JP2018501373A - 高流動性を有する熱可塑性樹脂組成物 - Google Patents
高流動性を有する熱可塑性樹脂組成物 Download PDFInfo
- Publication number
- JP2018501373A JP2018501373A JP2017533433A JP2017533433A JP2018501373A JP 2018501373 A JP2018501373 A JP 2018501373A JP 2017533433 A JP2017533433 A JP 2017533433A JP 2017533433 A JP2017533433 A JP 2017533433A JP 2018501373 A JP2018501373 A JP 2018501373A
- Authority
- JP
- Japan
- Prior art keywords
- polyamide
- oligomer
- composition according
- oligomers
- thermoplastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005992 thermoplastic resin Polymers 0.000 title description 2
- 239000011342 resin composition Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 144
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 69
- 229920000642 polymer Polymers 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 44
- 239000011159 matrix material Substances 0.000 claims abstract description 40
- -1 cyclic ester Chemical class 0.000 claims abstract description 37
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000002131 composite material Substances 0.000 claims abstract description 32
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 31
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 27
- 239000004744 fabric Substances 0.000 claims abstract description 24
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 229920002647 polyamide Polymers 0.000 claims description 105
- 239000004952 Polyamide Substances 0.000 claims description 104
- 230000008569 process Effects 0.000 claims description 24
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 15
- 239000000155 melt Substances 0.000 claims description 15
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 13
- 125000001931 aliphatic group Chemical group 0.000 claims description 12
- 229920003986 novolac Polymers 0.000 claims description 12
- 125000004122 cyclic group Chemical group 0.000 claims description 11
- 238000002347 injection Methods 0.000 claims description 11
- 239000007924 injection Substances 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- 238000006068 polycondensation reaction Methods 0.000 claims description 9
- 125000005842 heteroatom Chemical group 0.000 claims description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 7
- 229920002292 Nylon 6 Polymers 0.000 claims description 6
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 6
- 150000001413 amino acids Chemical class 0.000 claims description 6
- 150000003951 lactams Chemical class 0.000 claims description 6
- 229920000572 Nylon 6/12 Polymers 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 101000576320 Homo sapiens Max-binding protein MNT Proteins 0.000 claims description 4
- 229920000571 Nylon 11 Polymers 0.000 claims description 4
- 229920006659 PA12 Polymers 0.000 claims description 4
- 229920006121 Polyxylylene adipamide Polymers 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 229920006119 nylon 10T Polymers 0.000 claims description 4
- 238000009745 resin transfer moulding Methods 0.000 claims description 4
- 229920006182 PA 6T/6I/66 Polymers 0.000 claims description 3
- 150000004984 aromatic diamines Chemical class 0.000 claims description 3
- 229920006018 co-polyamide Polymers 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004597 plastic additive Substances 0.000 claims description 3
