JP2018145621A - 壁紙 - Google Patents
壁紙 Download PDFInfo
- Publication number
- JP2018145621A JP2018145621A JP2017039180A JP2017039180A JP2018145621A JP 2018145621 A JP2018145621 A JP 2018145621A JP 2017039180 A JP2017039180 A JP 2017039180A JP 2017039180 A JP2017039180 A JP 2017039180A JP 2018145621 A JP2018145621 A JP 2018145621A
- Authority
- JP
- Japan
- Prior art keywords
- wallpaper
- surface protective
- layer
- protective layer
- paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010410 layer Substances 0.000 claims abstract description 64
- 229920005989 resin Polymers 0.000 claims abstract description 57
- 239000011347 resin Substances 0.000 claims abstract description 56
- 239000011241 protective layer Substances 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 25
- 238000007639 printing Methods 0.000 claims abstract description 24
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 19
- 239000012209 synthetic fiber Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 17
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 17
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 8
- 239000004088 foaming agent Substances 0.000 claims description 28
- 238000005187 foaming Methods 0.000 claims description 15
- 238000004049 embossing Methods 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 9
- 239000011256 inorganic filler Substances 0.000 claims description 7
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 7
- 239000011342 resin composition Substances 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 5
- 239000005871 repellent Substances 0.000 claims description 2
- 230000002940 repellent Effects 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 11
- 230000001070 adhesive effect Effects 0.000 abstract description 11
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- 230000008602 contraction Effects 0.000 abstract description 3
- 239000012466 permeate Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 18
- 238000000576 coating method Methods 0.000 description 11
- 239000000976 ink Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 239000003086 colorant Substances 0.000 description 5
- 239000003292 glue Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- -1 silicas Chemical compound 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 238000007646 gravure printing Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000007607 die coating method Methods 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 2
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 238000010345 tape casting Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- FWLHAQYOFMQTHQ-UHFFFAOYSA-N 2-N-[8-[[8-(4-aminoanilino)-10-phenylphenazin-10-ium-2-yl]amino]-10-phenylphenazin-10-ium-2-yl]-8-N,10-diphenylphenazin-10-ium-2,8-diamine hydroxy-oxido-dioxochromium Chemical compound O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.Nc1ccc(Nc2ccc3nc4ccc(Nc5ccc6nc7ccc(Nc8ccc9nc%10ccc(Nc%11ccccc%11)cc%10[n+](-c%10ccccc%10)c9c8)cc7[n+](-c7ccccc7)c6c5)cc4[n+](-c4ccccc4)c3c2)cc1 FWLHAQYOFMQTHQ-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- HZEWFHLRYVTOIW-UHFFFAOYSA-N [Ti].[Ni] Chemical compound [Ti].[Ni] HZEWFHLRYVTOIW-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- GWVMLCQWXVFZCN-UHFFFAOYSA-N isoindoline Chemical compound C1=CC=C2CNCC2=C1 GWVMLCQWXVFZCN-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- OBJNZHVOCNPSCS-UHFFFAOYSA-N naphtho[2,3-f]quinazoline Chemical compound C1=NC=C2C3=CC4=CC=CC=C4C=C3C=CC2=N1 OBJNZHVOCNPSCS-UHFFFAOYSA-N 0.000 description 1
