JP2020528099A - 水性コーティング組成物 - Google Patents
水性コーティング組成物 Download PDFInfo
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- JP2020528099A JP2020528099A JP2020503706A JP2020503706A JP2020528099A JP 2020528099 A JP2020528099 A JP 2020528099A JP 2020503706 A JP2020503706 A JP 2020503706A JP 2020503706 A JP2020503706 A JP 2020503706A JP 2020528099 A JP2020528099 A JP 2020528099A
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- aqueous
- aqueous coating
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- 239000008199 coating composition Substances 0.000 title claims abstract description 77
- 239000000178 monomer Substances 0.000 claims abstract description 79
- 229920000642 polymer Polymers 0.000 claims abstract description 60
- 239000000758 substrate Substances 0.000 claims abstract description 29
- IWLXWEWGQZEKGZ-UHFFFAOYSA-N azane;zinc Chemical compound N.[Zn] IWLXWEWGQZEKGZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 150000004756 silanes Chemical class 0.000 claims abstract description 17
- 239000004815 dispersion polymer Substances 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims abstract description 15
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000007864 aqueous solution Substances 0.000 claims abstract description 13
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 12
- 238000000576 coating method Methods 0.000 claims description 46
- 239000011248 coating agent Substances 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 22
- 150000003839 salts Chemical class 0.000 claims description 20
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 11
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- 239000011787 zinc oxide Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 3
- 150000003751 zinc Chemical class 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims 1
- SXGBQDIIBBUDKN-UHFFFAOYSA-N acetic acid;azane;zinc Chemical compound [NH4+].[Zn].CC([O-])=O SXGBQDIIBBUDKN-UHFFFAOYSA-N 0.000 claims 1
- LRMILOBPOZGOSH-UHFFFAOYSA-N diazanium;carboxylato carbonate Chemical group [NH4+].[NH4+].[O-]C(=O)OC([O-])=O LRMILOBPOZGOSH-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000010586 diagram Methods 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 33
- 239000010408 film Substances 0.000 description 23
- -1 hydroxyalkyl acrylate Chemical compound 0.000 description 20
- 239000000839 emulsion Substances 0.000 description 17
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- 239000003973 paint Substances 0.000 description 15
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 14
- 239000004094 surface-active agent Substances 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 11
- 238000006116 polymerization reaction Methods 0.000 description 10
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- 239000002518 antifoaming agent Substances 0.000 description 8
- 229910000077 silane Inorganic materials 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000009477 glass transition Effects 0.000 description 6
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 4
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 4
