JP2022165082A - Cosmetic - Google Patents
Cosmetic Download PDFInfo
- Publication number
- JP2022165082A JP2022165082A JP2021070267A JP2021070267A JP2022165082A JP 2022165082 A JP2022165082 A JP 2022165082A JP 2021070267 A JP2021070267 A JP 2021070267A JP 2021070267 A JP2021070267 A JP 2021070267A JP 2022165082 A JP2022165082 A JP 2022165082A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- cosmetic
- alkyl
- modified
- cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 78
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229920003043 Cellulose fiber Polymers 0.000 claims abstract description 37
- 229960003512 nicotinic acid Drugs 0.000 claims abstract description 20
- 235000001968 nicotinic acid Nutrition 0.000 claims abstract description 19
- 239000011664 nicotinic acid Substances 0.000 claims abstract description 19
- 229920013820 alkyl cellulose Polymers 0.000 claims abstract description 14
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 13
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 13
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 claims description 22
- 229920002678 cellulose Polymers 0.000 claims description 22
- 239000001913 cellulose Substances 0.000 claims description 22
- 239000000835 fiber Substances 0.000 claims description 17
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 12
- 235000005152 nicotinamide Nutrition 0.000 claims description 11
- 239000011570 nicotinamide Substances 0.000 claims description 11
- 125000003172 aldehyde group Chemical group 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 4
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 4
- 229920006037 cross link polymer Polymers 0.000 claims description 4
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 abstract description 10
- 239000003921 oil Substances 0.000 description 50
- 235000019198 oils Nutrition 0.000 description 50
- -1 amide compound Chemical class 0.000 description 22
- 235000010980 cellulose Nutrition 0.000 description 19
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 11
- 238000011156 evaluation Methods 0.000 description 8
- 229920001296 polysiloxane Polymers 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000006096 absorbing agent Substances 0.000 description 7
- 239000003205 fragrance Substances 0.000 description 7
- 229960003966 nicotinamide Drugs 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000004945 emulsification Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- 235000015278 beef Nutrition 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 210000001724 microfibril Anatomy 0.000 description 4
- 239000002121 nanofiber Substances 0.000 description 4
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- DRRMRHKHTQRWMB-UHFFFAOYSA-N [3-(2-ethylhexanoyloxy)-2,2-bis(2-ethylhexanoyloxymethyl)propyl] 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(COC(=O)C(CC)CCCC)(COC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DRRMRHKHTQRWMB-UHFFFAOYSA-N 0.000 description 3
- 229940022663 acetate Drugs 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 229920003086 cellulose ether Polymers 0.000 description 3
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 3
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 3
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- NVIPUOMWGQAOIT-UHFFFAOYSA-N (E)-7-Hexadecen-16-olide Natural products O=C1CCCCCC=CCCCCCCCCO1 NVIPUOMWGQAOIT-UHFFFAOYSA-N 0.000 description 2
- DNRJTBAOUJJKDY-UHFFFAOYSA-N 2-Acetyl-3,5,5,6,8,8-hexamethyl-5,6,7,8- tetrahydronaphthalene Chemical compound CC(=O)C1=C(C)C=C2C(C)(C)C(C)CC(C)(C)C2=C1 DNRJTBAOUJJKDY-UHFFFAOYSA-N 0.000 description 2
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- NVIPUOMWGQAOIT-DUXPYHPUSA-N 7-hexadecen-1,16-olide Chemical compound O=C1CCCCC\C=C\CCCCCCCCO1 NVIPUOMWGQAOIT-DUXPYHPUSA-N 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 2
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 2
- 240000000912 Macadamia tetraphylla Species 0.000 description 2
- 240000005125 Myrtus communis Species 0.000 description 2
- 235000013418 Myrtus communis Nutrition 0.000 description 2
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 2
- 235000004347 Perilla Nutrition 0.000 description 2
- 244000124853 Perilla frutescens Species 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- KGEKLUUHTZCSIP-HOSYDEDBSA-N [(1s,4s,6r)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Chemical compound C1C[C@]2(C)[C@H](OC(=O)C)C[C@H]1C2(C)C KGEKLUUHTZCSIP-HOSYDEDBSA-N 0.000 description 2
- CMPDPBDUZTUXAD-UHFFFAOYSA-N [3-hydroxy-2-(16-methylheptadecanoyloxy)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCCCCCC(C)C CMPDPBDUZTUXAD-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 description 2
- 229940062909 amyl salicylate Drugs 0.000 description 2
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 2
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- KVYGGMBOZFWZBQ-UHFFFAOYSA-N benzyl nicotinate Chemical compound C=1C=CN=CC=1C(=O)OCC1=CC=CC=C1 KVYGGMBOZFWZBQ-UHFFFAOYSA-N 0.000 description 2
- 239000010495 camellia oil Substances 0.000 description 2
- HQKQRXZEXPXXIG-VJOHVRBBSA-N chembl2333940 Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@H]1[C@@](OC(C)=O)(C)CC2 HQKQRXZEXPXXIG-VJOHVRBBSA-N 0.000 description 2
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 239000010639 cypress oil Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- VJZWIFWPGRIJSN-XRHABHTOSA-N dilinoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O.CCCCC\C=C/C\C=C/CCCCCCCC(O)=O VJZWIFWPGRIJSN-XRHABHTOSA-N 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 229940090934 diphenylsiloxy phenyl trimethicone Drugs 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- NYNCZOLNVTXTTP-UHFFFAOYSA-N ethyl 2-(1,3-dioxoisoindol-2-yl)acetate Chemical compound C1=CC=C2C(=O)N(CC(=O)OCC)C(=O)C2=C1 NYNCZOLNVTXTTP-UHFFFAOYSA-N 0.000 description 2
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 2
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical compound CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 229940119170 jojoba wax Drugs 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 description 2
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 2
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 description 2
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 2
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 description 2
- 229960005323 phenoxyethanol Drugs 0.000 description 2
- 229960000969 phenyl salicylate Drugs 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N rose oxide Chemical compound CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 2
- DUXYWXYOBMKGIN-UHFFFAOYSA-N trimyristin Chemical compound CCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCC DUXYWXYOBMKGIN-UHFFFAOYSA-N 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 description 1
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- 239000001147 (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e][1]benzofuran Substances 0.000 description 1
- 229940098795 (3z)- 3-hexenyl acetate Drugs 0.000 description 1
- KZRXPHCVIMWWDS-AWEZNQCLSA-N (4S)-4-amino-5-dodecanoyloxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O KZRXPHCVIMWWDS-AWEZNQCLSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- 239000001306 (7E,9E,11E,13E)-pentadeca-7,9,11,13-tetraen-1-ol Substances 0.000 description 1
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 1
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 description 1
- KHQDWCKZXLWDNM-KPKJPENVSA-N (e)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol Chemical compound CC\C(CO)=C/CC1CC=C(C)C1(C)C KHQDWCKZXLWDNM-KPKJPENVSA-N 0.000 description 1
- CWLGEPSKQDNHIO-JOBJLJCHSA-N (e)-n-[(e)-benzylideneamino]-1-phenylmethanimine Chemical compound C=1C=CC=CC=1/C=N/N=C/C1=CC=CC=C1 CWLGEPSKQDNHIO-JOBJLJCHSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- DHGBAFGZLVRESL-UHFFFAOYSA-N 14-methylpentadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C DHGBAFGZLVRESL-UHFFFAOYSA-N 0.000 description 1
- LGEZTMRIZWCDLW-UHFFFAOYSA-N 14-methylpentadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C LGEZTMRIZWCDLW-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、化粧料に関する。 The present invention relates to cosmetics.
