JP2021187815A - Hair cosmetic composition - Google Patents
Hair cosmetic composition Download PDFInfo
- Publication number
- JP2021187815A JP2021187815A JP2020097585A JP2020097585A JP2021187815A JP 2021187815 A JP2021187815 A JP 2021187815A JP 2020097585 A JP2020097585 A JP 2020097585A JP 2020097585 A JP2020097585 A JP 2020097585A JP 2021187815 A JP2021187815 A JP 2021187815A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- oil
- cosmetic composition
- hair cosmetic
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
- DRRMRHKHTQRWMB-UHFFFAOYSA-N [3-(2-ethylhexanoyloxy)-2,2-bis(2-ethylhexanoyloxymethyl)propyl] 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(COC(=O)C(CC)CCCC)(COC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DRRMRHKHTQRWMB-UHFFFAOYSA-N 0.000 description 1
- 229940124532 absorption promoter Drugs 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- 150000003862 amino acid derivatives Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960005261 aspartic acid Drugs 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- DHAZIUXMHRHVMP-UHFFFAOYSA-N butyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCC DHAZIUXMHRHVMP-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 229940074979 cetyl palmitate Drugs 0.000 description 1
- 229940048851 cetyl ricinoleate Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 235000018597 common camellia Nutrition 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- SASYSVUEVMOWPL-NXVVXOECSA-N decyl oleate Chemical compound CCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC SASYSVUEVMOWPL-NXVVXOECSA-N 0.000 description 1
- BOUIEBMBWBCUPB-UHFFFAOYSA-N decyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCCCC BOUIEBMBWBCUPB-UHFFFAOYSA-N 0.000 description 1
- KWABLUYIOFEZOY-UHFFFAOYSA-N dioctyl butanedioate Chemical compound CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC KWABLUYIOFEZOY-UHFFFAOYSA-N 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- XMXOIHIZTOVVFB-JIZZDEOASA-L disodium;(2s)-2-aminobutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CC([O-])=O XMXOIHIZTOVVFB-JIZZDEOASA-L 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- 229950010030 dl-alanine Drugs 0.000 description 1
- QQQMUBLXDAFBRH-UHFFFAOYSA-N dodecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)O QQQMUBLXDAFBRH-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 229960003720 enoxolone Drugs 0.000 description 1
- DMMXZLMYEUEJFT-UHFFFAOYSA-N ethyl 16-methylheptadecanoate Chemical compound CCOC(=O)CCCCCCCCCCCCCCC(C)C DMMXZLMYEUEJFT-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- FMMOOAYVCKXGMF-MURFETPASA-N ethyl linoleate Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(=O)OCC FMMOOAYVCKXGMF-MURFETPASA-N 0.000 description 1
- 229940031016 ethyl linoleate Drugs 0.000 description 1
- GJQLBGWSDGMZKM-UHFFFAOYSA-N ethylhexyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(CC)CCCCC GJQLBGWSDGMZKM-UHFFFAOYSA-N 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 229960004949 glycyrrhizic acid Drugs 0.000 description 1
- 235000019410 glycyrrhizin Nutrition 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 239000010468 hazelnut oil Substances 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- PXDJXZJSCPSGGI-UHFFFAOYSA-N hexadecanoic acid hexadecyl ester Natural products CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 1
- XAMHKORMKJIEFW-AYTKPMRMSA-N hexadecyl (z,12r)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCC\C=C/C[C@H](O)CCCCCC XAMHKORMKJIEFW-AYTKPMRMSA-N 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- FPMPNVIMFPEKRN-UHFFFAOYSA-N hexyl 16-methylheptadecanoate Chemical compound CCCCCCOC(=O)CCCCCCCCCCCCCCC(C)C FPMPNVIMFPEKRN-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229940078545 isocetyl stearate Drugs 0.000 description 1
- 229940093629 isopropyl isostearate Drugs 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940060384 isostearyl isostearate Drugs 0.000 description 1
- 229940113915 isostearyl palmitate Drugs 0.000 description 1
- 150000003903 lactic acid esters Chemical class 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- FMMOOAYVCKXGMF-UHFFFAOYSA-N linoleic acid ethyl ester Natural products CCCCCC=CCC=CCCCCCCCC(=O)OCC FMMOOAYVCKXGMF-UHFFFAOYSA-N 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- VNLRTFSQCPNNIM-UHFFFAOYSA-N octadecyl octanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCC VNLRTFSQCPNNIM-UHFFFAOYSA-N 0.000 description 1
- KSCKTBJJRVPGKM-UHFFFAOYSA-N octan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-] KSCKTBJJRVPGKM-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 229960001679 octinoxate Drugs 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 229940116422 propylene glycol dicaprate Drugs 0.000 description 1
- 229940010310 propylene glycol dioleate Drugs 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 239000010667 rosehip oil Substances 0.000 description 1
- 239000010668 rosemary oil Substances 0.000 description 1
- 229940058206 rosemary oil Drugs 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 230000001256 tonic effect Effects 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- APVVRLGIFCYZHJ-UHFFFAOYSA-N trioctyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCC)CC(=O)OCCCCCCCC APVVRLGIFCYZHJ-UHFFFAOYSA-N 0.000 description 1
- COXJMKGEQAWXNP-UHFFFAOYSA-N tris(14-methylpentadecyl) 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CC(C)CCCCCCCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCCCCCCCC(C)C)CC(=O)OCCCCCCCCCCCCCC(C)C COXJMKGEQAWXNP-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は毛髪化粧料組成物に関し、詳しくは、ダメージを受けた毛髪へなめらかさ、しっとり感、ツヤといったトリートメント効果を付与しながらも子供の細い毛髪でも重くならず、べたつきが少ない毛髪化粧料組成物に関する。 The present invention relates to a hair cosmetic composition. Specifically, the present invention provides a treatment effect such as smoothness, moistness, and luster to damaged hair, but does not make even fine hair of a child heavy and less sticky. Regarding things.
毛髪になめらかさやツヤを付与し、くし通りをよくするために、洗い流さないタイプのコンディショニング効果を持つ毛髪化粧料が用いられ、一般にヘアエッセンス、ヘアクリーム、ヘアオイル、ヘアリクイド等の名称のヘアトリートメントが市販されている。 Hair cosmetics with a non-rinse type conditioning effect are used to give the hair smoothness and luster and improve combing, and hair treatments with names such as hair essence, hair cream, hair oil, and hair liquid are generally available on the market. Has been done.
毛髪になめらかさやツヤを与える目的でシリコーン油、高分子のジメチルポリシロキサン、高分子のメチルフェニルポリシロキサン等の油分が、可溶化、乳化、溶解されて用いられている。特にシリコーン油は、表面張力が低く毛髪へのなじみに優れ、良好なツヤを与えられることから、シリコーン油を含有する毛髪化粧料が多く提案されている（例えば、特許文献１）。 Oils such as silicone oil, high molecular weight dimethylpolysiloxane, and high molecular weight methylphenylpolysiloxane are solubilized, emulsified, and dissolved for the purpose of giving hair smoothness and luster. In particular, silicone oil has a low surface tension, is excellent in adapting to hair, and is given good luster. Therefore, many hair cosmetics containing silicone oil have been proposed (for example, Patent Document 1).
