JP2020199458A - Processing method of hard surface - Google Patents
Processing method of hard surface Download PDFInfo
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- JP2020199458A JP2020199458A JP2019108166A JP2019108166A JP2020199458A JP 2020199458 A JP2020199458 A JP 2020199458A JP 2019108166 A JP2019108166 A JP 2019108166A JP 2019108166 A JP2019108166 A JP 2019108166A JP 2020199458 A JP2020199458 A JP 2020199458A
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- hard surface
- present
- treatment liquid
- distilled water
- steam
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- 238000003672 processing method Methods 0.000 title abstract 3
- 239000007788 liquid Substances 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 26
- 238000011282 treatment Methods 0.000 claims description 60
- 241000196324 Embryophyta Species 0.000 claims description 39
- 239000012153 distilled water Substances 0.000 claims description 39
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 244000004281 Eucalyptus maculata Species 0.000 claims description 5
- 244000178231 Rosmarinus officinalis Species 0.000 claims description 5
- 244000178870 Lavandula angustifolia Species 0.000 claims description 3
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 3
- 235000014749 Mentha crispa Nutrition 0.000 claims description 3
- 244000246386 Mentha pulegium Species 0.000 claims description 3
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 3
- 244000078639 Mentha spicata Species 0.000 claims description 3
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- 240000002657 Thymus vulgaris Species 0.000 claims description 3
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- 244000062730 Melissa officinalis Species 0.000 claims description 2
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- 235000002899 Mentha suaveolens Nutrition 0.000 claims description 2
- 235000001636 Mentha x rotundifolia Nutrition 0.000 claims description 2
- 235000017304 Ruaghas Nutrition 0.000 claims description 2
- 244000223014 Syzygium aromaticum Species 0.000 claims description 2
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- 235000009051 Ambrosia paniculata var. peruviana Nutrition 0.000 claims 1
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- 239000001138 artemisia absinthium Substances 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 11
- 238000001256 steam distillation Methods 0.000 abstract description 7
- 239000000796 flavoring agent Substances 0.000 abstract 2
- 235000019634 flavors Nutrition 0.000 abstract 2
- 239000003205 fragrance Substances 0.000 description 36
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
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- WRYLYDPHFGVWKC-UHFFFAOYSA-N 4-terpineol Chemical compound CC(C)C1(O)CCC(C)=CC1 WRYLYDPHFGVWKC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 3
- 230000009965 odorless effect Effects 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229960005323 phenoxyethanol Drugs 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 2
- 125000002006 1,8-cineol group Chemical group 0.000 description 2
- UWKAYLJWKGQEPM-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl acetate Chemical compound CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 229940121375 antifungal agent Drugs 0.000 description 2
- 239000003429 antifungal agent Substances 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000004042 decolorization Methods 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000012756 surface treatment agent Substances 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- WRYLYDPHFGVWKC-SNVBAGLBSA-N 4-Terpineol Natural products CC(C)[C@]1(O)CCC(C)=CC1 WRYLYDPHFGVWKC-SNVBAGLBSA-N 0.000 description 1
- 125000005274 4-hydroxybenzoic acid group Chemical class 0.000 description 1
- WWJLCYHYLZZXBE-UHFFFAOYSA-N 5-chloro-1,3-dihydroindol-2-one Chemical compound ClC1=CC=C2NC(=O)CC2=C1 WWJLCYHYLZZXBE-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 235000017519 Artemisia princeps Nutrition 0.000 description 1
- 244000065027 Artemisia princeps Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- PSMFFFUWSMZAPB-UHFFFAOYSA-N Eukalyptol Natural products C1CC2CCC1(C)COCC2(C)C PSMFFFUWSMZAPB-UHFFFAOYSA-N 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- KGEKLUUHTZCSIP-UHFFFAOYSA-N Isobornyl acetate Natural products C1CC2(C)C(OC(=O)C)CC1C2(C)C KGEKLUUHTZCSIP-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000001940 [(1R,4S,6R)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Substances 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 229940022663 acetate Drugs 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000008365 aqueous carrier Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- RFFOTVCVTJUTAD-UHFFFAOYSA-N cineole Natural products C1CC2(C)CCC1(C(C)C)O2 RFFOTVCVTJUTAD-UHFFFAOYSA-N 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 description 1
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 235000008216 herbs Nutrition 0.000 description 1
- CBCIHIVRDWLAME-UHFFFAOYSA-N hexanitrodiphenylamine Chemical compound [O-][N+](=O)C1=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C1NC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O CBCIHIVRDWLAME-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
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- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
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- 150000007519 polyprotic acids Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- NJBNJRILTKLNQZ-UHFFFAOYSA-N propyl 4-hydroxybenzoate Chemical compound CCCOC(=O)C1=CC=C(O)C=C1.CCCOC(=O)C1=CC=C(O)C=C1 NJBNJRILTKLNQZ-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Fats And Perfumes (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Detergent Compositions (AREA)
Abstract
Description
本発明は硬質表面の処理方法に関する。 The present invention relates to a method for treating a hard surface.
