JP2019513148A - 有機ケイ素湿潤剤を含有するレシチン系スプレーアジュバント - Google Patents
有機ケイ素湿潤剤を含有するレシチン系スプレーアジュバント Download PDFInfo
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- JP2019513148A JP2019513148A JP2018551426A JP2018551426A JP2019513148A JP 2019513148 A JP2019513148 A JP 2019513148A JP 2018551426 A JP2018551426 A JP 2018551426A JP 2018551426 A JP2018551426 A JP 2018551426A JP 2019513148 A JP2019513148 A JP 2019513148A
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- lecithin
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- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
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- RDYMFSUJUZBWLH-SVWSLYAFSA-N endosulfan Chemical compound C([C@@H]12)OS(=O)OC[C@@H]1[C@]1(Cl)C(Cl)=C(Cl)[C@@]2(Cl)C1(Cl)Cl RDYMFSUJUZBWLH-SVWSLYAFSA-N 0.000 description 1
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
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- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
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- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000003208 petroleum Chemical class 0.000 description 1
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- 239000011591 potassium Substances 0.000 description 1
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- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 1
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- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
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- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
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- 229920002545 silicone oil Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
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- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229940079862 sodium lauryl sarcosinate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000011684 sodium molybdate Substances 0.000 description 1
- 235000015393 sodium molybdate Nutrition 0.000 description 1
