JP2018012665A - Foamable aerosol composition - Google Patents
Foamable aerosol composition Download PDFInfo
- Publication number
- JP2018012665A JP2018012665A JP2016143594A JP2016143594A JP2018012665A JP 2018012665 A JP2018012665 A JP 2018012665A JP 2016143594 A JP2016143594 A JP 2016143594A JP 2016143594 A JP2016143594 A JP 2016143594A JP 2018012665 A JP2018012665 A JP 2018012665A
- Authority
- JP
- Japan
- Prior art keywords
- mass
- aerosol composition
- oily
- foam
- stock solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 65
- 239000000203 mixture Substances 0.000 title claims abstract description 60
- 239000011550 stock solution Substances 0.000 claims abstract description 38
- 239000000463 material Substances 0.000 claims abstract description 34
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- 239000010696 ester oil Substances 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 4
- 239000006260 foam Substances 0.000 abstract description 45
- 239000007788 liquid Substances 0.000 abstract description 17
- 239000000243 solution Substances 0.000 abstract 1
- -1 polysiloxane Polymers 0.000 description 37
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 30
- 239000003921 oil Substances 0.000 description 26
- 235000019198 oils Nutrition 0.000 description 26
- 235000014113 dietary fatty acids Nutrition 0.000 description 22
- 239000000194 fatty acid Substances 0.000 description 22
- 229930195729 fatty acid Natural products 0.000 description 22
- 239000000843 powder Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- 239000002253 acid Substances 0.000 description 14
- 150000004665 fatty acids Chemical class 0.000 description 14
- 239000007789 gas Substances 0.000 description 13
- 239000004480 active ingredient Substances 0.000 description 12
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 12
- 150000001298 alcohols Chemical class 0.000 description 10
- 239000003240 coconut oil Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 229960003237 betaine Drugs 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000005187 foaming Methods 0.000 description 5
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- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
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- 239000003925 fat Substances 0.000 description 4
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- 238000009472 formulation Methods 0.000 description 4
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 4
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- 229940039717 lanolin Drugs 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
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- 229920001214 Polysorbate 60 Polymers 0.000 description 3
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- OGELJRHPEZALCC-UHFFFAOYSA-N [3-(2,3-dihydroxypropoxy)-2-hydroxypropyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(O)COCC(O)CO OGELJRHPEZALCC-UHFFFAOYSA-N 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
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- 229920001577 copolymer Polymers 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
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- 239000002736 nonionic surfactant Substances 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 239000004006 olive oil Substances 0.000 description 3
- 235000008390 olive oil Nutrition 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
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- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 229940024606 amino acid Drugs 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
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- CUFNKYGDVFVPHO-UHFFFAOYSA-N azulene Chemical compound C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 2
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 2
- 235000014593 oils and fats Nutrition 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- SSZBUIDZHHWXNJ-UHFFFAOYSA-N palmityl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC SSZBUIDZHHWXNJ-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
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Landscapes
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
Abstract
Description
本発明は、発泡性エアゾール組成物に関する。より詳細には、本発明は、油性基材を多量に含んでいるにもかかわらず、優れた弾力性を有し、泡持ちが良く、火気に対する安全性が高いフォームを形成することのできる発泡性エアゾール組成物に関する。 The present invention relates to a foamable aerosol composition. More specifically, the present invention is a foam capable of forming a foam having excellent elasticity, good foam retention, and high safety against fire despite containing a large amount of oily base material. The present invention relates to a functional aerosol composition.
従来、引火性の低減されたフォームを形成するエアゾール組成物が開発されている。特許文献１には、原液が液状油脂類よりなる引火性成分を含有し、噴射剤がトランス−１，３，３，３−テトラフルオロプロペン（ハイドロフルオロオレフィン）よりなり、当該噴射剤のエアゾール組成物１００質量％における含有割合が５〜４０質量％であるエアゾール組成物が開示されている。 Conventionally, aerosol compositions have been developed that form foams with reduced flammability. In Patent Document 1, the stock solution contains a flammable component made of liquid oils and fats, the propellant is made of trans-1,3,3,3-tetrafluoropropene (hydrofluoroolefin), and the aerosol composition of the propellant The aerosol composition whose content rate in 100 mass% of things is 5-40 mass% is disclosed.
特許文献１に記載のエアゾール組成物は、たとえば処方５および処方６として、それぞれハイドロフルオロオレフィンを含有するフォーム用エアゾール組成物が開示されている。しかしながら、これらフォーム用エアゾール組成物は、原液中に含まれる精製水の量が多く、液状油脂類が少ない。また、特許文献１に記載のエアゾール組成物は、泡立ちが不充分であり、消泡して流れ落ちやすい。さらに、得られる泡は、充分な弾力を有していない。 As the aerosol composition described in Patent Document 1, for example, as a formulation 5 and a formulation 6, a foam aerosol composition containing a hydrofluoroolefin is disclosed. However, these foam aerosol compositions have a large amount of purified water contained in the stock solution and a small amount of liquid fats and oils. In addition, the aerosol composition described in Patent Document 1 has insufficient foaming and is easy to flow out after being removed. Furthermore, the resulting foam does not have sufficient elasticity.
本発明は、このような従来の課題に鑑みてなされたものであり、油性基材を多く含んでいるにもかかわらず、優れた弾力性を有し、泡持ちが良く、火気に対する安全性が高いフォームを形成することのできる発泡性エアゾール組成物を提供することを目的とする。 The present invention has been made in view of such conventional problems, and despite having a large amount of oily base material, has excellent elasticity, good foam retention, and safety against fire. An object is to provide a foamable aerosol composition capable of forming a high foam.
上記課題を解決する本発明の吐出製品には、以下の構成が主に含まれる。 The discharge product of the present invention that solves the above problems mainly includes the following configurations.
（１）油性基材と界面活性剤とを含む油性原液と、液化ガスと、を含む発泡性エアゾール組成物であり、前記油性基材は、前記油性原液中に、７０〜９８質量％含まれ、前記液化ガスは、ハイドロフルオロオレフィンであり、発泡性エアゾール組成物中に、５〜５０質量％含まれる、発泡性エアゾール組成物。 (1) A foamable aerosol composition comprising an oily stock solution containing an oily base material and a surfactant, and a liquefied gas, wherein the oily base material is contained in an amount of 70 to 98% by mass in the oily stock solution. The liquefied gas is hydrofluoroolefin, and the foamable aerosol composition is contained in the foamable aerosol composition in an amount of 5 to 50% by mass.
