JP2022516750A - 化合物およびこれを含む有機発光素子 - Google Patents
化合物およびこれを含む有機発光素子 Download PDFInfo
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- JP2022516750A JP2022516750A JP2021539412A JP2021539412A JP2022516750A JP 2022516750 A JP2022516750 A JP 2022516750A JP 2021539412 A JP2021539412 A JP 2021539412A JP 2021539412 A JP2021539412 A JP 2021539412A JP 2022516750 A JP2022516750 A JP 2022516750A
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- 125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229940042055 systemic antimycotics triazole derivative Drugs 0.000 description 1
- 125000001113 thiadiazolyl group Chemical group 0.000 description 1
- 125000000335 thiazolyl group Chemical group 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 125000006617 triphenylamine group Chemical group 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
- NVCBVYYESHBQKS-UHFFFAOYSA-L zinc;2-carboxyquinolin-8-olate Chemical compound [Zn+2].C1=C(C([O-])=O)N=C2C(O)=CC=CC2=C1.C1=C(C([O-])=O)N=C2C(O)=CC=CC2=C1 NVCBVYYESHBQKS-UHFFFAOYSA-L 0.000 description 1
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Abstract
Description
R1~R4は各々独立して、水素;または重水素であり、
R5およびR6は各々独立して、置換もしくは非置換のアリール基;または置換もしくは非置換の複素環基であり、
aは0~6の整数であり、
bおよびdは各々独立して、0~4の整数であり、
cは0~2の整数であり、
a~dが各々独立して2以上である場合、括弧内の置換基は互いに同一であるかまたは異なり、
b~dが各々独立して2以上である場合、2以上のR2~R4は各々独立して、隣接した置換基は互いに結合して環を形成してもよい。
1 ・・・基板
2 ・・・第1電極
3 ・・・発光層
4 ・・・第2電極
5 ・・・正孔注入層
6 ・・・正孔輸送層
7 ・・・電子阻止層
8 ・・・正孔阻止層
9 ・・・電子注入および輸送層
R7およびR8は各々独立して水素;または重水素であり、
e1およびe2は各々0または1であり、e1とe2の和は1~2であり、
eは0~10の整数であり、fは0~8の整数であり、
eが2以上である場合、複数のR7は互いに同一であるかまたは異なり、
fが2以上である場合、複数のR8は互いに同一であるかまたは異なる。
Aは置換もしくは非置換のナフタレン環であり、
Ar1は置換もしくは非置換の炭素数6~60のアリール基であり、
L1~L3は各々独立して、単結合;または置換もしくは非置換の炭素数6~60のアリーレン基であり、
Ar2およびAr3は各々独立して、置換もしくは非置換の炭素数6~60のアリール基;または置換もしくは非置換のN、OおよびSのうち1個以上のヘテロ原子を含む炭素数2~60のヘテロアリール基であり、
pは0~9の整数である。
[合成例6]
Claims (14)
- 下記化学式1で表される化合物:
[化学式1]
R1は、水素;または重水素であり、
R5およびR6は各々独立して、置換もしくは非置換のアリール基;または置換もしくは非置換の複素環基であり、
aは0~6の整数であり、
bおよびdは各々独立して、0~4の整数であり、
cは0~2の整数であり、
a~dが各々独立して2以上である場合、括弧内の置換基は互いに同一であるかまたは異なり、
bが1である場合にはR2は水素または重水素であり、bが2以上である場合にはR2は水素または重水素であるか、若しくは2以上のR2が互いに結合して互いに環を結合してもよく、
cが1である場合にはR3は水素または重水素であり、cが2以上である場合にはR3は水素または重水素であるか、若しくは2以上のR3が互いに結合して互いに環を結合してもよく、
dが1である場合にはR4は水素または重水素であり、dが2以上である場合にはR4は水素または重水素であるか、若しくは2以上のR4が互いに結合して互いに環を結合してもよい。 - 第1電極、
前記第1電極と対向して備えられた第2電極、および
前記第1電極と前記第2電極との間に備えられた1層以上の有機物層
を含み、
前記有機物層のうち1層以上は、請求項1~6のいずれか1項に記載の化合物を含む
有機発光素子。 - 前記有機物層は発光層を含み、
前記発光層は前記化学式1で表される化合物を含む、
請求項7に記載の有機発光素子。 - 前記有機物層は発光層を含み、
前記発光層は前記化学式1で表される化合物をホストとして含む、
請求項7に記載の有機発光素子。 - 前記有機物層は正孔注入層または正孔輸送層を含み、
前記正孔注入層または正孔輸送層は前記化学式1で表される化合物を含む、
請求項7に記載の有機発光素子。 - 前記有機物層は電子輸送層または電子注入層を含み、
前記電子輸送層または電子注入層は前記化学式1で表される化合物を含む、
請求項7に記載の有機発光素子。 - 前記有機発光素子は、正孔注入層、正孔輸送層、電子輸送層、電子注入層、電子阻止層および正孔阻止層からなる群より選択される1層または2層以上をさらに含む、
請求項7から11のいずれか1項に記載の有機発光素子。 - 前記有機物層は発光層を含み、
前記発光層は、前記化学式1で表される化合物を第1ホストとして含み、下記化学式Hで表される第2ホストをさらに含む、
請求項7から12のいずれか1項に記載の有機発光素子:
[化学式H]
Aは置換もしくは非置換のナフタレン環であり、
Ar1は置換もしくは非置換の炭素数6~60のアリール基であり、
L1~L3は各々独立して、単結合;または置換もしくは非置換の炭素数6~60のアリーレン基であり、
Ar2およびAr3は各々独立して、置換もしくは非置換の炭素数6~60のアリール基;または置換もしくは非置換のN、OおよびSのうち1個以上のヘテロ原子を含む炭素数2~60のヘテロアリール基であり、
pは0~9の整数である。
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CN107827807A (zh) * | 2017-10-23 | 2018-03-23 | 长春海谱润斯科技有限公司 | 一种含有咔唑结构的衍生物及其制备方法和有机电致发光器件 |
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JP2023507910A (ja) * | 2019-12-27 | 2023-02-28 | エルティー・マテリアルズ・カンパニー・リミテッド | ヘテロ環化合物、これを含む有機発光素子、および有機発光素子の有機物層用組成物 |
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JP7197076B2 (ja) | 2022-12-27 |
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TW202033742A (zh) | 2020-09-16 |
US20220102646A1 (en) | 2022-03-31 |
EP3828180A1 (en) | 2021-06-02 |
CN113365993B (zh) | 2024-04-05 |
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CN113365993A (zh) | 2021-09-07 |
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