JP2020535284A - 洗剤パック - Google Patents
洗剤パック Download PDFInfo
- Publication number
- JP2020535284A JP2020535284A JP2020517862A JP2020517862A JP2020535284A JP 2020535284 A JP2020535284 A JP 2020535284A JP 2020517862 A JP2020517862 A JP 2020517862A JP 2020517862 A JP2020517862 A JP 2020517862A JP 2020535284 A JP2020535284 A JP 2020535284A
- Authority
- JP
- Japan
- Prior art keywords
- detergent
- activity
- water
- gram
- gram activity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 116
- 239000000203 mixture Substances 0.000 claims abstract description 80
- 230000000694 effects Effects 0.000 claims abstract description 48
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000004806 packaging method and process Methods 0.000 claims abstract description 26
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- 239000008139 complexing agent Substances 0.000 claims abstract description 14
- 229920000642 polymer Polymers 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 28
- 239000002736 nonionic surfactant Substances 0.000 claims description 19
- 239000007844 bleaching agent Substances 0.000 claims description 13
- 229920005646 polycarboxylate Polymers 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 229920006254 polymer film Polymers 0.000 claims description 9
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 7
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 7
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 6
- 238000004851 dishwashing Methods 0.000 claims description 6
- -1 polyethylene terephthalate Polymers 0.000 claims description 5
- 229920000134 Metallised film Polymers 0.000 claims description 4
- 239000003205 fragrance Substances 0.000 claims description 4
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 3
- 239000011140 metalized polyester Substances 0.000 claims description 3
- 229920006267 polyester film Polymers 0.000 claims description 3
- 229940045872 sodium percarbonate Drugs 0.000 claims description 3
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 35
- 239000010408 film Substances 0.000 description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 229920002125 Sokalan® Polymers 0.000 description 13
- 239000002245 particle Substances 0.000 description 13
- 238000004061 bleaching Methods 0.000 description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 10
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- 239000000178 monomer Substances 0.000 description 9
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- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 7
- 239000001913 cellulose Substances 0.000 description 7
- 235000010980 cellulose Nutrition 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
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- 229920000092 linear low density polyethylene Polymers 0.000 description 6
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- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
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- 230000000052 comparative effect Effects 0.000 description 5
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
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- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 229920000058 polyacrylate Polymers 0.000 description 4
- 229920002799 BoPET Polymers 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
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- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 125000000542 sulfonic acid group Chemical group 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical class OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
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- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