- 229910001000 nickel titanium Inorganic materials 0.000 description 1
- 125000000018 nitroso group Chemical group N(=O)* 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007763 reverse roll coating Methods 0.000 description 1
- 238000007777 rotary screen coating Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Images
Landscapes
- Paper (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Description
前記紙基材が疎水性の合成繊維と天然パルプとを含む混抄紙から成り、かつ、前記表面保護層がアクリル樹脂を主成分とすることを特徴とする壁紙である。
紙基材1は、いわゆる壁紙用裏打紙(繊維質シート)である。本発明においては、紙基材1は合成繊維と天然パルプとを含む混抄紙で構成されている必要がある。
維の重量は、天然パルプの重量の50%以上を占めることが望ましい。例えば、天然繊維パルプと疎水性合成繊維とを2〜3:1の質量比で混抄した紙である。なお、このような疎水性合成繊維としては、ポリエステル又はアクリル樹脂を素材とする合成繊維が使用できる。
発泡樹脂層2は、発泡剤を含有した発泡剤含有樹脂組成物を塗工した後、その樹脂組成物に含まれる発泡剤を加熱発泡させることによって形成することができる。発泡剤含有樹脂組成物は、水性エマルジョン系樹脂、無機フィラー及び発泡剤を混合して製造することができる。なお、この他、この発泡剤含有樹脂組成物には他の添加物を配合することができる。例えば着色剤である。
絵柄印刷層3は、発泡壁紙10に意匠性を付与する。絵柄印刷層3は、例えば、発泡樹
脂層2(発泡剤含有樹脂層)の表面に絵柄模様を印刷することで形成できる。絵柄印刷層3の厚みは、絵柄模様の種類より異なるが、一般には0.1μm以上10μm以下程度とすることが好ましい。
表面保護層4は、絵柄印刷層3の表面に、艶調整や絵柄印刷層3の保護を意図して形成されるものである。また、これに加えて、施工時に水性接着剤(糊)を適用した際に、壁紙の伸張を防ぐと共に、乾燥に伴う収縮を防止する機能を有している。このような機能を発揮するため、表面保護層4はアクリル樹脂を主成分として構成する必要がある。なお、表面保護層4には、アクリル樹脂のほか、艶調整を目的としてフィラーを添加することができる。また、表面保護層4は撥水性を有することが望ましい。
以上のように、壁紙10は、紙基材1の上に、順次、発泡剤含有樹脂層、絵柄印刷層3及び表面保護層4を塗布又は印刷し、その後、発泡剤含有樹脂層を加熱発泡させて発泡樹脂層2を形成することによって製造することができる。また、加熱発泡と同時又は加熱発泡の直後に、表面保護層4側からエンボスを施すことにより、図1のように、エンボス模様5を有する壁紙10を製造することができる。
紙基材1として、天然パルプと疎水性合成繊維とを2〜3:1の質量比で混抄した混抄紙を使用した。坪量は85g/m2である。
紙基材1として、天然パルプのみをパルプ成分とし、合成繊維を含有しない紙(坪量:85g/m2)を使用し、かつ、表面保護層4を形成することなく、壁紙を製造した。その他は実施例と同様である。
紙基材1として、天然パルプのみをパルプ成分とし、合成繊維を含有しない紙(坪量:85g/m2)を使用して、壁紙を製造した。その他は実施例と同様である。
実施例及び比較例1,2の壁紙について、水中に浸漬したときの伸縮性を評価した。この評価結果は、壁紙に水性接着剤(糊)を適用して施工した後、この壁紙が自然乾燥したときの収縮率の目安として利用できる。
水中伸縮率(%)=(Lmax−Lmin)/Lmax×100%
この結果を表1に示す。なお、表中、「○」は壁紙として優れた非伸縮性を有することを意味し、「×」は十分な非伸縮性がないことを示す。
Claims (10)
- 紙基材、発泡樹脂層、絵柄印刷層及び表面保護層がこの順に積層された壁紙において、
前記紙基材が疎水性の合成繊維と天然パルプとを含む混抄紙から成り、かつ、前記表面保護層がアクリル樹脂を主成分とすることを特徴とする壁紙。 - 前記合成繊維の重量が、天然パルプの重量の50%以上であることを特徴とする請求項1に記載の壁紙。
- 前記混抄紙の坪量が50〜100g/m2であることを特徴とする請求項1又は2に記載の壁紙。
- 前記混抄紙の厚みが100〜200μmであることを特徴とする請求項1〜3のいずれかに記載の壁紙。
- 前記表面保護層が撥水性であることを特徴とする請求項1〜4のいずれかに記載の壁紙。
- 前記表面保護層の坪量が10〜40g/m2であることを特徴とする請求項1〜5のいずれかに記載の壁紙。
- 前記表面保護層がフィラーを含有することを特徴とする請求項1〜6のいずれかに記載の壁紙。
- 前記表面保護層側からエンボスが施されていることを特徴とする請求項1〜7のいずれかに記載の壁紙。
- 前記発泡樹脂層が、水性エマルジョン系樹脂、無機フィラー及び発泡剤を含有する発泡性樹脂組成物を4倍以上の発泡倍率で発泡させて構成されており、その坪量が50〜150g/m2であることを特徴とする請求項1〜8のいずれかに記載の壁紙。
- 前記発泡樹脂層が水性エマルジョン系樹脂100質量部に対して無機フィラーを50質量部以上150質量部以下の範囲内、発泡剤を1質量部以上20質量部以下の範囲内で含有していることを特徴とする請求項9に記載の壁紙。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017039180A JP7336827B2 (ja) | 2017-03-02 | 2017-03-02 | 壁紙 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017039180A JP7336827B2 (ja) | 2017-03-02 | 2017-03-02 | 壁紙 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2018145621A true JP2018145621A (ja) | 2018-09-20 |
JP7336827B2 JP7336827B2 (ja) | 2023-09-01 |
Family
ID=63589640
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017039180A Active JP7336827B2 (ja) | 2017-03-02 | 2017-03-02 | 壁紙 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP7336827B2 (ja) |
Citations (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0647875A (ja) * | 1992-02-25 | 1994-02-22 | Achilles Corp | 装飾シートおよびその製造方法 |