- 229920006131 poly(hexamethylene isophthalamide-co-terephthalamide) Polymers 0.000 claims description 3
- 229920006128 poly(nonamethylene terephthalamide) Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 claims description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 2
- 125000001033 ether group Chemical group 0.000 claims 1
- 239000004014 plasticizer Substances 0.000 abstract description 9
- 230000002787 reinforcement Effects 0.000 abstract description 7
- 239000000178 monomer Substances 0.000 description 22
- 229920005989 resin Polymers 0.000 description 15
- 239000011347 resin Substances 0.000 description 15
- 239000000835 fiber Substances 0.000 description 14
- 239000000654 additive Substances 0.000 description 12
- 238000005259 measurement Methods 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 238000005470 impregnation Methods 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 125000003277 amino group Chemical group 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 238000005227 gel permeation chromatography Methods 0.000 description 6
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 6
- 229940024606 amino acid Drugs 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 5
- 125000002843 carboxylic acid group Chemical group 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 229920006122 polyamide resin Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 238000001542 size-exclusion chromatography Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000004609 Impact Modifier Substances 0.000 description 3
- 239000004642 Polyimide Substances 0.000 description 3
- 239000004734 Polyphenylene sulfide Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 235000011054 acetic acid Nutrition 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 229920003235 aromatic polyamide Polymers 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000012760 heat stabilizer Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920001721 polyimide Polymers 0.000 description 3
- 229920000069 polyphenylene sulfide Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 150000003141 primary amines Chemical group 0.000 description 3
- 230000000750 progressive effect Effects 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 2
- OYFRNYNHAZOYNF-UHFFFAOYSA-N 2,5-dihydroxyterephthalic acid Chemical compound OC(=O)C1=CC(O)=C(C(O)=O)C=C1O OYFRNYNHAZOYNF-UHFFFAOYSA-N 0.000 description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- CDOWNLMZVKJRSC-UHFFFAOYSA-N 2-hydroxyterephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(O)=C1 CDOWNLMZVKJRSC-UHFFFAOYSA-N 0.000 description 2
- BCEQKAQCUWUNML-UHFFFAOYSA-N 4-hydroxybenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=C(O)C(C(O)=O)=C1 BCEQKAQCUWUNML-UHFFFAOYSA-N 0.000 description 2
- XQXPVVBIMDBYFF-UHFFFAOYSA-N 4-hydroxyphenylacetic acid Chemical compound OC(=O)CC1=CC=C(O)C=C1 XQXPVVBIMDBYFF-UHFFFAOYSA-N 0.000 description 2
- QNVNLUSHGRBCLO-UHFFFAOYSA-N 5-hydroxybenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC(O)=CC(C(O)=O)=C1 QNVNLUSHGRBCLO-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 244000198134 Agave sisalana Species 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 240000000491 Corchorus aestuans Species 0.000 description 2
