JP2023504895A - 洗浄製品 - Google Patents
洗浄製品 Download PDFInfo
- Publication number
- JP2023504895A JP2023504895A JP2022534390A JP2022534390A JP2023504895A JP 2023504895 A JP2023504895 A JP 2023504895A JP 2022534390 A JP2022534390 A JP 2022534390A JP 2022534390 A JP2022534390 A JP 2022534390A JP 2023504895 A JP2023504895 A JP 2023504895A
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- JP
- Japan
- Prior art keywords
- surfactant
- composition
- cleaning
- weight
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000004140 cleaning Methods 0.000 title claims abstract description 101
- 239000000203 mixture Substances 0.000 claims abstract description 217
- 239000004094 surface-active agent Substances 0.000 claims abstract description 113
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 58
- 239000007921 spray Substances 0.000 claims abstract description 47
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000003960 organic solvent Substances 0.000 claims abstract description 14
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 11
- 238000005507 spraying Methods 0.000 claims abstract description 11
- 239000002888 zwitterionic surfactant Substances 0.000 claims abstract description 11
- 238000004851 dishwashing Methods 0.000 claims abstract description 8
- 238000009736 wetting Methods 0.000 claims abstract description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 42
- 150000001412 amines Chemical class 0.000 claims description 38
- 229960003237 betaine Drugs 0.000 claims description 23
- 239000003945 anionic surfactant Substances 0.000 claims description 17
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 15
- 239000002736 nonionic surfactant Substances 0.000 claims description 15
- 239000004210 ether based solvent Substances 0.000 claims description 14
- 238000005201 scrubbing Methods 0.000 claims description 8
- 239000003759 ester based solvent Substances 0.000 claims description 6
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 5
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 5
- 239000004064 cosurfactant Substances 0.000 claims description 5
- KKMIHKCGXQMFEU-UHFFFAOYSA-N 2-[dimethyl(tetradecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O KKMIHKCGXQMFEU-UHFFFAOYSA-N 0.000 claims description 3
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 claims description 3
- 229940075468 lauramidopropyl betaine Drugs 0.000 claims description 3
- 229940094506 lauryl betaine Drugs 0.000 claims description 3
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005456 alcohol based solvent Substances 0.000 claims description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000004519 grease Substances 0.000 abstract description 17