JP2001058375A (ja) * | 1999-08-20 | 2001-03-06 | Dainippon Printing Co Ltd | 壁装用シート |
JP2003286699A (ja) * | 2002-03-27 | 2003-10-10 | Yoshikawa Kami Shoji Kk | 抄造された壁紙加工用原紙とその製造方法 |
JP2005211709A (ja) * | 2004-01-27 | 2005-08-11 | Toli Corp | 壁紙、及び壁紙用表面処理剤、及び壁紙の改装方法 |
JP2005299017A (ja) * | 2004-04-13 | 2005-10-27 | Toppan Printing Co Ltd | 壁紙 |
JP2006200111A (ja) * | 2004-12-20 | 2006-08-03 | Yoshio Imai | 通気性壁紙およびその製造方法 |
JP2007313900A (ja) * | 2005-03-29 | 2007-12-06 | Dainippon Printing Co Ltd | 壁装用化粧シート |
JP2007332527A (ja) * | 2006-06-09 | 2007-12-27 | Celanese Internatl Corp | 水性下地被膜を有する合成不織壁紙 |
JP2008081890A (ja) * | 2006-09-27 | 2008-04-10 | Dainippon Printing Co Ltd | 発泡壁紙 |
JP4205562B2 (ja) * | 2003-11-27 | 2009-01-07 | アキレス株式会社 | 壁紙およびその施工方法 |
JP2009019293A (ja) * | 2007-07-10 | 2009-01-29 | Asahipen Corp | 粘着壁紙 |
JP2009214315A (ja) * | 2008-03-07 | 2009-09-24 | Toppan Printing Co Ltd | 発泡化粧材 |
JP2010116631A (ja) * | 2008-11-11 | 2010-05-27 | Okamoto Ind Inc | 壁紙 |
JP2011074693A (ja) * | 2009-09-30 | 2011-04-14 | Dainippon Printing Co Ltd | 接着壁紙及び壁紙用接着剤組成物 |
JP2011094312A (ja) * | 2009-10-27 | 2011-05-12 | Toppan Printing Co Ltd | 発泡壁紙 |
JP4766968B2 (ja) * | 2005-09-13 | 2011-09-07 | 日本製紙株式会社 | 壁紙用裏打ち紙 |
JP4888005B2 (ja) * | 2006-09-26 | 2012-02-29 | 大日本印刷株式会社 | 壁紙 |
JP2012117222A (ja) * | 2010-11-29 | 2012-06-21 | Suminoe Textile Co Ltd | 防汚消臭壁紙 |
JP2013209790A (ja) * | 2013-05-27 | 2013-10-10 | Dainippon Printing Co Ltd | 発泡壁紙の製造方法 |
JP2014069577A (ja) * | 2013-11-28 | 2014-04-21 | Dainippon Printing Co Ltd | 発泡積層シート |
JP2016199646A (ja) * | 2015-04-08 | 2016-12-01 | 凸版印刷株式会社 | 樹脂組成物、積層シート、積層体、発泡壁紙及び発泡壁紙の製造方法 |
-
2017
- 2017-03-02 JP JP2017039180A patent/JP7336827B2/ja active Active
Patent Citations (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0647875A (ja) * | 1992-02-25 | 1994-02-22 | Achilles Corp | 装飾シートおよびその製造方法 |
JP2001058375A (ja) * | 1999-08-20 | 2001-03-06 | Dainippon Printing Co Ltd | 壁装用シート |
JP2003286699A (ja) * | 2002-03-27 | 2003-10-10 | Yoshikawa Kami Shoji Kk | 抄造された壁紙加工用原紙とその製造方法 |
JP4205562B2 (ja) * | 2003-11-27 | 2009-01-07 | アキレス株式会社 | 壁紙およびその施工方法 |
JP2005211709A (ja) * | 2004-01-27 | 2005-08-11 | Toli Corp | 壁紙、及び壁紙用表面処理剤、及び壁紙の改装方法 |
JP2005299017A (ja) * | 2004-04-13 | 2005-10-27 | Toppan Printing Co Ltd | 壁紙 |
JP2006200111A (ja) * | 2004-12-20 | 2006-08-03 | Yoshio Imai | 通気性壁紙およびその製造方法 |
JP2007313900A (ja) * | 2005-03-29 | 2007-12-06 | Dainippon Printing Co Ltd | 壁装用化粧シート |
JP4766968B2 (ja) * | 2005-09-13 | 2011-09-07 | 日本製紙株式会社 | 壁紙用裏打ち紙 |
JP2007332527A (ja) * | 2006-06-09 | 2007-12-27 | Celanese Internatl Corp | 水性下地被膜を有する合成不織壁紙 |
JP4888005B2 (ja) * | 2006-09-26 | 2012-02-29 | 大日本印刷株式会社 | 壁紙 |
JP2008081890A (ja) * | 2006-09-27 | 2008-04-10 | Dainippon Printing Co Ltd | 発泡壁紙 |
JP2009019293A (ja) * | 2007-07-10 | 2009-01-29 | Asahipen Corp | 粘着壁紙 |
JP2009214315A (ja) * | 2008-03-07 | 2009-09-24 | Toppan Printing Co Ltd | 発泡化粧材 |
JP2010116631A (ja) * | 2008-11-11 | 2010-05-27 | Okamoto Ind Inc | 壁紙 |
JP2011074693A (ja) * | 2009-09-30 | 2011-04-14 | Dainippon Printing Co Ltd | 接着壁紙及び壁紙用接着剤組成物 |
JP2011094312A (ja) * | 2009-10-27 | 2011-05-12 | Toppan Printing Co Ltd | 発泡壁紙 |
JP2012117222A (ja) * | 2010-11-29 | 2012-06-21 | Suminoe Textile Co Ltd | 防汚消臭壁紙 |
JP2013209790A (ja) * | 2013-05-27 | 2013-10-10 | Dainippon Printing Co Ltd | 発泡壁紙の製造方法 |