ニコチン酸アミドはシミやシワの改善に有効な成分であることが知られている。しかしながら、例えば、微細セルロース繊維とアルキル変性カルボキシビニルポリマーとを組み合わせた基剤に、ニコチン酸アミドを加えるとみずみずしさや、乳化安定性が著しく低下する。 Nicotinamide is known to be an ingredient effective in improving blemishes and wrinkles. However, for example, when nicotinamide is added to a base in which fine cellulose fibers and an alkyl-modified carboxyvinyl polymer are combined, the freshness and emulsion stability are remarkably lowered.
これまでに、繊維状セルロースと、殺菌剤、抗炎症剤およびビタミン類からなる群から選択される一種または二種以上を含む皮膚化粧料が、皮膚に適用した際の耐汗性、耐摩擦性および有効成分の効果の持続性に優れることが知られているが（特許文献１参照）、当該皮膚化粧料にはニコチン酸アミドが配合されている具体的な例については全く記載されておらず、またそのみずみずしさや、乳化安定性についても何ら記載されていない。 So far, skin cosmetics containing fibrous cellulose and one or more selected from the group consisting of bactericidal agents, anti-inflammatory agents and vitamins have been found to exhibit sweat resistance and abrasion resistance when applied to the skin. and is known to be excellent in the durability of the effect of the active ingredient (see Patent Document 1), but there is no description of a specific example in which nicotinic acid amide is blended in the skin cosmetic. , and its freshness and emulsion stability are not described at all.
従って、ニコチン酸アミドまたはその誘導体を含有しつつ、みずみずしく、乳化安定性を向上できる化粧料について希求されているといえる。 Therefore, it can be said that there is a need for a cosmetic that contains nicotinic acid amide or a derivative thereof, is fresh and has improved emulsification stability.
本発明者らは、驚くべきことに、化粧料にニコチン酸またはその誘導体を含有させた場合であっても、化粧料に疎水変性アルキルセルロースと、微細セルロース繊維と、アルキル変性カルボキシビニルポリマーと、油分とを含有させることにより、良好なみずみずしさと、良好な乳化安定性とを有する化粧料とすることができることを見出した。本発明はこれらの知見に基づくものである。 The present inventors have surprisingly found that even when nicotinic acid or a derivative thereof is contained in a cosmetic, the cosmetic contains hydrophobically modified alkyl cellulose, fine cellulose fibers, alkyl-modified carboxyvinyl polymer, It has been found that a cosmetic having good freshness and good emulsification stability can be obtained by including an oil component. The present invention is based on these findings.
本発明によれば、以下の発明が提供される。
（１）（Ａ）ニコチン酸またはその誘導体と、
（Ｂ）疎水変性アルキルセルロースと、
（Ｃ）微細セルロース繊維と、
（Ｄ）アルキル変性カルボキシビニルポリマーと、
（Ｅ）油分と
を含有する化粧料であって、前記（Ａ）ニコチン酸またはその誘導体の配合量が、化粧料の全量に対して、１～１０質量％である、化粧料。
（２）前記（Ａ）ニコチン酸またはその誘導体が、ニコチン酸アミドである、（１）に記載の化粧料。
（３）前記（Ｂ）疎水変性アルキルセルロースが、ステアロキシヒドロキシプロピルメチルセルロースを含む、（１）または（２）に記載の化粧料。
（４）前記（Ｂ）疎水変性アルキルセルロースの配合量が、化粧料の全量に対して、０．０７～０．８質量％である、（１）～（３）のいずれかに記載の化粧料。
（５）前記（Ｃ）微細セルロース繊維が、最大繊維径が１０００ｎｍ以下であり、数平均繊維径が２～１００ｎｍのセルロース繊維であって、そのセルロースがＩ型結晶構造を有するとともに、セルロース分子中のグルコースユニットのＣ６位の水酸基が選択的に酸化されてアルデヒド基およびカルボキシル基に変性されており、前記カルボキシル基量が０．６～２．２ｍｍｏｌ／ｇの範囲であるものである、（１）～（４）のいずれかに記載の化粧料。
（６）前記（Ｃ）微細セルロース繊維が結晶セルロースを含む、（１）～（５）のいずれかに記載の化粧料。
（７）前記（Ｃ）微細セルロース繊維の配合量が、化粧料の全量に対して、０．０１～１質量％である、（１）～（６）のいずれかに記載の化粧料。
（８）前記（Ｄ）アルキル変性カルボキシビニルポリマーが、（アクリレーツ／アクリル酸アルキル（Ｃ１０－３０））クロスポリマーを含む、（１）～（７）のいずれかに記載の化粧料。
（９）前記（Ｄ）アルキル変性カルボキシビニルポリマーの配合量が、化粧料の全量に対して、０．００１～０．６質量％である、（１）～（８）のいずれかに記載の化粧料。
（１０）前記（Ｅ）油分の配合量が、化粧料の全量に対して、１０質量％以下である、（１）～（９）のいずれかに記載の化粧料。
According to the present invention, the following inventions are provided.
(1) (A) nicotinic acid or a derivative thereof;
(B) a hydrophobically modified alkyl cellulose;
(C) fine cellulose fibers;
(D) an alkyl-modified carboxyvinyl polymer;
(E) a cosmetic containing oil, wherein the content of (A) nicotinic acid or a derivative thereof is 1 to 10% by mass relative to the total amount of the cosmetic.
(2) The cosmetic according to (1), wherein (A) nicotinic acid or a derivative thereof is nicotinic acid amide.
(3) The cosmetic according to (1) or (2), wherein the (B) hydrophobically modified alkylcellulose contains stearoxyhydroxypropylmethylcellulose.
(4) The cosmetic according to any one of (1) to (3), wherein the amount of the (B) hydrophobically-modified alkyl cellulose is 0.07 to 0.8% by mass with respect to the total amount of the cosmetic. fee.
(5) The (C) fine cellulose fibers have a maximum fiber diameter of 1000 nm or less and a number average fiber diameter of 2 to 100 nm, and the cellulose has a type I crystal structure and The hydroxyl group at the C6 position of the glucose unit of is selectively oxidized and modified into an aldehyde group and a carboxyl group, and the amount of the carboxyl group is in the range of 0.6 to 2.2 mmol / g (1 ) to (4).
(6) The cosmetic according to any one of (1) to (5), wherein the (C) fine cellulose fibers contain crystalline cellulose.
(7) The cosmetic according to any one of (1) to (6), wherein the content of (C) fine cellulose fibers is 0.01 to 1% by mass relative to the total amount of the cosmetic.
(8) The cosmetic according to any one of (1) to (7), wherein the (D) alkyl-modified carboxyvinyl polymer comprises an (acrylates/alkyl acrylate (C10-30)) crosspolymer.
(9) The content of (D) the alkyl-modified carboxyvinyl polymer is 0.001 to 0.6% by mass relative to the total amount of the cosmetic composition, according to any one of (1) to (8). cosmetics.
(10) The cosmetic according to any one of (1) to (9), wherein the content of the (E) oil component is 10% by mass or less with respect to the total amount of the cosmetic.
本発明の化粧料を用いることにより、化粧料にニコチン酸またはその誘導体を含有させた場合であっても、良好なみずみずしさと、良好な乳化安定性とを実現できる点で有利である。 The use of the cosmetic of the present invention is advantageous in that good freshness and good emulsion stability can be achieved even when the cosmetic contains nicotinic acid or a derivative thereof.
本発明は、
（Ａ）ニコチン酸またはその誘導体と、
（Ｂ）疎水変性アルキルセルロースと、
（Ｃ）微細セルロース繊維と、
（Ｄ）アルキル変性カルボキシビニルポリマーと、
（Ｅ）油分と
を含有する化粧料であって、前記（Ａ）ニコチン酸またはその誘導体の配合量が、化粧料の全量に対して、１～１０質量％である、化粧料が提供される。
The present invention
(A) nicotinic acid or a derivative thereof;
(B) a hydrophobically modified alkyl cellulose;
(C) fine cellulose fibers;
(D) an alkyl-modified carboxyvinyl polymer;
(E) a cosmetic containing oil, wherein the amount of (A) nicotinic acid or a derivative thereof is 1 to 10% by mass with respect to the total amount of the cosmetic. .