近年、キッチンやテーブルなどを安全性の観点からエタノールなどの殺菌性溶剤や界面活性剤などの洗浄成分が含まれた硬質表面処理液を接触させて拭き掃除することが一般的に行われている。また、このような硬質表面処理剤に香料を応用する技術も研究されている。 In recent years, from the viewpoint of safety, it is generally practiced to wipe and clean kitchens and tables by contacting them with a hard surface treatment liquid containing a bactericidal solvent such as ethanol and a cleaning component such as a surfactant. In addition, techniques for applying fragrances to such hard surface treatment agents are also being researched.
特許文献１には、エタノールと所定の界面活性剤と炭化水素系香料を所定範囲の含有量で含有する除菌用組成物が開示されている。
また、特許文献２には、乳化作用を有する水溶性のアニオン性ポリマー及び香料を含有する乳化液が含浸されてなる硬質表面用ウエットシートであって、前記ウエットシートは、該ウエットシートによって硬質表面を拭くことで、該ウエットシートから前記含浸された乳化液を該硬質表面に放出させた後、該硬質表面を洗い流さず、該乳化液及び該乳化液中の前記香料が該硬質表面に残留するように用いられるものである硬質表面用ウエットシートが開示されている。
また、特許文献３には、所定の界面活性剤、窒素含有ポリマー、並びに、水および任意の有機溶媒を包含する水性担体を含む抗菌性硬質表面清浄用組成物が開示されている。
Patent Document 1 discloses a sterilizing composition containing ethanol, a predetermined surfactant, and a hydrocarbon-based fragrance in a predetermined range of contents.
Further, Patent Document 2 describes a wet sheet for a hard surface impregnated with an emulsifying solution containing a water-soluble anionic polymer having an emulsifying action and a fragrance, and the wet sheet is a hard surface formed by the wet sheet. After the impregnated emulsion is released from the wet sheet onto the hard surface, the hard surface is not washed away, and the emulsion and the fragrance in the emulsion remain on the hard surface. A wet sheet for a hard surface, which is used as described above, is disclosed.
Further, Patent Document 3 discloses an antibacterial hard surface cleaning composition containing a predetermined surfactant, a nitrogen-containing polymer, and an aqueous carrier containing water and an arbitrary organic solvent.
特許文献１〜３は、例えば実施例で比較的高濃度で香料を用いていることから、硬質表面を処理する場面や処理後に好ましい香りを呈することを目的としていると推察される。しかし、乳幼児のいる家庭などでは、テーブルなどの手、指、口に接触する対象物には、香りが残らないか無臭の処理剤の方が好まれる場合も多い。すすぎ工程を行う洗浄剤組成物では、洗い流すことにより香りを除去できるが、硬質表面用除菌・抗菌剤や硬質表面の仕上げ処理に用いられる処理剤のようなすすぎ工程を伴わないような処理剤では、香料を含有しない方が好まれる場合もある。一方で、処理した場合に香りが全くない水拭きのような方法の場合には、処理した達成感を感じない利用者も多い。こうした背景から、例えば、処理した瞬間は仄かに香るが、処理後は香りがほとんど残らない硬質表面処理剤が提供できれば、このような新たな要求に応えられるものとなる。 Since Patent Documents 1 to 3 use a fragrance at a relatively high concentration in, for example, in Examples, it is presumed that the purpose of Patent Documents 1 to 3 is to exhibit a preferable scent when treating a hard surface or after the treatment. However, in households with infants, odorless or odorless treatment agents are often preferred for objects that come into contact with hands, fingers, and mouth, such as tables. In a cleaning agent composition that performs a rinsing process, the fragrance can be removed by rinsing, but a treatment agent that does not involve a rinsing process such as a disinfectant / antibacterial agent for hard surfaces and a treatment agent used for finishing treatment of hard surfaces. In some cases, it is preferable not to contain fragrance. On the other hand, in the case of a method such as wiping with water, which has no scent when treated, many users do not feel the sense of accomplishment of the treatment. Against this background, for example, if a hard surface treatment agent that gives off a faint scent at the moment of treatment but leaves almost no scent after treatment can be provided, it will be possible to meet such new demands.
本発明は、硬質表面を処理した瞬間は仄かに香るが、処理後は香りがほとんど残らない硬質表面の処理方法を提供する。 The present invention provides a method for treating a hard surface, which has a faint scent at the moment when the hard surface is treated, but leaves almost no scent after the treatment.
本発明は、ハーブ植物の水蒸気蒸留水を配合してなる処理液で硬質表面を処理する、硬質表面の処理方法に関する。 The present invention relates to a method for treating a hard surface, which comprises treating the hard surface with a treatment liquid containing steam distilled water of an herbal plant.
