JP2023012572A - Hair cosmetic composition - Google Patents
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- JP2023012572A JP2023012572A JP2021116064A JP2021116064A JP2023012572A JP 2023012572 A JP2023012572 A JP 2023012572A JP 2021116064 A JP2021116064 A JP 2021116064A JP 2021116064 A JP2021116064 A JP 2021116064A JP 2023012572 A JP2023012572 A JP 2023012572A
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- 239000000203 mixture Substances 0.000 title claims abstract description 71
- 239000002537 cosmetic Substances 0.000 title claims abstract description 64
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- GLSRFBDXBWZNLH-UHFFFAOYSA-L disodium;2-chloroacetate;2-(4,5-dihydroimidazol-1-yl)ethanol;hydroxide Chemical compound [OH-].[Na+].[Na+].[O-]C(=O)CCl.OCCN1CCN=C1 GLSRFBDXBWZNLH-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229940096501 sodium cocoamphoacetate Drugs 0.000 claims abstract description 5
- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940091855 sodium lauraminopropionate Drugs 0.000 claims abstract description 4
- HWCHICTXVOMIIF-UHFFFAOYSA-M sodium;3-(dodecylamino)propanoate Chemical compound [Na+].CCCCCCCCCCCCNCCC([O-])=O HWCHICTXVOMIIF-UHFFFAOYSA-M 0.000 claims abstract description 4
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims abstract description 3
- 230000037308 hair color Effects 0.000 claims description 21
- 239000000981 basic dye Substances 0.000 claims description 18
- 239000002280 amphoteric surfactant Substances 0.000 claims description 16
- 239000002736 nonionic surfactant Substances 0.000 claims description 13
- 238000011282 treatment Methods 0.000 claims description 10
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims description 9
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 235000002949 phytic acid Nutrition 0.000 claims description 9
- 239000000467 phytic acid Substances 0.000 claims description 9
- 229940068041 phytic acid Drugs 0.000 claims description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 8
- 239000003086 colorant Substances 0.000 claims description 8
- 239000003002 pH adjusting agent Substances 0.000 claims description 7
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 6
- 229930182478 glucoside Natural products 0.000 claims description 6
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 claims description 5
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 5
- 229940073499 decyl glucoside Drugs 0.000 claims description 5
- 239000004220 glutamic acid Substances 0.000 claims description 5
- 235000013922 glutamic acid Nutrition 0.000 claims description 5
- 239000003607 modifier Substances 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 4
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 4
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 235000003704 aspartic acid Nutrition 0.000 claims description 4
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 230000002335 preservative effect Effects 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 239000000600 sorbitol Substances 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- 102000008186 Collagen Human genes 0.000 claims description 3
- 108010035532 Collagen Proteins 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 239000004471 Glycine Substances 0.000 claims description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 3
- -1 alkyl glucoside Chemical class 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 3
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 claims description 3
- 235000015165 citric acid Nutrition 0.000 claims description 3
- 235000019864 coconut oil Nutrition 0.000 claims description 3
- 239000003240 coconut oil Substances 0.000 claims description 3
- 229920001436 collagen Polymers 0.000 claims description 3
- 150000008131 glucosides Chemical class 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 229940075468 lauramidopropyl betaine Drugs 0.000 claims description 3
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 claims description 3
- 229940048848 lauryl glucoside Drugs 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- 229940097941 polyglyceryl-10 laurate Drugs 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 14
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 abstract description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 abstract description 2
- 239000013543 active substance Substances 0.000 abstract description 2
- 229960003237 betaine Drugs 0.000 abstract description 2
- 238000004043 dyeing Methods 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 241000047703 Nonion Species 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 21
- 125000000129 anionic group Chemical group 0.000 description 15
- 230000014759 maintenance of location Effects 0.000 description 14
- 239000000975 dye Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000118 hair dye Substances 0.000 description 6
- 230000003595 spectral effect Effects 0.000 description 5
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 4
- JDRSMPFHFNXQRB-IBEHDNSVSA-N decyl glucoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JDRSMPFHFNXQRB-IBEHDNSVSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003676 hair preparation Substances 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 238000005562 fading Methods 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 210000004761 scalp Anatomy 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- 150000004967 organic peroxy acids Chemical class 0.000 description 2
- 239000001024 permanent hair color Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- NZDXSXLYLMHYJA-UHFFFAOYSA-M 4-[(1,3-dimethylimidazol-1-ium-2-yl)diazenyl]-n,n-dimethylaniline;chloride Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1N=NC1=[N+](C)C=CN1C NZDXSXLYLMHYJA-UHFFFAOYSA-M 0.000 description 1
- 240000006890 Erythroxylum coca Species 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- RFQSMLBZXQOMKK-UHFFFAOYSA-N [3-[(4,8-diamino-6-bromo-1,5-dioxonaphthalen-2-yl)amino]phenyl]-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)C1=CC=CC(NC=2C(C3=C(N)C=C(Br)C(=O)C3=C(N)C=2)=O)=C1 RFQSMLBZXQOMKK-UHFFFAOYSA-N 0.000 description 1
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 description 1
- UXEAWNJALIUYRH-UHFFFAOYSA-N [8-[(4-aminophenyl)hydrazinylidene]-7-oxonaphthalen-2-yl]-trimethylazanium;chloride Chemical compound [Cl-].C12=CC([N+](C)(C)C)=CC=C2C=CC(=O)\C1=N/NC1=CC=C(N)C=C1 UXEAWNJALIUYRH-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 235000008957 cocaer Nutrition 0.000 description 1
- ZPUCINDJVBIVPJ-LJISPDSOSA-N ***e Chemical compound O([C@H]1C[C@@H]2CC[C@@H](N2C)[C@H]1C(=O)OC)C(=O)C1=CC=CC=C1 ZPUCINDJVBIVPJ-LJISPDSOSA-N 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
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- 238000009472 formulation Methods 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
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- 229940070765 laurate Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LLLILZLFKGJCCV-UHFFFAOYSA-M n-methyl-n-[(1-methylpyridin-1-ium-4-yl)methylideneamino]aniline;methyl sulfate Chemical compound COS([O-])(=O)=O.C=1C=CC=CC=1N(C)\N=C\C1=CC=[N+](C)C=C1 LLLILZLFKGJCCV-UHFFFAOYSA-M 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
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- 229940086560 pentaerythrityl tetrastearate Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000001026 semi permanent hair color Substances 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、毛髪化粧料組成物及び当該毛髪化粧料組成物を含む毛髪化粧料に関し、特に、色もちに優れる毛髪化粧料組成物及び当該毛髪化粧料組成物を含む毛髪化粧料に関する。 TECHNICAL FIELD The present invention relates to a hair cosmetic composition and a hair cosmetic containing the hair cosmetic composition, and more particularly to a hair cosmetic composition having excellent long-lasting color and a hair cosmetic containing the hair cosmetic composition.