＜ニコチン酸またはその誘導体＞
本発明の化粧料にはニコチン酸またはその誘導体が含まれる。ニコチン酸の誘導体としては、例えば、ニコチン酸アミド、ニコチン酸ベンジル、ニコチン酸トコフェロール、ニコチン酸β－ブトキシエステルが挙げられ、これらの中でもニコチン酸アミドが特に好ましい。ここで、ニコチン酸アミドは、ニコチンアミド、ナイアシンアミドともよばれ、ニコチン酸の誘導体であり、ニコチン酸（ビタミンＢ３／ナイアシン）のアミド化合物である。ニコチン酸アミドは水溶性ビタミンで、ビタミンＢ群の一つである公知の物質であり、天然物（米ぬかなど）から抽出されてもよく、または公知の方法によって合成することができる。例えば、第十八改正日本薬局方に収載されているものを用いることができる。
<Nicotinic acid or its derivative>
The cosmetics of the present invention contain nicotinic acid or its derivatives. Nicotinic acid derivatives include, for example, nicotinamide, benzyl nicotinate, tocopherol nicotinate, and nicotinic acid β-butoxyester, with nicotinamide being particularly preferred. Here, nicotinamide is also called nicotinamide or niacinamide, is a derivative of nicotinic acid, and is an amide compound of nicotinic acid (vitamin B3/niacin). Nicotinamide is a water-soluble vitamin, a known substance that is one of the B vitamins, and may be extracted from natural products (such as rice bran) or synthesized by known methods. For example, those listed in the Japanese Pharmacopoeia 18th Edition can be used.
本発明の化粧料に含まれるニコチン酸またはその誘導体の配合量は、化粧料の全量に対して、１～１０質量％であれば特に限定されるものではないが、好ましくは、化粧料の全量に対して、２～８質量％であり、より好ましくは、化粧料の全量に対して、３～７質量％である。この範囲とすることで、ニコチン酸またはその誘導体による効果、特にシワ改善効果を十分に発揮させた上で、乳化安定性も保つことができ、塗布後のべたつきも抑制することができる。 The amount of nicotinic acid or a derivative thereof contained in the cosmetic of the present invention is not particularly limited as long as it is 1 to 10% by mass with respect to the total amount of the cosmetic, but is preferably the total amount of the cosmetic. 2 to 8% by mass, more preferably 3 to 7% by mass relative to the total amount of the cosmetic. Within this range, the effect of nicotinic acid or a derivative thereof, particularly wrinkle-improving effect, can be sufficiently exhibited, emulsion stability can be maintained, and stickiness after application can be suppressed.
＜疎水変性アルキルセルロース＞
本発明の化粧料に含まれる疎水変性アルキルセルロースは、下記式（Ｉ）で示されるものが好ましい。
<Hydrophobic modified alkyl cellulose>
The hydrophobically modified alkylcellulose contained in the cosmetic of the present invention is preferably represented by the following formula (I).
上記式（Ｉ）において、Ｒは、結合基Ｒ１－Ｒ２であり、Ｒ１は、分子内で同一でも異なってもよく、－［ＣＨ２ＣＨ（ＣＨ３）Ｏ］ｒ－、－［ＣＨ２ＣＨ２Ｏ］ｒ－、および、－［ＣＨ２ＣＨ（ＯＨ）ＣＨ２Ｏ］ｒ－から選ばれる基（式中、ｒは、０～４の整数である）であり、Ｒ２は、炭素原子数が１２～２８の炭化水素基（好ましくは炭素原子数が１～４のアルキル基）、および水素原子から選ばれる１種以上の基であり、１分子中のＲ２の少なくとも１つは、炭素原子数が１２～２８の炭化水素基（好ましくは炭素原子数１～４のアルキル基）である。Ａは、基－（ＣＨ２）ｔ－（ｔは、１～３の整数）であり、ｓは、１００～１００００の数である。 In the above formula (I), R is a linking group R 1 -R 2 , and R 1 may be the same or different in the molecule and may be -[CH 2 CH(CH 3 )O] r -, -[ CH 2 CH 2 O] r — and —[CH 2 CH(OH)CH 2 O] r — (wherein r is an integer of 0 to 4), and R 2 is , a hydrocarbon group having 12 to 28 carbon atoms (preferably an alkyl group having 1 to 4 carbon atoms), and one or more groups selected from hydrogen atoms, and at least one of R 2 in one molecule One is a hydrocarbon group having 12 to 28 carbon atoms (preferably an alkyl group having 1 to 4 carbon atoms). A is a group —(CH 2 ) t — (t is an integer of 1-3), and s is a number of 100-10,000.
上記式（Ｉ）の疎水変性アルキルセルロースは、水溶性セルロースエーテル誘導体に、ポリオキシアルキレン鎖を介して疎水性基である長鎖アルキル基を導入した構造を有する。分子の基となる水溶性セルロースエーテル誘導体は、例えば、メチルセルロース、エチルセルロース、プロピルセルロース、ブチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース等であり、それらと長鎖アルキルグリシジルエーテル（例えば、下記式（Ｉ’）で表されるもの）とを反応させて得ることができる。 The hydrophobically modified alkyl cellulose of formula (I) has a structure in which a long-chain alkyl group, which is a hydrophobic group, is introduced into a water-soluble cellulose ether derivative through a polyoxyalkylene chain. Water-soluble cellulose ether derivatives that form the basis of the molecule include, for example, methyl cellulose, ethyl cellulose, propyl cellulose, butyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, etc., and long-chain alkyl glycidyl ethers (for example, the following formula (I') can be obtained by reacting with (I').
上記の水溶性セルロースエーテル誘導体としては、ヒドロキシプロピルメチルセルロースまたはヒドロキシエチルセルロースが好ましく、特に、ヒドロキシプロピルメチルセルロースを選択することが好適である。さらに、長鎖アルキルグリシジルエーテル（Ｉ’）のＲ’は、ステアリル基（－Ｃ１８Ｈ３７）またはセチル基（－Ｃ１６Ｈ３３）であることが好適である（これらの場合、－ＣＨ２ＣＨ（ＯＨ）ＣＨ２ＯＲ’は、－ＣＨ２ＣＨ（ＯＨ）ＣＨ２Ｏ－Ｃ１８Ｈ３７または－ＣＨ２ＣＨ（ＯＨ）ＣＨ２Ｏ－Ｃ１６Ｈ３３となる）。 As the above water-soluble cellulose ether derivative, hydroxypropylmethylcellulose or hydroxyethylcellulose is preferable, and hydroxypropylmethylcellulose is particularly preferable. Furthermore, R' of the long-chain alkyl glycidyl ether (I') is preferably a stearyl group (--C 18 H 37 ) or a cetyl group (--C 16 H 33 ) (in these cases --CH 2 CH(OH)CH 2 OR′ becomes —CH 2 CH(OH)CH 2 OC 18 H 37 or —CH 2 CH(OH)CH 2 OC 16 H 33 ).
疎水変性アルキルセルロースの最も好適な態様は、式（Ｉ’）における疎水基Ｒ’をステアリル基としたステアロキシヒドロキシプロピルメチルセルロースであり、「サンジェロース」という商品名で大同化成工業株式会社から市販されている製品を用いることも可能である。（商品名：サンジェロース９０Ｌ、９０Ｍ、９０Ｈ、６０Ｌ、６０Ｍ、および６０Ｈ等）。 The most preferred embodiment of the hydrophobically modified alkylcellulose is stearoxyhydroxypropylmethylcellulose in which the hydrophobic group R' in formula (I') is a stearyl group, and is commercially available from Daido Kasei Kogyo Co., Ltd. under the trade name "Sangelose". It is also possible to use products that are (Trade names: Sangelose 90L, 90M, 90H, 60L, 60M, and 60H, etc.).
