JP2022049999A - 洗浄料 - Google Patents
洗浄料 Download PDFInfo
- Publication number
- JP2022049999A JP2022049999A JP2020156340A JP2020156340A JP2022049999A JP 2022049999 A JP2022049999 A JP 2022049999A JP 2020156340 A JP2020156340 A JP 2020156340A JP 2020156340 A JP2020156340 A JP 2020156340A JP 2022049999 A JP2022049999 A JP 2022049999A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- mass
- cleaning agent
- fatty acid
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 34
- 150000001413 amino acids Chemical class 0.000 claims abstract description 12
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 8
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 8
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 7
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 abstract description 22
- 238000005406 washing Methods 0.000 abstract description 18
- 239000004094 surface-active agent Substances 0.000 abstract description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 31
- 239000000194 fatty acid Substances 0.000 description 31
- 229930195729 fatty acid Natural products 0.000 description 31
- 150000004665 fatty acids Chemical class 0.000 description 26
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 22
- 239000000284 extract Substances 0.000 description 20
- -1 fatty acid potassium glutamate Chemical class 0.000 description 18
- 239000011734 sodium Substances 0.000 description 18
- 235000019482 Palm oil Nutrition 0.000 description 12
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
- 239000002540 palm oil Substances 0.000 description 12
- 235000002639 sodium chloride Nutrition 0.000 description 12
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 11
- 239000003240 coconut oil Substances 0.000 description 11
- 235000019864 coconut oil Nutrition 0.000 description 11
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000003921 oil Substances 0.000 description 10
- 235000019198 oils Nutrition 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 229940024606 amino acid Drugs 0.000 description 9
- 235000001014 amino acid Nutrition 0.000 description 9
- 229960003237 betaine Drugs 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 239000002453 shampoo Substances 0.000 description 8
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 7
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 7
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- ILRSCQWREDREME-UHFFFAOYSA-N lauric acid amide propyl betaine Natural products CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 6
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 102100037644 Kelch-like protein 41 Human genes 0.000 description 5
- 108050003242 Kelch-like protein 41 Proteins 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 235000013922 glutamic acid Nutrition 0.000 description 5
- 239000004220 glutamic acid Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- NPKKRSHVJIQBKU-UHFFFAOYSA-N ornogenin Natural products CC(OC(=O)C=Cc1ccccc1)C2(O)CCC3(O)C4(O)CC=C5CC(O)CCC5(C)C4CC(OC(=O)C=Cc6ccccc6)C23C NPKKRSHVJIQBKU-UHFFFAOYSA-N 0.000 description 5
- 239000003346 palm kernel oil Substances 0.000 description 5