このような構成によれば、本発明の発泡性エアゾール組成物は、油性基材を油性原液中に７０〜９８質量％含み、ハイドロフルオロオレフィンを５〜５０質量％含んでいるため、得られる吐出物は、ハイドロフルオロオレフィンが気化することによってきめ細かいフォームとなる。また、このようなフォームは、優れた弾力性を有し、かつ、泡持ちが良く流れ落ちにくい。また、このようなフォームは、火気に対して安全性が高い。 According to such a structure, since the foamable aerosol composition of the present invention contains 70 to 98% by mass of the oily base material in the oily stock solution and 5 to 50% by mass of the hydrofluoroolefin, the resulting discharge is obtained. The product becomes a fine foam as the hydrofluoroolefin vaporizes. Moreover, such a foam has excellent elasticity and has good foam resistance and is difficult to flow down. Also, such foam is highly safe against fire.
（２）前記油性基材は、エステル油および油脂のうち少なくともいずれか一方を含む、（１）記載の発泡性エアゾール組成物。 (2) The foamable aerosol composition according to (1), wherein the oily base material contains at least one of ester oil and fat.
このような構成によれば、得られる吐出物は、フォーム状となりやすい。 According to such a configuration, the obtained discharge tends to be in the form of a foam.
（３）前記ハイドロフルオロオレフィンは、エアゾール組成物中に、１０〜３５質量％含まれる、（１）または（２）記載の発泡性エアゾール組成物。 (3) The foamable aerosol composition according to (1) or (2), wherein the hydrofluoroolefin is contained in an amount of 10 to 35% by mass in the aerosol composition.
このような構成によれば、得られる吐出物は、より優れた弾力性を有するフォームとなりやすい。 According to such a configuration, the obtained discharge is likely to be a foam having more excellent elasticity.
本発明によれば、油性基材を多く含んでいるにもかかわらず、優れた弾力性を有し、泡持ちが良く、火気に対する安全性が高いフォームを形成することのできる発泡性エアゾール組成物を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, although it contains many oily base materials, it has the outstanding elasticity, a foam retention is good, and the foamable aerosol composition which can form foam with high safety | security with respect to a fire Can be provided.
＜発泡性エアゾール組成物＞
本発明の一実施形態の発泡性エアゾール組成物（以下、エアゾール組成物ともいう）は、油性原液と、液化ガスと、を含む。以下、それぞれの構成について説明する。
<Foaming aerosol composition>
The foamable aerosol composition according to one embodiment of the present invention (hereinafter also referred to as an aerosol composition) includes an oily stock solution and a liquefied gas. Hereinafter, each configuration will be described.
（油性原液）
油性原液は、本実施形態のエアゾール組成物を構成する油性成分であり、油性基材と界面活性剤とを主に含む。
(Oil concentrate)
The oily stock solution is an oily component constituting the aerosol composition of the present embodiment, and mainly contains an oily base material and a surfactant.
・油性基材
油性基材は、油性原液の主たる成分であり、吐出されることによりフォームの液膜を構成し、皮膚に潤いや艶を与える、クレンジング効果を得る等の目的で配合される。
-Oily base material The oily base material is the main component of the oily stock solution, and forms a liquid film of foam by being discharged, and is blended for the purpose of moisturizing and glossing the skin and obtaining a cleansing effect.
油性基材としては、エステル油、油脂、炭化水素油、シリコーンオイル、液状の高級脂肪酸、液状の高級アルコール等の、２５℃において液状である液状油が例示される。これらの中でも、油性基材は、得られる吐出物が発泡してフォームを形成しやすい点から、エステル油および油脂のうち少なくともいずれか一方を含んでいることが好ましい。これらは併用されてもよい。 Examples of the oily base material include liquid oils that are liquid at 25 ° C., such as ester oils, fats and oils, hydrocarbon oils, silicone oils, liquid higher fatty acids, liquid higher alcohols, and the like. Among these, it is preferable that the oil-based base material contains at least one of ester oils and fats and oils from the viewpoint that the obtained discharged product is easily foamed to form a foam. These may be used in combination.
エステル油としては、ミリスチン酸イソプロピル、ミリスチン酸ミリスチル、オレイン酸デシル、ラウリン酸イソステアリル、ミリスチン酸イソセチル、ミリスチン酸イソステアリル、ミリスチン酸オクチルドデシル、パルミチン酸オクチル、ステアリン酸オクチル、オレイン酸オクチルドデシル、イソステアリン酸エチル、イソオクタン酸セチル、ジオクタン酸エチレングリコール、ジオレイン酸エチレングリコール、ジカプリル酸プロピレングリコール、ジオレイン酸プロピレングリコール、トリカプリル酸グリセリル、トリ（カプリル・カプリン酸）グリセリル、トリイソステアリン酸グリセリル、トリ２−エチルへキサン酸トリメチロールプロパン、ネオペンタン酸オクチルドデシル、ジメチルオクタン酸ヘキシルデシル、乳酸セチル、クエン酸トリエチル、コハク酸ジオクチル、アジピン酸ジイソプロピル、コハク酸ジエトキシエチル等が例示される。 Ester oils include isopropyl myristate, myristyl myristate, decyl oleate, isostearyl laurate, isocetyl myristate, isostearyl myristate, octyldodecyl myristate, octyl palmitate, octyl stearate, octyldodecyl oleate, isostearic acid Ethyl acid, cetyl isooctanoate, ethylene glycol dioctanoate, ethylene glycol dioleate, propylene glycol dicaprylate, propylene glycol dioleate, glyceryl tricaprylate, glyceryl tri (capryl / caprate), glyceryl triisostearate, tri-2-ethyl Trimethylolpropane xanthate, octyldodecyl neopentanoate, hexyldecyl dimethyloctanoate, cetyl lactate , Triethyl citrate, dioctyl succinate, diisopropyl adipate, diethoxyethyl succinate and the like.
油脂としては、アボカド油、ツバキ油、タートル油、マカデミアナッツ油、トウモロコシ油、ミンク油、オリーブ油、ナタネ油、ゴマ油、ヒマシ油、アマニ油、サフラワー油、ホホバ油、麦芽油、ヤシ油、パーム油等が例示される。 As fats and oils, avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, sesame oil, castor oil, linseed oil, safflower oil, jojoba oil, malt oil, coconut oil, palm oil Etc. are exemplified.
炭化水素油としては、ケロシン、流動パラフィン、スクワレン、スクワラン、イソパラフィン等が例示される。 Examples of the hydrocarbon oil include kerosene, liquid paraffin, squalene, squalane and isoparaffin.
シリコーンオイルとしては、メチルポリシロキサン、メチルフェニルポリシロキサン、メチルハイドロジェンポリシロキサン、メチルポリシクロシロキサン等が例示される。 Examples of the silicone oil include methyl polysiloxane, methyl phenyl polysiloxane, methyl hydrogen polysiloxane, methyl polycyclosiloxane, and the like.
液状の高級脂肪酸としては、オレイン酸、イソステアリン酸、リノール酸、リノレイン酸等が例示される。 Examples of liquid higher fatty acids include oleic acid, isostearic acid, linoleic acid, linolenic acid and the like.