本発明の化粧料に含まれる疎水変性アルキルセルロースの配合量は、特に限定されるものではないが、好ましくは、化粧料の全量に対して、０．０７～０．８質量％であり、より好ましくは、化粧料の全量に対して、０．０９～０．５質量％である。この範囲とすることで、乳化安定性を向上しつつ、塗布時のみずみずしさを保つことができる。 The amount of the hydrophobically modified alkyl cellulose contained in the cosmetic of the present invention is not particularly limited, but is preferably 0.07 to 0.8% by mass relative to the total amount of the cosmetic, and more Preferably, it is 0.09 to 0.5% by mass with respect to the total amount of the cosmetic. Within this range, it is possible to maintain freshness during application while improving emulsification stability.
＜微細セルロース繊維＞
本発明の化粧料に含まれる微細セルロース繊維は、植物由来のセルロースからなるナノファイバー（ミクロフィブリル）であって、ミクロフィブリル同士が実質的に１本ずつにまで分散されたもの（セルロールシングルナノファイバー：ＣＳＮＦとも呼ばれる）であり、好ましくは、結晶セルロースを含むものである。
<Fine cellulose fiber>
The fine cellulose fibers contained in the cosmetic of the present invention are nanofibers (microfibrils) made of plant-derived cellulose, in which microfibrils are substantially dispersed one by one (cellulose single nanofibers). Fiber: also called CSNF), preferably containing microcrystalline cellulose.
前記の微細セルロール繊維（セルロースシングルナノファーバー）は、水に対する高い増粘作用を有し、例えば、ポリビニルピロリドンと組み合わせて配合することによって強固なゲル状でありながら透明度の高い組成物となることが知られている（特許第５２４３３７１号公報参照）。また、微細セルロース繊維が、表面疎水化処理した粉末の水中での分散性を向上させる作用が見出され、微細セルロース繊維と撥水化処理した特定の固体とを配合した化粧料組成物も知られている（特許第５６２６８２８号公報参照）。かかる微細セルロール繊維は、「レオクリスタ」という商品名で第一工業製薬株式会社から市販されている。例えば、「レオクリスタＣ－２ＳＰ」（商品名）は、２質量％の微細セルロース繊維、１質量％のフェノキシエタノールを９７質量％の水中に含む製品である。 The fine cellulose fibers (cellulose single nanofibers) have a high thickening effect on water, and for example, by blending them in combination with polyvinylpyrrolidone, it is possible to obtain a strong gel-like composition with high transparency. known (see Japanese Patent No. 5243371). It has also been found that fine cellulose fibers have the effect of improving the dispersibility in water of powders subjected to surface hydrophobic treatment, and cosmetic compositions containing fine cellulose fibers and specific water-repellent treated solids are also known. (See Japanese Patent No. 5626828). Such fine cellulose fibers are commercially available from Daiichi Kogyo Seiyaku Co., Ltd. under the trade name of "Rheocrysta". For example, "Rheocrysta C-2SP" (trade name) is a product containing 2% by mass of fine cellulose fibers, 1% by mass of phenoxyethanol in 97% by mass of water.
本発明にあっては、前記の市販品（レオクリスタ）等を使用することができる。本発明で好ましく用いられる微細セルロール繊維の詳細について、特許第５２４３３７１号公報の記載を参照しつつ以下に説明する。 In the present invention, the commercially available product (Rheocrysta) or the like can be used. Details of the fine cellulose fibers preferably used in the present invention will be described below with reference to the description in Japanese Patent No. 5243371.
本発明における微細セルロース繊維としては、最大繊維径が１０００ｎｍ以下で、数平均繊維径が２～１００ｎｍのセルロース繊維であって、そのセルロースが、Ｉ型結晶構造を有するとともに、セルロース分子中のグルコースユニットのＣ６位の水酸基が選択的に酸化されてアルデヒド基およびカルボキシル基に変性されており、上記カルボキシル基量が０．６～２．２ｍｍｏｌ／ｇの範囲であるものが好ましい。 The fine cellulose fibers in the present invention are cellulose fibers having a maximum fiber diameter of 1000 nm or less and a number average fiber diameter of 2 to 100 nm, the cellulose having a type I crystal structure and a glucose unit in the cellulose molecule. is selectively oxidized to be modified into an aldehyde group and a carboxyl group, and the amount of the carboxyl group is preferably in the range of 0.6 to 2.2 mmol/g.
この微細セルロース繊維は、Ｉ型結晶構造を有する天然由来のセルロース固体原料を表面酸化し、微細化した繊維である。天然セルロースの生合成の過程においては、ほぼ例外なくミクロフィブリルと呼ばれるナノファイバーがまず形成され、これらが多束化して高次な固体構造を構成するが、本発明で用いる微細セルロール繊維は、上記ミクロフィブリル間の強い凝集力の原動となっている表面間の水素結合を弱めるために、その水酸基の一部が酸化され、アルデヒド基およびカルボキシル基に変換されている。 This fine cellulose fiber is a fiber obtained by subjecting a natural cellulose solid raw material having a type I crystal structure to surface oxidation and making it fine. In the process of biosynthesis of natural cellulose, almost without exception, nanofibers called microfibrils are first formed, and these bundles are bundled to form a higher-order solid structure. Some of the hydroxyl groups have been oxidized and converted to aldehyde and carboxyl groups in order to weaken the intersurface hydrogen bonds that drive the strong cohesive forces between microfibrils.
ここで、上記微細セルロース繊維を構成するセルロースがＩ型結晶構造を有することは、例えば、広角Ｘ線回折像測定により得られる回折プロファイルにおいて、２シータ＝１４～１７°付近と、２シータ＝２２～２３°付近の２つの位置に典型的なピークを持つことから同定することができる。 Here, the fact that the cellulose constituting the fine cellulose fibers has an I-type crystal structure is, for example, in the diffraction profile obtained by wide-angle X-ray diffraction image measurement, in the vicinity of 2 theta = 14 to 17 ° and 2 theta = 22 It can be identified by having typical peaks at two positions around ~23°.
上記微細セルロース繊維は、最大繊維径が１０００ｎｍ以下、かつ数平均繊維径が２～１００ｎｍであり、分散安定性の点から、最大繊維径が５００ｎｍ以下、かつ数平均繊維径が３～８０ｎｍであるのが好ましい。 The fine cellulose fibers have a maximum fiber diameter of 1000 nm or less and a number average fiber diameter of 2 to 100 nm, and from the viewpoint of dispersion stability, a maximum fiber diameter of 500 nm or less and a number average fiber diameter of 3 to 80 nm. is preferred.
上記微細セルロース繊維の数平均繊維径および最大繊維径は、例えば、次のようにして測定することができる。すなわち、セルロース繊維に水を加え、セルロースの固形分を１重量％とする。これを、超音波ホモジナイザー、高圧ホモジナイザー、回転速度１５，０００ｒｐｍ以上の能力を有するブレンダー等を用いて分散させた後、水を加えて希釈し、親水化処理済みのカーボン膜被覆グリッド上にキャストして、これを透過型電子顕微鏡（ＴＥＭ）等により観察し、得られた画像からセルロース繊維の数平均繊維径、最大繊維径を測定および算出することができる。 The number average fiber diameter and maximum fiber diameter of the fine cellulose fibers can be measured, for example, as follows. That is, water is added to cellulose fibers to make the solid content of cellulose 1% by weight. After dispersing this by using an ultrasonic homogenizer, a high-pressure homogenizer, a blender capable of rotating at a speed of 15,000 rpm or more, etc., it is diluted by adding water and cast on a carbon film-coated grid that has been hydrophilized. Then, this is observed with a transmission electron microscope (TEM) or the like, and the number average fiber diameter and maximum fiber diameter of the cellulose fibers can be measured and calculated from the obtained image.