- -1 sulfosuccinic acid ester Chemical class 0.000 description 40
- 239000000047 product Substances 0.000 description 24
- 239000003599 detergent Substances 0.000 description 23
- 239000002689 soil Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 15
- 239000007788 liquid Substances 0.000 description 14
- 239000002904 solvent Substances 0.000 description 13
- 239000000758 substrate Substances 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000006260 foam Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 9
- RGFNRWTWDWVHDD-UHFFFAOYSA-N isobutyl butyrate Chemical compound CCCC(=O)OCC(C)C RGFNRWTWDWVHDD-UHFFFAOYSA-N 0.000 description 9
- JSLCOZYBKYHZNL-UHFFFAOYSA-N isobutyric acid butyl ester Natural products CCCCOC(=O)C(C)C JSLCOZYBKYHZNL-UHFFFAOYSA-N 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- 150000001298 alcohols Chemical class 0.000 description 8
- 238000005187 foaming Methods 0.000 description 8
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 8
- 150000005691 triesters Chemical class 0.000 description 8
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
- RXGUIWHIADMCFC-UHFFFAOYSA-N 2-Methylpropyl 2-methylpropionate Chemical compound CC(C)COC(=O)C(C)C RXGUIWHIADMCFC-UHFFFAOYSA-N 0.000 description 6
- FZXRXKLUIMKDEL-UHFFFAOYSA-N 2-Methylpropyl propanoate Chemical compound CCC(=O)OCC(C)C FZXRXKLUIMKDEL-UHFFFAOYSA-N 0.000 description 6
- XMVBHZBLHNOQON-UHFFFAOYSA-N 2-butyl-1-octanol Chemical compound CCCCCCC(CO)CCCC XMVBHZBLHNOQON-UHFFFAOYSA-N 0.000 description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
- FFOPEPMHKILNIT-UHFFFAOYSA-N Isopropyl butyrate Chemical compound CCCC(=O)OC(C)C FFOPEPMHKILNIT-UHFFFAOYSA-N 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 6
- 239000002738 chelating agent Substances 0.000 description 6
- 150000005690 diesters Chemical class 0.000 description 6
- XAOGXQMKWQFZEM-UHFFFAOYSA-N isoamyl propanoate Chemical compound CCC(=O)OCCC(C)C XAOGXQMKWQFZEM-UHFFFAOYSA-N 0.000 description 6
- 235000013336 milk Nutrition 0.000 description 6
- 239000008267 milk Substances 0.000 description 6
- 210000004080 milk Anatomy 0.000 description 6
- JYVLIDXNZAXMDK-UHFFFAOYSA-N pentan-2-ol Chemical compound CCCC(C)O JYVLIDXNZAXMDK-UHFFFAOYSA-N 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000006254 rheological additive Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- KQTIIICEAUMSDG-UHFFFAOYSA-N tricarballylic acid Chemical compound OC(=O)CC(C(O)=O)CC(O)=O KQTIIICEAUMSDG-UHFFFAOYSA-N 0.000 description 6
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 5
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 description 5
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000003925 fat Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 4