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- ADWNFGORSPBALY-UHFFFAOYSA-M sodium;2-[dodecyl(methyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCN(C)CC([O-])=O ADWNFGORSPBALY-UHFFFAOYSA-M 0.000 description 1
- ASEFUFIKYOCPIJ-UHFFFAOYSA-M sodium;2-dodecoxyethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOS([O-])(=O)=O ASEFUFIKYOCPIJ-UHFFFAOYSA-M 0.000 description 1
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- 229940014213 spinosad Drugs 0.000 description 1
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- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
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- 230000001629 suppression Effects 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- YFNCATAIYKQPOO-UHFFFAOYSA-N thiophanate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OCC YFNCATAIYKQPOO-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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Abstract
Description
本出願は、2016年3月31日に出願された米国仮特許出願第62/316,183号の利益を主張し、その全体の内容は参照により本明細書に組み込まれる。
農薬配合物用のアジュバント組成物であって、
a)レシチン;および
b)一般式(I)の有機ケイ素界面活性剤を含み、
R1−Si(R2)(R3)−Z (I)
ここで
R1は1〜8個の炭素原子の直鎖または分岐の一価の炭化水素基またはR4−Si(R5)(R6)−R7−基であり、ここでR4は1〜8個の炭素原子の直鎖または分岐の一価の炭化水素基であり、R5およびR6は、独立して、1〜4個の炭素原子の直鎖または分岐の一価の炭化水素基であり、そしてR7は1〜4個の炭素原子の直鎖または分岐の二価の炭化水素基であり;
R2およびR3は、独立して、1〜4個の炭素原子の直鎖または分岐の一価の炭化水素基であり;
Zは、15個までのアルキレンオキシド単位のアルキレンオキシド含有基であって各単位は独立して1〜4個の炭素原子を含有するもの;カチオン基またはアルキルハライドを含まない第四級基である、アジュバント組成物が提供される。
本明細書のアジュバント組成物の一実施形態において、そのレシチン成分は、ホスファチジルコリン(PC)としてのレシチン10〜70重量%を含み、ホスファチジルエタノールアミン(PE)、ホスファチジルイノシトール(PI)およびホスファチド酸(PA)から選択され、そして60重量%を超える平均アセトン不溶物(AI)含量を有する残部を有してもよい。
R1−Si(R2)(R3)−Z
ここで
R1は1〜8個の炭素原子の直鎖または分岐の一価の炭化水素基、例えば、メチル、エチル、プロピル、イソプロピル、n−ブチル、s−ブチル、t−ブチル、ペンチル、イソペンチル、ヘキシル、イソヘキシル、オクチル、n−オクチル等、好ましくはメチル、エチル、プロピル、イソプロピル、n−ブチル、s−ブチルまたはt−ブチルであり、またはR1はR4−Si(R5)(R6)−R7−基であり、ここでR4は1〜8個の炭素原子の直鎖または分岐の一価の基、例えばR1として上記で示された任意のものであり、好ましくはメチル、エチル、プロピル、イソプロピル、n−ブチル、s−ブチルまたはt−ブチルであり、R5およびR6は、独立して、1〜4個の炭素原子の直鎖または分岐の一価の炭化水素基、例えばメチル、エチル、プロピル、イソプロピル、n−ブチル、s−ブチルまたはt−ブチル、好ましくはメチル、エチル、プロピルまたはイソプロピルであり、R7は1〜4個の炭素原子の直鎖または分岐鎖の二価の炭化水素基、例えばメチレン、エチレン、プロピレン、1−メチルエチレン、2−メチルエチレン、ブチレン、1−メチルプロピレン、2−メチルプロピレンまたは3−メチルプロピレン、好ましくはメチレンまたはプロピレンであり;