また、上記微細セルロース繊維は、セルロース分子中のグルコースユニットのＣ６位の水酸基が選択的に酸化されてアルデヒド基およびカルボキシル基に変性されており、カルボキシル基量が０．６～２．２ｍｍｏｌ／ｇであり、保形性能、分散安定性の点から、好ましくは０．６～２．０ｍｍｏｌ／ｇの範囲である。 In the fine cellulose fiber, the hydroxyl group at the C6 position of the glucose unit in the cellulose molecule is selectively oxidized to be modified into an aldehyde group and a carboxyl group, and the amount of carboxyl group is 0.6 to 2.2 mmol/g. , and from the viewpoint of shape retention performance and dispersion stability, it is preferably in the range of 0.6 to 2.0 mmol/g.
また、上記微細セルロース繊維は、アルデヒド基量が０．０３～０．３ｍｍｏｌ／ｇの範囲が好ましく、特に好ましくは０．１０～０．２５ｍｍｏｌ／ｇの範囲である。微細セルロース繊維に含まれるカルボキシル基量およびアルデヒド基量の測定は、微細セルロース繊維を分散させた水の電位差滴定により行うことができる。詳細は特許第５２４３３７１号公報を参照されたい。 The fine cellulose fibers preferably have an aldehyde group content in the range of 0.03 to 0.3 mmol/g, particularly preferably in the range of 0.10 to 0.25 mmol/g. The amount of carboxyl groups and the amount of aldehyde groups contained in the fine cellulose fibers can be measured by potentiometric titration of water in which the fine cellulose fibers are dispersed. See Japanese Patent No. 5243371 for details.
微細セルロース繊維におけるカルボキシル基量およびアルデヒド基量の調整は、セルロース繊維の酸化工程で用いる共酸化剤の添加量や反応時間を制御することにより行うことができる。また、微細セルロース繊維にアルデヒド基あるいはカルボキシル基が導入されていることは、全反射式赤外分光スペクトル（ＡＴＲ）解析により確認できる。詳細は特許第５２４３３７１号公報を参照されたい。 The amount of carboxyl groups and the amount of aldehyde groups in the fine cellulose fibers can be adjusted by controlling the amount of co-oxidizing agent added and the reaction time used in the step of oxidizing the cellulose fibers. Further, introduction of an aldehyde group or a carboxyl group into the fine cellulose fibers can be confirmed by total reflection infrared spectroscopy (ATR) analysis. See Japanese Patent No. 5243371 for details.
本発明の化粧料に含まれる微細セルロース繊維の配合量は、特に限定されるものではないが、好ましくは、化粧料の全量に対して、０．０１～１質量％であり、より好ましくは、化粧料の全量に対して、０．０５～０．５質量％である。この範囲とすることで、塗布後のみずみずしさを向上させることができる。 The amount of the fine cellulose fibers contained in the cosmetic of the present invention is not particularly limited, but is preferably 0.01 to 1% by mass relative to the total amount of the cosmetic, more preferably It is 0.05 to 0.5% by mass with respect to the total amount of the cosmetic. By setting it as this range, the freshness after application can be improved.
＜アルキル変性カルボキシビニルポリマー＞
本発明の化粧料に含まれるアルキル変性カルボキシビニルポリマーとしては、良好な乳化安定性とみずみずしい使用感を有するという観点から、（アクリレーツ／アクリル酸アルキル（Ｃ１０－Ｃ３０））クロスポリマーを好適に挙げることができる。（アクリレーツ／アクリル酸アルキル（Ｃ１０－Ｃ３０））クロスポリマーは市販品を用いてもよく、「ＰｅｍｕｌｅｎＴＲ－１ Ｐｏｌｙｍｅｒｉｃ Ｅｍｕｌｓｉｆｉｅｒ」、「ＰｅｍｕｌｅｎＴＲ－２ Ｐｏｌｙｍｅｒｉｃ Ｅｍｕｌｓｉｆｉｅｒ」（Ｌｕｂｒｉｚｏｌ Ａｄｖａｎｃｅｄ Ｍａｔｅｒｉａｌｓ，Ｉｎｃ．製）を挙げることができる。
<Alkyl-modified carboxyvinyl polymer>
As the alkyl-modified carboxyvinyl polymer contained in the cosmetic composition of the present invention, an (acrylates/alkyl acrylate (C10-C30)) crosspolymer is preferably mentioned from the viewpoint of having good emulsion stability and a fresh feeling in use. can be done. (Acrylates/alkyl acrylate (C10-C30)) crosspolymer may be a commercially available product, such as "Pemulen TR-1 Polymeric Emulsifier" and "Pemulen TR-2 Polymeric Emulsifier" (manufactured by Lubrizol Advanced Materials, Inc.). can be done.
本発明の化粧料に含まれるアルキル変性カルボキシビニルポリマーの配合量は、特に限定されるものではないが、好ましくは、化粧料の全量に対して、０．００１～０．６質量％であり、より好ましくは、化粧料の全量に対して、０．００５～０．３５質量％である。この範囲とすることで、乳化安定性を向上しつつ、塗布時のみずみずしさを保つことができる。 The amount of the alkyl-modified carboxyvinyl polymer contained in the cosmetic of the present invention is not particularly limited, but is preferably 0.001 to 0.6% by mass with respect to the total amount of the cosmetic, More preferably, it is 0.005 to 0.35% by mass with respect to the total amount of the cosmetic. Within this range, it is possible to maintain freshness during application while improving emulsification stability.
＜油分＞
本発明の化粧料に含まれる油分としては、特に限定されるものではなく、化粧料に用いられている炭化水素油、エステル油、シリコーン油、油脂、香料、油溶性紫外線吸収剤等から選択することができる。
<Oil content>
The oil contained in the cosmetic of the present invention is not particularly limited, and is selected from hydrocarbon oils, ester oils, silicone oils, fats, oils, fragrances, oil-soluble ultraviolet absorbers, etc. used in cosmetics. be able to.
炭化水素油としては、流動パラフィン、スクワラン、スクワレン、パラフィン、イソパラフィン、セレシン、イソドデカン、イソヘキサデカン、オゾケライト、プリスタン、ワセリン等が例示される。 Examples of hydrocarbon oils include liquid paraffin, squalane, squalene, paraffin, isoparaffin, ceresin, isododecane, isohexadecane, ozokerite, pristane, and vaseline.
