JP2017218444A - Ketone or oxime compound and herbicide - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a novel compound and a herbicide prepared using the same.SOLUTION: The present invention provides a ketone or oxime compound represented by formula (1) [B is B-1, B-2 or B-3; Q is O, NORor the like; m and n are an integer of 0-2; R, R, R, Rand Rare H, halogen, alkyl, cycloalkyl and the like].SELECTED DRAWING: None

Description

本発明は、新規なケトン若しくはオキシム化合物又はそれらの塩、並びにケトン若しくはオキシム化合物又はそれらの塩を有効成分として含有する農薬、特に除草剤に関するものである。また、本発明における農薬とは、農園芸分野における殺虫・殺ダニ剤、殺線虫剤、除草剤及び殺菌剤等を意味する。   The present invention relates to a novel ketone or oxime compound or a salt thereof, and an agrochemical, particularly a herbicide, containing the ketone or oxime compound or a salt thereof as an active ingredient. The agrochemical in the present invention means an insecticide / acaricide, nematicide, herbicide, fungicide, etc. in the field of agriculture and horticulture.

例えば、特許文献１〜４には、ある種のケトン若しくはオキシム化合物が開示されているが、本発明に係るケトン若しくはオキシム化合物に関しては何ら開示されていない。   For example, Patent Documents 1 to 4 disclose certain ketones or oxime compounds, but do not disclose any ketone or oxime compounds according to the present invention.

国際公開第２００１／０１７９７２号International Publication No. 2001/017972 国際公開第２００３／０６２２４４号International Publication No. 2003/062244 国際公開第２０１０／０００７７３号International Publication No. 2010/000773 国際公開第２０１０／０６９８３４号International Publication No. 2010/069834

本発明の目的は、より低薬量で各種雑草に対して効果を確実に示し、且つ、土壌汚染や後作物への影響等の問題が軽減された、安全性の高く、除草剤の有効成分として有用な化学物質を提供することである。   The object of the present invention is a highly safe and effective herbicide active ingredient that reliably shows effects on various weeds at a lower dose, and has reduced problems such as soil contamination and effects on subsequent crops. It is to provide useful chemical substances.

本発明者らは、上記の課題解決を目標に鋭意研究を重ねた結果、本発明に係る下記式（１）で表される新規なケトン若しくはオキシム化合物が除草剤として優れた除草活性並びに対象となる作物に対する高い安全性を有し、且つ、ホ乳動物、魚類及び益虫等の非標的生物に対してほとんど悪影響の無い、極めて有用な化合物であることを見い出し、本発明を完成した。   As a result of intensive research aimed at solving the above problems, the present inventors have found that the novel ketone or oxime compound represented by the following formula (1) according to the present invention has excellent herbicidal activity and target. The present invention has been completed by discovering that it is a highly useful compound that has a high safety against certain crops and has almost no adverse effect on non-target organisms such as mammals, fish and beneficial insects.

すなわち、本発明は下記〔１〕〜〔１５１〕に関するものである。
〔１〕
式（１）： That is, the present invention relates to the following [1] to [151].
[1]
Formula (1):

［式中、Ｂは、Ｂ−１、Ｂ−２又はＢ−３のいずれかで示される環を表し、 [Wherein, B represents a ring represented by any of B-1, B-2 and B-3,

Ｑは、酸素原子、硫黄原子又はＮＯＲ^７を表し、
Ａは、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−Ｓ（Ｏ）_ｒ２Ｒ^１、−Ｃ（Ｏ）ＯＲ^１、−Ｃ（Ｓ）ＯＲ^１、−Ｃ（Ｏ）ＳＲ^１、−Ｃ（Ｓ）ＳＲ^１、−Ｃ（Ｏ）Ｒ^２、−Ｃ（Ｓ）Ｒ^２、−Ｃ（Ｏ）Ｎ（Ｒ^４）Ｒ^３、−Ｃ（Ｓ）Ｎ（Ｒ^４）Ｒ^３、−Ｓ（Ｏ）_２Ｎ（Ｒ^４）Ｒ^３、−Ｐ（Ｏ）（ＯＲ^１）_２又は−Ｐ（Ｓ）（ＯＲ^１）_２を表し、
Ｒ^１は、Ｃ_１〜Ｃ_８アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、フェニル又は（Ｚ^２）_ｑ２で置換されたフェニルを表し、
Ｒ^２は、水素原子、Ｃ_１〜Ｃ_８アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−Ｃ（＝ＮＯＲ^３１）Ｒ^３２、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル、ナフチル、（Ｚ^２）_ｑ２で置換されたナフチル、Ｄ１−１〜Ｄ１−４２、Ｄ１−８１又はＤ１−８４を表し、
Ｒ^３及びＲ^４は、各々独立して水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル、Ｄ１−３２、Ｄ１−３３又はＤ１−３４を表すか、或いは、Ｒ^３はＲ^４と一緒になってＣ_２〜Ｃ_７のアルキレン鎖又はＣ_２〜Ｃ_７のアルケニレン鎖を形成することにより、Ｒ^３及びＲ^４が結合する窒素原子と共に３〜８員環を形成してもよく、このときこのアルキレン鎖又はアルケニレン鎖は酸素原子、硫黄原子又は窒素原子を１個含んでもよく、且つＣ_１〜Ｃ_６アルキル、オキソ又はチオキソによって任意に置換されてもよく、
Ｒ^５は、ハロゲン原子、シアノ、ニトロ、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＲ^３１、−Ｓ（Ｏ）_ｒ２Ｒ^３１、−Ｃ（Ｏ）ＯＲ^３１、−Ｃ（Ｏ）Ｒ^３２、−Ｎ（Ｒ^３４）Ｒ^３３、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル、Ｄ１−１、Ｄ１−１０、Ｄ１−３２、Ｄ１−３３又はＤ１−３４を表すか、或いは、２つのＲ^５が同一の炭素上に置換している場合、２つのＲ^５は一緒になってオキソ、チオキソ、イミノ、Ｃ_１〜Ｃ_６アルキルイミノ、Ｃ_１〜Ｃ_６アルコキシイミノ又はＣ_１〜Ｃ_６アルキリデンを形成してもよく、
Ｒ^６は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^１５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^１５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^１５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^１５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^１５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−Ｃ（＝ＮＯＲ^１６）Ｒ^１７、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル、Ｄ１−１０、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４、Ｄ１−３６、Ｄ１−３７、Ｄ１−３８又はＤ１−８１を表し、
Ｒ^７は、水素原子、Ｃ_１〜Ｃ_８アルキル、Ｒ^１５bで任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^１５ｂで任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^１５bで任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^１５ｂで任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^１５ｂで任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、フェニル又は（Ｚ^１）_ｑ１で置換されたフェニルを表し、
Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ及びＲ^９ｂは、各々独立して水素原子、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、−ＯＲ^１６ａ、−Ｓ（Ｏ）_ｒ１Ｒ^１６ａ、−Ｃ（Ｏ）ＯＲ^１６ａ、−Ｃ（Ｏ）Ｒ^１７ａ、−Ｃ（Ｏ）Ｎ（Ｒ^１９ａ）Ｒ^１８ａ、−Ｃ（＝ＮＯＲ^１６ａ）Ｒ^１７ａ、フェニル又は（Ｚ^１）_ｑ１で置換されたフェニルを表し、
Ｒ^１０、Ｒ^１１及びＲ^１２は、各々独立して水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^１５は、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＲ^１６、−Ｓ（Ｏ）_ｒ１Ｒ^１６、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３又はＤ１−３４を表し、
Ｒ^１５ｂは、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、ハロ（Ｃ_３〜Ｃ_８）シクロアルキル、−ＯＲ^１６ｂ、−Ｓ（Ｏ）_ｒ１Ｒ^１６ｂ、−Ｃ（Ｏ）ＯＲ^１６ｂ、−Ｃ（Ｏ）Ｎ（Ｒ^１８ｂ）Ｒ^１９ｂ、−Ｃ（＝ＮＯＲ^１６ｂ）Ｒ^１７ｂ、−Ｎ（Ｒ^１８ｂ）Ｒ^１９ｂ、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４、Ｄ１−３６、Ｄ１−３７、Ｄ１−３８、Ｄ１−８１又はＤ１−８４を表すか、或いは、２つのＲ^１５ｂが同一の炭素上に置換している場合、２つのＲ^１５ｂは一緒になってオキソ、チオキソ、イミノ、Ｃ_１〜Ｃ_６アルキルイミノ、Ｃ_１〜Ｃ_６アルコキシイミノ又はＣ_１〜Ｃ_６アルキリデンを形成してもよく、
Ｒ^１６、Ｒ^１６ａ、Ｒ^１６ｂ、Ｒ^１７、Ｒ^１７ａ、Ｒ^１７ｂ、Ｒ^１８ａ及びＲ^１９ａは、各々独立して水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^１８ｂ及びＲ^１９ｂは、各々独立して水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^２０で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｃ_１〜Ｃ_６アルコキシ又はフェニルを表すか、或いは、Ｒ^１８ｂはＲ^１９ｂと一緒になってＣ_２〜Ｃ_７のアルキレン鎖又はＣ_２〜Ｃ_７のアルケレン鎖を形成することにより、Ｒ^１８ｂ及びＲ^１９ｂが結合する窒素原子と共に３〜８員環を形成してもよく、このときこのアルキレン鎖又はアルケニレン鎖は酸素原子、硫黄原子又は窒素原子を１個含んでもよく、且つオキソ又はチオキソによって任意に置換されてもよく、
Ｒ^２０は、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_６アルキルチオ、Ｃ_１〜Ｃ_６アルコキシカルボニル、フェニル又は（Ｚ^１）_ｑ１で置換されたフェニルを表し、
Ｄ１−１〜Ｄ１−４２、Ｄ１−８１、Ｄ１−８４は、各々下記の構造で表される環を表し、 Q represents an oxygen atom, a sulfur atom or NOR ⁷ ;
A is a hydrogen _atom, C 1 -C ₆ alkyl, optionally substituted with ^{R 5} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ cycloalkyl, optionally substituted with ^{R 5} _(C 3 ~ C _{8) cycloalkyl,} C 2 -C _{6 alkenyl,} C 3 -C ₈ cycloalkenyl, optionally substituted with ^{R 5} _(C 3 ~C ₈₎ cycloalkenyl, optionally substituted with ^{R 5} _{(C 2} -C _{6) alkenyl,} C 2 -C ₆ alkynyl, optionally substituted with ^{R 5} _(C 2 ~C _{6) ^{alkynyl, -S (O) r2 R 1}} , -C (O) OR 1, -C ( ^{S) OR 1, -C (O} ) SR 1, -C (S) SR 1, -C (O) R 2, -C (S) R 2, -C (O) N (R 4) R 3, _{^{-C (S) N (R 4}} ) R 3, -S (O) 2 N (R 4) R 3, -P (O) (oR 1) 2 or -P ( S) (OR ¹ ) ₂
R ¹ _is, C 1 -C ₈ alkyl, optionally substituted with ^{R 5} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ cycloalkyl, optionally substituted with ^{R 5} _(C 3 ~C ₈ ) _cycloalkyl, C 2 -C ₆ alkenyl, optionally substituted with ^{R 5} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ cycloalkenyl, optionally substituted with ^{R 5} _(C 3 ~C ₈ ) Represents cycloalkenyl, C ₂ -C ₆ alkynyl, (C ₂ -C ₆ ) alkynyl, phenyl optionally substituted with R ⁵ , phenyl or phenyl substituted with (Z ² ) _q ² ,
R ² is a hydrogen _atom, C 1 -C ₈ alkyl, optionally substituted with ^{R 5} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ cycloalkyl, optionally substituted with ^{R 5} _{(C 3} -C _{8) cycloalkyl,} C 2 -C ₆ alkenyl, optionally substituted with ^{R 5} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ cycloalkenyl, optionally substituted with ^{R 5} _{(C 3} -C _{8) cycloalkenyl,} C 2 -C ₆ alkynyl, optionally substituted with ^{R 5} _(C 2 ~C ₆₎ ^{alkynyl, -C (= NOR 31) R} 32, ^phenyl, substituted with (Z _{2) q2} Phenyl, naphthyl, (Z ² ) _q2- substituted naphthyl, D1-1 to D1-42, D1-81 or D1-84,
R ³ and R ⁴ are each independently a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ⁵ , C ₃ -C ₈ cycloalkyl, optional with R ⁵ substituted in _(C 3 ~C _{8) cycloalkyl,} C 2 -C ₆ alkenyl, optionally substituted with ^{R 5} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ cycloalkenyl, optionally ^{R 5} substituted in _(C 3 ~C _{8) cycloalkenyl,} substituted C 2 -C ₆ alkynyl, optionally with ^{R 5} _(C 2 ~C ₆₎ alkynyl, ^phenyl, phenyl substituted with (Z _{2) q2} , D1-32, or represents D1-33 or D1-34, or ^{by R 3} to form a alkenylene chain alkylene chain or _C 2 -C ₇ of _C 2 -C ₇ together with ^{R 4} , R ³ and R ⁴ are combined A 3- to 8-membered ring may be formed together with the child, in which case the alkylene chain or alkenylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and by C ₁ -C ₆ alkyl, oxo or thioxo Optionally substituted,
R ⁵ is a halogen atom, cyano, nitro, C ₃ -C ₈ cycloalkyl, —OR ³¹ , —S (O) _{r 2} R ³¹ , —C (O) OR ³¹ , —C (O) R ³² , —N ^{(R 34) R 33, -Si} (R 32a) (R 32b) R 32c, ^phenyl, (Z ₂₎ phenyl substituted with _{q2, D1-1, D1-10, D1-32,} D1-33 or D1 or represents -34, or when two ^{R 5} are substituted on the same carbon, two ^{R 5} oxo together, thioxo, _imino, C 1 -C _{6 alkylimino, C} 1 ~ C ₆ alkoxyimino or C ₁ -C ₆ alkylidene may be formed,
R ⁶ is a hydrogen _atom, C 1 -C ₆ ^alkyl, optionally substituted with ^{R 15} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ ^cycloalkyl, optionally substituted with ^{R 15} _{(C 3} -C _{8) cycloalkyl,} C 2 -C ₆ ^alkenyl, optionally substituted with ^{R 15} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ ^{cycloalkenyl,} optionally substituted with ^{R 15} _{(C 3} -C _{8) cycloalkenyl,} C 2 -C ₆ ^alkynyl, optionally substituted with ^{R 15} _(C 2 ~C ₆₎ ^{alkynyl, -C (= NOR 16) R} 17, ^phenyl, substituted with (Z _{1) q1} Represented by phenyl, D1-10, D1-32, D1-33, D1-34, D1-36, D1-37, D1-38 or D1-81,
R ⁷ is a hydrogen _atom, C 1 -C ₈ ^alkyl, optionally substituted with ^{R 15b} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ ^cycloalkyl, optionally substituted with ^{R 15b} _{(C 3} -C _{8) cycloalkyl,} C 2 -C ₆ ^alkenyl, optionally substituted with ^{R 15b} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ ^{cycloalkenyl,} optionally substituted with ^{R 15b} _{(C 3} -C ₈₎ represents _{cycloalkenyl,} C 2 -C ₆ ^alkynyl, optionally substituted with ^{R 15b} _(C 2 ~C ₆₎ alkynyl, phenyl substituted with phenyl or ^(Z _{1) q1,}
R ^8a , R ^8b , R ^9a and R ^9b are each independently a hydrogen atom, a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, —OR ^16a , —S (O) _r1 R ^16a , —C (O) OR ^16a , —C (O) R ^17a , —C (O) N (R ^19a ) R ^18a , —C (═NOR ^16a ) R ^17a , phenyl or (Z ¹ ) represents phenyl substituted with _q1 ,
R ¹⁰ , R ¹¹ and R ¹² each independently represent a hydrogen atom or C ₁ -C ₆ alkyl;
R ¹⁵ is a halogen atom, _cyano, C 3 -C _{8 ^{cycloalkyl, -OR 16, -S (O)}} r1 R 16, ^phenyl, phenyl substituted with _{(Z 1) q1, D1-7,} D1-11 , D1-22, D1-32, D1-33 or D1-34,
R ^15b is a halogen atom, cyano, C ₃ -C ₈ cycloalkyl, halo (C ₃ -C ₈ ) cycloalkyl, —OR ^16b , —S (O) _r1 R ^16b , —C (O) OR ^16b , — C (O) N (R ^18b ) R ^19b , -C (= NOR ^16b ) R ^17b , -N (R ^18b ) R ^19b , -Si (R ^32a ) (R ^32b ) R ^32c , phenyl, (Z ¹ ) _q1- substituted phenyl, D1-32, D1-33, D1-34, D1-36, D1-37, D1-38, D1-81 or D1-84, or two R ^15b are the same The two R ^15b together form oxo, thioxo, imino, C ₁ -C ₆ alkylimino, C ₁ -C ₆ alkoxyimino or C ₁ -C ₆ alkylidene. The Well,
R ¹⁶ , R ^16a , R ^16b , R ¹⁷ , R ^17a , R ^17b , R ^18a and R ^19a each independently represent a hydrogen atom or C ₁ -C ₆ alkyl;
R ^18b and R ^19b are each independently a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ²⁰ , C ₂ -C ₆ alkenyl, C ₂ -C _{6. alkynyl,} or represents C 1 -C ₆ alkoxy or phenyl, ^or by ^{R 18b} is to form the Arukeren chain alkylene chain or _C 2 -C ₇ of _C 2 -C ₇ together with ^{R 19b,} R ^18b and R ^19b may form a 3- to 8-membered ring together with the nitrogen atom to which R ^19b is bonded, in which case the alkylene chain or alkenylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and oxo or thioxo Optionally substituted by
R ²⁰ represents cyano, C ₃ -C ₈ cycloalkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ alkylthio, C ₁ -C ₆ alkoxycarbonyl, phenyl or phenyl substituted with (Z ¹ ) _q1. ,
D1-1 to D1-42, D1-81, and D1-84 each represent a ring represented by the following structure:

Ｘ^１は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル又はＣ_３〜Ｃ_８シクロアルキルを表し、ｇ２、ｇ３又はｇ４が２以上の整数を表すとき、各々のＸ^１は互いに同一であっても又は互いに相異なってもよく、更に２つのＸ^１が隣接する場合には、隣接する２つのＸ^１は、−ＣＨ＝ＣＨＣＨ＝ＣＨ−を形成することにより、それぞれのＸ^１が結合する炭素原子と共に６員環を形成してもよく、このとき環を形成する各々の炭素原子に結合した水素原子は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_６アルキルチオ、Ｃ_１〜Ｃ_６アルキルスルフィニル又はＣ_１〜Ｃ_６アルキルスルホニルによって任意に置換されてもよく、
Ｘ^１ａは、水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｘ^１ｂは、Ｃ_１〜Ｃ_６アルキルを表し、
Ｚは、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、Ｒ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^４５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^４５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−ＯＲ^４１、−Ｓ（Ｏ）_ｒ３Ｒ^４１、−Ｃ（Ｏ）ＯＲ^４１、−Ｃ（Ｏ）Ｒ^４２、−Ｃ（Ｏ）Ｎ（Ｒ^４４ａ）Ｒ^４３ａ、−Ｃ（＝ＮＯＲ^４１）Ｒ^４２、−Ｎ（Ｒ^４４）Ｒ^４３、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−１、Ｄ１−２、Ｄ１−７、Ｄ１−１０、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４、Ｄ１−３６、Ｄ１−３７又はＤ１−３８を表し、ｑが２以上の整数を表すとき、各々のＺは互いに同一であっても又は互いに相異なってもよく、
Ｚ^１は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、ハロ（Ｃ_１〜Ｃ_６）アルコキシ又はＣ_１〜Ｃ_６アルコキシカルボニルを表し、ｑ１が２以上の整数を表すとき、各々のＺ^１は互いに同一であっても又は互いに相異なってもよく、
Ｚ^２は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、−ＯＲ^５１、−Ｓ（Ｏ）_ｒ２Ｒ^５１、−Ｃ（Ｏ）ＯＲ^５１ａ、−Ｃ（Ｏ）Ｒ^５２、−Ｃ（Ｏ）Ｎ（Ｒ^５４）Ｒ^５３、−Ｃ（Ｓ）Ｎ（Ｒ^５４）Ｒ^５３又は−Ｎ（Ｒ^５４）Ｒ^５３を表し、ｑ２が２以上の整数を表すとき、各々のＺ^２は互いに同一であっても又は互いに相異なってもよく、更に、２つのＺ^２が隣接する場合には、隣接する２つのＺ^２は−Ｎ＝ＣＨＣＨ＝ＣＨ−，−ＣＨ＝ＮＣＨ＝ＣＨ−，−Ｎ＝ＮＣＨ＝ＣＨ−，−ＣＨ＝ＮＮ＝ＣＨ−，−Ｎ＝ＣＨＣＨ＝Ｎ−、−Ｎ＝ＣＨＮ＝ＣＨ−又は−ＯＣＨ_２Ｏ−を形成することにより、それぞれのＺ^２が結合する炭素原子と共に５又は６員環を形成してもよく、このとき、環を形成する各々の炭素原子に結合した水素原子は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_６アルキルチオ、Ｃ_１〜Ｃ_６アルキルスルフィニル又はＣ_１〜Ｃ_６アルキルスルホニルによって任意に置換されてもよく、
Ｚ^３は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、ハロ（Ｃ_１〜Ｃ_６）アルコキシ、Ｃ_１〜Ｃ_６アルキルチオ、Ｃ_１〜Ｃ_６アルキルスルフィニル又はＣ_１〜Ｃ_６アルキルスルホニルを表し、ｑ３が２以上の整数を表すとき、各々のＺ^３は互いに同一であっても又は互いに相異なってもよく、
Ｒ^３１は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^３５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、−Ｃ（Ｏ）Ｒ^３７、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル、ナフチル又は（Ｚ^２）_ｑ２で置換されたナフチルを表し、
Ｒ^３２は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^３５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル又はフェニルを表し、
Ｒ^３２ａ、Ｒ^３２ｂ及びＲ^３２ｃは、各々独立してＣ_１〜Ｃ_６アルキルを表し、
Ｒ^３３及びＲ^３４は、各々独立して水素原子、Ｃ_１〜Ｃ_６アルキル、−Ｃ（Ｏ）ＯＲ^３６又は−Ｃ（Ｏ）Ｒ^３７を表し、
Ｒ^３５は、ハロゲン原子、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_６アルキルチオ、Ｃ_１〜Ｃ_６アルキルスルフィニル、Ｃ_１〜Ｃ_６アルキルスルホニル又はフェニルを表し、
Ｒ^３６は、Ｃ_１〜Ｃ_６アルキルを表し、
Ｒ^３７は、水素原子、Ｃ_１〜Ｃ_６アルキル、フェニル又は（Ｚ^２）_ｑ２で置換されたフェニルを表し、
Ｒ^４１は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_２〜Ｃ_６アルキニル、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−３２、Ｄ１−３３又はＤ１−３４を表し、
Ｒ^４２は、水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^４３及びＲ^４４は、各々独立して水素原子、Ｃ_１〜Ｃ_６アルキル、Ｃ_１〜Ｃ_６アルコキシカルボニル又はＣ_１〜Ｃ_６アルキルカルボニルを表し、
Ｒ^４３ａは、Ｃ_１〜Ｃ_６アルキル又はハロ（Ｃ_１〜Ｃ_６）アルキルを表し、
Ｒ^４４ａは、水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^４５は、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＨ、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_１０アルコキシカルボニル、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−１０、Ｄ１−３２、Ｄ１−３３又はＤ１−３４を表すか、或いは、２つのＲ^４５が同一の炭素上に置換している場合、２つのＲ^４５は一緒になってオキソ、チオキソ、イミノ、Ｃ_１〜Ｃ_６アルキルイミノ、Ｃ_１〜Ｃ_６アルコキシイミノ又はＣ_１〜Ｃ_６アルキリデンを形成してもよく、
Ｒ^５１は、水素原子、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、フェニル、ハロゲン原子によって任意に置換されたフェニル又はＤ１−３９を表し、
Ｒ^５１ａ及びＲ^５２は、各々独立して水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^５３及びＲ^５４は、各々独立して水素原子、Ｃ_１〜Ｃ_６アルキル又はＣ_１〜Ｃ_６アルキルカルボニルを表し、
ｆ５は、０、１、２、３、４又は５の整数を表し、
ｆ７は、０、１、２、３、４、５、６又は７の整数を表し、
ｇ１及びｐは、各々独立して０又は１の整数を表し、
ｇ２、ｍ、ｎ、ｒ１、ｒ２及びｒ３は、各々独立して０、１又は２の整数を表し、
ｇ３は、０、１、２又は３の整数を表し、
ｇ４は、０、１、２、３又は４の整数を表し、
ｑ、ｑ１、ｑ２及びｑ３は、各々独立して１、２、３、４又は５の整数を表す。〕で表されるケトン若しくはオキシム化合物又はそれらの塩。
〔２〕
Ｂは、Ｂ−１−ａ又はＢ−２−ａのいずれかで示される環を表し、 X ¹ represents a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl or C ₃ -C ₈ cycloalkyl, and g 2, g 3 or g 4 represents an integer of 2 or more. When each X ¹ may be the same as or different from each other, and when two X ¹ are adjacent to each other, the two adjacent X ¹ form —CH═CHCH═CH— By doing so, a 6-membered ring may be formed together with the carbon atom to which each X ¹ is bonded. At this time, the hydrogen atom bonded to each carbon atom forming the ring is a halogen atom, cyano, nitro, C _1. -C ₆ alkyl, halo _(C 1 ~C _{6) alkyl,} C 1 -C _{6 alkoxy,} C 1 -C _{6 alkylthio,} optionally by C 1 -C ₆ alkylsulfinyl or _C 1 -C ₆ alkylsulfonyl May be replaced,
X ^1a represents a hydrogen atom or C ₁ -C ₆ alkyl,
X ^1b represents C ₁ -C ₆ alkyl;
Z is a halogen atom, cyano, _nitro, substituted C 1 -C ₆ ^alkyl, which is optionally substituted with ^{R 45} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ ^cycloalkyl, optionally in ^{R 45} _(C 3 _{~C 8) cycloalkyl,} C 2 -C ₆ ^alkenyl, which is optionally substituted with ^{R 45} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ ^{cycloalkenyl,} optionally substituted with ^{R 45} _(C 3 _{~C 8) cycloalkenyl,} C 2 -C ₆ ^alkynyl, optionally substituted with ^{R 45} _(C 2 ~C _{6) ^{alkynyl, -OR 41, -S (O)}} r3 R 41, -C ( ^{O) OR 41, -C (O} ) R 42, -C (O) N (R 44a) R 43a, -C (= NOR 41) R 42, -N (R 44) R 43, phenyl, ^{(Z 3} ) phenyl substituted with _q3, D1-1, 1-2, D1-7, D1-10, D1-11, D1-22, D1-32, D1-33, D1-34, D1-36, D1-37 or D1-38, q is 2 or more Each Z may be the same as or different from each other,
Z ¹ is a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, C ₁ -C ₆ alkoxy, halo (C ₁ -C ₆ ) alkoxy or C ₁ -C _6. Represents alkoxycarbonyl, and when q1 represents an integer of 2 or more, each Z ¹ may be the same as or different from each other;
Z ² represents a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, —OR ⁵¹ , —S (O) _{r 2} R ⁵¹ , —C (O) OR ^51a , — C (O) R ⁵² , —C (O) N (R ⁵⁴ ) R ⁵³ , —C (S) N (R ⁵⁴ ) R ⁵³ or —N (R ⁵⁴ ) R ⁵³ , q2 is an integer of 2 or more when referring to, each of ^{Z 2} may be different or phase from each other be identical to each other, further, when two ^{Z 2} are adjacent, the two ^{Z 2} adjacent to each -N = CHCH = CH- , -CH = NCH = CH -, - N = NCH = CH -, - CH = NN = CH -, - N = CHCH = N -, - N = CHN = CH- or forming a -OCH ₂ O- May form a 5- or 6-membered ring with the carbon atom to which each Z ² is attached, And a hydrogen atom bonded to each carbon atom forming the ring is a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, C ₁ -C ₆ alkoxy, C ₁ -C _{6 alkylthio,} may be optionally substituted by C 1 -C ₆ alkylsulfinyl or _C 1 -C ₆ alkylsulfonyl,
Z ³ is a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, C ₁ -C ₆ alkoxy, halo (C ₁ -C ₆ ) alkoxy, C ₁ -C ₆ alkylthio represents a C ₁ -C ₆ alkylsulfinyl or C ₁ -C ₆ alkylsulfonyl, when q3 represents an integer of 2 or more, each of Z ³ may be or different from each other the same as each other,
R ³¹ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ³⁵ , C ₃ -C ₈ cycloalkyl, —C (O) R ³⁷ , phenyl, ( Z ²⁾ phenyl substituted with _q2, represents naphthyl substituted with naphthyl or ^(Z _{2) q2,}
R ³² represents a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl or phenyl optionally substituted with R ³⁵ ,
R ^32a , R ^32b and R ^32c each independently represent C ₁ -C ₆ alkyl;
R ³³ and R ³⁴ each independently represent a hydrogen atom, C ₁ -C ₆ alkyl, —C (O) OR ³⁶ or —C (O) R ³⁷ ,
R ³⁵ represents represents a halogen _atom, C 1 -C _{6 alkoxy,} C 1 -C _{6 alkylthio,} C 1 -C _{6 alkylsulfinyl,} a C 1 -C ₆ alkylsulfonyl or phenyl,
R ³⁶ represents C ₁ -C ₆ alkyl,
R ³⁷ represents a hydrogen atom, C ₁ -C ₆ alkyl, phenyl or phenyl substituted with (Z ² ) _q ² ,
R ⁴¹ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ⁴⁵ , C ₂ -C ₆ alkenyl, C ₂ -C ₆ alkynyl, phenyl, (Z ³ ) Represents phenyl, D1-32, D1-33 or D1-34 substituted with _q3 ;
R ⁴² represents a hydrogen atom or a _C 1 -C ₆ alkyl,
R ⁴³ and R ⁴⁴ each independently represent a hydrogen atom, C ₁ -C ₆ alkyl, C ₁ -C ₆ alkoxycarbonyl or C ₁ -C ₆ alkylcarbonyl,
R ^43a represents C ₁ -C ₆ alkyl or halo (C ₁ -C ₆ ) alkyl;
R ^44a represents a hydrogen atom or C ₁ -C ₆ alkyl;
R ⁴⁵ is a halogen atom, cyano, C ₃ -C ₈ cycloalkyl, —OH, C ₁ -C ₆ alkoxy, C ₁ -C ₁₀ alkoxycarbonyl, —Si (R ^32a ) (R ^32b ) R ^32c , phenyl, (Z ³ ) represents phenyl substituted with _q3 , D1-10, D1-32, D1-33 or D1-34, or when two R ⁴⁵ are substituted on the same carbon, R ⁴⁵ together may form oxo, thioxo, imino, C ₁ -C ₆ alkylimino, C ₁ -C ₆ alkoxyimino or C ₁ -C ₆ alkylidene;
R ⁵¹ represents a hydrogen atom, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, phenyl, phenyl optionally substituted with a halogen atom, or D1-39,
R ^51a and R ⁵² each independently represent a hydrogen atom or C ₁ -C ₆ alkyl;
R ⁵³ and R ⁵⁴ each independently represent a hydrogen atom, C ₁ -C ₆ alkyl or C ₁ -C ₆ alkylcarbonyl,
f5 represents an integer of 0, 1, 2, 3, 4 or 5,
f7 represents an integer of 0, 1, 2, 3, 4, 5, 6 or 7,
g1 and p each independently represent an integer of 0 or 1,
g2, m, n, r1, r2 and r3 each independently represents an integer of 0, 1 or 2;
g3 represents an integer of 0, 1, 2, or 3;
g4 represents an integer of 0, 1, 2, 3 or 4;
q, q1, q2 and q3 each independently represents an integer of 1, 2, 3, 4 or 5. ] The ketone or oxime compound represented by these, or those salts.
[2]
B represents a ring represented by either B-1-a or B-2-a;

Ｚ^ａ、Ｚ^ｃ及びＺ^ｅは、各々独立して水素原子、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、Ｒ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^４５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−ＯＲ^４１、−Ｓ（Ｏ）_ｒ３Ｒ^４１、−Ｃ（Ｏ）ＯＲ^４１、−Ｃ（Ｏ）Ｒ^４２、−Ｃ（Ｏ）Ｎ（Ｒ^４４ａ）Ｒ^４３ａ、−Ｃ（＝ＮＯＲ^４１）Ｒ^４２、−Ｎ（Ｒ^４４）Ｒ^４３、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−１、Ｄ１−２、Ｄ１−７、Ｄ１−１０、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４、Ｄ１−３６、Ｄ１−３７又はＤ１−３８を表す上記〔１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔３〕
Ｑは、酸素原子を表す上記〔２〕に記載のケトン化合物又はその塩。
〔４〕
Ｑは、ＮＯＲ^７を表す上記〔２〕に記載のオキシム化合物又はその塩。
〔５〕
Ａは、水素原子、Ｃ_１〜Ｃ_６アルキル又は−Ｃ（Ｏ）Ｒ^２を表し、
Ｒ^２は、Ｃ_１〜Ｃ_８アルキルを表し、
Ｒ^６は、Ｃ_１〜Ｃ_６アルキル、Ｒ^１５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、−Ｃ（＝ＮＯＲ^１６）Ｒ^１７、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル又はＤ１−３２を表し、
Ｒ^８ａは、水素原子、Ｃ_１〜Ｃ_６アルキル、−Ｃ（Ｏ）ＯＲ^１６ａ又は−Ｃ（Ｏ）Ｒ^１７ａを表し、
Ｒ^９ａは、水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^８ｂ及びＲ^９ｂは、水素原子を表し、
Ｒ^１０、Ｒ^１１及びＲ^１２は、水素原子を表し、
Ｒ^１５は、ハロゲン原子、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＲ^１６又はフェニルを表し、
Ｒ^１６、Ｒ^１６ａ、Ｒ^１７及びＲ^１７ａは、各々独立してＣ_１〜Ｃ_６アルキルを表し、
Ｘ^１は、ハロ（Ｃ_１〜Ｃ_６）アルキルを表し、
Ｚ^ａ、Ｚ^ｃ及びＺ^ｅは、各々独立して水素原子、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、−ＯＲ^４１、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２又はＤ１−３７を表し、
Ｚ^１は、ハロゲン原子を表し、
Ｚ^３は、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、ハロ（Ｃ_１〜Ｃ_６）アルコキシ又はＣ_１〜Ｃ_６アルキルチオを表し、
Ｒ^４１は、Ｃ_１〜Ｃ_６アルキル、Ｒ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、フェニル、Ｄ１−３２又はＤ１−３４を表し、
Ｒ^４５は、ハロゲン原子、フェニル又はＤ１−３４を表し、
ｇ２、ｇ３及びｐは、０を表し、
ｑ１及びｑ３は、１の整数を表し、
ｇ４、ｍ及びｎは、各々独立して０又は１の整数を表す上記〔３〕に記載のケトン化合物又はその塩。
〔６〕
Ｂは、Ｂ−１−ａを表し、
Ｚ^ａは、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル又はＣ_１〜Ｃ_６アルコキシを表し、
Ｚ^ｃは、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、−ＯＲ^４１、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２又はＤ１−３７を表し、
Ｚ^ｅは、ハロゲン原子又はＣ_１〜Ｃ_６アルキルを表す上記〔５〕に記載のケトン化合物又はその塩。
〔７〕
Ａは、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−Ｓ（Ｏ）_ｒ２Ｒ^１、−Ｃ（Ｏ）ＯＲ^１、−Ｃ（Ｏ）ＳＲ^１、−Ｃ（Ｓ）ＯＲ^１、−Ｃ（Ｏ）Ｒ^２、−Ｃ（Ｏ）Ｎ（Ｒ^４）Ｒ^３、−Ｃ（Ｓ）Ｎ（Ｒ^４）Ｒ^３又は−Ｓ（Ｏ）_２Ｎ（Ｒ^４）Ｒ^３を表し、
Ｒ^１は、Ｃ_１〜Ｃ_８アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、フェニル又は（Ｚ^２）_ｑ２で置換されたフェニルを表し、
Ｒ^２は、Ｃ_１〜Ｃ_８アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−Ｃ（＝ＮＯＲ^３１）Ｒ^３２、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル、Ｄ１−５、Ｄ１−６、Ｄ１−８、Ｄ１−１０又はＤ１−８１を表し、
Ｒ^３は、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_２〜Ｃ_６アルケニル、フェニル又は（Ｚ^２）_ｑ２で置換されたフェニルを表すか、或いは、Ｒ^３はＲ^４と一緒になってＣ_４又はＣ_５のアルキレン鎖を形成することにより、Ｒ^３及びＲ^４が結合する窒素原子と共に５又は６員環を形成し、このときこのアルキレン鎖は酸素原子、硫黄原子又は窒素原子を１個含んでもよく、且つＣ_１〜Ｃ_６アルキルによって任意に置換されてもよく、
Ｒ^４は、Ｃ_１〜Ｃ_６アルキル、Ｃ_２〜Ｃ_６アルケニル又はフェニルを表し、
Ｒ^５は、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＲ^３１、−Ｓ（Ｏ）_ｒ２Ｒ^３１、−Ｃ（Ｏ）ＯＲ^３１、−Ｃ（Ｏ）Ｒ^３２、−Ｎ（Ｒ^３４）Ｒ^３３、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル又はＤ１−１を表すか、或いは、２つのＲ^５が同一の炭素上に置換している場合、２つのＲ^５は一緒になってＣ_１〜Ｃ_６アルコキシイミノを形成してもよく、
Ｒ^６は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^１５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、−Ｃ（＝ＮＯＲ^１６）Ｒ^１７、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル又はＤ１−３２を表し、
Ｒ^７は、水素原子、Ｃ_１〜Ｃ_７アルキル、Ｒ^１５bで任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^１５bで任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル又はフェニルを表し、
Ｒ^８ａは、水素原子、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、−Ｃ（Ｏ）ＯＲ^１６ａ、−Ｃ（＝ＮＯＲ^１６ａ）Ｒ^１７ａ又は（Ｚ^１）_ｑ１で置換されたフェニルを表し、
Ｒ^９ａは、水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^８ｂ及びＲ^９ｂは、水素原子を表し、
Ｒ^１２は、水素原子を表し、
Ｒ^１５は、ハロゲン原子、Ｃ_３〜Ｃ_８シクロアルキル又は−ＯＲ^１６を表し、
Ｒ^１５ｂは、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、ハロ（Ｃ_３〜Ｃ_８）シクロアルキル、−ＯＲ^１６ｂ、−Ｓ（Ｏ）_ｒ１Ｒ^１６ｂ、−Ｃ（Ｏ）ＯＲ^１６ｂ、−Ｃ（Ｏ）Ｎ（Ｒ^１８ｂ）Ｒ^１９ｂ、−Ｃ（＝ＮＯＲ^１６ｂ）Ｒ^１７ｂ、−Ｎ（Ｒ^１８ｂ）Ｒ^１９ｂ、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル、Ｄ１−３２又はＤ１−８４を表し、
Ｒ^１６、Ｒ^１６ａ、Ｒ^１７、Ｒ^１７ａ及びＲ^１７ｂは、各々独立してＣ_１〜Ｃ_６アルキルを表し、
Ｒ^１８ｂは、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^２０で任意に置換された（Ｃ_１〜Ｃ_６）アルキル又はフェニルを表すか、或いは、Ｒ^１８ｂはＲ^１９ｂと一緒になってＣ_５のアルキレン鎖を形成することにより、Ｒ^１８ｂ及びＲ^１９ｂが結合する窒素原子と共に６員環を形成し、このときこのアルキレン鎖は酸素原子を１個含んでおり、
Ｒ^１９ｂは、水素原子又はＣ_１〜Ｃ_６アルキル を表し、
Ｒ^２０は、（Ｚ^１）_ｑ１で置換されたフェニルを表し、
Ｘ^１は、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル又はＣ_３〜Ｃ_８シクロアルキルを表し、ｇ３が２の整数を表し、更に２つのＸ^１が隣接して−ＣＨ＝ＣＨＣＨ＝ＣＨ−を形成することにより、それぞれのＸ^１が結合する炭素原子と共に６員環を形成し、このとき環を形成する各々の炭素原子に結合した水素原子の一つは、ハロゲン原子によって置換されてもよく、
Ｘ^１ａは、Ｃ_１〜Ｃ_６アルキルを表し、
Ｚ^ａ、Ｚ^ｃ及びＺ^ｅは、各々独立して水素原子、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−ＯＲ^４１、−Ｓ（Ｏ）_ｒ３Ｒ^４１、−Ｃ（Ｏ）ＯＲ^４１、−Ｃ（Ｏ）Ｒ^４２、−Ｃ（Ｏ）Ｎ（Ｒ^４４ａ）Ｒ^４３ａ、−Ｃ（＝ＮＯＲ^４１）Ｒ^４２、−Ｎ（Ｒ^４４）Ｒ^４３、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−２、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４又はＤ１−３７を表し、
Ｚ^１は、ハロゲン原子、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ又はＣ_１〜Ｃ_６アルコキシカルボニルを表し、ｑ１が２以上の整数を表すとき、各々のＺ^１は互いに同一であっても又は互いに相異なってもよく、
Ｚ^２は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、−ＯＲ^５１、−Ｓ（Ｏ）_ｒ２Ｒ^５１、−Ｃ（Ｏ）ＯＲ^５１ａ、−Ｃ（Ｏ）Ｒ^５２又は−Ｃ（Ｏ）Ｎ（Ｒ^５４）Ｒ^５３を表し、ｑ２が２以上の整数を表すとき、各々のＺ^２は互いに同一であっても又は互いに相異なってもよく、更に、２つのＺ^２が隣接する場合には、隣接する２つのＺ^２は−Ｎ＝ＣＨＣＨ＝ＣＨ−を形成することにより、それぞれのＺ^２が結合する炭素原子と共に６員環を形成してもよく、このとき、環を形成する各々の炭素原子に結合した水素原子の一つは、ハロゲン原子によって置換されてもよく、
Ｚ^３は、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、ハロ（Ｃ_１〜Ｃ_６）アルコキシ又はＣ_１〜Ｃ_６アルキルチオを表し、ｑ３が２以上の整数を表すとき、各々のＺ^３は互いに同一であっても又は互いに相異なってもよく、
Ｒ^３１は、Ｃ_１〜Ｃ_６アルキル、Ｒ^３５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、−Ｃ（Ｏ）Ｒ^３７、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル又はナフチルを表し、
Ｒ^３２は、Ｃ_１〜Ｃ_６アルキル又はＲ^３５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表し、
Ｒ^３３は、−Ｃ（Ｏ）Ｒ^３７を表し、
Ｒ^３４は、Ｃ_１〜Ｃ_６アルキルを表し、
Ｒ^３５は、ハロゲン原子、Ｃ_１〜Ｃ_６アルキルチオ又はフェニルを表し、
Ｒ^３７は、Ｃ_１〜Ｃ_６アルキル又はフェニルを表し、
Ｒ^４１は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、フェニル又はＤ１−３２を表し、
Ｒ^４２は、Ｃ_１〜Ｃ_６アルキルを表し、
Ｒ^４３は、Ｃ_１〜Ｃ_６アルコキシカルボニルを表し、
Ｒ^４４は、水素原子を表し、
Ｒ^４５は、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＨ、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_１０アルコキシカルボニル、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル又はＤ１−３４を表し、
Ｒ^５１は、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、ハロゲン原子によって任意に置換されたフェニル又はＤ１−３９を表し、
Ｒ^５１ａは、Ｃ_１〜Ｃ_６アルキルを表し、
Ｒ^５３及びＲ^５４は、各々独立してＣ_１〜Ｃ_６アルキルを表し、
ｇ２は、０、１又は２の整数を表し、
ｇ３及びｒ１は、各々独立して０、１又は２の整数を表し、
ｇ４、ｍ及びｎは、各々独立して０又は１の整数を表し、
ｆ７、ｐ及びｒ３は、０を表し、
ｑは、２又は３の整数を表し、
ｑ１は、１又は２の整数を表し、
ｑ２は、１、２又は３の整数を表し、
ｑ３は、１、２又は３の整数を表し、
ｒ２は、０又は２の整数を表す上記〔４〕に記載のオキシム化合物又はその塩。
〔８〕
Ｂは、Ｂ−１−ａを表し、
Ｚ^ａは、ハロゲン原子、ニトロ、Ｃ_１〜Ｃ_６アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_１〜Ｃ_６アルコキシ又はＣ_１〜Ｃ_６アルキルチオを表し、
Ｚ^ｃは、水素原子、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−ＯＲ^４１、−Ｓ（Ｏ）_ｒ３Ｒ^４１、−Ｃ（Ｏ）ＯＲ^４１、−Ｃ（Ｏ）Ｒ^４２、−Ｃ（Ｏ）Ｎ（Ｒ^４４ａ）Ｒ^４３ａ、−Ｃ（＝ＮＯＲ^４１）Ｒ^４２、−Ｎ（Ｒ^４４）Ｒ^４３、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−２、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４又はＤ１−３７を表し、
Ｚ^ｅは、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル又はＣ_１〜Ｃ_６アルコキシを表し、
Ｘ^１は、ハロゲン原子又はハロ（Ｃ_１〜Ｃ_６）アルキルを表し、
ｇ３は、０又は１の整数を表す上記〔７〕に記載のオキシム化合物又はその塩。
〔９〕
Ｂは、Ｂ−１又はＢ−２を表す上記〔１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１０〕
Ｂは、Ｂ−１を表す上記〔１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１１〕
Ｂは、Ｂ−２を表す上記〔１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１２〕
Ｂは、Ｂ−３を表す上記〔１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１３〕
Ｂは、Ｂ−１−ａを表す上記〔２〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１４〕
Ｂは、Ｂ−１−ｂを表す上記〔２〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１５〕
Ｂは、Ｂ−１又はＢ−２を表す上記〔３〕に記載のケトン化合物又はその塩。
〔１６〕
Ｂは、Ｂ−１を表す上記〔３〕に記載のケトン化合物又はその塩。
〔１７〕
Ｂは、Ｂ−２を表す上記〔３〕に記載のケトン化合物又はその塩。
〔１８〕
Ｂは、Ｂ−３を表す上記〔３〕に記載のケトン化合物又はその塩。
〔１９〕
Ｂは、Ｂ−１−ａを表す上記〔３〕、〔５〕に記載のケトン化合物又はその塩。
〔２０〕
Ｂは、Ｂ−１−ｂを表す上記〔３〕、〔５〕に記載のケトン化合物又はその塩。
〔２１〕
Ｂは、Ｂ−１又はＢ−２を表す上記〔４〕に記載のオキシム化合物又はそれらの塩。
〔２２〕
Ｂは、Ｂ−１を表す上記〔４〕に記載のオキシム化合物又はその塩。
〔２３〕
Ｂは、Ｂ−２を表す上記〔４〕に記載のオキシム化合物又はその塩。
〔２４〕
Ｂは、Ｂ−３を表す上記〔４〕に記載のオキシム化合物又はその塩。
〔２５〕
Ｂは、Ｂ−１−ａを表す上記〔４〕、〔７〕に記載のオキシム化合物又はその塩。
〔２６〕
Ｂは、Ｂ−１−ｂを表す上記〔４〕、〔７〕に記載のオキシム化合物又はその塩。
〔２７〕
Ａは、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル又はＲ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニルを表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔２８〕
Ａは、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_２〜Ｃ_６アルキニル又はＲ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニルを表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔２９〕
Ａは、水素原子、Ｃ_１〜Ｃ_６アルキル又はＲ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔３０〕
Ａは、水素原子、−Ｓ（Ｏ）_ｒ２Ｒ^１、−Ｃ（Ｏ）ＯＲ^１、−Ｃ（Ｏ）ＳＲ^１、−Ｃ（Ｓ）ＯＲ^１、−Ｃ（Ｏ）Ｒ^２、−Ｃ（Ｏ）Ｎ（Ｒ^４）Ｒ^３、−Ｃ（Ｓ）Ｎ（Ｒ^４）Ｒ^３又は−Ｓ（Ｏ）_２Ｎ（Ｒ^４）Ｒ^３を表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔３１〕
Ａは、水素原子、−Ｃ（Ｏ）ＯＲ^１、−Ｃ（Ｏ）ＳＲ^１、−Ｃ（Ｏ）Ｒ^２、−Ｃ（Ｏ）Ｎ（Ｒ^４）Ｒ^３又は−Ｃ（Ｓ）Ｎ（Ｒ^４）Ｒ^３を表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔３２〕
Ａは、水素原子、−Ｃ（Ｏ）ＳＲ^１、−Ｃ（Ｏ）Ｒ^２又は−Ｃ（Ｏ）Ｎ（Ｒ^４）Ｒ^３を表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔３３〕
Ａは、水素原子を表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔３４〕
Ａは、Ｃ_１〜Ｃ_６アルキル又はＲ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔３５〕
Ａは、Ｃ_２〜Ｃ_６アルキニル又はＲ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニルを表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔３６〕
Ａは、−Ｃ（Ｏ）ＳＲ^１を表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔３７〕
Ａは、−Ｃ（Ｏ）Ｒ^２を表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔３８〕
Ａは、−Ｃ（Ｏ）Ｎ（Ｒ^４）Ｒ^３を表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔３９〕
Ａは、−Ｃ（Ｓ）Ｎ（Ｒ^４）Ｒ^３を表す上記〔１〕〜〔２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔４０〕
Ｒ^１は、Ｃ_１〜Ｃ_８アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル又はＣ_２〜Ｃ_６アルケニルを表す上記〔１〕〜〔３９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔４１〕
Ｒ^１は、Ｃ_１〜Ｃ_８アルキルを表す上記〔１〕〜〔３９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔４２〕
Ｒ^１は、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表す上記〔１〕〜〔３９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔４３〕
Ｒ^１は、Ｃ_３〜Ｃ_８シクロアルキルを表す上記〔１〕〜〔３９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔４４〕
Ｒ^１は、Ｃ_２〜Ｃ_６アルケニルを表す上記〔１〕〜〔３９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔４５〕
Ｒ^２は、Ｃ_１〜Ｃ_８アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル又はＣ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル又は−Ｃ（＝ＮＯＲ^３１）Ｒ^３２を表す上記〔１〕〜〔４４〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔４６〕
Ｒ^２は、Ｃ_１〜Ｃ_８アルキル又はＲ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表す上記〔１〕〜〔４４〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔４７〕
Ｒ^２は、Ｃ_３〜Ｃ_８シクロアルキル又はＲ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキルを表す上記〔１〕〜〔４４〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔４８〕
Ｒ^２は、Ｃ_２〜Ｃ_６アルケニル又はＲ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニルを表す上記〔１〕〜〔４４〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔４９〕
Ｒ^２は、Ｃ_３〜Ｃ_８シクロアルケニル又はＲ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニルを表す上記〔１〕〜〔４４〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔５０〕
Ｒ^２は、Ｃ_２〜Ｃ_６アルキニル又はＲ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニルを表す上記〔１〕〜〔４４〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔５１〕
Ｒ^２は、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル、Ｄ１−５、Ｄ１−６、Ｄ１−８、Ｄ１−１０又はＤ１−８１を表す上記〔１〕〜〔４４〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔５２〕
Ｒ^２は、Ｃ_１〜Ｃ_８アルキルを表す上記〔１〕〜〔４４〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔５３〕
Ｒ^２は、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表す上記〔１〕〜〔４４〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔５４〕
Ｒ^３は、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_２〜Ｃ_６アルケニル、フェニル又は（Ｚ^２）_ｑ２で置換されたフェニルを表す上記〔１〕〜〔５３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔５５〕
Ｒ^３は、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル又はＣ_２〜Ｃ_６アルケニルを表す上記〔１〕〜〔５３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔５６〕
Ｒ^３は、フェニル又は（Ｚ^２）_ｑ２で置換されたフェニルを表す上記〔１〕〜〔５３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔５７〕
Ｒ^３は、Ｒ^３はＲ^４と一緒になってＣ_４又はＣ_５のアルキレン鎖を形成することにより、Ｒ^３及びＲ^４が結合する窒素原子と共に５又は６員環を形成し、このときこのアルキレン鎖は酸素原子又は窒素原子を１個含んでもよく、且つＣ_１〜Ｃ_６アルキルによって任意に置換されてもよい上記〔１〕〜〔５３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔５８〕
Ｒ^５は、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＲ^３１、−Ｓ（Ｏ）_ｒ２Ｒ^３１、−Ｃ（Ｏ）ＯＲ^３１又はフェニル、（Ｚ^２）_ｑ２で置換されたフェニルを表す上記〔１〕〜〔５７〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔５９〕
Ｒ^５は、ハロゲン原子、−ＯＲ^３１又は−Ｓ（Ｏ）_ｒ２Ｒ^３１を表す上記〔１〕〜〔５７〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔６０〕
Ｒ^５は、ハロゲン原子を表す上記〔１〕〜〔５７〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔６１〕
Ｒ^５は、−ＯＲ^３１を表す上記〔１〕〜〔５７〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔６２〕
Ｒ^５は、−Ｓ（Ｏ）_ｒ２Ｒ^３１を表す上記〔１〕〜〔５７〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔６３〕
Ｒ^５は、２つのＲ^５が同一の炭素上に置換している場合、２つのＲ^５は一緒になってＣ_１〜Ｃ_６アルコキシイミノを形成してもよい上記〔１〕〜〔５７〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔６４〕
Ｒ^６は、Ｃ_１〜Ｃ_６アルキル、Ｒ^１５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル又はＣ_２〜Ｃ_６アルケニルを表す上記〔１〕〜〔６３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔６５〕
Ｒ^６は、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル又はＤ１−３２を表す上記〔１〕〜〔６３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔６６〕
Ｒ^６は、Ｃ_１〜Ｃ_６アルキル又はＣ_３〜Ｃ_８シクロアルキルを表す上記〔１〕〜〔６３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔６７〕
Ｒ^６は、Ｃ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔６３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔６８〕
Ｒ^６は、Ｃ_３〜Ｃ_８シクロアルキルを表す上記〔１〕〜〔６３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔６９〕
Ｒ^７は、水素原子、Ｃ_１〜Ｃ_７アルキル、Ｒ^１５bで任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^１５bで任意に置換された（Ｃ_２〜Ｃ_６）アルケニル又はＣ_２〜Ｃ_６アルキニルを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔６３〕に記載のオキシム化合物又はその塩。
〔７０〕
Ｒ^７は、水素原子、Ｃ_１〜Ｃ_７アルキル又はＲ^１５bで任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔６３〕に記載のオキシム化合物又はその塩。
〔７１〕
Ｒ^７は、水素原子を表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔６３〕に記載のオキシム化合物又はその塩。
〔７２〕
Ｒ^７は、Ｃ_１〜Ｃ_７アルキルを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔６３〕に記載のオキシム化合物又はその塩。
〔７３〕
Ｒ^７は、Ｒ^１５bで任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔６３〕に記載のオキシム化合物又はその塩。
〔７４〕
Ｒ^８ａは、水素原子、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル又は−Ｃ（Ｏ）ＯＲ^１６ａを表す上記〔１〕〜〔７３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔７５〕
Ｒ^８ａは、水素原子又はＣ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔７３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔７６〕
Ｒ^８ａは、水素原子を表す上記〔１〕〜〔７３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔７７〕
Ｒ^８ａは、Ｃ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔７３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔７８〕
Ｒ^９ａは、水素原子を表す上記〔１〕〜〔７７〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔７９〕
Ｒ^９ａは、Ｃ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔７９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔８０〕
Ｒ^１５は、ハロゲン原子を表す上記〔１〕〜〔７９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔８１〕
Ｒ^１５は、Ｃ_３〜Ｃ_８シクロアルキルを表す上記〔１〕〜〔７９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔８２〕
Ｒ^１５は、−ＯＲ^１６を表す上記〔１〕〜〔７９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔８３〕
Ｒ^１５ｂは、ハロゲン原子、シアノ、ハロ（Ｃ_３〜Ｃ_８）シクロアルキル、−ＯＲ^１６ｂ、−Ｓ（Ｏ）_ｒ１Ｒ^１６ｂ又は−Ｃ（Ｏ）Ｎ（Ｒ^１８ｂ）Ｒ^１９ｂを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔８２〕に記載のオキシム化合物又はその塩。
〔８４〕
Ｒ^１５ｂは、ハロゲン原子、シアノ、−ＯＲ^１６ｂ又は−Ｓ（Ｏ）_ｒ１Ｒ^１６ｂを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔８２〕に記載のオキシム化合物又はその塩。
〔８５〕
Ｒ^１５ｂは、ハロゲン原子を表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔８２〕に記載のオキシム化合物又はその塩。
〔８６〕
Ｒ^１５ｂは、シアノを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔８２〕に記載のオキシム化合物又はその塩。
〔８７〕
Ｒ^１５ｂは、−ＯＲ^１６ｂを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔８２〕に記載のオキシム化合物又はその塩。
〔８８〕
Ｒ^１５ｂは、−Ｓ（Ｏ）_ｒ１Ｒ^１６ｂを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔８２〕に記載のオキシム化合物又はその塩。
〔８９〕
Ｒ^１５ｂは、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル、Ｄ１−３２又はＤ１−８４を表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔８２〕に記載のオキシム化合物又はその塩。
〔９０〕
Ｒ^１５ｂは、フェニル又は（Ｚ^１）_ｑ１で置換されたフェニルを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔８２〕に記載のオキシム化合物又はその塩。
〔９１〕
Ｒ^１８ｂは、水素原子又はＣ_１〜Ｃ_６アルキルを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔９０〕に記載のオキシム化合物又はその塩。
〔９２〕
Ｒ^１８ｂは、Ｒ^１８ｂはＲ^１９ｂと一緒になってＣ_５のアルキレン鎖を形成することにより、Ｒ^１８ｂ及びＲ^１９ｂが結合する窒素原子と共に６員環を形成し、このときこのアルキレン鎖は酸素原子を１個含んでいることを表す上記〔１〕、〔２〕、〔４〕、〔７〕〜〔１４〕、〔２１〕〜〔９０〕に記載のオキシム化合物又はその塩。
〔９３〕
Ｘ^１は、ハロ（Ｃ_１〜Ｃ_６）アルキル又はＣ_３〜Ｃ_８シクロアルキルを表す上記〔１〕〜〔９２〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔９４〕
Ｘ^１は、ハロゲン原子又はＣ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔９２〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔９５〕
Ｘ^１は、ハロゲン原子を表す上記〔１〕〜〔９２〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔９６〕
Ｘ^１は、Ｃ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔９２〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔９７〕
Ｚ^ａは、ハロゲン原子を表す上記〔１〕〜〔９６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔９８〕
Ｚ^ａは、Ｃ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔９６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔９９〕
Ｚ^ａは、Ｃ_１〜Ｃ_６アルコキシを表す上記〔１〕〜〔９６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１００〕
Ｚ^ａは、Ｃ_１〜Ｃ_６アルキルチオを表す上記〔１〕〜〔９６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１０１〕
Ｚ^ｃは、水素原子、ハロゲン原子、シアノ、Ｃ_１〜Ｃ_６アルキル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−２、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４又はＤ１−３７を表す上記〔１〕〜〔１００〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１０２〕
Ｚ^ｃは、水素原子、ハロゲン原子、シアノ、Ｃ_１〜Ｃ_６アルキル、Ｃ_２〜Ｃ_６アルキニル又はＲ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニルを表す上記〔１〕〜〔１００〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１０３〕
Ｚ^ｃは、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−２、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４又はＤ１−３７を表す上記〔１〕〜〔１００〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１０４〕
Ｚ^ｃは、Ｃ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔１００〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１０５〕
Ｚ^ｃは、Ｃ_２〜Ｃ_６アルキニル又はＲ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニルを表す上記〔１〕〜〔１００〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１０６〕
Ｚ^ｃは、フェニル又は（Ｚ^３）_ｑ３で置換されたフェニルを表す上記〔１〕〜〔１００〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１０７〕
Ｚ^ｃは、Ｄ１−２、Ｄ１−７、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４又はＤ１−３７を表す上記〔１〕〜〔１００〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１０８〕
Ｚ^ｃは、Ｄ１−３２、Ｄ１−３３又はＤ１−３４を表す上記〔１〕〜〔１００〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１０９〕
Ｚ^ｃは、Ｄ１−７を表す上記〔１〕〜〔１００〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１１０〕
Ｚ^ｅは、ハロゲン原子を表す上記〔１〕〜〔１０９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１１１〕
Ｚ^ｅは、Ｃ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔１０９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１１２〕
Ｚ^ｅは、Ｃ_１〜Ｃ_６アルコキシを表す上記〔１〕〜〔１０９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１１３〕
Ｚ^ｅは、Ｃ_１〜Ｃ_６アルキルチオを表す上記〔１〕〜〔１０９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１１４〕
Ｚ^２は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、−ＯＲ^５１又は−Ｓ（Ｏ）_ｒ２Ｒ^５１を表す上記〔１〕〜〔１１３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１１５〕
Ｚ^２は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル又はハロ（Ｃ_１〜Ｃ_６）アルキルを表す上記〔１〕〜〔１１３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１１６〕
Ｚ^２は、ハロゲン原子又はＣ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔１１３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１１７〕
Ｚ^２は、−ＯＲ^５１又は−Ｓ（Ｏ）_ｒ２Ｒ^５１を表す上記〔１〕〜〔１１３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１１８〕
Ｚ^２は、ハロゲン原子を表す上記〔１〕〜〔１１３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１１９〕
Ｚ^２は、Ｃ_１〜Ｃ_６アルキル、を表す上記〔１〕〜〔１１３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１２０〕
Ｚ^２は、−ＯＲ^５１を表す上記〔１〕〜〔１１３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１２１〕
Ｚ^２は、−Ｓ（Ｏ）_ｒ２Ｒ^５１を表す上記〔１〕〜〔１１３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１２２〕
Ｚ^３は、ハロゲン原子又はハロ（Ｃ_１〜Ｃ_６）アルコキシを表す上記〔１〕〜〔１２１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１２３〕
Ｚ^３は、ハロゲン原子を表す上記〔１〕〜〔１２１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１２４〕
Ｚ^３は、ハロ（Ｃ_１〜Ｃ_６）アルコキシを表す上記〔１〕〜〔１２１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１２５〕
Ｒ^３２は、Ｃ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔１２４〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１２６〕
Ｒ^３２は、Ｒ^３５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表す上記〔１〕〜〔１２４〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１２７〕
Ｒ^３５は、ハロゲン原子を表す上記〔１〕〜〔１２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１２８〕
Ｒ^３５は、Ｃ_１〜Ｃ_６アルキルチオを表す上記〔１〕〜〔１２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１２９〕
Ｒ^３５は、フェニルを表す上記〔１〕〜〔１２６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１３０〕
Ｒ^３７は、Ｃ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔１２９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１３１〕
Ｒ^３７は、フェニルを表す上記〔１〕〜〔１２９〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１３２〕
Ｒ^４１は、水素原子、Ｃ_１〜Ｃ_６アルキル又はＲ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表す上記〔１〕〜〔１３１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１３３〕
Ｒ^４１は、フェニル又はＤ１−３２を表す上記〔１〕〜〔１３１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１３４〕
Ｒ^４１は、水素原子を表す上記〔１〕〜〔１３１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１３５〕
Ｒ^４１は、Ｃ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔１３１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１３６〕
Ｒ^４１は、Ｒ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表す上記〔１〕〜〔１３１〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１３７〕
Ｒ^４５は、ハロゲン原子、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＨ又はＣ_１〜Ｃ_６アルコキシを表す上記〔１〕〜〔１３６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１３８〕
Ｒ^４５は、フェニル又はＤ１−３４を表す上記〔１〕〜〔１３６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１３９〕
Ｒ^４５は、ハロゲン原子を表す上記〔１〕〜〔１３６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１４０〕
Ｒ^４５は、Ｃ_３〜Ｃ_８シクロアルキルを表す上記〔１〕〜〔１３６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１４１〕
Ｒ^４５は、−ＯＨを表す上記〔１〕〜〔１３６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１４２〕
Ｒ^４５は、Ｃ_１〜Ｃ_６アルコキシを表す上記〔１〕〜〔１３６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１４３〕
Ｒ^５１は、Ｃ_１〜Ｃ_６アルキルを表す上記〔１〕〜〔１４２〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１４４〕
ｍは、０又は１の整数を表す上記〔１〕〜〔１４３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１４５〕
ｍは、０の整数を表す上記〔１〕〜〔１４３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１４６〕
ｍは、１の整数を表す上記〔１〕〜〔１４３〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１４７〕
ｎは、０又は１の整数を表す上記〔１〕〜〔１４６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１４８〕
ｎは、０の整数を表す上記〔１〕〜〔１４６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１４９〕
ｎは、１の整数を表す上記〔１〕〜〔１４６〕に記載のケトン若しくはオキシム化合物又はそれらの塩。
〔１５０〕
上記〔１〕〜〔１４９〕に記載のケトン及びオキシム化合物並びにそれらの塩から選ばれる１種又は２種以上を有効成分として含有する農薬。
〔１５１〕
上記〔１〕〜〔１４９〕に記載のケトン及びオキシム化合物並びにそれらの塩から選ばれる１種又は２種以上を有効成分として含有する除草剤。 Z ^a , Z ^c And Z ^e Each independently represents a hydrogen atom, a halogen atom, cyano, nitro, C ₁ ~ C ₆ Alkyl, R ⁴⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl, R ⁴⁵ Optionally substituted with (C ₃ ~ C ₈ ) Cycloalkyl, C ₂ ~ C ₆ Alkenyl, R ⁴⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkenyl, C ₂ ~ C ₆ Alkynyl, R ⁴⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkynyl, -OR ⁴¹ , -S (O) _r3 R ⁴¹ , -C (O) OR ⁴¹ , -C (O) R ⁴² , -C (O) N (R ^44a ) R ^43a , -C (= NOR ⁴¹ ) R ⁴² , -N (R ⁴⁴ ) R ⁴³ , Phenyl, (Z ³ ) _q3 Phenyl, D1-1, D1-2, D1-7, D1-10, D1-11, D1-22, D1-32, D1-33, D1-34, D1-36, D1-37 or The ketone or oxime compound or a salt thereof according to the above [1], which represents D1-38.
[3]
Q is the ketone compound or a salt thereof according to the above [2], wherein Q represents an oxygen atom.
[4]
Q is NOR ⁷ The oxime compound or a salt thereof according to the above [2], wherein
[5]
A is a hydrogen atom, C ₁ ~ C ₆ Alkyl or -C (O) R ² Represents
R ² Is C ₁ ~ C ₈ Represents alkyl,
R ⁶ Is C ₁ ~ C ₆ Alkyl, R ¹⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, -C (= NOR ¹⁶ ) R ¹⁷ , Phenyl, (Z ¹ ) _q1 Represents phenyl or D1-32 substituted with
R ^8a Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, -C (O) OR ^16a Or -C (O) R ^17a Represents
R ^9a Is a hydrogen atom or C ₁ ~ C ₆ Represents alkyl,
R ^8b And R ^9b Represents a hydrogen atom,
R ¹⁰ , R ¹¹ And R ¹² Represents a hydrogen atom,
R ¹⁵ Is a halogen atom, C ₃ ~ C ₈ Cycloalkyl, -OR ¹⁶ Or phenyl,
R ¹⁶ , R ^16a , R ¹⁷ And R ^17a Are each independently C ₁ ~ C ₆ Represents alkyl,
X ¹ Is a halo (C ₁ ~ C ₆ ) Represents alkyl,
Z ^a , Z ^c And Z ^e Each independently represents a hydrogen atom, a halogen atom, or C ₁ ~ C ₆ Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, R ⁴⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkenyl, C ₂ ~ C ₆ Alkynyl, -OR ⁴¹ , Phenyl, (Z ³ ) _q3 Represents phenyl, D1-7, D1-11, D1-22, D1-32 or D1-37, substituted with
Z ¹ Represents a halogen atom,
Z ³ Is a halogen atom, C ₁ ~ C ₆ Alkyl, halo (C ₁ ~ C ₆ ) Alkyl, C ₁ ~ C ₆ Alkoxy, halo (C ₁ ~ C ₆ ) Alkoxy or C ₁ ~ C ₆ Represents alkylthio,
R ⁴¹ Is C ₁ ~ C ₆ Alkyl, R ⁴⁵ Optionally substituted with (C ₁ ~ C ₆ ) Represents alkyl, phenyl, D1-32 or D1-34;
R ⁴⁵ Represents a halogen atom, phenyl or D1-34;
g2, g3 and p represent 0;
q1 and q3 represent an integer of 1,
g4, m and n each independently represents an integer of 0 or 1, the ketone compound or a salt thereof according to the above [3].
[6]
B represents B-1-a,
Z ^a Is a halogen atom, C ₁ ~ C ₆ Alkyl or C ₁ ~ C ₆ Represents alkoxy,
Z ^c Is a halogen atom, C ₁ ~ C ₆ Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, R ⁴⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkenyl, C ₂ ~ C ₆ Alkynyl, -OR ⁴¹ , Phenyl, (Z ³ ) _q3 Represents phenyl, D1-7, D1-11, D1-22, D1-32 or D1-37, substituted with
Z ^e Is a halogen atom or C ₁ ~ C ₆ The ketone compound or a salt thereof according to the above [5], which represents alkyl.
[7]
A is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkenyl, C ₂ ~ C ₆ Alkynyl, R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkynyl, -S (O) _r2 R ¹ , -C (O) OR ¹ , -C (O) SR ¹ , -C (S) OR ¹ , -C (O) R ² , -C (O) N (R ⁴ ) R ³ , -C (S) N (R ⁴ ) R ³ Or -S (O) ₂ N (R ⁴ ) R ³ Represents
R ¹ Is C ₁ ~ C ₈ Alkyl, R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, phenyl or (Z ² ) _q2 Represents phenyl substituted with
R ² Is C ₁ ~ C ₈ Alkyl, R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl, R ⁵ Optionally substituted with (C ₃ ~ C ₈ ) Cycloalkyl, C ₂ ~ C ₆ Alkenyl, R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkenyl, C ₃ ~ C ₈ Cycloalkenyl, R ⁵ Optionally substituted with (C ₃ ~ C ₈ ) Cycloalkenyl, C ₂ ~ C ₆ Alkynyl, R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkynyl, -C (= NOR ³¹ ) R ³² , Phenyl, (Z ² ) _q2 Represents phenyl, D1-5, D1-6, D1-8, D1-10 or D1-81 substituted with
R ³ Is C ₁ ~ C ₆ Alkyl, R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₂ ~ C ₆ Alkenyl, phenyl or (Z ² ) _q2 Represents phenyl substituted with R, or R ³ Is R ⁴ Together with C ₄ Or C ₅ By forming an alkylene chain of ³ And R ⁴ Forms a 5- or 6-membered ring with the nitrogen atom to which is bonded, wherein the alkylene chain may contain one oxygen, sulfur or nitrogen atom, and C ₁ ~ C ₆ Optionally substituted by alkyl,
R ⁴ Is C ₁ ~ C ₆ Alkyl, C ₂ ~ C ₆ Represents alkenyl or phenyl,
R ⁵ Is a halogen atom, cyano, C ₃ ~ C ₈ Cycloalkyl, -OR ³¹ , -S (O) _r2 R ³¹ , -C (O) OR ³¹ , -C (O) R ³² , -N (R ³⁴ ) R ³³ , -Si (R ^32a ) (R ^32b ) R ^32c , Phenyl, (Z ² ) _q2 Represents phenyl or D1-1 substituted with or two R ⁵ Are substituted on the same carbon, two R ⁵ Together C ₁ ~ C ₆ An alkoxyimino may be formed,
R ⁶ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ¹⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, -C (= NOR ¹⁶ ) R ¹⁷ , Phenyl, (Z ¹ ) _q1 Represents phenyl or D1-32 substituted with
R ⁷ Is a hydrogen atom, C ₁ ~ C ₇ Alkyl, R ^15b Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, C ₃ ~ C ₈ Cycloalkenyl, R ^15b Optionally substituted with (C ₂ ~ C ₆ ) Alkenyl, C ₂ ~ C ₆ Represents alkynyl or phenyl,
R ^8a Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, halo (C ₁ ~ C ₆ ) Alkyl, -C (O) OR ^16a , -C (= NOR ^16a ) R ^17a Or (Z ¹ ) _q1 Represents phenyl substituted with
R ^9a Is a hydrogen atom or C ₁ ~ C ₆ Represents alkyl,
R ^8b And R ^9b Represents a hydrogen atom,
R ¹² Represents a hydrogen atom,
R ¹⁵ Is a halogen atom, C ₃ ~ C ₈ Cycloalkyl or -OR ¹⁶ Represents
R ^15b Is a halogen atom, cyano, C ₃ ~ C ₈ Cycloalkyl, Halo (C ₃ ~ C ₈ ) Cycloalkyl, -OR ^16b , -S (O) _r1 R ^16b , -C (O) OR ^16b , -C (O) N (R ^18b ) R ^19b , -C (= NOR ^16b ) R ^17b , -N (R ^18b ) R ^19b , -Si (R ^32a ) (R ^32b ) R ^32c , Phenyl, (Z ¹ ) _q1 Represents phenyl, D1-32 or D1-84 substituted with
R ¹⁶ , R ^16a , R ¹⁷ , R ^17a And R ^17b Are each independently C ₁ ~ C ₆ Represents alkyl,
R ^18b Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ²⁰ Optionally substituted with (C ₁ ~ C ₆ ) Represents alkyl or phenyl, or R ^18b Is R ^19b Together with C ₅ By forming an alkylene chain of ^18b And R ^19b Forms a 6-membered ring with the nitrogen atom to which is bonded, and at this time, the alkylene chain contains one oxygen atom,
R ^19b Is a hydrogen atom or C ₁ ~ C ₆ Represents alkyl,
R ²⁰ (Z ¹ ) _q1 Represents phenyl substituted with
X ¹ Is a halogen atom, C ₁ ~ C ₆ Alkyl, halo (C ₁ ~ C ₆ ) Alkyl or C ₃ ~ C ₈ Represents cycloalkyl, g3 represents an integer of 2, and two X ¹ Are adjacent to each other to form -CH = CHCH = CH- ¹ Forms a 6-membered ring with the carbon atom to which is bonded, and at this time, one of the hydrogen atoms bonded to each carbon atom forming the ring may be replaced by a halogen atom
X ^1a Is C ₁ ~ C ₆ Represents alkyl,
Z ^a , Z ^c And Z ^e Each independently represents a hydrogen atom, a halogen atom, cyano, nitro, C ₁ ~ C ₆ Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, R ⁴⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkenyl, C ₂ ~ C ₆ Alkynyl, R ⁴⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkynyl, -OR ⁴¹ , -S (O) _r3 R ⁴¹ , -C (O) OR ⁴¹ , -C (O) R ⁴² , -C (O) N (R ^44a ) R ^43a , -C (= NOR ⁴¹ ) R ⁴² , -N (R ⁴⁴ ) R ⁴³ , Phenyl, (Z ³ ) _q3 Represents phenyl, D1-2, D1-7, D1-11, D1-22, D1-32, D1-33, D1-34 or D1-37 substituted with
Z ¹ Is a halogen atom, nitro, C ₁ ~ C ₆ Alkyl, halo (C ₁ ~ C ₆ ) Alkyl, C ₁ ~ C ₆ Alkoxy or C ₁ ~ C ₆ Represents alkoxycarbonyl, and when q1 represents an integer of 2 or more, each Z ¹ May be the same or different from each other,
Z ² Is a halogen atom, cyano, nitro, C ₁ ~ C ₆ Alkyl, halo (C ₁ ~ C ₆ ) Alkyl, -OR ⁵¹ , -S (O) _r2 R ⁵¹ , -C (O) OR ^51a , -C (O) R ⁵² Or -C (O) N (R ⁵⁴ ) R ⁵³ And when q2 represents an integer of 2 or more, each Z ² May be the same as or different from each other, and two Z ² Are adjacent to each other, two adjacent Z ² Form -N = CHCH = CH- to form each Z ² May form a 6-membered ring together with the carbon atom to which is bonded, and at this time, one of the hydrogen atoms bonded to each carbon atom forming the ring may be substituted with a halogen atom,
Z ³ Is a halogen atom, C ₁ ~ C ₆ Alkyl, halo (C ₁ ~ C ₆ ) Alkyl, C ₁ ~ C ₆ Alkoxy, halo (C ₁ ~ C ₆ ) Alkoxy or C ₁ ~ C ₆ When alkylthio represents q3 and represents an integer of 2 or more, each Z ³ May be the same or different from each other,
R ³¹ Is C ₁ ~ C ₆ Alkyl, R ³⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, -C (O) R ³⁷ , Phenyl, (Z ² ) _q2 Represents phenyl or naphthyl substituted with
R ³² Is C ₁ ~ C ₆ Alkyl or R ³⁵ Optionally substituted with (C ₁ ~ C ₆ ) Represents alkyl,
R ³³ Is -C (O) R ³⁷ Represents
R ³⁴ Is C ₁ ~ C ₆ Represents alkyl,
R ³⁵ Is a halogen atom, C ₁ ~ C ₆ Represents alkylthio or phenyl,
R ³⁷ Is C ₁ ~ C ₆ Represents alkyl or phenyl,
R ⁴¹ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ⁴⁵ Optionally substituted with (C ₁ ~ C ₆ ) Represents alkyl, phenyl or D1-32.
R ⁴² Is C ₁ ~ C ₆ Represents alkyl,
R ⁴³ Is C ₁ ~ C ₆ Represents alkoxycarbonyl,
R ⁴⁴ Represents a hydrogen atom,
R ⁴⁵ Is a halogen atom, cyano, C ₃ ~ C ₈ Cycloalkyl, -OH, C ₁ ~ C ₆ Alkoxy, C ₁ ~ C ₁₀ Alkoxycarbonyl, -Si (R ^32a ) (R ^32b ) R ^32c , Phenyl or D1-34,
R ⁵¹ Is C ₁ ~ C ₆ Alkyl, halo (C ₁ ~ C ₆ ) Represents alkyl, phenyl optionally substituted by halogen atoms or D1-39,
R ^51a Is C ₁ ~ C ₆ Represents alkyl,
R ⁵³ And R ⁵⁴ Are each independently C ₁ ~ C ₆ Represents alkyl,
g2 represents an integer of 0, 1 or 2;
g3 and r1 each independently represents an integer of 0, 1 or 2;
g4, m and n each independently represent an integer of 0 or 1,
f7, p and r3 represent 0;
q represents an integer of 2 or 3,
q1 represents an integer of 1 or 2,
q2 represents an integer of 1, 2 or 3,
q3 represents an integer of 1, 2 or 3,
r2 represents the integer of 0 or 2, The oxime compound or its salt as described in said [4].
[8]
B represents B-1-a,
Z ^a Is a halogen atom, nitro, C ₁ ~ C ₆ Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, C ₁ ~ C ₆ Alkoxy or C ₁ ~ C ₆ Represents alkylthio,
Z ^c Is a hydrogen atom, halogen atom, cyano, nitro, C ₁ ~ C ₆ Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, R ⁴⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkenyl, C ₂ ~ C ₆ Alkynyl, R ⁴⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkynyl, -OR ⁴¹ , -S (O) _r3 R ⁴¹ , -C (O) OR ⁴¹ , -C (O) R ⁴² , -C (O) N (R ^44a ) R ^43a , -C (= NOR ⁴¹ ) R ⁴² , -N (R ⁴⁴ ) R ⁴³ , Phenyl, (Z ³ ) _q3 Represents phenyl, D1-2, D1-7, D1-11, D1-22, D1-32, D1-33, D1-34 or D1-37 substituted with
Z ^e Is a halogen atom, C ₁ ~ C ₆ Alkyl or C ₁ ~ C ₆ Represents alkoxy,
X ¹ Is a halogen atom or halo (C ₁ ~ C ₆ ) Represents alkyl,
g3 represents the integer of 0 or 1, The oxime compound or its salt as described in said [7].
[9]
B is the ketone or oxime compound or a salt thereof according to the above [1], wherein B represents B-1 or B-2.
[10]
B is the ketone or oxime compound or a salt thereof according to the above [1], which represents B-1.
[11]
B is the ketone or oxime compound or a salt thereof according to the above [1], which represents B-2.
[12]
B is the ketone or oxime compound or a salt thereof according to the above [1], wherein B represents B-3.
[13]
B is the ketone or oxime compound or a salt thereof according to the above [2], which represents B-1-a.
[14]
B is the ketone or oxime compound or a salt thereof according to the above [2], which represents B-1-b.
[15]
B is the ketone compound or a salt thereof according to the above [3], which represents B-1 or B-2.
[16]
B is the ketone compound or a salt thereof according to the above [3], which represents B-1.
[17]
B is the ketone compound or a salt thereof according to the above [3], which represents B-2.
[18]
B is the ketone compound or a salt thereof according to the above [3], which represents B-3.
[19]
B is the ketone compound or a salt thereof according to the above [3] or [5], which represents B-1-a.
[20]
B is the ketone compound or a salt thereof according to the above [3] or [5], which represents B-1-b.
[21]
B is the oxime compound or a salt thereof according to the above [4], wherein B represents B-1 or B-2.
[22]
B is the oxime compound or a salt thereof according to the above [4], which represents B-1.
[23]
B is the oxime compound or a salt thereof according to the above [4], which represents B-2.
[24]
B is the oxime compound or a salt thereof according to the above [4], which represents B-3.
[25]
B is the oxime compound or a salt thereof according to the above [4] or [7], which represents B-1-a.
[26]
B is the oxime compound or a salt thereof according to the above [4] or [7], which represents B-1-b.
[27]
A is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkenyl, C ₂ ~ C ₆ Alkynyl or R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) The ketone or oxime compound or a salt thereof according to the above [1] to [26], which represents alkynyl.
[28]
A is a hydrogen atom, C ₁ ~ C ₆ Alkyl, R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₂ ~ C ₆ Alkenyl, C ₂ ~ C ₆ Alkynyl or R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) The ketone or oxime compound or the salt thereof according to [1] to [26], which represents alkynyl.
[29]
A is a hydrogen atom, C ₁ ~ C ₆ Alkyl or R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) The ketone or oxime compound or the salt thereof according to the above [1] to [26], which represents alkyl.
[30]
A is a hydrogen atom, -S (O) _r2 R ¹ , -C (O) OR ¹ , -C (O) SR ¹ , -C (S) OR ¹ , -C (O) R ² , -C (O) N (R ⁴ ) R ³ , -C (S) N (R ⁴ ) R ³ Or -S (O) ₂ N (R ⁴ ) R ³ The ketone or oxime compound according to the above [1] to [26], or a salt thereof.
[31]
A is a hydrogen atom, -C (O) OR ¹ , -C (O) SR ¹ , -C (O) R ² , -C (O) N (R ⁴ ) R ³ Or -C (S) N (R ⁴ ) R ³ The ketone or oxime compound according to the above [1] to [26], or a salt thereof.
[32]
A is a hydrogen atom, -C (O) SR ¹ , -C (O) R ² Or -C (O) N (R ⁴ ) R ³ The ketone or oxime compound according to the above [1] to [26], or a salt thereof.
[33]
A is the ketone or oxime compound or a salt thereof according to the above [1] to [26], wherein A represents a hydrogen atom.
[34]
A is C ₁ ~ C ₆ Alkyl or R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) The ketone or oxime compound or the salt thereof according to the above [1] to [26], which represents alkyl.
[35]
A is C ₂ ~ C ₆ Alkynyl or R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) The ketone or oxime compound or the salt thereof according to [1] to [26], which represents alkynyl.
[36]
A is -C (O) SR ¹ The ketone or oxime compound according to the above [1] to [26], or a salt thereof.
[37]
A is -C (O) R ² The ketone or oxime compound according to the above [1] to [26], or a salt thereof.
[38]
A is —C (O) N (R ⁴ ) R ³ The ketone or oxime compound according to the above [1] to [26], or a salt thereof.
[39]
A is -C (S) N (R ⁴ ) R ³ The ketone or oxime compound according to the above [1] to [26], or a salt thereof.
[40]
R ¹ Is C ₁ ~ C ₈ Alkyl, R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl or C ₂ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [39], which represents alkenyl.
[41]
R ¹ Is C ₁ ~ C ₈ The ketone or oxime compound or a salt thereof according to the above [1] to [39], which represents alkyl.
[42]
R ¹ Is R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) The ketone or oxime compound or a salt thereof according to the above [1] to [39], which represents alkyl.
[43]
R ¹ Is C ₃ ~ C ₈ The ketone or oxime compound or a salt thereof according to the above [1] to [39], which represents cycloalkyl.
[44]
R ¹ Is C ₂ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [39], which represents alkenyl.
[45]
R ² Is C ₁ ~ C ₈ Alkyl, R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl, R ⁵ Optionally substituted with (C ₃ ~ C ₈ ) Cycloalkyl, C ₂ ~ C ₆ Alkenyl, R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkenyl, C ₃ ~ C ₈ Cycloalkenyl, R ⁵ Optionally substituted with (C ₃ ~ C ₈ ) Cycloalkenyl or C ₂ ~ C ₆ Alkynyl, R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkynyl or -C (= NOR ³¹ ) R ³² The ketone or oxime compound according to the above [1] to [44], or a salt thereof.
[46]
R ² Is C ₁ ~ C ₈ Alkyl or R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) The ketone or oxime compound or the salt thereof according to the above [1] to [44], which represents alkyl.
[47]
R ² Is C ₃ ~ C ₈ Cycloalkyl or R ⁵ Optionally substituted with (C ₃ ~ C ₈ ) The ketone or oxime compound or a salt thereof according to the above [1] to [44], which represents cycloalkyl.
[48]
R ² Is C ₂ ~ C ₆ Alkenyl or R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) The ketone or oxime compound or the salt thereof according to the above [1] to [44], which represents alkenyl.
[49]
R ² Is C ₃ ~ C ₈ Cycloalkenyl or R ⁵ Optionally substituted with (C ₃ ~ C ₈ ) The ketone or oxime compound or a salt thereof according to the above [1] to [44], which represents cycloalkenyl.
[50]
R ² Is C ₂ ~ C ₆ Alkynyl or R ⁵ Optionally substituted with (C ₂ ~ C ₆ ) The ketone or oxime compound or the salt thereof according to the above [1] to [44], which represents alkynyl.
[51]
R ² Is phenyl, (Z ² ) _q2 The ketone or oxime compound or a salt thereof according to the above [1] to [44], which represents phenyl, D1-5, D1-6, D1-8, D1-10 or D1-81 substituted by
[52]
R ² Is C ₁ ~ C ₈ The ketone or oxime compound or a salt thereof according to the above [1] to [44], which represents alkyl.
[53]
R ² Is R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) The ketone or oxime compound or the salt thereof according to the above [1] to [44], which represents alkyl.
[54]
R ³ Is C ₁ ~ C ₆ Alkyl, R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₂ ~ C ₆ Alkenyl, phenyl or (Z ² ) _q2 The ketone or oxime compound or a salt thereof according to the above [1] to [53], which represents phenyl substituted with
[55]
R ³ Is C ₁ ~ C ₆ Alkyl, R ⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl or C ₂ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [53], which represents alkenyl.
[56]
R ³ Is phenyl or (Z ² ) _q2 The ketone or oxime compound or a salt thereof according to the above [1] to [53], which represents phenyl substituted with
[57]
R ³ Is R ³ Is R ⁴ Together with C ₄ Or C ₅ By forming an alkylene chain of ³ And R ⁴ Forms a 5- or 6-membered ring with the nitrogen atom to which is bonded, wherein the alkylene chain may contain one oxygen or nitrogen atom, and C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [53], which may be optionally substituted with alkyl.
[58]
R ⁵ Is a halogen atom, cyano, C ₃ ~ C ₈ Cycloalkyl, -OR ³¹ , -S (O) _r2 R ³¹ , -C (O) OR ³¹ Or phenyl, (Z ² ) _q2 The ketone or oxime compound or a salt thereof according to the above [1] to [57], which represents phenyl substituted with.
[59]
R ⁵ Is a halogen atom, -OR ³¹ Or -S (O) _r2 R ³¹ The ketone or oxime compound according to the above [1] to [57] or a salt thereof.
[60]
R ⁵ Is a ketone or oxime compound or a salt thereof according to the above [1] to [57], which represents a halogen atom.
[61]
R ⁵ Is -OR ³¹ The ketone or oxime compound according to the above [1] to [57] or a salt thereof.
[62]
R ⁵ Is -S (O) _r2 R ³¹ The ketone or oxime compound according to the above [1] to [57] or a salt thereof.
[63]
R ⁵ Is two R ⁵ Are substituted on the same carbon, two R ⁵ Together C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [57], which may form an alkoxyimino.
[64]
R ⁶ Is C ₁ ~ C ₆ Alkyl, R ¹⁵ Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl or C ₂ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [63], which represents alkenyl.
[65]
R ⁶ Is phenyl, (Z ¹ ) _q1 The ketone or oxime compound or a salt thereof according to the above [1] to [63], which represents phenyl substituted with or D1-32.
[66]
R ⁶ Is C ₁ ~ C ₆ Alkyl or C ₃ ~ C ₈ The ketone or oxime compound or a salt thereof according to the above [1] to [63], which represents cycloalkyl.
[67]
R ⁶ Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [63], which represents alkyl.
[68]
R ⁶ Is C ₃ ~ C ₈ The ketone or oxime compound or a salt thereof according to the above [1] to [63], which represents cycloalkyl.
[69]
R ⁷ Is a hydrogen atom, C ₁ ~ C ₇ Alkyl, R ^15b Optionally substituted with (C ₁ ~ C ₆ ) Alkyl, C ₃ ~ C ₈ Cycloalkyl, C ₂ ~ C ₆ Alkenyl, C ₃ ~ C ₈ Cycloalkenyl, R ^15b Optionally substituted with (C ₂ ~ C ₆ ) Alkenyl or C ₂ ~ C ₆ The oxime compound or a salt thereof according to the above [1], [2], [4], [7] to [14], [21] to [63] representing alkynyl.
[70]
R ⁷ Is a hydrogen atom, C ₁ ~ C ₇ Alkyl or R ^15b Optionally substituted with (C ₁ ~ C ₆ ) The oxime compound or a salt thereof according to the above [1], [2], [4], [7] to [14], [21] to [63] representing alkyl.
[71]
R ⁷ Represents an oxime compound or a salt thereof according to the above [1], [2], [4], [7] to [14], [21] to [63] representing a hydrogen atom.
[72]
R ⁷ Is C ₁ ~ C ₇ The oxime compound or a salt thereof according to the above [1], [2], [4], [7] to [14], [21] to [63] representing alkyl.
[73]
R ⁷ Is R ^15b Optionally substituted with (C ₁ ~ C ₆ ) The oxime compound or a salt thereof according to the above [1], [2], [4], [7] to [14], [21] to [63] representing alkyl.
[74]
R ^8a Is a hydrogen atom, C ₁ ~ C ₆ Alkyl, halo (C ₁ ~ C ₆ ) Alkyl or -C (O) OR ^16a The ketone or oxime compound according to the above [1] to [73], or a salt thereof.
[75]
R ^8a Is a hydrogen atom or C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [73], which represents alkyl.
[76]
R ^8a Is a ketone or oxime compound or a salt thereof according to the above [1] to [73], which represents a hydrogen atom.
[77]
R ^8a Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [73], which represents alkyl.
[78]
R ^9a Is a ketone or oxime compound or a salt thereof according to the above [1] to [77], which represents a hydrogen atom.
[79]
R ^9a Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [79], which represents alkyl.
[80]
R ¹⁵ Is a ketone or oxime compound or a salt thereof according to the above [1] to [79], which represents a halogen atom.
[81]
R ¹⁵ Is C ₃ ~ C ₈ The ketone or oxime compound or a salt thereof according to the above [1] to [79], which represents cycloalkyl.
[82]
R ¹⁵ Is -OR ¹⁶ The ketone or oxime compound according to the above [1] to [79], or a salt thereof.
[83]
R ^15b Is a halogen atom, cyano, halo (C ₃ ~ C ₈ ) Cycloalkyl, -OR ^16b , -S (O) _r1 R ^16b Or -C (O) N (R ^18b ) R ^19b The oxime compound or salt thereof according to [1], [2], [4], [7] to [14], and [21] to [82].
[84]
R ^15b Is a halogen atom, cyano, -OR ^16b Or -S (O) _r1 R ^16b The oxime compound or salt thereof according to [1], [2], [4], [7] to [14], and [21] to [82].
[85]
R ^15b Represents an oxime compound or a salt thereof according to the above [1], [2], [4], [7] to [14], [21] to [82], which represents a halogen atom.
[86]
R ^15b Is an oxime compound or a salt thereof according to the above [1], [2], [4], [7] to [14], [21] to [82] representing cyano.
[87]
R ^15b Is -OR ^16b The oxime compound or salt thereof according to [1], [2], [4], [7] to [14], and [21] to [82].
[88]
R ^15b Is -S (O) _r1 R ^16b The oxime compound or salt thereof according to [1], [2], [4], [7] to [14], and [21] to [82].
[89]
R ^15b Is phenyl, (Z ¹ ) _q1 The oxime compound of the above-mentioned [1], [2], [4], [7] to [14], [21] to [82], which represents phenyl substituted with D1-32 or D1-84 or its salt.
[90]
R ^15b Is phenyl or (Z ¹ ) _q1 The oxime compound or a salt thereof according to the above [1], [2], [4], [7] to [14], [21] to [82], which represents phenyl substituted with.
[91]
R ^18b Is a hydrogen atom or C ₁ ~ C ₆ The oxime compound or a salt thereof according to the above [1], [2], [4], [7] to [14], [21] to [90] representing alkyl.
[92]
R ^18b Is R ^18b Is R ^19b Together with C ₅ By forming an alkylene chain of ^18b And R ^19b Form a 6-membered ring with the nitrogen atom to which the above bonds are bonded, and at this time, this alkylene chain contains one oxygen atom. [1], [2], [4], [7] to [14] [21] to [90], the oxime compound or a salt thereof.
[93]
X ¹ Is a halo (C ₁ ~ C ₆ ) Alkyl or C ₃ ~ C ₈ The ketone or oxime compound or a salt thereof according to the above [1] to [92], which represents cycloalkyl.
[94]
X ¹ Is a halogen atom or C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [92], which represents alkyl.
[95]
X ¹ Is a ketone or oxime compound or a salt thereof according to the above [1] to [92], which represents a halogen atom.
[96]
X ¹ Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [92], which represents alkyl.
[97]
Z ^a Is a ketone or oxime compound or a salt thereof according to the above [1] to [96], which represents a halogen atom.
[98]
Z ^a Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [96], which represents alkyl.
[99]
Z ^a Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [96], which represents alkoxy.
[100]
Z ^a Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [96], which represents alkylthio.
[101]
Z ^c Is a hydrogen atom, halogen atom, cyano, C ₁ ~ C ₆ Alkyl, C ₂ ~ C ₆ Alkynyl, R ⁴⁵ Optionally substituted with (C ₂ ~ C ₆ ) Alkynyl, phenyl, (Z ³ ) _q3 The above-mentioned [1] to [100], which represents phenyl, D1-2, D1-7, D1-11, D1-22, D1-32, D1-33, D1-34 or D1-37 substituted with Ketones or oxime compounds or salts thereof;
[102]
Z ^c Is a hydrogen atom, halogen atom, cyano, C ₁ ~ C ₆ Alkyl, C ₂ ~ C ₆ Alkynyl or R ⁴⁵ Optionally substituted with (C ₂ ~ C ₆ ) The ketone or oxime compound or a salt thereof according to the above [1] to [100], which represents alkynyl.
[103]
Z ^c Is phenyl, (Z ³ ) _q3 The above-mentioned [1] to [100], which represents phenyl, D1-2, D1-7, D1-11, D1-22, D1-32, D1-33, D1-34 or D1-37 substituted with Ketones or oxime compounds or salts thereof;
[104]
Z ^c Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [100], which represents alkyl.
[105]
Z ^c Is C ₂ ~ C ₆ Alkynyl or R ⁴⁵ Optionally substituted with (C ₂ ~ C ₆ ) The ketone or oxime compound or a salt thereof according to the above [1] to [100], which represents alkynyl.
[106]
Z ^c Is phenyl or (Z ³ ) _q3 The ketone or oxime compound or a salt thereof according to the above [1] to [100], which represents phenyl substituted with.
[107]
Z ^c Is a ketone or oxime compound or a salt thereof according to the above [1] to [100], which represents D1-2, D1-7, D1-32, D1-33, D1-34 or D1-37.
[108]
Z ^c Is a ketone or oxime compound or a salt thereof according to the above [1] to [100], which represents D1-32, D1-33 or D1-34.
[109]
Z ^c Is a ketone or oxime compound or a salt thereof according to the above [1] to [100], which represents D1-7.
[110]
Z ^e Is a ketone or oxime compound or a salt thereof according to the above [1] to [109], which represents a halogen atom.
[111]
Z ^e Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [109], which represents alkyl.
[112]
Z ^e Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [109], which represents alkoxy.
[113]
Z ^e Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [109], which represents alkylthio.
[114]
Z ² Is a halogen atom, cyano, nitro, C ₁ ~ C ₆ Alkyl, halo (C ₁ ~ C ₆ ) Alkyl, -OR ⁵¹ Or -S (O) _r2 R ⁵¹ The ketone or oxime compound according to the above [1] to [113], or a salt thereof.
[115]
Z ² Is a halogen atom, cyano, nitro, C ₁ ~ C ₆ Alkyl or halo (C ₁ ~ C ₆ ) The ketone or oxime compound or a salt thereof according to the above [1] to [113], which represents alkyl.
[116]
Z ² Is a halogen atom or C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [113], which represents alkyl.
[117]
Z ² Is -OR ⁵¹ Or -S (O) _r2 R ⁵¹ The ketone or oxime compound according to the above [1] to [113], or a salt thereof.
[118]
Z ² Is a ketone or oxime compound or a salt thereof according to the above [1] to [113], which represents a halogen atom.
[119]
Z ² Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [113], which represents alkyl.
[120]
Z ² Is -OR ⁵¹ The ketone or oxime compound according to the above [1] to [113], or a salt thereof.
[121]
Z ² Is -S (O) _r2 R ⁵¹ The ketone or oxime compound according to the above [1] to [113], or a salt thereof.
[122]
Z ³ Is a halogen atom or halo (C ₁ ~ C ₆ ) The ketone or oxime compound or the salt thereof according to the above [1] to [121], which represents alkoxy.
[123]
Z ³ Is a ketone or oxime compound or a salt thereof according to the above [1] to [121], which represents a halogen atom.
[124]
Z ³ Is a halo (C ₁ ~ C ₆ ) The ketone or oxime compound or the salt thereof according to the above [1] to [121], which represents alkoxy.
[125]
R ³² Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [124], which represents alkyl.
[126]
R ³² Is R ³⁵ Optionally substituted with (C ₁ ~ C ₆ ) The ketone or oxime compound or a salt thereof according to the above [1] to [124], which represents alkyl.
[127]
R ³⁵ Is a ketone or oxime compound or a salt thereof according to the above [1] to [126], which represents a halogen atom.
[128]
R ³⁵ Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [126], which represents alkylthio.
[129]
R ³⁵ Is a ketone or oxime compound or a salt thereof according to the above [1] to [126], which represents phenyl.
[130]
R ³⁷ Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [129], which represents alkyl.
[131]
R ³⁷ Is a ketone or oxime compound or a salt thereof according to the above [1] to [129], which represents phenyl.
[132]
R ⁴¹ Is a hydrogen atom, C ₁ ~ C ₆ Alkyl or R ⁴⁵ Optionally substituted with (C ₁ ~ C ₆ ) The ketone or oxime compound or a salt thereof according to the above [1] to [131], which represents alkyl.
[133]
R ⁴¹ Represents phenyl or D1-32, the ketone or oxime compound according to the above [1] to [131] or a salt thereof.
[134]
R ⁴¹ Is a ketone or oxime compound or a salt thereof according to the above [1] to [131], which represents a hydrogen atom.
[135]
R ⁴¹ Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [131], which represents alkyl.
[136]
R ⁴¹ Is R ⁴⁵ Optionally substituted with (C ₁ ~ C ₆ ) The ketone or oxime compound or a salt thereof according to the above [1] to [131], which represents alkyl.
[137]
R ⁴⁵ Is a halogen atom, C ₃ ~ C ₈ Cycloalkyl, -OH or C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [136], which represents alkoxy.
[138]
R ⁴⁵ Is a ketone or oxime compound or a salt thereof according to the above [1] to [136], which represents phenyl or D1-34.
[139]
R ⁴⁵ Is a ketone or oxime compound or a salt thereof according to the above [1] to [136], which represents a halogen atom.
[140]
R ⁴⁵ Is C ₃ ~ C ₈ The ketone or oxime compound or a salt thereof according to the above [1] to [136], which represents cycloalkyl.
[141]
R ⁴⁵ Is a ketone or oxime compound or a salt thereof according to the above [1] to [136], which represents —OH.
[142]
R ⁴⁵ Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [136], which represents alkoxy.
[143]
R ⁵¹ Is C ₁ ~ C ₆ The ketone or oxime compound or a salt thereof according to the above [1] to [142], which represents alkyl.
[144]
m is the ketone or oxime compound or a salt thereof according to the above [1] to [143], wherein m represents an integer of 0 or 1.
[145]
m is the ketone or oxime compound or a salt thereof according to the above [1] to [143], in which m represents an integer of 0;
[146]
m represents the integer of 1, the ketone or oxime compound according to the above [1] to [143], or a salt thereof.
[147]
n is the ketone or oxime compound or a salt thereof according to the above [1] to [146], wherein n represents an integer of 0 or 1.
[148]
n is the ketone or oxime compound or a salt thereof according to the above [1] to [146], wherein n represents an integer of 0.
[149]
n represents the integer of 1, the ketone or oxime compound according to the above [1] to [146], or a salt thereof.
[150]
An agrochemical containing one or more selected from the ketones and oxime compounds described in the above [1] to [149] and salts thereof as active ingredients.
[151]
A herbicide containing, as an active ingredient, one or more selected from the ketones and oxime compounds according to the above [1] to [149] and salts thereof.

本発明化合物は、各種雑草に対して優れた除草活性並びに対象となる作物に対する高い安全性を有し、且つ、ホ乳動物、魚類及び益虫等の非標的生物に対してほとんど悪影響の無い、低残留性で環境に対する負荷も軽い。   The compound of the present invention has excellent herbicidal activity against various weeds and high safety against target crops, and has little adverse effect on non-target organisms such as mammals, fish and beneficial insects. Persistence and light environmental impact.

従って、本発明は水田、畑地及び果樹園等の農園芸分野において有用な除草剤を提供することができる。   Therefore, the present invention can provide a herbicide useful in the field of agriculture and horticulture such as paddy fields, upland fields, and orchards.

式（１）で表される本発明化合物に関しては、置換基の種類や条件に応じて、場合によっては例えば次式で表されるケト−エノール構造互変異性体としての存在が考えられるが、本発明はそれら全ての構造をも包含するものである。   Regarding the compound of the present invention represented by the formula (1), depending on the type and conditions of the substituents, it may be present as a keto-enol structure tautomer represented by the following formula in some cases, The present invention includes all such structures.

本発明に包含される化合物には、置換基の種類によってはＥの立体配置を有するＥ−体及びＺの立体配置を有するＺ−体の幾何異性体が存在する場合がある。本発明はこれらＥ−体、Ｚ−体又はＥ−体及びＺ−体を任意の割合で含む混合物を包含するものであり、本明細書においては、これらを例えば下記のように波線の結合として表す。   The compound included in the present invention may have an E-isomer having the E configuration and a Z-isomer geometric isomer having the Z configuration depending on the type of the substituent. The present invention encompasses these E-form, Z-form, or a mixture containing the E-form and Z-form in an arbitrary ratio. In the present specification, these are represented by, for example, the combination of wavy lines as described below. Represent.

また、本発明に包含される化合物は、１個又は２個以上の不斉炭素原子の存在に起因する光学活性体が存在するが、本発明は全ての光学活性体又はラセミ体を包含する。   In addition, the compounds included in the present invention include optically active substances resulting from the presence of one or more asymmetric carbon atoms, but the present invention includes all optically active substances or racemates.

本発明に包含される化合物のうちで、常法に従って酸付加塩にすることができるものは、例えば、フッ化水素酸、塩酸、臭化水素酸、ヨウ化水素酸等のハロゲン化水素酸の塩、硝酸、硫酸、リン酸、塩素酸、過塩素酸等の無機酸の塩、メタンスルホン酸、エタンスルホン酸、トリフルオロメタンスルホン酸、ベンゼンスルホン酸、p-トルエンスルホン酸等のスルホン酸の塩、ギ酸、酢酸、プロピオン酸、トリフルオロ酢酸、フマール酸、酒石酸、蓚酸、マレイン酸、リンゴ酸、コハク酸、安息香酸、マンデル酸、アスコルビン酸、乳酸、グルコン酸、クエン酸等のカルボン酸の塩又はグルタミン酸、アスパラギン酸等のアミノ酸の塩とすることができる。   Among the compounds included in the present invention, those that can be converted into acid addition salts according to a conventional method include, for example, hydrohalic acids such as hydrofluoric acid, hydrochloric acid, hydrobromic acid, hydroiodic acid, and the like. Salts, inorganic acid salts such as nitric acid, sulfuric acid, phosphoric acid, chloric acid, perchloric acid, sulfonic acid salts such as methanesulfonic acid, ethanesulfonic acid, trifluoromethanesulfonic acid, benzenesulfonic acid, p-toluenesulfonic acid , Salt of carboxylic acid such as formic acid, acetic acid, propionic acid, trifluoroacetic acid, fumaric acid, tartaric acid, succinic acid, maleic acid, malic acid, succinic acid, benzoic acid, mandelic acid, ascorbic acid, lactic acid, gluconic acid Or it can be set as the salt of amino acids, such as glutamic acid and aspartic acid.

或いは、本発明に包含される化合物のうちで、常法に従って金属塩にすることができるものは、例えば、リチウム、ナトリウム、カリウムといったアルカリ金属の塩、カルシウム、バリウム、マグネシウムといったアルカリ土類金属の塩又はアルミニウムの塩とすることができる。   Alternatively, among the compounds included in the present invention, those that can be converted into a metal salt according to a conventional method include, for example, alkali metal salts such as lithium, sodium, and potassium, and alkaline earth metals such as calcium, barium, and magnesium. It can be a salt or a salt of aluminum.

次に、本明細書において示した各置換基の具体例を以下に示す。ここで、ｎ−はノルマル、ｉ−はイソ、ｓ−はセカンダリー及びｔｅｒｔ−はターシャリーを各々意味し、Ｐｈはフェニルを意味する。   Next, specific examples of each substituent shown in the present specification are shown below. Here, n- represents normal, i- represents iso, s- represents secondary, and tert- represents tertiary, and Ph represents phenyl.

本明細書におけるハロゲン原子としては、フッ素原子、塩素原子、臭素原子及びヨウ素原子が挙げられる。尚、本明細書中「ハロ」の表記もこれらのハロゲン原子を表す。   Examples of the halogen atom in the present specification include a fluorine atom, a chlorine atom, a bromine atom and an iodine atom. In the present specification, the notation “halo” also represents these halogen atoms.

本明細書におけるＣ_ａ〜Ｃ_ｂアルキルの表記は、炭素原子数がａ〜ｂ個よりなる直鎖状又は分岐鎖状の炭化水素基を表し、例えばメチル基、エチル基、ｎ−プロピル基、ｉ−プロピル基、ｎ−ブチル基、ｉ−ブチル基、ｓ−ブチル基、ｔｅｒｔ−ブチル基、ｎ−ペンチル基、１，１−ジメチルプロピル基、ｎ−ヘキシル基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 The notation of C _a -C _b alkyl in the present specification represents a linear or branched hydrocarbon group having a carbon number of _a to _b , for example, methyl group, ethyl group, n-propyl group, Specific examples include i-propyl group, n-butyl group, i-butyl group, s-butyl group, tert-butyl group, n-pentyl group, 1,1-dimethylpropyl group, n-hexyl group, and the like. Each selected range of carbon atoms is selected.

本明細書におけるＣ_ａ〜Ｃ_ｂアルケニルの表記は、炭素原子数がａ〜ｂ個よりなる直鎖状又は分岐鎖状で、且つ分子内に１個又は２個以上の二重結合を有する不飽和炭化水素基を表し、例えばビニル基、１−プロペニル基、２−プロペニル基、１−メチルエテニル基、２−ブテニル基、２−メチル−２−プロペニル基、３−メチル−２−ブテニル基、１，１−ジメチル−２−プロペニル基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 In the present specification, C _a -C _b alkenyl is a linear or branched chain composed of _a to _b carbon atoms and has one or more double bonds in the molecule. Represents a saturated hydrocarbon group, for example, vinyl group, 1-propenyl group, 2-propenyl group, 1-methylethenyl group, 2-butenyl group, 2-methyl-2-propenyl group, 3-methyl-2-butenyl group, 1 , 1-dimethyl-2-propenyl group and the like are listed as specific examples, and each is selected within the range of the designated number of carbon atoms.

本明細書におけるＣ_ａ〜Ｃ_ｂアルキニルの表記は、炭素原子数がａ〜ｂ個よりなる直鎖状又は分岐鎖状で、且つ分子内に１個又は２個以上の三重結合を有する不飽和炭化水素基を表し、例えばエチニル基、１−プロピニル基、２−プロピニル基、１−ブチニル基、２−ブチニル基、３−ブチニル基、１，１−ジメチル−２−プロピニル基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 In the present specification, C _a -C _b alkynyl is a linear or branched chain composed of _a to _b carbon atoms and has one or more triple bonds in the molecule. Represents a hydrocarbon group, for example, ethynyl group, 1-propynyl group, 2-propynyl group, 1-butynyl group, 2-butynyl group, 3-butynyl group, 1,1-dimethyl-2-propynyl group, etc. Each of which is selected for each specified number of carbon atoms.

本明細書におけるハロ（Ｃ_ａ〜Ｃ_ｂ）アルキルの表記は、炭素原子に結合した水素原子が、ハロゲン原子によって任意に置換された、炭素原子数がａ〜ｂ個よりなる直鎖状又は分岐鎖状の炭化水素基を表し、このとき、２個以上のハロゲン原子によって置換されている場合、それらのハロゲン原子は互いに同一でも、又は互いに相異なっていてもよい。例えばフルオロメチル基、クロロメチル基、ブロモメチル基、ヨードメチル基、ジフルオロメチル基、ジクロロメチル基、トリフルオロメチル基、クロロジフルオロメチル基、トリクロロメチル基、ブロモジフルオロメチル基、２−フルオロエチル基、２−クロロエチル基、２−ブロモエチル基、２，２−ジフルオロエチル基、２，２，２−トリフルオロエチル基、２−クロロ−２，２−ジフルオロエチル基、２，２，２−トリクロロエチル基、１，１，２，２−テトラフルオロエチル基、２−クロロ−１，１，２−トリフルオロエチル基、ペンタフルオロエチル基、３，３，３−トリフルオロプロピル基、２，２，３，３，３−ペンタフルオロプロピル基、１，１，２，３，３，３−ヘキサフルオロプロピル基、ヘプタフルオロプロピル基、２，２，２−トリフルオロ−１−（トリフルオロメチル）エチル基、１，２，２，２−テトラフルオロ−１−（トリフルオロメチル）エチル基、２，２，３，３，４，４，４−ヘプタフルオロブチル基、ノナフルオロブチル基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 In the present specification, the notation of halo (C _a -C _b ) alkyl is a straight or branched chain consisting of _a to _b carbon atoms in which a hydrogen atom bonded to a carbon atom is optionally substituted with a halogen atom A chain-like hydrocarbon group is represented, and when substituted by two or more halogen atoms, these halogen atoms may be the same as or different from each other. For example, fluoromethyl group, chloromethyl group, bromomethyl group, iodomethyl group, difluoromethyl group, dichloromethyl group, trifluoromethyl group, chlorodifluoromethyl group, trichloromethyl group, bromodifluoromethyl group, 2-fluoroethyl group, 2- Chloroethyl group, 2-bromoethyl group, 2,2-difluoroethyl group, 2,2,2-trifluoroethyl group, 2-chloro-2,2-difluoroethyl group, 2,2,2-trichloroethyl group, 1 , 1,2,2-tetrafluoroethyl group, 2-chloro-1,1,2-trifluoroethyl group, pentafluoroethyl group, 3,3,3-trifluoropropyl group, 2,2,3,3 , 3-pentafluoropropyl group, 1,1,2,3,3,3-hexafluoropropyl group, heptafluoropropyl group 2,2,2-trifluoro-1- (trifluoromethyl) ethyl group, 1,2,2,2-tetrafluoro-1- (trifluoromethyl) ethyl group, 2,2,3,3,4, Specific examples include 4,4-heptafluorobutyl group, nonafluorobutyl group and the like, and each is selected within the range of the number of carbon atoms designated.

本明細書におけるＣ_ａ〜Ｃ_ｂシクロアルキルの表記は、炭素原子数がａ〜ｂ個よりなる環状の炭化水素基を表し、３員環から６員環までの単環又は複合環構造を形成することが出来る。また、各々の環は指定の炭素原子数の範囲でアルキル基によって任意に置換されていてもよい。例えばシクロプロピル基、１−メチルシクロプロピル基、２−メチルシクロプロピル基、２，２−ジメチルシクロプロピル基、シクロブチル基、シクロペンチル基、シクロヘキシル基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 In the present specification, C _a -C _b cycloalkyl represents a cyclic hydrocarbon group having a carbon number of _a to _b , and forms a monocyclic or complex ring structure having 3 to 6 members. I can do it. Each ring may be optionally substituted with an alkyl group within the range of the specified number of carbon atoms. Specific examples include, for example, cyclopropyl group, 1-methylcyclopropyl group, 2-methylcyclopropyl group, 2,2-dimethylcyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group and the like. Selected in a range of numbers.

本明細書におけるハロ（Ｃ_ａ〜Ｃ_ｂ）シクロアルキルの表記は、炭素原子に結合した水素原子が、ハロゲン原子によって任意に置換された、炭素原子数がａ〜ｂ個よりなる環状の炭化水素基を表し、３員環から６員環までの単環又は複合環構造を形成することが出来る。また、各々の環は指定の炭素原子数の範囲でアルキル基によって任意に置換されていてもよく、ハロゲン原子による置換は環構造部分であっても、側鎖部分であっても、或いはそれらの両方であってもよく、さらに、２個以上のハロゲン原子によって置換されている場合、それらのハロゲン原子は互いに同一でも、又は互いに相異なっていてもよい。例えば２，２−ジフルオロシクロプロピル基、２，２−ジクロロシクロプロピル基、２，２−ジブロモシクロプロピル基、２，２−ジフルオロ−１−メチルシクロプロピル基、２，２−ジクロロ−１−メチルシクロプロピル基、２，２−ジブロモ−１−メチルシクロプロピル基、２，２，３，３−テトラフルオロシクロブチル基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 In this specification, halo (C _a -C _b ) cycloalkyl is a cyclic hydrocarbon having _a to _b carbon atoms in which a hydrogen atom bonded to a carbon atom is optionally substituted with a halogen atom Represents a group, and can form a monocyclic or complex ring structure from 3 to 6-membered ring. Each ring may be optionally substituted with an alkyl group within the range of the specified number of carbon atoms, and the substitution with a halogen atom may be a ring structure part, a side chain part, They may be both, and when they are substituted by two or more halogen atoms, the halogen atoms may be the same as or different from each other. For example, 2,2-difluorocyclopropyl group, 2,2-dichlorocyclopropyl group, 2,2-dibromocyclopropyl group, 2,2-difluoro-1-methylcyclopropyl group, 2,2-dichloro-1-methyl Specific examples include cyclopropyl group, 2,2-dibromo-1-methylcyclopropyl group, 2,2,3,3-tetrafluorocyclobutyl group, and the like, and each is selected within the range of the designated number of carbon atoms. The

本明細書におけるＣ_ａ〜Ｃ_ｂシクロアルケニルの表記は、炭素原子数がａ〜ｂ個よりなる環状の、且つ１個又は２個以上の二重結合を有する不飽和炭化水素基を表し、３員環から６員環までの単環又は複合環構造を形成することが出来る。また、各々の環は指定の炭素原子数の範囲でアルキル基によって任意に置換されていてもよく、さらに、二重結合はｅｎｄｏ−又はｅｘｏ−のどちらの形式であってもよい。例えば１−シクロペンテン−１−イル基、２−シクロペンテン−１−イル基、１−シクロヘキセン−１−イル基、２−シクロヘキセン−１−イル基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 The notation of C _a -C _b cycloalkenyl in the present specification represents a cyclic unsaturated hydrocarbon group having 1 to 2 carbon atoms and having 1 or 2 or more double bonds. A monocyclic or complex ring structure from a member ring to a 6-member ring can be formed. Each ring may be optionally substituted with an alkyl group within the range of the specified number of carbon atoms, and the double bond may be either endo- or exo-. Specific examples include 1-cyclopenten-1-yl group, 2-cyclopenten-1-yl group, 1-cyclohexen-1-yl group, 2-cyclohexen-1-yl group, and the like. Selected in a range of numbers.

本明細書におけるＣ_ａ〜Ｃ_ｂアルコキシの表記は、炭素原子数がａ〜ｂ個よりなる前記の意味であるアルキル−Ｏ−基を表し、例えばメトキシ基、エトキシ基、ｎ−プロピルオキシ基、ｉ−プロピルオキシ基、ｎ−ブチルオキシ基、ｉ−ブチルオキシ基、ｓ−ブチルオキシ基、ｔｅｒｔ−ブチルオキシ基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 The notation of C _a -C _b alkoxy in the present specification represents an alkyl-O— group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, methoxy group, ethoxy group, n-propyloxy group, Specific examples include an i-propyloxy group, an n-butyloxy group, an i-butyloxy group, an s-butyloxy group, a tert-butyloxy group, and the like, and each is selected within the range of the designated number of carbon atoms.

本明細書におけるハロ（Ｃ_ａ〜Ｃ_ｂ）アルコキシの表記は、炭素原子数がａ〜ｂ個よりなる前記の意味であるハロアルキル−Ｏ−基を表し、例えばジフルオロメトキシ基、トリフルオロメトキシ基、クロロジフルオロメトキシ基、ブロモジフルオロメトキシ基、２−フルオロエトキシ基、２−クロロエトキシ基、２，２，２−トリフルオロエトキシ基、１，１，２，２，−テトラフルオロエトキシ基、２−クロロ−１，１，２−トリフルオロエトキシ基、１，１，２，３，３，３−ヘキサフルオロプロピルオキシ基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 In the present specification, the notation of halo (C _a -C _b ) alkoxy represents a haloalkyl-O-group having the above-mentioned meaning consisting of _a to _b carbon atoms, such as a difluoromethoxy group, a trifluoromethoxy group, Chlorodifluoromethoxy group, bromodifluoromethoxy group, 2-fluoroethoxy group, 2-chloroethoxy group, 2,2,2-trifluoroethoxy group, 1,1,2,2, -tetrafluoroethoxy group, 2-chloro Specific examples include -1,1,2-trifluoroethoxy group, 1,1,2,3,3,3-hexafluoropropyloxy group, and the like, and each is selected within the range of the designated number of carbon atoms. .

本明細書におけるＣ_ａ〜Ｃ_ｂアルキルチオの表記は、炭素原子数がａ〜ｂ個よりなる前記の意味であるアルキル−Ｓ−基を表し、例えばメチルチオ基、エチルチオ基、ｎ−プロピルチオ基、ｉ−プロピルチオ基、ｎ−ブチルチオ基、ｉ−ブチルチオ基、ｓ−ブチルチオ基、ｔｅｒｔ−ブチルチオ基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 The notation of C _a -C _b alkylthio in the present specification represents an alkyl-S-group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, methylthio group, ethylthio group, n-propylthio group, i Specific examples include -propylthio group, n-butylthio group, i-butylthio group, s-butylthio group, tert-butylthio group and the like, which are selected within the range of the number of carbon atoms specified.

本明細書におけるＣ_ａ〜Ｃ_ｂアルキルスルフィニルの表記は、炭素原子数がａ〜ｂ個よりなる前記の意味であるアルキル−Ｓ（Ｏ）−基を表し、例えばメチルスルフィニル基、エチルスルフィニル基、ｎ−プロピルスルフィニル基、ｉ−プロピルスルフィニル基、ｎ−ブチルスルフィニル基、ｉ−ブチルスルフィニル基、ｓ−ブチルスルフィニル基、ｔｅｒｔ−ブチルスルフィニル基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 The notation of C _a -C _b alkylsulfinyl in the present specification represents an alkyl-S (O) -group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, methylsulfinyl group, ethylsulfinyl group, Specific examples include n-propylsulfinyl group, i-propylsulfinyl group, n-butylsulfinyl group, i-butylsulfinyl group, s-butylsulfinyl group, tert-butylsulfinyl group and the like. The range is selected.

本明細書におけるＣ_ａ〜Ｃ_ｂアルキルスルホニルの表記は、炭素原子数がａ〜ｂ個よりなる前記の意味であるアルキル−ＳＯ_２−基を表し、例えばメチルスルホニル基、エチルスルホニル基、ｎ−プロピルスルホニル基、ｉ−プロピルスルホニル基、ｎ−ブチルスルホニル基、ｉ−ブチルスルホニル基、ｓ−ブチルスルホニル基、ｔｅｒｔ−ブチルスルホニル基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 The notation of C _a -C _b alkylsulfonyl in the present specification represents an alkyl-SO ₂ -group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, methylsulfonyl group, ethylsulfonyl group, n- Specific examples include a propylsulfonyl group, an i-propylsulfonyl group, an n-butylsulfonyl group, an i-butylsulfonyl group, an s-butylsulfonyl group, a tert-butylsulfonyl group, and the range of each designated number of carbon atoms. Selected.

本明細書におけるＣ_ａ〜Ｃ_ｂアルコキシカルボニルの表記は、炭素原子数がａ〜ｂ個よりなる前記の意味であるアルキル−Ｏ−Ｃ（Ｏ）−基を表し、例えばメトキシカルボニル基、エトキシカルボニル基、ｎ−プロピルオキシカルボニル基、ｉ−プロピルオキシカルボニル基、ｎ−ブトキシカルボニル基、ｉ−ブトキシカルボニル基、ｔｅｒｔ−ブトキシカルボニル基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 The notation of C _a -C _b alkoxycarbonyl in the present specification represents an alkyl-O—C (O) — group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, methoxycarbonyl group, ethoxycarbonyl Group, n-propyloxycarbonyl group, i-propyloxycarbonyl group, n-butoxycarbonyl group, i-butoxycarbonyl group, tert-butoxycarbonyl group and the like, and specific ranges of the number of carbon atoms are designated. Selected.

本明細書におけるＣ_ａ〜Ｃ_ｂアルキルカルボニルの表記は、炭素原子数がａ〜ｂ個よりなる前記の意味であるアルキル−Ｃ（Ｏ）−基を表し、例えばアセチル基、プロピオニル基、ブチリル基、イソブチリル基、バレリル基、イソバレリル基、２−メチルブタノイル基、ピバロイル基、ヘキサノイル基、ヘプタノイル基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 The notation of C _a -C _b alkylcarbonyl in the present specification represents an alkyl-C (O) -group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, acetyl group, propionyl group, butyryl group. , Isobutyryl group, valeryl group, isovaleryl group, 2-methylbutanoyl group, pivaloyl group, hexanoyl group, heptanoyl group, and the like, and specific examples thereof are selected within the range of the number of carbon atoms designated.

本明細書におけるＣ_ａ〜Ｃ_ｂアルキルイミノの表記は、炭素原子数がａ〜ｂ個よりなる前記の意味であるアルキル−Ｎ＝基を表し、例えばメチルイミノ基、エチルイミノ基、ｎ−プロピルイミノ基、ｉ−プロピルイミノ基、ｎ−ブチルイミノ基、ｉ−ブチルイミノ基、ｓ−ブチルイミノ基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 The notation of C _a -C _b alkylimino in the present specification represents an alkyl-N = group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, methylimino group, ethylimino group, n-propylimino group. Specific examples include i-propylimino group, n-butylimino group, i-butylimino group, s-butylimino group, and the like, and each is selected within the range of the number of carbon atoms designated.

本明細書におけるＣ_ａ〜Ｃ_ｂアルコキシイミノの表記は、炭素原子数がａ〜ｂ個よりなる前記の意味であるアルコキシ−Ｎ＝基を表し、例えばメトキシイミノ基、エトキシイミノ基、ｎ−プロピルオキシイミノ基、ｉ−プロピルオキシイミノ基、ｎ−ブチルオキシイミノ基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 The notation of C _a -C _b alkoxyimino in the present specification represents an alkoxy-N = group having the above-mentioned meaning consisting of _a to _b carbon atoms, for example, methoxyimino group, ethoxyimino group, n-propyl. Specific examples include an oxyimino group, an i-propyloxyimino group, an n-butyloxyimino group, and the like, and each is selected within the range of the designated number of carbon atoms.

本明細書におけるＣ_ａ〜Ｃ_ｂアルキリデンの表記は、炭素原子数がａ〜ｂ個よりなる直鎖状又は分岐鎖状で、二重結合によって結合した炭化水素基を表し、例えばメチリデン基、エチリデン基、プロピリデン基、１−メチルエチリデン基等が具体例として挙げられ、各々の指定の炭素原子数の範囲で選択される。 In the present specification, C _a -C _b alkylidene represents a linear or branched hydrocarbon group having a carbon number of _a to _b and bonded by a double bond, such as a methylidene group or an ethylidene group. Specific examples include a group, a propylidene group, a 1-methylethylidene group, and the like, and each group is selected within the range of the designated number of carbon atoms.

本明細書における「Ｒ^５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルキル」、「Ｒ^１５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルキル」、「Ｒ^１５ｂによって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルキル」、「Ｒ^２０によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルキル」、「Ｒ^３５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルキル」又は「Ｒ^４５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルキル」等の表記は、任意のＲ^５、Ｒ^１５、Ｒ^１５ｂ、Ｒ^２０、Ｒ^３５又はＲ^４５によって、炭素原子に結合した水素原子が任意に置換された炭素原子数がａ〜ｂ個よりなる前記の意味であるアルキル基を表し、各々の指定の炭素原子数の範囲で選択される。このとき、それぞれの（Ｃ_ａ〜Ｃ_ｂ）アルキル基上の置換基Ｒ^５、Ｒ^１５、Ｒ^１５ｂ、Ｒ^２０、Ｒ^３５又はＲ^４５が２個以上存在するとき、それぞれのＲ^５、Ｒ^１５、Ｒ^１５ｂ、Ｒ^２０、Ｒ^３５又はＲ^４５は互いに同一でも異なってもよい。 "Optionally substituted by ^{R 5} _(C a ^~C _b) alkyl" as used herein, "optionally substituted by ^{R 15} _(C a ^~C _b) alkyl" optionally substituted with ^{"R 15b} and _(C a _{~C b)} alkyl "," optionally substituted by ^{R 20} _(C a _{~C b)} alkyl "," optionally substituted by ^{R 35} _(C a _{~C b)} alkyl "or" optionally substituted by R ⁴⁵ _(C a ~C _b) alkyl "notation or the like, any of ^{R 5, R 15, R 15b} , by R ^{20, R 35} or ^{R 45,} hydrogen atoms bonded to carbon atoms Represents an optionally substituted alkyl group having the above-mentioned meanings consisting of a to b carbon atoms, and is selected in the range of each designated number of carbon atoms. At this time, when there are two or more substituents R ⁵ , R ¹⁵ , R ^15b , R ²⁰ , R ^35, or R ⁴⁵ on each (C _a -C _b ) alkyl group, each R ⁵ , R ¹⁵ , R ^15b , R ²⁰ , R ³⁵ or R ⁴⁵ may be the same as or different from each other.

本明細書における「Ｒ^５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）シクロアルキル」、「Ｒ^１５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）シクロアルキル」、「Ｒ^１５ｂによって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）シクロアルキル」又は「Ｒ^４５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）シクロアルキル」等の表記は、任意のＲ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）シクロアルキルによって、炭素原子に結合した水素原子が任意に置換された炭素原子数がａ〜ｂ個よりなる前記の意味であるシクロアルキル基を表し、各々の指定の炭素原子数の範囲で選択される。このとき、それぞれの（Ｃ_ａ〜Ｃ_ｂ）シクロアルキル基上の置換基Ｒ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５が２個以上存在するとき、それぞれのＲ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５は互いに同一でも異なってもよく、さらに置換位置は環構造部分であっても、側鎖部分であっても、或いはそれらの両方にあってもよい。 "Optionally substituted by ^{R 5} _(C a ^~C _b) cycloalkyl" as used herein, "optionally substituted by ^{R 15} _(C a ^~C _b) cycloalkyl", optionally by ^{"R 15b} substituted _(C a _{~C b)} optionally substituted by cycloalkyl "or" ^{R 45} _(C a _{~C b)} representation of cycloalkyl "and the like, any of ^{R 5,} R ^{15, R 15b} or R ^A cycloalkyl group having the above meaning consisting of _a to _b carbon atoms in which a hydrogen atom bonded to a carbon atom is optionally substituted by (C _a -C _b ) cycloalkyl optionally substituted by ⁴⁵ ; Selected and selected for each specified number of carbon atoms. At this time, when there are two or more substituents R ⁵ , R ¹⁵ , R ^15b or R ⁴⁵ on each (C _a -C _b ) cycloalkyl group, each R ⁵ , R ¹⁵ , R ^15b or R ⁴⁵ may be the same as or different from each other, and the substitution position may be a ring structure portion, a side chain portion, or both.

本明細書における「Ｒ^５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルケニル」、「Ｒ^１５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルケニル」、「Ｒ^１５ｂによって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルケニル」又は「Ｒ^４５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルケニル」等の表記は、任意のＲ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５によって、炭素原子に結合した水素原子が任意に置換された炭素原子数がａ〜ｂ個よりなる前記の意味であるアルケニル基を表し、各々の指定の炭素原子数の範囲で選択される。このとき、それぞれの（Ｃ_ａ〜Ｃ_ｂ）アルケニル基上の置換基Ｒ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５が２個以上存在するとき、それぞれのＲ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５は互いに同一でも異なってもよい。 "Optionally substituted by ^{R 5} _(C a ^~C _b) alkenyl" in the present specification, "optionally substituted by ^{R 15} _(C a ^~C _b) alkenyl", it is optionally substituted by ^{"R 15b} by the _(C a _{~C b)} alkenyl "or" optionally substituted by ^{R 45} _(C a _{~C b)} alkenyl "notation or the like, any of ^{R 5, R 15, R 15b,} or ^{R 45,} the carbon It represents an alkenyl group having the above-mentioned meaning, wherein the number of carbon atoms optionally substituted with hydrogen atoms bonded to the atoms is a to b, and is selected within the range of the respective designated number of carbon atoms. At this time, when two or more substituents R ⁵ , R ¹⁵ , R ^15b or R ⁴⁵ on each (C _a -C _b ) alkenyl group are present, each R ⁵ , R ¹⁵ , R ^15b or R ^{45 is present.} May be the same as or different from each other.

本明細書における「Ｒ^５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）シクロアルケニル」、「Ｒ^１５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）シクロアルケニル」、「Ｒ^１５ｂによって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）シクロアルケニル」又は「Ｒ^４５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）シクロアルケニル」等の表記は、任意のＲ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５によって、炭素原子に結合した水素原子が任意に置換された炭素原子数がａ〜ｂ個よりなる前記の意味であるシクロアルケニル基を表し、各々の指定の炭素原子数の範囲で選択される。このとき、それぞれの（Ｃ_ａ〜Ｃ_ｂ）シクロアルケニル基上の置換基Ｒ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５が２個以上存在するとき、それぞれのＲ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５は互いに同一でも異なってもよく、さらに置換位置は環構造部分であっても、側鎖部分であっても、或いはそれらの両方にあってもよい。 "Optionally substituted by ^{R 5} _(C a ^~C _b) cycloalkenyl" herein, "optionally substituted by ^{R 15} _(C a ^~C _b) cycloalkenyl", optionally by ^{"R 15b} substituted _(C a _{~C b)} representation of such cycloalkenyl "or" optionally substituted by ^{R 45} _(C a _{~C b)} cycloalkenyl ", any ^{R 5,} R ^{15, R 15b} or R ⁴⁵ represents a cycloalkenyl group as defined above, wherein the number of carbon atoms optionally substituted with hydrogen atoms bonded to carbon atoms is ab, and is selected within each specified number of carbon atoms . At this time, when two or more substituents R ⁵ , R ¹⁵ , R ^15b or R ⁴⁵ on each (C _a -C _b ) cycloalkenyl group are present, each R ⁵ , R ¹⁵ , R ^15b or R ⁴⁵ may be the same as or different from each other, and the substitution position may be a ring structure portion, a side chain portion, or both.

本明細書におけるＲ^５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルキニル、Ｒ^１５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルキニル、Ｒ^１５ｂによって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルキニル又はＲ^４５によって任意に置換された（Ｃ_ａ〜Ｃ_ｂ）アルキニル等の表記は、任意のＲ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５によって、炭素原子に結合した水素原子が任意に置換された炭素原子数がａ〜ｂ個よりなる前記の意味であるアルキニル基を表し、各々の指定の炭素原子数の範囲で選択される。このとき、それぞれの（Ｃ_ａ〜Ｃ_ｂ）アルキニル基上の置換基Ｒ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５が２個以上存在するとき、それぞれのＲ^５、Ｒ^１５、Ｒ^１５ｂ又はＲ^４５は互いに同一でも異なってもよい。 Optionally substituted by ^{R 5} in this specification _(C a _{~C b)} ^alkynyl, optionally substituted by ^{R 15} _(C a _{~C b)} ^alkynyl, optionally substituted by ^{R 15b} _(C a ~ C _b ) alkynyl or (C _a -C _b ) alkynyl optionally substituted by R ^{45 is represented} by any R ⁵ , R ¹⁵ , R ^15b or R ⁴⁵ , and a hydrogen atom bonded to a carbon atom is optional Represents an alkynyl group having the above meaning consisting of a to b carbon atoms, and is selected in the range of each designated number of carbon atoms. At this time, when two or more substituents R ⁵ , R ¹⁵ , R ^15b or R ⁴⁵ on each (C _a -C _b ) alkynyl group are present, each R ⁵ , R ¹⁵ , R ^15b or R ^{45 is present.} May be the same as or different from each other.

「Ｒ^３は、Ｒ^４と一緒になってＣ_２〜Ｃ_７のアルキレン鎖又はＣ_２〜Ｃ_７のアルケニレン鎖を形成することにより、Ｒ^３及びＲ^４が結合する窒素原子と共に３〜８員環を形成してもよいことを表し、このときこのアルキレン鎖又はアルケニレン鎖は酸素原子、硫黄原子又は窒素原子を１個含んでもよく、」の表記の具体例として、例えばアジリジン、アゼチジン、アゼチジン−２−オン、ピロリジン、ピロリジン−２−オン、オキサゾリジン、オキサゾリジン−２−オン、オキサゾリジン−２−チオン、チアゾリジン、チアゾリジン−２−オン、チアゾリジン−２−チオン、イミダゾリジン、イミダゾリジン−２−オン、イミダゾリジン−２−チオン、ピペリジン、ピペリジン−２−オン、ピペリジン−２−チオン、２Ｈ−３，４，５，６−テトラヒドロ−１，３−オキサジン−２−オン、２Ｈ−３，４，５，６−テトラヒドロ−１，３−オキサジン−２−チオン、モルホリン、２Ｈ−３，４，５，６−テトラヒドロ−１，３−チアジン−２−オン、２Ｈ−３，４，５，６−テトラヒドロ−１，３−チアジン−２−チオン、チオモルホリン、ペルヒドロピリミジン−２−オン、ピペラジン、ホモピペリジン、ホモピペリジン−２−オン、ヘプタメチレンイミン、１，２−ジヒドロピリジン、１，２−ジヒドロピリミジン、１，４−ジヒドロピリジン、２，３−ジヒドロ−１Ｈ−イミダゾール、２，３−ジヒドロチアゾール、２，３−ジヒドロオキサゾール、４，５−ジヒドロ−１Ｈ−ピラゾール、２，５−ジヒドロ−１Ｈ−ピロール、１，２，３，４−テトラヒドロピリジン、１，２，３，４−テトラヒドロピリミジン、１，２，３，４−テトラヒドロピリダジン等が挙げられ、各々の指定の原子数の範囲で選択される。 ^{"R 3,} by forming the alkenylene chain of the alkylene chain or _C 2 -C ₇ of _C 2 -C ₇ together with ^{R 4,} 3 to 8 membered together with the nitrogen atom ^{to which R 3} and ^{R 4} are bonded In this case, the alkylene chain or alkenylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and as a specific example of the notation, for example, aziridine, azetidine, azetidine- 2-one, pyrrolidine, pyrrolidin-2-one, oxazolidine, oxazolidine-2-one, oxazolidine-2-thione, thiazolidine, thiazolidine-2-one, thiazolidine-2-thione, imidazolidine, imidazolidin-2-one, Imidazolidine-2-thione, piperidine, piperidin-2-one, piperidine-2-thione, 2H-3,4,5 , 6-Tetrahydro-1,3-oxazin-2-one, 2H-3,4,5,6-tetrahydro-1,3-oxazin-2-thione, morpholine, 2H-3,4,5,6-tetrahydro -1,3-thiazin-2-one, 2H-3,4,5,6-tetrahydro-1,3-thiazin-2-thione, thiomorpholine, perhydropyrimidin-2-one, piperazine, homopiperidine, homo Piperidin-2-one, heptamethyleneimine, 1,2-dihydropyridine, 1,2-dihydropyrimidine, 1,4-dihydropyridine, 2,3-dihydro-1H-imidazole, 2,3-dihydrothiazole, 2,3- Dihydrooxazole, 4,5-dihydro-1H-pyrazole, 2,5-dihydro-1H-pyrrole, 1,2,3,4-tetrahydropyridine 1,2,3,4-tetrahydropyrimidine, 1,2,3,4-tetrahydronaphthalene pyridazine and the like, may be selected from the range of the number of each of the specified atoms.

「Ｒ^１８ｂは、Ｒ^１９ｂと一緒になってＣ_２〜Ｃ_７のアルキレン鎖を形成することにより、Ｒ^１８ｂ及びＲ^１９ｂが結合する窒素原子と共に３〜８員環を形成してもよいことを表し、このときこのアルキレン鎖は酸素原子、硫黄原子又は窒素原子を１個含んでもよく、」の表記の具体例として、例えばアジリジン、アゼチジン、アゼチジン−２−オン、ピロリジン、ピロリジン−２−オン、オキサゾリジン、オキサゾリジン−２−オン、オキサゾリジン−２−チオン、チアゾリジン、チアゾリジン−２−オン、チアゾリジン−２−チオン、イミダゾリジン、イミダゾリジン−２−オン、イミダゾリジン−２−チオン、ピペリジン、ピペリジン−２−オン、ピペリジン−２−チオン、２Ｈ−３，４，５，６−テトラヒドロ−１，３−オキサジン−２−オン、２Ｈ−３，４，５，６−テトラヒドロ−１，３−オキサジン−２−チオン、モルホリン、２Ｈ−３，４，５，６−テトラヒドロ−１，３−チアジン−２−オン、２Ｈ−３，４，５，６−テトラヒドロ−１，３−チアジン−２−チオン、チオモルホリン、ペルヒドロピリミジン−２−オン、ピペラジン、ホモピペリジン、ホモピペリジン−２−オン、ヘプタメチレンイミン等が挙げられ、各々の指定の原子数の範囲で選択される。 “R ^18b may form a C ₂ -C ₇ alkylene chain together with R ^19b to form a 3- to 8-membered ring with the nitrogen atom to which R ^18b and R ^19b are bonded. In this case, the alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and as a specific example of the notation, for example, aziridine, azetidine, azetidin-2-one, pyrrolidine, pyrrolidin-2-one, Oxazolidine, oxazolidine-2-one, oxazolidine-2-thione, thiazolidine, thiazolidine-2-one, thiazolidine-2-thione, imidazolidine, imidazolidin-2-one, imidazolidine-2-thione, piperidine, piperidine-2 -One, piperidine-2-thione, 2H-3,4,5,6-tetrahydro-1,3-oxa Gin-2-one, 2H-3,4,5,6-tetrahydro-1,3-oxazine-2-thione, morpholine, 2H-3,4,5,6-tetrahydro-1,3-thiazine-2- ON, 2H-3,4,5,6-tetrahydro-1,3-thiazin-2-thione, thiomorpholine, perhydropyrimidin-2-one, piperazine, homopiperidine, homopiperidin-2-one, heptamethyleneimine Etc., and each selected atom number is selected.

次に、本発明化合物の製造法を以下に説明する。尚、製造法Ａ〜製造法Ｋにおいて、式中のＡ^１は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−Ｓ（Ｏ）_ｒ２Ｒ^１、−Ｃ（Ｏ）ＯＲ^１、−Ｃ（Ｓ）ＯＲ^１、−Ｃ（Ｏ）ＳＲ^１、−Ｃ（Ｓ）ＳＲ^１、−Ｃ（Ｏ）Ｒ^２、−Ｃ（Ｓ）Ｒ^２、−Ｃ（Ｏ）Ｎ（Ｒ^４）Ｒ^３、−Ｃ（Ｓ）Ｎ（Ｒ^４）Ｒ^３、−Ｓ（Ｏ）_２Ｎ（Ｒ^４）Ｒ^３、−Ｐ（Ｏ）（ＯＲ^１）_２又は−Ｐ（Ｓ）（ＯＲ^１）_２を表し、Ｒ^１、Ｒ^５、Ｒ^２、Ｒ^３、Ｒ^４及びｒ２は前記と同じ意味を表す。 Next, the manufacturing method of this invention compound is demonstrated below. In production method A to production method K, A ¹ in the formula is a hydrogen atom, C _{1 to} C ₆ alkyl, (C _{1 to} C ₆ ) alkyl optionally substituted with R ⁵ , or C _{3 to} C _8. cycloalkyl, optionally substituted with ^{R 5} _(C 3 ~C _{8) cycloalkyl,} C 2 -C _{6 alkenyl,} C 3 -C ₈ cycloalkenyl, optionally substituted with ^{R 5} _(C 3 ~C ₈ ) cycloalkenyl, optionally substituted with ^{R 5} _(C 2 ~C _{6) alkenyl,} substituted C 2 -C ₆ alkynyl, optionally with ^{R 5} _(C 2 ~C ₆₎ alkynyl, -S (O) _{^{r2 R 1, -C (O)}} OR 1, -C (S) OR 1, -C (O) SR 1, -C (S) SR 1, -C (O) R 2, -C (S) R ^{2, -C (O) N (} R 4) R 3, -C (S) N (R 4) R 3, -S (O) 2 N (R 4) ^{3, -P (O) (OR} 1) 2 or -P _(S) ^(OR 1) represents _{^{2, R 1, R 5,}} R 2, R 3, R 4 and r2 are as defined above.

製造法Ａ   Manufacturing method A

本発明化合物のうち、式（１−１−ａ）で表される化合物を、式（７−１）［式中Ｊ^ａは、ハロゲン原子、−ＯＳＯ_２Ｍｅ、−ＯＳＯ_２ＣＦ_３等の脱離基を表し、Ａ^１は前記と同じ意味を表す。］で表される化合物と反応させて、式（１−１）［式中Ｑ、Ａ^１、Ｒ^６、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される本発明化合物及び式（１−２）［式中Ｑ、Ａ^１、Ｒ^６、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される本発明化合物を製造することができる。 Among the compounds of the present invention, the compound represented by the formula (1-1-a) is converted to the formula (7-1) [wherein J ^a is a halogen atom, —OSO ₂ Me, —OSO ₂ CF _3, etc. Represents a leaving group, and A ¹ represents the same meaning as described above. And a compound represented by formula (1-1) [wherein Q, A ¹ , R ⁶ , R ^8a , R ^8b , R ^9a , R ^9b , Z, m, n and q are as defined above] Represents the same meaning. The compound of the present invention represented by the formula (1-2) [wherein Q, A ¹ , R ⁶ , R ^8a , R ^8b , R ^9a , R ^9b , Z, m, n and q are as defined above] Represents. This invention compound represented by this can be manufactured.

式（７−１）で表される化合物の或るものは公知化合物であり、一部は市販品として入手できる。また、それ以外のものも文献記載の公知の方法に準じて製造することができる。   Some of the compounds represented by formula (7-1) are known compounds, and some of them are commercially available. Others can also be produced according to known methods described in the literature.

本反応では式（１−１−ａ）で表される化合物１当量に対して、式（７−１）で表される化合物は、０．５〜５０当量の範囲で用いることができる。必要ならば、トリエチルアミン、ピリジン、４−（ジメチルアミノ）ピリジン、１，８−ジアザビシクロ［５．４．０］−７−ウンデセン、ｎ−ブチルリチウム、リチウムジイソプロピルアミド、リチウムビス（トリメチルシリル）アミド、ナトリウムビス（トリメチルシリル）アミド、カリウムビス（トリメチルシリル）アミド、水素化ナトリウム、ナトリウムメトキシド、水酸化ナトリウム、水酸化カリウム、炭酸ナトリウム、炭酸カリウム等の塩基を使用することができる。   In this reaction, the compound represented by formula (7-1) can be used in the range of 0.5 to 50 equivalents with respect to 1 equivalent of the compound represented by formula (1-1-a). If necessary, triethylamine, pyridine, 4- (dimethylamino) pyridine, 1,8-diazabicyclo [5.4.0] -7-undecene, n-butyllithium, lithium diisopropylamide, lithium bis (trimethylsilyl) amide, sodium Bases such as bis (trimethylsilyl) amide, potassium bis (trimethylsilyl) amide, sodium hydride, sodium methoxide, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate and the like can be used.

本反応は、無溶媒で実施してもよいが、溶媒を用いてもよく、例えば、Ｎ，Ｎ−ジメチルホルムアミド、Ｎ，Ｎ−ジメチルアセトアミド、アセトニトリル、ジメチルスルホキシド、１，３−ジメチル−２−イミダゾリノン等の極性溶媒、メタノール、エタノール、プロパノール、２−プロパノール、エチレングリコール等のアルコール類、ジエチルエーテル、テトラヒドロフラン、ジフェニルエーテル等のエーテル類、ベンゼン、トルエン、キシレン等の芳香族炭化水素類、塩化メチレン、クロロホルム、四塩化炭素等のハロゲン化炭化水素類、ペンタン、ｎ−ヘキサン等の脂肪族炭化水素類が挙げられる。これらの溶媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。   This reaction may be carried out without solvent, but a solvent may be used, for example, N, N-dimethylformamide, N, N-dimethylacetamide, acetonitrile, dimethyl sulfoxide, 1,3-dimethyl-2- Polar solvents such as imidazolinone, alcohols such as methanol, ethanol, propanol, 2-propanol and ethylene glycol, ethers such as diethyl ether, tetrahydrofuran and diphenyl ether, aromatic hydrocarbons such as benzene, toluene and xylene, methylene chloride , Halogenated hydrocarbons such as chloroform and carbon tetrachloride, and aliphatic hydrocarbons such as pentane and n-hexane. These solvents may be used alone or as a mixture of two or more thereof.

反応温度は、−８０℃から反応混合物の還流温度までの任意の温度を設定することができ、反応時間は、反応基質の濃度、反応温度によって変化するが、通常５分から１００時間の範囲で任意に設定できる。   The reaction temperature can be set to any temperature from −80 ° C. to the reflux temperature of the reaction mixture, and the reaction time varies depending on the concentration of the reaction substrate and the reaction temperature, but is usually arbitrary within the range of 5 minutes to 100 hours. Can be set.

製造法Ｂ   Manufacturing method B

式（１−１−ａ）で表される化合物のうち、式（１−１−ａ１）[式中Ｒ^６、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される化合物を、式（３）[式中Ｒ^７は前記と同じ意味を表す。］で表される化合物と反応させることにより、式（１−１−ａ２）[式中Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される本発明化合物を製造することが出来る。 Of the compounds represented by formula (1-1-a), formula (1-1-a1) [wherein R ⁶ , R ^8a , R ^8b , R ^9a , R ^9b , Z, m, n and q are Represents the same meaning as above. The compound represented by formula (3) [wherein R ⁷ represents the same meaning as described above. And the compound represented by formula (1-1-a2) [wherein R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , Z, m, n, and q are Means the same. This invention compound represented by this can be manufactured.

式（３）で表される化合物の或るものは公知化合物であり、一部は市販品として入手できる。また、それ以外のものも文献記載の公知の方法に準じて製造することができる。   Some of the compounds represented by formula (3) are known compounds, and some of them are commercially available. Others can also be produced according to known methods described in the literature.

本反応では、式（１−１−ａ１）で表される化合物１当量に対して、式（３）で表される化合物は、０．１から１００当量の範囲で用いることができる。必要ならば、炭酸カリウム、トリエチルアミン、ピリジン、４−（ジメチルアミノ）ピリジン等の塩基を使用することができる。   In this reaction, the compound represented by formula (3) can be used in the range of 0.1 to 100 equivalents with respect to 1 equivalent of the compound represented by formula (1-1-a1). If necessary, a base such as potassium carbonate, triethylamine, pyridine, 4- (dimethylamino) pyridine can be used.

本反応は、無溶媒で実施してもよいが、溶媒を用いてもよく、例えば、Ｎ，Ｎ−ジメチルホルムアミド、Ｎ，Ｎ−ジメチルアセトアミド、アセトニトリル、ジメチルスルホキシド、１，３−ジメチル−２−イミダゾリノン等の極性溶媒、メタノール、エタノール、プロパノール、２−プロパノール、エチレングリコール等のアルコール類、ジエチルエーテル、テトラヒドロフラン、ジフェニルエーテル等のエーテル類、ベンゼン、トルエン、キシレン等の芳香族炭化水素類、塩化メチレン、クロロホルム、四塩化炭素等のハロゲン化炭化水素類、ペンタン、ｎ−ヘキサン等の脂肪族炭化水素類が挙げられる。これらの溶媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。   This reaction may be carried out without solvent, but a solvent may be used, for example, N, N-dimethylformamide, N, N-dimethylacetamide, acetonitrile, dimethyl sulfoxide, 1,3-dimethyl-2- Polar solvents such as imidazolinone, alcohols such as methanol, ethanol, propanol, 2-propanol and ethylene glycol, ethers such as diethyl ether, tetrahydrofuran and diphenyl ether, aromatic hydrocarbons such as benzene, toluene and xylene, methylene chloride , Halogenated hydrocarbons such as chloroform and carbon tetrachloride, and aliphatic hydrocarbons such as pentane and n-hexane. These solvents may be used alone or as a mixture of two or more thereof.

反応温度は、−８０℃から反応混合物の還流温度までの任意の温度を設定することができ、反応時間は、反応基質の濃度、反応温度によって変化するが、通常５分から１００時間の範囲で任意に設定できる。   The reaction temperature can be set to any temperature from −80 ° C. to the reflux temperature of the reaction mixture, and the reaction time varies depending on the concentration of the reaction substrate and the reaction temperature, but is usually arbitrary within the range of 5 minutes to 100 hours. Can be set.

製造法Ｃ   Manufacturing method C

式（１−１）で表される化合物のうち、式（１−１−ｂ）［式中Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表し、Ａ^３は、Ｃ_１〜Ｃ_６アルキル又はＲ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表し、Ｒ^５は前記と同じ意味を表す。］で表される化合物を、加水分解することにより、式（１−１−ａ１）で表される本発明化合物を得ることができる。 Of the compounds represented by formula (1-1), formula (1-1-b) [wherein R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , Z, m, n and q It is as defined above, ^{a 3} _is, C 1 optionally substituted with -C ₆ alkyl or ^{R 5} _(C 1 ~C ₆₎ alkyl, ^{R 5} are as defined above. The compound of the present invention represented by the formula (1-1-a1) can be obtained by hydrolyzing the compound represented by the formula:

本反応では、必要ならば水、メタノール、エタノール、ジクロロメタン、クロロホルム、ジエチルエーテル、テトラヒドロフラン、１，４−ジオキサン、アセトニトリル、アセトン等の溶媒を使用してもよい。これらの溶媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。   In this reaction, if necessary, a solvent such as water, methanol, ethanol, dichloromethane, chloroform, diethyl ether, tetrahydrofuran, 1,4-dioxane, acetonitrile, acetone or the like may be used. These solvents may be used alone or as a mixture of two or more thereof.

必要ならば式（１−１−ｂ）で表される化合物１当量に対して０．１〜２０当量の塩酸、硫酸、ｐ−トルエンスルホン酸等の酸存在下で反応させることができる。   If necessary, the reaction can be carried out in the presence of an acid such as 0.1 to 20 equivalents of hydrochloric acid, sulfuric acid, p-toluenesulfonic acid, etc. per 1 equivalent of the compound represented by the formula (1-1-b).

反応温度は、−８０℃から反応混合物の還流温度までの任意の温度を設定することができ、反応時間は、反応基質の濃度、反応温度によって変化するが、通常５分から１００時間の範囲で任意に設定できる。   The reaction temperature can be set to any temperature from −80 ° C. to the reflux temperature of the reaction mixture, and the reaction time varies depending on the concentration of the reaction substrate and the reaction temperature, but is usually arbitrary within the range of 5 minutes to 100 hours. Can be set.

製造法Ｄ   Manufacturing method D

式（４）[式中Ｚ及びｑは前記と同じ意味を表し、Ａ^３は、Ｃ_１〜Ｃ_６アルキル又はＲ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表し、Ｒ^５は前記と同じ意味を表す。］で表される化合物と式（５）［式中Ｊ^ａ、Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、ｍ及びｎは前記と同じ意味を表す。］で表される化合物を反応させることにより、式（１−１）で表される化合物のうち、式（１−１−ｂ）[式中Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表し、Ａ^３は、Ｃ_１〜Ｃ_６アルキル又はＲ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表し、Ｒ^５は前記と同じ意味を表す。］で表される本発明化合物を製造することができる。 Equation (4) [wherein Z and q are as defined above, ^{A 3} _is optionally substituted with C 1 -C ₆ alkyl or ^{R 5} _(C 1 ~C ₆₎ alkyl, ^{R 5} Represents the same meaning as described above. And a compound represented by formula (5): wherein J ^a , R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , m and n have the same meaning as described above. ] Among the compounds represented by the formula (1-1), the compound represented by the formula (1-1-b) [wherein R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , Z, m, n and q represent the same meaning as described above, A ³ represents C ₁ -C ₆ alkyl or (C ₁ -C ₆ ) alkyl optionally substituted with R ⁵ ; R ⁵ represents the same meaning as described above. This invention compound represented by this can be manufactured.

式（４）で表される化合物の或るものは公知化合物である。それ以外のものも、例えばヘミッシェ・ベリヒテ １９８３年，１１６巻，１１９頁等に記載の公知の方法に準じて製造することができる。   Some of the compounds represented by formula (4) are known compounds. Others can also be produced according to known methods described in, for example, Hemicche Berichte 1983, 116, 119.

式（５）で表される化合物の或るものは公知化号物である。それ以外のものも、例えばシンセシス １９８２年，３０５頁等に記載の公知の方法に準じて製造することができる。   Some of the compounds represented by formula (5) are known compounds. Others can also be produced according to known methods described in, for example, Synthesis 1982, page 305.

本反応では式（４）で表される化合物１当量に対して、式（５）で表される化合物は、０．５〜５０当量の範囲で用いることができる。必要ならば、ｎ−ブチルリチウム、リチウムジイソプロピルアミド、リチウムビス（トリメチルシリル）アミド、ナトリウムビス（トリメチルシリル）アミド、カリウムビス（トリメチルシリル）アミド、水素化ナトリウム、ナトリウムメトキシド、炭酸カリウム等の塩基を使用することができる。本反応は、無溶媒で実施してもよいが、溶媒を用いてもよく、例えば、Ｎ，Ｎ−ジメチルホルムアミド、Ｎ，Ｎ−ジメチルアセトアミド、ジメチルスルホキシド、１−メチル−２−ピロリドン、１，３−ジメチル−２−イミダゾリノン等の極性溶媒、メタノール、エタノール、プロパノール、２−プロパノール、エチレングリコール等のアルコール類、ジエチルエーテル、テトラヒドロフラン、ジフェニルエーテル等のエーテル類、ペンタン、ｎ−ヘキサン等の脂肪族炭化水素類が挙げられる。これらの溶媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。   In this reaction, the compound represented by the formula (5) can be used in the range of 0.5 to 50 equivalents with respect to 1 equivalent of the compound represented by the formula (4). If necessary, use a base such as n-butyllithium, lithium diisopropylamide, lithium bis (trimethylsilyl) amide, sodium bis (trimethylsilyl) amide, potassium bis (trimethylsilyl) amide, sodium hydride, sodium methoxide, potassium carbonate, etc. be able to. This reaction may be carried out without a solvent, but a solvent may be used, for example, N, N-dimethylformamide, N, N-dimethylacetamide, dimethyl sulfoxide, 1-methyl-2-pyrrolidone, 1, Polar solvents such as 3-dimethyl-2-imidazolinone, alcohols such as methanol, ethanol, propanol, 2-propanol and ethylene glycol, ethers such as diethyl ether, tetrahydrofuran and diphenyl ether, aliphatics such as pentane and n-hexane And hydrocarbons. These solvents may be used alone or as a mixture of two or more thereof.

反応温度は、−８０℃から反応混合物の還流温度までの任意の温度を設定することができ、反応時間は、反応基質の濃度、反応温度によって変化するが、通常５分から１００時間の範囲で任意に設定できる。   The reaction temperature can be set to any temperature from −80 ° C. to the reflux temperature of the reaction mixture, and the reaction time varies depending on the concentration of the reaction substrate and the reaction temperature, but is usually arbitrary within the range of 5 minutes to 100 hours. Can be set.

製造法Ｅ   Manufacturing method E

式（９）［式中Ｚ及びｑは前記と同じ意味を表す。］で表される化合物を、式（１０）［式中Ｒ^６、Ｒ^８ａ、Ｒ^９ａ及びＱは前記と同じ意味を表す。］で表される化合物と反応させて、式（１−１−ａ３）［式中Ｒ^６、Ｒ^８ａ、Ｒ^９ａ、Ｑ、Ｚ及びｑは前記と同じ意味を表す。］で表される本発明化合物を製造することができる。 Formula (9) [wherein Z and q represent the same meaning as described above. The compound represented by formula (10) [wherein R ⁶ , R ^8a , R ^9a and Q represent the same meaning as described above. And a compound represented by formula (1-1-a3) [wherein R ⁶ , R ^8a , R ^9a , Q, Z and q represent the same meaning as described above. This invention compound represented by this can be manufactured.

式（９）で表される化合物の或るものは公知化合物である。それ以外のものも、例えば国際公開第２００９／０１９００５号等に記載の公知の方法に準じて製造することができる。   Some of the compounds represented by formula (9) are known compounds. Others can also be produced according to known methods described in, for example, International Publication No. 2009/019005.

式（１０）で表される化合物の或るものは公知化合物であり、一部は市販品として入手できる。また、それ以外のものも文献記載の公知の方法に準じて製造することができる。   Some of the compounds represented by formula (10) are known compounds, and some of them are commercially available. Others can also be produced according to known methods described in the literature.

本反応では式（９）で表される化合物１当量に対して、式（１０）で表される化合物は、０．５〜５０当量の範囲で用いることができる。必要ならば、トリエチルアミン、ピリジン、４−（ジメチルアミノ）ピリジン、１，８−ジアザビシクロ［５．４．０］−７−ウンデセン、ｎ−ブチルリチウム、リチウムジイソプロピルアミド、リチウムビス（トリメチルシリル）アミド、ナトリウムビス（トリメチルシリル）アミド、カリウムビス（トリメチルシリル）アミド、水素化ナトリウム、ナトリウムメトキシド、水酸化ナトリウム、水酸化カリウム、炭酸ナトリウム、炭酸カリウム等の塩基を使用することができる。   In this reaction, the compound represented by the formula (10) can be used in the range of 0.5 to 50 equivalents with respect to 1 equivalent of the compound represented by the formula (9). If necessary, triethylamine, pyridine, 4- (dimethylamino) pyridine, 1,8-diazabicyclo [5.4.0] -7-undecene, n-butyllithium, lithium diisopropylamide, lithium bis (trimethylsilyl) amide, sodium Bases such as bis (trimethylsilyl) amide, potassium bis (trimethylsilyl) amide, sodium hydride, sodium methoxide, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate and the like can be used.

本反応は、無溶媒で実施してもよいが、溶媒を用いてもよく、例えば、Ｎ，Ｎ−ジメチルホルムアミド、Ｎ，Ｎ−ジメチルアセトアミド、アセトニトリル、ジメチルスルホキシド、１，３−ジメチル−２−イミダゾリノン等の極性溶媒、メタノール、エタノール、プロパノール、２−プロパノール、エチレングリコール等のアルコール類、ジエチルエーテル、テトラヒドロフラン、ジフェニルエーテル等のエーテル類、ベンゼン、トルエン、キシレン等の芳香族炭化水素類、塩化メチレン、クロロホルム、四塩化炭素等のハロゲン化炭化水素類、ペンタン、ｎ−ヘキサン等の脂肪族炭化水素類が挙げられる。これらの溶媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。   This reaction may be carried out without solvent, but a solvent may be used, for example, N, N-dimethylformamide, N, N-dimethylacetamide, acetonitrile, dimethyl sulfoxide, 1,3-dimethyl-2- Polar solvents such as imidazolinone, alcohols such as methanol, ethanol, propanol, 2-propanol and ethylene glycol, ethers such as diethyl ether, tetrahydrofuran and diphenyl ether, aromatic hydrocarbons such as benzene, toluene and xylene, methylene chloride , Halogenated hydrocarbons such as chloroform and carbon tetrachloride, and aliphatic hydrocarbons such as pentane and n-hexane. These solvents may be used alone or as a mixture of two or more thereof.

製造法Ｆ   Manufacturing method F

式（１−１−ａ）で表される化合物のうち、式（１−１−ａ４）［式中Ｒ^６、Ｒ^８ａ、Ｑ、Ｚ及びｑは前記と同じ意味を表し、Ｒ^９ａ−２は、−Ｃ（Ｏ）ＯＲ^１６ａを表し、Ｒ^１６ａは前記と同じ意味を表す。］で表される化合物を、加水分解次いで脱炭酸することにより、式（１−１−ａ５）［式中Ｒ^６、Ｒ^８ａ、Ｑ、Ｚ及びｑは前記と同じ意味を表す。］で表される本発明化合物を得ることができる。 Of the compounds represented by formula (1-1-a), formula (1-1-a4) [wherein R ⁶ , R ^8a , Q, Z and q represent the same meaning as described above, and R ^9a-2 Represents —C (O) OR ^16a , and R ^16a represents the same meaning as described above. The compound represented by formula (1-1-a5) [wherein R ⁶ , R ^8a , Q, Z and q represent the same meaning as described above]. This invention compound represented by this can be obtained.

本反応では、必要ならば水、メタノール、エタノール、ジクロロメタン、クロロホルム、ジエチルエーテル、テトラヒドロフラン、１，４−ジオキサン、アセトニトリル、アセトン等の溶媒を使用してもよい。これらの溶媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。   In this reaction, if necessary, a solvent such as water, methanol, ethanol, dichloromethane, chloroform, diethyl ether, tetrahydrofuran, 1,4-dioxane, acetonitrile, acetone or the like may be used. These solvents may be used alone or as a mixture of two or more thereof.

必要ならば式（１−１−ａ４）で表される化合物１当量に対して０．１〜２０当量の塩酸、硫酸、ｐ−トルエンスルホン酸等の酸又は水酸化ナトリウム、水酸化カリウム、炭酸ナトリウム、炭酸カリウム等の塩基存在下で反応させることができる。   If necessary, 0.1 to 20 equivalents of an acid such as hydrochloric acid, sulfuric acid, p-toluenesulfonic acid or the like, or sodium hydroxide, potassium hydroxide, carbonic acid with respect to 1 equivalent of the compound represented by formula (1-1-a4) The reaction can be carried out in the presence of a base such as sodium or potassium carbonate.

反応温度は、−８０℃から反応混合物の還流温度までの任意の温度を設定することができ、反応時間は、反応基質の濃度、反応温度によって変化するが、通常５分から１００時間の範囲で任意に設定できる。   The reaction temperature can be set to any temperature from −80 ° C. to the reflux temperature of the reaction mixture, and the reaction time varies depending on the concentration of the reaction substrate and the reaction temperature, but is usually arbitrary within the range of 5 minutes to 100 hours. Can be set.