ヘアカラーリングとして、主として、医薬部外品の永久染毛料であるヘアカラーと、化粧品の半永久染毛料であるヘアマニキュアやヘアカラートリートメント等がある。特に、永久染毛料のヘアカラーにはパラフェニレンジアミン（酸化染料）という物質が含まれるものが主流となっているが、黒色系の濃色の場合はジアミン系化合物の配合量が多くなるので更に注意が必要となっている。 Hair coloring mainly includes hair coloring, which is a quasi-drug permanent hair dye, and hair manicure and hair color treatment, which are semi-permanent hair dyes of cosmetics. In particular, most permanent hair dyes contain a substance called paraphenylenediamine (oxidation dye). Caution is required.
例えば、パラフェニレンジアミン(酸化染料)を含むヘアカラーリング組成物として、（ａ）水溶性過酸素ブリーチ；（ｂ）有機ペルオキシ酸ブリーチ前駆体及び／又は予め形成された有機ペルオキシ酸から選択されたブリーチング助剤；並びに、（ｃ）１以上のヘアカラーリング剤を含むことを特徴とするヘアカラーリング組成物が知られている(特許文献１)。 For example, hair coloring compositions containing paraphenylenediamine (oxidative dye) selected from (a) water-soluble peroxygen bleach; (b) organic peroxyacid bleach precursors and/or preformed organic peroxyacids; A hair coloring composition comprising a bleaching aid; and (c) one or more hair coloring agents is known (Patent Document 1).
しかしながら、上記特許文献１も含め、従来技術においては、パラフェニレンジアミン（酸化染料）を含むものは、上述のように黒色系の濃色の場合はジアミン系化合物の配合量が多くなるので更に注意が必要となっている以外に、近年、パラフェニレンジアミン（酸化染料）という物質が原因で皮膚障害が報告されている。 However, in the prior art, including the above-mentioned Patent Document 1, in the case of the dye containing paraphenylenediamine (oxidation dye), the amount of the diamine-based compound is increased in the case of dark black color as described above, so be careful. In recent years, skin disorders have been reported due to a substance called paraphenylenediamine (oxidation dye).
また、半永久染毛料のヘアマニキュアは１回の使用で色素（酸性染料）が髪の内部まで浸透し２～３週間の色持ちが特徴であるが、頭皮に付着し放置時間が長くなれば長くなるほど染まった色素が取れにくくなり、施術する側では生え際ギリギリまで塗布するのが難しく、施術者の技量の割にはヘアカラーに比べて染まりが悪いためサロンや美容室では敬遠されがちな染毛料となっている。 In addition, semi-permanent hair manicures are characterized by the pigment (acid dye) penetrating into the hair with one use and the color lasting for 2 to 3 weeks, but if it adheres to the scalp and is left for a long time, it will last longer. Indeed, it is difficult to remove the dyed pigment, and it is difficult for the practitioner to apply it to the very last minute of the hairline. It has become.
一方で、上述のヘアカラーでは、コルテックス（毛皮質。毛髪の内部）までしっかり染めることができるが、ヘアカラートリートメントでは、キューティクル（毛小皮）及び毛髪表面近くのコルテックスを染めるもので、十分に色もちが良いヘアカラーを達成できない場合もあった。 On the other hand, with the above-mentioned hair coloring, even the cortex (cortex, the inside of the hair) can be thoroughly dyed. In some cases, it was not possible to achieve a sufficiently long-lasting hair color.
そこで、本発明は、毛髪染料を行う上で、より色もちが良い毛髪化粧料組成物及び毛髪化粧料を提供することを目的とする。 Accordingly, an object of the present invention is to provide a hair cosmetic composition and a hair cosmetic that have better color retention when dyeing hair.
上記目的を達成するために、本発明者らは、ヘアカラートリートメントの前後の処理について鋭意検討した結果、本発明を見出すに至った。 In order to achieve the above object, the present inventors have made intensive studies on treatments before and after hair color treatment, and as a result, have found the present invention.
すなわち、本発明の毛髪化粧料組成物は、両性界面活性剤と、非イオン（ノニオン）性界面活性剤と、アルカリ剤、ｐH調整剤とを有することを特徴とする。 That is, the hair cosmetic composition of the present invention is characterized by comprising an amphoteric surfactant, a nonionic surfactant, an alkaline agent, and a pH adjuster.
