JP2020090410A - Ultra-high strength concrete and its mixing method - Google Patents

Ultra-high strength concrete and its mixing method Download PDF

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JP2020090410A
JP2020090410A JP2018227630A JP2018227630A JP2020090410A JP 2020090410 A JP2020090410 A JP 2020090410A JP 2018227630 A JP2018227630 A JP 2018227630A JP 2018227630 A JP2018227630 A JP 2018227630A JP 2020090410 A JP2020090410 A JP 2020090410A
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coarse aggregate
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high strength
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JP7199942B2 (en
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俊文 菊地
Toshibumi Kikuchi
俊文 菊地
圭一 ▲高▼橋
圭一 ▲高▼橋
Keiichi Takahashi
黒田 泰弘
Yasuhiro Kuroda
泰弘 黒田
遠藤 芳雄
Yoshio Endo
芳雄 遠藤
正美 戸澤
Masami Tozawa
正美 戸澤
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Shimizu Construction Co Ltd
Shimizu Corp
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Abstract

To provide ultra-high strength concrete excellent in gap passing property and crack resistance while having a high steel fiber mixing ratio, and a mixing method thereof.SOLUTION: The present invention provides the ultra-high strength concrete that contains cement, silica fume, water, coarse aggregate, fine aggregate, chemical admixture, steel fiber and organic fiber, and has a water/binder ratio of 25 wt.% or less and a steel fiber mixing ratio of more than 0.5 vol.% and 2 vol.% or less, in which the organic fiber includes a polypropylene fiber, a maximum size of the coarse aggregate is 15 mm or less, and the unit coarse aggregate bulk volume is 0.3 to 0.4 m/m.SELECTED DRAWING: None

Description

本発明は、超高強度コンクリート及びその調合方法に関する。 The present invention relates to ultra high strength concrete and a method for mixing the same.

コンクリートにおける水結合材比を低くすることで、コンクリートの圧縮強度を高めることができる。しかし、水結合材比が低くなると、火災時等、コンクリートが高温に曝されたときに、コンクリートの爆裂が生じやすくなる。
爆裂を抑制する手法として、コンクリートに有機繊維を配合する方法が知られており、高強度コンクリートには有機繊維が配合されることが多い。有機繊維としては、ポリプロピレン、ポリエチレン等のポリオレフィン系繊維、ポリビニルアルコール系繊維(ビニロン繊維)、ポリアセタール系繊維等がある(特許文献1)。
また、コンクリートに有機繊維と鋼繊維とを併有させることが提案されている(特許文献2〜3)。
The compressive strength of concrete can be increased by lowering the ratio of water binder in the concrete. However, when the ratio of the water binder is low, the concrete is likely to explode when exposed to high temperatures such as in a fire.
As a method for suppressing explosion, a method of mixing organic fiber with concrete is known, and high strength concrete is often mixed with organic fiber. Examples of organic fibers include polyolefin fibers such as polypropylene and polyethylene, polyvinyl alcohol fibers (vinylon fibers), and polyacetal fibers (Patent Document 1).
In addition, it has been proposed that organic fiber and steel fiber are incorporated in concrete (Patent Documents 2 to 3).

特許第4608176号公報Japanese Patent No. 4608176 特開2002−193654号公報JP 2002-193654 A 特許第4071983号公報Japanese Patent No. 4071983

近年、設計基準強度が100N/mm以上の超高強度コンクリートが超超高層RC建物のRC柱等の部材に適用されるようになっている。
超高強度コンクリートに鋼繊維を配合することは、超超高層RC建物の地震時のひび割れによる長周期化や極大地震時の端部圧壊による耐力低下を抑制するのに有効と考えられる。特に、鋼繊維の混入率を0.5容積%よりも高く、例えば1.0容積%程度にできれば、部材としての性能を著しく向上させることが可能になると考えられる。
しかし、超高強度コンクリートにおいて鋼繊維の混入率を高くすると、密に配筋された柱主筋やせん断補強筋の間隙に確実に充填されるような間隙通過性を確保することが困難である。
間隙通過性を確保するために、粗骨材量を減らすことが考えられる。しかし、間隙通過性を確保できる程度に粗骨材量を減らすと、コンクリートの収縮量が増え、ひび割れ抵抗性の低下につながる。
特許文献1〜3では、コンクリートの間隙通過性とひび割れ抵抗性とを両立するための配合設計について検討されていない。
In recent years, ultra-high strength concrete having a design standard strength of 100 N/mm 2 or more has been applied to members such as RC columns of ultra-high-rise RC buildings.
It is considered that the addition of steel fiber to ultra-high-strength concrete is effective in suppressing the extension of the period of an ultra-high-rise RC building due to cracks during an earthquake and the reduction in yield strength due to edge crushing during a maximum earthquake. In particular, if the mixing ratio of steel fibers can be made higher than 0.5% by volume, for example, about 1.0% by volume, it is considered that the performance as a member can be significantly improved.
However, if the mixing ratio of steel fibers in the ultra-high-strength concrete is increased, it is difficult to ensure the gap passage property such that the gaps between the column main reinforcements and the shear reinforcement reinforcements that are densely arranged are reliably filled.
It is conceivable to reduce the amount of coarse aggregate in order to secure the gap permeability. However, if the amount of coarse aggregate is reduced to such an extent that the gap permeability can be secured, the amount of shrinkage of concrete increases, leading to a reduction in crack resistance.
In Patent Documents 1 to 3, there is no study on a mix design for achieving both the gap permeability and the crack resistance of concrete.

本発明は、上記事情に鑑みてなされたものであって、鋼繊維混入率が高いながらも、間隙通過性及びひび割れ抵抗性に優れた超高強度コンクリート及びその調合方法を提供することを目的とする。 The present invention has been made in view of the above circumstances, and an object thereof is to provide an ultra-high-strength concrete excellent in gap passage property and crack resistance and a mixing method thereof, even though the steel fiber mixing ratio is high. To do.

本発明は以下の態様を有する。
[1]セメントと、シリカヒュームと、水と、粗骨材と、細骨材と、化学混和剤と、鋼繊維と、有機繊維とを含み、水結合材比が25質量%以下、前記鋼繊維の混入率が0.5容積%超2容積%以下である超高強度コンクリートであって、
前記有機繊維がポリプロピレン繊維を含み、
前記粗骨材の最大寸法が15mm以下であり、
単位粗骨材かさ容積が0.3〜0.4m/mである、超高強度コンクリート。
[2]前記有機繊維の混入率が0.14〜0.58容積%である前記[1]の超高強度コンクリート。
[3]前記鋼繊維の直径が0.15〜0.9mm、長さが12〜32mmである前記[1]又は[2]の超高強度コンクリート。
[4]セメントと、シリカヒュームと、水と、粗骨材と、細骨材と、化学混和剤と、鋼繊維と、有機繊維とを配合し、水結合材比が25質量%以下、前記鋼繊維の混入率が0.5容積%超2容積%以下である超高強度コンクリートを調合する方法であって、
前記有機繊維として少なくともポリプロピレン繊維を用い、
前記粗骨材の最大寸法を15mm以下とし、
下記式(1)により前記超高強度コンクリートの単位粗骨材かさ容積の目標値V’bGを算出し、前記目標値V’bGとなるように前記粗骨材の配合量を設定する、超高強度コンクリートの調合方法。
V’bG=VbG−(K・2r/3r−1)・V/G (1)
ここで、V’bGは、前記超高強度コンクリートの単位粗骨材かさ容積の目標値(m/m)を示し、
bGは、超高強度コンクリートの単位粗骨材かさ容積(m/m)の標準値の範囲であって0.5〜0.56(m/m)の数を示し、
は、影響係数であって0.8〜1の数を示し、
は、前記粗骨材を球形と仮定し、前記粗骨材の粒度分布から得られる総粗骨材表面積から算出した前記粗骨材の半径(mm)を示し、
は、前記鋼繊維を円柱形と仮定して算出した前記鋼繊維の半径(mm)を示し、
は、前記鋼繊維の混入率(容積%)を示し、
は、前記粗骨材の実積率(容積%)を示す。
[5]前記有機繊維の混入率が0.14〜0.58容積%である前記[4]の超高強度コンクリートの調合方法。
[6]前記鋼繊維の直径が0.15〜0.9mm、長さが12〜32mmである前記[4]又は[5]の超高強度コンクリートの調合方法。
The present invention has the following aspects.
[1] Cement, silica fume, water, coarse aggregate, fine aggregate, chemical admixture, steel fiber, organic fiber, and water binder ratio of 25% by mass or less, the steel An ultra-high strength concrete having a fiber mixture ratio of more than 0.5% by volume and 2% by volume or less,
The organic fibers include polypropylene fibers,
The maximum size of the coarse aggregate is 15 mm or less,
Unit coarse aggregate bulk volume is 0.3~0.4m 3 / m 3, ultra-high strength concrete.
[2] The super high-strength concrete according to the above [1], wherein the mixing ratio of the organic fibers is 0.14 to 0.58% by volume.
[3] The ultra high strength concrete according to [1] or [2], wherein the steel fiber has a diameter of 0.15 to 0.9 mm and a length of 12 to 32 mm.
[4] Cement, silica fume, water, coarse aggregate, fine aggregate, chemical admixture, steel fiber, and organic fiber are mixed, and the water binder ratio is 25% by mass or less, A method for mixing ultra-high-strength concrete in which the mixing ratio of steel fibers is more than 0.5% by volume and 2% by volume or less,
Using at least polypropylene fiber as the organic fiber,
The maximum size of the coarse aggregate is 15 mm or less,
The target value V'bG of the unit coarse aggregate bulk volume of the ultra-high strength concrete is calculated by the following formula (1), and the blending amount of the coarse aggregate is set to be the target value V'bG. Mixing method for high strength concrete.
V 'bG = V bG - ( K S · 2r G / 3r F -1) · V F / G S (1)
Here, V′ bG represents a target value (m 3 /m 3 ) of the unit coarse aggregate bulk volume of the ultra-high strength concrete,
V bG is a standard value range of the unit coarse aggregate bulk volume (m 3 /m 3 ) of ultra-high strength concrete and represents a number of 0.5 to 0.56 (m 3 /m 3 ),
K S is an influence coefficient and represents a number of 0.8 to 1,
r G represents the radius (mm) of the coarse aggregate calculated from the total coarse aggregate surface area obtained from the particle size distribution of the coarse aggregate, assuming that the coarse aggregate is spherical,
r F represents the radius (mm) of the steel fiber calculated assuming that the steel fiber has a cylindrical shape,
V F represents the mixing ratio (volume %) of the steel fiber,
G S represents the actual volume ratio (volume %) of the coarse aggregate.
[5] The mixing method of the ultra high strength concrete according to the above [4], wherein the mixing ratio of the organic fiber is 0.14 to 0.58% by volume.
[6] The method for mixing ultra-high strength concrete according to the above [4] or [5], wherein the steel fiber has a diameter of 0.15 to 0.9 mm and a length of 12 to 32 mm.

本発明によれば、鋼繊維混入率が高いながらも、間隙通過性及びひび割れ抵抗性に優れた超高強度コンクリート及びその調合方法を提供できる。 According to the present invention, it is possible to provide an ultrahigh-strength concrete excellent in gap passing property and crack resistance while having a high steel fiber mixing ratio, and a mixing method thereof.

実施例にて加振ボックス充填試験に用いたボックス形容器を説明する図である。It is a figure explaining the box-shaped container used for the vibration box filling test in an Example. 実施例における加振ボックス充填試験の結果(加振前及び加振後の充填高さ)を示すグラフである。It is a graph which shows the result (filling height before vibration and after vibration) of the vibration box filling test in an Example. 実施例における自己収縮ひずみの測定結果を示すグラフである。It is a graph which shows the measurement result of the self-contraction strain in an Example.

以下の用語の定義は、本明細書及び特許請求の範囲にわたって適用される。
「コンクリート」は、フレッシュコンクリート及び硬化コンクリートを包含する。
「超高強度コンクリート」は、設計基準強度が100N/mm以上であるコンクリートを示す。
「水結合材比」は、フレッシュコンクリート中の結合材の総質量に対する水の質量の割合(質量%)を示す。
「結合材」は、コンクリート中で水和反応する材料であり、例えばセメント、シリカフューム、スラグ、フライアッシュ等である。
「鋼繊維の混入率」は、コンクリートから鋼繊維及び有機繊維を除いた残部の総容積に対する鋼繊維の容積の割合(容積%)を示す。
「有機繊維の混入率」は、コンクリートから鋼繊維及び有機繊維を除いた残部の総容積に対する有機繊維の容積の割合(容積%)を示す。
The following definitions of terms apply throughout the specification and claims.
"Concrete" includes fresh concrete and hardened concrete.
“Ultra-high-strength concrete” refers to concrete having a design standard strength of 100 N/mm 2 or more.
The “water binder ratio” indicates the ratio (mass %) of the mass of water to the total mass of the binder in fresh concrete.
The "binder" is a material that undergoes a hydration reaction in concrete, and is, for example, cement, silica fume, slag, fly ash or the like.
The “mixture ratio of steel fibers” indicates the ratio (volume %) of the volume of steel fibers to the total volume of the remainder of the concrete except steel fibers and organic fibers.
The “mixing rate of organic fibers” refers to the ratio (volume %) of the volume of organic fibers to the total volume of the remainder of the concrete except steel fibers and organic fibers.

(超高強度コンクリート)
本発明の超高強度コンクリート(以下、「本コンクリート」ともいう。)は、セメントと、シリカヒュームと、水と、粗骨材と、細骨材と、化学混和剤と、鋼繊維と、有機繊維とを含む。
(Ultra high strength concrete)
The ultra-high-strength concrete (hereinafter, also referred to as “main concrete”) of the present invention is cement, silica fume, water, coarse aggregate, fine aggregate, chemical admixture, steel fiber, organic material. Including fibers.

セメントとしては、水和熱が低い点で、中庸熱ポルトランドセメント、低熱ポルトランドセメントが好ましい。 As the cement, medium heat Portland cement and low heat Portland cement are preferable because of their low heat of hydration.

シリカヒュームとしては、コンクリート用として公知のシリカヒュームであってよい。
シリカヒュームの含有量は、セメントの質量に対して9〜20質量%が好ましい。シリカヒュームの含有量が前記範囲内であれば、本コンクリートの流動性及び間隙通過性がより優れる。
The silica fume may be a known silica fume for concrete.
The content of silica fume is preferably 9 to 20% by mass with respect to the mass of cement. When the content of silica fume is within the above range, the flowability and gap permeability of the present concrete are more excellent.

水の含有量は、水結合材比が25質量%以下となる量である。水結合材比は、15〜25質量%が好ましく、15〜20質量%がより好ましい。
水結合材比が25質量%以下であれば、100N/mmを超える圧縮強度を得やすい。水結合材比が15質量%以上である場合、鋼繊維の混入率が間隙通過性に与える影響が大きく、本発明の有用性が高い。
The water content is such that the water binder ratio is 25% by mass or less. The water binder ratio is preferably 15 to 25% by mass, more preferably 15 to 20% by mass.
When the water binder ratio is 25% by mass or less, it is easy to obtain a compressive strength exceeding 100 N/mm 2 . When the water binder ratio is 15% by mass or more, the mixing ratio of the steel fibers has a large effect on the gap passing property, and the utility of the present invention is high.

粗骨材としては、硬質砂岩砕石、安山岩砕石、流紋岩砕石等が挙げられる。
粗骨材の表乾密度は、例えば2.55〜2.7g/cmであってよい。
粗骨材の粗粒率は、例えば6〜6.6であってよい。
Examples of the coarse aggregate include crushed hard sandstone, crushed andesite, crushed rhyolite, and the like.
The surface dry density of the coarse aggregate may be, for example, 2.55 to 2.7 g/cm 3 .
The coarse grain ratio of the coarse aggregate may be, for example, 6 to 6.6.

粗骨材の最大寸法は、15mm以下である。粗骨材の最大寸法は、粗骨材の90質量%以上が通るふるいのうち最小寸法のふるいの呼び寸法で示される寸法である。粗骨材の最大寸法が15mm以下であれば、単位粗骨材かさ容積を0.3m/m以上にしても、間隙通過性を確保できる。
最大寸法が15mm以下の粗骨材としては、例えば、最大寸法が15mmの粗骨材、最大寸法が13mmの粗骨材等が市販されている。
The maximum size of the coarse aggregate is 15 mm or less. The maximum size of the coarse aggregate is the size indicated by the nominal size of the sieve having the smallest size among the sieves through which 90% by mass or more of the coarse aggregate passes. If the maximum size of the coarse aggregate is 15 mm or less, the gap passing property can be secured even if the unit coarse aggregate bulk volume is 0.3 m 3 /m 3 or more.
As the coarse aggregate having a maximum size of 15 mm or less, for example, a coarse aggregate having a maximum size of 15 mm and a coarse aggregate having a maximum size of 13 mm are commercially available.

粗骨材の含有量は、本コンクリートの単位粗骨材かさ容積が0.3〜0.4m/mとなる量である。単位粗骨材かさ容積は、0.33〜0.37m/mが好ましい。
単位粗骨材かさ容積が0.3m/m以上であれば、ひび割れ抵抗性が優れる。単位粗骨材かさ容積が0.4m/m以下であれば、間隙通過性が優れる。
The content of coarse aggregate is the amount of the unit coarse aggregate bulk volume of the concrete is 0.3~0.4m 3 / m 3. Unit coarse aggregate bulk volume is preferably 0.33~0.37m 3 / m 3.
If the unit coarse aggregate bulk volume is 0.3 m 3 /m 3 or more, the crack resistance is excellent. If the unit coarse aggregate bulk volume is 0.4 m 3 /m 3 or less, the gap passing property is excellent.

細骨材としては、砕砂、山砂、陸砂等が挙げられる。
細骨材の表乾密度は、例えば2.55〜2.7g/cmであってよい。
Examples of the fine aggregate include crushed sand, mountain sand, land sand and the like.
The surface dry density of the fine aggregate may be, for example, 2.55 to 2.7 g/cm 3 .

化学混和剤としては、公知のものを使用でき、高性能減水剤、高性能AE減水剤等が挙げられる。これらの化学混和剤はいずれか1種を単独で用いてもよく2種以上を組み合わせて用いてもよい。 Known chemical admixtures can be used, and examples thereof include a high-performance water reducing agent and a high-performance AE water reducing agent. Any one of these chemical admixtures may be used alone, or two or more thereof may be used in combination.

本コンクリートは、化学混和剤として少なくとも、高性能減水剤を含むことが好ましい。高性能減水剤としては、例えば主成分がポリカルボン酸エーテル系のもの、主成分がポリカリボン酸コポリマーのもの等が挙げられる。
高性能減水剤の含有量は、主成分の固形分率30%程度の場合、例えば、セメントの質量に対して1〜5質量%程度である。
The concrete preferably contains at least a high-performance water reducing agent as a chemical admixture. Examples of the high-performance water reducing agent include those whose main component is a polycarboxylic acid ether type and whose main component is a polycarboxylic acid copolymer.
When the solid content of the main component is about 30%, the content of the high-performance water reducing agent is, for example, about 1 to 5% by mass with respect to the mass of the cement.

鋼繊維を構成する鋼材としては、普通鋼材、ステンレス鋼等が挙げられ、耐アルカリ性を有するものが好ましい。
また、防錆の観点から、鋼材表面に亜鉛めっきを施したものが好ましい。
鋼繊維の形状としては、フック型、ストレート型、波型等が挙げられる。コンクリートと鋼繊維の付着向上、コンクリートの靭性向上の点では、フック型が好ましい。
鋼繊維としては、例えば、鋼繊維補強コンクリート用の鋼繊維として市販されているものを使用できる。
Examples of the steel material constituting the steel fiber include ordinary steel material and stainless steel, and those having alkali resistance are preferable.
Further, from the viewpoint of rust prevention, it is preferable that the surface of the steel material is galvanized.
Examples of the shape of the steel fiber include hook type, straight type and corrugated type. The hook type is preferable in terms of improving adhesion between concrete and steel fiber and improving toughness of concrete.
As the steel fiber, for example, a commercially available steel fiber for steel fiber reinforced concrete can be used.

鋼繊維の長さは、12〜32mmが好ましく、24〜32mmがより好ましい。鋼繊維の長さが前記範囲内であれば、コンクリートの間隙通過性及びひび割れ抵抗性がより優れる。鋼繊維の長さは、ノギス等により測定される。
鋼繊維の直径は、0.15〜0.9mmが好ましく、0.38〜0.75mmがより好ましい。鋼繊維の直径が前記範囲内であれば、コンクリートの間隙通過性及びひび割れ抵抗性がより優れる。鋼繊維の直径は、ノギス等により測定される。
The length of the steel fiber is preferably 12 to 32 mm, more preferably 24 to 32 mm. When the length of the steel fiber is within the above range, the concrete has more excellent gap permeability and crack resistance. The length of the steel fiber is measured with a caliper or the like.
The diameter of the steel fiber is preferably 0.15 to 0.9 mm, more preferably 0.38 to 0.75 mm. When the diameter of the steel fiber is within the above range, the concrete has more excellent gap permeability and crack resistance. The diameter of the steel fiber is measured with a caliper or the like.

本コンクリートにおいて、鋼繊維の混入率は、0.5容積%超2容積%以下が好ましく、0.7〜1.2容積%がより好ましい。鋼繊維の混入率が0.5容積%超であれば、本コンクリートの靭性及びひび割れ抵抗性が優れる。鋼繊維の混入率が2容積%以下であれば、充分な間隙通過性を確保できる。 In this concrete, the mixing ratio of steel fibers is preferably more than 0.5% by volume and 2% by volume or less, and more preferably 0.7 to 1.2% by volume. When the mixing ratio of the steel fibers is more than 0.5% by volume, the concrete has excellent toughness and crack resistance. If the mixing ratio of the steel fibers is 2% by volume or less, sufficient gap passage property can be secured.

有機繊維は、ポリプロピレン繊維を含む。ポリプロピレン繊維は、他の有機繊維に比べて安価であり、経済性に優れる。
ポリプロピレン繊維は、ポリプロピレンを含む繊維である。
ポリプロピレンとしては、プロピレンのホモポリマー、プロピレンと他のモノマーとのコポリマー等が挙げられる。他のモノマーとしては、プロピレン以外のオレフィン(エチレン等)等が挙げられる。
Organic fibers include polypropylene fibers. Polypropylene fiber is cheaper than other organic fibers and is excellent in economic efficiency.
Polypropylene fibers are fibers that include polypropylene.
Examples of polypropylene include homopolymers of propylene and copolymers of propylene and other monomers. Examples of the other monomer include olefins other than propylene (ethylene and the like).

ポリプロピレン繊維は、ポリプロピレンのみから成るものでもよく、ポリプロピレンと他の樹脂とを含む繊維でもよい。
他の樹脂としては、例えば、ポリプロピレン以外のポリオレフィン樹脂(ポリエチレン等)、ポリビニルアルコール樹脂等が挙げられる。
ポリプロピレン繊維中のポリプロピレンの割合は、ポリプロピレン繊維の総質量に対し、45質量%以上が好ましい。
The polypropylene fiber may be made of only polypropylene, or may be a fiber containing polypropylene and another resin.
Examples of other resins include polyolefin resins (polyethylene, etc.) other than polypropylene, polyvinyl alcohol resins, and the like.
The proportion of polypropylene in the polypropylene fibers is preferably 45% by mass or more based on the total mass of the polypropylene fibers.

ポリプロピレン繊維の乾燥密度は、0.91g/cmが好ましい。乾燥密度が0.91であれば、コンクリート中の繊維の分散性がより優れる。乾燥密度はJIS L 1015により測定される。 The dry density of the polypropylene fiber is preferably 0.91 g/cm 3 . When the dry density is 0.91, the dispersibility of fibers in concrete is more excellent. The dry density is measured according to JIS L1015.

ポリプロピレン繊維の長さは、9〜11mmが好ましく、9.5〜10.5mmがより好ましい。ポリプロピレン繊維の長さが前記範囲内であれば、間隙通過性、コンクリート中の繊維の分散性がより優れる。ポリプロピレン繊維の長さは、JIS L 1015により測定される。
ポリプロピレン繊維の水分率は、20〜40%が好ましく、30〜40%がより好ましい。ポリプロピレン繊維の水分率が前記範囲内であれば、コンクリート中の繊維の分散性がより優れる。ポリプロピレン繊維の水分率は、JIS L 1015により測定される。
The length of the polypropylene fiber is preferably 9 to 11 mm, more preferably 9.5 to 10.5 mm. When the length of the polypropylene fiber is within the above range, the gap passing property and the dispersibility of the fiber in the concrete are more excellent. The length of polypropylene fiber is measured according to JIS L1015.
20-40% is preferable and, as for the water content of polypropylene fiber, 30-40% is more preferable. When the water content of the polypropylene fiber is within the above range, the dispersibility of the fiber in the concrete is more excellent. The water content of polypropylene fiber is measured according to JIS L1015.

ポリプロピレン繊維の断面形状は、円形、異形及び中空等のいずれであってもよい。
ポリプロピレン繊維が他の樹脂を含む場合、ポリプロピレン繊維は、ポリプロピレンと他の樹脂との混合樹脂からなる繊維でもよく、ポリプロピレンからなる層と他の樹脂からなる層とを有する複合繊維であってもよい。複合繊維の形態としては、並列型、芯鞘型、分割型等が挙げられる。
ポリプロピレン繊維は、例えば、特許第3889946号公報に記載の方法により製造できる。
The cross-sectional shape of the polypropylene fiber may be circular, irregular, hollow or the like.
When the polypropylene fiber contains another resin, the polypropylene fiber may be a fiber made of a mixed resin of polypropylene and another resin, or may be a composite fiber having a layer made of polypropylene and a layer made of another resin. .. Examples of the form of the composite fiber include a parallel type, a core-sheath type, and a split type.
The polypropylene fiber can be produced, for example, by the method described in Japanese Patent No. 3889946.

鋼繊維とポリプロピレン繊維との容積比(鋼繊維/ポリプロピレン繊維)は、0.9〜14.3が好ましく、1.6〜4.1がより好ましい。鋼繊維とポリプロピレン繊維との容積比が前記範囲内であれば、コンクリートの耐爆裂性、靭性、ひび割れ抵抗性がより優れる。 The volume ratio of steel fiber and polypropylene fiber (steel fiber/polypropylene fiber) is preferably 0.9 to 14.3, more preferably 1.6 to 4.1. When the volume ratio of the steel fiber and the polypropylene fiber is within the above range, the concrete has more excellent explosion resistance, toughness, and crack resistance.

本コンクリートにおいて、有機繊維の混入率は、0.14〜0.58容積%が好ましく、0.29〜0.44容積%がより好ましい。有機繊維の混入率が0.14容積%以上であれば、耐爆裂性が優れる。有機繊維の混入率が0.58容積%以下であれば、充分な間隙通過性を確保しやすい。 In the present concrete, the mixing ratio of the organic fibers is preferably 0.14 to 0.58% by volume, more preferably 0.29 to 0.44% by volume. When the mixing ratio of the organic fibers is 0.14% by volume or more, the explosion resistance is excellent. When the mixing ratio of the organic fibers is 0.58% by volume or less, it is easy to secure sufficient gap passing property.

本コンクリートは、所定の水結合材比、鋼繊維の混入率、単位粗骨材かさ容積等を満たすように、セメントと、シリカヒュームと、水と、粗骨材と、細骨材と、化学混和剤と、鋼繊維と、有機繊維と、必要に応じて他の成分と、を配合することにより調合できる。 This concrete has cement, silica fume, water, coarse aggregate, fine aggregate, and chemical so that the prescribed water-bonding agent ratio, steel fiber mixing ratio, unit coarse aggregate bulk volume, etc. are satisfied. It can be prepared by mixing the admixture, the steel fiber, the organic fiber and, if necessary, other components.

以上説明した本コンクリートにあっては、粗骨材の最大寸法が15mm以下であり、単位粗骨材かさ容積が0.3〜0.4m/mであるため、水結合材比が25質量%以下と低く、鋼繊維の混入率が0.5容積%超2容積%以下と高いながらも、間隙通過性及びひび割れ抵抗性に優れる。
これは以下の理由によると考えられる。
最大寸法が15mm以下である粗骨材は、最大寸法が15mm超、例えば20mmの粗骨材に比べて、コンクリートの収縮抑制効果に優れる。そのため、ひび割れ抵抗性を充分に確保しつつ、単位粗骨材かさ容積を0.3〜0.4m/mと少なくして、本コンクリートから鋼繊維を除いた残部の流動性が高めることができる。なお、一般的な超高強度コンクリートの単位粗骨材かさ容積は0.5〜0.56m/m程度である。
本コンクリートから鋼繊維を除いた残部の流動性が高いため、鋼繊維を多く含みながらも充分な流動性を確保できる。
また、本コンクリートにあっては、水結合材比が25質量%以下と低く、鋼繊維の混入率が0.5容積%超2容積%以下と高いため、優れた強度(例えば、JIS A 1108に従って測定される、材齢28日(4週)または、材齢56日(8週)における圧縮強度として110〜180N/mm)が得られる。また、有機繊維としてポリプロプレン繊維を含むため、耐爆裂性を有し、経済性にも優れる。
In the present concrete described above, the maximum size of coarse aggregate is at 15mm or less, because the unit coarse aggregate bulk volume is 0.3~0.4m 3 / m 3, water binder ratio is 25 Although it is as low as mass% or less and the mixing ratio of steel fibers is as high as more than 0.5% by volume and 2% by volume or less, it has excellent gap passing property and crack resistance.
This is considered to be due to the following reasons.
Coarse aggregate having a maximum size of 15 mm or less is more effective in suppressing shrinkage of concrete than coarse aggregate having a maximum size of more than 15 mm, for example, 20 mm. Therefore, while sufficiently ensuring the cracking resistance, the unit coarse aggregate bulk volume with less with 0.3~0.4m 3 / m 3, the fluidity of the remainder from the concrete without the steel fibers increased You can The unit coarse aggregate bulk volume of a typical ultra-high strength concrete is about 0.5~0.56m 3 / m 3.
Since the remainder of this concrete excluding steel fibers has high fluidity, sufficient fluidity can be ensured even though it contains a large amount of steel fibers.
Further, in the present concrete, the water binder ratio is as low as 25% by mass or less, and the mixing ratio of the steel fibers is as high as more than 0.5% by volume and 2% by volume or less, so that it has excellent strength (for example, JIS A 1108). The compressive strength at 28 days old (4 weeks) or 56 days old (8 weeks), which is measured according to the above method, is 110 to 180 N/mm 2 . Further, since it contains polypropylene fiber as the organic fiber, it has blast resistance and is excellent in economic efficiency.

(超高強度コンクリートの調合方法)
本発明の超高強度コンクリートの調合方法は、セメントと、シリカヒュームと、水と、粗骨材と、細骨材と、化学混和剤と、鋼繊維と、有機繊維とを配合し、水結合材比が25質量%以下、前記鋼繊維の混入率が0.5容積%超2容積%以下である超高強度コンクリートを調合する方法である。
セメント、シリカヒューム、粗骨材、細骨材、化学混和剤、鋼繊維、有機繊維とともに、他の成分を配合してもよい。
セメント、シリカヒューム、粗骨材、細骨材、化学混和剤、鋼繊維、有機繊維、他の成分はそれぞれ前記と同様である。
(Mixing method of ultra high strength concrete)
The super high-strength concrete compounding method of the present invention comprises cement, silica fume, water, coarse aggregate, fine aggregate, chemical admixture, steel fiber, organic fiber, and water bond. It is a method of mixing ultra high strength concrete having a material ratio of 25% by mass or less and a mixing ratio of the steel fibers of more than 0.5% by volume and 2% by volume or less.
Other components may be blended with the cement, silica fume, coarse aggregate, fine aggregate, chemical admixture, steel fiber and organic fiber.
Cement, silica fume, coarse aggregate, fine aggregate, chemical admixture, steel fiber, organic fiber, and other components are the same as described above.

また、本発明の調合方法では、下記式(1)により前記超高強度コンクリートの単位粗骨材かさ容積の目標値V’bGを算出し、前記目標値V’bGとなるように前記粗骨材の配合量を設定する。 Further, in the compounding method of the present invention, the target value V′ bG of the unit coarse aggregate bulk volume of the ultra-high strength concrete is calculated by the following formula (1), and the coarse bone is adjusted to the target value V′ bG. Set the compounding amount of the material.

V’bG=VbG−(K・2r/3r−1)・V/G (1)
ここで、V’bGは、前記超高強度コンクリートの単位粗骨材かさ容積の目標値(m/m)を示し、
bGは、超高強度コンクリートの単位粗骨材かさ容積(m/m)の標準値の範囲であって0.5〜0.56(m/m)の数を示し、
は、影響係数であって0.8〜1の数を示し、
は、前記粗骨材を球形と仮定し、前記粗骨材の粒度分布から得られる総粗骨材表面積から算出した前記粗骨材の半径(mm)を示し、
は、前記鋼繊維を円柱形と仮定して算出した前記鋼繊維の半径(mm)を示し、
は、前記鋼繊維の混入率(容積%)を示し、
は、前記粗骨材の実積率(容積%)を示す。
粗骨材の実積率はJIS A 1104により測定される。
V 'bG = V bG - ( K S · 2r G / 3r F -1) · V F / G S (1)
Here, V′ bG represents a target value (m 3 /m 3 ) of the unit coarse aggregate bulk volume of the ultra-high strength concrete,
V bG is a standard value range of the unit coarse aggregate bulk volume (m 3 /m 3 ) of ultra-high strength concrete and represents a number of 0.5 to 0.56 (m 3 /m 3 ),
K S is an influence coefficient and represents a number of 0.8 to 1,
r G represents the radius (mm) of the coarse aggregate calculated from the total coarse aggregate surface area obtained from the particle size distribution of the coarse aggregate, assuming that the coarse aggregate is spherical,
r F represents the radius (mm) of the steel fiber calculated assuming that the steel fiber has a cylindrical shape,
V F represents the mixing ratio (volume %) of the steel fiber,
G S represents the actual volume ratio (volume %) of the coarse aggregate.
The actual volume fraction of coarse aggregate is measured according to JIS A 1104.

影響係数Kが0.8以上であれば、得られる超高強度コンクリートの間隙通過性が優れる。影響係数Kが1未満であれば、得られる超高強度コンクリートのひび割れ抵抗性が優れる。影響係数Kは、0.9が好ましい。 When the influence coefficient K S is 0.8 or more, the resulting ultrahigh-strength concrete has excellent gap permeability. When the influence coefficient K S is less than 1, the resulting ultra-high strength concrete has excellent crack resistance. The influence coefficient K S is preferably 0.9.

設計基準強度が100N/mm未満の一般的な高流動鋼繊維補強コンクリートに用いられる粗骨材の最大寸法は20mmであり、このような高流動鋼繊維補強コンクリートを対象とした等価表面積置換による調合設計手法において、影響係数Kは1〜1.35程度である。
本発明者らは、粗骨材の最大寸法を15mm以下とした場合、一般的な高流動鋼繊維補強コンクリートに比べて、間隙通過性を確保するために必要な単位粗骨材かさ容積が小さいことを見出し、影響係数Kを0.8以上1未満に設定した。
The maximum size of coarse aggregate used for general high-flow steel fiber reinforced concrete having a design standard strength of less than 100 N/mm 2 is 20 mm. In the blending design method, the influence coefficient K S is about 1 to 1.35.
When the maximum size of the coarse aggregate is set to 15 mm or less, the present inventors have a smaller unit coarse aggregate bulk volume required to secure the gap passing property, as compared with general high flow steel fiber reinforced concrete. Therefore, the influence coefficient K S is set to 0.8 or more and less than 1.

水結合材比、鋼繊維の混入率の好ましい範囲は前記と同様である。
シリカヒューム、細骨材、化学混和剤、有機繊維等の好ましい配合量は、本コンクリートと同様である。
The preferable ranges of the water binder ratio and the mixing ratio of the steel fibers are the same as above.
The preferred blending amount of silica fume, fine aggregate, chemical admixture, organic fiber and the like is the same as that of the present concrete.

以上説明した本発明の調合方法にあっては、粗骨材の最大寸法を15mm以下とし、前記式(1)により算出した目標値V’bGとなるように粗骨材の配合量を設定するため、水結合材比が25質量%以下と低く、鋼繊維の混入率が0.5容積%超2容積%以下と高いながらも、間隙通過性及びひび割れ抵抗性に優れた超高強度コンクリートを調合できる。
また、得られる超高強度コンクリートは、水結合材比が25質量%以下と低く、鋼繊維の混入率が0.5容積%超2容積%以下と高いため、圧縮強度に優れる。また、有機繊維としてポリプロプレン繊維を含むため、耐爆裂性を有し、経済性にも優れる。
In the blending method of the present invention described above, the maximum size of the coarse aggregate is set to 15 mm or less, and the blending amount of the coarse aggregate is set so as to be the target value V′ bG calculated by the formula (1). Therefore, while the water binder ratio is as low as 25% by mass or less and the mixing ratio of steel fibers is as high as more than 0.5% by volume and 2% by volume or less, it is possible to obtain an ultra high strength concrete excellent in gap passing property and crack resistance. Can be mixed.
Further, the obtained ultra-high-strength concrete has a low water binder ratio of 25% by mass or less and a high mixing ratio of steel fibers of more than 0.5% by volume and 2% by volume or less, and therefore has excellent compressive strength. Further, since it contains polypropylene fiber as the organic fiber, it has blast resistance and is excellent in economic efficiency.

以下、実施例によって本発明を詳細に説明するが、本発明はこれらに限定されない。 Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited thereto.

(使用材料)
実施例での使用材料を表1に示す。
(Material used)
Table 1 shows materials used in the examples.

Figure 2020090410
Figure 2020090410

(調合1〜7)
<超高強度コンクリートの調合>
表2に従い、各材料を以下の手順で練混ぜて超高強度コンクリートを調合した。
W/Cは、設計基準強度100N/mm以上を想定して設定した。W/Cは、シリカフュームプレミックスセメント(C)に対する水(W)の質量割合であり、水結合材比に相当する。鋼繊維の混入量40kg/m及び80kg/mはそれぞれ、鋼繊維の混入率0.5容量%及び1容量%に相当する。有機繊維(ポリアセタール繊維)の混入量3.1kg/m及び3.9kg/mはそれぞれ、有機繊維の混入率0.2容量%及び0.3容量%に相当する。
練混ぜは、強制二軸練りミキサを用いた。シリカフュームプレミックスセメント(C)及び細骨材(S)を投入し、空練りした後、水(W)及び化学混和剤(SP)を投入及び混練し、モルタルとした。次いで、粗骨材(G)を投入及び混練し、コンクリートとした。さらに、ポリアセタール繊維(PA)及び鋼繊維(SF)を投入し、90秒間混練して鋼繊維入り超高強度コンクリートとした。
(Preparation 1-7)
<Mixing of ultra high strength concrete>
According to Table 2, each material was kneaded according to the following procedure to prepare ultra-high strength concrete.
W/C was set assuming a design standard strength of 100 N/mm 2 or more. W/C is a mass ratio of water (W) to silica fume premix cement (C), and corresponds to a water binder ratio. The steel fiber mixing rates of 40 kg/m 3 and 80 kg/m 3 correspond to the steel fiber mixing rates of 0.5% by volume and 1% by volume, respectively. The mixing amounts of the organic fibers (polyacetal fibers) of 3.1 kg/m 3 and 3.9 kg/m 3 correspond to the mixing ratios of the organic fibers of 0.2% by volume and 0.3% by volume, respectively.
A forced biaxial kneading mixer was used for kneading. After adding silica fume premix cement (C) and fine aggregate (S) and kneading, water (W) and chemical admixture (SP) were added and kneaded to obtain a mortar. Then, the coarse aggregate (G) was added and kneaded to obtain concrete. Further, polyacetal fiber (PA) and steel fiber (SF) were added and kneaded for 90 seconds to obtain an ultra high strength concrete containing steel fiber.

Figure 2020090410
Figure 2020090410

<評価>
調合した鋼繊維入り超高強度コンクリートについて、スランプフロー、フロー流動時間、空気量、コンクリート温度、単位容積質量、ボックス形容器への充填時間・高さ及び加振充填時間・高さ、並びに圧縮強度を測定した。また、調合1から鋼繊維を抜いたもの(鋼繊維混入率0容積%)、調合1(鋼繊維混入率0.5容積%)、調合5から鋼繊維を除いたもの(鋼繊維混入率0容積%)、調合5(鋼繊維混入率1容積%)、及び調合6から鋼繊維を除いたもの(鋼繊維混入率0容積%)について、自己収縮ひずみを測定した。
スランプフローとフロー流動時間はJIS A 1150、空気量はJIS A 1128、コンクリート温度はJIS A 1156、単位容積質量はJIS A 1116、圧縮強度はJIS A 1108に従って測定した。
充填時間・高さ、及び加振充填時間・高さは、土木学会規準(JSCE−F511−2012、JSCE−F701−2016)に準拠した加振ボックス充填試験方法により測定した。
自己収縮ひずみは、日本コンクリート工学協会:超流動コンクリート研究委員会報告書(II)、pp.209−210、1994.5の[付録1](仮称)高流動コンクリートの自己収縮試験方法に準拠し、東京測器研究所製の埋込み型ひずみ計KM−100BTを10×10×40cm供試体の中心部に設置して測定し、材齢7日の値で評価した。
<Evaluation>
Slump flow, flow flow time, air flow rate, concrete temperature, unit volume mass, box-shaped container filling time/height and vibrating filling time/height, and compressive strength for the super high-strength concrete containing steel fibers Was measured. In addition, steel fiber was removed from Preparation 1 (steel fiber mixing rate 0% by volume), Preparation 1 (steel fiber mixing rate 0.5% by volume), Preparation 5 from which steel fibers were removed (steel fiber mixing rate 0 (Volume %), Formulation 5 (steel fiber mixing ratio 1% by volume), and Compound 6 excluding steel fibers (steel fiber mixing ratio 0% by volume) were measured for self-shrinkage strain.
The slump flow and flow flow time were measured according to JIS A 1150, the air amount was JIS A 1128, the concrete temperature was JIS A 1156, the unit volume mass was JIS A 1116, and the compressive strength was measured according to JIS A 1108.
The filling time/height and the vibration filling time/height were measured by the vibration box filling test method based on the JSCE Standard (JSCE-F511-2012, JSCE-F701-2016).
The self-shrinkage strain is reported in Japan Concrete Institute: Superfluid Concrete Research Committee Report (II), pp. 209-210, 1994.5 [Appendix 1] (tentative name) In accordance with the self-shrinking test method for high-fluidity concrete, an embedded strain gauge KM-100BT manufactured by Tokyo Sokki Kenkyusho Co., Ltd. It was installed in the center, measured, and evaluated by the value of 7 days old material.