- PQSMEVPHTJECDZ-UHFFFAOYSA-N 2,3-dimethylheptan-2-ol Chemical compound CCCCC(C)C(C)(C)O PQSMEVPHTJECDZ-UHFFFAOYSA-N 0.000 description 4
- CYHBDKTZDLSRMY-UHFFFAOYSA-N Hexyl 2-methylpropanoate Chemical compound CCCCCCOC(=O)C(C)C CYHBDKTZDLSRMY-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 4
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Chemical group 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 230000000845 anti-microbial effect Effects 0.000 description 4
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- WDAXFOBOLVPGLV-UHFFFAOYSA-N ethyl isobutyrate Chemical compound CCOC(=O)C(C)C WDAXFOBOLVPGLV-UHFFFAOYSA-N 0.000 description 4
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- 239000003752 hydrotrope Substances 0.000 description 4
- PQLMXFQTAMDXIZ-UHFFFAOYSA-N isoamyl butyrate Chemical compound CCCC(=O)OCCC(C)C PQLMXFQTAMDXIZ-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- CFNJLPHOBMVMNS-UHFFFAOYSA-N pentyl butyrate Chemical compound CCCCCOC(=O)CCC CFNJLPHOBMVMNS-UHFFFAOYSA-N 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 4
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 3
- XVOUMQNXTGKGMA-OWOJBTEDSA-N (E)-glutaconic acid Chemical compound OC(=O)C\C=C\C(O)=O XVOUMQNXTGKGMA-OWOJBTEDSA-N 0.000 description 3
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 3
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 3
- HFZLSTDPRQSZCQ-UHFFFAOYSA-N 1-pyrrolidin-3-ylpyrrolidine Chemical compound C1CCCN1C1CNCC1 HFZLSTDPRQSZCQ-UHFFFAOYSA-N 0.000 description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 3
- UHOPWFKONJYLCF-UHFFFAOYSA-N 2-(2-sulfanylethyl)isoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(CCS)C(=O)C2=C1 UHOPWFKONJYLCF-UHFFFAOYSA-N 0.000 description 3
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- IJMWOMHMDSDKGK-UHFFFAOYSA-N Isopropyl propionate Chemical compound CCC(=O)OC(C)C IJMWOMHMDSDKGK-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- 229940091181 aconitic acid Drugs 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 3
- 125000004122 cyclic group Chemical class 0.000 description 3
- DTDMYWXTWWFLGJ-UHFFFAOYSA-N decan-4-ol Chemical compound CCCCCCC(O)CCC DTDMYWXTWWFLGJ-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000001530 fumaric acid Substances 0.000 description 3
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- HUAZGNHGCJGYNP-UHFFFAOYSA-N propyl butyrate Chemical compound CCCOC(=O)CCC HUAZGNHGCJGYNP-UHFFFAOYSA-N 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 3
- 125000006528 (C2-C6) alkyl group Chemical group 0.000 description 2
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 2
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 description 2