- 235000019865 palm kernel oil Nutrition 0.000 description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 240000007594 Oryza sativa Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 229940008099 dimethicone Drugs 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 229940058015 1,3-butylene glycol Drugs 0.000 description 3
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 3
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 3
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 244000303965 Cyamopsis psoralioides Species 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 3
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 3
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 3
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 235000013736 caramel Nutrition 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 3
- 230000037308 hair color Effects 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 3
- 229940094506 lauryl betaine Drugs 0.000 description 3
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 3
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 3
- 229960002216 methylparaben Drugs 0.000 description 3
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 3
- 229960005323 phenoxyethanol Drugs 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 108700004121 sarkosyl Proteins 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 235000010356 sorbitol Nutrition 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 2
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- HJDITXMCJQRQLU-UHFFFAOYSA-N 2-[dodecanoyl(methyl)amino]acetate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCC(=O)N(C)CC(O)=O HJDITXMCJQRQLU-UHFFFAOYSA-N 0.000 description 2
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 102000008186 Collagen Human genes 0.000 description 2
- 108010035532 Collagen Proteins 0.000 description 2
- 244000020551 Helianthus annuus Species 0.000 description 2
- 235000003222 Helianthus annuus Nutrition 0.000 description 2
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical compound CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 description 2
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 2
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- NKSOSPOXQKNIKJ-CLFAGFIQSA-N Polyoxyethylene dioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCOC(=O)CCCCCCC\C=C/CCCCCCCC NKSOSPOXQKNIKJ-CLFAGFIQSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
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- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
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- 239000001110 calcium chloride Substances 0.000 description 2
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- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 2
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- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
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- 239000003676 hair preparation Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 2
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- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