R2およびR3は、独立して、1〜4個の炭素原子の直鎖または分岐の一価の炭化水素基、例えばメチル、エチル、プロピル、イソプロピル、n−ブチル、s−ブチルまたはt−ブチル、好ましくはメチル、エチル、プロピルまたはイソプロピルであり;
Zは、1〜15個、より具体的には3〜12個、さらにより具体的には5〜12個のアルキレンオキシド単位のアルキレンオキシド含有基であって各単位は独立して1〜4個の炭素原子を含有するもの;またはZは、カチオン基またはアルキルハライドを含まない第四級基である。
−R8O[(C2H4O)a(C3H6O)b(C4H8O)c]d−R9
ここで
R8は3〜8個、好ましくは3〜6個の炭素原子の直鎖または分岐の二価の炭化水素基、例えば、プロピレン、イソプロピレン、n−ブチレン、イソブチレン、ペンチレン、イソペンチレン、ヘキシレン、イソへキシレンなどであり;R9は、水素、1〜4個の炭素原子の一価の炭化水素ラジカル、例えば上述した任意のもの、
であり;ここでRAおよびRBは−CH2CH(OH)CH2−であり、R10、R11、R13およびR14は独立して1または2個の炭素原子の一価の炭化水素基であり、R12およびR13は、独立して、1以上のヒドロキシル基で置換されていてもよい1〜6個の炭素原子の直鎖または分岐の一価の炭化水素基、例えば上述した任意のものであり、そして
は、2〜22個の炭素原子、より具体的には2〜12個の炭素原子、さらにより具体的には2〜6個の炭素原子の
含有基であり;下付き文字aは1〜15であり、下付き文字bおよびcはそれぞれ独立に0または1〜14であってa+b+c≦15という条件であり、下付き文字dは0または1である。
が下記一般式で表され得、
ここで
R16およびR17は、独立して、水素、ヒドロキシル、または1〜3個の炭素原子の一価の炭化水素基、またはヒドロキシメチルであり、R18は、水素、ヒドロキシル、1〜20個、具体的には1〜10個の炭素原子の一価の炭化水素基またはヒドロキシメチル基である。
の例としては、限定されるものではないが、酢酸、プロピオン酸、および酪酸等のモノカルボン酸;コハク酸、マレイン酸、シュウ酸、トリカルボン酸等のジカルボン酸;グリコール酸、乳酸、クエン酸、マンデル酸等のアルファ−ヒドロキシ酸;ヒドロキシプロピオン酸、サリチル酸、カルニチンβ−ヒドロキシβ−メチル酪酸、3−ヒドロキシ酪酸などのベータ−ヒドロキシ酸、ジメチロールプロピオン酸などのジヒドロキシ酸;およびカプリル酸、カプリン酸、カプロン酸、オレイン酸、ミリストレイン酸、ステアリン酸、リノール酸およびエルカ酸のような飽和および不飽和脂肪酸から誘導されるものを含む。
であり、ここでRBは−CH2CH(OH)CH2−であり、R13およびR14はメチルであり、R15は、1以上のヒドロキシル基で置換された3〜6個の炭素原子の直鎖または分岐の炭化水素基であり、
は、ジメチロールプロピオン酸、乳酸、プロピオン酸またはグリコール酸から誘導される。
本発明のアジュバント組成物は、農薬配合物に組み込むことが知られている1以上の任意の成分、例えば1以上の酸性化剤、湿潤剤、泡制御剤、溶媒、水などを含有することができる。
噴霧溶液のpHが>pH5である場合、アジュバント組成物に酸性化剤を含めることができる。pHをpH4〜5に低下させることは、除草剤の取り込みを助け、水硬度の問題に対処することができる。
非イオン性、アニオン性、カチオン性および両性イオン性の界面活性剤の中から選択された湿潤剤は、噴霧小滴の堆積を改善する手段として、噴霧溶液の動的表面張力をさらに低減することが望ましい場合には、本明細書のアンチドリフト組成物に組み込むことができる。
泡の形成を抑制するために、本発明のアジュバント組成物に泡制御剤を含めることができる。適切な泡抑制剤としては、シリカ充填ポキシジメチルシロキサンまたはシリカとポリジメチルシロキサンとの反応生成物が挙げられるが、これらに限定されない。
相溶化剤として、本発明のアジュバント組成物に1以上の溶媒を組み込むことができる。
広範囲に変化する量の水を、配合物に相溶化するために本明細書のアジュバント組成物に組み込むことができる。例えば、利用する場合、水は、アジュバント組成物の30重量%まで、より具体的には20重量%までのレベルで存在してもよい。