製造法Ｇ   Manufacturing method G

式（１−１−ａ）で表される化合物のうち、式（１−１−ａ６）［式中Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ^ａ、Ｚ^ｅ、ｍ及びｎは前記と同じ意味を表し、Ｊ^ｂはハロゲン原子、−ＯＳＯ_２Ｍｅ、−ＯＳＯ_２ＣＦ_３等の脱離基を表す。］で表される化合物と、式（１１）［式中Ｚ^ｃ−２はＣ_２〜Ｃ_６アルキニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、フェニル、（Ｚ^３）_ｑ３で置換されたフェニルを表し、Ｊ^ｃは−Ｃ（Ｏ）ＯＨ、−Ｓｎ（Ｃ_１〜Ｃ_６アルキル）_３、−Ｂ（ＯＨ）_２等を表し、Ｒ^４５、Ｚ^３及びｑ３は前記と同じ意味を表す。］を、触媒及び塩基の存在下で反応させることにより、式（１−１−ａ７）［式中Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ^ａ、Ｚ^ｅ、Ｚ^ｃ−２、ｍ及びｎは前記と同じ意味を表す。］で表される本発明化合物を製造することができる。 Among the compounds represented by formula (1-1-a), formula (1-1-a6) [wherein R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , Z ^a , Z ^e , m and n are as defined above, ^{J b} represents a halogen _atom, -OSO 2 Me, a leaving group such as -OSO ₂ CF _3. And a compound represented by formula (11) [wherein Z ^c-2 is C ₂ -C ₆ alkynyl, (C ₂ -C ₆ ) alkynyl optionally substituted with R ⁴⁵ , phenyl, (Z ³ ) represents phenyl substituted with _q3, ^{J c} is _{-C (O) OH, -Sn (} C 1 ~C 6 _alkyl) 3, represents the -B _{(OH) 2} or the ^like, R 45, ^{Z 3} and q3 are the Means the same. Is reacted in the presence of a catalyst and a base to give a compound of formula (1-1-a7) [wherein R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , Z ^a , Z ^e , Z ^c-2 , m and n represent the same meaning as described above. This invention compound represented by this can be manufactured.

式（１１）で表される化合物の量は、式（１−１−ａ６）で表される化合物１当量に対して０．５〜５０当量の範囲で、用いることができる。   The amount of the compound represented by the formula (11) can be used in the range of 0.5 to 50 equivalents relative to 1 equivalent of the compound represented by the formula (1-1-a6).

ここで用いられる式（１１）で表される化合物の或るものは公知化合物であり、一部は市販品として入手できる。また、それ以外のものも文献記載の方法に準じて製造することができる。   Some of the compounds represented by the formula (11) used here are known compounds, and some of them are commercially available. Others can also be produced according to the methods described in the literature.

本反応で使用できる触媒としては、例えば、パラジウム−炭素、塩化パラジウム、酢酸パラジウム、ビス（トリフェニルホスフィン）パラジウムジクロリド、テトラキス（トリフェニルホスフィン）パラジウム、［１，１’−ビス（ジフェニルホスフィノ）フェロセン］パラジウム（ＩＩ）ジクロリド ジクロロメタン付加物等のパラジウム触媒、金属銅、酢酸銅（１価）、酢酸銅（２価）、酸化銅（１価）、酸化銅（２価）、ヨウ化銅、臭化銅、塩化銅等の銅触媒が挙げられる。これらの触媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。触媒の使用量は、式（１−１−ａ６）で表される化合物１当量に対して０．００１〜１．０当量の範囲で、用いることができる。また、１，４−ビス（ジフェニルホスフィノ）ブタン等の配位子を触媒に対して０．００１〜１０当量の範囲で、用いることができる。   Examples of the catalyst that can be used in this reaction include palladium-carbon, palladium chloride, palladium acetate, bis (triphenylphosphine) palladium dichloride, tetrakis (triphenylphosphine) palladium, and [1,1′-bis (diphenylphosphino). Ferrocene] palladium (II) dichloride Palladium catalyst such as dichloromethane adduct, copper metal, copper acetate (monovalent), copper acetate (divalent), copper oxide (monovalent), copper oxide (divalent), copper iodide, Examples of the copper catalyst include copper bromide and copper chloride. These catalysts may be used alone or in combination of two or more of them. The usage-amount of a catalyst can be used in the range of 0.001-1.0 equivalent with respect to 1 equivalent of compounds represented by Formula (1-1-a6). A ligand such as 1,4-bis (diphenylphosphino) butane can be used in the range of 0.001 to 10 equivalents relative to the catalyst.

使用する塩基としては、例えば、ピリジン、ジイソプロピルエチルアミン、トリエチルアミン等の三級アミン化合物、水酸化ナトリウム水酸化カリウム、炭酸ナトリウム、炭酸カリウム、炭酸セシウム、炭酸水素ナトリウム、リン酸三カリウム等の無機塩基等が挙げられる。塩基の使用量は、式（１１）で表される化合物１当量に対して０．１〜１０．０当量の範囲で用いることができる。   Examples of the base used include tertiary amine compounds such as pyridine, diisopropylethylamine, and triethylamine, inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, cesium carbonate, sodium bicarbonate, and tripotassium phosphate. Is mentioned. The usage-amount of a base can be used in 0.1-10.0 equivalent with respect to 1 equivalent of compounds represented by Formula (11).

本反応は、無溶媒でも実施することができるが、溶媒を用いてもよい。使用できる溶媒としては、例えば、Ｎ，Ｎ−ジメチルホルムアミド、Ｎ，Ｎ−ジメチルアセトアミド、アセトニトリル、ジメチルスルホキシド、１，３−ジメチル−２−イミダゾリノン、水等の極性溶媒、メタノール、エタノール、プロパノール、２−プロパノール、エチレングリコール等のアルコール類、ジエチルエーテル、テトラヒドロフラン、ジフェニルエーテル等のエーテル類、ベンゼン、トルエン、キシレン等の芳香族炭化水素類、塩化メチレン、クロロホルム、四塩化炭素等のハロゲン化炭化水素類、ペンタン、ｎ−ヘキサン等の脂肪族炭化水素類が挙げられる。これらの溶媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。   This reaction can be carried out without solvent, but a solvent may be used. Examples of the solvent that can be used include N, N-dimethylformamide, N, N-dimethylacetamide, acetonitrile, dimethyl sulfoxide, 1,3-dimethyl-2-imidazolinone, water and other polar solvents, methanol, ethanol, propanol, Alcohols such as 2-propanol and ethylene glycol, ethers such as diethyl ether, tetrahydrofuran and diphenyl ether, aromatic hydrocarbons such as benzene, toluene and xylene, and halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride Aliphatic hydrocarbons such as pentane and n-hexane. These solvents may be used alone or as a mixture of two or more thereof.

反応温度は、−８０℃から反応混合物の還流温度までの任意の温度を設定することができ、反応時間は、反応基質の濃度、反応温度によって変化するが、通常５分から１００時間の範囲で任意に設定できる。   The reaction temperature can be set to any temperature from −80 ° C. to the reflux temperature of the reaction mixture, and the reaction time varies depending on the concentration of the reaction substrate and the reaction temperature, but is usually arbitrary within the range of 5 minutes to 100 hours. Can be set.

製造法Ｈ   Manufacturing method H

式（１−１−ａ）で表される化合物の内、式（１−１−ａ６）［式中Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ^ａ、Ｚ^ｅ、ｍ及びｎは前記と同じ意味を表し、Ｊ^ｂはハロゲン原子、−ＯＳＯ_２Ｍｅ、−ＯＳＯ_２ＣＦ_３等の脱離基を表す。］で表される化合物と、式（１２）［式中Ｘ^１及びｇ３は前記と同じ意味を表す。］を、触媒及び塩基の存在下で反応させることにより、式（１−１−ａ８）［式中Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ^ａ、Ｚ^ｅ、Ｘ^１、ｇ３、ｍ及びｎは前記と同じ意味を表す。］で表される本発明化合物を製造することができる。 Among the compounds represented by formula (1-1-a), formula (1-1-a6) [wherein R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , Z ^a , Z ^e , m and n are as defined above, ^{J b} represents a halogen _atom, -OSO 2 Me, a leaving group such as -OSO ₂ CF _3. And a compound represented by the formula (12) [wherein X ¹ and g3 represent the same meaning as described above. Is reacted in the presence of a catalyst and a base to give a compound of formula (1-1-a8) [wherein R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , Z ^a , Z ^e , X ¹ , g3, m and n represent the same meaning as described above. This invention compound represented by this can be manufactured.

式（１２）で表される化合物の量は、式（１−１−ａ６）で表される化合物１当量に対して０．５〜５０当量の範囲で、用いることができる。   The amount of the compound represented by the formula (12) can be used in the range of 0.5 to 50 equivalents relative to 1 equivalent of the compound represented by the formula (1-1-a6).

ここで用いられる式（１２）で表される化合物の或るものは公知化合物であり、一部は市販品として入手できる。また、それ以外のものも文献記載の方法に準じて製造することができる。   Some of the compounds represented by the formula (12) used here are known compounds, and some of them are available as commercial products. Others can also be produced according to the methods described in the literature.

本反応で使用できる触媒としては、例えば、パラジウム−炭素、塩化パラジウム、酢酸パラジウム、ビス（トリフェニルホスフィン）パラジウムジクロリド、テトラキス（トリフェニルホスフィン）パラジウム、［１，１’−ビス（ジフェニルホスフィノ）フェロセン］パラジウム（ＩＩ）ジクロリド ジクロロメタン付加物等のパラジウム触媒、金属銅、酢酸銅（１価）、酢酸銅（２価）、酸化銅（１価）、酸化銅（２価）、ヨウ化銅、臭化銅、塩化銅等の銅触媒が挙げられる。これらの触媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。触媒の使用量は、式（１−１−ａ６）で表される化合物１当量に対して０．００１〜１．０当量の範囲で、用いることができる。また、Ｎ，Ｎ’−ジメチルエチレンジアミン、Ｎ，Ｎ’−ジメチルシクロヘキサン−１，２−ジアミン等の配位子を触媒に対して０．００１〜１０当量の範囲で、用いることができる。   Examples of the catalyst that can be used in this reaction include palladium-carbon, palladium chloride, palladium acetate, bis (triphenylphosphine) palladium dichloride, tetrakis (triphenylphosphine) palladium, and [1,1′-bis (diphenylphosphino). Ferrocene] palladium (II) dichloride Palladium catalyst such as dichloromethane adduct, copper metal, copper acetate (monovalent), copper acetate (divalent), copper oxide (monovalent), copper oxide (divalent), copper iodide, Examples of the copper catalyst include copper bromide and copper chloride. These catalysts may be used alone or in combination of two or more of them. The usage-amount of a catalyst can be used in the range of 0.001-1.0 equivalent with respect to 1 equivalent of compounds represented by Formula (1-1-a6). A ligand such as N, N′-dimethylethylenediamine or N, N′-dimethylcyclohexane-1,2-diamine can be used in an amount of 0.001 to 10 equivalents relative to the catalyst.

使用する塩基としては、例えば、ピリジン、ジイソプロピルエチルアミン、トリエチルアミン等の三級アミン化合物、水酸化ナトリウム水酸化カリウム、炭酸ナトリウム、炭酸カリウム、炭酸セシウム、炭酸水素ナトリウム、リン酸三カリウム等の無機塩基等が挙げられる。塩基の使用量は、式（１２）で表される化合物１当量に対して０．１〜１０．０当量の範囲で用いることができる。   Examples of the base used include tertiary amine compounds such as pyridine, diisopropylethylamine, and triethylamine, inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, cesium carbonate, sodium bicarbonate, and tripotassium phosphate. Is mentioned. The usage-amount of a base can be used in 0.1-10.0 equivalent with respect to 1 equivalent of compounds represented by Formula (12).

本反応は、無溶媒でも実施することができるが、溶媒を用いてもよい。使用できる溶媒としては、例えば、Ｎ，Ｎ−ジメチルホルムアミド、Ｎ，Ｎ−ジメチルアセトアミド、アセトニトリル、ジメチルスルホキシド、１，３−ジメチル−２−イミダゾリノン、水等の極性溶媒、メタノール、エタノール、プロパノール、２−プロパノール、エチレングリコール等のアルコール類、ジエチルエーテル、テトラヒドロフラン、ジフェニルエーテル等のエーテル類、ベンゼン、トルエン、キシレン等の芳香族炭化水素類、塩化メチレン、クロロホルム、四塩化炭素等のハロゲン化炭化水素類、ペンタン、ｎ−ヘキサン等の脂肪族炭化水素類が挙げられる。これらの溶媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。   This reaction can be carried out without solvent, but a solvent may be used. Examples of the solvent that can be used include N, N-dimethylformamide, N, N-dimethylacetamide, acetonitrile, dimethyl sulfoxide, 1,3-dimethyl-2-imidazolinone, water and other polar solvents, methanol, ethanol, propanol, Alcohols such as 2-propanol and ethylene glycol, ethers such as diethyl ether, tetrahydrofuran and diphenyl ether, aromatic hydrocarbons such as benzene, toluene and xylene, and halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride Aliphatic hydrocarbons such as pentane and n-hexane. These solvents may be used alone or as a mixture of two or more thereof.

反応温度は、−８０℃から反応混合物の還流温度までの任意の温度を設定することができ、反応時間は、反応基質の濃度、反応温度によって変化するが、通常５分から１００時間の範囲で任意に設定できる。   The reaction temperature can be set to any temperature from −80 ° C. to the reflux temperature of the reaction mixture, and the reaction time varies depending on the concentration of the reaction substrate and the reaction temperature, but is usually arbitrary within the range of 5 minutes to 100 hours. Can be set.

製造法Ａから製造法Ｈの反応は、必要であれば窒素、アルゴン等の不活性ガス雰囲気下で実施しても良い。   The reaction from production method A to production method H may be carried out in an inert gas atmosphere such as nitrogen or argon if necessary.

製造法Ａから製造法Ｈの反応において、反応終了後の反応混合物は、直接濃縮又は有機溶媒に溶解し、水洗後濃縮又は氷水に投入、有機溶媒抽出後濃縮といった通常の後処理を行ない、目的の本発明化合物を得ることができる。また、精製の必要が生じたときには、再結晶、カラムクロマトグラフ、薄層クロマトグラフ、液体クロマトグラフ分取等の任意の精製方法によって分離、精製することができる。   In the reaction from production method A to production method H, the reaction mixture after completion of the reaction is directly concentrated or dissolved in an organic solvent, washed with water, poured into ice water, or subjected to normal post-treatment such as extraction after organic solvent extraction. Of the present invention can be obtained. Moreover, when the necessity for purification arises, it can be separated and purified by any purification method such as recrystallization, column chromatograph, thin layer chromatograph, liquid chromatographic fractionation and the like.

製造法Ｉ   Manufacturing method I

式（１３−１）［式中Ｒ^９０は、Ｃ_１〜Ｃ_６アルコキシ、ピラゾール−１−イル、イミダゾール−１−イル等の脱離基を表し、Ａ^１、Ｑ、Ｒ^６、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｒ^９０、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される化合物及び式（１３−２）［式中Ｒ^９０は、Ｃ_１〜Ｃ_６アルコキシ、ピラゾール−１−イル、イミダゾール−１−イル等の脱離基を表し、Ａ^１、Ｑ、Ｒ^６、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｒ^９０、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される化合物との混合物を、塩基と反応させることにより式（１−３）［式中Ａ^１、Ｑ、Ｒ^６、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される本発明化合物を製造することができる。 Formula (13-1) [wherein R ⁹⁰ represents a leaving group such as C ₁ -C ₆ alkoxy, pyrazol-1-yl, imidazol-1-yl, and is represented by A ¹ , Q, R ⁶ , R ^8a , R ^8b , R ^9a , R ^9b , R ⁹⁰ , Z, m, n and q represent the same meaning as described above. And a compound represented by formula (13-2) [wherein R ⁹⁰ represents a leaving group such as C ₁ -C ₆ alkoxy, pyrazol-1-yl, imidazol-1-yl, and the like, A ¹ , Q , R ⁶ , R ^8a , R ^8b , R ^9a , R ^9b , R ⁹⁰ , Z, m, n and q have the same meaning as described above. The compound represented by the formula (1-3) [wherein A ¹ , Q, R ⁶ , R ^8a , R ^8b , R ^9a , R ^9b , Z, m, n and q represent the same meaning as described above. This invention compound represented by this can be manufactured.

使用する塩基としては、例えば、ｎ−ブチルリチウム、リチウムジイソプロピルアミド、リチウムビス（トリメチルシリル）アミド、ナトリウムビス（トリメチルシリル）アミド、カリウムビス（トリメチルシリル）アミド、水素化ナトリウム、ナトリウムメトキシド、炭酸カリウム、トリエチルアミン、ピリジン、４−（ジメチルアミノ）ピリジン、１，８−ジアザビシクロ［５．４．０］−７−ウンデセン等が挙げられる。塩基の使用量は、式（１３−１）で表される化合物及び式（１３−２）で表される化合物の混合物１当量に対して０．１〜１０．０当量の範囲で用いることができる。   Examples of the base used include n-butyllithium, lithium diisopropylamide, lithium bis (trimethylsilyl) amide, sodium bis (trimethylsilyl) amide, potassium bis (trimethylsilyl) amide, sodium hydride, sodium methoxide, potassium carbonate, triethylamine , Pyridine, 4- (dimethylamino) pyridine, 1,8-diazabicyclo [5.4.0] -7-undecene, and the like. The base is used in an amount of 0.1 to 10.0 equivalents per 1 equivalent of the mixture of the compound represented by formula (13-1) and the compound represented by formula (13-2). it can.

本反応は、無溶媒でも実施することができるが、溶媒を用いてもよい。使用できる溶媒としては、例えば、Ｎ，Ｎ−ジメチルホルムアミド、Ｎ，Ｎ−ジメチルアセトアミド、アセトニトリル、ジメチルスルホキシド、１，３−ジメチル−２−イミダゾリノン、水等の極性溶媒、メタノール、エタノール、プロパノール、２−プロパノール、エチレングリコール等のアルコール類、ジエチルエーテル、テトラヒドロフラン、ジフェニルエーテル等のエーテル類、ベンゼン、トルエン、キシレン等の芳香族炭化水素類、塩化メチレン、クロロホルム、四塩化炭素等のハロゲン化炭化水素類、ペンタン、ｎ−ヘキサン等の脂肪族炭化水素類が挙げられる。これらの溶媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。   This reaction can be carried out without solvent, but a solvent may be used. Examples of the solvent that can be used include N, N-dimethylformamide, N, N-dimethylacetamide, acetonitrile, dimethyl sulfoxide, 1,3-dimethyl-2-imidazolinone, water and other polar solvents, methanol, ethanol, propanol, Alcohols such as 2-propanol and ethylene glycol, ethers such as diethyl ether, tetrahydrofuran and diphenyl ether, aromatic hydrocarbons such as benzene, toluene and xylene, and halogenated hydrocarbons such as methylene chloride, chloroform and carbon tetrachloride Aliphatic hydrocarbons such as pentane and n-hexane. These solvents may be used alone or as a mixture of two or more thereof.

反応温度は、−８０℃から反応混合物の還流温度までの任意の温度を設定することができ、反応時間は、反応基質の濃度、反応温度によって変化するが、通常５分から１００時間の範囲で任意に設定できる。   The reaction temperature can be set to any temperature from −80 ° C. to the reflux temperature of the reaction mixture, and the reaction time varies depending on the concentration of the reaction substrate and the reaction temperature, but is usually arbitrary within the range of 5 minutes to 100 hours. Can be set.

製造法Ｉで用いられる式（１３−１）で表される化合物及び式（１３−２）で表される化合物の混合物は、例えば反応式１に記載の製造ルートに従って製造することが出来る。   The mixture of the compound represented by Formula (13-1) and the compound represented by Formula (13-2) used in Production Method I can be produced, for example, according to the production route described in Reaction Scheme 1.

反応式１   Reaction formula 1

工程１
式（１７−１）［式中Ａ^１、Ｑ、Ｒ^６、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される化合物及び式（１７−２）［式中Ａ^１、Ｑ、Ｒ^６、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される化合物の混合物は、式（１５）［式中Ａ^１、Ｚ及びｑは前記と同じ意味を表す。］で表される化合物と式（１６）［Ｑ、Ｒ^６、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、ｍ及びｎは前記と同じ意味を表す。］で表される化合物とを、文献既知の方法、例えば、米国特許出願公開第１９８１／４２８３３４８号明細書等に記載の方法に準じて、反応させることにより製造することができる。 Process 1
Formula (17-1) [wherein ^{A 1, Q, R 6,} R 8a, R 8b, R 9a, R 9b, Z, m, n and q are as defined above. And a compound represented by formula (17-2) [wherein A ¹ , Q, R ⁶ , R ^8a , R ^8b , R ^9a , R ^9b , Z, m, n, and q represent the same meaning as described above. . The compound represented by formula (15) [wherein A ¹ , Z and q represent the same meaning as described above]. ] And the compound represented by formula (16) [Q, R ⁶ , R ^8a , R ^8b , R ^9a , R ^9b , m and n represent the same meaning as described above. The compound represented by formula (I) can be produced by reacting the compound according to a method known in the literature, for example, the method described in US Patent Application Publication No. 1981/42834848.

ここで用いられる式（１５）で表される化合物の或るものは公知化合物であり、一部は市販品として入手できる。また、それ以外のものも文献記載の方法に準じて製造することができる。   Some of the compounds represented by the formula (15) used here are known compounds, and some of them are commercially available. Others can also be produced according to the methods described in the literature.

また、式（１６）で表される化合物の或るものは公知化合物であり、例えば、ジャーナル オブ ザ ケミカル ソサェティー１９６５年，４３５５頁等に準じて製造することができる。   Some of the compounds represented by the formula (16) are known compounds and can be produced, for example, according to Journal of the Chemical Society, 1965, page 4355.

工程２
式（１７−１）で表される化合物及び式（１７−２）で表される化合物の混合物を、文献既知の公知の方法、例えば、実験化学講座 第４版（日本化学会編） １９９２年，２２巻，１２２頁等に記載の方法に準じて塩化チオニル又はオキサリルクロリド等のハロゲン化剤と反応させた後、式（１８）［式中Ｒ^９０はＣ_１〜Ｃ_６アルコキシ、ピラゾール−１−イル、イミダゾール−１−イル等を表す。］で表される化合物を、文献既知の公知の方法、例えば、実験化学講座 第４版（日本化学会編） １９９２年，２２巻，５０頁等に記載の方法に準じて反応させることにより式（１３−１）で表される化合物及び式（１３−２）で表される化合物の混合物を製造することができる。 Process 2
A mixture of the compound represented by the formula (17-1) and the compound represented by the formula (17-2) is converted into a known method known in the literature, for example, Experimental Chemistry Course 4th Edition (Edited by Chemical Society of Japan) 1992 , Vol. 22, p. 122, etc., after reacting with a halogenating agent such as thionyl chloride or oxalyl chloride, the compound represented by formula (18) [wherein R ⁹⁰ is C ₁ -C ₆ alkoxy, pyrazole-1 -Il, imidazol-1-yl, etc. are represented. The compound represented by the formula is reacted by a method known in the literature, for example, according to the method described in Experimental Chemistry Course 4th Edition (Edited by The Chemical Society of Japan) 1992, Vol. 22, p. 50, etc. A mixture of the compound represented by (13-1) and the compound represented by formula (13-2) can be produced.

ここで用いられる式（１８）で表される化合物の或るものは公知化合物であり、一部は市販品として入手できる。また、それ以外のものも文献記載の方法に準じて製造することができる。   Some of the compounds represented by the formula (18) used here are known compounds, and some of them are commercially available. Others can also be produced according to the methods described in the literature.

製造法Ｊ   Manufacturing method J

式（１−１）で表される化合物の内、式（１−１−ｂ）［式中Ａ^３、Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される化合物と、式（１９）［式中Ｒ^１０及びＪ^ａは前記と同じ意味を表す。］で表される化合物を、反応させることにより、式（１−１−ｂ２）［式中Ａ^３、Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｒ^１０、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される本発明化合物を製造することができる。 Among the compounds represented by formula (1-1), formula (1-1-b) [wherein A ³ , R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , Z, m, n and q represent the same meaning as described above. And a compound represented by formula (19) [wherein R ¹⁰ and J ^a represent the same meaning as described above. By reacting the compound represented by formula (1-1-b2) [wherein A ³ , R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , R ¹⁰ , Z, m, n and q represent the same meaning as described above. This invention compound represented by this can be manufactured.

式（１９）で表される化合物の或るものは公知化合物であり、一部は市販品として入手できる。また、それ以外のものも文献記載の公知の方法に準じて製造することができる。   Some of the compounds represented by formula (19) are known compounds, and some of them are commercially available. Others can also be produced according to known methods described in the literature.

本反応では式（１−１−ｂ）で表される化合物１当量に対して、式（１９）で表される化合物は、０．５〜５０当量の範囲で用いることができる。必要ならば、ｎ−ブチルリチウム，リチウムジイソプロピルアミド、リチウムビス（トリメチルシリル）アミド、ナトリウムビス（トリメチルシリル）アミド、カリウムビス（トリメチルシリル）アミド、水素化ナトリウム、ナトリウムメトキシド、炭酸カリウム等の塩基を、式（１−１−ｂ）で表される化合物１当量に対して０．５〜５０．０当量の範囲で使用することができる。本反応は、無溶媒で実施してもよいが、溶媒を用いてもよく、例えば、Ｎ，Ｎ−ジメチルホルムアミド、Ｎ，Ｎ−ジメチルアセトアミド、ジメチルスルホキシド、１−メチル−２−ピロリドン、１，３−ジメチル−２−イミダゾリノン等の極性溶媒、メタノール、エタノール、プロパノール、２−プロパノール、エチレングリコール等のアルコール類、ジエチルエーテル、テトラヒドロフラン、ジフェニルエーテル等のエーテル類、ペンタン、ｎ−ヘキサン等の脂肪族炭化水素類が挙げられる。これらの溶媒は単独で用いても、これらの内の２種類以上を混合して用いてもよい。   In this reaction, the compound represented by the formula (19) can be used in the range of 0.5 to 50 equivalents with respect to 1 equivalent of the compound represented by the formula (1-1-b). If necessary, a base such as n-butyllithium, lithium diisopropylamide, lithium bis (trimethylsilyl) amide, sodium bis (trimethylsilyl) amide, potassium bis (trimethylsilyl) amide, sodium hydride, sodium methoxide, potassium carbonate, etc. It can be used in the range of 0.5 to 50.0 equivalents relative to 1 equivalent of the compound represented by (1-1-b). This reaction may be carried out without a solvent, but a solvent may be used, for example, N, N-dimethylformamide, N, N-dimethylacetamide, dimethyl sulfoxide, 1-methyl-2-pyrrolidone, 1, Polar solvents such as 3-dimethyl-2-imidazolinone, alcohols such as methanol, ethanol, propanol, 2-propanol and ethylene glycol, ethers such as diethyl ether, tetrahydrofuran and diphenyl ether, aliphatics such as pentane and n-hexane And hydrocarbons. These solvents may be used alone or as a mixture of two or more thereof.

反応温度は、−８０℃から反応混合物の還流温度までの任意の温度を設定することができ、反応時間は、反応基質の濃度、反応温度によって変化するが、通常５分から１００時間の範囲で任意に設定できる。   The reaction temperature can be set to any temperature from −80 ° C. to the reflux temperature of the reaction mixture, and the reaction time varies depending on the concentration of the reaction substrate and the reaction temperature, but is usually arbitrary within the range of 5 minutes to 100 hours. Can be set.

製造法Ｋ   Manufacturing method K

式（１−２）で表される化合物の内、式（１−２−ｂ）［式中Ａ^３、Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される化合物と、式（２０）［式中Ｒ^１１及びＪ^ａは前記と同じ意味を表す。］を、製造法Ｊと同様の方法で反応させることにより、式（１−２−ｂ２）［式中Ａ^３、Ｒ^６、Ｒ^７、Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ、Ｒ^９ｂ、Ｒ^１１、Ｚ、ｍ、ｎ及びｑは前記と同じ意味を表す。］で表される本発明化合物を製造することができる。 Among the compounds represented by formula (1-2), formula (1-2b) [wherein A ³ , R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , Z, m, n and q represent the same meaning as described above. And a compound represented by formula (20): wherein R ¹¹ and J ^a have the same meaning as described above. Is reacted in the same manner as in production method J, thereby producing a compound of formula (1-2-b2) [wherein A ³ , R ⁶ , R ⁷ , R ^8a , R ^8b , R ^9a , R ^9b , R ^11]. , Z, m, n, and q have the same meaning as described above. This invention compound represented by this can be manufactured.

尚、製造法Ｊで用いる式（１-１-ｂ）で表される化合物と、製造法Ｋで用いる式（１−２−ｂ）で表される化合物は、前記の製造法Ａの方法により混合物として製造することができる。製造法Ａに記載の方法により得られた式（１-１-ｂ）で表される化合物及び式（１−２−ｂ）で表される化合物の混合物は、分離することなく製造法Ｊ及び製造法Ｋと同様の方法で反応させることにより、式（１−１−ｂ２）で表される化合物及び式（１−２−ｂ２）で表される化合物の混合物として製造することができ、式（１−１−ｂ２）で表される化合物及び式（１−２−ｂ２）で表される化合物は、該混合物より再結晶、カラムクロマトグラフィー等の任意の精製法によって分離、精製することで得ることができる。   The compound represented by the formula (1-1-b) used in the production method J and the compound represented by the formula (1-2-b) used in the production method K are obtained by the method of the production method A described above. It can be produced as a mixture. The mixture of the compound represented by the formula (1-1-b) and the compound represented by the formula (1-2-b) obtained by the method described in the production method A was separated without producing the production method J and By making it react by the method similar to the manufacturing method K, it can manufacture as a mixture of the compound represented by the compound represented by a formula (1-1-b2), and a formula (1-2-b2). The compound represented by (1-1-b2) and the compound represented by formula (1-2-b2) can be separated and purified from the mixture by any purification method such as recrystallization and column chromatography. Can be obtained.

製造法Ａから製造法Ｋの反応は、必要であれば窒素、アルゴン等の不活性ガス雰囲気下で実施しても良い。   The reaction from production method A to production method K may be carried out in an inert gas atmosphere such as nitrogen or argon if necessary.

製造法Ａから製造法Ｋの反応において、反応終了後の反応混合物は、直接濃縮又は有機溶媒に溶解し、水洗後濃縮又は氷水に投入、有機溶媒抽出後濃縮といった通常の後処理を行ない、目的の本発明化合物を得ることができる。また、精製の必要が生じたときには、再結晶、カラムクロマトグラフ、薄層クロマトグラフ、液体クロマトグラフ分取等の任意の精製方法によって分離、精製することができる。   In the reaction from production method A to production method K, the reaction mixture after completion of the reaction is directly concentrated or dissolved in an organic solvent, washed with water, poured into ice water, or subjected to usual post-treatment such as extraction after organic solvent extraction. Of the present invention can be obtained. Moreover, when the necessity for purification arises, it can be separated and purified by any purification method such as recrystallization, column chromatograph, thin layer chromatograph, liquid chromatographic fractionation and the like.

本発明に包含される活性化合物としては、具体的に例えば第１表に示す化合物が挙げられる。但し、第１表の化合物は例示のためのものであって、本発明はこれらのみに限定されるものではない。尚、表中、Ｍｅと記載される置換基はメチル基を表し、以下、Ｅｔとの記載はエチル基を表し、ｎ−Ｐｒ及びＰｒ−ｎはノルマルプロピル基を、ｉ−Ｐｒ及びＰｒ−ｉはイソプロピル基を、ｃ−Ｐｒ及びＰｒ−ｃはシクロプロピル基を、ｎ−Ｂｕ及びＢｕ−ｎはノルマルブチル基を、ｓ−Ｂｕ及びＢｕ−ｓはセカンダリーブチル基を、ｉ−Ｂｕ及びＢｕ−ｉはイソブチル基を、ｔ−Ｂｕ及びＢｕ−ｔはターシャリーブチル基を、ｃ−Ｂｕ及びＢｕ−ｃはシクロブチル基を、ｎ−Ｐｅｎ及びＰｅｎ−ｎはノルマルペンチル基を、ｃ−Ｐｅｎ及びＰｅｎ−ｃはシクロペンチル基を、ｎ−Ｈｅｘ及びＨｅｘ−ｎはノルマルヘキシル基を、ｃ−Ｈｅｘ及びＨｅｘ−ｃはシクロヘキシル基を、ｎ−Ｏｃｔ及びＯｃｔ−ｎはノルマルオクチル基を、Ｐｈはフェニル基をそれぞれ表す。   Specific examples of the active compound included in the present invention include compounds shown in Table 1. However, the compounds in Table 1 are for illustrative purposes, and the present invention is not limited thereto. In the table, the substituent described as Me represents a methyl group, hereinafter, Et represents an ethyl group, n-Pr and Pr-n represent normal propyl groups, i-Pr and Pr-i. Is an isopropyl group, c-Pr and Pr-c are cyclopropyl groups, n-Bu and Bu-n are normal butyl groups, s-Bu and Bu-s are secondary butyl groups, i-Bu and Bu- i is an isobutyl group, t-Bu and Bu-t are tertiary butyl groups, c-Bu and Bu-c are cyclobutyl groups, n-Pen and Pen-n are normal pentyl groups, c-Pen and Pen -C is a cyclopentyl group, n-Hex and Hex-n are normal hexyl groups, c-Hex and Hex-c are cyclohexyl groups, n-Oct and Oct-n are normal octyl groups, Ph is It represents a Eniru group respectively.

表中、Ｄ１−２ａ、Ｄ１−２ｃ、Ｄ１−７ａ、Ｄ１−７ｂ−１、Ｄ１−７ｂ−２、Ｄ１−７ｂ−３、Ｄ１−７ｂ−４、Ｄ１−１０ａ、Ｄ１−１１ａ、Ｄ１−１１ｂ−１、Ｄ１−１１ｂ−２、Ｄ１−１１ｂ−３、Ｄ１−１１ｂ−４、Ｄ１−２２ａ、Ｄ１−２２ｂ−１、Ｄ１−２２ｂ−２、Ｄ１−２２ｂ−３、Ｄ１−２２ｂ−４、Ｄ１−３２ａ、Ｄ１−３２ｂ−１、Ｄ１−３２ｂ−２、Ｄ１−３２ｂ−３、Ｄ１−３２ｂ−４、Ｄ１−３２ｂ−５、Ｄ１−３３ａ、Ｄ１−３３ｂ−１、Ｄ１−３３ｂ−２、Ｄ１−３３ｂ−３、Ｄ１−３３ｂ−４、Ｄ１−３４ａ、Ｄ１−３７ａ、Ｄ１−３７ｂ−１、Ｄ１−１０８ａ、Ｄ１−１０８ｂ−１、Ｄ１−１０８ｂ−２、Ｄ１−１０８ｂ−３、Ｄ１−１０８ｂ−４、Ｄ１−１０８ｂ−５、Ｄ１−１０８ｂ−６、Ｄ１−１０８ｂ−７、Ｄ１−１０８ｂ−８、Ｄ１−１０８ｂ−９、Ｄ１−１０８ｂ−１０、Ｄ１−１０８ｂ−１１、Ｄ１−１０８ｂ−１２、Ｄ１−１０８ｂ−１３、Ｄ１−１０８ｂ−１４、Ｄ１−１０８ｂ−１５、Ｄ１−１０８ｂ−１６、Ｄ１−１０８ｂ−１７、Ｄ１−１０８ｂ−１８、Ｄ１−１０８ｂ−１９、Ｄ１−１０３−１、Ｄ１−１０３−２、Ｄ１−１０３−３、Ｄ１−１０３−４、Ａ１〜Ａ２２６で表される構造は下記の構造を表す。   In the table, D1-2a, D1-2c, D1-7a, D1-7b-1, D1-7b-2, D1-7b-3, D1-7b-4, D1-10a, D1-11a, D1-11b -1, D1-11b-2, D1-11b-3, D1-11b-4, D1-22a, D1-22b-1, D1-22b-2, D1-22b-3, D1-22b-4, D1 -32a, D1-32b-1, D1-32b-2, D1-32b-3, D1-32b-4, D1-32b-5, D1-33a, D1-33b-1, D1-33b-2, D1 -33b-3, D1-33b-4, D1-34a, D1-37a, D1-37b-1, D1-108a, D1-108b-1, D1-108b-2, D1-108b-3, D1-108b -4, D1-108b-5, D1-108b-6, D -108b-7, D1-108b-8, D1-108b-9, D1-108b-10, D1-108b-11, D1-108b-12, D1-108b-13, D1-108b-14, D1-108b -15, D1-108b-16, D1-108b-17, D1-108b-18, D1-108b-19, D1-103-1, D1-103-2, D1-103-3, D1-103-4 , A1 to A226 represent the following structures.

〔第１表〕   [Table 1]

〔第１表〕 〔第１表〕（続き）
――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ――――――――――――――――
Me Me Me F H Me Me Et F H
Me Me Me Cl H Me Me Et Cl H
Me Me Me Br H Me Me Et Br H
Me Me Me I H Me Me Et I H
Me Me Me CN H Me Me Et CN H
Me Me Me NO₂ H Me Me Et NO₂ H
CH=CH₂ Me Me Me H CH=CH₂ Me Et Me H
c-Bu Me Me Me H c-Bu Me Et Me H
c-Pen Me Me Me H c-Pen Me Et Me H
c-Hex Me Me Me H c-Hex Me Et Me H
Ph Me Me Me H Ph Me Et Me H
CF₃ Me Me Me H CF₃ Me Et Me H
CH₂Cl Me Me Me H CH₂Cl Me Et Me H
CH₂OMe Me Me Me H CH₂OMe Me Et Me H
D1-32a Me Me Me H D1-32a Me Et Me H
Me Me Me Me H Me Me Et Me H
CH=CH₂ Me Me Me A1 Me Me Et Me A1
CH=CH₂ Me Me Me A13 Me Me Et Me A2
CH=CH₂ Me Me Me A14 Me Me Et Me A3
CH=CH₂ Me Me Me A15 Me Me Et Me A4
CH=CH₂ Me Me Me A16 Me Me Et Me A5
CH=CH₂ Me Me Me A20 Me Me Et Me A6
CH=CH₂ Me Me Me A23 Me Me Et Me A7
CH=CH₂ Me Me Me A24 Me Me Et Me A8
CH=CH₂ Me Me Me A25 Me Me Et Me A9
CH=CH₂ Me Me Me A26 Me Me Et Me A10
CH=CH₂ Me Me Me A27 Me Me Et Me A11
CH=CH₂ Me Me Me A28 Me Me Et Me A12
CH=CH₂ Me Me Me A29 Me Me Et Me A13
CH=CH₂ Me Me Me A34 Me Me Et Me A14
CH=CH₂ Me Me Me A35 Me Me Et Me A15
CH=CH₂ Me Me Me A36 Me Me Et Me A16
CH=CH₂ Me Me Me A37 Me Me Et Me A17
CH=CH₂ Me Me Me A42 Me Me Et Me A18
CH=CH₂ Me Me Me A58 Me Me Et Me A19
CH=CH₂ Me Me Me A63 Me Me Et Me A20
CH=CH₂ Me Me Me A64 Me Me Et Me A21
CH=CH₂ Me Me Me A65 Me Me Et Me A22
CH=CH₂ Me Me Me A67 Me Me Et Me A23
――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ――――――――――――――――
CH=CH₂ Me Me Me A69 Me Me Et Me A24
CH=CH₂ Me Me Me A72 Me Me Et Me A25
CH=CH₂ Me Me Me A73 Me Me Et Me A26
CH=CH₂ Me Me Me A74 Me Me Et Me A27
CH=CH₂ Me Me Me A75 Me Me Et Me A28
CH=CH₂ Me Me Me A76 Me Me Et Me A29
CH=CH₂ Me Me Me A77 Me Me Et Me A30
CH=CH₂ Me Me Me A81 Me Me Et Me A31
CH=CH₂ Me Me Me A83 Me Me Et Me A32
CH=CH₂ Me Me Me A88 Me Me Et Me A33
CH=CH₂ Me Me Me A91 Me Me Et Me A34
CH=CH₂ Me Me Me A97 Me Me Et Me A35
CH=CH₂ Me Me Me A98 Me Me Et Me A36
CH=CH₂ Me Me Me A102 Me Me Et Me A37
Ph Me Me Me A1 Me Me Et Me A38
Ph Me Me Me A13 Me Me Et Me A39
Ph Me Me Me A14 Me Me Et Me A40
Ph Me Me Me A15 Me Me Et Me A41
Ph Me Me Me A16 Me Me Et Me A42
Ph Me Me Me A20 Me Me Et Me A43
Ph Me Me Me A23 Me Me Et Me A44
Ph Me Me Me A24 Me Me Et Me A45
Ph Me Me Me A25 Me Me Et Me A46
Ph Me Me Me A26 Me Me Et Me A47
Ph Me Me Me A27 Me Me Et Me A48
Ph Me Me Me A28 Me Me Et Me A49
Ph Me Me Me A29 Me Me Et Me A50
Ph Me Me Me A34 Me Me Et Me A51
Ph Me Me Me A35 Me Me Et Me A52
Ph Me Me Me A36 Me Me Et Me A53
Ph Me Me Me A37 Me Me Et Me A54
Ph Me Me Me A42 Me Me Et Me A55
Ph Me Me Me A58 Me Me Et Me A56
Ph Me Me Me A63 Me Me Et Me A57
Ph Me Me Me A64 Me Me Et Me A58
Ph Me Me Me A65 Me Me Et Me A59
Ph Me Me Me A67 Me Me Et Me A60
Ph Me Me Me A69 Me Me Et Me A61
Ph Me Me Me A72 Me Me Et Me A62
――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ――――――――――――――――
Ph Me Me Me A73 Me Me Et Me A63
Ph Me Me Me A74 Me Me Et Me A64
Ph Me Me Me A75 Me Me Et Me A65
Ph Me Me Me A76 Me Me Et Me A66
Ph Me Me Me A77 Me Me Et Me A67
Ph Me Me Me A81 Me Me Et Me A68
Ph Me Me Me A83 Me Me Et Me A69
Ph Me Me Me A88 Me Me Et Me A70
Ph Me Me Me A91 Me Me Et Me A71
Ph Me Me Me A97 Me Me Et Me A72
Ph Me Me Me A98 Me Me Et Me A73
Ph Me Me Me A102 Me Me Et Me A74
Ph Me Me Me A1 Me Me Et Me A75
Ph Me Me Me A13 Me Me Et Me A76
Ph Me Me Me A14 Me Me Et Me A77
Ph Me Me Me A15 Me Me Et Me A78
Ph Me Me Me A16 Me Me Et Me A79
Ph Me Me Me A20 Me Me Et Me A80
Ph Me Me Me A23 Me Me Et Me A81
Ph Me Me Me A24 Me Me Et Me A82
Ph Me Me Me A25 Me Me Et Me A83
Ph Me Me Me A26 Me Me Et Me A84
Ph Me Me Me A27 Me Me Et Me A85
Ph Me Me Me A28 Me Me Et Me A86
Ph Me Me Me A29 Me Me Et Me A87
Ph Me Me Me A34 Me Me Et Me A88
Ph Me Me Me A35 Me Me Et Me A89
Ph Me Me Me A36 Me Me Et Me A90
Ph Me Me Me A37 Me Me Et Me A91
Ph Me Me Me A42 Me Me Et Me A92
Ph Me Me Me A58 Me Me Et Me A93
Ph Me Me Me A63 Me Me Et Me A94
Ph Me Me Me A64 Me Me Et Me A95
Ph Me Me Me A65 Me Me Et Me A96
Ph Me Me Me A67 Me Me Et Me A97
Ph Me Me Me A69 Me Me Et Me A98
Ph Me Me Me A72 Me Me Et Me A99
Ph Me Me Me A73 Me Me Et Me A100
Ph Me Me Me A74 Me Me Et Me A101
――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ――――――――――――――――
Ph Me Me Me A75 Me Me Et Me A102
Ph Me Me Me A76 Me Me Et Me A103
Ph Me Me Me A77 Me Me Et Me A104
Ph Me Me Me A81 Me Me Et Me A105
Ph Me Me Me A83 Me Me Et Me A106
Ph Me Me Me A88 Me Me Et Me A107
Ph Me Me Me A91 Me Me Et Me A108
Ph Me Me Me A97 Me Me Et Me A109
Ph Me Me Me A98 Me Me Et Me A110
Ph Me Me Me A102 Me Me Et Me A111
Ph Me Me Me A112 Me Me Et Me A112
Ph Me Me Me A113 Me Me Et Me A113
Ph Me Me Me A114 Me Me Et Me A114
c-Pr Me Me Me H c-Pr Me Et Me H
c-Pr Me Me Me A1 c-Pr Me Et Me A1
c-Pr Me Me Me A2 c-Pr Me Et Me A2
c-Pr Me Me Me A3 c-Pr Me Et Me A3
c-Pr Me Me Me A4 c-Pr Me Et Me A4
c-Pr Me Me Me A5 c-Pr Me Et Me A5
c-Pr Me Me Me A6 c-Pr Me Et Me A6
c-Pr Me Me Me A7 c-Pr Me Et Me A7
c-Pr Me Me Me A8 c-Pr Me Et Me A8
c-Pr Me Me Me A9 c-Pr Me Et Me A9
c-Pr Me Me Me A10 c-Pr Me Et Me A10
c-Pr Me Me Me A11 c-Pr Me Et Me A11
c-Pr Me Me Me A12 c-Pr Me Et Me A12
c-Pr Me Me Me A13 c-Pr Me Et Me A13
c-Pr Me Me Me A14 c-Pr Me Et Me A14
c-Pr Me Me Me A15 c-Pr Me Et Me A15
c-Pr Me Me Me A16 c-Pr Me Et Me A16
c-Pr Me Me Me A17 c-Pr Me Et Me A17
c-Pr Me Me Me A18 c-Pr Me Et Me A18
c-Pr Me Me Me A19 c-Pr Me Et Me A19
c-Pr Me Me Me A20 c-Pr Me Et Me A20
c-Pr Me Me Me A21 c-Pr Me Et Me A21
c-Pr Me Me Me A22 c-Pr Me Et Me A22
c-Pr Me Me Me A23 c-Pr Me Et Me A23
c-Pr Me Me Me A24 c-Pr Me Et Me A24
c-Pr Me Me Me A25 c-Pr Me Et Me A25
――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ――――――――――――――――
c-Pr Me Me Me A26 c-Pr Me Et Me A26
c-Pr Me Me Me A27 c-Pr Me Et Me A27
c-Pr Me Me Me A28 c-Pr Me Et Me A28
c-Pr Me Me Me A29 c-Pr Me Et Me A29
c-Pr Me Me Me A30 c-Pr Me Et Me A30
c-Pr Me Me Me A31 c-Pr Me Et Me A31
c-Pr Me Me Me A32 c-Pr Me Et Me A32
c-Pr Me Me Me A33 c-Pr Me Et Me A33
c-Pr Me Me Me A34 c-Pr Me Et Me A34
c-Pr Me Me Me A35 c-Pr Me Et Me A35
c-Pr Me Me Me A36 c-Pr Me Et Me A36
c-Pr Me Me Me A37 c-Pr Me Et Me A37
c-Pr Me Me Me A38 c-Pr Me Et Me A38
c-Pr Me Me Me A39 c-Pr Me Et Me A39
c-Pr Me Me Me A40 c-Pr Me Et Me A40
c-Pr Me Me Me A41 c-Pr Me Et Me A41
c-Pr Me Me Me A42 c-Pr Me Et Me A42
c-Pr Me Me Me A43 c-Pr Me Et Me A43
c-Pr Me Me Me A44 c-Pr Me Et Me A44
c-Pr Me Me Me A45 c-Pr Me Et Me A45
c-Pr Me Me Me A46 c-Pr Me Et Me A46
c-Pr Me Me Me A47 c-Pr Me Et Me A47
c-Pr Me Me Me A48 c-Pr Me Et Me A48
c-Pr Me Me Me A49 c-Pr Me Et Me A49
c-Pr Me Me Me A50 c-Pr Me Et Me A50
c-Pr Me Me Me A51 c-Pr Me Et Me A51
c-Pr Me Me Me A52 c-Pr Me Et Me A52
c-Pr Me Me Me A53 c-Pr Me Et Me A53
c-Pr Me Me Me A54 c-Pr Me Et Me A54
c-Pr Me Me Me A55 c-Pr Me Et Me A55
c-Pr Me Me Me A56 c-Pr Me Et Me A56
c-Pr Me Me Me A57 c-Pr Me Et Me A57
c-Pr Me Me Me A58 c-Pr Me Et Me A58
c-Pr Me Me Me A59 c-Pr Me Et Me A59
c-Pr Me Me Me A60 c-Pr Me Et Me A60
c-Pr Me Me Me A61 c-Pr Me Et Me A61
c-Pr Me Me Me A62 c-Pr Me Et Me A62
c-Pr Me Me Me A63 c-Pr Me Et Me A63
c-Pr Me Me Me A64 c-Pr Me Et Me A64
――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ――――――――――――――――
c-Pr Me Me Me A65 c-Pr Me Et Me A65
c-Pr Me Me Me A66 c-Pr Me Et Me A66
c-Pr Me Me Me A67 c-Pr Me Et Me A67
c-Pr Me Me Me A68 c-Pr Me Et Me A68
c-Pr Me Me Me A69 c-Pr Me Et Me A69
c-Pr Me Me Me A70 c-Pr Me Et Me A70
c-Pr Me Me Me A71 c-Pr Me Et Me A71
c-Pr Me Me Me A72 c-Pr Me Et Me A72
c-Pr Me Me Me A73 c-Pr Me Et Me A73
c-Pr Me Me Me A74 c-Pr Me Et Me A74
c-Pr Me Me Me A75 c-Pr Me Et Me A75
c-Pr Me Me Me A76 c-Pr Me Et Me A76
c-Pr Me Me Me A77 c-Pr Me Et Me A77
c-Pr Me Me Me A78 c-Pr Me Et Me A78
c-Pr Me Me Me A79 c-Pr Me Et Me A79
c-Pr Me Me Me A80 c-Pr Me Et Me A80
c-Pr Me Me Me A81 c-Pr Me Et Me A81
c-Pr Me Me Me A82 c-Pr Me Et Me A82
c-Pr Me Me Me A83 c-Pr Me Et Me A83
c-Pr Me Me Me A84 c-Pr Me Et Me A84
c-Pr Me Me Me A85 c-Pr Me Et Me A85
c-Pr Me Me Me A86 c-Pr Me Et Me A86
c-Pr Me Me Me A87 c-Pr Me Et Me A87
c-Pr Me Me Me A88 c-Pr Me Et Me A88
c-Pr Me Me Me A89 c-Pr Me Et Me A89
c-Pr Me Me Me A90 c-Pr Me Et Me A90
c-Pr Me Me Me A91 c-Pr Me Et Me A91
c-Pr Me Me Me A92 c-Pr Me Et Me A92
c-Pr Me Me Me A93 c-Pr Me Et Me A93
c-Pr Me Me Me A94 c-Pr Me Et Me A94
c-Pr Me Me Me A95 c-Pr Me Et Me A95
c-Pr Me Me Me A96 c-Pr Me Et Me A96
c-Pr Me Me Me A97 c-Pr Me Et Me A97
c-Pr Me Me Me A98 c-Pr Me Et Me A98
c-Pr Me Me Me A99 c-Pr Me Et Me A99
c-Pr Me Me Me A100 c-Pr Me Et Me A100
c-Pr Me Me Me A101 c-Pr Me Et Me A101
c-Pr Me Me Me A102 c-Pr Me Et Me A102
c-Pr Me Me Me A103 c-Pr Me Et Me A103
――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ――――――――――――――――
c-Pr Me Me Me A104 c-Pr Me Et Me A104
c-Pr Me Me Me A105 c-Pr Me Et Me A105
c-Pr Me Me Me A106 c-Pr Me Et Me A106
c-Pr Me Me Me A107 c-Pr Me Et Me A107
c-Pr Me Me Me A108 c-Pr Me Et Me A108
c-Pr Me Me Me A109 c-Pr Me Et Me A109
c-Pr Me Me Me A110 c-Pr Me Et Me A110
c-Pr Me Me Me A111 c-Pr Me Et Me A111
c-Pr Me Me Me A112 c-Pr Me Et Me A112
c-Pr Me Me Me A113 c-Pr Me Et Me A113
c-Pr Me Me Me A114 c-Pr Me Et Me A114
D1-108b-1 Me Me Me H D1-108b-1 Me Et Me H
D1-108b-4 Me Me Me H D1-108b-4 Me Et Me H
D1-108b-8 Me Me Me H D1-108b-8 Me Et Me H
D1-108b-16 Me Me Me H D1-108b-16 Me Et Me H
D1-108b-17 Me Me Me H D1-108b-17 Me Et Me H
D1-108b-18 Me Me Me H D1-108b-18 Me Et Me H
D1-108b-19 Me Me Me H D1-108b-19 Me Et Me H
CH₂Pr-c Me Me Me H CH₂Pr-c Me Et Me H
CH₂Bu-c Me Me Me H CH₂Bu-c Me Et Me H
CH₂Pen-c Me Me Me H CH₂Pen-c Me Et Me H
CH₂Hex-c Me Me Me H CH₂Hex-c Me Et Me H
―――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ――――――――――――――――
Me Me Me c-Pr H Me Me Et c-Pr H
Me Me Me CH=CH₂ H Me Me Et CH=CH₂ H
Me Me Me CH=CHPr-n H Me Me Et CH=CHPr-n H
Me Me Me CH=CHPh H Me Me Et CH=CHPh H
Me Me Me C(O)Me H Me Me Et C(O)Me H
Me Me Me C(O)OMe H Me Me Et C(O)OMe H
Me Me Me C(=NOMe)Me H Me Me Et C(=NOMe)Me H
Me Me Me OH H Me Me Et OH H
Me Me Me OMe H Me Me Et OMe H
Me Me Me OCH₂CH₂OMe H Me Me Et OCH₂CH₂OMe H
Me Me Me OCH₂Ph H Me Me Et OCH₂Ph H
Me Me Me OCH₂(D1-34a) H Me Me Et OCH₂(D1-34a) H
Me Me Me OPh H Me Me Et OPh H
Me Me Me O(D1-32b-1) H Me Me Et O(D1-32b-1) H
Me Me Me Me A115 Me Me Et Me A115
Me Me Me SMe H Me Me Et SMe H
Me Me Me S(O)Me H Me Me Et S(O)Me H
Me Me Me S(O)₂Me H Me Me Et S(O)₂Me H
Me Me Me NHC(O)OBu-t H Me Me Et NHC(O)OBu-t H
―――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ――――――――――――――――
Me Me Me H H Me Me Et H H
Me Me Me Br A1 Me Me Et Br A1
Me Me Me Br A2 Me Me Et Br A2
Me Me Me Br A3 Me Me Et Br A3
Me Me Me Br A4 Me Me Et Br A4
Me Me Me Br A5 Me Me Et Br A5
Me Me Me Br A6 Me Me Et Br A6
Me Me Me Br A7 Me Me Et Br A7
Me Me Me Br A8 Me Me Et Br A8
Me Me Me Br A9 Me Me Et Br A9
Me Me Me Br A10 Me Me Et Br A10
Me Me Me Br A11 Me Me Et Br A11
Me Me Me Br A12 Me Me Et Br A12
Me Me Me Br A13 Me Me Et Br A13
Me Me Me Br A14 Me Me Et Br A14
Me Me Me Br A15 Me Me Et Br A15
Me Me Me Br A16 Me Me Et Br A16
Me Me Me Br A17 Me Me Et Br A17
Me Me Me Br A18 Me Me Et Br A18
Me Me Me Br A19 Me Me Et Br A19
Me Me Me Br A20 Me Me Et Br A20
Me Me Me Br A21 Me Me Et Br A21
Me Me Me Br A22 Me Me Et Br A22
Me Me Me Br A23 Me Me Et Br A23
Me Me Me Br A24 Me Me Et Br A24
Me Me Me Br A25 Me Me Et Br A25
Me Me Me Br A26 Me Me Et Br A26
Me Me Me Br A27 Me Me Et Br A27
Me Me Me Br A28 Me Me Et Br A28
Me Me Me Br A29 Me Me Et Br A29
Me Me Me Br A30 Me Me Et Br A30
Me Me Me Br A31 Me Me Et Br A31
Me Me Me Br A32 Me Me Et Br A32
Me Me Me Br A33 Me Me Et Br A33
Me Me Me Br A34 Me Me Et Br A34
Me Me Me Br A35 Me Me Et Br A35
Me Me Me Br A36 Me Me Et Br A36
―――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ――――――――――――――――
Me Me Me Br A37 Me Me Et Br A37
Me Me Me Br A38 Me Me Et Br A38
Me Me Me Br A39 Me Me Et Br A39
Me Me Me Br A40 Me Me Et Br A40
Me Me Me Br A41 Me Me Et Br A41
Me Me Me Br A42 Me Me Et Br A42
Me Me Me Br A43 Me Me Et Br A43
Me Me Me Br A44 Me Me Et Br A44
Me Me Me Br A45 Me Me Et Br A45
Me Me Me Br A46 Me Me Et Br A46
Me Me Me Br A47 Me Me Et Br A47
Me Me Me Br A48 Me Me Et Br A48
Me Me Me Br A49 Me Me Et Br A49
Me Me Me Br A50 Me Me Et Br A50
Me Me Me Br A51 Me Me Et Br A51
Me Me Me Br A52 Me Me Et Br A52
Me Me Me Br A53 Me Me Et Br A53
Me Me Me Br A54 Me Me Et Br A54
Me Me Me Br A55 Me Me Et Br A55
Me Me Me Br A56 Me Me Et Br A56
Me Me Me Br A57 Me Me Et Br A57
Me Me Me Br A58 Me Me Et Br A58
Me Me Me Br A59 Me Me Et Br A59
Me Me Me Br A60 Me Me Et Br A60
Me Me Me Br A61 Me Me Et Br A61
Me Me Me Br A62 Me Me Et Br A62
Me Me Me Br A63 Me Me Et Br A63
Me Me Me Br A64 Me Me Et Br A64
Me Me Me Br A65 Me Me Et Br A65
Me Me Me Br A66 Me Me Et Br A66
Me Me Me Br A67 Me Me Et Br A67
Me Me Me Br A68 Me Me Et Br A68
Me Me Me Br A69 Me Me Et Br A69
Me Me Me Br A70 Me Me Et Br A70
Me Me Me Br A71 Me Me Et Br A71
Me Me Me Br A72 Me Me Et Br A72
Me Me Me Br A73 Me Me Et Br A73
Me Me Me Br A74 Me Me Et Br A74
Me Me Me Br A75 Me Me Et Br A75
―――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ――――――――――――――――
Me Me Me Br A76 Me Me Et Br A76
Me Me Me Br A77 Me Me Et Br A77
Me Me Me Br A78 Me Me Et Br A78
Me Me Me Br A79 Me Me Et Br A79
Me Me Me Br A80 Me Me Et Br A80
Me Me Me Br A81 Me Me Et Br A81
Me Me Me Br A82 Me Me Et Br A82
Me Me Me Br A83 Me Me Et Br A83
Me Me Me Br A84 Me Me Et Br A84
Me Me Me Br A85 Me Me Et Br A85
Me Me Me Br A86 Me Me Et Br A86
Me Me Me Br A87 Me Me Et Br A87
Me Me Me Br A88 Me Me Et Br A88
Me Me Me Br A89 Me Me Et Br A89
Me Me Me Br A90 Me Me Et Br A90
Me Me Me Br A91 Me Me Et Br A91
Me Me Me Br A92 Me Me Et Br A92
Me Me Me Br A93 Me Me Et Br A93
Me Me Me Br A94 Me Me Et Br A94
Me Me Me Br A95 Me Me Et Br A95
Me Me Me Br A96 Me Me Et Br A96
Me Me Me Br A97 Me Me Et Br A97
Me Me Me Br A98 Me Me Et Br A98
Me Me Me Br A99 Me Me Et Br A99
Me Me Me Br A100 Me Me Et Br A100
Me Me Me Br A101 Me Me Et Br A101
Me Me Me Br A102 Me Me Et Br A102
Me Me Me Br A103 Me Me Et Br A103
Me Me Me Br A104 Me Me Et Br A104
Me Me Me Br A105 Me Me Et Br A105
Me Me Me Br A106 Me Me Et Br A106
Me Me Me Br A107 Me Me Et Br A107
Me Me Me Br A108 Me Me Et Br A108
Me Me Me Br A109 Me Me Et Br A109
Me Me Me Br A110 Me Me Et Br A110
Me Me Me Br A111 Me Me Et Br A111
Me Me Me Br A112 Me Me Et Br A112
Me Me Me Br A113 Me Me Et Br A113
Me Me Me Br A114 Me Me Et Br A114
Me Me Me Br A115 Me Me Et Br A115
Me Me Me Br A116 Me Me Et Br A116
―――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ――――――――――――――――
Me Et Et F H Me Me n-Pr F H
Me Et Et Cl H Me Me n-Pr Cl H
Me Et Et Br H Me Me n-Pr Br H
Me Et Et I H Me Me n-Pr I H
Me Et Et CN H Me Me n-Pr CN H
Me Et Et NO₂ H Me Me n-Pr NO₂ H
CH=CH₂ Et Et Me H CH=CH₂ Me n-Pr Me H
c-Bu Et Et Me H c-Bu Me n-Pr Me H
c-Pen Et Et Me H c-Pen Me n-Pr Me H
c-Hex Et Et Me H c-Hex Me n-Pr Me H
Ph Et Et Me H Ph Me n-Pr Me H
CF₃ Et Et Me H CF₃ Me n-Pr Me H
CH₂Cl Et Et Me H CH₂Cl Me n-Pr Me H
CH₂OMe Et Et Me H CH₂OMe Me n-Pr Me H
D1-32a Et Et Me H D1-32a Me n-Pr Me H
Me Et Et Me H Me Me n-Pr Me H
Me Et Et Me A1 Me Me n-Pr Me A1
Me Et Et Me A2 Me Me n-Pr Me A2
Me Et Et Me A3 Me Me n-Pr Me A3
Me Et Et Me A4 Me Me n-Pr Me A4
Me Et Et Me A5 Me Me n-Pr Me A5
Me Et Et Me A6 Me Me n-Pr Me A6
Me Et Et Me A7 Me Me n-Pr Me A7
Me Et Et Me A8 Me Me n-Pr Me A8
Me Et Et Me A9 Me Me n-Pr Me A9
Me Et Et Me A10 Me Me n-Pr Me A10
Me Et Et Me A11 Me Me n-Pr Me A11
Me Et Et Me A12 Me Me n-Pr Me A12
Me Et Et Me A13 Me Me n-Pr Me A13
Me Et Et Me A14 Me Me n-Pr Me A14
Me Et Et Me A15 Me Me n-Pr Me A15
Me Et Et Me A16 Me Me n-Pr Me A16
Me Et Et Me A17 Me Me n-Pr Me A17
Me Et Et Me A18 Me Me n-Pr Me A18
Me Et Et Me A19 Me Me n-Pr Me A19
Me Et Et Me A20 Me Me n-Pr Me A20
Me Et Et Me A21 Me Me n-Pr Me A21
Me Et Et Me A22 Me Me n-Pr Me A22
Me Et Et Me A23 Me Me n-Pr Me A23
―――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――― ――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――― ――――――――――――――
Me Et Et Me A24 Me Me n-Pr Me A24
Me Et Et Me A25 Me Me n-Pr Me A25
Me Et Et Me A26 Me Me n-Pr Me A26
Me Et Et Me A27 Me Me n-Pr Me A27
Me Et Et Me A28 Me Me n-Pr Me A28
Me Et Et Me A29 Me Me n-Pr Me A29
Me Et Et Me A30 Me Me n-Pr Me A30
Me Et Et Me A31 Me Me n-Pr Me A31
Me Et Et Me A32 Me Me n-Pr Me A32
Me Et Et Me A33 Me Me n-Pr Me A33
Me Et Et Me A34 Me Me n-Pr Me A34
Me Et Et Me A35 Me Me n-Pr Me A35
Me Et Et Me A36 Me Me n-Pr Me A36
Me Et Et Me A37 Me Me n-Pr Me A37
Me Et Et Me A38 Me Me n-Pr Me A38
Me Et Et Me A39 Me Me n-Pr Me A39
Me Et Et Me A40 Me Me n-Pr Me A40
Me Et Et Me A41 Me Me n-Pr Me A41
Me Et Et Me A42 Me Me n-Pr Me A42
Me Et Et Me A43 Me Me n-Pr Me A43
Me Et Et Me A44 Me Me n-Pr Me A44
Me Et Et Me A45 Me Me n-Pr Me A45
Me Et Et Me A46 Me Me n-Pr Me A46
Me Et Et Me A47 Me Me n-Pr Me A47
Me Et Et Me A48 Me Me n-Pr Me A48
Me Et Et Me A49 Me Me n-Pr Me A49
Me Et Et Me A50 Me Me n-Pr Me A50
Me Et Et Me A51 Me Me n-Pr Me A51
Me Et Et Me A52 Me Me n-Pr Me A52
Me Et Et Me A53 Me Me n-Pr Me A53
Me Et Et Me A54 Me Me n-Pr Me A54
Me Et Et Me A55 Me Me n-Pr Me A55
Me Et Et Me A56 Me Me n-Pr Me A56
Me Et Et Me A57 Me Me n-Pr Me A57
Me Et Et Me A58 Me Me n-Pr Me A58
Me Et Et Me A59 Me Me n-Pr Me A59
Me Et Et Me A60 Me Me n-Pr Me A60
Me Et Et Me A61 Me Me n-Pr Me A61
Me Et Et Me A62 Me Me n-Pr Me A62
―――――――――――――― ――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――― ――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――― ――――――――――――――
Me Et Et Me A63 Me Me n-Pr Me A63
Me Et Et Me A64 Me Me n-Pr Me A64
Me Et Et Me A65 Me Me n-Pr Me A65
Me Et Et Me A66 Me Me n-Pr Me A66
Me Et Et Me A67 Me Me n-Pr Me A67
Me Et Et Me A68 Me Me n-Pr Me A68
Me Et Et Me A69 Me Me n-Pr Me A69
Me Et Et Me A70 Me Me n-Pr Me A70
Me Et Et Me A71 Me Me n-Pr Me A71
Me Et Et Me A72 Me Me n-Pr Me A72
Me Et Et Me A73 Me Me n-Pr Me A73
Me Et Et Me A74 Me Me n-Pr Me A74
Me Et Et Me A75 Me Me n-Pr Me A75
Me Et Et Me A76 Me Me n-Pr Me A76
Me Et Et Me A77 Me Me n-Pr Me A77
Me Et Et Me A78 Me Me n-Pr Me A78
Me Et Et Me A79 Me Me n-Pr Me A79
Me Et Et Me A80 Me Me n-Pr Me A80
Me Et Et Me A81 Me Me n-Pr Me A81
Me Et Et Me A82 Me Me n-Pr Me A82
Me Et Et Me A83 Me Me n-Pr Me A83
Me Et Et Me A84 Me Me n-Pr Me A84
Me Et Et Me A85 Me Me n-Pr Me A85
Me Et Et Me A86 Me Me n-Pr Me A86
Me Et Et Me A87 Me Me n-Pr Me A87
Me Et Et Me A88 Me Me n-Pr Me A88
Me Et Et Me A89 Me Me n-Pr Me A89
Me Et Et Me A90 Me Me n-Pr Me A90
Me Et Et Me A91 Me Me n-Pr Me A91
Me Et Et Me A92 Me Me n-Pr Me A92
Me Et Et Me A93 Me Me n-Pr Me A93
Me Et Et Me A94 Me Me n-Pr Me A94
Me Et Et Me A95 Me Me n-Pr Me A95
Me Et Et Me A96 Me Me n-Pr Me A96
Me Et Et Me A97 Me Me n-Pr Me A97
Me Et Et Me A98 Me Me n-Pr Me A98
Me Et Et Me A99 Me Me n-Pr Me A99
Me Et Et Me A100 Me Me n-Pr Me A100
Me Et Et Me A101 Me Me n-Pr Me A101
―――――――――――――― ――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ―――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ―――――――――――――――
Me Et Et Me A102 Me Me n-Pr Me A102
Me Et Et Me A103 Me Me n-Pr Me A103
Me Et Et Me A104 Me Me n-Pr Me A104
Me Et Et Me A105 Me Me n-Pr Me A105
Me Et Et Me A106 Me Me n-Pr Me A106
Me Et Et Me A107 Me Me n-Pr Me A107
Me Et Et Me A108 Me Me n-Pr Me A108
Me Et Et Me A109 Me Me n-Pr Me A109
Me Et Et Me A110 Me Me n-Pr Me A110
Me Et Et Me A111 Me Me n-Pr Me A111
Me Et Et Me A112 Me Me n-Pr Me A112
Me Et Et Me A113 Me Me n-Pr Me A113
Me Et Et Me A114 Me Me n-Pr Me A114
c-Pr Et Et Me H c-Pr Me n-Pr Me H
c-Pr Et Et Me A1 c-Pr Me n-Pr Me A1
c-Pr Et Et Me A2 c-Pr Me n-Pr Me A2
c-Pr Et Et Me A3 c-Pr Me n-Pr Me A3
c-Pr Et Et Me A4 c-Pr Me n-Pr Me A4
c-Pr Et Et Me A5 c-Pr Me n-Pr Me A5
c-Pr Et Et Me A6 c-Pr Me n-Pr Me A6
c-Pr Et Et Me A7 c-Pr Me n-Pr Me A7
c-Pr Et Et Me A8 c-Pr Me n-Pr Me A8
c-Pr Et Et Me A9 c-Pr Me n-Pr Me A9
c-Pr Et Et Me A10 c-Pr Me n-Pr Me A10
c-Pr Et Et Me A11 c-Pr Me n-Pr Me A11
c-Pr Et Et Me A12 c-Pr Me n-Pr Me A12
c-Pr Et Et Me A13 c-Pr Me n-Pr Me A13
c-Pr Et Et Me A14 c-Pr Me n-Pr Me A14
c-Pr Et Et Me A15 c-Pr Me n-Pr Me A15
c-Pr Et Et Me A16 c-Pr Me n-Pr Me A16
c-Pr Et Et Me A17 c-Pr Me n-Pr Me A17
c-Pr Et Et Me A18 c-Pr Me n-Pr Me A18
c-Pr Et Et Me A19 c-Pr Me n-Pr Me A19
c-Pr Et Et Me A20 c-Pr Me n-Pr Me A20
c-Pr Et Et Me A21 c-Pr Me n-Pr Me A21
c-Pr Et Et Me A22 c-Pr Me n-Pr Me A22
c-Pr Et Et Me A23 c-Pr Me n-Pr Me A23
c-Pr Et Et Me A24 c-Pr Me n-Pr Me A24
c-Pr Et Et Me A25 c-Pr Me n-Pr Me A25
――――――――――――――― ―――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ―――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ―――――――――――――――
c-Pr Et Et Me A26 c-Pr Me n-Pr Me A26
c-Pr Et Et Me A27 c-Pr Me n-Pr Me A27
c-Pr Et Et Me A28 c-Pr Me n-Pr Me A28
c-Pr Et Et Me A29 c-Pr Me n-Pr Me A29
c-Pr Et Et Me A30 c-Pr Me n-Pr Me A30
c-Pr Et Et Me A31 c-Pr Me n-Pr Me A31
c-Pr Et Et Me A32 c-Pr Me n-Pr Me A32
c-Pr Et Et Me A33 c-Pr Me n-Pr Me A33
c-Pr Et Et Me A34 c-Pr Me n-Pr Me A34
c-Pr Et Et Me A35 c-Pr Me n-Pr Me A35
c-Pr Et Et Me A36 c-Pr Me n-Pr Me A36
c-Pr Et Et Me A37 c-Pr Me n-Pr Me A37
c-Pr Et Et Me A38 c-Pr Me n-Pr Me A38
c-Pr Et Et Me A39 c-Pr Me n-Pr Me A39
c-Pr Et Et Me A40 c-Pr Me n-Pr Me A40
c-Pr Et Et Me A41 c-Pr Me n-Pr Me A41
c-Pr Et Et Me A42 c-Pr Me n-Pr Me A42
c-Pr Et Et Me A43 c-Pr Me n-Pr Me A43
c-Pr Et Et Me A44 c-Pr Me n-Pr Me A44
c-Pr Et Et Me A45 c-Pr Me n-Pr Me A45
c-Pr Et Et Me A46 c-Pr Me n-Pr Me A46
c-Pr Et Et Me A47 c-Pr Me n-Pr Me A47
c-Pr Et Et Me A48 c-Pr Me n-Pr Me A48
c-Pr Et Et Me A49 c-Pr Me n-Pr Me A49
c-Pr Et Et Me A50 c-Pr Me n-Pr Me A50
c-Pr Et Et Me A51 c-Pr Me n-Pr Me A51
c-Pr Et Et Me A52 c-Pr Me n-Pr Me A52
c-Pr Et Et Me A53 c-Pr Me n-Pr Me A53
c-Pr Et Et Me A54 c-Pr Me n-Pr Me A54
c-Pr Et Et Me A55 c-Pr Me n-Pr Me A55
c-Pr Et Et Me A56 c-Pr Me n-Pr Me A56
c-Pr Et Et Me A57 c-Pr Me n-Pr Me A57
c-Pr Et Et Me A58 c-Pr Me n-Pr Me A58
c-Pr Et Et Me A59 c-Pr Me n-Pr Me A59
c-Pr Et Et Me A60 c-Pr Me n-Pr Me A60
c-Pr Et Et Me A61 c-Pr Me n-Pr Me A61
c-Pr Et Et Me A62 c-Pr Me n-Pr Me A62
c-Pr Et Et Me A63 c-Pr Me n-Pr Me A63
c-Pr Et Et Me A64 c-Pr Me n-Pr Me A64
――――――――――――――― ―――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ―――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ―――――――――――――――
c-Pr Et Et Me A65 c-Pr Me n-Pr Me A65
c-Pr Et Et Me A66 c-Pr Me n-Pr Me A66
c-Pr Et Et Me A67 c-Pr Me n-Pr Me A67
c-Pr Et Et Me A68 c-Pr Me n-Pr Me A68
c-Pr Et Et Me A69 c-Pr Me n-Pr Me A69
c-Pr Et Et Me A70 c-Pr Me n-Pr Me A70
c-Pr Et Et Me A71 c-Pr Me n-Pr Me A71
c-Pr Et Et Me A72 c-Pr Me n-Pr Me A72
c-Pr Et Et Me A73 c-Pr Me n-Pr Me A73
c-Pr Et Et Me A74 c-Pr Me n-Pr Me A74
c-Pr Et Et Me A75 c-Pr Me n-Pr Me A75
c-Pr Et Et Me A76 c-Pr Me n-Pr Me A76
c-Pr Et Et Me A77 c-Pr Me n-Pr Me A77
c-Pr Et Et Me A78 c-Pr Me n-Pr Me A78
c-Pr Et Et Me A79 c-Pr Me n-Pr Me A79
c-Pr Et Et Me A80 c-Pr Me n-Pr Me A80
c-Pr Et Et Me A81 c-Pr Me n-Pr Me A81
c-Pr Et Et Me A82 c-Pr Me n-Pr Me A82
c-Pr Et Et Me A83 c-Pr Me n-Pr Me A83
c-Pr Et Et Me A84 c-Pr Me n-Pr Me A84
c-Pr Et Et Me A85 c-Pr Me n-Pr Me A85
c-Pr Et Et Me A86 c-Pr Me n-Pr Me A86
c-Pr Et Et Me A87 c-Pr Me n-Pr Me A87
c-Pr Et Et Me A88 c-Pr Me n-Pr Me A88
c-Pr Et Et Me A89 c-Pr Me n-Pr Me A89
c-Pr Et Et Me A90 c-Pr Me n-Pr Me A90
c-Pr Et Et Me A91 c-Pr Me n-Pr Me A91
c-Pr Et Et Me A92 c-Pr Me n-Pr Me A92
c-Pr Et Et Me A93 c-Pr Me n-Pr Me A93
c-Pr Et Et Me A94 c-Pr Me n-Pr Me A94
c-Pr Et Et Me A95 c-Pr Me n-Pr Me A95
c-Pr Et Et Me A96 c-Pr Me n-Pr Me A96
c-Pr Et Et Me A97 c-Pr Me n-Pr Me A97
c-Pr Et Et Me A98 c-Pr Me n-Pr Me A98
c-Pr Et Et Me A99 c-Pr Me n-Pr Me A99
c-Pr Et Et Me A100 c-Pr Me n-Pr Me A100
c-Pr Et Et Me A101 c-Pr Me n-Pr Me A101
c-Pr Et Et Me A102 c-Pr Me n-Pr Me A102
c-Pr Et Et Me A103 c-Pr Me n-Pr Me A103
c-Pr Et Et Me A104 c-Pr Me n-Pr Me A104
c-Pr Et Et Me A105 c-Pr Me n-Pr Me A105
c-Pr Et Et Me A106 c-Pr Me n-Pr Me A106
c-Pr Et Et Me A107 c-Pr Me n-Pr Me A107
c-Pr Et Et Me A108 c-Pr Me n-Pr Me A108
c-Pr Et Et Me A109 c-Pr Me n-Pr Me A109
c-Pr Et Et Me A110 c-Pr Me n-Pr Me A110
c-Pr Et Et Me A111 c-Pr Me n-Pr Me A111
c-Pr Et Et Me A112 c-Pr Me n-Pr Me A112
c-Pr Et Et Me A113 c-Pr Me n-Pr Me A113
c-Pr Et Et Me A114 c-Pr Me n-Pr Me A114
――――――――――――――― ―――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
D1-108b-1 Et Et Me H D1-108b-1 Me n-Pr Me H
D1-108b-4 Et Et Me H D1-108b-4 Me n-Pr Me H
D1-108b-8 Et Et Me H D1-108b-8 Me n-Pr Me H
D1-108b-16 Et Et Me H D1-108b-16 Me n-Pr Me H
D1-108b-17 Et Et Me H D1-108b-17 Me n-Pr Me H
D1-108b-18 Et Et Me H D1-108b-18 Me n-Pr Me H
D1-108b-19 Et Et Me H D1-108b-19 Me n-Pr Me H
CH₂Pr-c Et Et Me H CH₂Pr-c Me n-Pr Me H
CH₂Bu-c Et Et Me H CH₂Bu-c Me n-Pr Me H
CH₂Pen-c Et Et Me H CH₂Pen-c Me n-Pr Me H
CH₂Hex-c Et Et Me H CH₂Hex-c Me n-Pr Me H
―――――――――――――――― ―――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et c-Pr H Me Me n-Pr c-Pr H
Me Et Et CH=CH₂ H Me Me n-Pr CH=CH₂ H
Me Et Et CH=CHPr-n H Me Me n-Pr CH=CHPr-n H
Me Et Et CH=CHPh H Me Me n-Pr CH=CHPh H
Me Et Et C(O)Me H Me Me n-Pr C(O)Me H
Me Et Et C(O)OMe H Me Me n-Pr C(O)OMe H
Me Et Et C(=NOMe)Me H Me Me n-Pr C(=NOMe)Me H
Me Et Et OH H Me Me n-Pr OH H
Me Et Et OMe H Me Me n-Pr OMe H
Me Et Et OCH₂CH₂OMe H Me Me n-Pr OCH₂CH₂OMe H
Me Et Et OCH₂Ph H Me Me n-Pr OCH₂Ph H
Me Et Et OCH₂(D1-34a) H Me Me n-Pr OCH₂(D1-34a) H
Me Et Et OPh H Me Me n-Pr OPh H
Me Et Et O(D1-32b-1) H Me Me n-Pr O(D1-32b-1) H
Me Et Et Me A115 Me Me n-Pr Me A115
Me Et Et SMe H Me Me n-Pr SMe H
Me Et Et S(O)Me H Me Me n-Pr S(O)Me H
Me Et Et S(O)₂Me H Me Me n-Pr S(O)₂Me H
Me Et Et NHC(O)OBu-t H Me Me n-Pr NHC(O)OBu-t H
―――――――――――――――― ―――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――― ―――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――― ―――――――――――――――
Me Et Et H H Me Me n-Pr H H
Me Et Et Br A1 Me Me n-Pr Br A1
Me Et Et Br A2 Me Me n-Pr Br A2
Me Et Et Br A3 Me Me n-Pr Br A3
Me Et Et Br A4 Me Me n-Pr Br A4
Me Et Et Br A5 Me Me n-Pr Br A5
Me Et Et Br A6 Me Me n-Pr Br A6
Me Et Et Br A7 Me Me n-Pr Br A7
Me Et Et Br A8 Me Me n-Pr Br A8
Me Et Et Br A9 Me Me n-Pr Br A9
Me Et Et Br A10 Me Me n-Pr Br A10
Me Et Et Br A11 Me Me n-Pr Br A11
Me Et Et Br A12 Me Me n-Pr Br A12
Me Et Et Br A13 Me Me n-Pr Br A13
Me Et Et Br A14 Me Me n-Pr Br A14
Me Et Et Br A15 Me Me n-Pr Br A15
Me Et Et Br A16 Me Me n-Pr Br A16
Me Et Et Br A17 Me Me n-Pr Br A17
Me Et Et Br A18 Me Me n-Pr Br A18
Me Et Et Br A19 Me Me n-Pr Br A19
Me Et Et Br A20 Me Me n-Pr Br A20
Me Et Et Br A21 Me Me n-Pr Br A21
Me Et Et Br A22 Me Me n-Pr Br A22
Me Et Et Br A23 Me Me n-Pr Br A23
Me Et Et Br A24 Me Me n-Pr Br A24
Me Et Et Br A25 Me Me n-Pr Br A25
Me Et Et Br A26 Me Me n-Pr Br A26
Me Et Et Br A27 Me Me n-Pr Br A27
Me Et Et Br A28 Me Me n-Pr Br A28
Me Et Et Br A29 Me Me n-Pr Br A29
Me Et Et Br A30 Me Me n-Pr Br A30
Me Et Et Br A31 Me Me n-Pr Br A31
Me Et Et Br A32 Me Me n-Pr Br A32
Me Et Et Br A33 Me Me n-Pr Br A33
Me Et Et Br A34 Me Me n-Pr Br A34
Me Et Et Br A35 Me Me n-Pr Br A35
Me Et Et Br A36 Me Me n-Pr Br A36
――――――――――――― ―――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――― ―――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――― ―――――――――――――――
Me Et Et Br A37 Me Me n-Pr Br A37
Me Et Et Br A38 Me Me n-Pr Br A38
Me Et Et Br A39 Me Me n-Pr Br A39
Me Et Et Br A40 Me Me n-Pr Br A40
Me Et Et Br A41 Me Me n-Pr Br A41
Me Et Et Br A42 Me Me n-Pr Br A42
Me Et Et Br A43 Me Me n-Pr Br A43
Me Et Et Br A44 Me Me n-Pr Br A44
Me Et Et Br A45 Me Me n-Pr Br A45
Me Et Et Br A46 Me Me n-Pr Br A46
Me Et Et Br A47 Me Me n-Pr Br A47
Me Et Et Br A48 Me Me n-Pr Br A48
Me Et Et Br A49 Me Me n-Pr Br A49
Me Et Et Br A50 Me Me n-Pr Br A50
Me Et Et Br A51 Me Me n-Pr Br A51
Me Et Et Br A52 Me Me n-Pr Br A52
Me Et Et Br A53 Me Me n-Pr Br A53
Me Et Et Br A54 Me Me n-Pr Br A54
Me Et Et Br A55 Me Me n-Pr Br A55
Me Et Et Br A56 Me Me n-Pr Br A56
Me Et Et Br A57 Me Me n-Pr Br A57
Me Et Et Br A58 Me Me n-Pr Br A58
Me Et Et Br A59 Me Me n-Pr Br A59
Me Et Et Br A60 Me Me n-Pr Br A60
Me Et Et Br A61 Me Me n-Pr Br A61
Me Et Et Br A62 Me Me n-Pr Br A62
Me Et Et Br A63 Me Me n-Pr Br A63
Me Et Et Br A64 Me Me n-Pr Br A64
Me Et Et Br A65 Me Me n-Pr Br A65
Me Et Et Br A66 Me Me n-Pr Br A66
Me Et Et Br A67 Me Me n-Pr Br A67
Me Et Et Br A68 Me Me n-Pr Br A68
Me Et Et Br A69 Me Me n-Pr Br A69
Me Et Et Br A70 Me Me n-Pr Br A70
Me Et Et Br A71 Me Me n-Pr Br A71
Me Et Et Br A72 Me Me n-Pr Br A72
Me Et Et Br A73 Me Me n-Pr Br A73
Me Et Et Br A74 Me Me n-Pr Br A74
Me Et Et Br A75 Me Me n-Pr Br A75
――――――――――――― ―――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――― ―――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――― ―――――――――――――――
Me Et Et Br A76 Me Me n-Pr Br A76
Me Et Et Br A77 Me Me n-Pr Br A77
Me Et Et Br A78 Me Me n-Pr Br A78
Me Et Et Br A79 Me Me n-Pr Br A79
Me Et Et Br A80 Me Me n-Pr Br A80
Me Et Et Br A81 Me Me n-Pr Br A81
Me Et Et Br A82 Me Me n-Pr Br A82
Me Et Et Br A83 Me Me n-Pr Br A83
Me Et Et Br A84 Me Me n-Pr Br A84
Me Et Et Br A85 Me Me n-Pr Br A85
Me Et Et Br A86 Me Me n-Pr Br A86
Me Et Et Br A87 Me Me n-Pr Br A87
Me Et Et Br A88 Me Me n-Pr Br A88
Me Et Et Br A89 Me Me n-Pr Br A89
Me Et Et Br A90 Me Me n-Pr Br A90
Me Et Et Br A91 Me Me n-Pr Br A91
Me Et Et Br A92 Me Me n-Pr Br A92
Me Et Et Br A93 Me Me n-Pr Br A93
Me Et Et Br A94 Me Me n-Pr Br A94
Me Et Et Br A95 Me Me n-Pr Br A95
Me Et Et Br A96 Me Me n-Pr Br A96
Me Et Et Br A97 Me Me n-Pr Br A97
Me Et Et Br A98 Me Me n-Pr Br A98
Me Et Et Br A99 Me Me n-Pr Br A99
Me Et Et Br A100 Me Me n-Pr Br A100
Me Et Et Br A101 Me Me n-Pr Br A101
Me Et Et Br A102 Me Me n-Pr Br A102
Me Et Et Br A103 Me Me n-Pr Br A103
Me Et Et Br A104 Me Me n-Pr Br A104
Me Et Et Br A105 Me Me n-Pr Br A105
Me Et Et Br A106 Me Me n-Pr Br A106
Me Et Et Br A107 Me Me n-Pr Br A107
Me Et Et Br A108 Me Me n-Pr Br A108
Me Et Et Br A109 Me Me n-Pr Br A109
Me Et Et Br A110 Me Me n-Pr Br A110
Me Et Et Br A111 Me Me n-Pr Br A111
Me Et Et Br A112 Me Me n-Pr Br A112
Me Et Et Br A113 Me Me n-Pr Br A113
Me Et Et Br A114 Me Me n-Pr Br A114
Me Et Et Br A115 Me Me n-Pr Br A115
Me Et Et Br A116 Me Me n-Pr Br A116
――――――――――――― ―――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――― ―――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――― ―――――――――――――
H Me Me F H H Et Et F H
H Me Me Cl H H Et Et Cl H
H Me Me Br H H Et Et Br H
H Me Me I H H Et Et I H
H Me Me CN H H Et Et CN H
H Me Me NO₂ H H Et Et NO₂ H
H Me Me Me H H Et Et Me H
H Me Me Me A1 H Et Et Me A1
H Me Me Me A2 H Et Et Me A2
H Me Me Me A3 H Et Et Me A3
H Me Me Me A4 H Et Et Me A4
H Me Me Me A5 H Et Et Me A5
H Me Me Me A6 H Et Et Me A6
H Me Me Me A7 H Et Et Me A7
H Me Me Me A8 H Et Et Me A8
H Me Me Me A9 H Et Et Me A9
H Me Me Me A10 H Et Et Me A10
H Me Me Me A11 H Et Et Me A11
H Me Me Me A12 H Et Et Me A12
H Me Me Me A13 H Et Et Me A13
H Me Me Me A14 H Et Et Me A14
H Me Me Me A15 H Et Et Me A15
H Me Me Me A16 H Et Et Me A16
H Me Me Me A17 H Et Et Me A17
H Me Me Me A18 H Et Et Me A18
H Me Me Me A19 H Et Et Me A19
H Me Me Me A20 H Et Et Me A20
H Me Me Me A21 H Et Et Me A21
H Me Me Me A22 H Et Et Me A22
H Me Me Me A23 H Et Et Me A23
H Me Me Me A24 H Et Et Me A24
H Me Me Me A25 H Et Et Me A25
H Me Me Me A26 H Et Et Me A26
H Me Me Me A27 H Et Et Me A27
H Me Me Me A28 H Et Et Me A28
H Me Me Me A29 H Et Et Me A29
H Me Me Me A30 H Et Et Me A30
H Me Me Me A31 H Et Et Me A31
H Me Me Me A32 H Et Et Me A32
――――――――――――― ―――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――― ―――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――― ―――――――――――――
H Me Me Me A33 H Et Et Me A33
H Me Me Me A34 H Et Et Me A34
H Me Me Me A35 H Et Et Me A35
H Me Me Me A36 H Et Et Me A36
H Me Me Me A37 H Et Et Me A37
H Me Me Me A38 H Et Et Me A38
H Me Me Me A39 H Et Et Me A39
H Me Me Me A40 H Et Et Me A40
H Me Me Me A41 H Et Et Me A41
H Me Me Me A42 H Et Et Me A42
H Me Me Me A43 H Et Et Me A43
H Me Me Me A44 H Et Et Me A44
H Me Me Me A45 H Et Et Me A45
H Me Me Me A46 H Et Et Me A46
H Me Me Me A47 H Et Et Me A47
H Me Me Me A48 H Et Et Me A48
H Me Me Me A49 H Et Et Me A49
H Me Me Me A50 H Et Et Me A50
H Me Me Me A51 H Et Et Me A51
H Me Me Me A52 H Et Et Me A52
H Me Me Me A53 H Et Et Me A53
H Me Me Me A54 H Et Et Me A54
H Me Me Me A55 H Et Et Me A55
H Me Me Me A56 H Et Et Me A56
H Me Me Me A57 H Et Et Me A57
H Me Me Me A58 H Et Et Me A58
H Me Me Me A59 H Et Et Me A59
H Me Me Me A60 H Et Et Me A60
H Me Me Me A61 H Et Et Me A61
H Me Me Me A62 H Et Et Me A62
H Me Me Me A63 H Et Et Me A63
H Me Me Me A64 H Et Et Me A64
H Me Me Me A65 H Et Et Me A65
H Me Me Me A66 H Et Et Me A66
H Me Me Me A67 H Et Et Me A67
H Me Me Me A68 H Et Et Me A68
H Me Me Me A69 H Et Et Me A69
H Me Me Me A70 H Et Et Me A70
H Me Me Me A71 H Et Et Me A71
――――――――――――― ―――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――― ―――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――― ―――――――――――――
H Me Me Me A72 H Et Et Me A72
H Me Me Me A73 H Et Et Me A73
H Me Me Me A74 H Et Et Me A74
H Me Me Me A75 H Et Et Me A75
H Me Me Me A76 H Et Et Me A76
H Me Me Me A77 H Et Et Me A77
H Me Me Me A78 H Et Et Me A78
H Me Me Me A79 H Et Et Me A79
H Me Me Me A80 H Et Et Me A80
H Me Me Me A81 H Et Et Me A81
H Me Me Me A82 H Et Et Me A82
H Me Me Me A83 H Et Et Me A83
H Me Me Me A84 H Et Et Me A84
H Me Me Me A85 H Et Et Me A85
H Me Me Me A86 H Et Et Me A86
H Me Me Me A87 H Et Et Me A87
H Me Me Me A88 H Et Et Me A88
H Me Me Me A89 H Et Et Me A89
H Me Me Me A90 H Et Et Me A90
H Me Me Me A91 H Et Et Me A91
H Me Me Me A92 H Et Et Me A92
H Me Me Me A93 H Et Et Me A93
H Me Me Me A94 H Et Et Me A94
H Me Me Me A95 H Et Et Me A95
H Me Me Me A96 H Et Et Me A96
H Me Me Me A97 H Et Et Me A97
H Me Me Me A98 H Et Et Me A98
H Me Me Me A99 H Et Et Me A99
H Me Me Me A100 H Et Et Me A100
H Me Me Me A101 H Et Et Me A101
H Me Me Me A102 H Et Et Me A102
H Me Me Me A103 H Et Et Me A103
H Me Me Me A104 H Et Et Me A104
H Me Me Me A105 H Et Et Me A105
H Me Me Me A106 H Et Et Me A106
―――――――――――― ―――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ――――――――――――――――
H Me Me c-Pr H H Et Et c-Pr H
H Me Me CH=CH₂ H H Et Et CH=CH₂ H
H Me Me CH=CHPr-n H H Et Et CH=CHPr-n H
H Me Me CH=CHPh H H Et Et CH=CHPh H
H Me Me C(O)Me H H Et Et C(O)Me H
H Me Me C(O)OMe H H Et Et C(O)OMe H
H Me Me C(=NOMe)Me H H Et Et C(=NOMe)Me H
H Me Me OH H H Et Et OH H
H Me Me OMe H H Et Et OMe H
H Me Me OCH₂CH₂OMe H H Et Et OCH₂CH₂OMe H
H Me Me OCH₂Ph H H Et Et OCH₂Ph H
H Me Me OCH₂(D1-34a) H H Et Et OCH₂(D1-34a) H
H Me Me OPh H H Et Et OPh H
H Me Me O(D1-32b-1) H H Et Et O(D1-32b-1) H
H Me Me OCH₂CF₃ H H Et Et OCH₂CF₃ H
H Me Me SMe H H Et Et SMe H
H Me Me S(O)Me H H Et Et S(O)Me H
H Me Me S(O)₂Me H H Et Et S(O)₂Me H
H Me Me NHC(O)OBu-t H H Et Et NHC(O)OBu-t H
――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――― ――――――――――――――――
Me Me Me Me A116 Me Et Et Me A116
Me Me Et Me A116 Me Me n-Pr Me A116
CF₃ Me Me Me A1 CH₂OMe Me Me Me A1
CF₃ Me Me Me A13 CH₂OMe Me Me Me A13
CF₃ Me Me Me A14 CH₂OMe Me Me Me A14
CF₃ Me Me Me A15 CH₂OMe Me Me Me A15
CF₃ Me Me Me A16 CH₂OMe Me Me Me A16
CF₃ Me Me Me A20 CH₂OMe Me Me Me A20
CF₃ Me Me Me A23 CH₂OMe Me Me Me A23
CF₃ Me Me Me A24 CH₂OMe Me Me Me A24
CF₃ Me Me Me A25 CH₂OMe Me Me Me A25
CF₃ Me Me Me A26 CH₂OMe Me Me Me A26
CF₃ Me Me Me A27 CH₂OMe Me Me Me A27
CF₃ Me Me Me A28 CH₂OMe Me Me Me A28
CF₃ Me Me Me A29 CH₂OMe Me Me Me A29
CF₃ Me Me Me A34 CH₂OMe Me Me Me A34
CF₃ Me Me Me A35 CH₂OMe Me Me Me A35
CF₃ Me Me Me A36 CH₂OMe Me Me Me A36
CF₃ Me Me Me A37 CH₂OMe Me Me Me A37
CF₃ Me Me Me A42 CH₂OMe Me Me Me A42
CF₃ Me Me Me A58 CH₂OMe Me Me Me A58
CF₃ Me Me Me A63 CH₂OMe Me Me Me A63
CF₃ Me Me Me A64 CH₂OMe Me Me Me A64
CF₃ Me Me Me A65 CH₂OMe Me Me Me A65
CF₃ Me Me Me A67 CH₂OMe Me Me Me A67
CF₃ Me Me Me A69 CH₂OMe Me Me Me A69
CF₃ Me Me Me A72 CH₂OMe Me Me Me A72
CF₃ Me Me Me A73 CH₂OMe Me Me Me A73
CF₃ Me Me Me A74 CH₂OMe Me Me Me A74
CF₃ Me Me Me A75 CH₂OMe Me Me Me A75
CF₃ Me Me Me A76 CH₂OMe Me Me Me A76
CF₃ Me Me Me A77 CH₂OMe Me Me Me A77
CF₃ Me Me Me A81 CH₂OMe Me Me Me A81
CF₃ Me Me Me A83 CH₂OMe Me Me Me A83
CF₃ Me Me Me A88 CH₂OMe Me Me Me A88
CF₃ Me Me Me A91 CH₂OMe Me Me Me A91
CF₃ Me Me Me A97 CH₂OMe Me Me Me A97
CF₃ Me Me Me A98 CH₂OMe Me Me Me A98
CF₃ Me Me Me A102 CH₂OMe Me Me Me A102
――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ――――――――――――――――
D1-32a Me Me Me A1 D1-108b-1 Me Me Me A1
D1-32a Me Me Me A13 D1-108b-1 Me Me Me A13
D1-32a Me Me Me A14 D1-108b-1 Me Me Me A14
D1-32a Me Me Me A15 D1-108b-1 Me Me Me A15
D1-32a Me Me Me A16 D1-108b-1 Me Me Me A16
D1-32a Me Me Me A20 D1-108b-1 Me Me Me A20
D1-32a Me Me Me A23 D1-108b-1 Me Me Me A23
D1-32a Me Me Me A24 D1-108b-1 Me Me Me A24
D1-32a Me Me Me A25 D1-108b-1 Me Me Me A25
D1-32a Me Me Me A26 D1-108b-1 Me Me Me A26
D1-32a Me Me Me A27 D1-108b-1 Me Me Me A27
D1-32a Me Me Me A28 D1-108b-1 Me Me Me A28
D1-32a Me Me Me A29 D1-108b-1 Me Me Me A29
D1-32a Me Me Me A34 D1-108b-1 Me Me Me A34
D1-32a Me Me Me A35 D1-108b-1 Me Me Me A35
D1-32a Me Me Me A36 D1-108b-1 Me Me Me A36
D1-32a Me Me Me A37 D1-108b-1 Me Me Me A37
D1-32a Me Me Me A42 D1-108b-1 Me Me Me A42
D1-32a Me Me Me A58 D1-108b-1 Me Me Me A58
D1-32a Me Me Me A63 D1-108b-1 Me Me Me A63
D1-32a Me Me Me A64 D1-108b-1 Me Me Me A64
D1-32a Me Me Me A65 D1-108b-1 Me Me Me A65
D1-32a Me Me Me A67 D1-108b-1 Me Me Me A67
D1-32a Me Me Me A69 D1-108b-1 Me Me Me A69
D1-32a Me Me Me A72 D1-108b-1 Me Me Me A72
D1-32a Me Me Me A73 D1-108b-1 Me Me Me A73
D1-32a Me Me Me A74 D1-108b-1 Me Me Me A74
D1-32a Me Me Me A75 D1-108b-1 Me Me Me A75
D1-32a Me Me Me A76 D1-108b-1 Me Me Me A76
D1-32a Me Me Me A77 D1-108b-1 Me Me Me A77
D1-32a Me Me Me A81 D1-108b-1 Me Me Me A81
D1-32a Me Me Me A83 D1-108b-1 Me Me Me A83
D1-32a Me Me Me A88 D1-108b-1 Me Me Me A88
D1-32a Me Me Me A91 D1-108b-1 Me Me Me A91
D1-32a Me Me Me A97 D1-108b-1 Me Me Me A97
D1-32a Me Me Me A98 D1-108b-1 Me Me Me A98
D1-32a Me Me Me A102 D1-108b-1 Me Me Me A102
――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ―――――――――――――――――
CH₂Pr-c Me Me Me A1 D1-108b-8 Me Me Me A1
CH₂Pr-c Me Me Me A13 D1-108b-8 Me Me Me A13
CH₂Pr-c Me Me Me A14 D1-108b-8 Me Me Me A14
CH₂Pr-c Me Me Me A15 D1-108b-8 Me Me Me A15
CH₂Pr-c Me Me Me A16 D1-108b-8 Me Me Me A16
CH₂Pr-c Me Me Me A20 D1-108b-8 Me Me Me A20
CH₂Pr-c Me Me Me A23 D1-108b-8 Me Me Me A23
CH₂Pr-c Me Me Me A24 D1-108b-8 Me Me Me A24
CH₂Pr-c Me Me Me A25 D1-108b-8 Me Me Me A25
CH₂Pr-c Me Me Me A26 D1-108b-8 Me Me Me A26
CH₂Pr-c Me Me Me A27 D1-108b-8 Me Me Me A27
CH₂Pr-c Me Me Me A28 D1-108b-8 Me Me Me A28
CH₂Pr-c Me Me Me A29 D1-108b-8 Me Me Me A29
CH₂Pr-c Me Me Me A34 D1-108b-8 Me Me Me A34
CH₂Pr-c Me Me Me A35 D1-108b-8 Me Me Me A35
CH₂Pr-c Me Me Me A36 D1-108b-8 Me Me Me A36
CH₂Pr-c Me Me Me A37 D1-108b-8 Me Me Me A37
CH₂Pr-c Me Me Me A42 D1-108b-8 Me Me Me A42
CH₂Pr-c Me Me Me A58 D1-108b-8 Me Me Me A58
CH₂Pr-c Me Me Me A63 D1-108b-8 Me Me Me A63
CH₂Pr-c Me Me Me A64 D1-108b-8 Me Me Me A64
CH₂Pr-c Me Me Me A65 D1-108b-8 Me Me Me A65
CH₂Pr-c Me Me Me A67 D1-108b-8 Me Me Me A67
CH₂Pr-c Me Me Me A69 D1-108b-8 Me Me Me A69
CH₂Pr-c Me Me Me A72 D1-108b-8 Me Me Me A72
CH₂Pr-c Me Me Me A73 D1-108b-8 Me Me Me A73
CH₂Pr-c Me Me Me A74 D1-108b-8 Me Me Me A74
CH₂Pr-c Me Me Me A75 D1-108b-8 Me Me Me A75
CH₂Pr-c Me Me Me A76 D1-108b-8 Me Me Me A76
CH₂Pr-c Me Me Me A77 D1-108b-8 Me Me Me A77
CH₂Pr-c Me Me Me A81 D1-108b-8 Me Me Me A81
CH₂Pr-c Me Me Me A83 D1-108b-8 Me Me Me A83
CH₂Pr-c Me Me Me A88 D1-108b-8 Me Me Me A88
CH₂Pr-c Me Me Me A91 D1-108b-8 Me Me Me A91
CH₂Pr-c Me Me Me A97 D1-108b-8 Me Me Me A97
CH₂Pr-c Me Me Me A98 D1-108b-8 Me Me Me A98
CH₂Pr-c Me Me Me A102 D1-108b-8 Me Me Me A102
――――――――――――――― ―――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
D1-108b-4 Me Me Me A1 Me Me Me CN A1
D1-108b-4 Me Me Me A13 Me Me Me CN A13
D1-108b-4 Me Me Me A14 Me Me Me CN A14
D1-108b-4 Me Me Me A15 Me Me Me CN A15
D1-108b-4 Me Me Me A16 Me Me Me CN A16
D1-108b-4 Me Me Me A20 Me Me Me CN A20
D1-108b-4 Me Me Me A23 Me Me Me CN A23
D1-108b-4 Me Me Me A24 Me Me Me CN A24
D1-108b-4 Me Me Me A25 Me Me Me CN A25
D1-108b-4 Me Me Me A26 Me Me Me CN A26
D1-108b-4 Me Me Me A27 Me Me Me CN A27
D1-108b-4 Me Me Me A28 Me Me Me CN A28
D1-108b-4 Me Me Me A29 Me Me Me CN A29
D1-108b-4 Me Me Me A34 Me Me Me CN A34
D1-108b-4 Me Me Me A35 Me Me Me CN A35
D1-108b-4 Me Me Me A36 Me Me Me CN A36
D1-108b-4 Me Me Me A37 Me Me Me CN A37
D1-108b-4 Me Me Me A42 Me Me Me CN A42
D1-108b-4 Me Me Me A58 Me Me Me CN A58
D1-108b-4 Me Me Me A63 Me Me Me CN A63
D1-108b-4 Me Me Me A64 Me Me Me CN A64
D1-108b-4 Me Me Me A65 Me Me Me CN A65
D1-108b-4 Me Me Me A67 Me Me Me CN A67
D1-108b-4 Me Me Me A69 Me Me Me CN A69
D1-108b-4 Me Me Me A72 Me Me Me CN A72
D1-108b-4 Me Me Me A73 Me Me Me CN A73
D1-108b-4 Me Me Me A74 Me Me Me CN A74
D1-108b-4 Me Me Me A75 Me Me Me CN A75
D1-108b-4 Me Me Me A76 D1-108b-8 Me Me CN A76
D1-108b-4 Me Me Me A77 D1-108b-8 Me Me CN A77
D1-108b-4 Me Me Me A81 D1-108b-8 Me Me CN A81
D1-108b-4 Me Me Me A83 D1-108b-8 Me Me CN A83
D1-108b-4 Me Me Me A88 D1-108b-8 Me Me CN A88
D1-108b-4 Me Me Me A91 D1-108b-8 Me Me CN A91
D1-108b-4 Me Me Me A97 D1-108b-8 Me Me CN A97
D1-108b-4 Me Me Me A98 D1-108b-8 Me Me CN A98
D1-108b-4 Me Me Me A102 D1-108b-8 Me Me CN A102
―――――――――――――――― ―――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――― ―――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――― ―――――――――――――――
Me Me Me NO₂ A1 Me Me Me c-Pr A1
Me Me Me NO₂ A13 Me Me Me c-Pr A13
Me Me Me NO₂ A14 Me Me Me c-Pr A14
Me Me Me NO₂ A15 Me Me Me c-Pr A15
Me Me Me NO₂ A16 Me Me Me c-Pr A16
Me Me Me NO₂ A20 Me Me Me c-Pr A20
Me Me Me NO₂ A23 Me Me Me c-Pr A23
Me Me Me NO₂ A24 Me Me Me c-Pr A24
Me Me Me NO₂ A25 Me Me Me c-Pr A25
Me Me Me NO₂ A26 Me Me Me c-Pr A26
Me Me Me NO₂ A27 Me Me Me c-Pr A27
Me Me Me NO₂ A28 Me Me Me c-Pr A28
Me Me Me NO₂ A29 Me Me Me c-Pr A29
Me Me Me NO₂ A34 Me Me Me c-Pr A34
Me Me Me NO₂ A35 Me Me Me c-Pr A35
Me Me Me NO₂ A36 Me Me Me c-Pr A36
Me Me Me NO₂ A37 Me Me Me c-Pr A37
Me Me Me NO₂ A42 Me Me Me c-Pr A42
Me Me Me NO₂ A58 Me Me Me c-Pr A58
Me Me Me NO₂ A63 Me Me Me c-Pr A63
Me Me Me NO₂ A64 Me Me Me c-Pr A64
Me Me Me NO₂ A65 Me Me Me c-Pr A65
Me Me Me NO₂ A67 Me Me Me c-Pr A67
Me Me Me NO₂ A69 Me Me Me c-Pr A69
Me Me Me NO₂ A72 Me Me Me c-Pr A72
Me Me Me NO₂ A73 Me Me Me c-Pr A73
Me Me Me NO₂ A74 Me Me Me c-Pr A74
Me Me Me NO₂ A75 Me Me Me c-Pr A75
Me Me Me NO₂ A76 Me Me Me c-Pr A76
Me Me Me NO₂ A77 Me Me Me c-Pr A77
Me Me Me NO₂ A81 Me Me Me c-Pr A81
Me Me Me NO₂ A83 Me Me Me c-Pr A83
Me Me Me NO₂ A88 Me Me Me c-Pr A88
Me Me Me NO₂ A91 Me Me Me c-Pr A91
Me Me Me NO₂ A97 Me Me Me c-Pr A97
Me Me Me NO₂ A98 Me Me Me c-Pr A98
Me Me Me NO₂ A102 Me Me Me c-Pr A102
――――――――――――― ―――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ――――――――――――――――
Me Me Me CH=CH₂ A1 Me Me Me CH=CHPh A1
Me Me Me CH=CH₂ A13 Me Me Me CH=CHPh A13
Me Me Me CH=CH₂ A14 Me Me Me CH=CHPh A14
Me Me Me CH=CH₂ A15 Me Me Me CH=CHPh A15
Me Me Me CH=CH₂ A16 Me Me Me CH=CHPh A16
Me Me Me CH=CH₂ A20 Me Me Me CH=CHPh A20
Me Me Me CH=CH₂ A23 Me Me Me CH=CHPh A23
Me Me Me CH=CH₂ A24 Me Me Me CH=CHPh A24
Me Me Me CH=CH₂ A25 Me Me Me CH=CHPh A25
Me Me Me CH=CH₂ A26 Me Me Me CH=CHPh A26
Me Me Me CH=CH₂ A27 Me Me Me CH=CHPh A27
Me Me Me CH=CH₂ A28 Me Me Me CH=CHPh A28
Me Me Me CH=CH₂ A29 Me Me Me CH=CHPh A29
Me Me Me CH=CH₂ A34 Me Me Me CH=CHPh A34
Me Me Me CH=CH₂ A35 Me Me Me CH=CHPh A35
Me Me Me CH=CH₂ A36 Me Me Me CH=CHPh A36
Me Me Me CH=CH₂ A37 Me Me Me CH=CHPh A37
Me Me Me CH=CH₂ A42 Me Me Me CH=CHPh A42
Me Me Me CH=CH₂ A58 Me Me Me CH=CHPh A58
Me Me Me CH=CH₂ A63 Me Me Me CH=CHPh A63
Me Me Me CH=CH₂ A64 Me Me Me CH=CHPh A64
Me Me Me CH=CH₂ A65 Me Me Me CH=CHPh A65
Me Me Me CH=CH₂ A67 Me Me Me CH=CHPh A67
Me Me Me CH=CH₂ A69 Me Me Me CH=CHPh A69
Me Me Me CH=CH₂ A72 Me Me Me CH=CHPh A72
Me Me Me CH=CH₂ A73 Me Me Me CH=CHPh A73
Me Me Me CH=CH₂ A74 Me Me Me CH=CHPh A74
Me Me Me CH=CH₂ A75 Me Me Me CH=CHPh A75
Me Me Me CH=CH₂ A76 Me Me Me CH=CHPh A76
Me Me Me CH=CH₂ A77 Me Me Me CH=CHPh A77
Me Me Me CH=CH₂ A81 Me Me Me CH=CHPh A81
Me Me Me CH=CH₂ A83 Me Me Me CH=CHPh A83
Me Me Me CH=CH₂ A88 Me Me Me CH=CHPh A88
Me Me Me CH=CH₂ A91 Me Me Me CH=CHPh A91
Me Me Me CH=CH₂ A97 Me Me Me CH=CHPh A97
Me Me Me CH=CH₂ A98 Me Me Me CH=CHPh A98
Me Me Me CH=CH₂ A102 Me Me Me CH=CHPh A102
――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ――――――――――――――――
Me Me Me C(O)Me A1 Me Me Me C(O)OMe A1
Me Me Me C(O)Me A13 Me Me Me C(O)OMe A13
Me Me Me C(O)Me A14 Me Me Me C(O)OMe A14
Me Me Me C(O)Me A15 Me Me Me C(O)OMe A15
Me Me Me C(O)Me A16 Me Me Me C(O)OMe A16
Me Me Me C(O)Me A20 Me Me Me C(O)OMe A20
Me Me Me C(O)Me A23 Me Me Me C(O)OMe A23
Me Me Me C(O)Me A24 Me Me Me C(O)OMe A24
Me Me Me C(O)Me A25 Me Me Me C(O)OMe A25
Me Me Me C(O)Me A26 Me Me Me C(O)OMe A26
Me Me Me C(O)Me A27 Me Me Me C(O)OMe A27
Me Me Me C(O)Me A28 Me Me Me C(O)OMe A28
Me Me Me C(O)Me A29 Me Me Me C(O)OMe A29
Me Me Me C(O)Me A34 Me Me Me C(O)OMe A34
Me Me Me C(O)Me A35 Me Me Me C(O)OMe A35
Me Me Me C(O)Me A36 Me Me Me C(O)OMe A36
Me Me Me C(O)Me A37 Me Me Me C(O)OMe A37
Me Me Me C(O)Me A42 Me Me Me C(O)OMe A42
Me Me Me C(O)Me A58 Me Me Me C(O)OMe A58
Me Me Me C(O)Me A63 Me Me Me C(O)OMe A63
Me Me Me C(O)Me A64 Me Me Me C(O)OMe A64
Me Me Me C(O)Me A65 Me Me Me C(O)OMe A65
Me Me Me C(O)Me A67 Me Me Me C(O)OMe A67
Me Me Me C(O)Me A69 Me Me Me C(O)OMe A69
Me Me Me C(O)Me A72 Me Me Me C(O)OMe A72
Me Me Me C(O)Me A73 Me Me Me C(O)OMe A73
Me Me Me C(O)Me A74 Me Me Me C(O)OMe A74
Me Me Me C(O)Me A75 Me Me Me C(O)OMe A75
Me Me Me C(O)Me A76 Me Me Me C(O)OMe A76
Me Me Me C(O)Me A77 Me Me Me C(O)OMe A77
Me Me Me C(O)Me A81 Me Me Me C(O)OMe A81
Me Me Me C(O)Me A83 Me Me Me C(O)OMe A83
Me Me Me C(O)Me A88 Me Me Me C(O)OMe A88
Me Me Me C(O)Me A91 Me Me Me C(O)OMe A91
Me Me Me C(O)Me A97 Me Me Me C(O)OMe A97
Me Me Me C(O)Me A98 Me Me Me C(O)OMe A98
――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ――――――――――――――――
Me Me Me C(=NOMe)Me A1 Me Me Me OH A1
Me Me Me C(=NOMe)Me A13 Me Me Me OH A13
Me Me Me C(=NOMe)Me A14 Me Me Me OH A14
Me Me Me C(=NOMe)Me A15 Me Me Me OH A15
Me Me Me C(=NOMe)Me A16 Me Me Me OH A16
Me Me Me C(=NOMe)Me A20 Me Me Me OH A20
Me Me Me C(=NOMe)Me A23 Me Me Me OH A23
Me Me Me C(=NOMe)Me A24 Me Me Me OH A24
Me Me Me C(=NOMe)Me A25 Me Me Me OH A25
Me Me Me C(=NOMe)Me A26 Me Me Me OH A26
Me Me Me C(=NOMe)Me A27 Me Me Me OH A27
Me Me Me C(=NOMe)Me A28 Me Me Me OH A28
Me Me Me C(=NOMe)Me A29 Me Me Me OH A29
Me Me Me C(=NOMe)Me A34 Me Me Me OH A34
Me Me Me C(=NOMe)Me A35 Me Me Me OH A35
Me Me Me C(=NOMe)Me A36 Me Me Me OH A36
Me Me Me C(=NOMe)Me A37 Me Me Me OH A37
Me Me Me C(=NOMe)Me A42 Me Me Me OH A42
Me Me Me C(=NOMe)Me A58 Me Me Me OH A58
Me Me Me C(=NOMe)Me A63 Me Me Me OH A63
Me Me Me C(=NOMe)Me A64 Me Me Me OH A64
Me Me Me C(=NOMe)Me A65 Me Me Me OH A65
Me Me Me C(=NOMe)Me A67 Me Me Me OH A67
Me Me Me C(=NOMe)Me A69 Me Me Me OH A69
Me Me Me C(=NOMe)Me A72 Me Me Me OH A72
Me Me Me C(=NOMe)Me A73 Me Me Me OH A73
Me Me Me C(=NOMe)Me A74 Me Me Me OH A74
Me Me Me C(=NOMe)Me A75 Me Me Me OH A75
Me Me Me C(=NOMe)Me A76 Me Me Me OH A76
Me Me Me C(=NOMe)Me A77 Me Me Me OH A77
Me Me Me C(=NOMe)Me A81 Me Me Me OH A81
Me Me Me C(=NOMe)Me A83 Me Me Me OH A83
Me Me Me C(=NOMe)Me A88 Me Me Me OH A88
Me Me Me C(=NOMe)Me A91 Me Me Me OH A91
Me Me Me C(=NOMe)Me A97 Me Me Me OH A97
Me Me Me C(=NOMe)Me A98 Me Me Me OH A98
Me Me Me C(=NOMe)Me A102 Me Me Me OH A102
―――――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――― ――――――――――――――――
Me Me Me OMe A1 Me Me Me OCH₂OMe A1
Me Me Me OMe A13 Me Me Me OCH₂OMe A13
Me Me Me OMe A14 Me Me Me OCH₂OMe A14
Me Me Me OMe A15 Me Me Me OCH₂OMe A15
Me Me Me OMe A16 Me Me Me OCH₂OMe A16
Me Me Me OMe A20 Me Me Me OCH₂OMe A20
Me Me Me OMe A23 Me Me Me OCH₂OMe A23
Me Me Me OMe A24 Me Me Me OCH₂OMe A24
Me Me Me OMe A25 Me Me Me OCH₂OMe A25
Me Me Me OMe A26 Me Me Me OCH₂OMe A26
Me Me Me OMe A27 Me Me Me OCH₂OMe A27
Me Me Me OMe A28 Me Me Me OCH₂OMe A28
Me Me Me OMe A29 Me Me Me OCH₂OMe A29
Me Me Me OMe A34 Me Me Me OCH₂OMe A34
Me Me Me OMe A35 Me Me Me OCH₂OMe A35
Me Me Me OMe A36 Me Me Me OCH₂OMe A36
Me Me Me OMe A37 Me Me Me OCH₂OMe A37
Me Me Me OMe A42 Me Me Me OCH₂OMe A42
Me Me Me OMe A58 Me Me Me OCH₂OMe A58
Me Me Me OMe A63 Me Me Me OCH₂OMe A63
Me Me Me OMe A64 Me Me Me OCH₂OMe A64
Me Me Me OMe A65 Me Me Me OCH₂OMe A65
Me Me Me OMe A67 Me Me Me OCH₂OMe A67
Me Me Me OMe A69 Me Me Me OCH₂OMe A69
Me Me Me OMe A72 Me Me Me OCH₂OMe A72
Me Me Me OMe A73 Me Me Me OCH₂OMe A73
Me Me Me OMe A74 Me Me Me OCH₂OMe A74
Me Me Me OMe A75 Me Me Me OCH₂OMe A75
Me Me Me OMe A76 Me Me Me OCH₂OMe A76
Me Me Me OMe A77 Me Me Me OCH₂OMe A77
Me Me Me OMe A81 Me Me Me OCH₂OMe A81
Me Me Me OMe A83 Me Me Me OCH₂OMe A83
Me Me Me OMe A88 Me Me Me OCH₂OMe A88
Me Me Me OMe A91 Me Me Me OCH₂OMe A91
Me Me Me OMe A97 Me Me Me OCH₂OMe A97
Me Me Me OMe A98 Me Me Me OCH₂OMe A98
Me Me Me OMe A102 Me Me Me OCH₂OMe A102
―――――――――――――― ――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ――――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ――――――――――――――――――
Me Me Me OCH₂Ph A1 Me Me Me OCH₂(D1-34a) A1
Me Me Me OCH₂Ph A13 Me Me Me OCH₂(D1-34a) A13
Me Me Me OCH₂Ph A14 Me Me Me OCH₂(D1-34a) A14
Me Me Me OCH₂Ph A15 Me Me Me OCH₂(D1-34a) A15
Me Me Me OCH₂Ph A16 Me Me Me OCH₂(D1-34a) A16
Me Me Me OCH₂Ph A20 Me Me Me OCH₂(D1-34a) A20
Me Me Me OCH₂Ph A23 Me Me Me OCH₂(D1-34a) A23
Me Me Me OCH₂Ph A24 Me Me Me OCH₂(D1-34a) A24
Me Me Me OCH₂Ph A25 Me Me Me OCH₂(D1-34a) A25
Me Me Me OCH₂Ph A26 Me Me Me OCH₂(D1-34a) A26
Me Me Me OCH₂Ph A27 Me Me Me OCH₂(D1-34a) A27
Me Me Me OCH₂Ph A28 Me Me Me OCH₂(D1-34a) A28
Me Me Me OCH₂Ph A29 Me Me Me OCH₂(D1-34a) A29
Me Me Me OCH₂Ph A34 Me Me Me OCH₂(D1-34a) A34
Me Me Me OCH₂Ph A35 Me Me Me OCH₂(D1-34a) A35
Me Me Me OCH₂Ph A36 Me Me Me OCH₂(D1-34a) A36
Me Me Me OCH₂Ph A37 Me Me Me OCH₂(D1-34a) A37
Me Me Me OCH₂Ph A42 Me Me Me OCH₂(D1-34a) A42
Me Me Me OCH₂Ph A58 Me Me Me OCH₂(D1-34a) A58
Me Me Me OCH₂Ph A63 Me Me Me OCH₂(D1-34a) A63
Me Me Me OCH₂Ph A64 Me Me Me OCH₂(D1-34a) A64
Me Me Me OCH₂Ph A65 Me Me Me OCH₂(D1-34a) A65
Me Me Me OCH₂Ph A67 Me Me Me OCH₂(D1-34a) A67
Me Me Me OCH₂Ph A69 Me Me Me OCH₂(D1-34a) A69
Me Me Me OCH₂Ph A72 Me Me Me OCH₂(D1-34a) A72
Me Me Me OCH₂Ph A73 Me Me Me OCH₂(D1-34a) A73
Me Me Me OCH₂Ph A74 Me Me Me OCH₂(D1-34a) A74
Me Me Me OCH₂Ph A75 Me Me Me OCH₂(D1-34a) A75
Me Me Me OCH₂Ph A76 Me Me Me OCH₂(D1-34a) A76
Me Me Me OCH₂Ph A77 Me Me Me OCH₂(D1-34a) A77
Me Me Me OCH₂Ph A81 Me Me Me OCH₂(D1-34a) A81
Me Me Me OCH₂Ph A83 Me Me Me OCH₂(D1-34a) A83
Me Me Me OCH₂Ph A88 Me Me Me OCH₂(D1-34a) A88
Me Me Me OCH₂Ph A91 Me Me Me OCH₂(D1-34a) A91
Me Me Me OCH₂Ph A97 Me Me Me OCH₂(D1-34a) A97
Me Me Me OCH₂Ph A98 Me Me Me OCH₂(D1-34a) A98
Me Me Me OCH₂Ph A102 Me Me Me OCH₂(D1-34a) A102
――――――――――――――― ――――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――― ――――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――― ――――――――――――――――――
Me Me Me OPh A1 Me Me Me O(D1-32b-1) A1
Me Me Me OPh A13 Me Me Me O(D1-32b-1) A13
Me Me Me OPh A14 Me Me Me O(D1-32b-1) A14
Me Me Me OPh A15 Me Me Me O(D1-32b-1) A15
Me Me Me OPh A16 Me Me Me O(D1-32b-1) A16
Me Me Me OPh A20 Me Me Me O(D1-32b-1) A20
Me Me Me OPh A23 Me Me Me O(D1-32b-1) A23
Me Me Me OPh A24 Me Me Me O(D1-32b-1) A24
Me Me Me OPh A25 Me Me Me O(D1-32b-1) A25
Me Me Me OPh A26 Me Me Me O(D1-32b-1) A26
Me Me Me OPh A27 Me Me Me O(D1-32b-1) A27
Me Me Me OPh A28 Me Me Me O(D1-32b-1) A28
Me Me Me OPh A29 Me Me Me O(D1-32b-1) A29
Me Me Me OPh A34 Me Me Me O(D1-32b-1) A34
Me Me Me OPh A35 Me Me Me O(D1-32b-1) A35
Me Me Me OPh A36 Me Me Me O(D1-32b-1) A36
Me Me Me OPh A37 Me Me Me O(D1-32b-1) A37
Me Me Me OPh A42 Me Me Me O(D1-32b-1) A42
Me Me Me OPh A58 Me Me Me O(D1-32b-1) A58
Me Me Me OPh A63 Me Me Me O(D1-32b-1) A63
Me Me Me OPh A64 Me Me Me O(D1-32b-1) A64
Me Me Me OPh A65 Me Me Me O(D1-32b-1) A65
Me Me Me OPh A67 Me Me Me O(D1-32b-1) A67
Me Me Me OPh A69 Me Me Me O(D1-32b-1) A69
Me Me Me OPh A72 Me Me Me O(D1-32b-1) A72
Me Me Me OPh A73 Me Me Me O(D1-32b-1) A73
Me Me Me OPh A74 Me Me Me O(D1-32b-1) A74
Me Me Me OPh A75 Me Me Me O(D1-32b-1) A75
Me Me Me OPh A76 Me Me Me O(D1-32b-1) A76
Me Me Me OPh A77 Me Me Me O(D1-32b-1) A77
Me Me Me OPh A81 Me Me Me O(D1-32b-1) A81
Me Me Me OPh A83 Me Me Me O(D1-32b-1) A83
Me Me Me OPh A88 Me Me Me O(D1-32b-1) A88
Me Me Me OPh A91 Me Me Me O(D1-32b-1) A91
Me Me Me OPh A97 Me Me Me O(D1-32b-1) A97
Me Me Me OPh A98 Me Me Me O(D1-32b-1) A98
Me Me Me OPh A102 Me Me Me O(D1-32b-1) A102
――――――――――――― ――――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――― ――――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――― ――――――――――――――――――
Me Me Me SMe A1 Me Me Me NHC(O)OBu-t A1
Me Me Me SMe A13 Me Me Me NHC(O)OBu-t A13
Me Me Me SMe A14 Me Me Me NHC(O)OBu-t A14
Me Me Me SMe A15 Me Me Me NHC(O)OBu-t A15
Me Me Me SMe A16 Me Me Me NHC(O)OBu-t A16
Me Me Me SMe A20 Me Me Me NHC(O)OBu-t A20
Me Me Me SMe A23 Me Me Me NHC(O)OBu-t A23
Me Me Me SMe A24 Me Me Me NHC(O)OBu-t A24
Me Me Me SMe A25 Me Me Me NHC(O)OBu-t A25
Me Me Me SMe A26 Me Me Me NHC(O)OBu-t A26
Me Me Me SMe A27 Me Me Me NHC(O)OBu-t A27
Me Me Me SMe A28 Me Me Me NHC(O)OBu-t A28
Me Me Me SMe A29 Me Me Me NHC(O)OBu-t A29
Me Me Me SMe A34 Me Me Me NHC(O)OBu-t A34
Me Me Me SMe A35 Me Me Me NHC(O)OBu-t A35
Me Me Me SMe A36 Me Me Me NHC(O)OBu-t A36
Me Me Me SMe A37 Me Me Me NHC(O)OBu-t A37
Me Me Me SMe A42 Me Me Me NHC(O)OBu-t A42
Me Me Me SMe A58 Me Me Me NHC(O)OBu-t A58
Me Me Me SMe A63 Me Me Me NHC(O)OBu-t A63
Me Me Me SMe A64 Me Me Me NHC(O)OBu-t A64
Me Me Me SMe A65 Me Me Me NHC(O)OBu-t A65
Me Me Me SMe A67 Me Me Me NHC(O)OBu-t A67
Me Me Me SMe A69 Me Me Me NHC(O)OBu-t A69
Me Me Me SMe A72 Me Me Me NHC(O)OBu-t A72
Me Me Me SMe A73 Me Me Me NHC(O)OBu-t A73
Me Me Me SMe A74 Me Me Me NHC(O)OBu-t A74
Me Me Me SMe A75 Me Me Me NHC(O)OBu-t A75
Me Me Me SMe A76 Me Me Me NHC(O)OBu-t A76
Me Me Me SMe A77 Me Me Me NHC(O)OBu-t A77
Me Me Me SMe A81 Me Me Me NHC(O)OBu-t A81
Me Me Me SMe A83 Me Me Me NHC(O)OBu-t A83
Me Me Me SMe A88 Me Me Me NHC(O)OBu-t A88
Me Me Me SMe A91 Me Me Me NHC(O)OBu-t A91
Me Me Me SMe A97 Me Me Me NHC(O)OBu-t A97
Me Me Me SMe A98 Me Me Me NHC(O)OBu-t A98
Me Me Me SMe A102 Me Me Me NHC(O)OBu-t A102
――――――――――――― ――――――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
―――――――――――― ――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――― ――――――――――――――
Me Me Me Me A1 Me Me Me Me A11
Me Me Me Me A2 Me Me Me Me A12
Me Me Me Me A3 Me Me Me Me A13
Me Me Me Me A4 Me Me Me Me A14
Me Me Me Me A5 Me Me Me Me A15
Me Me Me Me A6 Me Me Me Me A16
Me Me Me Me A7 Me Me Me Me A17
Me Me Me Me A8 Me Me Me Me A18
Me Me Me Me A9 Me Me Me Me A19
Me Me Me Me A10 Me Me Me Me A20
Me Me Me Me A21 Me Me Me Me A60
Me Me Me Me A22 Me Me Me Me A61
Me Me Me Me A23 Me Me Me Me A62
Me Me Me Me A24 Me Me Me Me A63
Me Me Me Me A25 Me Me Me Me A64
Me Me Me Me A26 Me Me Me Me A65
Me Me Me Me A27 Me Me Me Me A66
Me Me Me Me A28 Me Me Me Me A67
Me Me Me Me A29 Me Me Me Me A68
Me Me Me Me A30 Me Me Me Me A69
Me Me Me Me A31 Me Me Me Me A70
Me Me Me Me A32 Me Me Me Me A71
Me Me Me Me A33 Me Me Me Me A72
Me Me Me Me A34 Me Me Me Me A73
Me Me Me Me A35 Me Me Me Me A74
Me Me Me Me A36 Me Me Me Me A75
Me Me Me Me A37 Me Me Me Me A76
Me Me Me Me A38 Me Me Me Me A77
Me Me Me Me A39 Me Me Me Me A78
Me Me Me Me A40 Me Me Me Me A79
Me Me Me Me A41 Me Me Me Me A80
Me Me Me Me A42 Me Me Me Me A81
Me Me Me Me A43 Me Me Me Me A82
Me Me Me Me A44 Me Me Me Me A83
Me Me Me Me A45 Me Me Me Me A84
Me Me Me Me A46 Me Me Me Me A85
Me Me Me Me A47 Me Me Me Me A86
Me Me Me Me A48 Me Me Me Me A87
Me Me Me Me A49 Me Me Me Me A88
Me Me Me Me A50 Me Me Me Me A89
Me Me Me Me A51 Me Me Me Me A90
Me Me Me Me A52 Me Me Me Me A91
Me Me Me Me A53 Me Me Me Me A92
Me Me Me Me A54 Me Me Me Me A93
Me Me Me Me A55 Me Me Me Me A94
Me Me Me Me A56 Me Me Me Me A95
Me Me Me Me A57 Me Me Me Me A96
Me Me Me Me A58 Me Me Me Me A97
Me Me Me Me A59 Me Me Me Me A98
Me Me Me Me A99 Me Me Me Me A108
Me Me Me Me A100 Me Me Me Me A109
Me Me Me Me A101 Me Me Me Me A110
Me Me Me Me A102 Me Me Me Me A111
Me Me Me Me A103 Me Me Me Me A112
Me Me Me Me A104 Me Me Me Me A113
Me Me Me Me A105 Me Me Me Me A114
Me Me Me Me A106 Me Me Me Me A115
―――――――――――― ――――――――――――――
〔第１表〕（続き） 〔第１表〕（続き）
――――――――――――――― ―――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ―――――――――――――――
Me Me Me Me A107 Me Me Me D1-103-3 H
Me Me Me D1-103-1 H Me Me Me D1-103-4 H
Me Me Me D1-103-2 H Me Et Et D1-103-3 H
Me Et Et D1-103-1 H Me Et Et D1-103-4 H
Me Et Et D1-103-2 H ―――――――――――――――
―――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――― ――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――― ――――――――――――――
Me Me Me Me A117 Me Me Me Me A170
Me Me Me Me A118 Me Me Me Me A171
Me Me Me Me A119 Me Me Me Me A172
Me Me Me Me A120 Me Me Me Me A173
Me Me Me Me A121 Me Me Me Me A174
Me Me Me Me A122 Me Me Me Me A175
Me Me Me Me A123 Me Me Me Me A176
Me Me Me Me A124 Me Me Me Me A177
Me Me Me Me A125 Me Me Me Me A178
Me Me Me Me A126 Me Me Me Me A179
Me Me Me Me A127 Me Me Me Me A180
Me Me Me Me A128 Me Me Me Me A181
Me Me Me Me A129 Me Me Me Me A182
Me Me Me Me A130 Me Me Me Me A183
Me Me Me Me A131 Me Me Me Me A184
Me Me Me Me A132 Me Me Me Me A185
Me Me Me Me A133 Me Me Me Me A186
Me Me Me Me A134 Me Me Me Me A187
Me Me Me Me A135 Me Me Me Me A188
Me Me Me Me A136 Me Me Me Me A189
Me Me Me Me A137 Me Me Me Me A190
Me Me Me Me A138 Me Me Me Me A191
Me Me Me Me A139 Me Me Me Me A192
Me Me Me Me A140 Me Me Me Me A193
Me Me Me Me A141 Me Me Me Me A194
Me Me Me Me A142 Me Me Me Me A195
Me Me Me Me A143 Me Me Me Me A196
Me Me Me Me A144 Me Me Me Me A197
Me Me Me Me A145 Me Me Me Me A198
Me Me Me Me A146 Me Me Me Me A199
Me Me Me Me A147 Me Me Me Me A200
Me Me Me Me A148 Me Me Me Me A205
Me Me Me Me A149 Me Me Me Me A206
Me Me Me Me A150 Me Me Me Me A207
Me Me Me Me A151 Me Me Me Me A208
Me Me Me Me A152 Me Me Me Me A209
Me Me Me Me A153 Me Me Me Me A210
Me Me Me Me A154 Me Me Me Me A211
Me Me Me Me A155 Me Me Me Me A212
Me Me Me Me A156 Me Me Me Me A213
Me Me Me Me A157 Me Me Me Me A214
Me Me Me Me A158 Me Me Me Me A215
Me Me Me Me A159 Me Me Me Me A216
Me Me Me Me A160 Me Me Me Me A217
Me Me Me Me A161 Me Me Me Me A218
Me Me Me Me A162 Me Me Me Me A219
Me Me Me Me A163 Me Me Me Me A220
Me Me Me Me A164 Me Me Me Me A221
Me Me Me Me A165 Me Me Me Me A222
Me Me Me Me A166 Me Me Me Me A223
Me Me Me Me A167 Me Me Me Me A224
Me Me Me Me A168 Me Me Me Me A225
Me Me Me Me A169 Me Me Me Me A226
―――――――――――― ――――――――――――――
第１表（続き） 〔第１表〕（続き）
――――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――――― ―――――――――――――――――
Me Me Me C≡CMe H Me Me Et C≡CMe H
Me Me Me C≡CMe A39 Me Me Et C≡CMe A39
Me Me Me C≡CMe A40 Me Me Et C≡CMe A40
Me Me Me C≡CMe A41 Me Me Et C≡CMe A41
c-Pr Me Me C≡CMe H c-Pr Me Et C≡CMe H
c-Pr Me Me C≡CMe A39 c-Pr Me Et C≡CMe A39
c-Pr Me Me C≡CMe A40 c-Pr Me Et C≡CMe A40
c-Pr Me Me C≡CMe A41 c-Pr Me Et C≡CMe A41
c-Bu Me Me C≡CMe H c-Bu Me Et C≡CMe H
c-Bu Me Me C≡CMe A39 c-Bu Me Et C≡CMe A39
c-Bu Me Me C≡CMe A40 c-Bu Me Et C≡CMe A40
c-Bu Me Me C≡CMe A41 c-Bu Me Et C≡CMe A41
c-Pen Me Me C≡CMe H c-Pen Me Et C≡CMe H
c-Pen Me Me C≡CMe A39 c-Pen Me Et C≡CMe A39
c-Pen Me Me C≡CMe A40 c-Pen Me Et C≡CMe A40
c-Pen Me Me C≡CMe A41 c-Pen Me Et C≡CMe A41
c-Hex Me Me C≡CMe H c-Hex Me Et C≡CMe H
c-Hex Me Me C≡CMe A39 c-Hex Me Et C≡CMe A39
c-Hex Me Me C≡CMe A40 c-Hex Me Et C≡CMe A40
c-Hex Me Me C≡CMe A41 c-Hex Me Et C≡CMe A41
Me Me Me C≡CSi(Me)₃ H Me Me Et C≡CSi(Me)₃ H
Me Me Me C≡CSi(Me)₃ A39 Me Me Et C≡CSi(Me)₃ A39
Me Me Me C≡CSi(Me)₃ A40 Me Me Et C≡CSi(Me)₃ A40
Me Me Me C≡CSi(Me)₃ A41 Me Me Et C≡CSi(Me)₃ A41
c-Pr Me Me C≡CSi(Me)₃ H c-Pr Me Et C≡CSi(Me)₃ H
c-Pr Me Me C≡CSi(Me)₃ A39 c-Pr Me Et C≡CSi(Me)₃ A39
c-Pr Me Me C≡CSi(Me)₃ A40 c-Pr Me Et C≡CSi(Me)₃ A40
c-Pr Me Me C≡CSi(Me)₃ A41 c-Pr Me Et C≡CSi(Me)₃ A41
c-Bu Me Me C≡CSi(Me)₃ H c-Bu Me Et C≡CSi(Me)₃ H
c-Bu Me Me C≡CSi(Me)₃ A39 c-Bu Me Et C≡CSi(Me)₃ A39
c-Bu Me Me C≡CSi(Me)₃ A40 c-Bu Me Et C≡CSi(Me)₃ A40
c-Bu Me Me C≡CSi(Me)₃ A41 c-Bu Me Et C≡CSi(Me)₃ A41
c-Pen Me Me C≡CSi(Me)₃ H c-Pen Me Et C≡CSi(Me)₃ H
c-Pen Me Me C≡CSi(Me)₃ A39 c-Pen Me Et C≡CSi(Me)₃ A39
c-Pen Me Me C≡CSi(Me)₃ A40 c-Pen Me Et C≡CSi(Me)₃ A40
c-Pen Me Me C≡CSi(Me)₃ A41 c-Pen Me Et C≡CSi(Me)₃ A41
c-Hex Me Me C≡CSi(Me)₃ H c-Hex Me Et C≡CSi(Me)₃ H
c-Hex Me Me C≡CSi(Me)₃ A39 c-Hex Me Et C≡CSi(Me)₃ A39
c-Hex Me Me C≡CSi(Me)₃ A40 c-Hex Me Et C≡CSi(Me)₃ A40
c-Hex Me Me C≡CSi(Me)₃ A41 c-Hex Me Et C≡CSi(Me)₃ A41
Me Me Me C≡CPr-c H Me Me Et C≡CPr-c H
Me Me Me C≡CPr-c A39 Me Me Et C≡CPr-c A39
Me Me Me C≡CPr-c A40 Me Me Et C≡CPr-c A40
Me Me Me C≡CPr-c A41 Me Me Et C≡CPr-c A41
c-Pr Me Me C≡CPr-c H c-Pr Me Et C≡CPr-c H
c-Pr Me Me C≡CPr-c A39 c-Pr Me Et C≡CPr-c A39
c-Pr Me Me C≡CPr-c A40 c-Pr Me Et C≡CPr-c A40
c-Pr Me Me C≡CPr-c A41 c-Pr Me Et C≡CPr-c A41
c-Bu Me Me C≡CPr-c H c-Bu Me Et C≡CPr-c H
c-Bu Me Me C≡CPr-c A39 c-Bu Me Et C≡CPr-c A39
c-Bu Me Me C≡CPr-c A40 c-Bu Me Et C≡CPr-c A40
c-Bu Me Me C≡CPr-c A41 c-Bu Me Et C≡CPr-c A41
c-Pen Me Me C≡CPr-c H c-Pen Me Et C≡CPr-c H
c-Pen Me Me C≡CPr-c A39 c-Pen Me Et C≡CPr-c A39
c-Pen Me Me C≡CPr-c A40 c-Pen Me Et C≡CPr-c A40
c-Pen Me Me C≡CPr-c A41 c-Pen Me Et C≡CPr-c A41
c-Hex Me Me C≡CPr-c H c-Hex Me Et C≡CPr-c H
c-Hex Me Me C≡CPr-c A39 c-Hex Me Et C≡CPr-c A39
c-Hex Me Me C≡CPr-c A40 c-Hex Me Et C≡CPr-c A40
c-Hex Me Me C≡CPr-c A41 c-Hex Me Et C≡CPr-c A41
――――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
――――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――――― ―――――――――――――――――
Me Me Me C≡CC(Me)₂OH H Me Me Et C≡CC(Me)₂OH H
Me Me Me C≡CC(Me)₂OH A39 Me Me Et C≡CC(Me)₂OH A39
Me Me Me C≡CC(Me)₂OH A40 Me Me Et C≡CC(Me)₂OH A40
Me Me Me C≡CC(Me)₂OH A41 Me Me Et C≡CC(Me)₂OH A41
Me Me Me C≡CCH₂OH H Me Me Et C≡CCH₂OH H
Me Me Me C≡CCH₂OH A39 Me Me Et C≡CCH₂OH A39
Me Me Me C≡CCH₂OH A40 Me Me Et C≡CCH₂OH A40
Me Me Me C≡CCH₂OH A41 Me Me Et C≡CCH₂OH A41
Me Me Me Ph H Me Me Et Ph H
Me Me Me Ph Me Me Me Et Ph Me
Me Me Me Ph A11 Me Me Et Ph A11
Me Me Me Ph A34 Me Me Et Ph A34
Me Me Me Ph A35 Me Me Et Ph A35
Me Me Me Ph A37 Me Me Et Ph A37
Me Me Me Ph A39 Me Me Et Ph A39
Me Me Me Ph A40 Me Me Et Ph A40
Me Me Me Ph A41 Me Me Et Ph A41
Me Me Me Ph A73 Me Me Et Ph A73
Me Me Me Ph A75 Me Me Et Ph A75
Me Me Me Ph A83 Me Me Et Ph A83
Me Me Me Ph A84 Me Me Et Ph A84
Me Me Me Ph A85 Me Me Et Ph A85
Me Me Me Ph A91 Me Me Et Ph A91
Me Me Me D1-108b-1 H Me Me Et D1-108b-1 H
Me Me Me D1-108b-1 Me Me Me Et D1-108b-1 Me
Me Me Me D1-108b-1 A11 Me Me Et D1-108b-1 A11
Me Me Me D1-108b-1 A34 Me Me Et D1-108b-1 A34
Me Me Me D1-108b-1 A35 Me Me Et D1-108b-1 A35
Me Me Me D1-108b-1 A37 Me Me Et D1-108b-1 A37
Me Me Me D1-108b-1 A39 Me Me Et D1-108b-1 A39
Me Me Me D1-108b-1 A40 Me Me Et D1-108b-1 A40
Me Me Me D1-108b-1 A41 Me Me Et D1-108b-1 A41
Me Me Me D1-108b-1 A73 Me Me Et D1-108b-1 A73
Me Me Me D1-108b-1 A75 Me Me Et D1-108b-1 A75
Me Me Me D1-108b-1 A83 Me Me Et D1-108b-1 A83
Me Me Me D1-108b-1 A84 Me Me Et D1-108b-1 A84
Me Me Me D1-108b-1 A85 Me Me Et D1-108b-1 A85
Me Me Me D1-108b-2 A91 Me Me Et D1-108b-2 A91
Me Me Me D1-108b-3 H Me Me Et D1-108b-3 H
Me Me Me D1-108b-4 H Me Me Et D1-108b-4 H
Me Me Me D1-108b-4 Me Me Me Et D1-108b-4 Me
Me Me Me D1-108b-4 A11 Me Me Et D1-108b-4 A11
Me Me Me D1-108b-4 A34 Me Me Et D1-108b-4 A34
Me Me Me D1-108b-4 A35 Me Me Et D1-108b-4 A35
Me Me Me D1-108b-4 A37 Me Me Et D1-108b-4 A37
Me Me Me D1-108b-4 A39 Me Me Et D1-108b-4 A39
Me Me Me D1-108b-4 A40 Me Me Et D1-108b-4 A40
Me Me Me D1-108b-4 A41 Me Me Et D1-108b-4 A41
Me Me Me D1-108b-4 A73 Me Me Et D1-108b-4 A73
Me Me Me D1-108b-4 A75 Me Me Et D1-108b-4 A75
Me Me Me D1-108b-4 A83 Me Me Et D1-108b-4 A83
Me Me Me D1-108b-4 A84 Me Me Et D1-108b-4 A84
Me Me Me D1-108b-4 A85 Me Me Et D1-108b-4 A85
Me Me Me D1-108b-4 A91 Me Me Et D1-108b-4 A91
Me Me Me D1-108b-5 H Me Me Et D1-108b-5 H
Me Me Me D1-108b-6 H Me Me Et D1-108b-6 H
Me Me Me D1-108b-7 H Me Me Et D1-108b-7 H
――――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Me Me D1-108b-8 H Me Me Et D1-108b-8 H
Me Me Me D1-108b-8 Me Me Me Et D1-108b-8 Me
Me Me Me D1-108b-8 A11 Me Me Et D1-108b-8 A11
Me Me Me D1-108b-8 A34 Me Me Et D1-108b-8 A34
Me Me Me D1-108b-8 A35 Me Me Et D1-108b-8 A35
Me Me Me D1-108b-8 A37 Me Me Et D1-108b-8 A37
Me Me Me D1-108b-8 A39 Me Me Et D1-108b-8 A39
Me Me Me D1-108b-8 A40 Me Me Et D1-108b-8 A40
Me Me Me D1-108b-8 A41 Me Me Et D1-108b-8 A41
Me Me Me D1-108b-8 A73 Me Me Et D1-108b-8 A73
Me Me Me D1-108b-8 A75 Me Me Et D1-108b-8 A75
Me Me Me D1-108b-8 A83 Me Me Et D1-108b-8 A83
Me Me Me D1-108b-8 A84 Me Me Et D1-108b-8 A84
Me Me Me D1-108b-8 A85 Me Me Et D1-108b-8 A85
Me Me Me D1-108b-8 A91 Me Me Et D1-108b-8 A91
Me Me Me D1-108b-9 H Me Me Et D1-108b-9 H
Me Me Me D1-108b-9 Me Me Me Et D1-108b-9 Me
Me Me Me D1-108b-9 A11 Me Me Et D1-108b-9 A11
Me Me Me D1-108b-9 A34 Me Me Et D1-108b-9 A34
Me Me Me D1-108b-9 A35 Me Me Et D1-108b-9 A35
Me Me Me D1-108b-9 A37 Me Me Et D1-108b-9 A37
Me Me Me D1-108b-9 A39 Me Me Et D1-108b-9 A39
Me Me Me D1-108b-9 A40 Me Me Et D1-108b-9 A40
Me Me Me D1-108b-9 A41 Me Me Et D1-108b-9 A41
Me Me Me D1-108b-9 A73 Me Me Et D1-108b-9 A73
Me Me Me D1-108b-9 A75 Me Me Et D1-108b-9 A75
Me Me Me D1-108b-9 A83 Me Me Et D1-108b-9 A83
Me Me Me D1-108b-9 A84 Me Me Et D1-108b-9 A84
Me Me Me D1-108b-9 A85 Me Me Et D1-108b-9 A85
Me Me Me D1-108b-9 A91 Me Me Et D1-108b-9 A91
Me Me Me D1-108b-10 H Me Me Et D1-108b-10 H
Me Me Me D1-108b-10 Me Me Me Et D1-108b-10 Me
Me Me Me D1-108b-10 A11 Me Me Et D1-108b-10 A11
Me Me Me D1-108b-10 A34 Me Me Et D1-108b-10 A34
Me Me Me D1-108b-10 A35 Me Me Et D1-108b-10 A35
Me Me Me D1-108b-10 A37 Me Me Et D1-108b-10 A37
Me Me Me D1-108b-10 A39 Me Me Et D1-108b-10 A39
Me Me Me D1-108b-10 A40 Me Me Et D1-108b-10 A40
Me Me Me D1-108b-10 A41 Me Me Et D1-108b-10 A41
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Me Me D1-108b-10 A73 Me Me Et D1-108b-10 A73
Me Me Me D1-108b-10 A75 Me Me Et D1-108b-10 A75
Me Me Me D1-108b-10 A83 Me Me Et D1-108b-10 A83
Me Me Me D1-108b-10 A84 Me Me Et D1-108b-10 A84
Me Me Me D1-108b-10 A85 Me Me Et D1-108b-10 A85
Me Me Me D1-108b-10 A91 Me Me Et D1-108b-10 A91
Me Me Me D1-108b-11 H Me Me Et D1-108b-11 H
Me Me Me D1-108b-12 H Me Me Et D1-108b-12 H
Me Me Me D1-108b-12 Me Me Me Et D1-108b-12 Me
Me Me Me D1-108b-12 A11 Me Me Et D1-108b-12 A11
Me Me Me D1-108b-12 A34 Me Me Et D1-108b-12 A34
Me Me Me D1-108b-12 A35 Me Me Et D1-108b-12 A35
Me Me Me D1-108b-12 A37 Me Me Et D1-108b-12 A37
Me Me Me D1-108b-12 A39 Me Me Et D1-108b-12 A39
Me Me Me D1-108b-12 A40 Me Me Et D1-108b-12 A40
Me Me Me D1-108b-12 A41 Me Me Et D1-108b-12 A41
Me Me Me D1-108b-12 A73 Me Me Et D1-108b-12 A73
Me Me Me D1-108b-12 A75 Me Me Et D1-108b-12 A75
Me Me Me D1-108b-12 A83 Me Me Et D1-108b-12 A83
Me Me Me D1-108b-12 A84 Me Me Et D1-108b-12 A84
Me Me Me D1-108b-12 A85 Me Me Et D1-108b-12 A85
Me Me Me D1-108b-12 A91 Me Me Et D1-108b-12 A91
Me Me Me D1-108b-13 H Me Me Et D1-108b-13 H
Me Me Me D1-108b-14 H Me Me Et D1-108b-14 H
Me Me Me D1-108b-15 H Me Me Et D1-108b-15 H
Me Me Me D1-108b-16 H Me Me Et D1-108b-16 H
Me Me Me D1-108b-17 H Me Me Et D1-108b-17 H
Me Me Me D1-108b-18 H Me Me Et D1-108b-18 H
Me Me Me D1-108b-19 H Me Me Et D1-108b-19 H
Me Me Me D1-2a H Me Me Et D1-2a H
Me Me Me D1-2b H Me Me Et D1-2b H
Me Me Me D1-7a H Me Me Et D1-7a H
Me Me Me D1-7b-1 H Me Me Et D1-7b-1 H
Me Me Me D1-7b-1 A39 Me Me Et D1-7b-1 A39
Me Me Me D1-7b-1 A40 Me Me Et D1-7b-1 A40
Me Me Me D1-7b-1 A41 Me Me Et D1-7b-1 A41
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
c-Pr Me Me D1-7b-1 H c-Pr Me Et D1-7b-1 H
c-Pr Me Me D1-7b-1 A39 c-Pr Me Et D1-7b-1 A39
c-Pr Me Me D1-7b-1 A40 c-Pr Me Et D1-7b-1 A40
c-Pr Me Me D1-7b-1 A41 c-Pr Me Et D1-7b-1 A41
c-Bu Me Me D1-7b-1 H c-Bu Me Et D1-7b-1 H
c-Bu Me Me D1-7b-1 A39 c-Bu Me Et D1-7b-1 A39
c-Bu Me Me D1-7b-1 A40 c-Bu Me Et D1-7b-1 A40
c-Bu Me Me D1-7b-1 A41 c-Bu Me Et D1-7b-1 A41
c-Pen Me Me D1-7b-1 H c-Pen Me Et D1-7b-1 H
c-Pen Me Me D1-7b-1 A39 c-Pen Me Et D1-7b-1 A39
c-Pen Me Me D1-7b-1 A40 c-Pen Me Et D1-7b-1 A40
c-Pen Me Me D1-7b-1 A41 c-Pen Me Et D1-7b-1 A41
c-Hex Me Me D1-7b-1 H c-Hex Me Et D1-7b-1 H
c-Hex Me Me D1-7b-1 A39 c-Hex Me Et D1-7b-1 A39
c-Hex Me Me D1-7b-1 A40 c-Hex Me Et D1-7b-1 A40
c-Hex Me Me D1-7b-1 A41 c-Hex Me Et D1-7b-1 A41
Me Me Me D1-7b-2 H Me Me Et D1-7b-2 H
Me Me Me D1-7b-2 A39 Me Me Et D1-7b-2 A39
Me Me Me D1-7b-2 A40 Me Me Et D1-7b-2 A40
Me Me Me D1-7b-2 A41 Me Me Et D1-7b-2 A41
c-Pr Me Me D1-7b-2 H c-Pr Me Et D1-7b-2 H
c-Pr Me Me D1-7b-2 A39 c-Pr Me Et D1-7b-2 A39
c-Pr Me Me D1-7b-2 A40 c-Pr Me Et D1-7b-2 A40
c-Pr Me Me D1-7b-2 A41 c-Pr Me Et D1-7b-2 A41
c-Bu Me Me D1-7b-2 H c-Bu Me Et D1-7b-2 H
c-Bu Me Me D1-7b-2 A39 c-Bu Me Et D1-7b-2 A39
c-Bu Me Me D1-7b-2 A40 c-Bu Me Et D1-7b-2 A40
c-Bu Me Me D1-7b-2 A41 c-Bu Me Et D1-7b-2 A41
c-Pen Me Me D1-7b-2 H c-Pen Me Et D1-7b-2 H
c-Pen Me Me D1-7b-2 A39 c-Pen Me Et D1-7b-2 A39
c-Pen Me Me D1-7b-2 A40 c-Pen Me Et D1-7b-2 A40
c-Pen Me Me D1-7b-2 A41 c-Pen Me Et D1-7b-2 A41
c-Hex Me Me D1-7b-2 H c-Hex Me Et D1-7b-2 H
c-Hex Me Me D1-7b-2 A39 c-Hex Me Et D1-7b-2 A39
c-Hex Me Me D1-7b-2 A40 c-Hex Me Et D1-7b-2 A40
c-Hex Me Me D1-7b-2 A41 c-Hex Me Et D1-7b-2 A41
Me Me Me D1-7b-3 H Me Me Et D1-7b-3 H
Me Me Me D1-7b-3 A39 Me Me Et D1-7b-3 A39
Me Me Me D1-7b-3 A40 Me Me Et D1-7b-3 A40
Me Me Me D1-7b-3 A41 Me Me Et D1-7b-3 A41
c-Pr Me Me D1-7b-3 H c-Pr Me Et D1-7b-3 H
c-Pr Me Me D1-7b-3 A39 c-Pr Me Et D1-7b-3 A39
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
c-Pr Me Me D1-7b-3 A40 c-Pr Me Et D1-7b-3 A40
c-Pr Me Me D1-7b-3 A41 c-Pr Me Et D1-7b-3 A41
c-Bu Me Me D1-7b-3 H c-Bu Me Et D1-7b-3 H
c-Bu Me Me D1-7b-3 A39 c-Bu Me Et D1-7b-3 A39
c-Bu Me Me D1-7b-3 A40 c-Bu Me Et D1-7b-3 A40
c-Bu Me Me D1-7b-3 A41 c-Bu Me Et D1-7b-3 A41
c-Pen Me Me D1-7b-3 H c-Pen Me Et D1-7b-3 H
c-Pen Me Me D1-7b-3 A39 c-Pen Me Et D1-7b-3 A39
c-Pen Me Me D1-7b-3 A40 c-Pen Me Et D1-7b-3 A40
c-Pen Me Me D1-7b-3 A41 c-Pen Me Et D1-7b-3 A41
c-Hex Me Me D1-7b-3 H c-Hex Me Et D1-7b-3 H
c-Hex Me Me D1-7b-3 A39 c-Hex Me Et D1-7b-3 A39
c-Hex Me Me D1-7b-3 A40 c-Hex Me Et D1-7b-3 A40
c-Hex Me Me D1-7b-3 A41 c-Hex Me Et D1-7b-3 A41
Me Me Me D1-7b-4 H Me Me Et D1-7b-4 H
Me Me Me D1-7b-4 A39 Me Me Et D1-7b-4 A39
Me Me Me D1-7b-4 A40 Me Me Et D1-7b-4 A40
Me Me Me D1-7b-4 A41 Me Me Et D1-7b-4 A41
c-Pr Me Me D1-7b-4 H c-Pr Me Et D1-7b-4 H
c-Pr Me Me D1-7b-4 A39 c-Pr Me Et D1-7b-4 A39
c-Pr Me Me D1-7b-4 A40 c-Pr Me Et D1-7b-4 A40
c-Pr Me Me D1-7b-4 A41 c-Pr Me Et D1-7b-4 A41
c-Bu Me Me D1-7b-4 H c-Bu Me Et D1-7b-4 H
c-Bu Me Me D1-7b-4 A39 c-Bu Me Et D1-7b-4 A39
c-Bu Me Me D1-7b-4 A40 c-Bu Me Et D1-7b-4 A40
c-Bu Me Me D1-7b-4 A41 c-Bu Me Et D1-7b-4 A41
c-Pen Me Me D1-7b-4 H c-Pen Me Et D1-7b-4 H
c-Pen Me Me D1-7b-4 A39 c-Pen Me Et D1-7b-4 A39
c-Pen Me Me D1-7b-4 A40 c-Pen Me Et D1-7b-4 A40
c-Pen Me Me D1-7b-4 A41 c-Pen Me Et D1-7b-4 A41
c-Hex Me Me D1-7b-4 H c-Hex Me Et D1-7b-4 H
c-Hex Me Me D1-7b-4 A39 c-Hex Me Et D1-7b-4 A39
c-Hex Me Me D1-7b-4 A40 c-Hex Me Et D1-7b-4 A40
c-Hex Me Me D1-7b-4 A41 c-Hex Me Et D1-7b-4 A41
Me Me Me D1-10a H Me Me Et D1-10a H
Me Me Me D1-11a H Me Me Et D1-11a H
Me Me Me D1-11b-1 H Me Me Et D1-11b-1 H
Me Me Me D1-11b-2 H Me Me Et D1-11b-2 H
Me Me Me D1-11b-3 H Me Me Et D1-11b-3 H
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Me Me D1-11b-4 H Me Me Et D1-11b-4 H
Me Me Me D1-22a H Me Me Et D1-22a H
Me Me Me D1-22b-1 H Me Me Et D1-22b-1 H
Me Me Me D1-22b-2 H Me Me Et D1-22b-2 H
Me Me Me D1-22b-3 H Me Me Et D1-22b-3 H
Me Me Me D1-22b-4 H Me Me Et D1-22b-4 H
Me Me Me D1-32a H Me Me Et D1-32a H
Me Me Me D1-32b-1 H Me Me Et D1-32b-1 H
Me Me Me D1-32b-2 H Me Me Et D1-32b-2 H
Me Me Me D1-32b-3 H Me Me Et D1-32b-3 H
Me Me Me D1-32b-4 H Me Me Et D1-32b-4 H
Me Me Me D1-32b-5 H Me Me Et D1-32b-5 H
Me Me Me D1-33a H Me Me Et D1-33a H
Me Me Me D1-33b-1 H Me Me Et D1-33b-1 H
Me Me Me D1-33b-2 H Me Me Et D1-33b-2 H
Me Me Me D1-33b-3 H Me Me Et D1-33b-3 H
Me Me Me D1-33b-4 H Me Me Et D1-33b-4 H
Me Me Me D1-34a H Me Me Et D1-34a H
Me Me Me D1-37a H Me Me Et D1-37a H
Me Me Me D1-37b-1 H Me Me Et D1-37b-1 H
Me Me Me C≡CH H Me Me Et C≡CH H
Me Me Me C≡CH A39 Me Me Et C≡CH A39
Me Me Me C≡CH A40 Me Me Et C≡CH A40
Me Me Me C≡CH A41 Me Me Et C≡CH A41
c-Pr Me Me C≡CH H c-Pr Me Et C≡CH H
c-Pr Me Me C≡CH A39 c-Pr Me Et C≡CH A39
c-Pr Me Me C≡CH A40 c-Pr Me Et C≡CH A40
c-Pr Me Me C≡CH A41 c-Pr Me Et C≡CH A41
c-Bu Me Me C≡CH H c-Bu Me Et C≡CH H
c-Bu Me Me C≡CH A39 c-Bu Me Et C≡CH A39
c-Bu Me Me C≡CH A40 c-Bu Me Et C≡CH A40
c-Bu Me Me C≡CH A41 c-Bu Me Et C≡CH A41
c-Pen Me Me C≡CH H c-Pen Me Et C≡CH H
c-Pen Me Me C≡CH A39 c-Pen Me Et C≡CH A39
c-Pen Me Me C≡CH A40 c-Pen Me Et C≡CH A40
c-Pen Me Me C≡CH A41 c-Pen Me Et C≡CH A41
c-Hex Me Me C≡CH H c-Hex Me Et C≡CH H
c-Hex Me Me C≡CH A39 c-Hex Me Et C≡CH A39
c-Hex Me Me C≡CH A40 c-Hex Me Et C≡CH A40
c-Hex Me Me C≡CH A41 c-Hex Me Et C≡CH A41
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Me Me C≡CBu-c H Me Me Et C≡CBu-c H
Me Me Me C≡CBu-c A39 Me Me Et C≡CBu-c A39
Me Me Me C≡CBu-c A40 Me Me Et C≡CBu-c A40
Me Me Me C≡CBu-c A41 Me Me Et C≡CBu-c A41
c-Pr Me Me C≡CBu-c H c-Pr Me Et C≡CBu-c H
c-Pr Me Me C≡CBu-c A39 c-Pr Me Et C≡CBu-c A39
c-Pr Me Me C≡CBu-c A40 c-Pr Me Et C≡CBu-c A40
c-Pr Me Me C≡CBu-c A41 c-Pr Me Et C≡CBu-c A41
c-Bu Me Me C≡CBu-c H c-Bu Me Et C≡CBu-c H
c-Bu Me Me C≡CBu-c A39 c-Bu Me Et C≡CBu-c A39
c-Bu Me Me C≡CBu-c A40 c-Bu Me Et C≡CBu-c A40
c-Bu Me Me C≡CBu-c A41 c-Bu Me Et C≡CBu-c A41
c-Pen Me Me C≡CBu-c H c-Pen Me Et C≡CBu-c H
c-Pen Me Me C≡CBu-c A39 c-Pen Me Et C≡CBu-c A39
c-Pen Me Me C≡CBu-c A40 c-Pen Me Et C≡CBu-c A40
c-Pen Me Me C≡CBu-c A41 c-Pen Me Et C≡CBu-c A41
c-Hex Me Me C≡CBu-c H c-Hex Me Et C≡CBu-c H
c-Hex Me Me C≡CBu-c A39 c-Hex Me Et C≡CBu-c A39
c-Hex Me Me C≡CBu-c A40 c-Hex Me Et C≡CBu-c A40
c-Hex Me Me C≡CBu-c A41 c-Hex Me Et C≡CBu-c A41
Me Me Me C≡CPen-c H Me Me Et C≡CPen-c H
Me Me Me C≡CPen-c A39 Me Me Et C≡CPen-c A39
Me Me Me C≡CPen-c A40 Me Me Et C≡CPen-c A40
Me Me Me C≡CPen-c A41 Me Me Et C≡CPen-c A41
c-Pr Me Me C≡CPen-c H c-Pr Me Et C≡CPen-c H
c-Pr Me Me C≡CPen-c A39 c-Pr Me Et C≡CPen-c A39
c-Pr Me Me C≡CPen-c A40 c-Pr Me Et C≡CPen-c A40
c-Pr Me Me C≡CPen-c A41 c-Pr Me Et C≡CPen-c A41
c-Bu Me Me C≡CPen-c H c-Bu Me Et C≡CPen-c H
c-Bu Me Me C≡CPen-c A39 c-Bu Me Et C≡CPen-c A39
c-Bu Me Me C≡CPen-c A40 c-Bu Me Et C≡CPen-c A40
c-Bu Me Me C≡CPen-c A41 c-Bu Me Et C≡CPen-c A41
c-Pen Me Me C≡CPen-c H c-Pen Me Et C≡CPen-c H
c-Pen Me Me C≡CPen-c A39 c-Pen Me Et C≡CPen-c A39
c-Pen Me Me C≡CPen-c A40 c-Pen Me Et C≡CPen-c A40
c-Pen Me Me C≡CPen-c A41 c-Pen Me Et C≡CPen-c A41
c-Hex Me Me C≡CPen-c H c-Hex Me Et C≡CPen-c H
c-Hex Me Me C≡CPen-c A39 c-Hex Me Et C≡CPen-c A39
c-Hex Me Me C≡CPen-c A40 c-Hex Me Et C≡CPen-c A40
c-Hex Me Me C≡CPen-c A41 c-Hex Me Et C≡CPen-c A41
Me Me Me C≡CHex-c H Me Me Et C≡CHex-c H
Me Me Me C≡CHex-c A39 Me Me Et C≡CHex-c A39
Me Me Me C≡CHex-c A40 Me Me Et C≡CHex-c A40
Me Me Me C≡CHex-c A41 Me Me Et C≡CHex-c A41
c-Pr Me Me C≡CHex-c H c-Pr Me Et C≡CHex-c H
c-Pr Me Me C≡CHex-c A39 c-Pr Me Et C≡CHex-c A39
c-Pr Me Me C≡CHex-c A40 c-Pr Me Et C≡CHex-c A40
c-Pr Me Me C≡CHex-c A41 c-Pr Me Et C≡CHex-c A41
c-Bu Me Me C≡CHex-c H c-Bu Me Et C≡CHex-c H
c-Bu Me Me C≡CHex-c A39 c-Bu Me Et C≡CHex-c A39
c-Bu Me Me C≡CHex-c A40 c-Bu Me Et C≡CHex-c A40
c-Bu Me Me C≡CHex-c A41 c-Bu Me Et C≡CHex-c A41
c-Pen Me Me C≡CHex-c H c-Pen Me Et C≡CHex-c H
c-Pen Me Me C≡CHex-c A39 c-Pen Me Et C≡CHex-c A39
c-Pen Me Me C≡CHex-c A40 c-Pen Me Et C≡CHex-c A40
c-Pen Me Me C≡CHex-c A41 c-Pen Me Et C≡CHex-c A41
c-Hex Me Me C≡CHex-c H c-Hex Me Et C≡CHex-c H
c-Hex Me Me C≡CHex-c A39 c-Hex Me Et C≡CHex-c A39
c-Hex Me Me C≡CHex-c A40 c-Hex Me Et C≡CHex-c A40
c-Hex Me Me C≡CHex-c A41 c-Hex Me Et C≡CHex-c A41
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
――――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――――― ―――――――――――――――――
Me Me Me Ph A74 Me Me Et Ph A74
Me Me Me D1-108b-1 A74 Me Me Et D1-108b-1 A74
Me Me Me D1-108b-2 H Me Me Et D1-108b-2 H
Me Me Me D1-108b-4 A74 Me Me Et D1-108b-4 A74
Me Me Me D1-108b-8 A74 Me Me Et D1-108b-8 A74
Me Me Me D1-108b-9 A74 Me Me Et D1-108b-9 A74
Me Me Me D1-108b-10 A74 Me Me Et D1-108b-10 A74
Me Me Me D1-108b-12 A74 Me Me Et D1-108b-12 A74
Me Et Et Ph A74 Me Me n-Pr Ph A74
Me Et Et D1-108b-1 A74 Me Me n-Pr D1-108b-1 A74
Me Et Et D1-108b-2 H Me Me n-Pr D1-108b-2 H
Me Et Et D1-108b-4 A74 Me Me n-Pr D1-108b-4 A74
Me Et Et D1-108b-8 A74 Me Me n-Pr D1-108b-8 A74
Me Et Et D1-108b-9 A74 Me Me n-Pr D1-108b-9 A74
Me Et Et D1-108b-10 A74 Me Me n-Pr D1-108b-10 A74
Me Et Et D1-108b-12 A74 Me Me n-Pr D1-108b-12 A74
Me Et Et C≡CMe H Me Me n-Pr C≡CMe H
Me Et Et C≡CMe A39 Me Me n-Pr C≡CMe A39
Me Et Et C≡CMe A40 Me Me n-Pr C≡CMe A40
Me Et Et C≡CMe A41 Me Me n-Pr C≡CMe A41
c-Pr Et Et C≡CMe H c-Pr Me n-Pr C≡CMe H
c-Pr Et Et C≡CMe A39 c-Pr Me n-Pr C≡CMe A39
c-Pr Et Et C≡CMe A40 c-Pr Me n-Pr C≡CMe A40
c-Pr Et Et C≡CMe A41 c-Pr Me n-Pr C≡CMe A41
c-Bu Et Et C≡CMe H c-Bu Me n-Pr C≡CMe H
c-Bu Et Et C≡CMe A39 c-Bu Me n-Pr C≡CMe A39
c-Bu Et Et C≡CMe A40 c-Bu Me n-Pr C≡CMe A40
c-Bu Et Et C≡CMe A41 c-Bu Me n-Pr C≡CMe A41
c-Pen Et Et C≡CMe H c-Pen Me n-Pr C≡CMe H
c-Pen Et Et C≡CMe A39 c-Pen Me n-Pr C≡CMe A39
c-Pen Et Et C≡CMe A40 c-Pen Me n-Pr C≡CMe A40
c-Pen Et Et C≡CMe A41 c-Pen Me n-Pr C≡CMe A41
c-Hex Et Et C≡CMe H c-Hex Me n-Pr C≡CMe H
c-Hex Et Et C≡CMe A39 c-Hex Me n-Pr C≡CMe A39
c-Hex Et Et C≡CMe A40 c-Hex Me n-Pr C≡CMe A40
c-Hex Et Et C≡CMe A41 c-Hex Me n-Pr C≡CMe A41
Me Et Et C≡CSi(Me)₃H Me Me n-Pr C≡CSi(Me)₃H
Me Et Et C≡CSi(Me)₃A39 Me Me n-Pr C≡CSi(Me)₃A39
Me Et Et C≡CSi(Me)₃A40 Me Me n-Pr C≡CSi(Me)₃A40
Me Et Et C≡CSi(Me)₃A41 Me Me n-Pr C≡CSi(Me)₃A41
c-Pr Et Et C≡CSi(Me)₃H c-Pr Me n-Pr C≡CSi(Me)₃H
c-Pr Et Et C≡CSi(Me)₃A39 c-Pr Me n-Pr C≡CSi(Me)₃A39
c-Pr Et Et C≡CSi(Me)₃A40 c-Pr Me n-Pr C≡CSi(Me)₃A40
c-Pr Et Et C≡CSi(Me)₃A41 c-Pr Me n-Pr C≡CSi(Me)₃A41
c-Bu Et Et C≡CSi(Me)₃H c-Bu Me n-Pr C≡CSi(Me)₃H
c-Bu Et Et C≡CSi(Me)₃A39 c-Bu Me n-Pr C≡CSi(Me)₃A39
c-Bu Et Et C≡CSi(Me)₃A40 c-Bu Me n-Pr C≡CSi(Me)₃A40
c-Bu Et Et C≡CSi(Me)₃A41 c-Bu Me n-Pr C≡CSi(Me)₃A41
c-Pen Et Et C≡CSi(Me)2 H c-Pen Me n-Pr C≡CSi(Me)2 H
c-Pen Et Et C≡CSi(Me)₃A39 c-Pen Me n-Pr C≡CSi(Me)₃A39
c-Pen Et Et C≡CSi(Me)₃A40 c-Pen Me n-Pr C≡CSi(Me)₃A40
c-Pen Et Et C≡CSi(Me)₃A41 c-Pen Me n-Pr C≡CSi(Me)₃A41
c-Hex Et Et C≡CSi(Me)₃H c-Hex Me n-Pr C≡CSi(Me)₃H
c-Hex Et Et C≡CSi(Me)₃A39 c-Hex Me n-Pr C≡CSi(Me)₃A39
c-Hex Et Et C≡CSi(Me)₃A40 c-Hex Me n-Pr C≡CSi(Me)₃A40
c-Hex Et Et C≡CSi(Me)₃A41 c-Hex Me n-Pr C≡CSi(Me)₃A41
――――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
――――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――――― ―――――――――――――――――
Me Et Et C≡CPr-c H Me Me n-Pr C≡CPr-c H
Me Et Et C≡CPr-c A39 Me Me n-Pr C≡CPr-c A39
Me Et Et C≡CPr-c A40 Me Me n-Pr C≡CPr-c A40
Me Et Et C≡CPr-c A41 Me Me n-Pr C≡CPr-c A41
c-Pr Et Et C≡CPr-c H c-Pr Me n-Pr C≡CPr-c H
c-Pr Et Et C≡CPr-c A39 c-Pr Me n-Pr C≡CPr-c A39
c-Pr Et Et C≡CPr-c A40 c-Pr Me n-Pr C≡CPr-c A40
c-Pr Et Et C≡CPr-c A41 c-Pr Me n-Pr C≡CPr-c A41
c-Bu Et Et C≡CPr-c H c-Bu Me n-Pr C≡CPr-c H
c-Bu Et Et C≡CPr-c A39 c-Bu Me n-Pr C≡CPr-c A39
c-Bu Et Et C≡CPr-c A40 c-Bu Me n-Pr C≡CPr-c A40
c-Bu Et Et C≡CPr-c A41 c-Bu Me n-Pr C≡CPr-c A41
c-Pen Et Et C≡CPr-c H c-Pen Me n-Pr C≡CPr-c H
c-Pen Et Et C≡CPr-c A39 c-Pen Me n-Pr C≡CPr-c A39
c-Pen Et Et C≡CPr-c A40 c-Pen Me n-Pr C≡CPr-c A40
c-Pen Et Et C≡CPr-c A41 c-Pen Me n-Pr C≡CPr-c A41
c-Hex Et Et C≡CPr-c H c-Hex Me n-Pr C≡CPr-c H
c-Hex Et Et C≡CPr-c A39 c-Hex Me n-Pr C≡CPr-c A39
c-Hex Et Et C≡CPr-c A40 c-Hex Me n-Pr C≡CPr-c A40
c-Hex Et Et C≡CPr-c A41 c-Hex Me n-Pr C≡CPr-c A41
Me Et Et C≡CC(Me)₂OH H Me Me n-Pr C≡CC(Me)₂OH H
Me Et Et C≡CC(Me)₂OH A39 Me Me n-Pr C≡CC(Me)₂OH A39
Me Et Et C≡CC(Me)₂OH A40 Me Me n-Pr C≡CC(Me)₂OH A40
Me Et Et C≡CC(Me)₂OH A41 Me Me n-Pr C≡CC(Me)₂OH A41
Me Et Et C≡CCH₂OH H Me Me n-Pr C≡CCH₂OH H
Me Et Et C≡CCH₂OH A39 Me Me n-Pr C≡CCH₂OH A39
Me Et Et C≡CCH₂OH A40 Me Me n-Pr C≡CCH₂OH A40
Me Et Et C≡CCH₂OH A41 Me Me n-Pr C≡CCH₂OH A41
――――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et Ph H Me Me n-Pr Ph H
Me Et Et Ph Me Me Me n-Pr Ph Me
Me Et Et Ph A11 Me Me n-Pr Ph A11
Me Et Et Ph A34 Me Me n-Pr Ph A34
Me Et Et Ph A35 Me Me n-Pr Ph A35
Me Et Et Ph A37 Me Me n-Pr Ph A37
Me Et Et Ph A39 Me Me n-Pr Ph A39
Me Et Et Ph A40 Me Me n-Pr Ph A40
Me Et Et Ph A41 Me Me n-Pr Ph A41
Me Et Et Ph A73 Me Me n-Pr Ph A73
Me Et Et Ph A75 Me Me n-Pr Ph A75
Me Et Et Ph A83 Me Me n-Pr Ph A83
Me Et Et Ph A84 Me Me n-Pr Ph A84
Me Et Et Ph A85 Me Me n-Pr Ph A85
Me Et Et Ph A91 Me Me n-Pr Ph A91
Me Et Et D1-108b-1 H Me Me n-Pr D1-108b-1 H
Me Et Et D1-108b-1 Me Me Me n-Pr D1-108b-1 Me
Me Et Et D1-108b-1 A11 Me Me n-Pr D1-108b-1 A11
Me Et Et D1-108b-1 A34 Me Me n-Pr D1-108b-1 A34
Me Et Et D1-108b-1 A35 Me Me n-Pr D1-108b-1 A35
Me Et Et D1-108b-1 A37 Me Me n-Pr D1-108b-1 A37
Me Et Et D1-108b-1 A39 Me Me n-Pr D1-108b-1 A39
Me Et Et D1-108b-1 A40 Me Me n-Pr D1-108b-1 A40
Me Et Et D1-108b-1 A41 Me Me n-Pr D1-108b-1 A41
Me Et Et D1-108b-1 A73 Me Me n-Pr D1-108b-1 A73
Me Et Et D1-108b-1 A75 Me Me n-Pr D1-108b-1 A75
Me Et Et D1-108b-1 A83 Me Me n-Pr D1-108b-1 A83
Me Et Et D1-108b-1 A84 Me Me n-Pr D1-108b-1 A84
Me Et Et D1-108b-1 A85 Me Me n-Pr D1-108b-1 A85
Me Et Et D1-108b-2 A91 Me Me n-Pr D1-108b-2 A91
Me Et Et D1-108b-3 H Me Me n-Pr D1-108b-3 H
Me Et Et D1-108b-4 H Me Me n-Pr D1-108b-4 H
Me Et Et D1-108b-4 Me Me Me n-Pr D1-108b-4 Me
Me Et Et D1-108b-4 A11 Me Me n-Pr D1-108b-4 A11
Me Et Et D1-108b-4 A34 Me Me n-Pr D1-108b-4 A34
Me Et Et D1-108b-4 A35 Me Me n-Pr D1-108b-4 A35
Me Et Et D1-108b-4 A37 Me Me n-Pr D1-108b-4 A37
Me Et Et D1-108b-4 A39 Me Me n-Pr D1-108b-4 A39
Me Et Et D1-108b-4 A40 Me Me n-Pr D1-108b-4 A40
Me Et Et D1-108b-4 A41 Me Me n-Pr D1-108b-4 A41
Me Et Et D1-108b-4 A73 Me Me n-Pr D1-108b-4 A73
Me Et Et D1-108b-4 A75 Me Me n-Pr D1-108b-4 A75
Me Et Et D1-108b-4 A83 Me Me n-Pr D1-108b-4 A83
Me Et Et D1-108b-4 A84 Me Me n-Pr D1-108b-4 A84
Me Et Et D1-108b-4 A85 Me Me n-Pr D1-108b-4 A85
Me Et Et D1-108b-4 A91 Me Me n-Pr D1-108b-4 A91
Me Et Et D1-108b-5 H Me Me n-Pr D1-108b-5 H
Me Et Et D1-108b-6 H Me Me n-Pr D1-108b-6 H
Me Et Et D1-108b-7 H Me Me n-Pr D1-108b-7 H
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et D1-108b-8 H Me Me n-Pr D1-108b-8 H
Me Et Et D1-108b-8 Me Me Me n-Pr D1-108b-8 Me
Me Et Et D1-108b-8 A11 Me Me n-Pr D1-108b-8 A11
Me Et Et D1-108b-8 A34 Me Me n-Pr D1-108b-8 A34
Me Et Et D1-108b-8 A35 Me Me n-Pr D1-108b-8 A35
Me Et Et D1-108b-8 A37 Me Me n-Pr D1-108b-8 A37
Me Et Et D1-108b-8 A39 Me Me n-Pr D1-108b-8 A39
Me Et Et D1-108b-8 A40 Me Me n-Pr D1-108b-8 A40
Me Et Et D1-108b-8 A41 Me Me n-Pr D1-108b-8 A41
Me Et Et D1-108b-8 A73 Me Me n-Pr D1-108b-8 A73
Me Et Et D1-108b-8 A75 Me Me n-Pr D1-108b-8 A75
Me Et Et D1-108b-8 A83 Me Me n-Pr D1-108b-8 A83
Me Et Et D1-108b-8 A84 Me Me n-Pr D1-108b-8 A84
Me Et Et D1-108b-8 A85 Me Me n-Pr D1-108b-8 A85
Me Et Et D1-108b-8 A91 Me Me n-Pr D1-108b-8 A91
Me Et Et D1-108b-9 H Me Me n-Pr D1-108b-9 H
Me Et Et D1-108b-9 Me Me Me n-Pr D1-108b-9 Me
Me Et Et D1-108b-9 A11 Me Me n-Pr D1-108b-9 A11
Me Et Et D1-108b-9 A34 Me Me n-Pr D1-108b-9 A34
Me Et Et D1-108b-9 A35 Me Me n-Pr D1-108b-9 A35
Me Et Et D1-108b-9 A37 Me Me n-Pr D1-108b-9 A37
Me Et Et D1-108b-9 A39 Me Me n-Pr D1-108b-9 A39
Me Et Et D1-108b-9 A40 Me Me n-Pr D1-108b-9 A40
Me Et Et D1-108b-9 A41 Me Me n-Pr D1-108b-9 A41
Me Et Et D1-108b-9 A73 Me Me n-Pr D1-108b-9 A73
Me Et Et D1-108b-9 A75 Me Me n-Pr D1-108b-9 A75
Me Et Et D1-108b-9 A83 Me Me n-Pr D1-108b-9 A83
Me Et Et D1-108b-9 A84 Me Me n-Pr D1-108b-9 A84
Me Et Et D1-108b-9 A85 Me Me n-Pr D1-108b-9 A85
Me Et Et D1-108b-9 A91 Me Me n-Pr D1-108b-9 A91
Me Et Et D1-108b-10 H Me Me n-Pr D1-108b-10 H
Me Et Et D1-108b-10 Me Me Me n-Pr D1-108b-10 Me
Me Et Et D1-108b-10 A11 Me Me n-Pr D1-108b-10 A11
Me Et Et D1-108b-10 A34 Me Me n-Pr D1-108b-10 A34
Me Et Et D1-108b-10 A35 Me Me n-Pr D1-108b-10 A35
Me Et Et D1-108b-10 A37 Me Me n-Pr D1-108b-10 A37
Me Et Et D1-108b-10 A39 Me Me n-Pr D1-108b-10 A39
Me Et Et D1-108b-10 A40 Me Me n-Pr D1-108b-10 A40
Me Et Et D1-108b-10 A41 Me Me n-Pr D1-108b-10 A41
Me Et Et D1-108b-10 A73 Me Me n-Pr D1-108b-10 A73
Me Et Et D1-108b-10 A75 Me Me n-Pr D1-108b-10 A75
Me Et Et D1-108b-10 A83 Me Me n-Pr D1-108b-10 A83
Me Et Et D1-108b-10 A84 Me Me n-Pr D1-108b-10 A84
Me Et Et D1-108b-10 A85 Me Me n-Pr D1-108b-10 A85
Me Et Et D1-108b-10 A91 Me Me n-Pr D1-108b-10 A91
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et D1-108b-11 H Me Me n-Pr D1-108b-11 H
Me Et Et D1-108b-12 H Me Me n-Pr D1-108b-12 H
Me Et Et D1-108b-12 Me Me Me n-Pr D1-108b-12 Me
Me Et Et D1-108b-12 A11 Me Me n-Pr D1-108b-12 A11
Me Et Et D1-108b-12 A34 Me Me n-Pr D1-108b-12 A34
Me Et Et D1-108b-12 A35 Me Me n-Pr D1-108b-12 A35
Me Et Et D1-108b-12 A37 Me Me n-Pr D1-108b-12 A37
Me Et Et D1-108b-12 A39 Me Me n-Pr D1-108b-12 A39
Me Et Et D1-108b-12 A40 Me Me n-Pr D1-108b-12 A40
Me Et Et D1-108b-12 A41 Me Me n-Pr D1-108b-12 A41
Me Et Et D1-108b-12 A73 Me Me n-Pr D1-108b-12 A73
Me Et Et D1-108b-12 A75 Me Me n-Pr D1-108b-12 A75
Me Et Et D1-108b-12 A83 Me Me n-Pr D1-108b-12 A83
Me Et Et D1-108b-12 A84 Me Me n-Pr D1-108b-12 A84
Me Et Et D1-108b-12 A85 Me Me n-Pr D1-108b-12 A85
Me Et Et D1-108b-12 A91 Me Me n-Pr D1-108b-12 A91
Me Et Et D1-108b-13 H Me Me n-Pr D1-108b-13 H
Me Et Et D1-108b-14 H Me Me n-Pr D1-108b-14 H
Me Et Et D1-108b-15 H Me Me n-Pr D1-108b-15 H
Me Et Et D1-108b-16 H Me Me n-Pr D1-108b-16 H
Me Et Et D1-108b-17 H Me Me n-Pr D1-108b-17 H
Me Et Et D1-108b-18 H Me Me n-Pr D1-108b-18 H
Me Et Et D1-108b-19 H Me Me n-Pr D1-108b-19 H
Me Et Et D1-2a H Me Me n-Pr D1-2a H
Me Et Et D1-2b H Me Me n-Pr D1-2b H
Me Et Et D1-7a H Me Me n-Pr D1-7a H
Me Et Et D1-7b-1 H Me Me n-Pr D1-7b-1 H
Me Et Et D1-7b-1 A39 Me Me n-Pr D1-7b-1 A39
Me Et Et D1-7b-1 A40 Me Me n-Pr D1-7b-1 A40
Me Et Et D1-7b-1 A41 Me Me n-Pr D1-7b-1 A41
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
c-Pr Et Et D1-7b-1 H c-Pr Me n-Pr D1-7b-1 H
c-Pr Et Et D1-7b-1 A39 c-Pr Me n-Pr D1-7b-1 A39
c-Pr Et Et D1-7b-1 A40 c-Pr Me n-Pr D1-7b-1 A40
c-Pr Et Et D1-7b-1 A41 c-Pr Me n-Pr D1-7b-1 A41
c-Bu Et Et D1-7b-1 H c-Bu Me n-Pr D1-7b-1 H
c-Bu Et Et D1-7b-1 A39 c-Bu Me n-Pr D1-7b-1 A39
c-Bu Et Et D1-7b-1 A40 c-Bu Me n-Pr D1-7b-1 A40
c-Bu Et Et D1-7b-1 A41 c-Bu Me n-Pr D1-7b-1 A41
c-Pen Et Et D1-7b-1 H c-Pen Me n-Pr D1-7b-1 H
c-Pen Et Et D1-7b-1 A39 c-Pen Me n-Pr D1-7b-1 A39
c-Pen Et Et D1-7b-1 A40 c-Pen Me n-Pr D1-7b-1 A40
c-Pen Et Et D1-7b-1 A41 c-Pen Me n-Pr D1-7b-1 A41
c-Hex Et Et D1-7b-1 H c-Hex Me n-Pr D1-7b-1 H
c-Hex Et Et D1-7b-1 A39 c-Hex Me n-Pr D1-7b-1 A39
c-Hex Et Et D1-7b-1 A40 c-Hex Me n-Pr D1-7b-1 A40
c-Hex Et Et D1-7b-1 A41 c-Hex Me n-Pr D1-7b-1 A41
Me Et Et D1-7b-2 H Me Me n-Pr D1-7b-2 H
Me Et Et D1-7b-2 A39 Me Me n-Pr D1-7b-2 A39
Me Et Et D1-7b-2 A40 Me Me n-Pr D1-7b-2 A40
Me Et Et D1-7b-2 A41 Me Me n-Pr D1-7b-2 A41
c-Pr Et Et D1-7b-2 H c-Pr Me n-Pr D1-7b-2 H
c-Pr Et Et D1-7b-2 A39 c-Pr Me n-Pr D1-7b-2 A39
c-Pr Et Et D1-7b-2 A40 c-Pr Me n-Pr D1-7b-2 A40
c-Pr Et Et D1-7b-2 A41 c-Pr Me n-Pr D1-7b-2 A41
c-Bu Et Et D1-7b-2 H c-Bu Me n-Pr D1-7b-2 H
c-Bu Et Et D1-7b-2 A39 c-Bu Me n-Pr D1-7b-2 A39
c-Bu Et Et D1-7b-2 A40 c-Bu Me n-Pr D1-7b-2 A40
c-Bu Et Et D1-7b-2 A41 c-Bu Me n-Pr D1-7b-2 A41
c-Pen Et Et D1-7b-2 H c-Pen Me n-Pr D1-7b-2 H
c-Pen Et Et D1-7b-2 A39 c-Pen Me n-Pr D1-7b-2 A39
c-Pen Et Et D1-7b-2 A40 c-Pen Me n-Pr D1-7b-2 A40
c-Pen Et Et D1-7b-2 A41 c-Pen Me n-Pr D1-7b-2 A41
c-Hex Et Et D1-7b-2 H c-Hex Me n-Pr D1-7b-2 H
c-Hex Et Et D1-7b-2 A39 c-Hex Me n-Pr D1-7b-2 A39
c-Hex Et Et D1-7b-2 A40 c-Hex Me n-Pr D1-7b-2 A40
c-Hex Et Et D1-7b-2 A41 c-Hex Me n-Pr D1-7b-2 A41
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et D1-7b-3 H Me Me n-Pr D1-7b-3 H
Me Et Et D1-7b-3 A39 Me Me n-Pr D1-7b-3 A39
Me Et Et D1-7b-3 A40 Me Me n-Pr D1-7b-3 A40
Me Et Et D1-7b-3 A41 Me Me n-Pr D1-7b-3 A41
c-Pr Et Et D1-7b-3 H c-Pr Me n-Pr D1-7b-3 H
c-Pr Et Et D1-7b-3 A39 c-Pr Me n-Pr D1-7b-3 A39
c-Pr Et Et D1-7b-3 A40 c-Pr Me n-Pr D1-7b-3 A40
c-Pr Et Et D1-7b-3 A41 c-Pr Me n-Pr D1-7b-3 A41
c-Bu Et Et D1-7b-3 H c-Bu Me n-Pr D1-7b-3 H
c-Bu Et Et D1-7b-3 A39 c-Bu Me n-Pr D1-7b-3 A39
c-Bu Et Et D1-7b-3 A40 c-Bu Me n-Pr D1-7b-3 A40
c-Bu Et Et D1-7b-3 A41 c-Bu Me n-Pr D1-7b-3 A41
c-Pen Et Et D1-7b-3 H c-Pen Me n-Pr D1-7b-3 H
c-Pen Et Et D1-7b-3 A39 c-Pen Me n-Pr D1-7b-3 A39
c-Pen Et Et D1-7b-3 A40 c-Pen Me n-Pr D1-7b-3 A40
c-Pen Et Et D1-7b-3 A41 c-Pen Me n-Pr D1-7b-3 A41
c-Hex Et Et D1-7b-3 H c-Hex Me n-Pr D1-7b-3 H
c-Hex Et Et D1-7b-3 A39 c-Hex Me n-Pr D1-7b-3 A39
c-Hex Et Et D1-7b-3 A40 c-Hex Me n-Pr D1-7b-3 A40
c-Hex Et Et D1-7b-3 A41 c-Hex Me n-Pr D1-7b-3 A41
Me Et Et D1-7b-4 H Me Me n-Pr D1-7b-4 H
Me Et Et D1-7b-4 A39 Me Me n-Pr D1-7b-4 A39
Me Et Et D1-7b-4 A40 Me Me n-Pr D1-7b-4 A40
Me Et Et D1-7b-4 A41 Me Me n-Pr D1-7b-4 A41
c-Pr Et Et D1-7b-4 H c-Pr Me n-Pr D1-7b-4 H
c-Pr Et Et D1-7b-4 A39 c-Pr Me n-Pr D1-7b-4 A39
c-Pr Et Et D1-7b-4 A40 c-Pr Me n-Pr D1-7b-4 A40
c-Pr Et Et D1-7b-4 A41 c-Pr Me n-Pr D1-7b-4 A41
c-Bu Et Et D1-7b-4 H c-Bu Me n-Pr D1-7b-4 H
c-Bu Et Et D1-7b-4 A39 c-Bu Me n-Pr D1-7b-4 A39
c-Bu Et Et D1-7b-4 A40 c-Bu Me n-Pr D1-7b-4 A40
c-Bu Et Et D1-7b-4 A41 c-Bu Me n-Pr D1-7b-4 A41
c-Pen Et Et D1-7b-4 H c-Pen Me n-Pr D1-7b-4 H
c-Pen Et Et D1-7b-4 A39 c-Pen Me n-Pr D1-7b-4 A39
c-Pen Et Et D1-7b-4 A40 c-Pen Me n-Pr D1-7b-4 A40
c-Pen Et Et D1-7b-4 A41 c-Pen Me n-Pr D1-7b-4 A41
c-Hex Et Et D1-7b-4 H c-Hex Me n-Pr D1-7b-4 H
c-Hex Et Et D1-7b-4 A39 c-Hex Me n-Pr D1-7b-4 A39
c-Hex Et Et D1-7b-4 A40 c-Hex Me n-Pr D1-7b-4 A40
c-Hex Et Et D1-7b-4 A41 c-Hex Me n-Pr D1-7b-4 A41
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et D1-10a H Me Me n-Pr D1-10a H
Me Et Et D1-11a H Me Me n-Pr D1-11a H
Me Et Et D1-11b-1 H Me Me n-Pr D1-11b-1 H
Me Et Et D1-11b-2 H Me Me n-Pr D1-11b-2 H
Me Et Et D1-11b-3 H Me Me n-Pr D1-11b-3 H
Me Et Et D1-11b-4 H Me Me n-Pr D1-11b-4 H
Me Et Et D1-22a H Me Me n-Pr D1-22a H
Me Et Et D1-22b-1 H Me Me n-Pr D1-22b-1 H
Me Et Et D1-22b-2 H Me Me n-Pr D1-22b-2 H
Me Et Et D1-22b-3 H Me Me n-Pr D1-22b-3 H
Me Et Et D1-22b-4 H Me Me n-Pr D1-22b-4 H
Me Et Et D1-32a H Me Me n-Pr D1-32a H
Me Et Et D1-32b-1 H Me Me n-Pr D1-32b-1 H
Me Et Et D1-32b-2 H Me Me n-Pr D1-32b-2 H
Me Et Et D1-32b-3 H Me Me n-Pr D1-32b-3 H
Me Et Et D1-32b-4 H Me Me n-Pr D1-32b-4 H
Me Et Et D1-32b-5 H Me Me n-Pr D1-32b-5 H
Me Et Et D1-33a H Me Me n-Pr D1-33a H
Me Et Et D1-33b-1 H Me Me n-Pr D1-33b-1 H
Me Et Et D1-33b-2 H Me Me n-Pr D1-33b-2 H
Me Et Et D1-33b-3 H Me Me n-Pr D1-33b-3 H
Me Et Et D1-33b-4 H Me Me n-Pr D1-33b-4 H
Me Et Et D1-34a H Me Me n-Pr D1-34a H
Me Et Et D1-37a H Me Me n-Pr D1-37a H
Me Et Et D1-37b-1 H Me Me n-Pr D1-37b-1 H
Me Et Et C≡CH H Me Me n-Pr C≡CH H
Me Et Et C≡CH A39 Me Me n-Pr C≡CH A39
Me Et Et C≡CH A40 Me Me n-Pr C≡CH A40
Me Et Et C≡CH A41 Me Me n-Pr C≡CH A41
c-Pr Et Et C≡CH H c-Pr Me n-Pr C≡CH H
c-Pr Et Et C≡CH A39 c-Pr Me n-Pr C≡CH A39
c-Pr Et Et C≡CH A40 c-Pr Me n-Pr C≡CH A40
c-Pr Et Et C≡CH A41 c-Pr Me n-Pr C≡CH A41
c-Bu Et Et C≡CH H c-Bu Me n-Pr C≡CH H
c-Bu Et Et C≡CH A39 c-Bu Me n-Pr C≡CH A39
c-Bu Et Et C≡CH A40 c-Bu Me n-Pr C≡CH A40
c-Bu Et Et C≡CH A41 c-Bu Me n-Pr C≡CH A41
c-Pen Et Et C≡CH H c-Pen Me n-Pr C≡CH H
c-Pen Et Et C≡CH A39 c-Pen Me n-Pr C≡CH A39
c-Pen Et Et C≡CH A40 c-Pen Me n-Pr C≡CH A40
c-Pen Et Et C≡CH A41 c-Pen Me n-Pr C≡CH A41
c-Hex Et Et C≡CH H c-Hex Me n-Pr C≡CH H
c-Hex Et Et C≡CH A39 c-Hex Me n-Pr C≡CH A39
c-Hex Et Et C≡CH A40 c-Hex Me n-Pr C≡CH A40
c-Hex Et Et C≡CH A41 c-Hex Me n-Pr C≡CH A41
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et C≡CBu-c H Me Me n-Pr C≡CBu-c H
Me Et Et C≡CBu-c A39 Me Me n-Pr C≡CBu-c A39
Me Et Et C≡CBu-c A40 Me Me n-Pr C≡CBu-c A40
Me Et Et C≡CBu-c A41 Me Me n-Pr C≡CBu-c A41
c-Pr Et Et C≡CBu-c H c-Pr Me n-Pr C≡CBu-c H
c-Pr Et Et C≡CBu-c A39 c-Pr Me n-Pr C≡CBu-c A39
c-Pr Et Et C≡CBu-c A40 c-Pr Me n-Pr C≡CBu-c A40
c-Pr Et Et C≡CBu-c A41 c-Pr Me n-Pr C≡CBu-c A41
c-Bu Et Et C≡CBu-c H c-Bu Me n-Pr C≡CBu-c H
c-Bu Et Et C≡CBu-c A39 c-Bu Me n-Pr C≡CBu-c A39
c-Bu Et Et C≡CBu-c A40 c-Bu Me n-Pr C≡CBu-c A40
c-Bu Et Et C≡CBu-c A41 c-Bu Me n-Pr C≡CBu-c A41
c-Pen Et Et C≡CBu-c H c-Pen Me n-Pr C≡CBu-c H
c-Pen Et Et C≡CBu-c A39 c-Pen Me n-Pr C≡CBu-c A39
c-Pen Et Et C≡CBu-c A40 c-Pen Me n-Pr C≡CBu-c A40
c-Pen Et Et C≡CBu-c A41 c-Pen Me n-Pr C≡CBu-c A41
c-Hex Et Et C≡CBu-c H c-Hex Me n-Pr C≡CBu-c H
c-Hex Et Et C≡CBu-c A39 c-Hex Me n-Pr C≡CBu-c A39
c-Hex Et Et C≡CBu-c A40 c-Hex Me n-Pr C≡CBu-c A40
c-Hex Et Et C≡CBu-c A41 c-Hex Me n-Pr C≡CBu-c A41
Me Et Et C≡CPen-c H Me Me n-Pr C≡CPen-c H
Me Et Et C≡CPen-c A39 Me Me n-Pr C≡CPen-c A39
Me Et Et C≡CPen-c A40 Me Me n-Pr C≡CPen-c A40
Me Et Et C≡CPen-c A41 Me Me n-Pr C≡CPen-c A41
c-Pr Et Et C≡CPen-c H c-Pr Me n-Pr C≡CPen-c H
c-Pr Et Et C≡CPen-c A39 c-Pr Me n-Pr C≡CPen-c A39
c-Pr Et Et C≡CPen-c A40 c-Pr Me n-Pr C≡CPen-c A40
c-Pr Et Et C≡CPen-c A41 c-Pr Me n-Pr C≡CPen-c A41
c-Bu Et Et C≡CPen-c H c-Bu Me n-Pr C≡CPen-c H
c-Bu Et Et C≡CPen-c A39 c-Bu Me n-Pr C≡CPen-c A39
c-Bu Et Et C≡CPen-c A40 c-Bu Me n-Pr C≡CPen-c A40
c-Bu Et Et C≡CPen-c A41 c-Bu Me n-Pr C≡CPen-c A41
c-Pen Et Et C≡CPen-c H c-Pen Me n-Pr C≡CPen-c H
c-Pen Et Et C≡CPen-c A39 c-Pen Me n-Pr C≡CPen-c A39
c-Pen Et Et C≡CPen-c A40 c-Pen Me n-Pr C≡CPen-c A40
c-Pen Et Et C≡CPen-c A41 c-Pen Me n-Pr C≡CPen-c A41
c-Hex Et Et C≡CPen-c H c-Hex Me n-Pr C≡CPen-c H
c-Hex Et Et C≡CPen-c A39 c-Hex Me n-Pr C≡CPen-c A39
c-Hex Et Et C≡CPen-c A40 c-Hex Me n-Pr C≡CPen-c A40
c-Hex Et Et C≡CPen-c A41 c-Hex Me n-Pr C≡CPen-c A41
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et C≡CHex-c H Me Me n-Pr C≡CHex-c H
Me Et Et C≡CHex-c A39 Me Me n-Pr C≡CHex-c A39
Me Et Et C≡CHex-c A40 Me Me n-Pr C≡CHex-c A40
Me Et Et C≡CHex-c A41 Me Me n-Pr C≡CHex-c A41
c-Pr Et Et C≡CHex-c H c-Pr Me n-Pr C≡CHex-c H
c-Pr Et Et C≡CHex-c A39 c-Pr Me n-Pr C≡CHex-c A39
c-Pr Et Et C≡CHex-c A40 c-Pr Me n-Pr C≡CHex-c A40
c-Pr Et Et C≡CHex-c A41 c-Pr Me n-Pr C≡CHex-c A41
c-Bu Et Et C≡CHex-c H c-Bu Me n-Pr C≡CHex-c H
c-Bu Et Et C≡CHex-c A39 c-Bu Me n-Pr C≡CHex-c A39
c-Bu Et Et C≡CHex-c A40 c-Bu Me n-Pr C≡CHex-c A40
c-Bu Et Et C≡CHex-c A41 c-Bu Me n-Pr C≡CHex-c A41
c-Pen Et Et C≡CHex-c H c-Pen Me n-Pr C≡CHex-c H
c-Pen Et Et C≡CHex-c A39 c-Pen Me n-Pr C≡CHex-c A39
c-Pen Et Et C≡CHex-c A40 c-Pen Me n-Pr C≡CHex-c A40
c-Pen Et Et C≡CHex-c A41 c-Pen Me n-Pr C≡CHex-c A41
c-Hex Et Et C≡CHex-c H c-Hex Me n-Pr C≡CHex-c H
c-Hex Et Et C≡CHex-c A39 c-Hex Me n-Pr C≡CHex-c A39
c-Hex Et Et C≡CHex-c A40 c-Hex Me n-Pr C≡CHex-c A40
c-Hex Et Et C≡CHex-c A41 c-Hex Me n-Pr C≡CHex-c A41
―――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ―――――――――――――――――
Me OMe Me Me H Me OMe Et Me H
Me OMe Me Me A13 Me OMe Et Me A13
Me OMe Me Me A14 Me OMe Et Me A14
Me OMe Me Me A16 Me OMe Et Me A16
Me OMe Me Me A35 Me OMe Et Me A35
Me OMe Me Me A38 Me OMe Et Me A38
Me OMe Me Me A39 Me OMe Et Me A39
Me OMe Me Me A40 Me OMe Et Me A40
Me OMe Me Me A41 Me OMe Et Me A41
Me OMe Me Me A73 Me OMe Et Me A73
Me OMe Me Me A74 Me OMe Et Me A74
Me OMe Me Me A75 Me OMe Et Me A75
Me OMe Me Me A81 Me OMe Et Me A81
Me OMe Me Me A82 Me OMe Et Me A82
Me OMe Me Me A83 Me OMe Et Me A83
Me OMe Me Me A84 Me OMe Et Me A84
Me OMe Me Me A85 Me OMe Et Me A85
Me OMe Me Me A86 Me OMe Et Me A86
Me OMe Me Me A87 Me OMe Et Me A87
Me OMe Me Me A91 Me OMe Et Me A91
Me OMe Me Me A92 Me OMe Et Me A92
Me OMe Me Me A93 Me OMe Et Me A93
Me OMe Me Me A94 Me OMe Et Me A94
Me OMe Me Me A95 Me OMe Et Me A95
Me OMe Me Me A97 Me OMe Et Me A97
Et OMe Me Me H Et OMe Et Me H
Et OMe Me Me A13 Et OMe Et Me A13
Et OMe Me Me A14 Et OMe Et Me A14
Et OMe Me Me A16 Et OMe Et Me A16
Et OMe Me Me A35 Et OMe Et Me A35
Et OMe Me Me A38 Et OMe Et Me A38
Et OMe Me Me A39 Et OMe Et Me A39
Et OMe Me Me A40 Et OMe Et Me A40
Et OMe Me Me A41 Et OMe Et Me A41
Et OMe Me Me A73 Et OMe Et Me A73
Et OMe Me Me A74 Et OMe Et Me A74
Et OMe Me Me A75 Et OMe Et Me A75
Et OMe Me Me A81 Et OMe Et Me A81
Et OMe Me Me A82 Et OMe Et Me A82
Et OMe Me Me A83 Et OMe Et Me A83
Et OMe Me Me A84 Et OMe Et Me A84
Et OMe Me Me A85 Et OMe Et Me A85
Et OMe Me Me A86 Et OMe Et Me A86
Et OMe Me Me A87 Et OMe Et Me A87
Et OMe Me Me A91 Et OMe Et Me A91
Et OMe Me Me A92 Et OMe Et Me A92
Et OMe Me Me A93 Et OMe Et Me A93
Et OMe Me Me A94 Et OMe Et Me A94
Et OMe Me Me A95 Et OMe Et Me A95
Et OMe Me Me A97 Et OMe Et Me A97
――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ―――――――――――――――――
Me OMe n-Pr Me H Me OEt Me Me H
Me OMe n-Pr Me A13 Me OEt Me Me A13
Me OMe n-Pr Me A14 Me OEt Me Me A14
Me OMe n-Pr Me A16 Me OEt Me Me A16
Me OMe n-Pr Me A35 Me OEt Me Me A35
Me OMe n-Pr Me A38 Me OEt Me Me A38
Me OMe n-Pr Me A39 Me OEt Me Me A39
Me OMe n-Pr Me A40 Me OEt Me Me A40
Me OMe n-Pr Me A41 Me OEt Me Me A41
Me OMe n-Pr Me A73 Me OEt Me Me A73
Me OMe n-Pr Me A74 Me OEt Me Me A74
Me OMe n-Pr Me A75 Me OEt Me Me A75
Me OMe n-Pr Me A81 Me OEt Me Me A81
Me OMe n-Pr Me A82 Me OEt Me Me A82
Me OMe n-Pr Me A83 Me OEt Me Me A83
Me OMe n-Pr Me A84 Me OEt Me Me A84
Me OMe n-Pr Me A85 Me OEt Me Me A85
Me OMe n-Pr Me A86 Me OEt Me Me A86
Me OMe n-Pr Me A87 Me OEt Me Me A87
Me OMe n-Pr Me A91 Me OEt Me Me A91
Me OMe n-Pr Me A92 Me OEt Me Me A92
Me OMe n-Pr Me A93 Me OEt Me Me A93
Me OMe n-Pr Me A94 Me OEt Me Me A94
Me OMe n-Pr Me A95 Me OEt Me Me A95
Me OMe n-Pr Me A97 Me OEt Me Me A97
Et OMe n-Pr Me H Et OEt Me Me H
Et OMe n-Pr Me A13 Et OEt Me Me A13
Et OMe n-Pr Me A14 Et OEt Me Me A14
Et OMe n-Pr Me A16 Et OEt Me Me A16
Et OMe n-Pr Me A35 Et OEt Me Me A35
Et OMe n-Pr Me A38 Et OEt Me Me A38
Et OMe n-Pr Me A39 Et OEt Me Me A39
Et OMe n-Pr Me A40 Et OEt Me Me A40
Et OMe n-Pr Me A41 Et OEt Me Me A41
Et OMe n-Pr Me A73 Et OEt Me Me A73
Et OMe n-Pr Me A74 Et OEt Me Me A74
Et OMe n-Pr Me A75 Et OEt Me Me A75
Et OMe n-Pr Me A81 Et OEt Me Me A81
Et OMe n-Pr Me A82 Et OEt Me Me A82
Et OMe n-Pr Me A83 Et OEt Me Me A83
Et OMe n-Pr Me A84 Et OEt Me Me A84
Et OMe n-Pr Me A85 Et OEt Me Me A85
Et OMe n-Pr Me A86 Et OEt Me Me A86
Et OMe n-Pr Me A87 Et OEt Me Me A87
Et OMe n-Pr Me A91 Et OEt Me Me A91
Et OMe n-Pr Me A92 Et OEt Me Me A92
Et OMe n-Pr Me A93 Et OEt Me Me A93
Et OMe n-Pr Me A94 Et OEt Me Me A94
Et OMe n-Pr Me A95 Et OEt Me Me A95
Et OMe n-Pr Me A97 Et OEt Me Me A97
――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
――――――――――――――― ―――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――― ―――――――――――――――――
Me OEt Et Me H Me OMe Me Et H
Me OEt Et Me A13 Me OMe Me Et A13
Me OEt Et Me A14 Me OMe Me Et A14
Me OEt Et Me A16 Me OMe Me Et A16
Me OEt Et Me A35 Me OMe Me Et A35
Me OEt Et Me A38 Me OMe Me Et A38
Me OEt Et Me A39 Me OMe Me Et A39
Me OEt Et Me A40 Me OMe Me Et A40
Me OEt Et Me A41 Me OMe Me Et A41
Me OEt Et Me A73 Me OMe Me Et A73
Me OEt Et Me A74 Me OMe Me Et A74
Me OEt Et Me A75 Me OMe Me Et A75
Me OEt Et Me A81 Me OMe Me Et A81
Me OEt Et Me A82 Me OMe Me Et A82
Me OEt Et Me A83 Me OMe Me Et A83
Me OEt Et Me A84 Me OMe Me Et A84
Me OEt Et Me A85 Me OMe Me Et A85
Me OEt Et Me A86 Me OMe Me Et A86
Me OEt Et Me A87 Me OMe Me Et A87
Me OEt Et Me A91 Me OMe Me Et A91
Me OEt Et Me A92 Me OMe Me Et A92
Me OEt Et Me A93 Me OMe Me Et A93
Me OEt Et Me A94 Me OMe Me Et A94
Me OEt Et Me A95 Me OMe Me Et A95
Me OEt Et Me A97 Me OMe Me Et A97
Et OEt Et Me H Et OMe Me Et H
Et OEt Et Me A13 Et OMe Me Et A13
Et OEt Et Me A14 Et OMe Me Et A14
Et OEt Et Me A16 Et OMe Me Et A16
Et OEt Et Me A35 Et OMe Me Et A35
Et OEt Et Me A38 Et OMe Me Et A38
Et OEt Et Me A39 Et OMe Me Et A39
Et OEt Et Me A40 Et OMe Me Et A40
Et OEt Et Me A41 Et OMe Me Et A41
Et OEt Et Me A73 Et OMe Me Et A73
Et OEt Et Me A74 Et OMe Me Et A74
Et OEt Et Me A75 Et OMe Me Et A75
Et OEt Et Me A81 Et OMe Me Et A81
Et OEt Et Me A82 Et OMe Me Et A82
Et OEt Et Me A83 Et OMe Me Et A83
Et OEt Et Me A84 Et OMe Me Et A84
Et OEt Et Me A85 Et OMe Me Et A85
Et OEt Et Me A86 Et OMe Me Et A86
Et OEt Et Me A87 Et OMe Me Et A87
Et OEt Et Me A91 Et OMe Me Et A91
Et OEt Et Me A92 Et OMe Me Et A92
Et OEt Et Me A93 Et OMe Me Et A93
Et OEt Et Me A94 Et OMe Me Et A94
Et OEt Et Me A95 Et OMe Me Et A95
Et OEt Et Me A97 Et OMe Me Et A97
――――――――――――――― ―――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ――――――――――――――――
Me Me Me OCH₂CF₃ H Me Me Et OCH₂CF₃ H
Me Et Et OCH₂CF₃ H Me Me n-Pr OCH₂CF₃ H
Me Me Me OCF₃ H Me Me Et OCF₃ H
Me Et Et OCF₃ H Me Me n-Pr OCF₃ H
Me Me Me OCF₂H H Me Me Et OCF₂H H
Me Et Et OCF₂H H Me Me n-Pr OCF₂H H
Me Me Me OCF₂Cl H Me Me Et OCF₂Cl H
Me Et Et OCF₂Cl H Me Me n-Pr OCF₂Cl H
Me Me Me OCF₂Br H Me Me Et OCF₂Br H
Me Et Et OCF₂Br H Me Me n-Pr OCF₂Br H
Me Me Me O(D1-32a) H Me Et Et O(D1-32a) H
Me Me Me O(D1-32b-2) H Me Et Et O(D1-32b-2) H
Me Me Me O(D1-32b-3) H Me Et Et O(D1-32b-3) H
Me Me Me O(D1-32b-4) H Me Et Et O(D1-32b-4) H
Me Me Me O(D1-32b-5) H Me Et Et O(D1-32b-5) H
Me Me Me O(D1-33a) H Me Me Me O(D1-33a) H
Me Me Me O(D1-33b-1) H Me Me Me O(D1-33b-1) H
Me Me Me O(D1-33b-2) H Me Me Me O(D1-33b-2) H
Me Me Me O(D1-33b-3) H Me Me Me O(D1-33b-3) H
Me Me Me O(D1-33b-4) H Me Me Me O(D1-33b-4) H
Me OMe Me Ph H Me OMe Et Ph H
Me OMe Me Ph A39 Me OMe Et Ph A39
Me OMe Me Ph A40 Me OMe Et Ph A40
Me OMe Me Ph A41 Me OMe Et Ph A41
Me OMe Me D1-108b-4 H Me OMe Et D1-108b-4 H
Me OMe Me D1-108b-4 A39 Me OMe Et D1-108b-4 A39
Me OMe Me D1-108b-4 A40 Me OMe Et D1-108b-4 A40
Me OMe Me D1-108b-4 A41 Me OMe Et D1-108b-4 A41
Me OMe Me D1-108b-4 A74 Me OMe Et D1-108b-4 A74
Me OMe Me D1-108b-4 A75 Me OMe Et D1-108b-4 A75
Me OMe Me D1-108b-4 A84 Me OMe Et D1-108b-4 A84
Me OMe Me D1-108b-4 A85 Me OMe Et D1-108b-4 A85
Me OMe Me D1-108b-4 A86 Me OMe Et D1-108b-4 A86
Me OMe Me D1-108b-4 A87 Me OMe Et D1-108b-4 A87
Me OMe Me D1-108b-8 H Me OMe Et D1-108b-8 H
Me OMe Me D1-108b-8 A39 Me OMe Et D1-108b-8 A39
Me OMe Me D1-108b-8 A40 Me OMe Et D1-108b-8 A40
Me OMe Me D1-108b-8 A41 Me OMe Et D1-108b-8 A41
Me OMe Me D1-108b-8 A74 Me OMe Et D1-108b-8 A74
Me OMe Me D1-108b-8 A75 Me OMe Et D1-108b-8 A75
Me OMe Me D1-108b-8 A84 Me OMe Et D1-108b-8 A84
Me OMe Me D1-108b-8 A85 Me OMe Et D1-108b-8 A85
Me OMe Me D1-108b-8 A86 Me OMe Et D1-108b-8 A86
Me OMe Me D1-108b-8 A87 Me OMe Et D1-108b-8 A87
Me OMe Me Br H Me OMe Et Br H
Me SMe Me Me H Me SMe Et Me H
c-Pr OMe Me Me H c-Pr OMe Et Me H
c-Pr OMe Me Me A12 c-Pr OMe Et Me A12
c-Pr OMe Me Me A13 c-Pr OMe Et Me A13
c-Pr OMe Me Me A74 c-Pr OMe Et Me A74
c-Bu OMe Me Me H c-Bu OMe Et Me H
c-Bu OMe Me Me A12 c-Bu OMe Et Me A12
c-Bu OMe Me Me A13 c-Bu OMe Et Me A13
c-Bu OMe Me Me A74 c-Bu OMe Et Me A74
c-Pen OMe Me Me H c-Pen OMe Et Me H
c-Pen OMe Me Me A12 c-Pen OMe Et Me A12
c-Pen OMe Me Me A13 c-Pen OMe Et Me A13
c-Pen OMe Me Me A74 c-Pen OMe Et Me A74
c-Hex OMe Me Me H c-Hex OMe Et Me H
―――――――――――――――― ――――――――――――――――
第１表（続き） 〔第１表〕（続き）
―――――――――――――――― ――――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
―――――――――――――――― ――――――――――――――――
Me OMe n-Pr Ph H Me OEt Me Ph H
Me OMe n-Pr Ph A39 Me OEt Me Ph A39
Me OMe n-Pr Ph A40 Me OEt Me Ph A40
Me OMe n-Pr Ph A41 Me OEt Me Ph A41
Me OMe n-Pr D1-108b-4 H Me OEt Me D1-108b-4 H
Me OMe n-Pr D1-108b-4 A39 Me OEt Me D1-108b-4 A39
Me OMe n-Pr D1-108b-4 A40 Me OEt Me D1-108b-4 A40
Me OMe n-Pr D1-108b-4 A41 Me OEt Me D1-108b-4 A41
Me OMe n-Pr D1-108b-4 A74 Me OEt Me D1-108b-4 A74
Me OMe n-Pr D1-108b-4 A75 Me OEt Me D1-108b-4 A75
Me OMe n-Pr D1-108b-4 A84 Me OEt Me D1-108b-4 A84
Me OMe n-Pr D1-108b-4 A85 Me OEt Me D1-108b-4 A85
Me OMe n-Pr D1-108b-4 A86 Me OEt Me D1-108b-4 A86
Me OMe n-Pr D1-108b-4 A87 Me OEt Me D1-108b-4 A87
Me OMe n-Pr D1-108b-8 H Me OEt Me D1-108b-8 H
Me OMe n-Pr D1-108b-8 A39 Me OEt Me D1-108b-8 A39
Me OMe n-Pr D1-108b-8 A40 Me OEt Me D1-108b-8 A40
Me OMe n-Pr D1-108b-8 A41 Me OEt Me D1-108b-8 A41
Me OMe n-Pr D1-108b-8 A74 Me OEt Me D1-108b-8 A74
Me OMe n-Pr D1-108b-8 A75 Me OEt Me D1-108b-8 A75
Me OMe n-Pr D1-108b-8 A84 Me OEt Me D1-108b-8 A84
Me OMe n-Pr D1-108b-8 A85 Me OEt Me D1-108b-8 A85
Me OMe n-Pr D1-108b-8 A86 Me OEt Me D1-108b-8 A86
Me OMe n-Pr D1-108b-8 A87 Me OEt Me D1-108b-8 A87
―――――――――――――――― ――――――――――――――――
第１表（続き） 〔第１表〕（続き）
――――――――――――――――― ――――――――――――――
R⁶ Z^a Z^e Z^c A R⁶ Z^a Z^e Z^c A
――――――――――――――――― ――――――――――――――
Me OMe n-Pr Br H Me OEt Me Br H
Me SMe n-Pr Me H Me SEt Me Me H
c-Pr OMe n-Pr Me H c-Pr OEt Me Me H
c-Pr OMe n-Pr Me A12 c-Pr OEt Me Me A12
c-Pr OMe n-Pr Me A13 c-Pr OEt Me Me A13
c-Pr OMe n-Pr Me A74 c-Pr OEt Me Me A74
c-Bu OMe n-Pr Me H c-Bu OEt Me Me H
c-Bu OMe n-Pr Me A12 c-Bu OEt Me Me A12
c-Bu OMe n-Pr Me A13 c-Bu OEt Me Me A13
c-Bu OMe n-Pr Me A74 c-Bu OEt Me Me A74
c-Pen OMe n-Pr Me H c-Pr OEt Me Me H
c-Pen OMe n-Pr Me A12 c-Pen OEt Me Me A12
c-Pen OMe n-Pr Me A13 c-Pen OEt Me Me A13
c-Pen OMe n-Pr Me A74 c-Pen OEt Me Me A74
c-Hex OMe n-Pr Me H c-Hex OEt Me Me H
Me OEt Et Ph H c-Hex OMe Me Me A12
Me OEt Et Ph A39 c-Hex OMe Me Me A13
Me OEt Et Ph A40 c-Hex OMe Me Me A74
Me OEt Et Ph A41 Me OMe Me Me H
Me OEt Et D1-108b-4 H Me OMe Br Me H
Me OEt Et D1-108b-4 A39 Me Me Me Me H
Me OEt Et D1-108b-4 A40 c-Hex OMe n-Pr Me A12
Me OEt Et D1-108b-4 A41 c-Hex OMe n-Pr Me A13
Me OEt Et D1-108b-4 A74 c-Hex OMe n-Pr Me A74
Me OEt Et D1-108b-4 A75 Me OMe n-Pr Me H
Me OEt Et D1-108b-4 A84 Me OMe n-Pr Me H
Me OEt Et D1-108b-4 A85 Me Me n-Pr Me H
Me OEt Et D1-108b-4 A86 Me OMe F Br H
Me OEt Et D1-108b-4 A87 Me OMe F Ph H
Me OEt Et D1-108b-8 H Me OMe F Me H
Me OEt Et D1-108b-8 A39 c-Hex OMe Et Me A12
Me OEt Et D1-108b-8 A40 c-Hex OMe Et Me A13
Me OEt Et D1-108b-8 A41 c-Hex OMe Et Me A74
Me OEt Et D1-108b-8 A74 Me OMe Et Me H
Me OEt Et D1-108b-8 A75 Me OMe Et Me H
Me OEt Et D1-108b-8 A84 Me Me Et Me H
Me OEt Et D1-108b-8 A85 c-Hex OEt Me Me A12
Me OEt Et D1-108b-8 A86 c-Hex OEt Me Me A13
Me OEt Et D1-108b-8 A87 c-Hex OEt Me Me A74
Me OEt Et Br H Me OMe Et Me H
Me SEt Et Me H Me OMe Et Me H
c-Pr OEt Et Me H Me Et Et Me H
c-Pr OEt Et Me A12 Me OEt F Br H
c-Pr OEt Et Me A13 Me OEt F Ph H
c-Pr OEt Et Me A74 Me OEt F Me H
c-Bu OEt Et Me H c-Pen OEt Et Me A13
c-Bu OEt Et Me A12 c-Pen OEt Et Me A74
c-Bu OEt Et Me A13 c-Hex OEt Et Me H
c-Bu OEt Et Me A74 c-Hex OEt Et Me A12
c-Pen OEt Et Me H c-Hex OEt Et Me A13
c-Pen OEt Et Me A12 c-Hex OEt Et Me A74
Me OMe F Br H Me OEt F Br H
Me OMe F Ph H Me OEt F Ph H
Me OMe F Me H Me OEt F Me H
Me OMe OMe Br H Me OH Me Br H
Et OMe OMe Br H Et OH Me Br H
c-Pr OMe OMe Br H c-Pr OH Me Br H
Me OEt Me C≡CMe H Me OEt Me Br Et
Et OEt Me C≡CMe H Et OEt Me Br Et
c-Pr OEt Me C≡CMe H c-Pr OEt Me Br Et
Et OEt Me D1-108b-4 H Et OEt Me Br H
c-Pr OEt Me D1-108b-4 H c-Pr OEt Me Br H
Et OMe Me Br H Et OEt Me Ph H
c-Pr OMe Me Br H c-Pr OEt Me Ph H
Et OEt Me D1-108b-8 H ――――――――――――――
c-Pr OEt Me D1-108b-8 H
―――――――――――――――――
本発明化合物は水田用の除草剤として、湛水下の土壌処理及び茎葉処理のいずれの処理方法においても使用できる。水田雑草としては、例えば、ヒルムシロ（Ｐｏｔａｍｏｇｅｔｏｎ ｄｉｓｔｉｎｃｔｕｓ）等に代表されるヒルムシロ科（Ｐｏｔａｍｏｇｅｔｏｎａｃｅａｅ）雑草、ヘラオモダカ（Ａｌｉｓｍａ ｃａｎａｌｉｃｕｌａｔｕｍ）、ウリカワ（Ｓａｇｉｔｔａｒｉａ ｐｙｇｍａｅａ）及びオモダカ（Ｓａｇｉｔｔａｒｉａ ｔｒｉｆｏｌｉａ）等に代表されるオモダカ科（Ａｌｉｓｍａｔａｃｅａｅ）雑草、アゼガヤ（Ｌｅｐｔｏｃｈｌｏａ ｃｈｉｎｅｎｓｉｓ）、イヌビエ（Ｅｃｈｉｎｏｃｈｌｏａ ｃｒｕｓ−ｇａｌｌｉ）、タイヌビエ（Ｅｃｈｉｎｏｃｈｌｏａ ｏｒｙｚｉｃｏｌａ）、アシカキ（Ｈｏｍａｌｏｃｅｎｃｈｒｕｓ ｊａｐｏｎｏｃｕｓ）及びキシュウスズメノヒエ（Ｐａｓｐａｌｕｍ ｄｉｓｔｉｃｈｕｍ）等に代表されるイネ科（Ｇｒａｍｉｎｅａｅ）雑草、クログワイ（Ｅｌｅｏｃｈａｒｉｓ ｋｕｒｏｇｕｗａｉ）、ホタルイ（Ｓｃｉｒｐｕｓ ｊｕｎｃｏｉｄｅｓ）、シズイ（Ｓｃｉｒｐｕｓ ｎｉｐｐｏｎｉｃｕｓ）、ミズガヤツリ（Ｃｙｐｅｒｕｓ ｓｅｒｏｔｉｎｕｓ）、タマガヤツリ（Ｃｙｐｅｒｕｓ ｄｉｆｆｏｒｍｉｓ）及びヒナガヤツリ（Ｃｙｐｅｒｕｓ ｈａｋｏｎｅｎｓｉｓ）等に代表されるカヤツリグサ科（Ｃｙｐｅｒａｃｅａｅ）雑草、ウキクサ（Ｓｐｉｒｏｄｅｌａ ｐｏｌｙｒｈｉｚａ）及びアオウキクサ（Ｌｅｍｎａ ｐａｕｃｉｃｏｓｔａｔａ）等に代表されるウキクサ科（Ｌｅｍｎａｃｅａｅ）雑草、イボクサ（Ｍｕｒｄａｎｎｉａ ｋｅｉｓａｋ）等に代表されるツユクサ科（Ｃｏｍｍｅｌｉｎａｃｅａｅ）雑草、ミズアオイ（Ｍｏｎｏｃｈｏｒｉａ ｋｏｒｓａｋｏｗｉｉ）及びコナギ（Ｍｏｎｏｃｈｏｒｉａ ｖａｇｉｎａｌｉｓ）等に代表されるミズアオイ科（Ｐｏｎｔｅｄｅｒｉａｃｅａｅ）雑草、ミゾハコベ（Ｅｌａｔｉｎｅ ｔｒｉａｎｄｒａ）等に代表されるミゾハコベ科（Ｅｌａｔｉｎａｃｅａｅ）雑草、ヒメミソハギ（Ａｍｍａｎｎｉａ ｍｕｌｔｉｆｌｏｒａ）及びキカシグサ（Ｒｏｔａｌａ ｉｎｄｉｃａ）等に代表されるミソハギ科（Ｌｙｔｈｒａｃｅａｅ）雑草、チョウジタデ（Ｌｉｄｗｉｇｉａ ｅｐｉｌｏｂｉｏｉｄｅｓ）等に代表されるアカバナ科（Ｏｅｎｏｔｈｅｒａｃｅａｅ）雑草、アブノメ（Ｄｏｐａｔｒｉｕｍ ｊｕｎｃｅｕｍ）、オオアブノメ（Ｇｒａｔｉｏｌａ ｊａｐｏｎｉｃａ）、キクモ（Ｌｉｍｎｏｐｈｉｌａ ｓｅｓｓｉｌｉｆｏｌｉａ）、アゼナ（Ｌｉｎｄｅｒｎｉａ ｐｙｘｉｄａｒｉａ）及びアメリカアゼナ（Ｌｉｎｄｅｒｎｉａ ｄｕｂｉａ）等に代表されるゴマノハグサ科（Ｓｃｒｏｐｈｕｌａｒｉａｃｅａｅ）雑草、クサネム（Ａｅｓｃｈｙｎｏｍｅｎｅ ｉｎｄｉｃａ）等に代表されるマメ科（Ｌｅｇｕｍｉｎｏｓａｅ）雑草、並びにアメリカセンダングサ（Ｂｉｄｅｎｓ ｆｒｏｎｄｏｓａ）及びタウコギ（Ｂｉｄｅｎｓ ｔｒｉｐａｒｔｉｔａ）等に代表されるキク科（Ｃｏｍｐｏｓｉｔａｅ）雑草等が挙げられる。 [Table 1] [Table 1] (continued)
――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ――――――――――――――――
Me Me Me FH Me Me Et FH
Me Me Me Cl H Me Me Et Cl H
Me Me Me Br H Me Me Et Br H
Me Me Me IH Me Me Et IH
Me Me Me CN H Me Me Et CN H
Me Me Me NO ₂ H Me Me Et NO ₂ H
CH = CH ₂ Me Me Me H CH = CH ₂ Me Et Me H
c-Bu Me Me Me H c-Bu Me Et Me H
c-Pen Me Me Me H c-Pen Me Et Me H
c-Hex Me Me Me H c-Hex Me Et Me H
Ph Me Me Me H Ph Me Et Me H
CF _Three Me Me Me H CF _Three Me Et Me H
CH ₂ Cl Me Me Me H CH ₂ Cl Me Et Me H
CH ₂ OMe Me Me Me H CH ₂ OMe Me Et Me H
D1-32a Me Me Me H D1-32a Me Et Me H
Me Me Me Me H Me Me Et Me H
CH = CH ₂ Me Me Me A1 Me Me Et Me A1
CH = CH ₂ Me Me Me A13 Me Me Et Me A2
CH = CH ₂ Me Me Me A14 Me Me Et Me A3
CH = CH ₂ Me Me Me A15 Me Me Et Me A4
CH = CH ₂ Me Me Me A16 Me Me Et Me A5
CH = CH ₂ Me Me Me A20 Me Me Et Me A6
CH = CH ₂ Me Me Me A23 Me Me Et Me A7
CH = CH ₂ Me Me Me A24 Me Me Et Me A8
CH = CH ₂ Me Me Me A25 Me Me Et Me A9
CH = CH ₂ Me Me Me A26 Me Me Et Me A10
CH = CH ₂ Me Me Me A27 Me Me Et Me A11
CH = CH ₂ Me Me Me A28 Me Me Et Me A12
CH = CH ₂ Me Me Me A29 Me Me Et Me A13
CH = CH ₂ Me Me Me A34 Me Me Et Me A14
CH = CH ₂ Me Me Me A35 Me Me Et Me A15
CH = CH ₂ Me Me Me A36 Me Me Et Me A16
CH = CH ₂ Me Me Me A37 Me Me Et Me A17
CH = CH ₂ Me Me Me A42 Me Me Et Me A18
CH = CH ₂ Me Me Me A58 Me Me Et Me A19
CH = CH ₂ Me Me Me A63 Me Me Et Me A20
CH = CH ₂ Me Me Me A64 Me Me Et Me A21
CH = CH ₂ Me Me Me A65 Me Me Et Me A22
CH = CH ₂ Me Me Me A67 Me Me Et Me A23
――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ――――――――――――――――
CH = CH ₂ Me Me Me A69 Me Me Et Me A24
CH = CH ₂ Me Me Me A72 Me Me Et Me A25
CH = CH ₂ Me Me Me A73 Me Me Et Me A26
CH = CH ₂ Me Me Me A74 Me Me Et Me A27
CH = CH ₂ Me Me Me A75 Me Me Et Me A28
CH = CH ₂ Me Me Me A76 Me Me Et Me A29
CH = CH ₂ Me Me Me A77 Me Me Et Me A30
CH = CH ₂ Me Me Me A81 Me Me Et Me A31
CH = CH ₂ Me Me Me A83 Me Me Et Me A32
CH = CH ₂ Me Me Me A88 Me Me Et Me A33
CH = CH ₂ Me Me Me A91 Me Me Et Me A34
CH = CH ₂ Me Me Me A97 Me Me Et Me A35
CH = CH ₂ Me Me Me A98 Me Me Et Me A36
CH = CH ₂ Me Me Me A102 Me Me Et Me A37
Ph Me Me Me A1 Me Me Et Me A38
Ph Me Me Me A13 Me Me Et Me A39
Ph Me Me Me A14 Me Me Et Me A40
Ph Me Me Me A15 Me Me Et Me A41
Ph Me Me Me A16 Me Me Et Me A42
Ph Me Me Me A20 Me Me Et Me A43
Ph Me Me Me A23 Me Me Et Me A44
Ph Me Me Me A24 Me Me Et Me A45
Ph Me Me Me A25 Me Me Et Me A46
Ph Me Me Me A26 Me Me Et Me A47
Ph Me Me Me A27 Me Me Et Me A48
Ph Me Me Me A28 Me Me Et Me A49
Ph Me Me Me A29 Me Me Et Me A50
Ph Me Me Me A34 Me Me Et Me A51
Ph Me Me Me A35 Me Me Et Me A52
Ph Me Me Me A36 Me Me Et Me A53
Ph Me Me Me A37 Me Me Et Me A54
Ph Me Me Me A42 Me Me Et Me A55
Ph Me Me Me A58 Me Me Et Me A56
Ph Me Me Me A63 Me Me Et Me A57
Ph Me Me Me A64 Me Me Et Me A58
Ph Me Me Me A65 Me Me Et Me A59
Ph Me Me Me A67 Me Me Et Me A60
Ph Me Me Me A69 Me Me Et Me A61
Ph Me Me Me A72 Me Me Et Me A62
――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ――――――――――――――――
Ph Me Me Me A73 Me Me Et Me A63
Ph Me Me Me A74 Me Me Et Me A64
Ph Me Me Me A75 Me Me Et Me A65
Ph Me Me Me A76 Me Me Et Me A66
Ph Me Me Me A77 Me Me Et Me A67
Ph Me Me Me A81 Me Me Et Me A68
Ph Me Me Me A83 Me Me Et Me A69
Ph Me Me Me A88 Me Me Et Me A70
Ph Me Me Me A91 Me Me Et Me A71
Ph Me Me Me A97 Me Me Et Me A72
Ph Me Me Me A98 Me Me Et Me A73
Ph Me Me Me A102 Me Me Et Me A74
Ph Me Me Me A1 Me Me Et Me A75
Ph Me Me Me A13 Me Me Et Me A76
Ph Me Me Me A14 Me Me Et Me A77
Ph Me Me Me A15 Me Me Et Me A78
Ph Me Me Me A16 Me Me Et Me A79
Ph Me Me Me A20 Me Me Et Me A80
Ph Me Me Me A23 Me Me Et Me A81
Ph Me Me Me A24 Me Me Et Me A82
Ph Me Me Me A25 Me Me Et Me A83
Ph Me Me Me A26 Me Me Et Me A84
Ph Me Me Me A27 Me Me Et Me A85
Ph Me Me Me A28 Me Me Et Me A86
Ph Me Me Me A29 Me Me Et Me A87
Ph Me Me Me A34 Me Me Et Me A88
Ph Me Me Me A35 Me Me Et Me A89
Ph Me Me Me A36 Me Me Et Me A90
Ph Me Me Me A37 Me Me Et Me A91
Ph Me Me Me A42 Me Me Et Me A92
Ph Me Me Me A58 Me Me Et Me A93
Ph Me Me Me A63 Me Me Et Me A94
Ph Me Me Me A64 Me Me Et Me A95
Ph Me Me Me A65 Me Me Et Me A96
Ph Me Me Me A67 Me Me Et Me A97
Ph Me Me Me A69 Me Me Et Me A98
Ph Me Me Me A72 Me Me Et Me A99
Ph Me Me Me A73 Me Me Et Me A100
Ph Me Me Me A74 Me Me Et Me A101
――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ――――――――――――――――
Ph Me Me Me A75 Me Me Et Me A102
Ph Me Me Me A76 Me Me Et Me A103
Ph Me Me Me A77 Me Me Et Me A104
Ph Me Me Me A81 Me Me Et Me A105
Ph Me Me Me A83 Me Me Et Me A106
Ph Me Me Me A88 Me Me Et Me A107
Ph Me Me Me A91 Me Me Et Me A108
Ph Me Me Me A97 Me Me Et Me A109
Ph Me Me Me A98 Me Me Et Me A110
Ph Me Me Me A102 Me Me Et Me A111
Ph Me Me Me A112 Me Me Et Me A112
Ph Me Me Me A113 Me Me Et Me A113
Ph Me Me Me A114 Me Me Et Me A114
c-Pr Me Me Me H c-Pr Me Et Me H
c-Pr Me Me Me A1 c-Pr Me Et Me A1
c-Pr Me Me Me A2 c-Pr Me Et Me A2
c-Pr Me Me Me A3 c-Pr Me Et Me A3
c-Pr Me Me Me A4 c-Pr Me Et Me A4
c-Pr Me Me Me A5 c-Pr Me Et Me A5
c-Pr Me Me Me A6 c-Pr Me Et Me A6
c-Pr Me Me Me A7 c-Pr Me Et Me A7
c-Pr Me Me Me A8 c-Pr Me Et Me A8
c-Pr Me Me Me A9 c-Pr Me Et Me A9
c-Pr Me Me Me A10 c-Pr Me Et Me A10
c-Pr Me Me Me A11 c-Pr Me Et Me A11
c-Pr Me Me Me A12 c-Pr Me Et Me A12
c-Pr Me Me Me A13 c-Pr Me Et Me A13
c-Pr Me Me Me A14 c-Pr Me Et Me A14
c-Pr Me Me Me A15 c-Pr Me Et Me A15
c-Pr Me Me Me A16 c-Pr Me Et Me A16
c-Pr Me Me Me A17 c-Pr Me Et Me A17
c-Pr Me Me Me A18 c-Pr Me Et Me A18
c-Pr Me Me Me A19 c-Pr Me Et Me A19
c-Pr Me Me Me A20 c-Pr Me Et Me A20
c-Pr Me Me Me A21 c-Pr Me Et Me A21
c-Pr Me Me Me A22 c-Pr Me Et Me A22
c-Pr Me Me Me A23 c-Pr Me Et Me A23
c-Pr Me Me Me A24 c-Pr Me Et Me A24
c-Pr Me Me Me A25 c-Pr Me Et Me A25
――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ――――――――――――――――
c-Pr Me Me Me A26 c-Pr Me Et Me A26
c-Pr Me Me Me A27 c-Pr Me Et Me A27
c-Pr Me Me Me A28 c-Pr Me Et Me A28
c-Pr Me Me Me A29 c-Pr Me Et Me A29
c-Pr Me Me Me A30 c-Pr Me Et Me A30
c-Pr Me Me Me A31 c-Pr Me Et Me A31
c-Pr Me Me Me A32 c-Pr Me Et Me A32
c-Pr Me Me Me A33 c-Pr Me Et Me A33
c-Pr Me Me Me A34 c-Pr Me Et Me A34
c-Pr Me Me Me A35 c-Pr Me Et Me A35
c-Pr Me Me Me A36 c-Pr Me Et Me A36
c-Pr Me Me Me A37 c-Pr Me Et Me A37
c-Pr Me Me Me A38 c-Pr Me Et Me A38
c-Pr Me Me Me A39 c-Pr Me Et Me A39
c-Pr Me Me Me A40 c-Pr Me Et Me A40
c-Pr Me Me Me A41 c-Pr Me Et Me A41
c-Pr Me Me Me A42 c-Pr Me Et Me A42
c-Pr Me Me Me A43 c-Pr Me Et Me A43
c-Pr Me Me Me A44 c-Pr Me Et Me A44
c-Pr Me Me Me A45 c-Pr Me Et Me A45
c-Pr Me Me Me A46 c-Pr Me Et Me A46
c-Pr Me Me Me A47 c-Pr Me Et Me A47
c-Pr Me Me Me A48 c-Pr Me Et Me A48
c-Pr Me Me Me A49 c-Pr Me Et Me A49
c-Pr Me Me Me A50 c-Pr Me Et Me A50
c-Pr Me Me Me A51 c-Pr Me Et Me A51
c-Pr Me Me Me A52 c-Pr Me Et Me A52
c-Pr Me Me Me A53 c-Pr Me Et Me A53
c-Pr Me Me Me A54 c-Pr Me Et Me A54
c-Pr Me Me Me A55 c-Pr Me Et Me A55
c-Pr Me Me Me A56 c-Pr Me Et Me A56
c-Pr Me Me Me A57 c-Pr Me Et Me A57
c-Pr Me Me Me A58 c-Pr Me Et Me A58
c-Pr Me Me Me A59 c-Pr Me Et Me A59
c-Pr Me Me Me A60 c-Pr Me Et Me A60
c-Pr Me Me Me A61 c-Pr Me Et Me A61
c-Pr Me Me Me A62 c-Pr Me Et Me A62
c-Pr Me Me Me A63 c-Pr Me Et Me A63
c-Pr Me Me Me A64 c-Pr Me Et Me A64
――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ――――――――――――――――
c-Pr Me Me Me A65 c-Pr Me Et Me A65
c-Pr Me Me Me A66 c-Pr Me Et Me A66
c-Pr Me Me Me A67 c-Pr Me Et Me A67
c-Pr Me Me Me A68 c-Pr Me Et Me A68
c-Pr Me Me Me A69 c-Pr Me Et Me A69
c-Pr Me Me Me A70 c-Pr Me Et Me A70
c-Pr Me Me Me A71 c-Pr Me Et Me A71
c-Pr Me Me Me A72 c-Pr Me Et Me A72
c-Pr Me Me Me A73 c-Pr Me Et Me A73
c-Pr Me Me Me A74 c-Pr Me Et Me A74
c-Pr Me Me Me A75 c-Pr Me Et Me A75
c-Pr Me Me Me A76 c-Pr Me Et Me A76
c-Pr Me Me Me A77 c-Pr Me Et Me A77
c-Pr Me Me Me A78 c-Pr Me Et Me A78
c-Pr Me Me Me A79 c-Pr Me Et Me A79
c-Pr Me Me Me A80 c-Pr Me Et Me A80
c-Pr Me Me Me A81 c-Pr Me Et Me A81
c-Pr Me Me Me A82 c-Pr Me Et Me A82
c-Pr Me Me Me A83 c-Pr Me Et Me A83
c-Pr Me Me Me A84 c-Pr Me Et Me A84
c-Pr Me Me Me A85 c-Pr Me Et Me A85
c-Pr Me Me Me A86 c-Pr Me Et Me A86
c-Pr Me Me Me A87 c-Pr Me Et Me A87
c-Pr Me Me Me A88 c-Pr Me Et Me A88
c-Pr Me Me Me A89 c-Pr Me Et Me A89
c-Pr Me Me Me A90 c-Pr Me Et Me A90
c-Pr Me Me Me A91 c-Pr Me Et Me A91
c-Pr Me Me Me A92 c-Pr Me Et Me A92
c-Pr Me Me Me A93 c-Pr Me Et Me A93
c-Pr Me Me Me A94 c-Pr Me Et Me A94
c-Pr Me Me Me A95 c-Pr Me Et Me A95
c-Pr Me Me Me A96 c-Pr Me Et Me A96
c-Pr Me Me Me A97 c-Pr Me Et Me A97
c-Pr Me Me Me A98 c-Pr Me Et Me A98
c-Pr Me Me Me A99 c-Pr Me Et Me A99
c-Pr Me Me Me A100 c-Pr Me Et Me A100
c-Pr Me Me Me A101 c-Pr Me Et Me A101
c-Pr Me Me Me A102 c-Pr Me Et Me A102
c-Pr Me Me Me A103 c-Pr Me Et Me A103
――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ――――――――――――――――
c-Pr Me Me Me A104 c-Pr Me Et Me A104
c-Pr Me Me Me A105 c-Pr Me Et Me A105
c-Pr Me Me Me A106 c-Pr Me Et Me A106
c-Pr Me Me Me A107 c-Pr Me Et Me A107
c-Pr Me Me Me A108 c-Pr Me Et Me A108
c-Pr Me Me Me A109 c-Pr Me Et Me A109
c-Pr Me Me Me A110 c-Pr Me Et Me A110
c-Pr Me Me Me A111 c-Pr Me Et Me A111
c-Pr Me Me Me A112 c-Pr Me Et Me A112
c-Pr Me Me Me A113 c-Pr Me Et Me A113
c-Pr Me Me Me A114 c-Pr Me Et Me A114
D1-108b-1 Me Me Me H D1-108b-1 Me Et Me H
D1-108b-4 Me Me Me H D1-108b-4 Me Et Me H
D1-108b-8 Me Me Me H D1-108b-8 Me Et Me H
D1-108b-16 Me Me Me H D1-108b-16 Me Et Me H
D1-108b-17 Me Me Me H D1-108b-17 Me Et Me H
D1-108b-18 Me Me Me H D1-108b-18 Me Et Me H
D1-108b-19 Me Me Me H D1-108b-19 Me Et Me H
CH ₂ Pr-c Me Me Me H CH ₂ Pr-c Me Et Me H
CH ₂ Bu-c Me Me Me H CH ₂ Bu-c Me Et Me H
CH ₂ Pen-c Me Me Me H CH ₂ Pen-c Me Et Me H
CH ₂ Hex-c Me Me Me H CH ₂ Hex-c Me Et Me H
―――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ――――――――――――――――
Me Me Me c-Pr H Me Me Et c-Pr H
Me Me Me CH = CH ₂ H Me Me Et CH = CH ₂ H
Me Me Me CH = CHPr-n H Me Me Et CH = CHPr-n H
Me Me Me CH = CHPh H Me Me Et CH = CHPh H
Me Me Me C (O) Me H Me Me Et C (O) Me H
Me Me Me C (O) OMe H Me Me Et C (O) OMe H
Me Me Me C (= NOMe) Me H Me Me Et C (= NOMe) Me H
Me Me Me OH H Me Me Et OH H
Me Me Me OMe H Me Me Et OMe H
Me Me Me OCH ₂ CH ₂ OMe H Me Me Et OCH ₂ CH ₂ OMe H
Me Me Me OCH ₂ Ph H Me Me Et OCH ₂ Ph H
Me Me Me OCH ₂ (D1-34a) H Me Me Et OCH ₂ (D1-34a) H
Me Me Me OPh H Me Me Et OPh H
Me Me Me O (D1-32b-1) H Me Me Et O (D1-32b-1) H
Me Me Me Me A115 Me Me Et Me A115
Me Me Me SMe H Me Me Et SMe H
Me Me Me S (O) Me H Me Me Et S (O) Me H
Me Me Me S (O) ₂ Me H Me Me Et S (O) ₂ Me H
Me Me Me NHC (O) OBu-t H Me Me Et NHC (O) OBu-t H
―――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ――――――――――――――――
Me Me Me HH Me Me Et HH
Me Me Me Br A1 Me Me Et Br A1
Me Me Me Br A2 Me Me Et Br A2
Me Me Me Br A3 Me Me Et Br A3
Me Me Me Br A4 Me Me Et Br A4
Me Me Me Br A5 Me Me Et Br A5
Me Me Me Br A6 Me Me Et Br A6
Me Me Me Br A7 Me Me Et Br A7
Me Me Me Br A8 Me Me Et Br A8
Me Me Me Br A9 Me Me Et Br A9
Me Me Me Br A10 Me Me Et Br A10
Me Me Me Br A11 Me Me Et Br A11
Me Me Me Br A12 Me Me Et Br A12
Me Me Me Br A13 Me Me Et Br A13
Me Me Me Br A14 Me Me Et Br A14
Me Me Me Br A15 Me Me Et Br A15
Me Me Me Br A16 Me Me Et Br A16
Me Me Me Br A17 Me Me Et Br A17
Me Me Me Br A18 Me Me Et Br A18
Me Me Me Br A19 Me Me Et Br A19
Me Me Me Br A20 Me Me Et Br A20
Me Me Me Br A21 Me Me Et Br A21
Me Me Me Br A22 Me Me Et Br A22
Me Me Me Br A23 Me Me Et Br A23
Me Me Me Br A24 Me Me Et Br A24
Me Me Me Br A25 Me Me Et Br A25
Me Me Me Br A26 Me Me Et Br A26
Me Me Me Br A27 Me Me Et Br A27
Me Me Me Br A28 Me Me Et Br A28
Me Me Me Br A29 Me Me Et Br A29
Me Me Me Br A30 Me Me Et Br A30
Me Me Me Br A31 Me Me Et Br A31
Me Me Me Br A32 Me Me Et Br A32
Me Me Me Br A33 Me Me Et Br A33
Me Me Me Br A34 Me Me Et Br A34
Me Me Me Br A35 Me Me Et Br A35
Me Me Me Br A36 Me Me Et Br A36
―――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ――――――――――――――――
Me Me Me Br A37 Me Me Et Br A37
Me Me Me Br A38 Me Me Et Br A38
Me Me Me Br A39 Me Me Et Br A39
Me Me Me Br A40 Me Me Et Br A40
Me Me Me Br A41 Me Me Et Br A41
Me Me Me Br A42 Me Me Et Br A42
Me Me Me Br A43 Me Me Et Br A43
Me Me Me Br A44 Me Me Et Br A44
Me Me Me Br A45 Me Me Et Br A45
Me Me Me Br A46 Me Me Et Br A46
Me Me Me Br A47 Me Me Et Br A47
Me Me Me Br A48 Me Me Et Br A48
Me Me Me Br A49 Me Me Et Br A49
Me Me Me Br A50 Me Me Et Br A50
Me Me Me Br A51 Me Me Et Br A51
Me Me Me Br A52 Me Me Et Br A52
Me Me Me Br A53 Me Me Et Br A53
Me Me Me Br A54 Me Me Et Br A54
Me Me Me Br A55 Me Me Et Br A55
Me Me Me Br A56 Me Me Et Br A56
Me Me Me Br A57 Me Me Et Br A57
Me Me Me Br A58 Me Me Et Br A58
Me Me Me Br A59 Me Me Et Br A59
Me Me Me Br A60 Me Me Et Br A60
Me Me Me Br A61 Me Me Et Br A61
Me Me Me Br A62 Me Me Et Br A62
Me Me Me Br A63 Me Me Et Br A63
Me Me Me Br A64 Me Me Et Br A64
Me Me Me Br A65 Me Me Et Br A65
Me Me Me Br A66 Me Me Et Br A66
Me Me Me Br A67 Me Me Et Br A67
Me Me Me Br A68 Me Me Et Br A68
Me Me Me Br A69 Me Me Et Br A69
Me Me Me Br A70 Me Me Et Br A70
Me Me Me Br A71 Me Me Et Br A71
Me Me Me Br A72 Me Me Et Br A72
Me Me Me Br A73 Me Me Et Br A73
Me Me Me Br A74 Me Me Et Br A74
Me Me Me Br A75 Me Me Et Br A75
―――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ――――――――――――――――
Me Me Me Br A76 Me Me Et Br A76
Me Me Me Br A77 Me Me Et Br A77
Me Me Me Br A78 Me Me Et Br A78
Me Me Me Br A79 Me Me Et Br A79
Me Me Me Br A80 Me Me Et Br A80
Me Me Me Br A81 Me Me Et Br A81
Me Me Me Br A82 Me Me Et Br A82
Me Me Me Br A83 Me Me Et Br A83
Me Me Me Br A84 Me Me Et Br A84
Me Me Me Br A85 Me Me Et Br A85
Me Me Me Br A86 Me Me Et Br A86
Me Me Me Br A87 Me Me Et Br A87
Me Me Me Br A88 Me Me Et Br A88
Me Me Me Br A89 Me Me Et Br A89
Me Me Me Br A90 Me Me Et Br A90
Me Me Me Br A91 Me Me Et Br A91
Me Me Me Br A92 Me Me Et Br A92
Me Me Me Br A93 Me Me Et Br A93
Me Me Me Br A94 Me Me Et Br A94
Me Me Me Br A95 Me Me Et Br A95
Me Me Me Br A96 Me Me Et Br A96
Me Me Me Br A97 Me Me Et Br A97
Me Me Me Br A98 Me Me Et Br A98
Me Me Me Br A99 Me Me Et Br A99
Me Me Me Br A100 Me Me Et Br A100
Me Me Me Br A101 Me Me Et Br A101
Me Me Me Br A102 Me Me Et Br A102
Me Me Me Br A103 Me Me Et Br A103
Me Me Me Br A104 Me Me Et Br A104
Me Me Me Br A105 Me Me Et Br A105
Me Me Me Br A106 Me Me Et Br A106
Me Me Me Br A107 Me Me Et Br A107
Me Me Me Br A108 Me Me Et Br A108
Me Me Me Br A109 Me Me Et Br A109
Me Me Me Br A110 Me Me Et Br A110
Me Me Me Br A111 Me Me Et Br A111
Me Me Me Br A112 Me Me Et Br A112
Me Me Me Br A113 Me Me Et Br A113
Me Me Me Br A114 Me Me Et Br A114
Me Me Me Br A115 Me Me Et Br A115
Me Me Me Br A116 Me Me Et Br A116
―――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ――――――――――――――――
Me Et Et FH Me Me n-Pr FH
Me Et Et Cl H Me Me n-Pr Cl H
Me Et Et Br H Me Me n-Pr Br H
Me Et Et IH Me Me n-Pr IH
Me Et Et CN H Me Me n-Pr CN H
Me Et Et NO ₂ H Me Me n-Pr NO ₂ H
CH = CH ₂ Et Et Me H CH = CH ₂ Me n-Pr Me H
c-Bu Et Et Me H c-Bu Me n-Pr Me H
c-Pen Et Et Me H c-Pen Me n-Pr Me H
c-Hex Et Et Me H c-Hex Me n-Pr Me H
Ph Et Et Me H Ph Me n-Pr Me H
CF _Three Et Et Me H CF _Three Me n-Pr Me H
CH ₂ Cl Et Et Me H CH ₂ Cl Me n-Pr Me H
CH ₂ OMe Et Et Me H CH ₂ OMe Me n-Pr Me H
D1-32a Et Et Me H D1-32a Me n-Pr Me H
Me Et Et Me H Me Me n-Pr Me H
Me Et Et Me A1 Me Me n-Pr Me A1
Me Et Et Me A2 Me Me n-Pr Me A2
Me Et Et Me A3 Me Me n-Pr Me A3
Me Et Et Me A4 Me Me n-Pr Me A4
Me Et Et Me A5 Me Me n-Pr Me A5
Me Et Et Me A6 Me Me n-Pr Me A6
Me Et Et Me A7 Me Me n-Pr Me A7
Me Et Et Me A8 Me Me n-Pr Me A8
Me Et Et Me A9 Me Me n-Pr Me A9
Me Et Et Me A10 Me Me n-Pr Me A10
Me Et Et Me A11 Me Me n-Pr Me A11
Me Et Et Me A12 Me Me n-Pr Me A12
Me Et Et Me A13 Me Me n-Pr Me A13
Me Et Et Me A14 Me Me n-Pr Me A14
Me Et Et Me A15 Me Me n-Pr Me A15
Me Et Et Me A16 Me Me n-Pr Me A16
Me Et Et Me A17 Me Me n-Pr Me A17
Me Et Et Me A18 Me Me n-Pr Me A18
Me Et Et Me A19 Me Me n-Pr Me A19
Me Et Et Me A20 Me Me n-Pr Me A20
Me Et Et Me A21 Me Me n-Pr Me A21
Me Et Et Me A22 Me Me n-Pr Me A22
Me Et Et Me A23 Me Me n-Pr Me A23
―――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――― ――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――― ――――――――――――――
Me Et Et Me A24 Me Me n-Pr Me A24
Me Et Et Me A25 Me Me n-Pr Me A25
Me Et Et Me A26 Me Me n-Pr Me A26
Me Et Et Me A27 Me Me n-Pr Me A27
Me Et Et Me A28 Me Me n-Pr Me A28
Me Et Et Me A29 Me Me n-Pr Me A29
Me Et Et Me A30 Me Me n-Pr Me A30
Me Et Et Me A31 Me Me n-Pr Me A31
Me Et Et Me A32 Me Me n-Pr Me A32
Me Et Et Me A33 Me Me n-Pr Me A33
Me Et Et Me A34 Me Me n-Pr Me A34
Me Et Et Me A35 Me Me n-Pr Me A35
Me Et Et Me A36 Me Me n-Pr Me A36
Me Et Et Me A37 Me Me n-Pr Me A37
Me Et Et Me A38 Me Me n-Pr Me A38
Me Et Et Me A39 Me Me n-Pr Me A39
Me Et Et Me A40 Me Me n-Pr Me A40
Me Et Et Me A41 Me Me n-Pr Me A41
Me Et Et Me A42 Me Me n-Pr Me A42
Me Et Et Me A43 Me Me n-Pr Me A43
Me Et Et Me A44 Me Me n-Pr Me A44
Me Et Et Me A45 Me Me n-Pr Me A45
Me Et Et Me A46 Me Me n-Pr Me A46
Me Et Et Me A47 Me Me n-Pr Me A47
Me Et Et Me A48 Me Me n-Pr Me A48
Me Et Et Me A49 Me Me n-Pr Me A49
Me Et Et Me A50 Me Me n-Pr Me A50
Me Et Et Me A51 Me Me n-Pr Me A51
Me Et Et Me A52 Me Me n-Pr Me A52
Me Et Et Me A53 Me Me n-Pr Me A53
Me Et Et Me A54 Me Me n-Pr Me A54
Me Et Et Me A55 Me Me n-Pr Me A55
Me Et Et Me A56 Me Me n-Pr Me A56
Me Et Et Me A57 Me Me n-Pr Me A57
Me Et Et Me A58 Me Me n-Pr Me A58
Me Et Et Me A59 Me Me n-Pr Me A59
Me Et Et Me A60 Me Me n-Pr Me A60
Me Et Et Me A61 Me Me n-Pr Me A61
Me Et Et Me A62 Me Me n-Pr Me A62
―――――――――――――― ――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――― ――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――― ――――――――――――――
Me Et Et Me A63 Me Me n-Pr Me A63
Me Et Et Me A64 Me Me n-Pr Me A64
Me Et Et Me A65 Me Me n-Pr Me A65
Me Et Et Me A66 Me Me n-Pr Me A66
Me Et Et Me A67 Me Me n-Pr Me A67
Me Et Et Me A68 Me Me n-Pr Me A68
Me Et Et Me A69 Me Me n-Pr Me A69
Me Et Et Me A70 Me Me n-Pr Me A70
Me Et Et Me A71 Me Me n-Pr Me A71
Me Et Et Me A72 Me Me n-Pr Me A72
Me Et Et Me A73 Me Me n-Pr Me A73
Me Et Et Me A74 Me Me n-Pr Me A74
Me Et Et Me A75 Me Me n-Pr Me A75
Me Et Et Me A76 Me Me n-Pr Me A76
Me Et Et Me A77 Me Me n-Pr Me A77
Me Et Et Me A78 Me Me n-Pr Me A78
Me Et Et Me A79 Me Me n-Pr Me A79
Me Et Et Me A80 Me Me n-Pr Me A80
Me Et Et Me A81 Me Me n-Pr Me A81
Me Et Et Me A82 Me Me n-Pr Me A82
Me Et Et Me A83 Me Me n-Pr Me A83
Me Et Et Me A84 Me Me n-Pr Me A84
Me Et Et Me A85 Me Me n-Pr Me A85
Me Et Et Me A86 Me Me n-Pr Me A86
Me Et Et Me A87 Me Me n-Pr Me A87
Me Et Et Me A88 Me Me n-Pr Me A88
Me Et Et Me A89 Me Me n-Pr Me A89
Me Et Et Me A90 Me Me n-Pr Me A90
Me Et Et Me A91 Me Me n-Pr Me A91
Me Et Et Me A92 Me Me n-Pr Me A92
Me Et Et Me A93 Me Me n-Pr Me A93
Me Et Et Me A94 Me Me n-Pr Me A94
Me Et Et Me A95 Me Me n-Pr Me A95
Me Et Et Me A96 Me Me n-Pr Me A96
Me Et Et Me A97 Me Me n-Pr Me A97
Me Et Et Me A98 Me Me n-Pr Me A98
Me Et Et Me A99 Me Me n-Pr Me A99
Me Et Et Me A100 Me Me n-Pr Me A100
Me Et Et Me A101 Me Me n-Pr Me A101
―――――――――――――― ――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ―――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ―――――――――――――――
Me Et Et Me A102 Me Me n-Pr Me A102
Me Et Et Me A103 Me Me n-Pr Me A103
Me Et Et Me A104 Me Me n-Pr Me A104
Me Et Et Me A105 Me Me n-Pr Me A105
Me Et Et Me A106 Me Me n-Pr Me A106
Me Et Et Me A107 Me Me n-Pr Me A107
Me Et Et Me A108 Me Me n-Pr Me A108
Me Et Et Me A109 Me Me n-Pr Me A109
Me Et Et Me A110 Me Me n-Pr Me A110
Me Et Et Me A111 Me Me n-Pr Me A111
Me Et Et Me A112 Me Me n-Pr Me A112
Me Et Et Me A113 Me Me n-Pr Me A113
Me Et Et Me A114 Me Me n-Pr Me A114
c-Pr Et Et Me H c-Pr Me n-Pr Me H
c-Pr Et Et Me A1 c-Pr Me n-Pr Me A1
c-Pr Et Et Me A2 c-Pr Me n-Pr Me A2
c-Pr Et Et Me A3 c-Pr Me n-Pr Me A3
c-Pr Et Et Me A4 c-Pr Me n-Pr Me A4
c-Pr Et Et Me A5 c-Pr Me n-Pr Me A5
c-Pr Et Et Me A6 c-Pr Me n-Pr Me A6
c-Pr Et Et Me A7 c-Pr Me n-Pr Me A7
c-Pr Et Et Me A8 c-Pr Me n-Pr Me A8
c-Pr Et Et Me A9 c-Pr Me n-Pr Me A9
c-Pr Et Et Me A10 c-Pr Me n-Pr Me A10
c-Pr Et Et Me A11 c-Pr Me n-Pr Me A11
c-Pr Et Et Me A12 c-Pr Me n-Pr Me A12
c-Pr Et Et Me A13 c-Pr Me n-Pr Me A13
c-Pr Et Et Me A14 c-Pr Me n-Pr Me A14
c-Pr Et Et Me A15 c-Pr Me n-Pr Me A15
c-Pr Et Et Me A16 c-Pr Me n-Pr Me A16
c-Pr Et Et Me A17 c-Pr Me n-Pr Me A17
c-Pr Et Et Me A18 c-Pr Me n-Pr Me A18
c-Pr Et Et Me A19 c-Pr Me n-Pr Me A19
c-Pr Et Et Me A20 c-Pr Me n-Pr Me A20
c-Pr Et Et Me A21 c-Pr Me n-Pr Me A21
c-Pr Et Et Me A22 c-Pr Me n-Pr Me A22
c-Pr Et Et Me A23 c-Pr Me n-Pr Me A23
c-Pr Et Et Me A24 c-Pr Me n-Pr Me A24
c-Pr Et Et Me A25 c-Pr Me n-Pr Me A25
――――――――――――――― ―――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ―――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ―――――――――――――――
c-Pr Et Et Me A26 c-Pr Me n-Pr Me A26
c-Pr Et Et Me A27 c-Pr Me n-Pr Me A27
c-Pr Et Et Me A28 c-Pr Me n-Pr Me A28
c-Pr Et Et Me A29 c-Pr Me n-Pr Me A29
c-Pr Et Et Me A30 c-Pr Me n-Pr Me A30
c-Pr Et Et Me A31 c-Pr Me n-Pr Me A31
c-Pr Et Et Me A32 c-Pr Me n-Pr Me A32
c-Pr Et Et Me A33 c-Pr Me n-Pr Me A33
c-Pr Et Et Me A34 c-Pr Me n-Pr Me A34
c-Pr Et Et Me A35 c-Pr Me n-Pr Me A35
c-Pr Et Et Me A36 c-Pr Me n-Pr Me A36
c-Pr Et Et Me A37 c-Pr Me n-Pr Me A37
c-Pr Et Et Me A38 c-Pr Me n-Pr Me A38
c-Pr Et Et Me A39 c-Pr Me n-Pr Me A39
c-Pr Et Et Me A40 c-Pr Me n-Pr Me A40
c-Pr Et Et Me A41 c-Pr Me n-Pr Me A41
c-Pr Et Et Me A42 c-Pr Me n-Pr Me A42
c-Pr Et Et Me A43 c-Pr Me n-Pr Me A43
c-Pr Et Et Me A44 c-Pr Me n-Pr Me A44
c-Pr Et Et Me A45 c-Pr Me n-Pr Me A45
c-Pr Et Et Me A46 c-Pr Me n-Pr Me A46
c-Pr Et Et Me A47 c-Pr Me n-Pr Me A47
c-Pr Et Et Me A48 c-Pr Me n-Pr Me A48
c-Pr Et Et Me A49 c-Pr Me n-Pr Me A49
c-Pr Et Et Me A50 c-Pr Me n-Pr Me A50
c-Pr Et Et Me A51 c-Pr Me n-Pr Me A51
c-Pr Et Et Me A52 c-Pr Me n-Pr Me A52
c-Pr Et Et Me A53 c-Pr Me n-Pr Me A53
c-Pr Et Et Me A54 c-Pr Me n-Pr Me A54
c-Pr Et Et Me A55 c-Pr Me n-Pr Me A55
c-Pr Et Et Me A56 c-Pr Me n-Pr Me A56
c-Pr Et Et Me A57 c-Pr Me n-Pr Me A57
c-Pr Et Et Me A58 c-Pr Me n-Pr Me A58
c-Pr Et Et Me A59 c-Pr Me n-Pr Me A59
c-Pr Et Et Me A60 c-Pr Me n-Pr Me A60
c-Pr Et Et Me A61 c-Pr Me n-Pr Me A61
c-Pr Et Et Me A62 c-Pr Me n-Pr Me A62
c-Pr Et Et Me A63 c-Pr Me n-Pr Me A63
c-Pr Et Et Me A64 c-Pr Me n-Pr Me A64
――――――――――――――― ―――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ―――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ―――――――――――――――
c-Pr Et Et Me A65 c-Pr Me n-Pr Me A65
c-Pr Et Et Me A66 c-Pr Me n-Pr Me A66
c-Pr Et Et Me A67 c-Pr Me n-Pr Me A67
c-Pr Et Et Me A68 c-Pr Me n-Pr Me A68
c-Pr Et Et Me A69 c-Pr Me n-Pr Me A69
c-Pr Et Et Me A70 c-Pr Me n-Pr Me A70
c-Pr Et Et Me A71 c-Pr Me n-Pr Me A71
c-Pr Et Et Me A72 c-Pr Me n-Pr Me A72
c-Pr Et Et Me A73 c-Pr Me n-Pr Me A73
c-Pr Et Et Me A74 c-Pr Me n-Pr Me A74
c-Pr Et Et Me A75 c-Pr Me n-Pr Me A75
c-Pr Et Et Me A76 c-Pr Me n-Pr Me A76
c-Pr Et Et Me A77 c-Pr Me n-Pr Me A77
c-Pr Et Et Me A78 c-Pr Me n-Pr Me A78
c-Pr Et Et Me A79 c-Pr Me n-Pr Me A79
c-Pr Et Et Me A80 c-Pr Me n-Pr Me A80
c-Pr Et Et Me A81 c-Pr Me n-Pr Me A81
c-Pr Et Et Me A82 c-Pr Me n-Pr Me A82
c-Pr Et Et Me A83 c-Pr Me n-Pr Me A83
c-Pr Et Et Me A84 c-Pr Me n-Pr Me A84
c-Pr Et Et Me A85 c-Pr Me n-Pr Me A85
c-Pr Et Et Me A86 c-Pr Me n-Pr Me A86
c-Pr Et Et Me A87 c-Pr Me n-Pr Me A87
c-Pr Et Et Me A88 c-Pr Me n-Pr Me A88
c-Pr Et Et Me A89 c-Pr Me n-Pr Me A89
c-Pr Et Et Me A90 c-Pr Me n-Pr Me A90
c-Pr Et Et Me A91 c-Pr Me n-Pr Me A91
c-Pr Et Et Me A92 c-Pr Me n-Pr Me A92
c-Pr Et Et Me A93 c-Pr Me n-Pr Me A93
c-Pr Et Et Me A94 c-Pr Me n-Pr Me A94
c-Pr Et Et Me A95 c-Pr Me n-Pr Me A95
c-Pr Et Et Me A96 c-Pr Me n-Pr Me A96
c-Pr Et Et Me A97 c-Pr Me n-Pr Me A97
c-Pr Et Et Me A98 c-Pr Me n-Pr Me A98
c-Pr Et Et Me A99 c-Pr Me n-Pr Me A99
c-Pr Et Et Me A100 c-Pr Me n-Pr Me A100
c-Pr Et Et Me A101 c-Pr Me n-Pr Me A101
c-Pr Et Et Me A102 c-Pr Me n-Pr Me A102
c-Pr Et Et Me A103 c-Pr Me n-Pr Me A103
c-Pr Et Et Me A104 c-Pr Me n-Pr Me A104
c-Pr Et Et Me A105 c-Pr Me n-Pr Me A105
c-Pr Et Et Me A106 c-Pr Me n-Pr Me A106
c-Pr Et Et Me A107 c-Pr Me n-Pr Me A107
c-Pr Et Et Me A108 c-Pr Me n-Pr Me A108
c-Pr Et Et Me A109 c-Pr Me n-Pr Me A109
c-Pr Et Et Me A110 c-Pr Me n-Pr Me A110
c-Pr Et Et Me A111 c-Pr Me n-Pr Me A111
c-Pr Et Et Me A112 c-Pr Me n-Pr Me A112
c-Pr Et Et Me A113 c-Pr Me n-Pr Me A113
c-Pr Et Et Me A114 c-Pr Me n-Pr Me A114
――――――――――――――― ―――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
D1-108b-1 Et Et Me H D1-108b-1 Me n-Pr Me H
D1-108b-4 Et Et Me H D1-108b-4 Me n-Pr Me H
D1-108b-8 Et Et Me H D1-108b-8 Me n-Pr Me H
D1-108b-16 Et Et Me H D1-108b-16 Me n-Pr Me H
D1-108b-17 Et Et Me H D1-108b-17 Me n-Pr Me H
D1-108b-18 Et Et Me H D1-108b-18 Me n-Pr Me H
D1-108b-19 Et Et Me H D1-108b-19 Me n-Pr Me H
CH ₂ Pr-c Et Et Me H CH ₂ Pr-c Me n-Pr Me H
CH ₂ Bu-c Et Et Me H CH ₂ Bu-c Me n-Pr Me H
CH ₂ Pen-c Et Et Me H CH ₂ Pen-c Me n-Pr Me H
CH ₂ Hex-c Et Et Me H CH ₂ Hex-c Me n-Pr Me H
―――――――――――――――― ―――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et c-Pr H Me Me n-Pr c-Pr H
Me Et Et CH = CH ₂ H Me Me n-Pr CH = CH ₂ H
Me Et Et CH = CHPr-n H Me Me n-Pr CH = CHPr-n H
Me Et Et CH = CHPh H Me Me n-Pr CH = CHPh H
Me Et Et C (O) Me H Me Me n-Pr C (O) Me H
Me Et Et C (O) OMe H Me Me n-Pr C (O) OMe H
Me Et Et C (= NOMe) Me H Me Me n-Pr C (= NOMe) Me H
Me Et Et OH H Me Me n-Pr OH H
Me Et Et OMe H Me Me n-Pr OMe H
Me Et Et OCH ₂ CH ₂ OMe H Me Me n-Pr OCH ₂ CH ₂ OMe H
Me Et Et OCH ₂ Ph H Me Me n-Pr OCH ₂ Ph H
Me Et Et OCH ₂ (D1-34a) H Me Me n-Pr OCH ₂ (D1-34a) H
Me Et Et OPh H Me Me n-Pr OPh H
Me Et Et O (D1-32b-1) H Me Me n-Pr O (D1-32b-1) H
Me Et Et Me A115 Me Me n-Pr Me A115
Me Et Et SMe H Me Me n-Pr SMe H
Me Et Et S (O) Me H Me Me n-Pr S (O) Me H
Me Et Et S (O) ₂ Me H Me Me n-Pr S (O) ₂ Me H
Me Et Et NHC (O) OBu-t H Me Me n-Pr NHC (O) OBu-t H
―――――――――――――――― ―――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――― ―――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――― ―――――――――――――――
Me Et Et HH Me Me n-Pr HH
Me Et Et Br A1 Me Me n-Pr Br A1
Me Et Et Br A2 Me Me n-Pr Br A2
Me Et Et Br A3 Me Me n-Pr Br A3
Me Et Et Br A4 Me Me n-Pr Br A4
Me Et Et Br A5 Me Me n-Pr Br A5
Me Et Et Br A6 Me Me n-Pr Br A6
Me Et Et Br A7 Me Me n-Pr Br A7
Me Et Et Br A8 Me Me n-Pr Br A8
Me Et Et Br A9 Me Me n-Pr Br A9
Me Et Et Br A10 Me Me n-Pr Br A10
Me Et Et Br A11 Me Me n-Pr Br A11
Me Et Et Br A12 Me Me n-Pr Br A12
Me Et Et Br A13 Me Me n-Pr Br A13
Me Et Et Br A14 Me Me n-Pr Br A14
Me Et Et Br A15 Me Me n-Pr Br A15
Me Et Et Br A16 Me Me n-Pr Br A16
Me Et Et Br A17 Me Me n-Pr Br A17
Me Et Et Br A18 Me Me n-Pr Br A18
Me Et Et Br A19 Me Me n-Pr Br A19
Me Et Et Br A20 Me Me n-Pr Br A20
Me Et Et Br A21 Me Me n-Pr Br A21
Me Et Et Br A22 Me Me n-Pr Br A22
Me Et Et Br A23 Me Me n-Pr Br A23
Me Et Et Br A24 Me Me n-Pr Br A24
Me Et Et Br A25 Me Me n-Pr Br A25
Me Et Et Br A26 Me Me n-Pr Br A26
Me Et Et Br A27 Me Me n-Pr Br A27
Me Et Et Br A28 Me Me n-Pr Br A28
Me Et Et Br A29 Me Me n-Pr Br A29
Me Et Et Br A30 Me Me n-Pr Br A30
Me Et Et Br A31 Me Me n-Pr Br A31
Me Et Et Br A32 Me Me n-Pr Br A32
Me Et Et Br A33 Me Me n-Pr Br A33
Me Et Et Br A34 Me Me n-Pr Br A34
Me Et Et Br A35 Me Me n-Pr Br A35
Me Et Et Br A36 Me Me n-Pr Br A36
――――――――――――― ―――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――― ―――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――― ―――――――――――――――
Me Et Et Br A37 Me Me n-Pr Br A37
Me Et Et Br A38 Me Me n-Pr Br A38
Me Et Et Br A39 Me Me n-Pr Br A39
Me Et Et Br A40 Me Me n-Pr Br A40
Me Et Et Br A41 Me Me n-Pr Br A41
Me Et Et Br A42 Me Me n-Pr Br A42
Me Et Et Br A43 Me Me n-Pr Br A43
Me Et Et Br A44 Me Me n-Pr Br A44
Me Et Et Br A45 Me Me n-Pr Br A45
Me Et Et Br A46 Me Me n-Pr Br A46
Me Et Et Br A47 Me Me n-Pr Br A47
Me Et Et Br A48 Me Me n-Pr Br A48
Me Et Et Br A49 Me Me n-Pr Br A49
Me Et Et Br A50 Me Me n-Pr Br A50
Me Et Et Br A51 Me Me n-Pr Br A51
Me Et Et Br A52 Me Me n-Pr Br A52
Me Et Et Br A53 Me Me n-Pr Br A53
Me Et Et Br A54 Me Me n-Pr Br A54
Me Et Et Br A55 Me Me n-Pr Br A55
Me Et Et Br A56 Me Me n-Pr Br A56
Me Et Et Br A57 Me Me n-Pr Br A57
Me Et Et Br A58 Me Me n-Pr Br A58
Me Et Et Br A59 Me Me n-Pr Br A59
Me Et Et Br A60 Me Me n-Pr Br A60
Me Et Et Br A61 Me Me n-Pr Br A61
Me Et Et Br A62 Me Me n-Pr Br A62
Me Et Et Br A63 Me Me n-Pr Br A63
Me Et Et Br A64 Me Me n-Pr Br A64
Me Et Et Br A65 Me Me n-Pr Br A65
Me Et Et Br A66 Me Me n-Pr Br A66
Me Et Et Br A67 Me Me n-Pr Br A67
Me Et Et Br A68 Me Me n-Pr Br A68
Me Et Et Br A69 Me Me n-Pr Br A69
Me Et Et Br A70 Me Me n-Pr Br A70
Me Et Et Br A71 Me Me n-Pr Br A71
Me Et Et Br A72 Me Me n-Pr Br A72
Me Et Et Br A73 Me Me n-Pr Br A73
Me Et Et Br A74 Me Me n-Pr Br A74
Me Et Et Br A75 Me Me n-Pr Br A75
――――――――――――― ―――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――― ―――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――― ―――――――――――――――
Me Et Et Br A76 Me Me n-Pr Br A76
Me Et Et Br A77 Me Me n-Pr Br A77
Me Et Et Br A78 Me Me n-Pr Br A78
Me Et Et Br A79 Me Me n-Pr Br A79
Me Et Et Br A80 Me Me n-Pr Br A80
Me Et Et Br A81 Me Me n-Pr Br A81
Me Et Et Br A82 Me Me n-Pr Br A82
Me Et Et Br A83 Me Me n-Pr Br A83
Me Et Et Br A84 Me Me n-Pr Br A84
Me Et Et Br A85 Me Me n-Pr Br A85
Me Et Et Br A86 Me Me n-Pr Br A86
Me Et Et Br A87 Me Me n-Pr Br A87
Me Et Et Br A88 Me Me n-Pr Br A88
Me Et Et Br A89 Me Me n-Pr Br A89
Me Et Et Br A90 Me Me n-Pr Br A90
Me Et Et Br A91 Me Me n-Pr Br A91
Me Et Et Br A92 Me Me n-Pr Br A92
Me Et Et Br A93 Me Me n-Pr Br A93
Me Et Et Br A94 Me Me n-Pr Br A94
Me Et Et Br A95 Me Me n-Pr Br A95
Me Et Et Br A96 Me Me n-Pr Br A96
Me Et Et Br A97 Me Me n-Pr Br A97
Me Et Et Br A98 Me Me n-Pr Br A98
Me Et Et Br A99 Me Me n-Pr Br A99
Me Et Et Br A100 Me Me n-Pr Br A100
Me Et Et Br A101 Me Me n-Pr Br A101
Me Et Et Br A102 Me Me n-Pr Br A102
Me Et Et Br A103 Me Me n-Pr Br A103
Me Et Et Br A104 Me Me n-Pr Br A104
Me Et Et Br A105 Me Me n-Pr Br A105
Me Et Et Br A106 Me Me n-Pr Br A106
Me Et Et Br A107 Me Me n-Pr Br A107
Me Et Et Br A108 Me Me n-Pr Br A108
Me Et Et Br A109 Me Me n-Pr Br A109
Me Et Et Br A110 Me Me n-Pr Br A110
Me Et Et Br A111 Me Me n-Pr Br A111
Me Et Et Br A112 Me Me n-Pr Br A112
Me Et Et Br A113 Me Me n-Pr Br A113
Me Et Et Br A114 Me Me n-Pr Br A114
Me Et Et Br A115 Me Me n-Pr Br A115
Me Et Et Br A116 Me Me n-Pr Br A116
――――――――――――― ―――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――― ―――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――― ―――――――――――――
H Me Me FHH Et Et FH
H Me Me Cl HH Et Et Cl H
H Me Me Br HH Et Et Br H
H Me Me IHH Et Et IH
H Me Me CN HH Et Et CN H
H Me Me NO ₂ HH Et Et NO ₂ H
H Me Me Me HH Et Et Me H
H Me Me Me A1 H Et Et Me A1
H Me Me Me A2 H Et Et Me A2
H Me Me Me A3 H Et Et Me A3
H Me Me Me A4 H Et Et Me A4
H Me Me Me A5 H Et Et Me A5
H Me Me Me A6 H Et Et Me A6
H Me Me Me A7 H Et Et Me A7
H Me Me Me A8 H Et Et Me A8
H Me Me Me A9 H Et Et Me A9
H Me Me Me A10 H Et Et Me A10
H Me Me Me A11 H Et Et Me A11
H Me Me Me A12 H Et Et Me A12
H Me Me Me A13 H Et Et Me A13
H Me Me Me A14 H Et Et Me A14
H Me Me Me A15 H Et Et Me A15
H Me Me Me A16 H Et Et Me A16
H Me Me Me A17 H Et Et Me A17
H Me Me Me A18 H Et Et Me A18
H Me Me Me A19 H Et Et Me A19
H Me Me Me A20 H Et Et Me A20
H Me Me Me A21 H Et Et Me A21
H Me Me Me A22 H Et Et Me A22
H Me Me Me A23 H Et Et Me A23
H Me Me Me A24 H Et Et Me A24
H Me Me Me A25 H Et Et Me A25
H Me Me Me A26 H Et Et Me A26
H Me Me Me A27 H Et Et Me A27
H Me Me Me A28 H Et Et Me A28
H Me Me Me A29 H Et Et Me A29
H Me Me Me A30 H Et Et Me A30
H Me Me Me A31 H Et Et Me A31
H Me Me Me A32 H Et Et Me A32
――――――――――――― ―――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――― ―――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――― ―――――――――――――
H Me Me Me A33 H Et Et Me A33
H Me Me Me A34 H Et Et Me A34
H Me Me Me A35 H Et Et Me A35
H Me Me Me A36 H Et Et Me A36
H Me Me Me A37 H Et Et Me A37
H Me Me Me A38 H Et Et Me A38
H Me Me Me A39 H Et Et Me A39
H Me Me Me A40 H Et Et Me A40
H Me Me Me A41 H Et Et Me A41
H Me Me Me A42 H Et Et Me A42
H Me Me Me A43 H Et Et Me A43
H Me Me Me A44 H Et Et Me A44
H Me Me Me A45 H Et Et Me A45
H Me Me Me A46 H Et Et Me A46
H Me Me Me A47 H Et Et Me A47
H Me Me Me A48 H Et Et Me A48
H Me Me Me A49 H Et Et Me A49
H Me Me Me A50 H Et Et Me A50
H Me Me Me A51 H Et Et Me A51
H Me Me Me A52 H Et Et Me A52
H Me Me Me A53 H Et Et Me A53
H Me Me Me A54 H Et Et Me A54
H Me Me Me A55 H Et Et Me A55
H Me Me Me A56 H Et Et Me A56
H Me Me Me A57 H Et Et Me A57
H Me Me Me A58 H Et Et Me A58
H Me Me Me A59 H Et Et Me A59
H Me Me Me A60 H Et Et Me A60
H Me Me Me A61 H Et Et Me A61
H Me Me Me A62 H Et Et Me A62
H Me Me Me A63 H Et Et Me A63
H Me Me Me A64 H Et Et Me A64
H Me Me Me A65 H Et Et Me A65
H Me Me Me A66 H Et Et Me A66
H Me Me Me A67 H Et Et Me A67
H Me Me Me A68 H Et Et Me A68
H Me Me Me A69 H Et Et Me A69
H Me Me Me A70 H Et Et Me A70
H Me Me Me A71 H Et Et Me A71
――――――――――――― ―――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――― ―――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――― ―――――――――――――
H Me Me Me A72 H Et Et Me A72
H Me Me Me A73 H Et Et Me A73
H Me Me Me A74 H Et Et Me A74
H Me Me Me A75 H Et Et Me A75
H Me Me Me A76 H Et Et Me A76
H Me Me Me A77 H Et Et Me A77
H Me Me Me A78 H Et Et Me A78
H Me Me Me A79 H Et Et Me A79
H Me Me Me A80 H Et Et Me A80
H Me Me Me A81 H Et Et Me A81
H Me Me Me A82 H Et Et Me A82
H Me Me Me A83 H Et Et Me A83
H Me Me Me A84 H Et Et Me A84
H Me Me Me A85 H Et Et Me A85
H Me Me Me A86 H Et Et Me A86
H Me Me Me A87 H Et Et Me A87
H Me Me Me A88 H Et Et Me A88
H Me Me Me A89 H Et Et Me A89
H Me Me Me A90 H Et Et Me A90
H Me Me Me A91 H Et Et Me A91
H Me Me Me A92 H Et Et Me A92
H Me Me Me A93 H Et Et Me A93
H Me Me Me A94 H Et Et Me A94
H Me Me Me A95 H Et Et Me A95
H Me Me Me A96 H Et Et Me A96
H Me Me Me A97 H Et Et Me A97
H Me Me Me A98 H Et Et Me A98
H Me Me Me A99 H Et Et Me A99
H Me Me Me A100 H Et Et Me A100
H Me Me Me A101 H Et Et Me A101
H Me Me Me A102 H Et Et Me A102
H Me Me Me A103 H Et Et Me A103
H Me Me Me A104 H Et Et Me A104
H Me Me Me A105 H Et Et Me A105
H Me Me Me A106 H Et Et Me A106
―――――――――――― ―――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ――――――――――――――――
H Me Me c-Pr HH Et Et c-Pr H
H Me Me CH = CH ₂ HH Et Et CH = CH ₂ H
H Me Me CH = CHPr-n HH Et Et CH = CHPr-n H
H Me Me CH = CHPh HH Et Et CH = CHPh H
H Me Me C (O) Me HH Et Et C (O) Me H
H Me Me C (O) OMe HH Et Et C (O) OMe H
H Me Me C (= NOMe) Me HH Et Et C (= NOMe) Me H
H Me Me OH HH Et Et OH H
H Me Me OMe HH Et Et OMe H
H Me Me OCH ₂ CH ₂ OMe HH Et Et OCH ₂ CH ₂ OMe H
H Me Me OCH ₂ Ph HH Et Et OCH ₂ Ph H
H Me Me OCH ₂ (D1-34a) HH Et Et OCH ₂ (D1-34a) H
H Me Me OPh HH Et Et OPh H
H Me Me O (D1-32b-1) HH Et Et O (D1-32b-1) H
H Me Me OCH ₂ CF _Three HH Et Et OCH ₂ CF _Three H
H Me Me SMe HH Et Et SMe H
H Me Me S (O) Me HH Et Et S (O) Me H
H Me Me S (O) ₂ Me HH Et Et S (O) ₂ Me H
H Me Me NHC (O) OBu-t HH Et Et NHC (O) OBu-t H
――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――― ――――――――――――――――
Me Me Me Me A116 Me Et Et Me A116
Me Me Et Me A116 Me Me n-Pr Me A116
CF _Three Me Me Me A1 CH ₂ OMe Me Me Me A1
CF _Three Me Me Me A13 CH ₂ OMe Me Me Me A13
CF _Three Me Me Me A14 CH ₂ OMe Me Me Me A14
CF _Three Me Me Me A15 CH ₂ OMe Me Me Me A15
CF _Three Me Me Me A16 CH ₂ OMe Me Me Me A16
CF _Three Me Me Me A20 CH ₂ OMe Me Me Me A20
CF _Three Me Me Me A23 CH ₂ OMe Me Me Me A23
CF _Three Me Me Me A24 CH ₂ OMe Me Me Me A24
CF _Three Me Me Me A25 CH ₂ OMe Me Me Me A25
CF _Three Me Me Me A26 CH ₂ OMe Me Me Me A26
CF _Three Me Me Me A27 CH ₂ OMe Me Me Me A27
CF _Three Me Me Me A28 CH ₂ OMe Me Me Me A28
CF _Three Me Me Me A29 CH ₂ OMe Me Me Me A29
CF _Three Me Me Me A34 CH ₂ OMe Me Me Me A34
CF _Three Me Me Me A35 CH ₂ OMe Me Me Me A35
CF _Three Me Me Me A36 CH ₂ OMe Me Me Me A36
CF _Three Me Me Me A37 CH ₂ OMe Me Me Me A37
CF _Three Me Me Me A42 CH ₂ OMe Me Me Me A42
CF _Three Me Me Me A58 CH ₂ OMe Me Me Me A58
CF _Three Me Me Me A63 CH ₂ OMe Me Me Me A63
CF _Three Me Me Me A64 CH ₂ OMe Me Me Me A64
CF _Three Me Me Me A65 CH ₂ OMe Me Me Me A65
CF _Three Me Me Me A67 CH ₂ OMe Me Me Me A67
CF _Three Me Me Me A69 CH ₂ OMe Me Me Me A69
CF _Three Me Me Me A72 CH ₂ OMe Me Me Me A72
CF _Three Me Me Me A73 CH ₂ OMe Me Me Me A73
CF _Three Me Me Me A74 CH ₂ OMe Me Me Me A74
CF _Three Me Me Me A75 CH ₂ OMe Me Me Me A75
CF _Three Me Me Me A76 CH ₂ OMe Me Me Me A76
CF _Three Me Me Me A77 CH ₂ OMe Me Me Me A77
CF _Three Me Me Me A81 CH ₂ OMe Me Me Me A81
CF _Three Me Me Me A83 CH ₂ OMe Me Me Me A83
CF _Three Me Me Me A88 CH ₂ OMe Me Me Me A88
CF _Three Me Me Me A91 CH ₂ OMe Me Me Me A91
CF _Three Me Me Me A97 CH ₂ OMe Me Me Me A97
CF _Three Me Me Me A98 CH ₂ OMe Me Me Me A98
CF _Three Me Me Me A102 CH ₂ OMe Me Me Me A102
――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ――――――――――――――――
D1-32a Me Me Me A1 D1-108b-1 Me Me Me A1
D1-32a Me Me Me A13 D1-108b-1 Me Me Me A13
D1-32a Me Me Me A14 D1-108b-1 Me Me Me A14
D1-32a Me Me Me A15 D1-108b-1 Me Me Me A15
D1-32a Me Me Me A16 D1-108b-1 Me Me Me A16
D1-32a Me Me Me A20 D1-108b-1 Me Me Me A20
D1-32a Me Me Me A23 D1-108b-1 Me Me Me A23
D1-32a Me Me Me A24 D1-108b-1 Me Me Me A24
D1-32a Me Me Me A25 D1-108b-1 Me Me Me A25
D1-32a Me Me Me A26 D1-108b-1 Me Me Me A26
D1-32a Me Me Me A27 D1-108b-1 Me Me Me A27
D1-32a Me Me Me A28 D1-108b-1 Me Me Me A28
D1-32a Me Me Me A29 D1-108b-1 Me Me Me A29
D1-32a Me Me Me A34 D1-108b-1 Me Me Me A34
D1-32a Me Me Me A35 D1-108b-1 Me Me Me A35
D1-32a Me Me Me A36 D1-108b-1 Me Me Me A36
D1-32a Me Me Me A37 D1-108b-1 Me Me Me A37
D1-32a Me Me Me A42 D1-108b-1 Me Me Me A42
D1-32a Me Me Me A58 D1-108b-1 Me Me Me A58
D1-32a Me Me Me A63 D1-108b-1 Me Me Me A63
D1-32a Me Me Me A64 D1-108b-1 Me Me Me A64
D1-32a Me Me Me A65 D1-108b-1 Me Me Me A65
D1-32a Me Me Me A67 D1-108b-1 Me Me Me A67
D1-32a Me Me Me A69 D1-108b-1 Me Me Me A69
D1-32a Me Me Me A72 D1-108b-1 Me Me Me A72
D1-32a Me Me Me A73 D1-108b-1 Me Me Me A73
D1-32a Me Me Me A74 D1-108b-1 Me Me Me A74
D1-32a Me Me Me A75 D1-108b-1 Me Me Me A75
D1-32a Me Me Me A76 D1-108b-1 Me Me Me A76
D1-32a Me Me Me A77 D1-108b-1 Me Me Me A77
D1-32a Me Me Me A81 D1-108b-1 Me Me Me A81
D1-32a Me Me Me A83 D1-108b-1 Me Me Me A83
D1-32a Me Me Me A88 D1-108b-1 Me Me Me A88
D1-32a Me Me Me A91 D1-108b-1 Me Me Me A91
D1-32a Me Me Me A97 D1-108b-1 Me Me Me A97
D1-32a Me Me Me A98 D1-108b-1 Me Me Me A98
D1-32a Me Me Me A102 D1-108b-1 Me Me Me A102
――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ―――――――――――――――――
CH ₂ Pr-c Me Me Me A1 D1-108b-8 Me Me Me A1
CH ₂ Pr-c Me Me Me A13 D1-108b-8 Me Me Me A13
CH ₂ Pr-c Me Me Me A14 D1-108b-8 Me Me Me A14
CH ₂ Pr-c Me Me Me A15 D1-108b-8 Me Me Me A15
CH ₂ Pr-c Me Me Me A16 D1-108b-8 Me Me Me A16
CH ₂ Pr-c Me Me Me A20 D1-108b-8 Me Me Me A20
CH ₂ Pr-c Me Me Me A23 D1-108b-8 Me Me Me A23
CH ₂ Pr-c Me Me Me A24 D1-108b-8 Me Me Me A24
CH ₂ Pr-c Me Me Me A25 D1-108b-8 Me Me Me A25
CH ₂ Pr-c Me Me Me A26 D1-108b-8 Me Me Me A26
CH ₂ Pr-c Me Me Me A27 D1-108b-8 Me Me Me A27
CH ₂ Pr-c Me Me Me A28 D1-108b-8 Me Me Me A28
CH ₂ Pr-c Me Me Me A29 D1-108b-8 Me Me Me A29
CH ₂ Pr-c Me Me Me A34 D1-108b-8 Me Me Me A34
CH ₂ Pr-c Me Me Me A35 D1-108b-8 Me Me Me A35
CH ₂ Pr-c Me Me Me A36 D1-108b-8 Me Me Me A36
CH ₂ Pr-c Me Me Me A37 D1-108b-8 Me Me Me A37
CH ₂ Pr-c Me Me Me A42 D1-108b-8 Me Me Me A42
CH ₂ Pr-c Me Me Me A58 D1-108b-8 Me Me Me A58
CH ₂ Pr-c Me Me Me A63 D1-108b-8 Me Me Me A63
CH ₂ Pr-c Me Me Me A64 D1-108b-8 Me Me Me A64
CH ₂ Pr-c Me Me Me A65 D1-108b-8 Me Me Me A65
CH ₂ Pr-c Me Me Me A67 D1-108b-8 Me Me Me A67
CH ₂ Pr-c Me Me Me A69 D1-108b-8 Me Me Me A69
CH ₂ Pr-c Me Me Me A72 D1-108b-8 Me Me Me A72
CH ₂ Pr-c Me Me Me A73 D1-108b-8 Me Me Me A73
CH ₂ Pr-c Me Me Me A74 D1-108b-8 Me Me Me A74
CH ₂ Pr-c Me Me Me A75 D1-108b-8 Me Me Me A75
CH ₂ Pr-c Me Me Me A76 D1-108b-8 Me Me Me A76
CH ₂ Pr-c Me Me Me A77 D1-108b-8 Me Me Me A77
CH ₂ Pr-c Me Me Me A81 D1-108b-8 Me Me Me A81
CH ₂ Pr-c Me Me Me A83 D1-108b-8 Me Me Me A83
CH ₂ Pr-c Me Me Me A88 D1-108b-8 Me Me Me A88
CH ₂ Pr-c Me Me Me A91 D1-108b-8 Me Me Me A91
CH ₂ Pr-c Me Me Me A97 D1-108b-8 Me Me Me A97
CH ₂ Pr-c Me Me Me A98 D1-108b-8 Me Me Me A98
CH ₂ Pr-c Me Me Me A102 D1-108b-8 Me Me Me A102
――――――――――――――― ―――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
D1-108b-4 Me Me Me A1 Me Me Me CN A1
D1-108b-4 Me Me Me A13 Me Me Me CN A13
D1-108b-4 Me Me Me A14 Me Me Me CN A14
D1-108b-4 Me Me Me A15 Me Me Me CN A15
D1-108b-4 Me Me Me A16 Me Me Me CN A16
D1-108b-4 Me Me Me A20 Me Me Me CN A20
D1-108b-4 Me Me Me A23 Me Me Me CN A23
D1-108b-4 Me Me Me A24 Me Me Me CN A24
D1-108b-4 Me Me Me A25 Me Me Me CN A25
D1-108b-4 Me Me Me A26 Me Me Me CN A26
D1-108b-4 Me Me Me A27 Me Me Me CN A27
D1-108b-4 Me Me Me A28 Me Me Me CN A28
D1-108b-4 Me Me Me A29 Me Me Me CN A29
D1-108b-4 Me Me Me A34 Me Me Me CN A34
D1-108b-4 Me Me Me A35 Me Me Me CN A35
D1-108b-4 Me Me Me A36 Me Me Me CN A36
D1-108b-4 Me Me Me A37 Me Me Me CN A37
D1-108b-4 Me Me Me A42 Me Me Me CN A42
D1-108b-4 Me Me Me A58 Me Me Me CN A58
D1-108b-4 Me Me Me A63 Me Me Me CN A63
D1-108b-4 Me Me Me A64 Me Me Me CN A64
D1-108b-4 Me Me Me A65 Me Me Me CN A65
D1-108b-4 Me Me Me A67 Me Me Me CN A67
D1-108b-4 Me Me Me A69 Me Me Me CN A69
D1-108b-4 Me Me Me A72 Me Me Me CN A72
D1-108b-4 Me Me Me A73 Me Me Me CN A73
D1-108b-4 Me Me Me A74 Me Me Me CN A74
D1-108b-4 Me Me Me A75 Me Me Me CN A75
D1-108b-4 Me Me Me A76 D1-108b-8 Me Me CN A76
D1-108b-4 Me Me Me A77 D1-108b-8 Me Me CN A77
D1-108b-4 Me Me Me A81 D1-108b-8 Me Me CN A81
D1-108b-4 Me Me Me A83 D1-108b-8 Me Me CN A83
D1-108b-4 Me Me Me A88 D1-108b-8 Me Me CN A88
D1-108b-4 Me Me Me A91 D1-108b-8 Me Me CN A91
D1-108b-4 Me Me Me A97 D1-108b-8 Me Me CN A97
D1-108b-4 Me Me Me A98 D1-108b-8 Me Me CN A98
D1-108b-4 Me Me Me A102 D1-108b-8 Me Me CN A102
―――――――――――――――― ―――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――― ―――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――― ―――――――――――――――
Me Me Me NO ₂ A1 Me Me Me c-Pr A1
Me Me Me NO ₂ A13 Me Me Me c-Pr A13
Me Me Me NO ₂ A14 Me Me Me c-Pr A14
Me Me Me NO ₂ A15 Me Me Me c-Pr A15
Me Me Me NO ₂ A16 Me Me Me c-Pr A16
Me Me Me NO ₂ A20 Me Me Me c-Pr A20
Me Me Me NO ₂ A23 Me Me Me c-Pr A23
Me Me Me NO ₂ A24 Me Me Me c-Pr A24
Me Me Me NO ₂ A25 Me Me Me c-Pr A25
Me Me Me NO ₂ A26 Me Me Me c-Pr A26
Me Me Me NO ₂ A27 Me Me Me c-Pr A27
Me Me Me NO ₂ A28 Me Me Me c-Pr A28
Me Me Me NO ₂ A29 Me Me Me c-Pr A29
Me Me Me NO ₂ A34 Me Me Me c-Pr A34
Me Me Me NO ₂ A35 Me Me Me c-Pr A35
Me Me Me NO ₂ A36 Me Me Me c-Pr A36
Me Me Me NO ₂ A37 Me Me Me c-Pr A37
Me Me Me NO ₂ A42 Me Me Me c-Pr A42
Me Me Me NO ₂ A58 Me Me Me c-Pr A58
Me Me Me NO ₂ A63 Me Me Me c-Pr A63
Me Me Me NO ₂ A64 Me Me Me c-Pr A64
Me Me Me NO ₂ A65 Me Me Me c-Pr A65
Me Me Me NO ₂ A67 Me Me Me c-Pr A67
Me Me Me NO ₂ A69 Me Me Me c-Pr A69
Me Me Me NO ₂ A72 Me Me Me c-Pr A72
Me Me Me NO ₂ A73 Me Me Me c-Pr A73
Me Me Me NO ₂ A74 Me Me Me c-Pr A74
Me Me Me NO ₂ A75 Me Me Me c-Pr A75
Me Me Me NO ₂ A76 Me Me Me c-Pr A76
Me Me Me NO ₂ A77 Me Me Me c-Pr A77
Me Me Me NO ₂ A81 Me Me Me c-Pr A81
Me Me Me NO ₂ A83 Me Me Me c-Pr A83
Me Me Me NO ₂ A88 Me Me Me c-Pr A88
Me Me Me NO ₂ A91 Me Me Me c-Pr A91
Me Me Me NO ₂ A97 Me Me Me c-Pr A97
Me Me Me NO ₂ A98 Me Me Me c-Pr A98
Me Me Me NO ₂ A102 Me Me Me c-Pr A102
――――――――――――― ―――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ――――――――――――――――
Me Me Me CH = CH ₂ A1 Me Me Me CH = CHPh A1
Me Me Me CH = CH ₂ A13 Me Me Me CH = CHPh A13
Me Me Me CH = CH ₂ A14 Me Me Me CH = CHPh A14
Me Me Me CH = CH ₂ A15 Me Me Me CH = CHPh A15
Me Me Me CH = CH ₂ A16 Me Me Me CH = CHPh A16
Me Me Me CH = CH ₂ A20 Me Me Me CH = CHPh A20
Me Me Me CH = CH ₂ A23 Me Me Me CH = CHPh A23
Me Me Me CH = CH ₂ A24 Me Me Me CH = CHPh A24
Me Me Me CH = CH ₂ A25 Me Me Me CH = CHPh A25
Me Me Me CH = CH ₂ A26 Me Me Me CH = CHPh A26
Me Me Me CH = CH ₂ A27 Me Me Me CH = CHPh A27
Me Me Me CH = CH ₂ A28 Me Me Me CH = CHPh A28
Me Me Me CH = CH ₂ A29 Me Me Me CH = CHPh A29
Me Me Me CH = CH ₂ A34 Me Me Me CH = CHPh A34
Me Me Me CH = CH ₂ A35 Me Me Me CH = CHPh A35
Me Me Me CH = CH ₂ A36 Me Me Me CH = CHPh A36
Me Me Me CH = CH ₂ A37 Me Me Me CH = CHPh A37
Me Me Me CH = CH ₂ A42 Me Me Me CH = CHPh A42
Me Me Me CH = CH ₂ A58 Me Me Me CH = CHPh A58
Me Me Me CH = CH ₂ A63 Me Me Me CH = CHPh A63
Me Me Me CH = CH ₂ A64 Me Me Me CH = CHPh A64
Me Me Me CH = CH ₂ A65 Me Me Me CH = CHPh A65
Me Me Me CH = CH ₂ A67 Me Me Me CH = CHPh A67
Me Me Me CH = CH ₂ A69 Me Me Me CH = CHPh A69
Me Me Me CH = CH ₂ A72 Me Me Me CH = CHPh A72
Me Me Me CH = CH ₂ A73 Me Me Me CH = CHPh A73
Me Me Me CH = CH ₂ A74 Me Me Me CH = CHPh A74
Me Me Me CH = CH ₂ A75 Me Me Me CH = CHPh A75
Me Me Me CH = CH ₂ A76 Me Me Me CH = CHPh A76
Me Me Me CH = CH ₂ A77 Me Me Me CH = CHPh A77
Me Me Me CH = CH ₂ A81 Me Me Me CH = CHPh A81
Me Me Me CH = CH ₂ A83 Me Me Me CH = CHPh A83
Me Me Me CH = CH ₂ A88 Me Me Me CH = CHPh A88
Me Me Me CH = CH ₂ A91 Me Me Me CH = CHPh A91
Me Me Me CH = CH ₂ A97 Me Me Me CH = CHPh A97
Me Me Me CH = CH ₂ A98 Me Me Me CH = CHPh A98
Me Me Me CH = CH ₂ A102 Me Me Me CH = CHPh A102
――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ――――――――――――――――
Me Me Me C (O) Me A1 Me Me Me C (O) OMe A1
Me Me Me C (O) Me A13 Me Me Me C (O) OMe A13
Me Me Me C (O) Me A14 Me Me Me C (O) OMe A14
Me Me Me C (O) Me A15 Me Me Me C (O) OMe A15
Me Me Me C (O) Me A16 Me Me Me C (O) OMe A16
Me Me Me C (O) Me A20 Me Me Me C (O) OMe A20
Me Me Me C (O) Me A23 Me Me Me C (O) OMe A23
Me Me Me C (O) Me A24 Me Me Me C (O) OMe A24
Me Me Me C (O) Me A25 Me Me Me C (O) OMe A25
Me Me Me C (O) Me A26 Me Me Me C (O) OMe A26
Me Me Me C (O) Me A27 Me Me Me C (O) OMe A27
Me Me Me C (O) Me A28 Me Me Me C (O) OMe A28
Me Me Me C (O) Me A29 Me Me Me C (O) OMe A29
Me Me Me C (O) Me A34 Me Me Me C (O) OMe A34
Me Me Me C (O) Me A35 Me Me Me C (O) OMe A35
Me Me Me C (O) Me A36 Me Me Me C (O) OMe A36
Me Me Me C (O) Me A37 Me Me Me C (O) OMe A37
Me Me Me C (O) Me A42 Me Me Me C (O) OMe A42
Me Me Me C (O) Me A58 Me Me Me C (O) OMe A58
Me Me Me C (O) Me A63 Me Me Me C (O) OMe A63
Me Me Me C (O) Me A64 Me Me Me C (O) OMe A64
Me Me Me C (O) Me A65 Me Me Me C (O) OMe A65
Me Me Me C (O) Me A67 Me Me Me C (O) OMe A67
Me Me Me C (O) Me A69 Me Me Me C (O) OMe A69
Me Me Me C (O) Me A72 Me Me Me C (O) OMe A72
Me Me Me C (O) Me A73 Me Me Me C (O) OMe A73
Me Me Me C (O) Me A74 Me Me Me C (O) OMe A74
Me Me Me C (O) Me A75 Me Me Me C (O) OMe A75
Me Me Me C (O) Me A76 Me Me Me C (O) OMe A76
Me Me Me C (O) Me A77 Me Me Me C (O) OMe A77
Me Me Me C (O) Me A81 Me Me Me C (O) OMe A81
Me Me Me C (O) Me A83 Me Me Me C (O) OMe A83
Me Me Me C (O) Me A88 Me Me Me C (O) OMe A88
Me Me Me C (O) Me A91 Me Me Me C (O) OMe A91
Me Me Me C (O) Me A97 Me Me Me C (O) OMe A97
Me Me Me C (O) Me A98 Me Me Me C (O) OMe A98
――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ――――――――――――――――
Me Me Me C (= NOMe) Me A1 Me Me Me OH A1
Me Me Me C (= NOMe) Me A13 Me Me Me OH A13
Me Me Me C (= NOMe) Me A14 Me Me Me OH A14
Me Me Me C (= NOMe) Me A15 Me Me Me OH A15
Me Me Me C (= NOMe) Me A16 Me Me Me OH A16
Me Me Me C (= NOMe) Me A20 Me Me Me OH A20
Me Me Me C (= NOMe) Me A23 Me Me Me OH A23
Me Me Me C (= NOMe) Me A24 Me Me Me OH A24
Me Me Me C (= NOMe) Me A25 Me Me Me OH A25
Me Me Me C (= NOMe) Me A26 Me Me Me OH A26
Me Me Me C (= NOMe) Me A27 Me Me Me OH A27
Me Me Me C (= NOMe) Me A28 Me Me Me OH A28
Me Me Me C (= NOMe) Me A29 Me Me Me OH A29
Me Me Me C (= NOMe) Me A34 Me Me Me OH A34
Me Me Me C (= NOMe) Me A35 Me Me Me OH A35
Me Me Me C (= NOMe) Me A36 Me Me Me OH A36
Me Me Me C (= NOMe) Me A37 Me Me Me OH A37
Me Me Me C (= NOMe) Me A42 Me Me Me OH A42
Me Me Me C (= NOMe) Me A58 Me Me Me OH A58
Me Me Me C (= NOMe) Me A63 Me Me Me OH A63
Me Me Me C (= NOMe) Me A64 Me Me Me OH A64
Me Me Me C (= NOMe) Me A65 Me Me Me OH A65
Me Me Me C (= NOMe) Me A67 Me Me Me OH A67
Me Me Me C (= NOMe) Me A69 Me Me Me OH A69
Me Me Me C (= NOMe) Me A72 Me Me Me OH A72
Me Me Me C (= NOMe) Me A73 Me Me Me OH A73
Me Me Me C (= NOMe) Me A74 Me Me Me OH A74
Me Me Me C (= NOMe) Me A75 Me Me Me OH A75
Me Me Me C (= NOMe) Me A76 Me Me Me OH A76
Me Me Me C (= NOMe) Me A77 Me Me Me OH A77
Me Me Me C (= NOMe) Me A81 Me Me Me OH A81
Me Me Me C (= NOMe) Me A83 Me Me Me OH A83
Me Me Me C (= NOMe) Me A88 Me Me Me OH A88
Me Me Me C (= NOMe) Me A91 Me Me Me OH A91
Me Me Me C (= NOMe) Me A97 Me Me Me OH A97
Me Me Me C (= NOMe) Me A98 Me Me Me OH A98
Me Me Me C (= NOMe) Me A102 Me Me Me OH A102
―――――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――― ――――――――――――――――
Me Me Me OMe A1 Me Me Me OCH ₂ OMe A1
Me Me Me OMe A13 Me Me Me OCH ₂ OMe A13
Me Me Me OMe A14 Me Me Me OCH ₂ OMe A14
Me Me Me OMe A15 Me Me Me OCH ₂ OMe A15
Me Me Me OMe A16 Me Me Me OCH ₂ OMe A16
Me Me Me OMe A20 Me Me Me OCH ₂ OMe A20
Me Me Me OMe A23 Me Me Me OCH ₂ OMe A23
Me Me Me OMe A24 Me Me Me OCH ₂ OMe A24
Me Me Me OMe A25 Me Me Me OCH ₂ OMe A25
Me Me Me OMe A26 Me Me Me OCH ₂ OMe A26
Me Me Me OMe A27 Me Me Me OCH ₂ OMe A27
Me Me Me OMe A28 Me Me Me OCH ₂ OMe A28
Me Me Me OMe A29 Me Me Me OCH ₂ OMe A29
Me Me Me OMe A34 Me Me Me OCH ₂ OMe A34
Me Me Me OMe A35 Me Me Me OCH ₂ OMe A35
Me Me Me OMe A36 Me Me Me OCH ₂ OMe A36
Me Me Me OMe A37 Me Me Me OCH ₂ OMe A37
Me Me Me OMe A42 Me Me Me OCH ₂ OMe A42
Me Me Me OMe A58 Me Me Me OCH ₂ OMe A58
Me Me Me OMe A63 Me Me Me OCH ₂ OMe A63
Me Me Me OMe A64 Me Me Me OCH ₂ OMe A64
Me Me Me OMe A65 Me Me Me OCH ₂ OMe A65
Me Me Me OMe A67 Me Me Me OCH ₂ OMe A67
Me Me Me OMe A69 Me Me Me OCH ₂ OMe A69
Me Me Me OMe A72 Me Me Me OCH ₂ OMe A72
Me Me Me OMe A73 Me Me Me OCH ₂ OMe A73
Me Me Me OMe A74 Me Me Me OCH ₂ OMe A74
Me Me Me OMe A75 Me Me Me OCH ₂ OMe A75
Me Me Me OMe A76 Me Me Me OCH ₂ OMe A76
Me Me Me OMe A77 Me Me Me OCH ₂ OMe A77
Me Me Me OMe A81 Me Me Me OCH ₂ OMe A81
Me Me Me OMe A83 Me Me Me OCH ₂ OMe A83
Me Me Me OMe A88 Me Me Me OCH ₂ OMe A88
Me Me Me OMe A91 Me Me Me OCH ₂ OMe A91
Me Me Me OMe A97 Me Me Me OCH ₂ OMe A97
Me Me Me OMe A98 Me Me Me OCH ₂ OMe A98
Me Me Me OMe A102 Me Me Me OCH ₂ OMe A102
―――――――――――――― ――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ――――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ――――――――――――――――――
Me Me Me OCH ₂ Ph A1 Me Me Me OCH ₂ (D1-34a) A1
Me Me Me OCH ₂ Ph A13 Me Me Me OCH ₂ (D1-34a) A13
Me Me Me OCH ₂ Ph A14 Me Me Me OCH ₂ (D1-34a) A14
Me Me Me OCH ₂ Ph A15 Me Me Me OCH ₂ (D1-34a) A15
Me Me Me OCH ₂ Ph A16 Me Me Me OCH ₂ (D1-34a) A16
Me Me Me OCH ₂ Ph A20 Me Me Me OCH ₂ (D1-34a) A20
Me Me Me OCH ₂ Ph A23 Me Me Me OCH ₂ (D1-34a) A23
Me Me Me OCH ₂ Ph A24 Me Me Me OCH ₂ (D1-34a) A24
Me Me Me OCH ₂ Ph A25 Me Me Me OCH ₂ (D1-34a) A25
Me Me Me OCH ₂ Ph A26 Me Me Me OCH ₂ (D1-34a) A26
Me Me Me OCH ₂ Ph A27 Me Me Me OCH ₂ (D1-34a) A27
Me Me Me OCH ₂ Ph A28 Me Me Me OCH ₂ (D1-34a) A28
Me Me Me OCH ₂ Ph A29 Me Me Me OCH ₂ (D1-34a) A29
Me Me Me OCH ₂ Ph A34 Me Me Me OCH ₂ (D1-34a) A34
Me Me Me OCH ₂ Ph A35 Me Me Me OCH ₂ (D1-34a) A35
Me Me Me OCH ₂ Ph A36 Me Me Me OCH ₂ (D1-34a) A36
Me Me Me OCH ₂ Ph A37 Me Me Me OCH ₂ (D1-34a) A37
Me Me Me OCH ₂ Ph A42 Me Me Me OCH ₂ (D1-34a) A42
Me Me Me OCH ₂ Ph A58 Me Me Me OCH ₂ (D1-34a) A58
Me Me Me OCH ₂ Ph A63 Me Me Me OCH ₂ (D1-34a) A63
Me Me Me OCH ₂ Ph A64 Me Me Me OCH ₂ (D1-34a) A64
Me Me Me OCH ₂ Ph A65 Me Me Me OCH ₂ (D1-34a) A65
Me Me Me OCH ₂ Ph A67 Me Me Me OCH ₂ (D1-34a) A67
Me Me Me OCH ₂ Ph A69 Me Me Me OCH ₂ (D1-34a) A69
Me Me Me OCH ₂ Ph A72 Me Me Me OCH ₂ (D1-34a) A72
Me Me Me OCH ₂ Ph A73 Me Me Me OCH ₂ (D1-34a) A73
Me Me Me OCH ₂ Ph A74 Me Me Me OCH ₂ (D1-34a) A74
Me Me Me OCH ₂ Ph A75 Me Me Me OCH ₂ (D1-34a) A75
Me Me Me OCH ₂ Ph A76 Me Me Me OCH ₂ (D1-34a) A76
Me Me Me OCH ₂ Ph A77 Me Me Me OCH ₂ (D1-34a) A77
Me Me Me OCH ₂ Ph A81 Me Me Me OCH ₂ (D1-34a) A81
Me Me Me OCH ₂ Ph A83 Me Me Me OCH ₂ (D1-34a) A83
Me Me Me OCH ₂ Ph A88 Me Me Me OCH ₂ (D1-34a) A88
Me Me Me OCH ₂ Ph A91 Me Me Me OCH ₂ (D1-34a) A91
Me Me Me OCH ₂ Ph A97 Me Me Me OCH ₂ (D1-34a) A97
Me Me Me OCH ₂ Ph A98 Me Me Me OCH ₂ (D1-34a) A98
Me Me Me OCH ₂ Ph A102 Me Me Me OCH ₂ (D1-34a) A102
――――――――――――――― ――――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――― ――――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――― ――――――――――――――――――
Me Me Me OPh A1 Me Me Me O (D1-32b-1) A1
Me Me Me OPh A13 Me Me Me O (D1-32b-1) A13
Me Me Me OPh A14 Me Me Me O (D1-32b-1) A14
Me Me Me OPh A15 Me Me Me O (D1-32b-1) A15
Me Me Me OPh A16 Me Me Me O (D1-32b-1) A16
Me Me Me OPh A20 Me Me Me O (D1-32b-1) A20
Me Me Me OPh A23 Me Me Me O (D1-32b-1) A23
Me Me Me OPh A24 Me Me Me O (D1-32b-1) A24
Me Me Me OPh A25 Me Me Me O (D1-32b-1) A25
Me Me Me OPh A26 Me Me Me O (D1-32b-1) A26
Me Me Me OPh A27 Me Me Me O (D1-32b-1) A27
Me Me Me OPh A28 Me Me Me O (D1-32b-1) A28
Me Me Me OPh A29 Me Me Me O (D1-32b-1) A29
Me Me Me OPh A34 Me Me Me O (D1-32b-1) A34
Me Me Me OPh A35 Me Me Me O (D1-32b-1) A35
Me Me Me OPh A36 Me Me Me O (D1-32b-1) A36
Me Me Me OPh A37 Me Me Me O (D1-32b-1) A37
Me Me Me OPh A42 Me Me Me O (D1-32b-1) A42
Me Me Me OPh A58 Me Me Me O (D1-32b-1) A58
Me Me Me OPh A63 Me Me Me O (D1-32b-1) A63
Me Me Me OPh A64 Me Me Me O (D1-32b-1) A64
Me Me Me OPh A65 Me Me Me O (D1-32b-1) A65
Me Me Me OPh A67 Me Me Me O (D1-32b-1) A67
Me Me Me OPh A69 Me Me Me O (D1-32b-1) A69
Me Me Me OPh A72 Me Me Me O (D1-32b-1) A72
Me Me Me OPh A73 Me Me Me O (D1-32b-1) A73
Me Me Me OPh A74 Me Me Me O (D1-32b-1) A74
Me Me Me OPh A75 Me Me Me O (D1-32b-1) A75
Me Me Me OPh A76 Me Me Me O (D1-32b-1) A76
Me Me Me OPh A77 Me Me Me O (D1-32b-1) A77
Me Me Me OPh A81 Me Me Me O (D1-32b-1) A81
Me Me Me OPh A83 Me Me Me O (D1-32b-1) A83
Me Me Me OPh A88 Me Me Me O (D1-32b-1) A88
Me Me Me OPh A91 Me Me Me O (D1-32b-1) A91
Me Me Me OPh A97 Me Me Me O (D1-32b-1) A97
Me Me Me OPh A98 Me Me Me O (D1-32b-1) A98
Me Me Me OPh A102 Me Me Me O (D1-32b-1) A102
――――――――――――― ――――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――― ――――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――― ――――――――――――――――――
Me Me Me SMe A1 Me Me Me NHC (O) OBu-t A1
Me Me Me SMe A13 Me Me Me NHC (O) OBu-t A13
Me Me Me SMe A14 Me Me Me NHC (O) OBu-t A14
Me Me Me SMe A15 Me Me Me NHC (O) OBu-t A15
Me Me Me SMe A16 Me Me Me NHC (O) OBu-t A16
Me Me Me SMe A20 Me Me Me NHC (O) OBu-t A20
Me Me Me SMe A23 Me Me Me NHC (O) OBu-t A23
Me Me Me SMe A24 Me Me Me NHC (O) OBu-t A24
Me Me Me SMe A25 Me Me Me NHC (O) OBu-t A25
Me Me Me SMe A26 Me Me Me NHC (O) OBu-t A26
Me Me Me SMe A27 Me Me Me NHC (O) OBu-t A27
Me Me Me SMe A28 Me Me Me NHC (O) OBu-t A28
Me Me Me SMe A29 Me Me Me NHC (O) OBu-t A29
Me Me Me SMe A34 Me Me Me NHC (O) OBu-t A34
Me Me Me SMe A35 Me Me Me NHC (O) OBu-t A35
Me Me Me SMe A36 Me Me Me NHC (O) OBu-t A36
Me Me Me SMe A37 Me Me Me NHC (O) OBu-t A37
Me Me Me SMe A42 Me Me Me NHC (O) OBu-t A42
Me Me Me SMe A58 Me Me Me NHC (O) OBu-t A58
Me Me Me SMe A63 Me Me Me NHC (O) OBu-t A63
Me Me Me SMe A64 Me Me Me NHC (O) OBu-t A64
Me Me Me SMe A65 Me Me Me NHC (O) OBu-t A65
Me Me Me SMe A67 Me Me Me NHC (O) OBu-t A67
Me Me Me SMe A69 Me Me Me NHC (O) OBu-t A69
Me Me Me SMe A72 Me Me Me NHC (O) OBu-t A72
Me Me Me SMe A73 Me Me Me NHC (O) OBu-t A73
Me Me Me SMe A74 Me Me Me NHC (O) OBu-t A74
Me Me Me SMe A75 Me Me Me NHC (O) OBu-t A75
Me Me Me SMe A76 Me Me Me NHC (O) OBu-t A76
Me Me Me SMe A77 Me Me Me NHC (O) OBu-t A77
Me Me Me SMe A81 Me Me Me NHC (O) OBu-t A81
Me Me Me SMe A83 Me Me Me NHC (O) OBu-t A83
Me Me Me SMe A88 Me Me Me NHC (O) OBu-t A88
Me Me Me SMe A91 Me Me Me NHC (O) OBu-t A91
Me Me Me SMe A97 Me Me Me NHC (O) OBu-t A97
Me Me Me SMe A98 Me Me Me NHC (O) OBu-t A98
Me Me Me SMe A102 Me Me Me NHC (O) OBu-t A102
――――――――――――― ――――――――――――――――――
[Table 1] (continued) [Table 1] (continued)
―――――――――――― ――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――― ――――――――――――――
Me Me Me Me A1 Me Me Me Me A11
Me Me Me Me A2 Me Me Me Me A12
Me Me Me Me A3 Me Me Me Me A13
Me Me Me Me A4 Me Me Me Me A14
Me Me Me Me A5 Me Me Me Me A15
Me Me Me Me A6 Me Me Me Me A16
Me Me Me Me A7 Me Me Me Me A17
Me Me Me Me A8 Me Me Me Me A18
Me Me Me Me A9 Me Me Me Me A19
Me Me Me Me A10 Me Me Me Me A20
Me Me Me Me A21 Me Me Me Me A60
Me Me Me Me A22 Me Me Me Me A61
Me Me Me Me A23 Me Me Me Me A62
Me Me Me Me A24 Me Me Me Me A63
Me Me Me Me A25 Me Me Me Me A64
Me Me Me Me A26 Me Me Me Me A65
Me Me Me Me A27 Me Me Me Me A66
Me Me Me Me A28 Me Me Me Me A67
Me Me Me Me A29 Me Me Me Me A68
Me Me Me Me A30 Me Me Me Me A69
Me Me Me Me A31 Me Me Me Me A70
Me Me Me Me A32 Me Me Me Me A71
Me Me Me Me A33 Me Me Me Me A72
Me Me Me Me A34 Me Me Me Me A73
Me Me Me Me A35 Me Me Me Me A74
Me Me Me Me A36 Me Me Me Me A75
Me Me Me Me A37 Me Me Me Me A76
Me Me Me Me A38 Me Me Me Me A77
Me Me Me Me A39 Me Me Me Me A78
Me Me Me Me A40 Me Me Me Me A79
Me Me Me Me A41 Me Me Me Me A80
Me Me Me Me A42 Me Me Me Me A81
Me Me Me Me A43 Me Me Me Me A82
Me Me Me Me A44 Me Me Me Me A83
Me Me Me Me A45 Me Me Me Me A84
Me Me Me Me A46 Me Me Me Me A85
Me Me Me Me A47 Me Me Me Me A86
Me Me Me Me A48 Me Me Me Me A87
Me Me Me Me A49 Me Me Me Me A88
Me Me Me Me A50 Me Me Me Me A89
Me Me Me Me A51 Me Me Me Me A90
Me Me Me Me A52 Me Me Me Me A91
Me Me Me Me A53 Me Me Me Me A92
Me Me Me Me A54 Me Me Me Me A93
Me Me Me Me A55 Me Me Me Me A94
Me Me Me Me A56 Me Me Me Me A95
Me Me Me Me A57 Me Me Me Me A96
Me Me Me Me A58 Me Me Me Me A97
Me Me Me Me A59 Me Me Me Me A98
Me Me Me Me A99 Me Me Me Me A108
Me Me Me Me A100 Me Me Me Me A109
Me Me Me Me A101 Me Me Me Me A110
Me Me Me Me A102 Me Me Me Me A111
Me Me Me Me A103 Me Me Me Me A112
Me Me Me Me A104 Me Me Me Me A113
Me Me Me Me A105 Me Me Me Me A114
Me Me Me Me A106 Me Me Me Me A115
―――――――――――― ――――――――――――――
[Table 1] (continued) [Table 1] (continued)
――――――――――――――― ―――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ―――――――――――――――
Me Me Me Me A107 Me Me Me D1-103-3 H
Me Me Me D1-103-1 H Me Me Me D1-103-4 H
Me Me Me D1-103-2 H Me Et Et D1-103-3 H
Me Et Et D1-103-1 H Me Et Et D1-103-4 H
Me Et Et D1-103-2 H ―――――――――――――――
―――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――― ――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――― ――――――――――――――
Me Me Me Me A117 Me Me Me Me A170
Me Me Me Me A118 Me Me Me Me A171
Me Me Me Me A119 Me Me Me Me A172
Me Me Me Me A120 Me Me Me Me A173
Me Me Me Me A121 Me Me Me Me A174
Me Me Me Me A122 Me Me Me Me A175
Me Me Me Me A123 Me Me Me Me A176
Me Me Me Me A124 Me Me Me Me A177
Me Me Me Me A125 Me Me Me Me A178
Me Me Me Me A126 Me Me Me Me A179
Me Me Me Me A127 Me Me Me Me A180
Me Me Me Me A128 Me Me Me Me A181
Me Me Me Me A129 Me Me Me Me A182
Me Me Me Me A130 Me Me Me Me A183
Me Me Me Me A131 Me Me Me Me A184
Me Me Me Me A132 Me Me Me Me A185
Me Me Me Me A133 Me Me Me Me A186
Me Me Me Me A134 Me Me Me Me A187
Me Me Me Me A135 Me Me Me Me A188
Me Me Me Me A136 Me Me Me Me A189
Me Me Me Me A137 Me Me Me Me A190
Me Me Me Me A138 Me Me Me Me A191
Me Me Me Me A139 Me Me Me Me A192
Me Me Me Me A140 Me Me Me Me A193
Me Me Me Me A141 Me Me Me Me A194
Me Me Me Me A142 Me Me Me Me A195
Me Me Me Me A143 Me Me Me Me A196
Me Me Me Me A144 Me Me Me Me A197
Me Me Me Me A145 Me Me Me Me A198
Me Me Me Me A146 Me Me Me Me A199
Me Me Me Me A147 Me Me Me Me A200
Me Me Me Me A148 Me Me Me Me A205
Me Me Me Me A149 Me Me Me Me A206
Me Me Me Me A150 Me Me Me Me A207
Me Me Me Me A151 Me Me Me Me A208
Me Me Me Me A152 Me Me Me Me A209
Me Me Me Me A153 Me Me Me Me A210
Me Me Me Me A154 Me Me Me Me A211
Me Me Me Me A155 Me Me Me Me A212
Me Me Me Me A156 Me Me Me Me A213
Me Me Me Me A157 Me Me Me Me A214
Me Me Me Me A158 Me Me Me Me A215
Me Me Me Me A159 Me Me Me Me A216
Me Me Me Me A160 Me Me Me Me A217
Me Me Me Me A161 Me Me Me Me A218
Me Me Me Me A162 Me Me Me Me A219
Me Me Me Me A163 Me Me Me Me A220
Me Me Me Me A164 Me Me Me Me A221
Me Me Me Me A165 Me Me Me Me A222
Me Me Me Me A166 Me Me Me Me A223
Me Me Me Me A167 Me Me Me Me A224
Me Me Me Me A168 Me Me Me Me A225
Me Me Me Me A169 Me Me Me Me A226
―――――――――――― ――――――――――――――
Table 1 (continued) [Table 1] (continued)
――――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――――― ―――――――――――――――――
Me Me Me C≡CMe H Me Me Et C≡CMe H
Me Me Me C≡CMe A39 Me Me Et C≡CMe A39
Me Me Me C≡CMe A40 Me Me Et C≡CMe A40
Me Me Me C≡CMe A41 Me Me Et C≡CMe A41
c-Pr Me Me C≡CMe H c-Pr Me Et C≡CMe H
c-Pr Me Me C≡CMe A39 c-Pr Me Et C≡CMe A39
c-Pr Me Me C≡CMe A40 c-Pr Me Et C≡CMe A40
c-Pr Me Me C≡CMe A41 c-Pr Me Et C≡CMe A41
c-Bu Me Me C≡CMe H c-Bu Me Et C≡CMe H
c-Bu Me Me C≡CMe A39 c-Bu Me Et C≡CMe A39
c-Bu Me Me C≡CMe A40 c-Bu Me Et C≡CMe A40
c-Bu Me Me C≡CMe A41 c-Bu Me Et C≡CMe A41
c-Pen Me Me C≡CMe H c-Pen Me Et C≡CMe H
c-Pen Me Me C≡CMe A39 c-Pen Me Et C≡CMe A39
c-Pen Me Me C≡CMe A40 c-Pen Me Et C≡CMe A40
c-Pen Me Me C≡CMe A41 c-Pen Me Et C≡CMe A41
c-Hex Me Me C≡CMe H c-Hex Me Et C≡CMe H
c-Hex Me Me C≡CMe A39 c-Hex Me Et C≡CMe A39
c-Hex Me Me C≡CMe A40 c-Hex Me Et C≡CMe A40
c-Hex Me Me C≡CMe A41 c-Hex Me Et C≡CMe A41
Me Me Me C≡CSi (Me) _Three H Me Me Et C≡CSi (Me) _Three H
Me Me Me C≡CSi (Me) _Three A39 Me Me Et C≡CSi (Me) _Three A39
Me Me Me C≡CSi (Me) _Three A40 Me Me Et C≡CSi (Me) _Three A40
Me Me Me C≡CSi (Me) _Three A41 Me Me Et C≡CSi (Me) _Three A41
c-Pr Me Me C≡CSi (Me) _Three H c-Pr Me Et C≡CSi (Me) _Three H
c-Pr Me Me C≡CSi (Me) _Three A39 c-Pr Me Et C≡CSi (Me) _Three A39
c-Pr Me Me C≡CSi (Me) _Three A40 c-Pr Me Et C≡CSi (Me) _Three A40
c-Pr Me Me C≡CSi (Me) _Three A41 c-Pr Me Et C≡CSi (Me) _Three A41
c-Bu Me Me C≡CSi (Me) _Three H c-Bu Me Et C≡CSi (Me) _Three H
c-Bu Me Me C≡CSi (Me) _Three A39 c-Bu Me Et C≡CSi (Me) _Three A39
c-Bu Me Me C≡CSi (Me) _Three A40 c-Bu Me Et C≡CSi (Me) _Three A40
c-Bu Me Me C≡CSi (Me) _Three A41 c-Bu Me Et C≡CSi (Me) _Three A41
c-Pen Me Me C≡CSi (Me) _Three H c-Pen Me Et C≡CSi (Me) _Three H
c-Pen Me Me C≡CSi (Me) _Three A39 c-Pen Me Et C≡CSi (Me) _Three A39
c-Pen Me Me C≡CSi (Me) _Three A40 c-Pen Me Et C≡CSi (Me) _Three A40
c-Pen Me Me C≡CSi (Me) _Three A41 c-Pen Me Et C≡CSi (Me) _Three A41
c-Hex Me Me C≡CSi (Me) _Three H c-Hex Me Et C≡CSi (Me) _Three H
c-Hex Me Me C≡CSi (Me) _Three A39 c-Hex Me Et C≡CSi (Me) _Three A39
c-Hex Me Me C≡CSi (Me) _Three A40 c-Hex Me Et C≡CSi (Me) _Three A40
c-Hex Me Me C≡CSi (Me) _Three A41 c-Hex Me Et C≡CSi (Me) _Three A41
Me Me Me C≡CPr-c H Me Me Et C≡CPr-c H
Me Me Me C≡CPr-c A39 Me Me Et C≡CPr-c A39
Me Me Me C≡CPr-c A40 Me Me Et C≡CPr-c A40
Me Me Me C≡CPr-c A41 Me Me Et C≡CPr-c A41
c-Pr Me Me C≡CPr-c H c-Pr Me Et C≡CPr-c H
c-Pr Me Me C≡CPr-c A39 c-Pr Me Et C≡CPr-c A39
c-Pr Me Me C≡CPr-c A40 c-Pr Me Et C≡CPr-c A40
c-Pr Me Me C≡CPr-c A41 c-Pr Me Et C≡CPr-c A41
c-Bu Me Me C≡CPr-c H c-Bu Me Et C≡CPr-c H
c-Bu Me Me C≡CPr-c A39 c-Bu Me Et C≡CPr-c A39
c-Bu Me Me C≡CPr-c A40 c-Bu Me Et C≡CPr-c A40
c-Bu Me Me C≡CPr-c A41 c-Bu Me Et C≡CPr-c A41
c-Pen Me Me C≡CPr-c H c-Pen Me Et C≡CPr-c H
c-Pen Me Me C≡CPr-c A39 c-Pen Me Et C≡CPr-c A39
c-Pen Me Me C≡CPr-c A40 c-Pen Me Et C≡CPr-c A40
c-Pen Me Me C≡CPr-c A41 c-Pen Me Et C≡CPr-c A41
c-Hex Me Me C≡CPr-c H c-Hex Me Et C≡CPr-c H
c-Hex Me Me C≡CPr-c A39 c-Hex Me Et C≡CPr-c A39
c-Hex Me Me C≡CPr-c A40 c-Hex Me Et C≡CPr-c A40
c-Hex Me Me C≡CPr-c A41 c-Hex Me Et C≡CPr-c A41
――――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
――――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――――― ―――――――――――――――――
Me Me Me C≡CC (Me) ₂ OH H Me Me Et C≡CC (Me) ₂ OH H
Me Me Me C≡CC (Me) ₂ OH A39 Me Me Et C≡CC (Me) ₂ OH A39
Me Me Me C≡CC (Me) ₂ OH A40 Me Me Et C≡CC (Me) ₂ OH A40
Me Me Me C≡CC (Me) ₂ OH A41 Me Me Et C≡CC (Me) ₂ OH A41
Me Me Me C≡CCH ₂ OH H Me Me Et C≡CCH ₂ OH H
Me Me Me C≡CCH ₂ OH A39 Me Me Et C≡CCH ₂ OH A39
Me Me Me C≡CCH ₂ OH A40 Me Me Et C≡CCH ₂ OH A40
Me Me Me C≡CCH ₂ OH A41 Me Me Et C≡CCH ₂ OH A41
Me Me Me Ph H Me Me Et Ph H
Me Me Me Ph Me Me Me Et Ph Me
Me Me Me Ph A11 Me Me Et Ph A11
Me Me Me Ph A34 Me Me Et Ph A34
Me Me Me Ph A35 Me Me Et Ph A35
Me Me Me Ph A37 Me Me Et Ph A37
Me Me Me Ph A39 Me Me Et Ph A39
Me Me Me Ph A40 Me Me Et Ph A40
Me Me Me Ph A41 Me Me Et Ph A41
Me Me Me Ph A73 Me Me Et Ph A73
Me Me Me Ph A75 Me Me Et Ph A75
Me Me Me Ph A83 Me Me Et Ph A83
Me Me Me Ph A84 Me Me Et Ph A84
Me Me Me Ph A85 Me Me Et Ph A85
Me Me Me Ph A91 Me Me Et Ph A91
Me Me Me D1-108b-1 H Me Me Et D1-108b-1 H
Me Me Me D1-108b-1 Me Me Me Et D1-108b-1 Me
Me Me Me D1-108b-1 A11 Me Me Et D1-108b-1 A11
Me Me Me D1-108b-1 A34 Me Me Et D1-108b-1 A34
Me Me Me D1-108b-1 A35 Me Me Et D1-108b-1 A35
Me Me Me D1-108b-1 A37 Me Me Et D1-108b-1 A37
Me Me Me D1-108b-1 A39 Me Me Et D1-108b-1 A39
Me Me Me D1-108b-1 A40 Me Me Et D1-108b-1 A40
Me Me Me D1-108b-1 A41 Me Me Et D1-108b-1 A41
Me Me Me D1-108b-1 A73 Me Me Et D1-108b-1 A73
Me Me Me D1-108b-1 A75 Me Me Et D1-108b-1 A75
Me Me Me D1-108b-1 A83 Me Me Et D1-108b-1 A83
Me Me Me D1-108b-1 A84 Me Me Et D1-108b-1 A84
Me Me Me D1-108b-1 A85 Me Me Et D1-108b-1 A85
Me Me Me D1-108b-2 A91 Me Me Et D1-108b-2 A91
Me Me Me D1-108b-3 H Me Me Et D1-108b-3 H
Me Me Me D1-108b-4 H Me Me Et D1-108b-4 H
Me Me Me D1-108b-4 Me Me Me Et D1-108b-4 Me
Me Me Me D1-108b-4 A11 Me Me Et D1-108b-4 A11
Me Me Me D1-108b-4 A34 Me Me Et D1-108b-4 A34
Me Me Me D1-108b-4 A35 Me Me Et D1-108b-4 A35
Me Me Me D1-108b-4 A37 Me Me Et D1-108b-4 A37
Me Me Me D1-108b-4 A39 Me Me Et D1-108b-4 A39
Me Me Me D1-108b-4 A40 Me Me Et D1-108b-4 A40
Me Me Me D1-108b-4 A41 Me Me Et D1-108b-4 A41
Me Me Me D1-108b-4 A73 Me Me Et D1-108b-4 A73
Me Me Me D1-108b-4 A75 Me Me Et D1-108b-4 A75
Me Me Me D1-108b-4 A83 Me Me Et D1-108b-4 A83
Me Me Me D1-108b-4 A84 Me Me Et D1-108b-4 A84
Me Me Me D1-108b-4 A85 Me Me Et D1-108b-4 A85
Me Me Me D1-108b-4 A91 Me Me Et D1-108b-4 A91
Me Me Me D1-108b-5 H Me Me Et D1-108b-5 H
Me Me Me D1-108b-6 H Me Me Et D1-108b-6 H
Me Me Me D1-108b-7 H Me Me Et D1-108b-7 H
――――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Me Me D1-108b-8 H Me Me Et D1-108b-8 H
Me Me Me D1-108b-8 Me Me Me Et D1-108b-8 Me
Me Me Me D1-108b-8 A11 Me Me Et D1-108b-8 A11
Me Me Me D1-108b-8 A34 Me Me Et D1-108b-8 A34
Me Me Me D1-108b-8 A35 Me Me Et D1-108b-8 A35
Me Me Me D1-108b-8 A37 Me Me Et D1-108b-8 A37
Me Me Me D1-108b-8 A39 Me Me Et D1-108b-8 A39
Me Me Me D1-108b-8 A40 Me Me Et D1-108b-8 A40
Me Me Me D1-108b-8 A41 Me Me Et D1-108b-8 A41
Me Me Me D1-108b-8 A73 Me Me Et D1-108b-8 A73
Me Me Me D1-108b-8 A75 Me Me Et D1-108b-8 A75
Me Me Me D1-108b-8 A83 Me Me Et D1-108b-8 A83
Me Me Me D1-108b-8 A84 Me Me Et D1-108b-8 A84
Me Me Me D1-108b-8 A85 Me Me Et D1-108b-8 A85
Me Me Me D1-108b-8 A91 Me Me Et D1-108b-8 A91
Me Me Me D1-108b-9 H Me Me Et D1-108b-9 H
Me Me Me D1-108b-9 Me Me Me Et D1-108b-9 Me
Me Me Me D1-108b-9 A11 Me Me Et D1-108b-9 A11
Me Me Me D1-108b-9 A34 Me Me Et D1-108b-9 A34
Me Me Me D1-108b-9 A35 Me Me Et D1-108b-9 A35
Me Me Me D1-108b-9 A37 Me Me Et D1-108b-9 A37
Me Me Me D1-108b-9 A39 Me Me Et D1-108b-9 A39
Me Me Me D1-108b-9 A40 Me Me Et D1-108b-9 A40
Me Me Me D1-108b-9 A41 Me Me Et D1-108b-9 A41
Me Me Me D1-108b-9 A73 Me Me Et D1-108b-9 A73
Me Me Me D1-108b-9 A75 Me Me Et D1-108b-9 A75
Me Me Me D1-108b-9 A83 Me Me Et D1-108b-9 A83
Me Me Me D1-108b-9 A84 Me Me Et D1-108b-9 A84
Me Me Me D1-108b-9 A85 Me Me Et D1-108b-9 A85
Me Me Me D1-108b-9 A91 Me Me Et D1-108b-9 A91
Me Me Me D1-108b-10 H Me Me Et D1-108b-10 H
Me Me Me D1-108b-10 Me Me Me Et D1-108b-10 Me
Me Me Me D1-108b-10 A11 Me Me Et D1-108b-10 A11
Me Me Me D1-108b-10 A34 Me Me Et D1-108b-10 A34
Me Me Me D1-108b-10 A35 Me Me Et D1-108b-10 A35
Me Me Me D1-108b-10 A37 Me Me Et D1-108b-10 A37
Me Me Me D1-108b-10 A39 Me Me Et D1-108b-10 A39
Me Me Me D1-108b-10 A40 Me Me Et D1-108b-10 A40
Me Me Me D1-108b-10 A41 Me Me Et D1-108b-10 A41
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Me Me D1-108b-10 A73 Me Me Et D1-108b-10 A73
Me Me Me D1-108b-10 A75 Me Me Et D1-108b-10 A75
Me Me Me D1-108b-10 A83 Me Me Et D1-108b-10 A83
Me Me Me D1-108b-10 A84 Me Me Et D1-108b-10 A84
Me Me Me D1-108b-10 A85 Me Me Et D1-108b-10 A85
Me Me Me D1-108b-10 A91 Me Me Et D1-108b-10 A91
Me Me Me D1-108b-11 H Me Me Et D1-108b-11 H
Me Me Me D1-108b-12 H Me Me Et D1-108b-12 H
Me Me Me D1-108b-12 Me Me Me Et D1-108b-12 Me
Me Me Me D1-108b-12 A11 Me Me Et D1-108b-12 A11
Me Me Me D1-108b-12 A34 Me Me Et D1-108b-12 A34
Me Me Me D1-108b-12 A35 Me Me Et D1-108b-12 A35
Me Me Me D1-108b-12 A37 Me Me Et D1-108b-12 A37
Me Me Me D1-108b-12 A39 Me Me Et D1-108b-12 A39
Me Me Me D1-108b-12 A40 Me Me Et D1-108b-12 A40
Me Me Me D1-108b-12 A41 Me Me Et D1-108b-12 A41
Me Me Me D1-108b-12 A73 Me Me Et D1-108b-12 A73
Me Me Me D1-108b-12 A75 Me Me Et D1-108b-12 A75
Me Me Me D1-108b-12 A83 Me Me Et D1-108b-12 A83
Me Me Me D1-108b-12 A84 Me Me Et D1-108b-12 A84
Me Me Me D1-108b-12 A85 Me Me Et D1-108b-12 A85
Me Me Me D1-108b-12 A91 Me Me Et D1-108b-12 A91
Me Me Me D1-108b-13 H Me Me Et D1-108b-13 H
Me Me Me D1-108b-14 H Me Me Et D1-108b-14 H
Me Me Me D1-108b-15 H Me Me Et D1-108b-15 H
Me Me Me D1-108b-16 H Me Me Et D1-108b-16 H
Me Me Me D1-108b-17 H Me Me Et D1-108b-17 H
Me Me Me D1-108b-18 H Me Me Et D1-108b-18 H
Me Me Me D1-108b-19 H Me Me Et D1-108b-19 H
Me Me Me D1-2a H Me Me Et D1-2a H
Me Me Me D1-2b H Me Me Et D1-2b H
Me Me Me D1-7a H Me Me Et D1-7a H
Me Me Me D1-7b-1 H Me Me Et D1-7b-1 H
Me Me Me D1-7b-1 A39 Me Me Et D1-7b-1 A39
Me Me Me D1-7b-1 A40 Me Me Et D1-7b-1 A40
Me Me Me D1-7b-1 A41 Me Me Et D1-7b-1 A41
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
c-Pr Me Me D1-7b-1 H c-Pr Me Et D1-7b-1 H
c-Pr Me Me D1-7b-1 A39 c-Pr Me Et D1-7b-1 A39
c-Pr Me Me D1-7b-1 A40 c-Pr Me Et D1-7b-1 A40
c-Pr Me Me D1-7b-1 A41 c-Pr Me Et D1-7b-1 A41
c-Bu Me Me D1-7b-1 H c-Bu Me Et D1-7b-1 H
c-Bu Me Me D1-7b-1 A39 c-Bu Me Et D1-7b-1 A39
c-Bu Me Me D1-7b-1 A40 c-Bu Me Et D1-7b-1 A40
c-Bu Me Me D1-7b-1 A41 c-Bu Me Et D1-7b-1 A41
c-Pen Me Me D1-7b-1 H c-Pen Me Et D1-7b-1 H
c-Pen Me Me D1-7b-1 A39 c-Pen Me Et D1-7b-1 A39
c-Pen Me Me D1-7b-1 A40 c-Pen Me Et D1-7b-1 A40
c-Pen Me Me D1-7b-1 A41 c-Pen Me Et D1-7b-1 A41
c-Hex Me Me D1-7b-1 H c-Hex Me Et D1-7b-1 H
c-Hex Me Me D1-7b-1 A39 c-Hex Me Et D1-7b-1 A39
c-Hex Me Me D1-7b-1 A40 c-Hex Me Et D1-7b-1 A40
c-Hex Me Me D1-7b-1 A41 c-Hex Me Et D1-7b-1 A41
Me Me Me D1-7b-2 H Me Me Et D1-7b-2 H
Me Me Me D1-7b-2 A39 Me Me Et D1-7b-2 A39
Me Me Me D1-7b-2 A40 Me Me Et D1-7b-2 A40
Me Me Me D1-7b-2 A41 Me Me Et D1-7b-2 A41
c-Pr Me Me D1-7b-2 H c-Pr Me Et D1-7b-2 H
c-Pr Me Me D1-7b-2 A39 c-Pr Me Et D1-7b-2 A39
c-Pr Me Me D1-7b-2 A40 c-Pr Me Et D1-7b-2 A40
c-Pr Me Me D1-7b-2 A41 c-Pr Me Et D1-7b-2 A41
c-Bu Me Me D1-7b-2 H c-Bu Me Et D1-7b-2 H
c-Bu Me Me D1-7b-2 A39 c-Bu Me Et D1-7b-2 A39
c-Bu Me Me D1-7b-2 A40 c-Bu Me Et D1-7b-2 A40
c-Bu Me Me D1-7b-2 A41 c-Bu Me Et D1-7b-2 A41
c-Pen Me Me D1-7b-2 H c-Pen Me Et D1-7b-2 H
c-Pen Me Me D1-7b-2 A39 c-Pen Me Et D1-7b-2 A39
c-Pen Me Me D1-7b-2 A40 c-Pen Me Et D1-7b-2 A40
c-Pen Me Me D1-7b-2 A41 c-Pen Me Et D1-7b-2 A41
c-Hex Me Me D1-7b-2 H c-Hex Me Et D1-7b-2 H
c-Hex Me Me D1-7b-2 A39 c-Hex Me Et D1-7b-2 A39
c-Hex Me Me D1-7b-2 A40 c-Hex Me Et D1-7b-2 A40
c-Hex Me Me D1-7b-2 A41 c-Hex Me Et D1-7b-2 A41
Me Me Me D1-7b-3 H Me Me Et D1-7b-3 H
Me Me Me D1-7b-3 A39 Me Me Et D1-7b-3 A39
Me Me Me D1-7b-3 A40 Me Me Et D1-7b-3 A40
Me Me Me D1-7b-3 A41 Me Me Et D1-7b-3 A41
c-Pr Me Me D1-7b-3 H c-Pr Me Et D1-7b-3 H
c-Pr Me Me D1-7b-3 A39 c-Pr Me Et D1-7b-3 A39
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
c-Pr Me Me D1-7b-3 A40 c-Pr Me Et D1-7b-3 A40
c-Pr Me Me D1-7b-3 A41 c-Pr Me Et D1-7b-3 A41
c-Bu Me Me D1-7b-3 H c-Bu Me Et D1-7b-3 H
c-Bu Me Me D1-7b-3 A39 c-Bu Me Et D1-7b-3 A39
c-Bu Me Me D1-7b-3 A40 c-Bu Me Et D1-7b-3 A40
c-Bu Me Me D1-7b-3 A41 c-Bu Me Et D1-7b-3 A41
c-Pen Me Me D1-7b-3 H c-Pen Me Et D1-7b-3 H
c-Pen Me Me D1-7b-3 A39 c-Pen Me Et D1-7b-3 A39
c-Pen Me Me D1-7b-3 A40 c-Pen Me Et D1-7b-3 A40
c-Pen Me Me D1-7b-3 A41 c-Pen Me Et D1-7b-3 A41
c-Hex Me Me D1-7b-3 H c-Hex Me Et D1-7b-3 H
c-Hex Me Me D1-7b-3 A39 c-Hex Me Et D1-7b-3 A39
c-Hex Me Me D1-7b-3 A40 c-Hex Me Et D1-7b-3 A40
c-Hex Me Me D1-7b-3 A41 c-Hex Me Et D1-7b-3 A41
Me Me Me D1-7b-4 H Me Me Et D1-7b-4 H
Me Me Me D1-7b-4 A39 Me Me Et D1-7b-4 A39
Me Me Me D1-7b-4 A40 Me Me Et D1-7b-4 A40
Me Me Me D1-7b-4 A41 Me Me Et D1-7b-4 A41
c-Pr Me Me D1-7b-4 H c-Pr Me Et D1-7b-4 H
c-Pr Me Me D1-7b-4 A39 c-Pr Me Et D1-7b-4 A39
c-Pr Me Me D1-7b-4 A40 c-Pr Me Et D1-7b-4 A40
c-Pr Me Me D1-7b-4 A41 c-Pr Me Et D1-7b-4 A41
c-Bu Me Me D1-7b-4 H c-Bu Me Et D1-7b-4 H
c-Bu Me Me D1-7b-4 A39 c-Bu Me Et D1-7b-4 A39
c-Bu Me Me D1-7b-4 A40 c-Bu Me Et D1-7b-4 A40
c-Bu Me Me D1-7b-4 A41 c-Bu Me Et D1-7b-4 A41
c-Pen Me Me D1-7b-4 H c-Pen Me Et D1-7b-4 H
c-Pen Me Me D1-7b-4 A39 c-Pen Me Et D1-7b-4 A39
c-Pen Me Me D1-7b-4 A40 c-Pen Me Et D1-7b-4 A40
c-Pen Me Me D1-7b-4 A41 c-Pen Me Et D1-7b-4 A41
c-Hex Me Me D1-7b-4 H c-Hex Me Et D1-7b-4 H
c-Hex Me Me D1-7b-4 A39 c-Hex Me Et D1-7b-4 A39
c-Hex Me Me D1-7b-4 A40 c-Hex Me Et D1-7b-4 A40
c-Hex Me Me D1-7b-4 A41 c-Hex Me Et D1-7b-4 A41
Me Me Me D1-10a H Me Me Et D1-10a H
Me Me Me D1-11a H Me Me Et D1-11a H
Me Me Me D1-11b-1 H Me Me Et D1-11b-1 H
Me Me Me D1-11b-2 H Me Me Et D1-11b-2 H
Me Me Me D1-11b-3 H Me Me Et D1-11b-3 H
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Me Me D1-11b-4 H Me Me Et D1-11b-4 H
Me Me Me D1-22a H Me Me Et D1-22a H
Me Me Me D1-22b-1 H Me Me Et D1-22b-1 H
Me Me Me D1-22b-2 H Me Me Et D1-22b-2 H
Me Me Me D1-22b-3 H Me Me Et D1-22b-3 H
Me Me Me D1-22b-4 H Me Me Et D1-22b-4 H
Me Me Me D1-32a H Me Me Et D1-32a H
Me Me Me D1-32b-1 H Me Me Et D1-32b-1 H
Me Me Me D1-32b-2 H Me Me Et D1-32b-2 H
Me Me Me D1-32b-3 H Me Me Et D1-32b-3 H
Me Me Me D1-32b-4 H Me Me Et D1-32b-4 H
Me Me Me D1-32b-5 H Me Me Et D1-32b-5 H
Me Me Me D1-33a H Me Me Et D1-33a H
Me Me Me D1-33b-1 H Me Me Et D1-33b-1 H
Me Me Me D1-33b-2 H Me Me Et D1-33b-2 H
Me Me Me D1-33b-3 H Me Me Et D1-33b-3 H
Me Me Me D1-33b-4 H Me Me Et D1-33b-4 H
Me Me Me D1-34a H Me Me Et D1-34a H
Me Me Me D1-37a H Me Me Et D1-37a H
Me Me Me D1-37b-1 H Me Me Et D1-37b-1 H
Me Me Me C≡CH H Me Me Et C≡CH H
Me Me Me C≡CH A39 Me Me Et C≡CH A39
Me Me Me C≡CH A40 Me Me Et C≡CH A40
Me Me Me C≡CH A41 Me Me Et C≡CH A41
c-Pr Me Me C≡CH H c-Pr Me Et C≡CH H
c-Pr Me Me C≡CH A39 c-Pr Me Et C≡CH A39
c-Pr Me Me C≡CH A40 c-Pr Me Et C≡CH A40
c-Pr Me Me C≡CH A41 c-Pr Me Et C≡CH A41
c-Bu Me Me C≡CH H c-Bu Me Et C≡CH H
c-Bu Me Me C≡CH A39 c-Bu Me Et C≡CH A39
c-Bu Me Me C≡CH A40 c-Bu Me Et C≡CH A40
c-Bu Me Me C≡CH A41 c-Bu Me Et C≡CH A41
c-Pen Me Me C≡CH H c-Pen Me Et C≡CH H
c-Pen Me Me C≡CH A39 c-Pen Me Et C≡CH A39
c-Pen Me Me C≡CH A40 c-Pen Me Et C≡CH A40
c-Pen Me Me C≡CH A41 c-Pen Me Et C≡CH A41
c-Hex Me Me C≡CH H c-Hex Me Et C≡CH H
c-Hex Me Me C≡CH A39 c-Hex Me Et C≡CH A39
c-Hex Me Me C≡CH A40 c-Hex Me Et C≡CH A40
c-Hex Me Me C≡CH A41 c-Hex Me Et C≡CH A41
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Me Me C≡CBu-c H Me Me Et C≡CBu-c H
Me Me Me C≡CBu-c A39 Me Me Et C≡CBu-c A39
Me Me Me C≡CBu-c A40 Me Me Et C≡CBu-c A40
Me Me Me C≡CBu-c A41 Me Me Et C≡CBu-c A41
c-Pr Me Me C≡CBu-c H c-Pr Me Et C≡CBu-c H
c-Pr Me Me C≡CBu-c A39 c-Pr Me Et C≡CBu-c A39
c-Pr Me Me C≡CBu-c A40 c-Pr Me Et C≡CBu-c A40
c-Pr Me Me C≡CBu-c A41 c-Pr Me Et C≡CBu-c A41
c-Bu Me Me C≡CBu-c H c-Bu Me Et C≡CBu-c H
c-Bu Me Me C≡CBu-c A39 c-Bu Me Et C≡CBu-c A39
c-Bu Me Me C≡CBu-c A40 c-Bu Me Et C≡CBu-c A40
c-Bu Me Me C≡CBu-c A41 c-Bu Me Et C≡CBu-c A41
c-Pen Me Me C≡CBu-c H c-Pen Me Et C≡CBu-c H
c-Pen Me Me C≡CBu-c A39 c-Pen Me Et C≡CBu-c A39
c-Pen Me Me C≡CBu-c A40 c-Pen Me Et C≡CBu-c A40
c-Pen Me Me C≡CBu-c A41 c-Pen Me Et C≡CBu-c A41
c-Hex Me Me C≡CBu-c H c-Hex Me Et C≡CBu-c H
c-Hex Me Me C≡CBu-c A39 c-Hex Me Et C≡CBu-c A39
c-Hex Me Me C≡CBu-c A40 c-Hex Me Et C≡CBu-c A40
c-Hex Me Me C≡CBu-c A41 c-Hex Me Et C≡CBu-c A41
Me Me Me C≡CPen-c H Me Me Et C≡CPen-c H
Me Me Me C≡CPen-c A39 Me Me Et C≡CPen-c A39
Me Me Me C≡CPen-c A40 Me Me Et C≡CPen-c A40
Me Me Me C≡CPen-c A41 Me Me Et C≡CPen-c A41
c-Pr Me Me C≡CPen-c H c-Pr Me Et C≡CPen-c H
c-Pr Me Me C≡CPen-c A39 c-Pr Me Et C≡CPen-c A39
c-Pr Me Me C≡CPen-c A40 c-Pr Me Et C≡CPen-c A40
c-Pr Me Me C≡CPen-c A41 c-Pr Me Et C≡CPen-c A41
c-Bu Me Me C≡CPen-c H c-Bu Me Et C≡CPen-c H
c-Bu Me Me C≡CPen-c A39 c-Bu Me Et C≡CPen-c A39
c-Bu Me Me C≡CPen-c A40 c-Bu Me Et C≡CPen-c A40
c-Bu Me Me C≡CPen-c A41 c-Bu Me Et C≡CPen-c A41
c-Pen Me Me C≡CPen-c H c-Pen Me Et C≡CPen-c H
c-Pen Me Me C≡CPen-c A39 c-Pen Me Et C≡CPen-c A39
c-Pen Me Me C≡CPen-c A40 c-Pen Me Et C≡CPen-c A40
c-Pen Me Me C≡CPen-c A41 c-Pen Me Et C≡CPen-c A41
c-Hex Me Me C≡CPen-c H c-Hex Me Et C≡CPen-c H
c-Hex Me Me C≡CPen-c A39 c-Hex Me Et C≡CPen-c A39
c-Hex Me Me C≡CPen-c A40 c-Hex Me Et C≡CPen-c A40
c-Hex Me Me C≡CPen-c A41 c-Hex Me Et C≡CPen-c A41
Me Me Me C≡CHex-c H Me Me Et C≡CHex-c H
Me Me Me C≡CHex-c A39 Me Me Et C≡CHex-c A39
Me Me Me C≡CHex-c A40 Me Me Et C≡CHex-c A40
Me Me Me C≡CHex-c A41 Me Me Et C≡CHex-c A41
c-Pr Me Me C≡CHex-c H c-Pr Me Et C≡CHex-c H
c-Pr Me Me C≡CHex-c A39 c-Pr Me Et C≡CHex-c A39
c-Pr Me Me C≡CHex-c A40 c-Pr Me Et C≡CHex-c A40
c-Pr Me Me C≡CHex-c A41 c-Pr Me Et C≡CHex-c A41
c-Bu Me Me C≡CHex-c H c-Bu Me Et C≡CHex-c H
c-Bu Me Me C≡CHex-c A39 c-Bu Me Et C≡CHex-c A39
c-Bu Me Me C≡CHex-c A40 c-Bu Me Et C≡CHex-c A40
c-Bu Me Me C≡CHex-c A41 c-Bu Me Et C≡CHex-c A41
c-Pen Me Me C≡CHex-c H c-Pen Me Et C≡CHex-c H
c-Pen Me Me C≡CHex-c A39 c-Pen Me Et C≡CHex-c A39
c-Pen Me Me C≡CHex-c A40 c-Pen Me Et C≡CHex-c A40
c-Pen Me Me C≡CHex-c A41 c-Pen Me Et C≡CHex-c A41
c-Hex Me Me C≡CHex-c H c-Hex Me Et C≡CHex-c H
c-Hex Me Me C≡CHex-c A39 c-Hex Me Et C≡CHex-c A39
c-Hex Me Me C≡CHex-c A40 c-Hex Me Et C≡CHex-c A40
c-Hex Me Me C≡CHex-c A41 c-Hex Me Et C≡CHex-c A41
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
――――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――――― ―――――――――――――――――
Me Me Me Ph A74 Me Me Et Ph A74
Me Me Me D1-108b-1 A74 Me Me Et D1-108b-1 A74
Me Me Me D1-108b-2 H Me Me Et D1-108b-2 H
Me Me Me D1-108b-4 A74 Me Me Et D1-108b-4 A74
Me Me Me D1-108b-8 A74 Me Me Et D1-108b-8 A74
Me Me Me D1-108b-9 A74 Me Me Et D1-108b-9 A74
Me Me Me D1-108b-10 A74 Me Me Et D1-108b-10 A74
Me Me Me D1-108b-12 A74 Me Me Et D1-108b-12 A74
Me Et Et Ph A74 Me Me n-Pr Ph A74
Me Et Et D1-108b-1 A74 Me Me n-Pr D1-108b-1 A74
Me Et Et D1-108b-2 H Me Me n-Pr D1-108b-2 H
Me Et Et D1-108b-4 A74 Me Me n-Pr D1-108b-4 A74
Me Et Et D1-108b-8 A74 Me Me n-Pr D1-108b-8 A74
Me Et Et D1-108b-9 A74 Me Me n-Pr D1-108b-9 A74
Me Et Et D1-108b-10 A74 Me Me n-Pr D1-108b-10 A74
Me Et Et D1-108b-12 A74 Me Me n-Pr D1-108b-12 A74
Me Et Et C≡CMe H Me Me n-Pr C≡CMe H
Me Et Et C≡CMe A39 Me Me n-Pr C≡CMe A39
Me Et Et C≡CMe A40 Me Me n-Pr C≡CMe A40
Me Et Et C≡CMe A41 Me Me n-Pr C≡CMe A41
c-Pr Et Et C≡CMe H c-Pr Me n-Pr C≡CMe H
c-Pr Et Et C≡CMe A39 c-Pr Me n-Pr C≡CMe A39
c-Pr Et Et C≡CMe A40 c-Pr Me n-Pr C≡CMe A40
c-Pr Et Et C≡CMe A41 c-Pr Me n-Pr C≡CMe A41
c-Bu Et Et C≡CMe H c-Bu Me n-Pr C≡CMe H
c-Bu Et Et C≡CMe A39 c-Bu Me n-Pr C≡CMe A39
c-Bu Et Et C≡CMe A40 c-Bu Me n-Pr C≡CMe A40
c-Bu Et Et C≡CMe A41 c-Bu Me n-Pr C≡CMe A41
c-Pen Et Et C≡CMe H c-Pen Me n-Pr C≡CMe H
c-Pen Et Et C≡CMe A39 c-Pen Me n-Pr C≡CMe A39
c-Pen Et Et C≡CMe A40 c-Pen Me n-Pr C≡CMe A40
c-Pen Et Et C≡CMe A41 c-Pen Me n-Pr C≡CMe A41
c-Hex Et Et C≡CMe H c-Hex Me n-Pr C≡CMe H
c-Hex Et Et C≡CMe A39 c-Hex Me n-Pr C≡CMe A39
c-Hex Et Et C≡CMe A40 c-Hex Me n-Pr C≡CMe A40
c-Hex Et Et C≡CMe A41 c-Hex Me n-Pr C≡CMe A41
Me Et Et C≡CSi (Me) _Three H Me Me n-Pr C≡CSi (Me) _Three H
Me Et Et C≡CSi (Me) _Three A39 Me Me n-Pr C≡CSi (Me) _Three A39
Me Et Et C≡CSi (Me) _Three A40 Me Me n-Pr C≡CSi (Me) _Three A40
Me Et Et C≡CSi (Me) _Three A41 Me Me n-Pr C≡CSi (Me) _Three A41
c-Pr Et Et C≡CSi (Me) _Three H c-Pr Me n-Pr C≡CSi (Me) _Three H
c-Pr Et Et C≡CSi (Me) _Three A39 c-Pr Me n-Pr C≡CSi (Me) _Three A39
c-Pr Et Et C≡CSi (Me) _Three A40 c-Pr Me n-Pr C≡CSi (Me) _Three A40
c-Pr Et Et C≡CSi (Me) _Three A41 c-Pr Me n-Pr C≡CSi (Me) _Three A41
c-Bu Et Et C≡CSi (Me) _Three H c-Bu Me n-Pr C≡CSi (Me) _Three H
c-Bu Et Et C≡CSi (Me) _Three A39 c-Bu Me n-Pr C≡CSi (Me) _Three A39
c-Bu Et Et C≡CSi (Me) _Three A40 c-Bu Me n-Pr C≡CSi (Me) _Three A40
c-Bu Et Et C≡CSi (Me) _Three A41 c-Bu Me n-Pr C≡CSi (Me) _Three A41
c-Pen Et Et C≡CSi (Me) 2 H c-Pen Me n-Pr C≡CSi (Me) 2 H
c-Pen Et Et C≡CSi (Me) _Three A39 c-Pen Me n-Pr C≡CSi (Me) _Three A39
c-Pen Et Et C≡CSi (Me) _Three A40 c-Pen Me n-Pr C≡CSi (Me) _Three A40
c-Pen Et Et C≡CSi (Me) _Three A41 c-Pen Me n-Pr C≡CSi (Me) _Three A41
c-Hex Et Et C≡CSi (Me) _Three H c-Hex Me n-Pr C≡CSi (Me) _Three H
c-Hex Et Et C≡CSi (Me) _Three A39 c-Hex Me n-Pr C≡CSi (Me) _Three A39
c-Hex Et Et C≡CSi (Me) _Three A40 c-Hex Me n-Pr C≡CSi (Me) _Three A40
c-Hex Et Et C≡CSi (Me) _Three A41 c-Hex Me n-Pr C≡CSi (Me) _Three A41
――――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
――――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――――― ―――――――――――――――――
Me Et Et C≡CPr-c H Me Me n-Pr C≡CPr-c H
Me Et Et C≡CPr-c A39 Me Me n-Pr C≡CPr-c A39
Me Et Et C≡CPr-c A40 Me Me n-Pr C≡CPr-c A40
Me Et Et C≡CPr-c A41 Me Me n-Pr C≡CPr-c A41
c-Pr Et Et C≡CPr-c H c-Pr Men n-Pr C≡CPr-c H
c-Pr Et Et C≡CPr-c A39 c-Pr Men n-Pr C≡CPr-c A39
c-Pr Et Et C≡CPr-c A40 c-Pr Men n-Pr C≡CPr-c A40
c-Pr Et Et C≡CPr-c A41 c-Pr Men n-Pr C≡CPr-c A41
c-Bu Et Et C≡CPr-c H c-Bu Me n-Pr C≡CPr-c H
c-Bu Et Et C≡CPr-c A39 c-Bu Me n-Pr C≡CPr-c A39
c-Bu Et Et C≡CPr-c A40 c-Bu Me n-Pr C≡CPr-c A40
c-Bu Et Et C≡CPr-c A41 c-Bu Me n-Pr C≡CPr-c A41
c-Pen Et Et C≡CPr-c H c-Pen Men n-Pr C≡CPr-c H
c-Pen Et Et C≡CPr-c A39 c-Pen Men n-Pr C≡CPr-c A39
c-Pen Et Et C≡CPr-c A40 c-Pen Men n-Pr C≡CPr-c A40
c-Pen Et Et C≡CPr-c A41 c-Pen Men n-Pr C≡CPr-c A41
c-Hex Et Et C≡CPr-c H c-Hex Me n-Pr C≡CPr-c H
c-Hex Et Et C≡CPr-c A39 c-Hex Me n-Pr C≡CPr-c A39
c-Hex Et Et C≡CPr-c A40 c-Hex Me n-Pr C≡CPr-c A40
c-Hex Et Et C≡CPr-c A41 c-Hex Me n-Pr C≡CPr-c A41
Me Et Et C≡CC (Me) ₂ OH H Me Me n-Pr C≡CC (Me) ₂ OH H
Me Et Et C≡CC (Me) ₂ OH A39 Me Me n-Pr C≡CC (Me) ₂ OH A39
Me Et Et C≡CC (Me) ₂ OH A40 Me Me n-Pr C≡CC (Me) ₂ OH A40
Me Et Et C≡CC (Me) ₂ OH A41 Me Me n-Pr C≡CC (Me) ₂ OH A41
Me Et Et C≡CCH ₂ OH H Me Me n-Pr C≡CCH ₂ OH H
Me Et Et C≡CCH ₂ OH A39 Me Me n-Pr C≡CCH ₂ OH A39
Me Et Et C≡CCH ₂ OH A40 Me Me n-Pr C≡CCH ₂ OH A40
Me Et Et C≡CCH ₂ OH A41 Me Me n-Pr C≡CCH ₂ OH A41
――――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et Ph H Me Me n-Pr Ph H
Me Et Et Ph Me Me Me n-Pr Ph Me
Me Et Et Ph A11 Me Me n-Pr Ph A11
Me Et Et Ph A34 Me Me n-Pr Ph A34
Me Et Et Ph A35 Me Me n-Pr Ph A35
Me Et Et Ph A37 Me Me n-Pr Ph A37
Me Et Et Ph A39 Me Me n-Pr Ph A39
Me Et Et Ph A40 Me Me n-Pr Ph A40
Me Et Et Ph A41 Me Me n-Pr Ph A41
Me Et Et Ph A73 Me Me n-Pr Ph A73
Me Et Et Ph A75 Me Me n-Pr Ph A75
Me Et Et Ph A83 Me Me n-Pr Ph A83
Me Et Et Ph A84 Me Me n-Pr Ph A84
Me Et Et Ph A85 Me Me n-Pr Ph A85
Me Et Et Ph A91 Me Me n-Pr Ph A91
Me Et Et D1-108b-1 H Me Me n-Pr D1-108b-1 H
Me Et Et D1-108b-1 Me Me Me n-Pr D1-108b-1 Me
Me Et Et D1-108b-1 A11 Me Me n-Pr D1-108b-1 A11
Me Et Et D1-108b-1 A34 Me Me n-Pr D1-108b-1 A34
Me Et Et D1-108b-1 A35 Me Me n-Pr D1-108b-1 A35
Me Et Et D1-108b-1 A37 Me Me n-Pr D1-108b-1 A37
Me Et Et D1-108b-1 A39 Me Me n-Pr D1-108b-1 A39
Me Et Et D1-108b-1 A40 Me Me n-Pr D1-108b-1 A40
Me Et Et D1-108b-1 A41 Me Me n-Pr D1-108b-1 A41
Me Et Et D1-108b-1 A73 Me Me n-Pr D1-108b-1 A73
Me Et Et D1-108b-1 A75 Me Me n-Pr D1-108b-1 A75
Me Et Et D1-108b-1 A83 Me Me n-Pr D1-108b-1 A83
Me Et Et D1-108b-1 A84 Me Me n-Pr D1-108b-1 A84
Me Et Et D1-108b-1 A85 Me Me n-Pr D1-108b-1 A85
Me Et Et D1-108b-2 A91 Me Me n-Pr D1-108b-2 A91
Me Et Et D1-108b-3 H Me Me n-Pr D1-108b-3 H
Me Et Et D1-108b-4 H Me Me n-Pr D1-108b-4 H
Me Et Et D1-108b-4 Me Me Me n-Pr D1-108b-4 Me
Me Et Et D1-108b-4 A11 Me Me n-Pr D1-108b-4 A11
Me Et Et D1-108b-4 A34 Me Me n-Pr D1-108b-4 A34
Me Et Et D1-108b-4 A35 Me Me n-Pr D1-108b-4 A35
Me Et Et D1-108b-4 A37 Me Me n-Pr D1-108b-4 A37
Me Et Et D1-108b-4 A39 Me Me n-Pr D1-108b-4 A39
Me Et Et D1-108b-4 A40 Me Me n-Pr D1-108b-4 A40
Me Et Et D1-108b-4 A41 Me Me n-Pr D1-108b-4 A41
Me Et Et D1-108b-4 A73 Me Me n-Pr D1-108b-4 A73
Me Et Et D1-108b-4 A75 Me Me n-Pr D1-108b-4 A75
Me Et Et D1-108b-4 A83 Me Me n-Pr D1-108b-4 A83
Me Et Et D1-108b-4 A84 Me Me n-Pr D1-108b-4 A84
Me Et Et D1-108b-4 A85 Me Me n-Pr D1-108b-4 A85
Me Et Et D1-108b-4 A91 Me Me n-Pr D1-108b-4 A91
Me Et Et D1-108b-5 H Me Me n-Pr D1-108b-5 H
Me Et Et D1-108b-6 H Me Me n-Pr D1-108b-6 H
Me Et Et D1-108b-7 H Me Me n-Pr D1-108b-7 H
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et D1-108b-8 H Me Me n-Pr D1-108b-8 H
Me Et Et D1-108b-8 Me Me Me n-Pr D1-108b-8 Me
Me Et Et D1-108b-8 A11 Me Me n-Pr D1-108b-8 A11
Me Et Et D1-108b-8 A34 Me Me n-Pr D1-108b-8 A34
Me Et Et D1-108b-8 A35 Me Me n-Pr D1-108b-8 A35
Me Et Et D1-108b-8 A37 Me Me n-Pr D1-108b-8 A37
Me Et Et D1-108b-8 A39 Me Me n-Pr D1-108b-8 A39
Me Et Et D1-108b-8 A40 Me Me n-Pr D1-108b-8 A40
Me Et Et D1-108b-8 A41 Me Me n-Pr D1-108b-8 A41
Me Et Et D1-108b-8 A73 Me Me n-Pr D1-108b-8 A73
Me Et Et D1-108b-8 A75 Me Me n-Pr D1-108b-8 A75
Me Et Et D1-108b-8 A83 Me Me n-Pr D1-108b-8 A83
Me Et Et D1-108b-8 A84 Me Me n-Pr D1-108b-8 A84
Me Et Et D1-108b-8 A85 Me Me n-Pr D1-108b-8 A85
Me Et Et D1-108b-8 A91 Me Me n-Pr D1-108b-8 A91
Me Et Et D1-108b-9 H Me Me n-Pr D1-108b-9 H
Me Et Et D1-108b-9 Me Me Me n-Pr D1-108b-9 Me
Me Et Et D1-108b-9 A11 Me Me n-Pr D1-108b-9 A11
Me Et Et D1-108b-9 A34 Me Me n-Pr D1-108b-9 A34
Me Et Et D1-108b-9 A35 Me Me n-Pr D1-108b-9 A35
Me Et Et D1-108b-9 A37 Me Me n-Pr D1-108b-9 A37
Me Et Et D1-108b-9 A39 Me Me n-Pr D1-108b-9 A39
Me Et Et D1-108b-9 A40 Me Me n-Pr D1-108b-9 A40
Me Et Et D1-108b-9 A41 Me Me n-Pr D1-108b-9 A41
Me Et Et D1-108b-9 A73 Me Me n-Pr D1-108b-9 A73
Me Et Et D1-108b-9 A75 Me Me n-Pr D1-108b-9 A75
Me Et Et D1-108b-9 A83 Me Me n-Pr D1-108b-9 A83
Me Et Et D1-108b-9 A84 Me Me n-Pr D1-108b-9 A84
Me Et Et D1-108b-9 A85 Me Me n-Pr D1-108b-9 A85
Me Et Et D1-108b-9 A91 Me Me n-Pr D1-108b-9 A91
Me Et Et D1-108b-10 H Me Me n-Pr D1-108b-10 H
Me Et Et D1-108b-10 Me Me Me n-Pr D1-108b-10 Me
Me Et Et D1-108b-10 A11 Me Me n-Pr D1-108b-10 A11
Me Et Et D1-108b-10 A34 Me Me n-Pr D1-108b-10 A34
Me Et Et D1-108b-10 A35 Me Me n-Pr D1-108b-10 A35
Me Et Et D1-108b-10 A37 Me Me n-Pr D1-108b-10 A37
Me Et Et D1-108b-10 A39 Me Me n-Pr D1-108b-10 A39
Me Et Et D1-108b-10 A40 Me Me n-Pr D1-108b-10 A40
Me Et Et D1-108b-10 A41 Me Me n-Pr D1-108b-10 A41
Me Et Et D1-108b-10 A73 Me Me n-Pr D1-108b-10 A73
Me Et Et D1-108b-10 A75 Me Me n-Pr D1-108b-10 A75
Me Et Et D1-108b-10 A83 Me Me n-Pr D1-108b-10 A83
Me Et Et D1-108b-10 A84 Me Me n-Pr D1-108b-10 A84
Me Et Et D1-108b-10 A85 Me Me n-Pr D1-108b-10 A85
Me Et Et D1-108b-10 A91 Me Me n-Pr D1-108b-10 A91
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et D1-108b-11 H Me Me n-Pr D1-108b-11 H
Me Et Et D1-108b-12 H Me Me n-Pr D1-108b-12 H
Me Et Et D1-108b-12 Me Me Me n-Pr D1-108b-12 Me
Me Et Et D1-108b-12 A11 Me Me n-Pr D1-108b-12 A11
Me Et Et D1-108b-12 A34 Me Me n-Pr D1-108b-12 A34
Me Et Et D1-108b-12 A35 Me Me n-Pr D1-108b-12 A35
Me Et Et D1-108b-12 A37 Me Me n-Pr D1-108b-12 A37
Me Et Et D1-108b-12 A39 Me Me n-Pr D1-108b-12 A39
Me Et Et D1-108b-12 A40 Me Me n-Pr D1-108b-12 A40
Me Et Et D1-108b-12 A41 Me Me n-Pr D1-108b-12 A41
Me Et Et D1-108b-12 A73 Me Me n-Pr D1-108b-12 A73
Me Et Et D1-108b-12 A75 Me Me n-Pr D1-108b-12 A75
Me Et Et D1-108b-12 A83 Me Me n-Pr D1-108b-12 A83
Me Et Et D1-108b-12 A84 Me Me n-Pr D1-108b-12 A84
Me Et Et D1-108b-12 A85 Me Me n-Pr D1-108b-12 A85
Me Et Et D1-108b-12 A91 Me Me n-Pr D1-108b-12 A91
Me Et Et D1-108b-13 H Me Me n-Pr D1-108b-13 H
Me Et Et D1-108b-14 H Me Me n-Pr D1-108b-14 H
Me Et Et D1-108b-15 H Me Me n-Pr D1-108b-15 H
Me Et Et D1-108b-16 H Me Me n-Pr D1-108b-16 H
Me Et Et D1-108b-17 H Me Me n-Pr D1-108b-17 H
Me Et Et D1-108b-18 H Me Me n-Pr D1-108b-18 H
Me Et Et D1-108b-19 H Me Me n-Pr D1-108b-19 H
Me Et Et D1-2a H Me Me n-Pr D1-2a H
Me Et Et D1-2b H Me Me n-Pr D1-2b H
Me Et Et D1-7a H Me Me n-Pr D1-7a H
Me Et Et D1-7b-1 H Me Me n-Pr D1-7b-1 H
Me Et Et D1-7b-1 A39 Me Me n-Pr D1-7b-1 A39
Me Et Et D1-7b-1 A40 Me Me n-Pr D1-7b-1 A40
Me Et Et D1-7b-1 A41 Me Me n-Pr D1-7b-1 A41
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
c-Pr Et Et D1-7b-1 H c-Pr Men n-Pr D1-7b-1 H
c-Pr Et Et D1-7b-1 A39 c-Pr Men n-Pr D1-7b-1 A39
c-Pr Et Et D1-7b-1 A40 c-Pr Men n-Pr D1-7b-1 A40
c-Pr Et Et D1-7b-1 A41 c-Pr Men n-Pr D1-7b-1 A41
c-Bu Et Et D1-7b-1 H c-Bu Men n-Pr D1-7b-1 H
c-Bu Et Et D1-7b-1 A39 c-Bu Me n-Pr D1-7b-1 A39
c-Bu Et Et D1-7b-1 A40 c-Bu Me n-Pr D1-7b-1 A40
c-Bu Et Et D1-7b-1 A41 c-Bu Me n-Pr D1-7b-1 A41
c-Pen Et Et D1-7b-1 H c-Pen Men n-Pr D1-7b-1 H
c-Pen Et Et D1-7b-1 A39 c-Pen Men n-Pr D1-7b-1 A39
c-Pen Et Et D1-7b-1 A40 c-Pen Men n-Pr D1-7b-1 A40
c-Pen Et Et D1-7b-1 A41 c-Pen Men n-Pr D1-7b-1 A41
c-Hex Et Et D1-7b-1 H c-Hex Men n-Pr D1-7b-1 H
c-Hex Et Et D1-7b-1 A39 c-Hex Men n-Pr D1-7b-1 A39
c-Hex Et Et D1-7b-1 A40 c-Hex Men n-Pr D1-7b-1 A40
c-Hex Et Et D1-7b-1 A41 c-Hex Men n-Pr D1-7b-1 A41
Me Et Et D1-7b-2 H Me Me n-Pr D1-7b-2 H
Me Et Et D1-7b-2 A39 Me Me n-Pr D1-7b-2 A39
Me Et Et D1-7b-2 A40 Me Me n-Pr D1-7b-2 A40
Me Et Et D1-7b-2 A41 Me Me n-Pr D1-7b-2 A41
c-Pr Et Et D1-7b-2 H c-Pr Men n-Pr D1-7b-2 H
c-Pr Et Et D1-7b-2 A39 c-Pr Men n-Pr D1-7b-2 A39
c-Pr Et Et D1-7b-2 A40 c-Pr Men n-Pr D1-7b-2 A40
c-Pr Et Et D1-7b-2 A41 c-Pr Men n-Pr D1-7b-2 A41
c-Bu Et Et D1-7b-2 H c-Bu Me n-Pr D1-7b-2 H
c-Bu Et Et D1-7b-2 A39 c-Bu Me n-Pr D1-7b-2 A39
c-Bu Et Et D1-7b-2 A40 c-Bu Me n-Pr D1-7b-2 A40
c-Bu Et Et D1-7b-2 A41 c-Bu Me n-Pr D1-7b-2 A41
c-Pen Et Et D1-7b-2 H c-Pen Men n-Pr D1-7b-2 H
c-Pen Et Et D1-7b-2 A39 c-Pen Men n-Pr D1-7b-2 A39
c-Pen Et Et D1-7b-2 A40 c-Pen Men n-Pr D1-7b-2 A40
c-Pen Et Et D1-7b-2 A41 c-Pen Men n-Pr D1-7b-2 A41
c-Hex Et Et D1-7b-2 H c-Hex Me n-Pr D1-7b-2 H
c-Hex Et Et D1-7b-2 A39 c-Hex Me n-Pr D1-7b-2 A39
c-Hex Et Et D1-7b-2 A40 c-Hex Me n-Pr D1-7b-2 A40
c-Hex Et Et D1-7b-2 A41 c-Hex Me n-Pr D1-7b-2 A41
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et D1-7b-3 H Me Me n-Pr D1-7b-3 H
Me Et Et D1-7b-3 A39 Me Me n-Pr D1-7b-3 A39
Me Et Et D1-7b-3 A40 Me Me n-Pr D1-7b-3 A40
Me Et Et D1-7b-3 A41 Me Me n-Pr D1-7b-3 A41
c-Pr Et Et D1-7b-3 H c-Pr Men n-Pr D1-7b-3 H
c-Pr Et Et D1-7b-3 A39 c-Pr Men n-Pr D1-7b-3 A39
c-Pr Et Et D1-7b-3 A40 c-Pr Men n-Pr D1-7b-3 A40
c-Pr Et Et D1-7b-3 A41 c-Pr Men n-Pr D1-7b-3 A41
c-Bu Et Et D1-7b-3 H c-Bu Men n-Pr D1-7b-3 H
c-Bu Et Et D1-7b-3 A39 c-Bu Me n-Pr D1-7b-3 A39
c-Bu Et Et D1-7b-3 A40 c-Bu Me n-Pr D1-7b-3 A40
c-Bu Et Et D1-7b-3 A41 c-Bu Me n-Pr D1-7b-3 A41
c-Pen Et Et D1-7b-3 H c-Pen Men n-Pr D1-7b-3 H
c-Pen Et Et D1-7b-3 A39 c-Pen Men n-Pr D1-7b-3 A39
c-Pen Et Et D1-7b-3 A40 c-Pen Men n-Pr D1-7b-3 A40
c-Pen Et Et D1-7b-3 A41 c-Pen Men n-Pr D1-7b-3 A41
c-Hex Et Et D1-7b-3 H c-Hex Me n-Pr D1-7b-3 H
c-Hex Et Et D1-7b-3 A39 c-Hex Me n-Pr D1-7b-3 A39
c-Hex Et Et D1-7b-3 A40 c-Hex Me n-Pr D1-7b-3 A40
c-Hex Et Et D1-7b-3 A41 c-Hex Me n-Pr D1-7b-3 A41
Me Et Et D1-7b-4 H Me Me n-Pr D1-7b-4 H
Me Et Et D1-7b-4 A39 Me Me n-Pr D1-7b-4 A39
Me Et Et D1-7b-4 A40 Me Me n-Pr D1-7b-4 A40
Me Et Et D1-7b-4 A41 Me Me n-Pr D1-7b-4 A41
c-Pr Et Et D1-7b-4 H c-Pr Men n-Pr D1-7b-4 H
c-Pr Et Et D1-7b-4 A39 c-Pr Men n-Pr D1-7b-4 A39
c-Pr Et Et D1-7b-4 A40 c-Pr Men n-Pr D1-7b-4 A40
c-Pr Et Et D1-7b-4 A41 c-Pr Men n-Pr D1-7b-4 A41
c-Bu Et Et D1-7b-4 H c-Bu Men n-Pr D1-7b-4 H
c-Bu Et Et D1-7b-4 A39 c-Bu Me n-Pr D1-7b-4 A39
c-Bu Et Et D1-7b-4 A40 c-Bu Me n-Pr D1-7b-4 A40
c-Bu Et Et D1-7b-4 A41 c-Bu Me n-Pr D1-7b-4 A41
c-Pen Et Et D1-7b-4 H c-Pen Men n-Pr D1-7b-4 H
c-Pen Et Et D1-7b-4 A39 c-Pen Men n-Pr D1-7b-4 A39
c-Pen Et Et D1-7b-4 A40 c-Pen Men n-Pr D1-7b-4 A40
c-Pen Et Et D1-7b-4 A41 c-Pen Men n-Pr D1-7b-4 A41
c-Hex Et Et D1-7b-4 H c-Hex Me n-Pr D1-7b-4 H
c-Hex Et Et D1-7b-4 A39 c-Hex Me n-Pr D1-7b-4 A39
c-Hex Et Et D1-7b-4 A40 c-Hex Me n-Pr D1-7b-4 A40
c-Hex Et Et D1-7b-4 A41 c-Hex Me n-Pr D1-7b-4 A41
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et D1-10a H Me Me n-Pr D1-10a H
Me Et Et D1-11a H Me Me n-Pr D1-11a H
Me Et Et D1-11b-1 H Me Me n-Pr D1-11b-1 H
Me Et Et D1-11b-2 H Me Me n-Pr D1-11b-2 H
Me Et Et D1-11b-3 H Me Me n-Pr D1-11b-3 H
Me Et Et D1-11b-4 H Me Me n-Pr D1-11b-4 H
Me Et Et D1-22a H Me Me n-Pr D1-22a H
Me Et Et D1-22b-1 H Me Me n-Pr D1-22b-1 H
Me Et Et D1-22b-2 H Me Me n-Pr D1-22b-2 H
Me Et Et D1-22b-3 H Me Me n-Pr D1-22b-3 H
Me Et Et D1-22b-4 H Me Me n-Pr D1-22b-4 H
Me Et Et D1-32a H Me Me n-Pr D1-32a H
Me Et Et D1-32b-1 H Me Me n-Pr D1-32b-1 H
Me Et Et D1-32b-2 H Me Me n-Pr D1-32b-2 H
Me Et Et D1-32b-3 H Me Me n-Pr D1-32b-3 H
Me Et Et D1-32b-4 H Me Me n-Pr D1-32b-4 H
Me Et Et D1-32b-5 H Me Me n-Pr D1-32b-5 H
Me Et Et D1-33a H Me Me n-Pr D1-33a H
Me Et Et D1-33b-1 H Me Me n-Pr D1-33b-1 H
Me Et Et D1-33b-2 H Me Me n-Pr D1-33b-2 H
Me Et Et D1-33b-3 H Me Me n-Pr D1-33b-3 H
Me Et Et D1-33b-4 H Me Me n-Pr D1-33b-4 H
Me Et Et D1-34a H Me Me n-Pr D1-34a H
Me Et Et D1-37a H Me Me n-Pr D1-37a H
Me Et Et D1-37b-1 H Me Me n-Pr D1-37b-1 H
Me Et Et C≡CH H Me Me n-Pr C≡CH H
Me Et Et C≡CH A39 Me Me n-Pr C≡CH A39
Me Et Et C≡CH A40 Me Me n-Pr C≡CH A40
Me Et Et C≡CH A41 Me Me n-Pr C≡CH A41
c-Pr Et Et C≡CH H c-Pr Me n-Pr C≡CH H
c-Pr Et Et C≡CH A39 c-Pr Me n-Pr C≡CH A39
c-Pr Et Et C≡CH A40 c-Pr Me n-Pr C≡CH A40
c-Pr Et Et C≡CH A41 c-Pr Me n-Pr C≡CH A41
c-Bu Et Et C≡CH H c-Bu Me n-Pr C≡CH H
c-Bu Et Et C≡CH A39 c-Bu Me n-Pr C≡CH A39
c-Bu Et Et C≡CH A40 c-Bu Me n-Pr C≡CH A40
c-Bu Et Et C≡CH A41 c-Bu Me n-Pr C≡CH A41
c-Pen Et Et C≡CH H c-Pen Me n-Pr C≡CH H
c-Pen Et Et C≡CH A39 c-Pen Me n-Pr C≡CH A39
c-Pen Et Et C≡CH A40 c-Pen Me n-Pr C≡CH A40
c-Pen Et Et C≡CH A41 c-Pen Me n-Pr C≡CH A41
c-Hex Et Et C≡CH H c-Hex Me n-Pr C≡CH H
c-Hex Et Et C≡CH A39 c-Hex Me n-Pr C≡CH A39
c-Hex Et Et C≡CH A40 c-Hex Me n-Pr C≡CH A40
c-Hex Et Et C≡CH A41 c-Hex Me n-Pr C≡CH A41
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et C≡CBu-c H Me Me n-Pr C≡CBu-c H
Me Et Et C≡CBu-c A39 Me Me n-Pr C≡CBu-c A39
Me Et Et C≡CBu-c A40 Me Me n-Pr C≡CBu-c A40
Me Et Et C≡CBu-c A41 Me Me n-Pr C≡CBu-c A41
c-Pr Et Et C≡CBu-c H c-Pr Men n-Pr C≡CBu-c H
c-Pr Et Et C≡CBu-c A39 c-Pr Men n-Pr C≡CBu-c A39
c-Pr Et Et C≡CBu-c A40 c-Pr Men n-Pr C≡CBu-c A40
c-Pr Et Et C≡CBu-c A41 c-Pr Men n-Pr C≡CBu-c A41
c-Bu Et Et C≡CBu-c H c-Bu Me n-Pr C≡CBu-c H
c-Bu Et Et C≡CBu-c A39 c-Bu Me n-Pr C≡CBu-c A39
c-Bu Et Et C≡CBu-c A40 c-Bu Me n-Pr C≡CBu-c A40
c-Bu Et Et C≡CBu-c A41 c-Bu Me n-Pr C≡CBu-c A41
c-Pen Et Et C≡CBu-c H c-Pen Men n-Pr C≡CBu-c H
c-Pen Et Et C≡CBu-c A39 c-Pen Men n-Pr C≡CBu-c A39
c-Pen Et Et C≡CBu-c A40 c-Pen Men n-Pr C≡CBu-c A40
c-Pen Et Et C≡CBu-c A41 c-Pen Men n-Pr C≡CBu-c A41
c-Hex Et Et C≡CBu-c H c-Hex Me n-Pr C≡CBu-c H
c-Hex Et Et C≡CBu-c A39 c-Hex Me n-Pr C≡CBu-c A39
c-Hex Et Et C≡CBu-c A40 c-Hex Me n-Pr C≡CBu-c A40
c-Hex Et Et C≡CBu-c A41 c-Hex Me n-Pr C≡CBu-c A41
Me Et Et C≡CPen-c H Me Me n-Pr C≡CPen-c H
Me Et Et C≡CPen-c A39 Me Me n-Pr C≡CPen-c A39
Me Et Et C≡CPen-c A40 Me Me n-Pr C≡CPen-c A40
Me Et Et C≡CPen-c A41 Me Me n-Pr C≡CPen-c A41
c-Pr Et Et C≡CPen-c H c-Pr Men n-Pr C≡CPen-c H
c-Pr Et Et C≡CPen-c A39 c-Pr Men n-Pr C≡CPen-c A39
c-Pr Et Et C≡CPen-c A40 c-Pr Men n-Pr C≡CPen-c A40
c-Pr Et Et C≡CPen-c A41 c-Pr Men n-Pr C≡CPen-c A41
c-Bu Et Et C≡CPen-c H c-Bu Me n-Pr C≡CPen-c H
c-Bu Et Et C≡CPen-c A39 c-Bu Me n-Pr C≡CPen-c A39
c-Bu Et Et C≡CPen-c A40 c-Bu Me n-Pr C≡CPen-c A40
c-Bu Et Et C≡CPen-c A41 c-Bu Me n-Pr C≡CPen-c A41
c-Pen Et Et C≡CPen-c H c-Pen Men n-Pr C≡CPen-c H
c-Pen Et Et C≡CPen-c A39 c-Pen Men n-Pr C≡CPen-c A39
c-Pen Et Et C≡CPen-c A40 c-Pen Men n-Pr C≡CPen-c A40
c-Pen Et Et C≡CPen-c A41 c-Pen Men n-Pr C≡CPen-c A41
c-Hex Et Et C≡CPen-c H c-Hex Me n-Pr C≡CPen-c H
c-Hex Et Et C≡CPen-c A39 c-Hex Me n-Pr C≡CPen-c A39
c-Hex Et Et C≡CPen-c A40 c-Hex Me n-Pr C≡CPen-c A40
c-Hex Et Et C≡CPen-c A41 c-Hex Me n-Pr C≡CPen-c A41
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ―――――――――――――――――
Me Et Et C≡CHex-c H Me Me n-Pr C≡CHex-c H
Me Et Et C≡CHex-c A39 Me Me n-Pr C≡CHex-c A39
Me Et Et C≡CHex-c A40 Me Me n-Pr C≡CHex-c A40
Me Et Et C≡CHex-c A41 Me Me n-Pr C≡CHex-c A41
c-Pr Et Et C≡CHex-c H c-Pr Men n-Pr C≡CHex-c H
c-Pr Et Et C≡CHex-c A39 c-Pr Me n-Pr C≡CHex-c A39
c-Pr Et Et C≡CHex-c A40 c-Pr Me n-Pr C≡CHex-c A40
c-Pr Et Et C≡CHex-c A41 c-Pr Me n-Pr C≡CHex-c A41
c-Bu Et Et C≡CHex-c H c-Bu Me n-Pr C≡CHex-c H
c-Bu Et Et C≡CHex-c A39 c-Bu Me n-Pr C≡CHex-c A39
c-Bu Et Et C≡CHex-c A40 c-Bu Me n-Pr C≡CHex-c A40
c-Bu Et Et C≡CHex-c A41 c-Bu Me n-Pr C≡CHex-c A41
c-Pen Et Et C≡CHex-c H c-Pen Me n-Pr C≡CHex-c H
c-Pen Et Et C≡CHex-c A39 c-Pen Me n-Pr C≡CHex-c A39
c-Pen Et Et C≡CHex-c A40 c-Pen Me n-Pr C≡CHex-c A40
c-Pen Et Et C≡CHex-c A41 c-Pen Me n-Pr C≡CHex-c A41
c-Hex Et Et C≡CHex-c H c-Hex Me n-Pr C≡CHex-c H
c-Hex Et Et C≡CHex-c A39 c-Hex Me n-Pr C≡CHex-c A39
c-Hex Et Et C≡CHex-c A40 c-Hex Me n-Pr C≡CHex-c A40
c-Hex Et Et C≡CHex-c A41 c-Hex Me n-Pr C≡CHex-c A41
―――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ―――――――――――――――――
Me OMe Me Me H Me OMe Et Me H
Me OMe Me Me A13 Me OMe Et Me A13
Me OMe Me Me A14 Me OMe Et Me A14
Me OMe Me Me A16 Me OMe Et Me A16
Me OMe Me Me A35 Me OMe Et Me A35
Me OMe Me Me A38 Me OMe Et Me A38
Me OMe Me Me A39 Me OMe Et Me A39
Me OMe Me Me A40 Me OMe Et Me A40
Me OMe Me Me A41 Me OMe Et Me A41
Me OMe Me Me A73 Me OMe Et Me A73
Me OMe Me Me A74 Me OMe Et Me A74
Me OMe Me Me A75 Me OMe Et Me A75
Me OMe Me Me A81 Me OMe Et Me A81
Me OMe Me Me A82 Me OMe Et Me A82
Me OMe Me Me A83 Me OMe Et Me A83
Me OMe Me Me A84 Me OMe Et Me A84
Me OMe Me Me A85 Me OMe Et Me A85
Me OMe Me Me A86 Me OMe Et Me A86
Me OMe Me Me A87 Me OMe Et Me A87
Me OMe Me Me A91 Me OMe Et Me A91
Me OMe Me Me A92 Me OMe Et Me A92
Me OMe Me Me A93 Me OMe Et Me A93
Me OMe Me Me A94 Me OMe Et Me A94
Me OMe Me Me A95 Me OMe Et Me A95
Me OMe Me Me A97 Me OMe Et Me A97
Et OMe Me Me H Et OMe Et Me H
Et OMe Me Me A13 Et OMe Et Me A13
Et OMe Me Me A14 Et OMe Et Me A14
Et OMe Me Me A16 Et OMe Et Me A16
Et OMe Me Me A35 Et OMe Et Me A35
Et OMe Me Me A38 Et OMe Et Me A38
Et OMe Me Me A39 Et OMe Et Me A39
Et OMe Me Me A40 Et OMe Et Me A40
Et OMe Me Me A41 Et OMe Et Me A41
Et OMe Me Me A73 Et OMe Et Me A73
Et OMe Me Me A74 Et OMe Et Me A74
Et OMe Me Me A75 Et OMe Et Me A75
Et OMe Me Me A81 Et OMe Et Me A81
Et OMe Me Me A82 Et OMe Et Me A82
Et OMe Me Me A83 Et OMe Et Me A83
Et OMe Me Me A84 Et OMe Et Me A84
Et OMe Me Me A85 Et OMe Et Me A85
Et OMe Me Me A86 Et OMe Et Me A86
Et OMe Me Me A87 Et OMe Et Me A87
Et OMe Me Me A91 Et OMe Et Me A91
Et OMe Me Me A92 Et OMe Et Me A92
Et OMe Me Me A93 Et OMe Et Me A93
Et OMe Me Me A94 Et OMe Et Me A94
Et OMe Me Me A95 Et OMe Et Me A95
Et OMe Me Me A97 Et OMe Et Me A97
――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ―――――――――――――――――
Me OMe n-Pr Me H Me OEt Me Me H
Me OMe n-Pr Me A13 Me OEt Me Me A13
Me OMe n-Pr Me A14 Me OEt Me Me A14
Me OMe n-Pr Me A16 Me OEt Me Me A16
Me OMe n-Pr Me A35 Me OEt Me Me A35
Me OMe n-Pr Me A38 Me OEt Me Me A38
Me OMe n-Pr Me A39 Me OEt Me Me A39
Me OMe n-Pr Me A40 Me OEt Me Me A40
Me OMe n-Pr Me A41 Me OEt Me Me A41
Me OMe n-Pr Me A73 Me OEt Me Me A73
Me OMe n-Pr Me A74 Me OEt Me Me A74
Me OMe n-Pr Me A75 Me OEt Me Me A75
Me OMe n-Pr Me A81 Me OEt Me Me A81
Me OMe n-Pr Me A82 Me OEt Me Me A82
Me OMe n-Pr Me A83 Me OEt Me Me A83
Me OMe n-Pr Me A84 Me OEt Me Me A84
Me OMe n-Pr Me A85 Me OEt Me Me A85
Me OMe n-Pr Me A86 Me OEt Me Me A86
Me OMe n-Pr Me A87 Me OEt Me Me A87
Me OMe n-Pr Me A91 Me OEt Me Me A91
Me OMe n-Pr Me A92 Me OEt Me Me A92
Me OMe n-Pr Me A93 Me OEt Me Me A93
Me OMe n-Pr Me A94 Me OEt Me Me A94
Me OMe n-Pr Me A95 Me OEt Me Me A95
Me OMe n-Pr Me A97 Me OEt Me Me A97
Et OMe n-Pr Me H Et OEt Me Me H
Et OMe n-Pr Me A13 Et OEt Me Me A13
Et OMe n-Pr Me A14 Et OEt Me Me A14
Et OMe n-Pr Me A16 Et OEt Me Me A16
Et OMe n-Pr Me A35 Et OEt Me Me A35
Et OMe n-Pr Me A38 Et OEt Me Me A38
Et OMe n-Pr Me A39 Et OEt Me Me A39
Et OMe n-Pr Me A40 Et OEt Me Me A40
Et OMe n-Pr Me A41 Et OEt Me Me A41
Et OMe n-Pr Me A73 Et OEt Me Me A73
Et OMe n-Pr Me A74 Et OEt Me Me A74
Et OMe n-Pr Me A75 Et OEt Me Me A75
Et OMe n-Pr Me A81 Et OEt Me Me A81
Et OMe n-Pr Me A82 Et OEt Me Me A82
Et OMe n-Pr Me A83 Et OEt Me Me A83
Et OMe n-Pr Me A84 Et OEt Me Me A84
Et OMe n-Pr Me A85 Et OEt Me Me A85
Et OMe n-Pr Me A86 Et OEt Me Me A86
Et OMe n-Pr Me A87 Et OEt Me Me A87
Et OMe n-Pr Me A91 Et OEt Me Me A91
Et OMe n-Pr Me A92 Et OEt Me Me A92
Et OMe n-Pr Me A93 Et OEt Me Me A93
Et OMe n-Pr Me A94 Et OEt Me Me A94
Et OMe n-Pr Me A95 Et OEt Me Me A95
Et OMe n-Pr Me A97 Et OEt Me Me A97
――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
――――――――――――――― ―――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――― ―――――――――――――――――
Me OEt Et Me H Me OMe Me Et H
Me OEt Et Me A13 Me OMe Me Et A13
Me OEt Et Me A14 Me OMe Me Et A14
Me OEt Et Me A16 Me OMe Me Et A16
Me OEt Et Me A35 Me OMe Me Et A35
Me OEt Et Me A38 Me OMe Me Et A38
Me OEt Et Me A39 Me OMe Me Et A39
Me OEt Et Me A40 Me OMe Me Et A40
Me OEt Et Me A41 Me OMe Me Et A41
Me OEt Et Me A73 Me OMe Me Et A73
Me OEt Et Me A74 Me OMe Me Et A74
Me OEt Et Me A75 Me OMe Me Et A75
Me OEt Et Me A81 Me OMe Me Et A81
Me OEt Et Me A82 Me OMe Me Et A82
Me OEt Et Me A83 Me OMe Me Et A83
Me OEt Et Me A84 Me OMe Me Et A84
Me OEt Et Me A85 Me OMe Me Et A85
Me OEt Et Me A86 Me OMe Me Et A86
Me OEt Et Me A87 Me OMe Me Et A87
Me OEt Et Me A91 Me OMe Me Et A91
Me OEt Et Me A92 Me OMe Me Et A92
Me OEt Et Me A93 Me OMe Me Et A93
Me OEt Et Me A94 Me OMe Me Et A94
Me OEt Et Me A95 Me OMe Me Et A95
Me OEt Et Me A97 Me OMe Me Et A97
Et OEt Et Me H Et OMe Me Et H
Et OEt Et Me A13 Et OMe Me Et A13
Et OEt Et Me A14 Et OMe Me Et A14
Et OEt Et Me A16 Et OMe Me Et A16
Et OEt Et Me A35 Et OMe Me Et A35
Et OEt Et Me A38 Et OMe Me Et A38
Et OEt Et Me A39 Et OMe Me Et A39
Et OEt Et Me A40 Et OMe Me Et A40
Et OEt Et Me A41 Et OMe Me Et A41
Et OEt Et Me A73 Et OMe Me Et A73
Et OEt Et Me A74 Et OMe Me Et A74
Et OEt Et Me A75 Et OMe Me Et A75
Et OEt Et Me A81 Et OMe Me Et A81
Et OEt Et Me A82 Et OMe Me Et A82
Et OEt Et Me A83 Et OMe Me Et A83
Et OEt Et Me A84 Et OMe Me Et A84
Et OEt Et Me A85 Et OMe Me Et A85
Et OEt Et Me A86 Et OMe Me Et A86
Et OEt Et Me A87 Et OMe Me Et A87
Et OEt Et Me A91 Et OMe Me Et A91
Et OEt Et Me A92 Et OMe Me Et A92
Et OEt Et Me A93 Et OMe Me Et A93
Et OEt Et Me A94 Et OMe Me Et A94
Et OEt Et Me A95 Et OMe Me Et A95
Et OEt Et Me A97 Et OMe Me Et A97
――――――――――――――― ―――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ――――――――――――――――
Me Me Me OCH ₂ CF _Three H Me Me Et OCH ₂ CF _Three H
Me Et Et OCH ₂ CF _Three H Me Me n-Pr OCH ₂ CF _Three H
Me Me Me OCF _Three H Me Me Et OCF _Three H
Me Et Et OCF _Three H Me Me n-Pr OCF _Three H
Me Me Me OCF ₂ HH Me Me Et OCF ₂ HH
Me Et Et OCF ₂ HH Me Me n-Pr OCF ₂ HH
Me Me Me OCF ₂ Cl H Me Me Et OCF ₂ Cl H
Me Et Et OCF ₂ Cl H Me Me n-Pr OCF ₂ Cl H
Me Me Me OCF ₂ Br H Me Me Et OCF ₂ Br H
Me Et Et OCF ₂ Br H Me Me n-Pr OCF ₂ Br H
Me Me Me O (D1-32a) H Me Et Et O (D1-32a) H
Me Me Me O (D1-32b-2) H Me Et Et O (D1-32b-2) H
Me Me Me O (D1-32b-3) H Me Et Et O (D1-32b-3) H
Me Me Me O (D1-32b-4) H Me Et Et O (D1-32b-4) H
Me Me Me O (D1-32b-5) H Me Et Et O (D1-32b-5) H
Me Me Me O (D1-33a) H Me Me Me O (D1-33a) H
Me Me Me O (D1-33b-1) H Me Me Me O (D1-33b-1) H
Me Me Me O (D1-33b-2) H Me Me Me O (D1-33b-2) H
Me Me Me O (D1-33b-3) H Me Me Me O (D1-33b-3) H
Me Me Me O (D1-33b-4) H Me Me Me O (D1-33b-4) H
Me OMe Me Ph H Me OMe Et Ph H
Me OMe Me Ph A39 Me OMe Et Ph A39
Me OMe Me Ph A40 Me OMe Et Ph A40
Me OMe Me Ph A41 Me OMe Et Ph A41
Me OMe Me D1-108b-4 H Me OMe Et D1-108b-4 H
Me OMe Me D1-108b-4 A39 Me OMe Et D1-108b-4 A39
Me OMe Me D1-108b-4 A40 Me OMe Et D1-108b-4 A40
Me OMe Me D1-108b-4 A41 Me OMe Et D1-108b-4 A41
Me OMe Me D1-108b-4 A74 Me OMe Et D1-108b-4 A74
Me OMe Me D1-108b-4 A75 Me OMe Et D1-108b-4 A75
Me OMe Me D1-108b-4 A84 Me OMe Et D1-108b-4 A84
Me OMe Me D1-108b-4 A85 Me OMe Et D1-108b-4 A85
Me OMe Me D1-108b-4 A86 Me OMe Et D1-108b-4 A86
Me OMe Me D1-108b-4 A87 Me OMe Et D1-108b-4 A87
Me OMe Me D1-108b-8 H Me OMe Et D1-108b-8 H
Me OMe Me D1-108b-8 A39 Me OMe Et D1-108b-8 A39
Me OMe Me D1-108b-8 A40 Me OMe Et D1-108b-8 A40
Me OMe Me D1-108b-8 A41 Me OMe Et D1-108b-8 A41
Me OMe Me D1-108b-8 A74 Me OMe Et D1-108b-8 A74
Me OMe Me D1-108b-8 A75 Me OMe Et D1-108b-8 A75
Me OMe Me D1-108b-8 A84 Me OMe Et D1-108b-8 A84
Me OMe Me D1-108b-8 A85 Me OMe Et D1-108b-8 A85
Me OMe Me D1-108b-8 A86 Me OMe Et D1-108b-8 A86
Me OMe Me D1-108b-8 A87 Me OMe Et D1-108b-8 A87
Me OMe Me Br H Me OMe Et Br H
Me SMe Me Me H Me SMe Et Me H
c-Pr OMe Me Me H c-Pr OMe Et Me H
c-Pr OMe Me Me A12 c-Pr OMe Et Me A12
c-Pr OMe Me Me A13 c-Pr OMe Et Me A13
c-Pr OMe Me Me A74 c-Pr OMe Et Me A74
c-Bu OMe Me Me H c-Bu OMe Et Me H
c-Bu OMe Me Me A12 c-Bu OMe Et Me A12
c-Bu OMe Me Me A13 c-Bu OMe Et Me A13
c-Bu OMe Me Me A74 c-Bu OMe Et Me A74
c-Pen OMe Me Me H c-Pen OMe Et Me H
c-Pen OMe Me Me A12 c-Pen OMe Et Me A12
c-Pen OMe Me Me A13 c-Pen OMe Et Me A13
c-Pen OMe Me Me A74 c-Pen OMe Et Me A74
c-Hex OMe Me Me H c-Hex OMe Et Me H
―――――――――――――――― ――――――――――――――――
Table 1 (continued) [Table 1] (continued)
―――――――――――――――― ――――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
―――――――――――――――― ――――――――――――――――
Me OMe n-Pr Ph H Me OEt Me Ph H
Me OMe n-Pr Ph A39 Me OEt Me Ph A39
Me OMe n-Pr Ph A40 Me OEt Me Ph A40
Me OMe n-Pr Ph A41 Me OEt Me Ph A41
Me OMe n-Pr D1-108b-4 H Me OEt Me D1-108b-4 H
Me OMe n-Pr D1-108b-4 A39 Me OEt Me D1-108b-4 A39
Me OMe n-Pr D1-108b-4 A40 Me OEt Me D1-108b-4 A40
Me OMe n-Pr D1-108b-4 A41 Me OEt Me D1-108b-4 A41
Me OMe n-Pr D1-108b-4 A74 Me OEt Me D1-108b-4 A74
Me OMe n-Pr D1-108b-4 A75 Me OEt Me D1-108b-4 A75
Me OMe n-Pr D1-108b-4 A84 Me OEt Me D1-108b-4 A84
Me OMe n-Pr D1-108b-4 A85 Me OEt Me D1-108b-4 A85
Me OMe n-Pr D1-108b-4 A86 Me OEt Me D1-108b-4 A86
Me OMe n-Pr D1-108b-4 A87 Me OEt Me D1-108b-4 A87
Me OMe n-Pr D1-108b-8 H Me OEt Me D1-108b-8 H
Me OMe n-Pr D1-108b-8 A39 Me OEt Me D1-108b-8 A39
Me OMe n-Pr D1-108b-8 A40 Me OEt Me D1-108b-8 A40
Me OMe n-Pr D1-108b-8 A41 Me OEt Me D1-108b-8 A41
Me OMe n-Pr D1-108b-8 A74 Me OEt Me D1-108b-8 A74
Me OMe n-Pr D1-108b-8 A75 Me OEt Me D1-108b-8 A75
Me OMe n-Pr D1-108b-8 A84 Me OEt Me D1-108b-8 A84
Me OMe n-Pr D1-108b-8 A85 Me OEt Me D1-108b-8 A85
Me OMe n-Pr D1-108b-8 A86 Me OEt Me D1-108b-8 A86
Me OMe n-Pr D1-108b-8 A87 Me OEt Me D1-108b-8 A87
―――――――――――――――― ――――――――――――――――
Table 1 (continued) [Table 1] (continued)
――――――――――――――――― ――――――――――――――
R ⁶ Z ^a Z ^e Z ^c AR ⁶ Z ^a Z ^e Z ^c A
――――――――――――――――― ――――――――――――――
Me OMe n-Pr Br H Me OEt Me Br H
Me SMe n-Pr Me H Me SEt Me Me H
c-Pr OMe n-Pr Me H c-Pr OEt Me Me H
c-Pr OMe n-Pr Me A12 c-Pr OEt Me Me A12
c-Pr OMe n-Pr Me A13 c-Pr OEt Me Me A13
c-Pr OMe n-Pr Me A74 c-Pr OEt Me Me A74
c-Bu OMe n-Pr Me H c-Bu OEt Me Me H
c-Bu OMe n-Pr Me A12 c-Bu OEt Me Me A12
c-Bu OMe n-Pr Me A13 c-Bu OEt Me Me A13
c-Bu OMe n-Pr Me A74 c-Bu OEt Me Me A74
c-Pen OMe n-Pr Me H c-Pr OEt Me Me H
c-Pen OMe n-Pr Me A12 c-Pen OEt Me Me A12
c-Pen OMe n-Pr Me A13 c-Pen OEt Me Me A13
c-Pen OMe n-Pr Me A74 c-Pen OEt Me Me A74
c-Hex OMe n-Pr Me H c-Hex OEt Me Me H
Me OEt Et Ph H c-Hex OMe Me Me A12
Me OEt Et Ph A39 c-Hex OMe Me Me A13
Me OEt Et Ph A40 c-Hex OMe Me Me A74
Me OEt Et Ph A41 Me OMe Me Me H
Me OEt Et D1-108b-4 H Me OMe Br Me H
Me OEt Et D1-108b-4 A39 Me Me Me Me H
Me OEt Et D1-108b-4 A40 c-Hex OMe n-Pr Me A12
Me OEt Et D1-108b-4 A41 c-Hex OMe n-Pr Me A13
Me OEt Et D1-108b-4 A74 c-Hex OMe n-Pr Me A74
Me OEt Et D1-108b-4 A75 Me OMe n-Pr Me H
Me OEt Et D1-108b-4 A84 Me OMe n-Pr Me H
Me OEt Et D1-108b-4 A85 Me Me n-Pr Me H
Me OEt Et D1-108b-4 A86 Me OMe F Br H
Me OEt Et D1-108b-4 A87 Me OMe F Ph H
Me OEt Et D1-108b-8 H Me OMe F Me H
Me OEt Et D1-108b-8 A39 c-Hex OMe Et Me A12
Me OEt Et D1-108b-8 A40 c-Hex OMe Et Me A13
Me OEt Et D1-108b-8 A41 c-Hex OMe Et Me A74
Me OEt Et D1-108b-8 A74 Me OMe Et Me H
Me OEt Et D1-108b-8 A75 Me OMe Et Me H
Me OEt Et D1-108b-8 A84 Me Me Et Me H
Me OEt Et D1-108b-8 A85 c-Hex OEt Me Me A12
Me OEt Et D1-108b-8 A86 c-Hex OEt Me Me A13
Me OEt Et D1-108b-8 A87 c-Hex OEt Me Me A74
Me OEt Et Br H Me OMe Et Me H
Me SEt Et Me H Me OMe Et Me H
c-Pr OEt Et Me H Me Et Et Me H
c-Pr OEt Et Me A12 Me OEt F Br H
c-Pr OEt Et Me A13 Me OEt F Ph H
c-Pr OEt Et Me A74 Me OEt F Me H
c-Bu OEt Et Me H c-Pen OEt Et Me A13
c-Bu OEt Et Me A12 c-Pen OEt Et Me A74
c-Bu OEt Et Me A13 c-Hex OEt Et Me H
c-Bu OEt Et Me A74 c-Hex OEt Et Me A12
c-Pen OEt Et Me H c-Hex OEt Et Me A13
c-Pen OEt Et Me A12 c-Hex OEt Et Me A74
Me OMe F Br H Me OEt F Br H
Me OMe F Ph H Me OEt F Ph H
Me OMe F Me H Me OEt F Me H
Me OMe OMe Br H Me OH Me Br H
Et OMe OMe Br H Et OH Me Br H
c-Pr OMe OMe Br H c-Pr OH Me Br H
Me OEt Me C≡CMe H Me OEt Me Br Et
Et OEt Me C≡CMe H Et OEt Me Br Et
c-Pr OEt Me C≡CMe H c-Pr OEt Me Br Et
Et OEt Me D1-108b-4 H Et OEt Me Br H
c-Pr OEt Me D1-108b-4 H c-Pr OEt Me Br H
Et OMe Me Br H Et OEt Me Ph H
c-Pr OMe Me Br H c-Pr OEt Me Ph H
Et OEt Me D1-108b-8 H ――――――――――――――
c-Pr OEt Me D1-108b-8 H
―――――――――――――――――
The compound of the present invention can be used as a herbicide for paddy fields in any treatment method of soil treatment and foliage treatment under flooded water. As paddy field weeds, for example, weeping family (Potamogetonaceatiaceae) represented by Potamogeton distinctus, etc. ) Weed, Azegaya (Leptochloa chinensis), Echinochloa crus-galli, Echinochloa oryzicola, Ashiaki (Homalocenchrus japonocus) Gramineae weed, Kurowai (Eleocharis kuroguwai), Firefly (Sirpus juncoides), Shizuus sarius (Cirpus sarius) Cyperaceae weeds, Spirodella polyrhiza, Lemna paucicostata, and other species such as Lemnaceae weeds, and Dendrobinous weeds (Murdannia coesae). Nochoria korsakowii) and scallops (Pontederiaceae) and other species such as the mosquito family (Elatine triamdra) Lythaceae weeds represented by, Lythigia epilobioides weeds, Oenotheraceae weeds, Dopatrium junceum, Graonilop olia, Azena (Lindernia pyxidaria), American Azena (Lindernia dubia), and the like, Agrocynoceae (Rosaceae), rosaneceae (Aesyomenine indica), etc. Examples thereof include Compositae weeds represented by Bidens tripartita.

また、本発明化合物は、畑地及び果樹園用の除草剤として、土壌処理、土壌混和処理及び茎葉処理のいずれの処理方法においても使用できる。畑地雑草としては、例えば、イヌホウズキ（Ｓｏｌａｎｕｍ ｎｉｇｒｕｍ）及びチョウセンアサガオ（Ｄａｔｕｒａ ｓｔｒａｍｏｎｉｕｍ）等に代表されるナス科（Ｓｏｌａｎａｃｅａｅ）雑草、アメリカフウロ(Ｇｒａｎｉｕｍ ｃａｒｏｌｉｎｉａｎｕｍ)等に代表されるフウロソウ科（Ｇｅｒａｎｉａｃｅａｅ）雑草、イチビ（Ａｂｕｔｉｌｏｎ ｔｈｅｏｐｈｒａｓｔｉ）及びアメリカキンゴジカ（Ｓｉｄａ ｓｐｉｎｏｓａ）等に代表されるアオイ科（Ｍａｌｖａｃｅａｅ）雑草、マルバアサガオ（Ｉｐｏｍｏｅａ ｐｕｒｐｕｒｅａ）等のアサガオ類（Ｉｐｏｍｏｅａ ｓｐｐｓ．）及びヒルガオ類（Ｃａｌｙｓｔｅｇｉａ ｓｐｐｓ．）等に代表されるヒルガオ科（Ｃｏｎｖｏｌｖｕｌａｃｅａｅ）雑草、イヌビユ（Ａｍａｒａｎｔｈｕｓ ｌｉｖｉｄｕｓ）及びアオビユ（Ａｍａｒａｎｔｈｕｓ ｒｅｔｒｏｆｌｅｘｕｓ）等に代表されるヒユ科（Ａｍａｒａｎｔｈａｃｅａｅ）雑草、オナモミ（ｘａｎｔｈｉｕｍ ｐｅｎｓｙｌｖａｎｉｃｕｍ）、ブタクサ（Ａｍｂｒｏｓｉａ ａｒｔｅｍｉｓｉａｅｆｏｌｉａ）、ヒマワリ（Ｈｅｌｉａｎｔｈｕｓ ａｎｎｕｕｓ）、ハキダメギク（Ｇａｌｉｎｓｏｇａ ｃｉｌｉａｔａ）、セイヨウトゲアザミ（Ｃｉｒｓｉｕｍ ａｒｖｅｎｓｅ）、ノボロギク（Ｓｅｎｅｃｉｏ ｖｕｌｇａｒｉｓ）及びヒメジョン（Ｅｒｉｇｅｒｏｎ ａｎｎｕｓ）等に代表されるキク科（Ｃｏｍｐｏｓｉｔａｅ）雑草、イヌガラシ（Ｒｏｒｉｐｐａ ｉｎｄｉｃａ）、ノハラガラシ（Ｓｉｎａｐｉｓ ａｒｖｅｎｓｉｓ）及びナズナ（Ｃａｐｓｅｌｌａ Ｂｕｒｓａｐａｓｔｏｒｉｓ）等に代表されるアブラナ科（Ｃｒｕｃｉｆｅｒａｅ）雑草、イヌタデ（Ｐｏｌｙｇｏｎｕｍ Ｂｌｕｍｅｉ）及びソバカズラ（Ｐｏｌｙｇｏｎｕｍ ｃｏｎｖｏｌｖｕｌｕｓ）等に代表されるタデ科（Ｐｏｌｙｇｏｎａｃｅａｅ）雑草、スベリヒユ（Ｐｏｒｔｕｌａｃａ ｏｌｅｒａｃｅａ）等に代表されるスベリヒユ科（Ｐｏｒｔｕｌａｃａｃｅａｅ）雑草、シロザ（Ｃｈｅｎｏｐｏｄｉｕｍ ａｌｂｕｍ）、コアカザ（Ｃｈｅｎｏｐｏｄｉｕｍ ｆｉｃｉｆｏｌｉｕｍ）及びホウキギ（Ｋｏｃｈｉａ ｓｃｏｐａｒｉａ）等に代表されるアカザ科（Ｃｈｅｎｏｐｏｄｉａｃｅａｅ）雑草、ハコベ（Ｓｔｅｌｌａｒｉａ ｍｅｄｉａ）等に代表されるナデシコ科（Ｃａｒｙｏｐｈｙｌｌａｃｅａｅ）雑草、オオイヌノフグリ（Ｖｅｒｏｎｉｃａ ｐｅｒｓｉｃａ）等に代表されるゴマノハグサ科（Ｓｃｒｏｐｈｕｌａｒｉａｃｅａｅ）雑草、ツユクサ（Ｃｏｍｍｅｌｉｎａ ｃｏｍｍｕｎｉｓ）等に代表されるツユクサ科（Ｃｏｍｍｅｌｉｎａｃｅａｅ）雑草、ホトケノザ（Ｌａｍｉｕｍ ａｍｐｌｅｘｉｃａｕｌｅ）及びヒメオドリコソウ（Ｌａｍｉｕｍ ｐｕｒｐｕｒｅｕｍ）等に代表されるシソ科（Ｌａｂｉａｔａｅ）雑草、コニシキソウ（Ｅｕｐｈｏｒｂｉａ ｓｕｐｉｎａ）及びオオニシキソウ（Ｅｕｐｈｏｒｂｉａ ｍａｃｕｌａｔａ）等に代表されるトウダイグサ科（Ｅｕｐｈｏｒｂｉａｃｅａｅ）雑草、ヤエムグラ（Ｇａｌｉｕｍ ｓｐｕｒｉｕｍ）及びアカネ（Ｒｕｂｉａ ａｋａｎｅ）等に代表されるアカネ科（Ｒｕｂｉａｃｅａｅ）雑草、スミレ（Ｖｉｏｌａ ｍａｎｄｓｈｕｒｉｃａ）等に代表されるスミレ科（Ｖｉｏｌａｃｅａｅ）雑草並びにアメリカツノクサネム（Ｓｅｓｂａｎｉａ ｅｘａｌｔａｔａ）及びエビスグサ（Ｃａｓｓｉａ ｏｂｔｕｓｉｆｏｌｉａ）等に代表されるマメ科（Ｌｅｇｕｍｉｎｏｓａｅ）雑草、カタバミ（Ｏｘｓａｌｉｓ ｃｏｕｒｎｉｃｕｌａｔａ）に代表されるカタバミ科（Ｏｘｓａｌｄａｓｅａｅ）等の広葉雑草（Ｂｒｏａｄ−ｌｅａｖｅｄ ｗｅｅｄｓ）。野生ソルガム（Ｓｏｒｇｈａｍ ｂｉｃｏｌｏｒ）、オオクサキビ（Ｐａｎｉｃｕｍ ｄｉｃｈｏｔｏｍｉｆｌｏｒｕｍ）、ジョンソングラス（Ｓｏｒｇｈｕｍ ｈａｌｅｐｅｎｓｅ）、イヌビエ（Ｅｃｈｉｎｏｃｈｌｏａ ｃｒｕｓ−ｇａｌｌｉ ｖａｒ． ｃｒｕｓ−ｇａｌｌｉ）、ヒメイヌビエ（Ｅｃｈｉｎｏｃｈｌｏａ ｃｒｕｓ−ｇａｌｌｉ ｖａｒ． ｐｒａｔｉｃｏｌａ）、栽培ビエ（Ｅｃｈｉｎｏｃｈｌｏａ ｕｔｉｌｉｓ）、メヒシバ（Ｄｉｇｉｔａｒｉａ ｃｉｌｉａｒｉｓ）、カラスムギ（Ａｖｅｎａ ｆａｔｕａ）、ブラックグラス（Ａｌｏｐｅｃｕｒｕｓ ｍｙｏｓｕｒｏｉｄｅｓ）、オヒシバ（Ｅｌｅｕｓｉｎｅ ｉｎｄｉｃａ）、エノコログサ（Ｓｅｔａｒｉａ ｖｉｒｉｄｉｓ）、アキノエノコログサ（Ｓｅｔａｒｉａ ｆａｂｅｒｉ）及びスズメノテッポウ（Ａｌｏｐｅｃｕｒｕｓ ａｅｇｕａｌｉｓ）等に代表されるイネ科雑草（Ｇｒａｍｉｎａｃｅｏｕｓ ｗｅｅｄｓ）並びにハマスゲ（Ｃｙｐｅｒｕｓ ｒｏｔｕｎｄｕｓ，Ｃｙｐｅｒｕｓ ｅｓｃｕｌｅｎｔｕｓ）等に代表されるカヤツリグサ科雑草（Ｃｙｐｅｒａｃｅｏｕｓ ｗｅｅｄｓ）等が挙げられる。   Further, the compound of the present invention can be used as a herbicide for field and orchard in any treatment method of soil treatment, soil admixture treatment and foliage treatment. Examples of upland field weeds include Solanumae weeds represented by Solanum nigrum and Datura stramonium, Sauranaceae weeds represented by Grunum carolinianum, Aiaceae cereals (Gaeumaceae) (Abutilon theophrasti) and malvaaceae weeds represented by Sida spinosa, etc., Ipomoea purpurea, etc. and Ipomoea spps. Convolvulaceae weed, Amaran (Amaran) hus lividus) and slender amaranth (Amaranthus retroflexus) Amaranthaceae represented by such (Amaranthaceae) weeds, cocklebur (xanthium pensylvanicum), ragweed (Ambrosia artemisiaefolia), sunflower (Helianthus annuus), galinsoga quadriradiata (Galinsoga ciliata), western thorns thistle (Cirsium arvense, Sorgio vulgaris, Erigeron annus, and other species of Compositae weeds, Roppa indica, Shirapis arvensis Ca a bursaceae weed, represented by a Bursapastoris, etc. Weeds represented by, for example, Polygonaceae weeds represented by, for example, Polygonum bulvoluis, Polygonum convolvulus, olulaceae, etc. (Portulacaceae) weeds, white-spotted (Chenopodium album), red-breasted (Chenopodium falifolium), weeds (Chenopodiacee) weeds represented by weeds (Cenopodiaceae) The Weeds such as Sphaphulariaceae represented by Veronica persica, Ceminaurae weeds represented by Commelina communis, etc., and Lamium urumiles. Euphorbiaceae (Euphorbiaceae) and other species such as Euphorbiaceae (Galium spurium), representatives of Euphorbiaceula (Euporbiaacea) Rubyaceae Weeds such as Violaceae weeds represented by weeds and violets (Viola mandhurica) and leguminous weeds represented by Sesbania exaltata and Cassia obtusifolia, etc. Broad-leaved weeds such as the representative Oxsaldasee. Wild sorghum (Sorgham dichotomiflorum), Johnson grass (Sorghum halo chilli), Echinochloa cru-galli var. Crus-galli , Barnyard grass (Digitaria ciliaris), oats (Avena fatua), blackgrass (Alopecurus myosuroides), barnyard grass (Eleusine indica), Enocologia (Sateria viridis), Akinosae faberi) and water foxtail (Alopecurus aegualis) gramineous weeds (Graminaceous weeds typified etc.) and Cyperus (Cyperus rotundus, Cyperus esculentus) Cyperaceae weeds (Cyperaceous weeds typified like).

また、本発明化合物は、水田、畑地及び果樹園等の農園芸分野以外に芝地、運動場、空地、道路脇、及び線路端等非農耕地において、土壌処理、土壌混和処理及び茎葉処理のいずれの処理方法においても使用できる。その雑草としては、畑地及び果樹園用雑草で述べたものに加えて、スズメノカタビラ（Ｐｏａ ａｎｎｕａ）、セイヨウタンポポ（Ｔａｒａｘａｃｕｍｏｆｆｉｃｉｎａｌｅ）、オオアレチノギク（Ｃｏｎｙｚａ ｓｕｍａｔｒｅｎｓｉｓ）、タネツケバナ（Ｃａｒｄａｍｉｎｅ ｆｌｅｘｕｏｓａ）、シロツメクサ（Ｔｒｉｆｏｌｉｕｍｒｅｐｅｎｓ）、チドメグサ（Ｈｙｄｒｏｃｏｔｙｌｅ ｓｉｂｔｈｏｒｐｉｏｉｄｅｓ）、オオバコ（Ｐｌａｎｔａｇｏ ａｓｉａｔｉｃａ）、ヒメクグ（Ｃｙｐｅｒｕｓ ｂｒｅｖｉｆｏｌｉｕｓ、Ｋｙｌｌｉｎｇａｂｒｅｖｉｆｏｌｉａ）、スギナ（Ｅｑｕｉｓｅｔｕｍ ａｒｖｅｎｓｅ）等が挙げられる。   Further, the compound of the present invention can be used for soil treatment, soil admixture treatment, and foliage treatment in non-agricultural lands such as turf, playground, open space, roadside, and track end in addition to the fields of agriculture and horticulture such as paddy fields, upland fields and orchards It can also be used in the processing method. As the weeds, in addition to those described in upland and orchard weeds, Poa annua, Taraxacumofficinale, Conyzaolumetres, Cardamine minx, sibthorpioides), plantain asiatica, Cyperus brevifolia, Kyllingbrevifolia, Equisetum arvense and the like.

本発明化合物は必要に応じて製剤または散布時に他種の除草剤、各種殺虫剤、殺菌剤、植物生長調節剤又は共力剤等と混合施用しても良い。   The compound of the present invention may be mixed and applied with other types of herbicides, various insecticides, fungicides, plant growth regulators, synergists, and the like, as necessary, during formulation or spraying.

特に、他の除草剤と混合施用することにより、施用薬量の減少による低コスト化、混合薬剤の相乗作用による殺草スペクトラムの拡大や、より高い殺草効果が期待できる。この際、同時に複数の公知除草剤との組み合わせも可能である。   In particular, when mixed with other herbicides, cost reduction due to a decrease in the amount of applied medicine, expansion of the herbicidal spectrum due to the synergistic action of the mixed drugs, and higher herbicidal effects can be expected. At this time, a combination with a plurality of known herbicides is also possible.

本発明化合物と混合使用されるのに好ましい除草剤としては、例えば、アセトクロール（ａｃｅｔｏｃｈｌｏｒ／一般名）、アシフルオルフェン（ａｃｉｆｌｕｏｒｆｅｎ／一般名）、アクロニフェン（ａｃｌｏｎｉｆｅｎ／一般名）、アラクロール（ａｌａｃｈｌｏｒ／一般名）、アロキシジム（ａｌｌｏｘｙｄｉｍ／一般名）、アロキシジムナトリウム（ａｌｌｏｘｙｄｉｍ―ｓｏｄｉｕｍ／一般名）、アメトリン（ａｍｅｔｒｙｎ／一般名）、アミカルバソン（ａｍｉｃａｒｂａｚｏｎｅ／一般名）、アミドスルフロン（ａｍｉｄｏｓｕｌｆｕｒｏｎ／一般名）、アミノシクロピラクロール（ａｍｉｎｏｃｙｃｌｏｐｉｒａｃｈｌｏｒ／一般名)、アミノシクロピラクロールの塩及びエステル（ａｍｉｎｏｃｙｃｌｏｐｉｒａｃｈｌｏｒ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ)、アミノピラリド（ａｍｉｎｏｐｙｒａｌｉｄ／一般名）、アミノピラリドの塩及びエステル（ａｍｉｎｏｐｙｒａｌｉｄ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、アミプロホスメチル（ａｍｉｐｒｏｐｈｏｓ―ｍｅｔｈｙｌ／一般名）、アミトロール（ａｍｉｔｒｏｌ／一般名）、アニロホス（ａｎｉｌｏｆｏｓ／一般名）、アシュラム（ａｓｕｌａｍ／一般名）、アトラジン（ａｔｒａｚｉｎｅ／一般名）、アザフェニジン（ａｚａｆｅｎｉｄｉｎ／一般名）、アジムスルフロン（ａｚｉｍｓｕｌｆｕｒｏｎ／一般名）、ベフルブタミド（ｂｅｆｌｕｂｕｔａｍｉｄ／一般名）、ベナゾリンエチル（ｂｅｎａｚｏｌｉｎ−ｅｔｈｙｌ／一般名）、ベンカルバゾン（ｂｅｎｃａｒｂａｚｏｎｅ／一般名）、ベンフルラリン（ｂｅｎｆｌｕｒａｌｉｎ、ｂｅｎｅｆｉｎ／一般名）、ベンフレセート（ｂｅｎｆｕｒｅｓａｔｅ／一般名）、ベンスルフロンメチル（ｂｅｎｓｕｌｆｕｒｏｎ−ｍｅｔｈｙｌ／一般名）、ベンスリド（ｂｅｎｓｕｌｉｄｅ／一般名）、ベンタゾン（ｂｅｎｔａｚｏｎｅ／一般名）、ベンタゾンナトリウム（ｂｅｎｔａｚｏｎｅ―ｓｏｄｉｕｍ／一般名）、ベンタゾンの塩（ｂｅｎｔａｚｏｎｅ―ｓａｌｔｓ）、ベンチオカーブ（ｂｅｎｔｈｉｏｃａｒｂ／一般名）、ベンズフェンジゾン（ｂｅｎｚｆｅｎｄｉｚｏｎｅ／一般名）、ベンゾビシクロン（ｂｅｎｚｏｂｉｃｙｃｌｏｎ／一般名）、ベンゾフェナップ（ｂｅｎｚｏｆｅｎａｐ／一般名）、ビアラホス（ｂｉａｌａｐｈｏｓ／一般名）、ビアラホスナトリウム（ｂｉａｌａｐｈｏｓ―ｓｏｄｉｕｍ／一般名）、ビシクロピロン（ｂｉｃｙｃｌｏｐｙｒｏｎｅ／一般名）、ビフェノックス（ｂｉｆｅｎｏｘ／一般名）、ビスピリバック（ｂｉｓｐｙｒｉｂａｃ／一般名）、ビスピリバックナトリウム（ｂｉｓｐｙｒｉｂａｃ―ｓｏｄｉｕｍ／一般名）、ブロマシル（ｂｒｏｍａｃｉｌ／一般名）、ブロモブチド（ｂｒｏｍｏｂｕｔｉｄｅ／一般名）、ブロモフェノキシム（ｂｒｏｍｏｆｅｎｏｘｉｍ／一般名）、ブロモキシニル（ｂｒｏｍｏｘｙｎｉｌ／一般名）、ブロモキシニルの塩及びエステル（ｂｒｏｍｏｘｙｎｉｌ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、ブタクロール（ｂｕｔａｃｈｌｏｒ／一般名）、ブタフェナシル（ｂｕｔａｆｅｎａｃｉｌ／一般名）、ブタミホス（ｂｕｔａｍｉｆｏｓ／一般名）、ブテナクロール（ｂｕｔｅｎａｃｈｌｏｒ／一般名）、ブトラリン（ｂｕｔｒａｌｉｎ／一般名）、ブトロキシジム（ｂｕｔｒｏｘｙｄｉｍ／一般名）、ブチレート（ｂｕｔｙｌａｔｅ／一般名）、カフェンストロール（ｃａｆｅｎｓｔｒｏｌｅ／一般名）、カルベタミド（ｃａｒｂｅｔａｍｉｄｅ／一般名）、カルフェントラゾンエチル（ｃａｒｆｅｎｔｒａｚｏｎｅ−ｅｔｈｙｌ）、クロメトキシフェン（ｃｈｌｏｍｅｔｈｏｘｙｆｅｎ／一般名）、クロメトキシニル（ｃｈｌｏｍｅｔｈｏｘｙｎｉｌ／一般名）、クロランベン（ｃｈｌｏｒａｍｂｅｎ／一般名）、クロランベンの塩及びエステル（ｃｈｌｏｒａｍｂｅｎ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、クロランスラムメチル（ｃｈｌｏｒａｎｓｕｌａｍ―ｍｅｔｈｙｌ／一般名）、クロルフルレノールメチル（ｃｈｌｏｒｆｌｕｒｅｎｏｌ―ｍｅｔｈｙｌ／一般名）、クロリダゾン（ｃｈｌｏｒｉｄａｚｏｎ／一般名）、クロリムロンエチル（ｃｈｌｏｒｉｍｕｒｏｎ―ｅｔｈｙｌ／一般名）、クロロブロムロン（ｃｈｌｏｒｏｂｒｏｍｕｒｏｎ／一般名）、クロロトルロン（ｃｈｌｏｒｏｔｏｌｕｒｏｎ／一般名）、クロロクスロン（ｃｈｌｏｒｏｘｕｒｏｎ／一般名）、クロルフタリム（ｃｈｌｏｒｐｈｔａｌｉｍ／一般名）、クロルプロファム（ｃｈｌｏｒｐｒｏｐｈａｍ／一般名）、クロロＩＰＣ（ｃｈｌｏｒｐｒｏｐｈａｍ／一般名）、クロルスルフロン（ｃｈｌｏｒｓｕｌｆｕｒｏｎ／一般名）、クロルタルジメチル（ｃｈｌｏｒｔｈａｌ−ｄｉｍｅｔｈｙｌ／一般名）、クロルチアミド（ｃｈｌｏｒｔｈｉａｍｉｄ／一般名）、シニドンエチル（ｃｉｎｉｄｏｎ−ｅｔｈｙｌ／一般名）、シンメスリン（ｃｉｎｍｅｔｈｙｌｉｎ／一般名）、シノスルフロン（ｃｉｎｏｓｕｌｆｕｒｏｎ／一般名）、クレトジム（ｃｌｅｔｈｏｄｉｍ／一般名）、クロジナホップ（ｃｌｏｄｉｎａｆｏｐ／一般名）、クロジナホッププロパルギル（ｃｌｏｄｉｎａｆｏｐ―ｐｒｏｐａｒｇｙｌ／一般名）、クロマゾン（ｃｌｏｍａｚｏｎｅ／一般名）、クロメプロップ（ｃｌｏｍｅｐｒｏｐ／一般名）、クロピラリド（ｃｌｏｐｙｒａｌｉｄ／一般名）、クロピラリドの塩及びエステル（ｃｌｏｐｙｒａｌｉｄ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、ＣＮＰ（一般名）、クミルロン（ｃｕｍｙｌｕｒｏｎ／一般名）、シアナジン（ｃｙａｎａｚｉｎ／一般名）、シクロエート（ｃｙｃｌｏａｔｅ／一般名）、シクロピリモレート（ｃｙｃｌｏｐｙｒｉｍｏｒａｔｅ／一般名、ＳＷ−０６５／試験名)、シクロスルファムロン（ｃｙｃｌｏｓｕｌｆａｍｕｒｏｎ／一般名）、シクロキシジム（ｃｙｃｌｏｘｙｄｉｍ／一般名）、シハロホップブチル（ｃｙｈａｌｏｆｏｐ−ｂｕｔｙｌ／一般名）、ＤＡＨ−５００（試験名）、ダラポン（ｄａｌａｐｏｎ／一般名）、ダゾメット（ｄａｚｏｍｅｔ／一般名）、デスメディファム（ｄｅｓｍｅｄｉｐｈａｍ／一般名）、デスメトリン（ｄｅｓｍｅｔｒｙｎ／一般名）、ダイカンバ（ｄｉｃａｍｂａ／一般名）、ダイカンバの塩及びエステル（ｄｉｃａｍｂａ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、ジクロベニル（ｄｉｃｈｌｏｂｅｎｉｌ／一般名）、ジクロホップ（ｄｉｃｌｏｆｏｐ／一般名）、ジクロホップメチル（ｄｉｃｌｏｆｏｐ−ｍｅｔｈｙｌ／一般名）、ジクロルプロップ（ｄｉｃｈｌｏｒｐｒｏｐ／一般名）、ジクロルプロップの塩及びエステル（ｄｉｃｈｌｏｒｐｒｏｐ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、Ｐジクロルプロップ（ｄｉｃｈｌｏｒｐｒｏｐ―Ｐ／一般名）、Ｐジクロルプロップの塩及びエステル（ｄｉｃｈｌｏｒｐｒｏｐ―Ｐ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、ジクロスラム（ｄｉｃｌｏｓｕｌａｍ／一般名）、ジフェンゾコート（ｄｉｆｅｎｚｏｑｕａｔ／一般名）、ジフルフェニカン（ｄｉｆｌｕｆｅｎｉｃａｎ／一般名）、ジフルフェンゾピル（ｄｉｆｌｕｆｅｎｚｏｐｙｒ／一般名）、ジフルフェンゾピルナトリウム（ｄｉｆｌｕｆｅｎｚｏｐｙｒ―ｓｏｄｉｕｍ／一般名）、ジメピペレート（ｄｉｍｅｐｉｐｅｒａｔｅ／一般名）、ジメタメトリン（ｄｉｍｅｔｈａｍｅｔｒｙｎ／一般名）、ジメタクロール（ｄｉｍｅｔｈａｃｈｌｏｒ／一般名）、ジメテナミド（ｄｉｍｅｔｈｅｎａｍｉｄ／一般名）、Ｐジメテナミド（ｄｉｍｅｔｈｅｎａｍｉｄ―ｐ／一般名）、ジメシピン（ｄｉｍｅｔｈｉｐｉｎ／一般名）、ジニトロアミン（ｄｉｎｉｔｒａｍｉｎｅ／一般名）、ジノセブ（ｄｉｎｏｓｅｂ／一般名）、ジノテルブ（ｄｉｎｏｔｅｒｂ／一般名）、ＤＮＯＣ／一般名、ジフェナミド（ｄｉｐｈｅｎａｍｉｄ／一般名）、ジクワット（ｄｉｑｕｑｔ／一般名）、ジチオピル（ｄｉｔｈｉｏｐｙｌ／一般名）、ジウロン（ｄｉｕｒｏｎ／一般名）、ＤＳＭＡ／一般名、ダイムロン（ｄｙｍｒｏｎ／一般名）、エンドタール（ｅｎｄｏｔｈａｌ／一般名）、ＥＰＴＣ／一般名、エスプロカルブ（ｅｓｐｒｏｃａｒｂ／一般名）、エタルフルラリン（ｅｔｈａｌｆｌｕｒａｌｉｎ／一般名）、エタメトスルフロンメチル（ｅｔｈａｍｅｔｓｕｌｆｕｒｏｎ―ｍｅｔｈｙｌ／一般名）、エトフメセート（ｅｔｈｏｆｕｍｅｓａｔｅ／一般名）、エトベンザニド（ｅｔｏｂｅｎｚａｎｉｄ／一般名）、エトキシスルフロン（ｅｔｈｏｘｙｓｕｌｆｕｒｏｎ／一般名）、フラザスルフロン（ｆｌａｚａｓｕｌｆｕｒｏｎ／一般名）、フェノキサプロップ（ｆｅｎｏｘａｐｒｏｐ／一般名）、フェノキサプロップエチル（ｆｅｎｏｘａｐｒｏｐ−ｅｔｈｙｌ／一般名）、フェノキサスルホン（ｆｅｎｏｘａｓｕｌｆｏｎｅ／一般名）、フェンキノトリオン（ｆｅｎｑｕｉｏｎｏｔｒｉｏｎ／一般名）、フェントラザミド（ｆｅｎｔｒａｚａｍｉｄｅ／一般名）、フラムプロップ（ｆｌａｍｐｒｏｐ／一般名）、フラザスルフロン（ｆｌａｚａｓｕｌｆｕｒｏｎ／一般名）、フロラスラム（ｆｌｏｒａｓｕｌａｍ／一般名）、フルアジホップ（ｆｌｕａｚｉｆｏｐ／一般名）、フルアジホップブチル（ｆｌｕａｚｉｆｏｐ−ｂｕｔｙｌ／一般名）、フルアゾレート（ｆｌｕａｚｏｌａｔｅ／一般名）、フルカルバゾンナトリウム（ｆｌｕｃａｒｂａｚｏｎｅ−ｓｏｄｉｕｍ／一般名）、フルセトスルフロン(ｆｌｕｃｅｔｏｓｕｌｆｕｒｏｎ／一般名)、フルクロラリン（ｆｌｕｃｌｏｒａｌｉｎ／一般名）、フルフェナセット（ｆｌｕｆｅｎａｃｅｔ／一般名）、フルフェンピルエチル（ｆｌｕｆｅｎｐｙｌ−ｅｔｈｙｌ／一般名）、フルメツラム（ｆｌｕｍｅｔｓｕｌａｍ／一般名）、フルミクロラックペンチル（ｆｌｕｍｉｃｌｏｒａｃ−ｐｅｎｔｙｌ／一般名）、フルミオキサジン（ｆｌｕｍｉｏｘａｚｉｎ／一般名）、フルオメツロン（ｆｌｕｏｍｅｔｕｒｏｎ／一般名）、フルオログリコフェンエチル（ｆｌｕｏｒｏｇｌｙｃｏｆｅｎ−ｅｔｈｙｌ／一般名）、フルピルスルフロン（ｆｌｕｐｙｒｓｕｌｆｕｒｏｎ／一般名）、フルポキサム（ｆｌｕｐｏｘａｍ／一般名）、フルレノール（ｆｌｕｒｅｎｏｌ／一般名）、フルリドン（ｆｌｕｒｉｄｏｎｅ／一般名）、フルロクロリドン（ｆｌｕｒｏｃｈｌｏｒｉｄｏｎｅ／一般名）、フルロキシピル（ｆｌｕｒｏｘｙｐｙｒ／一般名）、フルロキシピルのエステル（ｆｌｕｒｏｘｙｐｙｒ―ｅｓｔｅｒｓ）、フルプリミドール（ｆｌｕｒｐｒｉｍｉｄｏｌ／一般名）、フルタモン（ｆｌｕｒｔａｍｏｎｅ／一般名）、フルチアセットメチル（ｆｌｕｔｈｉａｃｅｔ−ｍｅｔｈｙｌ／一般名）、フォメサフェン（ｆｏｍｅｓａｆｅｎ／一般名）、フォラムスルフロン（ｆｏｒａｍｓｕｌｆｕｒｏｎ／一般名）、フォサミン（ｆｏｓａｍｉｎｅ／一般名）、グルホシネート（ｇｌｕｆｏｓｉｎａｔｅ／一般名）、グルホシネートアンモニウム（ｇｌｕｆｏｓｉｎａｔｅ−ａｍｍｏｎｉｕｍ／一般名）、グリホサート（ｇｌｙｐｈｏｓａｔｅ／一般名）、グリホサートアンモニウム（ｇｌｙｐｈｏｓａｔｅ−ａｍｍｏｎｉｕｍ／一般名）、グリホサートイソプロピルアミン（ｇｌｙｐｈｏｓａｔｅ−ｉｓｏ−ｐｒｏｐｙｌａｍｍｏｎｉｕｍ／一般名）、グリホサートカリウム（ｇｌｙｐｈｏｓａｔｅ−ｐｏｔａｓｓｉｕｍ／一般名）、グリホサートナトリウム（ｇｌｙｐｈｏｓａｔｅ−ｓｏｄｉｕｍ／一般名）、グリホサートトリメシウム（ｇｌｙｐｈｏｓａｔｅ−ｔｒｉｍｅｓｉｕｍ／一般名）、ハロウキシフェン（ｈａｌａｕｘｉｆｅｎ／一般名）、ハロウキシフェンの塩及びエステル（ｈａｌａｕｘｉｆｅｎ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、ハロサフェン（ｈａｌｏｓａｆｅｎ／一般名）、ハロスルフロン（ｈａｌｏｓｕｌｆｕｒｏｎ／一般名）、ハロスルフロンメチル（ｈａｌｏｓｕｌｆｕｒｏｎ−ｍｅｔｈｙｌ／一般名）、ハロキシホップ（ｈａｌｏｘｙｆｏｐ／一般名）、ハロキシホップメチル（ｈａｌｏｘｙｆｏｐ−ｍｅｔｈｙｌ／一般名）、ヘキサジノン（ｈｅｘａｚｉｎｏｎｅ／一般名）、イマザメタベンズメチル（ｉｍａｚａｍｅｔｈａｂｅｎｚ―ｍｅｔｈｙｌ／一般名）、イマザモックス（ｉｍａｚａｍｏｘ／一般名）、イマザピク（ｉｍａｚａｐｉｃ／一
般名）、イマザピル（ｉｍａｚａｐｙｒ／一般名）、イマゼタピル（ｉｍａｚｅｔｈａｐｙｒ／一般名）、イマザキン（ｉｍａｚａｑｕｉｎ／一般名）、イマゾスルフロン（ｉｍａｚｏｓｕｌｆｕｒｏｎ／一般名）、インダノファン（ｉｎｄａｎｏｆａｎ／一般名）、インダジフラム（ｉｎｄａｚｉｆｌａｍ／一般名）、ヨードスルフロンメチルナトリウム（ｉｏｄｏｓｕｌｆｕｒｏｎ−ｍｅｔｈｙｌ−ｓｏｄｉｕｍ／一般名）、アイオキシニル（ｉｏｘｙｎｉｌ ｏｃｔａｎｏａｔｅ／一般名）、アイオキシニルの塩及びエステル（ｉｏｘｙｎｉｌ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、イプフェンカルバゾン（ｉｐｆｅｎｃａｒｂａｚｏｎｅ／一般名）、イソプロチュロン（ｉｓｏｐｒｏｔｕｒｏｎ／一般名）、イソウロン（ｉｓｏｕｒｏｎ／一般名）、イソキサベン（ｉｓｏｘａｂｅｎ／一般名）、イソキサフルトール（ｉｓｏｘａｆｌｕｔｏｌｅ／一般名）、カルブチレート（ｋａｒｂｕｔｉｌａｔｅ／一般名）、ラクトフェン（ｌａｃｔｏｆｅｎ／一般名）、レナシル（ｌｅｎａｃｉｌ／一般名）、リニュロン（ｌｉｎｕｒｏｎ／一般名）、マレイン酸ヒドラジド（ｍａｌｅｉｃ ｈｙｄｒａｚｉｄｅ／一般名）、ＭＣＰＡ（一般名）、ＭＣＰＡの塩及びエステル（ＭＣＰＡ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、ＭＣＰＢ（一般名）、ＭＣＰＢの塩及びエステル（ＭＣＰＢ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、メコプロップ（ｍｅｃｏｐｒｏｐ、ＭＣＰＰ／一般名）、メコプロップの塩及びエステル（ｍｅｃｏｐｒｏｐ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、Ｐメコプロップ（ｍｅｃｏｐｒｏｐ―Ｐ、ＭＣＰＰ―Ｐ／一般名）、Ｐメコプロップの塩及びエステル（ｍｅｃｏｐｒｏｐ―Ｐ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、メフェナセット（ｍｅｆｅｎａｃｅｔ／一般名）、メフルイジド（ｍｅｆｌｕｉｄｉｄｅ／一般名）、メソスルフロンメチル（ｍｅｓｏｓｕｌｆｕｒｏｎ―ｍｅｔｈｙｌ／一般名）、メソトリオン（ｍｅｓｏｔｒｉｏｎｅ／一般名）、メタム（ｍｅｔａｍ／一般名）、メタミホップ（ｍｅｔａｍｉｆｏｐ／一般名）、メタミトロン（ｍｅｔａｍｉｔｒｏｎ／一般名）、メタザクロール（ｍｅｔａｚａｃｈｌｏｒ／一般名）、メタベンズチアズロン（ｍｅｔｈａｂｅｎｚｔｈｉａｚｕｒｏｎ／一般名）、メタゾスルフロン（ｍｅｔａｚｏｓｕｌｆｕｒｏｎ／一般名）、メチオゾリン（ｍｅｔｈｉｏｚｏｌｉｎ／一般名）、メチルアジド（ｍｅｔｈｙｌ ａｚｉｄｅ／一般名）、臭化メチル（ｍｅｔｈｙｌ ｂｒｏｍｉｄｅ／一般名）、メチルダイムロン（ｍｅｔｈｙｌ ｄｙｍｒｏｎ／一般名）、ヨウ化メチル（ｍｅｔｈｙｌ ｉｏｄｉｄｅ／一般名）、メトベンズロン（ｍｅｔｏｂｅｎｚｕｒｏｎ／一般名）、メトラクロール（ｍｅｔｏｌａｃｈｌｏｒ／一般名）、Ｓメトラクロール（ｍｅｔｏｌａｃｈｌｏｒ―Ｓ／一般名）、メトスラム（ｍｅｔｏｓｕｌａｍ／一般名）、メトリブジン（ｍｅｔｒｉｂｕｚｉｎ／一般名）、メトスルフロンメチル（ｍｅｔｓｕｌｆｕｒｏｎ−ｍｅｔｈｙｌ／一般名）、メトクスロン（ｍｅｔｏｘｕｒｏｎ／一般名）、モリネート（ｍｏｌｉｎａｔｅ／一般名）、モノリニュロン（ｍｏｎｏｌｉｎｕｒｏｎ／一般名）、モノスルフロン（ｍｏｎｏｓｕｌｆｕｒｏｎ／一般名）、モノスルフロンメチル（ｍｏｎｏｓｕｌｆｕｒｏｎ−ｍｅｔｈｙｌ／一般名）、ＭＳＭＡ／一般名、ナプロアニリド（ｎａｐｒｏａｎｉｌｉｄｅ／一般名）、ナプロパミド（ｎａｐｒｏｐａｍｉｄｅ／一般名）、ナプタラム（ｎａｐｔａｌａｍ／一般名）、ナプタラムナトリウム（ｎａｐｔａｌａｍ―ｓｏｄｉｕｍ／一般名）、ネブロン（ｎｅｂｕｒｏｎ／一般名）、ニコスルフロン（ｎｉｃｏｓｕｌｆｕｒｏｎ／一般名）、ノルフルラゾン（ｎｏｒｆｌｕｒａｚｏｎ／一般名）、ＯＫ−７０１（試験名）、オレイン酸（ｏｌｅｉｃ ａｃｉｄ／一般名）、オルベンカーブ（ｏｒｂｅｎｃａｒｂ／一般名）、オルソスルファムロン（ｏｒｔｈｏｓｕｌｆａｍｕｒｏｎ／一般名）、オリザリン（ｏｒｙｚａｌｉｎ／一般名）、オキサジアルギル（ｏｘａｄｉａｒｇｙｌ／一般名）、オキサジアゾン（ｏｘａｄｉａｚｏｎ／一般名）、オキサスルフロン（ｏｘａｓｕｌｆｕｒｏｎ／一般名）、オキサジクロメホン（ｏｘａｚｉｃｌｏｍｅｆｏｎｅ／一般名）、オキシフルオルフェン（ｏｘｙｆｌｕｏｒｆｅｎ／一般名）、パラコート（ｐａｒａｑｕａｔ／一般名）、ペラルゴン酸（ｐｅｌａｒｇｏｎｉｃａｃｉｄ／一般名）、ペンディメタリン（ｐｅｎｄｉｍｅｔｈａｌｉｎ／一般名）、ペノキススラム（ｐｅｎｏｘｓｕｌａｍ／一般名）、ペンタノクロール（ｐｅｎｔａｎｏｃｈｌｏｒ／一般名）、ペントキサゾン（ｐｅｎｔｏｘａｚｏｎｅ／一般名）、ペトキサミド（ｐｅｔｈｏｘａｍｉｄ／一般名）、フェンメディファムエチル（ｐｈｅｎｍｅｄｉｐｈａｍ―ｅｔｈｙｌ／一般名）、ピクロラム（ｐｉｃｌｏｒａｍ／一般名）、ピクロラムの塩及びエステル（ｐｉｃｌｏｒａｍ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、ピコリナフェン（ｐｉｃｏｌｉｎａｆｅｎ／一般名）、ピノキサデン（ｐｉｎｏｘａｄｅｎ／一般名）、ピペロフォス（ｐｉｐｅｒｏｐｈｏｓ／一般名）、プレチラクロール（ｐｒｅｔｉｌａｃｈｌｏｒ／一般名）、プリミスルフロンメチル（ｐｒｉｍｉｓｕｌｆｕｒｏｎ―ｍｅｔｈｙｌ／一般名）、プロジアミン（ｐｒｏｄｉａｍｉｎｅ／一般名）、プロフルアゾール（ｐｒｏｆｌｕａｚｏｌ／一般名）、プロフォキシジム（ｐｒｏｆｏｘｙｄｉｍ／一般名）、プロメトン（ｐｒｏｍｅｔｏｎ／一般名）、プロメトリン（ｐｒｏｍｅｔｒｙｎ／一般名）、プロパクロール（ｐｒｏｐａｃｈｌｏｒ／一般名）、プロパニル（ｐｒｏｐａｎｉｌ／一般名）、プロパキザホップ（ｐｒｏｐａｑｕｉｚａｆｏｐ／一般名）、プロパジン（ｐｒｏｐａｚｉｎ／一般名）、プロファム（ｐｒｏｐｈａｍ／一般名）、プロピソクロール（ｐｒｏｐｉｓｏｃｈｌｏｒ／一般名）、プロポキシカルバゾンナトリウム（ｐｒｏｐｏｘｙｃａｒｂａｚｏｎｅ−ｓｏｄｉｕｍ／一般名）、プロピリスルフロン（ｐｒｏｐｙｒｉｓｕｌｆｕｒｏｎ／一般名）、プロピザミド（ｐｒｏｐｙｚａｍｉｄｅ／一般名）、プルスルホカーブ（ｐｒｏｓｕｌｆｏｃａｒｂ／一般名）、プロスルフロン（ｐｒｏｓｕｌｆｕｒｏｎ／一般名）、ピラクロニル（ｐｙｒａｃｌｏｎｉｌ／一般名）、ピラフルフェンエチル（ｐｙｒａｆｌｕｆｅｎ―ｅｔｈｙｌ／一般名）、ピラスルホトール（ｐｙｒａｓｕｌｆｏｔｏｌｅ／一般名）、ピラゾリネート（ｐｙｒａｚｏｌｙｎａｔｅ／一般名）、ピラゾスルフロン（ｐｙｒａｚｏｓｕｌｆｕｒｏｎ／一般名）、ピラゾスルフロンエチル（ｐｙｒａｚｏｓｕｌｆｕｒｏｎ−ｅｔｈｙｌ／一般名）、ピラゾキシフェン（ｐｙｒａｚｏｘｙｆｅｎ／一般名）、ピリベンゾキシム（ｐｙｒｉｂｅｎｚｏｘｉｍ／一般名）、ピリブチカルブ（ｐｙｒｉｂｕｔｉｃａｒｂ／一般名）、ピリダフォル（ｐｙｒｉｄａｆｏｌ／一般名）、ピリデート（ｐｙｒｉｄａｔｅ／一般名）、ピリフタリド（ｐｙｒｉｆｔａｌｉｄ／一般名）、ピリミノバックメチル（ｐｙｒｉｍｉｎｏｂａｃ−ｍｅｔｈｙｌ／一般名）、ピリミスルファン（ｐｙｒｉｍｉｓｕｌｆａｎ／一般名）、ピリチオバックナトリウム（ｐｙｒｉｔｈｉｏｂａｃ―ｓｏｄｉｕｍ／一般名）、ピロキサスルホン（ｐｙｒｏｘａｓｕｌｆｏｎｅ／一般名）、ピロキシスラム（ｐｙｒｏｘｓｕｌａｍ／一般名）、キンクロラック（ｑｕｉｎｃｌｏｒａｃ／一般名）、キンメラック（ｑｕｉｎｍｅｒａｃ／一般名）、キノクラミン（ｑｕｉｎｏｃｌａｍｉｎｅ／一般名）、キザロホップ（ｑｕｉｚａｌｏｆｏｐ／一般名）、キザロホップエチル（ｑｕｉｚａｌｏｆｏｐ−ｅｔｈｙｌ／一般名）、キザロホップテフリル（ｑｕｉｚａｌｏｆｏｐ−ｔｅｆｕｒｙｌ／一般名）、Ｐキザロホップ（ｑｕｉｚａｌｏｆｏｐ―Ｐ／一般名）、Ｐキザロホップエチル（ｑｕｉｚａｌｏｆｏｐ―Ｐ−ｅｔｈｙｌ／一般名）、Ｐキザロホップテフリル（ｑｕｉｚａｌｏｆｏｐ―Ｐ−ｔｅｆｕｒｙｌ／一般名）、リムスルフロン（ｒｉｍｓｕｌｆｕｒｏｎ／一般名）、サフルフェナシル（ｓａｆｌｕｆｅｎａｃｉｌ／一般名）、セトキシジム（ｓｅｔｈｏｘｙｄｉｍ／一般名）、シデュロン（ｓｉｄｕｒｏｎ／一般名）、シマジン（ｓｉｍａｚｉｎｅ／一般名）、シメトリン（ｓｉｍｅｔｒｙｎ／一般名）、ＳＬ−２６１（試験名）、スルコトリオン（ｓｕｌｃｏｔｒｉｏｎｅ／一般名）、スルフェントラゾン（ｓｕｌｆｅｎｔｒａｚｏｎｅ／一般名）、スルフォメツロンメチル（ｓｕｌｆｏｍｅｔｕｒｏｎ―ｍｅｔｈｙｌ／一般名）、スルフォスルフロン（ｓｕｌｆｏｓｕｌｆｕｒｏｎ／一般名）、ＴＣＢＡ（２，３，６−ＴＢＡ／一般名）、ＴＣＢＡの塩及びエステル（２，３，６−ＴＢＡ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、ＴＣＴＰ（ｃｈｌｏｒｔｈａｌ−ｄｉｍｅｔｈｙｌ，ｔｅｔｏｒａｃｈｌｏｒｏｔｈｉｏｐｈｅｎｅ／一般名）、テブタム（ｔｅｂｕｔａｍ／一般名）、テブティウロン（ｔｅｂｕｔｈｉｕｒｏｎ／一般名）、テフリルトリオン（ｔｅｆｕｒｙｌｔｒｉｏｎｅ／一般名）、テンボトリオン（ｔｅｍｂｏｔｒｉｏｎｅ／一般名）、テプラロキシジム（ｔｅｐｒａｌｏｘｙｄｉｍ／一般名）、ターバシル（ｔｅｒｂａｃｉｌ／一般名）、ターブメトン（ｔｅｒｂｕｍｅｔｏｎ／一般名）、ターブチラジン（ｔｅｒｂｕｔｈｙｌａｚｉｎｅ／一般名）、ターブトリン（ｔｅｒｂｕｔｒｙｎ／一般名）、テトラピオン（ｔｅｔｒａｐｉｏｎ／ｆｌｕｐｒｏｐａｎａｔｅ／一般名）、テニルクロール（ｔｈｅｎｙｌｃｈｌｏｒ／一般名）、チアザフルロン（ｔｈｉａｚａｆｌｕｒｏｎ／一般名）、チアゾピル（ｔｈｉａｚｏｐｙｒ／一般名）、チジアジミン（ｔｈｉｄｉａｚｉｍｉｎ／一般名）、チジアズロン（ｔｈｉｄｉａｚｕｒｏｎ／一般名）、チエンカルバゾンメチル（ｔｈｉｅｎｃａｒｂａｚｏｎｅ−ｍｅｔｈｙｌ／一般名）、チフェンスルフロンメチル（ｔｈｉｆｅｎｓｕｌｆｕｒｏｎ−ｍｅｔｈｙｌ／一般名）、トルピラレート（ｔｏｌｐｙｒａｌａｔｅ／一般名）、トプラメゾン（ｔｏｐｒａｍｅｚｏｎ／一般名）、トラルコキシジム（ｔｒａｌｋｏｘｙｄｉｍ／一般名）、トリアファモン（ｔｒｉａｆａｍｏｎｅ／一般名）、トリアレート（ｔｒｉａｌｌａｔｅ／一般名）、トリアスルフロン（ｔｒｉａｓｕｌｆｕｒｏｎ／一般名）、トリアジフラム（ｔｒｉａｚｉｆｌａｍ／一般名）、トリベニュロンメチル（ｔｒｉｂｅｎｕｒｏｎ−ｍｅｔｈｙｌ／一般名）、トリクロピル（ｔｒｉｃｌｏｐｙｒ／一般名）、トリクロピルの塩及びエステル（ｔｒｉｃｌｏｐｙｒ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、トリディファン（ｔｒｉｄｉｐｈａｎｅ／一般名）、トリエタジン（ｔｒｉｅｔａｚｉｎｅ／一般名）、トリフルディモキサジン（ｔｒｉｆｌｕｄｉｍｏｘａｄｉｎ／一般名）、トリフロキシスルフロン（ｔｒｉｆｌｏｘｙｓｕｌｆｕｒｏｎ／一般名）、トリフルラリン（ｔｒｉｆｌｕｒａｌｉｎ／一般名）、トリフルスルフロンメチル（ｔｒｉｆｌｕｓｕｌｆｕｒｏｎ―ｍｅｔｈｙｌ／一般名）、トリトスルフロン（ｔｒｉｔｏｓｕｌｆｕｒｏｎ／一般名）、２，４−ＰＡ（一般名）、２，４−ＰＡの塩及びエステル（２，４−ＰＡ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）、２，４−ＤＢ（一般名）、２，４−ＤＢの塩及びエステル（２，４−ＤＢ―ｓａｌｔｓ ａｎｄ ｅｓｔｅｒｓ）等が挙げられる。これらの成分は単独でまたは２種以上混合して使用することができ、混合する場合の比も自由に選択できる。 Preferred herbicides to be used in combination with the compound of the present invention include, for example, acetochlor (acetochlor / generic name), acifluorfen (acifluorfen / generic name), aclonifen (aclonifen / generic name), alachlor (alachlor / (Generic name), alloxidim (alloxydim / generic name), sodium alloxidim-sodium / generic name, ametrine (generic name), amicarbazone (generic name), amidosulfuron (common name), Aminocyclopyranchlor (generic name), salts and esters of aminocyclopyracryl (aminocyclapirchlor) Salts and esters, aminopyralides (general names), salts and esters of aminopyrides (aminopyrid-salts and esters), amiprophos-methyl (generic names), amitrols (generic names) anilofos / generic name), ashram (asuram / generic name), atrazine (atrazine / generic name), azaphenidin (azafenidin / generic name), azimusulfuron / generic name, beflubutamide (generic name), benazoline / benzolin -Ethyl / generic name), bencarbazone (generic name), Flufluralin (benfulin / generic name), benfrecetate (benfuresate / generic name), bensulfuron methyl (bensulfuron-methyl / generic name), bensulide (bensulide / generic name), bentazone (benzonone / generic name), bentazone sodium (entazone e) -Sodium / general name), bentazone-salts, beniocarb (benthocarb / generic name), benzfendizone (generic name), benzobicyclon (benzobiclon / generic name), benzofenap (benzofen) / Generic name), bialaphos (generic name), bialaphos sodium (bi alaphos-sodium / generic name), bicyclopyrone (bicyclopyrone / generic name), biphenox (bifenox / generic name), bispyribac (bispyribac / generic name), bispilibac sodium (bispyribac-sodium / generic name), bromacil / bromacil (Generic name), bromobutide (generic name), bromophenoxime (generic name), bromoxynil (generic name), salts and esters of bromoxynil (general name) and butachlor (general name) , Butafenacil (generic name), butamifos (general name) ), Butenachlor (butenachlor / generic name), butralin (butralin / generic name), butroxydim (butoxydim / generic name), butyrate (butylate / generic name), fenfentrol (general name), carbetamid (common name) Carfentrazone-ethyl, chloromethoxyphen (Chlomethoxyn / generic name), chloromethoxynyl (generic name), chloramben (chloramben / generic name), chloramben salts and esters (chloramben-salts and esters) Chloranslammethyl (one) Name), chloroflurenol-methyl / generic name, chloridazon (generic name), chlorimuron-ethyl / generic name, chlorobromouron / generic name, chlorotoluron / Generic name), chloroxuron (generic name), chlorphthalim (general name), chlorprofam (general name), chloro IPC (chlorprofam / generic name), chlorsulfuron (generic name), Chlortal dimethyl (chlor-dimethyl / generic name), chlorthiamid (chlo thiamid / generic name), sinidone ethyl (cinidon-ethyl / generic name), simmesulin (cinmethyllin / generic name), sinosulfuron (cynosulfuron / generic name), cletodim (clethodidim / generic name), clodinahop / clodinafop / generic name Hoppropargyl (clodinafop-propargyl / generic name), clomazone (clomazone / generic name), clomeprop (cloproprop / generic name), clopyralid (clopyralid / generic name), clopyralid salts and esters (clopyralid-Nsalts, Cropandlide-Salts) (Generic name), cumylron (generic name), cyanazine (generic name) , Cycloate (common name), cyclopyrimoleate (common name, SW-065 / study name), cyclosulfamuron (common name), cycloxydim (cycloxydim / common name), cihalohop butyl (Cyhalofop-butyl / generic name), DAH-500 (test name), dalapon (dalapon / generic name), dazomet (dazomet / generic name), desmedifam (desmedifam / generic name), desmethrin (desmetrin / generic name) Dicamba (generic name), dicamba salts and esters, diclobenil (generic name), dicamba Hops (dicofop / generic name), diclohop-methyl (generic name), dichloroprop (generic name), dichlorprop-salts and esters, dichloroprop ( dichlorprop-P / generic name, salt and ester of P-dichloroprop (dichlorprop-p-salts and esters), diclosram (generic name), difenzoquat (common name), diflufenican / name Diflufenzopyr (general name), diflufenzopyr sodium (diflufenzopyr- odium / generic name), dimethylpiperate (common name), dimetamethrin (dimethametrin / generic name), dimetachlor (dimethachlor / generic name), dimethenamide (geneticid / generic name), P-dimethenamide (dimethenamide) (Dimethipin / generic name), dinitroamine (dinitamine / generic name), dinoseb (dinoseb / generic name), dinoteb (dinotarb / generic name), DNOC / generic name, diphenamide / generic name, diquat / generic Name), dithiopyr (dithiopyl / generic name), diuron (diuron / generic name), DSMA / generic name, dimron (dy) mron / generic name), endotal (endothal / generic name), EPTC / generic name, esprocarb (generic name), ethalfluralin (ethalfluralin / generic name), ethamesulfuron-methyl (generic name) , Etofumesate (ethofumesate / generic name), ettobenzanide (etobenzanid / generic name), ethoxysulfuron (ethoxysulfuron / generic name), flazasulfuron (general name), fenoxaprop (generic name) Ethyl (fenoxaprop-ethyl / generic name), phenoxasulfone (fenoxasulfone / generic name), Quinotrione (fenquition / generic name), fentrazamide (fentrazamide / generic name), flamprop (general name), flazasulfuron (general name), florasulam (general name), fluazif (generic name) , Fluazifopbutyl (general name), fluazolate (general name), flucarbazone sodium (general name), flucarbazone-sodium / generic name, flucetosulfuron (generic name), fluchloralin (general name) Name), flufenacet (flufenacet / generic name), flufenpyreth (Flufenpyl-ethyl / generic name), flumeturum (flumetsulam / generic name), full microlac pentyl (flumichlorac-pentyl / generic name), flumioxazin (generic name), fluometuron glyco (generic name) Phenethyl (fluoroglycofen-ethyl / generic name), flupirsulfuron (flupyrsulfuron / generic name), flupoxam (fluoxam / generic name), flulenol (flulenol / generic name), fluridone (fluridone / generic name), flurochloridone (flurochloridone) / Generic name), fluroxypyr (generic name), fluroxypyr beauty treatment (Fluoxypyr-esters), fluprimidol (flurprimidol / generic name), flutamon (flutatamone / generic name), fluthiaset-methyl (generic name), fomesafen (fomesafen / generic name), foramsulfuron (Generic name), fosamine (fosamine / generic name), glufosinate (glufosinate / generic name), glufosinate ammonium (glyphosate-ammonium / generic name), glyphosate (glyphosate / generic name), glyphosate-ammonium (generic name), Glyphosate-isopropylamine (glyphosate-iso- ropylammonium / generic name), glyphosate potassium (glyphosate-potassium / generic name), glyphosate sodium (glyphosate-sodium / generic name), glyphosate-trimesium (generic name), haloxifene (halixen) Haloxifene salts and esters (haloxifen-salts and esters), halosafene (halosafen / generic name), halosulfuron (halosulfuron / generic name), halosulfuron-methyl (generic name), haloxyhop (generic name) ), Haloxyhop-methyl / Generic name), hexazinone (generic name), imazametabenzmethyl (imazamethabenz-methyl / generic name), imazamox (general name), imazapic (common name), imazapyr (imazapi) , Imazetapyr (common name), imazaquin (common name), imazosulfuron (common name), indanophan (common name), indaziflam (common name), indazoflam (common name) -Sodium / generic name), ioxynyl octanoate / generic name, Aio Salts and esters of sinyl (ioxynil-salts and esters), ipfencarbazone (ipfencarbazone / generic name), isoproturon (isoproturon / generic name), isouron (isouron / generic name), isoxaben (common name), Isoxaflutol (isoxaflutole / generic name), carbutylate (karbutilate / generic name), lactofen (lactofen / generic name), renacil (lenacil / generic name), linuron (generic name), maleic hydrazide / Generic name), MCPA (generic name), MCPA salts and esters (MCPA-salts and esters), MCPB (generic name), M CPB salts and esters (MCPB-salts and esters), mecoprop (mecoprop, MCPP / generic name), mecoprop salts and esters (mecoprop-salts and esters), P mecoprop-p (MCPP-P / generic name) , Salts and esters of P mecoprop (mecoprop-P-salts and esters), mefenacet (mefenacet / generic name), mefluidide (mefluideide / generic name), mesosulfuron-methyl / generic name, mesotrione (mesotrione) Name), metam (metam / generic name), metamihop (metamihop / generic name), metamitron (metamitro) / Generic name), metazachlor (metazachlor / generic name), metabenzthiazuron (generic name), metazosulfuron (general name), methiozoline (geniozolin / generic name), methyl azide (methylazide name) , Methyl bromide (generic name), methyl dimron (generic name), methyl iodide (methyl iodide / generic name), metbenzuron (general name), metolachlor (metolachlor / generic name), S-metrachlor (S / general name), metoslam (metoslam / generic name), metribuzin (metr) benzin / generic name), metsulfuron-methyl / (general name), methoxuron / (generic name), molinate (generic name / generic name), monolinuron (generic name), monosulfuron / (generic name), Monosulfuron-methyl (monosulfuron-methyl / generic name), MSMA / generic name, naproanilide (generic name / generic name), napropamide (general name / generic name), naptalam / generic name (naptalum / general name) Name), nebulon (generic name), nicosulfuron (generic name), nor Lurazon (norflurazon / generic name), OK-701 (test name), oleic acid (oleic acid / generic name), olvencurve (orbencarb / generic name), orthosulfamuron (generic name), oryzalin / general Name), oxadialgyl (generic name), oxadiazone (generic name), oxasulfuron (generic name), oxadichromefone (generic name), oxyfluorfen (generic name), paraquat (arqua p) Generic name), pelargonic acid (pelargonic acid / generic name), pendimethalin / (Generic name), penoxsulam (generic name), pentanochlor (pentanochlor / generic name), pentoxazone (general name), petoxamide (genetic name), phenmedifamethyl (generic name) , Picloram (picloram / generic name), picloram salts and esters (picloram-salts and esters), picolinafen (picolinafene / generic name), pinoxaden (pinoxaden / generic name), piperophos (piperophos / generic name), pretilachlor p (Generic name), primissulfuron-methyl / generic name , Prodiamine (prodiamin / generic name), profluazole (profluazol / generic name), proxidim (profoxydim / generic name), prometon (promethon / generic name), promethrin (prometrin / generic name), propachlor (propachlor / generic name) Name), propanil (propanil / generic name), propaxahop (propaquizafop / generic name), propazine (propazin / generic name), propham (propam / generic name), propisochlor (propisochlor / generic name), propoxycarbazone Sodium (propoxycarbazone-sodium / generic name), propyrisulfuron (generic name), pro Zamide (propyamide / generic name), pull sulfocurve (prosulfocarb / generic name), prosulfuron (prosulfuron / generic name), pyraclonyl (pyraclonil / generic name), pyraflufen-ethyl (pyraflufen-ethyl / generic name), pyrasulfo Pyrazosulfuron (generic name), pyrazosulfuron (generic name), pyrazosulfuron-ethyl (generic name), pyrazosulfuron (generic name), pyrazosulfuron (generic name), pyrazosulfuron-ethyl (pyrazoxufuron / generic name) Name), piributicalbu (pyributicarb / generic name), pyridaf Ol (pyridafol / generic name), pyridate (pyridate / generic name), pyriftalide (pyriftalid / generic name), pyriminobac-methyl (generic name), pyrimisulfan (pyrimisulfan / generic name), pyrithio Buck sodium (pyrithiobac-sodium / generic name), piroxasulfone (pyroxasulphone / generic name), piroxislam (pyroxsulam / generic name), quinclorac (quinocracrac / generic name), quinmerac (quinomerac / generic name), quinoclamin / Generic name), quizalofop / common name, quizalofop-ethyl / Common name), quizalofop-tefuryl (generic name), P quizalofop-P / generic name, P quizalofop-P-ethyl / generic name, P quizalofopte Frill (quizalofop-P-tefuryl / generic name), rimsulfuron (rimsulfuron / generic name), saflufenacil (saffluenacil / generic name), cetoxydim (sethoxydim / generic name), siduron / generic name, simazine (sim / zimine) Name), cimetrin (simetrin / generic name), SL-261 (test name), sulcotrione (sulcotrione / generic name), sulfentrazone (sulfentrazone / (Generic name), sulfometuron methyl (sulfometuron-methyl / generic name), sulfosulfuron (sulfosulfuron / generic name), TCBA (2,3,6-TBA / generic name), TCBA salts and esters (2,3 , 6-TBA-salts and esters), TCTP (chlorthal-dimethyl, tetrachlorothiophene / generic name), tebutam (general name), tebuthiuron / general name, tefuryl trion (tefuryl trion name, tefuryl trion name) tebotrione / generic name), teplaloxidim (general name), terbacil (general name), terbumetone (te bumeton / generic name), terbuthylazine (generic name), terbutrin (general name), tetrapion (general name), tenylchlor (generic name), thiazaflulone (general name) thiazopyr / generic name), thiazimine (generic name), thiazuron / generic name, thiencarbazone-methyl / generic name, thifensulfuron-methyl / general name (Topylate / generic name), topramaison (top) amazoon / generic name), tolalkoxidim / generic name, triafamone / generic name, triarate / generic name, triasulfuron / generic name, triaziflam / generic name, triaziflam / generic name Nuronmethyl (tribenuron-methyl / generic name), triclopyr (triclopyr / generic name), salts and esters of triclopyr (tricyclophane-salts and esters), tridiphane (generic name), trietazine (generic name) , Trifludimoxazine (generic name), trifloxysulfuron (trifloxy) ulfuron / generic name), trifluralin (trifluralin / generic name), triflusulfuron methyl (triflusulfuron-methyl / generic name), tritosulfuron (tritosulfuron / generic name), 2,4-PA (generic name), 2,4 -Salts and esters of PA (2,4-PA-salts and esters), 2,4-DB (generic name), salts and esters of 2,4-DB (2,4-DB-salts and esters), etc. Can be mentioned. These components can be used alone or in admixture of two or more, and the ratio in the case of mixing can also be freely selected.

薬害軽減剤としては、例えば、ＡＤ−６７、ベノキサコル（ｂｅｎｏｘａｃｏｒ／一般名）、クロキントセットメキシル（ｃｌｏｑｕｉｎｔｏｃｅｔ−ｍｅｘｙｌ／一般名）、シオメトリニル（ｃｙｏｍｅｒｉｎｉｌ／一般名）、ジクロルミド（ｄｉｃｈｌｏｒｍｉｄ／一般名）、ジシクロノン（ｄｉｃｙｃｌｏｎｏｎｅ／一般名）、シプロスルファミド（ｃｙｐｒｏｓｕｌｆａｍｉｄｅ／一般名）、ジエトレート（ｄｉｅｔｈｏｒａｔｅ／一般名）、ＤＫＡ−２４、ダイムロン（ｄｙｍｒｏｎ／一般名）、フェンクロラゾールエチル（ｆｅｎｃｌｏｒａｚｏｌｅ−ｅｔｈｙｌ／一般名）、フェンクロリム（ｆｅｎｃｌｏｒｉｍ／一般名）、ヘキシム（ＨＥＸＩＭ／一般名）、フルラゾール（ｆｌｕｒａｚｏｌｅ／一般名）、フルキソフェニム（ｆｌｕｘｏｆｅｎｉｍ／一般名）、フリラゾール（ｆｕｒｉｌａｚｏｌｅ／一般名）、イソキサジフェン（ｉｓｏｘａｄｉｆｅｎ／一般名）、イソキサジフェンエチル（ｉｓｏｘａｄｉｆｅｎ―ｅｔｈｙｌ／一般名）、ＭＣＰＡ、メコプロップ（ｍｅｃｏｐｒｏｐ／一般名）、メフェンピル（ｍｅｆｅｎｐｙｒ／一般名）、メフェンピルエチル（ｍｅｆｅｎｐｙｒ−ｅｔｈｙｌ／一般名）、メフェンピルジエチル（ｍｅｆｅｎｐｙｒ−ｄｉｅｔｈｙｌ／一般名）、メフェネート（ｍｅｐｈｅｎａｔｅ／一般名）、ＭＧ−１９１、ＮＡ（Ｎａｐｈｔｈａｌｉｃ ａｎｈｙｄｒｉｄｅ）、ＯＭ（Ｏｃｔａｍｅｔｈｙｌｅｎｅ―ｄｉａｍｉｎｅ）、オキサベトリニル（ｏｘａｂｅｔｒｉｎｉｌ／一般名）、ＰＰＧ−１２９２、Ｒ−２９１４８等が挙げられる。これらの成分は単独でまたは２種以上混合して使用することができ、混合する場合の比も自由に選択できる。   As the safener, for example, AD-67, Benoxacol (benoxacor / generic name), cloquintocet-mexyl (generic name), ciomethrinil (cyomerinil / generic name), dichlormid (dichlormid / generic name), Dicyclonone (common name), cyprosulfamide (generic name), dietrate (generic name), DKA-24, dimron (common name), fenchlorazole-ethyl (general name) ), Fencrolim (general name), hexime (general name), flurazole (generic name), fluxofeni (Fluxofenim / generic name), flirazole (furilazole / generic name), isoxadifen (isoxadifen / generic name), isoxadifen-ethyl (isoxadifen-ethyl / generic name), MCPA, mecoprop (generic name), mefenpyr (mefenpy) / Generic name), mefenpyr-ethyl (mefenpyr-ethyl / generic name), mefenpyr-diethyl (mefenpyr-diethyl / generic name), mephenate (mephenate / generic name), MG-191, NA (Naphtalic anhydride), OM (Octamethylene-diamin), oxabetrinyl (oxabetrilin / generic name), PPG-1292, R-29148, etc. Can be mentioned. These components can be used alone or in admixture of two or more, and the ratio in the case of mixing can also be freely selected.

本発明化合物を除草剤として施用するにあたっては、通常適当な固体担体又は液体担体と混合し、更に所望により界面活性剤、浸透剤、展着剤、増粘剤、凍結防止剤、結合剤、固結防止剤、崩壊剤及び分解防止剤等を添加して、水和剤、乳剤、フロアブル剤、ドライフロアブル剤、液剤、粉剤、粒剤又はゲル剤等任意の剤型の製剤にて実用に供することができる。また、省力化及び安全性向上の観点から、上記任意の剤型の製剤を水溶性包装体に封入して供することもできる。   In applying the compound of the present invention as a herbicide, it is usually mixed with a suitable solid carrier or liquid carrier, and if desired, a surfactant, a penetrating agent, a spreading agent, a thickening agent, an antifreezing agent, a binder, a solid carrier. Add anti-caking agent, disintegrant, anti-decomposition agent, etc., and put to practical use in any dosage form such as wettable powder, emulsion, flowable, dry flowable, liquid, powder, granule or gel. be able to. In addition, from the viewpoint of labor saving and safety improvement, the preparation of any dosage form can be enclosed in a water-soluble package.

固体担体としては、例えば石英、カオリナイト、パイロフィライト、セリサイト、タルク、ベントナイト、酸性白土、アタパルジャイト、ゼオライト及び珪藻土等の天然鉱物質類、炭酸カルシウム、硫酸アンモニウム、硫酸ナトリウム及び塩化カリウム等の無機塩類、合成珪酸並びに合成珪酸塩が挙げられる。   Examples of solid carriers include quartz, kaolinite, pyrophyllite, sericite, talc, bentonite, acid clay, attapulgite, zeolite, and diatomaceous earth, and other minerals, calcium carbonate, ammonium sulfate, sodium sulfate, and potassium chloride. Examples include salts, synthetic silicic acid and synthetic silicates.

液体担体としては、例えばエチレングリコール、プロピレングリコール及びイソプロパノール等のアルコール類、キシレン、アルキルベンゼン及びアルキルナフタレン等の芳香族炭化水素類、ブチルセロソルブ等のエーテル類、シクロヘキサノン等のケトン類、γ−ブチロラクトン等のエステル類、Ｎ−メチルピロリドン、Ｎ−オクチルピロリドン等の酸アミド類、大豆油、ナタネ油、綿実油及びヒマシ油等の植物油並びに水が挙げられる。   Examples of the liquid carrier include alcohols such as ethylene glycol, propylene glycol and isopropanol, aromatic hydrocarbons such as xylene, alkylbenzene and alkylnaphthalene, ethers such as butyl cellosolve, ketones such as cyclohexanone, and esters such as γ-butyrolactone. And acid amides such as N-methylpyrrolidone and N-octylpyrrolidone, vegetable oils such as soybean oil, rapeseed oil, cottonseed oil and castor oil, and water.

これら固体及び液体担体は、単独で用いても２種以上を併用してもよい。   These solid and liquid carriers may be used alone or in combination of two or more.

界面活性剤としては、例えばポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレンスチリルフェニルエーテル、ポリオキシエチレンポリオキシプロピレンブロックコポリマー、ポリオキシエチレン脂肪酸エステル、ソルビタン脂肪酸エステル及びポリオキシエチレンソルビタン脂肪酸エステル等のノニオン性界面活性剤、アルキル硫酸塩、アルキルベンゼンスルホン酸塩、リグニンスルホン酸塩、アルキルスルホコハク酸塩、ナフタレンスルホン酸塩、アルキルナフタレンスルホン酸塩、ナフタレンスルホン酸のホルマリン縮合物の塩、アルキルナフタレンスルホン酸のホルマリン縮合物の塩、ポリオキシエチレンアルキルアリールエーテル硫酸及び燐酸塩、ポリオキシエチレンスチリルフェニルエーテル硫酸及び燐酸塩、ポリカルボン酸塩及びポリスチレンスルホン酸塩等のアニオン性界面活性剤、アルキルアミン塩及びアルキル４級アンモニウム塩等のカチオン性界面活性剤並びにアミノ酸型及びベタイン型等の両性界面活性剤が挙げられる。   Examples of the surfactant include polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene styryl phenyl ether, polyoxyethylene polyoxypropylene block copolymer, polyoxyethylene fatty acid ester, sorbitan fatty acid ester and polyoxyethylene sorbitan. Nonionic surfactant such as fatty acid ester, alkyl sulfate, alkylbenzene sulfonate, lignin sulfonate, alkyl sulfosuccinate, naphthalene sulfonate, alkyl naphthalene sulfonate, salt of formalin condensate of naphthalene sulfonate, Salt of formalin condensate of alkylnaphthalenesulfonic acid, polyoxyethylene alkylaryl ether sulfate and phosphate, polyoxyethylene polystyrene Anionic surfactants such as phenyl ether sulfate and phosphate, polycarboxylate and polystyrene sulfonate, cationic surfactants such as alkylamine salt and alkyl quaternary ammonium salt, and amphoteric interfaces such as amino acid type and betaine type An activator is mentioned.

これら界面活性剤の含有量は、特に限定されるものではないが、本発明の製剤１００質量部に対し、通常０．０５から２０質量部の範囲が望ましい。また、これら界面活性剤は、単独で用いても２種以上を併用してもよい。   The content of these surfactants is not particularly limited, but is usually in the range of 0.05 to 20 parts by mass with respect to 100 parts by mass of the preparation of the present invention. These surfactants may be used alone or in combination of two or more.

本発明化合物は必要に応じて製剤又は散布時に他種の除草剤、各種殺虫剤、殺菌剤、植物生長調節剤又は共力剤等と混合施用してもよい。   The compound of the present invention may be mixed and applied with other types of herbicides, various insecticides, fungicides, plant growth regulators, synergists, and the like, as necessary, during formulation or spraying.

特に、他の除草剤と混合施用することにより、施用薬量の減少による低コスト化、混合薬剤の相乗作用による殺草スペクトラムの拡大や、より高い殺草効果が期待できる。この際、同時に複数の公知除草剤との組み合わせも可能である。   In particular, when mixed with other herbicides, cost reduction due to a decrease in the amount of applied medicine, expansion of the herbicidal spectrum due to the synergistic action of the mixed drugs, and higher herbicidal effects can be expected. At this time, a combination with a plurality of known herbicides is also possible.

本発明化合物の施用薬量は適用場面、施用時期、施用方法、栽培作物等により差異はあるが一般には有効成分量としてヘクタール（ｈａ）当たり０．００５から５０ｋｇ程度が適当である。   The application dose of the compound of the present invention varies depending on the application scene, application time, application method, cultivated crops, etc., but generally an amount of 0.005 to 50 kg per hectare (ha) is appropriate as the amount of active ingredient.

次に本発明化合物を用いる場合の製剤の配合例を示す。但し本発明の配合例は、これらのみに限定されるものではない。尚、以下の配合例において「部」は質量部を意味する。
水和剤
本発明化合物 ０．１〜８０部
固体担体 ５〜９８．９部
界面活性剤 １〜１０部
その他 ０〜 ５部
その他として、例えば固結防止剤、分解防止剤等が挙げられる。
乳 剤
本発明化合物 ０．１〜３０部
液体担体 ４５〜９５部
界面活性剤 ４．９〜１５部
その他 ０〜１０部
その他として、例えば展着剤、分解防止剤等が挙げられる。
フロアブル（ｆｌｏｗａｂｌｅ）剤
本発明化合物 ０．１〜７０部
液体担体 １５〜９８．８９部
界面活性剤 １〜１２部
その他 ０．０１〜３０部
その他として、例えば凍結防止剤、増粘剤等が挙げられる。
ドライフロアブル（ｄｒｙ ｆｌｏｗａｂｌｅ）剤
本発明化合物 ０．１〜９０部
固体担体 ０〜９８．９部
界面活性剤 １〜２０部
その他 ０〜１０部
その他として、例えば結合剤、分解防止剤等が挙げられる。
液 剤
本発明化合物 ０．０１〜７０部
液体担体 ２０〜９９．９９部
その他 ０〜１０部
その他として、例えば凍結防止剤、展着剤等が挙げられる。
粒 剤
本発明化合物 ０．０１〜８０部
固体担体 １０〜９９．９９部
その他 ０〜１０部
その他として、例えば結合剤、分解防止剤等が挙げられる。
粉 剤
本発明化合物 ０．０１〜３０部
固体担体 ６５〜９９．９９部
その他 ０〜１０部
その他として、例えばドリフト防止剤、分解防止剤等が挙げられる。 Next, formulation examples of the preparation when the compound of the present invention is used are shown. However, the formulation examples of the present invention are not limited to these. In the following formulation examples, “part” means part by mass.
Wettable compound of the present invention 0.1-80 parts Solid carrier 5-98.9 parts Surfactant 1-10 parts Others 0-5 parts Others include, for example, anti-caking agents and decomposition inhibitors.
Emulsified compound of the present invention 0.1-30 parts Liquid carrier 45-95 parts Surfactant 4.9-15 parts Others 0-10 parts Others include, for example, spreading agents, decomposition inhibitors and the like.
Flowable agent compound of the present invention 0.1 to 70 parts Liquid carrier 15 to 98.89 parts Surfactant 1 to 12 parts Others 0.01 to 30 parts Others include, for example, antifreezing agents and thickeners. It is done.
Dry flowable agent compound of the present invention 0.1-90 parts Solid carrier 0-98.9 parts Surfactant 1-20 parts Others 0-10 parts Others include, for example, binders, decomposition inhibitors, etc. .
Liquid compound of the present invention 0.01 to 70 parts Liquid carrier 20 to 99.99 parts Others 0 to 10 parts Others include, for example, antifreezing agents and spreading agents.
Granules of the present invention compound 0.01 to 80 parts Solid carrier 10 to 99.99 parts Others 0 to 10 parts Others include, for example, binders and decomposition inhibitors.
Powder Compound of the Present Invention 0.01-30 parts Solid carrier 65-99.99 parts Others 0-10 parts Others include, for example, drift inhibitors and decomposition inhibitors.

使用に際しては上記製剤をそのままで、又は水で１〜１００００倍に希釈して散布する。   In use, the preparation is sprayed as it is or diluted 1 to 10,000 times with water.

製剤例
次に具体的に本発明化合物を有効成分とする農薬製剤例を示すがこれらのみに限定されるものではない。尚、以下の配合例において「部」は質量部を意味する。
〔配合例１〕水和剤
本発明化合物Ｎｏ．１−００１ ２０部
パイロフィライト ７６部
ソルポール５０３９ ２部
（アニオン性界面活性剤：東邦化学工業（株）商品名）
カープレックス＃８０ ２部
（合成含水珪酸：塩野義製薬（株）商品名）
以上を均一に混合粉砕して水和剤とする。
〔配合例２〕乳 剤
本発明化合物Ｎｏ．１−００１ ５部
キシレン ７５部
Ｎ−メチルピロリドン １５部
ソルポール２６８０ ５部
（アニオン性界面活性剤：東邦化学工業（株）商品名）
以上を均一に混合して乳剤とする。
〔配合例３〕フロアブル剤
本発明化合物Ｎｏ．１−００１ ２５部
アグリゾールＳ−７１０ １０部
（非イオン性界面活性剤：花王（株）商品名）
ルノックス１０００Ｃ ０．５部
（アニオン性界面活性剤：東邦化学工業（株）商品名）
キサンタンガム ０．０２部
水 ６４．４８部
以上を均一に混合した後、湿式粉砕してフロアブル剤とする。
〔配合例４〕ドライフロアブル剤
本発明化合物Ｎｏ．１−００１ ７５部
ハイテノールＮＥ−１５ ５部
（アニオン性界面活性剤：第一工業製薬（株）商品名）
バニレックスＮ １０部
（アニオン性界面活性剤：日本製紙（株）商品名）
カープレックス＃８０ １０部
（合成含水珪酸：塩野義製薬（株）商品名）
以上を均一に混合粉砕した後、少量の水を加えて撹拌混合捏和し、押出式造粒機で造粒し、乾燥してドライフロアブル剤とする。
〔配合例５〕粒 剤
本発明化合物Ｎｏ．１−００１ １部
ベントナイト ５５部
タルク ４４部
以上を均一に混合粉砕した後、少量の水を加えて撹拌混合捏和し、押出式造粒機で造粒し、乾燥して粒剤とする。 Formulation Examples Next, specific examples of agrochemical formulations containing the compound of the present invention as an active ingredient are shown, but the invention is not limited thereto. In the following formulation examples, “part” means part by mass.
[Formulation Example 1] Wetting Agent Compound No. 1-001 20 parts Pyrophyllite 76 parts Solpol 5039 2 parts (Anionic surfactant: Toho Chemical Industries, Ltd. trade name)
Carplex # 80 2 parts (Synthetic hydrous silicate: Shionogi Pharmaceutical Co., Ltd. trade name)
The above is uniformly mixed and ground to obtain a wettable powder.
[Composition Example 2] Milk Compound No. of the present invention. 1-001 5 parts Xylene 75 parts N-methylpyrrolidone 15 parts Solpol 2680 5 parts (anionic surfactant: Toho Chemical Industries, Ltd. trade name)
The above is uniformly mixed to obtain an emulsion.
[Composition Example 3] Flowable Agent Compound No. 1-001 25 parts Agrisol S-710 10 parts (Nonionic surfactant: trade name of Kao Corporation)
Lnox 1000C 0.5 part (anionic surfactant: Toho Chemical Co., Ltd. trade name)
Xanthan gum 0.02 parts Water 64.48 parts After uniformly mixing the above, wet milling to obtain a flowable agent.
[Composition Example 4] Dry flowable agent Compound No. 1-001 75 parts Hightenol NE-15 5 parts (Anionic surfactant: trade name of Daiichi Kogyo Seiyaku Co., Ltd.)
Vanillex N 10 parts (anionic surfactant: Nippon Paper Industries Co., Ltd. trade name)
Carplex # 80 10 parts (Synthetic hydrous silicic acid: Shionogi Pharmaceutical Co., Ltd. trade name)
After uniformly mixing and pulverizing the above, a small amount of water is added and stirred and kneaded, granulated with an extrusion granulator, and dried to obtain a dry flowable agent.
[Formulation Example 5] Granule The present compound No. 1-001 1 part Bentonite 55 parts Talc 44 parts After uniformly mixing and pulverizing the above, a small amount of water is added and mixed with stirring, kneaded, granulated with an extrusion granulator, and dried to form granules.

以下に本発明の除草剤において、活性成分として用いられる式（１）で表されるケトン若しくはオキシム化合物の合成例、試験例を実施例として具体的に述べることで、本発明を更に詳しく説明するが、本発明はこれらによって限定されるものではない。   In the herbicide of the present invention, the present invention will be described in more detail by specifically describing, as examples, synthesis examples and test examples of ketones or oxime compounds represented by the formula (1) used as an active ingredient. However, the present invention is not limited by these.

合成例に記載した中圧分取液体クロマトグラフィーは、山善社製、中圧分取装置；ＹＦＬＣ−Ｗｐｒｅｐ（流速１８ｍｌ／ｍｉｎ、シリカゲル４０μｍのカラム）を使用した。   The medium-pressure preparative liquid chromatography described in the synthesis example used an intermediate-pressure preparative device manufactured by Yamazen Co., Ltd .; YFLC-Wprep (flow rate 18 ml / min, silica gel 40 μm column).

マイクロ波合成装置はＣＥＭ社製 Ｄｉｓｃａｖｅｒを用い、また、反応容器は装置専用の密閉容器を使用した。   The microwave synthesizer used was a Discover made by CEM, and the reaction vessel used was a sealed vessel dedicated to the device.

高速液体クロマトグラフィーは、島津製作所製；１０ＡＶＰシステムを使用した。   For high performance liquid chromatography, Shimadzu Corporation 10AVP system was used.

高速液体クロマトグラフィーを用いた定性分析は、以下に記載する測定条件を用いて実施した。
カラム：Ｉｎｅｒｔｓｉｌ ＯＤＳ−ＳＰ（長さ２５０ｍｍ、内径４．６ｍｍ、シリカゲル粒子径５μｍ、ジーエルサイエンス社製）
流速：１．０ｍＬ／ｍｉｎ．
カラム温度：４０℃
検出波長：ＵＶ ２５４ｎｍ
溶離液：アセトニトリル／水／トリフルオロ酢酸＝７００／３００／１（体積比）
また、実施例のプロトン核磁気共鳴ケミカルシフト値は、基準物質としてＭｅ_４Ｓｉ（テトラメチルシラン）を用い、３００ＭＨｚにて測定した。また測定に使用した溶媒を以下の合成例中に記載する。また、実施例のプロトン核磁気共鳴ケミカルシフト値における記号は、下記の意味を表す。
ｓ：シングレット、ｂｒｓ：ブロードシングレット、ｄ：ダブレット、ｔ：トリプレット、ｍ：マルチプレット
合成例
合成例１：２−メシチル−３−メトキシ−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノン（化合物No.1-001）の製造
国際公開第２０１０／０００７７３号記載の方法により合成した２−メシチル−３−メトキシシクロペンタ−２−エノン０．５ｇ及びテトラヒドロフラン１０ｍｌの混合溶液を、窒素雰囲気下、−７８℃まで冷却した後、リチウムジイソプロピルアミド（約１．５ｍｏｌ／Ｌ ｎ−ヘキサン及びテトラヒドロフランの混合溶液、関東化学社製）２．３ｍｌを滴下した。滴下終了後、該反応混合物を同温度にて３０分間撹拌した。撹拌終了後、該反応混合物に、１−クロロプロパン−２−オン Ｏ−メチル オキシム０．３４ｇを添加した。添加終了後、該反応溶液を−７８℃にて２０分間撹拌した後、室温まで昇温し、同温度にて１５時間撹拌した。反応終了後、該反応混合物を氷水に添加し、酢酸エチル２０ｍｌにて抽出した。得られた有機層を水洗、無水硫酸ナトリウムにて脱水・乾燥後、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル[１：１（体積比、以下同じである。）]にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物７６ｍｇを白色固体として得た。
融点９２−９８℃
合成例２：３−ヒドロキシ−２−メシチル−５−（２−オキソプロピル）シクロペンタ−２−エノン（化合物No.2-001）の製造
２−メシチル−３−メトキシ−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノン６０ｍｇ及びアセトン１ｍｌの混合溶液に、２Ｍ塩酸水溶液１ｍｌを添加した。添加終了後、該反応混合物を５０℃にて４時間撹拌した。反応終了後、該反応混合物に酢酸エチル５ｍｌを添加し、有機層を取り出した。得られた有機層を水洗した後、無水硫酸ナトリウムにて脱水・乾燥後、減圧下にて溶媒を留去し、目的物５６ｍｇを白色固体として得た。
融点；１８３−１８５℃
合成例３：３−ヒドロキシ−２−メシチル−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノン（化合物No.1-002）の製造
３−ヒドロキシ−２−メシチル−５−（２−オキソプロピル）シクロペンタ−２−エノン５０ｍｇ、メタノール２ｍｌ及び水１ｍｌの混合溶液に、Ｏ−メチルヒドロキシルアミン 塩酸塩２４ｍｇを添加した。添加終了後、該反応混合物を５０℃にて１時間撹拌した。反応終了後、該反応混合物から減圧下にて溶媒を留去した。得られた残留物に酢酸エチル１０ｍｌを添加した後、水洗した。得られた有機層を、飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去して目的物３１ｍｇを白色固体として得た。
融点；１７０−１７３℃
合成例４：２‐メシチル‐４‐｛２‐（メトキシイミノ）プロピル｝‐３‐オキソシクロペンタ‐１‐エン‐１‐イル ピバレート（化合物No.1-004）の製造
３‐ヒドロキシ‐２‐メシチル‐５‐｛２‐（メトキシイミノ）プロピル｝シクロペンタ−２−エノン１５０ｍｇ及びジクロロメタン５ｍｌの混合溶液に、トリエチルアミン１３９ｍｇ、４−ジメチルアミノピリジンを６ｍｇ及びピバル酸無水物１８６ｍｇを順次添加した。添加終了後、該反応混合物を室温にて１５時間撹拌した。反応終了後、水５ｍｌを該反応混合物に添加し、クロロホルム１０ｍｌにて抽出した。得られた有機層を無水硫酸ナトリウムで脱水・乾燥した後、減圧下にて溶媒を留去した。溶媒を留去した後、得られた残留物をヘキサン−酢酸エチル（２：１）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物１５０ｍｇを無色油状物として得た。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ６．８５−６．８１（ｍ，２Ｈ），３．８７−３．８２（ｍ，３Ｈ），３．７０−２．１８（ｍ，８Ｈ），２．１５−１．７８（ｍ，９Ｈ），１．０８ ａｎｄ １．０６（ｓ，９Ｈ）。 The qualitative analysis using high performance liquid chromatography was performed using the measurement conditions described below.
Column: Inertsil ODS-SP (length: 250 mm, inner diameter: 4.6 mm, silica gel particle diameter: 5 μm, manufactured by GL Sciences Inc.)
Flow rate: 1.0 mL / min.
Column temperature: 40 ° C
Detection wavelength: UV 254 nm
Eluent: acetonitrile / water / trifluoroacetic acid = 700/300/1 (volume ratio)
Moreover, the proton nuclear magnetic resonance chemical shift value of the Example was measured at 300 MHz using Me ₄ Si (tetramethylsilane) as a reference material. Moreover, the solvent used for the measurement is described in the following synthesis examples. Moreover, the symbol in the proton nuclear magnetic resonance chemical shift value of an Example represents the following meaning.
s: singlet, brs: broad singlet, d: doublet, t: triplet, m: multiplet Synthesis example Synthesis example 1: 2-mesityl-3-methoxy-5- {2- (methoxyimino) propyl} cyclopent-2- Production of Enone (Compound No. 1-001) A mixed solution of 0.5 g of 2-mesityl-3-methoxycyclopent-2-enone and 10 ml of tetrahydrofuran synthesized by the method described in WO 2010/000773 was added to a nitrogen atmosphere. Then, after cooling to −78 ° C., 2.3 ml of lithium diisopropylamide (about 1.5 mol / L n-hexane and tetrahydrofuran mixed solution, manufactured by Kanto Chemical Co., Inc.) was added dropwise. After completion of the dropwise addition, the reaction mixture was stirred at the same temperature for 30 minutes. After completion of stirring, 0.34 g of 1-chloropropan-2-one O-methyl oxime was added to the reaction mixture. After completion of the addition, the reaction solution was stirred at −78 ° C. for 20 minutes, then warmed to room temperature and stirred at the same temperature for 15 hours. After completion of the reaction, the reaction mixture was added to ice water and extracted with 20 ml of ethyl acetate. The obtained organic layer was washed with water, dehydrated and dried over anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate [1: 1 (volume ratio, the same shall apply hereinafter)] to obtain 76 mg of the target product as a white solid. Obtained.
Melting point 92-98 ° C
Synthesis Example 2: Production of 3-hydroxy-2-mesityl-5- (2-oxopropyl) cyclopent-2-enone (Compound No. 2-001) 2-mesityl-3-methoxy-5- {2- (methoxy 1 ml of 2M aqueous hydrochloric acid was added to a mixed solution of 60 mg of imino) propyl} cyclopent-2-enone and 1 ml of acetone. After completion of the addition, the reaction mixture was stirred at 50 ° C. for 4 hours. After completion of the reaction, 5 ml of ethyl acetate was added to the reaction mixture, and the organic layer was taken out. The obtained organic layer was washed with water, dehydrated and dried over anhydrous sodium sulfate, and the solvent was evaporated under reduced pressure to obtain 56 mg of the desired product as a white solid.
Melting point: 183-185 ° C
Synthesis Example 3: Production of 3-hydroxy-2-mesityl-5- {2- (methoxyimino) propyl} cyclopent-2-enone (Compound No. 1-002) 3-hydroxy-2-mesityl-5- (2 To a mixed solution of -oxopropyl) cyclopent-2-enone 50 mg, methanol 2 ml and water 1 ml, 24 mg of O-methylhydroxylamine hydrochloride was added. After the addition was complete, the reaction mixture was stirred at 50 ° C. for 1 hour. After completion of the reaction, the solvent was distilled off from the reaction mixture under reduced pressure. After adding 10 ml of ethyl acetate to the obtained residue, it was washed with water. The obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure to obtain 31 mg of the desired product as a white solid.
Melting point: 170-173 ° C
Synthesis Example 4: Preparation of 2-mesityl-4- {2- (methoxyimino) propyl} -3-oxocyclopent-1-en-1-yl pivalate (Compound No. 1-004) 3-hydroxy-2- To a mixed solution of 150 mg of mesityl-5- {2- (methoxyimino) propyl} cyclopent-2-enone and 5 ml of dichloromethane, 139 mg of triethylamine, 6 mg of 4-dimethylaminopyridine and 186 mg of pivalic anhydride were sequentially added. After the addition was complete, the reaction mixture was stirred at room temperature for 15 hours. After completion of the reaction, 5 ml of water was added to the reaction mixture and extracted with 10 ml of chloroform. The obtained organic layer was dehydrated and dried over anhydrous sodium sulfate, and then the solvent was distilled off under reduced pressure. After the solvent was distilled off, the obtained residue was purified by medium pressure preparative liquid chromatography eluting with hexane-ethyl acetate (2: 1) to obtain 150 mg of the desired product as a colorless oil.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 6.85-6.81 (m, 2H), 3.87-3.82 (m, 3H), 3.70-2.18 (m, 8H) ), 2.15-1.78 (m, 9H), 1.08 and 1.06 (s, 9H).

合成例５：２−（４−ブロモ−２−メトキシ−６−メチルフェニル）−３−ヒドロキシ−５−（２−オキソプロピル）シクロペンタ−２−エノン（化合物No.7-027）の製造
工程１：５−ブロモ−２−ヨード−１−メトキシ−３−メチルベンゼンの製造
国際公開第２００５／０２８４７９号記載の方法により合成した４−ブロモ−２−メトキシ−６−メチルアニリン１５．７ｇ、濃塩酸１３０ｍｌ及び水１３０ｍｌの混合溶液を０℃に冷却した。該混合溶液に、５℃以下の温度を保ちながら亜硝酸ナトリウム５．５ｇを添加し、更に３０分間撹拌した。次いで、該反応溶液にヨウ化カリウム１３．３ｇ及び水６５ｍｌの混合溶液を、５℃以下の温度を保ちながら添加した後、室温にて１５時間撹拌した。反応終了後、該反応溶液を１，２−ジクロロエタン２００ｍｌにて抽出した。得られた有機層を、１ｍｏｌ／Ｌ水酸化ナトリウム水溶液２００ｍｌ、１ｍｏｌ／Ｌ亜硫酸ナトリウム水溶液２００ｍｌ、１ｍｏｌ／Ｌ塩酸水溶液２００ｍｌ、飽和炭酸水素ナトリウム２００ｍｌの順で洗浄した。引き続き得られた有機層を、飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（１０：１）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物１０．３ｇを茶色固体として得た。
融点；７２−７５℃
工程２：（４−ブロモ−２−メトキシ−６−メチルフェニル）（フラン−２−イル）メタノールの製造
５−ブロモ−２−ヨード−１−メトキシ−３−メチルベンゼン５ｇ及びテトラヒドロフラン５０ｍｌの混合溶液を、窒素雰囲気下で−７０℃に冷却した。該混合溶液にイソプロピルマグネシウムクロリド 塩化リチウム錯体（約１ｍｏｌ／Ｌテトラヒドロフラン溶液、東京化成工業社製）８．１ｍｌ次いでイソプロピルマグネシウムクロリド（約１ｍｏｌ／Ｌテトラヒドロフラン溶液、東京化成工業社製）４．６ｍｌを順次添加し、３０分間撹拌した後、フルフラール２．２ｇ及びテトラヒドロフラン２０ｍｌの混合溶液を添加した。添加終了後、室温まで昇温し、同温度にて１５時間撹拌した。反応終了後、該反応溶液に飽和塩化アンモニウム水溶液５０ｍｌを添加し、減圧下にて溶媒を半量になるまで留去した。得られた残留物を酢酸エチル３０ｍｌにて抽出し、飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（２０：１〜１０：１のグラジエント）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物４．６ｇを黄色油状物として得た。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．３８−７．３４（ｍ，１Ｈ），７．００（ｂｒｓ，１Ｈ），６．９７（ｂｒｓ，１Ｈ），６．３７−６．２０（ｍ，１Ｈ），６．０３−５．９２（ｍ，２Ｈ），３．８３（ｓ，３Ｈ），４．２１（ｄ，Ｊ＝１０．８Ｈｚ，１Ｈ），２．３１（ｓ，３Ｈ）。 Synthesis Example 5 Production of 2- (4-bromo-2-methoxy-6-methylphenyl) -3-hydroxy-5- (2-oxopropyl) cyclopent-2-enone (Compound No. 7-027) Step 1 : Production of 5-bromo-2-iodo-1-methoxy-3-methylbenzene 15.7 g of 4-bromo-2-methoxy-6-methylaniline synthesized by the method described in International Publication No. 2005/028479, concentrated hydrochloric acid A mixed solution of 130 ml and 130 ml of water was cooled to 0 ° C. 5.5 g of sodium nitrite was added to the mixed solution while maintaining a temperature of 5 ° C. or lower, and the mixture was further stirred for 30 minutes. Next, a mixed solution of 13.3 g of potassium iodide and 65 ml of water was added to the reaction solution while maintaining a temperature of 5 ° C. or lower, and then stirred at room temperature for 15 hours. After completion of the reaction, the reaction solution was extracted with 200 ml of 1,2-dichloroethane. The obtained organic layer was washed with a 1 mol / L aqueous sodium hydroxide solution (200 ml), a 1 mol / L aqueous sodium sulfite solution (200 ml), a 1 mol / L aqueous hydrochloric acid solution (200 ml), and a saturated sodium bicarbonate solution (200 ml) in this order. Subsequently, the obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (10: 1) to obtain 10.3 g of the objective product as a brown solid.
Melting point: 72-75 ° C
Step 2: Preparation of (4-bromo-2-methoxy-6-methylphenyl) (furan-2-yl) methanol A mixed solution of 5 g of 5-bromo-2-iodo-1-methoxy-3-methylbenzene and 50 ml of tetrahydrofuran Was cooled to −70 ° C. under a nitrogen atmosphere. To the mixed solution, 8.1 ml of an isopropylmagnesium chloride lithium chloride complex (about 1 mol / L tetrahydrofuran solution, manufactured by Tokyo Chemical Industry Co., Ltd.) and then 4.6 ml of isopropylmagnesium chloride (about 1 mol / L tetrahydrofuran solution, manufactured by Tokyo Chemical Industry Co., Ltd.) were sequentially added. After adding and stirring for 30 minutes, a mixed solution of 2.2 g of furfural and 20 ml of tetrahydrofuran was added. After completion of the addition, the temperature was raised to room temperature and stirred at the same temperature for 15 hours. After completion of the reaction, 50 ml of a saturated aqueous ammonium chloride solution was added to the reaction solution, and the solvent was distilled off under reduced pressure to half the amount. The obtained residue was extracted with 30 ml of ethyl acetate, dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (gradient 20: 1 to 10: 1) to obtain 4.6 g of the objective product as a yellow oil. It was.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.38-7.34 (m, 1H), 7.00 (brs, 1H), 6.97 (brs, 1H), 6.37-6. 20 (m, 1H), 6.03-5.92 (m, 2H), 3.83 (s, 3H), 4.21 (d, J = 10.8 Hz, 1H), 2.31 (s, 3H).

工程３：５−（４−ブロモ−２−メトキシ−６−メチルフェニル）−４−ヒドロキシシクロペンタ−２−エノンの製造
（４−ブロモ−２−メトキシ−６−メチルフェニル）（フラン−２−イル）メタノール４．６ｇ、アセトン３５ｍｌ及び水１０ｍｌの混合溶液に、ポリリン酸２．６ｇ、アセトン１０ｍｌ及び水４ｍｌの混合溶液を添加し、５５℃にて１時間撹拌した。反応終了後、減圧化にて該反応混合物の体積が半量になるまで溶媒を留去した。得られた残留物に水３０ｍｌを添加した後、酢酸エチル３０ｍｌにて抽出した。得られた有機層を飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（４：１〜１：２のグラジエント）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物３．１ｇを茶色油状物として得た。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．５２−７．４６（ｍ，１Ｈ），７．０２（ｂｒｓ，１Ｈ），６．８４（ｂｒｓ，１Ｈ），６．３６−６．２８（ｍ，１Ｈ），５．０９−５．０１（ｍ，１Ｈ），３．８６−３．５２（ｍ，５Ｈ），２．３６（ｓ，３Ｈ）。 Step 3: Preparation of 5- (4-bromo-2-methoxy-6-methylphenyl) -4-hydroxycyclopent-2-enone (4-Bromo-2-methoxy-6-methylphenyl) (furan-2- I) To a mixed solution of 4.6 g of methanol, 35 ml of acetone and 10 ml of water, a mixed solution of 2.6 g of polyphosphoric acid, 10 ml of acetone and 4 ml of water was added and stirred at 55 ° C. for 1 hour. After completion of the reaction, the solvent was distilled off under reduced pressure until the volume of the reaction mixture became half. 30 ml of water was added to the obtained residue, followed by extraction with 30 ml of ethyl acetate. The obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (4: 1 to 1: 2 gradient) to obtain 3.1 g of the objective product as a brown oil. It was.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.52-7.46 (m, 1H), 7.02 (brs, 1H), 6.84 (brs, 1H), 6.36-6. 28 (m, 1H), 5.09-5.01 (m, 1H), 3.86-3.52 (m, 5H), 2.36 (s, 3H).

工程４：２−（４−ブロモ−２−メトキシ−６−メチルフェニル）シクロペンタ−４−エン−１，３−ジオンの製造
酸化クロム（６価）１．６ｇ及び水８．６ｍｌの混合溶液に、氷冷下にて濃硫酸１．１ｍｌを添加した。該反応溶液を、別途調整した５−（４−ブロモ−２−メトキシ−６−メチルフェニル）−４−ヒドロキシシクロペンタ−２−エノン３．１ｇ及びアセトン２８ｍｌの混合溶液に、氷冷化にて添加し、２５分間撹拌した。反応終了後、該反応溶液にイソプロピルアルコール３０ｍｌを添加した後、減圧下にて溶媒を留去した。得られた残留物に、酢酸エチル３０ｍｌを添加し、飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去した。得られた固体をジイソプロピルエーテルにて洗浄し、目的物１．８ｇを黄色固体として得た。
融点；１０４−１０７℃
工程５：２−（４−ブロモ−２−メトキシ−６−メチルフェニル）−３−ヒドロキシ−５−（２−オキソプロピル）シクロペンタ−２−エノンの製造
２−（４−ブロモ−２−メトキシ−６−メチルフェニル）シクロペンタ−４−エン−１，３−ジオン１．８ｇ及びＮ，Ｎ−ジメチルホルムアミド３０ｍｌの混合溶液に、炭酸カリウム１．７ｇ及びアセト酢酸メチル０．８５ｇを順次添加し、室温にて１５時間撹拌した。反応終了後、該反応溶液に１ｍｏｌ／Ｌ塩酸水溶液を添加してｐＨ３とし、酢酸エチル３０ｍｌにて抽出した。得られた有機層を、飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去した。得られた残留物に、メタノール２０ｍｌ及び水５ｍｌを添加した後、更に水酸化カリウム１ｇを添加し、室温にて１５時間撹拌した。反応終了後、減圧下にて溶媒を留去した。得られた残留物に、１ｍｏｌ／Ｌ塩酸水溶液２０ｍｌを添加し酢酸エチル２０ｍｌにて抽出した。得られた有機層を、飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去して目的物１．８ｇを茶色粘性物質として得た。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．０２（ｂｒｓ，１Ｈ），６．８８（ｂｒｓ，１Ｈ），３．９１−３．６２（ｍ，３Ｈ），３．５１−１．９７（ｍ，１２Ｈ）。 Step 4: Preparation of 2- (4-bromo-2-methoxy-6-methylphenyl) cyclopent-4-ene-1,3-dione To a mixed solution of 1.6 g of chromium oxide (hexavalent) and 8.6 ml of water Under ice cooling, 1.1 ml of concentrated sulfuric acid was added. The reaction solution was mixed with a separately prepared mixed solution of 3.1 g of 5- (4-bromo-2-methoxy-6-methylphenyl) -4-hydroxycyclopent-2-enone and 28 ml of acetone by cooling with ice. Added and stirred for 25 minutes. After completion of the reaction, 30 ml of isopropyl alcohol was added to the reaction solution, and then the solvent was distilled off under reduced pressure. 30 ml of ethyl acetate was added to the obtained residue, dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained solid was washed with diisopropyl ether to obtain 1.8 g of the objective product as a yellow solid.
Melting point: 104-107 ° C
Step 5: Preparation of 2- (4-bromo-2-methoxy-6-methylphenyl) -3-hydroxy-5- (2-oxopropyl) cyclopent-2-enone 2- (4-Bromo-2-methoxy- To a mixed solution of 1.8 g of 6-methylphenyl) cyclopent-4-ene-1,3-dione and 30 ml of N, N-dimethylformamide, 1.7 g of potassium carbonate and 0.85 g of methyl acetoacetate were sequentially added. For 15 hours. After completion of the reaction, a 1 mol / L hydrochloric acid aqueous solution was added to the reaction solution to adjust the pH to 3, followed by extraction with 30 ml of ethyl acetate. The obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. After adding 20 ml of methanol and 5 ml of water to the obtained residue, 1 g of potassium hydroxide was further added and stirred at room temperature for 15 hours. After completion of the reaction, the solvent was distilled off under reduced pressure. To the obtained residue, 1 ml / L hydrochloric acid aqueous solution (20 ml) was added and extracted with ethyl acetate (20 ml). The obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure to obtain 1.8 g of the desired product as a brown viscous substance.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.02 (brs, 1H), 6.88 (brs, 1H), 3.91-3.62 (m, 3H), 3.51-1. 97 (m, 12H).

合成例６：２−（４−ブロモ−２−メトキシ−６−メチルフェニル）−３−ヒドロキシ−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノン（化合物No.6-076）の製造
合成例３と同様の方法で、２−（４−ブロモ−２−メトキシ−６−メチルフェニル）−３−ヒドロキシ−５−（２−オキソプロピル）シクロペンタ−２−エノンから製造した。 Synthesis Example 6: 2- (4-Bromo-2-methoxy-6-methylphenyl) -3-hydroxy-5- {2- (methoxyimino) propyl} cyclopent-2-enone (Compound No. 6-076) Production was carried out in the same manner as in Synthesis Example 3 from 2- (4-bromo-2-methoxy-6-methylphenyl) -3-hydroxy-5- (2-oxopropyl) cyclopent-2-enone.

融点；１５０−１５３℃
合成例７：２−（４’−クロロ−３−メトキシ−５−メチル−[１，１’−ビフェニル]−４−イル）−３−ヒドロキシ−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノン（化合物No.6-077）の製造
２−（４−ブロモ−２−メトキシ−６−メチルフェニル）−３−ヒドロキシ−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノン １．１ｇ、４−クロロフェニルボロン酸５４０ｍｇ、１，４−ジオキサン８ｍｌ及び水２．５ｍｌの混合溶液に、リン酸三カリウム２．２ｇ、［１，１’−ビス（ジフェニルホスフィノ）フェロセン］パラジウム（ＩＩ）ジクロリド ジクロロメタン付加物２３７ｍｇを順次添加した。添加終了後、該反応容器中を窒素ガスで置換した後に、１００℃にて２時間撹拌した。反応終了後、該反応混合物に１ｍｏｌ／Ｌ塩酸水溶液を添加してｐＨ３とし、酢酸エチル１０ｍｌで抽出した。得られた有機層を、飽和食塩水次いで無水硫酸ナトリウムで脱水・乾燥後、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（８：１〜１：１のグラジエント）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物１．１ｇを橙色粘性物質として得た。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ１１．３６（ｂｒｓ，１Ｈ），７．５９−７．３４（ｍ，４Ｈ），７．０９−６．８７（ｍ，２Ｈ），４．００−３．７８（ｍ，６Ｈ），３．５４−３．３２（ｍ，１Ｈ），３．０９−２．５０ ａｎｄ ２．３８−１．８１（ｍ，１０Ｈ）。 Melting point: 150-153 ° C
Synthesis Example 7: 2- (4′-chloro-3-methoxy-5-methyl- [1,1′-biphenyl] -4-yl) -3-hydroxy-5- {2- (methoxyimino) propyl} cyclopenta Preparation of 2-enone (Compound No. 6-077) 2- (4-Bromo-2-methoxy-6-methylphenyl) -3-hydroxy-5- {2- (methoxyimino) propyl} cyclopent-2- To a mixed solution of 1.1 g of enone, 540 mg of 4-chlorophenylboronic acid, 8 ml of 1,4-dioxane and 2.5 ml of water, 2.2 g of tripotassium phosphate, [1,1′-bis (diphenylphosphino) ferrocene] 237 mg of palladium (II) dichloride dichloromethane adduct was added sequentially. After completion of the addition, the inside of the reaction vessel was replaced with nitrogen gas, followed by stirring at 100 ° C. for 2 hours. After completion of the reaction, the reaction mixture was added with 1 mol / L hydrochloric acid aqueous solution to pH 3, and extracted with 10 ml of ethyl acetate. The obtained organic layer was dehydrated and dried with saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (gradient 8: 1 to 1: 1) to obtain 1.1 g of the objective product as an orange viscous substance. It was.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 11.36 (brs, 1H), 7.59-7.34 (m, 4H), 7.09-6.87 (m, 2H), 4. 00-3.78 (m, 6H), 3.54-3.32 (m, 1H), 3.09-2.50 and 2.38-1.81 (m, 10H).

合成例８：２−（４’−クロロ−３−メトキシ−５−メチル−[１，１’−ビフェニル]−４−イル）−４−｛２−（メトキシイミノ）プロピル｝−３−オキソシクロペンタ−１−エン−１−イル モルホリン−４−カルボキシレート（化合物No.6-078）の製造
２−（４’−クロロ−３−メトキシ−５−メチル−[１，１’−ビフェニル]−４−イル）−３−ヒドロキシ−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノン７０ｍｇ及びＮ，Ｎ−ジメチルホルムアミド３ｍｌの混合溶液に、炭酸カリウム３５ｍｇ次いで４−モルホリニルカルボニルクロリド３１ｍｇを順次添加し、室温にて３時間撹拌した。反応終了後、該反応溶液に水５ｍｌを添加し、酢酸エチル５ｍｌにて抽出した。得られた有機層を水洗した後、飽和食塩水次いで無水硫酸ナトリウムで脱水・乾燥後、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（３：１〜１：１のグラジエント）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物７７ｍｇを無色油状物として得た。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．５８−７．３４（ｍ，４Ｈ），７．０３（ｓ，１Ｈ），６．９０−６．８６（ｍ，１Ｈ），３．９２−３．２２（ｍ，１５Ｈ），３．０９−２．６８（ｍ，３Ｈ），２．４０−２．１３（ｍ，４Ｈ），１．８８（ｓ，３Ｈ）。 Synthesis Example 8: 2- (4′-chloro-3-methoxy-5-methyl- [1,1′-biphenyl] -4-yl) -4- {2- (methoxyimino) propyl} -3-oxocyclo Preparation of penta-1-en-1-yl morpholine-4-carboxylate (Compound No. 6-078) 2- (4′-Chloro-3-methoxy-5-methyl- [1,1′-biphenyl]- To a mixed solution of 70 mg of 4-yl) -3-hydroxy-5- {2- (methoxyimino) propyl} cyclopent-2-enone and 3 ml of N, N-dimethylformamide, 35 mg of potassium carbonate and then 4-morpholinylcarbonyl chloride 31 mg was sequentially added, and the mixture was stirred at room temperature for 3 hours. After completion of the reaction, 5 ml of water was added to the reaction solution and extracted with 5 ml of ethyl acetate. The obtained organic layer was washed with water, dehydrated and dried with saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (3: 1 to 1: 1 gradient) to obtain 77 mg of the desired product as a colorless oil.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.58-7.34 (m, 4H), 7.03 (s, 1H), 6.90-6.86 (m, 1H), 3. 92-3.22 (m, 15H), 3.09-2.68 (m, 3H), 2.40-2.13 (m, 4H), 1.88 (s, 3H).

合成例９：３−ヒドロキシ−２−（２−メトキシ−４，６−ジメチルフェニル）−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノン（化合物No.6-037）の製造
２−（４−ブロモ−２−メトキシ−６−メチルフェニル）−３−ヒドロキシ−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノン１ｇ及びトリメチルボロキシン３２６ｍｇ及び１，４−ジオキサン２５ｍｌの混合溶液に、炭酸カリウム１．１ｇ、［１，１’−ビス（ジフェニルホスフィノ）フェロセン］パラジウム（ＩＩ）ジクロリド ジクロロメタン付加物４２４ｍｇを順次添加した。添加終了後、該反応容器中を窒素ガスで置換した後に、９０℃にて３時間撹拌した。反応終了後、該反応混合物に１ｍｏｌ／Ｌ塩酸水溶液を添加してｐＨ３とし、酢酸エチル２５ｍｌで抽出した。得られた有機層を、飽和食塩水次いで無水硫酸ナトリウムで脱水・乾燥後、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（１：１）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物４９６ｍｇを橙色粘性物質として得た。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ１１．００（ｂｒｓ，１Ｈ），６．７８−６．５３（ｍ，２Ｈ），４．０５−３．７０（ｍ，６Ｈ），３．５０−３．２８（ｍ，１Ｈ），３．００−２．５５（ｍ，３Ｈ），２．４０−１．８０（ｍ，１０Ｈ）。 Synthesis Example 9 Production of 3-hydroxy-2- (2-methoxy-4,6-dimethylphenyl) -5- {2- (methoxyimino) propyl} cyclopent-2-enone (Compound No. 6-037) 2 1 g of-(4-bromo-2-methoxy-6-methylphenyl) -3-hydroxy-5- {2- (methoxyimino) propyl} cyclopent-2-enone and 326 mg of trimethylboroxine and 25 ml of 1,4-dioxane To the mixed solution, 1.1 g of potassium carbonate and 424 mg of [1,1′-bis (diphenylphosphino) ferrocene] palladium (II) dichloride dichloromethane adduct were sequentially added. After completion of the addition, the inside of the reaction vessel was replaced with nitrogen gas, followed by stirring at 90 ° C. for 3 hours. After completion of the reaction, the reaction mixture was adjusted to pH 3 by adding 1 mol / L hydrochloric acid aqueous solution and extracted with 25 ml of ethyl acetate. The obtained organic layer was dehydrated and dried with saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (1: 1) to obtain 496 mg of the desired product as an orange viscous substance.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 11.00 (brs, 1H), 6.78-6.53 (m, 2H), 4.05-3.70 (m, 6H), 3. 50-3.28 (m, 1H), 3.00-2.55 (m, 3H), 2.40-1.80 (m, 10H).

合成例１０：３−（ベンジルオキシ）−２−メシチル−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノン及び３−（ベンジルオキシ）−２−メシチル−４−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノンの混合物（化合物No.1-009）の製造
３‐ヒドロキシ‐２‐メシチル‐５‐｛２‐（メトキシイミノ）プロピル｝シクロペンタ−２−エノン５００ｍｇ及びアセトン６ｍｌの混合溶液に、炭酸カリウム４５８ｍｇ次いでベンジルブロミド３４１ｍｇを順次添加し、室温にて１８時間撹拌した。反応終了後、該反応溶液に水２０ｍｌを添加し、酢酸エチル２０ｍｌにて抽出した。得られた有機層を水洗した後、飽和食塩水次いで無水硫酸ナトリウムで脱水・乾燥後、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（５：１〜１：１のグラジエント）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物６８０ｍｇを無色油状物として得た。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．２８−７．０３（ｍ，５Ｈ），６．９２−６．８０（ｍ，２Ｈ），４．９７−４．９２ ａｎｄ ４．７３−４．６８（ｍ，２Ｈ），３．８６−３．７７（ｍ，３Ｈ），３．３１−１．８０（ｍ，１７Ｈ）。 Synthesis Example 10: 3- (Benzyloxy) -2-mesityl-5- {2- (methoxyimino) propyl} cyclopent-2-enone and 3- (benzyloxy) -2-mesityl-4- {2- (methoxy Preparation of a mixture of (imino) propyl} cyclopent-2-enone (compound No. 1-009) 3-hydroxy-2-mesityl-5- {2- (methoxyimino) propyl} cyclopent-2-enone 500 mg and acetone 6 ml To the mixed solution, 458 mg of potassium carbonate and then 341 mg of benzyl bromide were sequentially added and stirred at room temperature for 18 hours. After completion of the reaction, 20 ml of water was added to the reaction solution and extracted with 20 ml of ethyl acetate. The obtained organic layer was washed with water, dehydrated and dried with saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (gradient 5: 1 to 1: 1) to obtain 680 mg of the desired product as a colorless oil.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.28-7.03 (m, 5H), 6.92-6.80 (m, 2H), 4.97-4.92 and 4.73 -4.68 (m, 2H), 3.86-3.77 (m, 3H), 3.31-1.80 (m, 17H).

得られた目的物は、１−００９ａ−１、１−００９ａ−２、１−００９ｂ−１及び１−００９ｂ−２の混合物であり、その混合比は１６：３：８：１であった。混合比は、高速液体クロマトグラフィー［移動相；｛（アセトニトリル：水＝４：１）＋体積比１％酢酸｝、測定波長；２５４ｎｍ］による定性分析によって決定した。尚、１−００９ａ−１、１−００９ａ−２、１−００９ｂ−１及び１−００９ｂ−２の構造は下記の通りである。   The obtained target product was a mixture of 1-009a-1, 1-009a-2, 1-009b-1 and 1-009b-2, and the mixing ratio was 16: 3: 8: 1. The mixing ratio was determined by qualitative analysis by high performance liquid chromatography [mobile phase; {(acetonitrile: water = 4: 1) + volume ratio 1% acetic acid}, measurement wavelength; 254 nm]. The structures of 1-009a-1, 1-009a-2, 1-009b-1 and 1-009b-2 are as follows.

合成例１１：３−（ベンジルオキシ）−２−メシチル−５−｛２−（メトキシイミノ）プロピル｝−５−メチルシクロペンタ−２−エノン（化合物No.11-001）及び３−（ベンジルオキシ）−２−メシチル−４−｛２−（メトキシイミノ）プロピル｝−５−メチルシクロペンタ−２−エノン（化合物No.12-001）の製造
３−（ベンジルオキシ）−２−メシチル−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノン及び３−（ベンジルオキシ）−２−メシチル−４−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エノンの混合物（化合物No.1-009）６１１ｍｇ及びテトラヒドロフラン７ｍｌの混合溶液を、窒素雰囲気下、−７８℃まで冷却した後、該混合溶液にリチウムジイソプロピルアミド（約１．５ｍｏｌ／Ｌ ｎ−ヘキサン及びテトラヒドロフランの混合溶液、関東化学社製）１．７ｍｌを滴下した。滴下終了後、該反応混合物を同温度にて３０分間撹拌した。撹拌終了後、該反応混合物に、ヨードメタン２４４ｍｇを添加した。添加終了後、該反応混合物を室温まで昇温し、同温度にて３０分間撹拌した。反応終了後、該反応混合物を氷水３０ｍｌに添加し、酢酸エチル２０ｍｌにて抽出した。得られた有機層を水洗、無水硫酸ナトリウムにて脱水・乾燥後、減圧下にて溶媒を留去した。得られた残留物をアセトニトリル−水[４：１（体積比）]にて溶出する高速液体クロマトグラフィーにて精製し、化合物No.11-001 １７３ｍｇを無色油状物として、化合物No.12-001 ８６ｍｇを無色油状物として各々得た。
化合物No.11-001：^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．３９−７．１２（ｍ，５Ｈ），６．８６（ｂｒｓ，２Ｈ），４．９６（ｓ，２Ｈ），３．８１（ｓ，３Ｈ），３．２７−３．１３（ｍ，１Ｈ），２．６１−２．２２（ｍ，６Ｈ），２．０６（ｂｒｓ，６Ｈ），１．８７−１．７７（ｍ，３Ｈ），１．２６（ｓ，３Ｈ）。
化合物No.12-001：^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．３７−７．２５（ｍ，３Ｈ），７．１４−７．０４（ｍ，２Ｈ），６．８６（ｂｒｓ，２Ｈ），４．７１（ｓ，２Ｈ），３．８３（ｓ，３Ｈ），２．８８−２．７７（ｍ，２Ｈ），２．４７−２．２３（ｍ，５Ｈ），２．１５−２．０２（ｍ，６Ｈ），１．８８（ｓ，３Ｈ），１．３７−１．２２（ｍ，３Ｈ）。 Synthesis Example 11: 3- (benzyloxy) -2-mesityl-5- {2- (methoxyimino) propyl} -5-methylcyclopent-2-enone (Compound No. 11-001) and 3- (benzyloxy) ) -2-Mesityl-4- {2- (methoxyimino) propyl} -5-methylcyclopent-2-enone (Compound No. 12-001) 3- (Benzyloxy) -2-mesityl-5 A mixture of {2- (methoxyimino) propyl} cyclopent-2-enone and 3- (benzyloxy) -2-mesityl-4- {2- (methoxyimino) propyl} cyclopent-2-enone (Compound No. 1- [009] After cooling a mixed solution of 611 mg and 7 ml of tetrahydrofuran to -78 ° C under a nitrogen atmosphere, lithium diisopropylamide (about 1.5 mol / L n-hexa was added to the mixed solution. 1.7 ml of a mixed solution of ethanol and tetrahydrofuran, manufactured by Kanto Chemical Co., Ltd. was added dropwise. After completion of the dropwise addition, the reaction mixture was stirred at the same temperature for 30 minutes. After completion of the stirring, 244 mg of iodomethane was added to the reaction mixture. After completion of the addition, the reaction mixture was warmed to room temperature and stirred at the same temperature for 30 minutes. After completion of the reaction, the reaction mixture was added to 30 ml of ice water and extracted with 20 ml of ethyl acetate. The obtained organic layer was washed with water, dehydrated and dried over anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by high performance liquid chromatography eluting with acetonitrile-water [4: 1 (volume ratio)] to give 173 mg of Compound No. 11-001 as a colorless oil, and to Compound No. 12-001. 86 mg of each was obtained as a colorless oil.
Compound No. 11-001: ¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.39-7.12 (m, 5H), 6.86 (brs, 2H), 4.96 (s, 2H) , 3.81 (s, 3H), 3.27-3.13 (m, 1H), 2.61-2.22 (m, 6H), 2.06 (brs, 6H), 1.87-1 .77 (m, 3H), 1.26 (s, 3H).
Compound No. 12-001: ¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.37-7.25 (m, 3H), 7.14-7.04 (m, 2H), 6.86 ( brs, 2H), 4.71 (s, 2H), 3.83 (s, 3H), 2.88-2.77 (m, 2H), 2.47-2.23 (m, 5H), 2 15-2.02 (m, 6H), 1.88 (s, 3H), 1.37-1.22 (m, 3H).

合成例１２：２−（２−メトキシ−４，６−ジメチルフェニル）−４−｛２−（メトキシイミノ）プロピル｝−３−オキソシクロペンタ−１−エン−１−イル モルホリン−４−カルボキシレート［化合物No.6-094及び化合物No.6-094(*2)］の製造法
３−ヒドロキシ−２−（２−メトキシ−４，６−ジメチルフェニル）−５−｛２−（メトキシイミノ）プロピル｝シクロペンタ−２−エン−１−オン２２ｇを原料として用い、合成例８と同様の方法により合成し、得られた残留物をｎ−ヘキサン−酢酸エチル（９：１〜１：１のグラジエント）にて溶出する中圧分取液体クロマトグラフィーにて精製し、化合物No.6-094 ２５８ｍｇを薄黄色油状物として、化合物No.6-094(*2) １７ｇを薄黄色油状物として得た。高速液体クロマトグラフィーによる定性分析を、前記測定条件にて測定した結果、化合物No.6-094の保持時間は４．６５分であり、化合物No.6-094(*2)の保持時間は４．８８分であった。
化合物No.6-094：^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ６．６６（ｂｒｓ，１Ｈ），６．５７−６．５２（ｍ，１Ｈ），３．８５ ａｎｄ ３．８４（ｓ，３Ｈ），３．７３−３．２７（ｍ，１３Ｈ），３．０９−２．７７（ｍ，３Ｈ），２．３９−２．２０（ｍ，３Ｈ），２．１２−２．０４（ｍ，３Ｈ），１．８６（ｓ，３Ｈ）。
化合物No.6-094(*2)：^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ６．７０−６．６３（ｍ，１Ｈ），６．５７−６．５０（ｍ，１Ｈ），３．８９−３．８１（ｍ，３Ｈ），３．７４−３．２５（ｍ，１２Ｈ），３．０８−２．７７（ｍ，３Ｈ），２．３８−２．１６（ｍ，４Ｈ），２．１２−２．０３（ｍ，３Ｈ），１．９４−１．８４（ｍ，３Ｈ）。 Synthesis Example 12 2- (2-methoxy-4,6-dimethylphenyl) -4- {2- (methoxyimino) propyl} -3-oxocyclopent-1-en-1-yl morpholine-4-carboxylate Production Method of [Compound No. 6-094 and Compound No. 6-094 (* 2)] 3-Hydroxy-2- (2-methoxy-4,6-dimethylphenyl) -5- {2- (methoxyimino) Propyl} cyclopent-2-en-1-one (22 g) was used as a starting material and synthesized in the same manner as in Synthesis Example 8. The obtained residue was diluted with n-hexane-ethyl acetate (gradient of 9: 1 to 1: 1). ) To obtain 258 mg of compound No. 6-094 as a pale yellow oil and 17 g of compound No. 6-094 (* 2) as a pale yellow oil. . As a result of qualitative analysis by high performance liquid chromatography under the above measurement conditions, the retention time of Compound No. 6-094 was 4.65 minutes, and the retention time of Compound No. 6-094 (* 2) was 4. .88 minutes.
Compound No. 6-094: ¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 6.66 (brs, 1H), 6.57-6.52 (m, 1H), 3.85 and 3.84 ( s, 3H), 3.73-3.27 (m, 13H), 3.09-2.77 (m, 3H), 2.39-2.20 (m, 3H), 2.12-2. 04 (m, 3H), 1.86 (s, 3H).
Compound No. 6-094 (* 2): ¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 6.70-6.63 (m, 1H), 6.57-6.50 (m, 1H), 3.89-3.81 (m, 3H), 3.74-3.25 (m, 12H), 3.08-2.77 (m, 3H), 2.38-2.16 (m, 4H) ), 2.12-2.03 (m, 3H), 1.94-1.84 (m, 3H).

本発明化合物を製造するための製造中間体の合成例を、以下に反応例１〜反応例６として具体的に述べるが、本発明の製造中間体はこれらのみに限定されるものではない。   Synthesis examples of production intermediates for producing the compounds of the present invention are specifically described below as Reaction Examples 1 to 6, but the production intermediates of the present invention are not limited to these.

反応例１：２−（２，６−ジメトキシ−４−メチルフェニル）シクロペンタ−４−エン−１，３−ジオンの製造
工程１：(２，６−ジメトキシ−４−メチルフェニル)（フラン−２−イル）メタノールの製造
フラン０．６９ｇ及びテトラヒドロフラン１０ｍｌの混合溶液を、窒素雰囲気下で−１０℃に冷却した。該混合溶液にｎ−ブチルリチウム（１．６Ｍテトラヒドロフラン溶液）６．９ｍｌを添加し、同温度にて１時間３０分撹拌した。該反応溶液に２，６−ジメトキシ−４−メチルベンズアルデヒド２．０ｇ及びテトラヒドロフラン１０ｍｌの混合溶液を、−１０℃にて添加した後、該反応溶液を室温まで昇温し、１２時間撹拌した。反応終了後、該反応溶液を氷水に注ぎ、酢酸エチル２０ｍｌにて抽出した。得られた有機層を、飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（３：１）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物１．８９ｇを黄白色固体として得た。
融点；７５−８５℃
工程２：２−（２，６−ジメトキシ−４−メチルフェニル）シクロペンタ−４−エン−１，３−ジオンの製造
(２，６−ジメトキシ−４−メチルフェニル)（フラン−２−イル）メタノール１００ｍｇ及び水１ｍｌの混合溶液を、マイクロ波合成装置を用いてマイクロ波（２００Ｗ）を照射し、２００℃にて３０分間撹拌した。反応終了後、該反応溶液を酢酸エチル３ｍｌにて抽出し、得られた有機層を無水硫酸ナトリウムで乾燥し、減圧下にて溶媒を留去した。得られた残留物にジクロロメタン５ｍｌ、クロロクロム酸ピリジニウム０．１３ｇを順次添加し、添加終了後室温にて２時間撹拌した。反応終了後、該反応溶液にイソプロピルアルコール５ｍｌを添加した後、減圧下にて溶媒を留去した。得られた残留物に水１０ｍｌを添加し、酢酸エチル１０ｍｌにて抽出した。得られた有機層を飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（２：１）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物２０ｍｇを黄色固体として得た。
融点：１２２−１２６℃
反応例２：２−（２−メトキシ−４，６−ジメチルフェニル）シクロペンタ−４−エン−１，３−ジオンの製造
ジャーナル オブ ジ アメリカン ケミカル ソサェティー ２０００年，１２２巻，５０４３頁記載の方法により合成した２−メトキシ−４，６−ジメチルアニリン１０．０ｇを原料として用い、合成例５の工程１〜工程４と同様の方法により、２−（２−メトキシ−４，６−ジメチルフェニル）シクロペンタ−４−エン−１，３−ジオン０．２ｇを黄色固体として得た。
融点；１２３−１２５℃
尚、合成例５の工程２と同様の方法により製造した、フラン−２−イル（２−メトキシ−４，６−ジメチルフェニル）メタノールのプロトン核磁気共鳴スペクトラムの測定データは下記の通りである。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．３７−７．３３（ｍ，１Ｈ），６．６８−６．５７（ｍ，２Ｈ），６．２８−６．２５（ｍ，１Ｈ），６．００−５．９２（ｍ，２Ｈ），４．４７（ｄ，Ｊ＝１０．８Ｈｚ，１Ｈ），３．８１（ｓ，３Ｈ），２．３１（ｓ，３Ｈ），２．２９（ｓ，３Ｈ）．
また、合成例５の工程３と同様の方法により製造した、４−ヒドロキシ−５−（２−メトキシ−４，６−ジメチルフェニル）シクロペンタ−２−エン−１−オンのプロトン核磁気共鳴スペクトラムの測定データは下記の通りである。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．５０−７．４２（ｍ，１Ｈ），６．６７（ｂｒｓ，１Ｈ），６．５２（ｂｒｓ，１Ｈ），６．３５−６．２７（ｍ，１Ｈ），５．０６（ｂｒｓ，１Ｈ），３．６０（ｓ，３Ｈ），３．５８−３．５２（ｍ，１Ｈ），２．３４（ｓ，３Ｈ），２．２９（ｓ，３Ｈ）．
反応例３：２−（２−クロロ−４，６−ジメチルフェニル）シクロペンタ−４−エン−１，３−ジオンの製造
２−クロロ−４，６−ジメチルアニリン１０．０ｇを原料として用い、合成例５の工程１〜工程４と同様の方法により、２−（２−クロロ−４，６−ジメチルフェニル）シクロペンタ−４−エン−１，３−ジオン１．５ｇを薄黄色固体として得た。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．４０−７．３０（ｍ，２Ｈ），７．００−６．９５（ｍ，２Ｈ），４．３０−４．２３（ｍ，１Ｈ），２．３６（ｓ，３Ｈ），２．２７（ｓ，３Ｈ）。 Reaction Example 1: Production of 2- (2,6-dimethoxy-4-methylphenyl) cyclopent-4-ene-1,3-dione Step 1: (2,6-dimethoxy-4-methylphenyl) (furan-2 -Il) Production of methanol A mixed solution of furan (0.69 g) and tetrahydrofuran (10 ml) was cooled to -10 ° C under a nitrogen atmosphere. To the mixed solution, 6.9 ml of n-butyllithium (1.6M tetrahydrofuran solution) was added, and the mixture was stirred at the same temperature for 1 hour and 30 minutes. A mixed solution of 2.0 g of 2,6-dimethoxy-4-methylbenzaldehyde and 10 ml of tetrahydrofuran was added to the reaction solution at −10 ° C., and then the reaction solution was warmed to room temperature and stirred for 12 hours. After completion of the reaction, the reaction solution was poured into ice water and extracted with 20 ml of ethyl acetate. The obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (3: 1) to obtain 1.89 g of the desired product as a pale yellow solid.
Melting point: 75-85 ° C
Step 2: Production of 2- (2,6-dimethoxy-4-methylphenyl) cyclopent-4-ene-1,3-dione
A mixed solution of 100 mg of (2,6-dimethoxy-4-methylphenyl) (furan-2-yl) methanol and 1 ml of water was irradiated with microwaves (200 W) using a microwave synthesizer, and 30 ° C. at 30 ° C. Stir for minutes. After completion of the reaction, the reaction solution was extracted with 3 ml of ethyl acetate, the resulting organic layer was dried over anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. To the obtained residue, 5 ml of dichloromethane and 0.13 g of pyridinium chlorochromate were sequentially added, and the mixture was stirred at room temperature for 2 hours. After completion of the reaction, 5 ml of isopropyl alcohol was added to the reaction solution, and then the solvent was distilled off under reduced pressure. 10 ml of water was added to the obtained residue, and the mixture was extracted with 10 ml of ethyl acetate. The obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (2: 1) to obtain 20 mg of the objective product as a yellow solid.
Melting point: 122-126 ° C
Reaction Example 2: Production of 2- (2-methoxy-4,6-dimethylphenyl) cyclopent-4-ene-1,3-dione Synthesis by the method described in Journal of the American Chemical Society 2000, 122, 5043 By using the same 2-methoxy-4,6-dimethylaniline 10.0 g as a raw material in the same manner as in Step 1 to Step 4 of Synthesis Example 5, 2- (2-methoxy-4,6-dimethylphenyl) cyclopenta- 0.2 g of 4-ene-1,3-dione was obtained as a yellow solid.
Melting point: 123-125 ° C
The measurement data of the proton nuclear magnetic resonance spectrum of furan-2-yl (2-methoxy-4,6-dimethylphenyl) methanol produced by the same method as in Step 2 of Synthesis Example 5 is as follows.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.37-7.33 (m, 1H), 6.68-6.57 (m, 2H), 6.28-6.25 (m, 1H) ), 6.00-5.92 (m, 2H), 4.47 (d, J = 10.8 Hz, 1H), 3.81 (s, 3H), 2.31 (s, 3H), 2. 29 (s, 3H).
Further, the proton nuclear magnetic resonance spectrum of 4-hydroxy-5- (2-methoxy-4,6-dimethylphenyl) cyclopent-2-en-1-one produced by the same method as in Step 3 of Synthesis Example 5 was obtained. The measurement data is as follows.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.50-7.42 (m, 1H), 6.67 (brs, 1H), 6.52 (brs, 1H), 6.35-6. 27 (m, 1H), 5.06 (brs, 1H), 3.60 (s, 3H), 3.58-3.52 (m, 1H), 2.34 (s, 3H), 2.29 (S, 3H).
Reaction Example 3: Production of 2- (2-chloro-4,6-dimethylphenyl) cyclopent-4-ene-1,3-dione Synthesis using 10.0 g of 2-chloro-4,6-dimethylaniline as a raw material In the same manner as in Step 1 to Step 4 of Example 5, 1.5 g of 2- (2-chloro-4,6-dimethylphenyl) cyclopent-4-ene-1,3-dione was obtained as a pale yellow solid.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.40-7.30 (m, 2H), 7.00-6.95 (m, 2H), 4.30-4.23 (m, 1H ), 2.36 (s, 3H), 2.27 (s, 3H).

尚、合成例５の工程２と同様の方法により製造した、（２−クロロ−４，６−ジメチルフェニル）（フラン−２−イル）メタノールのプロトン核磁気共鳴スペクトラムの測定データは下記の通りである。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．４０−７．３５（ｍ，１Ｈ），７．０８−７．０２（ｍ，１Ｈ），６．９５−６．８８（ｍ，１Ｈ），６．４５−６．３８（ｍ，１Ｈ），６．３５−６．３０（ｍ，１Ｈ），６．１０−６．０４（ｍ，１Ｈ），２．９８−２．９２（ｍ，１Ｈ），２．３７（ｓ，３Ｈ），２．２９（ｓ，３Ｈ）。 The measurement data of the proton nuclear magnetic resonance spectrum of (2-chloro-4,6-dimethylphenyl) (furan-2-yl) methanol produced by the same method as in Step 2 of Synthesis Example 5 is as follows. is there.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.40-7.35 (m, 1H), 7.08-7.02 (m, 1H), 6.95-6.88 (m, 1H) ), 6.45-6.38 (m, 1H), 6.35-6.30 (m, 1H), 6.10-6.04 (m, 1H), 2.98-2.92 (m , 1H), 2.37 (s, 3H), 2.29 (s, 3H).

また、合成例５の工程３と同様の方法により製造した、５−（２−クロロ−４，６−ジメチルフェニル）−４−ヒドロキシシクロペンタ−２−エン−１−オンのプロトン核磁気共鳴スペクトラムの測定データは下記の通りである。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．６２−７．４５（ｍ，１Ｈ），７．１４−６．８２（ｍ，２Ｈ），６．４２−６．１５（ｍ，１Ｈ），５．３２−４．７７（ｍ，１Ｈ），４．４５−３．７３（ｍ，１Ｈ），２．５５−１．９０（ｍ，６Ｈ）(OHに相当するシグナルは検出されなかった)。 In addition, the proton nuclear magnetic resonance spectrum of 5- (2-chloro-4,6-dimethylphenyl) -4-hydroxycyclopent-2-en-1-one produced by the same method as in Step 3 of Synthesis Example 5 The measurement data is as follows.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.62-7.45 (m, 1H), 7.14-6.82 (m, 2H), 6.42-6.15 (m, 1H ), 5.32-4.77 (m, 1H), 4.45-3.73 (m, 1H), 2.55-1.90 (m, 6H) (the signal corresponding to OH was not detected. )

反応例４：４−ヒドロキシ−５−（２−メトキシ−４，６−ジメチルフェニル）シクロペンタ−２−エン−１−オンの製造
工程１：２−｛フラン−２−イル（ヒドロキシ）メチル｝−３，５−ジメチルフェノールの製造
３，５−ジメチルフェノール１．０ｇ及びテトラヒドロフラン２５ｍｌの混合溶液に、氷冷下にてフルフラール１．６ｇ及び塩化マグネシウム（無水）１．２ｇを順次添加し、３０分間撹拌した。引き続き、該反応溶液にトリエチルアミン１．７ｇを添加し、溶媒の還流温度にて２時間撹拌した。反応終了後、該反応溶液の溶媒を減圧下にて留去した。得られた残留物に、１ｍｏｌ／Ｌ塩酸を添加してｐＨ１とした後、酢酸エチル３０ｍｌにて抽出した。得られた有機層を飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（５：１）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物０．５５ｇを白色固体として得た。
融点；９４−９６℃
工程２：フラン−２−イル（２−メトキシ−４，６−ジメチルフェニル）メタノールの製造
２−｛フラン−２−イル（ヒドロキシ）メチル｝−３，５−ジメチルフェノール０．３ｇ及びアセトン５ｍｌの混合溶液に、炭酸カリウム０．４５ｇ及び硫酸ジメチル０．２１ｇを順次添加し、室温にて３時間撹拌した。反応終了後、該反応溶液に飽和塩化アンモニウム水溶液１０ｍｌを添加した後、酢酸エチル１５ｍｌにて抽出した。得られた有機層を飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（１０：１）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物０．３７ｇを薄黄色粘性物質として得た。
^１Ｈ ＮＭＲ（ＣＤＣｌ_３，Ｍｅ_４Ｓｉ，３００ＭＨｚ）δ７．３７−７．３３（ｍ，１Ｈ），６．６８−６．５７（ｍ，２Ｈ），６．２８−６．２５（ｍ，１Ｈ），６．００−５．９２（ｍ，２Ｈ），４．４７（ｄ，Ｊ＝１０．８Ｈｚ，１Ｈ），３．８１（ｓ，３Ｈ），２．３１（ｓ，３Ｈ），２．２９（ｓ，３Ｈ）．
工程３：４−ヒドロキシ−５−（２−メトキシ−４，６−ジメチルフェニル）シクロペンタ−２−エン−１−オンの製造
フラン−２−イル（２−メトキシ−４，６−ジメチルフェニル）メタノール５ｇ、１，４−ジオキサン１３０ｍｌ及び水８０ｍｌの混合溶液に、塩化亜鉛１１ｇ及び１ｍｏｌ／Ｌ塩酸０．１ｍｌを添加し、溶媒の還流温度にて１時間撹拌した。反応終了後、該反応溶液の溶媒を減圧下にて留去した。得られた残留物に飽和炭酸水素ナトリウム水溶液１００ｍｌを添加した後、酢酸エチル１００ｍｌにて抽出した。得られた有機層を飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去し、目的物４．５ｇを薄茶色固体として得た。
融点；１２２−１２５℃
反応例５：２−（２−メトキシ−４，６−ジメチルフェニル）シクロペンタ−４−エン−１，３−ジオンの製造
４−ヒドロキシ−５−（２−メトキシ−４，６−ジメチルフェニル）シクロペンタ−２−エン−１−オン０．５ｇ及び１，２−ジクロロエタン１０ｍｌの混合溶液に、ジメチルスルホキシド１．５ｍｌ、トリエチルアミン０．６５ｇ及び三酸化硫黄−ピリジン錯体０．５１ｇを順次添加し、室温にて１８時間撹拌した。反応終了後、該反応溶液に１ｍｏｌ／Ｌ塩酸を１５ｍｌ添加し、１ｍｏｌ／Ｌ塩酸で２回洗浄した。得られた有機層を、飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、酢酸エチルにて溶出するショートカラムにて原点成分を除去し、減圧下にて溶媒を留去した。得られた固体をｎ−ヘキサンにて洗浄し、目的物０．３９ｇを黄色固体として得た。
融点；９８−１０５℃
反応例６：２−（２−メトキシ−４，６−ジメチルフェニル）シクロペンタ−４−エン−１，３−ジオンの製造
４−ヒドロキシ−５−（２−メトキシ−４，６−ジメチルフェニル）シクロペンタ−２−エン−１−オン０．１ｇ及びジメチルスルホキシド３ｍｌの混合溶液に、無水酢酸１ｍｌを添加し、室温にて２０時間撹拌した。反応終了後、該反応溶液に飽和塩化アンモニウム水溶液２０ｍｌ、水１０ｍｌを添加し、酢酸エチル２０ｍｌで２回抽出した。得られた有機層を、飽和食塩水次いで無水硫酸ナトリウムの順で脱水・乾燥し、減圧下にて溶媒を留去した。得られた残留物をｎ−ヘキサン−酢酸エチル（３：１〜１：２のグラジエント）にて溶出する中圧分取液体クロマトグラフィーにて精製し、目的物６２ｍｇを黄色固体として得た。
融点；１０２−１０６℃
本発明化合物は、前記製造例に準じて合成することができる。合成例１〜合成例１２同様に製造した本発明化合物の例を第２表〜第１９表に示すが、本発明はこれらのみに限定されるものではない。尚、表中Ｍｅとの記載はメチル基を表し、以下、Ｅｔとの記載はエチル基を表し、ｎ−Ｐｒ及びＰｒ−ｎはノルマルプロピル基を、ｉ−Ｐｒ及びＰｒ−ｉはイソプロピル基を、ｃ−Ｐｒ及びＰｒ−ｃはシクロプロピル基を、ｎ−Ｂｕ及びＢｕ−ｎはノルマルブチル基を、ｓ−Ｂｕ及びＢｕ−ｓはセカンダリーブチル基を、ｉ−Ｂｕ及びＢｕ−ｉはイソブチル基を、ｔ−Ｂｕ及びＢｕ−ｔはターシャリーブチル基を、ｃ−Ｂｕ及びＢｕ−ｃはシクロブチル基を、ｎ−Ｐｅｎ及びＰｅｎ−ｎはノルマルペンチル基を、ｃ−Ｐｅｎ及びＰｅｎ−ｃはシクロペンチル基を、ｎ−Ｈｅｘ及びＨｅｘ−ｎはノルマルヘキシル基を、ｃ−Ｈｅｘ及びＨｅｘ−ｃはシクロヘキシル基を、ｎ−Ｈｅｐｔ及びＨｅｐｔ−ｎはノルマルヘプチル基を、ｎ−Ｏｃｔ及びＯｃｔ−ｎはオクチル基を、Ｐｈはフェニル基をそれぞれ表し、Ｄ１−１ａ、Ｄ１−２ｃ、Ｄ１−５ｄ、Ｄ１−５ｅ、Ｄ１−６ｄ、Ｄ１−７ａ、Ｄ１−７ｂ、Ｄ１−８ｂ、Ｄ１−８ｃ、Ｄ１−８ｄ、Ｄ１−１０ｄ、Ｄ１−１０ｅ、Ｄ１−１１ａ、Ｄ１−２２ａ、Ｄ１−３２ａ、Ｄ１−３２ｂ、Ｄ１−３３ａ、Ｄ１−３３ｂ、Ｄ１−３４ａ、Ｄ１−３７ａ、Ｄ１−８１ａ、Ｄ１−８１ｂ、Ｄ１−８４ａ、Ｄ１−１０３ａ、Ｄ１−１０３ｂ、Ｄ１−１０３ｃ、Ｄ１−１０３ｄ、Ｄ１−１０３ｅ、Ｄ１−１０３ｆ、Ｄ１−１０３ｇ、Ｄ１−１０３ｈ、Ｄ１−１０３ｉ、Ｄ１−１０３ｊ、Ｄ１−１０３ｋ、Ｄ１−１０３ｌ、Ｄ１−１０３ｍ、Ｄ１−１０３ｎ、Ｄ１−１０３ｏ、Ｄ１−１０３ｐ、Ｄ１−１０３ｑ、Ｄ１−１０３ｒ、Ｄ１−１０３ｓ、Ｄ１−１０３ｔ、Ｄ１−１０３ｘ、Ｄ１−１０３ｙ、Ｄ１−１０３ｚ、Ｄ１−１０４ａ、Ｄ１−１０４ｂ、Ｄ１−１０８ｂ、Ｄ１−１０８ｃ、Ｄ１−１０８ｄ、Ｄ１−１０８ｅで表される構造は下記の構造を表し、Ｄ１−５ｄ、Ｄ１−５ｅ、Ｄ１−６ｄ、Ｄ１−７ｂ、Ｄ１−１０ｄ、Ｄ１−１０ｅ、Ｄ１−３２ｂ、Ｄ１−３３ｂの構造式に記された番号は、Ｘ^１の置換位置を表し、Ｄ１−１０８ｂの構造式に記された番号は、Ｚ^３の置換位置を表し、Ｄ１−１０８ｃの構造式に記された番号は、Ｚ^１の置換位置を表し、Ｄ１−１０３ｑ、Ｄ１−１０３ｚ、Ｄ１−１０８ｄの構造式に記された番号は、Ｚ^２の置換位置を表す。 Reaction Example 4: Production of 4-hydroxy-5- (2-methoxy-4,6-dimethylphenyl) cyclopent-2-en-1-one Step 1: 2- {furan-2-yl (hydroxy) methyl}- Production of 3,5-dimethylphenol To a mixed solution of 1.0 g of 3,5-dimethylphenol and 25 ml of tetrahydrofuran, 1.6 g of furfural and 1.2 g of magnesium chloride (anhydrous) were sequentially added under ice-cooling for 30 minutes. Stir. Subsequently, 1.7 g of triethylamine was added to the reaction solution, and the mixture was stirred at the reflux temperature of the solvent for 2 hours. After completion of the reaction, the solvent of the reaction solution was distilled off under reduced pressure. The obtained residue was adjusted to pH 1 by adding 1 mol / L hydrochloric acid, and extracted with 30 ml of ethyl acetate. The obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (5: 1) to obtain 0.55 g of the desired product as a white solid.
Melting point: 94-96 ° C
Step 2: Production of furan-2-yl (2-methoxy-4,6-dimethylphenyl) methanol 0.3 g of 2- {furan-2-yl (hydroxy) methyl} -3,5-dimethylphenol and 5 ml of acetone To the mixed solution, 0.45 g of potassium carbonate and 0.21 g of dimethyl sulfate were sequentially added, and the mixture was stirred at room temperature for 3 hours. After completion of the reaction, 10 ml of a saturated aqueous ammonium chloride solution was added to the reaction solution, followed by extraction with 15 ml of ethyl acetate. The obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (10: 1) to obtain 0.37 g of the desired product as a pale yellow viscous substance.
¹ H NMR (CDCl ₃ , Me ₄ Si, 300 MHz) δ 7.37-7.33 (m, 1H), 6.68-6.57 (m, 2H), 6.28-6.25 (m, 1H) ), 6.00-5.92 (m, 2H), 4.47 (d, J = 10.8 Hz, 1H), 3.81 (s, 3H), 2.31 (s, 3H), 2. 29 (s, 3H).
Step 3: Preparation of 4-hydroxy-5- (2-methoxy-4,6-dimethylphenyl) cyclopent-2-en-1-one Furan-2-yl (2-methoxy-4,6-dimethylphenyl) methanol To a mixed solution of 5 g, 130 ml of 1,4-dioxane and 80 ml of water, 11 g of zinc chloride and 0.1 ml of 1 mol / L hydrochloric acid were added and stirred for 1 hour at the reflux temperature of the solvent. After completion of the reaction, the solvent of the reaction solution was distilled off under reduced pressure. To the obtained residue was added 100 ml of saturated aqueous sodium hydrogen carbonate solution, and the mixture was extracted with 100 ml of ethyl acetate. The obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure to obtain 4.5 g of the objective product as a light brown solid.
Melting point: 122-125 ° C
Reaction Example 5: Preparation of 2- (2-methoxy-4,6-dimethylphenyl) cyclopent-4-ene-1,3-dione 4-hydroxy-5- (2-methoxy-4,6-dimethylphenyl) cyclopenta To a mixed solution of 0.5 g of 2-en-1-one and 10 ml of 1,2-dichloroethane, 1.5 ml of dimethyl sulfoxide, 0.65 g of triethylamine and 0.51 g of sulfur trioxide-pyridine complex were sequentially added to room temperature. And stirred for 18 hours. After completion of the reaction, 15 ml of 1 mol / L hydrochloric acid was added to the reaction solution and washed twice with 1 mol / L hydrochloric acid. The obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, the origin component was removed with a short column eluting with ethyl acetate, and the solvent was distilled off under reduced pressure. The obtained solid was washed with n-hexane to obtain 0.39 g of the desired product as a yellow solid.
Melting point: 98-105 ° C
Reaction Example 6: Preparation of 2- (2-methoxy-4,6-dimethylphenyl) cyclopent-4-ene-1,3-dione 4-hydroxy-5- (2-methoxy-4,6-dimethylphenyl) cyclopenta To a mixed solution of 0.1 g of 2-en-1-one and 3 ml of dimethyl sulfoxide, 1 ml of acetic anhydride was added and stirred at room temperature for 20 hours. After completion of the reaction, 20 ml of a saturated aqueous ammonium chloride solution and 10 ml of water were added to the reaction solution, and extracted twice with 20 ml of ethyl acetate. The obtained organic layer was dehydrated and dried in the order of saturated brine and then anhydrous sodium sulfate, and the solvent was distilled off under reduced pressure. The obtained residue was purified by medium pressure preparative liquid chromatography eluting with n-hexane-ethyl acetate (gradient 3: 1 to 1: 2) to obtain 62 mg of the desired product as a yellow solid.
Melting point: 102-106 ° C
The compound of the present invention can be synthesized according to the above production examples. Although the example of this invention compound manufactured similarly to the synthesis example 1-the synthesis example 12 is shown in Table 2-Table 19, this invention is not limited only to these. In the table, the description of Me represents a methyl group, the description of Et represents an ethyl group, n-Pr and Pr-n represent normal propyl groups, i-Pr and Pr-i represent isopropyl groups. , C-Pr and Pr-c are cyclopropyl groups, n-Bu and Bu-n are normal butyl groups, s-Bu and Bu-s are secondary butyl groups, and i-Bu and Bu-i are isobutyl groups. T-Bu and Bu-t are tertiary butyl groups, c-Bu and Bu-c are cyclobutyl groups, n-Pen and Pen-n are normal pentyl groups, and c-Pen and Pen-c are cyclopentyl groups. N-Hex and Hex-n are normal hexyl groups, c-Hex and Hex-c are cyclohexyl groups, n-Hept and Hept-n are normal heptyl groups, n-Oct and ct-n represents an octyl group, Ph represents a phenyl group, and D1-1a, D1-2c, D1-5d, D1-5e, D1-6d, D1-7a, D1-7b, D1-8b, D1- 8c, D1-8d, D1-10d, D1-10e, D1-11a, D1-22a, D1-32a, D1-32b, D1-33a, D1-33b, D1-34a, D1-37a, D1-81a, D1-81b, D1-84a, D1-103a, D1-103b, D1-103c, D1-103d, D1-103e, D1-103f, D1-103g, D1-103h, D1-103i, D1-103j, D1- 103k, D1-103l, D1-103m, D1-103n, D1-103o, D1-103p, D1-103q, D1-103r, D1-103s, D -103t, D1-103x, D1-103y, D1-103z, D1-104a, D1-104b, D1-108b, D1-108c, D1-108d, D1-108e represent the following structures, D1-5d, represents D1-5e, D1-6d, D1-7b, D1-10d, D1-10e, D1-32b, structure number marked on the type D1-33b is the substitution position of ^{X 1,} D1 number marked on the structural formula of -108b represents the substitution position of ^{Z 3,} numbers written in the structural formula of D1-108c represents the substitution position of ^{Z 1,} D1-103q, D1-103z, D1 The number given in the structural formula of −108d represents the substitution position of Z ² .

また表中、「m.p.」の記載は「融点」を表し、「*1」の記載は「樹脂状」を表し、「decomp.」の記載は分解をそれぞれ意味する。   In the table, “m.p.” represents “melting point”, “* 1” represents “resinous”, and “decomp.” Represents decomposition.

表中、化合物No.に記載した「*2」は、オキシム構造に由来する幾何異性体を表し、例えば「6-094(*2)」との記載は、化合物No.6-094(*2)が化合物No.6-094の幾何異性体であることを表す。   In the table, “* 2” described in Compound No. represents a geometric isomer derived from the oxime structure. For example, the description “6-094 (* 2)” refers to Compound No. 6-094 (* 2 ) Represents the geometric isomer of Compound No. 6-094.

〔第２表〕   [Table 2]

――――――――――――――――――――――――――――――――――――
No. R⁶ R⁷ A m.p.(℃)
――――――――――――――――――――――――――――――――――――
1-001 Me Me Me 92-98
1-002 Me Me H 170-173
1-003 Me Et H 135-140
1-004 Me Me C(O)Bu-t *1
1-005 Me Me C(O)Me *1
1-006 Me Me S(O)₂Me *1
1-007 Me Me CH₂CH=CH₂ *1
1-008 Me Me CH₂C≡CH *1
1-009 Me Me CH₂Ph *1
1-010 Me Me C(O)Ph *1
1-011 Me Me CH₂CH₂SMe *1
1-012 Me Me CH₂C(O)OMe *1
1-013 Me Me CH₂CN *1
1-014 Me Me C(O)OMe *1
1-015 Me Me C(O)Pr-c *1
1-016 Me Me C(O)C(Me)₂CH₂Cl *1
1-017 Me Me C(O)C(Me)₂OPh *1
1-018 Me CH₂CH=CH₂ H 119-120
1-019 Me CH₂C≡CH H 113-114
1-020 Me CH₂Ph H 190-192
1-022 Me CH₂(D1-32a) H 118-120
1-023 Me CH₂C(O)OMe H 100-102
1-024 Me CH₂Pr-c H 138-140
1-025 Me CH₂C(O)(D1-103a) H 152-156
1-026 Me CH₂{D1-108c(2-F)} H 198-200
1-027 Me CH₂CH(OH)Me H 143-144
1-028 Me CH₂CF₃ H 172-174
1-029 Me CH₂CH₂SMe H 94-102
1-031 Me Me CH₂C≡CSi(Me)₃ *1
1-033 Me Me C(O)Oct-n *1
1-034 Me Me C(O)C(Me)₂OC(O)Me *1
1-035 Me Me C(O)CH₂CH₂Hex-c *1
1-036 Me Me C(O)(D1-103b) *1
1-037 Me Me CH₂CH₂OMe *1
1-038 Et Me H 147-149
1-039 Me Me C(O)C(Me)₂F *1
1-040 CH₂OMe Me H 150-153
1-041 Me CH₂CH₂OMe H 129-132
1-042 Me Me C(O)CH(Me)Cl *1
1-043 Me Me C(O)CH₂OPh *1
1-044 Me Me C(O)CH₂O{D1-108d(4-Cl)} *1
1-045 D1-32a Me H *1
1-046 c-Pr Me H *1
1-047 Ph Me H *1
1-048 i-Pr Me H *1
1-050 H Me H 96-108
1-051 Me Me C(O)C(Me)₂O{D1-108d(4-Cl)} *1
1-052 Me i-Pr H 93-95
1-053 Me t-Bu H 145-147
1-054 Me n-Hept H 136-137
1-055 Me CH₂CH₂Si(Me)₃ H 133-135
1-056 Me CH₂CH=CHCl H 100-102
1-057 Me Ph H 149-151
1-058 Me H H 95-98
1-059 t-Bu Me H 163-164
1-060 Me Me C(O)CH(Me)OPh *1
1-062 n-Pr Me H 134-137
1-063 c-Pr Me C(O)CH₂OPh *1
1-064 Me Me C(O)C(Me)₂O{D1-108d(2-Cl)} *1
1-065 Me Me C(O)C(Me)₂O{D1-108d(3-Cl)} *1
1-066 s-Bu Me H 154-156
1-067 Me Me C(O)CH₂O{D1-108d(2-OMe)} *1
1-068 Me Me C(O)CH₂O{D1-108d(3-OMe)} *1
1-069 Me Me C(O)CH₂O{D1-108d(4-OMe)} *1
1-070 CH₂Pr-c Me H 153-155
1-071 Me Me C(O)CH₂O{D1-108d(2-NO₂)} *1
1-072 Me Me C(O)CH₂O{D1-108d(4-Me)} *1
1-073 Me Me C(O)CH₂O{D1-108d(4-F)} *1
1-074 Me Me C(O)CH₂O{D1-108d(3-CN)} *1
1-075 Me Me C(O)CH₂O{D1-108d[2,4-(Cl)₂} *1
1-076 Me Me C(O)(D1-81a) *1
1-077 CH₂Cl Me Me *1
1-078 c-Pen Me H 161-163
1-079 Me Me C(O)CH₂O{D1-108d(4-CHO)} *1
1-080 Me Me C(O)CH₂O{D1-108d[4-C(O)Me]} *1
1-081 Me Me C(O)CH₂O{D1-108d(4-Br)} *1
1-082 Me Me C(O)CH₂O{D1-108d(4-I)} *1
1-083 Me Me C(O)CH₂O(D1-108e) *1
1-084 CH₂Cl Me H 159-161
1-085 c-Hex Me H 149-152
1-086 CH=CH₂ Me H 115-117
1-087 Me Me C(O)CH(Me)O(D1-103d) *1
1-088 Me Me C(O)(D1-103e) *1
1-089 Me Me C(O)(D1-103f) *1
1-090 Me Me C(O)CH=CHPr-n *1
1-091 Me Me C(O)CH=CH(D1-1a) *1
1-092 Me Me C(O)CH₂OCH₂CF₃ *1
1-093 Me Me C(O)CH₂OMe *1
1-094 Me Me C(O)CH₂OCH₂Ph *1
1-095 Me Me C(O)C≡CMe *1
1-096 Me Me C(O)C≡CSi(Me)₃ *1
1-097 CF₃ Me H 115-118
1-098 Me Me C(O)C(=NOMe)CH₂SMe *1
1-099 Me Me C(O){D1-6d(4,5-Cl₂)} *1
1-100 Me Me C(O){D1-5d(5-Me)} *1
1-101 Me Me C(O){D1-10d(2,5-Me₂)} *1
1-102 Me CH₂CN H 163-166
1-103 Me Me C(O){D1-5e(5-Pr-c)} *1
1-104 Me Me C(O)(D1-103a) *1
1-105 Me CH₂C(=NOMe)Me H 118-122
1-106 Me c-Pen H 120-122
1-107 Me Me S(O)₂C8H17 *1
1-108 Me Me C(O)N(Me)₂ *1
1-109 Me CH₂(D1-103g) H 155-158
1-110 Me CH₂CH₂S(O)₂Me H 130-132
1-111 Me CH₂(D1-84a) H 150-153
1-112 Me CH₂{D1-108c(4-OMe)} H 179-180
1-113 Me CH₂{D1-108c(2-Cl)} H 194-197
1-114 Me CH₂{D1-108c(3-Cl)} H 188-193
1-115 Me CH₂{D1-108c(2-Cl,6-F)} H 225-228
1-116 Me CH₂{D1-108c(2-CF₃)} H 147-154
1-117 Me CH₂{D1-108c(3-CF₃)} H 143-154
1-118 Me CH₂{D1-108c[4-C(O)OMe]} H 183-189
1-119 Me CH₂{D1-108c(2-NO₂)} H 177-179
1-120 Me D1-103h H 162-166
1-121 Me CH₂CH(Cl)Me H 182-185
1-122 Me Me SO₂N(Me)₂ *1
1-123 Me n-Pr H 123-126
1-124 Me CH₂C(O)NH₂ H 120-123
1-125 Me CH₂CH₂S(O)Me H *1
1-126 Me Me C(O)N(Me)(CH₂)4Cl *1
1-127 Me Me C(O)N(i-Pr)Ph *1
1-128 Me Me C(O)N(i-Pr){D1-108d(4-F)} *1
1-129 Me Me C(O)N(i-Pr){D1-108d(2,4-F₂)} *1
1-130 Me Me C(O)N(Et)CH₂C(Me)=CH₂ *1
1-131 c-Pr CH₂CF₃ H 137-138
1-132 Me CH₂CH₂NH₂ H 209(decomp.)
1-133 D1-108c(4-F) Me H 181-183
1-134 Me Me C(O)CH₂SPh *1
1-135 Me CH₂CH(Br)Me H 179-181
1-136 Me CH₂{D1-108c(4-F)} H 171-180
1-137 Me CH₂{D1-108c(4-Cl)} H 135-150
1-138 Me CH₂{D1-108c(4-CF₃)} H 168-173
1-139 Me Me C(O)CH₂N(Me)C(O)Ph *1
1-140 Me Me C(O)CH(Et)O(D1-103i) *1
1-141 Me Me C(S)N(Me)₂ *1
1-142 Me Me SO₂(CH₂)₃Cl *1
1-143 Me Me SO₂Pr-c *1
1-144 Me Me SO₂(CH₂)₂Si(Me)₃ *1
1-145 Me Me C(O)OCH₂Ph *1
1-146 Me Me C(O)OCH₂CH=CH₂ *1
1-147 Me Me C(O)O(CH₂)₂OMe *1
1-148 Me Me C(O)C(Me)₂{D1-108d(4-Cl)} *1
1-149 Me Me C(O){D1-108d(4-CF₃)} *1
1-150 Me Me C(O)(D1-103j) *1
1-151 Me Me C(O)(D1-103k) *1
1-152 Me Me C(O)(D1-103l) *1
1-153 Me Me C(O)N(CH₂CH=CH₂)₂ *1
1-154 Me Me C(O){D1-108d(2-CF₃)} 90-92
1-155 Me Me C(O){D1-108d(2-OCF₃)} *1
1-156 Me Me C(O)CH₂{D1-108d(4-OMe)} *1
1-157 Me Me C(O)N(Ph)₂ 165-168
1-158 Me Me C(O)N(i-Pr)₂ 74-75
1-159 Me Me C(O)N(Me)Ph *1
1-160 Me Me C(O)(D1-8b) *1
1-161 Me Me SO₂{D1-108d(4-Me)} *1
1-162 Me Me C(O){D1-108d[2-Cl,3-C(O)OMe,4-SO₂Me] *1
1-163 Me Me C(O)CH(Me)O(D1-103m) *1
1-164 D1-108c(4-Me) Me H *1
1-165 Me Me c-Pen *1
1-166 Me Me CH₂C(Cl)=CHCl *1
1-167 Me Me C(O)O{D1-108d(4-Me)} *1
1-168 Me Me C(O)O{D1-108d(4-OMe)} *1
1-169 Me Me C(O)CH(Ph)OC(O)Me *1
1-170 Me Me SO₂(D1-103k) *1
1-171 Me Me C(O)N(Me)Et *1
1-172 Me Me C(O)C(Me)₂Ph 78-81
1-173 Me Me C(O)(D1-103p) *1
1-174 Me Me C(O){D1-103q(4-Cl)} *1
1-175 Me Me C(O)OHex-n *1
1-176 Me Me C(O)O(Oct-n) *1
1-177 Me Me C(O)OCH₂CH₂Cl *1
1-178 Me Me C(O)OCH₂CH₂CH₂Cl *1
1-179 Me Me C(O)OCH₂CH₂CH₂CH₂Cl *1
1-180 Me Me C(O)OBu-n *1
1-181 Me Me C(O)O{D1-108d(4-Cl)} *1
1-182 Me Me C(O)O{D1-108d(2-Cl)} 144-147
1-183 Me Me C(O)OCH₂CH₂F *1
1-184 Me Me C(O)OCH₂{D1-108d(4-NO₂)} *1
1-185 Me Me C(S)(D1-103a) *1
1-186 Me Me C(O)(D1-103o) *1
1-187 Me Me C(S)OCH₂CH₂OCH₂CH₂OMe *1
1-188 Me Me C(O)(D1-103r) *1
1-189 Me Me C(O)(D1-103s) *1
1-190 Me Me C(O)(D1-103t) *1
1-191 Me Me C(S)SEt *1
1-192 Me Me CH₂C(O)Ph *1
1-193 Me Me CH₂OMe *1
1-194 Me CH₂(D1-81a) H 159-160
1-195 Me CH₂(D1-81b) H 164-166
1-196 Me CH₂{D1-108c(4-NO₂)} H 144-147
1-197 Me CH₂{D1-108c(4-Me)} H 170-172
1-198 Me CH₂{D1-108c(4-OCF₃)} H 184-186
1-199 Me CH₂C≡CMe H 152-156
1-200 Me CH₂CH₂OEt H 121-128
1-201 Me CH₂{D1-108c(4-CN)} H 165-167
1-202 Me CH₂CH₂CF₃ H 168-169
1-203 Me Me SO₂{D1-108d(4-Br)} 134-135
1-204 Me Me SO₂{D1-108d(2-CF₃)} 127-128
1-205 Me Me SO₂{D1-108d(3-CN)} 112-116
1-206 Me Me SO₂{D1-108d(2-NO₂)} 202-204
1-207 Me Me SO₂[D1-108d{4-C(O)Me}] 118-120
1-208 Me Me SO₂{D1-108d(3-CF₃)} 98-101
1-209 Me Me SO₂{D1-108d(2-CN)} 135-137
1-210 Me Me C(O){D1-108d(2,5-Cl₂)} *1
1-211 Me Me C(O)[D1-108d{2,6-(OMe)₂}] 161-166
1-212 Me CH(Me)CN H 202-203
1-213 Me CH₂CH₂CN H 140-142
1-214 Me Me SO₂{D1-108d(2-Me)} 122-126
1-215 Me Me SO₂{D1-108d(3-Me)} 111-113
1-216 Me Me SO₂{D1-108d(2,5-Me₂)} 107-109
1-217 Me Me SO₂{D1-108d(4-Cl)} 106-109
1-218 Me Me SO₂{D1-108d(2,4,6-Cl₃)} 112-114
1-219 Me Me C(O){D1-108d(3,5-Me₂)} 107-111
1-220 Me Me C(O){D1-108d(2,4,6-Me₃)} *1
1-221 Me CH₂CH=C(Cl)₂ H 152-157
1-222 Me Me C(O){D1-108d(2,6-Cl₂)} *1
1-223 Me CH(Me)C(O)NH₂ H 143-145
1-224 Me CH₂CH₂C(O)OMe H 145-147
1-225 Me Me SO₂{D1-108d(2,4-Me₂)} 118-120
1-226 Me Me CH₂OHex-c *1
1-227 Me Me CH₂OCH₂CH₂OMe *1
1-228 Me Me CH₂OEt *1
1-229 Me Me SO₂{D1-108d(3-OMe)} 89-90
1-230 Me Me SO₂{D1-108d(4-OMe)} 110-112
1-231 Me Me SO₂{D1-108d(2,4,6-Me₃)} 114-116
1-232 Me Me SO₂{D1-108d(2-Cl)} 131-133
1-233 Me Me SO₂{D1-108d(2,6-Cl₂)} 129-131
1-234 Me Me SO₂{D1-108d(4-F)} 103-105
1-235 Me Me SO₂{D1-108d(4-CF₃)} 103-105
1-236 Me Me SO₂{D1-108d(4-NO₂)} 141-142
1-237 Me Me SO₂{D1-108d(2-OCF₃)} 114-116
1-238 Me Me C(O){D1-108d(2,3-Cl₂)} 102-106
1-239 Me Me C(O){D1-108d(2,4-Cl₂)} *1
1-240 Me Me C(O){D1-108d(3,5-Cl₂)} 108-110
1-241 Me Me C(O){D1-108d(3,4-Cl₂)} 104-108
1-242 Me Me C(O){D1-108d(2,4,6-Cl₃)} *1
1-243 Me Me C(O){D1-108d(3-Me)} *1
1-244 Me Me C(O){D1-108d(2-OMe)} *1
1-245 Me Me C(O){D1-108d(3-F)} *1
1-246 Me Me C(O){D1-108d(4-F)} *1
1-247 Me Me C(O){D1-108d(3-Br)} *1
1-248 Me Me SO₂{D1-108d(3-Cl)} 94-96
1-249 Me Me SO₂{D1-108d(4-CN)} 149-151
1-250 Me Me SO₂{D1-108d(3-NO₂)} 120-121
1-251 Me Me SO₂{D1-108d(4-OCF₃)} 84-86
1-252 Me Me C(O)[D1-108d{3,5-(OMe)₂}] *1
1-253 Me Me C(O){D1-108d(2-Me)} 82-86
1-254 Me Me C(O){D1-108d(3-Cl)} *1
1-255 Me Me C(O){D1-108d(4-Cl)} 116-117
1-256 Me Me C(O){D1-108d(2-Br)} 80-83
1-257 Me Me C(O){D1-108d(4-Br)} 111-114
1-258 Me Me C(O){D1-108d(2-NO₂)} *1
1-259 Me Me C(O){D1-108d(3-CF₃)} *1
1-260 Me Me C(O){D1-108d(4-Me)} 108-110
1-261 Me Me C(O){D1-108d(4-OMe)} 109-112
1-262 Me Me C(O){D1-108d(3-OMe)} 95-96
1-263 Me Me C(O){D1-108d(2-F)} *1
1-264 Me Me C(O){D1-108d(2-Cl)} 87-88
1-265 Me Me C(O){D1-108d(4-SMe)} *1
1-266 Me Me C(O){D1-108d(3-NO₂)} *1
1-267 Me Me C(O)[D1-108d{3-C(O)OMe}] 101-102
1-268 Me Me C(O){D1-108d(3-OCF₃)} *1
1-269 Me Me C(O){D1-108d(4-OCF₃)} *1
1-270 Me Me C(O)SPen-c *1
1-271 Me Me C(O)SHex-c 89-90
1-272 Me Me C(O)SCH₂Ph *1
1-273 Me Me C(O)SCH₂CH=CH₂ *1
1-274 Me Me C(O)[D1-108d{2-C(O)OMe}] *1
1-275 Me Me C(O)[D1-108d{4-C(O)OMe}] *1
1-276 Me Me C(O){D1-108d(4-CN)} *1
1-277 Me Me C(O){D1-108d(3-CN)} *1
1-278 Me Me C(O)[D1-108d{2,4-(OMe)₂}] *1
1-279 Me Me C(O){D1-108d(4-NO₂)} *1
1-280 Me Me C(O)CH₂{D1-108d(4-Cl)} *1
1-281 Me Me C(O)CH₂{D1-108d(2-Cl)} *1
1-282 Me Me C(O)CH₂{D1-108d(4-Me)} *1
1-283 Me Me C(O)CH₂{D1-108d(3-Me)} *1
1-284 Me Me C(O)CH₂{D1-108d(4-CF₃)} *1
1-285 Me Me C(O)CH₂{D1-108d(2-OMe)} *1
1-286 Me Me C(O){D1-103q(4-OMe)} *1
1-287 Me Me C(O){D1-103q(4-Me)} *1
1-288 Me Me C(O){D1-103q(2,4-Cl₂)} *1
1-289 Me Me C(O)(D1-103x) *1
1-290 Me Me C(O)(D1-103y) 95-96
1-291 Me Me C(O){D1-103z(4-Me)} *1
1-292 Me Me C(O){D1-103z(3-F)} 82-83
1-293 Me Me C(O){D1-103z(4-Cl)} *1
1-294 Me Me C(O){D1-103z(4-F)} 74-77
1-295 Me Me C(O){D1-103z(4-OMe)} *1
1-296 Me CH₂C(O)OH H 194(decomp.)
1-297 Me Me C(O)(D1-33a) *1
1-298 Me Me C(O)(D1-34a) *1
1-299 Me Me C(O)CH₂{D1-108d(2-Me)} *1
1-300 Me Me C(O)CH₂{D1-108d(2-CF₃)} *1
1-301 Me Me C(O)CH₂{D1-108d(3-Cl)} *1
1-302 Me Me C(O)CH₂{D1-108d(3-OMe)} *1
1-303 Me Me C(O)CH₂{D1-108d(3-OCF₃)} 69-71
1-304 Me Me C(S)OCH₂CH=CH₂ *1
1-305 Me Me C(S)OHex-c *1
1-306 Me Me C(S)OMe 60-61
1-307 Me Me C(S)OPen-c 76-77
1-308 Me Me C(S)OCH₂Ph 71-79
1-309 Me Me C(S)OCH₂C≡CH *1
1-310 Me H C(O)(D1-103a) *1
1-311 Me Me C(O)CH₂{D1-108d(3-CF₃)} *1
1-312 Me Me C(O)(D1-32a) *1
1-313 D1-10e(2-Me) Me H *1
1-314 D1-10e(2-Me) Me C(O)Bu-t *1
1-315 c-Pr Et H 77-79
――――――――――――――――――――――――――――――――――――
なお、本発明化合物Ｎｏ．１−００９は、前記の合成例１０に記載の化合物Ｎｏ．１−００９ａ−１，１−００９ａ−２，１−００９ｂ−１及び１−００９ｂ−２の混合物であり、１−００９ａ−１と１−００９ａ−２及び１−００９ｂ−１と１−００９ｂ−２はそれぞれオキシム部の幾何異性体を表す。 ――――――――――――――――――――――――――――――――――――
No. R ⁶ R ⁷ A mp (℃)
――――――――――――――――――――――――――――――――――――
1-001 Me Me Me 92-98
1-002 Me Me H 170-173
1-003 Me Et H 135-140
1-004 Me Me C (O) Bu-t * 1
1-005 Me Me C (O) Me * 1
1-006 Me Me S (O) ₂ Me * 1
1-007 Me Me CH ₂ CH = CH ₂ * 1
1-008 Me Me CH ₂ C≡CH * 1
1-009 Me Me CH ₂ Ph * 1
1-010 Me Me C (O) Ph * 1
1-011 Me Me CH ₂ CH ₂ SMe * 1
1-012 Me Me CH ₂ C (O) OMe * 1
1-013 Me Me CH ₂ CN * 1
1-014 Me Me C (O) OMe * 1
1-015 Me Me C (O) Pr-c * 1
1-016 Me Me C (O) C (Me) ₂ CH ₂ Cl * 1
1-017 Me Me C (O) C (Me) ₂ OPh * 1
1-018 Me CH ₂ CH = CH ₂ H 119-120
1-019 Me CH ₂ C≡CH H 113-114
1-020 Me CH ₂ Ph H 190-192
1-022 Me CH ₂ (D1-32a) H 118-120
1-023 Me CH ₂ C (O) OMe H 100-102
1-024 Me CH ₂ Pr-c H 138-140
1-025 Me CH ₂ C (O) (D1-103a) H 152-156
1-026 Me CH ₂ {D1-108c (2-F)} H 198-200
1-027 Me CH ₂ CH (OH) Me H 143-144
1-028 Me CH ₂ CF ₃ H 172-174
1-029 Me CH ₂ CH ₂ SMe H 94-102
1-031 Me Me CH ₂ C≡CSi (Me) ₃ * 1
1-033 Me Me C (O) Oct-n * 1
1-034 Me Me C (O) C (Me) ₂ OC (O) Me * 1
1-035 Me Me C (O) CH ₂ CH ₂ Hex-c * 1
1-036 Me Me C (O) (D1-103b) * 1
1-037 Me Me CH ₂ CH ₂ OMe * 1
1-038 Et Me H 147-149
1-039 Me Me C (O) C (Me) ₂ F * 1
1-040 CH ₂ OMe Me H 150-153
1-041 Me CH ₂ CH ₂ OMe H 129-132
1-042 Me Me C (O) CH (Me) Cl * 1
1-043 Me Me C (O) CH ₂ OPh * 1
1-044 Me Me C (O) CH ₂ O {D1-108d (4-Cl)} * 1
1-045 D1-32a Me H * 1
1-046 c-Pr Me H * 1
1-047 Ph Me H * 1
1-048 i-Pr Me H * 1
1-050 H Me H 96-108
1-051 Me Me C (O) C (Me) ₂ O {D1-108d (4-Cl)} * 1
1-052 Me i-Pr H 93-95
1-053 Me t-Bu H 145-147
1-054 Me n-Hept H 136-137
1-055 Me CH ₂ CH ₂ Si (Me) ₃ H 133-135
1-056 Me CH ₂ CH = CHCl H 100-102
1-057 Me Ph H 149-151
1-058 Me HH 95-98
1-059 t-Bu Me H 163-164
1-060 Me Me C (O) CH (Me) OPh * 1
1-062 n-Pr Me H 134-137
1-063 c-Pr Me C (O) CH ₂ OPh * 1
1-064 Me Me C (O) C (Me) ₂ O {D1-108d (2-Cl)} * 1
1-065 Me Me C (O) C (Me) ₂ O {D1-108d (3-Cl)} * 1
1-066 s-Bu Me H 154-156
1-067 Me Me C (O) CH ₂ O {D1-108d (2-OMe)} * 1
1-068 Me Me C (O) CH ₂ O {D1-108d (3-OMe)} * 1
1-069 Me Me C (O) CH ₂ O {D1-108d (4-OMe)} * 1
1-070 CH ₂ Pr-c Me H 153-155
1-071 Me Me C (O) CH ₂ O {D1-108d (2-NO ₂ )} * 1
1-072 Me Me C (O) CH ₂ O {D1-108d (4-Me)} * 1
1-073 Me Me C (O) CH ₂ O {D1-108d (4-F)} * 1
1-074 Me Me C (O) CH ₂ O {D1-108d (3-CN)} * 1
1-075 Me Me C (O) CH ₂ O {D1-108d [2,4- (Cl) ₂ } * 1
1-076 Me Me C (O) (D1-81a) * 1
1-077 CH ₂ Cl Me Me * 1
1-078 c-Pen Me H 161-163
1-079 Me Me C (O) CH ₂ O {D1-108d (4-CHO)} * 1
1-080 Me Me C (O) CH ₂ O {D1-108d [4-C (O) Me]} * 1
1-081 Me Me C (O) CH ₂ O {D1-108d (4-Br)} * 1
1-082 Me Me C (O) CH ₂ O {D1-108d (4-I)} * 1
1-083 Me Me C (O) CH ₂ O (D1-108e) * 1
1-084 CH ₂ Cl Me H 159-161
1-085 c-Hex Me H 149-152
1-086 CH = CH ₂ Me H 115-117
1-087 Me Me C (O) CH (Me) O (D1-103d) * 1
1-088 Me Me C (O) (D1-103e) * 1
1-089 Me Me C (O) (D1-103f) * 1
1-090 Me Me C (O) CH = CHPr-n * 1
1-091 Me Me C (O) CH = CH (D1-1a) * 1
1-092 Me Me C (O) CH ₂ OCH ₂ CF ₃ * 1
1-093 Me Me C (O) CH ₂ OMe * 1
1-094 Me Me C (O) CH ₂ OCH ₂ Ph * 1
1-095 Me Me C (O) C≡CMe * 1
1-096 Me Me C (O) C≡CSi (Me) ₃ * 1
1-097 CF ₃ Me H 115-118
1-098 Me Me C (O) C (= NOMe) CH ₂ SMe * 1
1-099 Me Me C (O) {D1-6d (4,5-Cl ₂ )} * 1
1-100 Me Me C (O) {D1-5d (5-Me)} * 1
1-101 Me Me C (O) {D1-10d (2,5-Me ₂ )} * 1
1-102 Me CH ₂ CN H 163-166
1-103 Me Me C (O) {D1-5e (5-Pr-c)} * 1
1-104 Me Me C (O) (D1-103a) * 1
1-105 Me CH ₂ C (= NOMe) Me H 118-122
1-106 Me c-Pen H 120-122
1-107 Me Me S (O) ₂ C8H17 * 1
1-108 Me Me C (O) N (Me) ₂ * 1
1-109 Me CH ₂ (D1-103g) H 155-158
1-110 Me CH ₂ CH ₂ S (O) ₂ Me H 130-132
1-111 Me CH ₂ (D1-84a) H 150-153
1-112 Me CH ₂ {D1-108c (4-OMe)} H 179-180
1-113 Me CH ₂ {D1-108c (2-Cl)} H 194-197
1-114 Me CH ₂ {D1-108c (3-Cl)} H 188-193
1-115 Me CH ₂ {D1-108c (2-Cl, 6-F)} H 225-228
1-116 Me CH ₂ {D1-108c (2-CF ₃ )} H 147-154
1-117 Me CH ₂ {D1-108c (3-CF ₃ )} H 143-154
1-118 Me CH ₂ {D1-108c [4-C (O) OMe]} H 183-189
1-119 Me CH ₂ {D1-108c (2-NO ₂ )} H 177-179
1-120 Me D1-103h H 162-166
1-121 Me CH ₂ CH (Cl) Me H 182-185
1-122 Me Me SO ₂ N (Me) ₂ * 1
1-123 Me n-Pr H 123-126
1-124 Me CH ₂ C (O) NH ₂ H 120-123
1-125 Me CH ₂ CH ₂ S (O) Me H * 1
1-126 Me Me C (O) N (Me) (CH ₂ ) 4Cl * 1
1-127 Me Me C (O) N (i-Pr) Ph * 1
1-128 Me Me C (O) N (i-Pr) {D1-108d (4-F)} * 1
1-129 Me Me C (O) N (i-Pr) {D1-108d (2,4-F ₂ )} * 1
1-130 Me Me C (O) N (Et) CH ₂ C (Me) = CH ₂ * 1
1-131 c-Pr CH ₂ CF ₃ H 137-138
1-132 Me CH ₂ CH ₂ NH ₂ H 209 (decomp.)
1-133 D1-108c (4-F) Me H 181-183
1-134 Me Me C (O) CH ₂ SPh * 1
1-135 Me CH ₂ CH (Br) Me H 179-181
1-136 Me CH ₂ {D1-108c (4-F)} H 171-180
1-137 Me CH ₂ {D1-108c (4-Cl)} H 135-150
1-138 Me CH ₂ {D1-108c (4-CF ₃ )} H 168-173
1-139 Me Me C (O) CH ₂ N (Me) C (O) Ph * 1
1-140 Me Me C (O) CH (Et) O (D1-103i) * 1
1-141 Me Me C (S) N (Me) ₂ * 1
1-142 Me Me SO ₂ (CH ₂ ) ₃ Cl * 1
1-143 Me Me SO ₂ Pr-c * 1
1-144 Me Me SO ₂ (CH ₂ ) ₂ Si (Me) ₃ * 1
1-145 Me Me C (O) OCH ₂ Ph * 1
1-146 Me Me C (O) OCH ₂ CH = CH ₂ * 1
1-147 Me Me C (O) O (CH ₂ ) ₂ OMe * 1
1-148 Me Me C (O) C (Me) ₂ {D1-108d (4-Cl)} * 1
1-149 Me Me C (O) {D1-108d (4-CF ₃ )} * 1
1-150 Me Me C (O) (D1-103j) * 1
1-151 Me Me C (O) (D1-103k) * 1
1-152 Me Me C (O) (D1-103l) * 1
1-153 Me Me C (O) N (CH ₂ CH = CH ₂ ) ₂ * 1
1-154 Me Me C (O) {D1-108d (2-CF ₃ )} 90-92
1-155 Me Me C (O) {D1-108d (2-OCF ₃ )} * 1
1-156 Me Me C (O) CH ₂ {D1-108d (4-OMe)} * 1
1-157 Me Me C (O) N (Ph) ₂ 165-168
1-158 Me Me C (O) N (i-Pr) ₂ 74-75
1-159 Me Me C (O) N (Me) Ph * 1
1-160 Me Me C (O) (D1-8b) * 1
1-161 Me Me SO ₂ {D1-108d (4-Me)} * 1
1-162 Me Me C (O) {D1-108d [2-Cl, 3-C (O) OMe, 4-SO ₂ Me] * 1
1-163 Me Me C (O) CH (Me) O (D1-103m) * 1
1-164 D1-108c (4-Me) Me H * 1
1-165 Me Me c-Pen * 1
1-166 Me Me CH ₂ C (Cl) = CHCl * 1
1-167 Me Me C (O) O {D1-108d (4-Me)} * 1
1-168 Me Me C (O) O {D1-108d (4-OMe)} * 1
1-169 Me Me C (O) CH (Ph) OC (O) Me * 1
1-170 Me Me SO ₂ (D1-103k) * 1
1-171 Me Me C (O) N (Me) Et * 1
1-172 Me Me C (O) C (Me) ₂ Ph 78-81
1-173 Me Me C (O) (D1-103p) * 1
1-174 Me Me C (O) {D1-103q (4-Cl)} * 1
1-175 Me Me C (O) OHex-n * 1
1-176 Me Me C (O) O (Oct-n) * 1
1-177 Me Me C (O) OCH ₂ CH ₂ Cl * 1
1-178 Me Me C (O) OCH ₂ CH ₂ CH ₂ Cl * 1
1-179 Me Me C (O) OCH ₂ CH ₂ CH ₂ CH ₂ Cl * 1
1-180 Me Me C (O) OBu-n * 1
1-181 Me Me C (O) O {D1-108d (4-Cl)} * 1
1-182 Me Me C (O) O {D1-108d (2-Cl)} 144-147
1-183 Me Me C (O) OCH ₂ CH ₂ F * 1
1-184 Me Me C (O) OCH ₂ {D1-108d (4-NO ₂ )} * 1
1-185 Me Me C (S) (D1-103a) * 1
1-186 Me Me C (O) (D1-103o) * 1
1-187 Me Me C (S) OCH ₂ CH ₂ OCH ₂ CH ₂ OMe * 1
1-188 Me Me C (O) (D1-103r) * 1
1-189 Me Me C (O) (D1-103s) * 1
1-190 Me Me C (O) (D1-103t) * 1
1-191 Me Me C (S) SEt * 1
1-192 Me Me CH ₂ C (O) Ph * 1
1-193 Me Me CH ₂ OMe * 1
1-194 Me CH ₂ (D1-81a) H 159-160
1-195 Me CH ₂ (D1-81b) H 164-166
1-196 Me CH ₂ {D1-108c (4-NO ₂ )} H 144-147
1-197 Me CH ₂ {D1-108c (4-Me)} H 170-172
1-198 Me CH ₂ {D1-108c (4-OCF ₃ )} H 184-186
1-199 Me CH ₂ C≡CMe H 152-156
1-200 Me CH ₂ CH ₂ OEt H 121-128
1-201 Me CH ₂ {D1-108c (4-CN)} H 165-167
1-202 Me CH ₂ CH ₂ CF ₃ H 168-169
1-203 Me Me SO ₂ {D1-108d (4-Br)} 134-135
1-204 Me Me SO ₂ {D1-108d (2-CF ₃ )} 127-128
1-205 Me Me SO ₂ {D1-108d (3-CN)} 112-116
1-206 Me Me SO ₂ {D1-108d (2-NO ₂ )} 202-204
1-207 Me Me SO ₂ [D1-108d {4-C (O) Me}] 118-120
1-208 Me Me SO ₂ {D1-108d (3-CF ₃ )} 98-101
1-209 Me Me SO ₂ {D1-108d (2-CN)} 135-137
1-210 Me Me C (O) {D1-108d (2,5-Cl ₂ )} * 1
1-211 Me Me C (O) [D1-108d {2,6- (OMe) ₂ }] 161-166
1-212 Me CH (Me) CN H 202-203
1-213 Me CH ₂ CH ₂ CN H 140-142
1-214 Me Me SO ₂ {D1-108d (2-Me)} 122-126
1-215 Me Me SO ₂ {D1-108d (3-Me)} 111-113
1-216 Me Me SO ₂ {D1-108d (2,5-Me ₂ )} 107-109
1-217 Me Me SO ₂ {D1-108d (4-Cl)} 106-109
1-218 Me Me SO ₂ {D1-108d (2,4,6-Cl ₃ )} 112-114
1-219 Me Me C (O) {D1-108d (3,5-Me ₂ )} 107-111
1-220 Me Me C (O) {D1-108d (2,4,6-Me ₃ )} * 1
1-221 Me CH ₂ CH = C (Cl) ₂ H 152-157
1-222 Me Me C (O) {D1-108d (2,6-Cl ₂ )} * 1
1-223 Me CH (Me) C (O) NH ₂ H 143-145
1-224 Me CH ₂ CH ₂ C (O) OMe H 145-147
1-225 Me Me SO ₂ {D1-108d (2,4-Me ₂ )} 118-120
1-226 Me Me CH ₂ OHex-c * 1
1-227 Me Me CH ₂ OCH ₂ CH ₂ OMe * 1
1-228 Me Me CH ₂ OEt * 1
1-229 Me Me SO ₂ {D1-108d (3-OMe)} 89-90
1-230 Me Me SO ₂ {D1-108d (4-OMe)} 110-112
1-231 Me Me SO ₂ {D1-108d (2,4,6-Me ₃ )} 114-116
1-232 Me Me SO ₂ {D1-108d (2-Cl)} 131-133
1-233 Me Me SO ₂ {D1-108d (2,6-Cl ₂ )} 129-131
1-234 Me Me SO ₂ {D1-108d (4-F)} 103-105
1-235 Me Me SO ₂ {D1-108d (4-CF ₃ )} 103-105
1-236 Me Me SO ₂ {D1-108d (4-NO ₂ )} 141-142
1-237 Me Me SO ₂ {D1-108d (2-OCF ₃ )} 114-116
1-238 Me Me C (O) {D1-108d (2,3-Cl ₂ )} 102-106
1-239 Me Me C (O) {D1-108d (2,4-Cl ₂ )} * 1
1-240 Me Me C (O) {D1-108d (3,5-Cl ₂ )} 108-110
1-241 Me Me C (O) {D1-108d (3,4-Cl ₂ )} 104-108
1-242 Me Me C (O) {D1-108d (2,4,6-Cl ₃ )} * 1
1-243 Me Me C (O) {D1-108d (3-Me)} * 1
1-244 Me Me C (O) {D1-108d (2-OMe)} * 1
1-245 Me Me C (O) {D1-108d (3-F)} * 1
1-246 Me Me C (O) {D1-108d (4-F)} * 1
1-247 Me Me C (O) {D1-108d (3-Br)} * 1
1-248 Me Me SO ₂ {D1-108d (3-Cl)} 94-96
1-249 Me Me SO ₂ {D1-108d (4-CN)} 149-151
1-250 Me Me SO ₂ {D1-108d (3-NO ₂ )} 120-121
1-251 Me Me SO ₂ {D1-108d (4-OCF ₃ )} 84-86
1-252 Me Me C (O) [D1-108d {3,5- (OMe) ₂ }] * 1
1-253 Me Me C (O) {D1-108d (2-Me)} 82-86
1-254 Me Me C (O) {D1-108d (3-Cl)} * 1
1-255 Me Me C (O) {D1-108d (4-Cl)} 116-117
1-256 Me Me C (O) {D1-108d (2-Br)} 80-83
1-257 Me Me C (O) {D1-108d (4-Br)} 111-114
1-258 Me Me C (O) {D1-108d (2-NO ₂ )} * 1
1-259 Me Me C (O) {D1-108d (3-CF ₃ )} * 1
1-260 Me Me C (O) {D1-108d (4-Me)} 108-110
1-261 Me Me C (O) {D1-108d (4-OMe)} 109-112
1-262 Me Me C (O) {D1-108d (3-OMe)} 95-96
1-263 Me Me C (O) {D1-108d (2-F)} * 1
1-264 Me Me C (O) {D1-108d (2-Cl)} 87-88
1-265 Me Me C (O) {D1-108d (4-SMe)} * 1
1-266 Me Me C (O) {D1-108d (3-NO ₂ )} * 1
1-267 Me Me C (O) [D1-108d {3-C (O) OMe}] 101-102
1-268 Me Me C (O) {D1-108d (3-OCF ₃ )} * 1
1-269 Me Me C (O) {D1-108d (4-OCF ₃ )} * 1
1-270 Me Me C (O) SPen-c * 1
1-271 Me Me C (O) SHex-c 89-90
1-272 Me Me C (O) SCH ₂ Ph * 1
1-273 Me Me C (O) SCH ₂ CH = CH ₂ * 1
1-274 Me Me C (O) [D1-108d {2-C (O) OMe}] * 1
1-275 Me Me C (O) [D1-108d {4-C (O) OMe}] * 1
1-276 Me Me C (O) {D1-108d (4-CN)} * 1
1-277 Me Me C (O) {D1-108d (3-CN)} * 1
1-278 Me Me C (O) [D1-108d {2,4- (OMe) ₂ }] * 1
1-279 Me Me C (O) {D1-108d (4-NO ₂ )} * 1
1-280 Me Me C (O) CH ₂ {D1-108d (4-Cl)} * 1
1-281 Me Me C (O) CH ₂ {D1-108d (2-Cl)} * 1
1-282 Me Me C (O) CH ₂ {D1-108d (4-Me)} * 1
1-283 Me Me C (O) CH ₂ {D1-108d (3-Me)} * 1
1-284 Me Me C (O) CH ₂ {D1-108d (4-CF ₃ )} * 1
1-285 Me Me C (O) CH ₂ {D1-108d (2-OMe)} * 1
1-286 Me Me C (O) {D1-103q (4-OMe)} * 1
1-287 Me Me C (O) {D1-103q (4-Me)} * 1
1-288 Me Me C (O) {D1-103q (2,4-Cl ₂ )} * 1
1-289 Me Me C (O) (D1-103x) * 1
1-290 Me Me C (O) (D1-103y) 95-96
1-291 Me Me C (O) {D1-103z (4-Me)} * 1
1-292 Me Me C (O) {D1-103z (3-F)} 82-83
1-293 Me Me C (O) {D1-103z (4-Cl)} * 1
1-294 Me Me C (O) {D1-103z (4-F)} 74-77
1-295 Me Me C (O) {D1-103z (4-OMe)} * 1
1-296 Me CH ₂ C (O) OH H 194 (decomp.)
1-297 Me Me C (O) (D1-33a) * 1
1-298 Me Me C (O) (D1-34a) * 1
1-299 Me Me C (O) CH ₂ {D1-108d (2-Me)} * 1
1-300 Me Me C (O) CH ₂ {D1-108d (2-CF ₃ )} * 1
1-301 Me Me C (O) CH ₂ {D1-108d (3-Cl)} * 1
1-302 Me Me C (O) CH ₂ {D1-108d (3-OMe)} * 1
1-303 Me Me C (O) CH ₂ {D1-108d (3-OCF ₃ )} 69-71
1-304 Me Me C (S) OCH ₂ CH = CH ₂ * 1
1-305 Me Me C (S) OHex-c * 1
1-306 Me Me C (S) OMe 60-61
1-307 Me Me C (S) OPen-c 76-77
1-308 Me Me C (S) OCH ₂ Ph 71-79
1-309 Me Me C (S) OCH ₂ C≡CH * 1
1-310 Me HC (O) (D1-103a) * 1
1-311 Me Me C (O) CH ₂ {D1-108d (3-CF ₃ )} * 1
1-312 Me Me C (O) (D1-32a) * 1
1-313 D1-10e (2-Me) Me H * 1
1-314 D1-10e (2-Me) Me C (O) Bu-t * 1
1-315 c-Pr Et H 77-79
――――――――――――――――――――――――――――――――――――
In addition, this invention compound No. 1-009 is compound No. 1 described in Synthesis Example 10 above. 1-009a-1, 1-009a-2, 1-009b-1 and 1-009b-2, 1-009a-1, 1-009a-2 and 1-009b-1, 1-009b- Each 2 represents a geometric isomer of the oxime part.

〔第３表〕   [Table 3]

――――――――――――――――――――――――――――――――
No. R⁶ R⁷ R^8a R^9a A m.p.(℃)
――――――――――――――――――――――――――――――――
1-021 Me Me C(=NOMe)Me H H 163-164
1-030 H Me Me Me H 176-180
1-032 Me Me Me H H 199-206
1-049 Me Me D1-108c(4-F) H H 160-168
1-061 Me Me CF₃ H H 155-158
――――――――――――――――――――――――――――――――
〔第４表〕 ――――――――――――――――――――――――――――――――
No. R ⁶ R ⁷ R ^8a R ^9a A mp (℃)
――――――――――――――――――――――――――――――――
1-021 Me Me C (= NOMe) Me HH 163-164
1-030 H Me Me Me H 176-180
1-032 Me Me Me HH 199-206
1-049 Me Me D1-108c (4-F) HH 160-168
1-061 Me Me CF ₃ HH 155-158
――――――――――――――――――――――――――――――――
[Table 4]

――――――――――――――――――――――――――――――――
No. R⁶ R^8a R^9a A m.p.(℃)
――――――――――――――――――――――――――――――――
2-001 Me H H H 183-185
2-002 Me C(O)Me H H 190-193
2-003 Me C(O)OMe H H 155-158
2-004 Me C(O)OEt Me H 154-163
2-005 Me Me H H 153-158
2-006 Et H H H 197-198
2-007 CH₂OMe H H H 143-145
2-008 Ph C(O)OEt H H *1
2-009 i-Pr C(O)OEt H H 150-153
2-010 CF₃ C(O)OEt H H *1
2-011 CH₂Ph C(O)OEt H H 110-114
2-012 Me C(O)OEt Et H 140-144
2-013 D1-32a C(O)OEt H H 79-88
2-014 c-Pr C(O)OMe H H 204-206
2-015 CH₂Ph H H H *1
2-016 i-Pr H H H 139-144
2-017 c-Pr H H H 191-192
2-018 Me H H C(O)Bu-t *1
2-019 t-Bu C(O)OMe H H 192-194
2-020 n-Pr C(O)OMe H H 164-167
2-021 n-Pr H H H 190-193
2-022 t-Bu H H H 50-54
2-023 Me C(O)OMe Et H 160-163
2-024 s-Bu H H H 112-115
2-025 CH₂Pr-c C(O)OEt H H 132-134
2-026 CH₂Pr-c H H H 195-197
2-027 c-Pen C(O)OEt H H 168-170
2-028 c-Pen H H H 147-149
2-029 c-Hex C(O)OEt H H 154-157
2-030 c-Hex H H H 167-169
2-031 CH=CH₂ H H H 123-126
2-032 D1-108c(4-F) H H H 194-196
2-033 D1-81a C(O)OEt H H *1
2-034 D1-10e(2-Me) C(O)OEt H H *1
2-035 D1-10e(2-Me) H H H *1
――――――――――――――――――――――――――――――――
〔第５表〕 ――――――――――――――――――――――――――――――――
No. R ⁶ R ^8a R ^9a A mp (℃)
――――――――――――――――――――――――――――――――
2-001 Me HHH 183-185
2-002 Me C (O) Me HH 190-193
2-003 Me C (O) OMe HH 155-158
2-004 Me C (O) OEt Me H 154-163
2-005 Me Me HH 153-158
2-006 Et HHH 197-198
2-007 CH ₂ OMe HHH 143-145
2-008 Ph C (O) OEt HH * 1
2-009 i-Pr C (O) OEt HH 150-153
2-010 CF ₃ C (O) OEt HH * 1
2-011 CH ₂ Ph C (O) OEt HH 110-114
2-012 Me C (O) OEt Et H 140-144
2-013 D1-32a C (O) OEt HH 79-88
2-014 c-Pr C (O) OMe HH 204-206
2-015 CH ₂ Ph HHH * 1
2-016 i-Pr HHH 139-144
2-017 c-Pr HHH 191-192
2-018 Me HHC (O) Bu-t * 1
2-019 t-Bu C (O) OMe HH 192-194
2-020 n-Pr C (O) OMe HH 164-167
2-021 n-Pr HHH 190-193
2-022 t-Bu HHH 50-54
2-023 Me C (O) OMe Et H 160-163
2-024 s-Bu HHH 112-115
2-025 CH ₂ Pr-c C (O) OEt HH 132-134
2-026 CH ₂ Pr-c HHH 195-197
2-027 c-Pen C (O) OEt HH 168-170
2-028 c-Pen HHH 147-149
2-029 c-Hex C (O) OEt HH 154-157
2-030 c-Hex HHH 167-169
2-031 CH = CH ₂ HHH 123-126
2-032 D1-108c (4-F) HHH 194-196
2-033 D1-81a C (O) OEt HH * 1
2-034 D1-10e (2-Me) C (O) OEt HH * 1
2-035 D1-10e (2-Me) HHH * 1
――――――――――――――――――――――――――――――――
[Table 5]

――――――――――――――――――――――――――――――
No. R⁶ R⁷ A m.p.(℃)
――――――――――――――――――――――――――――――
3-001 H Me H *1
3-002 Me Me H *1
――――――――――――――――――――――――――――――
〔第６表〕 ――――――――――――――――――――――――――――――
No. R ⁶ R ⁷ A mp (℃)
――――――――――――――――――――――――――――――
3-001 H Me H * 1
3-002 Me Me H * 1
――――――――――――――――――――――――――――――
[Table 6]

――――――――――――――――――――――――――――――
No. R⁶ R⁷ R^8a R^8b R^9a R^9b A m.p.(℃)
――――――――――――――――――――――――――――――
4-001 Et Me H H H H H *1
――――――――――――――――――――――――――――――

〔第７表〕 ――――――――――――――――――――――――――――――
No. R ⁶ R ⁷ R ^8a R ^8b R ^9a R ^9b A mp (℃)
――――――――――――――――――――――――――――――
4-001 Et Me HHHHH * 1
――――――――――――――――――――――――――――――

[Table 7]

――――――――――――――――――――――――――――――
No. R⁶ R^8a R^8b R^9a R^9b A m.p.(℃)
――――――――――――――――――――――――――――――
5-001 Et H H H H H *1
5-002 Et H H H H Me *1
――――――――――――――――――――――――――――――
〔第８表〕 ――――――――――――――――――――――――――――――
No. R ⁶ R ^8a R ^8b R ^9a R ^9b A mp (℃)
――――――――――――――――――――――――――――――
5-001 Et HHHHH * 1
5-002 Et HHHH Me * 1
――――――――――――――――――――――――――――――
[Table 8]

―――――――――――――――――――――――――――――――――――
No. Z^a Z^c Z^e R^8a A m.p.(℃)
―――――――――――――――――――――――――――――――――――
6-001 Et Br Me H H 151-153
6-002 Et Br Me C(O)OMe H 184-188
6-003 Me Br Me H H 164-166
6-004 Me D1-7b(X1=4-Cl) Me H H *1
6-005 Et D1-7b(X1=4-Cl) Me H H *1
6-006 Et C≡CMe Me H H *1
6-007 Et Me Me H H 122-125
6-008 Et C≡CSi(Me)₃ Me H H *1
6-009 Me C≡CMe Me H H 60-65
6-010 Me C≡CPr-c Me H H *1
6-011 Me Br Me H Me *1
6-012 Me Ph Me H Me *1
6-013 Me D1-108b(4-Me) Me H Me *1
6-014 Me D1-108b(4-CF₃) Me H Me *1
6-015 Me Ph Me H H 167-169
6-016 Me D1-108b(4-CF₃) Me H H 163-164
6-017 Me D1-108b(4-OMe) Me H H 155-157
6-018 Me D1-108b(4-Me) Me H H 137-139
6-019 Me D1-108b(4-Cl) Me H Me *1
6-020 Me D1-108b(4-OMe) Me H Me 124-125
6-021 Me D1-108b(4-SMe) Me H Me 65-66
6-022 Me S(D1-103c) Me H H *1
6-023 Me C(O)OMe Me H H *1
6-024 Me SMe Me H H *1
6-025 Me C≡CCH₂OH Me H H *1
6-026 Me C(O)Me Me H H *1
6-027 Me CN Me H H 181-184
6-028 Me D1-32a Me H Me 151-154
6-029 Me D1-108b(4-Cl) Me H H 145-150
6-030 Me D1-108b(4-SMe) Me H H 167-169
6-031 Me CH=CH₂ Me H H 166-172
6-032 Me NO₂ Me H H 181-183
6-033 Me NHC(O)OBu-t Me H H *1
6-034 Me D1-108b(3-Cl) Me H H 197-199
6-035 Me D1-33b(6-Cl) Me H H *1
6-036 Me C≡CC(Me)₂OH Me H H *1
6-037 OMe Me Me H H 130-133
6-038 Br Me Me H H *1
6-039 Me c-Pr Me H Me *1
6-040 Me D1-7a Me H Me 129-132
6-041 Me OPh Me H Me *1
6-042 Me OCH₂CF₃ Me H Me 117-119
6-043 Me D1-108b(4-OCF₃) Me H Me *1
6-044 Me D1-37a Me H Me 166-169
6-045 Me OCH₂Ph Me H Me *1
6-046 Me OCH₂(D1-34a) Me H Me *1
6-047 Me O{D1-32b(5-CF₃)} Me H Me *1
6-048 Me OMe Me H Me 82-85
6-049 Me OCH₂CF₃ Me H H 165-172
6-050 Me c-Pr Me H H 170-178
6-051 Me D1-32a Me H H *1
6-052 Me OPh Me H H *1
6-053 Me OCH₂(D1-34a) Me H H 118-122
6-054 Me O{D1-32b(5-CF₃)} Me H H 169-172
6-055 Me OMe Me H H 141-143
6-056 Me D1-108b(4-OCF₃) Me H H 161-163
6-057 Me D1-37a Me H H 183-188
6-058 Me D1-108b(4-F) Me H H 159-161
6-059 Me D1-108b(4-F) Me H C(O)(D1-103a) *1
6-060 Me D1-108b(4-F) Me H S(O)₂N(Me)₂ *1
6-061 Me D1-108b(4-Cl) Me H C(O)CH₂OPh *1
6-062 Me D1-108b(4-Cl) Me H C(O)(D1-103a) *1
6-063 Me D1-108b(4-Cl) Me H C(O)N(Me)₂ *1
6-064 Et D1-108b(4-Cl) Me H C(O)(D1-103a) *1
6-065 Me C(=NOMe)Me Me H H 177-180
6-066 Et D1-108b(4-Cl) Me H H 165-167
6-067 Me CH=CHPr-n Me H Me *1
6-068 Me CH=CHPh Me H Me 125-126
6-069 Me OH Me H Me 192-195
6-070 Me OCH₂(D1-34a) Me H H *1
6-071 Me CH=CHPr-n Me H H 171-177
6-072 Me CH=CHPh Me H H 150-152
6-073 Me D1-7a Me H H 200-203
6-074 Me D1-22a Me H H 164-167
6-075 SMe Me Me H H *1
6-076 OMe Br Me H H 150-153
6-077 OMe D1-108b(4-Cl) Me H H *1
6-078 OMe D1-108b(4-Cl) Me H C(O)(D1-103a) *1
6-079 OMe D1-108b(4-Cl) Me H C(O)CH₂OPh *1
6-080 Me D1-108b(4-Cl) Me H C(O)CH₂CH₂CH₂C(O)Me *1
6-081 OMe D1-108b(4-Cl) Me H C(O)N(Me)₂ *1
6-082 Me D1-108b(4-Cl) Me H C(O)SBu-t *1
6-083 Me D1-108b(4-Cl) Me H CH₂OC(O)Ph *1
6-084 Me D1-108b(2-F,4-Cl) Me H H 175-177
6-085 Me D1-108b(3-Cl,4-F) Me H H 187-190
6-086 Me D1-108b(4-Cl) Me H C(O)CH(Me)CH₂SMe *1
6-087 Me D1-108b(3,5-Cl₂) Me H H 205-215
6-088 Me D1-108b(2,4-Cl₂) Me H H 148-151
6-089 Me D1-108b(2-F,4-Cl) Me H C(O)(D1-103a) *1
6-090 Me D1-108b(2,4-Cl₂) Me H C(O)(D1-103a) *1
6-091 OMe Me Me H C(O)CH₂OPh *1
6-092 Me D1-108b(2,4-Cl₂) Me H C(O)CH₂OPh *1
6-093 Me D1-108b(3-Cl,4-F) Me H C(O)(D1-103a) *1
6-094 OMe Me Me H C(O)(D1-103a) *1
6-094(*2) *1
6-095 OMe Me Me H S(O)₂N(Me)₂ *1
6-096 OMe Br F H H 157-159
6-097 Me OCH₂CH₂OMe Me H Me *1
6-098 Me OCH₂CH₂OMe Me H H 119-121
6-099 OMe Ph Me H H 175-177
6-100 OMe Ph Me H C(O)CH₂OPh *1
6-101 Me D1-11a Me H Me *1
6-102 Me D1-22a Me H Me 103-104
6-103 OMe Me OMe H H 171-175
6-104 Me D1-108b(3,4,5-F₃) Me H H 161-163
6-105 Me D1-34a Me H H *1
6-106 Me D1-2c Me H H 204-207
6-107 OMe Ph F H H 175-177
6-108 OMe Me F H H *1
6-109 OMe Me Me H C(O)N(Me)₂ *1
6-110 OMe Me Me H C(O)(D1-103j) *1
6-111 OMe Me Me H C(O)(D1-103k) *1
6-112 Me H Me H H 167-170
6-113 OMe Br Me Me H *1
6-114 OMe Me Me Me H *1
6-115 OMe Me Me H C(O)N(Et)₂ *1
6-116 OMe Me Me H C(S)N(Et)₂ *1
6-117 OMe Me Me H C(O)Bu-t *1
6-118 OMe Me Me H C(O){D1-108d[4-C(O)N(Me)₂]} *1
6-119 OMe Me Me H C(S)OPh *1
6-120 OMe Me Me H C(O)CH=CH₂ *1
6-121 OMe Me Me H C(O)Ph *1
6-122 OMe Me Me H C(O)CH₂OC(O)Me *1
6-123 OMe Me Me Me C(O)Bu-t *1
6-124 OMe Me Me H C(O)SBu-t *1
6-125 OMe Me Me H C(S)N(Me)₂ *1
6-126 OMe Me Me H C(O)CH₂CH₂CH₂Cl *1
6-127 OMe Me Me Me C(O)(D1-103a) *1
6-128 OMe C≡CMe Me H H 176-178
6-129 OMe C≡CMe Me H C(O)Bu-t *1
6-130 OMe C≡CMe Me H C(O)OMe *1
6-131 OMe C≡CMe Me H C(O)Ph *1
6-132 OMe C≡CMe Me H C(O)(D1-103a) *1
6-133 OMe C≡CMe Me H C(O)(D1-103j) *1
6-134 OMe C≡CMe Me H S(O)₂Me *1
6-135 OMe C≡CMe Me H S(O)₂NMe₂ *1
6-136 OMe C≡CMe Me H C(O)CH₂OPh *1
6-137 H Me Me H H 154-157
6-138 OMe Me Me H C(O)(D1-103s) *1
6-139 OMe Me Me H C(O)(D1-103t) *1
6-140 OMe Me Me H C(O)(D1-103r) *1
6-141 Et Me Et H H 172-176
6-142 Et Me Et H C(O)(D1-103a) *1
6-143 Et Me Et H C(O)(D1-103j) *1
6-144 Et Me Et H S(O)₂Me *1
6-145 Et Me Et H S(O)₂NMe₂ *1
6-146 Et Me Et H C(O)CH₂OPh *1
6-147 Et Me Et H C(O)OMe *1
6-148 Et Me Et H C(O)Ph *1
6-149 Me D1-108b(4-Cl) Me H C(O)C(Me)₂{D1-108d(4-Cl)} *1
6-150 Me D1-108b(4-Cl) Me H S(O)₂{D1-108d(4-Me)} *1
6-151 Me D1-108b(4-Cl) Me H C(O)C(Ph)=C(Me)₂ *1
6-152 Et Me Et H C(O)Bu-t *1
6-153 MeO Me Me H C(O)C(Me)₂Ph *1
6-154 OEt Me Me H H *1
6-155 OMe Me Me H C(O)O{D1-108d(4-Me)} *1
6-156 OMe Me Me H C(O)OHex-n *1
6-157 OMe Me Me H C(O)OOct-n *1
6-158 OMe Me Me H C(O)OCH₂CH₂Cl *1
6-159 OMe Me Me H C(O)OCH₂CH₂CH₂Cl *1
6-160 OMe Me Me H C(O)OPr-n *1
6-161 OMe Me Me H C(O)O{D1-108d(4-Cl)} *1
6-162 OMe Me Me H C(O)O{D1-108d(2-Cl)} *1
6-163 OMe Me Me H C(O)OCH₂CH₂CH₂Cl *1
6-164 OMe Me Me H C(O)CH₂CH(Et)Bu-n *1
6-165 OMe Me Me H C(O)OEt *1
6-166 OMe Me Me H C(O)OBu-i *1
6-167 OMe Me Me H C(O)OPr-n *1
6-168 OMe Me Me H CH₂OMe *1
6-169 OMe Me Me H CH₂OCH₂CH₂OMe *1
6-170 OMe Me Me H CH₂OHex-c *1
6-171 OMe Me Me H CH₂OEt *1
6-172 OMe Me Me H C(S)SEt *1
6-173 OMe Me Me H C(O)CH₂{D1-108d(3-Cl)} *1
6-174 OMe Me Me H C(O)CH₂{D1-108d(2-Cl)} *1
6-175 OMe Me Me H C(O)CH(Me){D1-108d(4-Cl)} *1
6-176 OMe Me Me H C(O)CH(Me)Ph *1
6-177 OMe Me Me H C(O)CH₂{D1-108d(4-Cl)} *1
6-178 OMe Me Me H C(O)CH₂{D1-108d(4-OMe)} *1
6-179 OMe Me Me H C(O)CH₂{D1-108d(4-CF₃)} *1
6-180 OMe Me Me H C(O)CH₂{D1-108d(2-Me)} *1
6-181 OMe Me Me H C(O)CH₂{D1-108d(4-OCF₃)} *1
6-182 OMe Me Me H C(O)CH₂{D1-108d(4-SMe)} *1
6-183 OMe Me Me H C(O)CH₂{D1-108d(2,4,6-Me₃)} *1
6-184 OMe Me Me H C(O)C(Me)₂OPh *1
6-185 OMe Me Me H C(O)CH(Me)OPh *1
6-186 OMe Me Me H C(O)CH₂O{D1-108d(4-Cl)} *1
6-187 OMe Me Me H C(O)CH₂O{D1-108d(4-OMe)} *1
6-188 OMe Me Me H C(O)CH₂O{D1-108d(4-CF₃)} *1
6-189 OMe Me Me H C(O)CH₂O{D1-108d(4-OCF₃)} *1
6-190 OMe Me Me H C(O)CH₂O{D1-108d(3-CN)} *1
6-191 OMe Me Me H C(O)CH₂O{D1-108d(3,4-Cl₂)} *1
6-192 OMe Me Me H C(O)CH(Me)O{D1-108d(4-Cl) *1
6-193 OMe Me Me H C(O)OPh *1
6-194 Me C(O)H Me H Me 70-74
6-195 OMe Me Me H C(O)(D1-104a) *1
6-196 OMe Me Me H CH₂OCH₂Ph *1
6-197 OMe Me Me H S(O)₂{D1-108d(2-NO₂)} *1
6-198 OMe Me Me H S(O)₂{D1-108d(2-CF₃)} *1
6-199 OMe Me Me H S(O)₂{D1-108d(4-Cl)} *1
6-200 OMe Me Me H S(O)₂{D1-108d(4-Me)} *1
6-201 OMe Me Me H S(O)₂(D1-103j) *1
6-202 OMe Me Me H S(O)₂(D1-103a) *1
6-203 OMe Me Me H C(O){D1-108d(2,6-Me₂)} *1
6-204 OMe Me Me H C(O){D1-108d(2,4,6-Me₃)} *1
6-205 OMe Me Me H C(O)[D1-108d{2,6-(OMe)₂}] *1
6-206 OMe Me Me H C(O){D1-108d(2,6-Cl₂)} *1
6-207 OMe Me Me H C(O)C(Me)₂CH₂Cl *1
6-208 OMe Me Me H CH₂OC(O)Bu-t *1
6-209 OMe Me Me H S(O)₂Ph 94-97
6-210 OMe Me Me H S(O)₂{D1-108d(4-Br)} 101-104
6-211 OMe Me Me H S(O)₂{D1-108d(2-CN)} 129-131
6-212 OMe Me Me H S(O)₂{D1-108d(3-CN)} 138-139
6-213 OMe Me Me H S(O)₂{D1-108d(3-CF₃)} 72-76
6-214 OMe Me Me H S(O)₂{D1-108d(2,5-Me₂)} *1
6-215 OMe Me Me H S(O)₂{D1-108d(2,4,6-Cl₃)} 111-114
6-216 OMe Me Me H S(O)₂{D1-108d(2,4-Me₂)} 137-141
6-217 OMe Me Me H S(O)₂{D1-108d(2-Cl)} 144-147
6-218 OMe Me Me H S(O)₂{D1-108d(2,4,6-Me₃)} 86-89
6-219 OMe Me Me H S(O)₂{D1-108d(2-Me)} 127-129
6-220 OMe Me Me H S(O)₂{D1-108d(3-Me)} *1
6-221 OMe Me Me H S(O)₂{D1-108d(4-CF₃)} 109-112
6-222 OMe Me Me H S(O)₂{D1-108d(3-OMe)} 82-86
6-223 OMe Me Me H S(O)₂{D1-108d(3-Cl)} 98-100
6-224 OMe Me Me H C(O){D1-108d(2-CF₃)} *1
6-225 OMe Me Me H C(O){D1-108d(3,5-Me₂)} *1
6-226 OMe Me Me H C(O){D1-108d(2,3-Cl₂)} *1
6-227 OMe Me Me H C(O){D1-108d(3,5-Cl₂)} *1
6-228 OMe Me Me H C(O){D1-108d(3,4-Cl₂)} *1
6-229 OMe Me Me H C(O){D1-108d(2,4,6-Cl₃)} *1
6-230 OMe Me Me H C(O){D1-108d(4-F)} *1
6-231 OMe Me Me H C(O)[D1-108d{3,5-(OMe)₂} *1
6-232 OMe Me Me H C(O){D1-108d(2-Me)} *1
6-232(*2) *1
6-233 OMe Me Me H C(O){D1-108d(2-Br)} *1
6-234 OMe Me Me H C(O)C(Me)₂CH₂CH₂Me *1
6-235 OMe Me Me H C(O)CH₂Bu-t *1
6-236 Me Me Me OH CH₂Ph *1
6-237 Me Me Me OH H *1
6-238 OMe Me Me OH Me 113-117
6-239 OMe Me Me H C(O)(D1-104b) *1
6-240 OMe Me Me H C(O){D1-108d(3-Cl)} *1
6-241 OMe Me Me H C(O){D1-108d(4-Cl)} *1
6-242 OMe Me Me H C(O){D1-108d(3-CF₃)} *1
6-243 OMe Me Me H C(O){D1-108d(3-NO₂)} *1
6-244 OMe Me Me H S(O)₂{D1-108d(4-OMe)} 91-93
6-245 OMe Me Me H S(O)₂{D1-108d(2,6-Cl₂)} 100-103
6-246 OMe Me Me H S(O)₂{D1-108d(4-OCF₃)} *1
6-247 OMe Me Me H S(O)₂{D1-108d(4-CN)} 109-111
6-248 OMe Me Me H S(O)₂{D1-108d(3-NO₂)} 151-152
6-249 OMe Me Me H C(O){D1-108d(2,5-Cl₂)} *1
6-250 OMe Me Me H C(O){D1-108d(2-OMe)} *1
6-251 OMe Me Me H C(O){D1-108d(3-F)} *1
6-252 OMe Me Me H C(O){D1-108d(2-NO₂)} *1
6-253 Cl Me Me H H 58-62
6-254 Cl Me Me H C(O)Bu-t *1
6-255 Cl Me Me H C(O)O{D1-108d(4-Me)} *1
6-256 Cl Me Me H CH₂OCH₂CH₂OMe *1
6-257 Cl Me Me H C(O)(D1-103a) *1
6-258 Cl Me Me H S(O)₂{D1-108d(4-Me)} 134-138
6-259 OH Me Me H H *1
6-260 OMe Me Me H C(O)(D1-8b) *1
6-261 OMe Me Me H C(O)(D1-8c) *1
6-262 OMe Me Me H C(O)(D1-8d) *1
6-263 OMe Me Me H C(O){D1-10e(2-Me,4-i-Pr)} *1
6-264 OMe Me Me H C(O){D1-10e(2-Me,5-CF₃)} *1
6-265 OCH₂Ph Me Me H H 168-174
6-266 OCF₂H Me Me H H *1
6-267 OMe Me Me F H *1
6-268 OCH₂CH=CH₂ Me Me H H *1
6-269 OCH₂C≡CH Me Me H H *1
6-270 OCH₂CH₂OMe Me Me H H 149-150
6-271 OCH₂{D1-10e(2-Cl)} Me Me H H *1
6-272 OCH₂CN Me Me H H *1
6-273 OCH₂C(O)OMe Me Me H H *1
6-274 OCH₂CF₃ Me Me H H *1
6-275 OMe Me Me CN H *1
6-276 OMe Me Me C(O)NH₂ H 115-120
―――――――――――――――――――――――――――――――――――
〔第９表〕 ―――――――――――――――――――――――――――――――――――
No. Z ^a Z ^c Z ^e R ^8a A mp (℃)
―――――――――――――――――――――――――――――――――――
6-001 Et Br Me HH 151-153
6-002 Et Br Me C (O) OMe H 184-188
6-003 Me Br Me HH 164-166
6-004 Me D1-7b (X1 = 4-Cl) Me HH * 1
6-005 Et D1-7b (X1 = 4-Cl) Me HH * 1
6-006 Et C≡CMe Me HH * 1
6-007 Et Me Me HH 122-125
6-008 Et C≡CSi (Me) ₃ Me HH * 1
6-009 Me C≡CMe Me HH 60-65
6-010 Me C≡CPr-c Me HH * 1
6-011 Me Br Me H Me * 1
6-012 Me Ph Me H Me * 1
6-013 Me D1-108b (4-Me) Me H Me * 1
6-014 Me D1-108b (4-CF ₃ ) Me H Me * 1
6-015 Me Ph Me HH 167-169
6-016 Me D1-108b (4-CF ₃ ) Me HH 163-164
6-017 Me D1-108b (4-OMe) Me HH 155-157
6-018 Me D1-108b (4-Me) Me HH 137-139
6-019 Me D1-108b (4-Cl) Me H Me * 1
6-020 Me D1-108b (4-OMe) Me H Me 124-125
6-021 Me D1-108b (4-SMe) Me H Me 65-66
6-022 Me S (D1-103c) Me HH * 1
6-023 Me C (O) OMe Me HH * 1
6-024 Me SMe Me HH * 1
6-025 Me C≡CCH ₂ OH Me HH * 1
6-026 Me C (O) Me Me HH * 1
6-027 Me CN Me HH 181-184
6-028 Me D1-32a Me H Me 151-154
6-029 Me D1-108b (4-Cl) Me HH 145-150
6-030 Me D1-108b (4-SMe) Me HH 167-169
6-031 Me CH = CH ₂ Me HH 166-172
6-032 Me NO ₂ Me HH 181-183
6-033 Me NHC (O) OBu-t Me HH * 1
6-034 Me D1-108b (3-Cl) Me HH 197-199
6-035 Me D1-33b (6-Cl) Me HH * 1
6-036 Me C≡CC (Me) ₂ OH Me HH * 1
6-037 OMe Me Me HH 130-133
6-038 Br Me Me HH * 1
6-039 Me c-Pr Me H Me * 1
6-040 Me D1-7a Me H Me 129-132
6-041 Me OPh Me H Me * 1
6-042 Me OCH ₂ CF ₃ Me H Me 117-119
6-043 Me D1-108b (4-OCF ₃ ) Me H Me * 1
6-044 Me D1-37a Me H Me 166-169
6-045 Me OCH ₂ Ph Me H Me * 1
6-046 Me OCH ₂ (D1-34a) Me H Me * 1
6-047 Me O {D1-32b (5-CF ₃ )} Me H Me * 1
6-048 Me OMe Me H Me 82-85
6-049 Me OCH ₂ CF ₃ Me HH 165-172
6-050 Me c-Pr Me HH 170-178
6-051 Me D1-32a Me HH * 1
6-052 Me OPh Me HH * 1
6-053 Me OCH ₂ (D1-34a) Me HH 118-122
6-054 Me O {D1-32b (5-CF ₃ )} Me HH 169-172
6-055 Me OMe Me HH 141-143
6-056 Me D1-108b (4-OCF ₃ ) Me HH 161-163
6-057 Me D1-37a Me HH 183-188
6-058 Me D1-108b (4-F) Me HH 159-161
6-059 Me D1-108b (4-F) Me HC (O) (D1-103a) * 1
6-060 Me D1-108b (4-F) Me HS (O) ₂ N (Me) ₂ * 1
6-061 Me D1-108b (4-Cl) Me HC (O) CH ₂ OPh * 1
6-062 Me D1-108b (4-Cl) Me HC (O) (D1-103a) * 1
6-063 Me D1-108b (4-Cl) Me HC (O) N (Me) ₂ * 1
6-064 Et D1-108b (4-Cl) Me HC (O) (D1-103a) * 1
6-065 Me C (= NOMe) Me Me HH 177-180
6-066 Et D1-108b (4-Cl) Me HH 165-167
6-067 Me CH = CHPr-n Me H Me * 1
6-068 Me CH = CHPh Me H Me 125-126
6-069 Me OH Me H Me 192-195
6-070 Me OCH ₂ (D1-34a) Me HH * 1
6-071 Me CH = CHPr-n Me HH 171-177
6-072 Me CH = CHPh Me HH 150-152
6-073 Me D1-7a Me HH 200-203
6-074 Me D1-22a Me HH 164-167
6-075 SMe Me Me HH * 1
6-076 OMe Br Me HH 150-153
6-077 OMe D1-108b (4-Cl) Me HH * 1
6-078 OMe D1-108b (4-Cl) Me HC (O) (D1-103a) * 1
6-079 OMe D1-108b (4-Cl) Me HC (O) CH ₂ OPh * 1
6-080 Me D1-108b (4-Cl) Me HC (O) CH ₂ CH ₂ CH ₂ C (O) Me * 1
6-081 OMe D1-108b (4-Cl) Me HC (O) N (Me) ₂ * 1
6-082 Me D1-108b (4-Cl) Me HC (O) SBu-t * 1
6-083 Me D1-108b (4-Cl) Me H CH ₂ OC (O) Ph * 1
6-084 Me D1-108b (2-F, 4-Cl) Me HH 175-177
6-085 Me D1-108b (3-Cl, 4-F) Me HH 187-190
6-086 Me D1-108b (4-Cl) Me HC (O) CH (Me) CH ₂ SMe * 1
6-087 Me D1-108b (3,5-Cl ₂ ) Me HH 205-215
6-088 Me D1-108b (2,4-Cl ₂ ) Me HH 148-151
6-089 Me D1-108b (2-F, 4-Cl) Me HC (O) (D1-103a) * 1
6-090 Me D1-108b (2,4-Cl ₂ ) Me HC (O) (D1-103a) * 1
6-091 OMe Me Me HC (O) CH ₂ OPh * 1
6-092 Me D1-108b (2,4-Cl ₂ ) Me HC (O) CH ₂ OPh * 1
6-093 Me D1-108b (3-Cl, 4-F) Me HC (O) (D1-103a) * 1
6-094 OMe Me Me HC (O) (D1-103a) * 1
6-094 (* 2) * 1
6-095 OMe Me Me HS (O) ₂ N (Me) ₂ * 1
6-096 OMe Br FHH 157-159
6-097 Me OCH ₂ CH ₂ OMe Me H Me * 1
6-098 Me OCH ₂ CH ₂ OMe Me HH 119-121
6-099 OMe Ph Me HH 175-177
6-100 OMe Ph Me HC (O) CH ₂ OPh * 1
6-101 Me D1-11a Me H Me * 1
6-102 Me D1-22a Me H Me 103-104
6-103 OMe Me OMe HH 171-175
6-104 Me D1-108b (3,4,5-F ₃ ) Me HH 161-163
6-105 Me D1-34a Me HH * 1
6-106 Me D1-2c Me HH 204-207
6-107 OMe Ph FHH 175-177
6-108 OMe Me FHH * 1
6-109 OMe Me Me HC (O) N (Me) ₂ * 1
6-110 OMe Me Me HC (O) (D1-103j) * 1
6-111 OMe Me Me HC (O) (D1-103k) * 1
6-112 Me H Me HH 167-170
6-113 OMe Br Me Me H * 1
6-114 OMe Me Me Me H * 1
6-115 OMe Me Me HC (O) N (Et) ₂ * 1
6-116 OMe Me Me HC (S) N (Et) ₂ * 1
6-117 OMe Me Me HC (O) Bu-t * 1
6-118 OMe Me Me HC (O) {D1-108d [4-C (O) N (Me) ₂ ]} * 1
6-119 OMe Me Me HC (S) OPh * 1
6-120 OMe Me Me HC (O) CH = CH ₂ * 1
6-121 OMe Me Me HC (O) Ph * 1
6-122 OMe Me Me HC (O) CH ₂ OC (O) Me * 1
6-123 OMe Me Me Me C (O) Bu-t * 1
6-124 OMe Me Me HC (O) SBu-t * 1
6-125 OMe Me Me HC (S) N (Me) ₂ * 1
6-126 OMe Me Me HC (O) CH ₂ CH ₂ CH ₂ Cl * 1
6-127 OMe Me Me Me C (O) (D1-103a) * 1
6-128 OMe C≡CMe Me HH 176-178
6-129 OMe C≡CMe Me HC (O) Bu-t * 1
6-130 OMe C≡CMe Me HC (O) OMe * 1
6-131 OMe C≡CMe Me HC (O) Ph * 1
6-132 OMe C≡CMe Me HC (O) (D1-103a) * 1
6-133 OMe C≡CMe Me HC (O) (D1-103j) * 1
6-134 OMe C≡CMe Me HS (O) ₂ Me * 1
6-135 OMe C≡CMe Me HS (O) ₂ NMe ₂ * 1
6-136 OMe C≡CMe Me HC (O) CH ₂ OPh * 1
6-137 H Me Me HH 154-157
6-138 OMe Me Me HC (O) (D1-103s) * 1
6-139 OMe Me Me HC (O) (D1-103t) * 1
6-140 OMe Me Me HC (O) (D1-103r) * 1
6-141 Et Me Et HH 172-176
6-142 Et Me Et HC (O) (D1-103a) * 1
6-143 Et Me Et HC (O) (D1-103j) * 1
6-144 Et Me Et HS (O) ₂ Me * 1
6-145 Et Me Et HS (O) ₂ NMe ₂ * 1
6-146 Et Me Et HC (O) CH ₂ OPh * 1
6-147 Et Me Et HC (O) OMe * 1
6-148 Et Me Et HC (O) Ph * 1
6-149 Me D1-108b (4-Cl) Me HC (O) C (Me) ₂ {D1-108d (4-Cl)} * 1
6-150 Me D1-108b (4-Cl) Me HS (O) ₂ {D1-108d (4-Me)} * 1
6-151 Me D1-108b (4-Cl) Me HC (O) C (Ph) = C (Me) ₂ * 1
6-152 Et Me Et HC (O) Bu-t * 1
6-153 MeO Me Me HC (O) C (Me) ₂ Ph * 1
6-154 OEt Me Me HH * 1
6-155 OMe Me Me HC (O) O {D1-108d (4-Me)} * 1
6-156 OMe Me Me HC (O) OHex-n * 1
6-157 OMe Me Me HC (O) OOct-n * 1
6-158 OMe Me Me HC (O) OCH ₂ CH ₂ Cl * 1
6-159 OMe Me Me HC (O) OCH ₂ CH ₂ CH ₂ Cl * 1
6-160 OMe Me Me HC (O) OPr-n * 1
6-161 OMe Me Me HC (O) O {D1-108d (4-Cl)} * 1
6-162 OMe Me Me HC (O) O {D1-108d (2-Cl)} * 1
6-163 OMe Me Me HC (O) OCH ₂ CH ₂ CH ₂ Cl * 1
6-164 OMe Me Me HC (O) CH ₂ CH (Et) Bu-n * 1
6-165 OMe Me Me HC (O) OEt * 1
6-166 OMe Me Me HC (O) OBu-i * 1
6-167 OMe Me Me HC (O) OPr-n * 1
6-168 OMe Me Me H CH ₂ OMe * 1
6-169 OMe Me Me H CH ₂ OCH ₂ CH ₂ OMe * 1
6-170 OMe Me Me H CH ₂ OHex-c * 1
6-171 OMe Me Me H CH ₂ OEt * 1
6-172 OMe Me Me HC (S) SEt * 1
6-173 OMe Me Me HC (O) CH ₂ {D1-108d (3-Cl)} * 1
6-174 OMe Me Me HC (O) CH ₂ {D1-108d (2-Cl)} * 1
6-175 OMe Me Me HC (O) CH (Me) {D1-108d (4-Cl)} * 1
6-176 OMe Me Me HC (O) CH (Me) Ph * 1
6-177 OMe Me Me HC (O) CH ₂ {D1-108d (4-Cl)} * 1
6-178 OMe Me Me HC (O) CH ₂ {D1-108d (4-OMe)} * 1
6-179 OMe Me Me HC (O) CH ₂ {D1-108d (4-CF ₃ )} * 1
6-180 OMe Me Me HC (O) CH ₂ {D1-108d (2-Me)} * 1
6-181 OMe Me Me HC (O) CH ₂ {D1-108d (4-OCF ₃ )} * 1
6-182 OMe Me Me HC (O) CH ₂ {D1-108d (4-SMe)} * 1
6-183 OMe Me Me HC (O) CH ₂ {D1-108d (2,4,6-Me ₃ )} * 1
6-184 OMe Me Me HC (O) C (Me) ₂ OPh * 1
6-185 OMe Me Me HC (O) CH (Me) OPh * 1
6-186 OMe Me Me HC (O) CH ₂ O {D1-108d (4-Cl)} * 1
6-187 OMe Me Me HC (O) CH ₂ O {D1-108d (4-OMe)} * 1
6-188 OMe Me Me HC (O) CH ₂ O {D1-108d (4-CF ₃ )} * 1
6-189 OMe Me Me HC (O) CH ₂ O {D1-108d (4-OCF ₃ )} * 1
6-190 OMe Me Me HC (O) CH ₂ O {D1-108d (3-CN)} * 1
6-191 OMe Me Me HC (O) CH ₂ O {D1-108d (3,4-Cl ₂ )} * 1
6-192 OMe Me Me HC (O) CH (Me) O {D1-108d (4-Cl) * 1
6-193 OMe Me Me HC (O) OPh * 1
6-194 Me C (O) H Me H Me 70-74
6-195 OMe Me Me HC (O) (D1-104a) * 1
6-196 OMe Me Me H CH ₂ OCH ₂ Ph * 1
6-197 OMe Me Me HS (O) ₂ {D1-108d (2-NO ₂ )} * 1
6-198 OMe Me Me HS (O) ₂ {D1-108d (2-CF ₃ )} * 1
6-199 OMe Me Me HS (O) ₂ {D1-108d (4-Cl)} * 1
6-200 OMe Me Me HS (O) ₂ {D1-108d (4-Me)} * 1
6-201 OMe Me Me HS (O) ₂ (D1-103j) * 1
6-202 OMe Me Me HS (O) ₂ (D1-103a) * 1
6-203 OMe Me Me HC (O) {D1-108d (2,6-Me ₂ )} * 1
6-204 OMe Me Me HC (O) {D1-108d (2,4,6-Me ₃ )} * 1
6-205 OMe Me Me HC (O) [D1-108d {2,6- (OMe) ₂ }] * 1
6-206 OMe Me Me HC (O) {D1-108d (2,6-Cl ₂ )} * 1
6-207 OMe Me Me HC (O) C (Me) ₂ CH ₂ Cl * 1
6-208 OMe Me Me H CH ₂ OC (O) Bu-t * 1
6-209 OMe Me Me HS (O) ₂ Ph 94-97
6-210 OMe Me Me HS (O) ₂ {D1-108d (4-Br)} 101-104
6-211 OMe Me Me HS (O) ₂ {D1-108d (2-CN)} 129-131
6-212 OMe Me Me HS (O) ₂ {D1-108d (3-CN)} 138-139
6-213 OMe Me Me HS (O) ₂ {D1-108d (3-CF ₃ )} 72-76
6-214 OMe Me Me HS (O) ₂ {D1-108d (2,5-Me ₂ )} * 1
6-215 OMe Me Me HS (O) ₂ {D1-108d (2,4,6-Cl ₃ )} 111-114
6-216 OMe Me Me HS (O) ₂ {D1-108d (2,4-Me ₂ )} 137-141
6-217 OMe Me Me HS (O) ₂ {D1-108d (2-Cl)} 144-147
6-218 OMe Me Me HS (O) ₂ {D1-108d (2,4,6-Me ₃ )} 86-89
6-219 OMe Me Me HS (O) ₂ {D1-108d (2-Me)} 127-129
6-220 OMe Me Me HS (O) ₂ {D1-108d (3-Me)} * 1
6-221 OMe Me Me HS (O) ₂ {D1-108d (4-CF ₃ )} 109-112
6-222 OMe Me Me HS (O) ₂ {D1-108d (3-OMe)} 82-86
6-223 OMe Me Me HS (O) ₂ {D1-108d (3-Cl)} 98-100
6-224 OMe Me Me HC (O) {D1-108d (2-CF ₃ )} * 1
6-225 OMe Me Me HC (O) {D1-108d (3,5-Me ₂ )} * 1
6-226 OMe Me Me HC (O) {D1-108d (2,3-Cl ₂ )} * 1
6-227 OMe Me Me HC (O) {D1-108d (3,5-Cl ₂ )} * 1
6-228 OMe Me Me HC (O) {D1-108d (3,4-Cl ₂ )} * 1
6-229 OMe Me Me HC (O) {D1-108d (2,4,6-Cl ₃ )} * 1
6-230 OMe Me Me HC (O) {D1-108d (4-F)} * 1
6-231 OMe Me Me HC (O) [D1-108d {3,5- (OMe) ₂ } * 1
6-232 OMe Me Me HC (O) {D1-108d (2-Me)} * 1
6-232 (* 2) * 1
6-233 OMe Me Me HC (O) {D1-108d (2-Br)} * 1
6-234 OMe Me Me HC (O) C (Me) ₂ CH ₂ CH ₂ Me * 1
6-235 OMe Me Me HC (O) CH ₂ Bu-t * 1
6-236 Me Me Me OH CH ₂ Ph * 1
6-237 Me Me Me OH H * 1
6-238 OMe Me Me OH Me 113-117
6-239 OMe Me Me HC (O) (D1-104b) * 1
6-240 OMe Me Me HC (O) {D1-108d (3-Cl)} * 1
6-241 OMe Me Me HC (O) {D1-108d (4-Cl)} * 1
6-242 OMe Me Me HC (O) {D1-108d (3-CF ₃ )} * 1
6-243 OMe Me Me HC (O) {D1-108d (3-NO ₂ )} * 1
6-244 OMe Me Me HS (O) ₂ {D1-108d (4-OMe)} 91-93
6-245 OMe Me Me HS (O) ₂ {D1-108d (2,6-Cl ₂ )} 100-103
6-246 OMe Me Me HS (O) ₂ {D1-108d (4-OCF ₃ )} * 1
6-247 OMe Me Me HS (O) ₂ {D1-108d (4-CN)} 109-111
6-248 OMe Me Me HS (O) ₂ {D1-108d (3-NO ₂ )} 151-152
6-249 OMe Me Me HC (O) {D1-108d (2,5-Cl ₂ )} * 1
6-250 OMe Me Me HC (O) {D1-108d (2-OMe)} * 1
6-251 OMe Me Me HC (O) {D1-108d (3-F)} * 1
6-252 OMe Me Me HC (O) {D1-108d (2-NO ₂ )} * 1
6-253 Cl Me Me HH 58-62
6-254 Cl Me Me HC (O) Bu-t * 1
6-255 Cl Me Me HC (O) O {D1-108d (4-Me)} * 1
6-256 Cl Me Me H CH ₂ OCH ₂ CH ₂ OMe * 1
6-257 Cl Me Me HC (O) (D1-103a) * 1
6-258 Cl Me Me HS (O) ₂ {D1-108d (4-Me)} 134-138
6-259 OH Me Me HH * 1
6-260 OMe Me Me HC (O) (D1-8b) * 1
6-261 OMe Me Me HC (O) (D1-8c) * 1
6-262 OMe Me Me HC (O) (D1-8d) * 1
6-263 OMe Me Me HC (O) {D1-10e (2-Me, 4-i-Pr)} * 1
6-264 OMe Me Me HC (O) {D1-10e (2-Me, 5-CF ₃ )} * 1
6-265 OCH ₂ Ph Me Me HH 168-174
6-266 OCF ₂ H Me Me HH * 1
6-267 OMe Me Me FH * 1
6-268 OCH ₂ CH = CH ₂ Me Me HH * 1
6-269 OCH ₂ C≡CH Me Me HH * 1
6-270 OCH ₂ CH ₂ OMe Me Me HH 149-150
6-271 OCH ₂ {D1-10e (2-Cl)} Me Me HH * 1
6-272 OCH ₂ CN Me Me HH * 1
6-273 OCH ₂ C (O) OMe Me Me HH * 1
6-274 OCH ₂ CF ₃ Me Me HH * 1
6-275 OMe Me Me CN H * 1
6-276 OMe Me Me C (O) NH ₂ H 115-120
―――――――――――――――――――――――――――――――――――
[Table 9]

――――――――――――――――――――――――――――――――
No. Z^a Z^c Z^e R^8a A m.p.(℃)
――――――――――――――――――――――――――――――――
7-001 Et Br Me C(O)OMe H *1
7-002 Me Br Me H H 203-204
7-003 Et Br Me H H 170-172
7-004 Me Ph Me H H 196-200
7-005 Me D1-108b(4-CF₃) Me H H 174-176
7-006 Me D1-108b(4-OMe) Me H H 170-171
7-007 Me D1-108b(4-Me) Me H H 90-93
7-008 Me D1-108b(4-Cl) Me H H 173-175
7-009 Me D1-108b(4-SMe) Me H H 179-184
7-010 Me C≡CMe Me H H 207-209
7-011 Br Me Me H H 182-186
7-012 Me D1-32a Me H H 118-122
7-013 Me c-Pr Me H H 176-183
7-014 Me OPh Me H H 142-148
7-015 Me OCH₂CF₃ Me H H 122-125
7-016 Me D1-108b(4-OCF₃) Me H H 169-172
7-017 Me D1-37a Me H H *1
7-018 Me OCH₂Ph Me H H 156-158
7-019 Me O{D1-32b(5-CF₃)} Me H H 100-102
7-020 Me OMe Me H H 204-207
7-021 Me OCH₂(D1-34a) Me H H 187(decomp.)
7-022 Me CH=CHPr-n Me H H 106-116
7-023 Me CH=CHPh Me H H 181-185
7-024 Me D1-7a Me H H 184-187
7-025 Me D1-11a Me H H 61-65
7-026 Me D1-22a Me H H 54-66
7-027 OMe Br Me H H *1
7-028 OMe Br F C(O)OMe H 210-213
7-029 OMe Br F H H 163-165
7-030 OMe Me Me H H 147-152
7-031 OMe Br Me Me H 93-95
7-032 Et Me Et C(O)OMe H *1
7-033 Et Me Et H H 194-196
7-034 OEt Me Me C(O)OMe H *1
7-035 OEt Me Me H H 181-185
7-036 OMe Me Me C(O)OMe H 131-134
7-037 OMe Me Me H C(O)(D1-103a) *1
7-038 OCH₂Ph Me Me H H 110-115
7-039 OCH₂Ph Me Me H CH₂Ph *1
7-040 OH Me Me H H 150-160
7-041 OCF₂H Me Me C(O)OMe H 126-129
7-042 OCF₂H Me Me H H 170-172
7-043 OMe Me Me F H *1
7-044 OCH₂CH=CH₂ Me Me H CH₂CH=CH₂ *1
7-045 OCH₂C≡CH Me Me H CH₂C≡CH *1
7-046 OCH₂CH₂OMe Me Me H CH₂CH₂OMe *1
7-047 OCH₂{D1-10e(2-Cl)} Me Me H CH₂{D1-10e(2-Cl)} *1
7-048 OCH₂CH=CH₂ Me Me H H 157-161
7-049 OCH₂C≡CH Me Me H H *1
7-050 OCH₂CH₂OMe Me Me H H 114-117
7-051 OCH₂{D1-10e(2-Cl)} Me Me H H 176-178
7-052 OCH₂CF₃ Me Me H CH₂CF₃ *1
7-053 OCH₂CN Me Me H CH₂CN *1
7-054 OCH₂C(O)OMe Me Me H CH₂C(O)OMe *1
7-055 OCH₂CN Me Me H H *1
7-056 OCH₂CF₃ Me Me H H *1
7-057 OMe Me Me C(O)NH₂ H 127-133
――――――――――――――――――――――――――――――――
〔第１０表〕 ――――――――――――――――――――――――――――――――
No. Z ^a Z ^c Z ^e R ^8a A mp (℃)
――――――――――――――――――――――――――――――――
7-001 Et Br Me C (O) OMe H * 1
7-002 Me Br Me HH 203-204
7-003 Et Br Me HH 170-172
7-004 Me Ph Me HH 196-200
7-005 Me D1-108b (4-CF ₃ ) Me HH 174-176
7-006 Me D1-108b (4-OMe) Me HH 170-171
7-007 Me D1-108b (4-Me) Me HH 90-93
7-008 Me D1-108b (4-Cl) Me HH 173-175
7-009 Me D1-108b (4-SMe) Me HH 179-184
7-010 Me C≡CMe Me HH 207-209
7-011 Br Me Me HH 182-186
7-012 Me D1-32a Me HH 118-122
7-013 Me c-Pr Me HH 176-183
7-014 Me OPh Me HH 142-148
7-015 Me OCH ₂ CF ₃ Me HH 122-125
7-016 Me D1-108b (4-OCF ₃ ) Me HH 169-172
7-017 Me D1-37a Me HH * 1
7-018 Me OCH ₂ Ph Me HH 156-158
7-019 Me O {D1-32b (5-CF ₃ )} Me HH 100-102
7-020 Me OMe Me HH 204-207
7-021 Me OCH ₂ (D1-34a) Me HH 187 (decomp.)
7-022 Me CH = CHPr-n Me HH 106-116
7-023 Me CH = CHPh Me HH 181-185
7-024 Me D1-7a Me HH 184-187
7-025 Me D1-11a Me HH 61-65
7-026 Me D1-22a Me HH 54-66
7-027 OMe Br Me HH * 1
7-028 OMe Br FC (O) OMe H 210-213
7-029 OMe Br FHH 163-165
7-030 OMe Me Me HH 147-152
7-031 OMe Br Me Me H 93-95
7-032 Et Me Et C (O) OMe H * 1
7-033 Et Me Et HH 194-196
7-034 OEt Me Me C (O) OMe H * 1
7-035 OEt Me Me HH 181-185
7-036 OMe Me Me C (O) OMe H 131-134
7-037 OMe Me Me HC (O) (D1-103a) * 1
7-038 OCH ₂ Ph Me Me HH 110-115
7-039 OCH ₂ Ph Me Me H CH ₂ Ph * 1
7-040 OH Me Me HH 150-160
7-041 OCF ₂ H Me Me C (O) OMe H 126-129
7-042 OCF ₂ H Me Me HH 170-172
7-043 OMe Me Me FH * 1
7-044 OCH ₂ CH = CH ₂ Me Me H CH ₂ CH = CH ₂ * 1
7-045 OCH ₂ C≡CH Me Me H CH ₂ C≡CH * 1
7-046 OCH ₂ CH ₂ OMe Me Me H CH ₂ CH ₂ OMe * 1
7-047 OCH ₂ {D1-10e (2-Cl)} Me Me H CH ₂ {D1-10e (2-Cl)} * 1
7-048 OCH ₂ CH = CH ₂ Me Me HH 157-161
7-049 OCH ₂ C≡CH Me Me HH * 1
7-050 OCH ₂ CH ₂ OMe Me Me HH 114-117
7-051 OCH ₂ {D1-10e (2-Cl)} Me Me HH 176-178
7-052 OCH ₂ CF ₃ Me Me H CH ₂ CF ₃ * 1
7-053 OCH ₂ CN Me Me H CH ₂ CN * 1
7-054 OCH ₂ C (O) OMe Me Me H CH ₂ C (O) OMe * 1
7-055 OCH ₂ CN Me Me HH * 1
7-056 OCH ₂ CF ₃ Me Me HH * 1
7-057 OMe Me Me C (O) NH ₂ H 127-133
――――――――――――――――――――――――――――――――
[Table 10]

――――――――――――――――――――――――――――――
No. Q R⁶ A m.p.(℃)
――――――――――――――――――――――――――――――
8-001 O Me H 178-182
8-002 O C(=NOMe)Me H 50-55
8-003 NOMe C(=NOMe)Me H 190(decomp.)
――――――――――――――――――――――――――――――
〔第１１表〕 ――――――――――――――――――――――――――――――
No. QR ⁶ A mp (℃)
――――――――――――――――――――――――――――――
8-001 O Me H 178-182
8-002 OC (= NOMe) Me H 50-55
8-003 NOMe C (= NOMe) Me H 190 (decomp.)
――――――――――――――――――――――――――――――
[Table 11]

―――――――――――――――――――――――――――――――――
No. R⁶ R⁷ Z^c A m.p.(℃)
―――――――――――――――――――――――――――――――――
9-001 i-Pr Me Br H 93-96
9-002 c-Pr Me Br H 167-168
9-003 i-Pr Me C≡CMe C(O)CH₂OPh *1
9-004 i-Pr Me D1-7b(X¹=4-Cl) H *1
9-005 i-Pr Me C≡CSi(Me)₃ H *1
9-006 i-Pr Me C≡CMe H 176-178
9-007 c-Pr Me D1-7b(X¹=4-Cl) H *1
9-008 c-Pr Me C≡CMe H 170-173
9-009 c-Pr CH₂CF₃ Br H 128-130
9-010 Me CH₂CF₃ D1-7b(X¹=4-Cl) H 161-184
9-011 Me CH₂CF₃ C≡CMe H 158-161
9-012 Me CH₂CF₃ D1-7b(X¹=4-Cl) C(O)CH₂OPh *1
9-013 Me CH₂CF₃ C≡CMe C(O)CH₂OPh *1
9-014 i-Pr CH₂CF₃ D1-7b(X¹=4-Cl) H *1
9-015 i-Pr CH₂CF₃ C≡CMe H 189-192
9-016 Me CH₂CH₂OMe D1-7b(X¹=4-Cl) H 119-122
9-017 Me CH₂CH₂OMe Br H 70-74
9-018 i-Pr CH₂CH₂OMe Br H *1
9-019 c-Pr CH₂CH₂OMe Br H *1
9-020 c-Pr CH₂CH₂OMe D1-7b(X¹=4-Cl) H *1
9-021 c-Pr CH₂CH₂OMe C≡CMe H *1
9-022 i-Pr CH₂CH₂OMe D1-7b(X¹=4-Cl) H *1
9-023 i-Pr CH₂CH₂OMe C≡CMe H *1
9-024 Me CH₂CF₃ D1-108b(4-Cl) H 202-204
9-025 Me CH₂CF₃ D1-108b(4-Cl) C(O)(D1-103a) *1
9-026 Me CH₂CF₃ D1-108b(4-Cl) C(O)N(Me)₂ *1
9-027 Me CH₂CF₃ D1-108b(4-Cl) C(O)CH₂OPh *1
9-028 c-Pr Me Ph H 202-209
9-029 Me CH₂C(O)N(Me)₂ Br H *1
9-030 Me D1-103n Br H *1
9-031 Me CH₂C(O)NHPh Br H 121-124
9-032 Me Me OCH₂CN Me *1
9-033 Me Me OCH₂C(O)OMe Me 102-105
9-034 Me Me OCH₂CN H *1
9-035 Me Me OCH₂C(O)OMe H 121-123
9-036 Me Me C(O)OH H 184-187
9-037 Me Me C(O)NMe₂ H *1
9-038 Me Me C(O)NHCH₂CF₃ H *1
9-039 Me CH₂C(O)NHCH₂CH=CH₂ Br H *1
9-040 Me CH₂C(O)NHCH₂C≡CH Br H *1
9-041 Me CH₂C(O)NHCH₂Pr-c Br H *1
9-042 Me CH₂C(O)NHCH₂CH₂OMe Br H *1
9-043 Me CH₂C(O)NHCH₂CH₂SMe Br H *1
9-044 Me CH₂C(O)NHCH₂CN Br H *1
9-045 Me CH₂C(O)NHOMe Br H *1
9-046 Me CH₂C(O)NHCH₂C(O)OMe Br H *1
―――――――――――――――――――――――――――――――――
〔第１２表〕 ―――――――――――――――――――――――――――――――――
No. R ⁶ R ⁷ Z ^c A mp (℃)
―――――――――――――――――――――――――――――――――
9-001 i-Pr Me Br H 93-96
9-002 c-Pr Me Br H 167-168
9-003 i-Pr Me C≡CMe C (O) CH ₂ OPh * 1
9-004 i-Pr Me D1-7b (X ¹ = 4-Cl) H * 1
9-005 i-Pr Me C≡CSi (Me) ₃ H * 1
9-006 i-Pr Me C≡CMe H 176-178
9-007 c-Pr Me D1-7b (X ¹ = 4-Cl) H * 1
9-008 c-Pr Me C≡CMe H 170-173
9-009 c-Pr CH ₂ CF ₃ Br H 128-130
9-010 Me CH ₂ CF ₃ D1-7b (X ¹ = 4-Cl) H 161-184
9-011 Me CH ₂ CF ₃ C≡CMe H 158-161
9-012 Me CH ₂ CF ₃ D1-7b (X ¹ = 4-Cl) C (O) CH ₂ OPh * 1
9-013 Me CH ₂ CF ₃ C≡CMe C (O) CH ₂ OPh * 1
9-014 i-Pr CH ₂ CF ₃ D1-7b (X ¹ = 4-Cl) H * 1
9-015 i-Pr CH ₂ CF ₃ C≡CMe H 189-192
9-016 Me CH ₂ CH ₂ OMe D1-7b (X ¹ = 4-Cl) H 119-122
9-017 Me CH ₂ CH ₂ OMe Br H 70-74
9-018 i-Pr CH ₂ CH ₂ OMe Br H * 1
9-019 c-Pr CH ₂ CH ₂ OMe Br H * 1
9-020 c-Pr CH ₂ CH ₂ OMe D1-7b (X ¹ = 4-Cl) H * 1
9-021 c-Pr CH ₂ CH ₂ OMe C≡CMe H * 1
9-022 i-Pr CH ₂ CH ₂ OMe D1-7b (X ¹ = 4-Cl) H * 1
9-023 i-Pr CH ₂ CH ₂ OMe C≡CMe H * 1
9-024 Me CH ₂ CF ₃ D1-108b (4-Cl) H 202-204
9-025 Me CH ₂ CF ₃ D1-108b (4-Cl) C (O) (D1-103a) * 1
9-026 Me CH ₂ CF ₃ D1-108b (4-Cl) C (O) N (Me) ₂ * 1
9-027 Me CH ₂ CF ₃ D1-108b (4-Cl) C (O) CH ₂ OPh * 1
9-028 c-Pr Me Ph H 202-209
9-029 Me CH ₂ C (O) N (Me) ₂ Br H * 1
9-030 Me D1-103n Br H * 1
9-031 Me CH ₂ C (O) NHPh Br H 121-124
9-032 Me Me OCH ₂ CN Me * 1
9-033 Me Me OCH ₂ C (O) OMe Me 102-105
9-034 Me Me OCH ₂ CN H * 1
9-035 Me Me OCH ₂ C (O) OMe H 121-123
9-036 Me Me C (O) OH H 184-187
9-037 Me Me C (O) NMe ₂ H * 1
9-038 Me Me C (O) NHCH ₂ CF ₃ H * 1
9-039 Me CH ₂ C (O) NHCH ₂ CH = CH ₂ Br H * 1
9-040 Me CH ₂ C (O) NHCH ₂ C≡CH Br H * 1
9-041 Me CH ₂ C (O) NHCH ₂ Pr-c Br H * 1
9-042 Me CH ₂ C (O) NHCH ₂ CH ₂ OMe Br H * 1
9-043 Me CH ₂ C (O) NHCH ₂ CH ₂ SMe Br H * 1
9-044 Me CH ₂ C (O) NHCH ₂ CN Br H * 1
9-045 Me CH ₂ C (O) NHOMe Br H * 1
9-046 Me CH ₂ C (O) NHCH ₂ C (O) OMe Br H * 1
―――――――――――――――――――――――――――――――――
[Table 12]

――――――――――――――――――――――――――――――
No. R⁶ R^8a Z^c A m.p.(℃)
――――――――――――――――――――――――――――――
10-001 i-Pr C(O)OEt Br H 143-145
10-002 c-Pr C(O)OMe Br H 171-173
10-003 i-Pr H Br H 151-153
10-004 c-Pr H Br H 171-174
――――――――――――――――――――――――――――――
〔第１３表〕 ――――――――――――――――――――――――――――――
No. R ⁶ R ^8a Z ^c A mp (℃)
――――――――――――――――――――――――――――――
10-001 i-Pr C (O) OEt Br H 143-145
10-002 c-Pr C (O) OMe Br H 171-173
10-003 i-Pr H Br H 151-153
10-004 c-Pr H Br H 171-174
――――――――――――――――――――――――――――――
[Table 13]

――――――――――――――――――――――――――――――――
No. R⁶ R⁷ R¹⁰ A m.p.(℃)
――――――――――――――――――――――――――――――――
11-001 Me Me Me CH₂Ph *1
11-002 Me Me Me H 165-168
――――――――――――――――――――――――――――――――
〔第１４表〕 ――――――――――――――――――――――――――――――――
No. R ⁶ R ⁷ R ¹⁰ A mp (℃)
――――――――――――――――――――――――――――――――
11-001 Me Me Me CH ₂ Ph * 1
11-002 Me Me Me H 165-168
――――――――――――――――――――――――――――――――
[Table 14]

――――――――――――――――――――――――――――――
No. R⁶ R⁷ R¹¹ A m.p.(℃)
――――――――――――――――――――――――――――――
12-001 Me Me Me CH₂Ph *1
12-002 Me Me Me H *1
――――――――――――――――――――――――――――――
〔第１５表〕 ――――――――――――――――――――――――――――――
No. R ⁶ R ⁷ R ¹¹ A mp (℃)
――――――――――――――――――――――――――――――
12-001 Me Me Me CH ₂ Ph * 1
12-002 Me Me Me H * 1
――――――――――――――――――――――――――――――
[Table 15]

―――――――――――――――――――――――――――――――――
No. Z^a Z^c Z^e R⁶ A m.p.(℃)
―――――――――――――――――――――――――――――――――
13-001 OMe Br Me Et H *1
13-002 OMe Me Me c-Pr H 81-84
13-003 OMe Me Me Et H 81-84
13-004 OMe Ph Me Et H 178-181
13-005 OMe Me Me c-Pr C(O)(D1-103a) *1
13-006 OMe Me Me c-Pr C(O)Bu-t *1
13-007 OMe Me Me Et C(O)(D1-103a) *1
13-008 OMe Me Me Et C(O)(D1-103j) *1
13-009 OMe Me Me Et C(O)Bu-t *1
13-010 OMe Me Me Et C(O)CH₂OPh *1
13-011 OMe Me Me Et C(O)OMe *1
13-012 c-Pr Me Me Me H *1
13-013 CH=CH₂ Me Me Me H *1
13-014 NO₂ Me Me Me H *1
13-015 OMe Me Me Me C(O)OCH₂CH₂OMe *1
13-016 OMe Me Me Me C(O)OCH₂Ph *1
13-017 OMe Me Me Me C(O)OCH₂CH=CH₂ *1
13-018 OMe Me Me Me C(O)C(Me)₂{D1-108d(4-Cl)} *1
13-019 OEt Me Me c-Pr H 127-130
13-020 OEt Me Me c-Pr C(O)C(Me)₂{D1-108d(4-Cl)} 114-119
13-021 OEt Me Me c-Pr C(O)CH₂OPh *1
13-022 OEt Me Me c-Pr C(O)Bu-t *1
13-023 OEt Me Me c-Pr C(O)OEt *1
13-024 OEt Me Me c-Pr C(O)(D1-103a) *1
―――――――――――――――――――――――――――――――――
〔第１６表〕 ―――――――――――――――――――――――――――――――――
No. Z ^a Z ^c Z ^e R ⁶ A mp (℃)
―――――――――――――――――――――――――――――――――
13-001 OMe Br Me Et H * 1
13-002 OMe Me Me c-Pr H 81-84
13-003 OMe Me Me Et H 81-84
13-004 OMe Ph Me Et H 178-181
13-005 OMe Me Me c-Pr C (O) (D1-103a) * 1
13-006 OMe Me Me c-Pr C (O) Bu-t * 1
13-007 OMe Me Me Et C (O) (D1-103a) * 1
13-008 OMe Me Me Et C (O) (D1-103j) * 1
13-009 OMe Me Me Et C (O) Bu-t * 1
13-010 OMe Me Me Et C (O) CH ₂ OPh * 1
13-011 OMe Me Me Et C (O) OMe * 1
13-012 c-Pr Me Me Me H * 1
13-013 CH = CH ₂ Me Me Me H * 1
13-014 NO ₂ Me Me Me H * 1
13-015 OMe Me Me Me C (O) OCH ₂ CH ₂ OMe * 1
13-016 OMe Me Me Me C (O) OCH ₂ Ph * 1
13-017 OMe Me Me Me C (O) OCH ₂ CH = CH ₂ * 1
13-018 OMe Me Me Me C (O) C (Me) ₂ {D1-108d (4-Cl)} * 1
13-019 OEt Me Me c-Pr H 127-130
13-020 OEt Me Me c-Pr C (O) C (Me) ₂ {D1-108d (4-Cl)} 114-119
13-021 OEt Me Me c-Pr C (O) CH ₂ OPh * 1
13-022 OEt Me Me c-Pr C (O) Bu-t * 1
13-023 OEt Me Me c-Pr C (O) OEt * 1
13-024 OEt Me Me c-Pr C (O) (D1-103a) * 1
―――――――――――――――――――――――――――――――――
[Table 16]

――――――――――――――――――――――――――――――――
No. Z^a Z^c Z^e R⁶ R^8a R^9a A m.p.(℃)
――――――――――――――――――――――――――――――――
14-001 OMe Br Me c-Pr H H H *1
14-002 OMe Br Me Et H H H *1
14-003 OMe Me Me Et H H H *1
14-004 OEt Me Me c-Pr H H H 149-151
14-005 OCF₂H Me Me c-Pr C(O)OMe H H 158-161
14-006 OCF₂H Me Me c-Pr H H H 167-169
14-007 OMe Me Me Me F C(O)OEt H *1
――――――――――――――――――――――――――――――――
〔第１７表〕 ――――――――――――――――――――――――――――――――
No. Z ^a Z ^c Z ^e R ⁶ R ^8a R ^9a A mp (℃)
――――――――――――――――――――――――――――――――
14-001 OMe Br Me c-Pr HHH * 1
14-002 OMe Br Me Et HHH * 1
14-003 OMe Me Me Et HHH * 1
14-004 OEt Me Me c-Pr HHH 149-151
14-005 OCF ₂ H Me Me c-Pr C (O) OMe HH 158-161
14-006 OCF ₂ H Me Me c-Pr HHH 167-169
14-007 OMe Me Me Me FC (O) OEt H * 1
――――――――――――――――――――――――――――――――
[Table 17]

―――――――――――――――――――――――――――――――
No. Z^a Z^c Z^e R⁷ A m.p.(℃)
―――――――――――――――――――――――――――――――
15-001 OMe Me Me CH₂C≡CH H *1
15-002 OMe Me Me CH₂CH=CH₂ H *1
15-003 OMe Me Me CH₂Pr-c H *1
15-004 OMe Me Me CH₂CH₂OMe H *1
15-005 OMe Me Me CH₂CF₃ H *1
15-006 OMe Me Me CH₂CN H *1
15-007 OMe Me Me CH₂CH₂OMe C(O)(D1-103a) *1
15-008 OMe Me Me CH₂CH₂OMe C(S)N(Me)₂ *1
15-009 OMe Me Me CH₂CF₃ C(O)Bu-t *1
15-010 OMe Me Me CH₂CF₃ C(O)N(Me)₂ *1
15-011 OMe Me Me CH₂CN S(O)₂Me *1
15-012 OMe Me Me CH₂CN C(O)N(Et)₂ *1
15-013 OMe Me Me CH₂C≡CH C(O)OMe *1
15-014 OMe Me Me CH₂Pr-c C(O)SBu-t *1
15-015 OMe Me Me CH₂CH=CH₂ C(O)CH₂OPh *1
15-016 OMe Me Me CH₂C≡CH C(O)(D1-103j) *1
15-017 OMe Me Me CH₂CH=CH₂ C(O)(D1-103l) *1
15-018 OMe Me Me CH₂Pr-c C(O)(D1-103k) *1
15-019 OMe Me Me CH₂C≡CH C(O)(D1-103a) *1
15-020 OMe Me Me CH₂CH=CH₂ C(O)(D1-103a) *1
15-021 OMe Me Me CH₂Pr-c C(O)(D1-103a) *1
15-022 OMe Me Me H H 186-188
15-023 OMe Me Me Et H 79-83
15-024 OMe Me Me Et C(O)(D1-103a) *1
15-024(*2) *1
15-025 OMe Me Me Et S(O)₂{D1-108d(4-Me)} *1
15-026 OMe Me Me Pr-i C(O)(D1-103a) *1
15-027 OMe Me Me Pr-i S(O)₂{D1-108d(4-Me)} *1
15-028 OMe Me Me Pr-i H *1
15-029 OMe Me Me Et C(O)Bu-t *1
15-030 OMe Me Me Et C(O)O{D1-108d(4-Me)} *1
15-031 OMe Me Me Pr-i C(O)Bu-t *1
15-032 OMe Me Me Pr-i C(O)O{D1-108d(4-Me)} *1
15-033 OMe Me Me Pr-i C(O)CH₂OPh *1
15-034 OMe Me Me Pr-i CH₂OCH₂CH₂OMe *1
15-035 OMe Me Me Pr-n H *1
15-036 OMe Me Me Bu-t H 154-157
15-037 OMe Me Me Bu-n H *1
15-038 OMe Me Me Et C(O){D1-108d(2-Me)} *1
15-039 OMe Me Me Et CH₂OCH₂CH₂OMe *1
15-040 OMe Me Me Et C(O)C(Me)₂Ph *1
15-041 OMe Me Me Et C(O){D1-108d(4-NO₂)} *1
15-042 Cl Me Me Et H *1
15-043 Cl Me Me Pr-i H 75-77
15-044 OMe Me Me Et C(O)(D1-103j) *1
15-045 OMe Me Me Et C(O)(D1-103k) *1
15-046 OMe Me Me Bu-s H *1
15-047 OMe Me Me CH₂CF₂CF₂H H *1
―――――――――――――――――――――――――――――――
〔第１８表〕 ―――――――――――――――――――――――――――――――
No. Z ^a Z ^c Z ^e R ⁷ A mp (℃)
―――――――――――――――――――――――――――――――
15-001 OMe Me Me CH ₂ C≡CH H * 1
15-002 OMe Me Me CH ₂ CH = CH ₂ H * 1
15-003 OMe Me Me CH ₂ Pr-c H * 1
15-004 OMe Me Me CH ₂ CH ₂ OMe H * 1
15-005 OMe Me Me CH ₂ CF ₃ H * 1
15-006 OMe Me Me CH ₂ CN H * 1
15-007 OMe Me Me CH ₂ CH ₂ OMe C (O) (D1-103a) * 1
15-008 OMe Me Me CH ₂ CH ₂ OMe C (S) N (Me) ₂ * 1
15-009 OMe Me Me CH ₂ CF ₃ C (O) Bu-t * 1
15-010 OMe Me Me CH ₂ CF ₃ C (O) N (Me) ₂ * 1
15-011 OMe Me Me CH ₂ CN S (O) ₂ Me * 1
15-012 OMe Me Me CH ₂ CN C (O) N (Et) ₂ * 1
15-013 OMe Me Me CH ₂ C≡CH C (O) OMe * 1
15-014 OMe Me Me CH ₂ Pr-c C (O) SBu-t * 1
15-015 OMe Me Me CH ₂ CH = CH ₂ C (O) CH ₂ OPh * 1
15-016 OMe Me Me CH ₂ C≡CH C (O) (D1-103j) * 1
15-017 OMe Me Me CH ₂ CH = CH ₂ C (O) (D1-103l) * 1
15-018 OMe Me Me CH ₂ Pr-c C (O) (D1-103k) * 1
15-019 OMe Me Me CH ₂ C≡CH C (O) (D1-103a) * 1
15-020 OMe Me Me CH ₂ CH = CH ₂ C (O) (D1-103a) * 1
15-021 OMe Me Me CH ₂ Pr-c C (O) (D1-103a) * 1
15-022 OMe Me Me HH 186-188
15-023 OMe Me Me Et H 79-83
15-024 OMe Me Me Et C (O) (D1-103a) * 1
15-024 (* 2) * 1
15-025 OMe Me Me Et S (O) ₂ {D1-108d (4-Me)} * 1
15-026 OMe Me Me Pr-i C (O) (D1-103a) * 1
15-027 OMe Me Me Pr-i S (O) ₂ {D1-108d (4-Me)} * 1
15-028 OMe Me Me Pr-i H * 1
15-029 OMe Me Me Et C (O) Bu-t * 1
15-030 OMe Me Me Et C (O) O {D1-108d (4-Me)} * 1
15-031 OMe Me Me Pr-i C (O) Bu-t * 1
15-032 OMe Me Me Pr-i C (O) O {D1-108d (4-Me)} * 1
15-033 OMe Me Me Pr-i C (O) CH ₂ OPh * 1
15-034 OMe Me Me Pr-i CH ₂ OCH ₂ CH ₂ OMe * 1
15-035 OMe Me Me Pr-n H * 1
15-036 OMe Me Me Bu-t H 154-157
15-037 OMe Me Me Bu-n H * 1
15-038 OMe Me Me Et C (O) {D1-108d (2-Me)} * 1
15-039 OMe Me Me Et CH ₂ OCH ₂ CH ₂ OMe * 1
15-040 OMe Me Me Et C (O) C (Me) ₂ Ph * 1
15-041 OMe Me Me Et C (O) {D1-108d (4-NO ₂ )} * 1
15-042 Cl Me Me Et H * 1
15-043 Cl Me Me Pr-i H 75-77
15-044 OMe Me Me Et C (O) (D1-103j) * 1
15-045 OMe Me Me Et C (O) (D1-103k) * 1
15-046 OMe Me Me Bu-s H * 1
15-047 OMe Me Me CH ₂ CF ₂ CF ₂ HH * 1
―――――――――――――――――――――――――――――――
[Table 18]

――――――――――――――――――――――――――――――――
No. Z^a Z^b Z^c Z^e A m.p.(℃)
――――――――――――――――――――――――――――――――
16-001 Me Cl Me Me H *1
――――――――――――――――――――――――――――――――
〔第１９表〕 ――――――――――――――――――――――――――――――――
No. Z ^a Z ^b Z ^c Z ^e A mp (℃)
――――――――――――――――――――――――――――――――
16-001 Me Cl Me Me H * 1
――――――――――――――――――――――――――――――――
[Table 19]

―――――――――――――――――――――――――――――――――
No. Z^a Z^c Z^e R⁶ A⁺ m.p.(℃)
―――――――――――――――――――――――――――――――――
17-001 Me Me Me Me K⁺ *1
17-002 Me Me Me Me Na⁺ *1
―――――――――――――――――――――――――――――――――
本発明化合物のうち、融点の記載のない化合物の^１Ｈ−ＮＭＲデータを第２０表に示す。 ―――――――――――――――――――――――――――――――――
No. Z ^a Z ^c Z ^e R ⁶ A ⁺ mp (℃)
―――――――――――――――――――――――――――――――――
17-001 Me Me Me Me K ⁺ * 1
17-002 Me Me Me Me Na ⁺ * 1
―――――――――――――――――――――――――――――――――
Of the compounds of the present invention, Table ¹ shows ¹ H-NMR data of compounds having no melting point.

尚、プロトン核磁気共鳴ケミカルシフト値は、基準物質としてＭｅ_４Ｓｉ（テトラメチルシラン）を用い、重クロロホルム溶媒中で、３００ＭＨｚにて測定した。また、第２０表の記号は下記の意味を表す。ｓ：シングレット、ｂｒｓ：ブロードシングレット、ｄ：ダブレット、ｔ：トリプレット、ｍ：マルチプレット。また、２種以上の構造異性体が存在する場合に解析が可能なシグナルについて、各々のケミカルシフト値を「ａｎｄ」と記載した。尚、表中の「*3」と記載は、ヒドロキシのプロトンに相当するシグナルが観測されなかったことを表す。 The proton nuclear magnetic resonance chemical shift value was measured at 300 MHz in deuterated chloroform solvent using Me ₄ Si (tetramethylsilane) as a reference substance. Moreover, the symbol of Table 20 represents the following meaning. s: singlet, brs: broad singlet, d: doublet, t: triplet, m: multiplet. In addition, regarding a signal that can be analyzed when two or more kinds of structural isomers exist, each chemical shift value is described as “and”. In the table, “* 3” indicates that a signal corresponding to a hydroxy proton was not observed.

〔第２０表〕
――――――――――――――――――――――――――――――――――――――
No. ¹H-NMR (CDCl₃, Me₄Si, 300MHz)
――――――――――――――――――――――――――――――――――――――
1-004;
δ6.85-6.81 (m, 2H), 3.87-3.82 (m, 3H), 3.70-2.18 (m, 8H), 2.15-1.78 (m, 9H), 1.08 and 1.06 (s, 9H).
1-005;
δ6.90-6.85 (m, 2H), 3.87-3.82 (m, 3H), 3.77-2.18 (m, 8H), 2.17-1.98 (m, 9H), 1.97-1.83 (m, 3H).
1-006;
δ6.92-6.87 (m, 2H), 3.84 (s, 3H), 3.37-2.60 (m, 7H), 2.40-2.24 (m, 4H), 2.13-2.02 (m, 6H), 1.97-1.83 (m, 3H).
1-007;
δ6.90-6.85 (m, 2H), 5.90-5.67 (m, 1H), 5.28-5.07 (m, 2H), 4.50-4.40 and 4.23-4.15 (m, 2H), 3.88-3.78 (m, 3H), 3.00-1.85 (m, 17H).
1-008;
δ6.90-6.80 (m, 2H), 4.60-4.48 and 4.38-4.30 (m, 2H), 3.90-3.75 (m, 3H), 3.31-2.35 (m, 6H), 2.33-2.00 (m, 9H), 1.97-1.85 (m, 3H).
1-009;
δ7.28-7.03 (m, 5H), 6.92-6.80 (m, 2H), 4.97-4.92 and 4.73-4.68 (m, 2H), 3.86-3.77 (m, 3H), 3.31-1.80 (m, 17H).
1-009a-1;
δ7.35-7.30 (m, 3H), 7.20-7.15 (m, 2H), 6.90-6.85 (m, 2H), 4.95 (s, 2H), 3.84 (s, 3H), 3.00-2.80 (m, 3H), 2.65-2.55 (m, 1H), 2.27 (s, 3H), 2.25-2.15 (m, 1H), 2.10-2.00 (m, 6H), 1.86 (s, 3H).
1-009a-2;
δ7.35-7.30 (m, 3H), 7.20-7.15 (m, 2H), 6.90-6.85 (m, 2H), 4.95 (s, 2H), 3.80 (s, 3H), 2.95-2.80 (m, 2H), 2.76-2.70 (m, 1H), 2.66-2.57 (m, 2H), 2.27 (s, 3H), 2.10-2.00 (m, 6H), 1.91 (s, 3H).
1-009b-1;
δ7.31-7.28 (m, 3H), 7.10-7.07 (m, 2H), 6.87-6.85 (m, 2H), 4.72 (s, 2H), 3.84 (s, 3H), 3.30-3.20 (m, 1H), 2.90-2.80 (m, 1H), 2.80-2.70 (m, 1H), 2.42-2.37 (m, 1H), 2.30-2.23 (m, 4H), 2.08-2.05 (m, 6H), 1.86 (s, 3H).
1-009b-2;
δ7.32-7.28 (m, 3H), 7.10-7.07 (m, 2H), 6.88-6.86 (m, 2H), 4.74 (s, 2H), 3.83 (s, 3H), 3.29-3.24 (m, 1H), 2.82-2.63 (m, 3H), 2.39-2.34 (m, 1H), 2.28 (s, 3H), 2.10 (s, 3H), 2.05 (s, 3H), 1.92 (s, 3H).
1-010;
δ7.96-7.15 (m, 5H), 6.90-6.87 (m, 2H), 3.88-3.75 (m, 3H), 3.55-1.83 (m, 17H).
1-011;
δ6.98-6.75 (m, 2H), 4.20-4.77 (m, 5H), 3.28-2.60 (m, 6H), 2.45-1.80 (m, 16H).
1-012;
δ6.92-6.80 (m, 2H), 4.69 and 4.53 and 4.35and 4.25 (s, 2H), 3.88-3.58 (m, 6H), 3.38-3.28 and 3.00-1.80 (m, 17H).
1-013;
δ6.98-6.87 (m, 2H), 4.56 and 4.55 and 4.46 and 4.44 (s, 2H), 3.92-3.82 (m, 3H), 3.36-3.25 and 3.10-2.60 (m, 4H), 2.60-1.80 (m, 13H).
1-014;
δ6.91-6.85 (m, 2H), 3.85 (s, 3H), 3.77 and 3.70 (s, 3H), 3.35-3.18 (m, 1H), 3.10-2.65 (m, 3H), 2.35-2.22 (m, 4H), 2.10-2.02 (m, 6H), 1.90-1.83 (m, 3H).
1-015;
δ6.91-6.82 (m, 2H), 3.90-3.80 (m, 3H), 3.31-3.20 (m, 1H), 3.07-2.78 (m, 3H), 2.35-2.20 (m, 4H), 2.10-2.00 (m, 6H), 1.95-1.83 (m, 3H), 1.75-1.50 (m, 1H), 1.07-0.80 (m, 4H).
1-016;
δ6.91-6.77 (m, 2H), 3.90-3.77 (m, 3H), 3.68-3.42 (m, 2H), 3.28-2.48 (m, 4H), 2.35-1.80 (m, 13H), 1.37 (s, 3H), 1.16 (s, 3H).
1-017;
δ7.17-7.05 (m, 2H), 7.00-6.90 (m, 1H), 6.87-6.78 (m, 2H), 6.65-6.55 (m, 2H), 3.87-3.82 (m, 3H), 3.56-3.45 and 3.18-2.20 (m, 8H), 2.19-1.70 (m, 9H), 1.50-1.38 (m, 6H).
1-031;
δ6.90-6.85 (m, 2H), 4.55 and 4.34 (s, 2H), 3.88-3.80 (m, 3H), 3.30-2.35 (m, 4H), 2.30-1.80 (m, 13H), 1.20-1.10 (m, 9H).
1-033;
δ6.90-6.83 (m, 2H), 3.84 (s, 3H), 3.28-3.15 (m, 1H), 3.07-2.96 (m, 1H), 2.90-2.75 (m, 2H), 3.40-3.20 (m, 6H), 2.06 (s, 3H), 2.04 (s, 3H), 1.86 (s, 3H), 1.58-1.45 (m, 2H), 1.35-1.10 (m, 10H), 0.92-0.83 (m, 3H).
1-034;
δ6.90-6.80 (m, 2H), 3.90-3.80 (m, 3H), 3.35-3.22 (m, 1H), 3.09-2.98 (m, 1H), 2.96-2.70 (m, 2H), 2.35-2.20 (m, 4H), 2.12-2.00 (m, 6H), 1.92-1.78 (m, 6H), 1.48-1.35 (m, 6H).
1-035;
δ6.90-6.82 (m, 2H), 3.84 (s, 3H), 3.28-3.15 (m, 1H), 3.08-2.97 (m, 1H), 2.90-2.75 (m, 2H), 2.50-2.20 (m, 8H), 2.10-2.02 (m, 6H), 1.86 (s, 3H), 1.80-0.70 (m, 11H).
1-036;
δ6.90-6.80 (m, 2H), 3.87-3.80 (m, 3H), 3.26-3.15 (m, 1H), 3.10-3.00 (m, 1H), 2.90-2.78 (m, 2H), 2.38-2.13 (m, 4H), 2.10-2.00 (m, 6H), 1.86 (s, 3H), 1.58-1.40 (m, 5H).
1-037;
δ6.90-6.80 (m, 2H), 4.07-3.52 (m, 14H), 2.45-2.00 (m, 10H), 1.90-1.84 (m, 3H).
1-039;
δ6.90-6.80 (m, 2H), 3.84 (s, 3H), 3.25-3.13 (m, 1H), 3.12-3.01 (m, 1H), 2.90-2.75 (m, 2H), 2.38-2.20 (m, 4H), 2.06 (s, 3H), 2.05 (s, 3H), 1.84 (s, 3H), 1.48-1.35 (m, 6H).
1-042;
δ6.88-6.83 (m, 2H), 3.87-3.82 (m, 3H), 3.32-2.22 (m, 9H), 2.15-2.03 (m, 6H), 1.89-1.85 (m, 3H), 1.59-1.47 (m, 3H).
1-043;
δ7.28-7.17 (m, 2H), 7.02-6.96 (m, 1H), 6.89-6.83 (m, 2H), 6.74-6.60 (m, 2H), 4.65 and 4.62 (s, 2H), 3.84 (s, 3H), 3.29-3.18 (m, 1H), 3.12-3.00 (m, 1H), 2.92-2.80 (m, 2H), 2.40-2.20 (m, 4H), 2.10-2.00 (m, 6H), 1.90-1.83 (m, 3H).
1-044;
δ7.28-7.17 (m, 2H), 6.88-6.83 (m, 2H), 6.63-6.48 (m, 2H), 4.62 and 4.58 (s, 2H), 3.84 (s, 3H), 3.70-2.22 (m, 8H), 2.03-1.95 (m, 6H), 1.86 (s, 3H).
1-045(*3);
δ8.52-8.47 (m, 1H), 8.04-7.98 (m, 1H), 7.91-7.83 (m, 1H), 7.46-7.38 (m, 1H), 6.93-6.85 (m, 2H), 4.10 (s, 3H), 3.43-3.35 (m, 1H), 3.15-2.90 (m, 3H), 2.58-2.48 (m, 1H), 2.26 (s, 3H), 2.17 (s, 3H), 2.11 (s, 3H).
1-046;
δ11.85 (brs, 1H), 6.95-6.85 (m, 2H), 3.95-3.78 (m, 3H), 3.40-2.02 (m, 14H), 1.08-0.70 (m, 5H).
1-047(*3);
δ8.14-7.34 (m, 5H), 6.95-6.85 (m, 2H), 4.05-3.88 (m, 3H), 3.35-2.00 (m, 14H).
1-048;
δ11.78-11.65 (m, 1H), 7.00-6.83 (m, 2H), 3.97-3.80 (m, 3H), 3.55-2.00 (m, 15H), 1.25-1.00 (m, 6H).
1-051;
δ7.06-6.98 (m, 2H), 6.87-6.80 (m, 2H), 6.52-6.44 (m, 2H), 3.87-3.82 (m, 3H), 3.62-2.13 (m, 8H), 2.08-2.00 (m, 6H), 1.87 and 1.82 (s, 3H), 1.58-1.40 (m, 6H).
1-060;
δ7.24-7.22 (m, 2H), 7.00-6.90 (m, 1H), 6.88-6.78 (m, 2H), 6.72-6.60 (m, 2H), 4.78-4.65 (m, 1H), 3.90-3.76 (m, 3H), 3.25-2.96 (m, 2H), 2.89-2.69 (m, 2H), 2.35-2.20 (m, 4H), 2.10-1.94 (m, 6H), 1.88-1.80 (m, 3H), 1.55-1.45 (m, 3H).
1-063;
δ7.30-7.15 (m, 2H), 7.03-6.94 (m, 1H), 6.89-6.82 (m, 2H), 6.75-6.60 (m, 2H), 4.67-4.60 (m, 2H), 3.88-3.77 (m, 3H), 3.33-1.80 (m, 14H), 0.90-0.65 (m, 5H).
1-064;
δ7.40-7.30 (m, 1H), 7.12-6.77 (m, 4H), 6.53-6.27 (m, 1H), 4.77-4.59 (m, 2H), 3.90-2.80 (m, 6H), 2.67-2.17 (m, 5H), 2.15-1.80 (m, 9H).
1-065;
δ7.18-7.05 (m, 1H), 7.00-6.95 (m, 1H), 6.88-6.72 (m, 3H), 6.60-6.42 (m, 1H), 4.65-4.53 (m, 2H), 3.88-2.45 (m, 7H), 2.37-1.85 (m, 13H).
1-067;
δ7.03-6.68 (m, 5H), 6.60-6.38 (m, 1H), 4.73-4.65 (m, 2H), 3.90-3.80 (m, 6H), 3.75-2.15 (m, 8H), 2.10-2.00 (m, 6H), 1.90-1.82 (m, 3H).
1-068;
δ7.15-7.07 (m, 1H), 6.90-6.80 (m, 2H), 6.60-6.52 (m, 1H), 6.43-6.37 (m, 1H), 6.30-6.22 (m, 1H), 4.63 (s, 2H), 3.83 (s, 3H), 3.76 (s, 3H), 3.30-3.20 (m, 1H), 3.10-3.00 (m, 1H), 2.92-2.80 (m, 2H), 2.36-2.23 (m, 4H), 2.04 (s, 3H), 2.03 (s, 3H), 1.54 (s, 3H).
1-069;
δ6.92-6.53 (m, 6H), 4.70-4.52 (m, 2H), 3.84 (s, 3H), 3.76 (s, 3H), 3.30-2.10 (m, 8H), 2.09-1.95 (m, 6H), 1.93-1.82 (m, 3H).
1-071;
δ7.88-7.80 (m, 1H), 7.40-7.20 (m, 1H), 7.14-7.03 (m, 1H), 6.90-6.82 (m, 2H), 6.57-6.50 and 6.37-6.29 (m, 1H), 4.78 and 4.74 (s, 2H), 3.87-3.82 (m, 3H), 3.70-2.22 (m, 8H), 2.14-1.97 (m, 6H), 1.90-1.85 (m, 3H).
1-072;
δ7.05-6.97 (m, 2H), 6.92-6.85 (m, 2H), 6.65-6.50 (m, 2H), 4.65-4.55 (m, 2H), 3.90-3.80 (m, 3H), 3.29-2.79 (m, 4H), 2.38-2.22 (m, 7H), 2.10-2.02 (m, 6H), 1.88-1.72 (m, 3H).
1-073;
δ6.93-6.80 (m, 4H), 6.67-6.50 (m, 2H), 4.65-4.55 (m, 2H), 3.84 (s, 3H), 3.28-2.45 (m, 4H), 2.35-2.20 (m, 4H), 2.10-1.95 (m, 6H), 1.93-1.80 (m, 3H).
1-074;
δ7.35-6.70 (m, 6H), 4.67 and 4.64 (s, 2H), 3.84 (s, 3H), 3.30-2.20 (m, 8H), 2.15-1.95 (m, 6H), 1.92-1.85 (m, 3H).
1-075;
δ7.37-6.12 (m, 5H), 4.73-4.65 (m, 2H), 3.88-3.80 (m, 3H), 3.72-2.20 (m, 8H), 2.10-1.95 (m, 6H), 1.90-1.82 (m, 3H).
1-076;
δ6.87-6.82 (m, 2H), 4.50-4.40 (m, 1H), 3.90-3.82 (m, 3H), 3.80-1.40 (m, 23H).
1-077;
δ6.87 (s, 2H), 4.25-4.20 (m, 2H), 3.90 (s, 3H), 3.72 (s, 3H), 3.15-2.90 (m, 2H), 2.85-2.70 (m, 2H), 2.60-2.50 (m, 1H), 2.26 (s, 3H), 2.09 (s, 6H).
1-079;
δ9.95-9.87 (m, 1H), 7.77-7.68 (m, 2H), 6.90-6.65 (m, 4H), 4.73 and 4.69 (s, 2H), 3.88-3.82 (m, 3H), 3.70-2.45 (m, 5H), 2.37-1.85 (m, 12H).
1-080;
δ7.88-7.80 (m, 2H), 6.86 (brs, 2H), 6.75-6.57 (m, 2H), 4.70 and 4.67 (s, 2H), 3.84 (s, 3H), 3.70-3.58and3.30-2.45 (m, 7H), 2.40-2.22 (m, 4H), 2.15-1.95 (m, 6H), 1.86 (s, 3H).
1-081;
δ7.33-7.20 (m, 2H), 6.86 (brs, 2H), 6.58-6.42 (m, 2H), 4.61 (s, 2H), 3.84 (s, 3H), 3.27-3.17 (m, 1H), 3.12-3.00 (m, 1H), 2.90-2.79 (m, 2H), 2.37-2.25 (m, 4H), 2.02 (s, 3H), 2.00 (s, 3H), 1.86 (s, 3H).
1-082;
δ7.52-7.40 (m, 2H), 6.86 (brs, 2H), 6.48-6.30 (m, 2H), 4.61 and 4.57 (s, 2H), 3.84 (s, 3H), 3.27-3.15 (m, 1H), 3.12-3.00 (m, 1H), 2.90-2.79 (m, 2H), 2.35-2.25 (m, 4H), 2.05-1.98 (m, 6H), 1.86 (s, 3H).
1-083;
δ7.80-7.70 (m, 2H), 7.65-7.58 (m, 1H), 7.50-7.30 (m, 2H)7.15-7.05 (m, 1H), 6.92-6.85 (m, 1H), 6.80 (brs, 2H), 4.77 and 4.75 (s, 2H), 3.82 (s, 3H), 3.32-3.20 (m, 1H), 3.12-3.00 (m, 1H), 2.95-2.80 (m, 2H), 2.35-2.23 (m, 4H), 2.08-1.98 (m, 6H), 1.86 (s, 3H).
1-087;
δ8.61 (s, 1H), 8.06 (s, 1H), 7.70-7.61 (m, 2H), 7.10-7.05 (m, 2H), 6.87-6.65 (m, 4H), 4.75-4.69 (m, 1H), 3.84 (s, 3H)3.28-2.81 (m, 4H)2.40-1.95 (m, 10H)1.83 (s, 3H), 1.52 (m, 3H).
1-088;
δ6.86 (brs, 2H), 6.81-6.78 (m, 1H), 3.84 (s, 3H), 3.38-3.27 (m, 1H), 3.09-2.98 (m, 1H), 2.95-2.80 (m, 2H), 2.55-2.45 (m, 4H), 2.35-2.21 (m, 4H), 2.10-2.01 (m, 6H), 2.00-1.90 (m, 2H), 1.86 (s, 3H).
1-089;
δ6.86 (brs, 2H), 3.84 (s, 3H), 3.40-3.27 (m, 1H), 3.10-2.98 (m, 1H), 2.97-2.70 (m, 4H), 2.58-2.50 (m, 2H), 2.35-2.23 (m, 4H), 2.10-1.86 (m, 11H).
1-090;
δ7.08-6.97 (m, 1H), 6.87 (brs, 2H), 5.83-5.75 (m, 1H), 3.84 (s, 3H), 3.37-3.26 (m, 1H), 3.08-2.98 (m, 1H), 2.93-2.80 (m, 2H), 2.35-2.10 (m, 6H), 2.07 (s, 3H), 2.06 (s, 3H), 1.86 (s, 3H), 1.55-1.40 (m, 2H), 0.91 (t, J=7.2Hz, 3H).
1-091;
δ7.52-7.49 (m, 1H), 7.40 (d, J=15.6Hz, 1H), 6.87 (brs, 2H), 6.68-6.65 (m, 1H), 6.50-6.47 (m, 1H), 6.24 (d, J=15.6Hz, 1H), 3.84 (s, 3H), 3.40-3.29 (m, 1H), 3.10-2.99 (m, 1H), 2.98-2.81 (m, 2H), 2.35-2.25 (m, 4H), 2.09 (s, 3H), 2.07 (s, 3H), 1.86 (s, 3H).
1-092;
δ6.87 (brs, 2H), 4.24 and 4.19 (brs, 2H), 3.84 (s, 3H), 3.75-2.22 (m, 10H), 2.15-2.02 (m, 6H), 1.90-1.85 (m, 3H).
1-093;
δ6.86 (brs, 2H), 4.05 (s, 2H), 3.84 (s, 3H), 3.33 (s, 3H), 3.32-3.20 (m, 1H), 3.10-3.00 (m, 1H), 2.92-2.80 (m, 2H), 2.35-2.23 (m, 4H), 2.10-2.02 (m, 6H), 1.87 (s, 3H).
1-094;
δ7.40-7.15 (m, 5H), 6.86 (brs, 2H), 4.46and4.38 (s, 2H), 4.11 and 4.08 (s, 2H), 3.84and3.83 (s, 3H), 3.78-2.20 (m, 8H), 2.06 (s, 3H), 2.04 (s, 3H), 1.87 (s, 3H).
1-095;
δ6.88 (brs, 2H), 3.84 (s, 3H), 3.30-3.18 (m, 1H), 3.08-2.98 (m, 1H), 2.92-2.79 (m, 2H), 2.35-2.23 (m, 4H), 2.10-2.03 (m, 6H), 1.98 (s, 3H), 1.86 (s, 3H).
1-096;
δ6.89 (brs, 2H), 3.83 (s, 3H), 3.28-3.18 (m, 1H), 3.08-2.99 (m, 1H), 2.90-2.88 (m, 2H), 2.35-2.24 (m, 4H), 2.07 (s, 3H), 2.06 (s, 3H), 1.86 (s, 3H), 0.23 (s, 9H).
1-098;
δ6.84 (brs, 2H), 4.03 (s, 3H), 3.84 (s, 3H), 3.39 (s, 2H), 3.32-3.20 (m, 1H), 3.12-3.00 (m, 1H), 2.95-2.80 (m, 2H), 2.37-2.22 (m, 4H), 2.09 (s, 3H), 2.08 (s, 3H), 1.92 (s, 3H), 1.86 (s, 3H).
1-099;
δ6.87-6.80 (m, 2H), 3.84 and 3.78 (s, 3H), 3.40-2.28 (m, 5H), 2.26-2.22 (m, 3H), 2.15-2.08 (m, 6H), 1.88 and 1.86 (s, 3H).
1-100;
δ6.85 (brs, 2H), 6.32-6.28 (m, 1H), 3.84 (s, 3H), 3.37-3.28 (m, 1H), 3.16-3.05 (m, 1H), 3.00-2.80 (m, 2H), 2.50-2.45 (m, 3H), 2.40-2.29 (m, 1H), 2.24 (s, 3H), 2.11 (s, 3H), 2.10 (s, 3H), 1.88 (s, 3H).
1-101;
δ6.87 (brs, 2H), 3.84 (s, 3H), 3.45-3.33 (m, 1H), 3.13-2.80 (m, 3H), 2.65 (s, 3H), 2.55 (s, 3H), 2.37-2.24 (m, 4H), 2.10 (s, 3H), 2.08 (s, 3H), 1.88 (s, 3H).
1-103;
δ8.31 (s, 1H), 6.85 (brs, 2H), 3.85 (s, 3H), 3.55-3.42 (m, 1H), 3.13-3.03 (m, 2H), 2.92-2.83 (m, 1H), 2.38-2.18 (m, 4H), 2.09 (s, 3H), 2.07 (s, 3H), 1.89 (s, 3H), 1.65-1.50 (m, 1H), 1.23-1.17 (m, 2H), 1.03-0.97 (m, 2H).
1-104;
δ6.87 (brs, 2H), 3.85 (s, 3H), 3.70-3.22 (m, 10H), 3.08-2.97 (m, 1H), 2.96-2.80 (m, 2H), 2.32-2.19 (m, 3H), 2.08 (s, 3H), 2.05 (m, 3H), 1.87 (s, 3H).
1-107;
δ6.86 (brs, 2H), 3.84 (s, 3H), 3.42-3.31 (m, 1H), 3.07-2.72 (m, 9H), 2.31-2.19 (m, 4H), 2.09 (s, 3H), 2.06 (s, 3H), 1.86 (s, 3H).
1-108;
δ7.27 (brs, 2H), 3.84 (s, 3H), 3.38-3.23 (m, 1H), 3.15-2.78 (m, 5H), 2.40-2.01 (m, 10H), 1.86 (s, 3H), 1.69-1.48 (m, 3H), 1.38-1.05 (m, 10H).
1-122;
δ6.86 (brs, 2H), 3.85 (s, 3H), 3.39-3.28 (m, 1H), 3.11-2.59 (m, 9H), 2.36-1.98 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.54 (s, 3H).
1-125;
δ10.06 (brs, 1H), 6.99-6.81 (m, 2H), 4.66-4.42 (m, 2H), 3.50-3.32 (m, 2H), 3.04-1.42 (m, 20H).
1-126;
δ6.86 (brs, 2H), 3.84 (brs, 3H), 3.58-2.72 (m, 12H), 2.35-1.20 (m, 16H).
1-127;
δ7.32-6.62 (m, 7H), 4.55-4.28 (m, 1H), 3.89-3.79 (m, 3H), 3.38-3.20 (m, 1H), 3.02-2.65 (m, 3H), 2.29-1.44 (m, 13H), 1.13-0.87 (m, 6H).
1-128;
δ6.97-6.66 (m, 6H), 4.57-4.31 (m, 1H), 3.84 (s, 3H), 3.38-3.23 (m, 1H), 3.04-2.71 (m, 3H), 2.30-1.40 (m, 13H), 1.17-0.79 (m, 6H).
1-129;
δ6.98-6.43 (m, 5H), 4.59-4.40 (m, 1H), 3.85 (s, 3H), 3.50-3.31 (m, 1H), 3.07-2.76 (m, 3H), 2.32-1.50 (m, 13H), 1.20-0.81 (m, 6H).
1-130;
δ6.84 (brs, 2H), 4.92-4.58 (m, 2H), 3.84 (s, 3H), 3.82-2.77 (m, 9H), 2.37-1.32 (m, 15H), 1.12-0.81 (m, 3H).
1-134;
δ7.50-7.00 (m, 5H), 6.85 (brs, 2H), 3.85-3.50 (m, 5H), 3.20-2.18 (m, 8H), 2.10-1.97 (m, 6H), 1.85 and 1.78 (s, 3H).
1-139;
δ7.78-7.57 (m, 5H), 6.90-6.82 (m, 2H), 4.11 (s, 2H), 3.89 (s, 3H), 3.85 (s, 3H), 3.62-2.20 (m, 8H), 2.16-1.85 (m, 9H).
1-140;
δ6.92-6.82 (m, 2H), 3.87-3.82 (m, 3H), 3.68-3.30 (m, 1H), 3.28-2.00 (m, 19H), 1.92-1.84 (m, 3H).
1-141;
δ6.89 (brs, 2H), 3.84 (s, 3H), 3.38-2.78 (m, 8H), 2.40-2.25 (m, 4H), 2.15-1.82 (m, 11H).
1-142;
δ6.88 (brs, 2H), 3.85 (s, 3H), 3.63-2.22 (m, 9H), 2.13-2.02 (m, 6H), 1.90-1.82 (m, 3H), 1.28-0.70 (m, 4H).
1-143;
δ6.88 (brs, 2H), 3.85 (s, 3H), 3.42-2.80 (m, 6H), 2.40-1.70 (m, 13H), 0.85-0.72 (m, 2H), -0.07 (s, 9H).
1-144;
δ7.45-7.22 (m, 5H), 6.86 (brs, 2H), 5.13 (s, 2H), 3.84 (s, 3H), 3.35-2.22 (m, 8H), 2.14-2.00 (m, 6H), 1.97-1.80 (m, 3H).
1-145;
δ6.87 (brs, 2H), 5.94-5.75 (m, 1H), 5.45-5.20 (m, 2H), 4.73-4.48 (m, 2H), 3.84 (s, 3H), 3.34-3.23 (m, 1H), 3.10-2.80 (m, 3H), 2.40-2.22 (m, 4H), 2.07 (s, 3H), 2.05 (s, 3H), 1.86 (s, 3H).
1-146;
δ6.87 (brs, 2H), 4.33-4.15 (m, 2H), 3.85 (s, 3H), 3.62-3.52 (m, 2H), 3.43-3.22 (m, 4H), 3.10-2.80 (m, 3H), 2.35-2.22 (m, 4H), 2.13-2.01 (m, 6H), 1.86 (s, 3H).
1-147;
δ6.87 (brs, 2H), 4.33-4.15 (m, 2H), 3.85 (s, 3H), 3.62-3.52 (m, 2H), 3.43-3.22 (m, 4H), 3.10-2.80 (m, 3H), 2.35-2.22 (m, 4H), 2.13-2.01 (m, 6H), 1.86 (s, 3H).
1-148;
δ7.13-7.08 (m, 2H), 6.98-6.92 (m, 2H), 6.78 (brs, 2H), 3.84 (s, 3H), 3.15-2.96 (m, 2H), 2.88-2.67 (m, 2H), 2.33-2.19 (m, 4H), 1.90 (s, 3H), 1.87 (s, 3H), 1.85 (s, 3H), 1.47 (s, 3H), 1.47 (s, 3H).
1-149;
δ8.10-7.97 (m, 2H), 7.75-7.65 (m, 2H), 6.86 (brs, 2H), 3.85 (s, 3H), 3.45-3.35 (m, 1H), 3.18-2.85 (m, 3H), 2.42-2.29 (m, 1H), 2.25 (s, 3H), 2.13 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-150;
δ6.86 (s, 2H), 3.84 (s, 3H), 3.47-3.32 (m, 3H), 3.29-3.19 (m, 2H), 3.07-2.80 (m, 3H), 2.32-2.19 (m, 4H), 2.09 (s, 3H), 2.07 (s, 3H), 1.90-1.80 (m, 7H).
1-151;
δ6.86 (s, 2H), 3.85 (s, 3H), 3.44-3.20 (m, 5H), 3.08-2.80 (m, 3H), 2.32-2.19 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.64-1.37 (m, 6H).
1-152;
δ6.86 (s, 2H), 3.84 (s, 3H), 3.51-3.28 (m, 5H), 3.08-2.80 (m, 3H), 2.40-2.18 (m, 11H), 2.08 (s, 3H), 2.05 (s, 3H), 1.86 (s, 3H).
1-153;
δ6.85 (brs, 2H), 5.90-5.42 (m, 2H), 5.33-4.74 (m, 4H), 4.00-3.58 (m, 7H), 3.44-3.30 (m, 1H), 3.09-2.80 (m, 3H), 2.37-2.18 (m, 4H), 2.07 (s, 3H), 2.04 (s, 3H), 1.87 (s, 3H).
1-155;
δ7.83-7.77 (m, 1H), 7.65-7.57 (m, 1H), 7.39-7.29 (m, 2H), 6.85 (brs, 2H), 3.85 (s, 3H), 3.40-3.29 (m, 1H), 3.18-3.05 (m, 1H), 3.03-2.84 (m, 2H), 2.41-2.28 (m, 1H), 2.25 (s, 3H), 2.11 (s, 3H), 2.09 (s, 3H), 1.88 (s, 3H).
1-156;
δ7.10-6.92 (m, 2H), 6.90-6.72 (m, 4H), 3.85 (s, 3H), 3.80 (s, 3H), 3.68-3.53 (m, 2H), 3.24-3.12 (m, 1H), 3.07-2.74 (m, 3H), 2.51-1.82 (m, 13H).
1-159;
δ7.30-6.67 (m, 7H), 3.84 (s, 3H), 3.41-3.18 (m, 4H), 3.10-2.77 (m, 3H), 2.30-1.66 (m, 13H).
1-160;
δ6.84 (brs, 2H), 3.84 (s, 3H), 3.79 (s, 3H), 3.40-2.82 (m, 4H), 2.35-2.25 (m, 1H), 2.25 (s, 3H), 2.09 (s, 3H), 2.07 (s, 3H), 1.87 (s, 3H).
1-161;
δ7.56 (d, J=8.4Hz, 2H), 7.20 (d, J=8.4Hz, 2H), 6.86 (brs, 2H), 3.84 (s, 3H), 3.38-2.75 (m, 4H), 2.42 (s, 3H), 2.41-2.09 (m, 1H), 2.25 (s, 3H), 1.92 (s, 3H), 1.89 (s, 3H), 1.85 (s, 3H).
1-162;
δ7.97 (d, J=8.1Hz, 1H), 7.75 (d, J=8.1Hz, 1H), 6.87 (brs, 2H), 4.01 (s, 3H), 3.86 (s, 3H), 3.42-3.30 (m, 1H), 3.20-3.08 (m, 4H), 3.05-2.73 (m, 2H), 2.43-2.22 (m, 4H), 2.14-2.05 (m, 6H), 1.98-1.85 (m, 3H).
1-163;
δ7.50-7.44 (m, 1H), 7.21-7.13 (m, 1H), 6.92-6.70 (m, 5H), 6.68-6.55 (m, 2H), 4.72-4.59 (m, 1H), 3.84 (s, 3H), 3.23-2.67 (m, 4H), 2.38-2.16 (m, 4H), 2.12-1.80 and 1.62-1.40 (m, 12H).
1-164;
δ11.4 (brs, 1H), 7.56-7.10 (m, 4H), 6.87-6.82 (m, 2H), 3.96-3.85 (m, 3H)3.40-2.65 (m, 3H), 2.51-1.97 (m, 14H).
1-165;
δ6.85 (brs, 2H), 4.85-4.50 (m, 1H), 3.90-3.80 (m, 3H), 3.20-2.50 (m, 4H), 2.38-2.00 (m, 10H), 1.90-1.83 (m, 3H), 1.75-1.35 (m, 8H).
1-166;
δ6.87 (brs, 2H), 6.37-6.05 (m, 1H), 4.72-4.30 (m, 2H), 3.90-3.80 (m, 3H), 3.35-2.55 (m, 4H), 2.45-2.03 (m, 10H), 1.92-1.85 (m, 3H).
1-167;
δ7.19-7.08 (m, 2H), 6.96-6.86 (m, 4H), 3.84 (s, 3H), 3.33 (dd, J=18.3Hz, 6.9Hz, 1H), 3.12-3.02 (m, 1H), 3.00-2.80 (m, 1H), 2.40-2.20 (m, 8H), 2.11 (s, 3H), 2.09 (s, 3H), 1.92-1.84 (m, 3H).
1-168;
δ7.00-6.71 (m, 6H), 3.88-3.72 (m, 6H), 3.33 (dd, J=18.3Hz, 6.9Hz, 1H), 3.15-2.80 (m, 3H), 2.40-2.25 (m, 4H), 2.11 (s, 3H), 2.09 (s, 3H), 1.92-1.84 (m, 3H).
1-169;
δ7.48-7.07 (m, 5H), 6.90-6.60 (m, 2H), 6.00-5.81 (m, 1H), 3.91-3.80 (m, 3H), 3.27-1.70 (m, 20H).
1-170;
δ6.58 (s, 2H), 3.84 (s, 3H)3.45-2.78 (m, 8H), 2.39-2.24 (m, 4H), 2.13-2.04 (m, 6H), 1.86 (s, 3H), 1.56-1.33 (brs, 6H).
1-171;
δ6.86 (brs, 2H), 3.84 (s, 3H), 3.43-2.71 (m, 9H), 2.35-2.19 (m, 4H), 2.17-2.00 (m, 6H), 1.87 (s, 3H), 1.12-0.89 (m, 3H).
1-173;
δ7.35-7.10 (m, 5H), 6.82 (brs, 2H), 3.87-3.80 (m, 3H), 3.23-2.67 (m, 4H), 2.29 (s, 3H), 2.28-2.17 (m, 1H), 1.93-1.80 (m, 9H), 1.55-1.48 (m, 2H), 1.25-1.18 (m, 2H).
1-174;
δ7.16-7.10 (m, 2H), 7.05-6.99 (m, 2H), 6.82 (brs, 2H), 3.85-3.80 (m, 3H), 3.28-2.67 (m, 4H), 2.30 (s, 3H), 2.28-2.17 (m, 1H), 1.92-1.81 (m, 9H), 1.60-1.40 (m, 2H), 1.23-1.17 (m, 2H).
1-175;
δ6.88 (brs, 2H), 4.11 (t, J=6.9Hz, 2H), 3.85 (s, 3H), 3.27 (dd, J=18.3Hz, 6.9Hz, 1H), 3.10-2.80 (m, 3H), 2.37-2.20 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.67-1.52 (m, 2H), 1.41-1.17 (m, 6H), 0.98-0.80 (m, 3H).
1-176;
δ6.87 (brs, 2H), 4.15-4.08 (m, 2H), 3.85 (s, 3H), 3.27 (dd, J=18.6Hz, 6.9Hz, 1H), 3.09-2.80 and 2.38-2.02 (m, 13H), 1.87 (s, 3H), 1.70-1.52 (m, 3H), 1.40-1.14 (m, 9H), 0.99-0.82 (m, 3H).
1-177;
δ6.88 (brs, 2H), 4.39-4.32 (m, 2H), 3.85 (s, 3H), 3.64-3.58 (m, 2H), 3.27 (dd, J=18.3Hz, 6.9Hz, 1H), 3.11-2.80 (m, 3H), 2.37-2.22 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H).
1-178;
δ6.88 (brs, 2H), 4.33-4.25 (m, 2H), 3.85 (s, 3H), 3.68-3.50 (m, 2H), 3.27 (dd, J=18.3Hz, 6.9Hz, 1H), 3.11-2.80 (m, 3H), 2.37-2.22 (m, 4H), 2.13-2.00 (m, 8H), 1.87 (s, 3H).
1-179;
δ6.88 (brs, 2H), 4.20-4.10 (m, 2H), 3.85 (s, 3H), 3.55-3.47 (m, 2H), 3.27 (dd, J=18.3Hz, 6.9Hz, 1H), 3.10-2.80 (m, 3H), 2.35-2.23 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.84-1.68 (m, 4H).
1-180;
δ6.87 (brs, 2H), 4.18-4.08 (m, 2H), 3.85 (s, 3H), 3.27 (dd, J=18.6Hz, 6.9Hz, 1H), 3.10-2.80 (m, 3H), 2.37-2.20 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.67-1.52 (m, 2H), 1.41-1.22 (m, 2H), 0.98-0.86 (m, 3H).
1-181;
δ7.38-7.28 (m, 2H), 7.00-6.70 (m, 4H), 3.84 (s, 3H), 3.32 (dd, J=18.3Hz, 6.9Hz, 1H), 3.15-2.75 (m, 3H), 2.38-2.27 (m, 4H), 2.10 (s, 3H), 2.09 (s, 3H), 1.97-1.85 (m, 3H).
1-183;
δ6.88 (brs, 2H), 4.68-4.29 (m, 4H), 3.85 (s, 3H), 3.28 (dd, J=18.3Hz, 6.9Hz, 1H), 3.11-3.00 (m, 1H), 2.97-2.80 (m, 2H), 2.37-2.22 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H).
1-184;
δ8.25-8.13 (m, 2H), 7.47-7.37 (m, 2H), 6.87 (brs, 2H), 5.21 (s, 2H), 3.84 (s, 3H), 3.25 (dd, J=18.3Hz, 6.9Hz, 1H), 3.11-3.00 (m, 1H), 2.96-2.80 (m, 2H), 2.37-2.22 (m, 4H), 2.06 (s, 3H), 2.04 (s, 3H), 1.87 (s, 3H).
1-185;
δ6.92-6.80 (m, 2H), 4.30-3.28 (m, 12H), 3.14-2.75 (m, 3H), 2.68-1.85 (m, 13H).
1-186;
δ6.86 (brs, 2H), 3.84 (s, 3H), 3.75-3.52 (m, 4H), 3.38-3.24 (m, 1H), 3.08-2.97 (m, 1H), 2.93-2.80 (m, 2H), 2.61-2.50 (m, 2H), 2.48-2.37 (m, 2H), 2.32-2.19 (m, 4H), 2.08 (s, 3H), 2.05 (s, 3H), 1.87 (s, 3H).
1-187;
δ6.85 (brs, 2H), 4.53-4.45 (m, 2H), 3.84 (s, 3H), 3.78-3.70 (m, 2H), 3.63-3.57 (m, 2H), 3.55-3.48 (m, 2H), 3.36 (s, 3H), 3.28-3.18 (m, 1H), 3.13-3.02 (m, 1H), 3.00-2.72 (m, 2H), 2.40-2.28 (m, 1H), 2.26 (s, 3H), 2.10 (s, 3H), 2.08 (s, 3H), 1.87 (s, 3H).
1-188;
δ6.87 (brs, 2H), 4.00-3.72 and 3.62-3.22 and 3.10-2.79 and 2.58-2.41 (m, 13H), 2.33-
2.18 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.20-0.96 (m, 6H).
1-189;
δ6.86 (brs, 2H), 4.00-3.80 (m, 4H), 3.41-3.23 and 3.08-2.78 and 2.32-2.19 (m, 11H), 2.09 and 2.08 (s, 3H), 2.06 and 2.05 (s, 3H), 1.87 (s, 3H), 1.73-0.97 (m, 8H).
1-190;
δ6.86 (brs, 2H), 4.00-3.80 (m, 4H), 3.76-3.49 (m, 2H), 3.44-3.26 (m, 1H), 3.08-2.62 and 2.51-2.19 (m, 10H), 2.09 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.12-0.70 (m, 6H).
1-191;
δ6.87-6.80 (m, 2H), 3.86-3.80 (m, 3H), 3.30-2.45 (m, 6H), 2.40-2.03 (m, 10H), 1.86 (s, 3H), 1.30-1.20 (m, 3H).
1-192;
δ7.66 (m, 5H), 6.80-6.53 (m, 2H), 5.32-5.10 (m, 2H), 3.86 and 3.84 (s, 3H), 3.50-3.37 and 3.10-1.79 (m, 17H).
1-193;
δ6.88 (brs, 2H), 5.15-5.00 (m, 2H), 3.86 (s, 3H), 3.42 (s, 3H), 3.13-2.61 (m, 4H), 2.27 (s, 3H), 2.22-2.14 (m, 1H), 2.13-2.03 (m, 6H), 1.97-1.86 (m, 3H).
1-210;
δ7.58 (s, 1H), 7.40-7.31 (m, 2H), 6.84 (s, 2H), 3.81 (s, 3H), 3.32 (dd, J=12.0Hz, J=6.8Hz, 1H), 3.13-3.06 (m, 1H), 2.97-2.83 (m, 2H), 2.34-2.28 (m, 1H), 2.22 (s, 3H), 2.08 (s, 3H), 2.06 (s, 3H), 1.85 (s, 3H).
1-220;
δ6.83 (s, 2H), 6.80 (s, 2H), 3.86 (s, 3H), 3.32-3.27 (m, 1H), 3.20-3.05 (m, 1H), 3.00-2.85 (m, 2H), 2.40-2.30 (m, 1H), 2.25 (s, 3H), 2.24 (s, 3H), 2.15-2.00 (m, 12H), 1.89 (s, 3H).
1-222;
δ7.30-7.22 (m, 3H), 6.82 (s, 2H), 3.85 (s, 3H), 3.34 (dd, J=18.4Hz, 6.8Hz, 1H), 3.18-3.07 (m, 1H), 3.03-2.83 (m, 2H), 2.40-2.30 (m, 1H), 2.22 (s, 3H), 2.08 (s, 3H), 2.05 (s, 3H), 1.87 (s, 3H).
1-226;
δ6.87 (brs, 1H), 6.85 (brs, 1H), 5.24-5.11 and 4.92-4.84 (m, 2H), 3.85 and 3.84 (s, 3H), 3.67-3.40 (m, 1H), 3.31-2.66 and 2.46-2.33 (m, 4H), 2.31-2.12 (m, 1H), 2.26 (s, 3H), 2.09 (s, 3H), 2.05 (s, 3H), 1.89 and 1.88 (s, 3H), 1.86-1.42 (m, 4H) 1.40-1.12 (m, 6H).
1-227;
δ6.87 (brs, 1H), 6.84 (brs, 1H), 5.22-5.09 and 4.90-4.80 (m, 2H), 3.85 and 3.84 (s, 3H), 3.80-3.46 (m, 4H), 3.36 and 3.34 (s, 3H), 3.32-3.22 and 3.13-3.02 (m, 1H), 2.98-2.60 (m, 3H), 2.43-2.13 (m, 1H), 2.08 (s, 3H), 2.05 (s, 3H), 1.89 and 1.87 (s, 3H), 1.59 (s, 3H).
1-228;
δ6.88 (brs, 2H), 5.20-5.03 and 4.86-4.75 (m, 2H), 3.86 (s, 3H), 3.73-3.52 (m, 2H), 3.12-2.62 and 2.30-2.14 (m, 5H), 2.26 (s, 3H), 2.08 (s, 3H), 2.05 (s, 3H), 1.96-1.82 (m, 3H), 1.20 (t, J=6.8Hz, 3H).
1-239;
δ7.64 (d, J=8.8Hz, 1H), 7.46 (d, J=2.0Hz, 1H), 7.30-7.23 (m, 1H), 6.85 (s, 2H), 3.84 (s, 3H), 3.37 (dd, J=18.4Hz, 4.0Hz, 1H), 3.17-3.08 (m, 1H), 3.05-2.85 (m, 2H), 2.40-2.22 (m, 4H), 2.10 (s, 3H), 2.08 (s, 3H), 1.88 (s, 3H).
1-242;
δ7.31 (s, 2H), 6.84 (s, 2H), 3.87 (s, 3H), 3.32 (dd, J=18.4Hz, 3.2Hz, 1H), 3.20-3.10 (m, 1H), 3.05-2.85 (m, 2H), 2.45-2.30 (m, 1H), 2.25 (s, 3H), 2.09 (s, 3H), 2.07 (s, 3H), 1.90 (s, 3H).
1-243;
δ7.92-7.89 (m, 1H), 7.71-7.67 (m, 1H), 7.43-7.25 (m, 2H), 6.87 (s, 2H), 3.85 (s, 3H), 3.38 (dd, J=18.4Hz, 6.8Hz, 1H), 3.15-3.07 (m, 1H), 3.02-2.88 (m, 2H), 2.40-2.30 (m, 4H), 2.25 (s, 3H), 2.13 (s, 3H), 2.12 (s, 3H), 1.89 (s, 3H).
1-244;
δ7.70-7.67 (m, 1H), 7.51-7.48 (m, 1H), 6.96-6.92 (m, 2H), 6.86 (s, 2H), 3.84 (s, 3H), 3.81 (s, 3H), 3.43-3.38 (m, 1H), 3.03-2.86 (m, 3H), 2.34-2.25 (m, 4H), 2.13 (s, 3H), 2.11 (s, 3H), 1.88 (s, 3H).
1-245;
δ7.95-7.91 (m, 2H), 7.12-7.08 (m, 2H), 6.87 (s, 2H), 3.84 (s, 3H), 3.39 (dd, J=11.6Hz, 7.2Hz, 1H), 3.01-2.96 (m, 1H), 2.91-2.85 (m, 2H), 2.36-2.30 (m, 1H), 2.26 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-246;
δ7.93-7.89 (m, 2H), 7.10-7.06 (m, 2H), 6.85 (s, 2H), 3.83 (s, 3H), 3.38 (dd, J=11.6Hz, 6.8Hz, 1H), 3.07-2.99 (m, 1H), 2.94-2.85 (m, 2H), 2.34-2.31 (m, 1H), 2.24 (s, 3H), 2.11 (s, 3H), 2.09 (s, 3H), 1.87 (s, 3H).
1-247;
δ8.05 (s, 1H), 7.83 (d, J=8.0Hz, 1H), 7.72 (d, J=8.0Hz, 1H), 7.31 (t, J=8.0Hz, 1H), 6.87 (s, 2H), 3.85 (s, 3H), 3.36 (dd, J=11.6Hz, 6.8Hz, 1H), 3.14-3.06 (m, 1H), 2.99-2.86 (m, 2H), 2.37-2.31 (m, 1H), 2.26 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-252;
δ7.03 (s, 2H), 6.87 (s, 2H), 6.67 (s, 1H), 3.86 (s, 3H), 3.76 (s, 3H), 3.34 (dd, J=11.6Hz, 6.8Hz, 1H), 3.15-3.08 (m, 1H), 3.05-2.89 (m, 2H), 2.38-2.30 (m, 1H), 2.25 (s, 3H), 2.14 (s, 3H), 2.12 (s, 3H), 1.90 (s, 3H), 1.26 (s, 3H).
1-254;
δ7.89 (s, 1H), 7.79 (d, J=8.0Hz, 1H), 7.57 (d, J=8.0Hz, 1H), 7.38 (d, J=8.0Hz, 1H), 6.87 (s, 2H), 3.85 (s, 3H), 3.37 (dd, J=18.8Hz, 6.8Hz, 1H), 3.14-3.07 (m, 1H), 3.00-2.86 (m, 2H), 2.39-2.31 (m, 1H), 2.50 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-258;
δ7.92-7.88 (m, 1H), 7.61-7.57 (m, 2H), 7.47-7.44 (m, 1H), 6.79 (s, 2H), 3.80 (s, 3H), 3.40-3.34 (m, 1H), 3.07-3.00 (m, 2H), 2.88-2.79 (m, 1H), 2.34-2.26 (m, 1H), 2.18 (s, 3H), 2.00 (s, 3H), 1.98 (s, 3H), 1.83 (s, 3H).
1-259;
δ8.17 (s, 1H), 8.08 (d, J=8.0Hz, 1H), 7.85 (d, J=8.0Hz, 1H), 7.59 (t, J=8.0Hz, 1H), 6.88 (s, 2H), 3.90 (s, 3H), 3.39 (dd, J=18.8Hz, 6.8Hz, 1H), 3.15-3.09 (m, 1H), 3.02-2.87 (m, 2H), 2.38-2.31 (m, 1H), 2.26 (s, 3H), 2.13 (s, 3H), 2.12 (s, 3H), 1.89 (s, 3H).
1-263;
δ7.90-7.75 (m, 1H), 7.65-7.50 (m, 1H), 7.25-7.05 (m, 2H), 6.87 (s, 2H), 3.85 (s, 3H), 3.45-3.33 (m, 1H), 3.20-3.07 (m, 1H), 3.05-2.85 (m, 2H), 2.40-2.30 (m, 1H), 2.26 (s, 3H), 2.13 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-265;
δ7.78 (d, J=8.8Hz, 2H), 7.21 (d, J=8.8Hz, 2H), 6.86 (s, 2H), 3.84 (s, 3H), 3.45-3.35 (m, 1H), 3.13-2.85 (m, 3H), 2.49 (s, 3H), 2.35-2.20 (m, 4H), 2.12 (s, 3H), 2.10 (s, 3H), 1.88 (s, 3H).
1-266;
δ8.75 (brs, 1H), 8.50-8.40 (m, 1H), 8.26-8.20 (m, 1H), 7.70-7.60 (m, 1H), 6.89 (s, 2H), 3.85 (s, 3H), 3.45-3.35 (m, 1H), 3.20-3.10 (m, 1H), 3.07-2.85 (m, 2H), 2.45-2.30 (m, 1H), 2.26 (s, 3H), 2.14 (s, 3H), 2.13 (s, 3H), 1.90 (s, 3H).
1-268;
δ7.90-7.83 (m, 1H), 7.74 (brs, 1H), 7.55-7.43 (m, 2H), 6.87 (s, 2H), 3.84 (s, 3H), 3.45-3.35 (m, 1H), 3.17-3.09 (m, 1H), 3.06-2.85 (m, 2H), 2.40-2.31 (m, 1H), 2.25 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-269;
δ7.95 (d, J=9.2Hz, 2H), 7.30-7.22 (m, 2H), 6.86 (s, 2H), 3.84 (s, 3H), 3.45-3.33 (m, 1H), 3.17-2.85 (m, 3H), 2.40-2.30 (m, 1H), 2.25 (s, 3H), 2.11 (s, 3H), 2.10 (s, 3H), 1.88 (s, 3H).
1-270;
δ6.87 (brs, 2H), 3.85 (s, 3H), 3.61-3.49 (m, 1H), 3.35-3.22 (m, 1H), 3.09-2.96 (m, 1H), 2.93-2.78 (m, 2H), 2.35-2.2.21 (m, 1H), 2.28 (s, 3H), 2.15-1.99 (m, 2H), 2.05 (s, 3H), 2.02 (s, 3H), 1.86 (s, 3H), 1.78-1.42 (m, 6H).
1-272;
δ7.29-7.23 (m, 5H), 6.86 (s, 2H), 4.05 (s, 2H), 3.85 (s, 3H), 3.29-3.23 (m, 1H), 3.03-2.98 (m, 1H), 2.91-2.82 (m, 2H), 2.31-2.27 (m, 4H), 2.05 (s, 3H), 2.03 (s, 3H), 1.86 (s, 3H).
1-273;
δ6.85 (s, 2H), 5.78-5.68 (m, 1H), 5.23-5.10 (m, 2H), 3.83 (s, 3H), 3.46-3.43 (m, 2H), 3.29-3.22 (m, 1H), 3.05-2.98 (m, 1H), 2.90-2.81 (m, 2H), 2.29-2.23 (m, 4H), 2.05 (s, 3H), 2.03 (s, 3H), 1.85 (s, 3H).
1-274;
δ7.75 (d, J=7.2Hz, 1H), 7.57-7.51 (m, 3H), 6.85 (s, 2H), 3.86-3.82 (m, 6H), 3.48-3.42 (m, 1H), 3.12-2.56 (m, 3H), 2.38-2.31 (m, 1H), 2.25 (s, 3H), 2.09 (s, 3H), 2.07 (s, 3H), 1.89 (s, 3H).
1-275;
δ8.08 (d, J=6.8Hz, 2H), 7.97 (d, J=6.8Hz, 2H), 6.87 (s, 2H), 3.94 (s, 3H), 3.84 (s, 3H), 3.40 (dd, J=18.8Hz, 6.8Hz, 1H), 3.13-3.08 (m, 1H), 3.04-2.86 (m, 2H), 2.37-2.32 (m, 1H), 2.25 (s, 3H), 2.13 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-276;
δ8.01 (d, J=8.4Hz, 2H), 7.74 (d, J=8.4Hz, 2H), 6.88 (s, 2H), 3.85 (s, 3H), 3.39 (dd, J=18.8Hz, 6.8Hz, 1H), 3.15-3.11 (m, 1H), 3.03-2.86 (m, 2H), 2.38-2.32 (m, 1H), 2.26 (s, 3H), 2.13 (s, 3H), 2.11 (s, 3H), 1.90 (s, 3H).
1-277;
δ8.18 (s, 1H), 8.13 (d, J=8.0Hz, 1H), 7.87 (d, J=8.0Hz, 1H), 7.59 (t, J=8.0Hz, 1H), 6.88 (s, 2H), 3.85 (s, 3H), 3.37 (dd, J=18.4Hz, 6.8Hz, 1H), 3.14-3.09 (m, 1H), 3.00-2.86 (m, 2H), 2.39-2.33 (m, 1H), 2.26 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-278;
δ7.71 (d, J=8.8Hz, 1H), 6.87 (s, 2H), 6.46-6.44 (m, 2H), 3.86 (s, 6H), 3.81 (s, 3H), 3.43 (dd, J=18.0Hz, 6.0Hz, 1H), 3.10-2.85 (m, 3H), 2.34-2.25 (m, 4H), 2.13 (s, 3H), 2.11 (s, 3H), 1.88 (s, 3H).
1-279;
δ8.27 (d, J=9.2Hz, 2H), 8.08 (d, J=9.2Hz, 2H), 6.82 (s, 2H), 3.85 (s, 3H), 3.39 (dd, J=18.4Hz, 6.8Hz, 1H), 3.14-3.10 (m, 1H), 3.03-2.87 (m, 2H), 2.38-2.32 (m, 1H), 2.26 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-280;
δ7.18 (d, J=8.4Hz, 2H), 6.96 (d, J=8.4Hz, 2H), 6.82 (s, 2H), 3.84 (s, 3H), 3.61 (s, 2H), 3.18 (dd, J=18.8Hz, 6.8Hz, 1H), 3.03-2.99 (m, 1H), 2.85-2.77 (m, 2H), 2.30-2.23 (m, 4H), 1.97 (s, 3H), 1.95 (s, 3H), 1.85 (s, 3H).
1-281;
δ7.33-7.05 (m, 4H), 6.82 (s, 2H), 3.83 (s, 3H), 3.80 (s, 2H), 3.22 (dd, J=18.8Hz, 6.8Hz, 1H), 3.05-2.99 (m, 1H), 2.87-2.81 (m, 2H), 2.30-2.23 (m, 4H), 1.99 (s, 3H), 1.96 (s, 3H), 1.85 (s, 3H).
1-282;
δ7.05 (d, J=7.6Hz, 2H), 6.94 (d, J=7.6Hz, 2H), 6.84 (s, 2H), 3.83 (s, 3H), 3.21 (s, 2H), 3.18 (dd, J=18.4Hz, 6.8Hz, 1H), 3.02-2.98 (m, 1H), 2.85-2.77 (m, 2H), 2.33-2.22 (m, 7H), 1.99 (s, 3H), 1.97 (s, 3H), 1.85 (s, 3H).
1-283;
δ7.15-7.06 (m, 2H), 6.88-6.83 (m, 4H), 3.83 (s, 3H), 3.60 (s, 2H), 3.19 (dd, J=18.8Hz, 7.2Hz, 1H), 3.03-2.97 (m, 1H), 2.85-2.78 (m, 2H), 2.35-2.22 (m, 7H), 1.99 (s, 3H), 1.96 (s, 3H), 1.85 (s, 3H).
1-284;
δ7.46 (d, J=8.0Hz, 2H), 7.13 (d, J=8.0Hz, 2H), 6.80 (s, 2H), 3.87-3.80 (m, 3H), 3.70 (s, 2H), 3.23-2.70 (m, 4H), 2.30-2.08 (m, 4H), 2.05-1.80 (m, 9H).
1-285;
δ7.30-7.20 (m, 1H), 7.05-7.00 (m, 1H), 6.90-6.75 (m, 4H), 3.83 (s, 3H), 3.65 (s, 5H), 3.40-3.30 (m, 1H), 3.07-2.95 (m, 1H), 2.90-2.80 (m, 2H), 2.30-2.10 (m, 4H), 1.98 (s, 3H), 1.95 (s, 3H), 1.85 (s, 3H).
1-286;
δ7.03 (d, J=8.8Hz, 2H), 6.82 (brs, 2H), 6.72 (d, J=8.8Hz, 2H), 3.82 (s, 3H), 3.79 (s, 3H), 3.23-3.12 (m, 1H), 3.02-2.92 (m, 1H), 2.85-2.70 (m, 2H), 2.32-2.15 (m, 4H), 1.92 (s, 3H), 1.87 (s, 3H), 1.84 (s, 3H), 1.55-1.15 (m, 4H).
1-287;
δ7.01 (s, 4H), 6.82 (brs, 2H), 3.82 (s, 3H), 3.23-3.12 (m, 1H), 3.02-2.92 (m, 1H), 2.85-2.70 (m, 2H), 2.32 (s, 3H), 2.29 (s, 3H), 2.28-2.15 (m, 1H), 1.91 (s, 3H), 1.86 (s, 3H), 1.83 (s, 3H), 1.70-1.15 (m, 4H).
1-288;
δ7.12-7.02 (m, 3H), 6.76 (brs, 2H), 3.83 (s, 3H), 3.33-3.25 (m, 1H), 3.01-2.75 (m, 3H), 2.29 (s, 3H), 2.27-2.18 (m, 1H), 1.84 (s, 6H), 1.80 (s, 3H), 1.72-1.65 (m, 2H), 1.27-1.20 (m, 2H).
1-289;
δ7.11 (d, J=8.4Hz, 2H), 6.91 (d, J=8.4Hz, 2H), 6.75 (s, 2H), 3.83 (s, 3H), 3.18-3.09 (m, 1H), 3.04-2.95 (m, 1H), 2.86-2.62 (m, 4H), 2.46-2.34 (m, 2H), 2.31-2.17 (m, 4H), 2.03-1.78 (m, 11H).
1-291;
δ7.01 (s, 4H), 6.77 (s, 2H), 3.82 (s, 3H), 3.10-2.92 (m, 2H), 2.86-2.77 (m, 1H), 2.70-2.62 (m, 1H), 2.50-2.40 (m, 2H), 2.35-2.18 (m, 7H), 1.95-1.75 (m, 11H), 1.70-1.40 (m, 4H).
1-293;
δ7.10 (d, J=11.2Hz, 2H), 7.00 (d, J=11.2Hz, 2H), 6.76 (s, 2H), 3.83 (s, 3H), 3.12-2.95 (m, 2H), 2.86-2.78 (m, 1H), 2.72-2.62 (m, 1H), 2.52-2.40 (m, 2H), 2.32-2.18 (m, 4H), 1.92-1.50 (m, 15H).
1-295;
δ7.02 (d, J=8.0Hz, 2H), 6.78 (s, 2H), 6.70 (d, J=8.0Hz, 2H), 3.82 (s, 3H), 3.79 (s, 3H), 3.10-2.92 (m, 2H), 2.85-2.78 (m, 1H), 2.72-2.62 (m, 1H), 2.50-2.40 (m, 2H), 2.30-2.15 (m, 4H), 1.95-1.45 (m, 15H).
1-297;
δ9.14-9.06 (m, 1H), 8.85-8.78 (m, 1H), 8.24-8.15 (m, 1H), 7.44-7.36 (m, 1H), 6.88 (brs, 2H), 3.86 (s, 3H), 3.44 (dd, J=18.8Hz, 6.8Hz, 1H), 3.17-3.08 (m, 1H), 3.07-2.97 (m, 1H), 2.95-2.85 (m, 1H), 2.42-2.31 (m, 1H), 2.26 (s, 3H), 2.13 (s, 3H), 2.12 (s, 3H), 1.91 (s, 3H).
1-298;
δ8.87-8.73 (m, 2H), 7.75-7.67 (m, 2H), 6.88 (brs, 2H), 3.86 (s, 3H), 3.39 (dd, J=18.4Hz, 6.8Hz, 1H), 3.17-3.09 (m, 1H), 3.05-2.96 (m, 1H), 2.94-2.86 (m, 1H), 2.40-2.31 (m, 1H), 2.27 (s, 3H), 2.13 (s, 3H), 2.12 (s, 3H), 1.90 (s, 3H).
1-299;
δ7.22-7.13 (m, 1H), 7.11-7.05 (m, 2H), 7.04-6.98 (m, 1H), 6.81 (brs, 2H), 3.83 (s, 3H), 3.64 (s, 2H), 3.19 (dd, J=18.4Hz, 6.8Hz, 1H), 3.05-2.96 (m, 1H), 2.87-2.72 (m, 2H), 2.32-2.21 (m, 1H), 2.28 (s, 3H), 2.00 (s, 3H), 1.94 (s, 3H), 1.91 (s, 3H), 1.85 (s, 3H).
1-300;
δ7.62 (d, J=6.8Hz, 1H), 7.46-7.36 (m, 2H), 7.12-7.08 (m, 1H), 6.83 (brs, 2H), 3.85 (s, 2H), 3.83 (s, 3H), 3.20 (dd, J=18.4Hz, 1H), 3.07-2.97 (m, 1H), 2.88-2.78 (m, 2H), 2.32-2.20 (m, 1H), 2.30 (s, 3H), 1.97 (s, 3H), 1.94 (s, 3H), 1.85 (s, 3H).
1-301;
δ7.23 (brs, 1H), 7.20-7.13 (m, 1H), 7.09-7.06 (m, 1H), 6.92 (d, J=8.0Hz, 1H), 6.83 (s, 2H), 3.83 (s, 3H), 3.61 (s, 2H), 3.20 (dd, J=18.8Hz, 7.2Hz, 1H), 3.08-2.98 (m, 1H), 2.89-2.78 (m, 2H), 2.32-2.19 (m, 1H), 2.28 (s, 3H), 2.00 (s, 3H), 1.98 (s, 3H), 1.86 (s, 3H).
1-302;
δ7.16 (t, J=8.0Hz, 1H), 6.82-6.79 (m, 3H), 6.66-6.62 (m, 2H), 3.82 (s, 3H), 3.74 (s, 3H), 3.61 (s, 2H), 3.22-3.15 (m, 1H), 3.02-2.97 (m, 1H), 2.85-2.77 (m, 2H), 2.28-2.20 (m, 4H), 1.98 (s, 3H), 1.96 (s, 3H), 1.85 (s, 3H).
1-304;
δ6.90-6.86 (m, 2H), 5.95-5.67 (m, 1H), 5.35-5.11 (m, 2H), 4.82 (d, J=2.0Hz, 1H), 3.85 (s, 3H), 3.46 (d, J=7.2Hz, 1H), 3.31-3.17 (m, 1H), 3.10-3.01 (m, 1H), 2.90-2.82 (m, 2H), 2.37-2.24 (m, 4H), 2.10-2.05 (m, 6H), 1.87 and 1.86 (s, 3H).
1-305;
δ6.85 (s, 2H), 5.50-5.00 (m, 1H), 3.84 (s, 3H), 3.24-3.18 (m, 1H), 3.10-3.05 (m, 1H), 2.84 (d, J=18.0Hz, 2H), 2.37-2.30 (m, 1H), 2.26 (s, 3H), 2.10 (s, 3H), 2.09 (s, 3H), 1.94-1.87 (m, 5H), 1.52 (brs, 2H), 1.33-1.26 (m, 6H).
1-309;
δ6.85 (s, 2H), 4.92 (d, J=2.8Hz, 2H), 3.84 (s, 3H), 3.30-3.18 (m, 1H), 3.15-3.05 (m, 1H), 2.90-2.80 (m, 2H), 2.60-2.52 (m, 1H), 2.40-2.24 (m, 4H), 2.09 (s, 3H), 2.08 (s, 3H), 1.87 (s, 3H).
1-310;
δ7.35 (brs, 1H), 6.86 (s, 2H), 3.65-3.27 (m, 9H), 3.08-2.79 (m, 3H), 2.36-2.27 (m, 4H), 2.08 (s, 3H), 2.04 (s, 3H), 1.91 (s, 3H).
1-311;
δ7.60-7.13 (m, 4H), 6.90-6.76 (m, 2H), 3.88-3.78 (m, 3H), 3.75-3.65 (m, 2H), 3.65-3.57 and 3.23-2.05 (m, 8H), 2.00-1.80 (m, 9H).
1-312;
δ8.80-8.75 (m, 1H), 7.98-7.93 (m, 1H), 7.85-7.78 (m, 1H), 7.57-7.47 (m, 1H), 6.84and 6.79 (brs, 2H), 3.83 and 3.77 (s, 3H), 3.41-2.10 (m, 14H), 1.88 and 1.85 (s, 3H).
1-313(*3);
δ8.05 (s, 1H), 6.87 (brs, 2H), 4.20-3.95 (m, 3H), 3.65-1.85 (m, 17H).
1-314;
δ8.13-7.70 (m, 1H), 6.90-6.80 (m, 2H), 4.10-3.94 (m, 3H), 3.90-2.52 (m, 8H), 2.33-2.22 (m, 3H), 2.15-2.02 (m, 6H), 1.17-1.05 (m, 9H).
2-008;
δ10.05-10.02 (m, 1H), 8.08-7.95 (m, 2H), 7.80-7.35 (m, 3H), 6.95-6.85 (m, 2H), 5.23-4.78 (m, 1H), 4.25-4.05 (m, 2H), 3.90-2.00 (m, 12H), 1.30-1.10 (m, 3H).
2-010(*3);
δ7.00-6.85 (m, 2H), 4.40-4.25 (m, 2H), 4.00-2.02 (m, 13H), 1.40-1.22 (m, 3H).
2-015;
δ10.20-9.95 (m, 1H), 8.20-7.98 (m, 2H), 7.75-7.45 (m, 3H), 7.05-6.80 (m, 2H), 3.97-3.72 (m, 1H), 3.60-3.47 (m, 1H), 3.32-2.95 (m, 2H), 2.55-2.05 (m, 10H).
2-018;
δ6.84 (s, 2H), 3.30-3.20 (m, 1H), 3.18-3.07 (m, 1H), 3.10-3.00 (m, 1H), 2.82-2.68 (m, 2H), 2.25 (s, 3H), 2.20 (s, 3H), 2.08 (s, 3H), 2.06 (s, 3H), 1.08 (s, 9H).
2-033(*3);
δ6.89 (brs, 2H), 4.63-1.80 (m, 22H), 1.36-1.15 (m, 3H).
2-034(*3);
δ8.35-8.21 (m, 1H), 6.95-6.80 (m, 2H), 4.85-4.50 (m, 1H), 4.30-4.08 (m, 2H), 3.90-2.70 (m, 6H), 2.30-1.88 (m, 9H), 1.35-1.15 (m, 3H).
2-035(*3);
δ8.32-8.15 (m, 1H), 6.89 (brs, 2H), 3.70-2.72 (m, 7H), 2.60-2.00 (m, 10H).
3-001;
δ7.60-7.48 and 6.95-6.80 (m, 3H), 4.07-3.85 (m, 4H), 3.85-2.50 (m, 3H), 2.35-2.00 (m, 9H).
3-002(*3);
δ6.97-6.83 (m, 2H), 3.88 (s, 3H), 3.00-2.42 (m, 3H), 2.27 (s, 3H), 2.15-2.05 (m, 6H), 1.86 (s, 3H).
4-001(*3);
δ6.88 (s, 2H), 3.84 and 3.82 (s, 3H), 2.95-2.71 (m, 1H), 2.55-1.96 (m, 17H), 1.10 (t, J=7.5Hz, 3H).
5-001(*3);
δ6.88 (s, 2H), 2.85-1.99 (m, 17H), 1.88-1.78 (m, 1H), 1.07 (t, J=7.5Hz, 3H).
5-002;
δ6.86 (s, 2H), 3.72 (s, 3H), 3.01-2.92 (m, 1H), 2.72-1.85 (m, 17H), 1.60 (t, J=7.5Hz, 3H).
6-004;
δ11.90-11.60 (m, 1H), 8.15-7.55 (m, 2H), 7.40-7.25 (m, 2H), 4.00-3.80 (m, 3H), 3.50-3.35 (m, 1H), 3.05-2.55 (m, 3H), 2.40-1.90 (m, 10H).
6-005;
δ11.80-11.60 (m, 1H), 8.00-7.00 (m, 4H), 4.00-3.80 (m, 3H), 3.50-3.30 (m, 1H), 3.05-1.95 (m, 12H), 1.20-1.00 (m, 3H).
6-006;
δ11.60-11.45 (m, 1H), 7.15-7.05 (m, 2H), 3.95-3.85 (m, 3H), 3.50-3.35 (m, 1H), 3.00-2.50 (m, 3H), 2.50-2.30 (m, 2H), 2.30-1.80 (m, 10H), 1.20-1.00 (m, 3H).
6-008;
δ11.60-11.40 (m, 1H), 7.25-7.15 (m, 2H), 3.95-3.85 (m, 3H), 3.50-3.35 (m, 1H), 3.00-2.85 (m, 1H), 2.85-2.70 (m, 1H), 2.70-2.30 (m, 3H), 2.30-2.18 (m, 1H), 2.18-2.05 (m, 3H), 2.05-1.95 (m, 3H), 1.20-1.00 (m, 3H), 0.30-0.10 (m, 9H).
6-010;
δ11.52 (brs, 1H), 7.21 (brs, 2H), 3.95-3.85 (m, 3H), 3.45-3.30 (m, 1H), 3.00-2.50 (m, 3H), 2.25-1.90 (m, 10H), 1.50-1.35 (m, 1H), 0.90-0.70 (m, 4H).
6-011;
δ7.21 (brs, 2H), 3.85 (s, 3H), 3.76 (s, 3H), 2.95-2.55 (m, 5H), 2.11 (s, 6H), 1.95 (s, 3H).
6-012;
δ7.63-7.55 (m, 2H), 7.48-7.40 (m, 2H), 7.40-7.25 (m, 3H), 3.86 (m, 3H), 3.79 (s, 3H), 3.00-2.55 (m, 5H), 2.21 (s, 6H), 1.95 (s, 3H).
6-013;
δ7.55-7.40 (m, 2H), 7.35-7.17 (m, 4H), 3.86 (s, 3H), 3.78 (s, 3H), 3.00-2.55 (m, 5H), 2.38 (s, 3H), 2.19 (s, 6H), 1.95 (s, 3H).
6-014;
δ7.74-7.63 (m, 4H), 7.29 (brs, 2H), 3.86 (s, 3H), 3.81 (s, 3H), 3.03-2.57 (m, 5H), 2.22 (s, 6H), 1.96 (s, 3H).
6-019;
δ7.50 (d, J=8.4Hz, 2H), 7.38 (d, J=8.4Hz, 2H), 7.25 (brs, 2H), 3.86 (s, 3H), 3.80 (s, 3H), 3.03-2.57 (m, 5H), 2.20 (s, 6H), 1.96 (s, 3H).
6-022;
δ11.61 (brs, 1H), 7.07 (brs, 2H), 4.05-4.00 (m, 2H), 3.91 (s, 3H), 3.50-3.35 (m, 1H), 3.20-2.50 (m, 7H), 2.30-1.90 (m, 10H), 1.60-1.20 (m, 9H), 0.95-0.85 (m, 6H).
6-023;
δ11.74 (brs, 1H), 7.73 (s, 2H), 3.91 (s, 3H), 3.88 (s, 3H), 3.55-3.35 (m, 1H), 3.05-2.50 (m, 3H), 2.20-1.90 (m, 10H).
6-024;
δ11.58 (brs, 1H), 6.97 (brs, 2H), 3.90 (s, 3H), 3.50-3.30 (m, 1H), 3.00-2.50 (m, 3H), 2.44 (s, 3H), 2.20-1.90 (m, 10H).
6-025;
δ11.65 (brs, 1H), 7.25-7.13 (m, 2H), 4.47 (s, 2H), 3.91 (s, 3H), 3.50-3.31 (m, 1H), 3.02-2.50 (m, 3H), 2.41-1.79 (m, 10H).
6-026;
δ11.79 (brs, 1H), 7.63 (s, 2H), 3.91 (s, 3H), 3.53-3.31 (m, 1H), 3.02-1.90 (m, 16H).
6-033;
δ11.38 (brs, 1H), 7.20-7.01 (m, 2H), 6.34 (s, 1H), 3.91 (s, 3H), 2.99-2.50 (m, 3H), 2.28-1.90 (m, 11H), 1.51 (s, 9H).
6-035;
δ11.63 (brs, 1H), 7.57-7.27 (m, 5H), 3.92 (s, 3H), 3.51-3.38 (m, 1H), 3.03-2.54 (m, 3H), 2.32-2.14 (m, 7H), 2.01 (s, 3H).
6-036;
δ11.70 (brs, 1H), 7.21 (brs, 2H), 3.91 (s, 3H), 3.47-3.33 (m, 1H), 2.99-2.52 (m, 3H), 2.35-1.80 (m, 14H), 1.71-1.36 (m, 3H).
6-037;
δ11.00 (brs, 1H), 6.78-6.53 (m, 2H), 4.05-3.70 (m, 6H), 3.50-3.28 (m, 1H), 3.00-2.55 (m, 3H), 2.40-1.80 (m, 10H).
6-038;
δ11.61 (brs, 1H), 7.32-7.25 (m, 1H), 7.03-6.96 (m, 1H), 3.91 (s, 3H), 3.53-3.30 (m, 1H), 3.05-2.10 (m, 10H), 1.99 (m, 3H).
6-039;
δ6.75 (brs, 2H), 3.86 (s, 3H), 3.74 (s, 3H), 2.97-2.83 (m, 3H), 2.63-2.52 (m, 1H), 2.25-1.75 (m, 2H), 2.09 (s, 3H), 2.06 (s, 3H), 1.88 (s, 3H), 0.95-0.85 (m, 2H), 0.70-0.60 (m, 2H).
6-041;
δ7.40-7.30 (m, 2H), 7.15-7.00 (m, 3H), 6.70 (brs, 2H), 3.87 (s, 3H), 3.80 (s, 3H), 3.02-2.85 (m, 3H), 2.65-2.2.55 (m, 1H), 2.30-2.15 (m, 1H), 2.09 (s, 3H), 2.07 (s, 3H), 1.89 (s, 3H).
6-043;
δ7.56 (d, J=8.8Hz, 2H), 7.30-7.20 (m, 4H), 3.87 (s, 3H), 3.80 (s, 3H), 3.05-2.85 (m, 3H), 2.70-2.2.55 (m, 1H), 2.25-2.15 (m, 1H), 2.22 (s, 3H), 2.21 (s, 3H), 1.89 (s, 3H).
6-045;
δ7.45-7.25 (m, 5H), 6.69 (brs, 2H), 5.01 (s, 2H), 3.86 (s, 3H), 3.76 (s, 3H), 3.00-2.85 (m, 3H), 2.65-2.50 (m, 1H), 2.25-2.15 (m, 1H), 2.10 (s, 3H), 2.07 (s, 3H), 1.88 (s, 3H).
6-046;
δ8.65-8.55 (m, 2H), 7.40-7.30 (m, 2H), 6.64 (brs, 2H), 5.03 (s, 2H), 3.84 (s, 3H), 3.75 (s, 3H), 3.00-2.80 (m, 3H), 2.65-2.50 (m, 1H), 2.25-2.15 (m, 1H), 2.16 (s, 3H), 2.08 (s, 3H), 1.86 (s, 3H).
6-047;
δ8.46 (brs, 1H), 7.90-7.80 (m, 1H), 7.00-6.90 (m, 1H), 6.84 (brs, 2H), 3.86 (s, 3H), 3.82 (s, 3H), 3.05-2.85 (m, 3H), 2.70-2.55 (m, 1H), 2.30-2.10 (m, 1H), 2.13 (s, 3H), 2.10 (s, 3H), 1.89 (s, 3H).
6-051(*3);
δ8.70-8.66 (m, 1H), 7.78-7.60 (m, 3H), 7.26-7.17 (m, 2H), 3.91 (s, 3H), 3.60-3.35 (m, 1H), 3.03-2.91 (m, 1H), 2.85-2.55 (m, 2H), 2.35-2.18 (m, 7H), 2.00 (s, 3H).
6-052;
δ11.52 (brs, 1H), 7.36-7.28 (m, 2H), 7.12-7.00 (m, 3H), 6.70 (brs, 2H), 3.92 (s, 3H), 3.46-3.37 (m, 1H), 2.95 (dd, J=18.0, 7.5Hz, 1H), 2.78 (dd, J=18.0, 2.7Hz, 1H), 2.61 (dd, J=18.0, 10.8Hz, 1H), 2.25 (dd, J=18.0, 2.7Hz, 1H)2.12 (s, 3H), 2.10 (s, 3H), 1.99 (s, 3H).
6-059;
δ7.65-7.50 (m, 2H), 7.27-7.20 (m, 2H), 7.16-7.08 (m, 2H), 3.86 (s, 3H), 3.72-3.31 (m, 9H), 3.13-2.83 (m, 3H), 2.39-2.15 (m, 7H), 1.90 (s, 3H).
6-060;
δ7.56-7.50 (m, 2H), 7.23 (s, 2H), 7.14-7.06 (m, 2H), 3.86 (s, 3H)3.48-3.33 (m, 1H), 3.17-2.72 (m, 9H), 2.39-2.18 (m, 7H), 1.91-1.87 (m, 3H).
6-061;
δ7.53-7.45 (m, 2H), 7.43-7.35 (m, 2H), 7.25-7.10 (m, 4H), 6.97-6.88 (m, 1H), 6.74-6.62 (m, 2H), 4.67and4.64 (s, 2H), 3.84 (s, 3H), 3.75-3.65 and 3.34-2.06 (m, 11H), 1.87and1.86 (s, 3H).
6-062;
δ7.54-7.47 (m, 2H), 7.40-7.34 (m, 2H), 7.23 (brs, 2H), 3.85 (s, 3H), 3.70-3.27 (m, 9H), 3.12-3.01 (m, 1H), 2.98-2.82 (m, 2H), 2.29 (dd, J=15.3, 11.1Hz, 1H), 2.18 (s, 3H), 2.16 (s, 3H), 1.88 (s, 3H).
6-063;
δ7.54-7.47 (m, 2H), 7.40-7.34 (m, 2H), 7.23 (brs, 2H), 3.84 (s, 3H), 3.40 (dd, J=18.6, 6.9Hz, 1H), 3.10-2.80 (m, 9H), 2.28 (dd, J=15.3, 11.1Hz, 1H), 2.18 (s, 3H), 2.17 (s, 3H), 1.88 (s, 3H).
6-064;
δ7.55-7.24 (m, 6H), 3.86 (s, 3H), 3.70-2.80 (m, 12H), 2.57-2.04 (m, 6H), 1.89 (s, 3H), 1.20-1.01 (m, 3H).
6-067;
δ7.01 (brs, 2H), 6.31-6.10 (m, 2H), 3.84 (s, 3H), 3.71 (s, 3H), 2.95-2.80 (m, 3H), 2.60-2.50 (m, 1H), 2.24-2.05 (m, 9H), 1.86 (s, 3H), 1.50-1.40 (m, 2H), 0.97-0.85 (m, 3H).
6-070(*3);
δ8.50-7.82 (m, 2H), 7.38-7.10 (m, 2H), 6.65-6.25 (m, 2H), 5.05-4.75 (m, 2H), 3.93-3.80 (m, 3H), 3.45-1.82 (m, 14H).
6-075;
δ11.45 (brs, 1H), 6.90-6.82 (m, 2H), 3.89 (s, 3H), 3.69-3.33 and 3.05-1.85 (m, 17H).
6-077;
δ11.36 (brs, 1H), 7.59-7.34 (m, 4H), 7.09-6.87 (m, 2H), 4.00-3.78 (m, 6H), 3.54-3.32 (m, 1H), 3.09-2.50 and 2.38-1.81 (m, 10H).
6-078;
δ7.58-7.34 (m, 4H), 7.03 (s, 1H), 6.90-6.86 (m, 1H), 3.92-3.22 (m, 15H), 3.09-2.68 (m, 3H), 2.40-2.13 (m, 4H), 1.88 (s, 3H).
6-079;
δ7.54-7.48 (m, 2H), 7.43-7.38 (m, 2H), 7.25-7.15 (m, 2H), 7.05-6.68 (m, 5H), 4.68 (s, 2H), 3.87 and 3.84 (s, 3H), 3.75 and 3.73 (s, 3H), 3.41-2.11 (m, 8H), 1.90-1.84 (m, 3H).
6-080;
δ7.54-7.48 (m, 2H), 7.41-7.35 (m, 2H), 7.22 (brs, 2H), 3.88-3.82 (m, 3H), 3.58-3.20 and 3.05-2.78 and 2.68-1.70 (m, 23H).
6-081;
δ7.58-7.32 (m, 4H), 7.02 (brs, 1H), 6.92-6.82 (m, 1H), 3.98-3.69 (m, 6H), 3.51-3.26 (m, 1H), 3.11-2.73 (m, 9H), 2.45-2.12 (m, 4H), 1.87 (s, 3H).
6-082;
δ7.66-7.12 (m, 6H), 4.04-3.79 (m, 3H), 3.39-2.79 (m, 4H), 2.43-1.82 (m, 10H), 1.38 (s, 9H).
6-083;
δ8.12-7.91 (m, 2H), 7.72-7.16 (m, 9H), 5.92-5.58 (m, 2H), 3.92-3.79 (m, 3H), 3.42-2.74 (m, 4H), 2.52-1.84 (m, 10H).
6-086;
δ7.53-7.48 (m, 2H), 7.40-7.36 (m, 2H), 7.22 (brs, 2H), 3.86 (s, 3H), 3.35-2.25 (m, 8H), 2.20-2.12 (m, 6H), 1.99-1.96 (m, 3H), 1.88 (s, 3H), 1.18-1.12 (m, 3H).
6-089;
δ7.42-7.30 (m, 1H), 7.25-7.12 (m, 4H), 3.86 (s, 3H), 3.70-3.26 (m, 9H), 3.15-2.79 (m, 3H), 2.40-2.11 (m, 7H), 1.88 (s, 3H).
6-090;
δ7.51-7.45 (m, 1H), 7.32-7.19 (m, 2H), 7.09 (brs, 2H), 3.86 (s, 3H), 3.70-3.26 (m, 9H), 3.12-2.82 (m, 3H), 2.36-2.23 (m, 1H), 2.17 (s, 3H), 2.14 (s, 3H), 1.89 (s, 3H).
6-091;
δ7.29-7.19 (m, 2H), 7.03-6.93 (m, 1H), 6.85-6.70 (m, 2H), 6.67 (brs, 1H), 6.54 (brs, 1H), 4.65 (s, 2H), 3.84 and 3.83 (s, 3H), 3.69-3.60 (m, 3H), 3.38-2.77 (m, 3H), 2.65-2.20 and 2.11-1.99 (m, 8H), 1.89-1.79 (m, 3H).
6-092;
δ7.50-7.47 (m, 1H), 7.31-6.92 (m, 7H), 6.80-6.67 (m, 2H), 4.69 (s, 2H), 3.85 (s, 3H), 3.37-2.78 (m, 4H), 2.40-2.28 (m, 1H), 2.15-2.02 (m, 6H), 1.88 (s, 3H).
6-093;
δ7.65-7.57 (m, 1H), 7.48-7.38 (m, 1H), 7.25-7.15 (m, 3H), 3.86 (s, 3H), 3.70-3.30 (m, 9H), 3.11-2.82 (m, 3H), 2.35-2.24 (m, 1H), 2.18 (s, 3H), 2.16 (s, 3H), 2.05 (s, 3H).
6-094;
δ6.66 (brs, 1H), 6.57-6.52 (m, 1H), 3.85and3.84 (s, 3H), 3.73-3.27 (m, 13H), 3.09-2.77 (m, 3H), 2.39-2.20 (m, 3H), 2.12-2.04 (m, 3H), 1.86 (s, 3H).
6-094(*2);
δ6.70-6.63 (m,1H), 6.57-6.50 (m,1H), 3.89-3.81 (m,3H), 3.74-3.25 (m,12H), 3.08-2.77 (m,3H), 2.38-2.16 (m,4H), 2.12-2.03 (m,3H), 1.94-1.84 (m,3H).
6-095;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 3.86and3.84 (s, 3H), 3.75-3.65 (m, 3H), 3.41-3.18 (m, 1H), 3.11-2.02 (m, 16H), 1.86 (s, 3H).
6-097;
δ6.63 (brs, 2H), 4.13-4.05 (m, 2H), 3.85 (s, 3H), 3.75-3.68 (m, 5H), 3.43 (s, 3H), 2.97-2.82 (m, 3H), 2.62-2.50 (m, 1H), 2.25-2.13 (m, 1H), 2.09 (s, 3H)), 2.06 (s, 3H)), 1.88 (s, 3H).
6-100;
δ7.67-7.51 (m, 2H), 7.50-7.27 (m, 5H), 7.14-6.87 (m, 5H), 4.64 (s, 2H), 4.00-3.71 (m, 6H), 3.52-3.30 (m, 1H), 3, 07-1.85 (m, 10H).
6-101;
δ7.82 (s, 1H), 7.25 (s, 1H), 7.18 (s, 1H), 7.09 (brs, 2H), 3.87 (s, 3H), 3.85 (s, 3H), 3.10-2.55 (m, 4H), 2.30-2.15 (m, 7H), 1.90 (s, 3H).
6-105;
δ8.49-8.40 (m, 1H), 7.57-7.27 (m, 5H), 7.14 (brs, 1H), 3.76-3.65 (m, 3H), 2.80-1.70 (m, 14H).
6-108;
δ11.32 (brs, 1H), 6.69-6.47 (m, 2H), 4.00-3.71 (m, 6H), 3.49-3.31 (m, 1H), 3.00-2.62 (m, 3H), 2.41-2.13 (m, 4H), 1.97 (s, 3H).
6-109;
δ6.66 (brs, 1H), 6.60-6.50 (m, 1H), 3.97-3.81 (m, 3H), 3.79-3.66 (m, 3H), 3.49-3.22 (m, 1H), 3.10-2.68 (m, 9H), 2.44-2.19 (m, 4H), 2.18-2.02 (m, 3H), 1.98-1.80 (m, 3H).
6-110;
δ6.66 (m, 1H), 6.57-6.52 (m, 1H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.47-3.20 (m, 5H), 3.07-2.78 (m, 3H), 2.39-2.17 (m, 4H), 2.10 and 2.08 (s, 3H), 1.93-1.77 (m.7H).
6-111;
δ6.66 (m, 1H), 6.57-6.50 (m, 1H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.50-3.11 (m, 5H), 3.06-2.67 (m, 3H), 2.38-2.19 (m, 4H), 2.09 and 2.07 (s, 3H), 1.97-1.83 (m.3H), 1.67-1.38 (m, 6H).
6-113;
δ11.85-11.73 and 10.63-10.52 and 9.65-9.35 (m, 1H), 7.07-6.98 (m, 1H), 6.92-6.83 (m, 1H), 4.33-4.05 (m, 1H), 3.93-3.65 (m, 6H), 3.57-1.82 (m, 9H), 1.38-0.98 (m, 3H).
6-114;
δ11.60-11.47 and 10.20-10.07 and 7.72-7.37 (m, 1H), 6.80-6.53 (m, 2H), 4.43-3.65 (m, 6H), 3.58-1.77 (m, 13H), 1.40-0.97 (m, 3H).
6-115;
δ6.70-6.45 (m, 2H), 3.88-3.77 (m, 3H), 3.70-3.60 (m, 3H), 3.48-2.62 (m, 8H), 2.37-2.13 (m, 4H), 2.11-1.99 (m, 3H), 1.94-1.78 (m, 3H), 1.13-0.82 (m, 6H).
6-116;
δ6.75-6.47 (m, 2H), 3.91-3.78 (m, 3H), 3.74-3.64 (m, 3H), 3.56-3.19 (m, 5H), 3.02-2.41 (m, 2H), 2.40-1.81 (m, 9H), 1.41-1.00 (m, 8H).
6-117;
δ6.71-6.48 (m, 2H), 3.93-3.62 (m, 6H), 3.31-2.70 (m, 3H), 2.42-1.81 (m, 11H), 1.21-1.05 (m, 9H).
6-118;
δ8.00-7.94 (m, 2H), 7.50-7.41 (m, 2H), 6.70-6.63 (m, 1H), 6.57-6.49 (m, 1H), 3.91-3.60 (m, 6H), 3.50-3.22 (m, 1H), 3.18-2.82 and 2.46-2.09 (m, 16H), 1.90-1.85 (m, 3H).
6-119;
δ7.43-7.28 (m, 3H), 6.97-6.87 (m, 2H), 6.68 (brs, 1H), 6.58 (brs, 1H), 3.89-3.82 (m, 3H), 3.75-3.67 (m, 3H), 3.37-2.78 (m, 4H), 2.49-2.28 (m, 4H), 2.15-2.06 (m, 3H), 1.98-1.82 (m, 3H).
6-120;
δ6.71-6.38 (m, 3H), 6.19-5.90 (m, 2H), 3.91-3.79 (m, 3H), 3.73-3.60 (m, 3H), 3.40-3.21 (m, 1H), 3.10-2.75 and 2.70-2.20 (m, 7H), 2.17-2.00 (m, 3H), 1.97-1.80 (m, 3H).
6-121;
δ8.00-7.90 (m, 2H), 7.67-7.53 (m, 1H), 7.50-7.37 (m, 2H), 6.69-6.63 (m, 1H), 6.57-6.50 (m, 1H), 3.91-3.82 (m, 3H), 3.69-3.62 (m, 3H), 3.49-3.32 (m, 1H), 3.15-2.65 (m, 3H), 2.46-2.22 (m, 4H), 2.20-2.02 (m, 3H), 1.97-1.80 (m, 3H).
6-122;
δ6.67 (brs, 1H), 6.55 (brs, 1H), 4.72-4.54 (m, 2H), 3.91-3.82 (m, 3H), 3.78-3.65 (m, 3H), 3.40-1.80 (m, 17H).
6-123;
δ6.70-6.47 (m, 2H), 4.22-3.50 (m, 6H), 3.30-2.40 (m, 4H), 2.29 (s, 3H), 2.15-1.79 (m, 6H), 1.40-1.02 (m, 12H).
6-124;
δ6.72-6.50 (m, 2H), 3.96-3.63 (m, 6H), 3.38-2.68 and 2.42-1.25 (m, 23H).
6-125;
δ6.79-6.53 (m, 2H), 4.00-3.62 (m, 6H), 3.30-2.65 and 2.40-1.81 (m, 20H).
6-126;
δ6.67 (brs, 1H), 6.56 (brs, 1H), 3.98-3.80 (m, 3H), 3.79-3.64 (m, 3H), 3.58-2.71 (m, 6H), 2.69-2.52 (m, 2H), 2.42-2.20 (m, 4H), 2.19-1.80 (m, 8H).
6-127;
δ6.66 (brs, 1H), 6.54 (brs, 1H), 3.88-2.83 (m, 18H), 2.39-1.77 (m, 9H), 1.38-1.02 (m, 3H).
6-129;
δ6.92-6.85 (m, 1H), 6.77-6.59 (m, 1H), 3.90-3.80 (m, 3H), 3.72-3.60 (m, 3H), 3.30-2.15 (m, 5H), 2.13-1.97 (m, 6H), 1.95-1.80 (m, 3H), 1.15-1.05 (m, 9H).
6-130;
δ6.90-6.80 (m, 1H), 6.77-6.57 (m, 1H), 3.87-3.60 (m, 9H), 3.38-2.70 (m, 4H), 2.40-2.20 (m, 1H), 2.10-1.97 (m, 6H), 1.90-1.78 (m, 3H).
6-131;
δ7.95-7.85 (m, 2H), 7.65-7.55 (m, 1H), 7.48-7.38 (m, 2H), 6.90 (brs, 1H), 6.75-6.70 (m, 1H), 3.85 and 3.84 (s, 3H), 3.65 and 3.63 (s, 3H), 3.51-3.35 (m, 1H), 3.15-2.80 (m, 3H), 2.45-2.28 (m, 1H), 2.13 and 2.11 (s, 3H), 2.06-2.00 (m, 3H), 1.88 (s, 3H).
6-132;
δ6.90 (brs, 1H), 6.80-6.70 (m, 1H), 3.85 and 3.84 (s, 3H), 3.73-3.25 (m, 12H), 3.10-2.70 (m, 3H), 2.40-2.20 (m, 1H), 2.15-2.00 (m, 6H), 1.86 (s, 3H).
6-133;
δ6.89 (brs, 1H), 6.78-6.60 (m, 1H), 3.84 and 3.83 (s, 3H), 3.69 and 3.68 (s, 3H), 3.48-3.15 (m, 5H), 3.05-2.75 (m, 3H), 2.37-1.80 (m, 14H).
6-134;
δ6.90 (brs, 1H), 6.77 (brs, 1H), 3.85 and 3.84 (s, 3H), 3.72 and 3.71 (s, 3H), 3.40-3.22 (m, 1H), 3.15-2.75 (m, 6H), 2.43-2.25 (m, 1H), 2.09 and 2.08 (s, 3H), 2.05 (s, 3H), 1.85 (s, 3H).
6-135;
δ6.90 (brs, 1H), 6.76 (brs, 1H), 3.85 and 3.84 (s, 3H), 3.71 and 3.69 (s, 3H), 3.43-3.25 (m, 1H), 3.13-2.55 (m, 9H), 2.43-2.20 (m, 1H), 2.09 and 2.08 (s, 3H), 2.05 (s, 3H), 1.85 (s, 3H).
6-136;
δ7.30-6.70 (m, 7H), 4.65 (s, 2H), 3.84 and 3.83 (s, 3H), 3.66 and 3.65 (s, 3H), 3.38-2.75 (m, 4H), 2.42-2.15 (m, 1H), 2.10-2.00 (m, 6H), 1.90-1.80 (m, 3H).
6-138;
δ6.66 (brs, 1H), 6.53 (brs, 1H), 3.85and3.84 (s, 3H), 3.73-3.64 (m, 3H), 3.50-3.20 (m, 1H), 3.09-2.73 (m, 4H), 2.38-2.15 (m, 9H), 2.11-2.05 (m, 3H), 1.91-1.83 (m, 3H), 1.66-1.55 (m, 3H), 1.18-1.00 (m, 3H).
6-139;
δ6.66 (brs, 1H), 6.57-6.50 (m, 1H), 4.00-3.61 (m, 9H), 3.51-3.20 (m, 1H), 3.08-2.62 and 2.50-
2.20 (m, 10H), 2.09 and 2.07 (s, 3H), 1.86 (s, 3H), 1.12-0.73 (m, 6H).
6-140;
δ6.66 (brs, 1H), 6.53 (brs, 1H), 4.03-3.20 and 3.12-2.68 and 2.60-2.23 (m, 20H), 2.20-2.04
(m, 3H), 1.98-1.82 (m, 3H), 1.21-0.98 (m, 6H).
6-142;
δ6.90 (brs, 2H), 3.85 (s, 3H), 3.70-3.60 (m, 2H), 3.57-3.22 (m, 7H), 3.09-2.98 (m, 1H), 2.97-2.82 (m, 2H), 2.49-2.15 (m, 8H), 1.87 (s, 3H), 1.13-1.02 (m, 6H).
6-143;
δ6.90 (brs, 2H), 3.85 (s, 3H), 3.59-3.42 (m, 3H), 3.25-3.15 (m, 2H), 3.06-2.80 (m, 3H), 2.53-2.17 (m, 8H), 1.90-1.75 (m, 7H), 1.13-1.02 (m, 6H).
6-144;
δ6.92 (brs, 2H), 3.85 (s, 3H), 3.42-3.30 (m, 1H), 3.14-2.80 (m, 6H), 2.45-2.20 (m, 8H), 1.86 (m, 3H), 1.18-1.02 (m, 6H).
6-145;
δ6.90 (brs, 2H), 3.85 (s, 3H), 3.42-3.30 (m, 1H), 3.13-2.82 (m, 3H), 2.74 (s, 6H), 2.50-2.20 (m, 8H), 1.87 (s, 3H), 1.12-1.02 (m, 6H).
6-146;
δ7.28-7.17 (m, 2H), 7.02-6.94 (m, 1H), 6.91 (brs, 2H), 6.75-6.52 (m, 2H), 4.64 and 4.62 (s, 2H), 3.84 (s, 3H), 3.35-3.25 (m, 1H), 3.12-3.02 (m, 1H), 3.00-2.82 (m, 2H), 2.62-2.20 (m, 8H), 1.86 and 1.85 (s, 3H), 1.12-1.02 (m, 6H).
6-147;
δ6.91 (brs, 2H), 3.85 (s, 3H), 3.78 (s, 3H), 3.40-3.27 (m, 1H), 3.12-3.00 (m, 1H), 2.98-2.70 (m, 2H), 2.45-2.20 (m, 8H), 1.87 (s, 3H), 1.13-1.00 (m, 6H).
6-148;
δ7.95-7.87 (m, 2H), 7.65-7.55 (m, 1H), 7.48-7.38 (m, 2H), 6.95-6.86 (m, 2H), 3.85 and 3.77 (s, 3H), 3.50-3.39 (m, 1H), 3.15-2.85 (m, 3H), 2.80-2.20 (m, 8H), 1.89 and 1.84 (s, 3H), 1.20-1.02 (m, 6H).
6-149;
δ7.57-7.52 (m, 2H), 7.43-7.38 (m, 2H), 7.16 (brs, 2H), 7.10 (m, 2H), 6.98-6.93 (m, 2H), 3.85 (s, 3H), 3.18-3.00 (m, 2H), 2.87-2.72 (m, 2H), 2.32-2.23 (m, 1H), 2.00 (s, 3H), 1.97 (s, 3H), 1.87 (s, 3H), 1.49 (s, 3H), 1.48 (s, 3H).
6-150;
δ7.61-7.56 (m, 2H), 7.50-7.46 (m, 2H), 7.41-7.37 (m, 2H), 7.20-7.17 (m, 2H), 7.13 (brs, 2H), 3.86 (s, 3H), 3.35-3.27 (m, 1H), 3.08-2.93 (m, 2H), 2.84-2.78 (m, 1H), 2.36 (s, 3H), 2.34-2.25 (m, 1H), 2.04 (s, 3H), 2.03 (s, 3H), 1.87 (s, 3H).
6-151;
δ7.54-7.49 (m, 2H), 7.42-7.38 (m, 2H), 7.19-7.12 (m, 5H), 6.87-6.83 (m, 2H), 3.84 (s, 3H), 3.28-3.20 (m, 1H), 3.05-2.97 (m, 1H), 2.87-2.80 (m, 2H), 2.30-2.21 (m, 1H), 2.13 (s, 3H), 1.96 (s, 3H)1.89 (s, 3H), 1.86 (s, 3H), 1.66 (s, 3H).
6-152;
δ6.88 (brs, 2H), 3.87-3.82 (m, 3H), 3.32-3.15 (m, 1H), 3.10-2.70 (m, 3H), 2.65-2.20 (m, 8H), 1.94 and 1.87 (s, 3H), 1.15-1.00 (m, 15H).
6-153;
δ7.25-7.12 (m, 5H), 6.62-6.42 (m, 2H), 3.87-3.80 (m, 3H), 3.60-3.52 (m, 3H), 3.21-2.62 (m, 4H), 2.38-2.17 (m, 4H), 2.00-1.83 (m.6H), 1.53-1.43 (m, 6H).
6-154;
δ10.74 (s, 1H), 6.78-6.50 (m, 2H), 4.15-1.80 (m, 19H), 1.38-1.20 (m, 3H).
6-155;
δ7.19-7.10 (m, 2H), 6.99-6.76 (m, 2H), 6.69 (brs, 1H), 6.56 (brs, 1H), 3.88-3.77 (m, 3H), 3.76-3.66 (m, 3H), 3.43-3.21 (m, 1H), 3.13-2.70 (m, 3H), 2.60-2.23 (m, 1H), 2.34 (s, 3H), 2.33 (s, 3H), 2.11 and 2.10 (s, 3H), 1.93-1.82 (m, 3H).
6-156;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 4.13 (t, J=6.8Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.37-3.16 (m, 1H), 3.09-2.63 (m, 3H), 2.40-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.67-1.52 (m, 3H), 1.39-1.20 (m, 5H), 0.93-0.81 (m, 3H).
6-157;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 4.13 (t, J=6.8Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.37-3.16 (m, 1H), 3.09-2.64 (m, 3H), 2.40-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.70-1.50 (m, 3H), 1.43-1.13 (m, 9H), 0.93-0.81 (m, 3H).
6-158;
δ6.67 (brs, 1H), 6.56 (brs, 1H), 4.37 (t, J=5.7Hz, 2H), 3.85 and 3.84 (s, 3H), 3.71 and 3.69 (s, 3H), 3.67-3.60 (m, 2H), 3.39-2.60 (m, 4H), 2.42-2.22 (m, 1H), 2.31 (s, 3H), 2.08 and 2.07 (s, 3H), 1.94-1.82 (m, 3H).
6-159;
δ6.67 (brs, 1H), 6.56 (brs, 1H), 4.30 (t, J=6.0Hz, 2H), 3.85 and 3.83 (s, 3H), 3.71 and 3.69 (s, 3H), 3.56 (t, J=6.3Hz, 2H), 3.38-3.13 (m, 1H), 3.10-2.78 (m, 3H), 2.41-2.22 (m, 1H), 2.31 (s, 3H), 2.13-2.02 (m, 5H), 1.94-1.82 (m, 3H).
6-160;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 4.13 (t, J=6.6Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.38-3.17 (m, 1H), 3.10-2.76 (m, 3H), 2.40-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.68-1.52 (m, 2H), 1.42-1.22 (m, 2H), 0.91 (t, J=7.2Hz, 3H).
6-161;
δ7.37-7.29 (m, 2H), 7.05-6.82 (m, 2H), 6.69 (brs, 1H), 6.58 (brs, 1H), 3.84 and 3.83 (s, 3H), 3.72 and 3.70 (s, 3H), 3.43-3.15 (m, 1H), 3.12-2.70 (m, 3H), 2.60-2.23 (m, 1H), 2.33 (s, 3H), 2.11 and 2.09 (s, 3H), 1.93-1.82 (m, 3H).
6-162;
δ7.50-7.41 (m, 1H), 7.33-7.09 (m, 3H), 6.69 (brs, 1H), 6.58 (brs, 1H), 3.84 and 3.83 (s, 3H), 3.73 and 3.72 (s, 3H), 3.43-3.22 (m, 1H), 3.12-2.78 (m, 3H), 2.46-2.25 (m, 1H), 2.33 (s, 3H), 2.11 and 2.10 (s, 3H), 1.93-1.84 (m, 3H).
6-163;
δ6.67 (brs, 1H), 6.56 (brs, 1H), 4.29-4.10 (m, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.69 (s, 3H), 3.61-3.46 (m, 2H), 3.37-3.14 (m, 1H), 3.10-2.65 (m, 3H), 2.42-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.99-1.67 (m, 7H).
6-164;
δ6.66 (brs, 1H), 6.58-6.51 (m, 1H), 4.11-3.97 (m, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.37-3.11 (m, 1H), 3.10-2.64 (m, 3H), 2.41-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.62-1.48 and 1.40-1.15 (m, 9H), 0.95-0.80 (m, 6H).
6-165;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 4.20 (q, J=7.2Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.69 (s, 3H), 3.37-3.11 (m, 1H), 3.08-2.62 (m, 3H), 2.42-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.28 (t, J=7.2Hz, 3H).
6-166;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 3.92 (d, J=6.6Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.37-3.17 (m, 1H), 3.09-2.77 (m, 3H), 2.42-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 2.01-1.83 (m, 1H), 1.86 (s, 3H), 0.93 (s, 3H), 0.91 (s, 3H).
6-167;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 4.10 (t, J=6.9Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.38-3.11 (m, 1H), 3.08-2.62 (m, 3H), 2.42-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.72-1.60 (m, 2H) , 0.93 (t, J=7.5Hz, 3H).
6-168;
δ6.67 (brs, 1H), 6.60-6.50 (m, 1H), 5.13-5.00 and 4.88-4.80 (m, 2H), 3.86 and 3.85 (s, 3H), 3.71 and 3.69 (s, 3H), 3.48-3.35 (m, 3H), 3.11-2.56 (m, 4H), 2.41-2.13 (m, 1H), 2.31 (s, 3H), 2.13-2.03 (m, 3H), 1.87 (s, 3H).
6-169;
δ6.66 (brs, 1H), 6.60-6.43 (m, 1H), 5.30-4.70 (m, 2H), 3.95-3.28 (m, 14H), 3.17-2.53 (m, 3H), 2.50-2.22 (m, 1H), 2.30 (s, 3H), 2.08 and 2.05 (s, 3H), 1.86 (s, 3H).
6-170;
δ6.66 (brs, 1H), 6.57-6.49 (m, 1H), 5.21-5.12 (m, 1H), 5.00-4.90 (m, 1H), 3.88-3.82 (m, 3H), 3.73-3.65 (m, 3H), 3.63-3.40 (m, 1H), 3.31-2.60 and 2.45-2.12 (m, 5H), 2.30 (s, 3H), 2.08 and 2.05 (s, 3H), 1.93-1.12 (m, 13H).
6-171;
δ6.70-6.63 (m, 1H), 6.58-6.50 (m, 1H), 5.18-5.06 (m, 1H), 4.92-4.84 (m, 1H), 3.90-3.82 (m, 3H), 3.75-3.52 (m, 5H), 3.31-3.18 and 3.11-2.57 and 2.43-2.13 (m, 5H), 2.32 (s, 3H), 2.10-2.03 (m, 3H), 1.92-1.84 (m, 3H), 1.29-1.13 (m, 3H).
6-172;
δ6.70-6.47 (m, 2H), 3.90-3.65 (m, 6H), 3.52-1.80 (m, 16H), 1.40-1.18 (m, 3H).
6-173;
δ7.29-7.10 (m, 3H), 7.03-6.95 (m, 1H), 6.63 (brs, 1H), 6.50 (brs, 1H), 3.83 and 3.82 (s, 3H), 3.62 (s, 2H), 3.59 and 3.58 (s, 3H), 3.30-2.72 (m, 4H), 2.40-2.20 (m, 4H), 2.00 and 1.97 (s, 3H), 1.85 and 1.84 (s, 3H).
6-174;
δ7.37-7.32 (m, 1H), 7.28-7.10 (m, 3H), 6.63(brs, 1H), 6.53-6.48 (m, 1H), 3.83 and 3.82 (s, 3H), 3.81 (s, 2H), 3.64 and 3.62 (s, 3H), 3.35-3.15 (m, 1H), 3.08-2.75 (m, 3H), 2.38-2.20 (m, 4H), 2.00 and 1.98 (s, 3H), 1.84 (s, 3H).
6-175;
δ7.20-7.13 (m, 2H), 7.05-6.96 (m, 2H), 6.63-6.57 (m, 1H), 6.48-6.39 (m, 1H), 3.87-3.80 (m, 3H), 3.78-3.67 (m, 1H), 3.57-3.48 (m, 3H), 3.28-2.63 (m, 4H), 2.38-2.18 (m, 4H), 1.98-1.88 (m, 3H), 1.85-1.82 (m, 3H), 1.47-1.39 (m, 3H).
6-176;
δ7.30-7.20 (m, 3H), 7.17-7.05 (m, 2H), 6.65-6.58 (m, 1H), 6.50-6.41 (m, 1H), 3.87-3.68 (m, 4H), 3.60-3.59 (m, 3H), 3.32-2.60 (m, 4H), 2.38-2.15 (m, 4H), 1.98-1.89 (m, 3H), 1.88-1.81 (m, 3H), 1.45 and 1.42 (s, 3H).
6-177;
δ7.23-7.15 (m, 2H), 7.05-6.97 (m, 2H), 6.65-6.57 (m, 1H), 6.50-6.42 (m, 1H), 3.86-3.80 (m, 3H), 3.65-3.50 (m, 5H), 3.30-2.13 (m, 8H), 2.05-1.80 (m, 6H).
6-178;
δ7.08-7.00 (m, 2H), 6.82-6.75 (m, 2H), 6.64 (brs, 1H), 6.51 (brs, 1H), 3.83 and 3.82 (s, 3H), 3.79 (s, 3H), 3.62-3.57 (m, 5H), 3.31-3.10 (m, 1H), 3.05-2.72 (m, 3H), 2.38-2.20 (m, 4H), 2.00 and 1.98 (s, 3H), 1.85-1.82 (m, 3H).
6-179;
δ7.53-7.45 (m, 2H), 7.30-7.28 (m, 2H), 6.66-6.58 (m, 1H), 6.50-6.40 (m, 1H), 3.87-3.80 (m, 3H), 3.75-3.68 (m, 2H), 3.63-3.48 (m, 3H), 3.33-2.18 (m, 8H), 2.15-1.80 (m, 6H).
6-180;
δ7.22-7.02 (m, 4H), 6.61 (brs, 1H), 6.50-6.47 (m, 1H), 3.83 and 3.82 (s, 3H), 3.65 (s, 2H), 3.57 and 3.55 (s, 3H), 3.30-3.10 (m, 1H), 3.05-2.92 (m, 1H), 2.90-2.72 (m, 2H), 2.38-2.15 (m, 4H), 2.09 (s, 3H), 1.96 and 1.93 (s, 3H), 1.86-1.82 (m, 3H).
6-181;
δ7.18-7.05 (m, 4H), 6.68-6.58 (m, 1H), 6.53-6.40 (m, 1H), 3.90-3.80 (m, 3H), 3.70-3.49 (m, 5H), 3.32-2.15 (m, 8H), 2.07-1.80 (m, 6H).
6-182;
δ7.17-7.10 (m, 2H), 7.16-6.98 (m, 2H), 6.65-6.58 (m, 1H), 6.52-6.44 (m, 1H), 3.85-3.80 (m, 3H), 3.65-3.52 (m, 5H), 3.30-2.65 (m, 4H), 2.47 (s, 3H), 2.40-2.10 (m, 4H), 2.05-1.78 (m, 6H).
6-183;
δ6.89-6.86 and 6.82-6.76 and 6.62-6.57 and 6.50-6.42 (m, 4H), 3.90-3.80 (m, 3H), 3.70-3.62 (m, 2H), 3.60-3.52 (m, 3H), 3.30-2.60 (m, 4H), 2.35-2.15 (m, 7H), 2.12-2.06 (m, 6H), 1.96-1.82 (m, 6H).
6-184;
δ7.20-7.10 (m, 2H), 7.00-6.93 (m, 1H), 6.75-6.60 (m, 3H), 6.42-6.36 (m, 1H), 3.88-3.80 (m, 3H), 3.67-3.60 (m, 3H), 3.25-2.95 (m, 2H), 2.88-2.57 (m, 2H), 2.41-2.23 (m, 4H), 2.10-2.00 (m, 3H), 1.88-1.82 (m, 3H), 1.55-1.45 (m, 6H).
6-185;
δ7.30-7.15 (m, 3H), 7.02-6.93 (m, 1H), 6.80-6.60 (m, 2H), 6.55-6.45 (m, 1H), 4.82-4.68 (m, 1H), 3.90-3.80 (m, 3H), 3.75-3.55 (m, 3H), 3.30-2.65 (m, 4H), 2.40-2.20 (m, 4H), 2.10-1.97 (m, 3H), 1.95-1.80 (m, 3H), 1.65-1.45 (m, 3H).
6-186;
δ7.20-7.13 (m, 2H), 6.72-6.65 (m, 3H), 6.54 (brs, 1H), 4.62 (s, 2H), 3.84 and 3.83 (s, 3H), 3.66 and 3.64 (s, 3H), 3.35-2.77 (m, 4H), 2.40-2.17 (m, 4H), 2.05 and 2.03 (s, 3H), 1.86 and 1.85 (s, 3H).
6-187;
δ6.80-6.52 (m, 6H), 4.59 (s, 2H), 3.84 and 3.83 (s, 3H), 3.76 (s, 3H), 3.66 and 3.65 (s, 3H), 3.38-3.13 (m, 1H), 3.10-2.75 (m, 3H), 2.42-2.22 (m, 4H), 2.06 and 2.04 (s, 3H), 1.86 and 1.85 (s, 3H).
6-188;
δ7.52-7.40 (m, 2H), 6.82-6.52 (m, 4H), 4.72-4.63 (m, 2H), 3.85-3.80 (m, 3H), 3.68-3.62 (m, 3H), 3.35-2.20 (m, 8H), 2.07-2.00 (m, 3H), 1.87-1.82 (m, 3H).
6-189;
δ7.12-7.00 (m, 2H), 6.78-6.50 (m, 4H), 4.65-4.60 (m, 2H), 3.84 and 3.83 (s, 3H), 3.66 and 3.64 (s, 3H), 3.35-3.13 (m, 1H), 3.12-2.75 (m, 3H), 2.65-2.20 (m, 4H), 2.10-2.00 (m, 3H), 1.95-1.80 (m, 3H).
6-190;
δ7.37-7.20 (m, 2H), 7.05-6.93 (m, 2H), 6.66 (brs, 1H), 6.55 (brs, 1H), 4.68 (s, 2H), 3.84 and 3.83 (s, 3H), 3.68 and 3.66 (s, 3H), 3.38-3.13 (m, 1H), 3.11-2.75 (m, 3H), 2.40-2.15 (m, 4H), 2.05 and 2.03 (s, 3H), 1.86 and 1.85 (s, 3H).
6-191;
δ7.37-7.30 (m, 1H), 7.05-6.98 (m, 1H), 6.64 (brs, 1H), 6.55-6.48 (m, 2H), 4.70 (s, 2H), 3.84 and 3.83 (s, 3H), 3.65 and 3.64 (s, 3H), 3.36-3.13 (m, 1H), 3.11-2.75 (m, 3H), 2.40-2.25 (m, 4H), 2.03 and 2.01 (s, 3H), 1.86 and 1.85 (s, 3H).
6-192;
δ7.17-7.08 (m, 2H), 6.68-6.59 (m, 3H), 6.56-6.46 (m, 1H), 4.74-4.62 (m, 1H), 3.87-3.81 (m, 3H), 3.67 and 3.66 and 3.58 and 3.56 (s, 3H), 3.29-2.95 (m, 2H), 2.90-2.66 (m, 2H), 2.38-2.20 (m, 1H), 2.33 (s, 3H), 2.05-1.96 (m, 3H), 1.85 and 1.84 (s, 3H), 1.60-1.49 (m, 3H).
6-193;
δ7.43-7.20 (m, 3H), 7.12-7.02 (m, 2H), 6.69 (brs, 1H), 6.58 (brs, 1H), 3.84 and 3.83 (s, 3H), 3.72 and 3.71 (s, 3H), 3.45-3.20 (m, 1H), 3.13-2.70 (m, 3H), 2.45-2.25 (m, 4H), 2.11 and 2.10 (s, 3H), 1.86 and 1.85 (s, 3H).
6-195;
δ6.65 (brs, 1H), 6.55-6.49 (m, 1H), 3.85 and 3.84 (s, 3H), 3.69 and 3.67 (s, 3H), 3.44-3.21 (m, 6H), 3.07-2.78 (m, 3H), 2.39-2.19 (m, 1H), 2.30 (s, 3H), 2.09 and 2.07 (s, 3H), 1.86 (s, 3H), 1.79-1.56 (m, 7H) .
6-196;
δ7.39-7.21 (m, 5H), 6.70-6.47 (m, 2H), 5.25-5.12 (m, 1H), 5.00-4.93 (m, 1H), 4.72-4.56 (m, 2H), 3.89-3.81 (m, 3H), 3.72-3.63 (m, 3H), 3.28-2.58 and 2.43-2.13 (m, 8H), 2.11- 2.01 (m, 3H), 1.98-1.84 (m, 3H).
6-197;
δ7.85-7.82 (m, 1H), 7.77-7.65 (m, 2H), 7.57-7.49 (m, 1H), 6.46 (s, 1H), 6.29 (s, 1H), 3.85 and 3.84 (s, 3H), 3.58-3.56 (m, 3H), 3.33-2.76 (m, 4H), 2.47-2.29 (m, 1H), 2.22 (s, 3H), 1.98 and 1.97 (s, 3H), 1.86 and 1.85 (s, 3H).
6-198;
δ7.99-7.97 (m, 1H), 7.75-7.65 (m, 2H), 7.59-7.53 (m, 1H), 6.47 (s, 1H), 6.28 (s, 1H), 3.86 and 3.84 (s, 3H), 3.56 and 3.53 (s, 3H), 3.31-3.16 (m, 1H), 3.07-2.73 (m, 3H), 2.38-2.18 (m, 4H), 1.93 and 1.92 (s, 3H), 1.85 and 1.84 (s, 3H).
6-199;
δ7.60-7.56 (m, 2H), 7.32-7.27 (m, 2H), 6.54 (s, 1H), 6.38 (s, 1H), 3.87 and 3.84 (s, 3H), 3.58 and 3.56 (s, 3H), 3.30-2.71 (m, 4H), 2.38-2.22 (m, 4H), 1.94 and 1.93 (s, 3H), 1.84 and 1.83 (s, 3H).
6-200;
δ7.61 (d, J=8.7Hz, 2H), 7.20 (d, J=8.7Hz, 2H), 6.55 (s, 1H), 6.42 (s, 1H), 3.86 and 3.84 (s, 3H), 3.61 and 3.58 (s, 3H), 3.26-2.17 (m, 1H), 2.94-2.74 (m, 3H), 2.42-2.17 (m, 7H), 1.94 and 1.92 (s, 3H), 1.84 and 1.83 (s, 3H).
6-201;
δ6.65 (s, 1H), 6.54 (m, 1H), 3.85-3.83 (m, 3H), 3.70 and 3.69 (s, 3H), 3.33-3.26 (m, 4H), 3.16-2.79 (m, 4H), 2.39-2.24 (m 4H), 2.08 and 2.07 (s, 3H), 1.93-1.86 (m, 7H).
6-202;
δ6.66 (s, 1H), 6.55 (s, 1H), 3.86-3.84 (m, 3H), 3.71 and 3.70 (s, 3H), 3.65-3.57 (m, 4H), 3.38-2.79 (m, 8H), 2.40-2.28 (m, 4H), 2.07 and 2.06 (s, 3H), 1.86 (s, 3H).
6-203;
δ7.21-7.15 (m, 1H), 6.99-6.97 (m, 2H), 6.63 (s, 1H), 6.51 (s, 1H), 3.87-3.82 (m, 3H), 3.68-3.63 (m, 3H), 3.41-2.74 (m, 4H), 2.63-2.34 (m, 1H), 2.29 (s, 3H), 2.17 (s, 3H), 2.13-2.06 (m, 6H), 1.97-1.88 (m, 3H).
6-204;
δ6.87 (s, 1H), 6.80 (s, 1H), 6.62 (s, 1H), 6.51 (s, 1H), 3.88-2.82 (m, 3H), 3.68-3.63 (m, 3H), 3.49-3.28 (m, 4H), 2.63-2.33 (m, 4H), 2.29-2.25 (m, 6H), 2.18 (s, 3H), 2.12-2.04 (m, 3H), 1.96-1.88 (m, 3H).
6-205;
δ7.31-7.26 (m, 1H), 6.63 (s, 1H), 6.53-6.48 (m, 3H), 3.86-3.81 (m, 3H), 3.74-3.66 (m, 9H), 3.41-2.81 (m, 4H), 2.63-2.28 (m, 4H), 2.18-2.04 (m, 3H), 1.96-1.87 (m, 3H).
6-206;
δ7.28-7.23 (m, 3H), 6.63 (s, 1H), 6.52 (s, 1H), 3.87 and 3.84 (s, 3H), 3.69 and 3.65 (s, 3H), 3.43-3.30 (m, 1H), 3.14-2.84 (m, 3H), 2.57-2.32 (m, 1H), 2.29 (s, 3H), 2.11 and 2.09 (s, 3H), 1.89 (s, 3H).
6-207;
δ6.63 (s, 1H), 6.52 (s, 1H), 3.85 and 3.84 (s, 3H), 3.68 and 3.67 (s, 3H), 3.49 (s, 2H), 3.30-3.13 (m, 1H), 3.08-2.97 (m, 1H), 2.90-2.63 (m, 2H), 2.38-2.24 (m, 4H), 2.09-2.02 (m, 3H), 1.93-1.86 (m, 3H), 1.20 and 1.19 (s, 6H).
6-208;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 5.62-5.30 (m, 2H), 3.89-3.76 (m, 3H), 3.75-3.60 (m, 3H), 3.30-2.50 and 2.42-1.97 (m, 11H), 1.95-1.79 (m, 3H), 1.21 (s, 3H), 1.20 (s, 3H), 1.16 (s, 3H).
6-214;
δ7.70-7.62 (m, 1H), 7.30-7.24 (m, 1H), 7.08-7.00 (m, 1H), 6.55-6.50 (m, 1H), 6.40-6.33 (m, 1H), 3.90-3.82 (m, 3H), 3.72-3.52 (m, 3H), 3.30-3.15 (m, 1H), 3.05-2.60 (m, 3H), 2.40-2.17 (m, 10H), 1.95-1.80 (m, 6H).
6-220;
δ7.58-7.26 (m, 4H), 6.58-6.52 (m, 1H), 6.46-6.40 (m, 1H), 3.85 and 3.84 (s, 3H), 3.60 and 3.57 (s, 3H), 3.31-3.15 (m, 1H), 3.08-2.70 (m, 3H), 2.40-2.20 (m, 7H), 1.93 and 1.91 (s, 3H), 1.84 and 1.83 (s, 3H).
6-224;
δ7.80-7.53 (m, 4H), 6.65 (brs, 1H), 6.53 (brs, 1H), 3.85 and 3.84 (s, 3H), 3.67 and 3.65 (s, 3H), 3.48-3.27 (m, 1H), 3.17-2.82 (m, 3H), 2.46-2.32 (m, 1H), 2.29 (s, 3H), 2.10 and 2.08 (s, 3H), 1.89 and 1.88 (s, 3H).
6-225;
δ7.54 (brs, 2H), 7.20 (brs, 1H), 6.66 (brs, 1H), 6.55-6.51 (m, 1H), 3.84 and 3.83 (s, 3H), 3.67 and 3.66 (s, 3H), 3.43-3.32 (m, 1H), 3.12-2.82 (m, 3H), 2.42-2.28 (m, 10H), 2.13 and 2.11 (s, 3H), 1.88 (s, 3H).
6-226;
δ7.70-7.55 (m, 2H), 7.32-7.19 (m, 1H), 6.65 (brs, 1H), 6.52 (brs, 1H), 3.85 and 3.84 (s, 3H), 3.67 and 3.65 (s, 3H), 3.48-3.27 (m, 1H), 3.17-2.80 (m, 3H), 2.45-2.28 (m, 4H), 2.11 and 2.09 (s, 3H), 1.89 and 1.88 (s, 3H).
6-227;
δ7.82-7.77 (m, 2H), 7.60-7.55 (m, 1H), 6.67 (brs, 1H), 6.56-6.50 (m, 1H), 3.85 and 3.84 (s, 3H), 3.68 and 3.67 (s, 3H), 3.41-3.28 (m, 1H), 3.15-2.80 (m, 3H), 2.45-2.28 (m, 4H), 2.12 and 2.10 (s, 3H), 1.88 and 1.87 (s, 3H).
6-228;
δ8.01 (d, J=1.5Hz, 1H), 7.74 (dd, J=8.1Hz, 1.5Hz, 1H), 7.51 (d, J=8.1Hz, 1H), 6.67 (brs, 1H), 6.56-6.51 (m, 1H), 3.85 and 3.84 (s, 3H), 3.66 and 3.65 (s, 3H), 3.44-3.31 (m, 1H), 3.15-2.80 (m, 3H), 2.43-2.28 (m, 4H), 2.12 and 2.10 (s, 3H), 1.88 and 1.87 (s, 3H).
6-229;
δ7.31 (s, 2H), 6.62 (brs, 1H), 6.54-6.48 (m, 1H), 3.86 and 3.85 (s, 3H), 3.68 and 3.66 (s, 3H), 3.43-3.27 (m, 1H), 3.20-2.80 (m, 3H), 2.48-2.28 (m, 4H), 2.09 and 2.07 (s, 3H), 1.88 (s, 3H).
6-230;
δ8.00-7.90 (m, 2H), 7.15-7.05 (m, 2H), 6.66 (brs, 1H), 6.55-6.48 (m, 1H), 3.85 and 3.84 (s, 3H), 3.65 and 3.63 (s, 3H), 3.48-3.32 (m, 1H), 3.13-2.80 (m, 3H), 2.43-2.28 (m, 4H), 2.12 and 2.10 (s, 3H), 1.88 (s, 3H).
6-231;
δ7.08-7.03 (m, 2H), 6.67-6.62 (m, 2H), 6.55-6.50 (m, 1H), 3.85 and 3.84 (s, 3H), 3.75 (s, 6H), 3.66 and 3.65 (s, 3H), 3.52-3.32 (m, 1H), 3.13-2.80 (m, 3H), 2.45-2.25 (m, 4H), 2.13 and 2.11 (s, 3H), 1.88 (s, 3H).
6-232;
δ7.85-7.78 (m, 1H), 7.48-7.38 (m, 1H), 7.31-7.16 (m, 2H), 6.65 (brs, 1H), 6.55-6.50 (m, 1H), 3.85 and 3.84 (s, 3H), 3.66 and 3.64 (s, 3H), 3.45-3.32 (m, 1H), 3.15-2.82 (m, 3H), 2.49 (s, 3H), 2.45-2.27 (m, 4H), 2.12 and 2.10 (s, 3H), 1.88 (s, 3H).
6-232(*2);
δ7.90-7.78 (m,1H), 7.50-7.37 (m,1H), 7.32-7.15 (m,2H), 6.70-6.42 (m,2H), 3.90-3.52 (m,6H), 3.42-1.82 (m,17H).
6-233;
δ7.75-7.65 (m, 2H), 7.40-7.28 (m, 2H), 6.66 (brs, 1H), 6.55-6.51 (m, 1H), 3.85 and 3.84 (s, 3H), 3.68 and 3.66 (s, 3H), 3.50-3.30 (m, 1H), 3.15-2.82 (m, 3H), 2.45-2.27 (m, 4H), 2.12 and 2.10 (s, 3H), 1.89 and 1.88 (s, 3H).
6-234;
δ6.63 (s, 1H), 6.51 (s, 1H), 3.85 and 3.84 (s, 3H), 3.68 and 3.67 (s, 3H), 3.26-2.71 (m, 4H), 2.39-2.23 (m, 4H), 2.06 and 2.05 (s, 3H), 1.86 (s, 3H), 1.55-1.25 (m, 4H), 1.17 and 1.09 (s, 6H), 0.76-0.71 (m, 3H).
6-235;
δ6.64 (s, 1H), 6.53 (s, 1H), 3.85 and 3.84 (s, 3H), 3.68 and 3.66 (s, 3H), 3.30-3.14 (m, 1H), 3.07-2.95 (m, 1H), 2.88-2.75 (m, 2H), 2.39-2.28 (m, 4H), 2.06 and 2.04 (s, 3H), 1.86 (s, 3H), 1.06 (s, 2H), 0.94 and 0.93 (s, 9H).
6-236;
δ7.34-7.28 (m, 3H), 7.18-7.12 (m, 2H), 6.87 (s, 2H), 4.99 and 4.95 (s, 3H), 4.28-4.10 (m, 1H), 3.88 (s, 3H), 2.89-2.78 (m, 2H), 2.63-2.53 (m, 1H), 2.27 (s, 3H), 2.06 (s, 6H), 1.90 (s, 3H).
6-237(*3);
δ6.89 (s, 2H), 4.33 (brs, 1H), 3.89 (s, 3H), 3.38 (brs, 1H), 2.76-2.38 (m, 1H), 2.45-2.39 (m, 1H), 2.26 (s, 3H), 2.11 and 2.09 (s, 6H), 1.97 (s, 3H).
6-239;
δ7.84-7.77 (m, 1H), 7.64-7.59 (m, 1H), 7.14-7.08 (m, 1H), 6.67 (brs, 1H), 6.60-6.50 (m, 1H), 3.85 and 3.84 (s, 3H), 3.66 and 3.65 (s, 3H), 3.46-3.32 (m, 1H), 3.14-2.60 (m, 3H), 2.45-2.05 (m, 7H), 1.96-1.84 (m, 3H).
6-240;
δ7.94-7.89 (m, 1H), 7.87-7.78 (m, 1H), 7.60-7.52 (m, 1H), 7.40-7.32 (m, 1H), 6.67 (s, 1H), 6.57-6.50 (m, 1H), 3.85 and 3.84 (s, 3H), 3.67 and 3.66 (s, 3H), 3.46-3.32 (m, 1H), 3.13-2.82 (m, 3H), 2.45-2.30 (m, 4H), 2.13 and 2.11 (s, 3H), 1.90-1.87 (m, 3H).
6-241;
δ7.92-7.82 (m, 2H), 7.47-7.36 (m, 2H), 6.66 (s, 1H), 6.55-6.49 (m, 1H), 3.85 and 3.84 (s, 3H), 3.65 and 3.63 (s, 3H), 3.48-3.31 (m, 1H), 3.14-2.82 (m, 3H), 2.45-2.27 (m, 4H), 2.12 and 2.10 (s, 3H), 1.88 (brs, 3H).
6-242;
δ8.20 (brs, 1H), 8.14-8.08 (m, 1H), 7.88-7.80 (m, 1H), 7.63-7.55 (m, 1H), 6.67 (s, 1H), 6.56-6.49 (m, 1H), 3.85 and 3.84 (s, 3H), 3.67 and 3.65 (s, 3H), 3.46-3.34 (m, 1H), 3.17-2.82 (m, 3H), 2.45-2.28 (m, 4H), 2.13 and 2.12 (s, 3H), 1.92-1.87 (m, 3H).
6-243;
δ8.79-8.76 (m, 1H), 8.47-8.41 (m, 1H), 8.29-8.23 (m, 1H), 7.70-7.62 (m, 1H), 6.68 (s, 1H), 6.55 (brs, 1H), 3.86 and 3.85 (s, 3H), 3.70 and 3.69 (s, 3H), 3.48-3.33 (m, 1H), 3.18-2.83 (m, 3H), 2.45-2.25 (m, 4H), 2.14 and 2.12 (s, 3H), 1.93-1.87 (m, 3H).
6-246;
δ7.76-7.68 (m, 2H), 7.20-7.12 (m, 2H), 6.55 (brs, 1H), 6.39 (brs, 1H), 3.87 and 3.84 (s, 3H), 3.59 and 3.56 (s, 3H), 3.32-3.19 (m, 1H), 3.10-2.72 (m, 3H), 2.40-2.10 (m, 4H), 1.94 and 1.92 (s, 3H), 1.85 and 1.84 (s, 3H).
6-249;
δ7.74-7.68 (m, 1H), 7.47-7.35 (m, 2H), 6.67 (brs, 1H), 6.55 (brs, 1H), 3.86 and 3.85 (s, 3H), 3.71 and 3.69 (s, 3H), 3.45-3.30 (m, 1H), 3.14-2.83 (m, 3H), 2.45- 2.25 (m, 4H), 2.12 and 2.10 (s, 3H), 1.89 and 1.88 (s, 3H).
6-250;
δ7.73-7.68 (m, 1H), 7.55-7.46 (m, 1H), 7.05-6.88 (m, 2H), 6.65 (brs, 1H), 6.57-6.50 (m, 1H), 3.87-3.78 (m, 6H), 3.75-3.60 (m, 3H), 3.50-3.33 (m, 1H), 3.12-2.82 (m, 3H), 2.43-2.25 (m, 4H), 2.12 and 2.10 (s, 3H), 1.88 (s, 3H).
6-251;
δ7.77-7.70 (m, 1H), 7.65-7.57 (m, 1H), 7.45-7.37 (m, 1H), 7.34-7.27 (m, 1H), 6.67 (brs, 1H), 6.56-6.50 (m, 1H), 3.85 and 3.84 (s, 3H), 3.66 and 3.65 (s, 3H), 3.46-3.32 (m, 1H), 3.14-2.82 (m, 3H), 2.46-2.30 (m, 4H), 2.13 and 2.11 (s, 3H), 1.88 (s, 3H).
6-252;
δ8.00-7.90 (m, 1H), 7.72-7.52 (m, 3H), 6.68 (brs, 1H), 6.54 (brs, 1H), 3.87 and 3.86 (s, 3H), 3.68 and 3.67 (s, 3H), 3.53-3.34 (m, 1H), 3.17-2.82 (m, 3H), 2.48-2.27 (m, 4H) , 2.10 and 2.07 (s, 3H), 1.92-1.87 (m, 3H).
6-254;
δ7.09-7.04 (m, 1H), 6.96-6.90 (m, 1H), 3.89-3.82 (m, 3H), 3.34-3.19 (m, 1H), 3.13-2.98 (m, 1H), 2.91-2.80 (m, 2H), 2.39-2.24 (m, 4H), 2.14-2.08 (m, 3H), 1.91-1.85 (m, 3H), 1.16-1.13 (m, 9H).
6-255;
δ7.22-6.94 (m, 5H), 6.76-6.68 (m, 1H), 3.87-3.83 (m, 3H), 3.53-3.29 (m, 1H), 3.18-2.77 (m, 3H), 2.43-2.25 (m, 7H), 2.18-2.11 (m, 3H), 1.93-1.84 (m, 3H).
6-256;
δ7.12-7.02 (m, 1H), 7.00-6.90 (m, 1H), 5.32-4.86 (m, 2H), 3.92-3.84 (m, 3H), 3.84-2.09 (m, 18H), 1.93-1.85 (m, 3H).
6-257;
δ7.11-7.03 (m, 1H), 7.01-6.90 (m, 1H), 3.91-3.82 (m, 3H), 3.76-3.21 (m, 9H), 3.12-2.75 (m, 3H), 2.45-2.09 (m, 7H), 1.91-1.86 (m, 3H).
6-259(*3);
δ6.70-6.40 (m, 2H), 3.90 (s, 3H), 3.45-3.30 (m, 1H), 3.00-2.50 (m, 3H), 2.40-1.85 (m, 10H).
6-260;
δ6.62 (brs, 1H), 6.52-6.48 (m, 1H), 3.90-3.75 (m, 6H), 3.70-3.65 (m, 3H), 3.50-3.35 (m, 1H), 3.15-2.80 (m, 3H), 2.40-2.05 (m, 7H), 1.86 (s, 3H).
6-261;
δ6.63 (brs, 1H), 6.55-6.45 (m, 1H), 4.00-3.82 (m, 6H), 3.70-3.60 (m, 3H), 3.50-3.35 (m, 1H), 3.18-2.80 (m, 3H), 2.43-2.05 (m, 10H), 1.98-1.82 (s, 6H).
6-262;
δ6.63 (brs, 1H), 6.55-6.40 (m, 1H), 5.20-5.12 (m, 1H), 3.88-3.77 (m, 3H), 3.65-3.55 (m, 3H), 3.50-3.30 (m, 1H), 3.18-2.80 (m, 3H), 2.45-2.00 (m, 10H), 1.90-1.75 (m, 6H), 1.40-1.20 (m, 6H).
6-263;
δ6.65 (brs, 1H), 6.55-6.40 (m, 1H), 3.90-3.80 (m, 3H), 3.78-3.60 (m, 4H), 3.50-3.30 (m, 1H), 3.15-2.80 (m, 3H), 2.66 (s, 3H), 2.32-2.25 (m, 4H), 2.20-2.18 (m, 3H), 1.87 (s, 3H), 1.25-1.10 (m, 6H).
6-264;
δ6.66 (brs, 1H), 6.51 (brs, 1H), 3.85 and 3.83 (s, 3H), 3.65 and 3.63 (s, 3H), 3.47-3.25 (m, 1H), 3.15-2.80 (m, 3H), 2.74 (s, 3H), 2.45-2.25 (m, 4H), 2.15-2.02 (m, 3H), 1.95-1.85 (m, 3H).
6-266(*3);
δ7.10-6.82 (m, 2H), 6.67-6.04 (m, 1H), 3.91 (s, 3H), 3.53-3.31 (m, 1H), 3.07-2.50 (m, 3H), 2.32-1.20 (m, 10H).
6-267;
δ9.75-9.40 and 9.30-8.60 and 8.00-7.50 (m, 1H), 6.80-6.52 (m, 2H), 5.80-5.00 (m, 1H), 4.05- 3.70 (m, 6H), 3.69-1.85 (m, 12H).
6-268;
δ11.10-10.90 (m, 1H), 6.80-6.50 (m, 2H), 6.04-5.87 (m, 1H), 5.42-5.10 (m, 2H), 4.60-4.38 (m, 2H), 3.95-3.80 (m, 3H), 3.46-3.30 (m, 1H), 2.98-1.83 (m, 13H).
6-269;
δ11.22-10.95 (m, 1H), 6.85-6.65 (m, 2H), 4.70-4.55 (m, 2H), 3.95-3.81 (m, 3H), 3.50-3.30 (m, 1H), 3.04-1.80 (m, 14H).
6-271;
δ11.55-11.37 (m, 1H), 7.52-7.43 (m, 1H), 6.82-6.59 (m, 2H), 5.18-4.99 (m, 2H), 3.97-3.82 (m, 3H), 3.45-3.30 (m, 1H), 2.98-1.82 (m, 13H).
6-272;
δ11.78-10.90 (m, 1H), 6.88-6.50 (m, 2H), 4.80-4.55 (m, 2H), 4.00-3.60 (m, 3H), 3.50-3.25 (m, 1H), 3.05-1.80 (m, 13H).
6-273;
δ11.05-10.95 (m, 1H), 6.80-6.37 (m, 2H), 5.00-4.50 (m, 2H), 3.95-3.70 (m, 6H), 3.50-3.25 (m, 1H), 3.00-1.82 (m, 13H).
6-274;
δ11.60-11.30 (m, 1H), 6.90-6.72 (m, 1H), 6.65-6.50 (m, 1H), 4.35-4.18 (m, 2H), 4.00-3.78 (m, 3H), 3.50-3.30 (m, 1H), 3.05-1.80 (m, 13H).
6-275(*3);
δ6.80-6.55 (m, 2H), 4.28-3.70 (m, 6H), 3.30-1.95 (m, 13H).
7-001(*3);
δ7.25-7.15 (m, 2H), 4.20-4.05 (m, 1H), 3.90-3.65 (m, 4H), 3.30-2.00 (m, 10H), 1.15-1.00 (m, 3H).
7-017(*3);
δ8.90-8.80 (m, 2H), 8.03 (brs, 2H), 7.70-7.60 (m, 1H), 3.00-2.80 (m, 3H), 2.70-2.60 (m, 1H), 2.35-2.25 (m, 1H), 2.12 (s, 9H).
7-027;
δ7.02 (brs, 1H), 6.88 (brs, 1H), 3.91-3.62 (m, 3H), 3.51-1.97 (m, 12H).
7-030;
δ9.05 (brs, 1H), 6.81-6.55 (m, 2H), 3.86-3.81 (m, 3H), 3.52-2.53 (m, 3H), 2.52-2.03 (m, 11H).
7-032;
δ9.92-9.00 (m, 1H), 6.91 (brs, 2H), 4.25-4.50 (m, 4H), 3.30-3.10 (m, 1H), 3.00-2.65 (m, 2H), 2.55-2.10 (m, 10H), 1.15-0.95 (m, 6H).
7-034;
δ9.20-8.30 (m, 1H), 6.75-6.65 (m, 1H), 6.64-6.50 (m, 1H), 4.25-3.85 (m, 2H), 3.83-3.67 (m, 3H), 3.40-2.05 (m, 13H), 1.40-1.20 (m, 3H).
7-037;
δ6.66 (s, 1H), 6.54 (s, 1H), 3.69-3.32 (m, 12H), 3.18-3.01 (m, 2H), 2.92-2.59 (m, 2H), 2.31 (s, 3H), 2.20 and 2.18 (s, 3H), 2.10 and 2.08 (s, 3H).
7-039;
δ7.43-7.00 (m, 10H), 6.73-6.55 (m, 2H), 5.10-4.85 (m, 4H), 3.40-2.00 (m, 14H).
7-043(*3);
δ6.81-6.72 (m, 1H), 6.66-6.57 (m, 1H), 5.59-4.80 (m, 1H), 3.89-3.74 (m, 3H), 3.24-2.56 (m, 3H), 2.45-2.28 (m, 6H), 2.19-2.03 (m, 3H).
7-044;
δ6.66 (brs, 1H), 6.53 (brs, 1H), 6.05-5.65 (m, 2H), 5.40-5.05 (m, 4H), 4.60-4.35 (m, 4H), 3.50-2.00 (m, 14H).
7-045;
δ6.80-6.65 (m, 2H), 4.70-4.50 (m, 4H), 3.25-2.80 (m, 4H), 2.75-2.05 (m, 12H).
7-046;
δ6.75-6.50 (m, 2H), 4.25-3.90 (m, 4H), 3.75-2.05 (m, 24H).
7-047;
δ7.50-7.25 (m, 2H), 6.80-6.70 (m, 1H), 6.60-6.50 (m, 1H), 5.20-4.80 (m, 4H), 3.20-2.00 (m, 14H).
7-049;
δ9.20-9.00 (m, 1H), 6.80-6.65 (m, 2H), 4.65-4.50 (m, 2H), 3.40-2.05 (m, 15H).
7-052;
δ7.18-6.50 (m, 2H), 4.60-3.95 (m, 4H), 3.55-2.03 (m, 14H).
7-053;
δ6.93-6.82 (m, 1H), 6.75-6.60 (m, 1H), 4.78-4.50 (m, 4H), 3.80-2.00 (m, 14H).
7-054;
δ6.80-6.68 (m, 1H), 6.45-6.37 (m, 1H), 4.75-4.50 (m, 4H), 3.82-3.60 (m, 6H), 3.22-2.92 (m, 3H), 2.70-2.02 (m, 11H).
7-055;
δ10.20-9.92 (m, 1H), 6.92-6.50 (m, 2H), 4.75-4.50 (m, 2H), 3.85-1.95 (m, 14H).
7-056;
δ9.90-9.65 (m, 1H), 6.90-6.47 (m, 2H), 4.42-4.05 (m, 2H), 3.42-1.90 (m, 14H).
9-003;
δ7.25-7.19 (m, 2H), 7.08 (s, 2H), 7.02-6.92 (m, 1H), 6.73-6.54 (m, 2H), 4.67-4.57 (m, 2H), 3.85-3.77 (m, 3H), 3.41-2.38 (m, 5H), 2.24-1.95 (m, 10H), 1.17-0.99 (m, 6H).
9-004;
δ11.95 (s, 1H), 7.85 (s, 1H), 7.59 (s, 1H), 7.33 (s, 2H), 3.91 (s, 3H), 3.50-3.29 (m, 2H), 3.03-2.92 (m, 1H), 2.87-2.77 (m, 1H), 2.50-2.09 (m, 8H), 1.17-1.05 (m, 6H).
9-005;
δ11.79 (s, 1H), 7.09 (s, 2H), 3.91 (s, 3H), 3.50-3.25 (m, 2H), 3.10-2.75 (m, 2H), 2.48-2.35 (m, 1H), 2.33-2.21 (m, 1H), 2.19-2.00 (m, 9H), 1.19-1.05 (m, 6H).
9-007;
δ12.17 (s, 1H), 7.85 (s, 1H), 7.59 (s, 1H), 7.38-7.28 (m, 2H), 3.94 (s, 3H), 3.38-3.25 (m, 1H), 2.92 (dd, J=17.7, 7.5Hz, 1H), 2.47-2.35 (m, 1H), 2.30-2.07 (m, 8H), 1.10-0.82 (m, 5H).
9-012;
δ7.89 (s, 1H), 7.64 (s, 1H), 7.32 (brs, 2H), 7.23-7.11 (m, 2H), 6.99-6.88 (m, 1H), 6.75-6.61 (m, 2H), 4.70-4.59 (m, 2H), 4.47-4.32 (m, 2H), 3.72-1.83 (m, 14H).
9-013;
δ7.28-7.18 (m, 2H), 7.07 (brs, 2H), 7.03-6.95 (m, 1H), 6.70-6.56 (m, 2H), 4.70-4.63 (m, 2H), 4.48-4.32 (m, 2H), 3.70-3.56 (m, 1H), 3.30-1.82 (m, 16H).
9-014;
δ7.82 (s, 1H), 7.59 (s, 1H), 7.25 (brs, 2H), 4.50-4.25 (m, 2H), 3.52-3.10 (m, 1H), 3.03-1.70 (m, 12H), 1.17-0.88 (m, 6H).
9-018;
δ11.60 (brs, 1H), 7.20 (s, 2H), 4.25-4.05 (m, 2H), 3.70-3.20 (m, 6H), 3.00-2.70 (m, 1H), 2.50-1.80 (m, 10H), 1.20-1.00 (m, 6H).
9-019;
δ11.90 (brs, 1H), 7.20 (brs, 2H), 4.30-4.20 (m, 2H), 3.70-3.60 (m, 2H), 3.38 (s, 3H), 3.35-3.20 (m, 1H), 2.90-2.85 (m, 1H), 2.55-2.40 (m, 1H), 2.25-2.00 (m, 9H), 1.10-0.75 (m, 4H).
9-020;
δ11.95 (brs, 1H), 7.86 (s, 1H), 7.60 (s, 1H), 7.32 (brs, 2H), 4.36-4.21 (m, 2H), 3.71-3.59 (m, 2H), 3.45-3.22 (m, 4H), 3.00-2.86 (m, 1H), 2.56-2.04 (m, 10H), 1.15-0.69 (m, 4H).
9-021;
δ11.79 (s, 1H), 7.09 (brs, 2H), 4.32-4.21 (m, 2H), 3.70-3.55 (m, 2H), 3.38 (s, 3H), 3.35-3.22 (m, 1H), 2.96-2.83 (m, 1H), 2.52-2.40 (m, 1H), 2.30-2.00 (m, 12H), 1.09-0.71 (m, 4H).
9-022;
δ11.67 (brs, 1H), 7.86 (s, 1H), 7.60 (s, 1H), 7.33 (brs, 2H), 4.29-4.20 (m, 2H), 3.69-3.40 (m, 7H), 3.03-2.75 (m, 2H), 2.52-2.08 (m, 8H), 1.18-1.01 (m, 6H).
9-023;
δ11.52 (brs, 1H), 7.09 (brs, 2H), 4.30-4.12 (m, 2H), 3.69-3.17 (m, 7H), 3.03-2.73 (m, 2H), 2.58-1.91 (m, 11H), 1.21-0.99 (m, 6H).
9-025;
δ7.58-7.19 (m, 6H), 4.50-4.32 (m, 2H), 3.72-3.22 (m, 9H), 3.14-2.71 (m, 3H), 2.41-1.82 (m, 10H).
9-026;
δ7.61-7.21 (m, 6H), 4.56-4.32 (m, 2H), 3.49-3.30 (m, 1H), 3.19-2.67 (m, 9H), 2.48-1.87 (m, 10H).
9-027;
δ7.57-7.11 (m, 8H), 7.02-6.87 (m, 1H), 6.75-6.60 (m, 2H), 4.70-4.59 (m, 2H), 4.49-4.34 (m, 2H), 3.33-1.87 (m, 14H).
9-029(*3);
δ7.07 (brs, 2H), 4.75-4.50 (m, 2H), 3.10-2.90 (m, 6H), 2.85-1.85 (m, 14H).
9-030;
δ12.00-11.76 (m, 1H), 7.21 (brs, 2H), 6.04-5.95 (m, 1H), 5.87-5.70 (m, 1H), 4.70-4.57 (m, 1H), 3.48-3.33 (m, 1H), 3.00-2.53 and 2.30-1.49 (m, 19H).
9-032;
δ6.68 (brs, 2H), 4.72 (s, 2H), 3.86 (s, 3H), 3.78 (s, 3H), 3.03-2.82 (m, 3H), 2.65-2.50 (m, 1H), 2.27-2.00 (m, 7H), 1.88 (s, 3H).
9-034;
δ11.62 (brs, 1H), 6.69 (brs, 2H), 4.70 (s, 2H), 3.91 (s, 3H), 3.50-3.35 (m, 1H), 3.10-2.50 (m, 3H), 2.40-1.97 (m, 10H).
9-037;
δ11.64 (brs, 1H), 7.02 and 6.70 (brs, 2H), 3.90 and 3.85 (s, 3H), 3.08-2.70 (m, 10H),
2.30-1.99 (10H).
9-038;
δ11.77 (brs, 1H), 7.46 (brs, 2H), 6.33 (brs, 1H), 4.15-4.04 (m, 2H), 3.91 (s, 3H), 3.00-2.57 (m, 3H), 2.30-2.11 (m, 8H), 2.00 (s, 3H).
9-039(*3);
δ8.15-7.10 (m, 1H), 7.07 (brs, 2H), 5.90-5.56 (m, 1H), 5.16-4.89 (m, 2H), 4.43-4.15 (m, 4H), 3.80-3.62 (m, 2H), 2.78-2.20 and 2.05-1.78 (m, 12H).
9-040(*3);
δ8.43-7.11 (m, 1H), 7.07 (brs, 2H), 4.37 and 4.33 (s, 2H), 3.93-3.45 (m, 2H), 2.73-2.21 (m, 3H), 2.11-1.78 (m, 12H).
9-041(*3);
δ8.02-7.50 (m, 1H), 7.06 (brs, 2H), 4.33 and 4.28 (s, 2H), 3.16 (s, 2H), 3.07-2.20 and 2.13-1.98 (m, 15H), 0.43-0.02 (m, 4H).
9-042(*3);
δ7.95-7.12 (m, 1H), 7.07 (brs, 2H), 4.35 and 4.29 (s, 2H), 3.68-3.20 (m, 5H), 2.79-2.23 and 2.13-1.80 (m, 16H).
9-043(*3);
δ8.18-7.60 (m, 1H), 7.04 (brs, 2H), 4.32 and 4.26 (s, 2H), 3.32-2.98 (m, 2H), 2.79-2.18 and 2.13-1.80 (m, 19H).
9-044(*3);
δ8.80-7.10 (m, 1H), 7.07 (brs, 2H), 4.50-4.20 (m, 2H), 4.13-3.60 (m, 2H), 2.78-2.20 and 2.13-1.77 (m, 14H).
9-045(*3);
δ7.04 (brs, 2H), 4.40-4.18 (m, 1H), 3.73-3.55 (m, 1H), 2.77-1.75 (m, 17H).
9-046(*3);
δ8.41-7.10 (m, 1H), 7.06 (brs, 2H), 4.41 and 4.36 (s, 2H), 3.92-3.60 (m, 7H), 2.78-2.20 and 2.15-1.78 (m, 12H).
11-001;
δ7.39-7.12 (m, 5H), 6.86 (brs, 2H), 4.96 (s, 2H), 3.81 (s, 3H), 3.27-3.13 (m, 1H), 2.61-2.22 (m, 6H), 2.06 (brs, 6H), 1.87-1.77 (m, 3H), 1.26 (s, 3H).
12-001;
δ7.37-7.25 (m, 3H), 7.14-7.04 (m, 2H), 6.86 (brs, 2H), 4.71 (s, 2H), 3.83 (s, 3H), 2.88-2.77 (m, 2H), 2.47-2.23 (m, 5H), 2.15-2.02 (m, 6H), 1.88 (s, 3H), 1.37-1.22 (m, 3H).
12-002;
δ11.31 (brs, 1H), 6.87 (brs, 2H), 3.89 (s, 3H), 2.97-1.20 (m, 19H).
13-001;
δ11.60 and 11.57 (brs, 1H), 7.09-6.85 (m, 2H), 3.96-3.69 (m, 6H), 3.47-3.25 (m, 1H), 3.02-2.07 (m, 9H), 1.19-1.02 (m, 3H).
13-005;
δ6.66 (s, 1H), 6.55 (s, 1H), 3.91-2.45 and 2.39-2.00 and 1.97-1.40 (m, 26H), 0.94-0.64 (m, 4H).
13-006;
δ6.64 (s, 1H), 6.52 (s, 1H), 3.95-3.60 (m, 6H), 3.36-2.64 (m, 3H), 2.60-2.42 (m, 1H), 2.38-2.00 (m, 7H), 1.97-1.78 (m, 1H), 1.13 (s, 9H), 0.94-0.61 (m, 4H).
13-007;
δ6.66 (brs, 1H), 6.54 (brs, 1H), 3.87-3.80 (m, 3H), 3.75-3.15 (m, 12H), 3.10-2.60 (m, 3H), 2.50-2.05 (m, 9H), 1.15-1.03 (m, 3H).
13-008;
δ6.65 (brs, 1H), 6.54 (brs, 1H), 3.86-3.80 (m, 3H), 3.75-3.67 (m, 3H), 3.48-3.20 (m, 5H), 3.10-2.60 (m, 3H), 2.45-2.02 (m, 9H), 1.92-1.78 (m, 4H), 1.17-1.02 (m, 3H).
13-009;
δ6.67-6.60 (m, 1H), 6.54-6.48 (m, 1H), 3.95-3.60 (m, 6H), 3.33-2.02 (m, 13H), 1.37-1.00 (m, 12H).
13-010;
δ7.30-7.17 (m, 2H), 7.05-6.97 (m, 1H), 6.83-6.75 (m, 2H), 6.70-6.65 (m, 1H), 6.58-6.52 (m, 1H), 4.70-4.60 (m, 2H), 3.90-3.75 (m, 3H), 3.72-3.62 (m, 3H), 3.40-2.00 (m, 13H), 1.15-1.00 (m, 3H).
13-011;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 3.85-3.67 (m, 9H), 3.39-2.03 (m, 13H), 1.17-1.02 (m, 3H).
13-012(*3);
δ7.09-6.53 (m, 2H), 3.98-3.82 (m, 3H), 3.50-3.32 (m, 1H), 3.08-2.50 and 2.33-1.98 (m, 13H), 1.92-1.67 and 0.82-0.42 (m, 5H).
13-013;
δ11.55-11.30 (m, 1H), 7.11-6.80 (m, 2H), 6.75-6.30 (m, 1H), 5.71-5.53 (m, 1H), 5.32-5.05 (m, 1H), 3.94-3.85 (m, 3H), 3.50-3.30 (m, 1H), 3.03-2.52 and 2.40-1.84 (m, 13H).
13-014(*3);
δ7.70-7.25 (m, 2H), 3.91 and 3.89 (s, 3H), 3.50-3.30 (m, 1H), 3.05-2.56 (m, 3H),
2.38 (s, 3H), 2.34-2.17 (m, 4H), 2.02-1.94 (m, 3H).
13-015;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 4.35-4.23 (m, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.64-3.55 (m, 2H), 3.38-3.17 (m, 1H), 3.35 (s, 3H), 3.11-2.77 (m, 3H), 2.42-2.21 (m, 4H), 2.08 and 2.06 (s, 3H), 1.93-1.83 (m, 3H).
13-016;
δ7.47-7.29 (m, 5H), 6.70-6.49 (m, 2H), 5.15 (s, 2H), 3.85 and 3.84 (s, 3H), 3.61 and 3.59 (s, 3H), 3.40-2.72 (m, 4H), 2.42-2.20 (m, 4H), 2.06 and 2.03 (s, 3H), 1.86 and 1.85 (s, 3H).
13-017;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 5.95-5.79 (m, 1H), 5.50-5.20 (m, 2H), 4.78-4.53 (m, 2H)3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.40-2.78 (m, 4H), 2.42-2.20 (m, 4H), 2.18-2.06 (m, 3H), 1.92-1.82 (m, 3H).
13-018;
δ7.19-7.00 (m, 4H), 6.62-6.42 (m, 2H), 3.85 and 3.83 (s, 3H), 3.56 and 3.53 (s, 3H), 3.21-2.92 (m, 2H), 2.88-2.64 (m, 2H), 2.40-2.17 (m, 4H), 1.97-1.83 (m.6H), 1.52-1.45 (m, 6H).
13-021;
δ7.27-7.19 (m, 2H), 6.97 (t, J=7.5Hz, 1H), 6.78 (d, J=7.5Hz, 2H), 6.65 (brs, 1H), 6.54 (brs, 1H), 4.65 (s, 2H), 3.94-3.77 (m, 5H), 3.40-2.04 (m, 12H), 1.31 (m, 3H), 0.85-0.70 (m, 4H).
13-022;
δ6.62 (brs, 1H), 6.50 (brs, 1H), 3.96-3.72 (m, 5H), 3.34-1.43 (m, 12H), 1.34-1.22 (m,3H), 1.14-1.11 (m, 9H), 0.85-0.70 (m, 4H).
13-023;
δ6.64 (brs, 1H), 6.53 (brs, 1H), 4.20 (q, J=7.2Hz, 2H), 3.99-3.78 (m, 5H), 3.34-1.45 (m, 12H), 1.32-1.20 (m, 6H), 0.85-0.70 (m, 4H).
13-024;
δ6.64 (brs, 1H), 6.53 (brs, 1H), 3.98-3.78 (m, 5H), 3.65-1.45 (m, 20H), 1.29-1.22 (m, 3H), 0.87-0.69 (m, 4H).
14-001;
δ10.53 and 10.48 (brs, 1H), 7.10-6.82 (m, 2H), 3.82-3.60 (m, 3H), 3.50-3.21 and 3.10-2.79 (m, 3H), 2.31-2.07 and 1.31-0.82 (m, 10H).
14-002;
δ10.05 and 9.99 (brs, 1H), 7.10-6.83 (m, 2H), 3.84-3.59 (m, 3H), 3.39-1.02 (m, 13H).
14-003;
δ9.65-9.25 (m, 1H), 6.80-6.55 (m, 2H), 3.82-3.65 (m, 3H), 3.45-2.02 (m, 13H), 1.20-1.00 (m, 3H).
14-007(*3);
δ6.83-6.57 (m, 2H), 3.89-3.66 (m, 6H), 3.60-3.18 (m, 2H), 2.59-2.27 (m, 6H), 2.19-2.07 (m, 3H), 1.33-1.11 (m, 3H).
15-001;
δ10.10-9.96 (m, 1H), 6.85-6.52 (m, 2H), 4.81-4.60 (m, 2H), 3.92-3.61 (m, 3H), 3.53-3.28 (m, 1H), 3.04-1.86 (m, 14H).
15-002;
δ10.89-10.70 (m, 1H), 6.89-6.51 (m, 2H), 6.10-5.84 (m, 1H), 5.50-5.11 (m, 2H), 4.76-4.50 (m, 2H), 3.93-3.60 (m, 3H), 3.50-3.23 (m, 1H), 3.03-1.84 (m, 13H).
15-003;
δ11.22 (brs, 1H), 6.78-6.52 (m, 2H), 4.00-3.61 (m, 5H), 3.50-3.23 (m, 1H), 3.02-2.49 (m, 3H), 2.40-1.83 (m, 10H), 1.19-1.03 (m, 1H), 0.64-0.47 (m, 2H), 0.38-0.18 (m, 2H).
15-004;
δ10.90-10.60 and 8.10-7.60 (m, 1H), 6.80-6.55 (m, 2H), 4.40-4.06 (m, 2H), 3.90-3.70 (m, 3H), 3.70-3.53 (m, 2H), 3.37 (s, 3H), 3.03-1.85 (m, 14H).
15-005(*3);
δ6.85-6.50 (m, 2H), 4.55-4.32 (m, 2H), 3.85-3.67 (m, 3H), 3.30-2.25 (m, 8H), 2.20-1.85 (m, 6H).
15-006;
δ8.20-7.95 and 7.15-6.95 (m, 1H), 6.80-6.55 (m, 2H), 4.69 (s, 2H), 3.77 (s, 3H), 3.45-2.40 (m, 4H), 2.33 (s, 3H), 2.20-1.85 (m, 7H).
15-007;
δ6.70-6.52 (m, 2H), 4.25-4.15 (m, 2H), 3.80-3.22 (m, 16H), 3.10-2.70 (m, 4H), 2.40-2.02 (m, 7H), 1.95-1.85 (m, 3H).
15-008;
δ6.70-6.48 (m, 2H), 4.25-4.00 (m, 2H), 3.75-3.60 (m, 5H), 3.57-3.22 (m, 6H), 3.20-2.28 (m, 11H), 2.20-1.88 (m, 6H).
15-009;
δ6.70-6.48 (m, 2H), 4.50-4.35 (m, 2H), 3.80-3.63 (m, 3H), 3.35-2.50 (m, 4H), 2.48-1.85 (m, 10H), 1.15-1.10 (m, 9H).
15-010;
δ6.70-6.50 (m, 2H), 4.50-4.30 (m, 2H), 3.75-3.65 (m, 3H), 3.45-3.20 (m, 1H), 3.10-2.70 (m, 9H), 2.45-1.85 (m, 10H).
15-011;
δ6.72-6.55 (m, 2H), 4.72-4.65 (m, 2H), 3.73 (s, 3H), 3.45-2.70 (m, 7H), 2.55-1.90 (m, 10H).
15-012;
δ6.65 (brs, 1H), 6.53 (brs, 1H), 4.72-4.68 (m, 2H), 3.72-3.68 (m, 3H), 3.45-2.70 (m, 8H), 2.45-1.85 (m, 10H), 1.15-0.90 (m, 6H).
15-013;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 4.69-4.61 (m, 2H), 3.84-3.68 (m, 6H), 3.40-2.68 and 2.59-2.23 and 2.20-1.88 (m, 15H).
15-014;
δ6.72-6.47 (m, 2H), 3.98-3.80 (m, 2H), 3.79-3.63 (m, 3H), 3.39-2.60 and 2.41-2.20 (m, 7H), 2.17-2.01 (m, 4H), 1.98-1.83 (m, 3H), 1.65-1.03 (m, 10H), 0.63-0.42 (m, 2H), 0.37-0.17 (m, 2H).
15-015;
δ7.39-7.18 and 7.09-6.49 (m, 7H), 6.08-5.89 (m, 1H), 5.33-5.15 (m, 2H), 4.69-4.48 (m, 4H), 3.72-3.61 (m, 3H), 3.39-2.72 (m, 4H), 2.48-2.21 (m, 4H), 2.17-1.80 (m, 6H).
15-016;
δ6.69-6.62 (m, 1H), 6.58-6.51 (m, 1H), 4.68-4.61 (m, 2H), 3.75-3.66 (m, 3H), 3.47-3.18 (m, 4H), 3.08-2.72 (m, 3H), 2.49-2.21 and 2.13-2.02 and 1.98-1.79 (m, 16H).
15-017;
δ6.70-6.64 (m, 1H), 6.58-6.50 (m, 1H), 6.09-5.91 (m, 1H), 5.35-5.16 (m, 2H), 4.60-4.50 (m, 2H), 3.74-3.63 (m, 3H), 3.58-3.23 (m, 5H), 3.08-2.76 (m, 3H), 2.44-2.18 (m, 11H), 2.13-2.03 (m, 3H), 1.89 (s, 3H).
15-018;
δ6.70-6.63 (m, 1H), 6.58-6.50 (m, 1H), 3.92-3.81 (m, 2H), 3.78-3.62 (m, 3H), 3.54-2.72 (m, 11H), 2.40-2.21 (m, 4H), 2.17-2.07 (m, 3H), 1.98-1.82 (m, 3H), 1.70-1.05 (m, 4H), 0.61-0.46 (m, 2H), 0.32-0.20 (m, 2H).
15-019;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 4.70-4.60 (m, 2H), 3.80-3.22 and 3.10-2.65 and 2.51-2.22 (m, 20H), 2.13-2.05 (m, 3H), 2.01-1.86 (m, 3H).
15-020;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 6.08-5.92 (m, 1H), 5.34-5.13 (m, 2H), 4.59-4.52 (m, 2H), 3.77-3.23 (m, 12H), 3.09-2.72 (m, 3H), 2.40-2.20 (m, 4H), 2.09 and 2.06 (s, 3H), 1.97-1.83 (m, 3H).
15-021;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 3.92-3.80 (m, 2H), 3.78-3.22 (m, 12H), 3.10-2.78 (m, 3H), 2.40-2.19 (m, 4H), 2.09 and 2.06 (s, 3H), 1.96-1.87 (m, 3H), 1.05-1.25 (m, 1H), 0.59-0.43 (m, 2H), 0.33-0.20 (m, 2H).
15-024;
δ6.66 (brs, 1H), 6.58-6.51 (m, 1H), 4.19-4.02 (m, 2H), 3.73-3.27 (m, 12H), 3.08-2.78 (m, 3H), 2.40-2.00 (m, 7H), 1.86 (s, 3H), 1.32-1.20 (m, 3H).
15-024(*2);
δ6.75-6.65 (m, 1H), 6.62-6.51 (m, 1H), 4.19-4.02 (m, 2H), 3.80-1.90 (m, 25H), 1.36-1.20 (m, 3H).
15-025;
δ7.68-7.58 (m, 2H), 7.24-7.17 (m, 2H), 6.56 (brs, 1H), 6.43 (brs, 1H), 4.19-4.03 (m, 2H), 3.62 and 3.59 (s, 3H), 3.31-2.72 (m, 4H), 2.43 (s, 3H), 2.38-2.15 (m, 4H), 1.95 and 1.92 (s, 3H), 1.85 and 1.84 (s, 3H), 1.32-1.21 (m, 3H).
15-026;
δ6.67 (brs, 1H), 6.60-6.50 (m, 1H), 4.38-4.22 (m, 1H), 3.78-2.15 (m, 19H), 2.09 and 2.07 (s, 3H), 1.97-1.82 (m, 3H), 1.34-1.17 (m, 6H).
15-027;
δ7.70-7.58 (m, 2H), 7.26-7.17 (m, 2H), 6.62-6.40 (m, 2H), 4.39-4.20 (m, 1H), 3.70-3.58 (m, 3H), 3.32-2.12 (m, 14H), 2.00-1.81 (m, 3H), 1.33-1.20 (m, 6H).
15-028;
δ11.29 and 11.28 (brs, 1H), 6.77-6.66 (m, 1H), 6.64-6.55 (m, 1H), 4.43-4.27 (m, 1H), 3.82-3.69 (m, 3H), 3.51-3.30 (m, 1H), 3.07-2.49 (m, 3H), 2.37-1.85 (m, 10H), 1.32-1.21 (m, 6H).
15-029;
δ6.66-6.63 (m, 1H), 6.54-6.49 (m, 1H), 4.15-4.05 (m, 2H), 3.69 and 3.68 (s, 3H), 3.33-2.62 (m, 4H), 2.42-2.18 (m, 4H), 2.08 and 2.06 (s, 3H), 1.89-1.87 (m, 3H), 1.31-1.22 (m, 3H), 1.14 and 1.13 (s, 9H).
15-030;
δ7.22-6.77 (m, 4H), 6.73-6.67 (m, 1H), 6.61-6.56 (m, 1H), 4.17-4.03 (m, 2H), 3.76-3.69 (m, 3H), 3.47-2.24 (m, 11H), 2.15-2.09 (m, 3H), 1.93-1.85 (m, 3H), 1.31-1.19 (m, 3H).
15-031;
δ6.67-6.62 (m, 1H), 6.54-6.49 (m, 1H), 4.40-4.21 (m, 1H), 3.72-3.64 (m, 3H), 3.35-2.61 (m, 4H), 2.41-2.16 (m, 4H), 2.11-2.03 (m, 3H), 1.87 (s, 3H), 1.27-1.19 (m, 6H), 1.15-1.10 (m, 9H).
15-032;
δ7.21-6.76 (m, 4H), 6.72-6.68 (m, 1H), 6.62-6.56 (m, 1H), 4.39-4.20 (m, 1H), 3.80-3.68 (m, 3H), 3.48-2.22 (m, 11H), 2.16-2.09 (m, 3H), 1.96-1.84 (m, 3H), 1.30-1.20 (m, 6H).
15-033;
δ7.30-7.18 (m, 2H), 7.04-6.95 (m, 1H), 6.84-6.64 (m, 3H), 6.58-6.51 (m, 1H), 4.69-4.62 (m, 2H), 4.36-4.20 (m, 1H), 3.72-3.63 (m, 3H), 3.42-2.02 (m, 11H), 1.92-1.82 (m, 3H), 1.31-1.18 (m, 6H).
15-034;
δ6.69-6.62 (m, 1H), 6.59-6.49 (m, 1H), 5.22-5.07 (m, 1H), 5.00-4.88 (m, 1H), 4.39-4.21 (m, 1H), 3.85-3.63 (m, 5H), 3.60-3.45 (m, 2H), 3.43-2.02 (m, 14H), 1.96-1.80 (m, 3H), 1.32-1.16 (m, 6H).
15-035;
δ11.18 and 11.17 (brs, 1H), 6.76-6.66 (m, 1H), 6.63-6.55 (m, 1H), 4.09-3.94 (m, 2H), 3.83-3.68 (m, 3H), 3.49-3.29 (m, 1H), 3.04-1.87 (m, 13H), 1.76-1.59 (m, 2H), 1.01-0.87 (m, 3H).
15-037;
δ11.18 (brs, 1H), 6.77-6.65 (m, 1H), 6.64-6.55 (m, 1H), 4.14-3.99 (m, 2H), 3.83-3.69 (m, 3H), 3.51-3.26 (m, 1H), 3.06-1.85 (m, 13H), 1.71-1.58 (m, 2H), 1.47-1.31 (m, 2H), 1.01-0.87 (m, 3H).
15-038;
δ7.87-7.77 (m, 1H), 7.49-7.37 (m, 1H), 7.26-7.16 (m, 2H), 6.70-6.64 (m, 1H), 6.57-6.49 (m, 1H), 4.18-4.04 (m, 2H), 3.72-3.64 (m, 3H), 3.47-3.31 (m, 1H), 3.18-2.83 (m, 3H), 2.46-2.09 (m, 10H), 1.95-1.87 (m, 3H), 1.33-1.21 (m, 3H).
15-039;
δ6.71-6.61 (m, 1H), 6.60-6.48 (m, 1H), 5.22-5.09 (m, 1H), 4.99-4.88 (m, 1H), 4.19-3.97 (m, 2H), 3.86-3.64 (m, 5H), 3.60-3.46 (m, 2H), 3.41-2.52 (m, 7H), 2.47-2.02 (m, 7H), 1.96-1.82 (m, 3H), 1.34-1.19 (m, 3H).
15-040;
δ7.44-7.12 (m, 5H), 6.66-6.41 (m, 2H), 4.22-4.01 (m, 2H), 3.63-3.51 (m, 3H), 3.23-2.61 (m, 4H), 2.44-2.16 (m, 4H), 2.00-1.83 (m, 6H), 1.68-1.58 (m, 6H), 1.31-1.17 (m, 3H).
15-041;
δ8.81-8.75 (m, 1H), 8.49-8.41 (m, 1H), 8.31-8.24 (m, 1H), 7.71-7.62 (m, 1H), 6.72-6.66 (m, 1H), 6.60-6.53 (m, 1H), 4.18-4.04 (m, 2H), 3.78-3.67 (m, 3H), 3.50-3.33 (m, 1H), 3.21-2.83 (m, 3H), 2.48-2.29 (m, 4H), 2.19-2.11 (m, 3H), 1.97-1.88 (m, 3H), 1.34-1.21 (m, 3H).
15-042;
δ11.84-11.72 (m, 1H), 7.15-7.04 (m, 1H), 7.02-6.89 (m, 1H), 4.25-4.07 (m, 2H), 3.54-3.33 (m, 1H), 3.08-2.51 (m, 3H), 2.35-2.12 (m, 7H), 2.04-1.94 (m, 3H), 1.35-1.23 (m, 3H).
15-044;
δ6.69-6.63 (m, 1H), 6.57-6.51 (m, 1H), 4.17-4.03 (m, 2H), 3.71 and 3.69 (s, 3H), 3.47-2.77 (m, 8H), 2.40-2.19 (m, 4H), 2.11 and 2.08 (s, 3H), 1.92-1.79 (m, 7H), 1.32-1.20 (m, 3H).
15-045;
δ6.69-6.63 (m, 1H), 6.59-6.51 (m, 1H), 4.19-3.99 (m, 2H), 3.71 and 3.69 (s, 3H), 3.52-2.71 (m, 8H), 2.38-2.19 (m, 4H), 2.10 and 2.08 (s, 3H), 1.95-1.84 (m, 3H), 1.64-1.39 (m, 6H), 1.31-1.21 (m, 3H).
15-046;
δ11.36-11.23 (m, 1H), 6.79-6.65 (m, 1H), 6.64-6.55 (m, 1H), 4.20-4.05 (m, 1H), 3.84-3.69 (m, 3H), 3.51-3.27 (m, 1H), 3.03-2.43 (m, 3H), 2.36-1.44 (m, 12H), 1.34-1.18 (m, 3H), 0.98-0.86 (m, 3H).
15-047(*3);
δ6.79-6.56 (m, 2H), 6.13-5.62 (m, 1H), 4.55-4.36 (m, 2H), 3.84-3.70 (m, 3H), 3.53-2.20 (m, 8H), 2.18-1.86 (m, 6H).
16-001;
δ11.70-11.60 (m, 1H), 7.02-6.85 (m, 1H), 3.90 (s, 3H), 3.48-3.35 (m, 1H), 3.00-2.87 (m, 1H), 2.85-2.50 (m, 3H), 2.37-1.97 (m, 12H).
17-001;
δ6.65 (brs, 2H), 3.71 (s, 3H), 2.62 (dd, J=13.2, 3.3Hz, 1H), 2.45-2.32 (m, 1H), 2.20-2.06 (m, 4H), 2.00 (s, 3H), 1.97 (s, 3H), 1.90-1.72 (m, 5H).
17-002;
δ6.65 (brs, 2H), 3.71 (s, 3H), 2.62 (dd, J=13.2, 3.3Hz, 1H), 2.44-2.30 (m, 1H), 2.20-2.06 (m, 4H), 2.00 (s, 3H), 1.97 (s, 3H), 1.88-1.70 (m, 5H).
――――――――――――――――――――――――――――――――――――――
試験例
次に、本発明化合物の除草剤としての有用性について、以下の試験例において具体的に説明するが、本発明はこれらのみに限定されるものではない。
〔試験例１〕湛水条件における雑草発生前処理による除草効果試験
１／１００００アールのワグネルポットに沖積土壌を入れた後、水を入れて混和し、水深４cmの湛水条件とした。ノビエ、ホタルイ及びコナギの種子を上記カップに混播した後、２．５葉期のイネ苗を移植した。播種当日、配合例２に準じて調製した本発明化合物の乳剤を所定の薬量になるように水で希釈し、水面に処理した。カップを２５〜３０℃の温室内に置いて植物を育成し、薬剤処理３週間後に、各種植物に対する影響を下記の判定基準に従い調査した。結果を第２１表に示す。 [Table 20]
――――――――――――――――――――――――――――――――――――――
No. ¹ H-NMR (CDCl _Three , Me _Four (Si, 300MHz)
――――――――――――――――――――――――――――――――――――――
1-004;
δ6.85-6.81 (m, 2H), 3.87-3.82 (m, 3H), 3.70-2.18 (m, 8H), 2.15-1.78 (m, 9H), 1.08 and 1.06 (s, 9H).
1-005;
δ6.90-6.85 (m, 2H), 3.87-3.82 (m, 3H), 3.77-2.18 (m, 8H), 2.17-1.98 (m, 9H), 1.97-1.83 (m, 3H).
1-006;
δ6.92-6.87 (m, 2H), 3.84 (s, 3H), 3.37-2.60 (m, 7H), 2.40-2.24 (m, 4H), 2.13-2.02 (m, 6H), 1.97-1.83 (m , 3H).
1-007;
δ6.90-6.85 (m, 2H), 5.90-5.67 (m, 1H), 5.28-5.07 (m, 2H), 4.50-4.40 and 4.23-4.15 (m, 2H), 3.88-3.78 (m, 3H) , 3.00-1.85 (m, 17H).
1-008;
δ6.90-6.80 (m, 2H), 4.60-4.48 and 4.38-4.30 (m, 2H), 3.90-3.75 (m, 3H), 3.31-2.35 (m, 6H), 2.33-2.00 (m, 9H) , 1.97-1.85 (m, 3H).
1-009;
δ7.28-7.03 (m, 5H), 6.92-6.80 (m, 2H), 4.97-4.92 and 4.73-4.68 (m, 2H), 3.86-3.77 (m, 3H), 3.31-1.80 (m, 17H) .
1-009a-1;
δ7.35-7.30 (m, 3H), 7.20-7.15 (m, 2H), 6.90-6.85 (m, 2H), 4.95 (s, 2H), 3.84 (s, 3H), 3.00-2.80 (m, 3H ), 2.65-2.55 (m, 1H), 2.27 (s, 3H), 2.25-2.15 (m, 1H), 2.10-2.00 (m, 6H), 1.86 (s, 3H).
1-009a-2;
δ7.35-7.30 (m, 3H), 7.20-7.15 (m, 2H), 6.90-6.85 (m, 2H), 4.95 (s, 2H), 3.80 (s, 3H), 2.95-2.80 (m, 2H ), 2.76-2.70 (m, 1H), 2.66-2.57 (m, 2H), 2.27 (s, 3H), 2.10-2.00 (m, 6H), 1.91 (s, 3H).
1-009b-1;
δ7.31-7.28 (m, 3H), 7.10-7.07 (m, 2H), 6.87-6.85 (m, 2H), 4.72 (s, 2H), 3.84 (s, 3H), 3.30-3.20 (m, 1H ), 2.90-2.80 (m, 1H), 2.80-2.70 (m, 1H), 2.42-2.37 (m, 1H), 2.30-2.23 (m, 4H), 2.08-2.05 (m, 6H), 1.86 (s , 3H).
1-009b-2;
δ7.32-7.28 (m, 3H), 7.10-7.07 (m, 2H), 6.88-6.86 (m, 2H), 4.74 (s, 2H), 3.83 (s, 3H), 3.29-3.24 (m, 1H ), 2.82-2.63 (m, 3H), 2.39-2.34 (m, 1H), 2.28 (s, 3H), 2.10 (s, 3H), 2.05 (s, 3H), 1.92 (s, 3H).
1-010;
δ7.96-7.15 (m, 5H), 6.90-6.87 (m, 2H), 3.88-3.75 (m, 3H), 3.55-1.83 (m, 17H).
1-011;
δ6.98-6.75 (m, 2H), 4.20-4.77 (m, 5H), 3.28-2.60 (m, 6H), 2.45-1.80 (m, 16H).
1-012;
δ6.92-6.80 (m, 2H), 4.69 and 4.53 and 4.35and 4.25 (s, 2H), 3.88-3.58 (m, 6H), 3.38-3.28 and 3.00-1.80 (m, 17H).
1-013;
δ6.98-6.87 (m, 2H), 4.56 and 4.55 and 4.46 and 4.44 (s, 2H), 3.92-3.82 (m, 3H), 3.36-3.25 and 3.10-2.60 (m, 4H), 2.60-1.80 ( m, 13H).
1-014;
δ6.91-6.85 (m, 2H), 3.85 (s, 3H), 3.77 and 3.70 (s, 3H), 3.35-3.18 (m, 1H), 3.10-2.65 (m, 3H), 2.35-2.22 (m , 4H), 2.10-2.02 (m, 6H), 1.90-1.83 (m, 3H).
1-015;
δ6.91-6.82 (m, 2H), 3.90-3.80 (m, 3H), 3.31-3.20 (m, 1H), 3.07-2.78 (m, 3H), 2.35-2.20 (m, 4H), 2.10-2.00 (m, 6H), 1.95-1.83 (m, 3H), 1.75-1.50 (m, 1H), 1.07-0.80 (m, 4H).
1-016;
δ6.91-6.77 (m, 2H), 3.90-3.77 (m, 3H), 3.68-3.42 (m, 2H), 3.28-2.48 (m, 4H), 2.35-1.80 (m, 13H), 1.37 (s , 3H), 1.16 (s, 3H).
1-017;
δ7.17-7.05 (m, 2H), 7.00-6.90 (m, 1H), 6.87-6.78 (m, 2H), 6.65-6.55 (m, 2H), 3.87-3.82 (m, 3H), 3.56-3.45 and 3.18-2.20 (m, 8H), 2.19-1.70 (m, 9H), 1.50-1.38 (m, 6H).
1-031;
δ6.90-6.85 (m, 2H), 4.55 and 4.34 (s, 2H), 3.88-3.80 (m, 3H), 3.30-2.35 (m, 4H), 2.30-1.80 (m, 13H), 1.20-1.10 (m, 9H).
1-033;
δ6.90-6.83 (m, 2H), 3.84 (s, 3H), 3.28-3.15 (m, 1H), 3.07-2.96 (m, 1H), 2.90-2.75 (m, 2H), 3.40-3.20 (m , 6H), 2.06 (s, 3H), 2.04 (s, 3H), 1.86 (s, 3H), 1.58-1.45 (m, 2H), 1.35-1.10 (m, 10H), 0.92-0.83 (m, 3H ).
1-034;
δ6.90-6.80 (m, 2H), 3.90-3.80 (m, 3H), 3.35-3.22 (m, 1H), 3.09-2.98 (m, 1H), 2.96-2.70 (m, 2H), 2.35-2.20 (m, 4H), 2.12-2.00 (m, 6H), 1.92-1.78 (m, 6H), 1.48-1.35 (m, 6H).
1-035;
δ6.90-6.82 (m, 2H), 3.84 (s, 3H), 3.28-3.15 (m, 1H), 3.08-2.97 (m, 1H), 2.90-2.75 (m, 2H), 2.50-2.20 (m , 8H), 2.10-2.02 (m, 6H), 1.86 (s, 3H), 1.80-0.70 (m, 11H).
1-036;
δ6.90-6.80 (m, 2H), 3.87-3.80 (m, 3H), 3.26-3.15 (m, 1H), 3.10-3.00 (m, 1H), 2.90-2.78 (m, 2H), 2.38-2.13 (m, 4H), 2.10-2.00 (m, 6H), 1.86 (s, 3H), 1.58-1.40 (m, 5H).
1-037;
δ6.90-6.80 (m, 2H), 4.07-3.52 (m, 14H), 2.45-2.00 (m, 10H), 1.90-1.84 (m, 3H).
1-039;
δ6.90-6.80 (m, 2H), 3.84 (s, 3H), 3.25-3.13 (m, 1H), 3.12-3.01 (m, 1H), 2.90-2.75 (m, 2H), 2.38-2.20 (m , 4H), 2.06 (s, 3H), 2.05 (s, 3H), 1.84 (s, 3H), 1.48-1.35 (m, 6H).
1-042;
δ6.88-6.83 (m, 2H), 3.87-3.82 (m, 3H), 3.32-2.22 (m, 9H), 2.15-2.03 (m, 6H), 1.89-1.85 (m, 3H), 1.59-1.47 (m, 3H).
1-043;
δ7.28-7.17 (m, 2H), 7.02-6.96 (m, 1H), 6.89-6.83 (m, 2H), 6.74-6.60 (m, 2H), 4.65 and 4.62 (s, 2H), 3.84 (s , 3H), 3.29-3.18 (m, 1H), 3.12-3.00 (m, 1H), 2.92-2.80 (m, 2H), 2.40-2.20 (m, 4H), 2.10-2.00 (m, 6H), 1.90 -1.83 (m, 3H).
1-044;
δ7.28-7.17 (m, 2H), 6.88-6.83 (m, 2H), 6.63-6.48 (m, 2H), 4.62 and 4.58 (s, 2H), 3.84 (s, 3H), 3.70-2.22 (m , 8H), 2.03-1.95 (m, 6H), 1.86 (s, 3H).
1-045 (* 3);
δ8.52-8.47 (m, 1H), 8.04-7.98 (m, 1H), 7.91-7.83 (m, 1H), 7.46-7.38 (m, 1H), 6.93-6.85 (m, 2H), 4.10 (s , 3H), 3.43-3.35 (m, 1H), 3.15-2.90 (m, 3H), 2.58-2.48 (m, 1H), 2.26 (s, 3H), 2.17 (s, 3H), 2.11 (s, 3H ).
1-046;
δ11.85 (brs, 1H), 6.95-6.85 (m, 2H), 3.95-3.78 (m, 3H), 3.40-2.02 (m, 14H), 1.08-0.70 (m, 5H).
1-047 (* 3);
δ8.14-7.34 (m, 5H), 6.95-6.85 (m, 2H), 4.05-3.88 (m, 3H), 3.35-2.00 (m, 14H).
1-048;
δ11.78-11.65 (m, 1H), 7.00-6.83 (m, 2H), 3.97-3.80 (m, 3H), 3.55-2.00 (m, 15H), 1.25-1.00 (m, 6H).
1-051;
δ7.06-6.98 (m, 2H), 6.87-6.80 (m, 2H), 6.52-6.44 (m, 2H), 3.87-3.82 (m, 3H), 3.62-2.13 (m, 8H), 2.08-2.00 (m, 6H), 1.87 and 1.82 (s, 3H), 1.58-1.40 (m, 6H).
1-060;
δ7.24-7.22 (m, 2H), 7.00-6.90 (m, 1H), 6.88-6.78 (m, 2H), 6.72-6.60 (m, 2H), 4.78-4.65 (m, 1H), 3.90-3.76 (m, 3H), 3.25-2.96 (m, 2H), 2.89-2.69 (m, 2H), 2.35-2.20 (m, 4H), 2.10-1.94 (m, 6H), 1.88-1.80 (m, 3H) , 1.55-1.45 (m, 3H).
1-063;
δ7.30-7.15 (m, 2H), 7.03-6.94 (m, 1H), 6.89-6.82 (m, 2H), 6.75-6.60 (m, 2H), 4.67-4.60 (m, 2H), 3.88-3.77 (m, 3H), 3.33-1.80 (m, 14H), 0.90-0.65 (m, 5H).
1-064;
δ7.40-7.30 (m, 1H), 7.12-6.77 (m, 4H), 6.53-6.27 (m, 1H), 4.77-4.59 (m, 2H), 3.90-2.80 (m, 6H), 2.67-2.17 (m, 5H), 2.15-1.80 (m, 9H).
1-065;
δ7.18-7.05 (m, 1H), 7.00-6.95 (m, 1H), 6.88-6.72 (m, 3H), 6.60-6.42 (m, 1H), 4.65-4.53 (m, 2H), 3.88-2.45 (m, 7H), 2.37-1.85 (m, 13H).
1-067;
δ7.03-6.68 (m, 5H), 6.60-6.38 (m, 1H), 4.73-4.65 (m, 2H), 3.90-3.80 (m, 6H), 3.75-2.15 (m, 8H), 2.10-2.00 (m, 6H), 1.90-1.82 (m, 3H).
1-068;
δ7.15-7.07 (m, 1H), 6.90-6.80 (m, 2H), 6.60-6.52 (m, 1H), 6.43-6.37 (m, 1H), 6.30-6.22 (m, 1H), 4.63 (s , 2H), 3.83 (s, 3H), 3.76 (s, 3H), 3.30-3.20 (m, 1H), 3.10-3.00 (m, 1H), 2.92-2.80 (m, 2H), 2.36-2.23 (m , 4H), 2.04 (s, 3H), 2.03 (s, 3H), 1.54 (s, 3H).
1-069;
δ6.92-6.53 (m, 6H), 4.70-4.52 (m, 2H), 3.84 (s, 3H), 3.76 (s, 3H), 3.30-2.10 (m, 8H), 2.09-1.95 (m, 6H ), 1.93-1.82 (m, 3H).
1-071;
δ7.88-7.80 (m, 1H), 7.40-7.20 (m, 1H), 7.14-7.03 (m, 1H), 6.90-6.82 (m, 2H), 6.57-6.50 and 6.37-6.29 (m, 1H) , 4.78 and 4.74 (s, 2H), 3.87-3.82 (m, 3H), 3.70-2.22 (m, 8H), 2.14-1.97 (m, 6H), 1.90-1.85 (m, 3H).
1-072;
δ7.05-6.97 (m, 2H), 6.92-6.85 (m, 2H), 6.65-6.50 (m, 2H), 4.65-4.55 (m, 2H), 3.90-3.80 (m, 3H), 3.29-2.79 (m, 4H), 2.38-2.22 (m, 7H), 2.10-2.02 (m, 6H), 1.88-1.72 (m, 3H).
1-073;
δ6.93-6.80 (m, 4H), 6.67-6.50 (m, 2H), 4.65-4.55 (m, 2H), 3.84 (s, 3H), 3.28-2.45 (m, 4H), 2.35-2.20 (m , 4H), 2.10-1.95 (m, 6H), 1.93-1.80 (m, 3H).
1-074;
δ7.35-6.70 (m, 6H), 4.67 and 4.64 (s, 2H), 3.84 (s, 3H), 3.30-2.20 (m, 8H), 2.15-1.95 (m, 6H), 1.92-1.85 (m , 3H).
1-075;
δ7.37-6.12 (m, 5H), 4.73-4.65 (m, 2H), 3.88-3.80 (m, 3H), 3.72-2.20 (m, 8H), 2.10-1.95 (m, 6H), 1.90-1.82 (m, 3H).
1-076;
δ6.87-6.82 (m, 2H), 4.50-4.40 (m, 1H), 3.90-3.82 (m, 3H), 3.80-1.40 (m, 23H).
1-077;
δ6.87 (s, 2H), 4.25-4.20 (m, 2H), 3.90 (s, 3H), 3.72 (s, 3H), 3.15-2.90 (m, 2H), 2.85-2.70 (m, 2H), 2.60-2.50 (m, 1H), 2.26 (s, 3H), 2.09 (s, 6H).
1-079;
δ9.95-9.87 (m, 1H), 7.77-7.68 (m, 2H), 6.90-6.65 (m, 4H), 4.73 and 4.69 (s, 2H), 3.88-3.82 (m, 3H), 3.70-2.45 (m, 5H), 2.37-1.85 (m, 12H).
1-080;
δ7.88-7.80 (m, 2H), 6.86 (brs, 2H), 6.75-6.57 (m, 2H), 4.70 and 4.67 (s, 2H), 3.84 (s, 3H), 3.70-3.58and3.30- 2.45 (m, 7H), 2.40-2.22 (m, 4H), 2.15-1.95 (m, 6H), 1.86 (s, 3H).
1-081;
δ7.33-7.20 (m, 2H), 6.86 (brs, 2H), 6.58-6.42 (m, 2H), 4.61 (s, 2H), 3.84 (s, 3H), 3.27-3.17 (m, 1H), 3.12-3.00 (m, 1H), 2.90-2.79 (m, 2H), 2.37-2.25 (m, 4H), 2.02 (s, 3H), 2.00 (s, 3H), 1.86 (s, 3H).
1-082;
δ7.52-7.40 (m, 2H), 6.86 (brs, 2H), 6.48-6.30 (m, 2H), 4.61 and 4.57 (s, 2H), 3.84 (s, 3H), 3.27-3.15 (m, 1H ), 3.12-3.00 (m, 1H), 2.90-2.79 (m, 2H), 2.35-2.25 (m, 4H), 2.05-1.98 (m, 6H), 1.86 (s, 3H).
1-083;
δ7.80-7.70 (m, 2H), 7.65-7.58 (m, 1H), 7.50-7.30 (m, 2H) 7.15-7.05 (m, 1H), 6.92-6.85 (m, 1H), 6.80 (brs, 2H), 4.77 and 4.75 (s, 2H), 3.82 (s, 3H), 3.32-3.20 (m, 1H), 3.12-3.00 (m, 1H), 2.95-2.80 (m, 2H), 2.35-2.23 ( m, 4H), 2.08-1.98 (m, 6H), 1.86 (s, 3H).
1-087;
δ8.61 (s, 1H), 8.06 (s, 1H), 7.70-7.61 (m, 2H), 7.10-7.05 (m, 2H), 6.87-6.65 (m, 4H), 4.75-4.69 (m, 1H ), 3.84 (s, 3H) 3.28-2.81 (m, 4H) 2.40-1.95 (m, 10H) 1.83 (s, 3H), 1.52 (m, 3H).
1-088;
δ6.86 (brs, 2H), 6.81-6.78 (m, 1H), 3.84 (s, 3H), 3.38-3.27 (m, 1H), 3.09-2.98 (m, 1H), 2.95-2.80 (m, 2H ), 2.55-2.45 (m, 4H), 2.35-2.21 (m, 4H), 2.10-2.01 (m, 6H), 2.00-1.90 (m, 2H), 1.86 (s, 3H).
1-089;
δ6.86 (brs, 2H), 3.84 (s, 3H), 3.40-3.27 (m, 1H), 3.10-2.98 (m, 1H), 2.97-2.70 (m, 4H), 2.58-2.50 (m, 2H ), 2.35-2.23 (m, 4H), 2.10-1.86 (m, 11H).
1-090;
δ7.08-6.97 (m, 1H), 6.87 (brs, 2H), 5.83-5.75 (m, 1H), 3.84 (s, 3H), 3.37-3.26 (m, 1H), 3.08-2.98 (m, 1H ), 2.93-2.80 (m, 2H), 2.35-2.10 (m, 6H), 2.07 (s, 3H), 2.06 (s, 3H), 1.86 (s, 3H), 1.55-1.40 (m, 2H), 0.91 (t, J = 7.2Hz, 3H).
1-091;
δ7.52-7.49 (m, 1H), 7.40 (d, J = 15.6Hz, 1H), 6.87 (brs, 2H), 6.68-6.65 (m, 1H), 6.50-6.47 (m, 1H), 6.24 ( d, J = 15.6Hz, 1H), 3.84 (s, 3H), 3.40-3.29 (m, 1H), 3.10-2.99 (m, 1H), 2.98-2.81 (m, 2H), 2.35-2.25 (m, 4H), 2.09 (s, 3H), 2.07 (s, 3H), 1.86 (s, 3H).
1-092;
δ6.87 (brs, 2H), 4.24 and 4.19 (brs, 2H), 3.84 (s, 3H), 3.75-2.22 (m, 10H), 2.15-2.02 (m, 6H), 1.90-1.85 (m, 3H ).
1-093;
δ6.86 (brs, 2H), 4.05 (s, 2H), 3.84 (s, 3H), 3.33 (s, 3H), 3.32-3.20 (m, 1H), 3.10-3.00 (m, 1H), 2.92- 2.80 (m, 2H), 2.35-2.23 (m, 4H), 2.10-2.02 (m, 6H), 1.87 (s, 3H).
1-094;
δ7.40-7.15 (m, 5H), 6.86 (brs, 2H), 4.46and4.38 (s, 2H), 4.11 and 4.08 (s, 2H), 3.84and3.83 (s, 3H), 3.78-2.20 (m, 8H), 2.06 (s, 3H), 2.04 (s, 3H), 1.87 (s, 3H).
1-095;
δ6.88 (brs, 2H), 3.84 (s, 3H), 3.30-3.18 (m, 1H), 3.08-2.98 (m, 1H), 2.92-2.79 (m, 2H), 2.35-2.23 (m, 4H ), 2.10-2.03 (m, 6H), 1.98 (s, 3H), 1.86 (s, 3H).
1-096;
δ6.89 (brs, 2H), 3.83 (s, 3H), 3.28-3.18 (m, 1H), 3.08-2.99 (m, 1H), 2.90-2.88 (m, 2H), 2.35-2.24 (m, 4H ), 2.07 (s, 3H), 2.06 (s, 3H), 1.86 (s, 3H), 0.23 (s, 9H).
1-098;
δ6.84 (brs, 2H), 4.03 (s, 3H), 3.84 (s, 3H), 3.39 (s, 2H), 3.32-3.20 (m, 1H), 3.12-3.00 (m, 1H), 2.95- 2.80 (m, 2H), 2.37-2.22 (m, 4H), 2.09 (s, 3H), 2.08 (s, 3H), 1.92 (s, 3H), 1.86 (s, 3H).
1-099;
δ6.87-6.80 (m, 2H), 3.84 and 3.78 (s, 3H), 3.40-2.28 (m, 5H), 2.26-2.22 (m, 3H), 2.15-2.08 (m, 6H), 1.88 and 1.86 (s, 3H).
1-100;
δ6.85 (brs, 2H), 6.32-6.28 (m, 1H), 3.84 (s, 3H), 3.37-3.28 (m, 1H), 3.16-3.05 (m, 1H), 3.00-2.80 (m, 2H ), 2.50-2.45 (m, 3H), 2.40-2.29 (m, 1H), 2.24 (s, 3H), 2.11 (s, 3H), 2.10 (s, 3H), 1.88 (s, 3H).
1-101;
δ6.87 (brs, 2H), 3.84 (s, 3H), 3.45-3.33 (m, 1H), 3.13-2.80 (m, 3H), 2.65 (s, 3H), 2.55 (s, 3H), 2.37- 2.24 (m, 4H), 2.10 (s, 3H), 2.08 (s, 3H), 1.88 (s, 3H).
1-103;
δ8.31 (s, 1H), 6.85 (brs, 2H), 3.85 (s, 3H), 3.55-3.42 (m, 1H), 3.13-3.03 (m, 2H), 2.92-2.83 (m, 1H), 2.38-2.18 (m, 4H), 2.09 (s, 3H), 2.07 (s, 3H), 1.89 (s, 3H), 1.65-1.50 (m, 1H), 1.23-1.17 (m, 2H), 1.03- 0.97 (m, 2H).
1-104;
δ6.87 (brs, 2H), 3.85 (s, 3H), 3.70-3.22 (m, 10H), 3.08-2.97 (m, 1H), 2.96-2.80 (m, 2H), 2.32-2.19 (m, 3H ), 2.08 (s, 3H), 2.05 (m, 3H), 1.87 (s, 3H).
1-107;
δ6.86 (brs, 2H), 3.84 (s, 3H), 3.42-3.31 (m, 1H), 3.07-2.72 (m, 9H), 2.31-2.19 (m, 4H), 2.09 (s, 3H), 2.06 (s, 3H), 1.86 (s, 3H).
1-108;
δ7.27 (brs, 2H), 3.84 (s, 3H), 3.38-3.23 (m, 1H), 3.15-2.78 (m, 5H), 2.40-2.01 (m, 10H), 1.86 (s, 3H), 1.69-1.48 (m, 3H), 1.38-1.05 (m, 10H).
1-122;
δ6.86 (brs, 2H), 3.85 (s, 3H), 3.39-3.28 (m, 1H), 3.11-2.59 (m, 9H), 2.36-1.98 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.54 (s, 3H).
1-125;
δ10.06 (brs, 1H), 6.99-6.81 (m, 2H), 4.66-4.42 (m, 2H), 3.50-3.32 (m, 2H), 3.04-1.42 (m, 20H).
1-126;
δ6.86 (brs, 2H), 3.84 (brs, 3H), 3.58-2.72 (m, 12H), 2.35-1.20 (m, 16H).
1-127;
δ7.32-6.62 (m, 7H), 4.55-4.28 (m, 1H), 3.89-3.79 (m, 3H), 3.38-3.20 (m, 1H), 3.02-2.65 (m, 3H), 2.29-1.44 (m, 13H), 1.13-0.87 (m, 6H).
1-128;
δ6.97-6.66 (m, 6H), 4.57-4.31 (m, 1H), 3.84 (s, 3H), 3.38-3.23 (m, 1H), 3.04-2.71 (m, 3H), 2.30-1.40 (m , 13H), 1.17-0.79 (m, 6H).
1-129;
δ6.98-6.43 (m, 5H), 4.59-4.40 (m, 1H), 3.85 (s, 3H), 3.50-3.31 (m, 1H), 3.07-2.76 (m, 3H), 2.32-1.50 (m , 13H), 1.20-0.81 (m, 6H).
1-130;
δ6.84 (brs, 2H), 4.92-4.58 (m, 2H), 3.84 (s, 3H), 3.82-2.77 (m, 9H), 2.37-1.32 (m, 15H), 1.12-0.81 (m, 3H ).
1-134;
δ7.50-7.00 (m, 5H), 6.85 (brs, 2H), 3.85-3.50 (m, 5H), 3.20-2.18 (m, 8H), 2.10-1.97 (m, 6H), 1.85 and 1.78 (s , 3H).
1-139;
δ7.78-7.57 (m, 5H), 6.90-6.82 (m, 2H), 4.11 (s, 2H), 3.89 (s, 3H), 3.85 (s, 3H), 3.62-2.20 (m, 8H), 2.16-1.85 (m, 9H).
1-140;
δ6.92-6.82 (m, 2H), 3.87-3.82 (m, 3H), 3.68-3.30 (m, 1H), 3.28-2.00 (m, 19H), 1.92-1.84 (m, 3H).
1-141;
δ6.89 (brs, 2H), 3.84 (s, 3H), 3.38-2.78 (m, 8H), 2.40-2.25 (m, 4H), 2.15-1.82 (m, 11H).
1-142;
δ6.88 (brs, 2H), 3.85 (s, 3H), 3.63-2.22 (m, 9H), 2.13-2.02 (m, 6H), 1.90-1.82 (m, 3H), 1.28-0.70 (m, 4H ).
1-143;
δ6.88 (brs, 2H), 3.85 (s, 3H), 3.42-2.80 (m, 6H), 2.40-1.70 (m, 13H), 0.85-0.72 (m, 2H), -0.07 (s, 9H) .
1-144;
δ7.45-7.22 (m, 5H), 6.86 (brs, 2H), 5.13 (s, 2H), 3.84 (s, 3H), 3.35-2.22 (m, 8H), 2.14-2.00 (m, 6H), 1.97-1.80 (m, 3H).
1-145;
δ6.87 (brs, 2H), 5.94-5.75 (m, 1H), 5.45-5.20 (m, 2H), 4.73-4.48 (m, 2H), 3.84 (s, 3H), 3.34-3.23 (m, 1H ), 3.10-2.80 (m, 3H), 2.40-2.22 (m, 4H), 2.07 (s, 3H), 2.05 (s, 3H), 1.86 (s, 3H).
1-146;
δ6.87 (brs, 2H), 4.33-4.15 (m, 2H), 3.85 (s, 3H), 3.62-3.52 (m, 2H), 3.43-3.22 (m, 4H), 3.10-2.80 (m, 3H ), 2.35-2.22 (m, 4H), 2.13-2.01 (m, 6H), 1.86 (s, 3H).
1-147;
δ6.87 (brs, 2H), 4.33-4.15 (m, 2H), 3.85 (s, 3H), 3.62-3.52 (m, 2H), 3.43-3.22 (m, 4H), 3.10-2.80 (m, 3H ), 2.35-2.22 (m, 4H), 2.13-2.01 (m, 6H), 1.86 (s, 3H).
1-148;
δ7.13-7.08 (m, 2H), 6.98-6.92 (m, 2H), 6.78 (brs, 2H), 3.84 (s, 3H), 3.15-2.96 (m, 2H), 2.88-2.67 (m, 2H ), 2.33-2.19 (m, 4H), 1.90 (s, 3H), 1.87 (s, 3H), 1.85 (s, 3H), 1.47 (s, 3H), 1.47 (s, 3H).
1-149;
δ8.10-7.97 (m, 2H), 7.75-7.65 (m, 2H), 6.86 (brs, 2H), 3.85 (s, 3H), 3.45-3.35 (m, 1H), 3.18-2.85 (m, 3H ), 2.42-2.29 (m, 1H), 2.25 (s, 3H), 2.13 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-150;
δ6.86 (s, 2H), 3.84 (s, 3H), 3.47-3.32 (m, 3H), 3.29-3.19 (m, 2H), 3.07-2.80 (m, 3H), 2.32-2.19 (m, 4H ), 2.09 (s, 3H), 2.07 (s, 3H), 1.90-1.80 (m, 7H).
1-151;
δ6.86 (s, 2H), 3.85 (s, 3H), 3.44-3.20 (m, 5H), 3.08-2.80 (m, 3H), 2.32-2.19 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.64-1.37 (m, 6H).
1-152;
δ6.86 (s, 2H), 3.84 (s, 3H), 3.51-3.28 (m, 5H), 3.08-2.80 (m, 3H), 2.40-2.18 (m, 11H), 2.08 (s, 3H), 2.05 (s, 3H), 1.86 (s, 3H).
1-153;
δ6.85 (brs, 2H), 5.90-5.42 (m, 2H), 5.33-4.74 (m, 4H), 4.00-3.58 (m, 7H), 3.44-3.30 (m, 1H), 3.09-2.80 (m , 3H), 2.37-2.18 (m, 4H), 2.07 (s, 3H), 2.04 (s, 3H), 1.87 (s, 3H).
1-155;
δ7.83-7.77 (m, 1H), 7.65-7.57 (m, 1H), 7.39-7.29 (m, 2H), 6.85 (brs, 2H), 3.85 (s, 3H), 3.40-3.29 (m, 1H ), 3.18-3.05 (m, 1H), 3.03-2.84 (m, 2H), 2.41-2.28 (m, 1H), 2.25 (s, 3H), 2.11 (s, 3H), 2.09 (s, 3H), 1.88 (s, 3H).
1-156;
δ7.10-6.92 (m, 2H), 6.90-6.72 (m, 4H), 3.85 (s, 3H), 3.80 (s, 3H), 3.68-3.53 (m, 2H), 3.24-3.12 (m, 1H ), 3.07-2.74 (m, 3H), 2.51-1.82 (m, 13H).
1-159;
δ7.30-6.67 (m, 7H), 3.84 (s, 3H), 3.41-3.18 (m, 4H), 3.10-2.77 (m, 3H), 2.30-1.66 (m, 13H).
1-160;
δ6.84 (brs, 2H), 3.84 (s, 3H), 3.79 (s, 3H), 3.40-2.82 (m, 4H), 2.35-2.25 (m, 1H), 2.25 (s, 3H), 2.09 ( s, 3H), 2.07 (s, 3H), 1.87 (s, 3H).
1-161;
δ7.56 (d, J = 8.4Hz, 2H), 7.20 (d, J = 8.4Hz, 2H), 6.86 (brs, 2H), 3.84 (s, 3H), 3.38-2.75 (m, 4H), 2.42 (s, 3H), 2.41-2.09 (m, 1H), 2.25 (s, 3H), 1.92 (s, 3H), 1.89 (s, 3H), 1.85 (s, 3H).
1-162;
δ7.97 (d, J = 8.1Hz, 1H), 7.75 (d, J = 8.1Hz, 1H), 6.87 (brs, 2H), 4.01 (s, 3H), 3.86 (s, 3H), 3.42-3.30 (m, 1H), 3.20-3.08 (m, 4H), 3.05-2.73 (m, 2H), 2.43-2.22 (m, 4H), 2.14-2.05 (m, 6H), 1.98-1.85 (m, 3H) .
1-163;
δ7.50-7.44 (m, 1H), 7.21-7.13 (m, 1H), 6.92-6.70 (m, 5H), 6.68-6.55 (m, 2H), 4.72-4.59 (m, 1H), 3.84 (s , 3H), 3.23-2.67 (m, 4H), 2.38-2.16 (m, 4H), 2.12-1.80 and 1.62-1.40 (m, 12H).
1-164;
δ11.4 (brs, 1H), 7.56-7.10 (m, 4H), 6.87-6.82 (m, 2H), 3.96-3.85 (m, 3H) 3.40-2.65 (m, 3H), 2.51-1.97 (m, 14H).
1-165;
δ6.85 (brs, 2H), 4.85-4.50 (m, 1H), 3.90-3.80 (m, 3H), 3.20-2.50 (m, 4H), 2.38-2.00 (m, 10H), 1.90-1.83 (m , 3H), 1.75-1.35 (m, 8H).
1-166;
δ6.87 (brs, 2H), 6.37-6.05 (m, 1H), 4.72-4.30 (m, 2H), 3.90-3.80 (m, 3H), 3.35-2.55 (m, 4H), 2.45-2.03 (m , 10H), 1.92-1.85 (m, 3H).
1-167;
δ7.19-7.08 (m, 2H), 6.96-6.86 (m, 4H), 3.84 (s, 3H), 3.33 (dd, J = 18.3Hz, 6.9Hz, 1H), 3.12-3.02 (m, 1H) , 3.00-2.80 (m, 1H), 2.40-2.20 (m, 8H), 2.11 (s, 3H), 2.09 (s, 3H), 1.92-1.84 (m, 3H).
1-168;
δ7.00-6.71 (m, 6H), 3.88-3.72 (m, 6H), 3.33 (dd, J = 18.3Hz, 6.9Hz, 1H), 3.15-2.80 (m, 3H), 2.40-2.25 (m, 4H), 2.11 (s, 3H), 2.09 (s, 3H), 1.92-1.84 (m, 3H).
1-169;
δ7.48-7.07 (m, 5H), 6.90-6.60 (m, 2H), 6.00-5.81 (m, 1H), 3.91-3.80 (m, 3H), 3.27-1.70 (m, 20H).
1-170;
δ6.58 (s, 2H), 3.84 (s, 3H) 3.45-2.78 (m, 8H), 2.39-2.24 (m, 4H), 2.13-2.04 (m, 6H), 1.86 (s, 3H), 1.56 -1.33 (brs, 6H).
1-171;
δ6.86 (brs, 2H), 3.84 (s, 3H), 3.43-2.71 (m, 9H), 2.35-2.19 (m, 4H), 2.17-2.00 (m, 6H), 1.87 (s, 3H), 1.12-0.89 (m, 3H).
1-173;
δ7.35-7.10 (m, 5H), 6.82 (brs, 2H), 3.87-3.80 (m, 3H), 3.23-2.67 (m, 4H), 2.29 (s, 3H), 2.28-2.17 (m, 1H ), 1.93-1.80 (m, 9H), 1.55-1.48 (m, 2H), 1.25-1.18 (m, 2H).
1-174;
δ7.16-7.10 (m, 2H), 7.05-6.99 (m, 2H), 6.82 (brs, 2H), 3.85-3.80 (m, 3H), 3.28-2.67 (m, 4H), 2.30 (s, 3H ), 2.28-2.17 (m, 1H), 1.92-1.81 (m, 9H), 1.60-1.40 (m, 2H), 1.23-1.17 (m, 2H).
1-175;
δ6.88 (brs, 2H), 4.11 (t, J = 6.9Hz, 2H), 3.85 (s, 3H), 3.27 (dd, J = 18.3Hz, 6.9Hz, 1H), 3.10-2.80 (m, 3H ), 2.37-2.20 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.67-1.52 (m, 2H), 1.41-1.17 (m, 6H), 0.98-0.80 (m, 3H).
1-176;
δ6.87 (brs, 2H), 4.15-4.08 (m, 2H), 3.85 (s, 3H), 3.27 (dd, J = 18.6Hz, 6.9Hz, 1H), 3.09-2.80 and 2.38-2.02 (m, 13H), 1.87 (s, 3H), 1.70-1.52 (m, 3H), 1.40-1.14 (m, 9H), 0.99-0.82 (m, 3H).
1-177;
δ6.88 (brs, 2H), 4.39-4.32 (m, 2H), 3.85 (s, 3H), 3.64-3.58 (m, 2H), 3.27 (dd, J = 18.3Hz, 6.9Hz, 1H), 3.11 -2.80 (m, 3H), 2.37-2.22 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H).
1-178;
δ6.88 (brs, 2H), 4.33-4.25 (m, 2H), 3.85 (s, 3H), 3.68-3.50 (m, 2H), 3.27 (dd, J = 18.3Hz, 6.9Hz, 1H), 3.11 -2.80 (m, 3H), 2.37-2.22 (m, 4H), 2.13-2.00 (m, 8H), 1.87 (s, 3H).
1-179;
δ6.88 (brs, 2H), 4.20-4.10 (m, 2H), 3.85 (s, 3H), 3.55-3.47 (m, 2H), 3.27 (dd, J = 18.3Hz, 6.9Hz, 1H), 3.10 -2.80 (m, 3H), 2.35-2.23 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.84-1.68 (m, 4H).
1-180;
δ6.87 (brs, 2H), 4.18-4.08 (m, 2H), 3.85 (s, 3H), 3.27 (dd, J = 18.6Hz, 6.9Hz, 1H), 3.10-2.80 (m, 3H), 2.37 -2.20 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.67-1.52 (m, 2H), 1.41-1.22 (m, 2H), 0.98-0.86 (m, 3H).
1-181;
δ7.38-7.28 (m, 2H), 7.00-6.70 (m, 4H), 3.84 (s, 3H), 3.32 (dd, J = 18.3Hz, 6.9Hz, 1H), 3.15-2.75 (m, 3H) , 2.38-2.27 (m, 4H), 2.10 (s, 3H), 2.09 (s, 3H), 1.97-1.85 (m, 3H).
1-183;
δ6.88 (brs, 2H), 4.68-4.29 (m, 4H), 3.85 (s, 3H), 3.28 (dd, J = 18.3Hz, 6.9Hz, 1H), 3.11-3.00 (m, 1H), 2.97 -2.80 (m, 2H), 2.37-2.22 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H).
1-184;
δ8.25-8.13 (m, 2H), 7.47-7.37 (m, 2H), 6.87 (brs, 2H), 5.21 (s, 2H), 3.84 (s, 3H), 3.25 (dd, J = 18.3Hz, 6.9Hz, 1H), 3.11-3.00 (m, 1H), 2.96-2.80 (m, 2H), 2.37-2.22 (m, 4H), 2.06 (s, 3H), 2.04 (s, 3H), 1.87 (s , 3H).
1-185;
δ6.92-6.80 (m, 2H), 4.30-3.28 (m, 12H), 3.14-2.75 (m, 3H), 2.68-1.85 (m, 13H).
1-186;
δ6.86 (brs, 2H), 3.84 (s, 3H), 3.75-3.52 (m, 4H), 3.38-3.24 (m, 1H), 3.08-2.97 (m, 1H), 2.93-2.80 (m, 2H ), 2.61-2.50 (m, 2H), 2.48-2.37 (m, 2H), 2.32-2.19 (m, 4H), 2.08 (s, 3H), 2.05 (s, 3H), 1.87 (s, 3H).
1-187;
δ6.85 (brs, 2H), 4.53-4.45 (m, 2H), 3.84 (s, 3H), 3.78-3.70 (m, 2H), 3.63-3.57 (m, 2H), 3.55-3.48 (m, 2H ), 3.36 (s, 3H), 3.28-3.18 (m, 1H), 3.13-3.02 (m, 1H), 3.00-2.72 (m, 2H), 2.40-2.28 (m, 1H), 2.26 (s, 3H ), 2.10 (s, 3H), 2.08 (s, 3H), 1.87 (s, 3H).
1-188;
δ6.87 (brs, 2H), 4.00-3.72 and 3.62-3.22 and 3.10-2.79 and 2.58-2.41 (m, 13H), 2.33-
2.18 (m, 4H), 2.08 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.20-0.96 (m, 6H).
1-189;
δ6.86 (brs, 2H), 4.00-3.80 (m, 4H), 3.41-3.23 and 3.08-2.78 and 2.32-2.19 (m, 11H), 2.09 and 2.08 (s, 3H), 2.06 and 2.05 (s, 3H), 1.87 (s, 3H), 1.73-0.97 (m, 8H).
1-190;
δ6.86 (brs, 2H), 4.00-3.80 (m, 4H), 3.76-3.49 (m, 2H), 3.44-3.26 (m, 1H), 3.08-2.62 and 2.51-2.19 (m, 10H), 2.09 (s, 3H), 2.06 (s, 3H), 1.87 (s, 3H), 1.12-0.70 (m, 6H).
1-191;
δ6.87-6.80 (m, 2H), 3.86-3.80 (m, 3H), 3.30-2.45 (m, 6H), 2.40-2.03 (m, 10H), 1.86 (s, 3H), 1.30-1.20 (m , 3H).
1-192;
δ7.66 (m, 5H), 6.80-6.53 (m, 2H), 5.32-5.10 (m, 2H), 3.86 and 3.84 (s, 3H), 3.50-3.37 and 3.10-1.79 (m, 17H).
1-193;
δ6.88 (brs, 2H), 5.15-5.00 (m, 2H), 3.86 (s, 3H), 3.42 (s, 3H), 3.13-2.61 (m, 4H), 2.27 (s, 3H), 2.22- 2.14 (m, 1H), 2.13-2.03 (m, 6H), 1.97-1.86 (m, 3H).
1-210;
δ7.58 (s, 1H), 7.40-7.31 (m, 2H), 6.84 (s, 2H), 3.81 (s, 3H), 3.32 (dd, J = 12.0Hz, J = 6.8Hz, 1H), 3.13 -3.06 (m, 1H), 2.97-2.83 (m, 2H), 2.34-2.28 (m, 1H), 2.22 (s, 3H), 2.08 (s, 3H), 2.06 (s, 3H), 1.85 (s , 3H).
1-220;
δ6.83 (s, 2H), 6.80 (s, 2H), 3.86 (s, 3H), 3.32-3.27 (m, 1H), 3.20-3.05 (m, 1H), 3.00-2.85 (m, 2H), 2.40-2.30 (m, 1H), 2.25 (s, 3H), 2.24 (s, 3H), 2.15-2.00 (m, 12H), 1.89 (s, 3H).
1-222;
δ7.30-7.22 (m, 3H), 6.82 (s, 2H), 3.85 (s, 3H), 3.34 (dd, J = 18.4Hz, 6.8Hz, 1H), 3.18-3.07 (m, 1H), 3.03 -2.83 (m, 2H), 2.40-2.30 (m, 1H), 2.22 (s, 3H), 2.08 (s, 3H), 2.05 (s, 3H), 1.87 (s, 3H).
1-226;
δ6.87 (brs, 1H), 6.85 (brs, 1H), 5.24-5.11 and 4.92-4.84 (m, 2H), 3.85 and 3.84 (s, 3H), 3.67-3.40 (m, 1H), 3.31-2.66 and 2.46-2.33 (m, 4H), 2.31-2.12 (m, 1H), 2.26 (s, 3H), 2.09 (s, 3H), 2.05 (s, 3H), 1.89 and 1.88 (s, 3H), 1.86 -1.42 (m, 4H) 1.40-1.12 (m, 6H).
1-227;
δ6.87 (brs, 1H), 6.84 (brs, 1H), 5.22-5.09 and 4.90-4.80 (m, 2H), 3.85 and 3.84 (s, 3H), 3.80-3.46 (m, 4H), 3.36 and 3.34 (s, 3H), 3.32-3.22 and 3.13-3.02 (m, 1H), 2.98-2.60 (m, 3H), 2.43-2.13 (m, 1H), 2.08 (s, 3H), 2.05 (s, 3H) , 1.89 and 1.87 (s, 3H), 1.59 (s, 3H).
1-228;
δ6.88 (brs, 2H), 5.20-5.03 and 4.86-4.75 (m, 2H), 3.86 (s, 3H), 3.73-3.52 (m, 2H), 3.12-2.62 and 2.30-2.14 (m, 5H) , 2.26 (s, 3H), 2.08 (s, 3H), 2.05 (s, 3H), 1.96-1.82 (m, 3H), 1.20 (t, J = 6.8Hz, 3H).
1-239;
δ7.64 (d, J = 8.8Hz, 1H), 7.46 (d, J = 2.0Hz, 1H), 7.30-7.23 (m, 1H), 6.85 (s, 2H), 3.84 (s, 3H), 3.37 (dd, J = 18.4Hz, 4.0Hz, 1H), 3.17-3.08 (m, 1H), 3.05-2.85 (m, 2H), 2.40-2.22 (m, 4H), 2.10 (s, 3H), 2.08 ( s, 3H), 1.88 (s, 3H).
1-242;
δ7.31 (s, 2H), 6.84 (s, 2H), 3.87 (s, 3H), 3.32 (dd, J = 18.4Hz, 3.2Hz, 1H), 3.20-3.10 (m, 1H), 3.05-2.85 (m, 2H), 2.45-2.30 (m, 1H), 2.25 (s, 3H), 2.09 (s, 3H), 2.07 (s, 3H), 1.90 (s, 3H).
1-243;
δ7.92-7.89 (m, 1H), 7.71-7.67 (m, 1H), 7.43-7.25 (m, 2H), 6.87 (s, 2H), 3.85 (s, 3H), 3.38 (dd, J = 18.4 Hz, 6.8Hz, 1H), 3.15-3.07 (m, 1H), 3.02-2.88 (m, 2H), 2.40-2.30 (m, 4H), 2.25 (s, 3H), 2.13 (s, 3H), 2.12 (s, 3H), 1.89 (s, 3H).
1-244;
δ7.70-7.67 (m, 1H), 7.51-7.48 (m, 1H), 6.96-6.92 (m, 2H), 6.86 (s, 2H), 3.84 (s, 3H), 3.81 (s, 3H), 3.43-3.38 (m, 1H), 3.03-2.86 (m, 3H), 2.34-2.25 (m, 4H), 2.13 (s, 3H), 2.11 (s, 3H), 1.88 (s, 3H).
1-245;
δ7.95-7.91 (m, 2H), 7.12-7.08 (m, 2H), 6.87 (s, 2H), 3.84 (s, 3H), 3.39 (dd, J = 11.6Hz, 7.2Hz, 1H), 3.01 -2.96 (m, 1H), 2.91-2.85 (m, 2H), 2.36-2.30 (m, 1H), 2.26 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 (s , 3H).
1-246;
δ7.93-7.89 (m, 2H), 7.10-7.06 (m, 2H), 6.85 (s, 2H), 3.83 (s, 3H), 3.38 (dd, J = 11.6Hz, 6.8Hz, 1H), 3.07 -2.99 (m, 1H), 2.94-2.85 (m, 2H), 2.34-2.31 (m, 1H), 2.24 (s, 3H), 2.11 (s, 3H), 2.09 (s, 3H), 1.87 (s , 3H).
1-247;
δ8.05 (s, 1H), 7.83 (d, J = 8.0Hz, 1H), 7.72 (d, J = 8.0Hz, 1H), 7.31 (t, J = 8.0Hz, 1H), 6.87 (s, 2H ), 3.85 (s, 3H), 3.36 (dd, J = 11.6Hz, 6.8Hz, 1H), 3.14-3.06 (m, 1H), 2.99-2.86 (m, 2H), 2.37-2.31 (m, 1H) , 2.26 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-252;
δ7.03 (s, 2H), 6.87 (s, 2H), 6.67 (s, 1H), 3.86 (s, 3H), 3.76 (s, 3H), 3.34 (dd, J = 11.6Hz, 6.8Hz, 1H ), 3.15-3.08 (m, 1H), 3.05-2.89 (m, 2H), 2.38-2.30 (m, 1H), 2.25 (s, 3H), 2.14 (s, 3H), 2.12 (s, 3H), 1.90 (s, 3H), 1.26 (s, 3H).
1-254;
δ7.89 (s, 1H), 7.79 (d, J = 8.0Hz, 1H), 7.57 (d, J = 8.0Hz, 1H), 7.38 (d, J = 8.0Hz, 1H), 6.87 (s, 2H ), 3.85 (s, 3H), 3.37 (dd, J = 18.8Hz, 6.8Hz, 1H), 3.14-3.07 (m, 1H), 3.00-2.86 (m, 2H), 2.39-2.31 (m, 1H) , 2.50 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-258;
δ7.92-7.88 (m, 1H), 7.61-7.57 (m, 2H), 7.47-7.44 (m, 1H), 6.79 (s, 2H), 3.80 (s, 3H), 3.40-3.34 (m, 1H ), 3.07-3.00 (m, 2H), 2.88-2.79 (m, 1H), 2.34-2.26 (m, 1H), 2.18 (s, 3H), 2.00 (s, 3H), 1.98 (s, 3H), 1.83 (s, 3H).
1-259;
δ8.17 (s, 1H), 8.08 (d, J = 8.0Hz, 1H), 7.85 (d, J = 8.0Hz, 1H), 7.59 (t, J = 8.0Hz, 1H), 6.88 (s, 2H ), 3.90 (s, 3H), 3.39 (dd, J = 18.8Hz, 6.8Hz, 1H), 3.15-3.09 (m, 1H), 3.02-2.87 (m, 2H), 2.38-2.31 (m, 1H) , 2.26 (s, 3H), 2.13 (s, 3H), 2.12 (s, 3H), 1.89 (s, 3H).
1-263;
δ7.90-7.75 (m, 1H), 7.65-7.50 (m, 1H), 7.25-7.05 (m, 2H), 6.87 (s, 2H), 3.85 (s, 3H), 3.45-3.33 (m, 1H ), 3.20-3.07 (m, 1H), 3.05-2.85 (m, 2H), 2.40-2.30 (m, 1H), 2.26 (s, 3H), 2.13 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-265;
δ7.78 (d, J = 8.8Hz, 2H), 7.21 (d, J = 8.8Hz, 2H), 6.86 (s, 2H), 3.84 (s, 3H), 3.45-3.35 (m, 1H), 3.13 -2.85 (m, 3H), 2.49 (s, 3H), 2.35-2.20 (m, 4H), 2.12 (s, 3H), 2.10 (s, 3H), 1.88 (s, 3H).
1-266;
δ8.75 (brs, 1H), 8.50-8.40 (m, 1H), 8.26-8.20 (m, 1H), 7.70-7.60 (m, 1H), 6.89 (s, 2H), 3.85 (s, 3H), 3.45-3.35 (m, 1H), 3.20-3.10 (m, 1H), 3.07-2.85 (m, 2H), 2.45-2.30 (m, 1H), 2.26 (s, 3H), 2.14 (s, 3H), 2.13 (s, 3H), 1.90 (s, 3H).
1-268;
δ7.90-7.83 (m, 1H), 7.74 (brs, 1H), 7.55-7.43 (m, 2H), 6.87 (s, 2H), 3.84 (s, 3H), 3.45-3.35 (m, 1H), 3.17-3.09 (m, 1H), 3.06-2.85 (m, 2H), 2.40-2.31 (m, 1H), 2.25 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 ( s, 3H).
1-269;
δ7.95 (d, J = 9.2Hz, 2H), 7.30-7.22 (m, 2H), 6.86 (s, 2H), 3.84 (s, 3H), 3.45-3.33 (m, 1H), 3.17-2.85 ( m, 3H), 2.40-2.30 (m, 1H), 2.25 (s, 3H), 2.11 (s, 3H), 2.10 (s, 3H), 1.88 (s, 3H).
1-270;
δ6.87 (brs, 2H), 3.85 (s, 3H), 3.61-3.49 (m, 1H), 3.35-3.22 (m, 1H), 3.09-2.96 (m, 1H), 2.93-2.78 (m, 2H ), 2.35-2.2.21 (m, 1H), 2.28 (s, 3H), 2.15-1.99 (m, 2H), 2.05 (s, 3H), 2.02 (s, 3H), 1.86 (s, 3H), 1.78-1.42 (m, 6H).
1-272;
δ7.29-7.23 (m, 5H), 6.86 (s, 2H), 4.05 (s, 2H), 3.85 (s, 3H), 3.29-3.23 (m, 1H), 3.03-2.98 (m, 1H), 2.91-2.82 (m, 2H), 2.31-2.27 (m, 4H), 2.05 (s, 3H), 2.03 (s, 3H), 1.86 (s, 3H).
1-273;
δ6.85 (s, 2H), 5.78-5.68 (m, 1H), 5.23-5.10 (m, 2H), 3.83 (s, 3H), 3.46-3.43 (m, 2H), 3.29-3.22 (m, 1H ), 3.05-2.98 (m, 1H), 2.90-2.81 (m, 2H), 2.29-2.23 (m, 4H), 2.05 (s, 3H), 2.03 (s, 3H), 1.85 (s, 3H).
1-274;
δ7.75 (d, J = 7.2Hz, 1H), 7.57-7.51 (m, 3H), 6.85 (s, 2H), 3.86-3.82 (m, 6H), 3.48-3.42 (m, 1H), 3.12- 2.56 (m, 3H), 2.38-2.31 (m, 1H), 2.25 (s, 3H), 2.09 (s, 3H), 2.07 (s, 3H), 1.89 (s, 3H).
1-275;
δ8.08 (d, J = 6.8Hz, 2H), 7.97 (d, J = 6.8Hz, 2H), 6.87 (s, 2H), 3.94 (s, 3H), 3.84 (s, 3H), 3.40 (dd , J = 18.8Hz, 6.8Hz, 1H), 3.13-3.08 (m, 1H), 3.04-2.86 (m, 2H), 2.37-2.32 (m, 1H), 2.25 (s, 3H), 2.13 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-276;
δ8.01 (d, J = 8.4Hz, 2H), 7.74 (d, J = 8.4Hz, 2H), 6.88 (s, 2H), 3.85 (s, 3H), 3.39 (dd, J = 18.8Hz, 6.8 Hz, 1H), 3.15-3.11 (m, 1H), 3.03-2.86 (m, 2H), 2.38-2.32 (m, 1H), 2.26 (s, 3H), 2.13 (s, 3H), 2.11 (s, 3H), 1.90 (s, 3H).
1-277;
δ8.18 (s, 1H), 8.13 (d, J = 8.0Hz, 1H), 7.87 (d, J = 8.0Hz, 1H), 7.59 (t, J = 8.0Hz, 1H), 6.88 (s, 2H ), 3.85 (s, 3H), 3.37 (dd, J = 18.4Hz, 6.8Hz, 1H), 3.14-3.09 (m, 1H), 3.00-2.86 (m, 2H), 2.39-2.33 (m, 1H) , 2.26 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-278;
δ7.71 (d, J = 8.8Hz, 1H), 6.87 (s, 2H), 6.46-6.44 (m, 2H), 3.86 (s, 6H), 3.81 (s, 3H), 3.43 (dd, J = 18.0Hz, 6.0Hz, 1H), 3.10-2.85 (m, 3H), 2.34-2.25 (m, 4H), 2.13 (s, 3H), 2.11 (s, 3H), 1.88 (s, 3H).
1-279;
δ8.27 (d, J = 9.2Hz, 2H), 8.08 (d, J = 9.2Hz, 2H), 6.82 (s, 2H), 3.85 (s, 3H), 3.39 (dd, J = 18.4Hz, 6.8 Hz, 1H), 3.14-3.10 (m, 1H), 3.03-2.87 (m, 2H), 2.38-2.32 (m, 1H), 2.26 (s, 3H), 2.12 (s, 3H), 2.11 (s, 3H), 1.89 (s, 3H).
1-280;
δ7.18 (d, J = 8.4Hz, 2H), 6.96 (d, J = 8.4Hz, 2H), 6.82 (s, 2H), 3.84 (s, 3H), 3.61 (s, 2H), 3.18 (dd , J = 18.8Hz, 6.8Hz, 1H), 3.03-2.99 (m, 1H), 2.85-2.77 (m, 2H), 2.30-2.23 (m, 4H), 1.97 (s, 3H), 1.95 (s, 3H), 1.85 (s, 3H).
1-281;
δ7.33-7.05 (m, 4H), 6.82 (s, 2H), 3.83 (s, 3H), 3.80 (s, 2H), 3.22 (dd, J = 18.8Hz, 6.8Hz, 1H), 3.05-2.99 (m, 1H), 2.87-2.81 (m, 2H), 2.30-2.23 (m, 4H), 1.99 (s, 3H), 1.96 (s, 3H), 1.85 (s, 3H).
1-282;
δ7.05 (d, J = 7.6Hz, 2H), 6.94 (d, J = 7.6Hz, 2H), 6.84 (s, 2H), 3.83 (s, 3H), 3.21 (s, 2H), 3.18 (dd , J = 18.4Hz, 6.8Hz, 1H), 3.02-2.98 (m, 1H), 2.85-2.77 (m, 2H), 2.33-2.22 (m, 7H), 1.99 (s, 3H), 1.97 (s, 3H), 1.85 (s, 3H).
1-283;
δ7.15-7.06 (m, 2H), 6.88-6.83 (m, 4H), 3.83 (s, 3H), 3.60 (s, 2H), 3.19 (dd, J = 18.8Hz, 7.2Hz, 1H), 3.03 -2.97 (m, 1H), 2.85-2.78 (m, 2H), 2.35-2.22 (m, 7H), 1.99 (s, 3H), 1.96 (s, 3H), 1.85 (s, 3H).
1-284;
δ7.46 (d, J = 8.0Hz, 2H), 7.13 (d, J = 8.0Hz, 2H), 6.80 (s, 2H), 3.87-3.80 (m, 3H), 3.70 (s, 2H), 3.23 -2.70 (m, 4H), 2.30-2.08 (m, 4H), 2.05-1.80 (m, 9H).
1-285;
δ7.30-7.20 (m, 1H), 7.05-7.00 (m, 1H), 6.90-6.75 (m, 4H), 3.83 (s, 3H), 3.65 (s, 5H), 3.40-3.30 (m, 1H ), 3.07-2.95 (m, 1H), 2.90-2.80 (m, 2H), 2.30-2.10 (m, 4H), 1.98 (s, 3H), 1.95 (s, 3H), 1.85 (s, 3H).
1-286;
δ7.03 (d, J = 8.8Hz, 2H), 6.82 (brs, 2H), 6.72 (d, J = 8.8Hz, 2H), 3.82 (s, 3H), 3.79 (s, 3H), 3.23-3.12 (m, 1H), 3.02-2.92 (m, 1H), 2.85-2.70 (m, 2H), 2.32-2.15 (m, 4H), 1.92 (s, 3H), 1.87 (s, 3H), 1.84 (s , 3H), 1.55-1.15 (m, 4H).
1-287;
δ7.01 (s, 4H), 6.82 (brs, 2H), 3.82 (s, 3H), 3.23-3.12 (m, 1H), 3.02-2.92 (m, 1H), 2.85-2.70 (m, 2H), 2.32 (s, 3H), 2.29 (s, 3H), 2.28-2.15 (m, 1H), 1.91 (s, 3H), 1.86 (s, 3H), 1.83 (s, 3H), 1.70-1.15 (m, 4H).
1-288;
δ7.12-7.02 (m, 3H), 6.76 (brs, 2H), 3.83 (s, 3H), 3.33-3.25 (m, 1H), 3.01-2.75 (m, 3H), 2.29 (s, 3H), 2.27-2.18 (m, 1H), 1.84 (s, 6H), 1.80 (s, 3H), 1.72-1.65 (m, 2H), 1.27-1.20 (m, 2H).
1-289;
δ7.11 (d, J = 8.4Hz, 2H), 6.91 (d, J = 8.4Hz, 2H), 6.75 (s, 2H), 3.83 (s, 3H), 3.18-3.09 (m, 1H), 3.04 -2.95 (m, 1H), 2.86-2.62 (m, 4H), 2.46-2.34 (m, 2H), 2.31-2.17 (m, 4H), 2.03-1.78 (m, 11H).
1-291;
δ7.01 (s, 4H), 6.77 (s, 2H), 3.82 (s, 3H), 3.10-2.92 (m, 2H), 2.86-2.77 (m, 1H), 2.70-2.62 (m, 1H), 2.50-2.40 (m, 2H), 2.35-2.18 (m, 7H), 1.95-1.75 (m, 11H), 1.70-1.40 (m, 4H).
1-293;
δ7.10 (d, J = 11.2Hz, 2H), 7.00 (d, J = 11.2Hz, 2H), 6.76 (s, 2H), 3.83 (s, 3H), 3.12-2.95 (m, 2H), 2.86 -2.78 (m, 1H), 2.72-2.62 (m, 1H), 2.52-2.40 (m, 2H), 2.32-2.18 (m, 4H), 1.92-1.50 (m, 15H).
1-295;
δ7.02 (d, J = 8.0Hz, 2H), 6.78 (s, 2H), 6.70 (d, J = 8.0Hz, 2H), 3.82 (s, 3H), 3.79 (s, 3H), 3.10-2.92 (m, 2H), 2.85-2.78 (m, 1H), 2.72-2.62 (m, 1H), 2.50-2.40 (m, 2H), 2.30-2.15 (m, 4H), 1.95-1.45 (m, 15H) .
1-297;
δ9.14-9.06 (m, 1H), 8.85-8.78 (m, 1H), 8.24-8.15 (m, 1H), 7.44-7.36 (m, 1H), 6.88 (brs, 2H), 3.86 (s, 3H ), 3.44 (dd, J = 18.8Hz, 6.8Hz, 1H), 3.17-3.08 (m, 1H), 3.07-2.97 (m, 1H), 2.95-2.85 (m, 1H), 2.42-2.31 (m, 1H), 2.26 (s, 3H), 2.13 (s, 3H), 2.12 (s, 3H), 1.91 (s, 3H).
1-298;
δ8.87-8.73 (m, 2H), 7.75-7.67 (m, 2H), 6.88 (brs, 2H), 3.86 (s, 3H), 3.39 (dd, J = 18.4Hz, 6.8Hz, 1H), 3.17 -3.09 (m, 1H), 3.05-2.96 (m, 1H), 2.94-2.86 (m, 1H), 2.40-2.31 (m, 1H), 2.27 (s, 3H), 2.13 (s, 3H), 2.12 (s, 3H), 1.90 (s, 3H).
1-299;
δ7.22-7.13 (m, 1H), 7.11-7.05 (m, 2H), 7.04-6.98 (m, 1H), 6.81 (brs, 2H), 3.83 (s, 3H), 3.64 (s, 2H), 3.19 (dd, J = 18.4Hz, 6.8Hz, 1H), 3.05-2.96 (m, 1H), 2.87-2.72 (m, 2H), 2.32-2.21 (m, 1H), 2.28 (s, 3H), 2.00 (s, 3H), 1.94 (s, 3H), 1.91 (s, 3H), 1.85 (s, 3H).
1-300;
δ7.62 (d, J = 6.8Hz, 1H), 7.46-7.36 (m, 2H), 7.12-7.08 (m, 1H), 6.83 (brs, 2H), 3.85 (s, 2H), 3.83 (s, 3H), 3.20 (dd, J = 18.4Hz, 1H), 3.07-2.97 (m, 1H), 2.88-2.78 (m, 2H), 2.32-2.20 (m, 1H), 2.30 (s, 3H), 1.97 (s, 3H), 1.94 (s, 3H), 1.85 (s, 3H).
1-301;
δ7.23 (brs, 1H), 7.20-7.13 (m, 1H), 7.09-7.06 (m, 1H), 6.92 (d, J = 8.0Hz, 1H), 6.83 (s, 2H), 3.83 (s, 3H), 3.61 (s, 2H), 3.20 (dd, J = 18.8Hz, 7.2Hz, 1H), 3.08-2.98 (m, 1H), 2.89-2.78 (m, 2H), 2.32-2.19 (m, 1H ), 2.28 (s, 3H), 2.00 (s, 3H), 1.98 (s, 3H), 1.86 (s, 3H).
1-302;
δ7.16 (t, J = 8.0Hz, 1H), 6.82-6.79 (m, 3H), 6.66-6.62 (m, 2H), 3.82 (s, 3H), 3.74 (s, 3H), 3.61 (s, 2H), 3.22-3.15 (m, 1H), 3.02-2.97 (m, 1H), 2.85-2.77 (m, 2H), 2.28-2.20 (m, 4H), 1.98 (s, 3H), 1.96 (s, 3H), 1.85 (s, 3H).
1-304;
δ6.90-6.86 (m, 2H), 5.95-5.67 (m, 1H), 5.35-5.11 (m, 2H), 4.82 (d, J = 2.0Hz, 1H), 3.85 (s, 3H), 3.46 ( d, J = 7.2Hz, 1H), 3.31-3.17 (m, 1H), 3.10-3.01 (m, 1H), 2.90-2.82 (m, 2H), 2.37-2.24 (m, 4H), 2.10-2.05 ( m, 6H), 1.87 and 1.86 (s, 3H).
1-305;
δ6.85 (s, 2H), 5.50-5.00 (m, 1H), 3.84 (s, 3H), 3.24-3.18 (m, 1H), 3.10-3.05 (m, 1H), 2.84 (d, J = 18.0 Hz, 2H), 2.37-2.30 (m, 1H), 2.26 (s, 3H), 2.10 (s, 3H), 2.09 (s, 3H), 1.94-1.87 (m, 5H), 1.52 (brs, 2H) , 1.33-1.26 (m, 6H).
1-309;
δ6.85 (s, 2H), 4.92 (d, J = 2.8Hz, 2H), 3.84 (s, 3H), 3.30-3.18 (m, 1H), 3.15-3.05 (m, 1H), 2.90-2.80 ( m, 2H), 2.60-2.52 (m, 1H), 2.40-2.24 (m, 4H), 2.09 (s, 3H), 2.08 (s, 3H), 1.87 (s, 3H).
1-310;
δ7.35 (brs, 1H), 6.86 (s, 2H), 3.65-3.27 (m, 9H), 3.08-2.79 (m, 3H), 2.36-2.27 (m, 4H), 2.08 (s, 3H), 2.04 (s, 3H), 1.91 (s, 3H).
1-311;
δ7.60-7.13 (m, 4H), 6.90-6.76 (m, 2H), 3.88-3.78 (m, 3H), 3.75-3.65 (m, 2H), 3.65-3.57 and 3.23-2.05 (m, 8H) , 2.00-1.80 (m, 9H).
1-312;
δ8.80-8.75 (m, 1H), 7.98-7.93 (m, 1H), 7.85-7.78 (m, 1H), 7.57-7.47 (m, 1H), 6.84and 6.79 (brs, 2H), 3.83 and 3.77 (s, 3H), 3.41-2.10 (m, 14H), 1.88 and 1.85 (s, 3H).
1-313 (* 3);
δ8.05 (s, 1H), 6.87 (brs, 2H), 4.20-3.95 (m, 3H), 3.65-1.85 (m, 17H).
1-314;
δ8.13-7.70 (m, 1H), 6.90-6.80 (m, 2H), 4.10-3.94 (m, 3H), 3.90-2.52 (m, 8H), 2.33-2.22 (m, 3H), 2.15-2.02 (m, 6H), 1.17-1.05 (m, 9H).
2-008;
δ10.05-10.02 (m, 1H), 8.08-7.95 (m, 2H), 7.80-7.35 (m, 3H), 6.95-6.85 (m, 2H), 5.23-4.78 (m, 1H), 4.25-4.05 (m, 2H), 3.90-2.00 (m, 12H), 1.30-1.10 (m, 3H).
2-010 (* 3);
δ7.00-6.85 (m, 2H), 4.40-4.25 (m, 2H), 4.00-2.02 (m, 13H), 1.40-1.22 (m, 3H).
2-015;
δ10.20-9.95 (m, 1H), 8.20-7.98 (m, 2H), 7.75-7.45 (m, 3H), 7.05-6.80 (m, 2H), 3.97-3.72 (m, 1H), 3.60-3.47 (m, 1H), 3.32-2.95 (m, 2H), 2.55-2.05 (m, 10H).
2-018;
δ6.84 (s, 2H), 3.30-3.20 (m, 1H), 3.18-3.07 (m, 1H), 3.10-3.00 (m, 1H), 2.82-2.68 (m, 2H), 2.25 (s, 3H ), 2.20 (s, 3H), 2.08 (s, 3H), 2.06 (s, 3H), 1.08 (s, 9H).
2-033 (* 3);
δ6.89 (brs, 2H), 4.63-1.80 (m, 22H), 1.36-1.15 (m, 3H).
2-034 (* 3);
δ8.35-8.21 (m, 1H), 6.95-6.80 (m, 2H), 4.85-4.50 (m, 1H), 4.30-4.08 (m, 2H), 3.90-2.70 (m, 6H), 2.30-1.88 (m, 9H), 1.35-1.15 (m, 3H).
2-035 (* 3);
δ8.32-8.15 (m, 1H), 6.89 (brs, 2H), 3.70-2.72 (m, 7H), 2.60-2.00 (m, 10H).
3-001;
δ7.60-7.48 and 6.95-6.80 (m, 3H), 4.07-3.85 (m, 4H), 3.85-2.50 (m, 3H), 2.35-2.00 (m, 9H).
3-002 (* 3);
δ6.97-6.83 (m, 2H), 3.88 (s, 3H), 3.00-2.42 (m, 3H), 2.27 (s, 3H), 2.15-2.05 (m, 6H), 1.86 (s, 3H).
4-001 (* 3);
δ6.88 (s, 2H), 3.84 and 3.82 (s, 3H), 2.95-2.71 (m, 1H), 2.55-1.96 (m, 17H), 1.10 (t, J = 7.5Hz, 3H).
5-001 (* 3);
δ6.88 (s, 2H), 2.85-1.99 (m, 17H), 1.88-1.78 (m, 1H), 1.07 (t, J = 7.5Hz, 3H).
5-002;
δ6.86 (s, 2H), 3.72 (s, 3H), 3.01-2.92 (m, 1H), 2.72-1.85 (m, 17H), 1.60 (t, J = 7.5Hz, 3H).
6-004;
δ11.90-11.60 (m, 1H), 8.15-7.55 (m, 2H), 7.40-7.25 (m, 2H), 4.00-3.80 (m, 3H), 3.50-3.35 (m, 1H), 3.05-2.55 (m, 3H), 2.40-1.90 (m, 10H).
6-005;
δ11.80-11.60 (m, 1H), 8.00-7.00 (m, 4H), 4.00-3.80 (m, 3H), 3.50-3.30 (m, 1H), 3.05-1.95 (m, 12H), 1.20-1.00 (m, 3H).
6-006;
δ11.60-11.45 (m, 1H), 7.15-7.05 (m, 2H), 3.95-3.85 (m, 3H), 3.50-3.35 (m, 1H), 3.00-2.50 (m, 3H), 2.50-2.30 (m, 2H), 2.30-1.80 (m, 10H), 1.20-1.00 (m, 3H).
6-008;
δ11.60-11.40 (m, 1H), 7.25-7.15 (m, 2H), 3.95-3.85 (m, 3H), 3.50-3.35 (m, 1H), 3.00-2.85 (m, 1H), 2.85-2.70 (m, 1H), 2.70-2.30 (m, 3H), 2.30-2.18 (m, 1H), 2.18-2.05 (m, 3H), 2.05-1.95 (m, 3H), 1.20-1.00 (m, 3H) , 0.30-0.10 (m, 9H).
6-010;
δ11.52 (brs, 1H), 7.21 (brs, 2H), 3.95-3.85 (m, 3H), 3.45-3.30 (m, 1H), 3.00-2.50 (m, 3H), 2.25-1.90 (m, 10H ), 1.50-1.35 (m, 1H), 0.90-0.70 (m, 4H).
6-011;
δ7.21 (brs, 2H), 3.85 (s, 3H), 3.76 (s, 3H), 2.95-2.55 (m, 5H), 2.11 (s, 6H), 1.95 (s, 3H).
6-012;
δ7.63-7.55 (m, 2H), 7.48-7.40 (m, 2H), 7.40-7.25 (m, 3H), 3.86 (m, 3H), 3.79 (s, 3H), 3.00-2.55 (m, 5H ), 2.21 (s, 6H), 1.95 (s, 3H).
6-013;
δ7.55-7.40 (m, 2H), 7.35-7.17 (m, 4H), 3.86 (s, 3H), 3.78 (s, 3H), 3.00-2.55 (m, 5H), 2.38 (s, 3H), 2.19 (s, 6H), 1.95 (s, 3H).
6-014;
δ7.74-7.63 (m, 4H), 7.29 (brs, 2H), 3.86 (s, 3H), 3.81 (s, 3H), 3.03-2.57 (m, 5H), 2.22 (s, 6H), 1.96 ( s, 3H).
6-019;
δ7.50 (d, J = 8.4Hz, 2H), 7.38 (d, J = 8.4Hz, 2H), 7.25 (brs, 2H), 3.86 (s, 3H), 3.80 (s, 3H), 3.03-2.57 (m, 5H), 2.20 (s, 6H), 1.96 (s, 3H).
6-022;
δ11.61 (brs, 1H), 7.07 (brs, 2H), 4.05-4.00 (m, 2H), 3.91 (s, 3H), 3.50-3.35 (m, 1H), 3.20-2.50 (m, 7H), 2.30-1.90 (m, 10H), 1.60-1.20 (m, 9H), 0.95-0.85 (m, 6H).
6-023;
δ11.74 (brs, 1H), 7.73 (s, 2H), 3.91 (s, 3H), 3.88 (s, 3H), 3.55-3.35 (m, 1H), 3.05-2.50 (m, 3H), 2.20- 1.90 (m, 10H).
6-024;
δ11.58 (brs, 1H), 6.97 (brs, 2H), 3.90 (s, 3H), 3.50-3.30 (m, 1H), 3.00-2.50 (m, 3H), 2.44 (s, 3H), 2.20- 1.90 (m, 10H).
6-025;
δ11.65 (brs, 1H), 7.25-7.13 (m, 2H), 4.47 (s, 2H), 3.91 (s, 3H), 3.50-3.31 (m, 1H), 3.02-2.50 (m, 3H), 2.41-1.79 (m, 10H).
6-026;
δ11.79 (brs, 1H), 7.63 (s, 2H), 3.91 (s, 3H), 3.53-3.31 (m, 1H), 3.02-1.90 (m, 16H).
6-033;
δ11.38 (brs, 1H), 7.20-7.01 (m, 2H), 6.34 (s, 1H), 3.91 (s, 3H), 2.99-2.50 (m, 3H), 2.28-1.90 (m, 11H), 1.51 (s, 9H).
6-035;
δ11.63 (brs, 1H), 7.57-7.27 (m, 5H), 3.92 (s, 3H), 3.51-3.38 (m, 1H), 3.03-2.54 (m, 3H), 2.32-2.14 (m, 7H ), 2.01 (s, 3H).
6-036;
δ11.70 (brs, 1H), 7.21 (brs, 2H), 3.91 (s, 3H), 3.47-3.33 (m, 1H), 2.99-2.52 (m, 3H), 2.35-1.80 (m, 14H), 1.71-1.36 (m, 3H).
6-037;
δ11.00 (brs, 1H), 6.78-6.53 (m, 2H), 4.05-3.70 (m, 6H), 3.50-3.28 (m, 1H), 3.00-2.55 (m, 3H), 2.40-1.80 (m , 10H).
6-038;
δ11.61 (brs, 1H), 7.32-7.25 (m, 1H), 7.03-6.96 (m, 1H), 3.91 (s, 3H), 3.53-3.30 (m, 1H), 3.05-2.10 (m, 10H ), 1.99 (m, 3H).
6-039;
δ6.75 (brs, 2H), 3.86 (s, 3H), 3.74 (s, 3H), 2.97-2.83 (m, 3H), 2.63-2.52 (m, 1H), 2.25-1.75 (m, 2H), 2.09 (s, 3H), 2.06 (s, 3H), 1.88 (s, 3H), 0.95-0.85 (m, 2H), 0.70-0.60 (m, 2H).
6-041;
δ7.40-7.30 (m, 2H), 7.15-7.00 (m, 3H), 6.70 (brs, 2H), 3.87 (s, 3H), 3.80 (s, 3H), 3.02-2.85 (m, 3H), 2.65-2.2.55 (m, 1H), 2.30-2.15 (m, 1H), 2.09 (s, 3H), 2.07 (s, 3H), 1.89 (s, 3H).
6-043;
δ7.56 (d, J = 8.8Hz, 2H), 7.30-7.20 (m, 4H), 3.87 (s, 3H), 3.80 (s, 3H), 3.05-2.85 (m, 3H), 2.70-2.2. 55 (m, 1H), 2.25-2.15 (m, 1H), 2.22 (s, 3H), 2.21 (s, 3H), 1.89 (s, 3H).
6-045;
δ7.45-7.25 (m, 5H), 6.69 (brs, 2H), 5.01 (s, 2H), 3.86 (s, 3H), 3.76 (s, 3H), 3.00-2.85 (m, 3H), 2.65- 2.50 (m, 1H), 2.25-2.15 (m, 1H), 2.10 (s, 3H), 2.07 (s, 3H), 1.88 (s, 3H).
6-046;
δ8.65-8.55 (m, 2H), 7.40-7.30 (m, 2H), 6.64 (brs, 2H), 5.03 (s, 2H), 3.84 (s, 3H), 3.75 (s, 3H), 3.00- 2.80 (m, 3H), 2.65-2.50 (m, 1H), 2.25-2.15 (m, 1H), 2.16 (s, 3H), 2.08 (s, 3H), 1.86 (s, 3H).
6-047;
δ8.46 (brs, 1H), 7.90-7.80 (m, 1H), 7.00-6.90 (m, 1H), 6.84 (brs, 2H), 3.86 (s, 3H), 3.82 (s, 3H), 3.05- 2.85 (m, 3H), 2.70-2.55 (m, 1H), 2.30-2.10 (m, 1H), 2.13 (s, 3H), 2.10 (s, 3H), 1.89 (s, 3H).
6-051 (* 3);
δ8.70-8.66 (m, 1H), 7.78-7.60 (m, 3H), 7.26-7.17 (m, 2H), 3.91 (s, 3H), 3.60-3.35 (m, 1H), 3.03-2.91 (m , 1H), 2.85-2.55 (m, 2H), 2.35-2.18 (m, 7H), 2.00 (s, 3H).
6-052;
δ11.52 (brs, 1H), 7.36-7.28 (m, 2H), 7.12-7.00 (m, 3H), 6.70 (brs, 2H), 3.92 (s, 3H), 3.46-3.37 (m, 1H), 2.95 (dd, J = 18.0, 7.5Hz, 1H), 2.78 (dd, J = 18.0, 2.7Hz, 1H), 2.61 (dd, J = 18.0, 10.8Hz, 1H), 2.25 (dd, J = 18.0, 2.7Hz, 1H) 2.12 (s, 3H), 2.10 (s, 3H), 1.99 (s, 3H).
6-059;
δ7.65-7.50 (m, 2H), 7.27-7.20 (m, 2H), 7.16-7.08 (m, 2H), 3.86 (s, 3H), 3.72-3.31 (m, 9H), 3.13-2.83 (m , 3H), 2.39-2.15 (m, 7H), 1.90 (s, 3H).
6-060;
δ7.56-7.50 (m, 2H), 7.23 (s, 2H), 7.14-7.06 (m, 2H), 3.86 (s, 3H) 3.48-3.33 (m, 1H), 3.17-2.72 (m, 9H) , 2.39-2.18 (m, 7H), 1.91-1.87 (m, 3H).
6-061;
δ7.53-7.45 (m, 2H), 7.43-7.35 (m, 2H), 7.25-7.10 (m, 4H), 6.97-6.88 (m, 1H), 6.74-6.62 (m, 2H), 4.67and4. 64 (s, 2H), 3.84 (s, 3H), 3.75-3.65 and 3.34-2.06 (m, 11H), 1.87and1.86 (s, 3H).
6-062;
δ7.54-7.47 (m, 2H), 7.40-7.34 (m, 2H), 7.23 (brs, 2H), 3.85 (s, 3H), 3.70-3.27 (m, 9H), 3.12-3.01 (m, 1H ), 2.98-2.82 (m, 2H), 2.29 (dd, J = 15.3, 11.1Hz, 1H), 2.18 (s, 3H), 2.16 (s, 3H), 1.88 (s, 3H).
6-063;
δ7.54-7.47 (m, 2H), 7.40-7.34 (m, 2H), 7.23 (brs, 2H), 3.84 (s, 3H), 3.40 (dd, J = 18.6, 6.9Hz, 1H), 3.10- 2.80 (m, 9H), 2.28 (dd, J = 15.3, 11.1Hz, 1H), 2.18 (s, 3H), 2.17 (s, 3H), 1.88 (s, 3H).
6-064;
δ7.55-7.24 (m, 6H), 3.86 (s, 3H), 3.70-2.80 (m, 12H), 2.57-2.04 (m, 6H), 1.89 (s, 3H), 1.20-1.01 (m, 3H ).
6-067;
δ7.01 (brs, 2H), 6.31-6.10 (m, 2H), 3.84 (s, 3H), 3.71 (s, 3H), 2.95-2.80 (m, 3H), 2.60-2.50 (m, 1H), 2.24-2.05 (m, 9H), 1.86 (s, 3H), 1.50-1.40 (m, 2H), 0.97-0.85 (m, 3H).
6-070 (* 3);
δ8.50-7.82 (m, 2H), 7.38-7.10 (m, 2H), 6.65-6.25 (m, 2H), 5.05-4.75 (m, 2H), 3.93-3.80 (m, 3H), 3.45-1.82 (m, 14H).
6-075;
δ11.45 (brs, 1H), 6.90-6.82 (m, 2H), 3.89 (s, 3H), 3.69-3.33 and 3.05-1.85 (m, 17H).
6-077;
δ11.36 (brs, 1H), 7.59-7.34 (m, 4H), 7.09-6.87 (m, 2H), 4.00-3.78 (m, 6H), 3.54-3.32 (m, 1H), 3.09-2.50 and 2.38 -1.81 (m, 10H).
6-078;
δ7.58-7.34 (m, 4H), 7.03 (s, 1H), 6.90-6.86 (m, 1H), 3.92-3.22 (m, 15H), 3.09-2.68 (m, 3H), 2.40-2.13 (m , 4H), 1.88 (s, 3H).
6-079;
δ7.54-7.48 (m, 2H), 7.43-7.38 (m, 2H), 7.25-7.15 (m, 2H), 7.05-6.68 (m, 5H), 4.68 (s, 2H), 3.87 and 3.84 (s , 3H), 3.75 and 3.73 (s, 3H), 3.41-2.11 (m, 8H), 1.90-1.84 (m, 3H).
6-080;
δ7.54-7.48 (m, 2H), 7.41-7.35 (m, 2H), 7.22 (brs, 2H), 3.88-3.82 (m, 3H), 3.58-3.20 and 3.05-2.78 and 2.68-1.70 (m, 23H).
6-081;
δ7.58-7.32 (m, 4H), 7.02 (brs, 1H), 6.92-6.82 (m, 1H), 3.98-3.69 (m, 6H), 3.51-3.26 (m, 1H), 3.11-2.73 (m , 9H), 2.45-2.12 (m, 4H), 1.87 (s, 3H).
6-082;
δ7.66-7.12 (m, 6H), 4.04-3.79 (m, 3H), 3.39-2.79 (m, 4H), 2.43-1.82 (m, 10H), 1.38 (s, 9H).
6-083;
δ8.12-7.91 (m, 2H), 7.72-7.16 (m, 9H), 5.92-5.58 (m, 2H), 3.92-3.79 (m, 3H), 3.42-2.74 (m, 4H), 2.52-1.84 (m, 10H).
6-086;
δ7.53-7.48 (m, 2H), 7.40-7.36 (m, 2H), 7.22 (brs, 2H), 3.86 (s, 3H), 3.35-2.25 (m, 8H), 2.20-2.12 (m, 6H ), 1.99-1.96 (m, 3H), 1.88 (s, 3H), 1.18-1.12 (m, 3H).
6-089;
δ7.42-7.30 (m, 1H), 7.25-7.12 (m, 4H), 3.86 (s, 3H), 3.70-3.26 (m, 9H), 3.15-2.79 (m, 3H), 2.40-2.11 (m , 7H), 1.88 (s, 3H).
6-090;
δ7.51-7.45 (m, 1H), 7.32-7.19 (m, 2H), 7.09 (brs, 2H), 3.86 (s, 3H), 3.70-3.26 (m, 9H), 3.12-2.82 (m, 3H ), 2.36-2.23 (m, 1H), 2.17 (s, 3H), 2.14 (s, 3H), 1.89 (s, 3H).
6-091;
δ7.29-7.19 (m, 2H), 7.03-6.93 (m, 1H), 6.85-6.70 (m, 2H), 6.67 (brs, 1H), 6.54 (brs, 1H), 4.65 (s, 2H), 3.84 and 3.83 (s, 3H), 3.69-3.60 (m, 3H), 3.38-2.77 (m, 3H), 2.65-2.20 and 2.11-1.99 (m, 8H), 1.89-1.79 (m, 3H).
6-092;
δ7.50-7.47 (m, 1H), 7.31-6.92 (m, 7H), 6.80-6.67 (m, 2H), 4.69 (s, 2H), 3.85 (s, 3H), 3.37-2.78 (m, 4H ), 2.40-2.28 (m, 1H), 2.15-2.02 (m, 6H), 1.88 (s, 3H).
6-093;
δ7.65-7.57 (m, 1H), 7.48-7.38 (m, 1H), 7.25-7.15 (m, 3H), 3.86 (s, 3H), 3.70-3.30 (m, 9H), 3.11-2.82 (m , 3H), 2.35-2.24 (m, 1H), 2.18 (s, 3H), 2.16 (s, 3H), 2.05 (s, 3H).
6-094;
δ6.66 (brs, 1H), 6.57-6.52 (m, 1H), 3.85and3.84 (s, 3H), 3.73-3.27 (m, 13H), 3.09-2.77 (m, 3H), 2.39-2.20 ( m, 3H), 2.12-2.04 (m, 3H), 1.86 (s, 3H).
6-094 (* 2);
δ 6.70-6.63 (m, 1H), 6.57-6.50 (m, 1H), 3.89-3.81 (m, 3H), 3.74-3.25 (m, 12H), 3.08-2.77 (m, 3H), 2.38-2.16 (m, 4H), 2.12-2.03 (m, 3H), 1.94-1.84 (m, 3H).
6-095;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 3.86and3.84 (s, 3H), 3.75-3.65 (m, 3H), 3.41-3.18 (m, 1H), 3.11-2.02 (m, 16H), 1.86 (s, 3H).
6-097;
δ6.63 (brs, 2H), 4.13-4.05 (m, 2H), 3.85 (s, 3H), 3.75-3.68 (m, 5H), 3.43 (s, 3H), 2.97-2.82 (m, 3H), 2.62-2.50 (m, 1H), 2.25-2.13 (m, 1H), 2.09 (s, 3H)), 2.06 (s, 3H)), 1.88 (s, 3H).
6-100;
δ7.67-7.51 (m, 2H), 7.50-7.27 (m, 5H), 7.14-6.87 (m, 5H), 4.64 (s, 2H), 4.00-3.71 (m, 6H), 3.52-3.30 (m , 1H), 3, 07-1.85 (m, 10H).
6-101;
δ7.82 (s, 1H), 7.25 (s, 1H), 7.18 (s, 1H), 7.09 (brs, 2H), 3.87 (s, 3H), 3.85 (s, 3H), 3.10-2.55 (m, 4H), 2.30-2.15 (m, 7H), 1.90 (s, 3H).
6-105;
δ8.49-8.40 (m, 1H), 7.57-7.27 (m, 5H), 7.14 (brs, 1H), 3.76-3.65 (m, 3H), 2.80-1.70 (m, 14H).
6-108;
δ11.32 (brs, 1H), 6.69-6.47 (m, 2H), 4.00-3.71 (m, 6H), 3.49-3.31 (m, 1H), 3.00-2.62 (m, 3H), 2.41-2.13 (m , 4H), 1.97 (s, 3H).
6-109;
δ6.66 (brs, 1H), 6.60-6.50 (m, 1H), 3.97-3.81 (m, 3H), 3.79-3.66 (m, 3H), 3.49-3.22 (m, 1H), 3.10-2.68 (m , 9H), 2.44-2.19 (m, 4H), 2.18-2.02 (m, 3H), 1.98-1.80 (m, 3H).
6-110;
δ6.66 (m, 1H), 6.57-6.52 (m, 1H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.47-3.20 (m, 5H), 3.07-2.78 (m , 3H), 2.39-2.17 (m, 4H), 2.10 and 2.08 (s, 3H), 1.93-1.77 (m.7H).
6-111;
δ6.66 (m, 1H), 6.57-6.50 (m, 1H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.50-3.11 (m, 5H), 3.06-2.67 (m , 3H), 2.38-2.19 (m, 4H), 2.09 and 2.07 (s, 3H), 1.97-1.83 (m.3H), 1.67-1.38 (m, 6H).
6-113;
δ11.85-11.73 and 10.63-10.52 and 9.65-9.35 (m, 1H), 7.07-6.98 (m, 1H), 6.92-6.83 (m, 1H), 4.33-4.05 (m, 1H), 3.93-3.65 ( m, 6H), 3.57-1.82 (m, 9H), 1.38-0.98 (m, 3H).
6-114;
δ11.60-11.47 and 10.20-10.07 and 7.72-7.37 (m, 1H), 6.80-6.53 (m, 2H), 4.43-3.65 (m, 6H), 3.58-1.77 (m, 13H), 1.40-0.97 ( m, 3H).
6-115;
δ 6.70-6.45 (m, 2H), 3.88-3.77 (m, 3H), 3.70-3.60 (m, 3H), 3.48-2.62 (m, 8H), 2.37-2.13 (m, 4H), 2.11-1.99 (m, 3H), 1.94-1.78 (m, 3H), 1.13-0.82 (m, 6H).
6-116;
δ6.75-6.47 (m, 2H), 3.91-3.78 (m, 3H), 3.74-3.64 (m, 3H), 3.56-3.19 (m, 5H), 3.02-2.41 (m, 2H), 2.40-1.81 (m, 9H), 1.41-1.00 (m, 8H).
6-117;
δ6.71-6.48 (m, 2H), 3.93-3.62 (m, 6H), 3.31-2.70 (m, 3H), 2.42-1.81 (m, 11H), 1.21-1.05 (m, 9H).
6-118;
δ8.00-7.94 (m, 2H), 7.50-7.41 (m, 2H), 6.70-6.63 (m, 1H), 6.57-6.49 (m, 1H), 3.91-3.60 (m, 6H), 3.50-3.22 (m, 1H), 3.18-2.82 and 2.46-2.09 (m, 16H), 1.90-1.85 (m, 3H).
6-119;
δ7.43-7.28 (m, 3H), 6.97-6.87 (m, 2H), 6.68 (brs, 1H), 6.58 (brs, 1H), 3.89-3.82 (m, 3H), 3.75-3.67 (m, 3H ), 3.37-2.78 (m, 4H), 2.49-2.28 (m, 4H), 2.15-2.06 (m, 3H), 1.98-1.82 (m, 3H).
6-120;
δ6.71-6.38 (m, 3H), 6.19-5.90 (m, 2H), 3.91-3.79 (m, 3H), 3.73-3.60 (m, 3H), 3.40-3.21 (m, 1H), 3.10-2.75 and 2.70-2.20 (m, 7H), 2.17-2.00 (m, 3H), 1.97-1.80 (m, 3H).
6-121;
δ8.00-7.90 (m, 2H), 7.67-7.53 (m, 1H), 7.50-7.37 (m, 2H), 6.69-6.63 (m, 1H), 6.57-6.50 (m, 1H), 3.91-3.82 (m, 3H), 3.69-3.62 (m, 3H), 3.49-3.32 (m, 1H), 3.15-2.65 (m, 3H), 2.46-2.22 (m, 4H), 2.20-2.02 (m, 3H) , 1.97-1.80 (m, 3H).
6-122;
δ6.67 (brs, 1H), 6.55 (brs, 1H), 4.72-4.54 (m, 2H), 3.91-3.82 (m, 3H), 3.78-3.65 (m, 3H), 3.40-1.80 (m, 17H ).
6-123;
δ6.70-6.47 (m, 2H), 4.22-3.50 (m, 6H), 3.30-2.40 (m, 4H), 2.29 (s, 3H), 2.15-1.79 (m, 6H), 1.40-1.02 (m , 12H).
6-124;
δ6.72-6.50 (m, 2H), 3.96-3.63 (m, 6H), 3.38-2.68 and 2.42-1.25 (m, 23H).
6-125;
δ 6.79-6.53 (m, 2H), 4.00-3.62 (m, 6H), 3.30-2.65 and 2.40-1.81 (m, 20H).
6-126;
δ6.67 (brs, 1H), 6.56 (brs, 1H), 3.98-3.80 (m, 3H), 3.79-3.64 (m, 3H), 3.58-2.71 (m, 6H), 2.69-2.52 (m, 2H ), 2.42-2.20 (m, 4H), 2.19-1.80 (m, 8H).
6-127;
δ6.66 (brs, 1H), 6.54 (brs, 1H), 3.88-2.83 (m, 18H), 2.39-1.77 (m, 9H), 1.38-1.02 (m, 3H).
6-129;
δ6.92-6.85 (m, 1H), 6.77-6.59 (m, 1H), 3.90-3.80 (m, 3H), 3.72-3.60 (m, 3H), 3.30-2.15 (m, 5H), 2.13-1.97 (m, 6H), 1.95-1.80 (m, 3H), 1.15-1.05 (m, 9H).
6-130;
δ6.90-6.80 (m, 1H), 6.77-6.57 (m, 1H), 3.87-3.60 (m, 9H), 3.38-2.70 (m, 4H), 2.40-2.20 (m, 1H), 2.10-1.97 (m, 6H), 1.90-1.78 (m, 3H).
6-131;
δ7.95-7.85 (m, 2H), 7.65-7.55 (m, 1H), 7.48-7.38 (m, 2H), 6.90 (brs, 1H), 6.75-6.70 (m, 1H), 3.85 and 3.84 (s , 3H), 3.65 and 3.63 (s, 3H), 3.51-3.35 (m, 1H), 3.15-2.80 (m, 3H), 2.45-2.28 (m, 1H), 2.13 and 2.11 (s, 3H), 2.06 -2.00 (m, 3H), 1.88 (s, 3H).
6-132;
δ6.90 (brs, 1H), 6.80-6.70 (m, 1H), 3.85 and 3.84 (s, 3H), 3.73-3.25 (m, 12H), 3.10-2.70 (m, 3H), 2.40-2.20 (m , 1H), 2.15-2.00 (m, 6H), 1.86 (s, 3H).
6-133;
δ6.89 (brs, 1H), 6.78-6.60 (m, 1H), 3.84 and 3.83 (s, 3H), 3.69 and 3.68 (s, 3H), 3.48-3.15 (m, 5H), 3.05-2.75 (m , 3H), 2.37-1.80 (m, 14H).
6-134;
δ6.90 (brs, 1H), 6.77 (brs, 1H), 3.85 and 3.84 (s, 3H), 3.72 and 3.71 (s, 3H), 3.40-3.22 (m, 1H), 3.15-2.75 (m, 6H ), 2.43-2.25 (m, 1H), 2.09 and 2.08 (s, 3H), 2.05 (s, 3H), 1.85 (s, 3H).
6-135;
δ6.90 (brs, 1H), 6.76 (brs, 1H), 3.85 and 3.84 (s, 3H), 3.71 and 3.69 (s, 3H), 3.43-3.25 (m, 1H), 3.13-2.55 (m, 9H ), 2.43-2.20 (m, 1H), 2.09 and 2.08 (s, 3H), 2.05 (s, 3H), 1.85 (s, 3H).
6-136;
δ7.30-6.70 (m, 7H), 4.65 (s, 2H), 3.84 and 3.83 (s, 3H), 3.66 and 3.65 (s, 3H), 3.38-2.75 (m, 4H), 2.42-2.15 (m , 1H), 2.10-2.00 (m, 6H), 1.90-1.80 (m, 3H).
6-138;
δ6.66 (brs, 1H), 6.53 (brs, 1H), 3.85and3.84 (s, 3H), 3.73-3.64 (m, 3H), 3.50-3.20 (m, 1H), 3.09-2.73 (m, 4H), 2.38-2.15 (m, 9H), 2.11-2.05 (m, 3H), 1.91-1.83 (m, 3H), 1.66-1.55 (m, 3H), 1.18-1.00 (m, 3H).
6-139;
δ6.66 (brs, 1H), 6.57-6.50 (m, 1H), 4.00-3.61 (m, 9H), 3.51-3.20 (m, 1H), 3.08-2.62 and 2.50-
2.20 (m, 10H), 2.09 and 2.07 (s, 3H), 1.86 (s, 3H), 1.12-0.73 (m, 6H).
6-140;
δ6.66 (brs, 1H), 6.53 (brs, 1H), 4.03-3.20 and 3.12-2.68 and 2.60-2.23 (m, 20H), 2.20-2.04
(m, 3H), 1.98-1.82 (m, 3H), 1.21-0.98 (m, 6H).
6-142;
δ6.90 (brs, 2H), 3.85 (s, 3H), 3.70-3.60 (m, 2H), 3.57-3.22 (m, 7H), 3.09-2.98 (m, 1H), 2.97-2.82 (m, 2H ), 2.49-2.15 (m, 8H), 1.87 (s, 3H), 1.13-1.02 (m, 6H).
6-143;
δ6.90 (brs, 2H), 3.85 (s, 3H), 3.59-3.42 (m, 3H), 3.25-3.15 (m, 2H), 3.06-2.80 (m, 3H), 2.53-2.17 (m, 8H ), 1.90-1.75 (m, 7H), 1.13-1.02 (m, 6H).
6-144;
δ6.92 (brs, 2H), 3.85 (s, 3H), 3.42-3.30 (m, 1H), 3.14-2.80 (m, 6H), 2.45-2.20 (m, 8H), 1.86 (m, 3H), 1.18-1.02 (m, 6H).
6-145;
δ6.90 (brs, 2H), 3.85 (s, 3H), 3.42-3.30 (m, 1H), 3.13-2.82 (m, 3H), 2.74 (s, 6H), 2.50-2.20 (m, 8H), 1.87 (s, 3H), 1.12-1.02 (m, 6H).
6-146;
δ7.28-7.17 (m, 2H), 7.02-6.94 (m, 1H), 6.91 (brs, 2H), 6.75-6.52 (m, 2H), 4.64 and 4.62 (s, 2H), 3.84 (s, 3H ), 3.35-3.25 (m, 1H), 3.12-3.02 (m, 1H), 3.00-2.82 (m, 2H), 2.62-2.20 (m, 8H), 1.86 and 1.85 (s, 3H), 1.12-1.02 (m, 6H).
6-147;
δ6.91 (brs, 2H), 3.85 (s, 3H), 3.78 (s, 3H), 3.40-3.27 (m, 1H), 3.12-3.00 (m, 1H), 2.98-2.70 (m, 2H), 2.45-2.20 (m, 8H), 1.87 (s, 3H), 1.13-1.00 (m, 6H).
6-148;
δ7.95-7.87 (m, 2H), 7.65-7.55 (m, 1H), 7.48-7.38 (m, 2H), 6.95-6.86 (m, 2H), 3.85 and 3.77 (s, 3H), 3.50-3.39 (m, 1H), 3.15-2.85 (m, 3H), 2.80-2.20 (m, 8H), 1.89 and 1.84 (s, 3H), 1.20-1.02 (m, 6H).
6-149;
δ7.57-7.52 (m, 2H), 7.43-7.38 (m, 2H), 7.16 (brs, 2H), 7.10 (m, 2H), 6.98-6.93 (m, 2H), 3.85 (s, 3H), 3.18-3.00 (m, 2H), 2.87-2.72 (m, 2H), 2.32-2.23 (m, 1H), 2.00 (s, 3H), 1.97 (s, 3H), 1.87 (s, 3H), 1.49 ( s, 3H), 1.48 (s, 3H).
6-150;
δ7.61-7.56 (m, 2H), 7.50-7.46 (m, 2H), 7.41-7.37 (m, 2H), 7.20-7.17 (m, 2H), 7.13 (brs, 2H), 3.86 (s, 3H ), 3.35-3.27 (m, 1H), 3.08-2.93 (m, 2H), 2.84-2.78 (m, 1H), 2.36 (s, 3H), 2.34-2.25 (m, 1H), 2.04 (s, 3H ), 2.03 (s, 3H), 1.87 (s, 3H).
6-151;
δ7.54-7.49 (m, 2H), 7.42-7.38 (m, 2H), 7.19-7.12 (m, 5H), 6.87-6.83 (m, 2H), 3.84 (s, 3H), 3.28-3.20 (m , 1H), 3.05-2.97 (m, 1H), 2.87-2.80 (m, 2H), 2.30-2.21 (m, 1H), 2.13 (s, 3H), 1.96 (s, 3H) 1.89 (s, 3H) , 1.86 (s, 3H), 1.66 (s, 3H).
6-152;
δ6.88 (brs, 2H), 3.87-3.82 (m, 3H), 3.32-3.15 (m, 1H), 3.10-2.70 (m, 3H), 2.65-2.20 (m, 8H), 1.94 and 1.87 (s , 3H), 1.15-1.00 (m, 15H).
6-153;
δ7.25-7.12 (m, 5H), 6.62-6.42 (m, 2H), 3.87-3.80 (m, 3H), 3.60-3.52 (m, 3H), 3.21-2.62 (m, 4H), 2.38-2.17 (m, 4H), 2.00-1.83 (m.6H), 1.53-1.43 (m, 6H).
6-154;
δ10.74 (s, 1H), 6.78-6.50 (m, 2H), 4.15-1.80 (m, 19H), 1.38-1.20 (m, 3H).
6-155;
δ7.19-7.10 (m, 2H), 6.99-6.76 (m, 2H), 6.69 (brs, 1H), 6.56 (brs, 1H), 3.88-3.77 (m, 3H), 3.76-3.66 (m, 3H ), 3.43-3.21 (m, 1H), 3.13-2.70 (m, 3H), 2.60-2.23 (m, 1H), 2.34 (s, 3H), 2.33 (s, 3H), 2.11 and 2.10 (s, 3H ), 1.93-1.82 (m, 3H).
6-156;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 4.13 (t, J = 6.8Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.37-3.16 ( m, 1H), 3.09-2.63 (m, 3H), 2.40-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.67- 1.52 (m, 3H), 1.39-1.20 (m, 5H), 0.93-0.81 (m, 3H).
6-157;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 4.13 (t, J = 6.8Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.37-3.16 ( m, 1H), 3.09-2.64 (m, 3H), 2.40-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.70- 1.50 (m, 3H), 1.43-1.13 (m, 9H), 0.93-0.81 (m, 3H).
6-158;
δ6.67 (brs, 1H), 6.56 (brs, 1H), 4.37 (t, J = 5.7Hz, 2H), 3.85 and 3.84 (s, 3H), 3.71 and 3.69 (s, 3H), 3.67-3.60 ( m, 2H), 3.39-2.60 (m, 4H), 2.42-2.22 (m, 1H), 2.31 (s, 3H), 2.08 and 2.07 (s, 3H), 1.94-1.82 (m, 3H).
6-159;
δ6.67 (brs, 1H), 6.56 (brs, 1H), 4.30 (t, J = 6.0Hz, 2H), 3.85 and 3.83 (s, 3H), 3.71 and 3.69 (s, 3H), 3.56 (t, J = 6.3Hz, 2H), 3.38-3.13 (m, 1H), 3.10-2.78 (m, 3H), 2.41-2.22 (m, 1H), 2.31 (s, 3H), 2.13-2.02 (m, 5H) , 1.94-1.82 (m, 3H).
6-160;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 4.13 (t, J = 6.6Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.38-3.17 ( m, 1H), 3.10-2.76 (m, 3H), 2.40-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.68- 1.52 (m, 2H), 1.42-1.22 (m, 2H), 0.91 (t, J = 7.2Hz, 3H).
6-161;
δ7.37-7.29 (m, 2H), 7.05-6.82 (m, 2H), 6.69 (brs, 1H), 6.58 (brs, 1H), 3.84 and 3.83 (s, 3H), 3.72 and 3.70 (s, 3H ), 3.43-3.15 (m, 1H), 3.12-2.70 (m, 3H), 2.60-2.23 (m, 1H), 2.33 (s, 3H), 2.11 and 2.09 (s, 3H), 1.93-1.82 (m , 3H).
6-162;
δ7.50-7.41 (m, 1H), 7.33-7.09 (m, 3H), 6.69 (brs, 1H), 6.58 (brs, 1H), 3.84 and 3.83 (s, 3H), 3.73 and 3.72 (s, 3H ), 3.43-3.22 (m, 1H), 3.12-2.78 (m, 3H), 2.46-2.25 (m, 1H), 2.33 (s, 3H), 2.11 and 2.10 (s, 3H), 1.93-1.84 (m , 3H).
6-163;
δ6.67 (brs, 1H), 6.56 (brs, 1H), 4.29-4.10 (m, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.69 (s, 3H), 3.61-3.46 (m, 2H ), 3.37-3.14 (m, 1H), 3.10-2.65 (m, 3H), 2.42-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.99-1.67 (m , 7H).
6-164;
δ6.66 (brs, 1H), 6.58-6.51 (m, 1H), 4.11-3.97 (m, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.37-3.11 (m , 1H), 3.10-2.64 (m, 3H), 2.41-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.62-1.48 and 1.40-1.15 (m, 9H), 0.95-0.80 (m, 6H).
6-165;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 4.20 (q, J = 7.2Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.69 (s, 3H), 3.37-3.11 ( m, 1H), 3.08-2.62 (m, 3H), 2.42-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.28 ( t, J = 7.2Hz, 3H).
6-166;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 3.92 (d, J = 6.6Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.37-3.17 ( m, 1H), 3.09-2.77 (m, 3H), 2.42-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 2.01-1.83 (m, 1H), 1.86 ( s, 3H), 0.93 (s, 3H), 0.91 (s, 3H).
6-167;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 4.10 (t, J = 6.9Hz, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.38-3.11 ( m, 1H), 3.08-2.62 (m, 3H), 2.42-2.20 (m, 1H), 2.31 (s, 3H), 2.08 and 2.06 (s, 3H), 1.94-1.82 (m, 3H), 1.72- 1.60 (m, 2H), 0.93 (t, J = 7.5Hz, 3H).
6-168;
δ6.67 (brs, 1H), 6.60-6.50 (m, 1H), 5.13-5.00 and 4.88-4.80 (m, 2H), 3.86 and 3.85 (s, 3H), 3.71 and 3.69 (s, 3H), 3.48 -3.35 (m, 3H), 3.11-2.56 (m, 4H), 2.41-2.13 (m, 1H), 2.31 (s, 3H), 2.13-2.03 (m, 3H), 1.87 (s, 3H).
6-169;
δ6.66 (brs, 1H), 6.60-6.43 (m, 1H), 5.30-4.70 (m, 2H), 3.95-3.28 (m, 14H), 3.17-2.53 (m, 3H), 2.50-2.22 (m , 1H), 2.30 (s, 3H), 2.08 and 2.05 (s, 3H), 1.86 (s, 3H).
6-170;
δ6.66 (brs, 1H), 6.57-6.49 (m, 1H), 5.21-5.12 (m, 1H), 5.00-4.90 (m, 1H), 3.88-3.82 (m, 3H), 3.73-3.65 (m , 3H), 3.63-3.40 (m, 1H), 3.31-2.60 and 2.45-2.12 (m, 5H), 2.30 (s, 3H), 2.08 and 2.05 (s, 3H), 1.93-1.12 (m, 13H) .
6-171;
δ 6.70-6.63 (m, 1H), 6.58-6.50 (m, 1H), 5.18-5.06 (m, 1H), 4.92-4.84 (m, 1H), 3.90-3.82 (m, 3H), 3.75-3.52 (m, 5H), 3.31-3.18 and 3.11-2.57 and 2.43-2.13 (m, 5H), 2.32 (s, 3H), 2.10-2.03 (m, 3H), 1.92-1.84 (m, 3H), 1.29- 1.13 (m, 3H).
6-172;
δ 6.70-6.47 (m, 2H), 3.90-3.65 (m, 6H), 3.52-1.80 (m, 16H), 1.40-1.18 (m, 3H).
6-173;
δ7.29-7.10 (m, 3H), 7.03-6.95 (m, 1H), 6.63 (brs, 1H), 6.50 (brs, 1H), 3.83 and 3.82 (s, 3H), 3.62 (s, 2H), 3.59 and 3.58 (s, 3H), 3.30-2.72 (m, 4H), 2.40-2.20 (m, 4H), 2.00 and 1.97 (s, 3H), 1.85 and 1.84 (s, 3H).
6-174;
δ7.37-7.32 (m, 1H), 7.28-7.10 (m, 3H), 6.63 (brs, 1H), 6.53-6.48 (m, 1H), 3.83 and 3.82 (s, 3H), 3.81 (s, 2H ), 3.64 and 3.62 (s, 3H), 3.35-3.15 (m, 1H), 3.08-2.75 (m, 3H), 2.38-2.20 (m, 4H), 2.00 and 1.98 (s, 3H), 1.84 (s , 3H).
6-175;
δ7.20-7.13 (m, 2H), 7.05-6.96 (m, 2H), 6.63-6.57 (m, 1H), 6.48-6.39 (m, 1H), 3.87-3.80 (m, 3H), 3.78-3.67 (m, 1H), 3.57-3.48 (m, 3H), 3.28-2.63 (m, 4H), 2.38-2.18 (m, 4H), 1.98-1.88 (m, 3H), 1.85-1.82 (m, 3H) , 1.47-1.39 (m, 3H).
6-176;
δ7.30-7.20 (m, 3H), 7.17-7.05 (m, 2H), 6.65-6.58 (m, 1H), 6.50-6.41 (m, 1H), 3.87-3.68 (m, 4H), 3.60-3.59 (m, 3H), 3.32-2.60 (m, 4H), 2.38-2.15 (m, 4H), 1.98-1.89 (m, 3H), 1.88-1.81 (m, 3H), 1.45 and 1.42 (s, 3H) .
6-177;
δ7.23-7.15 (m, 2H), 7.05-6.97 (m, 2H), 6.65-6.57 (m, 1H), 6.50-6.42 (m, 1H), 3.86-3.80 (m, 3H), 3.65-3.50 (m, 5H), 3.30-2.13 (m, 8H), 2.05-1.80 (m, 6H).
6-178;
δ7.08-7.00 (m, 2H), 6.82-6.75 (m, 2H), 6.64 (brs, 1H), 6.51 (brs, 1H), 3.83 and 3.82 (s, 3H), 3.79 (s, 3H), 3.62-3.57 (m, 5H), 3.31-3.10 (m, 1H), 3.05-2.72 (m, 3H), 2.38-2.20 (m, 4H), 2.00 and 1.98 (s, 3H), 1.85-1.82 (m , 3H).
6-179;
δ7.53-7.45 (m, 2H), 7.30-7.28 (m, 2H), 6.66-6.58 (m, 1H), 6.50-6.40 (m, 1H), 3.87-3.80 (m, 3H), 3.75-3.68 (m, 2H), 3.63-3.48 (m, 3H), 3.33-2.18 (m, 8H), 2.15-1.80 (m, 6H).
6-180;
δ7.22-7.02 (m, 4H), 6.61 (brs, 1H), 6.50-6.47 (m, 1H), 3.83 and 3.82 (s, 3H), 3.65 (s, 2H), 3.57 and 3.55 (s, 3H ), 3.30-3.10 (m, 1H), 3.05-2.92 (m, 1H), 2.90-2.72 (m, 2H), 2.38-2.15 (m, 4H), 2.09 (s, 3H), 1.96 and 1.93 (s , 3H), 1.86-1.82 (m, 3H).
6-181;
δ7.18-7.05 (m, 4H), 6.68-6.58 (m, 1H), 6.53-6.40 (m, 1H), 3.90-3.80 (m, 3H), 3.70-3.49 (m, 5H), 3.32-2.15 (m, 8H), 2.07-1.80 (m, 6H).
6-182;
δ7.17-7.10 (m, 2H), 7.16-6.98 (m, 2H), 6.65-6.58 (m, 1H), 6.52-6.44 (m, 1H), 3.85-3.80 (m, 3H), 3.65-3.52 (m, 5H), 3.30-2.65 (m, 4H), 2.47 (s, 3H), 2.40-2.10 (m, 4H), 2.05-1.78 (m, 6H).
6-183;
δ6.89-6.86 and 6.82-6.76 and 6.62-6.57 and 6.50-6.42 (m, 4H), 3.90-3.80 (m, 3H), 3.70-3.62 (m, 2H), 3.60-3.52 (m, 3H), 3.30-2.60 (m, 4H), 2.35-2.15 (m, 7H), 2.12-2.06 (m, 6H), 1.96-1.82 (m, 6H).
6-184;
δ7.20-7.10 (m, 2H), 7.00-6.93 (m, 1H), 6.75-6.60 (m, 3H), 6.42-6.36 (m, 1H), 3.88-3.80 (m, 3H), 3.67-3.60 (m, 3H), 3.25-2.95 (m, 2H), 2.88-2.57 (m, 2H), 2.41-2.23 (m, 4H), 2.10-2.00 (m, 3H), 1.88-1.82 (m, 3H) , 1.55-1.45 (m, 6H).
6-185;
δ7.30-7.15 (m, 3H), 7.02-6.93 (m, 1H), 6.80-6.60 (m, 2H), 6.55-6.45 (m, 1H), 4.82-4.68 (m, 1H), 3.90-3.80 (m, 3H), 3.75-3.55 (m, 3H), 3.30-2.65 (m, 4H), 2.40-2.20 (m, 4H), 2.10-1.97 (m, 3H), 1.95-1.80 (m, 3H) , 1.65-1.45 (m, 3H).
6-186;
δ7.20-7.13 (m, 2H), 6.72-6.65 (m, 3H), 6.54 (brs, 1H), 4.62 (s, 2H), 3.84 and 3.83 (s, 3H), 3.66 and 3.64 (s, 3H ), 3.35-2.77 (m, 4H), 2.40-2.17 (m, 4H), 2.05 and 2.03 (s, 3H), 1.86 and 1.85 (s, 3H).
6-187;
δ6.80-6.52 (m, 6H), 4.59 (s, 2H), 3.84 and 3.83 (s, 3H), 3.76 (s, 3H), 3.66 and 3.65 (s, 3H), 3.38-3.13 (m, 1H ), 3.10-2.75 (m, 3H), 2.42-2.22 (m, 4H), 2.06 and 2.04 (s, 3H), 1.86 and 1.85 (s, 3H).
6-188;
δ7.52-7.40 (m, 2H), 6.82-6.52 (m, 4H), 4.72-4.63 (m, 2H), 3.85-3.80 (m, 3H), 3.68-3.62 (m, 3H), 3.35-2.20 (m, 8H), 2.07-2.00 (m, 3H), 1.87-1.82 (m, 3H).
6-189;
δ7.12-7.00 (m, 2H), 6.78-6.50 (m, 4H), 4.65-4.60 (m, 2H), 3.84 and 3.83 (s, 3H), 3.66 and 3.64 (s, 3H), 3.35-3.13 (m, 1H), 3.12-2.75 (m, 3H), 2.65-2.20 (m, 4H), 2.10-2.00 (m, 3H), 1.95-1.80 (m, 3H).
6-190;
δ7.37-7.20 (m, 2H), 7.05-6.93 (m, 2H), 6.66 (brs, 1H), 6.55 (brs, 1H), 4.68 (s, 2H), 3.84 and 3.83 (s, 3H), 3.68 and 3.66 (s, 3H), 3.38-3.13 (m, 1H), 3.11-2.75 (m, 3H), 2.40-2.15 (m, 4H), 2.05 and 2.03 (s, 3H), 1.86 and 1.85 (s , 3H).
6-191;
δ7.37-7.30 (m, 1H), 7.05-6.98 (m, 1H), 6.64 (brs, 1H), 6.55-6.48 (m, 2H), 4.70 (s, 2H), 3.84 and 3.83 (s, 3H ), 3.65 and 3.64 (s, 3H), 3.36-3.13 (m, 1H), 3.11-2.75 (m, 3H), 2.40-2.25 (m, 4H), 2.03 and 2.01 (s, 3H), 1.86 and 1.85 (s, 3H).
6-192;
δ7.17-7.08 (m, 2H), 6.68-6.59 (m, 3H), 6.56-6.46 (m, 1H), 4.74-4.62 (m, 1H), 3.87-3.81 (m, 3H), 3.67 and 3.66 and 3.58 and 3.56 (s, 3H), 3.29-2.95 (m, 2H), 2.90-2.66 (m, 2H), 2.38-2.20 (m, 1H), 2.33 (s, 3H), 2.05-1.96 (m, 3H), 1.85 and 1.84 (s, 3H), 1.60-1.49 (m, 3H).
6-193;
δ7.43-7.20 (m, 3H), 7.12-7.02 (m, 2H), 6.69 (brs, 1H), 6.58 (brs, 1H), 3.84 and 3.83 (s, 3H), 3.72 and 3.71 (s, 3H ), 3.45-3.20 (m, 1H), 3.13-2.70 (m, 3H), 2.45-2.25 (m, 4H), 2.11 and 2.10 (s, 3H), 1.86 and 1.85 (s, 3H).
6-195;
δ6.65 (brs, 1H), 6.55-6.49 (m, 1H), 3.85 and 3.84 (s, 3H), 3.69 and 3.67 (s, 3H), 3.44-3.21 (m, 6H), 3.07-2.78 (m , 3H), 2.39-2.19 (m, 1H), 2.30 (s, 3H), 2.09 and 2.07 (s, 3H), 1.86 (s, 3H), 1.79-1.56 (m, 7H).
6-196;
δ7.39-7.21 (m, 5H), 6.70-6.47 (m, 2H), 5.25-5.12 (m, 1H), 5.00-4.93 (m, 1H), 4.72-4.56 (m, 2H), 3.89-3.81 (m, 3H), 3.72-3.63 (m, 3H), 3.28-2.58 and 2.43-2.13 (m, 8H), 2.11- 2.01 (m, 3H), 1.98-1.84 (m, 3H).
6-197;
δ7.85-7.82 (m, 1H), 7.77-7.65 (m, 2H), 7.57-7.49 (m, 1H), 6.46 (s, 1H), 6.29 (s, 1H), 3.85 and 3.84 (s, 3H ), 3.58-3.56 (m, 3H), 3.33-2.76 (m, 4H), 2.47-2.29 (m, 1H), 2.22 (s, 3H), 1.98 and 1.97 (s, 3H), 1.86 and 1.85 (s , 3H).
6-198;
δ7.99-7.97 (m, 1H), 7.75-7.65 (m, 2H), 7.59-7.53 (m, 1H), 6.47 (s, 1H), 6.28 (s, 1H), 3.86 and 3.84 (s, 3H ), 3.56 and 3.53 (s, 3H), 3.31-3.16 (m, 1H), 3.07-2.73 (m, 3H), 2.38-2.18 (m, 4H), 1.93 and 1.92 (s, 3H), 1.85 and 1.84 (s, 3H).
6-199;
δ7.60-7.56 (m, 2H), 7.32-7.27 (m, 2H), 6.54 (s, 1H), 6.38 (s, 1H), 3.87 and 3.84 (s, 3H), 3.58 and 3.56 (s, 3H ), 3.30-2.71 (m, 4H), 2.38-2.22 (m, 4H), 1.94 and 1.93 (s, 3H), 1.84 and 1.83 (s, 3H).
6-200;
δ7.61 (d, J = 8.7Hz, 2H), 7.20 (d, J = 8.7Hz, 2H), 6.55 (s, 1H), 6.42 (s, 1H), 3.86 and 3.84 (s, 3H), 3.61 and 3.58 (s, 3H), 3.26-2.17 (m, 1H), 2.94-2.74 (m, 3H), 2.42-2.17 (m, 7H), 1.94 and 1.92 (s, 3H), 1.84 and 1.83 (s, 3H).
6-201;
δ6.65 (s, 1H), 6.54 (m, 1H), 3.85-3.83 (m, 3H), 3.70 and 3.69 (s, 3H), 3.33-3.26 (m, 4H), 3.16-2.79 (m, 4H ), 2.39-2.24 (m 4H), 2.08 and 2.07 (s, 3H), 1.93-1.86 (m, 7H).
6-202;
δ6.66 (s, 1H), 6.55 (s, 1H), 3.86-3.84 (m, 3H), 3.71 and 3.70 (s, 3H), 3.65-3.57 (m, 4H), 3.38-2.79 (m, 8H ), 2.40-2.28 (m, 4H), 2.07 and 2.06 (s, 3H), 1.86 (s, 3H).
6-203;
δ7.21-7.15 (m, 1H), 6.99-6.97 (m, 2H), 6.63 (s, 1H), 6.51 (s, 1H), 3.87-3.82 (m, 3H), 3.68-3.63 (m, 3H ), 3.41-2.74 (m, 4H), 2.63-2.34 (m, 1H), 2.29 (s, 3H), 2.17 (s, 3H), 2.13-2.06 (m, 6H), 1.97-1.88 (m, 3H ).
6-204;
δ6.87 (s, 1H), 6.80 (s, 1H), 6.62 (s, 1H), 6.51 (s, 1H), 3.88-2.82 (m, 3H), 3.68-3.63 (m, 3H), 3.49- 3.28 (m, 4H), 2.63-2.33 (m, 4H), 2.29-2.25 (m, 6H), 2.18 (s, 3H), 2.12-2.04 (m, 3H), 1.96-1.88 (m, 3H).
6-205;
δ7.31-7.26 (m, 1H), 6.63 (s, 1H), 6.53-6.48 (m, 3H), 3.86-3.81 (m, 3H), 3.74-3.66 (m, 9H), 3.41-2.81 (m , 4H), 2.63-2.28 (m, 4H), 2.18-2.04 (m, 3H), 1.96-1.87 (m, 3H).
6-206;
δ7.28-7.23 (m, 3H), 6.63 (s, 1H), 6.52 (s, 1H), 3.87 and 3.84 (s, 3H), 3.69 and 3.65 (s, 3H), 3.43-3.30 (m, 1H ), 3.14-2.84 (m, 3H), 2.57-2.32 (m, 1H), 2.29 (s, 3H), 2.11 and 2.09 (s, 3H), 1.89 (s, 3H).
6-207;
δ6.63 (s, 1H), 6.52 (s, 1H), 3.85 and 3.84 (s, 3H), 3.68 and 3.67 (s, 3H), 3.49 (s, 2H), 3.30-3.13 (m, 1H), 3.08-2.97 (m, 1H), 2.90-2.63 (m, 2H), 2.38-2.24 (m, 4H), 2.09-2.02 (m, 3H), 1.93-1.86 (m, 3H), 1.20 and 1.19 (s , 6H).
6-208;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 5.62-5.30 (m, 2H), 3.89-3.76 (m, 3H), 3.75-3.60 (m, 3H), 3.30-2.50 and 2.42-1.97 (m, 11H), 1.95-1.79 (m, 3H), 1.21 (s, 3H), 1.20 (s, 3H), 1.16 (s, 3H).
6-214;
δ7.70-7.62 (m, 1H), 7.30-7.24 (m, 1H), 7.08-7.00 (m, 1H), 6.55-6.50 (m, 1H), 6.40-6.33 (m, 1H), 3.90-3.82 (m, 3H), 3.72-3.52 (m, 3H), 3.30-3.15 (m, 1H), 3.05-2.60 (m, 3H), 2.40-2.17 (m, 10H), 1.95-1.80 (m, 6H) .
6-220;
δ7.58-7.26 (m, 4H), 6.58-6.52 (m, 1H), 6.46-6.40 (m, 1H), 3.85 and 3.84 (s, 3H), 3.60 and 3.57 (s, 3H), 3.31-3.15 (m, 1H), 3.08-2.70 (m, 3H), 2.40-2.20 (m, 7H), 1.93 and 1.91 (s, 3H), 1.84 and 1.83 (s, 3H).
6-224;
δ7.80-7.53 (m, 4H), 6.65 (brs, 1H), 6.53 (brs, 1H), 3.85 and 3.84 (s, 3H), 3.67 and 3.65 (s, 3H), 3.48-3.27 (m, 1H ), 3.17-2.82 (m, 3H), 2.46-2.32 (m, 1H), 2.29 (s, 3H), 2.10 and 2.08 (s, 3H), 1.89 and 1.88 (s, 3H).
6-225;
δ7.54 (brs, 2H), 7.20 (brs, 1H), 6.66 (brs, 1H), 6.55-6.51 (m, 1H), 3.84 and 3.83 (s, 3H), 3.67 and 3.66 (s, 3H), 3.43-3.32 (m, 1H), 3.12-2.82 (m, 3H), 2.42-2.28 (m, 10H), 2.13 and 2.11 (s, 3H), 1.88 (s, 3H).
6-226;
δ7.70-7.55 (m, 2H), 7.32-7.19 (m, 1H), 6.65 (brs, 1H), 6.52 (brs, 1H), 3.85 and 3.84 (s, 3H), 3.67 and 3.65 (s, 3H ), 3.48-3.27 (m, 1H), 3.17-2.80 (m, 3H), 2.45-2.28 (m, 4H), 2.11 and 2.09 (s, 3H), 1.89 and 1.88 (s, 3H).
6-227;
δ7.82-7.77 (m, 2H), 7.60-7.55 (m, 1H), 6.67 (brs, 1H), 6.56-6.50 (m, 1H), 3.85 and 3.84 (s, 3H), 3.68 and 3.67 (s , 3H), 3.41-3.28 (m, 1H), 3.15-2.80 (m, 3H), 2.45-2.28 (m, 4H), 2.12 and 2.10 (s, 3H), 1.88 and 1.87 (s, 3H).
6-228;
δ8.01 (d, J = 1.5Hz, 1H), 7.74 (dd, J = 8.1Hz, 1.5Hz, 1H), 7.51 (d, J = 8.1Hz, 1H), 6.67 (brs, 1H), 6.56- 6.51 (m, 1H), 3.85 and 3.84 (s, 3H), 3.66 and 3.65 (s, 3H), 3.44-3.31 (m, 1H), 3.15-2.80 (m, 3H), 2.43-2.28 (m, 4H ), 2.12 and 2.10 (s, 3H), 1.88 and 1.87 (s, 3H).
6-229;
δ7.31 (s, 2H), 6.62 (brs, 1H), 6.54-6.48 (m, 1H), 3.86 and 3.85 (s, 3H), 3.68 and 3.66 (s, 3H), 3.43-3.27 (m, 1H ), 3.20-2.80 (m, 3H), 2.48-2.28 (m, 4H), 2.09 and 2.07 (s, 3H), 1.88 (s, 3H).
6-230;
δ8.00-7.90 (m, 2H), 7.15-7.05 (m, 2H), 6.66 (brs, 1H), 6.55-6.48 (m, 1H), 3.85 and 3.84 (s, 3H), 3.65 and 3.63 (s , 3H), 3.48-3.32 (m, 1H), 3.13-2.80 (m, 3H), 2.43-2.28 (m, 4H), 2.12 and 2.10 (s, 3H), 1.88 (s, 3H).
6-231;
δ7.08-7.03 (m, 2H), 6.67-6.62 (m, 2H), 6.55-6.50 (m, 1H), 3.85 and 3.84 (s, 3H), 3.75 (s, 6H), 3.66 and 3.65 (s , 3H), 3.52-3.32 (m, 1H), 3.13-2.80 (m, 3H), 2.45-2.25 (m, 4H), 2.13 and 2.11 (s, 3H), 1.88 (s, 3H).
6-232;
δ7.85-7.78 (m, 1H), 7.48-7.38 (m, 1H), 7.31-7.16 (m, 2H), 6.65 (brs, 1H), 6.55-6.50 (m, 1H), 3.85 and 3.84 (s , 3H), 3.66 and 3.64 (s, 3H), 3.45-3.32 (m, 1H), 3.15-2.82 (m, 3H), 2.49 (s, 3H), 2.45-2.27 (m, 4H), 2.12 and 2.10 (s, 3H), 1.88 (s, 3H).
6-232 (* 2);
δ7.90-7.78 (m, 1H), 7.50-7.37 (m, 1H), 7.32-7.15 (m, 2H), 6.70-6.42 (m, 2H), 3.90-3.52 (m, 6H), 3.42-1.82 (m, 17H).
6-233;
δ7.75-7.65 (m, 2H), 7.40-7.28 (m, 2H), 6.66 (brs, 1H), 6.55-6.51 (m, 1H), 3.85 and 3.84 (s, 3H), 3.68 and 3.66 (s , 3H), 3.50-3.30 (m, 1H), 3.15-2.82 (m, 3H), 2.45-2.27 (m, 4H), 2.12 and 2.10 (s, 3H), 1.89 and 1.88 (s, 3H).
6-234;
δ6.63 (s, 1H), 6.51 (s, 1H), 3.85 and 3.84 (s, 3H), 3.68 and 3.67 (s, 3H), 3.26-2.71 (m, 4H), 2.39-2.23 (m, 4H ), 2.06 and 2.05 (s, 3H), 1.86 (s, 3H), 1.55-1.25 (m, 4H), 1.17 and 1.09 (s, 6H), 0.76-0.71 (m, 3H).
6-235;
δ6.64 (s, 1H), 6.53 (s, 1H), 3.85 and 3.84 (s, 3H), 3.68 and 3.66 (s, 3H), 3.30-3.14 (m, 1H), 3.07-2.95 (m, 1H ), 2.88-2.75 (m, 2H), 2.39-2.28 (m, 4H), 2.06 and 2.04 (s, 3H), 1.86 (s, 3H), 1.06 (s, 2H), 0.94 and 0.93 (s, 9H ).
6-236;
δ7.34-7.28 (m, 3H), 7.18-7.12 (m, 2H), 6.87 (s, 2H), 4.99 and 4.95 (s, 3H), 4.28-4.10 (m, 1H), 3.88 (s, 3H ), 2.89-2.78 (m, 2H), 2.63-2.53 (m, 1H), 2.27 (s, 3H), 2.06 (s, 6H), 1.90 (s, 3H).
6-237 (* 3);
δ6.89 (s, 2H), 4.33 (brs, 1H), 3.89 (s, 3H), 3.38 (brs, 1H), 2.76-2.38 (m, 1H), 2.45-2.39 (m, 1H), 2.26 ( s, 3H), 2.11 and 2.09 (s, 6H), 1.97 (s, 3H).
6-239;
δ7.84-7.77 (m, 1H), 7.64-7.59 (m, 1H), 7.14-7.08 (m, 1H), 6.67 (brs, 1H), 6.60-6.50 (m, 1H), 3.85 and 3.84 (s , 3H), 3.66 and 3.65 (s, 3H), 3.46-3.32 (m, 1H), 3.14-2.60 (m, 3H), 2.45-2.05 (m, 7H), 1.96-1.84 (m, 3H).
6-240;
δ7.94-7.89 (m, 1H), 7.87-7.78 (m, 1H), 7.60-7.52 (m, 1H), 7.40-7.32 (m, 1H), 6.67 (s, 1H), 6.57-6.50 (m , 1H), 3.85 and 3.84 (s, 3H), 3.67 and 3.66 (s, 3H), 3.46-3.32 (m, 1H), 3.13-2.82 (m, 3H), 2.45-2.30 (m, 4H), 2.13 and 2.11 (s, 3H), 1.90-1.87 (m, 3H).
6-241;
δ7.92-7.82 (m, 2H), 7.47-7.36 (m, 2H), 6.66 (s, 1H), 6.55-6.49 (m, 1H), 3.85 and 3.84 (s, 3H), 3.65 and 3.63 (s , 3H), 3.48-3.31 (m, 1H), 3.14-2.82 (m, 3H), 2.45-2.27 (m, 4H), 2.12 and 2.10 (s, 3H), 1.88 (brs, 3H).
6-242;
δ8.20 (brs, 1H), 8.14-8.08 (m, 1H), 7.88-7.80 (m, 1H), 7.63-7.55 (m, 1H), 6.67 (s, 1H), 6.56-6.49 (m, 1H ), 3.85 and 3.84 (s, 3H), 3.67 and 3.65 (s, 3H), 3.46-3.34 (m, 1H), 3.17-2.82 (m, 3H), 2.45-2.28 (m, 4H), 2.13 and 2.12 (s, 3H), 1.92-1.87 (m, 3H).
6-243;
δ8.79-8.76 (m, 1H), 8.47-8.41 (m, 1H), 8.29-8.23 (m, 1H), 7.70-7.62 (m, 1H), 6.68 (s, 1H), 6.55 (brs, 1H ), 3.86 and 3.85 (s, 3H), 3.70 and 3.69 (s, 3H), 3.48-3.33 (m, 1H), 3.18-2.83 (m, 3H), 2.45-2.25 (m, 4H), 2.14 and 2.12 (s, 3H), 1.93-1.87 (m, 3H).
6-246;
δ7.76-7.68 (m, 2H), 7.20-7.12 (m, 2H), 6.55 (brs, 1H), 6.39 (brs, 1H), 3.87 and 3.84 (s, 3H), 3.59 and 3.56 (s, 3H ), 3.32-3.19 (m, 1H), 3.10-2.72 (m, 3H), 2.40-2.10 (m, 4H), 1.94 and 1.92 (s, 3H), 1.85 and 1.84 (s, 3H).
6-249;
δ7.74-7.68 (m, 1H), 7.47-7.35 (m, 2H), 6.67 (brs, 1H), 6.55 (brs, 1H), 3.86 and 3.85 (s, 3H), 3.71 and 3.69 (s, 3H ), 3.45-3.30 (m, 1H), 3.14-2.83 (m, 3H), 2.45- 2.25 (m, 4H), 2.12 and 2.10 (s, 3H), 1.89 and 1.88 (s, 3H).
6-250;
δ7.73-7.68 (m, 1H), 7.55-7.46 (m, 1H), 7.05-6.88 (m, 2H), 6.65 (brs, 1H), 6.57-6.50 (m, 1H), 3.87-3.78 (m , 6H), 3.75-3.60 (m, 3H), 3.50-3.33 (m, 1H), 3.12-2.82 (m, 3H), 2.43-2.25 (m, 4H), 2.12 and 2.10 (s, 3H), 1.88 (s, 3H).
6-251;
δ7.77-7.70 (m, 1H), 7.65-7.57 (m, 1H), 7.45-7.37 (m, 1H), 7.34-7.27 (m, 1H), 6.67 (brs, 1H), 6.56-6.50 (m , 1H), 3.85 and 3.84 (s, 3H), 3.66 and 3.65 (s, 3H), 3.46-3.32 (m, 1H), 3.14-2.82 (m, 3H), 2.46-2.30 (m, 4H), 2.13 and 2.11 (s, 3H), 1.88 (s, 3H).
6-252;
δ8.00-7.90 (m, 1H), 7.72-7.52 (m, 3H), 6.68 (brs, 1H), 6.54 (brs, 1H), 3.87 and 3.86 (s, 3H), 3.68 and 3.67 (s, 3H ), 3.53-3.34 (m, 1H), 3.17-2.82 (m, 3H), 2.48-2.27 (m, 4H), 2.10 and 2.07 (s, 3H), 1.92-1.87 (m, 3H).
6-254;
δ7.09-7.04 (m, 1H), 6.96-6.90 (m, 1H), 3.89-3.82 (m, 3H), 3.34-3.19 (m, 1H), 3.13-2.98 (m, 1H), 2.91-2.80 (m, 2H), 2.39-2.24 (m, 4H), 2.14-2.08 (m, 3H), 1.91-1.85 (m, 3H), 1.16-1.13 (m, 9H).
6-255;
δ7.22-6.94 (m, 5H), 6.76-6.68 (m, 1H), 3.87-3.83 (m, 3H), 3.53-3.29 (m, 1H), 3.18-2.77 (m, 3H), 2.43-2.25 (m, 7H), 2.18-2.11 (m, 3H), 1.93-1.84 (m, 3H).
6-256;
δ7.12-7.02 (m, 1H), 7.00-6.90 (m, 1H), 5.32-4.86 (m, 2H), 3.92-3.84 (m, 3H), 3.84-2.09 (m, 18H), 1.93-1.85 (m, 3H).
6-257;
δ7.11-7.03 (m, 1H), 7.01-6.90 (m, 1H), 3.91-3.82 (m, 3H), 3.76-3.21 (m, 9H), 3.12-2.75 (m, 3H), 2.45-2.09 (m, 7H), 1.91-1.86 (m, 3H).
6-259 (* 3);
δ 6.70-6.40 (m, 2H), 3.90 (s, 3H), 3.45-3.30 (m, 1H), 3.00-2.50 (m, 3H), 2.40-1.85 (m, 10H).
6-260;
δ6.62 (brs, 1H), 6.52-6.48 (m, 1H), 3.90-3.75 (m, 6H), 3.70-3.65 (m, 3H), 3.50-3.35 (m, 1H), 3.15-2.80 (m , 3H), 2.40-2.05 (m, 7H), 1.86 (s, 3H).
6-261;
δ6.63 (brs, 1H), 6.55-6.45 (m, 1H), 4.00-3.82 (m, 6H), 3.70-3.60 (m, 3H), 3.50-3.35 (m, 1H), 3.18-2.80 (m , 3H), 2.43-2.05 (m, 10H), 1.98-1.82 (s, 6H).
6-262;
δ6.63 (brs, 1H), 6.55-6.40 (m, 1H), 5.20-5.12 (m, 1H), 3.88-3.77 (m, 3H), 3.65-3.55 (m, 3H), 3.50-3.30 (m , 1H), 3.18-2.80 (m, 3H), 2.45-2.00 (m, 10H), 1.90-1.75 (m, 6H), 1.40-1.20 (m, 6H).
6-263;
δ6.65 (brs, 1H), 6.55-6.40 (m, 1H), 3.90-3.80 (m, 3H), 3.78-3.60 (m, 4H), 3.50-3.30 (m, 1H), 3.15-2.80 (m , 3H), 2.66 (s, 3H), 2.32-2.25 (m, 4H), 2.20-2.18 (m, 3H), 1.87 (s, 3H), 1.25-1.10 (m, 6H).
6-264;
δ6.66 (brs, 1H), 6.51 (brs, 1H), 3.85 and 3.83 (s, 3H), 3.65 and 3.63 (s, 3H), 3.47-3.25 (m, 1H), 3.15-2.80 (m, 3H ), 2.74 (s, 3H), 2.45-2.25 (m, 4H), 2.15-2.02 (m, 3H), 1.95-1.85 (m, 3H).
6-266 (* 3);
δ7.10-6.82 (m, 2H), 6.67-6.04 (m, 1H), 3.91 (s, 3H), 3.53-3.31 (m, 1H), 3.07-2.50 (m, 3H), 2.32-1.20 (m , 10H).
6-267;
δ9.75-9.40 and 9.30-8.60 and 8.00-7.50 (m, 1H), 6.80-6.52 (m, 2H), 5.80-5.00 (m, 1H), 4.05- 3.70 (m, 6H), 3.69-1.85 ( m, 12H).
6-268;
δ11.10-10.90 (m, 1H), 6.80-6.50 (m, 2H), 6.04-5.87 (m, 1H), 5.42-5.10 (m, 2H), 4.60-4.38 (m, 2H), 3.95-3.80 (m, 3H), 3.46-3.30 (m, 1H), 2.98-1.83 (m, 13H).
6-269;
δ11.22-10.95 (m, 1H), 6.85-6.65 (m, 2H), 4.70-4.55 (m, 2H), 3.95-3.81 (m, 3H), 3.50-3.30 (m, 1H), 3.04-1.80 (m, 14H).
6-271;
δ11.55-11.37 (m, 1H), 7.52-7.43 (m, 1H), 6.82-6.59 (m, 2H), 5.18-4.99 (m, 2H), 3.97-3.82 (m, 3H), 3.45-3.30 (m, 1H), 2.98-1.82 (m, 13H).
6-272;
δ11.78-10.90 (m, 1H), 6.88-6.50 (m, 2H), 4.80-4.55 (m, 2H), 4.00-3.60 (m, 3H), 3.50-3.25 (m, 1H), 3.05-1.80 (m, 13H).
6-273;
δ11.05-10.95 (m, 1H), 6.80-6.37 (m, 2H), 5.00-4.50 (m, 2H), 3.95-3.70 (m, 6H), 3.50-3.25 (m, 1H), 3.00-1.82 (m, 13H).
6-274;
δ11.60-11.30 (m, 1H), 6.90-6.72 (m, 1H), 6.65-6.50 (m, 1H), 4.35-4.18 (m, 2H), 4.00-3.78 (m, 3H), 3.50-3.30 (m, 1H), 3.05-1.80 (m, 13H).
6-275 (* 3);
δ6.80-6.55 (m, 2H), 4.28-3.70 (m, 6H), 3.30-1.95 (m, 13H).
7-001 (* 3);
δ7.25-7.15 (m, 2H), 4.20-4.05 (m, 1H), 3.90-3.65 (m, 4H), 3.30-2.00 (m, 10H), 1.15-1.00 (m, 3H).
7-017 (* 3);
δ8.90-8.80 (m, 2H), 8.03 (brs, 2H), 7.70-7.60 (m, 1H), 3.00-2.80 (m, 3H), 2.70-2.60 (m, 1H), 2.35-2.25 (m , 1H), 2.12 (s, 9H).
7-027;
δ7.02 (brs, 1H), 6.88 (brs, 1H), 3.91-3.62 (m, 3H), 3.51-1.97 (m, 12H).
7-030;
δ9.05 (brs, 1H), 6.81-6.55 (m, 2H), 3.86-3.81 (m, 3H), 3.52-2.53 (m, 3H), 2.52-2.03 (m, 11H).
7-032;
δ9.92-9.00 (m, 1H), 6.91 (brs, 2H), 4.25-4.50 (m, 4H), 3.30-3.10 (m, 1H), 3.00-2.65 (m, 2H), 2.55-2.10 (m , 10H), 1.15-0.95 (m, 6H).
7-034;
δ9.20-8.30 (m, 1H), 6.75-6.65 (m, 1H), 6.64-6.50 (m, 1H), 4.25-3.85 (m, 2H), 3.83-3.67 (m, 3H), 3.40-2.05 (m, 13H), 1.40-1.20 (m, 3H).
7-037;
δ6.66 (s, 1H), 6.54 (s, 1H), 3.69-3.32 (m, 12H), 3.18-3.01 (m, 2H), 2.92-2.59 (m, 2H), 2.31 (s, 3H), 2.20 and 2.18 (s, 3H), 2.10 and 2.08 (s, 3H).
7-039;
δ7.43-7.00 (m, 10H), 6.73-6.55 (m, 2H), 5.10-4.85 (m, 4H), 3.40-2.00 (m, 14H).
7-043 (* 3);
δ6.81-6.72 (m, 1H), 6.66-6.57 (m, 1H), 5.59-4.80 (m, 1H), 3.89-3.74 (m, 3H), 3.24-2.56 (m, 3H), 2.45-2.28 (m, 6H), 2.19-2.03 (m, 3H).
7-044;
δ6.66 (brs, 1H), 6.53 (brs, 1H), 6.05-5.65 (m, 2H), 5.40-5.05 (m, 4H), 4.60-4.35 (m, 4H), 3.50-2.00 (m, 14H ).
7-045;
δ6.80-6.65 (m, 2H), 4.70-4.50 (m, 4H), 3.25-2.80 (m, 4H), 2.75-2.05 (m, 12H).
7-046;
δ6.75-6.50 (m, 2H), 4.25-3.90 (m, 4H), 3.75-2.05 (m, 24H).
7-047;
δ7.50-7.25 (m, 2H), 6.80-6.70 (m, 1H), 6.60-6.50 (m, 1H), 5.20-4.80 (m, 4H), 3.20-2.00 (m, 14H).
7-049;
δ9.20-9.00 (m, 1H), 6.80-6.65 (m, 2H), 4.65-4.50 (m, 2H), 3.40-2.05 (m, 15H).
7-052;
δ7.18-6.50 (m, 2H), 4.60-3.95 (m, 4H), 3.55-2.03 (m, 14H).
7-053;
δ6.93-6.82 (m, 1H), 6.75-6.60 (m, 1H), 4.78-4.50 (m, 4H), 3.80-2.00 (m, 14H).
7-054;
δ6.80-6.68 (m, 1H), 6.45-6.37 (m, 1H), 4.75-4.50 (m, 4H), 3.82-3.60 (m, 6H), 3.22-2.92 (m, 3H), 2.70-2.02 (m, 11H).
7-055;
δ10.20-9.92 (m, 1H), 6.92-6.50 (m, 2H), 4.75-4.50 (m, 2H), 3.85-1.95 (m, 14H).
7-056;
δ9.90-9.65 (m, 1H), 6.90-6.47 (m, 2H), 4.42-4.05 (m, 2H), 3.42-1.90 (m, 14H).
9-003;
δ7.25-7.19 (m, 2H), 7.08 (s, 2H), 7.02-6.92 (m, 1H), 6.73-6.54 (m, 2H), 4.67-4.57 (m, 2H), 3.85-3.77 (m , 3H), 3.41-2.38 (m, 5H), 2.24-1.95 (m, 10H), 1.17-0.99 (m, 6H).
9-004;
δ11.95 (s, 1H), 7.85 (s, 1H), 7.59 (s, 1H), 7.33 (s, 2H), 3.91 (s, 3H), 3.50-3.29 (m, 2H), 3.03-2.92 ( m, 1H), 2.87-2.77 (m, 1H), 2.50-2.09 (m, 8H), 1.17-1.05 (m, 6H).
9-005;
δ11.79 (s, 1H), 7.09 (s, 2H), 3.91 (s, 3H), 3.50-3.25 (m, 2H), 3.10-2.75 (m, 2H), 2.48-2.35 (m, 1H), 2.33-2.21 (m, 1H), 2.19-2.00 (m, 9H), 1.19-1.05 (m, 6H).
9-007;
δ12.17 (s, 1H), 7.85 (s, 1H), 7.59 (s, 1H), 7.38-7.28 (m, 2H), 3.94 (s, 3H), 3.38-3.25 (m, 1H), 2.92 ( dd, J = 17.7, 7.5Hz, 1H), 2.47-2.35 (m, 1H), 2.30-2.07 (m, 8H), 1.10-0.82 (m, 5H).
9-012;
δ7.89 (s, 1H), 7.64 (s, 1H), 7.32 (brs, 2H), 7.23-7.11 (m, 2H), 6.99-6.88 (m, 1H), 6.75-6.61 (m, 2H), 4.70-4.59 (m, 2H), 4.47-4.32 (m, 2H), 3.72-1.83 (m, 14H).
9-013;
δ7.28-7.18 (m, 2H), 7.07 (brs, 2H), 7.03-6.95 (m, 1H), 6.70-6.56 (m, 2H), 4.70-4.63 (m, 2H), 4.48-4.32 (m , 2H), 3.70-3.56 (m, 1H), 3.30-1.82 (m, 16H).
9-014;
δ7.82 (s, 1H), 7.59 (s, 1H), 7.25 (brs, 2H), 4.50-4.25 (m, 2H), 3.52-3.10 (m, 1H), 3.03-1.70 (m, 12H), 1.17-0.88 (m, 6H).
9-018;
δ11.60 (brs, 1H), 7.20 (s, 2H), 4.25-4.05 (m, 2H), 3.70-3.20 (m, 6H), 3.00-2.70 (m, 1H), 2.50-1.80 (m, 10H ), 1.20-1.00 (m, 6H).
9-019;
δ11.90 (brs, 1H), 7.20 (brs, 2H), 4.30-4.20 (m, 2H), 3.70-3.60 (m, 2H), 3.38 (s, 3H), 3.35-3.20 (m, 1H), 2.90-2.85 (m, 1H), 2.55-2.40 (m, 1H), 2.25-2.00 (m, 9H), 1.10-0.75 (m, 4H).
9-020;
δ11.95 (brs, 1H), 7.86 (s, 1H), 7.60 (s, 1H), 7.32 (brs, 2H), 4.36-4.21 (m, 2H), 3.71-3.59 (m, 2H), 3.45- 3.22 (m, 4H), 3.00-2.86 (m, 1H), 2.56-2.04 (m, 10H), 1.15-0.69 (m, 4H).
9-021;
δ11.79 (s, 1H), 7.09 (brs, 2H), 4.32-4.21 (m, 2H), 3.70-3.55 (m, 2H), 3.38 (s, 3H), 3.35-3.22 (m, 1H), 2.96-2.83 (m, 1H), 2.52-2.40 (m, 1H), 2.30-2.00 (m, 12H), 1.09-0.71 (m, 4H).
9-022;
δ11.67 (brs, 1H), 7.86 (s, 1H), 7.60 (s, 1H), 7.33 (brs, 2H), 4.29-4.20 (m, 2H), 3.69-3.40 (m, 7H), 3.03- 2.75 (m, 2H), 2.52-2.08 (m, 8H), 1.18-1.01 (m, 6H).
9-023;
δ11.52 (brs, 1H), 7.09 (brs, 2H), 4.30-4.12 (m, 2H), 3.69-3.17 (m, 7H), 3.03-2.73 (m, 2H), 2.58-1.91 (m, 11H ), 1.21-0.99 (m, 6H).
9-025;
δ7.58-7.19 (m, 6H), 4.50-4.32 (m, 2H), 3.72-3.22 (m, 9H), 3.14-2.71 (m, 3H), 2.41-1.82 (m, 10H).
9-026;
δ7.61-7.21 (m, 6H), 4.56-4.32 (m, 2H), 3.49-3.30 (m, 1H), 3.19-2.67 (m, 9H), 2.48-1.87 (m, 10H).
9-027;
δ7.57-7.11 (m, 8H), 7.02-6.87 (m, 1H), 6.75-6.60 (m, 2H), 4.70-4.59 (m, 2H), 4.49-4.34 (m, 2H), 3.33-1.87 (m, 14H).
9-029 (* 3);
δ7.07 (brs, 2H), 4.75-4.50 (m, 2H), 3.10-2.90 (m, 6H), 2.85-1.85 (m, 14H).
9-030;
δ12.00-11.76 (m, 1H), 7.21 (brs, 2H), 6.04-5.95 (m, 1H), 5.87-5.70 (m, 1H), 4.70-4.57 (m, 1H), 3.48-3.33 (m , 1H), 3.00-2.53 and 2.30-1.49 (m, 19H).
9-032;
δ6.68 (brs, 2H), 4.72 (s, 2H), 3.86 (s, 3H), 3.78 (s, 3H), 3.03-2.82 (m, 3H), 2.65-2.50 (m, 1H), 2.27- 2.00 (m, 7H), 1.88 (s, 3H).
9-034;
δ11.62 (brs, 1H), 6.69 (brs, 2H), 4.70 (s, 2H), 3.91 (s, 3H), 3.50-3.35 (m, 1H), 3.10-2.50 (m, 3H), 2.40- 1.97 (m, 10H).
9-037;
δ11.64 (brs, 1H), 7.02 and 6.70 (brs, 2H), 3.90 and 3.85 (s, 3H), 3.08-2.70 (m, 10H),
2.30-1.99 (10H).
9-038;
δ11.77 (brs, 1H), 7.46 (brs, 2H), 6.33 (brs, 1H), 4.15-4.04 (m, 2H), 3.91 (s, 3H), 3.00-2.57 (m, 3H), 2.30- 2.11 (m, 8H), 2.00 (s, 3H).
9-039 (* 3);
δ8.15-7.10 (m, 1H), 7.07 (brs, 2H), 5.90-5.56 (m, 1H), 5.16-4.89 (m, 2H), 4.43-4.15 (m, 4H), 3.80-3.62 (m , 2H), 2.78-2.20 and 2.05-1.78 (m, 12H).
9-040 (* 3);
δ8.43-7.11 (m, 1H), 7.07 (brs, 2H), 4.37 and 4.33 (s, 2H), 3.93-3.45 (m, 2H), 2.73-2.21 (m, 3H), 2.11-1.78 (m , 12H).
9-041 (* 3);
δ8.02-7.50 (m, 1H), 7.06 (brs, 2H), 4.33 and 4.28 (s, 2H), 3.16 (s, 2H), 3.07-2.20 and 2.13-1.98 (m, 15H), 0.43-0.02 (m, 4H).
9-042 (* 3);
δ7.95-7.12 (m, 1H), 7.07 (brs, 2H), 4.35 and 4.29 (s, 2H), 3.68-3.20 (m, 5H), 2.79-2.23 and 2.13-1.80 (m, 16H).
9-043 (* 3);
δ8.18-7.60 (m, 1H), 7.04 (brs, 2H), 4.32 and 4.26 (s, 2H), 3.32-2.98 (m, 2H), 2.79-2.18 and 2.13-1.80 (m, 19H).
9-044 (* 3);
δ8.80-7.10 (m, 1H), 7.07 (brs, 2H), 4.50-4.20 (m, 2H), 4.13-3.60 (m, 2H), 2.78-2.20 and 2.13-1.77 (m, 14H).
9-045 (* 3);
δ7.04 (brs, 2H), 4.40-4.18 (m, 1H), 3.73-3.55 (m, 1H), 2.77-1.75 (m, 17H).
9-046 (* 3);
δ8.41-7.10 (m, 1H), 7.06 (brs, 2H), 4.41 and 4.36 (s, 2H), 3.92-3.60 (m, 7H), 2.78-2.20 and 2.15-1.78 (m, 12H).
11-001;
δ7.39-7.12 (m, 5H), 6.86 (brs, 2H), 4.96 (s, 2H), 3.81 (s, 3H), 3.27-3.13 (m, 1H), 2.61-2.22 (m, 6H), 2.06 (brs, 6H), 1.87-1.77 (m, 3H), 1.26 (s, 3H).
12-001;
δ7.37-7.25 (m, 3H), 7.14-7.04 (m, 2H), 6.86 (brs, 2H), 4.71 (s, 2H), 3.83 (s, 3H), 2.88-2.77 (m, 2H), 2.47-2.23 (m, 5H), 2.15-2.02 (m, 6H), 1.88 (s, 3H), 1.37-1.22 (m, 3H).
12-002;
δ11.31 (brs, 1H), 6.87 (brs, 2H), 3.89 (s, 3H), 2.97-1.20 (m, 19H).
13-001;
δ11.60 and 11.57 (brs, 1H), 7.09-6.85 (m, 2H), 3.96-3.69 (m, 6H), 3.47-3.25 (m, 1H), 3.02-2.07 (m, 9H), 1.19-1.02 (m, 3H).
13-005;
δ6.66 (s, 1H), 6.55 (s, 1H), 3.91-2.45 and 2.39-2.00 and 1.97-1.40 (m, 26H), 0.94-0.64 (m, 4H).
13-006;
δ6.64 (s, 1H), 6.52 (s, 1H), 3.95-3.60 (m, 6H), 3.36-2.64 (m, 3H), 2.60-2.42 (m, 1H), 2.38-2.00 (m, 7H ), 1.97-1.78 (m, 1H), 1.13 (s, 9H), 0.94-0.61 (m, 4H).
13-007;
δ6.66 (brs, 1H), 6.54 (brs, 1H), 3.87-3.80 (m, 3H), 3.75-3.15 (m, 12H), 3.10-2.60 (m, 3H), 2.50-2.05 (m, 9H ), 1.15-1.03 (m, 3H).
13-008;
δ6.65 (brs, 1H), 6.54 (brs, 1H), 3.86-3.80 (m, 3H), 3.75-3.67 (m, 3H), 3.48-3.20 (m, 5H), 3.10-2.60 (m, 3H ), 2.45-2.02 (m, 9H), 1.92-1.78 (m, 4H), 1.17-1.02 (m, 3H).
13-009;
δ6.67-6.60 (m, 1H), 6.54-6.48 (m, 1H), 3.95-3.60 (m, 6H), 3.33-2.02 (m, 13H), 1.37-1.00 (m, 12H).
13-010;
δ7.30-7.17 (m, 2H), 7.05-6.97 (m, 1H), 6.83-6.75 (m, 2H), 6.70-6.65 (m, 1H), 6.58-6.52 (m, 1H), 4.70-4.60 (m, 2H), 3.90-3.75 (m, 3H), 3.72-3.62 (m, 3H), 3.40-2.00 (m, 13H), 1.15-1.00 (m, 3H).
13-011;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 3.85-3.67 (m, 9H), 3.39-2.03 (m, 13H), 1.17-1.02 (m, 3H).
13-012 (* 3);
δ7.09-6.53 (m, 2H), 3.98-3.82 (m, 3H), 3.50-3.32 (m, 1H), 3.08-2.50 and 2.33-1.98 (m, 13H), 1.92-1.67 and 0.82-0.42 ( m, 5H).
13-013;
δ11.55-11.30 (m, 1H), 7.11-6.80 (m, 2H), 6.75-6.30 (m, 1H), 5.71-5.53 (m, 1H), 5.32-5.05 (m, 1H), 3.94-3.85 (m, 3H), 3.50-3.30 (m, 1H), 3.03-2.52 and 2.40-1.84 (m, 13H).
13-014 (* 3);
δ7.70-7.25 (m, 2H), 3.91 and 3.89 (s, 3H), 3.50-3.30 (m, 1H), 3.05-2.56 (m, 3H),
2.38 (s, 3H), 2.34-2.17 (m, 4H), 2.02-1.94 (m, 3H).
13-015;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 4.35-4.23 (m, 2H), 3.85 and 3.84 (s, 3H), 3.70 and 3.68 (s, 3H), 3.64-3.55 (m, 2H ), 3.38-3.17 (m, 1H), 3.35 (s, 3H), 3.11-2.77 (m, 3H), 2.42-2.21 (m, 4H), 2.08 and 2.06 (s, 3H), 1.93-1.83 (m , 3H).
13-016;
δ7.47-7.29 (m, 5H), 6.70-6.49 (m, 2H), 5.15 (s, 2H), 3.85 and 3.84 (s, 3H), 3.61 and 3.59 (s, 3H), 3.40-2.72 (m , 4H), 2.42-2.20 (m, 4H), 2.06 and 2.03 (s, 3H), 1.86 and 1.85 (s, 3H).
13-017;
δ6.66 (brs, 1H), 6.56 (brs, 1H), 5.95-5.79 (m, 1H), 5.50-5.20 (m, 2H), 4.78-4.53 (m, 2H) 3.85 and 3.84 (s, 3H) , 3.70 and 3.68 (s, 3H), 3.40-2.78 (m, 4H), 2.42-2.20 (m, 4H), 2.18-2.06 (m, 3H), 1.92-1.82 (m, 3H).
13-018;
δ7.19-7.00 (m, 4H), 6.62-6.42 (m, 2H), 3.85 and 3.83 (s, 3H), 3.56 and 3.53 (s, 3H), 3.21-2.92 (m, 2H), 2.88-2.64 (m, 2H), 2.40-2.17 (m, 4H), 1.97-1.83 (m.6H), 1.52-1.45 (m, 6H).
13-021;
δ7.27-7.19 (m, 2H), 6.97 (t, J = 7.5Hz, 1H), 6.78 (d, J = 7.5Hz, 2H), 6.65 (brs, 1H), 6.54 (brs, 1H), 4.65 (s, 2H), 3.94-3.77 (m, 5H), 3.40-2.04 (m, 12H), 1.31 (m, 3H), 0.85-0.70 (m, 4H).
13-022;
δ6.62 (brs, 1H), 6.50 (brs, 1H), 3.96-3.72 (m, 5H), 3.34-1.43 (m, 12H), 1.34-1.22 (m, 3H), 1.14-1.11 (m, 9H ), 0.85-0.70 (m, 4H).
13-023;
δ6.64 (brs, 1H), 6.53 (brs, 1H), 4.20 (q, J = 7.2Hz, 2H), 3.99-3.78 (m, 5H), 3.34-1.45 (m, 12H), 1.32-1.20 ( m, 6H), 0.85-0.70 (m, 4H).
13-024;
δ6.64 (brs, 1H), 6.53 (brs, 1H), 3.98-3.78 (m, 5H), 3.65-1.45 (m, 20H), 1.29-1.22 (m, 3H), 0.87-0.69 (m, 4H ).
14-001;
δ10.53 and 10.48 (brs, 1H), 7.10-6.82 (m, 2H), 3.82-3.60 (m, 3H), 3.50-3.21 and 3.10-2.79 (m, 3H), 2.31-2.07 and 1.31-0.82 ( m, 10H).
14-002;
δ10.05 and 9.99 (brs, 1H), 7.10-6.83 (m, 2H), 3.84-3.59 (m, 3H), 3.39-1.02 (m, 13H).
14-003;
δ9.65-9.25 (m, 1H), 6.80-6.55 (m, 2H), 3.82-3.65 (m, 3H), 3.45-2.02 (m, 13H), 1.20-1.00 (m, 3H).
14-007 (* 3);
δ6.83-6.57 (m, 2H), 3.89-3.66 (m, 6H), 3.60-3.18 (m, 2H), 2.59-2.27 (m, 6H), 2.19-2.07 (m, 3H), 1.33-1.11 (m, 3H).
15-001;
δ10.10-9.96 (m, 1H), 6.85-6.52 (m, 2H), 4.81-4.60 (m, 2H), 3.92-3.61 (m, 3H), 3.53-3.28 (m, 1H), 3.04-1.86 (m, 14H).
15-002;
δ10.89-10.70 (m, 1H), 6.89-6.51 (m, 2H), 6.10-5.84 (m, 1H), 5.50-5.11 (m, 2H), 4.76-4.50 (m, 2H), 3.93-3.60 (m, 3H), 3.50-3.23 (m, 1H), 3.03-1.84 (m, 13H).
15-003;
δ11.22 (brs, 1H), 6.78-6.52 (m, 2H), 4.00-3.61 (m, 5H), 3.50-3.23 (m, 1H), 3.02-2.49 (m, 3H), 2.40-1.83 (m , 10H), 1.19-1.03 (m, 1H), 0.64-0.47 (m, 2H), 0.38-0.18 (m, 2H).
15-004;
δ10.90-10.60 and 8.10-7.60 (m, 1H), 6.80-6.55 (m, 2H), 4.40-4.06 (m, 2H), 3.90-3.70 (m, 3H), 3.70-3.53 (m, 2H) , 3.37 (s, 3H), 3.03-1.85 (m, 14H).
15-005 (* 3);
δ6.85-6.50 (m, 2H), 4.55-4.32 (m, 2H), 3.85-3.67 (m, 3H), 3.30-2.25 (m, 8H), 2.20-1.85 (m, 6H).
15-006;
δ8.20-7.95 and 7.15-6.95 (m, 1H), 6.80-6.55 (m, 2H), 4.69 (s, 2H), 3.77 (s, 3H), 3.45-2.40 (m, 4H), 2.33 (s , 3H), 2.20-1.85 (m, 7H).
15-007;
δ6.70-6.52 (m, 2H), 4.25-4.15 (m, 2H), 3.80-3.22 (m, 16H), 3.10-2.70 (m, 4H), 2.40-2.02 (m, 7H), 1.95-1.85 (m, 3H).
15-008;
δ6.70-6.48 (m, 2H), 4.25-4.00 (m, 2H), 3.75-3.60 (m, 5H), 3.57-3.22 (m, 6H), 3.20-2.28 (m, 11H), 2.20-1.88 (m, 6H).
15-009;
δ 6.70-6.48 (m, 2H), 4.50-4.35 (m, 2H), 3.80-3.63 (m, 3H), 3.35-2.50 (m, 4H), 2.48-1.85 (m, 10H), 1.15-1.10 (m, 9H).
15-010;
δ 6.70-6.50 (m, 2H), 4.50-4.30 (m, 2H), 3.75-3.65 (m, 3H), 3.45-3.20 (m, 1H), 3.10-2.70 (m, 9H), 2.45-1.85 (m, 10H).
15-011;
δ6.72-6.55 (m, 2H), 4.72-4.65 (m, 2H), 3.73 (s, 3H), 3.45-2.70 (m, 7H), 2.55-1.90 (m, 10H).
15-012;
δ6.65 (brs, 1H), 6.53 (brs, 1H), 4.72-4.68 (m, 2H), 3.72-3.68 (m, 3H), 3.45-2.70 (m, 8H), 2.45-1.85 (m, 10H ), 1.15-0.90 (m, 6H).
15-013;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 4.69-4.61 (m, 2H), 3.84-3.68 (m, 6H), 3.40-2.68 and 2.59-2.23 and 2.20-1.88 (m, 15H) .
15-014;
δ6.72-6.47 (m, 2H), 3.98-3.80 (m, 2H), 3.79-3.63 (m, 3H), 3.39-2.60 and 2.41-2.20 (m, 7H), 2.17-2.01 (m, 4H) , 1.98-1.83 (m, 3H), 1.65-1.03 (m, 10H), 0.63-0.42 (m, 2H), 0.37-0.17 (m, 2H).
15-015;
δ7.39-7.18 and 7.09-6.49 (m, 7H), 6.08-5.89 (m, 1H), 5.33-5.15 (m, 2H), 4.69-4.48 (m, 4H), 3.72-3.61 (m, 3H) , 3.39-2.72 (m, 4H), 2.48-2.21 (m, 4H), 2.17-1.80 (m, 6H).
15-016;
δ6.69-6.62 (m, 1H), 6.58-6.51 (m, 1H), 4.68-4.61 (m, 2H), 3.75-3.66 (m, 3H), 3.47-3.18 (m, 4H), 3.08-2.72 (m, 3H), 2.49-2.21 and 2.13-2.02 and 1.98-1.79 (m, 16H).
15-017;
δ 6.70-6.64 (m, 1H), 6.58-6.50 (m, 1H), 6.09-5.91 (m, 1H), 5.35-5.16 (m, 2H), 4.60-4.50 (m, 2H), 3.74-3.63 (m, 3H), 3.58-3.23 (m, 5H), 3.08-2.76 (m, 3H), 2.44-2.18 (m, 11H), 2.13-2.03 (m, 3H), 1.89 (s, 3H).
15-018;
δ 6.70-6.63 (m, 1H), 6.58-6.50 (m, 1H), 3.92-3.81 (m, 2H), 3.78-3.62 (m, 3H), 3.54-2.72 (m, 11H), 2.40-2.21 (m, 4H), 2.17-2.07 (m, 3H), 1.98-1.82 (m, 3H), 1.70-1.05 (m, 4H), 0.61-0.46 (m, 2H), 0.32-0.20 (m, 2H) .
15-019;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 4.70-4.60 (m, 2H), 3.80-3.22 and 3.10-2.65 and 2.51-2.22 (m, 20H), 2.13-2.05 (m, 3H) , 2.01-1.86 (m, 3H).
15-020;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 6.08-5.92 (m, 1H), 5.34-5.13 (m, 2H), 4.59-4.52 (m, 2H), 3.77-3.23 (m, 12H ), 3.09-2.72 (m, 3H), 2.40-2.20 (m, 4H), 2.09 and 2.06 (s, 3H), 1.97-1.83 (m, 3H).
15-021;
δ6.66 (brs, 1H), 6.55 (brs, 1H), 3.92-3.80 (m, 2H), 3.78-3.22 (m, 12H), 3.10-2.78 (m, 3H), 2.40-2.19 (m, 4H ), 2.09 and 2.06 (s, 3H), 1.96-1.87 (m, 3H), 1.05-1.25 (m, 1H), 0.59-0.43 (m, 2H), 0.33-0.20 (m, 2H).
15-024;
δ6.66 (brs, 1H), 6.58-6.51 (m, 1H), 4.19-4.02 (m, 2H), 3.73-3.27 (m, 12H), 3.08-2.78 (m, 3H), 2.40-2.00 (m , 7H), 1.86 (s, 3H), 1.32-1.20 (m, 3H).
15-024 (* 2);
δ6.75-6.65 (m, 1H), 6.62-6.51 (m, 1H), 4.19-4.02 (m, 2H), 3.80-1.90 (m, 25H), 1.36-1.20 (m, 3H).
15-025;
δ7.68-7.58 (m, 2H), 7.24-7.17 (m, 2H), 6.56 (brs, 1H), 6.43 (brs, 1H), 4.19-4.03 (m, 2H), 3.62 and 3.59 (s, 3H ), 3.31-2.72 (m, 4H), 2.43 (s, 3H), 2.38-2.15 (m, 4H), 1.95 and 1.92 (s, 3H), 1.85 and 1.84 (s, 3H), 1.32-1.21 (m , 3H).
15-026;
δ6.67 (brs, 1H), 6.60-6.50 (m, 1H), 4.38-4.22 (m, 1H), 3.78-2.15 (m, 19H), 2.09 and 2.07 (s, 3H), 1.97-1.82 (m , 3H), 1.34-1.17 (m, 6H).
15-027;
δ7.70-7.58 (m, 2H), 7.26-7.17 (m, 2H), 6.62-6.40 (m, 2H), 4.39-4.20 (m, 1H), 3.70-3.58 (m, 3H), 3.32-2.12 (m, 14H), 2.00-1.81 (m, 3H), 1.33-1.20 (m, 6H).
15-028;
δ11.29 and 11.28 (brs, 1H), 6.77-6.66 (m, 1H), 6.64-6.55 (m, 1H), 4.43-4.27 (m, 1H), 3.82-3.69 (m, 3H), 3.51-3.30 (m, 1H), 3.07-2.49 (m, 3H), 2.37-1.85 (m, 10H), 1.32-1.21 (m, 6H).
15-029;
δ6.66-6.63 (m, 1H), 6.54-6.49 (m, 1H), 4.15-4.05 (m, 2H), 3.69 and 3.68 (s, 3H), 3.33-2.62 (m, 4H), 2.42-2.18 (m, 4H), 2.08 and 2.06 (s, 3H), 1.89-1.87 (m, 3H), 1.31-1.22 (m, 3H), 1.14 and 1.13 (s, 9H).
15-030;
δ7.22-6.77 (m, 4H), 6.73-6.67 (m, 1H), 6.61-6.56 (m, 1H), 4.17-4.03 (m, 2H), 3.76-3.69 (m, 3H), 3.47-2.24 (m, 11H), 2.15-2.09 (m, 3H), 1.93-1.85 (m, 3H), 1.31-1.19 (m, 3H).
15-031;
δ6.67-6.62 (m, 1H), 6.54-6.49 (m, 1H), 4.40-4.21 (m, 1H), 3.72-3.64 (m, 3H), 3.35-2.61 (m, 4H), 2.41-2.16 (m, 4H), 2.11-2.03 (m, 3H), 1.87 (s, 3H), 1.27-1.19 (m, 6H), 1.15-1.10 (m, 9H).
15-032;
δ7.21-6.76 (m, 4H), 6.72-6.68 (m, 1H), 6.62-6.56 (m, 1H), 4.39-4.20 (m, 1H), 3.80-3.68 (m, 3H), 3.48-2.22 (m, 11H), 2.16-2.09 (m, 3H), 1.96-1.84 (m, 3H), 1.30-1.20 (m, 6H).
15-033;
δ7.30-7.18 (m, 2H), 7.04-6.95 (m, 1H), 6.84-6.64 (m, 3H), 6.58-6.51 (m, 1H), 4.69-4.62 (m, 2H), 4.36-4.20 (m, 1H), 3.72-3.63 (m, 3H), 3.42-2.02 (m, 11H), 1.92-1.82 (m, 3H), 1.31-1.18 (m, 6H).
15-034;
δ6.69-6.62 (m, 1H), 6.59-6.49 (m, 1H), 5.22-5.07 (m, 1H), 5.00-4.88 (m, 1H), 4.39-4.21 (m, 1H), 3.85-3.63 (m, 5H), 3.60-3.45 (m, 2H), 3.43-2.02 (m, 14H), 1.96-1.80 (m, 3H), 1.32-1.16 (m, 6H).
15-035;
δ11.18 and 11.17 (brs, 1H), 6.76-6.66 (m, 1H), 6.63-6.55 (m, 1H), 4.09-3.94 (m, 2H), 3.83-3.68 (m, 3H), 3.49-3.29 (m, 1H), 3.04-1.87 (m, 13H), 1.76-1.59 (m, 2H), 1.01-0.87 (m, 3H).
15-037;
δ11.18 (brs, 1H), 6.77-6.65 (m, 1H), 6.64-6.55 (m, 1H), 4.14-3.99 (m, 2H), 3.83-3.69 (m, 3H), 3.51-3.26 (m , 1H), 3.06-1.85 (m, 13H), 1.71-1.58 (m, 2H), 1.47-1.31 (m, 2H), 1.01-0.87 (m, 3H).
15-038;
δ7.87-7.77 (m, 1H), 7.49-7.37 (m, 1H), 7.26-7.16 (m, 2H), 6.70-6.64 (m, 1H), 6.57-6.49 (m, 1H), 4.18-4.04 (m, 2H), 3.72-3.64 (m, 3H), 3.47-3.31 (m, 1H), 3.18-2.83 (m, 3H), 2.46-2.09 (m, 10H), 1.95-1.87 (m, 3H) , 1.33-1.21 (m, 3H).
15-039;
δ6.71-6.61 (m, 1H), 6.60-6.48 (m, 1H), 5.22-5.09 (m, 1H), 4.99-4.88 (m, 1H), 4.19-3.97 (m, 2H), 3.86-3.64 (m, 5H), 3.60-3.46 (m, 2H), 3.41-2.52 (m, 7H), 2.47-2.02 (m, 7H), 1.96-1.82 (m, 3H), 1.34-1.19 (m, 3H) .
15-040;
δ7.44-7.12 (m, 5H), 6.66-6.41 (m, 2H), 4.22-4.01 (m, 2H), 3.63-3.51 (m, 3H), 3.23-2.61 (m, 4H), 2.44-2.16 (m, 4H), 2.00-1.83 (m, 6H), 1.68-1.58 (m, 6H), 1.31-1.17 (m, 3H).
15-041;
δ8.81-8.75 (m, 1H), 8.49-8.41 (m, 1H), 8.31-8.24 (m, 1H), 7.71-7.62 (m, 1H), 6.72-6.66 (m, 1H), 6.60-6.53 (m, 1H), 4.18-4.04 (m, 2H), 3.78-3.67 (m, 3H), 3.50-3.33 (m, 1H), 3.21-2.83 (m, 3H), 2.48-2.29 (m, 4H) , 2.19-2.11 (m, 3H), 1.97-1.88 (m, 3H), 1.34-1.21 (m, 3H).
15-042;
δ11.84-11.72 (m, 1H), 7.15-7.04 (m, 1H), 7.02-6.89 (m, 1H), 4.25-4.07 (m, 2H), 3.54-3.33 (m, 1H), 3.08-2.51 (m, 3H), 2.35-2.12 (m, 7H), 2.04-1.94 (m, 3H), 1.35-1.23 (m, 3H).
15-044;
δ6.69-6.63 (m, 1H), 6.57-6.51 (m, 1H), 4.17-4.03 (m, 2H), 3.71 and 3.69 (s, 3H), 3.47-2.77 (m, 8H), 2.40-2.19 (m, 4H), 2.11 and 2.08 (s, 3H), 1.92-1.79 (m, 7H), 1.32-1.20 (m, 3H).
15-045;
δ6.69-6.63 (m, 1H), 6.59-6.51 (m, 1H), 4.19-3.99 (m, 2H), 3.71 and 3.69 (s, 3H), 3.52-2.71 (m, 8H), 2.38-2.19 (m, 4H), 2.10 and 2.08 (s, 3H), 1.95-1.84 (m, 3H), 1.64-1.39 (m, 6H), 1.31-1.21 (m, 3H).
15-046;
δ11.36-11.23 (m, 1H), 6.79-6.65 (m, 1H), 6.64-6.55 (m, 1H), 4.20-4.05 (m, 1H), 3.84-3.69 (m, 3H), 3.51-3.27 (m, 1H), 3.03-2.43 (m, 3H), 2.36-1.44 (m, 12H), 1.34-1.18 (m, 3H), 0.98-0.86 (m, 3H).
15-047 (* 3);
δ 6.79-6.56 (m, 2H), 6.13-5.62 (m, 1H), 4.55-4.36 (m, 2H), 3.84-3.70 (m, 3H), 3.53-2.20 (m, 8H), 2.18-1.86 (m, 6H).
16-001;
δ11.70-11.60 (m, 1H), 7.02-6.85 (m, 1H), 3.90 (s, 3H), 3.48-3.35 (m, 1H), 3.00-2.87 (m, 1H), 2.85-2.50 (m , 3H), 2.37-1.97 (m, 12H).
17-001;
δ6.65 (brs, 2H), 3.71 (s, 3H), 2.62 (dd, J = 13.2, 3.3Hz, 1H), 2.45-2.32 (m, 1H), 2.20-2.06 (m, 4H), 2.00 ( s, 3H), 1.97 (s, 3H), 1.90-1.72 (m, 5H).
17-002;
δ6.65 (brs, 2H), 3.71 (s, 3H), 2.62 (dd, J = 13.2, 3.3Hz, 1H), 2.44-2.30 (m, 1H), 2.20-2.06 (m, 4H), 2.00 ( s, 3H), 1.97 (s, 3H), 1.88-1.70 (m, 5H).
――――――――――――――――――――――――――――――――――――――
Test example
Next, the usefulness of the compound of the present invention as a herbicide will be specifically described in the following test examples, but the present invention is not limited thereto.
[Test Example 1] Herbicidal effect test by pretreatment of weeds in flooded conditions
After alluvial soil was put into a 1/10000 are Wagner pot, water was added and mixed to create a submerged condition with a depth of 4 cm. After seeding nobies, firefly and koigi in the cup, rice seedlings at the 2.5 leaf stage were transplanted. On the day of sowing, the emulsion of the compound of the present invention prepared according to Formulation Example 2 was diluted with water to a predetermined dose and treated on the water surface. The cup was placed in a greenhouse at 25 to 30 ° C. to grow plants, and after 3 weeks of drug treatment, the effects on various plants were examined according to the following criteria. The results are shown in Table 21.