液状の高級アルコールとしては、オレイルアルコール、イソステアリルアルコール等が例示される。 Examples of liquid higher alcohols include oleyl alcohol and isostearyl alcohol.
なお、得られるフォームを硬くし、保形性を高める点から、液状油には、固形の高級脂肪酸、固形の高級アルコール、ロウ等の２５℃において固形である固形油が含まれてもよい。固形油が用いられる場合、固形油は、液状油に溶解させて液状にしてから用いられることが好ましい。 The liquid oil may contain solid oils that are solid at 25 ° C., such as solid higher fatty acids, solid higher alcohols, and waxes, from the viewpoint of hardening the resulting foam and improving shape retention. When solid oil is used, the solid oil is preferably used after being dissolved in a liquid oil to form a liquid.
高級脂肪酸としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸等が例示される。 Examples of the higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid and the like.
高級アルコールとしては、ラウリルアルコール、セチルアルコール、ステアリルアルコール、ベヘニルアルコール、ミリスチルアルコールなどの直鎖アルコール、ラノリンアルコール、ヘキシルドデカノール、セトステアリルアルコール、オクチルドデカノールなどの分枝鎖アルコール等が例示される。 Examples of the higher alcohol include linear alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, and myristyl alcohol, and branched chain alcohols such as lanolin alcohol, hexyl decanol, cetostearyl alcohol, and octyldodecanol.
ロウとしては、ミツロウ、ラノリン、カンデリラロウ、カルナウバロウ等が例示される。 Examples of the wax include beeswax, lanolin, candelilla wax, carnauba wax and the like.
油性基材の含有量は、油性原液中、７０質量％以上であればよく、７５質量％以上であることが好ましい。また、油性基材の含有量は、油性原液中、９８質量％以下であればよく、９５質量％以下であることが好ましい。油性基材の含有量が７０質量％未満である場合、吐出物の発泡性が低下しやすく、フォームが形成されにくい傾向がある。一方、油性基材の含有量が９８質量％を超える場合、油性原液は、他の成分を含有しにくくなる傾向がある。 Content of an oily base material should just be 70 mass% or more in an oil-based stock solution, and it is preferable that it is 75 mass% or more. Moreover, content of an oil-based base material should just be 98 mass% or less in an oil-based stock solution, and it is preferable that it is 95 mass% or less. When the content of the oily substrate is less than 70% by mass, the foamability of the discharged product tends to be lowered, and the foam tends to be difficult to be formed. On the other hand, when content of an oil-based base material exceeds 98 mass%, an oil-based stock solution tends to become difficult to contain another component.
・界面活性剤
界面活性剤は、油性基剤を発泡させてフォームを形成するためや、洗浄成分（有効成分）等として配合される。
-Surfactant Surfactant is mix | blended as a washing | cleaning component (active ingredient) etc. in order to foam an oily base and to form a foam.
界面活性剤としては、ノニオン性界面活性剤、アニオン性界面活性剤、両性界面活性剤、カチオン性界面活性剤、シリコーン系界面活性剤、アミノ酸系界面活性剤等が例示される。 Examples of the surfactant include nonionic surfactants, anionic surfactants, amphoteric surfactants, cationic surfactants, silicone surfactants, amino acid surfactants, and the like.
ノニオン性界面活性剤としては、モノオレイン酸ジグリセリル、モノステアリン酸ジグリセリル、モノラウリン酸ジグリセリル、モノカプリン酸ジグリセリル、モノラウリン酸ヘキサグリセリル、モノミリスチン酸ヘキサグリセリル、モノラウリン酸ペンタグリセリル、モノミリスチン酸ペンタグリセリル、モノオレイン酸ペンタグリセリル、モノステアリン酸ペンタグリセリル、ヘキサステアリン酸ペンタグリセリル、トリミリスチン酸ペンタグリセリル、トリオレイン酸ペンタグリセリル、モノラウリン酸デカグルセリル、モノミリスチン酸デカグリセリル、モノステアリン酸デカグリセリル、モノイソステアリン酸デカグリセリル、モノオレイン酸デカグリセリル、モノリノール酸デカグリセリル、ペンタステアリン酸デカグリセリル、ペンタオレイン酸デカグリセリルなどのポリグリセリン脂肪酸エステル；ＰＯＥ・ＰＯＰセチルエーテル、ＰＯＥ・ＰＯＰデシルテトラデシルエーテルなどのポリオキシエチレンポリオキシプロピレンアルキルエーテル；ＰＯＥセチルエーテル、ＰＯＥステアリルエーテル、ＰＯＥオレイルエーテル、ＰＯＥラウリルエーテル、ＰＯＥベヘニルエーテル、ＰＯＥオクチルドデシルエーテル、ＰＯＥイソセチルエーテル、ＰＯＥイソステアリルエーテルなどのポリオキシエチレンアルキルエーテル；モノラウリン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコールなどのポリエチレングリコール脂肪酸エステル；ＰＯＥ硬化ヒマシ油などのポリオキシエチレン硬化ヒマシ油；モノステアリン酸ＰＯＥグリセリル、モノオレイン酸ＰＯＥグリセリルなどのポリオキシエチレングリセリン脂肪酸エステル；ステアリン酸ＰＯＥセチルエーテル、イソステアリン酸ＰＯＥラウリルエーテルなどのポリオキシエチレンアルキルエーテル脂肪酸エステル；モノヤシ油脂肪酸ＰＯＥソルビタン、モノステアリン酸ＰＯＥソルビタン、モノオレイン酸ＰＯＥソルビタンなどのポリオキシエチレンソルビタン脂肪酸エステル；モノラウリン酸ＰＯＥソルビット、テトラステアリン酸ＰＯＥソルビット、テトラオレイン酸ＰＯＥソルビットなどのポリオキシエチレンソルビット脂肪酸エステル；ＰＯＥラノリンアルコールなどのポリオキシエチレンラノリンアルコール；ヤシ油脂肪酸Ｎ−メチルエタノールアミドなどのアルキルアルカノールアミドなどのアルキルアルカノール型；等が例示される。これらの中でも、ノニオン性界面活性剤は、特に油性基剤を発泡させやすい点から、ポリグリセリン脂肪酸エステルであることが好ましい。 Nonionic surfactants include diglyceryl monooleate, diglyceryl monostearate, diglyceryl monolaurate, diglyceryl monocaprate, hexaglyceryl monolaurate, hexaglyceryl monomyristate, pentaglyceryl monolaurate, monomyristic acid Pentaglyceryl, pentaglyceryl monooleate, pentaglyceryl monostearate, pentaglyceryl hexastearate, pentaglyceryl trimyristate, pentaglyceryl trioleate, decaglyceryl monolaurate, decaglyceryl monomyristate, decaglyceryl monostearate, mono Decaglyceryl isostearate, decaglyceryl monooleate, decaglyceryl monolinoleate, decaglyceryl pentastearate Polyglycerin fatty acid esters such as pentaoleic acid decaglyceryl; polyoxyethylene polyoxypropylene alkyl ethers such as POE · POP cetyl ether and POE · POP decyl tetradecyl ether; POE cetyl ether, POE stearyl ether, POE oleyl ether, POE lauryl Polyoxyethylene alkyl ethers such as ether, POE behenyl ether, POE octyldodecyl ether, POE isocetyl ether, and POE isostearyl ether; polyethylene glycol fatty acid esters such as polyethylene glycol monolaurate and polyethylene glycol monostearate; POE hydrogenated castor oil Polyoxyethylene hydrogenated castor oil; POE glyceryl monostearate, monoole Polyoxyethylene glyceryl fatty acid esters such as POE glyceryl acid; polyoxyethylene alkyl ether fatty acid esters such as POE cetyl stearate and POE lauryl isostearic acid; monococonut oil fatty acid POE sorbitan, monostearic acid POE sorbitan, monooleic acid POE Polyoxyethylene sorbitan fatty acid esters such as sorbitan; Polyoxyethylene sorbitol fatty acid esters such as monolauric acid POE sorbite, tetrastearic acid POE sorbit, tetraoleic acid POE sorbit; Polyoxyethylene lanolin alcohol such as POE lanolin alcohol; Palm oil fatty acid N -Alkyl alkanol types such as alkyl alkanol amides such as methylethanolamide; etc. Is exemplified. Among these, the nonionic surfactant is preferably a polyglycerin fatty acid ester from the viewpoint that the oily base is particularly easily foamed.