本発明によるアジュバント組成物は、周囲温度(約15℃)から70℃までの範囲の温度で、レシチン、有機ケイ素界面活性剤(I)および、存在する場合、任意成分を機械的に混合することを含むが、これらに限定されない当技術分野で周知の手順を用いて調製することができる。アジュバント組成物は、液体溶液、液体中の固体の分散液、液体中の液体の分散液、固体混合物、固溶体などのような様々な形態で調製することができる。
上記の手順を使用して、以下の表4に記載の成分および量でアジュバント組成物Sil-1〜Sil-15を調製した。SAG 1572は、Momentive Performance Materials, Inc.製の泡制御剤である。
湿潤剤の種類を変えながら、一定の割合のレシチンと一定の割合の有機ケイ素界面活性剤(I)を用いて、本発明によるアジュバント組成物(Sil-16〜Sil-19)を調製した。以下の表6は、組成物の成分およびその量を示す。
多くの種類の駆除剤は弱酸であり、酸性条件下での植物構造への浸透が改善されるため、より大きな有効性を示す。以下の表8のデータは、脱イオン(DI)水、300ppmのCa2+およびMg2+を含有する硬水および硬水中のグリホサート−IPAおよび2,4−Dアミンの噴霧溶液のpHを低減する本発明のアジュバント組成物(Sil-6)の能力を示している。pH調整能力は、比較例のアンチドリフト組成物LI-700と同等であった。
軟水および硬水中の分散性およびエマルション安定性は、メスシリンダー中で、1mLのアジュバント組成物Sil-3または比較例のアンチドリフトアジュバントLI-700を99mLの水に添加することによって評価した。シリンダーを手動で10回反転させた。エマルション安定性は外観にて1時間で観察され、そして分離の量はクリーム、泡または油のmLとして記録された。さらに、各組成物を完全に分散させるのに必要な反転の回数を測定した:1−3=容易に分散する;4−6=ゆっくり分散する;7−10=分散するのが困難。表9のデータが示すように、水の硬度は、100〜1000ppmのCa2+およびMg2+の範囲であった。
アジュバント組成物の凍結融解安定性は、各試験組成物を−5℃で一晩放置し、室温で2時間後にその外観を評価する5サイクルを通して評価した。各サイクルの後、激しい振盪により再分散することがやっとできた不溶性材料の上層を発達させた比較例のアジュバント組成物L-700とは対照的に、アジュバント組成物Sil-3は解凍後に均質な分散体を形成した。
14C−グリホサート除草剤のバーンヤードグラス(Echinochloacrus-galli)への取り込みを、Gastrinらによって記載された方法(Gaskin, R.E.; Stevens, P.J.G. Pestic. Sci. 38: 185-192, 1992)に従って処理の2時間後および24時間後に測定し、これにより、取り込み速度に対するアジュバントの界面活性剤成分の影響を定めた。取り込みは、最も若い完全に伸長した葉の軸方向の表面上で決定した;高さ約10cmの4葉期の植物。グリホサート溶液(Gly-IPA)を、750gのGly-IPA/100Lの水に相当する希釈率で適用した。以下の表10のデータは、アジュバント組成物Sil-6およびSil-10が、比較例アジュバントL1-700よりも処理後2時間でより速い取り込みを提供することを表している。
衝突した小滴のパーセントとしての噴霧小滴付着を、約400μmの単一サイズの小滴を形成する200μmのノズルオリフィスを有する圧電小滴発生器を使用して、上述したように測定した(Stevens et al., Pestic Sci. 38: 237-245, 1993)。小滴自由落下距離は53cm、速度は約1m/sであった。キャベツの葉(濡れにくい)を衝突面として22.5°の葉の角度で使用した。以下の表11のデータは、アジュバント組成物Sil-6およびSil-10が、比較例のアンチドリフトアジュバントLI-700と比べて、キャベツ葉上で同様またはより良好な小滴付着を提供したことを示す。付着は、アジュバント濃度の増加とともに増加した。
処理後2時間および24時間のキャノーラ植物について、14C−2,4−ジクロロフェノキシ酢酸、ジメチルアミン塩(2,4-D DMA塩)(1%a.e./100L/ha)の取り込みを、Lui, inPro. 18th Asian-Pacific Weed Sci. Soc. Conf, pp. 561-566, 2001に記載の方法に従って測定した。
2,4-Dおよびアジュバント組成物を含有する水性噴霧溶液の小滴付着を、濡れにくいバーンヤードグラスの葉(葉の軸表面上の20重量%のアセトン水溶液の接触角が180°である)について評価した。約400μmの直径を有する小滴は、22.5°の斜面を向いた葉上に53cmの高さから衝突した。