本発明によれば、硬質表面を処理した瞬間は仄かに香るが、処理後は香りがほとんど残らない硬質表面の処理方法が提供される。 According to the present invention, there is provided a method for treating a hard surface, which has a faint scent at the moment when the hard surface is treated, but leaves almost no scent after the treatment.
本発明では、ハーブ植物の水蒸気蒸留水を配合してなる処理液（以下、本発明の処理液という）で硬質表面を処理する。ここで、ハーブ植物の水蒸気蒸留水は、ハーブ植物の水抽出成分と水とを含む水性組成物であってよい。 In the present invention, the hard surface is treated with a treatment liquid (hereinafter referred to as the treatment liquid of the present invention) prepared by blending steam distilled water of herbal plants. Here, the steam-distilled water of the herb plant may be an aqueous composition containing the water extract component of the herb plant and water.
ハーブ植物の水蒸気蒸留水を得るためのハーブ植物としては、ローズマリー、ラベンダー、レモンバーム、レモングラス、レモンバーベナ、ジャーマンカモミール、ローマンカモミール、クローブ、セントジョーンワート、タイム、ティーツリー、ユーカリ、ロースゼラニウム、スペアミント、ペパーミント、アルベンシスミント、パルマローザ、ブラックマロー、よもぎ、エキナセア等が挙げられる。硬質表面を処理した瞬間は仄かに香り、処理後は香りがほとんど残らない観点では、ローズマリー、ラベンダー、ユーカリ、タイム、ペパーミント、スペアミントから選ばれるハーブ植物の水蒸気蒸留水が好ましい。 Herbal plants for obtaining steam-distilled water of herbal plants include rosemary, lavender, lemon balm, lemongrass, lemon verbena, German chamomile, roman chamomile, cloves, St. Joan wort, thyme, tea tree, eucalyptus, roast geranium, Examples include spearmint, peppermint, albensis mint, palmarosa, black mallow, YOMOGI, and echinacea. Steam-distilled water of herbal plants selected from rosemary, lavender, eucalyptus, thyme, peppermint, and spearmint is preferable from the viewpoint that the hard surface has a faint scent at the moment of treatment and almost no scent remains after treatment.
植物の水蒸気蒸留水は、例えば、香料として利用する精油成分を水蒸気蒸留で植物から採取する際の水相成分として入手される。そのような水蒸気蒸留水には、僅かながら香料成分が含まれているため、賦香目的で各種用途、例えば化粧料などに用いられることがある。しかし、ハーブ植物、とりわけ前記した所定のハーブ植物の水蒸気蒸留水が、硬質表面に適用した際に、処理した瞬間は仄かに香るが、処理後は香りがほとんど残らないという効果をもたらすことは、従来、知られておらず、本発明は当業者には予想外の効果を奏するものである。 The steam-distilled water of a plant is obtained, for example, as an aqueous phase component when an essential oil component used as a fragrance is collected from a plant by steam distillation. Since such steam-distilled water contains a small amount of fragrance components, it may be used for various purposes such as cosmetics for the purpose of fragrance. However, when the steam-distilled water of herbal plants, especially the above-mentioned predetermined herbal plants, is applied to a hard surface, it has an effect that the scent is faintly scented at the moment of treatment, but almost no scent remains after the treatment. Conventionally unknown, the present invention has an unexpected effect on those skilled in the art.
ハーブ植物の水蒸気蒸留水は、ハーブとして知られている各々の植物体の各種部位（花、花穂、果皮、果実、茎、葉、枝、枝葉、幹、樹皮、根茎、根皮、根、種子又は全草など）を、そのまま或いは粉砕後、公知の水蒸気蒸留装置を用いて得られた水蒸気蒸留水であってよい。水蒸気蒸留法については、植物から精油を得る為の手段として、例えば、藤巻正生ら「香料の事典」（p366.1980年８月２７日発行／朝倉書店）、亀高徳平ら「理論応用有機化学／第２１版」（p13.昭和２６年４月５日発行／丸善出版）などの文献を参照できる。又、水蒸気蒸留装置や原理についても、上記の文献などに示されている。尚、ハーブ植物の水蒸気蒸留水の製造方法は公知の水蒸気蒸留装置を用いて得られた水蒸気蒸留水であればよく、特に制限されるものではない。また、得られたハーブ植物の水蒸気蒸留水は、そのままの状態で利用できるが、必要ならば、その効果に影響のない範囲で更に、濾過、脱臭、脱色などの処理を加えてもよい。脱臭・脱色などの処理手段としては、活性炭カラムなどを用いればよく、一般的に適用される通常の手段を任意に選択して行えばよい。また、必要に応じて、防腐剤、溶媒などの成分を添加して組成を調整してもよい。 Steam-distilled water of herbal plants is a variety of parts of each plant known as herbs (flowers, spikes, peels, fruits, stems, leaves, branches, branches and leaves, trunks, bark, rhizomes, root bark, roots, seeds. Alternatively, it may be steam-distilled water obtained by using a known steam distillation apparatus as it is or after crushing the whole plant. Regarding the steam distillation method, as a means for obtaining essential oils from plants, for example, Masao Fujimaki et al., "Encyclopedia of Fragrances" (p. 366.1, published on August 27, 1980 / Asakura Shoten), Tokuhei Kametaka "Theoretical Applied Organic Chemistry" / 21st edition ”(p13. Published April 5, 1951 / Maruzen Publishing) and other documents can be referred to. Further, the steam distillation apparatus and the principle are also shown in the above-mentioned documents. The method for producing steam-distilled water of herbal plants is not particularly limited as long as it is steam-distilled water obtained by using a known steam distillation apparatus. The obtained steam-distilled water of the herb plant can be used as it is, but if necessary, further treatments such as filtration, deodorization, and decolorization may be added as long as the effect is not affected. As a treatment means for deodorization / decolorization, an activated carbon column or the like may be used, and generally applied ordinary means may be arbitrarily selected. Further, if necessary, components such as preservatives and solvents may be added to adjust the composition.
ハーブ植物の水蒸気蒸留では、香料成分の大部分はエッセンシャルオイルといわれる油層に存在するが、水蒸気蒸留水として取得される水層にも、わずかではあるが相対的に親水性の香料成分が含まれる。本発明ではそのような水蒸気蒸留水により硬質表面を処理することで、仄かに香り、残香しないという本発明の効果が発現する方法が可能となる。 In steam distillation of herbal plants, most of the fragrance components are present in an oil layer called essential oil, but the water layer obtained as steam distilled water also contains a small amount of relatively hydrophilic fragrance components. In the present invention, by treating the hard surface with such steam distilled water, a method capable of exhibiting the effect of the present invention of faint scent and no residual scent becomes possible.
ハーブ植物の水蒸気蒸留水に含まれる香料成分としては、ハーブ植物にもよるが、１，８−シネオール（２．７６／２０７．９８）、カンファー（２．１８／１．４３）、リナロール（２．５５／１１．０９）、テルピネン−４−オール（２．７５／５．６９）、テルピネオール（２．６３／２．６１）、リモネン（４．３５／１９３．３２）、ｌ−メントール（３．２３／１．０２）、メントン（２．８７／４９．３３）、酢酸リナリル（３．５／１７．４７）、ジヒドロジャスモン酸メチル（２．４２／０．１６）、ゲラニオール（２．７７／２．１２）、ｌ−カルボン（２．０１／１７．３３）、チモール（３．４０／２．２３）、シトラール（３．１２／１２．１７）、シトロネロール（３．２３／２．２５）、酢酸イソボルニル（３．５２／１４．２７）、サリチル酸メチル（２．４５／７．１２）、酢酸ヘキシル（２．８３／１９３．３２）、酢酸ゲラニル（３．７２／６．１７）、酢酸ベンジル（１．９６／２４．９３）などが挙げられる。ここで、かっこ内の数字はＬｏｇＰｏｗ／蒸気圧（Ｐａ）を示す。ハーブ植物の水蒸気蒸留水は、１，８−シネオールを含むことが好ましい。例えば、ハーブ植物の水蒸気蒸留水が香料成分を含む、香料成分中、好ましくは２０質量％以上、より好ましくは３０質量％以上、更に好ましくは５０質量％以上が１，８−シネオールであることが好ましい。 The fragrance component contained in the steam distilled water of herbal plants depends on the herbal plants, but is 1,8-cineol (2.76 / 207.98), camphor (2.18 / 1.43), linalool (2). .55 / 11.09), terpinen-4-ol (2.75 / 5.69), terpineol (2.63 / 2.61), limonene (4.35 / 193.32), l-menthol (3) .23 / 1.02), Menton (2.87 / 49.33), Linalool acetate (3.5 / 17.47), Methyl dihydrojasmonate (2.42 / 0.16), Geraniol (2.77) /2.12), l-carboxylic (2.01 / 17.33), timol (3.40 / 2.23), citral (3.12 / 12.17), citronellol (3.23 / 2.25) ), Isobornyl acetate (3.52 / 14.27), Methyl salicylate (2.45 / 7.12), Hexil acetate (2.83 / 193.32), Geranyl acetate (3.72 / 6.17), Examples thereof include benzyl acetate (1.96 / 24.93). Here, the numbers in parentheses indicate LogPower / vapor pressure (Pa). The steam-distilled water of the herbal plant preferably contains 1,8-cineole. For example, steam distilled water of an herbal plant contains a fragrance component, and among the fragrance components, preferably 20% by mass or more, more preferably 30% by mass or more, still more preferably 50% by mass or more is 1,8-cineole. preferable.
