240 サイクルまで実施した。この結果を表2と図
5に示す。
EXAMPLE A slab obtained by melting and continuously casting steels A to N having the chemical compositions shown in Table 1 in a converter was hot-rolled under the hot rolling conditions shown in Table 2 to produce a 2.9 mm thick steel sheet. . The finishing temperature and the winding temperature were set to 3 points or more and 940 ° C. or less and 550 ° C. or less, respectively. A tensile test was performed using JIS No. 5 test pieces prepared from these steel sheets. Table 2 shows the results of the mechanical test. The corrosion resistance test for investigating the hole piercing resistance was performed up to 240 cycles under the conditions shown in FIG. 4 using the samples prepared from these steel sheets. The results are shown in Table 2 and FIG.

【0033】表2から明らかなように、化学組成および
熱延条件が本発明の方法の範囲である本発明例では全て
耐穴明き性が良好であり、しかも機械的特性も望ましい
値を示している。一方、化学組成が本発明で定める範囲
であるA鋼を対象とする比較例の試験No.1〜3では、熱
延条件が本発明で定める範囲から外れているので、機械
的特性(TS×El )あるいは耐穴明き性のいずれかが
劣る。スラブ加熱温度が低い比較例の試験No.1およびス
ラブ加熱時間が短い比較例の試験No.3については、Cuの
表面濃化が不十分であるため、耐穴明き性がよくないこ
とが裏付けられている。
As is evident from Table 2, all of the examples of the present invention in which the chemical composition and the hot rolling conditions are within the range of the method of the present invention have good piercing resistance and also exhibit desirable mechanical properties. ing. On the other hand, in the test Nos. 1 to 3 of the comparative examples for the steel A whose chemical composition is in the range defined by the present invention, the mechanical properties (TS × El) or piercing resistance is inferior. Regarding the test No. 1 of the comparative example where the slab heating temperature is low and the test No. 3 of the comparative example where the slab heating time is short, since the surface concentration of Cu is insufficient, the perforation resistance is not good. It is supported.

【0034】化学組成が本発明で定める範囲外である鋼
L、Nを対象とする比較例の試験No.4、6では、熱延条
件が本発明で定める範囲内であっても、上記の機械的特
性あるいは耐穴明き性のいずれかもしくは両方がよくな
い。Niが本発明で定める範囲の上限を超える鋼Mを対象
とする比較例の試験No.5では、全ての特性が良好である
が、鋼のコストが高くなる。
In Tests Nos. 4 and 6 of Comparative Examples for steels L and N whose chemical compositions are out of the range defined by the present invention, even if the hot rolling conditions are within the range defined by the present invention, One or both of mechanical properties and / or puncture resistance are poor. In the test No. 5 of the comparative example in which Ni exceeds the upper limit of the range defined in the present invention, all the properties are good, but the cost of the steel increases.

【0035】図5は、耐食性試験のサイクルと最大浸食
深さ(%)との関係を示す図であるが、80サイクルを超
えると本発明の方法による鋼板では、最大浸食深さの増
加傾向に明確な差が生じ、上記鋼Mを用いた比較例の試
験No.5および鋼Aを用いた比較例の試験No.2を除き、比
較例のどれよりも優れていることがわかる。
FIG. 5 is a graph showing the relationship between the cycle of the corrosion resistance test and the maximum erosion depth (%). When the cycle exceeds 80 cycles, the maximum erosion depth tends to increase in the steel sheet according to the method of the present invention. A clear difference occurs, and it can be seen that it is superior to any of the comparative examples except for the test No. 5 of the comparative example using the steel M and the test No. 2 of the comparative example using the steel A.

【0036】[0036]

【表1】 [Table 1]

【0037】[0037]

【表2】 [Table 2]

【0038】[0038]

【発明の効果】本発明の方法によれば、低コストの、耐
食性、特に耐穴明き性に優れる熱延鋼板を製造すること
ができる。
According to the method of the present invention, it is possible to produce a low-cost hot-rolled steel sheet having excellent corrosion resistance, especially excellent piercing resistance.

【図面の簡単な説明】[Brief description of the drawings]

【図1】Cu、P、Niを含む鋼の表面の錆の層を説明する
模式的断面図である。
FIG. 1 is a schematic sectional view illustrating a rust layer on the surface of steel containing Cu, P, and Ni.

【図2】Cu、P、Niを含む鋼の表面の、Cu、Pの濃化状
況を説明する概略図である。
FIG. 2 is a schematic diagram illustrating the concentration of Cu and P on the surface of steel containing Cu, P and Ni.

【図3】Niを含まず、Cu、Pを含む鋼の表面の、Cu、P
の濃化状況を説明する概略図である。
FIG. 3 shows Cu and P on the surface of steel containing Cu and P without Ni.
It is a schematic diagram explaining the enrichment situation of.

【図4】耐穴明き性調査のための耐食性試験の条件を示
す図である。
FIG. 4 is a diagram showing conditions of a corrosion resistance test for investigating a hole piercing property.

【図5】図4の条件で実施した耐食性試験の結果を示す
図である。
FIG. 5 is a diagram showing the results of a corrosion resistance test performed under the conditions of FIG.

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 平5−311235(JP,A) 特開 平3−264615(JP,A) 特開 昭55−31123(JP,A) ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-5-311235 (JP, A) JP-A-3-264615 (JP, A) JP-A-55-31123 (JP, A)

Claims (2)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】重量%で、C: 0.10%未満、Si:1.5%以
下、Mn:2.0%以下、P: 0.02〜0.10%、 Cu: 0.2〜1.0
%未満、Ni:Cuの 1/4%未満、残部がFeおよび不可避的
不純物からなる鋼を1070〜1200℃で30〜75分間加熱保持
した後、熱間圧延を施すことを特徴とする耐食性に優れ
る熱延鋼板の製造方法。
(1) In weight%, C: less than 0.10%, Si: 1.5% or less, Mn: 2.0% or less, P: 0.02 to 0.10%, Cu: 0.2 to 1.0%
%, Ni: less than 1/4% of Cu, the balance being Fe and unavoidable impurities. The steel is heated at 1070-1200 ° C for 30-75 minutes and then hot-rolled. Excellent hot rolled steel sheet manufacturing method.
【請求項2】上記の鋼が更に、重量%で、 Cr: 0.3〜1.
0 %、Ti:0.01〜0.03%、Nb:0.01〜0.03%、V:0.01
〜0.03%および Mo: 0.1〜0.5 %の中の1種または2種
以上を含有する鋼であることを特徴とする請求項1に記
載の方法。
2. The steel according to claim 1, further comprising Cr: 0.3 to 1.
0%, Ti: 0.01 to 0.03%, Nb: 0.01 to 0.03%, V: 0.01
The method according to claim 1, wherein the steel contains one or more of 0.03% and Mo: 0.1 to 0.5%.
JP12026992A 1992-05-13 1992-05-13 Manufacturing method of hot rolled steel sheet with excellent corrosion resistance Expired - Fee Related JP2611603B2 (en)

Priority Applications (1)

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JP12026992A JP2611603B2 (en) 1992-05-13 1992-05-13 Manufacturing method of hot rolled steel sheet with excellent corrosion resistance

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Application Number Priority Date Filing Date Title
JP12026992A JP2611603B2 (en) 1992-05-13 1992-05-13 Manufacturing method of hot rolled steel sheet with excellent corrosion resistance

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JPH05311234A JPH05311234A (en) 1993-11-22
JP2611603B2 true JP2611603B2 (en) 1997-05-21

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