また、本発明の毛髪化粧料組成物の好ましい実施態様において、前記両性界面活性剤は、ココアンホ酢酸Na、ラウラミノプロピオン酸Ｎａ、コカミドプロピルベタイン、ラウラミドプロピルベタイン、又はラウリルヒドロキシスルタインから選択される少なくとも1種であることを特徴とする。 In a preferred embodiment of the hair cosmetic composition of the present invention, the amphoteric surfactant is selected from sodium cocoamphoacetate, sodium lauraminopropionate, cocamidopropyl betaine, lauramidopropyl betaine, or laurylhydroxysultaine. It is characterized by being at least one kind of
また、本発明の毛髪化粧料組成物の好ましい実施態様において、前記非イオン（ノニオン）性界面活性剤は、デシルグルコシド、（カプリリル／カプリル）グルコシド、ヤシ油アルキルグルコシド、ラウリルグルコシド、又はラウリン酸ポリグリセリル－１０から選択される少なくとも1種であることを特徴とする。 In a preferred embodiment of the hair cosmetic composition of the present invention, the nonionic surfactant is decyl glucoside, (caprylyl/capryl) glucoside, coconut oil alkyl glucoside, lauryl glucoside, or polyglyceryl laurate. It is characterized by being at least one selected from -10.
また、本発明の毛髪化粧料組成物の好ましい実施態様において、前記アルカリ剤は、テトラヒドロキシプロピルエチレンジアミン、トリエタノールアミン、水酸化ナトリウム、水酸化カリウム、又はアンモニア水から選択される少なくとも1種であることを特徴とする。 In a preferred embodiment of the hair cosmetic composition of the present invention, the alkaline agent is at least one selected from tetrahydroxypropylethylenediamine, triethanolamine, sodium hydroxide, potassium hydroxide, and aqueous ammonia. It is characterized by
また、本発明の毛髪化粧料組成物の好ましい実施態様において、前記ｐH調整剤は、リン酸、グリオキシル酸、乳酸、フィチン酸、クエン酸、リンゴ酸、コハク酸、グルタミン酸、アスパラギン酸、又は酒石酸から選択される少なくとも1種であることを特徴とする。 In a preferred embodiment of the hair cosmetic composition of the present invention, the pH adjuster is phosphoric acid, glyoxylic acid, lactic acid, phytic acid, citric acid, malic acid, succinic acid, glutamic acid, aspartic acid, or tartaric acid. It is characterized by being at least one selected.
また、本発明の毛髪化粧料組成物の好ましい実施態様において、さらに、塩化ナトリウム、グリシン、ソルビトール、加水分解コラーゲン、塩化カリウム、エデト酸類、又はエチドロン酸類から選択される少なくとも1種の改質剤を含有することを特徴とする。 In a preferred embodiment of the hair cosmetic composition of the present invention, at least one modifier selected from sodium chloride, glycine, sorbitol, hydrolyzed collagen, potassium chloride, edetic acids, or etidronic acids is further added. characterized by containing
また、本発明の毛髪化粧料組成物の好ましい実施態様において、前記毛髪化粧料組成物は、塩基性染料処理後に毛髪に適用するためのものであることを特徴とする。 In a preferred embodiment of the hair cosmetic composition of the present invention, the hair cosmetic composition is characterized in that it is for application to hair after treatment with a basic dye.
また、本発明の毛髪化粧料は、本発明の毛髪化粧料組成物を含むことを特徴とする。 Moreover, the hair cosmetics of this invention are characterized by including the hair cosmetics composition of this invention.
また、本発明のカラートリートメント方法は、塩基性染料と、増粘剤と、防腐剤とを含有するヘアカラー剤を塗布する工程と、本発明の毛髪化粧料組成物を適用する工程と、からなることを特徴とする。 Further, the color treatment method of the present invention comprises the steps of applying a hair coloring agent containing a basic dye, a thickener and a preservative, and applying the hair cosmetic composition of the present invention. characterized by becoming
本発明の毛髪化粧料組成物によれば、高齢化でヘアカラーの使用期間が長くなる可能性を秘めているため安心して使える色持ちの良く、また施術する側でも安心して頭皮への付着を気にせず新生部まで塗布出来るヘアカラー製品を提供することが可能であるという有利な効果を奏する。 According to the hair cosmetic composition of the present invention, since there is a possibility that the use period of hair color will be prolonged due to aging, the hair color can be used safely and has good color retention, and the hair cosmetic composition can be used safely on the scalp. There is an advantageous effect that it is possible to provide a hair color product that can be applied even to the nascent part without worrying about it.
本発明の毛髪化粧料組成物は、両性界面活性剤と、非イオン（ノニオン）性界面活性剤と、アルカリ剤と、ｐH調整剤とを有することを特徴とする。健康な毛髪のｐHは、およそ４．５～５．５の範囲であり、一般に、毛髪のイオン性は平衡に保たれている。本発明においては、両性界面活性剤と、非イオン（ノニオン）性界面活性剤との併用により、ヘアカラー剤を適用後に本発明の毛髪化粧料組成物を適用することにより、前記ヘアカラー剤の色持ちを良くすることが可能となる。 The hair cosmetic composition of the present invention is characterized by comprising an amphoteric surfactant, a nonionic surfactant, an alkaline agent, and a pH adjuster. The pH of healthy hair is in the approximate range of 4.5-5.5 and generally the ionic nature of hair is balanced. In the present invention, by using an amphoteric surfactant and a nonionic surfactant in combination, the hair cosmetic composition of the present invention is applied after applying the hair coloring agent, thereby reducing the effect of the hair coloring agent. It is possible to improve the color durability.
本発明の毛髪化粧料組成物のｐＨ値としては、染料の色持ちや毛髪の色調という観点から、好ましくは5.0～6.5、より好ましくは、5.5～6.0に調整することができる。 The pH value of the hair cosmetic composition of the present invention can be adjusted to preferably 5.0 to 6.5, more preferably 5.5 to 6.0, from the viewpoint of the color retention of the dye and the tone of the hair.