一般に使用される香料成分は揮発性によってトップノート、ミドルノート、ベースノートの３種類に分けられ、トップノートは香りの嗅ぎ口に影響し、ミドルノートは香りの中心的役割を有し、ベースノートは残香性を付与する役割を有することが知られている。このような香料成分を含有する香料組成物を用いた場合には比較的蒸気圧の低いミドルノート香料やベースノート香料が残香し、仄かな香りと残香しない本発明の効果を得ることができない。また、トップノートの香料のみを用いた場合においても、例えばポリプロピレンなどの疎水性の硬質表面を処理した場合には疎水性の香料成分との親和性から残香する。
これに対して、本発明で用いるハーブ植物の水蒸気蒸留水は、香料成分の中でも親水性の素材が僅かに水層に溶解したものであり、それら香料素材の揮発性、ＬｏｇＰｏｗ、及び含有量などが本発明の効果を付与できる最適な組み合わせになっていると考えられる。
従って、本発明の処理液はハーブ植物の水蒸気蒸留水以外の香料成分を含有しないことが好ましく、ハーブ植物の水蒸気蒸留水以外の香料成分を含有する場合には、本発明の効果を損なわない程度の量であることが好ましい。具体的には、例えば、本発明の処理液におけるハーブ植物の水蒸気蒸留水以外の香料成分の含有量は、ハーブ植物の水蒸気蒸留水１質量部あたり、好ましくは０．１質量部以下、より好ましくは０．０５質量部以下、更に好ましくは０．０１質量部以下である。
Commonly used fragrance components are divided into three types according to volatility: top note, middle note, and base note. The top note affects the scent sniffing mouth, and the middle note plays a central role in the scent. Is known to have a role of imparting residual fragrance. When a fragrance composition containing such a fragrance component is used, a middle note fragrance or a base note fragrance having a relatively low vapor pressure remains, and the effect of the present invention with a faint scent and no residual scent cannot be obtained. Further, even when only the top note fragrance is used, when a hydrophobic hard surface such as polypropylene is treated, the fragrance remains due to the affinity with the hydrophobic fragrance component.
On the other hand, the steam-distilled water of the herbal plant used in the present invention is a fragrance component in which a hydrophilic material is slightly dissolved in an aqueous layer, and the volatility, LogPower, content, etc. of the fragrance material are used. Is considered to be the optimum combination that can impart the effects of the present invention.
Therefore, the treatment liquid of the present invention preferably does not contain a fragrance component other than the steam-distilled water of the herbal plant, and when it contains a fragrance component other than the steam-distilled water of the herb plant, the effect of the present invention is not impaired. Is preferably the amount of. Specifically, for example, the content of the fragrance component other than the steam-distilled water of the herb plant in the treatment liquid of the present invention is preferably 0.1 part by mass or less per 1 part by mass of the steam-distilled water of the herb plant, more preferably. Is 0.05 parts by mass or less, more preferably 0.01 parts by mass or less.
本発明では、ハーブ植物の水蒸気蒸留水をそのまま本発明の処理液として用いてもよいが、ハーブ植物の水蒸気蒸留水と水とを配合してなる処理液を用いることが好ましい。すなわち、本発明では、ハーブ植物の水蒸気蒸留水と水とを混合して得た処理液を用いることができる。
ハーブ植物の水蒸気蒸留水と水との配合割合は、特に限定はなく、ハーブ植物の種類や水蒸気蒸留水中に含まれる香料成分の推定量などを踏まえて適宜決定できる。
一例として、前記で例示したハーブ植物の水蒸気蒸留水であれば、当該水蒸気蒸留水１質量部に対して好ましくは水１０質量部以上、より好ましくは２０質量部以上、更に好ましくは５０質量部以上、そして、好ましくは５００質量部以下、より好ましくは３００質量部以下、更に好ましくは２００質量部以下を配合してなる処理液を本発明の処理液とすることができる。
In the present invention, the steam-distilled water of the herb plant may be used as it is as the treatment liquid of the present invention, but it is preferable to use the treatment liquid obtained by mixing the steam-distilled water of the herb plant and water. That is, in the present invention, a treatment liquid obtained by mixing steam distilled water of an herb plant and water can be used.
The mixing ratio of the steam-distilled water of the herb plant and water is not particularly limited, and can be appropriately determined based on the type of the herb plant and the estimated amount of the fragrance component contained in the steam-distilled water.
As an example, in the case of the steam-distilled water of the herb plant exemplified above, preferably 10 parts by mass or more, more preferably 20 parts by mass or more, still more preferably 50 parts by mass or more with respect to 1 part by mass of the steam-distilled water. The treated liquid of the present invention can be prepared by blending preferably 500 parts by mass or less, more preferably 300 parts by mass or less, and further preferably 200 parts by mass or less.