アジュバント組成物Sil-2、Sil-3およびLI-700もまた、アンチドリフト性能について評価した。アンチドリフト効果は、1.0%a.e./Lグリホサート-IPA溶液(Rodeo、DowAgroSciences)を単独または0.25%または0.50%のアンチドリフトアジュバントと共に試験した。この方法論は以下の通りであった:1つのノズルおよび7つの噴霧溶液をSympatec Helos Vario KR粒度分析装置で、Henry et al.,W.E 2014. In: Carmine S. ed. Pesticide Formulation and Delivery Systems: 33rdVolume, “Sustainability: Contributions from Formulation Technology”, 23-25 Oct2012, Atlanta, USA, pp. 129-138に記載されるように分析した。噴霧品質に関するベンチュリノズルとアジュバント選択の関係が、Castelani P. ed., Proceedings of the 10th International Symposium onAdjuvants for Agrochemicals, 22-26 April 2013, Foz Do Iguasu, Brazil, pp.269-272に記述されている。R7レンズを装着して、分析装置は、レーザー回折を用いて粒径分布を決定することにより、18〜3,500ミクロンの範囲内の粒径を検出することができる。ノズルプルームの幅は、リニアアクチュエータによってレーザを横切ってノズルを移動させることによって分析した。すべての試験は15mphの低速風洞で行った。7つの噴霧溶液を1つのノズルを通して評価し、各処理を少なくとも3回繰り返した。XR11008ノズルを40psiで試験した。
トリシロキサンアルコキシレート(TSA)は高度に表面活性であり、その結果、非常に安定な泡を生成することができる。ポリジメチルシロキサン(PDM)油に基づく従来の消泡化合物は、TSA界面活性剤によって生成された泡を制御するのに効果がないことが判明している(Policello et. al., Pesticide Formulations and Application Systems:17th. Volume, ASTM STP 1328, G. Robert Goss, Michael J. Hopkinson, and HerbertM. Collins, Eds., American Society for Testing and Materials, 1997)。
トリシロキサンアルコキシレートに基づくアンチドリフトアジュバント組成物は、加水分解的に不安定であり、pHが6.5未満であると分解する。pHがこのレベルより低くなると、分解速度は増加する。本発明のアンチドリフト組成物のpHは典型的には<pH3.5である。したがって、トリシロキサンアルコキシレートの使用は、DSTの増加として観察される迅速な加水分解をもたらす。トリシロキサンアルコキシレートのこの酸不安定性は、それらをアンチドリフトアジュバント組成物での使用に適さないものにする。
Dow AgroSciences製のRodeo(53.8%のグリホサート−イソプロピルアンモニウム塩)の野外効力における本発明の組成物の影響を評価するために噴霧試験を行った。各噴霧試験は、無作為化された完全なブロック計画としてととのえられ、8の処理および各処理につき4回の繰り返しが行われた。プロットサイズは3x7mだった。対象とする雑草は、ヘアリークラブグラス(Digitaria sanguinalis)、スムーズクラグブラス(Digitariaischaemum)、およびヘラオオバコ(Plantago lanceolate)だった。Rodeoは単独で、またはアジュバントと組み合わせて0.80L/ha(0.38a.e./ha)で適用した。SIL-3(表4)またはLI-700のいずれかのアジュバントを、0.125、0.25および0.50L/haで適用した。噴霧量はすべての処理で100L/haであった。雑草の成長段階、1m2当たりの雑草の数、および地面の被覆率は、適用前に評価した。処置後の雑草防除は、0=制御なしおよび100=完全な制御によるパーセンテージスケールを用いて評価した。
Claims (21)
- アジュバント組成物であって、
a)レシチン;および
b)一般式(I)の有機ケイ素界面活性剤を含み、
R1−Si(R2)(R3)−Z (I)
ここで