また、本発明の毛髪化粧料組成物の好ましい実施態様において、前記両性界面活性剤は、特に限定されないが、起泡・洗浄力という観点から、例えば、ココアンホ酢酸Na、ラウラミノプロピオン酸Ｎａ、コカミドプロピルベタイン、ラウラミドプロピルベタイン、又はラウリルヒドロキシスルタインから選択される少なくとも1種であることを特徴とする。また、前記両性界面活性剤の量としては、特に限定されないが、洗浄及び乾燥後の指通りという観点から、組成物の合計量に対して、好ましくは１～２０質量％、より好ましくは３～１５質量％とすることができる。 In a preferred embodiment of the hair cosmetic composition of the present invention, the amphoteric surfactant is not particularly limited, but from the viewpoint of foaming and detergency, examples include sodium cocoamphoacetate, sodium lauraminopropionate, coca It is characterized by being at least one selected from midopropyl betaine, lauramidopropyl betaine, and lauryl hydroxysultaine. In addition, the amount of the amphoteric surfactant is not particularly limited, but from the viewpoint of finger combability after washing and drying, it is preferably 1 to 20% by mass, more preferably 3 to 20% by mass, based on the total amount of the composition. It can be 15% by mass.
また、本発明の毛髪化粧料組成物の好ましい実施態様において、前記非イオン（ノニオン）性界面活性剤は、泡立ちという観点から、デシルグルコシド、（カプリリル／カプリル）グルコシド、ヤシ油アルキルグルコシド、ラウリルグルコシド、又はラウリン酸ポリグリセリル－１０から選択される少なくとも1種であることを特徴とする。前記非イオン（ノニオン）性界面活性剤の量としては、特に限定されないが、洗浄力という観点から、組成物の合計量に対して、好ましくは１～２０質量％、より好ましくは３～１５質量％とすることができる。 In a preferred embodiment of the hair cosmetic composition of the present invention, the nonionic surfactant is decyl glucoside, (caprylyl/capryl) glucoside, coconut oil alkyl glucoside, lauryl glucoside, from the viewpoint of lathering. , or polyglyceryl-10 laurate. The amount of the nonionic (nonionic) surfactant is not particularly limited, but from the viewpoint of detergency, it is preferably 1 to 20% by mass, more preferably 3 to 15% by mass, based on the total amount of the composition. %.
また、本発明の毛髪化粧料組成物の好ましい実施態様において、前記アルカリ剤は、経時的な毛髪の色調という観点から、テトラヒドロキシプロピルエチレンジアミン、トリエタノールアミン、水酸化ナトリウム、水酸化カリウム、又はアンモニア水から選択される少なくとも1種であることを特徴とする。前記アルカリ剤の量としては、特に限定されないが、刺激という観点から、組成物の合計量に対して、好ましくは0.01～５質量％、より好ましくは0.1～3質量％とすることができる。 In a preferred embodiment of the hair cosmetic composition of the present invention, the alkaline agent is tetrahydroxypropylethylenediamine, triethanolamine, sodium hydroxide, potassium hydroxide, or ammonia, from the viewpoint of hair color tone over time. It is characterized by being at least one selected from water. The amount of the alkaline agent is not particularly limited, but from the viewpoint of stimulation, it is preferably 0.01 to 5% by mass, more preferably 0.1 to 3% by mass, based on the total amount of the composition.
また、本発明の毛髪化粧料組成物の好ましい実施態様において、前記ｐH調整剤は、染料の色持ちという観点から、リン酸、グリオキシル酸、乳酸、フィチン酸、クエン酸、リンゴ酸、コハク酸、グルタミン酸、アスパラギン酸、又は酒石酸から選択される少なくとも1種であることを特徴とする。前記ｐH調整剤の量としては、特に限定されないが、経時的な毛髪の色調という観点から、組成物の合計量に対して、好ましくは0.01～３質量％、より好ましくは0.1～２質量％とすることができる。 In a preferred embodiment of the hair cosmetic composition of the present invention, the pH adjuster includes phosphoric acid, glyoxylic acid, lactic acid, phytic acid, citric acid, malic acid, succinic acid, It is characterized by being at least one selected from glutamic acid, aspartic acid, and tartaric acid. The amount of the pH adjuster is not particularly limited, but from the viewpoint of the color tone of the hair over time, it is preferably 0.01 to 3% by mass, more preferably 0.1 to 2% by mass, based on the total amount of the composition. can do.
また、本発明の毛髪化粧料組成物の好ましい実施態様において、褪色抑制効果という観点から、さらに、塩化ナトリウム、グリシン、ソルビトール、加水分解コラーゲン、塩化カリウム、エデト酸類、又はエチドロン酸類から選択される少なくとも1種の改質剤を含有することを特徴とする。前記改質剤の量としては、特に限定されないが、褪色改良という観点から、組成物の合計量に対して、好ましくは0.１～３0質量％、より好ましくは1～２0質量％とすることができる。 Further, in a preferred embodiment of the hair cosmetic composition of the present invention, from the viewpoint of suppressing discoloration, at least one selected from sodium chloride, glycine, sorbitol, hydrolyzed collagen, potassium chloride, edetic acids, and etidronic acids is added. It is characterized by containing one modifier. The amount of the modifier is not particularly limited, but from the viewpoint of improving fading, it is preferably 0.1 to 30% by mass, more preferably 1 to 20% by mass, based on the total amount of the composition. can be done.
また、本発明の毛髪化粧料組成物の好ましい実施態様において、前記毛髪化粧料組成物は、塩基性染料処理後に毛髪に適用するためのものであることを特徴とする。すなわち、本発明の毛髪化粧料組成物において、当該毛髪化粧料組成物中に含まれる両性界面活性剤、及び非イオン（ノニオン）性界面活性剤により、前記ヘアカラー剤、すなわち、塩基性染料の色持ちを良くすることが可能となる。すなわち、上述のように健康な毛髪のｐHは、およそ4.5～5.5の範囲であり、一般に毛髪のイオン性は平衡に保たれているが、毛髪化粧料組成物のｐHが中性付近では、両性界面活性剤は、両性+陰イオン(アニオン)性であるため毛髪化粧料組成物内はマイナスイオンが多く存在し、塩基性染料のプラスイオンと引き合うことになる。塩基性染料はプラスに帯電しているため、仮に陰イオン(アニオン)性界面活性剤が含まれている場合には、当該陰イオン（アニオン）性界面活性剤の親水基がマイナスのイオン性を示し、染料を取り去る虞がある。これに対して、本発明のおいて使用する両性界面活性剤は、プラス及びマイナスの両方の性質を有するが、酸性域では、カチオン性を、アルカリ性域ではアニオン性を示す。また、非イオン（ノニオン）性界面活性剤の場合には、そもそも染料に影響を及ぼす物ではない。このようなことから、特に、染料、特に塩基性染料を使用した場合に、当該毛髪化粧料組成物中に含まれる両性界面活性剤、及び非イオン（ノニオン）性界面活性剤の使用により、染料の色持ちを良くすることが可能となることを本発明者らは見いだしたものである。 In a preferred embodiment of the hair cosmetic composition of the present invention, the hair cosmetic composition is characterized in that it is for application to hair after treatment with a basic dye. That is, in the hair cosmetic composition of the present invention, the amphoteric surfactant and nonionic surfactant contained in the hair cosmetic composition allow the hair coloring agent, that is, the basic dye to It is possible to improve the color durability. That is, as described above, the pH of healthy hair is in the range of about 4.5 to 5.5, and the ionicity of hair is generally balanced. Surfactants are amphoteric and anionic (anionic), so many negative ions are present in the hair cosmetic composition, and attract positive ions of the basic dye. Since basic dyes are positively charged, if an anionic (anionic) surfactant is contained, the hydrophilic group of the anionic (anionic) surfactant will have negative ionicity. may show up and take away the dye. On the other hand, the amphoteric surfactant used in the present invention has both positive and negative properties, but exhibits cationic properties in the acidic range and anionic properties in the alkaline range. Also, in the case of nonionic surfactants, they do not affect dyes in the first place. For this reason, especially when dyes, especially basic dyes, are used, the use of amphoteric surfactants and nonionic surfactants contained in the hair cosmetic composition allows dyes The present inventors have found that it is possible to improve the color retention of the color.
また、本発明の毛髪化粧料は、本発明の毛髪化粧料組成物を含むことを特徴とする。 Moreover, the hair cosmetics of this invention are characterized by including the hair cosmetics composition of this invention.
また、本発明のカラートリートメント方法は、塩基性染料と、増粘剤と、防腐剤とを含有するヘアカラー剤を塗布する工程と、本発明の毛髪化粧料組成物を適用する工程と、からなることを特徴とする。本発明において、塩基性染料としては、特に限定されないが、染色性という観点から、塩基性茶１６、塩基性青９９、塩基性赤５１、塩基性黄８７等を挙げることができる。前記塩基性染料の量としては、特に限定されないが、毛髪へのダメージという観点から、組成物の合計量に対して、好ましくは0.0005～5質量％、より好ましくは0.1～1質量％とすることができる。 Further, the color treatment method of the present invention comprises the steps of applying a hair coloring agent containing a basic dye, a thickener and a preservative, and applying the hair cosmetic composition of the present invention. characterized by becoming In the present invention, the basic dye is not particularly limited, but from the viewpoint of dyeability, basic brown 16, basic blue 99, basic red 51, basic yellow 87, and the like can be mentioned. The amount of the basic dye is not particularly limited, but from the viewpoint of hair damage, it is preferably 0.0005 to 5% by mass, more preferably 0.1 to 1% by mass, based on the total amount of the composition. can be done.
また、本発明において、増粘剤としては、特に限定されないが、泡立ちの増強や増粘という観点から、テトラステアリン酸ＰＥＧ－１５０ペンタエリスリチル、コカミドメチルＭＥＡ、コカミドＤＥＡ等を挙げることができる。前記塩基性染料の量としては、特に限定されないが、泡の安定性という観点から、組成物の合計量に対して、好ましくは0.１～１0質量％、より好ましくは0.3～7質量％とすることができる。 In the present invention, the thickening agent is not particularly limited, but from the viewpoint of enhancing foaming and increasing viscosity, PEG-150 pentaerythrityl tetrastearate, cocamide methyl MEA, cocamide DEA and the like can be mentioned. The amount of the basic dye is not particularly limited, but from the viewpoint of foam stability, it is preferably 0.1 to 10% by mass, more preferably 0.3 to 7% by mass, based on the total amount of the composition. can do.
また、本発明において、防腐剤としては、特に限定されないが、頭皮への負担という観点から、安息香酸ナトリウム、メチルパラベン、フェノキシエタノール等を挙げることができる。前記塩基性染料の量としては、特に限定されないが、製品の安定性という観点から、組成物の合計量に対して、好ましくは0.01～１質量％、より好ましくは0.1～0.8質量％とすることができる。 In the present invention, the antiseptic is not particularly limited, but from the viewpoint of stress on the scalp, sodium benzoate, methylparaben, phenoxyethanol and the like can be mentioned. The amount of the basic dye is not particularly limited, but from the viewpoint of product stability, it is preferably 0.01 to 1% by mass, more preferably 0.1 to 0.8% by mass, based on the total amount of the composition. can be done.