本発明の処理液は、ハーブ植物由来の成分以外の成分を含有することができる。例えば、陽イオン界面活性剤、両性界面活性剤、及び非イオン界面活性剤から選ばれる１種以上の界面活性剤を含有することができる。
また、本発明の処理液は、α−ヒドロキシカルボン酸、多塩基酸（但し、α−ヒドロキシカルボン酸を除く）、及びこれらの塩から選ばれる１種以上の有機酸又はその塩を含有することができる。
また、本発明の処理液は、炭素数２以上６以下の脂肪族アルコール、炭素数１以上６以下のアルキルグリコールエーテル、炭素数２以上６以下の脂肪族ジオールなどの揮発性有機溶媒を含有することができる。揮発性有機溶媒は、以下の防腐・防黴剤として機能するものであってよい。
また、本発明の処理液は、必要に応じて防腐・防黴剤として、４−ヒドロキシ安息香酸メチル（メチルパラベン）、４−ヒドロキシ安息香酸エチル（エチルパラベン）、４−ヒドロキシ安息香酸プロピル（プロピルパラベン）等のパラヒドロキシ安息香酸エステル（パラベン類）、エタノール、フェノキシエタノール、１，３−ブチレングリコール等のアルコールなどの成分を含有することができる。
また、本発明の処理液は、色素、酸化防止剤、ｐＨ調整剤等を任意に含有することができる。
The treatment liquid of the present invention can contain components other than those derived from herbal plants. For example, it can contain one or more surfactants selected from cationic surfactants, amphoteric surfactants, and nonionic surfactants.
In addition, the treatment liquid of the present invention contains α-hydroxycarboxylic acid, polybasic acid (excluding α-hydroxycarboxylic acid), and one or more organic acids selected from these salts or salts thereof. Can be done.
The treatment liquid of the present invention contains a volatile organic solvent such as an aliphatic alcohol having 2 to 6 carbon atoms, an alkyl glycol ether having 1 to 6 carbon atoms, and an aliphatic diol having 2 to 6 carbon atoms. be able to. The volatile organic solvent may function as the following antiseptic / antifungal agent.
The treatment liquid of the present invention also contains methyl 4-hydroxybenzoate (methylparaben), ethyl 4-hydroxybenzoate (ethylparaben), and propyl 4-hydroxybenzoate (propylparaben) as preservatives and antifungal agents, if necessary. ) And other parahydroxybenzoic acid esters (parabens), ethanol, phenoxyethanol, and alcohols such as 1,3-butylene glycol can be contained.
Further, the treatment liquid of the present invention can optionally contain a dye, an antioxidant, a pH adjuster and the like.
本発明の処理液は、２０℃におけるｐＨが、取扱いの容易さ及び手肌への刺激性の観点から、４．０以上、そして、９．０以下、好ましくは８．０以下、より好ましくは７．０以下である。ｐＨの調整には、ｐＨ調整剤を用いることができる。ｐＨ調整剤としては塩酸や硫酸など無機酸や、有機酸など酸剤を用いることができる。また、アルカリ剤としては、水酸化ナトリウムや水酸化カリウム、炭酸ナトリウム、炭酸カリウムを用いることができる。 The treatment liquid of the present invention has a pH at 20 ° C. of 4.0 or more and 9.0 or less, preferably 8.0 or less, more preferably from the viewpoint of ease of handling and irritation to the hand skin. It is 7.0 or less. A pH adjuster can be used to adjust the pH. As the pH adjuster, an inorganic acid such as hydrochloric acid or sulfuric acid or an acid agent such as an organic acid can be used. Further, as the alkaline agent, sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate can be used.
本発明が対象とする硬質表面は、プラスチック、ゴム、金属、タイル、レンガ、コンクリート、セメント、ガラス、木等からなる床、階段、壁等の固定物のほか、それらからなる各種器械、器具、道具、家具、食器等の人が接触するもの全般における硬質表面を挙げることができる。例えば、トイレ、風呂、洗面台、台所、リビングなどに存在する硬質表面に適用することができる。 The hard surface targeted by the present invention includes fixed objects such as floors, stairs, and walls made of plastic, rubber, metal, tile, brick, concrete, cement, glass, wood, etc., as well as various instruments and instruments made of them. The hard surface of all things that people come into contact with, such as tools, furniture, and tableware, can be mentioned. For example, it can be applied to hard surfaces existing in toilets, baths, wash basins, kitchens, living rooms and the like.
本発明では、ハーブ植物の水蒸気蒸留水を配合してなる本発明の処理液を硬質表面に接触させて硬質表面を処理する。硬質表面の処理は、洗浄、殺菌、除菌、仕上げなどを目的とするものであってよく、これらの複合であってもよい。
本発明では、本発明の処理液を、噴霧、塗布、浸漬などにより、硬質表面に接触させて硬質表面を処理する。
本発明の硬質表面の処理方法としては、（１）本発明の処理液を硬質表面に噴霧する、例えばトリガー等の噴霧器（スプレーヤー）を用いて、本発明の処理液を硬質表面に噴霧する方法、（２）吸水性の可撓性材料からなる清掃用物品に本発明の処理液を染み込ませて硬質表面を擦る方法、及び（３）本発明の処理液に対象物を浸漬させる方法が挙げられ、簡便性の観点から、（１）の方法が好適である。本発明では、本発明の処理液を硬質表面に適用した後、必要に応じて本発明の処理液を塗り伸ばす操作、及び本発明の処理液を拭き取る操作、硬質表面を乾燥する操作から選ばれる操作を、単独又は組み合わせて行うことができる。
In the present invention, the treatment liquid of the present invention, which is a mixture of steam distilled water of herbal plants, is brought into contact with the hard surface to treat the hard surface. The treatment of the hard surface may be for the purpose of cleaning, sterilization, sterilization, finishing, etc., and may be a composite of these.