アニオン性界面活性剤としては、ヤシ油脂肪酸カリウム、ミリスチン酸カリウム、ラウリン酸カリウムなどの脂肪酸石鹸；ラウリル硫酸カリウム、ラウリル硫酸ナトリウム、ラウリル硫酸トリエタノールアミン、ミリスチル硫酸ナトリウムなどのアルキル硫酸塩；ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ポリオキシエチレンラウリルエーテル硫酸トリエタノールアミンなどのポリオキシエチレンアルキルエーテル硫酸塩；ラウリルリン酸などのアルキルリン酸塩；ポリオキシエチレンラウリルエーテルリン酸などのポリオキシエチレンアルキルエーテルリン酸塩；アシルメチルタウリン酸；ラウリルスルホ酢酸ナトリウムなどのスルホン酸塩；等が例示される。 Anionic surfactants include fatty acid soaps such as coconut oil fatty acid potassium, potassium myristate and potassium laurate; alkyl sulfates such as potassium lauryl sulfate, sodium lauryl sulfate, triethanolamine lauryl sulfate and sodium myristyl sulfate; polyoxy Polyoxyethylene alkyl ether sulfates such as sodium ethylene lauryl ether sulfate and polyoxyethylene lauryl ether sulfate triethanolamine; alkyl phosphates such as lauryl phosphate; polyoxyethylene alkyl ether phosphorus such as polyoxyethylene lauryl ether phosphate Examples include acid salts; acylmethyl tauric acid; sulfonates such as sodium lauryl sulfoacetate; and the like.
両性界面活性剤としては、ラウリルジメチルアミノ酢酸ベタイン（ラウリルベタイン）、ステアリルベタイン、ラウリン酸アミドプロピルベタイン、ラウリルヒドロキシスルホベタイン、ステアリルジメチルアミノ酢酸ベタイン、ドデシルアミノメチルジメチルスルホプロピルベタイン、オクタデシルアミノメチルジメチルスルホプロピルベタインなどのアルキルベタイン、ヤシ酸アミドプロピルベタイン、ヤシ油脂肪酸アミドプロピルジメチルアミノ酢酸ベタイン（コカミドプロピルベタイン）、コカミドプロピルヒドロキシスルタインなどの脂肪酸アミドプロピルベタインなどのベタイン型；２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウムベタインなどのアルキルイミダゾール型；ラウリルジメチルアミンＮ−オキシド、オレイルジメチルアミンＮ−オキシドなどのアミンオキシド型；等が例示される。 Amphoteric surfactants include lauryl dimethylaminoacetic acid betaine (lauryl betaine), stearyl betaine, lauric acid amidopropyl betaine, lauryl hydroxysulfobetaine, stearyl dimethylaminoacetic acid betaine, dodecylaminomethyldimethylsulfopropylbetaine, octadecylaminomethyldimethylsulfone Betaine types such as alkylbetaines such as propylbetaine, amide propylbetaine cocoate, coconut oil fatty acid amidepropyldimethylaminoacetic acid betaine (cocamidopropylbetaine), fatty acid amidepropylbetaine such as cocamidopropylhydroxysultain; 2-alkyl- Alkyl imidazole type such as N-carboxymethyl-N-hydroxyethyl imidazolinium betaine; lauryl dimethylamino N- oxide, amine oxide, such as oleyl dimethyl amine N- oxide; and the like.
カチオン性界面活性剤としては、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化ベヘニルトリメチルアンモニウム、塩化ラウリルトリメチルアンモニウムなどのアルキルアンモニウム塩；アルキルベンジルアンモニウム塩；ステアリルアミンアセテート；ポリオキシエチレンラウリルアミン、ポリオキシエチレンステアリルアミンなどのポリオキシエチレンアルキルアミン；等が例示される。 Examples of cationic surfactants include alkyl ammonium salts such as cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, and lauryltrimethylammonium chloride; alkylbenzylammonium salts; stearylamine acetate; polyoxyethylene laurylamine, polyoxy Examples include polyoxyethylene alkylamines such as ethylene stearylamine.
シリコーン系界面活性剤としては、ポリオキシエチレン・メチルポリシロキサン共重合体、ポリオキシプロピレン・メチルポリシロキサン共重合体、ポリ（オキシエチレン・オキシプロピレン）・メチルポリシロキサン共重合体等が例示される。 Examples of silicone surfactants include polyoxyethylene / methylpolysiloxane copolymers, polyoxypropylene / methylpolysiloxane copolymers, poly (oxyethylene / oxypropylene) / methylpolysiloxane copolymers, and the like. .
アミノ酸系界面活性剤としては、Ｎ−ヤシ油脂肪酸アシル−Ｌ−グルタミン酸トリエタノールアミン、Ｎ−ヤシ油脂肪酸アシル−Ｌ−グルタミン酸カリウム、Ｎ−ヤシ油脂肪酸アシル−Ｌ−グルタミン酸ナトリウム、Ｎ−ラウロイル−Ｌ−グルタミン酸トリエタノールアミン、Ｎ−ラウロイル−Ｌ−グルタミン酸カリウム、Ｎ−ラウロイル−Ｌ−グルタミン酸ナトリウム、Ｎ−ミリストイル−Ｌ−グルタミン酸カリウム、Ｎ−ミリストイル−Ｌ−グルタミン酸ナトリウムおよびＮ−ステアロイル−Ｌ−グルタミン酸ナトリウムなどのＮ−アシルグルタミン酸塩；Ｎ−ヤシ油脂肪酸アシル−Ｌ−グルタミン酸、Ｎ−ラウロイル−Ｌ−グルタミン酸、Ｎ−ステアロイル−Ｌ−グルタミン酸などのＮ−アシルグルタミン酸；Ｎ−ヤシ油脂肪酸アシルグリシンカリウム、Ｎ−ヤシ油脂肪酸アシルグリシンナトリウムなどのＮ−アシルグリシン塩；Ｎ−ヤシ油脂肪酸アシル−ＤＬ−アラニントリエタノールアミンなどのＮ−アシルアラニン塩；等が例示される。 Amino acid surfactants include N-coconut oil fatty acid acyl-L-glutamic acid triethanolamine, N-coconut oil fatty acid acyl-L-glutamic acid potassium, N-coconut oil fatty acid acyl-sodium L-glutamate, N-lauroyl- L-glutamate triethanolamine, N-lauroyl-L-potassium glutamate, N-lauroyl-L-sodium glutamate, N-myristoyl-L-glutamate potassium, N-myristoyl-L-glutamate and N-stearoyl-L-glutamate N-acyl glutamate such as sodium; N-coconut fatty acid acyl-L-glutamic acid, N-lauroyl-L-glutamic acid, N-acylglutamic acid such as N-stearoyl-L-glutamic acid; N-coconut oil fatty acid acyl N- acyl alanine salts such as N- cocoyl -DL- alanine triethanolamine; lysine potassium, N- acyl glycine salts such as N- cocoyl glycine sodium and the like.
界面活性剤の含有量は、油性原液中、１質量％以上であることが好ましく、２質量％以上であることがより好ましい。また、界面活性剤の含有量は、油性原液中、２０質量％以下であることが好ましく、１５質量％以下であることがより好ましい。界面活性剤の含有量が１質量％未満である場合、吐出物が発泡しにくくなる傾向がある。一方、界面活性剤の含有量が２０質量％を超える場合、吐出物が吐出面に残りやすく、使用感が低下する傾向がある。 The surfactant content in the oily stock solution is preferably 1% by mass or more, and more preferably 2% by mass or more. The surfactant content in the oily stock solution is preferably 20% by mass or less, and more preferably 15% by mass or less. When the content of the surfactant is less than 1% by mass, the discharged product tends to be difficult to foam. On the other hand, when the content of the surfactant exceeds 20% by mass, the discharged material tends to remain on the discharge surface, and the feeling of use tends to decrease.
・任意成分
油性原液は、上記した油性基材および界面活性剤のほかに、エアゾール組成物を充填したエアゾール製品の性能や目的に応じて、製品の性能や目的などに応じて、有効成分、水、アルコール、粉体等の任意成分が含まれてもよい。
-Optional components In addition to the oily base material and surfactant described above, the oily stock solution contains active ingredients, water, depending on the performance and purpose of the aerosol product filled with the aerosol composition. Optional components such as alcohol and powder may be included.
有効成分としては、パラメトキシケイ皮酸エチルヘキシル、パラメトキシケイ皮酸イソプロピル、パラメトキシケイ皮酸オクチル、ジメトキシベンジリデンジオキソイミダゾリジンプロピオン酸オクチル、ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル、ｔ−ブチルメトキシジベンゾイルメタン、エチルヘキシルトリアゾン、オクトクレリン、オキシベンゾン、ヒドロキシベンゾフェノンスルホン酸、ジヒドロキシベンゾフェノンスルホン酸ナトリウム、ジヒドロキシベンゾフェノン、パラアミノ安息香酸などの紫外線吸収剤；Ｎ，Ｎ−ジエチル−ｍ−トルアミド（ディート）、カプリル酸ジエチルアミド、ハーブエキスなどの害虫忌避剤；α−トコフェロール、ジブチルヒドロキシトルエンなどの酸化防止剤；レチノール、ｄｌ−α−トコフェロールなどのビタミン類；アラントイン、グリチルレチン酸、グリチルリチン酸ジカリウム、アズレンなどの抗炎症剤；ｌ−メントール、カンフル、ミントオイルなどの清涼剤；緑茶エキス、柿タンニン、銀、ポリフェノールなどの消臭成分；パラオキシ安息香酸エステル、安息香酸ナトリウム、ソルビン酸カリウム、フェノキシエタノール、塩化ベンザルコニウム、塩化ベンゼトニウム、塩化クロルヘキシジン、感光素、パラクロルメタクレゾールなどの殺菌消毒剤；香料；等が例示される。 Active ingredients include ethylhexyl paramethoxycinnamate, isopropyl paramethoxycinnamate, octyl paramethoxycinnamate, octyl dimethoxybenzylidene dioxoimidazolidine propionate, hexyl diethylaminohydroxybenzoylbenzoate, t-butylmethoxydibenzoylmethane , Ethylhexyltriazone, octocrine, oxybenzone, hydroxybenzophenone sulfonic acid, sodium dihydroxybenzophenone sulfonate, dihydroxybenzophenone, paraaminobenzoic acid, etc .; N, N-diethyl-m-toluamide (diet), caprylic acid diethylamide, herb Pest repellents such as extracts; antioxidants such as α-tocopherol and dibutylhydroxytoluene; retinol, dl-α -Vitamins such as tocopherol; anti-inflammatory agents such as allantoin, glycyrrhetinic acid, dipotassium glycyrrhizinate and azulene; refreshing agents such as l-menthol, camphor and mint oil; deodorizing ingredients such as green tea extract, persimmon tannin, silver and polyphenol And bactericidal disinfectants such as paraoxybenzoic acid ester, sodium benzoate, potassium sorbate, phenoxyethanol, benzalkonium chloride, benzethonium chloride, chlorhexidine chloride, photosensitizer and parachlormetacresol;
有効成分が含まれる場合の含有量は、油性原液中、０．０１質量％以上であることが好ましく、０．１質量％以上であることがより好ましい。また、有効成分の含有量は、２０質量％以下であることが好ましく、１５質量％以下であることがより好ましい。有効成分の含有量が０．０１質量％未満である場合、有効成分を配合することによる効果が得られにくい傾向がある。また、有効成分の含有量が２０質量％を超える場合、有効成分によっては人体に悪影響を与える可能性がある。 When the active ingredient is contained, the content in the oily stock solution is preferably 0.01% by mass or more, and more preferably 0.1% by mass or more. Further, the content of the active ingredient is preferably 20% by mass or less, and more preferably 15% by mass or less. When content of an active ingredient is less than 0.01 mass%, there exists a tendency for the effect by mix | blending an active ingredient to be hard to be acquired. Moreover, when content of an active ingredient exceeds 20 mass%, there exists a possibility of having a bad influence on a human body depending on an active ingredient.