また、毛髪化粧料組成物については、上述の本発明の毛髪化粧料組成物の説明を参照することができる。 Further, with regard to the hair cosmetic composition, reference can be made to the above description of the hair cosmetic composition of the present invention.
以下では本発明の一実施例を説明するが、本発明は、下記の実施例に限定して解釈されるものではない。 An example of the present invention will be described below, but the present invention should not be construed as being limited to the example below.
実施例１
まず、試験用毛束サンプル１）を作成した。塩基性染料を用いての染毛毛束作製については以下の通りである。人毛白髪100% (1g X 1cm)(品番:BM-W-A,ビューラックス社製）の毛束に処方１の染毛料（ヘアカラー剤）を塗布してラップし後、定温乾燥器（型式：SDN27P、（株）三商）を用いて４０℃、３０分放置後、本発明の毛髪化粧料組成物を適用（洗浄）した後に乾燥させて試験用毛束サンプル１)とした。処方１の内容を表１に示す。処方１の染毛料において、ヒドロキシエチルセルロースは増粘剤として使用し、また、メチルパラベンは防腐剤として、使用している。染毛料のｐＨは６．８以上に調整した。
Example 1
First, a test hair bundle sample 1) was prepared. Preparation of a dyed hair tress using a basic dye is as follows. 100% white human hair (1g X 1cm) (product number: BM-WA, manufactured by Beaulux) was coated with the hair dye (hair coloring agent) of formula 1, wrapped, and dried in a constant temperature dryer (model: SDN27P (Sansho Co., Ltd.) was used to leave the hair at 40°C for 30 minutes, then the hair cosmetic composition of the present invention was applied (washed) and dried to prepare a hair tress sample 1) for test. The contents of Formula 1 are shown in Table 1. In the formulation 1 hair dye, hydroxyethylcellulose is used as a thickening agent and methylparaben is used as a preservative. The pH of the hair dye was adjusted to 6.8 or higher.
また、適用した本発明の毛髪化粧料組成物の成分表を、表２に示す。 Table 2 shows the component table of the applied hair cosmetic composition of the present invention.
なお、表２において、A)、D）、F）、及びH)の入手先の情報は、以下の通りである。A)ソフタゾリン CL-R（川研ファインケミカル（株）製）、D)Plantacare 2000 UP(BASFジャパン（株）製）、F)アデカカーポール MD-100(（株）ＡＤＥＫＡ製)、H)ニッピペプタイドCQT-F01-G(（株）ニッピ製)である。 In addition, in Table 2, information on where to obtain A), D), F), and H) is as follows. A) Softazolin CL-R (manufactured by Kawaken Fine Chemicals Co., Ltd.), D) Plantacare 2000 UP (manufactured by BASF Japan Co., Ltd.), F) ADEKACARPOL MD-100 (manufactured by ADEKA Co., Ltd.), H) Nippi Peptide It is CQT-F01-G (manufactured by Nippi Co., Ltd.).
作成した一例における本発明の毛髪化粧料組成物は、外観は淡黄色～黄褐色の液体、ｐＨは5.8程度、粘度は2,300mPa・sであった。本発明においては、陰イオン(アニオン)性界面活性剤を使わず、両性界面活性剤として、ココアンホ酢酸Naを、非イオン(ノニオン)性界面活性剤として、デシルグルコシドを用いた。 The hair cosmetic composition of the present invention in one example prepared had a pale yellow to yellowish brown liquid appearance, a pH of about 5.8, and a viscosity of 2,300 mPa·s. In the present invention, no anionic (anionic) surfactant was used, and sodium cocoamphoacetate was used as an amphoteric surfactant, and decyl glucoside was used as a nonionic (nonionic) surfactant.
次に、本発明の毛髪化粧料組成物を用いて、ヘアカラー剤の色保持性、すなわち褪色抑制効果について調べた。具体的には、上述のように用意した試験用毛束サンプル１）について分光色彩計（型式：SD6000、日本電色工業（株）製）を用いて測色した。その結果を、表３に示す。 Next, using the hair cosmetic composition of the present invention, the color retention properties of the hair coloring agent, that is, the effect of suppressing fading was examined. Specifically, the color of the test hair bundle sample 1) prepared as described above was measured using a spectral colorimeter (model: SD6000, manufactured by Nippon Denshoku Industries Co., Ltd.). The results are shown in Table 3.
実施例２
次に、実施例１の試験用毛束サンプル１）を用いて、陰イオン（アニオン）性界面活性剤と、非イオン（ノニオン）性界面活性剤とを用いた場合の比較を行った。実施例２、比較例１及び２について、毛髪化粧料組成物を、pH5.0付近に調整し、染毛した試験用毛束サンプル１）を各々の試験管に入れ、下記表４に示す
成分を有する実施例２、比較例１及び２の毛髪化粧料組成物を２５ｇを注入し、プログラム低温恒温器（型式：IN804型、ヤマト科学（株）製）を用いて２５℃、２４時間放置後、すすぎ・乾燥させて分光色彩計（型式：SD6000、日本電色工業（株）製）を用いて測色した。比較例1は、陰イオン(アニオン)性界面活性剤と両性界面活性剤の組み合わせで、陰イオン(アニオン)性界面活性剤として広く使われているポリオキシエチレンアルキルエーテル硫酸塩のラウレス硫酸Ｎａを使用した例である。また、比較例2は、陰イオン(アニオン)性界面活性剤と両性界面活性剤の組み合わせて、陰イオン(アニオン)性界面活性剤のアミノ酸系活性剤とて広く使われているココイルグルタミン酸ＴＥＡを使用した例である。また、実施例２は、非イオン(ノニオン)性界面活性剤と両性界面活性剤の組み合わせて、非イオン(ノニオン)性界面活性剤として起泡性に優れたアルキルポリグルコシドタイプのデシルグルコシドを使用した例である。表４に、各実施例２、比較例１及び２に用いた成分及び配合量等を示す。
Example 2
Next, using the test hair bundle sample 1) of Example 1, a comparison was made between the anionic (anionic) surfactant and the nonionic (nonionic) surfactant. For Example 2 and Comparative Examples 1 and 2, the hair cosmetic composition was adjusted to around pH 5.0, dyed test hair tress samples 1) were placed in respective test tubes, and the components shown in Table 4 below were added. 25 g of the hair cosmetic compositions of Example 2 and Comparative Examples 1 and 2 having , rinsed and dried, and colorimetrically measured using a spectral colorimeter (model: SD6000, manufactured by Nippon Denshoku Industries Co., Ltd.). Comparative Example 1 is a combination of an anionic surfactant and an amphoteric surfactant. This is the example used. In Comparative Example 2, cocoyl glutamic acid TEA, which is widely used as an amino acid-based active agent for anionic (anionic) surfactants, was used as a combination of an anionic (anionic) surfactant and an amphoteric surfactant. This is the example used. In addition, in Example 2, a nonionic (nonionic) surfactant and an amphoteric surfactant are combined, and alkyl polyglucoside type decylglucoside with excellent foaming properties is used as the nonionic (nonionic) surfactant. This is an example of Table 4 shows the components used in each of Example 2 and Comparative Examples 1 and 2, their blending amounts, and the like.
なお、表4において、A)～E)の入手先の情報は、以下の通りである。A)ソフタゾリン CL-R（川研ファインケミカル（株）製）、B)エマール327（花王（株）製）、C)アミソフトCT-12S(味の素（株）製）、D)Plantacare 2000 UP(BASFジャパン（株）製）、E)カチナール HC-200(東邦化学工業（株）製)である。 In Table 4, the information on where to obtain A) to E) is as follows. A) Softazolin CL-R (manufactured by Kawaken Fine Chemicals Co., Ltd.), B) Emal 327 (manufactured by Kao Corporation), C) Amisoft CT-12S (manufactured by Ajinomoto Co., Ltd.), D) Plantacare 2000 UP (BASF Japan Ltd.) and E) Catinal HC-200 (manufactured by Toho Chemical Industry Co., Ltd.).
また、同様に、実施例２、比較例１及び２に適用した試験用毛束サンプル１）について分光色彩計（型式：SD6000、日本電色工業（株）製）を用いて測色した。その結果を、表５に示す。 Similarly, the test hair bundle samples 1) applied to Example 2 and Comparative Examples 1 and 2 were measured using a spectral colorimeter (model: SD6000, manufactured by Nippon Denshoku Industries Co., Ltd.). The results are shown in Table 5.
その結果、非イオン(ノニオン)性界面活性剤と両性界面活性剤の組み合わせによる実施例２において、色差が17.29と小さく、色保持性、すなわち褪色抑制効果が優れていることが分かった。 As a result, it was found that in Example 2, in which a nonionic surfactant and an amphoteric surfactant were combined, the color difference was as small as 17.29, indicating excellent color retention, that is, excellent anti-fading effect.
実施例３
次に、非イオン(ノニオン)性界面活性剤を含む染料を用意して、試験用毛束サンプル２）を作成した。人毛白髪100% (1g X 1cm)(品番:BM-W-A,ビューラックス社製）の毛束を試験管に入れ処方２の染毛料を２５ｇ分注し、プログラム低温恒温器（型式：IN804型、ヤマト科学（株）製）を用いて２５℃、２０分静置後、本発明の毛髪化粧料組成物で洗浄した後に乾燥させて試験用毛束サンプル２)とした。処方１の内容を表６に示す。
Example 3
Next, a hair tress sample 2) for testing was prepared by preparing a dye containing a nonionic surfactant. Put a bundle of 100% white human hair (1g X 1cm) (product number: BM-WA, manufactured by Beaulux) in a test tube, add 25g of the hair dye of recipe 2, and place it in a programmed low-temperature thermostat (model: IN804). , manufactured by Yamato Scientific Co., Ltd.), allowed to stand at 25° C. for 20 minutes, washed with the hair cosmetic composition of the present invention, and dried to obtain hair tress sample 2) for test. The contents of Formula 1 are shown in Table 6.
なお、表６中のD)の入手先の情報は、以下の通りである。D)Plantacare 2000 UP(BASFジャパン（株）製）である。 The information on where to obtain D) in Table 6 is as follows. D) Plantacare 2000 UP (manufactured by BASF Japan Ltd.).