- 239000001099 ammonium carbonate Substances 0.000 description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 4
- 239000004568 cement Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 230000008961 swelling Effects 0.000 description 4
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000013500 performance material Substances 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000006254 rheological additive Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- DETXZQGDWUJKMO-UHFFFAOYSA-N 2-hydroxymethanesulfonic acid Chemical compound OCS(O)(=O)=O DETXZQGDWUJKMO-UHFFFAOYSA-N 0.000 description 2
- COCLLEMEIJQBAG-UHFFFAOYSA-N 8-methylnonyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C(C)=C COCLLEMEIJQBAG-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 150000001253 acrylic acids Chemical class 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
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- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
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- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 description 2
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 2
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- 125000000524 functional group Chemical group 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
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- 230000002209 hydrophobic effect Effects 0.000 description 2
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- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 2
- 229940026239 isoascorbic acid Drugs 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
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- 229920002635 polyurethane Polymers 0.000 description 2
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- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
- XFTALRAZSCGSKN-UHFFFAOYSA-M sodium;4-ethenylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=C(C=C)C=C1 XFTALRAZSCGSKN-UHFFFAOYSA-M 0.000 description 2
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
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- 150000003871 sulfonates Chemical class 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N -2,3-Dihydroxypropanoic acid Natural products OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 1
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 description 1
- DDHUNHGZUHZNKB-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diamine Chemical compound NCC(C)(C)CN DDHUNHGZUHZNKB-UHFFFAOYSA-N 0.000 description 1
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 description 1
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 1
- BPGIOCZAQDIBPI-UHFFFAOYSA-N 2-ethoxyethanamine Chemical compound CCOCCN BPGIOCZAQDIBPI-UHFFFAOYSA-N 0.000 description 1
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 1
- IBZKBSXREAQDTO-UHFFFAOYSA-N 2-methoxy-n-(2-methoxyethyl)ethanamine Chemical compound COCCNCCOC IBZKBSXREAQDTO-UHFFFAOYSA-N 0.000 description 1
- GASMGDMKGYYAHY-UHFFFAOYSA-N 2-methylidenehexanamide Chemical compound CCCCC(=C)C(N)=O GASMGDMKGYYAHY-UHFFFAOYSA-N 0.000 description 1