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- 239000011148 porous material Substances 0.000 description 2
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- 150000003384 small molecules Chemical class 0.000 description 2
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- 239000002904 solvent Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- DZSVIVLGBJKQAP-UHFFFAOYSA-N 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one Chemical compound CCC(=O)C1CC(C(C)C)CC=C1C DZSVIVLGBJKQAP-UHFFFAOYSA-N 0.000 description 1
- PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 description 1
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical class C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
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- 150000003138 primary alcohols Chemical class 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical group 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/09—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/40—Applications of laminates for particular packaging purposes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0068—Deodorant compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3711—Polyacetal carboxylates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Accessory Of Washing/Drying Machine, Commercial Washing/Drying Machine, Other Washing/Drying Machine (AREA)
- Wrappers (AREA)
Abstract
Description
洗剤パックは、3〜60個の水溶性単位用量洗剤製品を収容する包装容器を含む。包装容器は、3〜60個の水溶性単位用量洗剤製品を少なくとも部分的に包み込む金属層を含む。包装容器は、タブ、トレー、ジャー、ボトル、バッグ、ボックスなどであり得る。好ましくは、包装容器は再閉鎖可能である。好ましくは、包装容器はバッグ、好ましくは可撓性バッグ、より好ましくは可撓性再閉鎖可能バッグ、更により好ましくは自立型再閉鎖可能可撓性バッグである。「可撓性」バッグとは、手で絞ることにより容易に変形し得る、好ましくは単にバッグを握る動作によって変形し得るバッグを意味する。
水溶性単位用量洗剤製品について説明する。「単位用量」とは、洗剤組成物が、洗浄1回を行うのに十分な洗剤組成物を提供するのに十分な形態で提供されることを意味する。好適な単位用量製品としては、サッシェ、カプセル、パウチ、モールドなどが挙げられる。洗剤製品は、8グラム〜25グラム、好ましくは12グラム〜20グラム、より好ましくは13グラム〜19グラムの重量である。この重量範囲は、自動食器洗浄機用洗剤組成物ディスペンサ内に収まる。
本発明の洗剤組成物は単位容量の形態を採り、固体、液体、及びゲル形態を含む任意の物理的形態であり得る。本洗剤組成物は、2.5グラム活性を超える悪臭発生アミノカルボン酸錯化剤を含む。好ましくは、洗剤組成物は、少なくとも2.7グラム活性、好ましくは少なくとも3グラム活性、より好ましくは少なくとも3.2グラム活性、更により好ましくは少なくとも3.5グラム活性、なお更により好ましくは少なくとも3.7グラム活性、あるいは、2.7〜9グラム活性、又は3〜7グラム活性を含む。好ましくは、アミノカルボン酸錯化剤は、メチルグリシン二酢酸、その塩及びその誘導体、グルタミン酸−N,N−二酢酸、その塩及びその誘導体、並びにこれらの混合物からなる群から選択され、好ましくは、アミノカルボン酸はメチルグリシン二酢酸の塩である。理論に束縛されるものではないが、より多量の悪臭発生アミノカルボン酸錯化剤がアンモニア発生に寄与する。
Claims (15)
- 洗剤パックであって、3〜60個の水溶性単位用量洗剤製品を収容する包装容器を含み、
前記包装容器は、前記水溶性単位用量洗剤製品を少なくとも部分的に包み込む金属層を含み、
前記水溶性単位用量洗剤製品のそれぞれは、洗剤組成物と、前記洗剤組成物を被覆する外装材と、を含み、
前記洗剤組成物は、2.5グラム活性を超える悪臭発生アミノカルボン酸錯化剤を含む、洗剤パック。 - 前記金属層が、真空金属化ポリマーフィルムの真空金属化層であり、好ましくは、前記包装容器はバッグ、好ましくは可撓性バッグ、より好ましくは再閉鎖可能な可撓性バッグである、請求項1に記載の洗剤パック。
- 前記真空金属化ポリマーフィルムが、真空金属化ポリエステルフィルムであり、好ましくは真空金属化ポリエチレンテレフタレートフィルム層であり、より好ましくは真空アルミニウム化ポリエチレンテレフタレートフィルム層であり、
好ましくは、前記真空金属化ポリマーフィルムは多層フィルム型フィルム積層体のフィルム層であり、より好ましくは、前記真空金属化ポリマーフィルムは3層フィルム積層体の中央フィルム層であり、
より好ましくは、前記3層フィルム積層体の厚さは、70マイクロメートル〜130マイクロメートル、好ましくは80マイクロメートル〜120マイクロメートル、より好ましくは90マイクロメートル〜110マイクロメートルである、請求項2に記載の洗剤パック。 - 前記金属層が、前記単位容量洗剤製品を収容する前記容器の内側表面の少なくとも25%、好ましくは少なくとも50%、より好ましくは少なくとも75%、更により好ましくは少なくとも90%を包み込む、請求項1〜3のいずれか一項に記載の洗剤パック。
- 前記アミノカルボン酸錯化剤が、メチルグリシン二酢酸、その塩及びその誘導体、グルタミン酸−N,N−二酢酸、その塩及びその誘導体、並びにこれらの混合物からなる群から選択され、好ましくは、前記アミノカルボン酸はメチルグリシン二酢酸の塩である、請求項1〜4のいずれか一項に記載の洗剤パック。
- 前記アミノカルボン酸錯化剤が、少なくとも2.7グラム活性、好ましくは少なくとも3グラム活性、より好ましくは少なくとも3.2グラム活性、更により好ましくは少なくとも3.5グラム活性、なお更により好ましくは少なくとも3.7グラム活性を含む、請求項1〜5のいずれか一項に記載の洗剤パック。
- 前記洗剤組成物が、スルホン化ポリカルボキシレートポリマー、好ましくは0.1グラム活性〜1.1グラム活性、より好ましくは0.2グラム活性〜0.6グラム活性の前記スルホン化ポリカルボキシレートポリマーを更に含む、請求項1〜6のいずれか一項に記載の洗剤パック。
- 前記洗剤組成物が、0.4グラム活性未満、好ましくは0.3グラム活性未満、より好ましくは0.2グラム活性未満のクエン酸を含む、請求項1〜7のいずれか一項に記載の洗剤パック。
- 前記洗剤組成物が漂白剤を更に含み、好ましくは、前記漂白剤は過炭酸塩を含み、より好ましくは、前記洗剤組成物は、1グラム活性〜5グラム活性、好ましくは1.5グラム活性〜4グラム活性、より好ましくは1.7グラム活性〜3グラム活性の過炭酸ナトリウムを更に含む、請求項1〜8のいずれか一項に記載の洗剤パック。