R1は1〜8個の炭素原子の直鎖または分岐の一価の炭化水素基またはR4−Si(R5)(R6)−R7−基であり、ここでR4は1〜8個の炭素原子の直鎖または分岐の一価の炭化水素基であり、R5およびR6は、独立して、1〜4個の炭素原子の直鎖または分岐の一価の炭化水素基であり、そしてR7は1〜4個の炭素原子の直鎖または分岐の二価の炭化水素基であり;
R2およびR3は、独立して、1〜4個の炭素原子の直鎖または分岐の一価の炭化水素基であり;
Zは、15個までのアルキレンオキシド単位のアルキレンオキシド含有基であって各単位は独立して1〜4個の炭素原子を含有するもの;カチオン基またはアルキルハライドを含まない第四級基である、アジュバント組成物。 - 前記のレシチン成分が、ホスファチジルコリンとして10〜70重量%のレシチンを含み、残部が、ホスファチジルエタノールアミン、ホスファチジルイノシトールおよびホスファチジン酸から選択され、そして60重量%を超える平均アセトン不溶物含量を有する、請求項1に記載のアジュバント組成物。
- Zは下記一般式で表されるアルキレンオキサイド含有基であり、
−R8O[(C2H4O)a(C3H6O)b(C4H8O)c]d−R9
ここで
R8は3〜8個の炭素原子の直鎖または分岐の二価の炭化水素基であり;R9は、水素、1〜4個の炭素原子の一価の炭化水素ラジカル、
であり;ここでRAおよびRBは−CH2CH(OH)CH2−であり、R10、R11、R13およびR14は独立して1または2個の炭素原子の一価の炭化水素基であり、R12およびR13は、独立して、1以上のヒドロキシル基で置換されていてもよい1〜6個の炭素原子の直鎖または分岐の一価の炭化水素基であり、そして
は、2〜22個の炭素原子の
含有基であり;下付き文字aは1〜15であり、下付き文字bおよびcはそれぞれ独立に0または1〜14であってa+b+c≦14という条件であり、下付き文字dは0〜1である、請求項1に記載のアジュバント組成物。 -
が下記一般式で表され、
ここでR16およびR17は、独立して、水素、ヒドロキシル、または1〜3個の炭素原子の一価の炭化水素基、またはヒドロキシメチルであり、R18は、水素、ヒドロキシル、1〜20個の炭素原子の一価の炭化水素基またはヒドロキシメチル基である、請求項3に記載のアジュバント組成物。 - 有機ケイ素界面活性剤(I)が、レシチンおよび有機ケイ素界面活性剤(I)の総重量の1〜99重量%で存在する、請求項1に記載のアジュバント組成物。
- 少なくとも1つの酸性化剤をさらに含む、請求項1に記載のアジュバント組成物。
- 少なくとも1つの湿潤剤をさらに含む、請求項1に記載のアジュバント組成物。
- 泡抑制剤、有機溶媒および水からなる群から選択される少なくとも1つの成分をさらに含む、請求項1に記載のアジュバント組成物。
- 少なくとも1つの酸性化剤および少なくとも1つの湿潤剤をさらに含む、請求項1に記載のアジュバント組成物。
- レシチンおよび有機ケイ素界面活性剤(I)の総重量に基づいて、1〜99重量%の有機ケイ素界面活性剤(I)を含む、請求項1に記載のアジュバント組成物。
- レシチンおよび有機ケイ素界面活性剤(I)の総重量に基づいて、1〜50重量%の有機ケイ素界面活性剤(I)を含む、請求項1に記載のアジュバント組成物。
- レシチンおよび有機ケイ素界面活性剤(I)の総重量に基づいて、1〜10重量%の有機ケイ素界面活性剤(I)を含む、請求項1に記載のアジュバント組成物。
- アンチドリフト有効量の請求項1に記載のアジュバント組成物を含む農薬配合物。
- アンチドリフト有効量の請求項6に記載のアジュバント組成物を含む農薬配合物。
- アンチドリフト有効量の請求項7に記載のアジュバント組成物を含む農薬配合物。
- アンチドリフト有効量の請求項9に記載のアジュバント組成物を含む農薬配合物。
- 駆除剤、枯葉剤、肥料、生物剤、栄養素、微量栄養素、成長制御剤またはそれらの組み合わせからなる群から選択される少なくとも1つの生物活性物をさらに含む、請求項13に記載の農薬配合物。
- 請求項13に記載の農薬配合物を標的領域内に噴霧することを含む、標的領域に適用される農薬配合物のドリフトを抑制する方法。
- 請求項13に記載の農薬配合物を外部植物組織表面に噴霧することを含む、外部植物組織表面への農薬配合物の噴霧小滴の堆積および/または保持を増強または増加させる方法。
- 請求項13に記載の農業配合物を外部植物組織表面に噴霧することを含む、農薬配合物の生物活性成分の内部植物構造への浸透および/または取り込みを増強または増加させる方法。
- 請求項13に記載の農薬配合物を水質調整される植物の外部表面に噴霧することを含む、植物を水質調整する方法。
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