エステル油としては、テトラエチルヘキサン酸ペンタエリスリチル、エチルヘキサン酸セチル、ホホバ油、ラウロイルグルタミン酸ジ（フィトステリル／オクチルドデシル）、トリイソステアリン、ジイソステアリン酸グリセリル、トリエチルヘキサノイン、ダイマージリノール酸（フィトステリル／ベヘニル）、ダイマージリノール酸（フィトステリル／イソステアリル／セチル／ステアリル／イソステアリル／セチル／ステアリル／ベヘニル）、パルミチン酸イソプロピル、マカダミアナッツ脂肪酸フィトステリル、テトラ（ベヘン酸／安息香酸／エチルヘキサン酸）ペンタエリスリチル、パルミチン酸エチルヘキシル、ミリスチン酸ミリスチル、ミリスチン酸イソプロピル、ジピバリン酸トリプロピレングリコール、セバシン酸ジイソプロピル、ネオペンタン酸イソデシル、オクタン酸オクチル、ノナン酸ノニル、オクタン酸セチル、ミリスチン酸オクチルドデシル、ステアリン酸ブチル、ラウリン酸ヘキシル、オレイン酸デシル、ジメチルオクタン酸ヘキシルデシル、乳酸セチル、乳酸ミリスチル、酢酸ラノリン、ステアリン酸イソセチル、イソステアリン酸イソセチル、１２－ヒドロキシステアリン酸コレステリル、ジ－２－エチルヘキサン酸エチレングリコール、ジペンタエリスリトール脂肪酸エステル、モノイソステアリン酸Ｎ－アルキルグリコール、ジカプリン酸ネオペンチルグリコール、ピバリン酸トリプロピレングリコール、リンゴ酸ジイソステアリル、ジ－２－ヘプチルウンデカン酸グリセリン、ジイソステアリン酸グリセリン、トリ－２－エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ－２－エチルヘキサン酸ペンタエリスリトール、トリ－２－エチルヘキサン酸グリセリン、トリオクタン酸グリセリン、トリイソパルミチン酸グリセリン、セチル２－エチルヘキサノエート－２－エチルヘキシルパルミテート、トリミリスチン酸グリセリン、トリ－２－ヘプチルウンデカン酸グリセライド、ヒマシ油脂肪酸メチルエステル、オレイン酸オレイル、アセトグリセライド、パルミチン酸２－ヘプチルウンデシル、アジピン酸ジイソブチル、Ｎ－ラウロイル－Ｌ－グルタミン酸－２－オクチルドデシルエステル、アジピン酸ジ－２－ヘプチルウンデシル、エチルラウレート、セバシン酸ジ－２－エチルヘキシル、ミリスチン酸２－ヘキシルデシル、パルミチン酸２－ヘキシルデシル、アジピン酸２－ヘキシルデシル、コハク酸２－エチルヘキシル、クエン酸トリエチル等が例示でき、これらの中でも、テトラエチルヘキサン酸ペンタエリスリチルが好ましい。 Ester oils include pentaerythrityl tetraethylhexanoate, cetyl ethylhexanoate, jojoba oil, di(phytosteryl/octyldodecyl) lauroyl glutamate, triisostearin, glyceryl diisostearate, triethylhexanoin, dimer dilinoleic acid (phytosteryl/behenyl). , dimer dilinoleic acid (phytosteryl/isostearyl/cetyl/stearyl/isostearyl/cetyl/stearyl/behenyl), isopropyl palmitate, macadamia nut fatty acid phytosteryl, tetra (behenate/benzoate/ethylhexanoate) pentaerythrityl, Ethylhexyl palmitate, myristyl myristate, isopropyl myristate, tripropylene glycol dipivalate, diisopropyl sebacate, isodecyl neopentanoate, octyl octanoate, nonyl nonanoate, cetyl octanoate, octyldodecyl myristate, butyl stearate, hexyl laurate , decyl oleate, hexyldecyl dimethyloctanoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester , N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, tripropylene glycol pivalate, diisostearyl malate, glyceryl di-2-heptylundecanoate, glyceryl diisostearate, trimethylolpropane tri-2-ethylhexanoate. , trimethylolpropane triisostearate, pentaerythritol tetra-2-ethylhexanoate, glyceryl tri-2-ethylhexanoate, glyceryl trioctanoate, glyceryl triisopalmitate, cetyl 2-ethylhexanoate-2-ethylhexyl palmitate , glyceryl trimyristate, tri-2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid-2- octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, Examples include 2-hexyldecyl palmitate, 2-hexyldecyl adipate, 2-ethylhexyl succinate, and triethyl citrate. Among these, pentaerythrityl tetraethylhexanoate is preferred.
シリコーン油としては、例えば、鎖状ポリシロキサン（例えば、ジメチルポリシロキサン（ジメチコン）、メチルフェニルポリシロキサン（ジフェニルシロキシフェニルトリメチコン）、ジフェニルポリシロキサン等）、環状ポリシロキサン（例えば、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン等）、３次元網目構造を形成しているシリコーン樹脂、シリコーンゴム、各種変性ポリシロキサン（アミノ変性ポリシロキサン、ポリエーテル変性ポリシロキサン、アルキル変性ポリシロキサン、フッ素変性ポリシロキサン等）、アクリルシリコーン類等が挙げられ、これらの中でも、ジメチルポリシロキサンおよびジフェニルシロキシフェニルトリメチコンが好ましい。 Examples of silicone oils include linear polysiloxanes (e.g., dimethylpolysiloxane (dimethicone), methylphenylpolysiloxane (diphenylsiloxyphenyltrimethicone), diphenylpolysiloxane, etc.), cyclic polysiloxanes (e.g., octamethylcyclotetrasiloxane , decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, etc.), silicone resins that form a three-dimensional network structure, silicone rubber, various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane , fluorine-modified polysiloxane, etc.), acrylic silicones, etc. Among these, dimethylpolysiloxane and diphenylsiloxyphenyl trimethicone are preferred.
液体油脂としては、アマニ油、ツバキ油、マカダミアナッツ油、トウモロコシ油、ミンク油、オリーブ油、アボカド油、サザンカ油、ヒマシ油、サフラワー油、ナタネ油、大豆油、落花生油、トリグリセリン、タートル油、卵黄油、ゴマ油、パーシック油、小麦胚芽油、綿実油、エノ油、茶実油、カヤ油、コメヌカ油、シナギリ油、日本キリ油、ホホバ油、胚芽油等が挙げられる。また、固体油脂としては、例えば、カカオ脂、ヤシ油、馬脂、硬化ヤシ油、パーム油、牛脂、羊脂、硬化牛脂、パーム核油、豚脂、牛骨脂、モクロウ核油、硬化油、牛脚脂、モクロウ、硬化ヒマシ油等が挙げられる。 Liquid oils include linseed oil, camellia oil, macadamia nut oil, corn oil, mink oil, olive oil, avocado oil, sasanqua oil, castor oil, safflower oil, rapeseed oil, soybean oil, peanut oil, triglycerin, and turtle oil. , egg yolk oil, sesame oil, persic oil, wheat germ oil, cottonseed oil, perilla oil, tea seed oil, kaya oil, rice bran oil, sinagiri oil, Japanese paulownia oil, jojoba oil, germ oil and the like. Examples of solid fats and oils include cacao butter, coconut oil, horse fat, hydrogenated coconut oil, palm oil, beef tallow, mutton tallow, hydrogenated beef tallow, palm kernel oil, lard, beef bone fat, Japanese wax kernel oil, hydrogenated oil. , beef leg tallow, Japanese wax, hydrogenated castor oil and the like.