本実施形態の発泡性エアゾール組成物は、水を添加しないことが好ましい。しかしながら、水は、油性基材に溶解しない有効成分を配合する場合には、そのような有効成分の溶媒として適宜配合されてもよい。水は、精製水、イオン交換水、海洋深層水等が例示される。 The foamable aerosol composition of this embodiment preferably does not add water. However, when blending an active ingredient that does not dissolve in the oily base material, water may be blended appropriately as a solvent for such an active ingredient. Examples of the water include purified water, ion exchange water, deep sea water and the like.
水が含まれる場合の含有量は、油性原液中、０．１質量％以上であることが好ましく、０．５質量％以上であることがより好ましい。また、水の含有量は、油性原液中、２０質量％以下であることが好ましく、１０質量％以下であることがより好ましい。水の含有量が０．１質量％未満である場合、水を配合する効果が得られにくい傾向がある。一方、水の含有量が２０質量％を超える場合、吐出物の発泡性が低下する傾向がある。 When water is contained, the content in the oily stock solution is preferably 0.1% by mass or more, and more preferably 0.5% by mass or more. The water content is preferably 20% by mass or less, more preferably 10% by mass or less, in the oily stock solution. When the water content is less than 0.1% by mass, the effect of adding water tends to be difficult to obtain. On the other hand, when the content of water exceeds 20% by mass, the foamability of the discharged product tends to decrease.
アルコール類は、油性基材や水に溶解しにくい有効成分の溶媒として適宜配合される。また、アルコール類は、吐出物の発泡状態を調節する等の目的で適宜配合される。アルコール類としては、エタノール、イソプロパノールなどの１価アルコールや、プロピレングリコール、１，３−ブチレングリコール、ヘキシレングリコールなどの２価アルコール、グリセリンなどの３価アルコール等が例示される。 Alcohols are blended as appropriate as solvents for active ingredients that are difficult to dissolve in oily substrates and water. Moreover, alcohol is mix | blended suitably for the objective of adjusting the foaming state of discharged material. Examples of alcohols include monohydric alcohols such as ethanol and isopropanol, dihydric alcohols such as propylene glycol, 1,3-butylene glycol and hexylene glycol, and trihydric alcohols such as glycerin.
アルコール類が含まれる場合の含有量は、油性原液中、０．１質量％以上であることが好ましく、０．５質量％以上であることがより好ましい。また、アルコール類の含有量は、２０質量％以下であることが好ましく、１０質量％以下であることがより好ましい。アルコール類の含有量が０．１質量％未満である場合、アルコール類を配合する効果が得られにくい傾向がある。一方、アルコール類の含有量が２０質量％を超える場合、吐出物は発泡しにくくなる傾向がある。 When the alcohol is contained, the content in the oily stock solution is preferably 0.1% by mass or more, and more preferably 0.5% by mass or more. Moreover, it is preferable that it is 20 mass% or less, and, as for content of alcohol, it is more preferable that it is 10 mass% or less. When content of alcohol is less than 0.1 mass%, there exists a tendency for the effect which mix | blends alcohol to be hard to be acquired. On the other hand, when the content of alcohol exceeds 20% by mass, the discharged material tends to be less likely to foam.
粉体は、使用感を向上させる、汚れを落としやすくする等の目的で適宜配合される。粉体としては、タルク、カオリン、雲母、炭酸マグネシウム、炭酸カルシウム、ケイ酸亜鉛、ケイ酸マグネシウム、ケイ酸アルミニウム、ケイ酸カルシウム、シリカ、ゼオライト、セラミックパウダー、炭粉末、ナイロンパウダー、シルクパウダー、ウレタンパウダー、シリコーンパウダー、ポリエチレンパウダー等が例示される。 The powder is appropriately blended for the purpose of improving the feeling of use and making it easier to remove dirt. As powder, talc, kaolin, mica, magnesium carbonate, calcium carbonate, zinc silicate, magnesium silicate, aluminum silicate, calcium silicate, silica, zeolite, ceramic powder, charcoal powder, nylon powder, silk powder, urethane Examples thereof include powder, silicone powder, and polyethylene powder.
粉体が含まれる場合の含有量は、油性原液中、０．０５質量％以上であることが好ましく、０．１質量％以上であることがより好ましい。また、粉体の含有量は、５質量％以下であることが好ましく、３質量％以下であることがより好ましい。粉体の含有量が０．０５質量％未満である場合、粉体を配合する効果が得られにくい傾向がある。一方、粉体の含有量が５質量％を超える場合、粉体は、エアゾール容器内で沈降して固まりやすく、エアゾール組成物が吐出されにくくなったり、吐出物の組成が不均一となる傾向がある。 When the powder is contained, the content in the oily stock solution is preferably 0.05% by mass or more, and more preferably 0.1% by mass or more. Further, the content of the powder is preferably 5% by mass or less, and more preferably 3% by mass or less. When the content of the powder is less than 0.05% by mass, the effect of blending the powder tends to be difficult to obtain. On the other hand, when the content of the powder exceeds 5% by mass, the powder tends to settle and harden in the aerosol container, and the aerosol composition tends to be difficult to be discharged or the composition of the discharged material tends to be non-uniform. is there.
油性原液の調製方法は特に限定されない。一例を挙げると、油性原液は、油性基材および界面活性剤に、適宜の任意成分を添加して混合し、これらを溶解または分散させることによって調製することができる。 The method for preparing the oily stock solution is not particularly limited. As an example, an oily stock solution can be prepared by adding and mixing an appropriate arbitrary component to an oily base material and a surfactant, and dissolving or dispersing them.
油性原液の含有量は、エアゾール組成物中、５０質量％以上であることが好ましく、６０質量％以上であることがより好ましく、６５質量％以上であることがさらに好ましい。また、油性原液の含有量は、エアゾール組成物中、９５質量％以下であることが好ましく、９０質量％以下であることがより好ましく、８５質量％以下であることがさらに好ましい。油性原液の含有量が５０質量％未満である場合、フォームを構成する泡が破泡しやすく、フォーム状の吐出物が維持されにくい傾向がある。一方、油性原液の含有量が９５質量％を超える場合、吐出物がフォーム状に発泡しにくくなる傾向がある。 The content of the oily stock solution is preferably 50% by mass or more, more preferably 60% by mass or more, and further preferably 65% by mass or more in the aerosol composition. In addition, the content of the oily stock solution is preferably 95% by mass or less, more preferably 90% by mass or less, and further preferably 85% by mass or less in the aerosol composition. When the content of the oily stock solution is less than 50% by mass, the foam constituting the foam is liable to break, and the foam-like discharge tends to be hardly maintained. On the other hand, when the content of the oily stock solution exceeds 95% by mass, the discharged material tends to be difficult to foam into a foam shape.