In the present invention, the treatment liquid of the present invention is brought into contact with the hard surface by spraying, coating, dipping or the like to treat the hard surface.
As a method for treating a hard surface of the present invention, (1) the treatment liquid of the present invention is sprayed onto the hard surface, for example, the treatment liquid of the present invention is sprayed on the hard surface using a sprayer (sprayer) such as a trigger. Methods, (2) a method of impregnating a cleaning article made of a water-absorbent flexible material with the treatment liquid of the present invention and rubbing a hard surface, and (3) a method of immersing an object in the treatment liquid of the present invention. From the viewpoint of convenience, the method (1) is preferable. In the present invention, after applying the treatment liquid of the present invention to a hard surface, it is selected from an operation of spreading the treatment liquid of the present invention as necessary, an operation of wiping off the treatment liquid of the present invention, and an operation of drying the hard surface. The operation can be performed alone or in combination.
本発明の硬質表面の処理方法としては、本発明の処理液を、原液で、希釈せずに硬質表面に接触させる、つまり、本発明の処理液を、希釈することなく、硬質表面に接触させる硬質表面の処理方法が好ましく挙げられる。
本発明の処理液を希釈せずに硬質表面に接触させるとは、本発明の処理液を、意図的に水などで希釈した後、硬質表面と接触させないことである。例えば、本発明の処理液を水滴等が付着した硬質表面と接触させたり、本発明の処理液を硬質表面に接触させた後、硬質表面に水滴が付着したりする場合は、本発明の処理液を希釈せずに、硬質表面に接触させると理解できる。
本発明の硬質表面の処理方法では、本発明の処理液を、原液で、硬質表面に接触させるには、ボトルから直接塗布又は噴霧してもよく、ボトルとしては、例えば、スクイズボトル、スプレーボトル等が挙げられる。
また本発明の処理液を含浸させた清掃用物品使用時に、別途、他の本発明の処理液を、被清掃物又は前記清掃用物品に、噴霧しながら使用してもよい。当該使用方法によって、より広い面積を清掃することができる。
As a method for treating a hard surface of the present invention, the treatment liquid of the present invention is brought into contact with the hard surface without dilution with a stock solution, that is, the treatment liquid of the present invention is brought into contact with the hard surface without dilution. A method for treating a hard surface is preferable.
Contacting the treatment liquid of the present invention with a hard surface without diluting means that the treatment liquid of the present invention is intentionally diluted with water or the like and then not brought into contact with a hard surface. For example, when the treatment liquid of the present invention is brought into contact with a hard surface to which water droplets or the like are attached, or when the treatment liquid of the present invention is brought into contact with a hard surface and then water droplets are attached to the hard surface, the treatment of the present invention is carried out. It can be understood that the liquid is brought into contact with a hard surface without being diluted.
In the method for treating a hard surface of the present invention, the treatment liquid of the present invention may be directly applied or sprayed from a bottle in order to bring the treatment liquid of the present invention into contact with the hard surface as an undiluted solution. Examples of the bottle include a squeeze bottle and a spray bottle. And so on.
Further, when using a cleaning article impregnated with the treatment liquid of the present invention, another treatment liquid of the present invention may be separately used while being sprayed on the object to be cleaned or the cleaning article. A larger area can be cleaned by the method of use.
本発明の処理液を硬質表面に接触させた後は、水などによるすすぎ工程やハーブ植物の水蒸気蒸留水を対象表面からふき取るなどの工程は設けず、そのまま当該硬質表面を放置／乾燥させて、本発明の処理液の成分を硬質表面に残存させることが好ましい。 After the treatment liquid of the present invention is brought into contact with the hard surface, the hard surface is left as it is / dried without providing a step of rinsing with water or wiping the steam-distilled water of the herb plant from the target surface. It is preferable that the components of the treatment liquid of the present invention remain on the hard surface.