- 235000011777 Corchorus aestuans Nutrition 0.000 description 2
- 235000010862 Corchorus capsularis Nutrition 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 240000000797 Hibiscus cannabinus Species 0.000 description 2
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 2
- 240000006240 Linum usitatissimum Species 0.000 description 2
- 235000004431 Linum usitatissimum Nutrition 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 239000004697 Polyetherimide Substances 0.000 description 2
- 229920002873 Polyethylenimine Polymers 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000004760 aramid Substances 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 235000009120 camo Nutrition 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 235000005607 chanvre indien Nutrition 0.000 description 2
- 238000007385 chemical modification Methods 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003480 eluent Substances 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000012765 fibrous filler Substances 0.000 description 2
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 239000011487 hemp Substances 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 150000002596 lactones Chemical class 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920001652 poly(etherketoneketone) Polymers 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920006260 polyaryletherketone Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 229920001601 polyetherimide Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000012763 reinforcing filler Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical class O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 2
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- FTVFPPFZRRKJIH-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CC1(C)CC(N)CC(C)(C)N1 FTVFPPFZRRKJIH-UHFFFAOYSA-N 0.000 description 1
- PYFXEDDXCHOKKD-UHFFFAOYSA-N 2,4-diamino-3,5-dimethylphenol Chemical compound CC1=CC(O)=C(N)C(C)=C1N PYFXEDDXCHOKKD-UHFFFAOYSA-N 0.000 description 1
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical compound OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- WFNVGXBEWXBZPL-UHFFFAOYSA-N 3,5-diaminophenol Chemical compound NC1=CC(N)=CC(O)=C1 WFNVGXBEWXBZPL-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- CIVMSMDSVPVXSU-UHFFFAOYSA-N 3-[1,3,3-tris(2-carboxyethyl)-2-oxocyclohexyl]propanoic acid Chemical compound OC(=O)CCC1(CCC(O)=O)CCCC(CCC(O)=O)(CCC(O)=O)C1=O CIVMSMDSVPVXSU-UHFFFAOYSA-N 0.000 description 1
- NUNAWQZKZVVELQ-UHFFFAOYSA-N 3-amino-4-methylphenol Chemical compound CC1=CC=C(O)C=C1N NUNAWQZKZVVELQ-UHFFFAOYSA-N 0.000 description 1
- QPEJHSFTZVMSJH-UHFFFAOYSA-N 3-amino-5-hydroxybenzoic acid Chemical compound NC1=CC(O)=CC(C(O)=O)=C1 QPEJHSFTZVMSJH-UHFFFAOYSA-N 0.000 description 1
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 1
- 229940018563 3-aminophenol Drugs 0.000 description 1
- RSAITUMPGKOBNH-UHFFFAOYSA-N 4-(2-aminoethyl)octane-1,8-diamine Chemical compound NCCCCC(CCN)CCCN RSAITUMPGKOBNH-UHFFFAOYSA-N 0.000 description 1
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 1