JP2014069577A (ja) * | 2013-11-28 | 2014-04-21 | Dainippon Printing Co Ltd | 発泡積層シート |
JP2016199646A (ja) * | 2015-04-08 | 2016-12-01 | 凸版印刷株式会社 | 樹脂組成物、積層シート、積層体、発泡壁紙及び発泡壁紙の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
JP7336827B2 (ja) | 2023-09-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6930067B2 (ja) | 発泡壁紙、及び発泡壁紙の製造方法 | |
JP2014144644A (ja) | 発泡化粧シートの発泡前のシート、並びに発泡化粧シートの発泡前のシートの製造方法及び発泡化粧シートの製造方法 | |
JP4942682B2 (ja) | 発泡壁紙 | |
JP4765470B2 (ja) | 発泡壁紙 | |
JP5672864B2 (ja) | 発泡化粧シート | |
JP4110422B2 (ja) | 発泡壁紙 | |
JP6930066B2 (ja) | 発泡壁紙、及び発泡壁紙の製造方法 | |
JP4009873B2 (ja) | 発泡壁紙 | |
JP7043725B2 (ja) | 発泡壁紙及び発泡壁紙の製造方法 | |
JP6866568B2 (ja) | 発泡壁紙、及び発泡壁紙の製造方法 | |
JP2018145621A (ja) | 壁紙 | |
JP2006272693A (ja) | 壁装用化粧シート | |
JP5195960B2 (ja) | 発泡壁紙 | |
JP5392322B2 (ja) | 壁装用化粧シート及びその製造方法 | |
JP2019142202A (ja) | 発泡積層シート | |
JP4765469B2 (ja) | 発泡壁紙 | |
JPH10137678A (ja) | 立体模様化粧シート及びその製造方法 | |
JP5938996B2 (ja) | 積層シート及び発泡積層シート | |
JP6801360B2 (ja) | 発泡壁紙 | |
JP4793051B2 (ja) | 壁装用化粧シート原反及び壁装用化粧シート | |
JP2019085673A (ja) | 発泡壁紙、発泡壁紙の製造方法 | |
JP5476893B2 (ja) | 発泡化粧シート | |
JP2019085674A (ja) | 発泡壁紙、発泡壁紙の製造方法 | |
JP4606220B2 (ja) | 壁装用化粧シート | |
JP4707434B2 (ja) | 壁装用化粧シート |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20200221 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20201225 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210202 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20210222 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210706 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20210825 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20220111 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20220330 |
|
C60 | Trial request (containing other claim documents, opposition documents) |
Free format text: JAPANESE INTERMEDIATE CODE: C60 Effective date: 20220330 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20220406 |
|
C21 | Notice of transfer of a case for reconsideration by examiners before appeal proceedings |
Free format text: JAPANESE INTERMEDIATE CODE: C21 Effective date: 20220412 |
|
A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20220527 |
|
C211 | Notice of termination of reconsideration by examiners before appeal proceedings |
Free format text: JAPANESE INTERMEDIATE CODE: C211 Effective date: 20220531 |
|
C22 | Notice of designation (change) of administrative judge |
Free format text: JAPANESE INTERMEDIATE CODE: C22 Effective date: 20221101 |
|
C22 | Notice of designation (change) of administrative judge |
Free format text: JAPANESE INTERMEDIATE CODE: C22 Effective date: 20221122 |
|
C13 | Notice of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: C13 Effective date: 20221213 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230125 |
|
C13 | Notice of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: C13 Effective date: 20230314 |
|
C22 | Notice of designation (change) of administrative judge |
Free format text: JAPANESE INTERMEDIATE CODE: C22 Effective date: 20230425 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20230512 |
|
RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20230512 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20230822 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 7336827 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |