JP2019526668A - 低ナトリウム樹脂 - Google Patents
低ナトリウム樹脂 Download PDFInfo
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- JP2019526668A JP2019526668A JP2019511399A JP2019511399A JP2019526668A JP 2019526668 A JP2019526668 A JP 2019526668A JP 2019511399 A JP2019511399 A JP 2019511399A JP 2019511399 A JP2019511399 A JP 2019511399A JP 2019526668 A JP2019526668 A JP 2019526668A
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- Prior art keywords
- resin beads
- resin
- weight
- sodium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
- B01J49/57—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for anionic exchangers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2287—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/16—Organic material
- B01J39/18—Macromolecular compounds
- B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
- B01J41/05—Processes using organic exchangers in the strongly basic form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
- B01J49/07—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds containing anionic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
- B01J49/09—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds of mixed beds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Developing Agents For Electrophotography (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
ここで、樹脂ビーズは、第四級アンモニウム基を有する1つ以上のビニルポリマーを含み、
カチオン交換樹脂が、樹脂ビーズの集合体中に存在する場合、樹脂ビーズの集合体の重量に基づいて、0〜0.5重量%の量で存在し、
第四級アンモニウム基の90モル%以上が各々、水酸化物アニオンと会合し、
ナトリウムが存在する場合、樹脂ビーズの集合体の重量に基づいて、0〜100重量ppbの量で存在する。
(a)ナトリウム含有樹脂ビーズの集合体であって、
樹脂ビーズは、第四級アンモニウム基を有する1つ以上のビニルポリマーを含み、
カチオン交換樹脂は、樹脂ビーズの集合体中に存在する場合、樹脂ビーズの集合体の重量に基づいて、0〜0.5重量%の量で存在し、
第四級アンモニウム基の90モル%以上が各々、水酸化物アニオンと会合し、
ナトリウムは、ナトリウム含有樹脂ビーズの集合体の重量に基づいて、500重量ppbを超える量で存在する、ナトリウム含有樹脂ビーズの集合体を提供するステップと、
(b)ナトリウム含有樹脂ビーズの集合体を水性水酸化アンモニウムと接触させて混合物(b)を形成するステップと、を含む。
Claims (3)
- 樹脂ビーズの集合体であって、
前記樹脂ビーズが、第四級アンモニウム基を有する1つ以上のビニルポリマーを含み、
カチオン交換樹脂が、前記樹脂ビーズの集合体に存在する場合、前記樹脂ビーズの集合体の重量に基づき、0〜0.5重量%の量で存在し、
前記第四級アンモニウム基の90モル%以上が各々、水酸化物アニオンと会合し、
ナトリウムが、存在する場合、前記樹脂ビーズの集合体の重量に基づき、0〜100重量ppbの量で存在する、樹脂ビーズの集合体。 - 前記ビニルポリマーが、スチレンおよびジビニルベンゼンを含むモノマーを重合して、予備コポリマーを形成し、続いて、前記予備コポリマーを1回以上の化学反応に供して、第四級アンモニウム基を前記予備コポリマーに結合させることを含むプロセスによって作製されている、ビニル芳香族ポリマーである、請求項1に記載の樹脂ビーズの集合体。
- 前記ビニルポリマーが、1つ以上のアクリルモノマーを含むモノマーを重合して、予備コポリマーを形成し、続いて、前記予備コポリマーを1回以上の化学反応に供して、第四級アンモニウム基を前記予備コポリマーに結合させることを含むプロセスによって作製されている、アクリルポリマーである、請求項1に記載の樹脂ビーズの集合体。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201662381203P | 2016-08-30 | 2016-08-30 | |
US62/381,203 | 2016-08-30 | ||
US201762460954P | 2017-02-20 | 2017-02-20 | |
US62/460,954 | 2017-02-20 | ||
PCT/US2017/048544 WO2018044703A1 (en) | 2016-08-30 | 2017-08-25 | Low-sodium resin |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2019526668A true JP2019526668A (ja) | 2019-09-19 |
Family
ID=59930754
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2019511399A Pending JP2019526668A (ja) | 2016-08-30 | 2017-08-25 | 低ナトリウム樹脂 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20210277161A1 (ja) |
EP (1) | EP3507013A1 (ja) |
JP (1) | JP2019526668A (ja) |
KR (1) | KR20190046873A (ja) |
CN (1) | CN109661269A (ja) |
RU (1) | RU2019107043A (ja) |
WO (1) | WO2018044703A1 (ja) |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2669713A (en) * | 1950-10-27 | 1954-02-16 | Dow Chemical Co | Method of regenerating anion exchange resins |