また、ダメージを付けた毛髪の表面及び内部の状態を改善しながら、毛髪にハリ・コシ感や自然なツヤを与えるがべたつきがない軽い仕上がりを実現するために、二塩基酸のエステル化合物と、揮発性油、エステル油、炭化水素油、動植物油及びシリコーン油からなる群から選択される１種又は２種以上の油剤を含有する毛髪化粧料が提案されている（例えば、特許文献２）。 In addition, in order to improve the surface and internal condition of damaged hair while giving the hair a firm and firm feeling and a natural luster, but to achieve a light finish without stickiness, an ester compound of dibasic acid and Hair cosmetics containing one or more oils selected from the group consisting of volatile oils, ester oils, hydrocarbon oils, animal and vegetable oils and silicone oils have been proposed (eg, Patent Document 2).
しかしながら、特許文献１に記載のような洗い流さないオイルタイプの毛髪化粧料では、子供の細い髪に使用すると毛髪がべたつき、重くなってしまうという課題があった。 However, the oil-type hair cosmetics that do not wash off as described in Patent Document 1 have a problem that the hair becomes sticky and heavy when used on fine hair of children.
一方で、特許文献２に記載のようなべたつきの少ない、さらさらとした軽い手触りの毛髪化粧料では、大人のダメージを受けた毛髪へのコンディショニング効果が十分ではなく、毛髪へのなめらかさ、しっとり感、ツヤ付与効果が物足りないという問題があった。 On the other hand, a hair cosmetic with a light texture and less stickiness as described in Patent Document 2 does not have a sufficient conditioning effect on damaged hair of adults, and has a smooth and moist feeling on the hair. There was a problem that the gloss effect was not enough.
したがって本発明は、これらの問題を解決するために、ダメージを受けた毛髪へなめらかさ、しっとり感、ツヤといったトリートメント効果を付与しながらも子供の細い毛髪でも重くならず、べたつきが少ない毛髪化粧料組成物を提供することを課題とする。 Therefore, in order to solve these problems, the present invention provides a treatment effect such as smoothness, moistness, and luster to damaged hair, but does not make even fine children's hair heavy and less sticky. It is an object to provide a composition.
本発明者は、上記課題を解決すべく鋭意検討を行った結果、
（Ａ）トリイソステアリン酸ＰＥＧ−２０グリセリル、
（Ｂ）下記一般式（１）で表されるエステル化合物
Ｒ１Ｏ−（ＡＯ）ｎ−ＣＯＲ２ （１）
（式中、
Ｒ１はベンジル基を示し、
Ｒ２は炭素数１〜２５の直鎖又は分岐鎖のアルキル基又はアルケニル基を示し、
ＡＯは炭素数２以上４以下のアルキレンオキシ基を示し、
ｎは１〜５０の整数であって、
ｎが２以上の場合、ｎ個のＡＯ基は同一でも異なっていてもよい。）及び、
（Ｃ）前記成分（Ｂ）と異なる２０℃で液状のエステル油１種以上を含むことを特徴とする毛髪化粧料組成物により上記課題が解決されることを見出し、本発明を完成した。
As a result of diligent studies to solve the above problems, the present inventor
(A) PEG-20 glyceryl triisostearate,
(B) Ester compound represented by the following general formula (1) R 1 O- (AO) n- COR 2 (1)
(During the ceremony,
R 1 represents a benzyl group,
R 2 represents a linear or branched alkyl or alkenyl group having 1 to 25 carbon atoms.
AO represents an alkyleneoxy group having 2 or more and 4 or less carbon atoms.
n is an integer from 1 to 50
When n is 2 or more, the n AO groups may be the same or different. )as well as,
(C) The present invention has been completed by finding that the above-mentioned problems can be solved by a hair cosmetic composition characterized by containing one or more kinds of ester oils that are liquid at 20 ° C. different from the component (B).
第一の発明は、
（Ａ）トリイソステアリン酸ＰＥＧ−２０グリセリル、
（Ｂ）下記一般式（１）で表されるエステル化合物、
Ｒ１Ｏ−（ＡＯ）ｎ−ＣＯＲ２ （１）
（式中、
Ｒ１はベンジル基を示し、
Ｒ２は炭素数１〜２５の直鎖又は分岐鎖のアルキル基又はアルケニル基を示し、
ＡＯは、炭素数２以上４以下のアルキレンオキシ基を示し、
ｎは１〜５０の整数であって、
ｎが２以上の場合、ｎ個のＡＯ基は同一でも異なっていてもよい。）、及び
（Ｃ）前記成分（Ｂ）と異なる２０℃で液状のエステル油１種以上を含む、毛髪化粧料組成物である。
The first invention is
(A) PEG-20 glyceryl triisostearate,
(B) The ester compound represented by the following general formula (1),
R 1 O- (AO) n- COR 2 (1)
(During the ceremony,
R 1 represents a benzyl group,
R 2 represents a linear or branched alkyl or alkenyl group having 1 to 25 carbon atoms.
AO represents an alkyleneoxy group having 2 or more and 4 or less carbon atoms.
n is an integer from 1 to 50
When n is 2 or more, the n AO groups may be the same or different. ), And (C) a hair cosmetic composition containing one or more kinds of ester oils that are liquid at 20 ° C. different from the component (B).
本発明の毛髪化粧料組成物によれば、ダメージを受けた毛髪へなめらかさ、しっとり感、ツヤといったトリートメント効果を付与しながらも子供の細い毛髪でも重くならず、べたつきが少ない状態を実現することができる。 According to the hair cosmetic composition of the present invention, it is possible to realize a state in which even fine hair of a child does not become heavy and is less sticky while imparting treatment effects such as smoothness, moistness, and luster to damaged hair. Can be done.
以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.
［毛髪化粧料組成物］
本発明において毛髪化粧料組成物とは、（Ａ）トリイソステアリン酸ＰＥＧ−２０グリセリル、（Ｂ）特定のエステル化合物、及び（Ｃ）前記成分（Ｂ）と異なる２０℃で液状のエステル油を含むことを特徴とする、毛髪化粧料組成物である。これらの成分（Ａ）〜（Ｃ）を特定の割合で配合することにより、本発明による効果を発揮することができる。本発明の毛髪化粧料組成物は、本発明の効果を発揮できる限りにおいて洗い流さないタイプであっても洗い流すタイプであってもよいが、好ましくは洗い流さないタイプの毛髪化粧料である。ここで、「洗い流さないタイプの毛髪化粧料」とは、洗い流さず毛髪へ塗布したままにする、いわゆるアウトバスタイプの毛髪化粧料である。
[Hair cosmetic composition]
In the present invention, the hair cosmetic composition contains (A) PEG-20 glyceryl triisostearate, (B) a specific ester compound, and (C) an ester oil that is liquid at 20 ° C. different from the component (B). It is a hair cosmetic composition characterized by the above. By blending these components (A) to (C) in a specific ratio, the effect of the present invention can be exhibited. The hair cosmetic composition of the present invention may be a non-rinse type or a wash-off type as long as the effect of the present invention can be exhibited, but is preferably a non-rinse type hair cosmetic composition. Here, the "non-rinse type hair cosmetic" is a so-called out bath type hair cosmetic that is left applied to the hair without being washed away.