- HGDVHRITTGWMJK-UHFFFAOYSA-N 2,6-dimethylheptan-2-ol Chemical compound CC(C)CCCC(C)(C)O HGDVHRITTGWMJK-UHFFFAOYSA-N 0.000 description 2
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 description 2
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 2
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 2
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 2
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical compound CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 description 2
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 2
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 2
- KHBBRIBQJGWUOW-UHFFFAOYSA-N 2-methylcyclohexane-1,3-diamine Chemical compound CC1C(N)CCCC1N KHBBRIBQJGWUOW-UHFFFAOYSA-N 0.000 description 2
- WTXBAYPZJKPZHX-UHFFFAOYSA-N 2-methyldecan-2-ol Chemical compound CCCCCCCCC(C)(C)O WTXBAYPZJKPZHX-UHFFFAOYSA-N 0.000 description 2
- ACBMYYVZWKYLIP-UHFFFAOYSA-N 2-methylheptan-2-ol Chemical compound CCCCCC(C)(C)O ACBMYYVZWKYLIP-UHFFFAOYSA-N 0.000 description 2
- LCFKURIJYIJNRU-UHFFFAOYSA-N 2-methylhexan-1-ol Chemical compound CCCCC(C)CO LCFKURIJYIJNRU-UHFFFAOYSA-N 0.000 description 2
- NGDNVOAEIVQRFH-UHFFFAOYSA-N 2-nonanol Chemical compound CCCCCCCC(C)O NGDNVOAEIVQRFH-UHFFFAOYSA-N 0.000 description 2
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical group CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 2
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 description 2
- GYSCXPVAKHVAAY-UHFFFAOYSA-N 3-Nonanol Chemical compound CCCCCCC(O)CC GYSCXPVAKHVAAY-UHFFFAOYSA-N 0.000 description 2
- BCEQKAQCUWUNML-UHFFFAOYSA-N 4-hydroxybenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=C(O)C(C(O)=O)=C1 BCEQKAQCUWUNML-UHFFFAOYSA-N 0.000 description 2
- QTKDDPSHNLZGRO-UHFFFAOYSA-N 4-methylcyclohexane-1,3-diamine Chemical compound CC1CCC(N)CC1N QTKDDPSHNLZGRO-UHFFFAOYSA-N 0.000 description 2
- AJCVRKAWPQPCAA-UHFFFAOYSA-N 4-methylpentyl 2-methylpropanoate Chemical compound CC(C)CCCOC(=O)C(C)C AJCVRKAWPQPCAA-UHFFFAOYSA-N 0.000 description 2
- XXRMPEBULHOCFH-UHFFFAOYSA-N 4-methylpentyl butanoate Chemical compound CCCC(=O)OCCCC(C)C XXRMPEBULHOCFH-UHFFFAOYSA-N 0.000 description 2
- FMSKUFHLEKFBAI-UHFFFAOYSA-N 4-methylpentyl propanoate Chemical compound CCC(=O)OCCCC(C)C FMSKUFHLEKFBAI-UHFFFAOYSA-N 0.000 description 2
- RYFZXYQQFYLUHM-UHFFFAOYSA-N 7,7-dimethyloctan-1-ol Chemical compound CC(C)(C)CCCCCCO RYFZXYQQFYLUHM-UHFFFAOYSA-N 0.000 description 2
- QPKZDFIDVHQUFM-UHFFFAOYSA-N 8,8-dimethylnonan-1-ol Chemical compound CC(C)(C)CCCCCCCO QPKZDFIDVHQUFM-UHFFFAOYSA-N 0.000 description 2
- MWRSABPHNREIIX-UHFFFAOYSA-N 9,9-dimethyldecan-1-ol Chemical compound CC(C)(C)CCCCCCCCO MWRSABPHNREIIX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