香料としては、動物または植物より得られる天然香料と、化学的合成手段によって製造される合成香料、およびそれらの混合物である調合香料が挙げられ、特に限定されない。香料を配合することで、香りの持続性に優れた化粧料を得ることができる。香料としては、具体的には、アセチベノール、アニスアルデヒド、アネトール、アミルアセテート、アミルサリシレート、アリルアミルグリコレート、アリルカプロエート、アルデヒドＣ６～２０、アンブレットライド、アンブレットリド、アンブロキサン、イオノン、イソイースーパー、オイゲノール、オウランチオール、ガラクソリド、カローン、クマリン、ゲラニオール、ゲラニルアセテート、サンダロア、サンタロール、サンデラ、シクラメンアルデヒド、シス－３－ヘキセニルアセテート、シス－３－ヘキセノール、シトラール、シトロネリルアセテート、シトロネロール、シネオール、ジハイドロミルセノール、ジャスモラクトン、シンナミックアルコール、シンナミックアルデヒド、スチラリルアセテート、セドリルアセテート、セドロール、ダマスコン、ダマセノン、デカラクトン、テルピニルアセテート、テルピネオール、トナリッド、トナリド、トリプラール、ネロール、バクダノール、バニリン、ヒドロキシシトロネラール、フェニルエチルアセテート、フェニルエチルアルコール、ヘキシルサリシレート、ベチベリルアセテート、ヘディオン、ヘリオトロピン、ヘリオナール、ベルトフィックス、ベンジルアセテート、ベンジルサリシレート、ベンジルベンゾエート、ペンタリッド、ボルニルアセテート、マイオール、ムスクケトン、メチルアンスラニレート、メチルジヒドロジャスモネート、ヤラヤラ、ライムオキサイド、リナリルアセテート、リナロール、リモネン、リラール、リリアール、ローズオキサイド、ロジノール、アンジェリカオイル、アニスオイル、アルモアゼオイル、バジルオイル、ベイオイル、ベルガモットオイル、カラムスオイル、カンファーオイル、カナンガオイル、カルダモンオイル、カッシアオイル、セダーウッドオイル、セロリオイル、カモミールオイル、シナモンオイル、クローブオイル、コリアンダーオイル、クミンオイル、ディルオイル、エレミオイル、エストラゴンオイル、ユーカリオイル、フェンネルオイル、フェヌグリークオイル、ガルバナムオイル、ゼラニウムオイル、ジンジャーオイル、グレープフルーツオイル、ガヤックウッドオイル、ヒバオイル、ヒノキオイル、ジュニパーベリーオイル、ラバンジンオイル、ラベンダーオイル、レモンオイル、ライムオイル、マンダリンオイル、ジラムオイル、モミザオイル、ペパーミントオイル、スペアミントオイル、ミルオイル、ミルトルオイル、ナツメグオイル、オークモスオイル、オリバナムオイル、オポポナックスオイル、オレンジオイル、パセリオイル、パチュリオイル、ペッパーオイル、ペリラオイル、プチグレンオイル、ネロリオイル、オレンジフラワーオイル、ピメントオイル、オールスパイスオイル、パインオイル、ローズオイル、ローズマリーオイル、クラリセージオイル、セージオイル、サンダルウッドオイル、スチラックスオイル、タジェオイル、タイムオイル、チュベローズオイル、バレリアンオイル、ベチバーオイル、バイオレットリーフオイル、ウィンターグリーンオイル、ワームウッドオイル、イランイランオイル、ユズオイル、カッシーアブソリュート、ジュネアブソリュート、ヒヤシンスアブソリュート、インモルテルアブソリュート、ジャスミンアブソリュート、ジョンキルアブソリュート、ナルシスアブソリュート、ローズアブソリュート、バイオレットリーフアブソリュート、ベンゾイン等が挙げられる。 Flavors include, but are not limited to, natural fragrances obtained from animals or plants, synthetic fragrances produced by chemical synthesis means, and compounded fragrances that are mixtures thereof. By blending the fragrance, a cosmetic having a long-lasting fragrance can be obtained. Specific examples of perfumes include acetylenol, anisaldehyde, anethole, amyl acetate, amyl salicylate, allyl amyl glycolate, allyl caproate, aldehyde C6-20, ambrettolide, ambrettolide, ambroxan, ionone, Isoe super, eugenol, aurantiol, galaxolide, carone, coumarin, geraniol, geranyl acetate, sandalore, santalol, sandera, cyclamenaldehyde, cis-3-hexenyl acetate, cis-3-hexenol, citral, citronellyl acetate, citronellol , cineole, dihydromyrcenol, jasmolactone, cinnamic alcohol, cinnamic aldehyde, styraryl acetate, cedryl acetate, cedrol, damascone, damascenone, decalactone, terpinyl acetate, terpineol, tonalide, tonalide, tripral, Nerol, Bacdanol, Vanillin, Hydroxycitronellal, Phenylethyl Acetate, Phenylethyl Alcohol, Hexyl Salicylate, Betiveryl Acetate, Hedion, Heliotropine, Helional, Beltfix, Benzyl Acetate, Benzyl Salicylate, Benzyl Benzoate, Pentalid, Bornyl Acetate , Myol, Musk Ketone, Methyl Anthranilate, Methyl Dihydrojasmonate, Yarayara, Lime Oxide, Linalyl Acetate, Linalool, Limonene, Liral, Lilial, Rose Oxide, Rodinol, Angelica Oil, Anise Oil, Almoase Oil, Basil Oil , bay oil, bergamot oil, calamus oil, camphor oil, cananga oil, cardamom oil, cassia oil, cedarwood oil, celery oil, chamomile oil, cinnamon oil, clove oil, coriander oil, cumin oil, dill oil, elemi oil, estragon oil , eucalyptus oil, fennel oil, fenugreek oil, galbanum oil, geranium oil, ginger oil, grapefruit oil, gayac wood oil, cypress oil, cypress oil, juniper berry oil, lavandin oil, lavender oil, lemon oil, lime oil, mandarin oil , jiram oil, fir tree oil, peppermint oil, spare Mint oil, myrtle oil, myrtle oil, nutmeg oil, oakmoss oil, olibanum oil, opoponax oil, orange oil, parsley oil, patchouli oil, pepper oil, perilla oil, petitgrain oil, neroli oil, orange flower oil, pimento oil, allspice Oil, pine oil, rose oil, rosemary oil, clary sage oil, sage oil, sandalwood oil, styrax oil, tajee oil, thyme oil, tuberose oil, valerian oil, vetiver oil, violet leaf oil, wintergreen oil, wormwood oil, ylang-ylang oil, yuzu oil, cassi absolute, genea, hyacinth absolute, inmoltel absolute, jasmine absolute, jonquil absolute, narcissus absolute, rose absolute, violet leaf absolute, benzoin and the like.
油溶性紫外線吸収剤としては、例えば、パラアミノ安息香酸（ＰＡＢＡ）、ＰＡＢＡモノグリセリンエステル、Ｎ，Ｎ－ジプロポキシＰＡＢＡエチルエステル、Ｎ，Ｎ－ジエトキシＰＡＢＡエチルエステル、Ｎ，Ｎ－ジメチルＰＡＢＡエチルエステル、Ｎ，Ｎ－ジメチルＰＡＢＡブチルエステル等の安息香酸系紫外線吸収剤；ホモメンチル－Ｎ－アセチルアントラニレート等のアントラニル酸系紫外線吸収剤；アミルサリシレート、メンチルサリシレート、ホモメンチルサリシレート、オクチルサリシレート、フェニルサリシレート、ベンジルサリシレート、ｐ－イソプロパノールフェニルサリシレート等のサリチル酸系紫外線吸収剤；オクチルシンナメート、エチル－４－イソプロピルシンナメート、メチル－２，５－ジイソプロピルシンナメート、エチル－２，４－ジイソプロピルシンナメート、メチル－２，４－ジイソプロピルシンナメート、プロピル－ｐ－メトキシシンナメート、イソプロピル－ｐ－メトキシシンナメート、イソアミル－ｐ－メトキシシンナメート、オクチル－ｐ－メトキシシンナメート、２－エチルヘキシル－ｐ－メトキシシンナメート、２－エトキシエチル－ｐ－メトキシシンナメート、シクロヘキシル－ｐ－メトキシシンナメート、エチル－α－シアノ－β－フェニルシンナメート、２－エチルヘキシル－α－シアノ－β－フェニルシンナメート、グリセリルモノ－２－エチルヘキサノイル－ジパラメトキシシンナメート、３，４，５－トリメトキシケイ皮酸３－メチル－４－［メチルビス（トリメチルシリキシ）シリル］ブチル等のケイ皮酸系紫外線吸収剤；２－フェニル－５－メチルベンゾキサゾール、２，２’－ヒドロキシ－５－メチルフェニルベンゾトリアゾール、２－（２’－ヒドロキシ－５’－ｔ－オクチルフェニル）ベンゾトリアゾール、２－（２’－ヒドロキシ－５’－メチルフェニルベンゾトリアゾール、ジベンザラジン、ジアニソイルメタン、４－メトキシ－４’－ｔ－ブチルジベンゾイルメタン、５－（３，３－ジメチル－２－ノルボルニリデン）－３－ペンタン－２－オン、オクトクリレン等が例示される。 Examples of oil-soluble ultraviolet absorbers include para-aminobenzoic acid (PABA), PABA monoglycerol ester, N,N-dipropoxy PABA ethyl ester, N,N-diethoxy PABA ethyl ester, N,N-dimethyl PABA ethyl ester, N , N-dimethyl PABA butyl ester and other benzoic acid UV absorbers; homomenthyl-N-acetylanthranilate and other anthranilic acid UV absorbers; amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl Salicylic acid-based UV absorbers such as salicylate and p-isopropanol phenyl salicylate; octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2 , 4-diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-p-methoxycinnamate, 2-ethylhexyl-p-methoxycinnamate, 2 -ethoxyethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethyl Cinnamic acid-based UV absorbers such as hexanoyl-diparamethoxycinnamate, 3,4,5-trimethoxycinnamate 3-methyl-4-[methylbis(trimethylsiloxy)silyl]butyl; 2-phenyl- 5-methylbenzoxazole, 2,2'-hydroxy-5-methylphenylbenzotriazole, 2-(2'-hydroxy-5'-t-octylphenyl)benzotriazole, 2-(2'-hydroxy-5' -methylphenylbenzotriazole, dibenzalazine, dianisoylmethane, 4-methoxy-4'-t-butyldibenzoylmethane, 5-(3,3-dimethyl-2-norbornylidene)-3-pentan-2-one, octocrylene, etc. is exemplified.