（液化ガス）
液化ガスは、エアゾール容器内では加圧された液体であり、吐出されることにより気化して油性原液をフォーム状に膨張させるために配合される。本実施形態の液化ガスは、ハイドロフルオロオレフィンを主に含む。
(Liquefied gas)
The liquefied gas is a pressurized liquid in the aerosol container, and is blended in order to evaporate and expand the oily stock solution into a foam by being discharged. The liquefied gas of this embodiment mainly contains hydrofluoroolefin.
ハイドロフルオロオレフィンとしては、トランス−１，３，３，３−テトラフルオロプロパ−１−エン、トランス−２，３，３，３−テトラフルオロプロパ−１−エン等が例示される。 Examples of the hydrofluoroolefin include trans-1,3,3,3-tetrafluoroprop-1-ene, trans-2,3,3,3-tetrafluoroprop-1-ene and the like.
ハイドロフルオロオレフィンの含有量は、エアゾール組成物中、５質量％以上であればよく、１０質量％以上であることが好ましく、１５質量％以上であることがより好ましい。また、ハイドロフルオロオレフィンの含有量は、エアゾール組成物中、５０質量％以下であればよく、４０質量％以下であることが好ましく、３５質量％以下であることがより好ましい。ハイドロフルオロオレフィンの含有量が５質量％未満である場合、吐出物は充分に発泡されない傾向がある。一方、ハイドロフルオロオレフィンの含有量が５０質量％を超える場合、得られる吐出物は、飛び散りやすく、破泡しやすく、フォーム状の吐出物が維持されにくい傾向がある。ハイドロフルオロオレフィンの含有量が上記範囲内である場合、得られる吐出物は、火気に対して安全性が高く、かつ、きめ細かいフォームを形成しやすい。特に、ハイドロフルオロオレフィンの含有量が１０〜３５質量％である場合、得られる吐出物は、より優れた弾力性を有するフォームとなりやすい。 The content of the hydrofluoroolefin may be 5% by mass or more in the aerosol composition, preferably 10% by mass or more, and more preferably 15% by mass or more. Moreover, content of hydrofluoroolefin should just be 50 mass% or less in an aerosol composition, it is preferable that it is 40 mass% or less, and it is more preferable that it is 35 mass% or less. When the content of hydrofluoroolefin is less than 5% by mass, the discharged product tends not to be sufficiently foamed. On the other hand, when the content of the hydrofluoroolefin exceeds 50% by mass, the obtained ejected matter tends to be scattered, easily broken, and the foam-like ejected matter tends not to be maintained. When the content of the hydrofluoroolefin is within the above range, the obtained discharge is highly safe against fire and easily forms a fine foam. In particular, when the content of hydrofluoroolefin is 10 to 35% by mass, the obtained discharge product tends to be a foam having more excellent elasticity.
なお、本実施形態のエアゾール組成物は、効果の損なわれない範囲において、噴射剤として他の液化ガスや圧縮ガスが配合されてもよい。このような噴射剤としては、プロパン、イソブタン、ノルマルブタン、およびこれらの混合物である液化石油ガス、ジメチルエーテル等の液化ガス；亜酸化窒素ガス、炭酸ガス、窒素ガス、圧縮空気、酸素ガス等の圧縮ガスが例示される。 In addition, the liquefied gas and compressed gas other as a propellant may be mix | blended with the aerosol composition of this embodiment in the range which does not impair an effect. Examples of such propellants include propane, isobutane, normal butane, and liquefied gas such as liquefied petroleum gas and dimethyl ether, which are mixtures thereof; compressed nitrous oxide gas, carbon dioxide gas, nitrogen gas, compressed air, oxygen gas, etc. Gas is exemplified.
本実施形態のエアゾール組成物の製造方法は特に限定されない。一例を挙げると、エアゾール組成物は、上記油性原液を容器内に充填し、容器にエアゾールバルブを取り付けて密封し、エアゾールバルブから液化ガスを充填することにより製造し得る。 The manufacturing method of the aerosol composition of this embodiment is not specifically limited. For example, an aerosol composition can be produced by filling the above-mentioned oily stock solution in a container, attaching an aerosol valve to the container and sealing it, and filling a liquefied gas from the aerosol valve.
以上、本実施形態のエアゾール組成物は、油性基材を油性原液中に７０〜９８質量％含んでいても、ハイドロフルオロオレフィンが５〜５０質量％含まれているため、得られる吐出物は、ハイドロフルオロオレフィンが気化することによってきめ細かいフォームとなる。また、このようなフォームは、優れた弾力性を有し、かつ、泡持ちが良く流れ落ちにくい。また、このようなフォームは、火気に対して安全性が高い。 As mentioned above, even if the aerosol composition of this embodiment contains 70-98 mass% of an oily base material in an oily stock solution, since the hydrofluoroolefin is contained 5-50 mass%, the discharge thing obtained is When the hydrofluoroolefin is vaporized, a fine foam is formed. Moreover, such a foam has excellent elasticity and has good foam resistance and is difficult to flow down. Also, such foam is highly safe against fire.
以下、実施例により本発明をより具体的に説明する。本発明は、これら実施例に何ら限定されない。 Hereinafter, the present invention will be described more specifically with reference to examples. The present invention is not limited to these examples.
（実施例１）
以下の処方にしたがって、油性原液１を調製した。得られた油性原液１をアルミニウム製耐圧容器に充填し、エアゾールバルブを取り付けた。次いで、表１の配合割合（質量％）となるよう、ハイドロフルオロオレフィン（トランス−１，３，３，３−テトラフルオロプロパ−１−エン）を加圧充填し、発泡性エアゾール組成物を調製した。また、エアゾールバルブに噴射部材を取り付け、エアゾール製品を作製した。エアゾールバルブとしては、ステム孔がφ０．５、ハウジング（ベーパータップ孔無、アンダータップ孔φ１．５）を使用し、噴射部材として噴射孔の断面積が５．７ｍｍ2であるものを使用した。
＜油性原液１＞
モノラウリン酸ジグリセリル ３．０
モノオレイン酸ジグリセリル ３．０
トリ（カプリル／カプリン酸）グリセリル ３４．０
オリーブオイル ６０．０
合計 １００．０（質量％）
Example 1
Oily stock solution 1 was prepared according to the following formulation. The obtained oily stock solution 1 was filled in a pressure vessel made of aluminum, and an aerosol valve was attached. Next, hydrofluoroolefin (trans-1,3,3,3-tetrafluoroprop-1-ene) was pressure-filled to prepare a foamable aerosol composition so that the blending ratio (mass%) shown in Table 1 was obtained. did. Moreover, the injection member was attached to the aerosol valve, and the aerosol product was produced. As the aerosol valve, a stem hole of φ0.5, a housing (no vapor tap hole, no undertap hole φ1.5) was used, and an injection member having a cross-sectional area of 5.7 mm 2 was used.
<Oil stock solution 1>
Diglyceryl monolaurate 3.0
Diglyceryl monooleate 3.0
Tri (capryl / capric acid) glyceryl 34.0
Olive oil 60.0
Total 100.0 (mass%)
（実施例２〜９）
表１に記載の配合割合に変更した以外は、実施例１と同様の方法によりエアゾール製品を作製した。
(Examples 2-9)
An aerosol product was produced in the same manner as in Example 1 except that the blending ratios shown in Table 1 were changed.
（＊２）ノルマルブタンとイソブタンとプロパンの混合物（２５℃での蒸気圧が０．５ＭＰａ）
（比較例１）
以下の処方にしたがって調製した油性原液２を用いた以外は、実施例１と同様の方法により、エアゾール製品を作製した。
＜油性原液２＞
モノラウリン酸ジグリセリル ３．０
モノオレイン酸ジグリセリル ３．０
精製水 ３０．０
トリ（カプリル／カプリン酸）グリセリル ２０．０
オリーブオイル ４４．０
合計 １００．０（質量％）
(Comparative Example 1)
An aerosol product was produced in the same manner as in Example 1 except that the oily stock solution 2 prepared according to the following formulation was used.
<Oil stock solution 2>
Diglyceryl monolaurate 3.0
Diglyceryl monooleate 3.0
Purified water 30.0
Tri (capryl / capric acid) glyceryl 20.0
Olive oil 44.0
Total 100.0 (mass%)
（比較例２〜４）
表１に記載の配合割合に変更した以外は、実施例１と同様の方法によりエアゾール製品を作製した。
(Comparative Examples 2 to 4)
An aerosol product was produced in the same manner as in Example 1 except that the blending ratios shown in Table 1 were changed.
実施例１〜９、比較例１〜４において得られたエアゾール製品について、以下の評価方法にしたがって、発泡性、泡の硬さ、火炎の高さ、燃焼時間について評価した。結果を表３および表４に示す。 The aerosol products obtained in Examples 1 to 9 and Comparative Examples 1 to 4 were evaluated for foamability, foam hardness, flame height, and combustion time according to the following evaluation methods. The results are shown in Table 3 and Table 4.
＜発泡性＞
エアゾール容器を２５℃の恒温水槽中に１時間浸漬し、その後、吐出し、吐出物の発泡性を以下の評価基準にしたがって評価した。
（評価基準）
◎ ：吐出物は、弾力性があり、しっかりとした泡を形成し、泡の状態を維持した。
○ ：吐出物は、発泡して泡の状態を維持した。
△ ：吐出物は、発泡したが粗い泡になった。
×１：吐出物は、ほとんど発泡せず、液状であった。
×２：吐出物は、発泡したが、粗い泡になり飛び散った。
<Foaming properties>
The aerosol container was immersed in a constant temperature water bath at 25 ° C. for 1 hour, then discharged, and the foamability of the discharged material was evaluated according to the following evaluation criteria.
(Evaluation criteria)
(Double-circle): The discharge thing was elastic, formed the firm bubble, and maintained the state of the bubble.
○: The discharged product was foamed and maintained in a foam state.
(Triangle | delta): Although the discharge material foamed, it became a rough foam.
X1: The discharged material hardly foamed and was liquid.
X2: Although the discharged material foamed, it became a rough bubble and scattered.
＜泡の硬さ＞
容積２０ｍｌのカップにエアゾール組成物を吐出し、容器からはみ出した分の吐出物をすりきった後に、直径１０ｍｍの円板で１００ｍｍ／ｍｉｎの速さで１０ｍｍ押し下げた際に吐出物から受ける最大の荷重を測定し、泡の硬さとした。
<Hardness of foam>
The aerosol composition is discharged into a 20-ml cup, and the maximum amount received from the discharge when it is pushed down by 10 mm at a speed of 100 mm / min with a 10 mm diameter disc after the discharge from the container is exhausted. The load was measured and assumed to be the hardness of the foam.
＜火炎の高さ＞
吐出物に裸火を接触させ、着火した炎の高さを測定した。
なお、着火しなかった場合は０ｃｍとした。
<Flame height>
An open flame was brought into contact with the discharge, and the height of the ignited flame was measured.
In addition, it was set to 0 cm when not igniting.
＜燃焼時間＞
吐出物に裸火を接触させ、着火してから炎が消えるまでの時間を測定した。
なお、着火しなかった場合は０秒とした。
<Burning time>
An open flame was brought into contact with the discharged material, and the time from the ignition to the extinction of the flame was measured.
In addition, when it did not ignite, it was set to 0 second.
表３に示されるように、本発明の実施例１〜９のエアゾール製品は、発泡し、少なくとも泡の状態が維持される程度の優れた弾力性を有するフォームが形成された。このようなエアゾール製品は、着火されにくく、燃焼しにくかった。 As shown in Table 3, the aerosol products of Examples 1 to 9 of the present invention foamed and formed a foam having excellent elasticity so that at least the foamed state was maintained. Such aerosol products are difficult to ignite and difficult to burn.
一方、表４に示されるように、油性原液中の油性基材の含有量が少なかった比較例１のエアゾール製品や、ハイドロフルオロオレフィンの含有量が少なかった比較例２のエアゾール組成物は、ほとんど発泡せずに液状であった。また、ハイドロフルオロオレフィンの量の多かった比較例３のエアゾール組成物は、発泡したが粗い泡となり、飛び散った。さらに、ハイドロフルオロオレフィンを含んでいない比較例４のエアゾール製品は、着火した際の火炎の高さも高く、燃焼時間も長くなった。 On the other hand, as shown in Table 4, the aerosol product of Comparative Example 1 in which the content of the oily base material in the oily stock solution was small and the aerosol composition of Comparative Example 2 in which the content of hydrofluoroolefin was small were almost It was liquid without foaming. Moreover, although the aerosol composition of the comparative example 3 with much amount of hydrofluoroolefin foamed, it became a rough foam and scattered. Furthermore, the aerosol product of Comparative Example 4 containing no hydrofluoroolefin had a high flame height when ignited and a long combustion time.
Claims (3)
前記油性基材は、前記油性原液中に、７０〜９８質量％含まれ、
前記液化ガスは、ハイドロフルオロオレフィンであり、発泡性エアゾール組成物中に、５〜５０質量％含まれる、発泡性エアゾール組成物。 An foamable aerosol composition comprising an oily stock solution containing an oily substrate and a surfactant, and a liquefied gas,
The oily substrate is contained in the oily stock solution by 70 to 98% by mass,
The liquefied gas is a hydrofluoroolefin, and the foamable aerosol composition is contained in the foamable aerosol composition in an amount of 5 to 50% by mass.
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