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- PGQAXGHQYGXVDC-UHFFFAOYSA-N dodecyl(dimethyl)azanium;chloride Chemical compound Cl.CCCCCCCCCCCCN(C)C PGQAXGHQYGXVDC-UHFFFAOYSA-N 0.000 description 1
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- JPXGPRBLTIYFQG-UHFFFAOYSA-N heptan-4-yl acetate Chemical compound CCCC(CCC)OC(C)=O JPXGPRBLTIYFQG-UHFFFAOYSA-N 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- BGYICJVBGZQOCY-UHFFFAOYSA-N heptyl propanoate Chemical compound CCCCCCCOC(=O)CC BGYICJVBGZQOCY-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- YERFHJZYNMRVLO-UHFFFAOYSA-N hexyl pentanoate Chemical compound CCCCCCOC(=O)CCCC YERFHJZYNMRVLO-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
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- 230000002401 inhibitory effect Effects 0.000 description 1
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- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- PQCYCHFQWMNQRJ-UHFFFAOYSA-N isobutyric acid octyl ester Natural products CCCCCCCCOC(=O)C(C)C PQCYCHFQWMNQRJ-UHFFFAOYSA-N 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229940098895 maleic acid Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- WHSXTWFYRGOBGO-UHFFFAOYSA-N o-cresotic acid Natural products CC1=CC=CC(C(O)=O)=C1O WHSXTWFYRGOBGO-UHFFFAOYSA-N 0.000 description 1
- FUBGRVHGQADOJI-UHFFFAOYSA-N octyl 3-methyl-butanoate Chemical compound CCCCCCCCOC(=O)CC(C)C FUBGRVHGQADOJI-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- OUYCCOBIJYUMAK-UHFFFAOYSA-N octyl pentanoate Chemical compound CCCCCCCCOC(=O)CCCC OUYCCOBIJYUMAK-UHFFFAOYSA-N 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- FGPPDYNPZTUNIU-UHFFFAOYSA-N pentyl pentanoate Chemical compound CCCCCOC(=O)CCCC FGPPDYNPZTUNIU-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 235000002316 solid fats Nutrition 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
-
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2034—Monohydric alcohols aromatic
-
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
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- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
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- Chemical & Material Sciences (AREA)
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- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
Description
洗浄組成物は、好ましくは、食器手洗い用洗浄組成物であり、好ましくは液体形態である。この洗浄組成物は噴霧に好適である。
この組成物は、5重量%~25重量%、好ましくは7重量%~20重量%、より好ましくは8重量%~15重量%の界面活性剤系を含む。この界面活性剤系は、アルキルポリグルコシド界面活性剤を含む。この界面活性剤系は、両性界面活性剤、双性イオン性界面活性剤、及びこれらの混合物からなる群から選択され、好ましくは両性界面活性剤から選択され、より好ましくはアミンオキシド界面活性剤から選択される、補助界面活性剤を含む。アルキルポリグルコシド界面活性剤及び補助界面活性剤は、10:1~1:2、好ましくは5:1~1:1.5、最も好ましくは3:1~1:1の重量比で存在する。
当f界面活性剤系は、好ましくは、組成物の2.0重量%~12重量%、好ましくは2.5重量%~10重量%、より好ましくは3.0重量%~7.5重量%の濃度のアルキルポリグルコシド(「APG」)を含む。