- 239000004953 Aliphatic polyamide Substances 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004956 Amodel Substances 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 229920003261 Durez Polymers 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004954 Polyphthalamide Substances 0.000 description 1
- 229920006373 Solef Polymers 0.000 description 1
- 239000004958 Technyl Substances 0.000 description 1
- 229920006096 Technyl® Polymers 0.000 description 1
- RHQDFWAXVIIEBN-UHFFFAOYSA-N Trifluoroethanol Chemical compound OCC(F)(F)F RHQDFWAXVIIEBN-UHFFFAOYSA-N 0.000 description 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229920003231 aliphatic polyamide Polymers 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- QVYARBLCAHCSFJ-UHFFFAOYSA-N butane-1,1-diamine Chemical compound CCCC(N)N QVYARBLCAHCSFJ-UHFFFAOYSA-N 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 description 1
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- VKIRRGRTJUUZHS-UHFFFAOYSA-N cyclohexane-1,4-diamine Chemical compound NC1CCC(N)CC1 VKIRRGRTJUUZHS-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- GDAVCKWOYPPSEU-UHFFFAOYSA-N diethyl 4-oxocyclohexane-1,1-dicarboxylate Chemical compound CCOC(=O)C1(C(=O)OCC)CCC(=O)CC1 GDAVCKWOYPPSEU-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009950 felting Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000009730 filament winding Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 238000000892 gravimetry Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000012761 high-performance material Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- KRIOVPPHQSLHCZ-UHFFFAOYSA-N phenyl propionaldehyde Natural products CCC(=O)C1=CC=CC=C1 KRIOVPPHQSLHCZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920006139 poly(hexamethylene adipamide-co-hexamethylene terephthalamide) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920006375 polyphtalamide Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 229920006012 semi-aromatic polyamide Polymers 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 229960004441 tyrosine Drugs 0.000 description 1
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
- B29C70/48—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
- B29C70/52—Pultrusion, i.e. forming and compressing by continuously pulling through a die
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2461/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2461/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2461/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2461/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2461/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2461/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C08J2461/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols with monohydric phenols
- C08J2461/10—Phenol-formaldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2467/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
- C08J2471/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/04—Polymer mixtures characterised by other features containing interpenetrating networks
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Reinforced Plastic Materials (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
Description
(a)1種の熱可塑性ポリマーマトリックス;
(b)環状エステルオリゴマー、エーテルオリゴマー、およびそれらの混合物から選択される1種のオリゴマー;ならびに