アウトバスタイプの毛髪化粧料としては以下に限定されるものではないが、例えば、ヘアフォームや、ヘアワックス、ポマード、ヘアジェル、ヘアエッセンス、ヘアクリーム、ヘアスプレー、ヘアミスト、ヘアウォーター、ヘアリキッド、ヘアオイル、ヘアカラースプレー、ヘアトニック、養毛剤等が挙げられる。 Out-bath type hair cosmetics are not limited to the following, but for example, hair foam, hair wax, pomade, hair gel, hair essence, hair cream, hair spray, hair mist, hair water, hair liquid, hair oil. , Hair color spray, hair tonic, hair nourishing agent and the like.
本発明において毛髪化粧料の剤型は、公知の剤型の中から、その用途や使用目的等に応じて任意に選択することができる。例えば、液体状、乳液状、クリーム状、ゲル状、ペースト状、泡状等とすることができ、泡状の場合、エアゾール形態、ノンエアゾール形態のいずれでもよい。 In the present invention, the dosage form of the hair cosmetic can be arbitrarily selected from the known dosage forms according to its use, purpose of use and the like. For example, it can be in the form of liquid, milky liquid, cream, gel, paste, foam or the like, and in the case of foam, it may be in the aerosol form or the non-aerosol form.
以下、本発明の毛髪化粧料組成物の各成分について詳細に説明する。 Hereinafter, each component of the hair cosmetic composition of the present invention will be described in detail.
［（Ａ）トリイソステアリン酸ＰＥＧ−２０グリセリル］
本発明における（Ａ）トリイソステアリン酸ＰＥＧ−２０グリセリルとは、イソステアリン酸に酸化エチレンを付加重合し、多価アルコールの一種であるグリセリンとエステル結合して得られるトリエステルであり、酸化エチレン縮合型のポリオキシエチレン多価アルコール脂肪酸エステルに分類される非イオン界面活性剤である。一般的に（Ａ）トリイソステアリン酸ＰＥＧ−２０グリセリルは、毛髪化粧料中にエモリエント剤、乳化剤の目的で配合される。本発明においては、（Ａ）トリイソステアリン酸ＰＥＧ−２０グリセリルは市販品を用いてもよい。本発明において用いることができる市販品としては、これらに限定されるものではないが、例えば、ＣＩＴＨＲＯＬ １０ＧＴＩＳ（クローダジャパン株式会社製）、ＥＭＡＬＥＸ ＧＷＩＳ−３２０（日本エマルジョン株式会社製）、ＥＭＡＬＥＸ ＧＷＩＳ−３２０ＥＸ（日本エマルジョン株式会社製）、ＭファインオイルＩＳＧ−２０Ｔ（ミヨシ油脂株式会社製）、ＮＩＫＫＯＬ ＴＧＩ−２０（日光ケミカルズ株式会社製）、ハイパーオイルＧＷ−３２（交洋ファインケミカル株式会社製）、ユニオックスＧＴ−２０ＩＳ（日油株式会社製）、サラコス ＧＥ−３１８（日清オイリオグループ株式会社製）、等が挙げられる。このようなトリイソステアリン酸ＰＥＧ−２０グリセリルは、それぞれ単独で用いることもでき、また２種以上混合して用いることもできる。
[(A) PEG-20 glyceryl triisostearate]
The PEG-20 glyceryl triisostearate (A) in the present invention is a triester obtained by addition-polymerizing ethylene oxide to isostearic acid and ester-bonding it with glycerin, which is a kind of polyhydric alcohol, and is an ethylene oxide condensation type. It is a nonionic surfactant classified as polyoxyethylene polyhydric alcohol fatty acid ester. Generally, (A) PEG-20 glyceryl triisostearate is added to hair cosmetics for the purpose of emollients and emulsifiers. In the present invention, a commercially available product may be used as the (A) PEG-20 glyceryl triisostearate. The commercially available products that can be used in the present invention are not limited to these, but are, for example, CITHROLL 10GTIS (manufactured by Croder Japan Co., Ltd.), EMALEX GWIS-320 (manufactured by Nippon Emulsion Co., Ltd.), EMALEX GWIS-320EX. (Manufactured by Nippon Emulsion Co., Ltd.), M Fine Oil ISG-20T (manufactured by Miyoshi Oil & Fat Co., Ltd.), NIKKOL TGI-20 (manufactured by Nikko Chemicals Co., Ltd.), Hyper Oil GW-32 (manufactured by Koyo Fine Chemicals Co., Ltd.), Uniox GT-20IS (manufactured by Nissin Co., Ltd.), Sarakos GE-318 (manufactured by Nisshin Oillio Group Co., Ltd.), and the like can be mentioned. Such PEG-20 glyceryl triisostearate can be used alone or in combination of two or more.
本発明の毛髪化粧料組成物におけるＡ）トリイソステアリン酸ＰＥＧ−２０グリセリルの含有量は、好ましくは５質量％〜１５質量％であり、より好ましくは７質量％〜１２質量％である。本発明の毛髪化粧料組成物における（Ａ）トリイソステアリン酸ＰＥＧ−２０グリセリルの含有量が５質量％以上であれば、なめらかさ、しっとり感、ツヤやまとまり感といったトリートメント効果を毛髪へ付与することができ、１５質量％以下であれば過度のぬるつきやべたつきを生じない。 The content of A) PEG-20 glyceryl triisostearate in the hair cosmetic composition of the present invention is preferably 5% by mass to 15% by mass, and more preferably 7% by mass to 12% by mass. When the content of (A) PEG-20 glyceryl triisostearate in the hair cosmetic composition of the present invention is 5% by mass or more, a treatment effect such as smoothness, moist feeling, gloss and cohesiveness is imparted to the hair. If it is 15% by mass or less, excessive stickiness and stickiness do not occur.
［（Ｂ）エステル化合物］
本発明における（Ｂ）エステル化合物は、下記一般式（１）：
Ｒ１Ｏ−（ＡＯ）ｎ−ＣＯＲ２ （１）
（式中、
Ｒ１はベンジル基を示し、
Ｒ２は炭素数１〜２５の直鎖又は分岐鎖のアルキル基又はアルケニル基を示し、
ＡＯは、炭素数２以上４以下のアルキレンオキシ基を示し、
ｎは１〜５０の整数であって、
ｎが２以上の場合、ｎ個のＡＯ基は同一でも異なっていてもよい。）
で表される。
[(B) Ester compound]
The ester compound (B) in the present invention has the following general formula (1):
R 1 O- (AO) n- COR 2 (1)
(During the ceremony,
R 1 represents a benzyl group,
R 2 represents a linear or branched alkyl or alkenyl group having 1 to 25 carbon atoms.
AO represents an alkyleneoxy group having 2 or more and 4 or less carbon atoms.
n is an integer from 1 to 50
When n is 2 or more, the n AO groups may be the same or different. )
It is represented by.
一般式（１）のエステル化合物において、本発明の効果を発揮する観点から、Ｒ１はベンジル基である。Ｒ１がベンジル基であれば、成分（Ｂ）エステル化合物は相溶性が高く、低粘度であるため好ましい。 In the ester compound of the general formula (1), R 1 is a benzyl group from the viewpoint of exerting the effect of the present invention. When R 1 is a benzyl group, the component (B) ester compound is preferable because it has high compatibility and low viscosity.
本発明における（Ｂ）一般式（１）で表されるエステル化合物としては、ベンジルアルコールのプロピレンオキシド３モル付加体とミリスチン酸のエステル（ミリスチン酸ＰＰＧ−３ベンジルエーテル）、ベンジルアルコールのプロピレンオキシド３モル付加体と２−エチルヘキシル酸のエステル（エチルヘキサン酸ＰＰＧ−３ベンジルエーテル）が好ましい。これらの成分は一般的に毛髪化粧料中にエモリエント剤、滑沢剤、表面改質剤、褪色防止剤の目的で配合される。また、本発明においては、（Ｂ）一般式（１）で表されるエステル化合物は市販品を用いてもよい。本発明において用いることができる市販品としては、これらに限定されるものではないが、例えば、クロダモルＳＴＳやクロダモルＳＦＸ（いずれもクローダ社製）、等が挙げられ、クロダモルＳＴＳが好ましい。 Examples of the ester compound represented by (B) the general formula (1) in the present invention include a propylene oxide 3 mol adduct of benzyl alcohol, an ester of myristic acid (myristic acid PPG-3 benzyl ether), and a propylene oxide 3 of benzyl alcohol. Esters of the molar adduct and 2-ethylhexic acid (ethylhexanoic acid PPG-3 benzyl ether) are preferred. These ingredients are generally incorporated into hair cosmetics for the purpose of emollients, moisturizers, surface modifiers, and anti-fading agents. Further, in the present invention, a commercially available product may be used as the ester compound represented by (B) the general formula (1). Examples of commercially available products that can be used in the present invention include, but are not limited to, Kurodamol STS and Crodamol SFX (both manufactured by Croda), and Crodamol STS is preferable.
本発明の毛髪化粧料組成物における（Ｂ）一般式（１）のエステル化合物の含有量は、好ましくは３質量％〜２０質量％であり、より好ましくは５質量％〜１５質量％である。本発明の毛髪化粧料組成物における（Ｂ）一般式（１）のエステル化合物の含有量が３質量％以上であれば、上記成分（Ａ）のヌル付きやべたつきを軽減することができる。また、成分（Ｂ）の含有量が２０質量％以下であればダメージを受けた毛髪がパサつくことはない。したがって、この範囲内であれば、子供の細い毛髪でもべたつかせず、かつ、ふわっと軽い状態を実現することができる。 The content of the ester compound of the general formula (1) in the hair cosmetic composition of the present invention is preferably 3% by mass to 20% by mass, and more preferably 5% by mass to 15% by mass. When the content of the ester compound of the (B) general formula (1) in the hair cosmetic composition of the present invention is 3% by mass or more, it is possible to reduce the sliminess and stickiness of the above component (A). Further, if the content of the component (B) is 20% by mass or less, the damaged hair will not be dry. Therefore, within this range, it is possible to realize a fluffy and light state without making the child's fine hair sticky.
［（Ｃ）２０℃で液状のエステル油］
本発明の毛髪化粧料にて用いられる（Ｃ）２０℃で液状のエステル油は、脂肪酸とアルコールとのエステル体を主成分としたエステル油であって、一般的に化粧料中にはヘアコンディショニング剤、エモリエント剤、可溶化剤、加脂肪剤、感触改良剤、滑沢剤、表面改質剤、経皮吸収促進剤、酸化防止剤、紫外線吸収剤等の目的で配合される。本発明における（Ｃ）２０℃で液状のエステル油としては、これらに限定されるものではないが、例えば、ミリスチン酸イソプロピル、ミリスチン酸ブチル、パルミチン酸イソプロピル、ステアリン酸エチル、ステアリン酸ブチル、オレイン酸エチル、リノール酸エチル等の直鎖高級脂肪酸と低級アルコールとのエステル、カプリル酸セチル、ラウリン酸ヘキシル、ミリスチン酸デシル、ミリスチン酸ミリスチル、パルミチン酸セチル、ステアリン酸ステアリル、オレイン酸デシル、リシノレイン酸セチル、等の直鎖高級脂肪酸と直鎖高級アルコールとのエステル；ラウリン酸イソステアリル、ミリスチン酸イソトリデシル、ミリスチン酸イソセチル、ミリスチン酸イソステアリル、ミリスチン酸オクチルドデシル、パルミチン酸オクチル、パルミチン酸イソセチル、パルミチン酸イソステアリル、ステアリン酸イソセチル、ステアリン酸オクチルドデシル、オレイン酸イソデシル、オレイン酸オクチルドデシル等の直鎖脂肪酸と分枝アルコールとのエステル；イソステアリン酸エチル、イソステアリン酸イソプロピル等の分枝脂肪酸と低級アルコールとのエステル；オクタン酸セチル、オクタン酸セトステアリル、オクタン酸ステアリル、イソステアリン酸ヘキシル等の分枝脂肪酸と直鎖高級アルコールとのエステル；ジオクタン酸エチレングリコール、ジオレイン酸エチレングリコール、ジカプリル酸プロピレングリコール、ジカプリン酸プロピレングリコール、ジオレイン酸プロピレングリコール、ジカプリン酸ネオペンチルグリコール、テトラ２−エチルヘキサン酸ペンタエリトリット等の脂肪酸と多価アルコールとのエステル；ネオペンタン酸オクチルドデシル、オクタン酸イソセチル、オクタン酸イソステアリル、イソペラルゴン酸オクチル、ネオデカン酸オクチルドデシル、イソステアリン酸イソステアリル等の分枝脂肪酸と分枝アルコールとのエステル；乳酸ラウリル、乳酸ミリスチル、乳酸セチル等の乳酸エステル；クエン酸トリエチル、クエン酸トリオクチル、クエン酸トリイソセチル、リンゴ酸ジイソステアリル、コハク酸ジオクチル、セバシン酸ジエチル、セバシン酸ジオクチル等の二塩基酸のエステル；等が挙げられる。また、本発明においては、（Ｃ）２０℃で液状のエステル油は市販品を用いてもよい。本発明において用いることができる市販品としては、これらに限定されるものではないが、例えば、サラコス８１６Ｔ（日清オイリオグループ株式会社製）、ＣＥＨ（高級アルコール工業株式会社製）、サラコス９９（日清オイリオグループ株式会社製）、サラコスＰ−８（日清オイリオグループ株式会社製）、サラコス５４０８（日清オイリオグループ株式会社製）、ミリトール３１８（ＢＡＳＦジャパン株式会社製）、ユビナールＭＣ−８０（ＢＡＳＦジャパン株式会社製）、パラソルＭＣＸ−ＡＳ（ＤＳＭニュートリションジャパン株式会社製）等が挙げられる。このようなエステル油は、それぞれ単独で用いることもでき、また２種以上混合して用いることもできる。
[(C) Ester oil liquid at 20 ° C]
(C) The ester oil liquid at 20 ° C. used in the hair cosmetics of the present invention is an ester oil containing an ester of fatty acid and alcohol as a main component, and is generally used for hair conditioning in cosmetics. It is blended for the purpose of agents, emollients, solubilizers, fatty acids, tactile improvers, lubricants, surface modifiers, transdermal absorption promoters, antioxidants, ultraviolet absorbers and the like. The ester oil (C) liquid at 20 ° C. in the present invention is not limited to these, but is not limited to, for example, isopropyl myristate, butyl myristate, isopropyl palmitate, ethyl stearate, butyl stearate, and oleic acid. Esters of linear higher fatty acids such as ethyl, ethyl linoleate and lower alcohols, cetyl caprylate, hexyl laurate, decyl myristate, myristyl myristate, cetyl palmitate, stearyl stearate, decyl oleate, cetyl ricinoleate, Esters of linear higher fatty acids such as linear higher fatty acids and linear higher alcohols; isostearyl laurate, isotolideyl myristate, isosetyl myristate, isostearyl myristate, octyldodecyl myristate, octyl palmitate, isosetyl palmitate, isostearyl palmitate. , Esters of linear fatty acids such as isocetyl stearate, octyldodecyl stearate, isodecyl oleate, octyldodecyl oleate and branched alcohols; esters of branched fatty acids such as ethyl isostearate and isopropyl isostearate and lower alcohols; Esters of branched fatty acids such as cetyl octanoate, cetostearyl octanoate, stearyl octanoate, hexyl isostearate and linear higher alcohols; ethylene glycol dioctanoate, ethylene glycol dioleate, propylene glycol dicaprylate, propylene glycol dicaprate, Esters of fatty acids such as propylene glycol dioleate, neopentyl glycol dicaprate, pentaerythrit tetra2-ethylhexanoate and polyhydric alcohols; Esters of branched fatty acids such as octyldodecyl neodecanoate and isostearyl isostearate and branched alcohols; lactic acid esters such as lauryl lactate, myristyl lactate, and cetyl lactate; triethyl citrate, trioctyl citrate, triisocetyl citrate, diiocolate Examples thereof include esters of dibasic acids such as isostearyl, dioctyl succinate, diethyl sebacate, and dioctyl sebacate; and the like. Further, in the present invention, a commercially available product may be used as the ester oil (C) liquid at 20 ° C. The commercially available products that can be used in the present invention are not limited to these, and for example, Sarakos 816T (manufactured by Nisshin Oillio Group Co., Ltd.), CEH (manufactured by Higher Alcohol Industry Co., Ltd.), Sarakos 99 (Japan). Kiyo Oilio Group Co., Ltd., Sarakos P-8 (Nisshin Oilio Group Co., Ltd.), Sarakos 5408 (Nisshin Oilio Group Co., Ltd.), Militol 318 (BASF Japan Co., Ltd.), Ubinal MC-80 (BASF) Japan Co., Ltd.), Parasol MCX-AS (DSM Nutrition Japan Co., Ltd.) and the like. Such ester oils can be used alone or in combination of two or more.
本発明の毛髪化粧料組成物における（Ｃ）成分の配合量は、好ましくは１０質量％〜３０質量％であり、より好ましくは１５質量％〜２５質量％である。本発明の毛髪化粧料組成物における（Ｃ）２０℃で液状のエステル油の含有量が１０質量％以上であれば、毛髪へなめらかさ、しっとり感、ツヤやまとまり感といったトリートメント効果を毛髪へ付与
することができ、３０質量％以下であれば過度のべたつきが生じない。
The blending amount of the component (C) in the hair cosmetic composition of the present invention is preferably 10% by mass to 30% by mass, more preferably 15% by mass to 25% by mass. (C) When the content of the liquid ester oil at 20 ° C. in the hair cosmetic composition of the present invention is 10% by mass or more, the treatment effects such as smoothness, moistness, gloss and cohesiveness are imparted to the hair. If it is 30% by mass or less, excessive stickiness does not occur.
また、本発明の毛髪化粧料組成物において、上記成分（Ｂ）と上記成分（Ｃ）の合計含有量は、好ましくは１５質量％〜４０質量％であり、より好ましくは２０質量％〜３５質量％である。本発明の毛髪化粧料組成物における上記成分（Ｂ）と（Ｃ）の合計含有量がこの範囲内であれば、子供の細い頭髪でも塗布時に毛髪が重くなり過ぎることなく仕上げることができ、かつ、べたつきが少ない状態を実現することができる。 Further, in the hair cosmetic composition of the present invention, the total content of the above component (B) and the above component (C) is preferably 15% by mass to 40% by mass, more preferably 20% by mass to 35% by mass. %. When the total content of the above components (B) and (C) in the hair cosmetic composition of the present invention is within this range, even fine hair of a child can be finished without making the hair too heavy at the time of application. , It is possible to realize a state with less stickiness.
［（Ｄ）その他の成分］
本発明の毛髪化粧料組成物は、上記成分（Ａ）〜（Ｃ）を必須成分とし、溶剤などを加えた液にこれらを含有させることによって調製されるが、これらの必須成分以外にも本発明の効果を損なわない範囲において、通常毛髪化粧料に配合される（Ｄ）その他の成分を目的に応じて配合することができる。
[(D) Other ingredients]
The hair cosmetic composition of the present invention is prepared by containing the above components (A) to (C) as essential components and containing them in a liquid to which a solvent or the like is added. As long as the effect of the present invention is not impaired, (D) other ingredients usually blended in hair cosmetics can be blended according to the purpose.
上記のような他の成分としては、水、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、グリセリン脂肪酸エステル等の非イオン性界面活性剤；塩化ステアリルトリメチルアンモニウム、塩化アルキルトリメチルアンモニウム等のカチオン性界面活性剤；セタノール、ステアリルアルコール等の高級アルコール；グリセリン、プロピレングリコール、ブチレングリコール、ジプロピレングリコール、グリコシルトレハロース等の湿潤剤；ステアリン酸、ベヘニン酸、オレイン酸、イソステアリン酸、２−エチルヘキサン酸などの高級脂肪酸；流動イソパラフィン、ワセリン、スクワラン等の炭化水素；ジンクピリチオン、塩化ベンザルコニウム等の抗フケ成分；エタノール、メタノール、プロピルアルコール、イソプロピルアルコール等の低級アルコール；ｌ−メントール、ハッカ油等の冷感剤；アーモンド油、アボカド油、アマニ油、アルガニアスピノサ核油、アンズ核油、イチゴ種子油、エゴマ油、オリーブ油、オレンジ油、カニナバラ油、キョウニン油、クランベアビシニカ種子油 、グレープシード油、ゴマ種子油、コメヌカ油、サザンカ油、サフラワー油、シア脂、セイヨウハッカ油、ダイズ油、チャ実油、チャ種子油、ツバキ種子油、ナタネ油、ヒマワリ種子油、ブドウ種子油、ヘーゼルナッツ油、ホホバ油、モモ核油、ヤシ油、ユチャ油、レモン油、ローズヒップ油、ローズマリー油等の植物油；Ｌ−アスパラギン酸、Ｌ−アスパラギン酸ナトリウム、ＤＬ−アラニン、Ｌ−アルギニン、グリシン、Ｌ−グルタミン酸、Ｌ−システイン、Ｌスレオニン等のアミノ酸；グリチルレチン酸及び／又はその誘導体、グリチルリチン酸及び／又はその塩等の抗炎症剤；液化石油ガス、ジメチルエーテル等の噴射ガス；１２−ヒドロキシステアリン酸、ジベンジリデンソルビトール、アミノ酸誘導体等の低分子化合物、あるいはポリエチレン、ポリアクリル酸誘導体、デキストリン誘導体等のオイルゲル化剤；その他、紫外線吸収剤、防腐剤、糖類、植物由来エキス、動物由来エキス、香料、色剤、金属イオン封鎖剤、酸化防止剤、各種薬剤、等が挙げられる。 Other components as described above include nonionic surfactants such as water, polyoxyethylene alkyl ether, polyoxyethylene sorbitan fatty acid ester, glycerin fatty acid ester; and cationic such as stearyltrimethylammonium chloride and alkyltrimethylammonium chloride. Surface active agents; higher alcohols such as cetanol and stearyl alcohol; wetting agents such as glycerin, propylene glycol, butylene glycol, dipropylene glycol and glycosyl trehalose; stearic acid, behenic acid, oleic acid, isostearic acid, 2-ethylhexanoic acid and the like. Higher fatty acids of Sensitives; almond oil, avocado oil, flaxseed oil, Argania spinosa kernel oil, apricot kernel oil, strawberry seed oil, egoma oil, olive oil, orange oil, canina rose oil, kyonin oil, cranbear bicinica seed oil , grape seed oil , Sesame seed oil, rice bran oil, southern ka oil, safflower oil, shea butter, peppermint oil, soybean oil, cha seed oil, cha seed oil, camellia seed oil, rapeseed oil, sunflower seed oil, grape seed oil, hazelnut oil , Johova oil, peach kernel oil, palm oil, yucha oil, lemon oil, rose hip oil, rosemary oil and other vegetable oils; L-aspartic acid, sodium L-aspartate, DL-alanine, L-arginine, glycine, L -Amino acids such as glutamic acid, L-cysteine, L threonine; anti-inflammatory agents such as glycyrrhetinic acid and / or derivatives thereof, glycyrrhizinic acid and / or salts thereof; jet gas such as liquefied petroleum gas, dimethyl ether; 12-hydroxystearic acid, Divendilidene sorbitol, low molecular weight compounds such as amino acid derivatives, or oil gelling agents such as polyethylene, polyacrylic acid derivatives, dextrin derivatives; other UV absorbers, preservatives, sugars, plant-derived extracts, animal-derived extracts, fragrances, colors Examples thereof include agents, metal ion sequestering agents, antioxidants, various agents, and the like.
本発明の毛髪化粧料組成物は、ヘアローション、ヘアリキッド、ヘアミスト、ヘアウォーター、ヘアオイル等の液状毛髪化粧料、ヘアクリーム、ヘアトリートメント、ヘアミルク、ヘアジェル等の乳液・クリーム状毛髪化粧料、ヘアフォーム、ヘアスプレー等のエアゾール状毛髪化粧料等に用いることができ、特に好ましくはヘアオイル、ヘアオイルゲル、ヘアオイルミスト、ヘアスプレーなどのリーブオンタイプの毛髪化粧料に用いることができる。また本発明の毛髪化粧料組成物は、常法により製造することができる。 The hair cosmetic composition of the present invention includes liquid hair cosmetics such as hair lotion, hair liquid, hair mist, hair water, and hair oil, milky lotion / creamy hair cosmetics such as hair cream, hair treatment, hair milk, and hair gel, and hair foam. , Can be used for aerosol-like hair cosmetics such as hair sprays, and particularly preferably can be used for leave-on type hair cosmetics such as hair oils, hair oil gels, hair oil mists, and hair sprays. Further, the hair cosmetic composition of the present invention can be produced by a conventional method.
以下、実施例を挙げて本発明の実施の形態を更に具体的に説明する。ただし、本発明は、これらの実施例に何ら限定されるものではない。 Hereinafter, embodiments of the present invention will be described in more detail with reference to examples. However, the present invention is not limited to these examples.
［試料の調製］
以下の試料を下表１〜２に記載の成分・配合量で、常法により調製した。その他成分については、水添ポリイソブテン、水、ブチレングリコール（ＢＧ）及び香料等を適宜配合した。比較例７は成分（Ａ）の代わりにジメチコンを含む現行品のヘアオイルの比較例である。
[Sample preparation]
The following samples were prepared by a conventional method with the components and blending amounts shown in Tables 1 and 2 below. As for other components, hydrogenated polyisobutene, water, butylene glycol (BG), fragrance and the like were appropriately blended. Comparative Example 7 is a comparative example of the current hair oil containing dimethicone instead of the component (A).
［毛髪サンプルの調製］
本発明の毛髪化粧料組成物の有用性を評価するために、まず、次の方法で毛髪を処理した。市販の毛髪（１０ｇ、３０ｃｍ、ビューラックス社製）を濃度１０質量％のポリオキシエチレン（２Ｅ．Ｏ．）ラウリルエーテル硫酸ナトリウム水溶液２ｇでシャンプー洗浄し、お湯で充分に洗い流した後、タオルドライを行い、ドライヤーで毛髪を乾燥させた。次に、下表１〜２に示した実施例及び比較例の毛髪化粧料組成物をヘアオイルとして０．５ｇを均一に塗布し、自然乾燥させた後、なめらかさ、ツヤなど毛髪へのトリートメント効果を評価した。また、毛髪化粧料組成物を大人の頭髪及び、子供の頭髪に塗布した後の毛髪の状態を評価した。
[Preparation of hair sample]
In order to evaluate the usefulness of the hair cosmetic composition of the present invention, first, the hair was treated by the following method. Commercially available hair (10 g, 30 cm, manufactured by Bulux) was shampooed with 2 g of polyoxyethylene (2EO) lauryl ether sodium sulfate aqueous solution having a concentration of 10% by mass, thoroughly rinsed with hot water, and then towel-dried. And the hair was dried with a dryer. Next, 0.5 g of the hair cosmetic compositions of Examples and Comparative Examples shown in Tables 1 and 2 below were evenly applied as hair oil, and after being naturally dried, the treatment effect on hair such as smoothness and luster was achieved. Was evaluated. In addition, the condition of the hair after applying the hair cosmetic composition to the hair of an adult and the hair of a child was evaluated.
［毛髪サンプルの評価］
上記のように調製した毛髪サンプルを用いて、以下の指標について評価した。
[Evaluation of hair sample]
The following indicators were evaluated using the hair samples prepared as described above.
（１）なめらかさ
動摩擦係数を測定することにより毛髪のなめらかさを評価した。毛髪の動摩擦係数は、摩擦感テスター（ＫＥＳ−ＳＥ型、カトーテック株式会社製）を使用し、摩擦子としてシリコンシートを取り付け、荷重５０ｇ、移動スピード１ｍｍ／ｓｅｃの条件で動摩擦係数（ＭＩＵ値）の測定を行い、２０本の毛束の平均値を求めた。尚、動摩擦係数が低いほど、なめらかであることを示すものである。尚、評価基準は以下の通りである。
◎ ：極めて良好 ０．２未満
○ ：良好 ０．２以上０．３未満
△ ：やや悪い ０．３以上０．４未満
× ：悪い ０．４以上
(1) Smoothness The smoothness of hair was evaluated by measuring the coefficient of dynamic friction. For the dynamic friction coefficient of hair, use a friction feeling tester (KES-SE type, manufactured by Kato Tech Co., Ltd.), attach a silicon sheet as a friction element, and apply a dynamic friction coefficient (MIU value) under the conditions of a load of 50 g and a movement speed of 1 mm / sec. Was measured, and the average value of 20 hair bundles was obtained. The lower the coefficient of kinetic friction, the smoother it is. The evaluation criteria are as follows.
◎: Very good Less than 0.2 ○: Good 0.2 or more and less than 0.3 △: Slightly bad 0.3 or more and less than 0.4 ×: Bad 0.4 or more
（２）ツヤ
ＳＡＭＢＡ Ｈａｉｒ Ｓｙｓｔｅｍ（Ｂｏｓｓａ Ｎｏｖａ Ｖｉｓｉｏｎ社製）を使用し、２０本の毛束についてツヤ値（Ｌｕｓｔｅｒ Ｖａｌｕｅ）の測定を行い、平均値を求めた。尚、ツヤ値（Ｌｕｓｔｅｒ Ｖａｌｕｅ）が高いほどツヤがあることを示すものである。尚、評価基準は以下の通りである。
◎ ：極めて良好 ６０以上
○ ：良好 ５０以上６０未満
△ ：やや悪い ４０以上５０未満
× ：悪い ４０未満
(2) Using a glossy SAMBA Hair System (manufactured by Bossa Nova Vision), the gloss value (Luster Value) was measured for 20 hair bundles, and the average value was calculated. The higher the gloss value (Luster Value), the more glossy the product. The evaluation criteria are as follows.
◎: Extremely good 60 or more ○: Good 50 or more and less than 60 △: Slightly bad 40 or more and less than 50 ×: Bad Less than 40
（３）大人の毛髪の状態
２０名の訓練された専門パネラーにより大人の頭髪に毛髪化粧料組成物をつけた後の毛髪の状態を評価した。大人の毛髪の状態は２０名の評価結果の平均値で示した。尚、評価基準は以下の通りである。
１：塗布後の毛髪がバサバサしており乾燥している状態である。
２：塗布後の毛髪にややしっとり感は足りないがバサバサしておらず良好な状態である。３：塗布後の毛髪がしっとりしており理想の状態である。
４：塗布後の毛髪にややしっとり感は強いが重くなく良好な状態である。
５：塗布後の毛髪がべたつきすぎて重い状態である。
(3) Hair condition of adults The condition of hair after applying the hair cosmetic composition to the hair of adults was evaluated by 20 trained professional panelists. The hair condition of adults is shown by the average value of the evaluation results of 20 people. The evaluation criteria are as follows.
1: The hair after application is dry and dry.
2: The hair after application does not have a slightly moist feeling, but it is not dry and is in good condition. 3: The hair after application is moist and is in an ideal state.
4: The hair after application has a strong moist feeling, but it is not heavy and is in good condition.
5: The hair after application is too sticky and heavy.
（４）子供の毛髪の状態
２０名の訓練された専門パネラーにより１２歳以下の子供の頭髪に毛髪化粧料組成物をつけた後の毛髪の状態を評価した。子供の毛髪の状態は２０名の評価結果の平均値で示した。尚、評価基準は以下の通りである。
１：塗布後の毛髪がバサバサしており乾燥している状態である。
２：塗布後の毛髪にややしっとり感は足りないがバサバサしておらず良好な状態である。３：塗布後の毛髪がしっとりしており理想の状態である。
４：塗布後の毛髪にややしっとり感は強いが重くなく良好な状態である。
５：塗布後の毛髪がべたつきすぎて重い状態である。
(4) Hair condition of children The condition of hair after applying the hair cosmetic composition to the hair of children under 12 years old was evaluated by 20 trained professional panelists. The hair condition of the child was shown by the average value of the evaluation results of 20 people. The evaluation criteria are as follows.
1: The hair after application is dry and dry.
2: The hair after application does not have a slightly moist feeling, but it is not dry and is in good condition. 3: The hair after application is moist and is in an ideal state.
4: The hair after application has a strong moist feeling, but it is not heavy and is in good condition.
5: The hair after application is too sticky and heavy.
実施例１〜８及び比較例１〜７の配合及び評価結果を、下表１及び２に記載する。 The formulations and evaluation results of Examples 1 to 8 and Comparative Examples 1 to 7 are shown in Tables 1 and 2 below.
表１〜２から明らかなように、本発明の毛髪化粧料組成物に関する実施例１〜８は、比較例１〜７の組成物に比べていずれも優れた性能を示した。比較例７は、成分（Ａ）の代わりにジメチコンを含む市販品の例であるが、これらと比較してもなめらかさ、しっとり感、ツヤについては同等以上であり、子供の頭髪に塗布したのちの毛髪の状態は優れた結
果を示した。したがって、本発明の毛髪化粧料組成物は、ダメージを受けた毛髪へなめらかさ、しっとり感、ツヤといったトリートメント効果を付与しながら、子供の細い毛髪でも重さやべたつきが少ないという優れた性能を示すことが分かった。
As is clear from Tables 1 and 2, Examples 1 to 8 relating to the hair cosmetic composition of the present invention all showed excellent performance as compared with the compositions of Comparative Examples 1 to 7. Comparative Example 7 is an example of a commercially available product containing dimethicone instead of the component (A), but the smoothness, moist feeling, and gloss are equal to or higher than those of the commercial product, and it was applied to the hair of a child. The condition of the hair showed excellent results. Therefore, the hair cosmetic composition of the present invention exhibits excellent performance of less weight and stickiness even for fine hair of children, while imparting treatment effects such as smoothness, moist feeling, and gloss to damaged hair. I found out.
以下、本発明の毛髪化粧料組成物の処方例を挙げる。なお、これらの処方例の毛髪化粧料組成物についても、上記のなめらかさ、しっとり感、ツヤなど毛髪へのトリートメント効果、官能試験（大人の頭髪に塗布した後の毛髪の状態、子供の頭髪に塗布した後の毛髪の状態）について各項目を検討したところ、いずれの処方例においても、優れた特性を有しており良好であった。 Hereinafter, examples of prescribing the hair cosmetic composition of the present invention will be given. The hair cosmetic compositions of these prescription examples also have the above-mentioned smoothness, moist feeling, treatment effect on hair such as gloss, sensory test (condition of hair after application to adult hair, and hair of children). When each item was examined for the condition of the hair after application), all the prescription examples had excellent characteristics and were good.
処方例１（ヘアオイル） （％）
（１）トリイソステアリン酸ＰＥＧ−２０グリセリル １０．０
（２）ミリスチン酸ＰＰＧ−３ベンジルエーテル １０．０
（３）パルミチン酸エチルヘキシル ２０．０
（４）メトキシケイヒ酸エチルヘキシル １．０
（５）水添ポリイソブテン ５５．０
（６）ＢＧ １．０
（７）シア脂 ０．５
（８）ラクトフェリン ０．５
（９）ヨーグルト液 ０．５
（１０）グリチルリチン酸２Ｋ ０．１
（１１）香料 ０．３
（１２）水 残 余
Prescription example 1 (hair oil) (%)
(1) PEG-20 glyceryl triisostearate 10.0
(2) Myristic acid PPG-3 benzyl ether 10.0
(3) Ethylhexyl palmitate 20.0
(4) Ethylhexyl methoxycinnamate 1.0
(5) Hydrogenated polyisobutene 55.0
(6) BG 1.0
(7) Shea butter 0.5
(8) Lactoferrin 0.5
(9) Yogurt liquid 0.5
(10) Glycyrrhizinate 2K 0.1
(11) Fragrance 0.3
(12) Water residue
（製法）（５）に（２）、（３）、（４）、（７）及び（１１）を均一に分散し、別槽にて調製した（１）、（６）、（８）、（９）、（１０）及び（１２）を均一混合溶解したものを加えて均一に混合し、ディスペンサーポンプつき容器に充填してヘアオイルを調製した。 (Manufacturing method) (1), (6), (8), prepared in a separate tank by uniformly dispersing (2), (3), (4), (7) and (11) in (5). (9), (10) and (12) were uniformly mixed and dissolved, and the mixture was uniformly mixed and filled in a container with a dispenser pump to prepare hair oil.
処方例２（ヘアオイルゲル） （％）
（１）トリイソステアリン酸ＰＥＧ−２０グリセリル １２．０
（２）ミリスチン酸ＰＰＧ−３ベンジルエーテル １２．０
（３）エチルヘキサン酸セチル ２０．０
（４）トリ（カプリル酸／カプリン酸）グリセリル ５．０
（５）テトラエチルヘキサン酸ペンタエリスリチル １．０
（６）イソドデカン ３５．０
（７）パルミチン酸デキストリン ７．０
（８）ＢＧ ６．０
（９）シア脂 ０．５
（１０）ラクトフェリン ０．５
（１１）ヨーグルト液 ０．５
（１２）グリチルリチン酸２Ｋ ０．１
（１３）香料 ０．３
（１４）水 残 余
Prescription example 2 (hair oil gel) (%)
(1) PEG-20 glyceryl triisostearate 12.0
(2) Myristic acid PPG-3 benzyl ether 12.0
(3) Cetyl ethylhexanoate 20.0
(4) Tri (caprylic acid / capric acid) glyceryl 5.0
(5) Pentaerythrityl tetraethylhexanoate 1.0
(6) Isododecan 35.0
(7) Dextrin palmitate 7.0
(8) BG 6.0
(9) Shea butter 0.5
(10) Lactoferrin 0.5
(11) Yogurt liquid 0.5
(12) Glycyrrhizinate 2K 0.1
(13) Fragrance 0.3
(14) Water residue
（製法）（３）に（２）、（４）及び（５）を均一に分散し、加温した後（７）を加えて均一混合溶解した後、（６）、（９）及び（１３）を加えて均一混合した。（１）、（８）、（１０）、（１１）、（１２）及び（１４）を別槽にて均一に分散し、上記加温させたとものに混合、冷却し、ディスペンサーポンプつき容器に充填してヘアオイルゲルを調製した。
(Manufacturing method) (2), (4) and (5) are uniformly dispersed in (3), heated, and then (7) is added to uniformly mix and dissolve, and then (6), (9) and (13). ) Was added and uniformly mixed. (1), (8), (10), (11), (12) and (14) are uniformly dispersed in a separate tank, mixed and cooled in the heated state, and placed in a container with a dispenser pump. Filled to prepare a hair oil gel.
Claims (1)
（Ｂ）下記一般式（１）で表されるエステル化合物
Ｒ１Ｏ−（ＡＯ）ｎ−ＣＯＲ２ （１）
（式中、
Ｒ１はベンジル基を示し、
Ｒ２は炭素数１〜２５の直鎖又は分岐鎖のアルキル基又はアルケニル基を示し、
ＡＯは炭素数２以上４以下のアルキレンオキシ基を示し、
ｎは１〜５０の整数であって、
ｎが２以上の場合、ｎ個のＡＯ基は同一でも異なっていてもよい。）、及び
（Ｃ）前記成分（Ｂ）と異なる２０℃で液状のエステル油１種以上を含むことを特徴とする毛髪化粧料組成物。
(A) PEG-20 glyceryl triisostearate (B) Ester compound represented by the following general formula (1) R 1 O- (AO) n- COR 2 (1)
(During the ceremony,
R 1 represents a benzyl group,
R 2 represents a linear or branched alkyl or alkenyl group having 1 to 25 carbon atoms.
AO represents an alkyleneoxy group having 2 or more and 4 or less carbon atoms.
n is an integer from 1 to 50
When n is 2 or more, the n AO groups may be the same or different. ), And (C) a hair cosmetic composition comprising one or more kinds of ester oils that are liquid at 20 ° C. different from the component (B).
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2020
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