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- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
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- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
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- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
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- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- DHYWSAPLZYWZSZ-UHFFFAOYSA-N 2-(dimethylazaniumyl)hexadecanoate Chemical compound CCCCCCCCCCCCCCC(N(C)C)C(O)=O DHYWSAPLZYWZSZ-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
(A)アミノ酸系アニオン界面活性剤2種以上を全体質量中5質量%以上
(B)両性界面活性剤を全体質量中1質量%以上
(C)多価アルコール
(D)水溶性無機塩全体質量中1質量%以下%
本発明の洗浄料は、例えば、シャンプー、ボディソープ、ハンドソープ等に用いることができる。
本発明において、洗浄基材として、アミノ酸系界面活性剤の中でも特にアミノ酸系アニオン界面活性剤を2種以上任意に組み合わせて用いる。アミノ酸系アニオン界面活性剤を用いることですすぎ時の指通りの点で好適であり、さらに2種以上組合せることで洗浄時の髪の絡まりのなさの点で好適である。
本発明において、(B)両性界面活性剤は洗浄補助剤の目的で用いられる。
本発明において、(C)多価アルコールは毛髪のコンディショニングの目的で用いられる。
本発明において、(D)水溶性無機塩は製剤の増粘目的で用いられる。
量%以下が好ましい。(D)成分が1質量%以下であれば、タオルドライ後の指通りが良好である。さらに好ましくは、(D)成分が0.01質量%以上であれば、製剤の使用性が良好となる。
本発明の毛髪化粧料においては、本発明の効果を損なわない範囲で、必要に応じて、さらに通常毛髪化粧料に用いられている他の追加成分を配合することができる。これら追加成分としては、例えば、アボカド油、アルモンド油、オリーブ油、グレープシード油、キョウニン油、コメヌカ油、コメ胚芽油、月見草油、ツバキ油、サザンカ油、マカデミアナッツ油、メドフォーム油、シアバター、卵黄油、馬脂等の油脂類、ホホバ油、カルナウバロウ、キャンデリラロウ、ラノリン、ミツロウ等のロウ類、オゾケライト、流動パラフィン、スクワレン、ワセリン等の炭化水素類、イソステアリルアルコール、オクチルドデカノール、ラノリンアルコール、フィトステロール、セタノール、オレイルアルコール等の高級アルコール類、ミリスチン酸イソプロピル、オレイン酸エチル、ステアリン酸オクチル、2-エチルヘキサン酸セチル、イソノナン酸イソノニル、パルミチン酸オクチル、ジオレイン酸エチレングリコール、トリイソステアリン酸グリセリル、乳酸セチル、アジピン酸ジイソプロピル、イソステアリン酸コレステリル等のエステル油類等、エチルアルコール、イソプロパノール等の低級アルコール、キサンタンガム、グアガム、デンプン等の天然高分子及びその誘導体、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、メチルセルロース等のセルロール系高分子、カルボキシビニルポリマーやポリビニルピロリドン等の合成高分子等、ポリオキシエチレンセチルエーテル、モノステアリン酸ソルビタン、トリイソステアリン酸ポリオキシエチレンソルビタン、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンモノイソステアレート、ポリオキシエチレンジオレイン酸グリセリル、ヤシ油脂肪酸ジエタノールアミド、ヤシ油脂肪酸モノエタノールアミド、ヤシ油脂肪酸N-メチルエタノールアミド、ポリオキシエチレンポリオキシプロピレングリコール、モノラウリン酸ポリエチレングリコール等のノニオン性界面活性剤、ジステアリン酸エチレングリコール、ジステアリン酸トリエチレングリコール等のパール化剤、カオリン、無水ケイ酸、ケイ酸アルミニウムマグネシウム、タルク、マイカ、セルロース末、シルク末、デンプン、ポリエチレン末、ナイロン末、架橋ポリスチレン等の顔料、防腐剤、金属イオン封鎖剤、噴射剤、無機塩、有機酸及びその塩、ピロリドンカルボン酸及びその塩、ヒアルロン酸及びその塩、トリメチルグリシン等の保湿剤、塩化ベンザルコニウム、塩化ベンゼトニウム、イソプロピルメチルフェノール、ピロクトンオラミン、クララ抽出物、ジンクピリチオン、ヒノキチオール等の殺菌剤、その他、センブリ抽出物、塩化カプロニウム、セファランチン、サリチル酸、イノシット、ヨウ化ニンニク抽出物、レゾルシン、エストラジオール、エチニルエストラジオール、オキセンドロン、パントテン酸及びその誘導体、プラセンタ抽出物、ビオチン、モノニトログアヤコール、感光素301、ウシヘマチン、グリチルリチン酸ジカリウム、塩酸ピリドキシン、冷感剤、温感剤、動植物抽出物、ビタミン、紫外線吸収剤、アミノ酸及びその誘導体、タンパク質及びその誘導体、酸化防止剤、着色剤、香料等が挙げられる。
実施例及び比較例における洗浄料を、表1、2に記載の配合で常法により調製した。また、成分(A)~(D)としては以下のものを用いた。
<成分(A)>
(A-1)ラウロイルサルコシントリエタノールアミン
(A-2)ラウロイルメチル-β-アラニンナトリウム
(A-3)ラウロイルヒドロキシエチル-β-アラニンナトリウム
(A-4)ヤシ油脂肪酸メチルタウリンナトリウム
(A-5)ヤシ油脂肪酸グルタミン酸トリエタノールアミン
(A-6)ヤシ油脂肪酸グルタミン酸ナトリウム
<成分(B)>
(B-1)ラウリン酸アミドプロピルベタイン
(B-2)ヤシ油脂肪酸アミドプロピルベタイン
(B-3)パーム核脂肪酸アミドプロピルベタイン
(B-4)2-アルキル-N-カルボキシメチル-N-ヒドロキシエチルイミダゾリニウムベタイン
(B-5)ラウリルベタイン
<成分(C)>
(C-1)プロピレングリコール
(C-2)ジプロピレングリコール
(C-3)1,3ブチレングリコール
(C-4)グリセリン
(C-5)ソルビトール
(C-6)トレハロース
(C-7)イノシトール
<成分(D)>
(D-1)塩化ナトリウム
<成分(E)>
(E-1)安息香酸ナトリウム
<成分(F)>
(F-1)クエン酸
ビューラックス社製アジア人同一人毛(長さ30cm、重さ10g)の毛束を、表1、2に記載の実施例及び比較例におけるシャンプー(1g)で洗浄して、タオルドライを行った後、長さ25cm、毛量を同一に調整した。
実施例及び比較例において用いた試験方法、評価基準を以下に説明する。
(試験方法)