(c)1種のフェノールポリマー
を少なくとも含み;
前記化合物(b)および(c)は、0.25〜6好ましくはおおよそ0.75〜2.75変わる重量比(c)/(b)で存在する、熱可塑性組成物に関する。
前に示されたとおりに、本発明による組成物は、少なくとも1種の熱可塑性ポリマーマトリックスを含む。
− ポリエチレンイミン(PEI);
− ポリイミド(PI);
− 熱可塑性ポリウレタン(TPU);
− ポリエステル;ポリエチレンテレフタレート(PET)またはポリブチレンテレフタレート(PBT);
− ポリフェニレンスルフィド(PPS);
− ポリアリールエーテルケトン(PAEK)、例えば、ポリエーテルエーテルケトン(PEEK)およびポリエーテルケトンケトン(PEKK);
− 脂肪族ポリアミド(Pa)、および半芳香族ポリアミド(PPA)、これらのポリマーの一部は、TechnylおよびAmodelの名称の下でSolvay社により販売されている;
− 以下の式(I):CFX=CHX’(I)[式中、XおよびX’は、水素もしくはハロゲン原子(特にフッ素または塩素原子)またはペルハロゲン化(特にペルフッ素化)アルキル基を独立して意味し、好ましくは、X=FおよびX−Hである]を有する少なくとも1種のモノマーを含むフルオロポリマー、例えば、ポリ(フッ化ビニリデン)(好ましくは、フッ化ビニリデンと例えば、ヘキサフルオロプロピレン(HFP)とのコポリマーの形態の)、フルオロエチレン/プロピレン(FEP)コポリマー、エチレンと、フルオロエチレン/プロピレン(FEP)、もしくはテトラフルオロエチレン(TFE)、もしくはペルフルオロメチルビニルエーテル(PMVE)、もしくはクロロトリフルオロエチレン(CTFE)のいずれかとのコポリマー、これらのポリマーの一部は、特にSolefという名称の下でSolvay社により販売されている;ならびに
− それらのブレンド
から選択されてもよい。
a)以下の一般式(I)のモノマー:
b)以下の一般式(Ma)および一般式(Mb)のモノマー:
c)任意選択で以下の一般式(III)または一般式(IV)のモノマー:
Z−R3−Z(III)またはR4−Z(IV)
(式中、
− R1は、恐らくはヘテロ原子を含み少なくとも2個の炭素原子を含む線状または環状の芳香族または脂肪族炭化水素基であり;
− Aは、共有結合、またはヘテロ原子を含むことができかつ1〜20個の炭素原子を含む脂肪族炭化水素基であり;
− Zは、第一級アミン官能基またはカルボン酸官能基を表し;
− Yは、Xがカルボン酸官能基を表す場合、第一級アミン官能基であるか、またはXが第一級アミン官能基を表す場合、カルボン酸官能基であり;
− R2、R3およびR4は、同一であるかまたは異なり、恐らくはヘテロ原子を含み2〜20個の炭素原子を含む、置換または非置換の脂肪族、脂環式または芳香族炭化水素基を表し;
− mは、3〜8の整数を表す)
を少なくとも含むモノマーの混合物の共重合によって得られる。
(a)8000g/モル以上の数平均分子量Mnのポリアミド、および
(b)非進展性ポリアミド、すなわち、不活性雰囲気下で一定の温度および圧力で少なくとも30分間の間最大でも5%だけ、またはさらには最大でも2%だけ、好ましく
前記ポリアミド(b)は、5000g/モル〜8000g/モルの数平均分子量Mnを有する。
上述から明らかになるように、本発明の熱可塑性組成物は、環状エステルオリゴマーまたはエーテルオリゴマーおよびそれらの混合物から選択されるオリゴマータイプの少なくとも1種の可塑剤を含む。
−(1)環状ポリエスルオリゴマー、例えば、環化ポリ(ブチレンテレフタレート)(PBT)またはそれを含有する混合物、例えば、Cyclics Corporationにより販売されるCBT100樹脂など;
−(2)ラクチドオリゴマー、またはそれを含有する混合物;
−(3)ラクトンオリゴマー、例えば、ε−カプロラクトンダイマー、またはそれを含有する混合物など;
−(4)カーボネートオリゴマー、より特にはアルキレンカーボネートオリゴマー、例えば、エチレンカーボネート、プロピレンカーボネート、ブチレンカーボネート、およびそれらの混合物から選択されるもの;ならびに
−それらの混合物
から選択される。
− エチレングリコールオリゴマー;
− プロピレングリコールオリゴマー;および
− それらの混合物
から選択される。
前に述べられたとおりに、本発明の熱可塑性組成物は、フェノールポリマータイプの少なくとも1種の反可塑剤を含む。
(式中、Rは、水素原子、またはヘテロ原子を任意選択で含み、1〜20個の炭素原子を含む直鎖もしくは分岐アルキル基を表し、mは、6〜15であり、nは、5〜22である)
の単位を少なくとも含む。
(式中、R’は、水素原子、またはヘテロ原子を任意選択で含み、1〜20個の炭素原子を含む直鎖もしくは分岐アルキル基を表し、oは、6〜15である)
の単位を少なくとも含むポリマーであってもよい。RおよびR’は、互いに独立していても、または等しくてもよい。oは、特に6、7、8、9、10、11、12、13、14もしくは15の値、またはこれらの値間に含まれる任意の区間を取ってもよい。
本発明による組成物は、有利には、
(a)80重量%〜99.8重量%の熱可塑性ポリマーマトリックス、特にポリアミド;
(b)0.1重量%〜10重量%の環状エステルオリゴマー、エーテルオリゴマー、またはそれらの1つもしくは複数の混合物、特に環化ポリ(ブチレンテレフタレート);および
(c)0.1重量%〜12重量%のフェノールポリマー、特にノボラック樹脂
を含む。
(a)80重量%〜98重量%の熱可塑性ポリマーマトリックス、特にポリアミド;
(b)1重量%〜8重量%の環状エステルオリゴマー、エーテルオリゴマー、またはそれらの1つもしくは複数の混合物、特に環化ポリ(ブチレンテレフタレート);および
(c)1重量%〜12重量%のフェノールポリマー、特にノボラック樹脂
を含む。
(a)80重量%〜92重量%の熱可塑性ポリマーマトリックス、特にポリアミド;
(b)3重量%〜8重量%の環状エステルオリゴマー、エーテルオリゴマー、またはそれらの1つもしくは複数の混合物、特に環化ポリ(ブチレンテレフタレート);および
(c)5重量%〜12重量%のフェノールポリマー、特にノボラック樹脂を含む。
上述から明らかになるように、その態様の1つによれば、本発明は、強化布地に本発明による組成物を溶融状態で含浸させる少なくとも1つの工程を含む、複合材料物品を製造するための方法に関する。
用語「ヤーン」は、単一種類の繊維、または密接混合物としていくつかの種類の繊維から得られるモノフィラメント、連続マルチフィラメントヤーンまたはステープルヤーンを意味することが意図される。連続ヤーンはまた、いくつかのマルチフィラメントヤーンを集合させることによって得られてもよい。
本発明はまた、本発明の方法によって得られることができる物品に関する。物品は、特に強化布地を含むポリアミド系複合材料物品であってもよい。
Stabamidの名称の下でSolvayにより販売されるポリアミドPA66 22FE1に基づいて、本発明による、または本発明の外のいくつかの組成物を調製する。
前の実施例の熱可塑性組成物5を、複合材料の調製のためにこの実施例で使用する。
Claims (19)
- 溶融状態で高流動性を有する熱可塑性組成物であって、
(a)1種の熱可塑性ポリマーマトリックス;
(b)環状エステルオリゴマー、エーテルオリゴマーおよびそれらの混合物から選択される1種のオリゴマーであって、2〜25の重合度を有するオリゴマー;ならびに