実施例４～１２
次に、ｐH調整剤として適用可能な無機酸及び有機酸を広く調べた。すなわち、配合する無機酸および有機酸によって色保持性に変化があるか実施例４～１２の各成分を有する毛髪化粧料組成物をｐH４．５付近に調整し、定温乾燥器（型式：SDN27P、（株）三商）を用いて４０℃、６０分放置した。放置中に試験管に上述したように用意した試験用毛束サンプル２）を入れ、放置後各々の試験管に２５ｇ分注し、４０℃、３０分放置した。すすぎ・乾燥後、目視で色保持性を比較した。フィチン酸の他、グルタミン酸とアスパラギン酸について色保持性が良いことが判明した。また、最も色保持性が良かった有機酸は、フィチン酸であった。結果を表７に示す。これによって、実施例３の結果と照らし合わせると、塩基性染料に非イオン(ノニオン)性界面活性剤を含んだ染毛料を用いて、さらに本発明の毛髪化粧料組成物を適用しても良いことが分かる。また、本発明の毛髪化粧料組成物を適用後に、無機酸又は有機酸を適用しても、色保持性に優れることが判明した。
Examples 4-12
Next, inorganic acids and organic acids applicable as pH adjusters were extensively investigated. That is, the hair cosmetic composition having each component of Examples 4 to 12 was adjusted to around pH 4.5 to determine whether there was a change in color retention depending on the inorganic acid and organic acid to be blended, and dried in a constant temperature dryer (model: SDN27P, Sansho Co., Ltd.) and allowed to stand at 40° C. for 60 minutes. While standing, the test hair bundle sample 2) prepared as described above was placed in the test tube, and after standing, 25 g was dispensed into each test tube and left at 40° C. for 30 minutes. After rinsing and drying, the color retention was visually compared. In addition to phytic acid, glutamic acid and aspartic acid were found to have good color retention. Also, the organic acid with the best color retention was phytic acid. Table 7 shows the results. Therefore, when compared with the results of Example 3, the hair cosmetic composition of the present invention may be applied using a basic dye containing a nonionic surfactant. I understand. It was also found that the hair cosmetic composition of the present invention is excellent in color retention even when an inorganic acid or an organic acid is applied after application.
なお、表７において、F)の入手先は、以下の通りである。すなわち、F)アデカカーポール MD-100（（株）ＡＤＥＫＡ製）である。 In Table 7, the source of F) is as follows. That is, F) ADEKA CARPOL MD-100 (manufactured by ADEKA Co., Ltd.).
実施例１３～１５
実施例４～１２の結果、フィチン酸が優れていたため、次に、フィチン酸の配合量及びｐHと、色持ちとの関係について調べた。上述したように作成した試験用毛束サンプル２）を用いて、実施例１３～１５の成分を有する毛髪化粧料組成物におけるフィチン酸の配合量およびｐHによる色差確認のため、定温乾燥器（型式：SDN27P、（株）三商）を用いて４０℃、６０分放置した。放置中に試験管に試験用毛束サンプル２）を入れ、放置後各々の試験管に２５ｇ分注し、４０℃、３０分放置した。すすぎ・乾燥後分光色彩計（型式：SD6000、日本電色工業（株）製）を用いて測色した。同じくらいのｐHすなわちｐH３付近であれば、フィチン酸の配合量が多いほど、色差が小さく、フィチン酸（50％溶液）を２．８０％くらいにした場合はｐHの低いほど色差が小さかった。結果を表8に示す。
Examples 13-15
Since the results of Examples 4 to 12 showed that phytic acid was excellent, the relationship between the blending amount and pH of phytic acid and color retention was investigated. Using the test hair bundle sample 2) prepared as described above, a constant temperature dryer (model : SDN27P, Sansho Co., Ltd.) was used and allowed to stand at 40°C for 60 minutes. The test hair bundle sample 2) was placed in the test tube during standing, and after standing, 25 g was dispensed into each test tube and left at 40° C. for 30 minutes. After rinsing and drying, the color was measured using a spectral colorimeter (model: SD6000, manufactured by Nippon Denshoku Industries Co., Ltd.). At the same pH, that is, around pH 3, the more phytic acid was added, the smaller the color difference. When the phytic acid (50% solution) was about 2.80%, the lower the pH, the smaller the color difference. Table 8 shows the results.
実施例１６～２０
次に、改質剤の違いによって、色保持性に違いがあるか調べた。試験用毛束サンプルとしては、上述の実施例で用意した試験用毛束サンプル１）を用いた。その結果、塩基性染料で染色した試験用毛束サンプル１）において、塩化ナトリウムを配合したものが色差が最も少なかった。実施例１６～２０の成分及び配合量を表９に示す。
Examples 16-20
Next, it was investigated whether there is a difference in color retention depending on the modifier. As the test hair bundle sample, the test hair bundle sample 1) prepared in the above-described example was used. As a result, among the test hair tress samples 1) dyed with a basic dye, the one containing sodium chloride showed the least color difference. Table 9 shows the components and blending amounts of Examples 16-20.
なお、表９中のA)～H)の入手先の情報は、以下の通りである。A)ソフタゾリン CL-R（川研ファインケミカル（株）製）、D)Plantacare 2000 UP(BASFジャパン（株）製）、G)ソルビトール花王(花王（株）製)、H)ニッピペプタイドCQT-F01-G(（株）ニッピ製)である。 Information on where to obtain A) to H) in Table 9 is as follows. A) Softazolin CL-R (manufactured by Kawaken Fine Chemicals Co., Ltd.), D) Plantacare 2000 UP (manufactured by BASF Japan Co., Ltd.), G) Sorbitol Kao (manufactured by Kao Corporation), H) Nippipeptide CQT-F01- G (manufactured by Nippi Co., Ltd.).
また、上述の実施例と同様に、試験用毛束サンプル１）について分光色彩計（型式：SD6000、日本電色工業（株）製）を用いて測色した結果を、表１０に示す。 Further, in the same manner as in the above-described Examples, Table 10 shows the results of color measurement of the test hair bundle sample 1) using a spectral colorimeter (model: SD6000, manufactured by Nippon Denshoku Industries Co., Ltd.).
このように、本発明においては、毛髪染料、特に塩基性染料を処理した毛髪に対して適用した場合に、色保持性に優れる毛髪化粧料組成物、及び毛髪化粧料を提供することが判明した。 As described above, it was found that the present invention provides a hair cosmetic composition and a hair cosmetic which are excellent in color retention when applied to hair treated with a hair dye, particularly a basic dye. .
本発明によると、ヘアカラー処理に対して、色もちを改善することが可能であり、広範囲において、産業上利用価値が高い。 INDUSTRIAL APPLICABILITY According to the present invention, it is possible to improve the longevity of hair color treatment, and it has high industrial utility value in a wide range.
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