表１の成分を表１に示す配合量となるように配合して処理液を調製し、以下の項目について評価を行った。結果を表１に示す。表１の処理液を得るにあたり、まず、イオン交換水に、ローズマリー又はユーカリの水蒸気蒸留水と、表１に示す成分とを、表中の配合量となるように配合し、室温（２０℃）で溶解させた。配合後、ｐＨ調整剤として、水酸化ナトリウムを添加し、ｐＨを表１中に記載の値になるように調整した。なお、ｐＨはガラス電極法で測定した。
表１中、ローズマリー水蒸気蒸留水及びユーカリ水蒸気蒸留水の配合量で、かっこ内のｐｐｍは香料成分としての配合量を示す。また、表１中の配合量のｐｐｍと％は質量基準の割合であり、全て有効分に基づく数値である。表１の配合量は、イオン交換水の量で調整したので、便宜的にイオン交換水の配合量を「残部」と表記している。
The components in Table 1 were blended in the blending amounts shown in Table 1 to prepare a treatment liquid, and the following items were evaluated. The results are shown in Table 1. In order to obtain the treatment liquid shown in Table 1, first, steam-distilled rosemary or eucalyptus water and the components shown in Table 1 are mixed with ion-exchanged water so as to have the amounts shown in the table, and the temperature (20 ° C. ) Was dissolved. After compounding, sodium hydroxide was added as a pH adjuster to adjust the pH to the values shown in Table 1. The pH was measured by the glass electrode method.
In Table 1, the blending amount of rosemary steam distilled water and eucalyptus steam distilled water, and ppm in parentheses indicates the blending amount as a fragrance component. In addition, ppm and% of the compounding amount in Table 1 are mass-based ratios, and are all numerical values based on the effective amount. Since the blending amount in Table 1 was adjusted by the amount of ion-exchanged water, the blending amount of ion-exchanged water is referred to as "remaining portion" for convenience.
＜香りの評価方法＞
表１に示す処理液をスプレー容器に入れ、木製テーブルの天板に４回（１ｍ２あたり３ｍｌ）スプレーし、その後、すぐに紙で拭き取った。スプレー直後の香り強度と、拭き取り１分後の香り強度を、それぞれ、専門パネル３名が下記基準で評価し、平均値を算出した。表には、スプレー直後の香り強度の平均値と、拭き取り１分後の香り強度の平均値を、それぞれ示した。また、スプレー直後の香り強度の平均値については、１以上２以下を〇とし、それ以外を×として表に示した。更に、拭き取り１分後の香り強度については、１未満を〇とし、それ以外を×として表に示した。○は合格水準にあることを意味し、×はその水準に到達していないことを意味する。
＊香り強度評価基準
０：無臭
１：香りをほのかに感じる
２：香りを感じる
３：香りを強く感じる
<Aroma evaluation method>
The treatment liquid shown in Table 1 was placed in a spray container, sprayed four times (3 ml per 1 m 2 ) on the top plate of a wooden table, and then immediately wiped off with paper. The scent intensity immediately after spraying and the scent intensity 1 minute after wiping were evaluated by three specialized panels according to the following criteria, and average values were calculated. The table shows the average value of the scent intensity immediately after spraying and the average value of the scent intensity 1 minute after wiping. The average value of the scent intensity immediately after spraying was shown in the table as 0 for 1 or more and 2 or less, and x for the others. Further, the scent intensity 1 minute after wiping was shown in the table as 〇 for less than 1 and x for the others. ○ means that it is at the passing level, and × means that it has not reached that level.
* Scent intensity evaluation criteria 0: Odorless 1: Feel the scent faintly 2: Feel the scent 3: Feel the scent strongly
表中の成分は以下のものである。
・ローズマリー水蒸気蒸留水：香料成分を５０２ｐｐｍ、フェノキシエタノールを１質量％、１，３−ブチレングリコールを１０質量％含有し、香料成分中、６９．１質量％が１，８−シネオールであった。
・ユーカリ水蒸気蒸留水：香料成分を６７０ｐｐｍ、フェノキシエタノールを１質量％、１，３−ブチレングリコールを１０質量％含有し、香料成分中、８０質量％が１，８−シネオールであった。
・塩化ベンザルコニウム：サニゾールＣ、花王（株）製
・アルキルグリコシド：ＡＧ−１２４、花王（株）製
The components in the table are as follows.
-Rosemary steam distilled water: 502 ppm by mass of fragrance component, 1% by mass of phenoxyethanol, 10% by mass of 1,3-butylene glycol was contained, and 69.1% by mass of the fragrance component was 1,8-cineole.
-Eucalyptus steam distilled water: 670 ppm by mass of fragrance component, 1% by mass of phenoxyethanol, 10% by mass of 1,3-butylene glycol, and 80% by mass of fragrance component was 1,8-cineole.
・ Benzalkonium chloride: Sanizol C, manufactured by Kao Corporation ・ Alkyl glycoside: AG-124, manufactured by Kao Corporation
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| JP2003082400A (en) * | 2001-07-06 | 2003-03-19 | Lion Corp | Liquid detergent composition and deodorizing method |
| JP2004238299A (en) * | 2003-02-04 | 2004-08-26 | Ichimaru Pharcos Co Ltd | Cosmetic composition containing steam-distilled water originating from plant |
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| JP2003082400A (en) * | 2001-07-06 | 2003-03-19 | Lion Corp | Liquid detergent composition and deodorizing method |
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