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- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
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- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
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- CUHLTWOGTOCQBK-UHFFFAOYSA-L zinc;azane;carbonate Chemical compound N.[Zn+2].[O-]C([O-])=O CUHLTWOGTOCQBK-UHFFFAOYSA-L 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
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Abstract
Description
(a)ポリマーを含む水性ポリマー分散液であって、ポリマーが、ポリマーの重量に基づいて、
2重量%〜8重量%のα、β−エチレン性不飽和カルボン酸モノマーの構造単位、および
0.05重量%〜1.8重量%のエチレン性不飽和シラン官能性モノマーの構造単位を含む、水性ポリマー分散液と、
(b)亜鉛イオンを含む亜鉛アンモニア錯塩の水溶液と、
(c)水性コーティング組成物の総重量に基づいて、60重量%〜90重量%の充填剤と、を含み、
ポリマーに対する亜鉛イオンの重量比が、0.7%〜6%の範囲である、水性コーティング組成物である。
(a)ポリマーを含む水性ポリマー分散液であって、ポリマーが、ポリマーの重量に基づいて、
2重量%〜8重量%のα、β−エチレン性不飽和カルボン酸モノマーの構造単位、および
0.05重量%〜1.8重量%のエチレン性不飽和シラン官能性モノマーの構造単位を含む、水性ポリマー分散液と、
(b)亜鉛イオンを含む亜鉛アンモニア錯塩の水溶液と、
(c)水性コーティング組成物の総重量に基づいて、60重量%〜90重量%の充填剤と、を混合することを含み、
ポリマーに対する亜鉛イオンの重量比は、0.7%〜6%の範囲である。
第1の態様の水性コーティング組成物を提供することと、
水性コーティング組成物を、基材に塗布することと、
塗布された水性コーティング組成物を70℃以上で乾燥させて、厚さ2mm以上のコーティングを形成することと、を含む。
ここで、点線は、構造単位のポリマー骨格への結合点を表す。
式中、R1は、置換または非置換のエチレン性不飽和ヒドロカルビル基から選択される官能基を表しており、R2は、メチル、エチル、プロピル、イソプロピル、ブチルおよびtert−ブチルから独立して選択され、nは1〜3の整数である。好適なエチレン性不飽和シラン官能性モノマーの例には、アルキルビニルジアルコキシシラン、(メタ)アクリルオキシエチルトリメトキシシラン、およびガンマ−メタクリロキシプロピルトリメトキシシランおよびメタクリルオキシプロピルトリエトキシシランなどの(メタ)アクリルオキシプロピルトリメトキシシランを含む、(メタ)アクリルオキシアルキルトリアルコキシシラン、ビニルトリエトキシシランおよびビニルトリメトキシシランなどのビニルトリアルコキシシラン、その誘導体、またはそれらの組み合わせが含まれる。市販のエチレン性不飽和シラン官能性モノマーには、すべてMomentive Performance Materialsから入手可能である、SILQUEST A−174、A−171、A−151、A−2171、およびA−172E、およびCoatosil−1706、Coatosil−1757、ならびにY−11878シラン、またはそれらの混合物が含まれる。ポリマーは、ポリマーの重量に基づいて、0.05重量%以上、0.1重量%以上、0.15重量%以上、0.2重量%以上、またはさらに0.25重量%以上であると同時に、1.8重量%以下、1.5重量%以下、1.2重量%以下、またはさらに1.0重量%以下のエチレン性不飽和シラン官能性モノマーの構造単位を含み得る。
0.1重量%〜1重量%のエチレン性不飽和シラン官能性モノマーの構造単位、
2重量%〜4重量%のα、β−エチレン性不飽和カルボン酸モノマーの構造単位、
90重量%〜95重量%の、(メタ)アクリル酸のアルキルエステルなどのエチレン性不飽和非イオン性モノマーの構造単位、および
0〜5重量%の追加のエチレン性不飽和官能性モノマーの構造単位を含む。
水性コーティング組成物を提供することと、
水性コーティング組成物を基材に塗布することと、
塗布されたコーティング組成物を70℃以上で乾燥させて、2mm以上または3mm以上、好ましくは2〜5mmの厚さのコーティングを形成することと、を含む。
塗料配合物を、3mmの湿潤フィルム厚さで基材(セルロース繊維セメントシート、オートクレーブ)に塗布した。次いで、コーティングされた基材を80℃のオーブンで1時間、得られた塗膜が完全に硬化するまで乾燥させた。これは、水分計で測定した塗膜の水分含有量が5%未満であることによって示される。得られた乾燥塗膜を、引張試験機(Haftprufsystem HP1000、結合強度試験システム)を使用して、室温でISO 4624に従ってプルオフ強度について評価した。0.2MPa以上のプルオフ強度を有する塗膜は、塗膜が基材に良好に接着していることを示している。他の点では、プルオフ強度が0.2MPa未満の場合、塗膜の基材への密着性は貧弱である。
0.5グラム(g)のサンプル(0.0001g単位)を計量し、消化容器に加えた。5mlの濃硝酸を加えた。次いで、すべての残留物が溶解するまで、容器をホットプレート上でゆっくりと加熱した。得られた溶液を脱イオン(DI)水で50mLに希釈した。1mLの溶液を取り出し、さらにDI水で100mLに希釈し、誘導結合プラズマ(ICP)分光計で測定した。
塗料配合物を、3mmの湿潤フィルム厚さで基材(セルロース繊維セメントシート、オートクレーブ)に塗布した。その際、次いで、コーティングされた基材を80℃のオーブンで1時間、得られた塗膜が完全に硬化するまで乾燥させた。これは、水分計で測定した塗膜の水分含有量が5%未満であることによって示される。得られた乾燥塗膜を、室温で蒸留水に半分浸漬した。水に浸した塗膜の表面を最大7日間常に監視し、目視で観察した。塗膜の表面が7日後に白化、膨れ、ひび割れ、または基材からの剥離を示さない場合、塗膜の耐水性が良好であることを示している。浸漬部分と非浸漬部分との間の表面のわずかな色の変化は許容される。
塗料配合物のポットライフを、そのような塗料配合物の基材へのプルオフ強度の変化に基づいて、室温で一定期間保管する前後に評価した。