(c)1種のフェノールポリマー;
を少なくとも含み、
前記化合物(b)および(c)は、0.25〜6、好ましくはおよそ0.75〜2.75変わる重量比(c)/(b)で存在する、組成物。 - 前記マトリックスが、少なくとも1種のポリアミドを含み、好ましくはポリアミドからなる、請求項1に記載の組成物。
- 前記ポリアミドが、少なくとも1種の脂肪族ジカルボン酸と脂肪族もしくは環状ジアミンとの重縮合により得られるポリアミド、少なくとも1種の芳香族ジカルボン酸と脂肪族もしくは芳香族ジアミンとの重縮合により得られるポリアミド、少なくとも1種のアミノ酸もしくはラクタムのそれ自体との重縮合により得られるポリアミド、またはそれらのブレンドおよび(コ)ポリアミドから選択される、請求項1または2に記載の組成物。
- 前記ポリアミドが、前記ポリアミドの鎖に化学的に結合されたヒドロキシ芳香族単位を含む、請求項2または3に記載の組成物。
- 前記ポリアミドが、10000〜50000g/モル、優先的には12000〜30000g/モルの重量平均分子量Mwを有する、請求項2〜4のいずれか一項に記載の組成物。
- 前記ポリアミドが、PA66、PA6.10、PA6.12、PA12.12、PA4.6、MXD6、PA6、PA7、PA9T、PA10T、PA11、PA12、PA6T/6I、PA6T/6I/66、それらに由来するコポリアミド、およびそれらのブレンドから選択される、請求項2〜5のいずれか一項に記載の組成物。
- 前記オリゴマーが、前記熱可塑性ポリマーマトリックスのもの以下の融点Mpおよび溶融状態の前記熱可塑性マトリックスのもの未満の粘度を有する、請求項1〜6のいずれか一項に記載の組成物。
- 前記オリゴマーが、環状エステルオリゴマー、特に
− 環状ポリ(ブチレンテレフタレート)などの環状ポリエステルオリゴマーまたはそれを含有する混合物;
− ラクチドオリゴマー、またはそれを含有する混合物;
− ラクトンオリゴマー、またはそれを含有する混合物;
− エチレンカーボネート、プロピレンカーボネート、ブチレンカーボネートおよびそれらの混合物から選択されるアルキレンカーボネートオリゴマー;ならびに
− それらの混合物
から選択される、請求項1〜7のいずれか一項に記載の組成物。 - 前記オリゴマーが、エーテルオリゴマー、特に
− エチレングリコールオリゴマー;
− プロピレングリコールオリゴマー;および
− それらの混合物
から選択される、請求項1〜7のいずれか一項に記載の組成物。 - 前記フェノールポリマーが、フェノールとホルムアルデヒドとの縮合の生成物である、請求項1〜9のいずれか一項に記載の組成物。
- 前記フェノールポリマーが、以下の式(I):
(式中、Rは、水素原子、またはヘテロ原子を任意選択で含み、1〜20個の炭素原子を含む直鎖もしくは分岐アルキル基を表し、mは、6〜15であり、nは、5〜22である)
の単位を含む、請求項1〜9のいずれか一項に記載の組成物。 - 溶融状態で、75Pa.s未満、好ましくは50Pa.s未満、またはさらには20Pa.s以下の粘度を有する、請求項1〜11のいずれか一項に記載の組成物。
- (a)80重量%〜99.8重量%の熱可塑性ポリマーマトリックス、特にポリアミド;
(b)0.1重量%〜10重量%の、環状エステルオリゴマー、エーテルオリゴマー、またはそれらの1つもしくは複数の混合物、特に環化ポリ(ブチレンテレフタレート);および
(c)0.1重量%〜12重量%のフェノールポリマー、特にノボラック樹脂
を含む、請求項1〜12のいずれか一項に記載の組成物。 - 強化布地またはプレフォームに溶融状態の請求項1〜13のいずれか一項に記載の組成物を含浸させる少なくとも1つの工程を含む、複合材料物品を製造するための方法。
- 好ましくは直接射出による、引抜プロセス、または密閉成形射出によるRTMプロセスである、請求項14に記載の方法。
- 請求項14または15に記載の方法によって得られた複合材料物品。
- 熱可塑性ポリマーマトリックス中の可塑性添加物としての、少なくとも1種のフェノールポリマー(c)と組み合わせての、環状エステルオリゴマーまたはエーテルオリゴマーおよびそれらの混合物から選択されるオリゴマー(b)の使用であって、前記オリゴマーは、2〜25の重合度を有する、使用。
- 前記化合物(b)および(c)を、0.25〜6、好ましくはおよそ0.75〜2.75変わる重量比(c)/(b)で接触させる、請求項17に記載の使用。
- 前記化合物(b)および(c)の量が、前記マトリックスの溶融粘度を75Pa.s未満、好ましくは50Pa.s未満、またはさらには20Pa.s以下の値に低下させるように調整される、請求項17または18に記載の使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1463108A FR3030548B1 (fr) | 2014-12-22 | 2014-12-22 | Composition thermoplastique a haute fluidite |
FR1463108 | 2014-12-22 | ||
PCT/EP2015/080818 WO2016102481A1 (fr) | 2014-12-22 | 2015-12-21 | Composition thermoplastique a haute fluidite |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2018501373A true JP2018501373A (ja) | 2018-01-18 |
JP2018501373A5 JP2018501373A5 (ja) | 2019-01-24 |
JP6693960B2 JP6693960B2 (ja) | 2020-05-13 |
Family
ID=52684475
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017533433A Expired - Fee Related JP6693960B2 (ja) | 2014-12-22 | 2015-12-21 | 高流動性を有する熱可塑性樹脂組成物 |
Country Status (13)
Country | Link |
---|---|
US (1) | US10584241B2 (ja) |
EP (1) | EP3237544B1 (ja) |
JP (1) | JP6693960B2 (ja) |
KR (1) | KR20170097094A (ja) |
CN (1) | CN107250276A (ja) |
AU (1) | AU2015371136C1 (ja) |
BR (1) | BR112017013349A2 (ja) |
CA (1) | CA2971945A1 (ja) |
ES (1) | ES2785324T3 (ja) |
FR (1) | FR3030548B1 (ja) |
MX (1) | MX2017008238A (ja) |
RU (1) | RU2704185C2 (ja) |
WO (1) | WO2016102481A1 (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3067968B1 (fr) * | 2017-06-22 | 2020-11-06 | Arkema France | Materiau fibreux impregne de polymere thermoplastique |