本発明の化粧料に含まれる油分の配合量は、特に限定されるものではないが、好ましくは、化粧料の全量に対して、１０質量％以下であり、より好ましくは、化粧料の全量に対して、０．５～５質量％である。この範囲とすることで、塗布後のしっとりさなどの使用感を向上させることができ、同時に乳化安定性も保つことができる。 The amount of oil contained in the cosmetic of the present invention is not particularly limited, but is preferably 10% by mass or less, more preferably 10% by mass or less, based on the total amount of the cosmetic. On the other hand, it is 0.5 to 5% by mass. Within this range, the feeling of use such as moistness after application can be improved, and at the same time, emulsion stability can be maintained.
本発明の化粧料には、上記の成分以外に、例えば、粉末成分、紫外線吸収剤、各種水性溶媒、金属イオン封鎖剤、単糖、オリゴ糖、アミノ酸、有機アミン、高分子エマルジョン、アルコール類、ｐＨ調整剤、分散剤、酸化防止剤、防腐剤、安定化剤等を必要に応じて適宜配合してよい。 In addition to the above ingredients, the cosmetic of the present invention includes, for example, powder ingredients, ultraviolet absorbers, various aqueous solvents, sequestering agents, monosaccharides, oligosaccharides, amino acids, organic amines, polymer emulsions, alcohols, pH adjusters, dispersants, antioxidants, preservatives, stabilizers and the like may be appropriately blended as needed.
本発明の化粧料の形態は特に限定されるものではないが、例えば、化粧水、乳液、クリーム、洗顔料、ジェル、エッセンス（美容液）、パック等の基礎化粧品、口紅、アイシャドウ、アイライナー、マスカラ、ファンデーション、サンスクリーン等のメーキャップ化粧品、口腔化粧品、芳香化粧品、毛髪化粧品、ボディ化粧品等、従来化粧料に用いるものであればいずれの形態でも広く適用可能である。 The form of the cosmetic of the present invention is not particularly limited, but for example, basic cosmetics such as lotion, milky lotion, cream, facial cleanser, gel, essence (beauty essence), face pack, lipstick, eye shadow, and eyeliner. , makeup cosmetics such as mascara, foundation, and sunscreen, oral cosmetics, fragrance cosmetics, hair cosmetics, body cosmetics, and the like, and can be widely applied in any form as long as they are conventionally used in cosmetics.
以下の例に基づいて本発明を具体的に説明するが、本発明はこれらの例に限定されるものではない。配合量は特記しない限り、質量％で示す。 The present invention will be specifically described based on the following examples, but the present invention is not limited to these examples. Unless otherwise specified, the blending amount is expressed in mass %.
試験例１
下記の参考例、実施例１～５、および比較例１～６の化粧料（表１および２参照）について、「経時安定性」および「みずみずしさ」について評価を行った。各評価の評価方法は下記の通りに行った。また、各評価結果を下記表１および２に示す。
Test example 1
The cosmetics of Reference Examples, Examples 1 to 5, and Comparative Examples 1 to 6 below (see Tables 1 and 2) were evaluated for "stability over time" and "freshness". The evaluation method of each evaluation was performed as follows. In addition, each evaluation result is shown in Tables 1 and 2 below.
（１）経時安定性
作成した組成物を５０℃で１か月間保管し、その保管前後での乳化粒子のサイズを観察した。評価基準は下記のとおりである。
＜評価基準＞
Ａ：乳化粒子サイズにほぼ変化がない。
Ｂ：保管後に乳化粒子の肥大化または乳化破壊が起きている
(1) Stability over time The prepared composition was stored at 50°C for one month, and the size of emulsion particles was observed before and after the storage. Evaluation criteria are as follows.
<Evaluation Criteria>
A: Almost no change in emulsion particle size.
B: Enlargement of emulsified particles or destruction of emulsification occurs after storage
（２）みずみずしさ
実施例および比較例の化粧料について、１０名の専門パネラーに各実施例および比較例の化粧料を肌へ塗布した際のみずみずしさについて評価を行った。各評価の評価基準は以下である。
＜評価基準＞
Ａ：パネラーの９名以上がみずみずしさを感じたと回答した。
Ｂ：パネラーの６～８名がみずみずしさを感じたと回答した。
Ｃ：パネラーの５名以下がみずみずしさを感じたと回答した。
(2) Freshness With regard to the cosmetics of Examples and Comparative Examples, 10 expert panelists evaluated the freshness when the cosmetics of Examples and Comparative Examples were applied to the skin. The evaluation criteria for each evaluation are as follows.
<Evaluation Criteria>
A: Nine or more panelists answered that they felt freshness.
B: Six to eight panelists answered that they felt freshness.
C: Five or less panelists answered that they felt freshness.
※表１および２中の（C）結晶セルロースは、最大繊維径が１０００ｎｍ以下である微細繊維状セルロース（「レオクリスタＣ－２ＳＰ」（商品名）、第一工業製薬株式会社製）である。なお、「レオクリスタＣ－２ＳＰ」は、２質量％の微細繊維状セルロース、１質量％のフェノキシエタノール（防腐剤）を９７質量％の水中に含む製品であり、本明細書および表に記載している質量％は微細繊維状セルロースのみを指し、商品に含まれる水、防腐剤は含まれない。
*(C) crystalline cellulose in Tables 1 and 2 is fine fibrous cellulose (“Rheocrysta C-2SP” (trade name), manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) having a maximum fiber diameter of 1000 nm or less. "Rheocrysta C-2SP" is a product containing 2% by mass of fine fibrous cellulose, 1% by mass of phenoxyethanol (preservative) in 97% by mass of water, and is described in the specification and tables. % by mass indicates only fine fibrous cellulose, and does not include water and preservatives contained in the product.
Claims (10)
（Ｂ）疎水変性アルキルセルロースと、
（Ｃ）微細セルロース繊維と、
（Ｄ）アルキル変性カルボキシビニルポリマーと、
（Ｅ）油分と
を含有する化粧料であって、前記（Ａ）ニコチン酸またはその誘導体の配合量が、化粧料の全量に対して、１～１０質量％である、化粧料。 (A) nicotinic acid or a derivative thereof;
(B) a hydrophobically modified alkyl cellulose;
(C) fine cellulose fibers;
(D) an alkyl-modified carboxyvinyl polymer;
(E) a cosmetic containing oil, wherein the content of (A) nicotinic acid or a derivative thereof is 1 to 10% by mass relative to the total amount of the cosmetic.
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