訓練された20名の専門パネルが、表1、2の実施例及び比較例の洗浄料を、手に取った際に洗浄料がすぐに垂れ落ちること無く、髪全体へと塗り広げる際に洗浄料が伸ばしやすいかを「良い」、「普通」、「悪い」の3段階で判定し、次の基準で評価を行った。
(評価基準)
◎:「良い」と答えた専門パネルが16名以上
〇:「良い」と答えた専門パネルが11~15名
△:「良い」と答えた専門パネルが6~10名
×:「良い」と答えた専門パネルが5名以下
訓練された20名の専門パネルが、上記の毛束試料を用いて、表1、2の実施例及び比較例の洗浄料で洗浄し、洗浄時の髪の絡まりの無さを「良い」、「普通」、「悪い」の3段階で判定し、上記の基準で評価を行った。
訓練された20名の専門パネルが、各パネルの頭髪を表1、2の実施例及び比較例の洗浄料で洗浄し、濯ぎ時の毛髪のぬるつきの無さ、手や身体ぬるつきのなさの項目について、「良い」、「普通」、「悪い」の3段階で判定し、上記の基準で評価。
訓練された20名の専門パネルが、 上記の毛束試料を用いて、を表1、2の実施例及び比較例の洗浄料で洗浄し、タオルドライ後の指通りを「良い」、「普通」、「悪い」の3段階で判定し、上記の基準で評価を行った。
訓練された20名の専門パネルが、 上記の毛束試料を用いて、表1、2の実施例及び比較例の洗浄料で洗浄し、自然乾燥させた後の毛髪のまとまりを「良い」、「普通」、「悪い」の3段階で判定し、上記の基準で評価を行った。
訓練された20名の専門パネルが、 上記の毛束試料を用いて、 表1、2の実施例及び比較例の洗浄料で洗浄し、自然乾燥させた後の毛髪の艶を「良い」、「普通」、「悪い」の3段階で判定し、上記の基準で評価を行った。
(1)ラウロイルサルコシンTEA 10.0
(2)ココイルグルタミン酸TEA 1.0
(3)ラウロイルヒドロキシエチル-β-アラニンNa 1.0
(4)ココイルトレオニンNa 1.0
(5)ラウレス硫酸Na 1.0
(6)コカミドプロピルベタイン 0.5
(7)ラウリルベタイン 0.5
(8)コカミドMEA 2.0
(9)PPG-2コカミド 1.0
(10)PPG-3カプリリルエーテル 1.0
(11)ジステアリン酸グリコール 1.0
(12)ジメチコン 1.0
(13)PPG-12ジメチコン 2.0
(14)ポリクオタニウム-10 0.2
(15)グアーヒドロキシプロピルトリモニウムクロリド 0.1
(16)ポリクオタニウム-7 0.2
(17)ポリクオタニウム-49 0.2
(18)塩化Na 0.1
(19)EDTA-2Na 0.1
(20)BG 1.0
(21)カワラナデシコ種子抽出物 0.1
(22)ヒマワリ種子油 0.1
(23)ヒマワリ種子抽出物 0.1
(24)ヒマワリ花抽出物 0.1
(25)ヒマワリ芽抽出物 0.1
(26)メントール 0.1
(27)アセチルグルコサミン 0.1
(28)ラクトフェリン 0.1
(29)ヨーグルト液 0.1
(30)グリチルリチン酸2K 0.1
(31)トコフェロール 0.1
(32)ラウロイルグルタミン酸ジ(フィトステリル/オクチルドデシル)0.1
(33)セバシン酸ジエチル 0.1
(34)ラウリン酸 1.0
(35)安息香酸Na 0.5
(36)フェノキシエタノール 1.0
(37)メチルパラベン 1.0
(38)香料 1.0
(39)カラメル 1.0
(40)水 残余
(1)ラウロイルサルコシンTEA 2.0
(2)ココイルメチルタウリンNa 3.0
(3)ココイルグルタミン酸2Na 2.0
(4)ココイルグルタミン酸Na 2.0
(5)ココイルグルタミン酸TEA 2.0
(6)パーム核脂肪酸アミドプロピルベタイン 2.0
(7)ココベタイン 2.0
(8)コカミドプロピルベタイン 5.0
(9)コカミドMEA 1.0
(10)ラウラミドMIPA 5.0
(11)PPG-3カプリリル 0.5
(12)シクロヘキサン-1,4-ジカルボン酸ビスエトキシジグリコール3.0
(13)ヤシ油脂肪酸PEG-7グリセリル 0.5
(14)ポリクオタニウム-10 0.1
(15)グアーヒドロキシプロピルトリモニウムクロリド 1.0
(16)ポリクオタニウム-7 0.2
(17)ポリクオタニウム-107 0.01
(18)クエン酸 0.1
(19)EDTA-2Na 0.1
(20)グリセリン 1.0
(21)塩化ナトリウム 0.3
(22)コメヌカ油 0.001
(23)コメ抽出物 0.1
(24)ムクロジ抽出物 0.1
(25)コメ胚芽油 0.1
(26)ヒオウギ抽出物 0.1
(27)ツバキ種子抽出物 0.1
(28)コメヌカ抽出物 0.1
(29)アンズ核油 0.001
(30)チャ花抽出物 0.1
(31)コムラサキ果実抽出物 0.1
(32)ダイズ種子抽出物 0.1
(33)カワラナデシコ種子抽出物 1.0
(34)ミリスチン酸 0.1
(35)安息香酸Na 0.5
(36)フェノキシエタノール 1.0
(37)メチルパラベン 1.0
(38)香料 0.01
(39)カラメル 1.0
(40)水 残余
(1)ラウロイルサルコシンTEA 5.0
(2)ラウレス硫酸Na 1.0
(3)ラウリル硫酸Na 1.0
(4)ココイルグルタミン酸TEA 1.0
(5)ラウロイルメチルアラニンNa 1.0
(6)ラウラミドプロピルベタイン 2.0
(7)ヤシ油脂肪酸アミドプロピルベタイン 2.0
(8)ジステアリン酸グリコール 2.0
(9)セテアレス-60ミリスチルグリコール 1.0
(10)コカミドメチルMEA 1.0
(11)ヤシ油脂肪酸PEG-7グリセリル 1.0
(12)ジメチルポリシロキサン 2.0
(13)アモジメチコン 5.0
(14)(ジビニルジメチコン/ジメチコン)コポリマー 0.1
(15)ポリクオタニウム-10 1.0
(16)グアーヒドロキシプロピルトリモニウムクロリド 0.5
(17)ポリクオタニウム-7 0.1
(18)ポリクオタニウム-51 0.001
(19)クエン酸Na 0.1
(20)EDTA-2Na 0.1
(21)ソルビトール 1.0
(23)塩化ナトリウム 0.5
(24)紅藻抽出物 0.1
(25)褐藻抽出物 0.1
(26)緑藻抽出物 0.1
(27)カワラナデシコ種子抽出物 0.5
(28)加水分解スサビノリ 0.1
(29)海水 0.1
(30)加水分解コラーゲン 0.1
(31)水溶性コラーゲン 0.1
(32)セリン 0.1
(33)プロリン 0.1
(34)グルタミン酸Na 0.1
(35)アルギニン 0.1
(36)アラニン 0.1
(37)パルミチン酸 3.0
(38)安息香酸Na 0.5
(39)フェノキシエタノール 1.0
(40)メチルパラベン 1.0
(41)香料 1.0
(42)カラメル 1.0
(43)水 残余
Claims (3)
- 下記(A)、(B)、(C)及び(D)を含有することを特徴とする洗浄料。
(A)アミノ酸系アニオン界面活性剤2種以上を全体質量中5質量%以上
(B)両性界面活性剤を全体質量中1質量%以上
(C)多価アルコール
(D)水溶性無機塩全体質量中1質量%以下% - 前記(C)成分が0.005質量%以上である請求項1記載の洗浄料。
- 30℃におけるpHが6以下、粘度が1500~5000mPa・sである請求項1又は2記載の洗浄料。
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