EP3572205B1 (en) * | 2018-05-24 | 2021-07-07 | Rhodia Operations | Process for manufacturing composite articles |
WO2020038584A1 (en) | 2018-08-23 | 2020-02-27 | Rhodia Operations | Composites with flow enhancing structures and process for their manufacture |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100227962A1 (en) * | 2007-09-18 | 2010-09-09 | Caroll Vergelati | Thermoplastic polyamide compositions having enhanced melt flow indices |
US20120264864A1 (en) * | 2009-10-20 | 2012-10-18 | C.N.R.S. | Modified polyamide composition containing at least one phenolic compound |
JP2012532937A (ja) * | 2009-07-09 | 2012-12-20 | ロディア オペレーションズ | ポリアミド複合物品 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU737413A1 (ru) | 1977-12-16 | 1980-05-30 | Ленинградский Ордена Трудового Красного Знамени Технологический Институт Им. Ленсовета | Способ переработки ароматических полиамидов |
ATE176388T1 (de) | 1992-03-16 | 1999-02-15 | Macarthur Onslow Rohan James | Essgerät |
BE1008134A3 (nl) | 1994-03-16 | 1996-01-23 | Dsm Nv | Bereiding van stervormig vertakte polymeren. |
EP0682057A1 (en) | 1994-05-09 | 1995-11-15 | Dsm N.V. | Process for improvement of the processing characteristics of a polymer composition and polymer compositions obtained therefrom |
US5403875A (en) | 1994-05-12 | 1995-04-04 | Rohm And Haas Company | Melt-processed polymer blends |
EP0832149B1 (en) | 1995-05-03 | 2000-07-19 | Dsm N.V. | Star-shaped branched polyamide |
FR2743077B1 (fr) | 1995-12-29 | 1998-02-20 | Nyltech Italia | Polyamide et un procede de fabrication de celui-ci, et des compositions le contenant |
DE19654179A1 (de) | 1996-12-23 | 1998-06-25 | Basf Ag | H-förmige Polyamide |
RU2129134C1 (ru) | 1997-04-28 | 1999-04-20 | Товарищество с ограниченной ответственностью Научно-техническая фирма "Поларм" | Термопластичная композиция |
FR2766197B1 (fr) | 1997-07-17 | 1999-09-03 | Nyltech Italia | Copolyamide thermoplastique, composition a base de ce copolyamide thermoplastique |
FR2779730B1 (fr) | 1998-06-11 | 2004-07-16 | Nyltech Italia | Polyamides a fluidite elevee, son procede de fabrication, compositions comprenant ce copolyamide |
FR2793252B1 (fr) | 1999-05-05 | 2001-07-20 | Rhodianyl | Copolyamide hyperbranche, composition a base de ce copolyamide hyperbranche et procede d'obtention de ce dernier |
GB0020620D0 (en) | 2000-08-22 | 2000-10-11 | Cytec Tech Corp | Compostions adapted for chain linking |
FR2953755B1 (fr) | 2009-12-14 | 2012-01-20 | Rhodia Operations | Procede de fabrication d'articles composite a base de polyamide |
EP2615139B1 (en) | 2011-04-12 | 2016-03-30 | Mitsubishi Gas Chemical Company, Inc. | Polyamide resin-based composite material and method for producing same |
JP2013133354A (ja) * | 2011-12-26 | 2013-07-08 | Fuji Xerox Co Ltd | 樹脂化合物、樹脂組成物、及び樹脂成形体 |
FR2992321B1 (fr) * | 2012-06-22 | 2015-06-05 | Arkema France | Procede de fabrication d'un materiau fibreux pre-impregne de polymere thermoplastique. |
WO2014050303A1 (ja) | 2012-09-25 | 2014-04-03 | 三菱瓦斯化学株式会社 | 繊維強化ポリアミド樹脂材料 |
WO2014121842A1 (fr) * | 2013-02-08 | 2014-08-14 | Rhodia Operations | Composition d'un alliage de resines de polyamide et de polyester |
-
2014