加振ボックス充填試験では、図1に示すようなボックス形容器1を用いる。ボックス形容器1の底面2は防振用ゴムマット、側壁3は透明アクリル板で構成される。ボックス形容器1の内部は仕切り4によってA室とB室とに区画されている。A室には棒状のバイブレータ5が配置される。バイブレータ5はJIS A 8610に適合する電動機外部駆動式の手持形振動機で、振動体の呼び径は28mm、長さは580mm以上、振動数は200Hz程度のものとする。仕切り4の下端にはゲートGが設けられており、ゲートGには流動障害6が設けられている。ゲートGは、仕切り4に沿って配置された仕切り板7を上下させることによって開閉可能となっている。図中の寸法を示す数値の単位はmmである。プレキャスト部材に埋設される機械式継手相互の最小あき寸法が40mmを下回ることがあるため、流動障害6は、障害R2(D13鉄筋×3本,35mm間隔)とした。
加振ボックス充填試験では、ゲートGを閉じた状態で、コンクリートをA室の上端まで入れ、バイブレータ5の先端をA室の下端から100mmの高さの位置に設置する。次いで、ゲートGを開き、バイブレータ5を振動させずに、A室からB室へとコンクリートを流入させ、B室に流入したコンクリートの下端から上端までの高さ(加振前の充填高さ)を測定する。次いで、バイブレータ5を振動させ、B室に流入したコンクリートの下端から上端までの高さ(加振後の充填高さ)を測定する。
In the vibration box filling test, a box-shaped container 1 as shown in FIG. 1 is used. The bottom 2 of the box-shaped container 1 is made of a rubber mat for vibration isolation, and the side wall 3 is made of a transparent acrylic plate. The inside of the box-shaped container 1 is divided into a chamber A and a chamber B by a partition 4. A rod-shaped vibrator 5 is arranged in the chamber A. The vibrator 5 is a hand-held vibrator externally driven by an electric motor, which conforms to JIS A 8610. The vibrator has a nominal diameter of 28 mm, a length of 580 mm or more, and a frequency of about 200 Hz. A gate G is provided at the lower end of the partition 4, and a flow obstacle 6 is provided at the gate G. The gate G can be opened and closed by vertically moving a partition plate 7 arranged along the partition 4. The unit of the numerical value indicating the dimension in the drawing is mm. Since the minimum distance between the mechanical joints embedded in the precast member may be less than 40 mm, the flow obstacle 6 is the obstacle R2 (D13 rebar×3, 35 mm interval).
In the vibration box filling test, with the gate G closed, concrete is put into the upper end of the chamber A, and the tip of the vibrator 5 is installed at a position 100 mm higher than the lower end of the chamber A. Next, the gate G is opened, concrete is flowed into the B chamber from the A chamber without vibrating the vibrator 5, and the height of the concrete flowing into the B chamber from the lower end to the upper end (filling height before vibration) To measure. Next, the vibrator 5 is vibrated, and the height from the lower end to the upper end of the concrete flowing into the chamber B (filling height after vibration) is measured.

スランプフロー、フロー流動時間、空気量、コンクリート温度、単位容積質量、充填時間・高さ、加振充填時間・高さ、及び圧縮強度の測定結果を表3に示す。また、充填高さ(加振前の充填高さ)及び加振充填高さ(加振後の充填高さ)を図2に示す。自己収縮ひずみの測定結果から、各調合の単位粗骨材かさ容積(m/m)を横軸に、自己収縮ひずみを縦軸にプロットしたグラフを図3に示す。
スランプフロー、空気量及び圧縮強度は所定の品質を満足した。なお、圧縮強度について、鋼繊維混入率1.0容量%の調合は、空気量が圧縮強度に及ぼす影響を考慮すると、鋼繊維混入率0.5容量%の調合と同程度であった。
Table 3 shows the measurement results of slump flow, flow flow time, air amount, concrete temperature, unit volume mass, filling time/height, vibration filling time/height, and compressive strength. FIG. 2 shows the filling height (filling height before vibration) and the vibration filling height (filling height after vibration). FIG. 3 shows a graph in which the unit coarse aggregate bulk volume (m 3 /m 3 ) of each blend is plotted on the horizontal axis and the self-shrinkage strain is plotted on the vertical axis from the measurement result of the self-shrinkage strain.
The slump flow, air content and compressive strength satisfied the specified quality. Regarding the compressive strength, the blending ratio of the steel fiber of 1.0% by volume was about the same as the blending ratio of the steel fiber of 0.5% by volume in consideration of the influence of the air amount on the compressive strength.

鋼繊維混入率1.0容量%の調合のうち、単位粗骨材かさ容積が0.45m/mである調合4は、加振ボックス充填試験で閉塞が生じた。これに対し、調合5〜7は、閉塞が生じず、加振充填高さは300mmに達しており、間隙通過性に優れていた。
調合5〜6と調合7との対比から、水結合材比が小さいほど、加振前の充填高さが高くなる(間隙通過性が高くなる)傾向にあることが確認できた。ベースコンクリートの粘性が間隙通過性に影響したと推察される。
鋼繊維混入率0.5容量%の調合1〜3においては、間隙通過性の問題は見られなかった。しかし、鋼繊維混入率が低いため、調合5〜7に比べて、コンクリートの靭性に劣る。
図3中、鋼繊維混入率0容積%の調合の対比から、単位粗骨材かさ容積が小さくなると、自己収縮ひずみが大きくなることがわかる。また、調合1から鋼繊維を抜いたもの、調合1、調合5の対比から、鋼繊維の混入率を高くすることで、単位粗骨材かさ容積を小さくしても、単位粗骨材かさ容積が大きい場合と同程度に自己収縮ひずみを抑制できることがわかる。
Among the formulations having a steel fiber mixing ratio of 1.0% by volume, the formulation 4 having a unit coarse aggregate bulk volume of 0.45 m 3 /m 3 caused blockage in the vibration box filling test. On the other hand, in Formulations 5 to 7, no blockage occurred, the vibration filling height reached 300 mm, and the gap passing property was excellent.
From the comparison of the preparations 5 to 6 and the preparation 7, it was confirmed that the smaller the water binder ratio, the higher the filling height before vibration (the higher the gap passing property). It is speculated that the viscosity of the base concrete affected the gap permeability.
In Formulations 1 to 3 in which the mixing ratio of steel fiber was 0.5% by volume, the problem of gap passing property was not found. However, since the mixing ratio of steel fibers is low, the toughness of concrete is inferior as compared with Mixtures 5-7.
In FIG. 3, it can be seen from the comparison of the mixing ratio that the mixing ratio of the steel fibers is 0% by volume, as the unit coarse aggregate bulk volume decreases, the self-shrinkage strain increases. Moreover, even if the unit coarse aggregate bulk volume is made small by increasing the mixing ratio of the steel fibers from the comparison between the mixture 1 obtained by removing the steel fiber and the mixture 1 and 5, even if the unit coarse aggregate bulk volume is reduced, It can be seen that the self-shrinkage strain can be suppressed to the same extent as when the value is large.

Figure 2020090410
Figure 2020090410

なお、鋼繊維の混入率Vが1(容積%)、鋼繊維入り超高強度コンクリートの単位粗骨材かさ容積V’bGが0.4(m/m)である調合において、前記式(1)における各値は、VbGが0.5、rが4.24、rが0.31、Vが0.0102、Gが0.6であり、Kは0.9となった。 It should be noted that, in a mixture having a steel fiber mixing ratio V F of 1 (volume %) and a unit coarse aggregate bulk volume V′ bG of steel fiber-containing ultra-high strength concrete being 0.4 (m 3 /m 3 ), Each value in the formula (1) is 0.5 for V bG , 4.24 for r G , 0.31 for r F , 0.0102 for V F , and 0.6 for G S , and K S is 0. Became 9.

なお、本発明者らの検討によれば、有機繊維の種類は、間隙通過性及びひび割れ抵抗性には影響しないか、影響してもわずかである。調合1〜7では有機繊維としてポリアセタール繊維を使用したが、ポリアセタール繊維をポリプロピレン繊維に置き換えた場合でも、同様の結果が得られることを確認している。 According to the study by the present inventors, the type of the organic fiber has no effect on the gap passing property and the crack resistance, or has a slight effect. Although Polyacetal fibers were used as the organic fibers in Formulations 1 to 7, it has been confirmed that similar results can be obtained even when the polyacetal fibers are replaced with polypropylene fibers.

Claims (6)

セメントと、シリカヒュームと、水と、粗骨材と、細骨材と、化学混和剤と、鋼繊維と、有機繊維とを含み、水結合材比が25質量%以下、前記鋼繊維の混入率が0.50容積%超2容積%以下である超高強度コンクリートであって、
前記有機繊維がポリプロピレン繊維を含み、
前記粗骨材の最大寸法が15mm以下であり、
単位粗骨材かさ容積が0.3〜0.4m/mである、超高強度コンクリート。
Cement, silica fume, water, coarse aggregate, fine aggregate, chemical admixture, steel fiber, organic fiber, water binder ratio 25 mass% or less, mixing of the steel fiber A super high strength concrete having a ratio of more than 0.50% by volume and 2% by volume or less,
The organic fibers include polypropylene fibers,
The maximum size of the coarse aggregate is 15 mm or less,
Unit coarse aggregate bulk volume is 0.3~0.4m 3 / m 3, ultra-high strength concrete.
前記有機繊維の混入率が0.14〜0.58容積%である請求項1に記載の超高強度コンクリート。 The ultra high strength concrete according to claim 1, wherein the mixing ratio of the organic fibers is 0.14 to 0.58% by volume. 前記鋼繊維の直径が0.15〜0.9mm、長さが12〜32mmである請求項1又は2に記載の超高強度コンクリート。 The ultra high strength concrete according to claim 1 or 2, wherein the steel fiber has a diameter of 0.15 to 0.9 mm and a length of 12 to 32 mm. セメントと、シリカヒュームと、水と、粗骨材と、細骨材と、化学混和剤と、鋼繊維と、有機繊維とを配合し、水結合材比が25質量%以下、前記鋼繊維の混入率が0.5容積%超2容積%以下である超高強度コンクリートを調合する方法であって、
前記有機繊維として少なくともポリプロピレン繊維を用い、
前記粗骨材の最大寸法を15mm以下とし、
下記式(1)により前記超高強度コンクリートの単位粗骨材かさ容積の目標値V’bGを算出し、前記目標値V’bGとなるように前記粗骨材の配合量を設定する、超高強度コンクリートの調合方法。
V’bG=VbG−(K・2r/3r−1)・V/G (1)
ここで、V’bGは、前記超高強度コンクリートの単位粗骨材かさ容積の目標値(m/m)を示し、
bGは、超高強度コンクリートの単位粗骨材かさ容積(m/m)の標準値の範囲であって0.5〜0.56(m/m)の数を示し、
は、影響係数であって0.8〜1の数を示し、
は、前記粗骨材を球形と仮定し、前記粗骨材の粒度分布から得られる総粗骨材表面積から算出した前記粗骨材の半径(mm)を示し、
は、前記鋼繊維を円柱形と仮定して算出した前記鋼繊維の半径(mm)を示し、
は、前記鋼繊維の混入率(容積%)を示し、
は、前記粗骨材の実積率(容積%)を示す。
Cement, silica fume, water, coarse aggregate, fine aggregate, chemical admixture, steel fiber, and organic fiber are mixed, and the water binder ratio is 25% by mass or less, A method for mixing ultra high strength concrete having a mixing ratio of more than 0.5% by volume and 2% by volume or less,
Using at least polypropylene fiber as the organic fiber,
The maximum size of the coarse aggregate is 15 mm or less,
The target value V'bG of the unit coarse aggregate bulk volume of the ultra-high strength concrete is calculated by the following formula (1), and the blending amount of the coarse aggregate is set to be the target value V'bG. Mixing method for high strength concrete.
V 'bG = V bG - ( K S · 2r G / 3r F -1) · V F / G S (1)
Here, V′ bG represents a target value (m 3 /m 3 ) of the unit coarse aggregate bulk volume of the ultra-high strength concrete,
V bG is a standard value range of the unit coarse aggregate bulk volume (m 3 /m 3 ) of ultra-high strength concrete and represents a number of 0.5 to 0.56 (m 3 /m 3 ),
K S is an influence coefficient and represents a number of 0.8 to 1,
r G represents the radius (mm) of the coarse aggregate calculated from the total coarse aggregate surface area obtained from the particle size distribution of the coarse aggregate, assuming that the coarse aggregate is spherical,
r F represents the radius (mm) of the steel fiber calculated assuming that the steel fiber has a cylindrical shape,
V F represents the mixing ratio (volume %) of the steel fiber,
G S represents the actual volume ratio (volume %) of the coarse aggregate.
前記有機繊維の混入率が0.14〜0.58容積%である請求項4に記載の超高強度コンクリートの調合方法。 The method for mixing ultra-high strength concrete according to claim 4, wherein the mixing ratio of the organic fibers is 0.14 to 0.58% by volume. 前記鋼繊維の直径が0.15〜0.9mm、長さが12〜32mmである請求項4又は5に記載の超高強度コンクリートの調合方法。 The method for mixing ultra-high strength concrete according to claim 4 or 5, wherein the steel fiber has a diameter of 0.15 to 0.9 mm and a length of 12 to 32 mm.
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