120gの重炭酸アンモニウム(NH4HCO3)を、ビーカーに610gの水および190gのアンモニア(NH3H2O濃度:25〜28%)とともに加えた。80gの酸化亜鉛(ZnO)を、上記の得られた溶液に加えた。得られた混合物を、酸化亜鉛が溶解するまで約20分間連続的に攪拌しながら混合し、こうして亜鉛アンモニア錯体溶液を形成した。
538gのDI水、17gのPOLYSTEP P−12A(25%活性)、770gのEHA、615gのMMA、36gのMAA、および4.25gのA−174シランを混合して、モノマーエマルジョンを調製した。
結合剤2の調製に使用したモノマーエマルジョンが538gのDI水、17gのP−12A(25%活性)、764.7gのEHA、628gのMMA、25.9gのMAA、および4.25gのA−174シランを混合することにより調製されたことを除いて、バインダー2は、上記のバインダー1を調製した手順と同じ手順に従って調製された。
結合剤3の調製に使用したモノマーエマルジョンが538gのDI水、17gのP−12A(25%活性)、790gのEHA、542gのMMA、86.4gのMAA、および4.25gのA−174シランを混合することにより調製されたことを除いて、バインダー3は、上記のバインダー1を調製した手順と同じ手順に従って調製された。
結合剤4は、モノマーエマルジョンおよび反応器に直接充填されるP−12A界面活性剤の投与量が異なることを除いて、上記の結合剤1を調製した手順と同じ手順に従って調製された。結合剤4の調製に使用されるモノマーエマルジョンは、538gのDI水、17gのP−12A(25%活性)、768.8gのEHA、621gのMMA、28.8gのMAA、および4.25gのA−174シランを混合することにより調製された。5.67gのP−12A(25%活性)を、ケトル石鹸として反応器に直接的に充填した。
結合剤5の調製に使用したモノマーエマルジョンが538gのDI水、17gのP−12A(25%活性)、754.6gのEHA、603.8gのMMA、36gのMAA、および28.36gのA−174シランを混合することにより調製されたことを除いて、バインダー5は、上記のバインダー1を調製した手順と同じ手順に従って調製された。
結合剤6の調製に使用したモノマーエマルジョンが538gのDI水、17gのP−12A(25%活性)、766gのEHA、621gのMMA、および36gのMAAを混合することにより調製されたことを除いて、バインダー6は、上記のバインダー1を調製した手順と同じ手順に従って調製された。
結合剤7は、結合剤7を得るために、最初に結合剤6を上述のように調製し、次いで4.25gのA−187シランを反応器に加えることにより得られた。
結合剤8の調製に使用したモノマーエマルジョンが538gのDI水、17gのP−12A(25%活性)、772gのEHA、597gのMMA、および50.4gのMAA、および4.25gのA−174シランを混合することにより調製されたことを除いて、バインダー8は、上記のバインダー1を調製した手順と同じ手順に従って調製された。
結合剤9の調製に使用したモノマーエマルジョンが538gのDI水、17gのP−12A(25%活性)、779gのEHA、568.5gのMMA、および72gのMAA、および4.25gのA−174シランを混合することにより調製されたことを除いて、バインダー9は、上記のバインダー1を調製した手順と同じ手順に従って調製された。
上記で得られた結合剤を、表2に与えられた配合に基づいて、実施例1〜9の塗料配合物(すなわち、コーティング組成物)を調製するために使用した。各塗料配合物の水、結合剤および他の成分を、従来の実験室用ミキサーを使用して混合した。最後に、得られた混合物に砂を添加した。得られた塗料配合物を、上述の試験方法に従って評価し、結果を表2に与えた。
上記で得られた結合剤を含む比較例A−Gの塗料配合物を、表3に記載された配合に基づいて調製した。各塗料配合物の水、結合剤および他の成分を、従来の実験室用ミキサーを使用して混合した。最後に、得られた混合物に砂を添加した。得られた塗料配合物を、上述の試験方法に従って評価し、結果を表3に与えた。
Claims (10)
- 水性コーティング組成物であって、
(a)ポリマーを含む水性ポリマー分散液であって、前記ポリマーが、前記ポリマーの重量に基づいて、
2重量%〜8重量%のα、β−エチレン性不飽和カルボン酸モノマーの構造単位、および
0.05重量%〜1.8重量%のエチレン性不飽和シラン官能性モノマーの構造単位を含む、水性ポリマー分散液と、
(b)亜鉛イオンを含む亜鉛アンモニア錯塩の水溶液と、
(c)前記水性コーティング組成物の総重量に基づいて、60重量%〜90重量%の充填剤と、を含み、
前記ポリマーに対する前記亜鉛イオンの重量比が、0.7%〜6%の範囲である、水性コーティング組成物。 - 前記エチレン性不飽和シラン官能性モノマーが、(メタ)アクリルオキシエチルトリメトキシシラン、(メタ)アクリルオキシプロピルトリメトキシシラン、ビニルトリエトキシシラン、ビニルトリメトキシシラン、それらの誘導体、またはそれらの組み合わせから選択される、請求項1に記載の水性コーティング組成物。
- 前記ポリマーが、前記ポリマーの重量に基づいて、0.1重量%〜1重量%の前記エチレン性不飽和シラン官能性モノマーの構造単位を含む、請求項1に記載の水性コーティング組成物。
- 前記ポリマーに対する前記亜鉛イオンの重量比が、1.5%〜3%の範囲である、請求項1に記載の水性コーティング組成物。
- 前記亜鉛アンモニア錯塩が、重炭酸亜鉛アンモニウム、硝酸亜鉛アンモニウム、酢酸亜鉛アンモニウム、またはそれらの混合物から選択される、請求項1に記載の水性コーティング組成物。
- 前記ポリマーが、前記ポリマーの重量に基づいて、2重量%〜4重量%のα、β−エチレン性不飽和カルボン酸モノマーの構造単位を含む、請求項1に記載の水性コーティング組成物。
- 前記充填剤が、90〜600μmのふるい粒子サイズを有する、請求項1に記載の水性コーティング組成物。
- (a)ポリマーを含む水性ポリマー分散液であって、前記ポリマーが、前記ポリマーの重量に基づいて、
2重量%〜8重量%のα、β−エチレン性不飽和カルボン酸モノマーの構造単位、および
0.05重量%〜1.8重量%のエチレン性不飽和シラン官能性モノマーの構造単位を含む、水性ポリマー分散液と、
(b)亜鉛イオンを含む亜鉛アンモニア錯塩の水溶液と、
(c)水性コーティング組成物の総重量に基づいて、60重量%〜90重量%の充填剤と、を混合することを含み、
前記ポリマーに対する前記亜鉛イオンの重量比が、0.7%〜6%の範囲である、プロセス。 - 亜鉛アンモニア錯塩の前記水溶液が、アンモニアと、亜鉛塩または酸化亜鉛と、任意選択で水溶性炭酸塩とを混合することにより得られる、請求項8に記載のプロセス。
- コーティングを調製する方法であって、
請求項1〜7のいずれか1項に記載の水性コーティング組成物を提供することと、
前記水性コーティング組成物を、基材に塗布することと、
前記塗布された水性コーティング組成物を70℃以上で乾燥させて、厚さ2mm以上の前記コーティングを形成することと、を含む、方法。
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