この補助界面活性剤は、両性界面活性剤、双性イオン性界面活性剤、及びこれらの混合物からなる群から選択される。この洗剤組成物は、組成物の0.5~5.0重量%、好ましくは1.0重量%~4.5重量%、より好ましくは2.0重量%~4.0重量%の濃度の補助界面活性剤を含むことができる。
前述したように、アミンオキシド界面活性剤は、補助界面活性剤としての使用に好ましい。アミンオキシド界面活性剤は、直鎖状であっても分枝鎖状であってもよいが、直鎖状が好ましい。好適な直鎖状アミンオキシドは、典型的には、水溶性であり、式R1-N(R2)(R3)O(式中、R1は、C8~18アルキルであり、R2及びR3部分は、C1~3アルキル基、C1~3ヒドロキシアルキル基、及びこれらの混合物からなる群から選択される)によって特徴付けられる。例えば、R2及びR3は、メチル、エチル、プロピル、イソプロピル、2-ヒドロキシエチル、2-ヒドロキシプロピル、及び3-ヒドロキシプロピル、並びにこれらの混合物からなる群から選択することができるが、R2及びR3の一方又は両方がメチルであることが好ましい。直鎖状アミンオキシド界面活性剤としては、特に、直鎖状C10~C18アルキルジメチルアミンオキシド及び直鎖状C8~C12アルコキシエチルジヒドロキシエチルアミンオキシドを挙げることができる。
a)当該アミンオキシドの重量に基づいて、約10重量%~約45重量%の式R1R2R3AO(式中、R1及びR2は、独立して、水素、C1~C4アルキル、又はこれらの混合物から選択され、R3は、C10アルキル及びこれらの混合物から選択される)のローカットアミンオキシドと、
b)アミンオキシドの55重量%~90重量%の式R4R5R6AO(式中、R4及びR5は、独立して、水素、C1~C4のアルキル、又はこれらの混合物から選択され、R6は、C12~C16のアルキル又はこれらの混合物から選択される)であるミッドカットアミンオキシドと、を含むことができる。
本発明の組成物では、補助界面活性剤として双性イオン性界面活性剤を使用することにより、重合した又は「焼け付いた」グリースの除去を改善することが見出されている。好適な双性イオン性界面活性剤としては、ベタイン界面活性剤が挙げられる。このようなベタイン界面活性剤としては、アルキルベタイン、アルキルアミドベタイン、アミドアゾリニウムベタイン、スルホベタイン(INCIスルタイン)、及びホスホベタインが挙げられ、かかる界面活性剤は好ましくは式(II)を満たす:
R1-[CO-X(CH2)n]x-N+(R2)(R3)-(CH2)m-[CH(OH)-CH2]y-Y-
式(II)中、
R1は、飽和又は不飽和のC6~22アルキル残基、好ましくは、C8~18アルキル残基、より好ましくは、飽和C10~16アルキル残基、最も好ましくは、飽和C12~14アルキル残基からなる群から選択され、
Xは、NH、NR4(式中、R4は、C1~4アルキル残基である)、O、及びSからなる群から選択され、
nは、1~10、好ましくは2~5、より好ましくは3の整数であり、
xは、0又は1、好ましくは1であり、
R2及びR3は、独立して、C1~4アルキル残基、ヒドロキシエチルなどの置換されているヒドロキシ、及びこれらの混合からなる群から選択され、好ましくは、R2及びR3の両方がメチルであり、
mは、1~4の整数、好ましくは1、2、又は3の整数であり、
yは、0又は1であり、
Yは、COO、SO3、OPO(OR5)O、又はP(O)(OR5)O(式中、R5は、H又はC1~4アルキル残基である)からなる群から選択される)。
この洗剤組成物がアニオン性界面活性剤を含む場合、好適なアニオン性界面活性剤としては、その分子構造中に一般に8~22個の炭素原子又は一般に8~18個の炭素原子を含有する有機疎水性基と、水溶性化合物を形成するよう好ましくはスルホネート、サルフェート、及びカルボキシレートから選択される少なくとも1つの水溶性基と、を含有する界面活性化合物が挙げられるが、これらに限定されない。通常、疎水性基は、直鎖又は分岐鎖のC8~C22アルキル又はアシル基を含む。このような界面活性剤は、水溶性塩の形態で使用され、塩形成カチオンは、通常、ナトリウム、カリウム、アンモニウム、マグネシウム、及びモノ-、ジ-又はトリ-アルカノールアンモニウムから選択され、通常選択されるカチオンはナトリウムである。
この界面活性剤系は、非イオン性界面活性剤を更に含み得る。存在する場合、この界面活性剤系は、組成物の0.5重量%~10重量%、好ましくは1.0重量%~5.0重量%、より好ましくは1.5重量%~3.0重量%の更なる非イオン性界面活性剤を含み得る。
本発明で使用する組成物は、好ましくはカチオン性界面活性剤を含まず、特に抗菌性カチオン性界面活性剤を含まない。その理由は、そのような界面活性剤は典型的に、グリース洗浄及び表面光沢に有害であるためである。このような抗菌性カチオン性界面活性剤としては、ドデシルジメチルアンモニウムクロリド、アルキルジメチルベンジルアンモニウムクロリド、アルキルジメチルエチルベンジルアンモニウムクロリド、及びこれらの混合物などの、第四級アンモニウム化合物が挙げられる。
結晶質グリースの浸透及び除去を改善するために、この組成物は有機溶媒を含む。好適な有機溶媒は、グリコールエーテル溶媒、アルコール溶媒、エステル溶媒、及びこれらの混合物からなる群から選択することができ、グリコールエーテル溶媒は、結晶質グリースを除去するためにアルキルポリグルコシドと組み合わせて使用されるときに特に有効であり、泡立ちも改善することができるため、好ましい。
a)式I:R1O(R2O)nR3
R1は直鎖若しくは分岐鎖のC4、C5若しくはC6アルキル、又は置換若しくは非置換フェニルであり、R2はエチル又はイソプロピルであり、R3は水素又はメチルであり、nは1、2又は3である。
b)式II:R4O(R5O)nR6
R4はn-プロピル又はイソプロピルであり、R5はイソプロピルであり、R6は水素又はメチルであり、nは、1、2又は3である。
c)これらの混合物
a)式R1C=OOR2を有するモノエステル
式中、R1は直鎖又は分岐鎖のC1~C4アルキルであり、R2は直鎖又は分岐鎖のC2~C8アルキルである。
b)式R1(C=OOR2)nを有するジ-又はトリ-エステル