- 前記容器が、10〜40個、好ましくは15〜35個の前記水溶性単位用量洗剤製品を収容し、より好ましくは、前記水溶性単位用量洗剤製品は、水溶性単位用量自動食器洗浄洗剤製品である、請求項1〜9のいずれか一項に記載の洗剤パック。
- 前記外装材が、水溶性フィルム又は水溶性射出成形モールドであり、好ましくは前記水溶性フィルムである、請求項1〜10のいずれか一項に記載の洗剤パック。
- 32℃及び相対湿度80%の状態で8週間に発生したアンモニアが百万分の100部未満、好ましくは70部未満、より好ましくは50部未満、更により好ましくは30部未満、なお更により好ましくは10部未満である、請求項1〜11のいずれか一項に記載の洗剤パック。
- 前記洗剤組成物が、非イオン性界面活性剤及び香料を更に含み、好ましくは、前記洗剤組成物は、0.5グラム活性〜3グラム活性、好ましくは0.7グラム活性〜2グラム活性の前記非イオン性界面活性剤を含む、請求項1〜12のいずれか一項に記載の洗剤パック。
- a)それぞれの水溶性単位用量洗剤製品の質量が、12グラム〜20グラム、好ましくは13グラム〜19グラムであり、
b)前記洗剤組成物が、1重量パーセントで9〜12、好ましくは9.5〜11、より好ましくは10〜11のpHを有する、請求項1〜13の記載の洗剤パック。 - 前記容器内に収容された5〜60個の水溶性単位用量自動食器洗浄洗剤製品から生成された、前記容器のヘッドスペース内での、アンモニアを低減するための真空金属化包装容器の使用であって、前記水溶性単位用量洗剤製品のそれぞれは、漂白剤と、少なくとも2.6グラム活性のアミノカルボン酸錯化剤と、を含む、洗剤組成物を含む、使用。
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US201762576671P | 2017-10-25 | 2017-10-25 | |
US62/576,671 | 2017-10-25 | ||
PCT/US2018/056176 WO2019083782A1 (en) | 2017-10-25 | 2018-10-17 | DETERGENT PACKAGE |
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JP2020535284A5 JP2020535284A5 (ja) | 2021-12-02 |
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EP (1) | EP3701006A1 (ja) |
JP (1) | JP7264886B2 (ja) |
CN (1) | CN111278963A (ja) |
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DE102020212091A1 (de) * | 2020-09-25 | 2022-03-31 | Henkel Ag & Co. Kgaa | Konzentrierte fließfähige Waschmittelzubereitung mit verbesserten Eigenschaften |
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EP0199228A2 (de) * | 1985-04-23 | 1986-10-29 | Hoechst Aktiengesellschaft | Metallisierte Verbundfolie aus zwei mit Klebstoff verbundenen Kunststoffilmen |
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GB0128946D0 (en) * | 2001-12-03 | 2002-01-23 | Unilever Plc | Package for a water-soluble capsule |
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US20120067373A1 (en) * | 2010-04-15 | 2012-03-22 | Philip Frank Souter | Automatic Dishwashing Detergent Composition |
US20120070106A1 (en) * | 2010-09-20 | 2012-03-22 | Gustavo Jose Camargo-Parodi | Flexible bag containing unit dose articles |
US20120070107A1 (en) * | 2010-09-20 | 2012-03-22 | Gustavo Jose Camargo-Parodi | Unit dose articles and package therefor |
WO2016100499A1 (en) * | 2014-12-16 | 2016-06-23 | The Procter & Gamble Company | Coated microcapsules |
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EP3233266B1 (en) * | 2014-12-16 | 2020-05-06 | Noxell Corporation | Coated microcapsules |
BR112017012363B1 (pt) * | 2014-12-16 | 2021-01-19 | Noxell Corporation | microcápsulas revestidas, seu uso e produto de consumo que as compreende |
EP3124586A1 (en) * | 2015-07-29 | 2017-02-01 | The Procter and Gamble Company | Process for reducing malodour in a pack |
-
2018
- 2018-10-17 WO PCT/US2018/056176 patent/WO2019083782A1/en unknown
- 2018-10-17 EP EP18797383.9A patent/EP3701006A1/en active Pending
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- 2018-10-17 CA CA3076818A patent/CA3076818A1/en not_active Abandoned
- 2018-10-17 CN CN201880069920.5A patent/CN111278963A/zh active Pending
- 2018-10-23 US US16/167,566 patent/US20190119612A1/en not_active Abandoned
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US3442686A (en) * | 1964-03-13 | 1969-05-06 | Du Pont | Low permeability transparent packaging films |
JPS50149657U (ja) * | 1974-05-31 | 1975-12-12 | ||
EP0199228A2 (de) * | 1985-04-23 | 1986-10-29 | Hoechst Aktiengesellschaft | Metallisierte Verbundfolie aus zwei mit Klebstoff verbundenen Kunststoffilmen |
JPH05140595A (ja) * | 1991-09-25 | 1993-06-08 | O Ii M Network:Kk | 石 鹸 |
WO2016126581A1 (en) * | 2015-02-02 | 2016-08-11 | The Procter & Gamble Company | Detergent pack |
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EP3701006A1 (en) | 2020-09-02 |
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