- 2014-12-22 FR FR1463108A patent/FR3030548B1/fr not_active Expired - Fee Related
-
2015
- 2015-12-21 CA CA2971945A patent/CA2971945A1/en not_active Abandoned
- 2015-12-21 BR BR112017013349-0A patent/BR112017013349A2/pt not_active Application Discontinuation
- 2015-12-21 US US15/534,829 patent/US10584241B2/en not_active Expired - Fee Related
- 2015-12-21 WO PCT/EP2015/080818 patent/WO2016102481A1/fr active Application Filing
- 2015-12-21 RU RU2017126063A patent/RU2704185C2/ru active
- 2015-12-21 AU AU2015371136A patent/AU2015371136C1/en not_active Ceased
- 2015-12-21 CN CN201580076752.9A patent/CN107250276A/zh active Pending
- 2015-12-21 KR KR1020177019096A patent/KR20170097094A/ko active Search and Examination
- 2015-12-21 ES ES15820513T patent/ES2785324T3/es active Active
- 2015-12-21 MX MX2017008238A patent/MX2017008238A/es unknown
- 2015-12-21 EP EP15820513.8A patent/EP3237544B1/fr active Active
- 2015-12-21 JP JP2017533433A patent/JP6693960B2/ja not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100227962A1 (en) * | 2007-09-18 | 2010-09-09 | Caroll Vergelati | Thermoplastic polyamide compositions having enhanced melt flow indices |
JP2011500875A (ja) * | 2007-09-18 | 2011-01-06 | ロディア オペレーションズ | ポリアミド組成物 |
JP2012532937A (ja) * | 2009-07-09 | 2012-12-20 | ロディア オペレーションズ | ポリアミド複合物品 |
US20120264864A1 (en) * | 2009-10-20 | 2012-10-18 | C.N.R.S. | Modified polyamide composition containing at least one phenolic compound |
Also Published As
Publication number | Publication date |
---|---|
ES2785324T3 (es) | 2020-10-06 |
MX2017008238A (es) | 2017-10-06 |
BR112017013349A2 (pt) | 2018-03-06 |
FR3030548B1 (fr) | 2018-03-30 |
EP3237544B1 (fr) | 2020-02-12 |
EP3237544A1 (fr) | 2017-11-01 |
WO2016102481A1 (fr) | 2016-06-30 |
AU2015371136A1 (en) | 2017-06-29 |
RU2704185C2 (ru) | 2019-10-24 |
KR20170097094A (ko) | 2017-08-25 |
CN107250276A (zh) | 2017-10-13 |
JP6693960B2 (ja) | 2020-05-13 |
US10584241B2 (en) | 2020-03-10 |
CA2971945A1 (en) | 2016-06-30 |
US20170342267A1 (en) | 2017-11-30 |
RU2017126063A3 (ja) | 2019-04-19 |
AU2015371136C1 (en) | 2020-03-12 |
RU2017126063A (ru) | 2019-01-24 |
AU2015371136B2 (en) | 2019-11-28 |
FR3030548A1 (fr) | 2016-06-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6140862B2 (ja) | 複合ポリアミド物品 | |
JP6328554B2 (ja) | 安定化剤としてのポリアミド鎖延長化合物の使用 | |
JP5969641B2 (ja) | 低分子量ポリアミド樹脂を基材とする複合物品 | |
JP2011500875A (ja) | ポリアミド組成物 | |
JP2012532937A (ja) | ポリアミド複合物品 | |
JP2012532938A (ja) | ポリアミド複合物品 | |
CN111670221B (zh) | 高耐热性的聚酰胺模塑复合物 | |
CN107109054B (zh) | 具有改进的流动性的聚酰胺混合物 | |
CN102892810A (zh) | 复合聚酰胺制品 | |
JP6693960B2 (ja) | 高流動性を有する熱可塑性樹脂組成物 | |
EP3572205A1 (en) | Process for manufacturing composite articles |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20181206 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20181206 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20191010 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20191119 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200219 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20200407 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20200416 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6693960 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
LAPS | Cancellation because of no payment of annual fees |