R1は飽和又は不飽和のC2~C4アルキルであり、R2は、直鎖又は分岐鎖のC2~C8アルキルから独立に選択され、nは2又は3である。
c)安息香酸ベンジル、並びに
d)これらの混合物。
a)式I=R1O(R2O)nR3
(式中、
R1は直鎖又は分岐鎖のC4、C5又はC6アルキル、置換又は非置換フェニルであり、好ましくはn-ブチルである。ベンジルは、本明細書に用いるための置換フェニルのうちの1つである。
R2はエチル又はイソプロピル、好ましくはイソプロピルであり、
R3は水素又はメチル、好ましくは水素であり、
nは1、2又は3、好ましくは1又は2である。
b)式II=R4O(R5O)nR6
(式中、
R4はn-プロピル又はイソプロピル、好ましくはn-プロピルであり、
R5はイソプロピルであり、
R6は水素又はメチル、好ましくは水素であり、
nは1、2又は3、好ましくは1又は2である。
a)式(III):R1C=OOR2のモノエステル溶媒で、式中、
R1は直鎖又は分岐鎖のC1~C4アルキルであり、好ましくは直鎖又は分岐鎖のC2~C3アルキルである。
R2は、直鎖又は分岐鎖のC2~C8アルキル、好ましくは直鎖又は分岐鎖のC2~C6アルキル、最も好ましくは直鎖又は分岐鎖のC3~C4アルキルである。
b)式IV:R1(C=OOR2)nのジ-又はトリエステル溶媒で、式中、
R1は、飽和又は不飽和のC2~C4アルキルであり、
R2は、独立に、直鎖又は分岐鎖のC2~C8アルキル、好ましくは、直鎖又は分岐鎖のC2~C6アルキル、最も好ましくは、直鎖又は分岐鎖のC3~C4アルキルから選択される。
nは、2又は3であり、好ましくは2である。
キレート剤:
本明細書の組成物は、任意に、組成物の0.1重量%~10重量%、好ましくは0.2重量%~5重量%、より好ましくは0.2重量%~3重量%、最も好ましくは0.5重量%~1.5重量%の濃度でキレート剤を更に含んでもよい。
本明細書における組成物は、ビルダー、好ましくは、カルボキシレートビルダーを含み得る。本明細書で有用なカルボン酸の塩としては、C1~6の直鎖状の塩、又は少なくとも3個の炭素を含有する環状の酸の塩が挙げられる。カルボン酸又はその塩の直鎖又は環状炭素含有鎖は、ヒドロキシル、エステル、エーテル、1~6個、より好ましくは1~4個の炭素原子を有する脂肪族基、及びこれらの混合物からなる群から選択される置換基で置換されてよい。
本発明による組成物は、ヒドロトロープを更に含んでもよい。好ましくは、ヒドロトロープは、クメンスルホネート、キシレンスルホネート、トルエンスルホネート、最も好ましくはナトリウム中和クメンスルホネートから選択される。存在する場合、このヒドロトロープは、洗剤組成物の0.1重量%~5重量%、好ましくは0.25重量%~3重量%、最も好ましくは0.5重量%~2重量%配合される。
本発明による組成物は、レオロジー変性剤を更に含み、製品に剪断減粘レオロジープロファイルを提供し得る。レオロジー変性ポリマーを配合することにより、得られるスプレーの粒径分布を改善することができ、並びにスプレー液滴の刺痛感も軽減することができる。好ましくは、レオロジー変性剤は、非結晶質ポリマーレオロジー変性剤である。このポリマーレオロジー変性剤は、合成又は天然由来のポリマーであってよい。
本明細書の組成物は、無機塩(好ましくは塩化ナトリウム)、C2~C4アルコール、C2~C4ポリオール、ポリアルキレングリコール(及び特に1500~4000の重量平均分子量を有するポリプロピレングリコール)、及びこれらの混合物から選択されるレオロジー調整剤などの、多くの任意成分を含んでもよい。
スプレーディスペンサーは、本発明の組成物を収容するためのリザーバと、噴霧手段と、を含む。好適なスプレーディスペンサーとしては、ハンドポンプ(時に「トリガー」とも称される)装置、加圧缶装置、静電スプレー装置などが挙げられる。好ましくは、スプレーディスペンサーは非加圧であり、噴射手段はトリガー分注型である。リザーバは、典型的にはボトルなどの容器、より典型的にはプラスチックボトルである。
本明細書に記載される洗浄製品は、食器を洗浄する方法に特に好適であり、この方法は、任意に、食器を予め濡らす工程と、洗浄組成物を食器に噴霧する工程と、任意に、食器を擦り洗いする工程と、食器をすすぐ工程と、を含む。
A)予備アルカリ度(reserve alkalinity):
予備アルカリ度は、pH10の試験組成物を試験組成物のpHになるように滴定するのに必要なグラム(NaOH)/100g(組成物)として定義される。溶液の予備アルカリ度は以下のようにして測定される。
予備アルカリ度=mL(0.1N HCl)×0.1(当量/リットル)×当量NaOH(g/当量)×10
レオロジープロファイルは、円錐とプレートの構成(フラットなスチール製ペルチェプレート及び直径60mmで2.026°の円錐)を用いる「TA instruments DHR1」レオメーター(TA instruments、シリアル番号:SN960912)を使用して測定する。粘度測定手順は、20℃でのコンディショニング工程及びスイープ工程を含む。コンディショニング工程は、20℃でゼロ剪断で10秒、続いて20℃で10s-1で10秒間予剪断し、続いて20℃でゼロ剪断で30秒間、試料を平衡化させることからなる。スイープ工程は、20℃で0.01s-1から3,000s-1まで剪断速度を対数的に増大させ、サンプル時間15sで10当たり10点の取得速度、最大平衡化時間200秒で行う(公差3%に基づいて、レオメーターによって決定)。ずり流動化する製品組成物を測定する場合、高剪断粘度は1,000s-1の剪断速度で定義され、低剪断粘度は0.1s-1の剪断速度で定義される。ニュートン流体の製品組成物は、1000s-1での剪断速度が記録される。
様々な試験配合物の初期泡体積生成能力を相互比較できるように、これらの試験配合物を同じトリガー噴霧器内に順番に配置する。このトリガー噴霧器は、開口した500mLのメモリ付きコニカルビーカー(Kartell(登録商標)Art1424、コニカルビーカー)の中央頂部にスプレーノズルが位置付けられている状態で、45°の固定角度で保持されている。次に噴霧器ボトルは10回噴霧され、生成された泡体積の量(mL)、並びに噴霧された製品の総重量を測定する。泡体積を、噴霧された試料の重量で割った値を計算し、各製品-スプレーボトルの組み合わせについて3回の反復試験を平均する。