US2697080A (en) * | 1951-12-05 | 1954-12-14 | Koppers Co Inc | Ion-exchange resins containing quaternary ammonium hydroxide groups |
US2697079A (en) * | 1951-12-05 | 1954-12-14 | Koppers Co Inc | Ion-exchange resins containing quaternary ammonium hydroxide groups |
JPS58177140A (ja) * | 1982-04-12 | 1983-10-17 | Showa Denko Kk | 液体クロマトグラフイ−用多孔質充填剤及びその製造方法 |
JP2000501201A (ja) * | 1995-11-27 | 2000-02-02 | クラリアント・インターナショナル・リミテッド | キレート形成性イオン交換樹脂によってフォトレジスト組成物中の金属イオンを低減させる方法 |
JP2001506375A (ja) * | 1996-12-17 | 2001-05-15 | クラリアント・インターナショナル・リミテッド | 有機極性溶媒を含有するフォトレジスト組成物中の混入金属イオンをイオン交換により低減する方法 |
WO2010018810A1 (ja) * | 2008-08-12 | 2010-02-18 | 和光純薬工業株式会社 | 前処理カラムの充填剤用ポリマー |
JP2010042395A (ja) * | 2008-03-05 | 2010-02-25 | Mitsubishi Chemicals Corp | アニオン交換樹脂、マクロポーラス型アニオン交換樹脂の製造方法、脱塩装置、発電所用復水脱塩装置、および懸濁性金属腐蝕生成物の除去方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2591573A (en) * | 1947-07-05 | 1952-04-01 | Rohm & Haas | Resinous insoluble reaction products of tertiary amines with haloalkylated vinyl aromatic hydrocarbon copolymers |
US3385787A (en) | 1967-04-03 | 1968-05-28 | Crane Co | Condensate purification process |
US4025467A (en) | 1975-06-13 | 1977-05-24 | Rohm And Haas Company | Strong anion exchange resins free of active chloride and method of preparation |
US20080035564A1 (en) * | 2006-08-09 | 2008-02-14 | Solmetex, Inc. | Sorbent For Selective Removal Of Contaminants From Fluids |
-
2017
- 2017-08-25 EP EP17771913.5A patent/EP3507013A1/en not_active Withdrawn
- 2017-08-25 CN CN201780052306.3A patent/CN109661269A/zh active Pending
- 2017-08-25 RU RU2019107043A patent/RU2019107043A/ru unknown
- 2017-08-25 WO PCT/US2017/048544 patent/WO2018044703A1/en unknown
- 2017-08-25 JP JP2019511399A patent/JP2019526668A/ja active Pending
- 2017-08-25 US US16/321,671 patent/US20210277161A1/en not_active Abandoned
- 2017-08-25 KR KR1020197007556A patent/KR20190046873A/ko not_active Application Discontinuation
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2669713A (en) * | 1950-10-27 | 1954-02-16 | Dow Chemical Co | Method of regenerating anion exchange resins |
US2697080A (en) * | 1951-12-05 | 1954-12-14 | Koppers Co Inc | Ion-exchange resins containing quaternary ammonium hydroxide groups |
US2697079A (en) * | 1951-12-05 | 1954-12-14 | Koppers Co Inc | Ion-exchange resins containing quaternary ammonium hydroxide groups |
JPS58177140A (ja) * | 1982-04-12 | 1983-10-17 | Showa Denko Kk | 液体クロマトグラフイ−用多孔質充填剤及びその製造方法 |
JP2000501201A (ja) * | 1995-11-27 | 2000-02-02 | クラリアント・インターナショナル・リミテッド | キレート形成性イオン交換樹脂によってフォトレジスト組成物中の金属イオンを低減させる方法 |
JP2001506375A (ja) * | 1996-12-17 | 2001-05-15 | クラリアント・インターナショナル・リミテッド | 有機極性溶媒を含有するフォトレジスト組成物中の混入金属イオンをイオン交換により低減する方法 |
JP2010042395A (ja) * | 2008-03-05 | 2010-02-25 | Mitsubishi Chemicals Corp | アニオン交換樹脂、マクロポーラス型アニオン交換樹脂の製造方法、脱塩装置、発電所用復水脱塩装置、および懸濁性金属腐蝕生成物の除去方法 |
WO2010018810A1 (ja) * | 2008-08-12 | 2010-02-18 | 和光純薬工業株式会社 | 前処理カラムの充填剤用ポリマー |
Also Published As
Publication number | Publication date |
---|---|
RU2019107043A3 (ja) | 2020-12-04 |
KR20190046873A (ko) | 2019-05-07 |
US20210277161A1 (en) | 2021-09-09 |
WO2018044703A1 (en) | 2018-03-08 |
CN109661269A (zh) | 2019-04-19 |
EP3507013A1 (en) | 2019-07-10 |
RU2019107043A (ru) | 2020-09-14 |
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