様々な試験配合物の結晶質グリース除去を相互比較できるように、試験配合物を、結晶質グリース状汚れを含む汚れた基材上に噴霧し、洗浄試験前及び後の汚れた基材の重量を測定することによって、洗浄試験後の除去率(%)を重量測定法で評価する。
プラスチック表面(Tupperware(登録商標)など)を模倣するため、不織ポリプロピレンプラスチック基材(#2866/6589 ex、Avgol Ltd(Tel Aviv、Israel))を使用し、この基材を4.5cm×4.5cmの正方形に切断し、この正方形試料の個々の重量を記録した。融解したグリース状汚れ(50℃)200μLを、マイクロピペットを使用してPP不織プラスチック基材の中央に適用し、室温で固化させた後、この正方形試料の重量を再測定して、正方形試料上に堆積した結晶質グリース状汚れの量を求めた。
各試験群について、3つのジャー(高さ125mm、直径77mm)それぞれに、所望の水硬度(2dH又は15dH)及び温度(25℃又は35℃)の水200mLを、3つの大理石球(直径15mm)と共に入れて、いくらかの機械的撹拌を行った。
Claims (15)
- スプレーディスペンサー及び洗浄組成物を含む洗浄製品であって、前記組成物は前記スプレーディスペンサーに収容されており、前記洗浄組成物が、
a.前記組成物の5重量%~25重量%の界面活性剤系であって、
i.アルキルポリグルコシド界面活性剤、
ii.両性界面活性剤、双性イオン性界面活性剤、及びこれらの混合物から選択される補助界面活性剤、及び
iii.前記洗浄組成物の3重量%未満のアニオン性界面活性剤、を含み、
前記アルキルポリグルコシド界面活性剤及び前記補助界面活性剤が、10:1~1:2の重量比で存在する、界面活性剤系と、
b.前記組成物の0.1重量%~10重量%の有機溶媒系と、を含む、洗浄組成物。 - 前記組成物が、前記組成物の7重量%~20重量%、好ましくは10重量%~15重量%の前記界面活性剤系を含む、請求項1に記載の洗浄製品。
- 前記洗浄組成物が、前記組成物の2.0重量%~12重量%、好ましくは2.5重量%~10重量%、より好ましくは3.0重量%~7.5重量%の濃度の前記アルキルポリグルコシドを含む、請求項1又は2に記載の洗浄製品。
- 前記アルキルポリグルコシド界面活性剤が、C8~C18、好ましくはC10~C16、より好ましくはC12~C14のアルキル鎖を含み、前記アルキルポリグルコシド界面活性剤が、0.1~3.0、好ましくは1.0~2.0、より好ましくは1.2~1.6の数平均重合度を有する、請求項1~3のいずれか一項に記載の洗浄製品。
- 前記洗浄組成物が、前記組成物の0.5重量%~5.0重量%、好ましくは1.0重量%~4.5重量%、より好ましくは2.0重量%~4.0重量%の前記補助界面活性剤を含む、請求項1~4のいずれか一項に記載の洗浄製品。
- 前記補助界面活性剤が、アミンオキシド界面活性剤から選択される両性界面活性剤であり、好ましくは、前記アミンオキシド界面活性剤が、アルキルジメチルアミンオキシド、アルキルアミドプロピルジメチルアミンオキシド、及びこれらの混合物からなる群から選択され、より好ましくはアルキルジメチルアミンオキシドである、請求項1~5のいずれか一項に記載の洗浄製品。
- 前記補助界面活性剤が、ベタイン界面活性剤から選択される双性イオン性界面活性剤であり、好ましくは、前記ベタイン界面活性剤が、コカミドプロピルベタイン、ココベタイン、ラウラミドプロピルベタイン、ラウリルベタイン、ミリスチルアミドプロピルベタイン、ミリスチルベタイン、及びこれらの混合物からなる群から選択され、好ましくはコカミドプロピルベタインである、請求項1~5のいずれか一項に記載の洗浄製品。
- 前記アルキルポリグルコシド界面活性剤及び前記補助界面活性剤が、1:1超~10:1、好ましくは1.5:1~5:1、より好ましくは2:1~3:1の重量比で存在する、請求項1~7のいずれか一項に記載の洗浄製品。
- 前記界面活性剤系が、更なる非イオン性界面活性剤を含み、好ましくは前記組成物の0.5重量%~10重量%、より好ましくは1.0重量%~5.0重量%、最も好ましくは1.5重量%~3.0重量%の濃度の更なる非イオン性界面活性剤を含む、請求項1~8のいずれか一項に記載の洗浄製品。
- 前記更なる非イオン性界面活性剤が、アルキルエトキシレート界面活性剤であり、好ましくは、平均アルキル鎖長がC10以下、好ましくはC5~C8、より好ましくはC5~C7であり、かつ数平均エトキシル化度が1~10、好ましくは3~8、より好ましくは4~6であるアルキルエトキシレート界面活性剤である、請求項9に記載の洗浄製品。
- 前記界面活性剤系が、前記洗浄組成物の2重量%未満、より好ましくは1重量%未満のアニオン性界面活性剤を含み、最も好ましくはアニオン性界面活性剤を含まない、請求項1~10のいずれか一項に記載の洗浄製品。
- 前記組成物が、前記組成物の1.0重量%~8.0重量%、好ましくは3.0重量%~7.0重量%の前記有機溶媒を含む、請求項1~11のいずれか一項に記載の洗浄製品。
- 前記有機溶媒が、グリコールエーテル溶媒、アルコール溶媒、エステル溶媒、及びこれらの混合物からなる群から選択され、より好ましくはグリコールエーテル溶媒である、請求項1~12のいずれか一項に記載の組成物。
- 界面活性剤系及び前記有機溶媒が、5:1~1:5、好ましくは4:1~1:2、最も好ましくは3:1~1:1の重量比で存在する、請求項1~13のいずれか一項に記載の洗浄製品。
- 請求項1~14のいずれか一項に記載の洗浄製品を使用して食器を洗浄する方法であって、
a)任意に、前記食器を予め濡らす工程と、
b)前記洗浄組成物を前記食器に噴霧する工程と、
c)任意に、前記食器を擦り洗いする工程と、
d)前記食器をすすぐ工程と、を含む、方法。
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PCT/US2020/064152 WO2021126643A1 (en) | 2019-12-17 | 2020-12-10 | Cleaning product |
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