判定基準
５ … 殺草率 ９０％以上 （ほとんど完全枯死）
４ … 殺草率 ７０％以上９０％未満
３ … 殺草率 ４０％以上７０％未満
２ … 殺草率 ２０％以上４０％未満
１ … 殺草率 ５％以上２０％未満
０ … 殺草率 ５％以下 （ほとんど効力なし）
〔試験例２〕湛水条件における雑草生育期処理による除草効果試験
１／１００００アールのワグネルポットに沖積土壌を入れた後、水を入れて混和し、水深４cmの湛水条件とした。ノビエ、ホタルイ及びコナギの種子を上記カップに混播し、２５〜３０℃の温室内に置いて植物を育成した。ノビエ、ホタルイ及びコナギが１〜２葉期に達したとき、配合例２に準じて調製した本発明化合物の乳剤を所定の薬量になるように水で希釈し、水面に処理した。薬剤処理３週間後に、各種植物に対する影響を試験例１の判定基準に従って調査した。結果を第２２表に示す。
〔試験例３〕茎葉処理による除草効果試験
１／１００００アールのワグネルポットに沖積土壌を入れた後、水を入れて混和し、水深０．１〜０．５cmの条件とした。イヌビエ、アゼガヤ、タマガヤツリ及びイネの種子を播種し、２５〜３０℃の温室内に置いて植物を育成した。１４日間育成したのち、配合例２に準じて調製した本発明化合物の乳剤を所定の薬量になるように水で希釈し、茎葉部へ小型スプレーで均一に処理した。薬剤処理３週間後に、各種植物に対する影響を試験例１の判定基準に従って調査した。結果を第２３表に示す。
〔試験例４〕土壌処理による除草効果試験
縦２１cm、横１３cm、深さ７cmのプラスチック製箱に殺菌した洪積土壌を入れ、メヒシバ、エノコログサ、イヌビエ、カラスムギ、ブラックグラス、イタリアンライグラス、セイヨウヌカボ、イチビ、アオゲイトウ、シロザ、ハコベ、ヤエムグラ、オオイヌノフグリ、トウモロコシ、ダイズ、イネ、コムギ、ビート及びナタネの種子をそれぞれスポット状に播種し、約１．５cm覆土した。次いで配合例２に準じて調製した本発明化合物の乳剤を所定の薬量になるように水で希釈し、土壌表面へ小型スプレーで均一に処理した。プラスチック製箱を２５〜３０℃の温室内に置いて植物を育成し、薬剤処理３週間後に、各種植物に対する影響を試験例１の判定基準に従って調査した。結果を第２４表に示す。
〔試験例５〕茎葉処理による除草効果試験
縦２１cm、横１３cm、深さ７cmのプラスチック製箱に殺菌した洪積土壌を入れ、メヒシバ、エノコログサ、イヌビエ、カラスムギ、ブラックグラス、イタリアンライグラス、セイヨウヌカボ、イチビ、アオゲイトウ、シロザ、ハコベ、ヤエムグラ、オオイヌノフグリ、トウモロコシ、ダイズ、イネ、コムギ、ビート及びナタネの種子をそれぞれスポット状に播種し、約１．５cm覆土した後、２５〜３０℃の温室内において植物を育成した。１４日間育成したのち，配合例２に準じて調製した本発明化合物の乳剤を所定の薬量になるように水で希釈し、茎葉部へ小型スプレーで均一に処理した。薬剤処理３週間後に、各種植物に対する影響を試験例１の判定基準に従って調査した。結果を第２５表に示す。 Criterion 5 ... More than 90% of herbicide rate
4 ... Herbicidal Rate 70% or more and less than 90% 3 ... Herbicidal Rate 40% or more and less than 70% 2 ... Herbicidal Rate 20% or more and less than 40% 1 ... Herbicidal Rate 5% or more but less than 20% 0 ... Herbicidal Rate 5% or less (almost effective) None)
[Test Example 2] Herbicidal effect test by treatment with weed growing season in flooded condition After alluvial soil was put into a 1/10000 are Wagner pot, water was added and mixed to obtain a flooded condition of 4 cm in water depth. Nobies, firefly, and oak seeds were mixed in the above cups and placed in a greenhouse at 25-30 ° C. to grow plants. When Nobies, Firefly and Konagi reached the 1 to 2 leaf stage, the emulsion of the compound of the present invention prepared according to Formulation Example 2 was diluted with water so as to have a predetermined dosage, and then treated on the water surface. Three weeks after the drug treatment, the influence on various plants was investigated according to the criteria of Test Example 1. The results are shown in Table 22.
[Test Example 3] Herbicidal effect test by foliar treatment After alluvial soil was put into a 1/10000 are Wagner pot, water was added and mixed to obtain a condition of water depth of 0.1 to 0.5 cm. Inobie, Azegaya, Tamagayatsuri, and rice seeds were sown and placed in a greenhouse at 25-30 ° C. to grow the plants. After growing for 14 days, the emulsion of the compound of the present invention prepared according to Formulation Example 2 was diluted with water to a predetermined dose, and uniformly treated with a small spray on the foliage. Three weeks after the drug treatment, the influence on various plants was investigated according to the criteria of Test Example 1. The results are shown in Table 23.
[Test Example 4] Herbicidal effect test by soil treatment Put sterilized large soil in a plastic box 21cm long, 13cm wide and 7cm deep, and then weed bark, Enocorosa, Inobie, oats, blackgrass, Italian ryegrass, Atlantic cabbage, The seeds of Ichibi, Aogateto, Shiroza, Jacobe, Yamgra, Giant corn, corn, soybean, rice, wheat, beet and rapeseed were sown in a spot shape and covered with about 1.5 cm of soil. Next, the emulsion of the compound of the present invention prepared according to Formulation Example 2 was diluted with water to a predetermined dose, and uniformly treated with a small spray on the soil surface. Plants were grown by placing plastic boxes in a greenhouse at 25 to 30 ° C., and after 3 weeks of chemical treatment, the effects on various plants were examined according to the criteria of Test Example 1. The results are shown in Table 24.
[Test Example 5] Herbicidal effect test by foliar treatment Put sterilized piled soil in a plastic box 21cm long, 13cm wide, 7cm deep, and pearl bark, green croaker, barnyardgrass, oats, blackgrass, Italian ryegrass, yellow croaker, Spotted seeds of Ichibi, Aogateto, Shiroza, Jacobe, Yamgra, Giant corn, corn, soybean, rice, wheat, beet and rapeseed, covered with about 1.5 cm, and then planted in a greenhouse at 25-30 ° C. Nurtured. After growing for 14 days, the emulsion of the compound of the present invention prepared according to Formulation Example 2 was diluted with water to a predetermined dose, and uniformly treated with a small spray on the foliage. Three weeks after the drug treatment, the influence on various plants was investigated according to the criteria of Test Example 1. The results are shown in Table 25.

尚、第２１表〜第２５表中の記号は以下の意味を表す。
Ａ：ノビエ、Ｂ：ホタルイ、Ｃ：コナギ、Ｄ：アゼガヤ、Ｅ：コゴメガヤツリ、Ｆ：メヒシバ、Ｇ：エノコログサ、Ｈ：イヌビエ、Ｉ：カラスムギ、Ｊ：ブラックグラス、Ｋ：イタリアンライグラス、Ｌ：セイヨウヌカボ、Ｍ：イチビ、Ｎ：アオゲイトウ、Ｏ：シロザ、Ｐ：ハコベ、Ｑ：ヤエムグラ、Ｒ：オオイヌノフグリ、ａ：移植イネ、b:直播イネ、ｃ：トウモロコシ、ｄ：ダイズ、e：コムギ、f：ビート、g：ナタネ
また処理薬量（ｇ／ｈａ）とは、１ヘクタール（１ｈａ）当たりに換算したときに、記載した数値のグラム（ｇ）数だけ処理されるように濃度を調整したことを表す。 The symbols in Tables 21 to 25 represent the following meanings.
A: Nobies, B: Firefly, C: Konagi, D: Azegaya, E: Kogomegatsuri, F: Barbet, G: Enokirogusa, H: Inubie, I: Oats, J: Blackgrass, K: Italian ryegrass, L: Atlantic calyx , M: Ichibi, N: Blue-headed toe, O: Shiroza, P: Jacobe, Q: Yamgra, R: Giant corn, a: Transplanted rice, b: Directly sown rice, c: Corn, d: Soy, e: Wheat, f: Beet , G: rapeseed The treatment dose (g / ha) represents that the concentration was adjusted so that the number of grams (g) described was processed when converted per hectare (1 ha). .

〔第２１表〕
―――――――――――――――――――――――――
Ｎｏ． 処理薬量 Ａ Ｂ Ｃ ａ
（ｇ／hａ）
―――――――――――――――――――――――――
1-001 320 0 0 0 0
1-002 320 5 4 4 5
1-003 320 5 4 5 5
1-004 320 5 5 4 5
1-005 320 5 5 5 5
1-006 320 5 3 3 4
1-007 320 0 0 0 0
1-008 320 5 3 0 0
1-009 320 0 0 0 0
1-010 320 5 5 2 5
1-011 320 0 0 0 0
1-012 320 0 0 0 0
1-013 320 0 0 0 0
1-014 320 5 5 2 5
1-015 320 5 5 2 5
1-016 320 5 5 4 5
1-017 320 5 5 2 5
1-018 320 5 5 2 5
1-019 320 5 5 2 5
1-020 320 5 5 4 5
1-021 320 0 0 0 0
1-022 320 5 5 2 5
1-023 320 4 0 0 1
1-024 320 5 5 2 5
1-025 320 4 2 0 3
1-026 320 5 5 5 5
1-027 320 4 3 3 4
1-028 320 5 5 1 5
1-029 320 4 0 0 5
1-030 320 2 0 0 1
1-031 320 5 4 2 0
1-032 320 5 5 3 5
1-033 320 5 4 1 5
1-034 320 5 4 2 5
1-035 320 5 5 2 5
1-036 320 5 4 1 5
1-037 320 0 0 0 0
1-038 320 5 5 3 5
1-039 320 5 5 2 5
1-040 320 3 2 0 4
1-041 320 5 5 0 5
1-042 320 5 5 4 5
1-043 320 5 5 2 5
1-044 320 5 5 4 5
1-045 320 5 2 0 3
1-046 320 5 5 4 5
1-047 320 4 0 0 1
1-048 320 5 4 1 5
1-049 320 0 0 0 0
1-050 320 4 2 3 4
1-051 320 5 5 0 5
1-052 320 5 5 0 5
1-053 320 5 3 0 5
1-054 320 5 0 0 5
1-055 320 5 3 0 5
1-056 320 5 5 4 5
1-057 320 5 3 2 4
1-058 320 5 0 0 5
1-059 320 5 3 2 4
1-060 320 5 4 3 5
1-062 320 5 2 1 5
1-063 320 5 3 0 5
1-064 320 5 5 1 4
1-065 320 5 5 0 5
1-066 320 4 0 0 5
1-067 320 5 5 1 5
1-068 320 5 4 3 5
1-069 320 5 4 2 5
1-070 320 4 0 0 4
1-071 320 5 4 0 5
1-072 320 5 4 5
1-073 320 5 5 1 5
1-074 320 5 5 4 5
1-075 320 5 4 5
1-076 192 4 4 0 5
1-077 320 1 2 0 1
1-078 320 5 2 0 5
1-079 320 5 5 3 5
1-080 320 5 5 3 5
1-081 320 5 5 2 5
1-082 320 5 5 2 5
1-083 320 5 4 1 5
1-085 320 4 0 0 3
1-086 320 5 0 0 3
1-087 320 5 5 1 5
1-088 320 5 5 0 5
1-089 320 5 5 3 5
1-090 320 5 5 1 5
1-091 320 5 5 0 4
1-092 320 5 5 0 5
1-093 320 5 5 2 5
1-094 320 5 5 1 5
1-095 320 5 5 2 5
1-096 320 5 5 0 5
1-097 320 3 0 0 3
1-098 320 5 5 4 5
1-099 320 5 4 2 5
1-100 320 5 5 3 5
1-101 320 5 5 2 5
1-102 320 5 3 5
1-103 320 5 5 1 5
1-104 320 5 4 1 3
1-105 320 5 5 4 5
1-106 320 5 3 5
1-107 320 5 4 1 3
1-108 320 5 4 3 5
1-109 320 5 5 3 5
1-110 320 3 0 0 5
1-111 320 5 2 1 5
1-112 320 5 5 5 5
1-113 320 5 4 4 3
1-114 320 5 5 5 5
1-115 320 5 3 4 1
1-116 320 5 4 5 3
1-117 320 5 5 5 5
1-118 320 5 1 2 4
1-119 320 1 0 0 3
1-120 320 4 5 3 0
1-121 320 5 5 3 5
1-122 320 5 5 0 5
1-123 320 5 4 3 5
1-124 320 1 0 0 0
1-125 320 3 0 1 5
1-126 320 4 0 0 3
1-130 320 3 0 0 3
1-131 320 5 4 1 4
1-133 320 4 0 0 1
1-134 320 5 5 1 5
1-135 320 5 5 1 5
1-136 320 5 5 5 5
1-137 320 5 5 5 5
1-138 320 5 5 5 5
1-139 320 5 4 1 5
1-140 320 5 5 1 5
1-142 320 5 5 2 5
1-143 320 4 4 1 5
1-144 320 5 5 3 5
1-145 320 5 5 1 5
1-146 320 5 5 1 5
1-147 320 5 5 1 5
1-148 320 5 4 3 5
1-149 320 5 5 1 5
1-150 320 5 3 0 5
1-151 320 5 3 0 4
1-152 320 4 0 0 2
1-153 320 5 3 0 4
1-154 320 5 4 2 5
1-155 320 5 5 1 5
1-156 320 5 5 1 5
1-159 320 5 0 0 1
1-160 320 5 4 2 5
1-161 320 5 4 1 4
1-162 320 5 4 3 5
1-163 320 5 4 0 5
1-166 320 5 0 0 0
1-167 320 5 5 2 5
1-168 320 5 5 3 5
1-169 320 5 4 3 5
1-170 320 5 0 0 4
1-171 320 5 0 0 4
1-172 320 5 3 2 5
1-173 320 5 3 2 5
1-174 320 5 4 3 5
1-175 320 5 4 2 5
1-176 320 5 4 1 5
1-177 320 5 5 2 5
1-178 320 5 4 2 5
1-179 320 5 4 1 5
1-180 320 5 1 5
1-181 320 4 1 5
1-182 320 5 0 5
1-183 320 5 2 5
1-184 320 2 0 5
1-186 320 5 0 0 3
1-187 320 5 4 0 5
1-188 320 5 0 0 1
1-189 320 5 2 0 0
1-190 320 4 0 0 0
1-191 320 5 4 1 5
1-192 320 5 4 2 4
1-193 320 5 5 5 5
1-194 320 5 2 0 5
1-195 320 5 5 5 5
1-196 320 5 5 5 5
1-197 320 5 4 5 5
1-198 320 5 4 3 5
1-199 320 5 5 4 5
1-200 320 5 4 0 5
1-201 320 5 4 3 4
1-202 320 5 5 5 5
1-203 320 5 4 1 5
1-204 320 5 4 2 5
1-205 320 5 5 3 5
1-206 320 4 0 0 2
1-207 320 5 5 1 5
1-208 320 5 5 2 5
1-209 320 5 4 3 5
1-210 320 5 4 0 5
1-211 320 5 4 0 4
1-212 320 5 3 0 4
1-213 320 5 3 0 5
1-214 320 5 4 3 5
1-215 320 5 5 1 5
1-216 320 5 4 0 4
1-217 320 5 4 1 5
1-218 320 5 4 3 5
1-219 320 5 4 0 5
1-220 320 5 4 0 4
1-221 320 5 5
1-222 320 5 2 0
1-223 320 3 0 0 1
1-224 320 5 1 0 4
1-225 320 5 4 4
1-226 320 5 4 3 5
1-227 320 5 5 1 5
1-228 320 5 5 4 5
1-229 320 5 5 1 5
1-230 320 5 5 3 5
1-231 320 5 5 1 5
1-232 320 5 5 1 4
1-233 320 5 5 0 5
1-234 320 5 5 1 5
1-235 320 5 5 3 4
1-236 320 5 2 0 3
1-237 320 5 4 0 3
1-238 320 5 5 0 5
1-239 320 5 4 3 5
1-240 320 5 4 1 5
1-241 320 5 4 2 5
1-242 320 5 2 0 3
1-243 320 5 5 2 5
1-244 320 5 4 0 5
1-245 320 5 4 0 5
1-246 320 5 5 1 5
1-247 320 5 4 1 5
1-248 320 5 5 0 5
1-249 320 5 4 1 5
1-250 320 5 3 0 5
1-251 320 5 5 3 5
1-252 320 5 5 0 5
1-253 320 5 5 1 5
1-254 320 5 5 2 5
1-255 320 5 5 0 5
1-256 320 5 4 4 5
1-257 320 5 5 1 5
1-258 320 5 5 5 5
1-259 320 5 5 1 5
1-260 320 5 5 1 5
1-261 320 5 3 0 5
1-262 320 5 4 2 5
1-263 320 5 4 2 5
1-264 320 5 4 2 5
1-265 320 4 3 0 5
1-266 320 5 5 4 5
1-267 320 5 5 1 5
1-268 320 5 4 3 5
1-269 320 5 5 2 5
1-270 320 5 5 3 5
1-271 320 5 4 1 5
1-272 320 5 4 0 5
1-273 320 5 5 1 5
1-296 320 4 0 0 4
1-297 320 5 5 2 5
1-298 320 5 5 4 5
1-299 320 5 4 3 5
1-300 320 5 5 2 5
1-301 320 5 4 3 5
1-302 320 5 4 2 5
1-303 320 5 3 2 5
1-304 320 5 4 1 5
1-305 320 5 3 0 4
1-306 320 5 4 2 5
1-307 320 5 4 0 4
1-308 320 5 5 2 5
1-309 320 5 4 1 5
1-310 320 5 4 2
1-311 320 5 3 2 5
1-312 320 5 4 0 5
1-314 320 5 0 0 3
2-001 102 4 0 0 4
2-002 320 0 0 0 0
2-003 320 0 0 0 0
2-005 269 3 0 0 4
2-006 320 5 2 3 3
2-007 320 3 2 0 4
2-008 320 0 0 0 0
2-009 320 0 0 0 0
2-010 320 0 0 0 0
2-011 320 0 0 0 0
2-012 320 0 0 0 0
2-013 320 0 0 0 0
2-014 320 4 3 1 1
2-015 320 0 4 0 0
2-016 320 4 0 0 4
2-017 320 5 5 3 5
2-018 320 5 2 1 4
2-020 320 2 0 0 3
2-021 320 4 4 2 5
2-022 320 1 0 0 3
2-024 320 2 0 0 4
2-025 320 3 0 0 2
2-026 320 3 3 0 4
2-028 320 3 0 0 3
2-030 320 4 0 0 3
2-031 320 4 4 2 5
2-032 320 4 4 1 5
2-034 320 2 1 0 2
2-035 320 5 2 0 3
3-001 320 0 0 0 0
3-002 320 0 0 0 0
4-001 320 0 0 0 0
5-001 320 0 0 0 0
5-002 320 0 0 0 0
6-001 320 5 0 0 5
6-002 320 3 0 0 3
6-003 320 5 4 1 5
6-004 320 5 5 2 5
6-005 320 5 5 3 5
6-006 320 5 5 1 5
6-007 320 5 5 1 5
6-008 320 5 5 5 5
6-009 320 5 2 0 3
6-010 320 5 4 1 5
6-015 320 5 5 5 5
6-016 320 5 0 0 4
6-017 320 5 1 0 5
6-018 320 5 5 4 5
6-023 320 0 0 0 4
6-024 320 3 2 3
6-025 320 2 0 0 3
6-026 320 1 0 0 3
6-029 320 5 3 3 5
6-030 320 3 0 0 2
6-031 320 3 0 0 1
6-034 320 5 5 4 5
6-035 320 5 4 1 5
6-037 320 5 5 4 5
6-038 320 5 4 3 5
6-049 320 5 5 4 5
6-050 320 3 1 0 4
6-051 320 4 4 2 5
6-052 320 4 1 0 3
6-053 320 4 2 1 3
6-054 320 1 0 0 2
6-055 320 4 1 0 5
6-056 320 3 0 0 0
6-057 320 3 3 1 5
6-058 320 5 5 5 5
6-059 320 5 5 4 5
6-060 320 5 5 5 5
6-061 320 5 1 1 5
6-062 320 5 4 4 5
6-063 320 5 2 3 4
6-064 320 5 0 0 5
6-065 320 4 2 3 4
6-066 320 5 3 2 3
6-071 320 4 0 0 0
6-072 320 4 0 0 0
6-073 320 4 1 1 5
6-074 320 1 0 0 2
6-075 320 4 1 2 3
6-076 320 5 3 2 5
6-077 320 5 3 3 5
6-078 320 5 5 4 5
6-079 320 4 0 2 5
6-080 320 5 1 2 5
6-081 320 5 0 1 3
6-082 320 5 4 4 5
6-083 320 5 4 4 5
6-084 320 5 3 0 5
6-085 320 5 3 0 5
6-086 320 5 2 0 5
6-087 320 5 0 0 2
6-088 320 4 1 0 3
6-089 320 5 3 3 5
6-090 320 5 0 0 0
6-091 320 5 5 4 5
6-092 320 3 0 0 0
6-093 320 5 5 4 5
6-094 320 5 5 3 5
6-095 320 5 4 0 5
6-096 320 1 0 0 5
6-098 320 0 1 0 1
6-099 320 5 5 5 5
6-100 320 5 5 5 5
6-103 320 5 0 0 5
6-104 320 5 5 5 5
6-106 320 5 5 4 5
6-107 320 5 5 5 5
6-108 320 4 3 0 5
6-109 320 5 3 3 5
6-110 320 5 3 0 5
6-111 320 5 5 2 5
6-112 320 5 0 0 4
6-113 320 4 0 0 5
6-114 320 5 4 0 5
6-115 320 5 1 0 5
6-117 320 5 5 4 5
6-118 320 5 5 2 5
6-119 320 5 4 3 5
6-120 320 5 5 2 5
6-121 320 5 5 4 5
6-122 320 5 5 2 5
6-123 320 5 5 2 5
6-124 320 5 5 4 5
6-126 320 5 5 2 5
6-127 320 5 1 2 5
6-128 320 5 5 4 5
6-129 320 5 5 4 5
6-130 320 5 5 4 5
6-131 320 5 5 4 5
6-132 320 5 5 1 5
6-133 320 5 0 0 5
6-134 320 5 5 4 5
6-135 320 5 4 3 5
6-136 320 5 5 4 5
6-137 320 5 4 3 5
6-138 320 5 0 0 3
6-139 320 5 3 0 3
6-140 320 5 2 2 5
6-141 320 5 3 0 5
6-142 320 5 3 2
6-143 320 5 0 0 3
6-144 320 5 0 0 5
6-145 320 5 0 0 5
6-146 320 5 0 0 5
6-147 320 5 0 0 5
6-148 320 5 0 0 5
6-149 320 5 4 4 5
6-150 320 5 0 0 5
6-151 320 5 2 0 4
6-152 320 5 0 0 5
6-153 320 5 5 5 5
6-154 320 5 4 4 5
6-155 320 5 4 3 5
6-156 320 5 5 1 5
6-157 320 5 5 2 5
6-158 320 5 5 3 5
6-159 320 5 5 2 5
6-160 320 5 4 3 5
6-161 320 5 4 2 5
6-162 320 5 5 3 5
6-163 320 5 4 2 5
6-164 320 5 5 1 5
6-165 320 5 5 3 5
6-166 320 5 4 3 5
6-167 320 5 5 4 5
6-168 320 5 5 4 5
6-169 320 5 5 5 5
6-170 320 5 5 4 5
6-171 320 5 5 3 5
6-172 320 5 3 3 4
6-173 320 5 5 4 5
6-174 320 5 5 4 5
6-175 320 5 5 3 5
6-176 320 5 5 4 5
6-177 320 5 5 3 5
6-178 320 5 5 3 5
6-179 320 5 5 2 5
6-180 320 5 5 4 5
6-181 320 5 5 3 5
6-182 320 5 5 3 5
6-183 320 5 5 1 5
6-184 320 5 5 5 5
6-185 320 5 5 2 5
6-186 320 5 5 4 5
6-187 320 5 5 2 5
6-188 320 5 5 3 5
6-189 320 5 5 2 5
6-190 320 5 5 4 5
6-191 320 5 4 5 5
6-192 320 5 5 3 5
6-193 320 5 5 4 5
6-195 320 5 1 0 1
6-196 320 5 5 4 5
6-197 320 5 2 0 1
6-198 320 5 2 0 3
6-199 320 5 3 2 5
6-200 320 5 3 1 4
6-201 320 5 3 0 3
6-202 320 5 3 0 4
6-203 320 5 3 4 4
6-204 320 5 3 1 1
6-205 320 5 4 3 5
6-206 320 5 3 3 1
6-207 320 5 5 4 5
6-208 320 5 5 4 5
6-209 320 5 4 0 5
6-210 320 5 4 3 5
6-211 320 5 5 4 5
6-212 320 5 4 3 5
6-213 320 5 4 1 5
6-214 320 5 4 4 5
6-215 320 5 5 5 5
6-216 320 5 1 0 1
6-217 320 5 3 2 0
6-218 320 5 3 4 5
6-219 320 5 4 1 5
6-220 320 5 4 1 5
6-221 320 5 4 1 5
6-222 320 5 4 3 5
6-223 320 5 3 3 5
6-224 320 5 5 4 5
6-225 320 5 5 4 5
6-226 320 5 4 1 5
6-227 320 5 4 2 5
6-228 320 5 4 2 5
6-229 320 5 3 2 5
6-230 320 5 5 4 5
6-231 320 5 5 4 5
6-232 320 5 5 4 5
6-233 320 5 3 4 5
6-234 320 5 5 4 5
6-235 320 5 5 5 5
6-239 320 5 5 3 5
6-240 320 5 5 4 5
6-241 320 5 4 3 5
6-242 320 5 5 3 5
6-243 320 5 5 3 5
6-244 320 5 4 2 5
6-245 320 5 4 3 5
6-246 320 5 3 2 5
6-247 320 5 4 2 5
6-248 320 5 4 3 2
6-249 320 5 4 4 5
6-250 320 5 5 3 5
6-251 320 5 5 4 5
6-252 320 5 4 4 5
6-253 320 5 4 4 5
6-254 320 5 5 2 5
6-255 320 5 3 3 5
6-256 320 5 4 4 5
6-257 320 5 5 2 4
6-258 320 5 3 0 3
6-260 320 5 5 4 5
6-261 320 5 5 3 5
6-262 320 5 5 4 5
6-263 320 5 4 4 5
6-264 320 5 4 4 5
6-265 320 3 0 0 2
6-266 320 5 5 0 5
6-267 320 5 5 3 5
7-001 320 0 0 0 0
7-002 320 0 0 0 2
7-003 320 5 0 0 0
7-004 320 5 3 0 5
7-005 320 3 0 0 1
7-006 320 3 0 0 2
7-007 320 5 1 3 5
7-008 320 4 2 0 5
7-010 320 5 5 1 5
7-011 320 2 1 0 1
7-012 320 3 0 0 1
7-015 320 5 1 2 5
7-018 320 2 0 0 2
7-019 320 1 0 0 0
7-020 320 2 0 0 2
7-022 320 4 2 3 3
7-023 320 2 0 0 1
7-024 320 2 1 2 2
7-026 320 3 0 0 0
7-027 320 4 0 2 3
7-029 320 2 0 0 0
7-032 320 5 3 2 4
7-033 320 5 0 5
7-034 320 4 0 0 4
7-035 320 5 0 0 5
7-036 320 5 2 0 5
7-037 320 5 0 0 3
8-001 320 0 0 0 0
8-002 320 0 0 0 0
8-003 320 0 0 0 0
9-001 320 4 0 0 4
9-002 320 5 2 0 5
9-003 320 5 4 1 5
9-004 320 5 2 0 5
9-005 320 4 0 0 4
9-006 320 5 4 0 5
9-007 320 5 4 0 5
9-008 320 5 5 4 5
9-009 320 4 0 0 5
9-010 320 5 5 4 5
9-011 320 5 5 4 5
9-012 320 5 4 2 5
9-013 320 5 5 1 5
9-014 320 5 4 2 5
9-015 320 5 5 1 5
9-016 320 5 5 2 5
9-017 320 4 2 0 4
9-018 320 1 0 0 2
9-019 320 4 0 0 4
9-020 320 5 4 1 5
9-021 320 5 5 2 5
9-022 320 5 3 0 5
9-023 320 5 5 4 5
9-024 320 5 4 2 5
9-025 320 5 1 1 0
9-026 320 4 0 0 0
9-027 320 5 2 1 5
9-028 320 5 5 5 5
10-002 320 1 0 0 1
10-003 320 1 0 0 3
10-004 320 5 0 0 5
11-002 320 2 0 0 2
12-002 320 5 3 2 3
13-001 320 5 2 0 5
13-002 320 5 4 0 5
13-003 320 5 5 0 5
13-004 320 5 5 5 5
13-005 320 5 0 2 5
13-006 320 5 5 4 5
13-007 320 5 4 2 3
13-008 320 5 1 2 0
13-009 320 5 5 3 5
13-010 320 5 3 1 5
13-011 320 5 4 1 5
13-012 320 4 3 0 5
13-013 320 4 0 0 4
13-015 320 5 4 4 5
13-016 320 5 5 2 5
13-017 320 5 3 5
13-018 320 5 4 5
13-019 320 5 3 1 5
13-020 320 5 0 2
13-021 320 5 1 0 5
13-022 320 5 4 0 5
13-023 320 5 4 0 5
13-024 320 5 0 0 1
14-001 320 4 3 3 5
14-002 320 4 1 2 2
14-003 320 5 2 0 5
14-004 320 5 2 0 4
14-006 320 2 3 0 1
15-001 320 4 5 3 5
15-002 320 5 5 2 5
15-003 320 5 4 1 5
15-004 320 5 2 3 5
15-005 320 5 4 2 5
15-006 320 5 3 3 5
15-007 320 5 4 2 5
15-009 320 5 5 4 5
15-010 320 5 0 0 1
15-011 320 5 0 0 4
15-013 320 5 4 1 5
15-014 320 5 5 4 5
15-015 320 5 0 0 5
15-016 320 5 1 0 5
15-017 320 3 0 0 2
15-018 320 5 0 0 3
15-019 320 5 4 1 5
15-020 320 5 4 3 5
15-021 320 5 3 0 5
15-022 320 5 3 4 5
15-023 320 5 5 4 5
15-024 320 5 2 2 5
15-025 320 5 1 2 5
15-026 320 5 0 0 5
15-027 320 5 2 3 5
15-028 320 5 5 3 5
15-029 320 5 5 4 5
15-030 320 5 5 2 5
15-031 320 5 5 3 5
15-032 320 5 5 3 5
15-033 320 5 3 3 5
15-034 320 5 5 2 5
17-001 320 5 5 5 5
17-002 320 5 5 3 5
―――――――――――――――――――――――――
〔第２２表〕
―――――――――――――――――――――――――
Ｎｏ． 処理薬量 Ａ Ｂ Ｃ
（ｇ／hａ）
―――――――――――――――――――――――――
1-001 320 0 0 0
1-002 320 5 3 3
1-003 320 5 3 3
1-004 320 5 4 4
1-005 320 5 4 4
1-006 320 5 3 3
1-007 320 0 0 0
1-008 320 5 2 0
1-009 320 0 0 0
1-010 320 5 5 2
1-011 320 0 0 0
1-012 320 0 0 0
1-013 320 0 0 0
1-014 320 5 3 3
1-015 320 5 4 4
1-016 320 5 4 3
1-017 320 5 4 3
1-018 320 5 5 3
1-019 320 5 5 2
1-020 320 5 3 2
1-021 320 0 0 0
1-022 320 4 5 3
1-023 320 4 0 0
1-024 320 5 5 3
1-025 320 1 0 0
1-026 320 5 3 3
1-027 320 4 3 0
1-028 320 5 4 0
1-029 320 4 0 0
1-030 320 2 0 0
1-031 320 5 2 0
1-032 320 5 4 3
1-033 320 5 4 2
1-034 320 5 3 3
1-035 320 5 4 4
1-036 320 5 4 2
1-037 320 0 0 0
1-038 320 5 5 4
1-039 320 5 5 3
1-040 320 4 0 0
1-041 320 5 0 0
1-042 320 5 4 3
1-043 320 5 5 3
1-044 320 5 4 3
1-045 320 3 0 0
1-046 320 5 5 3
1-047 320 2 0 0
1-048 320 5 4 2
1-049 320 0 0 0
1-050 320 3 0 0
1-051 320 5 5 3
1-052 320 5 2 0
1-053 320 4 0 0
1-054 320 3 0 0
1-055 320 2 0 0
1-056 320 5 5 4
1-057 320 2 0 0
1-058 320 5 0 0
1-059 320 4 0 0
1-060 320 5 4 0
1-062 320 3 0 0
1-063 320 4 2 0
1-064 320 5 4 1
1-065 320 4 5 0
1-066 320 2 0 0
1-067 320 4 4 2
1-068 320 5 5 3
1-069 320 4 4 3
1-070 320 4 0 0
1-071 320 5 3
1-072 320 5 3 0
1-073 320 5 5 2
1-074 320 5 4
1-075 320 5 4
1-076 192 5 4 0
1-078 320 4 0 0
1-079 320 5 4 3
1-080 320 4 4 2
1-081 320 5 4 3
1-082 320 5 5 3
1-083 320 5 4 3
1-085 320 3 0 0
1-086 320 5 0
1-087 320 5 5 1
1-088 320 5 5 3
1-089 320 5 4 3
1-090 320 5 5 3
1-091 320 5 3 0
1-092 320 5 4 0
1-093 320 5 5 3
1-094 320 5 5 4
1-095 320 5 4 1
1-096 320 5 5
1-097 320 1 0 0
1-098 320 5 4 3
1-099 320 4 4 2
1-100 320 5 5 3
1-101 320 5 5 2
1-102 320 5 2 2
1-103 320 5 4 0
1-104 320 5 4 0
1-105 320 5 5 3
1-106 320 5 0 0
1-107 320 5 2 0
1-108 320 5 3 1
1-109 320 5 5 2
1-110 320 2 0 0
1-111 320 5 1 0
1-112 320 4 4 4
1-113 320 3 3 0
1-114 320 4 3 4
1-115 320 3 2 0
1-116 320 2 3 2
1-117 320 4 3 3
1-118 320 2 0
1-120 320 1 5 3
1-121 320 5 4 1
1-122 320 5 5 0
1-123 320 5 3 2
1-124 320 2 0 0
1-125 320 2 0 0
1-130 320 1 0 0
1-131 320 4 4 0
1-133 320 1 0 0
1-134 320 5 4 3
1-135 320 5 4 0
1-136 320 4 4 5
1-137 320 4 4 3
1-138 320 3 4 2
1-139 320 5 4 1
1-140 320 5 5 3
1-142 320 5 4
1-143 320 4 4 3
1-144 320 5 4 2
1-145 320 5 5 3
1-146 320 5 5 4
1-147 320 5 5 3
1-148 320 5 4 4
1-149 320 5 4 3
1-150 320 5 3 1
1-151 320 5 1 2
1-152 320 2 0 0
1-153 320 4 1 0
1-154 320 5 4 4
1-155 320 5 5 3
1-156 320 5 5 3
1-159 320 4 1 3
1-160 320 5 4 4
1-161 320 5 4 3
1-162 320 5 1 2
1-163 320 5 4 3
1-166 320 3 0 0
1-167 320 5 3 1
1-168 320 5 3 2
1-169 320 5 4 2
1-170 320 5 1 0
1-171 320 5 0 0
1-172 320 4 2
1-173 320 5 2
1-174 320 5 3
1-175 320 5 3
1-176 320 5 4
1-177 320 5 4 1
1-178 320 5 3
1-179 320 5 4
1-180 320 5 5 4
1-181 320 5 5 4
1-182 320 5 4 3
1-183 320 5 4
1-184 320 5 0 0
1-186 320 2 0 0
1-187 320 5 3 2
1-189 320 2 0 0
1-190 320 2 0 0
1-191 320 5 3 3
1-192 320 4 0 0
1-193 320 5 5 3
1-194 320 4 2 0
1-195 320 4 0 0
1-196 320 4 4 3
1-197 320 4 1 4
1-198 320 3 4 3
1-199 320 5 4 3
1-200 320 5 2 0
1-201 320 4 3 3
1-202 320 5 4 0
1-203 320 3 3 0
1-204 320 4 3 1
1-205 320 4 3 2
1-206 320 3 0 0
1-207 320 4 4 0
1-208 320 4 3 0
1-209 320 4 3 2
1-210 320 5 4 2
1-211 320 4 2 0
1-212 320 5 3 2
1-213 320 5 2 0
1-214 320 4 3 4
1-215 320 4 3 2
1-216 320 4 3 1
1-217 320 5 2 0
1-218 320 3 4 2
1-219 320 5 4 2
1-220 320 5 4 1
1-221 320 5 3 2
1-222 320 4 0 0
1-223 320 3 0 0
1-224 320 5 0 0
1-225 320 4 2 0
1-226 320 5 4 3
1-227 320 5 4 0
1-228 320 5 4 2
1-229 320 5 3 2
1-230 320 5 3 0
1-231 320 5 3 0
1-232 320 4 2 0
1-233 320 5 4 3
1-234 320 5 4 2
1-235 320 5 3 2
1-236 320 3 0 0
1-237 320 4 1 0
1-238 320 5 4 2
1-239 320 5 4 2
1-240 320 5 4 3
1-241 320 5 4 3
1-242 320 5 2 0
1-243 320 5 5 2
1-244 320 5 4 3
1-245 320 5 3 3
1-246 320 5 5 2
1-247 320 5 4 3
1-248 320 5 4 2
1-249 320 5 3 0
1-250 320 5 3 0
1-251 320 5 5 0
1-252 320 5 5 0
1-253 320 5 4 2
1-254 320 5 4 1
1-255 320 5 5 4
1-256 320 5 4 2
1-257 320 5 5 3
1-258 320 5 5 1
1-259 320 5 5 3
1-260 320 5 4 0
1-261 320 5 4 0
1-262 320 5 5 1
1-263 320 5 5 3
1-264 320 5 5 4
1-265 320 5 0 0
1-266 320 5 5 3
1-267 320 5 4 0
1-268 320 5 4 1
1-269 320 5 4 2
1-270 320 5 5 0
1-271 320 5 4 2
1-272 320 5 4 0
1-273 320 5 4 1
1-296 320 4 0 0
1-297 320 5 4 2
1-298 320 5 4 3
1-299 320 5 3 1
1-300 320 4 3 2
1-301 320 5 4 2
1-302 320 5 4 2
1-303 320 4 3 1
1-304 320 5 4 1
1-305 320 4 3 0
1-306 320 5 4 3
1-307 320 5 4 0
1-308 320 5 4 2
1-309 320 5 3 1
1-310 320 4 2 0
1-311 320 5 3 1
1-312 320 5 3 0
1-314 320 4 0 0
2-001 102 0 0 0
2-002 320 0 0 0
2-003 320 0 0 0
2-005 269 3 0 0
2-006 320 5 2 2
2-007 320 3 0 0
2-008 320 0 0 0
2-009 320 0 0 0
2-010 320 0 0 0
2-011 320 0 0 0
2-012 320 0 0 0
2-013 320 0 0 0
2-014 320 4 3 0
2-015 320 0 0 0
2-016 320 4 0 0
2-017 320 5 4 4
2-018 320 4 0 0
2-020 320 1 0 0
2-021 320 5 2 1
2-022 320 1 0 0
2-024 320 1 0 0
2-026 320 4 3 0
2-028 320 3 0 0
2-030 320 3 0 0
2-031 320 4 0 0
2-032 320 4 1 0
2-034 320 3 0 0
2-035 320 4 0 0
3-001 320 0 0 0
3-002 320 0 0 0
4-001 320 0 0 0
5-001 320 0 0 0
5-002 320 0 0 0
6-001 320 4 0 0
6-002 320 0 0 0
6-003 320 4 1 3
6-004 320 5 4
6-005 320 5 2 3
6-006 320 5 5 1
6-007 320 5 3 2
6-008 320 5 5 5
6-009 320 3 0 0
6-010 320 5 3 0
6-015 320 5 5 5
6-016 320 3 0 0
6-017 320 4 3 0
6-018 320 5 4 3
6-024 320 1 0 0
6-025 320 2 0 0
6-029 320 5 3 2
6-030 320 2 0 0
6-031 320 4 0 0
6-034 320 5 5 3
6-035 320 5 4 0
6-036 320 3 0 0
6-037 320 5 4 4
6-038 320 4 4 1
6-049 320 5 4 3
6-050 320 3 0 0
6-051 320 5 4 2
6-052 320 3 0 0
6-053 320 3 1 2
6-054 320 2 1 0
6-055 320 5 2 0
6-056 320 1 0 0
6-057 320 3 2 0
6-058 320 5 5 5
6-059 320 5 4 4
6-060 320 5 4 4
6-061 320 5 4 2
6-062 320 5 3 3
6-063 320 2 3 2
6-064 320 4 0 0
6-065 320 5 1 2
6-066 320 5 0 0
6-071 320 2 0 0
6-072 320 1 0 0
6-073 320 4 2 1
6-074 320 1 0 0
6-075 320 1 0 1
6-076 320 5 1 1
6-077 320 5 4 3
6-078 320 4 2 3
6-079 320 3 2 3
6-080 320 5 4 3
6-081 320 1 0 0
6-082 320 4 3 5
6-083 320 5 3 4
6-084 320 4 3 0
6-085 320 5 4 1
6-086 320 4 4 3
6-087 320 2 0 0
6-088 320 4 2 0
6-089 320 5 2 3
6-090 320 3 0 0
6-091 320 5 5 3
6-092 320 1 0 0
6-093 320 5 3 3
6-094 320 5 2 1
6-095 320 5 3 2
6-096 320 4 0 0
6-099 320 5 5 5
6-100 320 5 5 5
6-103 320 5 0 0
6-104 320 5 5 5
6-106 320 5 5 4
6-107 320 5 5 5
6-108 320 4 1 2
6-109 320 5 2 2
6-110 320 5 1 0
6-111 320 5 3 4
6-112 320 3 0 0
6-113 320 5 0 3
6-114 320 5 3 0
6-117 320 5 4 5
6-118 320 5 4 2
6-119 320 5 3 3
6-120 320 5 4 3
6-121 320 5 5 4
6-122 320 5 5 3
6-123 320 5 5 3
6-124 320 5 4 4
6-126 320 5 4 4
6-127 320 3 0 0
6-128 320 5 5 4
6-129 320 5 4 4
6-130 320 5 4 4
6-131 320 5 3 3
6-132 320 5 4 1
6-133 320 3 4 4
6-134 320 5 4 4
6-135 320 5 2 3
6-136 320 5 5 4
6-137 320 5 4 4
6-138 320 2 0 0
6-139 320 4 2 0
6-140 320 4 0 2
6-141 320 5 0 0
6-142 320 3 0 0
6-143 320 1 0 0
6-144 320 5 0 0
6-145 320 5 0 0
6-146 320 5 0 0
6-147 320 5 0 0
6-148 320 5 0 0
6-149 320 3 2 2
6-150 320 3 0 0
6-151 320 2 0 0
6-152 320 5 0 0
6-153 320 5 4 4
6-154 320 5 3 3
6-155 320 5 4 2
6-156 320 5 5 3
6-157 320 5 4 3
6-158 320 5 5 3
6-159 320 5 5 4
6-160 320 5 4 3
6-161 320 5 4 4
6-162 320 5 5 4
6-163 320 5 4 3
6-164 320 5 5 4
6-165 320 5 5 4
6-166 320 5 4 4
6-167 320 5 5 4
6-168 320 5 5 4
6-169 320 5 5 4
6-170 320 5 4 2
6-171 320 5 5 3
6-172 320 5 3 2
6-173 320 5 5 4
6-174 320 5 5 4
6-175 320 5 4 4
6-176 320 5 5 3
6-177 320 5 4 4
6-178 320 5 5 4
6-179 320 5 4 3
6-180 320 5 5 4
6-181 320 5 4 2
6-182 320 5 5 3
6-183 320 5 4 2
6-184 320 5 5 3
6-185 320 5 5 3
6-186 320 5 4 0
6-187 320 5 4 2
6-188 320 5 4 1
6-189 320 5 2 0
6-190 320 5 4 1
6-191 320 5 1 1
6-192 320 5 5 4
6-193 320 5 5 3
6-195 320 3 0 0
6-196 320 5 4 3
6-197 320 3 1 0
6-198 320 5 3 0
6-199 320 5 1 0
6-200 320 5 0 0
6-201 320 5 2 0
6-202 320 5 0 0
6-203 320 5 2 2
6-204 320 5 2 0
6-205 320 5 3 3
6-206 320 4 0 0
6-207 320 5 5 4
6-208 320 5 5 4
6-209 320 4 3 3
6-210 320 5 3 3
6-211 320 5 5 4
6-212 320 5 4 2
6-213 320 5 3 3
6-214 320 5 3 2
6-215 320 5 3 3
6-216 320 4 0 0
6-217 320 4 0 0
6-218 320 5 1 1
6-219 320 5 4 2
6-220 320 5 3 0
6-221 320 5 2 1
6-222 320 5 3 3
6-223 320 5 4 3
6-224 320 5 4 4
6-225 320 5 4 4
6-226 320 5 4 3
6-227 320 5 4 3
6-228 320 5 4 4
6-229 320 5 1 1
6-230 320 5 5 4
6-231 320 5 4 3
6-232 320 5 5 4
6-233 320 5 3 3
6-234 320 5 4 4
6-235 320 5 4 4
6-239 320 5 5 4
6-240 320 5 5 4
6-241 320 5 4 4
6-242 320 5 5 4
6-243 320 5 3 4
6-244 320 5 2 3
6-245 320 5 3 3
6-246 320 5 3 3
6-247 320 5 4 3
6-248 320 5 3 3
6-249 320 5 4 3
6-250 320 5 4 4
6-251 320 5 3 3
6-252 320 5 4 3
6-253 320 5 4 2
6-254 320 5 4 4
6-255 320 4 3 2
6-256 320 5 4 3
6-257 320 5 4 2
6-258 320 4 3 3
6-260 320 5 5 4
6-261 320 5 4 4
6-262 320 5 5 4
6-263 320 5 5 4
6-264 320 5 4 4
6-266 320 4 3 0
6-267 320 5 3 2
7-001 320 0 0 0
7-002 320 0 0 0
7-003 320 2 0 0
7-004 320 4 0 0
7-005 320 1 0 0
7-006 320 2 0 0
7-007 320 5 0 3
7-008 320 4 0 0
7-010 320 5 5 1
7-011 320 3 2 0
7-012 320 3 0 0
7-013 320 2 0 0
7-015 320 5 0 0
7-018 320 1 0 0
7-020 320 1 0 0
7-024 320 1 0 0
7-027 320 3 0 2
7-031 320 0 1 2
7-032 320 5 0 0
7-033 320 5 0
7-034 320 3 0 0
7-035 320 5 0 0
7-036 320 4 0 0
7-037 320 5 0 0
8-001 320 0 0 0
8-002 320 0 0 0
8-003 320 0 0 0
9-001 320 4 0 0
9-002 320 5 0 0
9-003 320 5 4
9-004 320 5 2 0
9-005 320 3 0 0
9-006 320 5 4
9-007 320 5 4
9-008 320 5 4 3
9-009 320 2 0 0
9-010 320 4 4 1
9-011 320 5 5 4
9-012 320 5 4 2
9-013 320 5 5 3
9-014 320 2 0 0
9-015 320 5 3
9-016 320 5 4 1
9-017 320 1 0 0
9-018 320 1 0 0
9-019 320 3 0 0
9-020 320 4 4 0
9-021 320 5 5
9-022 320 4 0 0
9-023 320 5 4 1
9-024 320 3 3 1
9-027 320 3 0 0
9-028 320 5 4 4
9-029 320 0 0 0
10-002 320 1 0 0
10-003 320 3 0 0
10-004 320 5 0 0
11-002 320 2 0 0
12-002 320 5 3 1
13-001 320 5 0 0
13-002 320 5 5 2
13-003 320 5 4 3
13-004 320 5 5 4
13-005 320 5 2
13-006 320 5 3 4
13-007 320 5 4 1
13-008 320 3 0 0
13-009 320 5 4 4
13-010 320 5 2 0
13-011 320 5 4 3
13-012 320 5 2 0
13-013 320 3 0 0
13-015 320 5 3 4
13-016 320 5 4 4
13-017 320 5 5 4
13-018 320 5 4 4
13-019 320 5 2 1
13-020 320 4 0 0
13-021 320 4 0 0
13-022 320 5 3 0
13-023 320 5 3 2
13-024 320 3 0 0
14-001 320 5 0 1
14-002 320 5 0 0
14-003 320 5 2 0
14-004 320 5 1 0
14-006 320 4 0 0
15-001 320 5 3 3
15-002 320 5 2 0
15-003 320 5 2 0
15-004 320 5 1 0
15-005 320 5 0 0
15-006 320 5 2 1
15-007 320 5 0 0
15-009 320 5 3 3
15-010 320 4 0 0
15-011 320 5 0 3
15-013 320 5 4 3
15-014 320 5 4 4
15-015 320 5 0
15-016 320 2 1 0
15-018 320 3 2 0
15-019 320 5 0 0
15-020 320 5 2 0
15-021 320 4 2 0
15-022 320 4 0 0
15-023 320 5 3 4
15-024 320 5 2 3
15-025 320 5 3 3
15-026 320 5 0 0
15-027 320 5 1 2
15-028 320 5 5 2
15-029 320 5 4 4
15-030 320 5 1 3
15-031 320 5 4 3
15-032 320 5 3 2
15-033 320 5 2 1
15-034 320 5 3 2
17-001 320 5 5 3
17-002 320 5 5 2
―――――――――――――――――――――――――
〔第２３表〕
―――――――――――――――――――――――――
Ｎｏ． 処理薬量 Ｈ Ｄ Ｅ ｂ
（ｇ／hａ）
―――――――――――――――――――――――――
1-001 320 0 0 0 0
1-002 320 5 5 5 5
1-003 320 5 5 5 5
1-004 320 5 5 5 5
1-005 320 5 5 5 5
1-006 320 5 5 5 5
1-007 320 0 5 0 0
1-008 320 5 5 4 5
1-009 320 0 0 0 0
1-010 320 5 5 5 5
1-011 320 0 5 0 0
1-012 320 0 0 0 0
1-013 320 0 2 0 0
1-014 320 5 5 5 5
1-015 320 5 5 5 5
1-016 320 5 5 5 5
1-017 320 5 5 5 5
1-018 320 5 5 3 5
1-019 320 5 5 5 5
1-020 320 5 5 2 5
1-021 320 2 0 0 0
1-022 320 5 5 4 5
1-023 320 5 5 0 4
1-024 320 5 5 5 5
1-025 320 5 5 5 5
1-026 320 5 5 5 5
1-027 320 5 5 5 5
1-028 320 5 5 5 5
1-029 320 5 5 4 5
1-030 320 5 5 3 5
1-031 320 3 4 0 5
1-032 320 5 5 5 5
1-033 320 5 5 5 5
1-034 320 5 5 5 5
1-035 320 5 5 5 5
1-036 320 5 5 5 5
1-037 320 0 0 0 0
1-038 320 5 5 5 5
1-039 320 5 5 5 5
1-040 320 5 4 4 5
1-041 320 5 5 5 5
1-042 320 5 5 5 5
1-043 320 5 5 5 5
1-044 320 5 5 5 5
1-045 320 5 4 0 3
1-046 320 5 5 5 5
1-047 320 1 3 0 2
1-048 320 5 4 5 5
1-049 320 0 0 0 0
1-050 320 5 4 5 5
1-051 320 5 5 5 5
1-052 320 5 5 5 5
1-053 320 5 5 4 5
1-054 320 5 5 0 5
1-055 320 5 5 4 5
1-056 320 5 5 5 5
1-057 320 4 3 3 5
1-058 320 5 5 5 5
1-059 320 4 1 3 5
1-060 320 5 5 5 5
1-062 320 4 3 4 5
1-063 320 5 5 5 5
1-064 320 5 5 5 5
1-065 320 5 5 5 5
1-066 320 5 2 5 5
1-067 320 5 5 5 5
1-068 320 5 5 5 5
1-069 320 5 5 5 5
1-070 320 5 4 4 5
1-071 320 5 5 5 5
1-072 320 4 5 4 5
1-073 320 5 5 5 5
1-074 320 5 5 5 5
1-075 320 5 5 5 5
1-076 192 5 5 5 5
1-078 320 5 4 0 5
1-079 320 5 5 5 5
1-080 320 5 5 5 5
1-081 320 5 5 5 5
1-082 320 5 5 5 5
1-083 320 5 5 5 5
1-084 320 2 0 0 1
1-085 320 5 4 0 5
1-086 320 5 4 4 5
1-087 320 5 5 5 5
1-088 320 5 5 5 5
1-089 320 5 5 5 5
1-090 320 5 5 5 5
1-091 320 5 5 5 5
1-092 320 5 5 5 5
1-093 320 5 5 5 5
1-094 320 5 5 4 5
1-095 320 5 5 5 5
1-096 320 5 5 5 5
1-098 320 5 5 5 5
1-099 320 5 5 5 5
1-100 320 5 5 5 5
1-101 320 5 5 5 5
1-102 320 5 5 5 5
1-103 320 5 5 5 5
1-104 320 5 5 5 5
1-105 320 5 5 5 5
1-106 320 5 5 5 5
1-107 320 5 5 5 5
1-108 320 5 5 5 5
1-109 320 5 5 5 5
1-110 320 5 5 5 5
1-111 320 5 5 5 5
1-112 320 5 5 5 5
1-114 320 5 5 2 5
1-116 320 5 3 4 5
1-117 320 5 4 5 5
1-118 320 4 0 0 5
1-119 320 5 4 0 5
1-120 320 5 0 4 3
1-121 320 5 5 4 5
1-122 320 5 5 5 5
1-123 320 5 5 4 5
1-124 320 5 5 0 5
1-125 320 5 5 2 5
1-126 320 3 5 2 5
1-130 320 4 5 4 5
1-131 320 5 5 5 5
1-132 320 2 1 0 1
1-133 320 3 0 0 0
1-134 320 5 5 5 5
1-135 320 5 4 5
1-136 320 5 2 5
1-137 320 5 5 5
1-138 320 3 2 5
1-139 320 5 5 5 5
1-140 320 5 5 5
1-141 320 2 0 1
1-142 320 5 5 5
1-143 320 4 4 5
1-144 320 5 5 5
1-145 320 5 5 5
1-146 320 5 5 5
1-147 320 5 5 5
1-148 320 5 5 4 5
1-149 320 5 5 5 5
1-150 320 5 4 5
1-151 320 4 4 5
1-152 320 5 5 5 5
1-153 320 5 5 4 5
1-154 320 5 5 5 5
1-155 320 5 5 5 5
1-156 320 5 5 5 5
1-157 320 0 4 0
1-158 320 0 2 0 2
1-159 320 4 5 4 5
1-160 320 5 5 5 5
1-161 320 4 5 4 5
1-162 320 5 5 5 5
1-163 320 5 5 5 5
1-164 320 2 3 0 4
1-166 320 4 4 3
1-167 320 5 5 5 5
1-168 320 5 5 5 5
1-169 320 5 5 5 5
1-170 320 5 5 4 5
1-171 320 5 4 4 5
1-172 320 5 5 5 5
1-173 320 5 5 5 5
1-174 320 5 5 5 5
1-175 320 5 5 5 5
1-176 320 5 5 5 5
1-177 320 5 5 5 5
1-178 320 5 5 5 5
1-179 320 5 5 5 5
1-180 320 5 5 5 5
1-181 320 5 5 5 5
1-182 320 4 5 5 5
1-183 320 5 5 5 5
1-184 320 5 5 4 5
1-186 320 4 5 4 5
1-187 320 5 5 4 5
1-188 320 4 4 4 4
1-189 320 4 5 5 4
1-190 320 4 3 0 5
1-191 320 5 5 4 5
1-192 320 2 4 0 4
1-193 320 5 5 5 5
1-194 320 5 5 4 5
1-195 320 5 5 4 5
1-196 320 5 5 5 5
1-197 320 5 5 4 5
1-198 320 5 5 4 5
1-199 320 5 5 5 5
1-200 320 5 5 4 5
1-201 320 5 5 4 5
1-202 320 5 5 2 5
1-203 320 5 5 5 5
1-204 320 5 5 5 5
1-205 320 5 5 5 5
1-206 320 5 5 4 5
1-207 320 5 5 5 5
1-208 320 5 5 4 5
1-209 320 5 5 5 5
1-210 320 5 5 5 5
1-212 320 5 5 0 5
1-213 320 5 5 2 5
1-214 320 5 5 3 5
1-215 320 5 5 5 5
1-216 320 5 5 5 5
1-217 320 5 5 5 5
1-218 320 5 5 5 5
1-219 320 5 5 3 5
1-221 320 5 5 0 5
1-222 320 3 2 0 4
1-223 320 5 5 3 5
1-224 320 5 2 0 5
1-225 320 4 5 2 5
1-226 320 5 5 5 5
1-227 320 5 5 5 5
1-228 320 5 5 5 5
1-229 320 5 5 5 5
1-230 320 5 4 3 5
1-231 320 5 4 4 5
1-232 320 3 3 0 4
1-233 320 5 3 3 5
1-234 320 3 2 0 5
1-235 320 3 2 0 5
1-236 320 2 0 0 0
1-238 320 5 5 4 5
1-239 320 5 5 4 5
1-240 320 5 5 4 5
1-241 320 5 5 3 5
1-242 320 5 5 3 4
1-243 320 5 5 5 5
1-244 320 5 5 5 5
1-245 320 5 5 5 5
1-246 320 5 5 5 5
1-247 320 5 5 5 5
1-248 320 5 5 5 5
1-249 320 4 5 4 5
1-250 320 5 5 5 5
1-251 320 5 5 5 5
1-252 320 5 5 5 5
1-253 320 5 5 5 5
1-254 320 5 5 5 5
1-255 320 5 5 5 5
1-256 320 5 5 5 5
1-257 320 5 5 5 5
1-258 320 5 5 5 5
1-259 320 5 5 5 5
1-260 320 5 5 5 5
1-261 320 5 5 5 5
1-262 320 5 5 5 5
1-263 320 5 5 5 5
1-264 320 5 5 5 5
1-265 320 5 5 5 5
1-266 320 5 5 5 5
1-267 320 5 5 5 5
1-268 320 5 5 5 5
1-269 320 5 5 5 5
1-270 320 5 5 5 5
1-271 320 5 5 5 5
1-272 320 5 5 5 5
1-273 320 5 5 5 5
1-296 320 5 5 4 5
1-297 320 5 5 5 5
1-298 320 5 5 5 5
1-299 320 5 5 5 5
1-300 320 5 5 5 5
1-301 320 5 5 5 5
1-302 320 5 5 5 5
1-303 320 5 5 5 5
1-304 320 5 5 5 5
1-305 320 5 5 5 5
1-306 320 5 5 5 5
1-307 320 5 5 5 5
1-308 320 5 5 5 5
1-309 320 5 5 5 5
1-310 320 5 5 4 5
1-311 320 5 5 5 5
1-312 320 5 5 5 5
1-313 320 3 3 0 4
1-314 320 4 3 0 4
2-001 102 5 5 5 5
2-002 320 0 0 0 0
2-003 320 5 5 4 4
2-005 269 5 5 4 5
2-006 320 5 5 5 5
2-007 320 5 5 5 5
2-008 320 0 0 0 0
2-009 320 3 0 0 1
2-010 320 3 0 0 1
2-011 320 0 0 0 0
2-012 320 0 0 0 0
2-013 320 0 0 0 0
2-014 320 5 4 5 5
2-015 320 1 0 0 4
2-016 320 5 5 4 5
2-017 320 5 5 5 5
2-018 320 5 5 5 5
2-020 320 2 2 0 2
2-021 320 5 3 3 5
2-022 320 1 4 2 5
2-024 320 5 3 0 5
2-025 320 3 1 0 4
2-026 320 5 4 5 5
2-027 320 3 0 0 5
2-028 320 5 5 4 5
2-029 320 0 0 0 4
2-030 320 4 5 0 5
2-031 320 5 5 5 5
2-032 320 5 3 4 5
2-034 320 4 4 4 5
2-035 320 5 5 3 5
3-001 320 3 2 0 2
3-002 320 0 0 0 0
4-001 320 2 3 0 4
5-001 320 2 3 0 5
5-002 320 0 0 0 0
6-001 320 5 5 0 5
6-002 320 4 4 0 5
6-003 320 5 5 5 5
6-004 320 5 5 5 5
6-005 320 5 5 3 5
6-006 320 5 5 5 5
6-007 320 5 5 5 5
6-008 320 5 5 5 5
6-009 320 5 5 0 5
6-010 320 5 5 5 5
6-015 320 5 5 5 5
6-016 320 5 5 1 5
6-017 320 5 5 4 5
6-018 320 5 5 5 5
6-023 320 5 5 4 5
6-024 320 3 2 3 3
6-025 320 5 5 4 5
6-026 320 5 5 5 5
6-027 320 2 3 0 0
6-029 320 5 5 5 5
6-030 320 4 5 0 2
6-031 320 3 2 2 4
6-033 320 0 0 3 0
6-034 320 5 5 4 5
6-035 320 5 5 5 5
6-036 320 4 5 3 4
6-037 320 5 5 5 5
6-038 320 5 5 5 5
6-049 320 5 5 5 5
6-050 320 5 5 5 5
6-051 320 5 5 5 5
6-052 320 5 5 3 5
6-053 320 5 5 3 5
6-054 320 5 5 3 5
6-055 320 5 5 5 5
6-056 320 4 5 3 5
6-057 320 5 5 5 5
6-058 320 5 5 5 5
6-059 320 5 5 5 5
6-060 320 5 5 5 5
6-061 320 5 5 5 5
6-062 320 5 5 5 5
6-063 320 4 5 1 5
6-064 320 5 5 0 4
6-065 320 5 5 5 5
6-066 320 5 5 5 5
6-068 320 0 2 0 0
6-070 320 0 4 0 0
6-071 320 4 5 0 1
6-072 320 5 5 0 0
6-073 320 5 5 5 5
6-074 320 4 5 2 1
6-075 320 3 3 3 4
6-076 320 5 5 5 5
6-077 320 5 5 5 5
6-078 320 5 5 0 5
6-079 320 5 5 4 5
6-080 320 5 5 5 5
6-081 320 1 3 0 0
6-082 320 5 5 5 5
6-083 320 5 5 5 5
6-084 320 5 5 5 5
6-085 320 5 5 5 5
6-086 320 5 5 5 5
6-087 320 5 5 0 5
6-088 320 5 5 5 5
6-089 320 5 5 4 5
6-090 320 0 5 0 0
6-091 320 5 5 5 5
6-092 320 5 5 4 5
6-093 320 5 5 4 5
6-094 320 5 5 5 5
6-095 320 5 5 5 5
6-096 320 5 4 5 5
6-098 320 3 5 4 5
6-099 320 5 5 5 5
6-100 320 5 5 5 5
6-103 320 5 5 5 5
6-104 320 5 5 5
6-105 320 3 4 4
6-106 320 4 5 5
6-107 320 5 5 5
6-108 320 5 5 5
6-109 320 5 4 5
6-110 320 5 5 5
6-111 320 5 5 5
6-112 320 5 5 4 5
6-113 320 5 5 5 5
6-114 320 5 5 5 5
6-115 320 5 5 4 5
6-117 320 5 5 5 5
6-118 320 5 5 4 5
6-119 320 5 5 5 5
6-120 320 5 5 4 5
6-121 320 5 5 5 5
6-122 320 5 5 4 5
6-123 320 5 5 5 5
6-124 320 5 5 5 5
6-125 320 0 3 0 0
6-126 320 5 5 5 5
6-127 320 5 5 4 5
6-128 320 5 5 5 5
6-129 320 5 5 3 5
6-130 320 5 5 4 5
6-131 320 5 5 5 5
6-132 320 5 5 5 5
6-133 320 5 5 0 5
6-134 320 5 5 3 5
6-135 320 5 3 3 5
6-136 320 5 5 5 5
6-137 320 5 5 5 5
6-138 320 5 0 0 5
6-139 320 5 0 0 5
6-140 320 5 2 0 5
6-141 320 5 4 4 5
6-142 320 5 0 0 5
6-143 320 5 0 0 5
6-144 320 4 0 0 5
6-145 320 4 0 0 5
6-146 320 5 4 0 5
6-147 320 5 4 1 5
6-148 320 5 2 0 5
6-149 320 5 4 2 5
6-150 320 5 4 0 5
6-151 320 5 3 0 5
6-152 320 5 5 0 5
6-153 320 5 5 5 5
6-154 320 5 5 4 5
6-155 320 5 5 5 5
6-156 320 5 5 5 5
6-157 320 5 5 5 5
6-158 320 5 5 5 5
6-159 320 5 5 5 5
6-160 320 5 5 5 5
6-161 320 5 5 4 5
6-162 320 5 5 4 5
6-163 320 5 5 4 5
6-164 320 5 5 5 5
6-165 320 5 5 5 5
6-166 320 5 5 5 5
6-167 320 5 5 5 5
6-168 320 5 5 4 5
6-169 320 5 5 5 5
6-170 320 5 5 5 5
6-171 320 5 5 5 5
6-172 320 5 5 5 5
6-173 320 5 5 4 5
6-174 320 5 5 5 5
6-175 320 5 5 4 5
6-176 320 5 5 5 5
6-177 320 5 5 5 5
6-178 320 5 5 5 5
6-179 320 5 5 5 5
6-180 320 5 5 5 5
6-181 320 5 5 4 5
6-182 320 5 5 4 5
6-183 320 5 5 5 5
6-184 320 5 5 5 5
6-185 320 5 5 5 5
6-186 320 5 5 4 5
6-187 320 5 5 5 5
6-188 320 5 5 4 5
6-189 320 5 5 5 5
6-190 320 5 5 5 5
6-191 320 5 5 5 5
6-192 320 5 5 4 5
6-193 320 5 5 5 5
6-195 320 5 5 5 5
6-196 320 5 5 5 5
6-197 320 5 5 5 5
6-198 320 5 5 5 5
6-199 320 5 5 5 5
6-200 320 5 5 5 5
6-201 320 5 5 4 5
6-202 320 5 5 5 5
6-203 320 5 5 5 5
6-204 320 5 5 5 5
6-205 320 5 5 5 5
6-206 320 5 5 4 5
6-207 320 5 5 5 5
6-208 320 5 5 5 5
6-209 320 5 5 5 5
6-210 320 5 5 5 5
6-211 320 5 5 5 5
6-212 320 5 5 5 5
6-213 320 5 5 5 5
6-214 320 5 5 4 5
6-215 320 5 5 5 5
6-216 320 5 4 4 5
6-217 320 5 5 4 5
6-218 320 5 5 5 5
6-219 320 5 5 4 5
6-220 320 5 5 5 5
6-221 320 5 5 5 5
6-222 320 5 5 5 5
6-223 320 5 5 5 5
6-224 320 5 5 5 5
6-225 320 5 5 5 5
6-226 320 5 5 5 5
6-227 320 5 5 5 5
6-228 320 5 5 5 5
6-229 320 5 5 5 5
6-230 320 5 5 5 5
6-231 320 5 5 5 5
6-232 320 5 5 5 5
6-233 320 5 5 5 5
6-234 320 5 5 5 5
6-235 320 5 5 5 5
6-237 320 2 5 4 5
6-239 320 5 5 5 5
6-240 320 5 5 5 5
6-241 320 5 5 5 5
6-242 320 5 5 5 5
6-243 320 5 5 5 5
6-244 320 5 5 5 5
6-245 320 5 5 5 5
6-246 320 5 5 5 5
6-247 320 5 5 5 5
6-248 320 5 5 4 5
6-249 320 5 5 5 5
6-250 320 5 5 5 5
6-251 320 5 5 5 5
6-252 320 5 5 5 5
6-253 320 5 5 5 5
6-254 320 5 5 5 5
6-255 320 5 5 5 5
6-256 320 5 5 5 5
6-257 320 5 5 5 5
6-258 320 4 4 3 4
6-259 320 5 5 5 5
6-260 320 5 5 5 5
6-261 320 5 5 5 5
6-262 320 5 5 5 5
6-263 320 5 5 5 5
6-264 320 5 5 5 5
6-265 320 4 4 4 0
6-266 320 5 2 0 5
6-267 320 5 5 5 5
7-001 320 4 5 0 2
7-002 320 5 5 3 5
7-003 320 5 5 0 5
7-004 320 5 5 5 5
7-005 320 5 5 0 5
7-006 320 5 5 0 5
7-007 320 5 5 4 5
7-008 320 5 5 5 5
7-010 320 5 5 5 5
7-011 320 5 4 5 5
7-012 320 5 5 4 5
7-014 320 4 5 2 5
7-015 320 5 5 5 5
7-016 320 0 5 0 0
7-017 320 5 5 4 5
7-018 320 3 5 3 3
7-019 320 5 4 2 3
7-020 320 4 5 3 4
7-021 320 2 2 0 0
7-022 320 0 4 0 0
7-023 320 0 5 0 0
7-024 320 5 5 2 3
7-025 320 1 3 0 0
7-026 320 0 3 0 0
7-027 320 5 5 4 5
7-028 320 0 0 0 0
7-029 320 3 4 0 0
7-031 320 4 5 3 5
7-032 320 5 0 0 4
7-033 320 5 4 3 5
7-034 320 4 2 0 3
7-035 320 5 5 0 5
7-036 320 5 5 4 5
7-037 320 5 5 4 5
7-042 320 3 0 0 0
8-001 320 0 0 0 0
8-002 320 0 0 0 0
8-003 320 0 0 0 0
9-001 320 5 4 2 5
9-002 320 5 5 5 5
9-003 320 5 5 5 5
9-004 320 5 5 5 5
9-005 320 5 5 2 4
9-006 320 5 5 5 5
9-007 320 5 5 5 5
9-008 320 5 5 5 5
9-009 320 5 5 4 5
9-010 320 5 5 5 5
9-011 320 5 5 5 5
9-012 320 5 5 5 5
9-013 320 5 5 5 5
9-014 320 5 5 5 5
9-015 320 5 5 5 5
9-016 320 5 5 5 5
9-017 320 5 5 3 5
9-018 320 2 0 0 4
9-019 320 5 5 4 5
9-020 320 5 5 5 5
9-021 320 5 5 5 5
9-022 320 5 5 5 5
9-023 320 5 5 5 5
9-024 320 5 5 5 5
9-025 320 0 5 0 2
9-026 320 0 3 0 0
9-027 320 5 5 5 3
9-028 320 5 5 5
9-029 320 4 4 3
9-030 320 4 5 4 1
9-034 320 2 5 3 3
9-039 320 3 3 0 3
9-040 320 3 4 0 3
9-041 320 4 4 2 4
9-042 320 4 5 3 4
9-043 320 2 4 3 2
9-044 320 3 0 0 3
9-045 320 4 5 0 5
10-001 320 5 4 0 3
10-002 320 5 5 3 5
10-003 320 5 4 0 5
10-004 320 5 5 5 5
11-002 320 5 5 4 5
12-002 320 5 5 5 5
13-001 320 5 5 4 5
13-002 320 5 5 5 5
13-003 320 5 5 5 5
13-004 320 5 5 5 5
13-005 320 5 5 5 5
13-006 320 5 5 5 5
13-007 320 5 4 4 5
13-008 320 5 4 1 5
13-009 320 5 5 4 5
13-010 320 5 5 5 5
13-011 320 5 5 5 5
13-012 320 5 5 5 5
13-013 320 4 5 4 5
13-014 320 2 3 4 2
13-015 320 5 5 5 5
13-016 320 5 5 5 5
13-017 320 5 5 5 5
13-018 320 5 5 5 5
13-019 320 5 3 0 5
13-020 320 5 0 0 5
13-021 320 5 3 1 5
13-022 320 5 2 0 5
13-023 320 5 1 3 5
13-024 320 5 0 0 5
14-001 320 5 5 5 5
14-002 320 5 5 5 5
14-003 320 5 5 5 5
14-004 320 4 2 0 5
14-005 320 2 0 0 1
14-006 320 4 0 0 0
15-001 320 5 5 5 5
15-002 320 5 5 4 5
15-003 320 5 5 4 5
15-004 320 5 5 5 5
15-005 320 5 5 5 5
15-006 320 5 5 4 5
15-007 320 5 5 4 5
15-009 320 5 5 4 5
15-010 320 5 5 4 5
15-011 320 5 5 5 5
15-012 320 5 5 4 2
15-013 320 5 5 5 5
15-014 320 5 5 5 5
15-015 320 5 5 5 5
15-016 320 5 5 5 5
15-017 320 5 5 5 5
15-018 320 5 5 5 5
15-019 320 5 5 4 5
15-020 320 5 5 4 5
15-021 320 5 5 5 5
15-022 320 5 5 4 5
15-023 320 5 5 5 5
15-024 320 5 5 5 5
15-025 320 5 5 5 5
15-026 320 5 5 5 5
15-027 320 5 5 5 5
15-028 320 5 5 5 5
15-029 320 5 5 5 5
15-030 320 5 5 5 5
15-031 320 5 5 5 5
15-032 320 5 5 5 5
15-033 320 5 5 5 5
15-034 320 5 5 5 5
17-001 320 5 5 5 5
17-002 320 5 5 5 5
―――――――――――――――――――――――――
〔第２４表〕
―――――――――――――――――――――――――――
処理薬量
No. (g/ha) F G H I J K L M N O P Q R b c d e f g
―――――――――――――――――――――――――――
1-001 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-002 320 5 5 5 5 5 5 5 5 5 5 3 1 5 5 4 0 4 5 5
1-003 320 5 5 5 4 5 5 5 4 3 3 0 5 5 3 5 2 4
1-004 320 5 5 5 5 5 5 5 5 5 0 0 0 5 4 3 3 4 4
1-005 320 5 5 5 5 5 5 5 5 5 0 0 0 5 4 2 4 4 4
1-006 320 5 4 5 3 4 5 5 4 4 0 0 0 0 5 1 0 0 0 0
1-007 320 0 0 0 0 0 2 3 0 0 0 0 0 0 0
1-008 320 5 4 4 0 5 5 5 0 0 3 0 0 0 0
1-009 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-010 320 5 5 5 5 5 5 5 5 5 4 2 4 5 4 4 4 4 4
1-011 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-012 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-013 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-014 320 5 5 5 5 5 5 5 4 5 4 4 4
1-015 320 5 5 5 5 5 5 5 5 5 3 5 4 3 3 4
1-016 320 5 5 5 5 5 5 5 5 5 5 4 3 2 0 4
1-017 320 5 5 5 5 5 5 5 5 5 5 4 2 2 0 4
1-018 320 5 5 5 4 5 5 5 4 2 5 4 0 4 0 4
1-019 320 5 5 5 5 5 5 5 4 3 5 4 3 3 0 4
1-020 320 5 5 5 4 5 5 5 3 0 0 0 5 1 0 2 0 4
1-021 320 0 0 0 0 0 2 0 0 0 0 0 2 0 0 0 0 0
1-022 320 5 5 5 4 5 5 5 0 0 5 0 0 4 3
1-023 320 4 3 3 0 0 3 4 0 0 0 0 0 5 0 0 0 0 0
1-024 320 5 5 5 4 5 5 5 3 4 0 5 1 1 4 0 3
1-025 320 5 5 5 3 4 5 5 0 0 0 0 5 0 0 0 0 4
1-026 320 5 5 5 3 5 5 5 0 0 0 4 0 0 2 3
1-027 320 5 5 5 4 5 5 5 0 0 0 5 4 0 3 0 4
1-028 320 5 5 5 4 5 5 5 3 3 5 0 0 4 0 4
1-029 320 5 5 5 4 3 5 5 0 0 0 5 0 0 0 0 3
1-030 320 3 2 2 0 3 5 3 0 0 4 0 0 0 0
1-031 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3
1-032 320 5 5 5 5 5 5 5 4 4 5 4 0 5 4 5
1-033 320 5 5 5 4 5 5 5 5 5 0 3 4 5 4 0 5 4 5
1-034 320 5 5 5 5 5 5 5 5 5 5 4 5 4 0 4 4 5
1-035 320 5 5 5 4 5 5 5 5 5 0 5 4 0 4 3 5
1-036 320 5 5 5 5 5 5 5 5 5 5 3 0 3 3 5
1-037 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-038 320 5 5 5 0 5 5 5 4 3 0 0 0 0 5 3 1 3 0 4
1-039 320 5 5 5 4 5 5 5 5 5 5 4 0 4 3 4
1-040 320 4 4 5 3 4 4 5 0 0 0 5 0 0 0 0 3
1-041 320 5 5 5 5 5 5 5 3 3 0 3 5 4 1 4 4
1-042 320 5 5 5 3 5 5 5 5 4 0 0 5 3 0 1 0 4
1-043 320 5 5 5 4 5 5 5 4 4 0 5 4 1 4 4 5
1-044 320 5 5 5 2 5 5 5 5 4 5 4 0 2 4
1-045 320 0 0 0 0 0 4 0 0 0 0 0 0 0 0 0 0
1-046 320 5 4 5 5 5 5 5 4 2 0 5 4 0 4 0 4
1-047 320 3 0 3 0 0 3 0 0 0 0 0 0 0 4 0 0 0 0
1-048 320 5 5 5 1 5 5 5 3 1 0 0 0 0 5 3 0 2 0 0
1-049 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-050 320 5 4 4 0 0 4 0 1 0 0 0 5 0 0 0 0 0
1-051 320 5 5 5 3 5 5 5 5 4 0 0 0 5 4 3 2 0 4
1-052 320 5 5 5 4 5 5 5 4 3 0 0 0 5 3 0 5 0 3
1-053 320 5 4 5 0 3 5 3 1 0 0 0 0 5 1 0 0 0 3
1-054 320 5 5 4 0 1 5 1 0 0 0 0 0 5 0 0 0 0 1
1-055 320 5 4 4 0 1 5 2 0 0 0 0 0 5 0 0 0 0 0
1-056 320 5 5 5 3 5 5 5 4 3 0 0 5 3 0 5 0 4
1-057 320 4 4 4 0 4 5 4 3 1 0 0 5 0 0 0 0 4
1-058 320 5 5 5 1 5 5 4 4 2 0 0 0 5 4 0 0 0 3
1-059 320 4 4 4 0 3 5 5 1 0 0 4 3 0 0 0 0
1-060 320 5 5 5 3 5 5 5 4 5 0 0 0 5 4 0 2 0 3
1-062 320 5 5 5 0 5 5 4 0 0 0 0 0 0 5 4 0 0 0 3
1-063 320 5 5 5 3 5 5 5 2 0 0 5 4 0 3 0
1-064 320 5 5 5 3 5 5 5 5 4 0 0 5 5 2 3 0 4
1-065 320 5 5 5 3 5 5 5 4 5 0 0 5 5 0 4 0 4
1-066 320 4 4 5 0 5 5 5 0 0 0 0 0 0 5 4 0 0 0 0
1-067 320 5 5 5 3 5 5 5 5 5 0 0 0 5 3 0 5 0 4
1-068 320 5 5 5 3 5 5 5 4 4 0 0 0 5 5 0 4 0 4
1-069 320 5 4 5 3 5 5 5 4 4 0 0 5 5 0 4 0 4
1-070 320 4 4 4 0 5 5 5 0 0 0 0 0 0 5 1 0 0 0 0
1-071 320 5 5 5 4 5 5 5 4 4 0 0 0 5 4 0 4 4
1-072 320 5 5 5 4 5 5 5 4 5 0 0 0 5 5 0 4 0 4
1-073 320 5 5 5 4 5 5 5 5 5 5 4 0 4 4
1-074 320 5 5 5 4 5 5 5 5 5 0 0 0 0 5 4 0 4 0 4
1-075 320 5 5 5 5 5 5 5 5 0 0 5 5 0 4
1-076 192 5 5 5 4 4 5 5 4 4 0 0 0 5 2 0 4 0 4
1-078 320 5 5 2 0 3 5 4 0 0 0 0 5 4 0 0 0 1
1-079 320 5 5 5 3 5 5 5 5 4 0 0 0 5 4 1 4 0 4
1-080 320 5 5 5 3 5 5 5 4 5 0 0 5 4 1 4 0 4
1-081 320 5 5 5 3 5 5 5 4 4 0 0 0 5 4 1 4 0 4
1-082 320 5 5 5 3 5 5 5 5 5 0 0 5 4 2 3 0 4
1-083 320 5 5 5 3 5 5 5 4 5 0 0 0 5 4 1 4 0 4
1-085 320 0 5 1 0 3 3 3 0 0 0 0 0 5 0 0 0 0 0
1-086 320 2 4 4 3 3 5 3 0 0 0 0 0 5 1 0 0 0 2
1-087 320 5 5 5 3 5 5 5 5 5 0 0 0 5 3 2 5 4 5
1-088 320 5 5 5 3 5 5 5 0 1 0 0 0 5 4 0 3 0 4
1-089 320 5 5 5 2 5 5 5 2 3 0 0 0 5 5 0 4 0 4
1-090 320 5 5 5 3 5 5 5 4 0 0 0 0 5 3 0 4 0 4
1-091 320 5 5 5 3 5 5 5 1 0 0 0 0 5 5 0 4 0 3
1-092 320 5 5 5 2 4 5 5 3 3 0 0 5 5 0 4 0 4
1-093 320 5 5 5 3 5 5 5 4 3 0 0 0 0 5 5 0 4 0 4
1-094 320 5 5 5 3 5 5 5 2 4 0 0 0 5 4 1 3 0 4
1-095 320 5 5 5 3 5 5 5 4 4 0 0 0 1 5 5 0 4 0 4
1-096 320 5 5 4 3 5 5 5 4 4 0 0 0 5 4 1 3 0 3
1-097 320 0 2 2 1 2 2 0 0 0 3 0 0 0 2 1 0 0 0 3
1-098 320 5 5 5 2 5 5 5 4 4 0 0 0 5 5 2 3 0 5
1-099 320 5 5 5 2 5 5 5 5 3 0 0 0 5 5 3 3 2 5
1-100 320 5 5 5 3 5 5 5 4 2 0 0 1 5 5 2 5 0 3
1-101 320 5 5 5 3 5 5 5 5 3 0 0 0 0 5 5 2 3 3 5
1-102 320 4 5 5 0 5 5 5 0 0 0 0 5 0 0 0 0 0
1-103 320 5 5 5 3 5 5 4 5 5 0 0 0 0 5 5 1 4 0 3
1-104 320 5 5 5 3 5 5 5 4 0 0 0 0 5 1 0 1 0 2
1-105 320 5 5 5 1 5 5 5 1 4 0 0 0 0 5 1 0 3 0 3
1-106 320 5 5 5 3 5 5 5 0 0 0 0 0 0 5 1 0 3 0 3
1-107 320 5 3 5 0 5 5 5 0 0 0 0 5 0 0 0 0 2
1-108 320 5 5 5 3 5 5 5 4 0 0 0 0 5 5 0 4 0 4
1-109 320 5 5 5 2 5 5 5 4 3 0 0 0 2 5 1 0 2 0 4
1-110 320 5 5 5 4 5 5 5 0 0 0 0 0 0 5 4 0 5 0 1
1-111 320 5 5 5 3 5 5 5 4 0 0 0 0 0 5 1 1 5 0 4
1-112 320 4 5 4 3 5 5 5 0 0 0 0 0 0 5 1 0 0 0 0
1-113 320 1 0 0 3 3 5 5 0 0 0 0 0 0 2 0 0 0 0 0
1-114 320 5 5 0 3 4 5 5 0 0 0 0 0 0 3 0 0 0 0 1
1-116 320 1 3 3 3 4 4 3 2 5 0 0 0 0 1 0 0 0 0 2
1-117 320 4 5 5 0 4 4 5 0 0 0 0 0 0 5 0 0 0 0 2
1-118 320 3 2 4 0 3 3 3 0 0 0 0 0 0 5 0 0 0 0 1
1-119 320 4 4 5 4 4 5 5 0 0 0 0 0 0 5 0 0 0 0 3
1-120 320 0 0 0 0 0 4 3 0 0 0 0 0 0 0 0 0 0 0 0
1-121 320 5 5 5 4 5 5 5 0 0 0 0 0 0 5 1 0 0 0 3
1-122 320 2 3 4 2 5 5 4 0 0 0 0 0 0 4 2 0 0 0 0
1-123 320 5 5 5 4 5 5 5 3 0 0 0 0 0 5 3 0 0 0 3
1-124 320 0 3 1 0 2 3 0 0 0 0 0 0 0 1 0 0 0 0 0
1-125 320 5 5 5 3 0 5 5 0 0 0 0 0 0 5 2 0 3 0 0
1-126 320 0 0 0 0 3 4 0 0 0 0 0 0 0 0 0 0 0 0 0
1-130 320 0 0 0 0 3 3 3 0 0 0 0 0 0 0 0 0 0 0 0
1-131 320 4 5 5 3 5 5 5 0 0 0 0 3 5 0 0 0 0 4
1-133 320 4 4 4 0 5 3 0 0 0 0 0 0 0 4 0 0 0
1-134 320 5 5 5 2 5 5 3 4 0 0 0 0 5 5 0 2 0 0
1-135 320 5 5 5 3 5 5 0 0 0 0 0 2 5 0 0 0 0 2
1-136 320 5 5 5 3 5 5 0 0 0 0 0 2 0 0 3 0 3
1-137 320 5 5 5 2 5 5 0 0 0 0 0 5 0 0 0 0 0
1-138 320 4 5 0 5 5 0 0 0 0 0 0 5 0 0 0 0 0
1-139 320 5 5 5 4 5 5 5 4 3 0 0 0 5 5 0 3 0 4
1-140 320 5 5 5 4 5 5 5 5 5 0 0 0 0 5 4 1 5 0 4
1-142 320 5 5 5 3 5 5 0 0 0 0 0 5 0 0 3 0 3
1-143 320 1 1 0 2 2 4 5 0 0 0 0 0 0 0 0 2 0 0
1-144 320 5 5 5 2 4 4 0 0 0 0 0 0 5 3 0 0 0 2
1-145 320 5 5 5 4 5 5 5 4 4 0 3 0 3 5 5 0 5 0 4
1-146 320 5 5 5 4 5 5 5 5 5 0 1 0 5 5 1 0 5 3 5
1-147 320 5 5 5 5 5 5 5 5 5 0 2 0 3 5 5 0 5 0 4
1-148 320 5 5 5 0 5 5 5 5 2 0 0 0 5 3 0 0 0 4
1-149 320 5 5 5 0 5 5 5 5 4 0 0 0 5 2 0 5 0 4
1-150 320 5 0 0 2 5 5 0 0 0 0 0 0 0 1 0 0
1-151 320 5 0 3 5 5 0 0 0 0 0 0 1 0 0 0 0 0
1-152 320 0 0 0 0 3 2 0 0 0 0 0 0 0 0 0 0 0 0
1-153 320 5 1 0 0 3 4 0 0 0 0 0 0 1 0 0 2 0 0
1-154 320 5 5 5 0 5 5 5 4 4 0 0 0 0 5 0 0 3 0 4
1-155 320 5 5 5 4 5 5 5 5 0 0 0 5 3 0 3 0 4
1-156 320 5 5 5 4 5 5 5 5 0 2 5 1 0 5 1 4
1-159 320 4 3 3 0 4 5 0 0 0 0 0 0 3 0 0 1 0 0
1-160 320 5 5 5 0 5 5 4 4 0 0 0 0 5 0 0 2 0 4
1-161 320 5 0 0 0 3 3 0 0 0 0 0 3 0 0 3 0 2
1-162 320 5 5 5 3 5 5 5 4 0 0 0 0 5 2 0 4 0 4
1-163 320 5 5 5 3 5 5 4 0 0 0 0 5 1 0 0 0 4
1-167 320 5 5 5 3 5 5 5 4 3 0 0 0 5 4 0 0 0 4
1-168 320 5 5 5 4 4 5 5 4 5 0 4 5 4 1 3 0 4
1-169 320 5 5 5 4 4 5 5 4 1 0 0 0 0 5 4 0 4 0 4
1-171 320 0 0 0 0 0 3 4 0 0 0 0 0 0 0 0 0 1 0 0
1-172 320 5 5 5 4 5 5 5 5 4 0 0 0 0 5 5 0 4 0 5
1-173 320 5 5 5 5 5 5 5 5 4 0 0 0 5 3 0 3 0 5
1-174 320 5 5 5 3 5 5 5 5 4 0 0 0 0 5 4 0 4 0 4
1-175 320 5 5 5 4 5 5 5 5 5 0 0 0 5 4 0 4 0 4
1-176 320 5 5 5 3 5 5 5 5 5 0 0 0 5 5 0 4 0 4
1-177 320 5 5 5 2 5 5 5 5 5 0 0 0 0 5 5 0 0 0 4
1-178 320 5 5 5 3 5 5 5 5 4 0 0 5 5 0 0 0 4
1-179 320 5 5 5 3 5 5 5 5 5 0 0 0 0 5 5 1 0 0 4
1-180 320 5 5 5 4 5 5 5 4 4 0 0 0 0 5 4 0 5 0 4
1-181 320 5 5 5 1 5 5 5 4 4 0 0 0 0 5 5 1 4 0 4
1-182 320 5 5 5 4 5 5 5 4 5 0 0 0 0 5 4 0 3 0 4
1-183 320 5 5 5 3 5 5 5 4 5 0 0 0 0 5 4 0 4 0 4
1-184 320 5 5 5 2 5 5 5 4 4 0 0 0 0 5 4 0 3 0 4
1-186 320 5 1 4 0 3 5 5 0 0 0 0 0 0 5 0 0 0 0 0
1-187 320 5 5 4 0 0 5 4 4 1 0 0 0 5 3 1 4 0 4
1-188 320 5 5 0 5 5 3 0 0 0 0 0 5 0 0 0 0 0
1-189 320 0 0 0 0 2 2 3 0 0 0 0 0 3 0 0 0 0 0
1-191 320 5 5 3 2 5 5 5 0 0 0 0 0 5 0 0 3 0 2
1-193 320 5 5 5 4 4 5 5 4 4 0 0 0 5 4 1 3 0 4
1-194 320 5 5 5 0 5 5 4 0 0 0 0 3 5 5 0 0 0 1
1-195 320 5 5 5 0 5 5 5 0 0 0 0 0 5 3 0 0 0 1
1-196 320 5 5 5 0 5 5 5 1 3 0 0 0 5 1 0 0 0 1
1-197 320 5 5 5 0 2 3 3 0 0 0 0 0 5 1 0 2 0 0
1-198 320 5 5 5 0 3 5 0 0 0 0 0 0 5 0 0 0 0 2
1-199 320 5 5 5 3 5 5 5 3 4 0 1 5 5 4 0 3 0 3
1-200 320 5 5 5 3 5 5 5 1 0 0 0 0 3 5 5 0 4 0 3
1-201 320 0 1 0 0 5 5 0 0 0 0 0 0 0 1 0 0 0 0 0
1-202 320 0 0 0 0 5 5 5 0 0 0 0 0 0 0 0 3 0 4
1-203 320 5 4 3 3 4 5 5 3 0 0 0 0 0 3 3 1 0 0 4
1-204 320 5 5 3 4 5 5 5 3 0 0 0 0 0 5 3 0 0 0 4
1-205 320 5 5 5 4 5 5 5 4 3 0 0 0 1 5 4 2 0 0 4
1-206 320 5 5 5 4 5 5 5 4 3 0 0 0 5 4 1 0 0 4
1-207 320 5 5 5 4 5 5 5 4 4 0 0 2 5 4 2 0 0 4
1-208 320 5 5 5 4 5 5 5 4 4 0 0 0 1 5 4 2 0 0 4
1-209 320 5 5 5 5 5 5 5 4 4 0 0 0 5 5 2 0 0 4
1-210 320 5 5 5 3 5 5 5 4 1 0 0 1 5 4 0 3 0 4
1-211 320 3 1 0 0 5 5 5 0 0 0 0 0 2 0 0 0 0 2
1-212 320 5 5 5 0 5 5 5 0 0 0 0 3 5 3 0 2 0 3
1-213 320 5 5 1 0 5 5 4 0 0 0 0 0 5 1 0 1 0 0
1-214 320 5 4 0 1 3 4 4 0 0 0 0 0 0 5 1 0 0 0 1
1-215 320 5 5 5 2 5 5 5 3 0 0 0 0 0 5 3 0 0 0 1
1-216 320 5 5 4 3 5 5 5 1 0 0 0 0 0 5 2 0 0 0 1
1-217 320 5 5 5 5 5 5 5 3 0 0 0 5 4 3 0 0 3
1-218 320 5 5 5 3 5 5 5 3 0 0 0 0 0 5 3 0 0 0 3
1-219 320 5 5 4 0 5 5 5 4 0 0 0 5 4 0 3 0 4
1-221 320 5 0 0 3 5 5 5 0 0 0 0 0 1 4 0 0 4 0 2
1-222 320 0 0 0 0 0 5 5 0 0 0 0 0 0 0 0 0 0 0
1-223 320 5 5 0 0 5 5 5 0 0 0 0 0 1 0 0 0 0 0
1-224 320 5 0 1 0 3 5 0 0 0 0 0 0 3 1 0 0 0 4
1-225 320 1 0 1 0 5 5 5 0 0 0 0 0 0 2 0 0 0 0 0
1-226 320 5 5 5 4 5 5 5 5 4 0 0 0 0 5 5 3 5 0 4
1-227 320 5 5 5 5 5 5 5 5 4 0 0 0 4 5 5 3 0 0 4
1-228 320 5 5 5 4 5 5 5 4 4 0 0 0 5 4 1 4 0 4
1-229 320 5 4 2 3 5 5 5 1 0 0 0 0 0 3 1 0 0 0 0
1-230 320 5 5 2 1 5 5 5 0 0 0 0 0 3 1 0 0 0 1
1-231 320 1 1 1 3 3 5 5 0 0 0 0 0 0 4 2 0 0 0 2
1-232 320 1 1 1 0 3 4 3 0 0 0 0 0 0 0 0 0 0 0 0
1-233 320 0 0 0 0 4 5 5 0 0 0 0 0 0 3 0 0 0 0 0
1-234 320 5 5 4 2 5 0 0 0 0 0 4 2 0 0 0 0
1-235 320 5 5 5 3 5 5 4 0 0 0 0 0 5 2 0 0 0 3
1-236 320 4 2 2 3 5 5 5 0 0 0 0 0 4 0 0 0 0 4
1-237 320 5 4 1 2 4 5 5 0 0 0 0 0 0 5 0 0 0 0 2
1-238 320 5 5 5 4 5 5 5 4 2 0 2 0 0 5 4 1 3 1 5
1-239 320 5 5 5 4 5 5 5 4 3 0 0 5 4 2 1 0 5
1-240 320 5 5 5 3 5 5 5 4 2 0 0 0 5 4 2 4 0 5
1-241 320 4 5 5 4 5 5 5 4 1 0 0 0 0 5 4 1 5 0 5
1-242 320 3 0 0 3 3 0 0 0 0 0 5 0 0 4 0 4
1-243 320 5 5 5 5 5 5 4 4 0 0 0 5 5 3 5 0 5
1-244 320 5 5 5 5 5 5 5 5 4 0 0 0 5 5 3 5 0 5
1-245 320 5 5 5 5 5 5 5 4 3 0 0 0 5 4 3 4 0 5
1-246 320 5 5 5 4 5 5 5 5 4 0 0 0 5 4 3 5 0 5
1-247 320 5 5 5 5 5 5 5 4 3 0 0 0 5 5 3 4 0 5
1-248 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 1 2 0 5
1-249 320 5 5 5 4 4 4 5 0 0 0 5 4 1 0 0 5
1-250 320 5 5 5 4 5 5 4 0 0 0 5 4 1 4 0 5
1-251 320 5 5 5 4 5 5 5 3 0 0 0 0 5 4 1 2 0 4
1-252 320 5 5 5 5 5 5 5 5 3 0 0 5 5 3 3 0 5
1-253 320 5 5 5 5 5 5 5 5 3 0 0 5 5 2 3 0 5
1-254 320 5 5 5 5 5 5 5 4 3 0 0 0 5 4 3 4 3 5
1-255 320 5 5 5 5 5 5 5 5 2 0 0 5 4 3 4 3 5
1-256 320 5 5 5 5 5 5 5 3 0 0 5 5 2 4 3 5
1-257 320 5 5 5 5 5 5 5 5 2 0 0 0 5 4 2 3 0 5
1-258 320 5 5 5 5 5 5 5 5 0 0 0 0 5 4 2 4 3 5
1-259 320 5 5 5 5 5 5 4 1 0 0 5 4 2 4 3 5
1-260 320 5 5 5 5 5 5 5 5 0 0 0 5 4 3 3 1 5
1-261 320 5 5 5 5 5 5 5 5 4 0 0 5 5 4 5 1 5
1-262 320 5 5 5 5 5 5 5 5 3 0 0 5 5 4 5 2 5
1-296 320 5 5 5 3 5 4 0 0 5 3 0 0 0 5
1-297 320 5 5 5 5 5 5 5 5 5 0 0 0 5 5 3 5 0 5
1-298 320 5 5 5 5 5 5 5 4 4 0 0 0 5 5 1 5 3 5
1-299 320 5 5 5 5 5 5 5 4 5 0 0 0 5 5 2 4 3 5
1-300 320 5 5 5 5 5 5 5 4 4 0 0 0 5 5 2 5 2 5
1-301 320 5 5 5 5 5 5 5 4 4 0 0 0 5 5 1 5 0 5
1-302 320 5 5 5 5 5 5 5 4 5 0 0 0 5 5 2 4 3 5
1-303 320 5 5 5 5 5 5 5 4 4 0 0 0 5 4 1 1 0 5
1-304 320 5 5 5 5 5 5 5 0 0 0 5 5 2 5 2 5
1-305 320 5 5 5 5 5 5 5 4 0 0 0 5 5 2 4 0 5
1-306 320 5 5 5 5 5 5 5 4 4 3 0 0 5 5 2 5 3 5
1-307 320 5 5 5 5 5 5 5 5 0 0 0 5 5 2 5 0 5
1-308 320 5 5 5 5 5 5 5 4 5 0 0 5 5 2 5 2 5
1-309 320 5 5 5 5 5 5 5 5 5 0 0 5 5 2 5 2 5
1-310 320 5 5 5 5 5 5 5 0 0 0 0 0 5 1 0 0 0 0
1-311 320 5 5 5 5 5 5 5 4 5 4 1 4 4 5
1-312 320 5 5 5 5 5 5 5 5 4 0 0 0 5 3 1 4 5
1-313 320 3 5 3 0 1 5 3 0 0 0 0 0 1 0 0 0 0 0
1-314 320 2 4 1 0 1 4 3 0 0 0 0 3 0 0 0 0 0
2-001 102 5 4 5 0 4 5 2 3 1 0 0 0 5 4 0 0 0 3
2-002 320 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0
2-003 320 4 0 0 0 4 5 5 0 0 0 0 2 0 0 0 0 0
2-005 269 5 4 5 0 4 5 1 0 0 0 0 5 0 0 0 0 4
2-006 320 5 5 5 3 5 5 5 4 0 0 0 0 0 5 2 0 0 0 4
2-007 320 5 4 5 0 3 5 3 0 0 0 0 0 5 0 0 0 0 4
2-008 320 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0
2-009 320 2 0 1 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0
2-010 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2-011 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2-012 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2-013 320 1 1 1 0 0 1 0 0 0 0 0 0 0 5 0 0 0 0 0
2-014 320 5 5 5 0 2 4 2 0 0 0 0 0 5 3 0 0 0 0
2-015 320 3 3 1 0 2 5 3 0 0 0 0 4 0 0 0 0 0
2-016 320 5 5 5 0 4 5 2 0 0 5 3 0 0 2
2-017 320 5 5 5 0 3 5 3 4 0 0 0 0 5 0 0 0 0 5
2-018 320 5 5 5 0 3 5 2 4 3 0 0 5 2 0 0 0 3
2-020 320 5 5 4 0 0 4 0 0 1 0 5 3 0 0 0 0
2-021 320 5 5 4 0 5 5 0 1 2 0 0 0 5 4 0 0 0 1
2-022 320 0 4 0 0 0 4 0 0 0 0 0 0 4 0 0 0 0 0
2-024 320 5 5 4 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0
2-025 320 4 5 4 0 0 4 0 0 0 0 0 0 0 5 0 0 0 0 0
2-026 320 5 5 5 0 3 5 2 0 0 0 0 5 1 0 0 0 4
2-027 320 3 5 3 0 1 2 0 0 0 0 0 4 1 0 0 0 0
2-028 320 4 5 1 0 3 5 2 1 0 0 0 0 0 5 2 0 0 0 0
2-030 320 4 5 1 0 3 4 4 0 0 0 0 0 0 5 1 0 0 0 0
2-031 320 5 5 5 0 3 5 2 1 0 0 0 0 5 5 0 3 0 3
2-032 320 4 5 4 0 5 5 0 0 0 0 0 0 5 1 0 0 0 1
2-034 320 5 4 4 0 0 5 0 0 0 0 0 0 5 2 0 0 0 0
2-035 320 5 5 5 3 5 5 5 0 0 0 0 5 1 0 5 0 0
3-001 320 2 0 0 0 1 4 5 0 0 0 0 0 0 2 0 0 0 0 0
3-002 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
4-001 320 2 0 0 0 3 5 5 0 0 0 5 0 0 0 0 1
5-001 320 4 0 1 0 2 5 5 0 0 0 5 0 0 0 0
5-002 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
6-001 320 5 5 5 5 5 5 5 0 0 0 0 5 5 0 5 0 2
6-002 320 2 3 2 0 2 5 4 0 0 0 5 0 0 0 0 0
6-003 320 5 5 5 3 5 5 5 5 3 0 0 5 4 0 0 0 4
6-004 320 5 5 5 4 5 5 5 0 4 0 5 2 0 0 4
6-005 320 5 5 5 4 5 5 5 0 0 0 0 0 5 3 1 4 0 0
6-006 320 5 5 5 4 5 5 5 4 3 0 0 2 5 5 0 5 0 4
6-007 320 5 5 5 4 5 5 5 4 3 0 0 0 5 5 0 5 0
6-008 320 5 5 5 4 4 5 5 0 0 0 0 0 5 3 0 4 0 0
6-009 320 5 5 5 4 5 5 5 5 5 4 5 5 0 5 2 4
6-010 320 5 5 5 3 5 5 5 3 1 0 5 4 0 4 0 0
6-015 320 5 5 5 0 5 5 5 3 5 3 2 5 5 0 0 0 4
6-016 320 5 5 4 0 0 0 5 0 2 0 0 0 0 2 0 0 0 0 0
6-017 320 5 5 3 0 4 5 0 1 0 0 0 0 3 0 0 0 0 0
6-018 320 5 5 5 0 5 5 5 0 0 0 0 0 0 3 0 0 0 0 0
6-023 320 1 3 0 0 4 5 4 0 0 0 0 5 1 0 0 3
6-025 320 3 4 0 2 2 5 4 0 0 0 0 0 5 0 0 0 0 0
6-026 320 4 4 1 0 1 1 0 0 2 0 0 0 0 5 0 0 0 0 0
6-029 320 5 5 5 4 5 5 5 0 0 3 4 5 2 0 4 0 2
6-031 320 0 0 0 0 0 3 0 0 4 0 0 0 0 0 0 0 3
6-034 320 5 5 5 4 5 5 5 1 2 0 0 4 2 1 0 0 0 1
6-035 320 5 5 5 3 4 5 5 0 0 3 0 3 5 2 0 0 0 0
6-037 320 5 5 5 5 5 5 5 5 3 0 0 0 1 5 5 2 5 0 3
6-038 320 5 4 5 2 5 5 5 5 4 0 0 1 5 5 1 1 0 5
6-049 320 5 5 5 5 5 5 5 4 4 4 4 3 4 5 5 0 5 3 5
6-050 320 5 4 4 2 4 5 0 0 0 3 0 5 1 0 0 0 2
6-051 320 5 5 5 1 5 5 5 1 5 0 2 0 0 5 1 1 2 0 4
6-052 320 4 3 4 0 0 0 5 0 0 0 2 0 0 1 0 0 0 0 3
6-053 320 4 3 2 1 0 0 0 0 0 0 0 2 1 0 0 0 0
6-055 320 5 5 5 0 4 5 5 3 0 0 0 0 0 5 5 0 0 0 0
6-056 320 0 2 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0
6-057 320 5 5 5 0 3 5 4 0 0 0 0 0 0 5 1 0 1 0 1
6-058 320 5 5 5 5 5 5 5 5 5 5 5 5 5 5 0 5 4 5
6-059 320 5 5 2 3 5 1 5 0 0 0 0 3 3 0 0 0 0 0 0
6-060 320 5 5 4 0 3 3 0 0 5 0 0 0 2 3 0 0 0 0 0
6-061 320 5 5 5 4 5 5 5 1 3 3 4 5 0 0 2 0 3
6-062 320 3 5 5 0 4 0 5 0 0 3 0 3 0 0 0 0 0 0
6-063 320 5 1 0 0 0 0 5 0 0 0 0 0 0 0 0 0 0 0 0
6-064 320 5 5 5 0 4 0 5 0 0 0 0 0 0 0 0 0 0 0 0
6-065 320 5 5 5 4 5 5 5 0 4 3 4 4 3 5 5 0 5 2 3
6-066 320 5 5 5 5 5 5 5 0 2 0 0 0 3 5 4 0 4 0 2
6-073 320 5 5 5 3 2 5 0 0 0 0 0 0 0 5 3 0 2 0 3
6-074 320 0 2 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0
6-075 320 0 0 0 0 4 4 3 0 0 0 0 0 0 0 0 0 0 0 0
6-076 320 5 5 5 3 0 5 5 5 1 0 0 0 0 5 5 0 0 0 2
6-077 320 5 5 5 4 5 5 5 5 5 4 3 4 4 5 0 0 0 1 4
6-078 320 5 5 0 3 0 0 3 1 0 0 0 0 1 0 1 0 0 0
6-079 320 5 5 5 0 3 5 5 1 4 0 0 0 3 3 0 0 3 0 0
6-080 320 5 5 5 0 5 5 5 0 1 0 0 0 0 0 0 0 0 0 0
6-082 320 5 5 5 3 5 5 5 2 0 0 0 3 1 0 0 0 0 0
6-083 320 5 5 0 0 5 1 5 0 0 0 0 0 3 0 0 0 0 0 0
6-084 320 5 5 5 5 5 5 0 4 3 3 3 4 2 0 5 2 0 1
6-085 320 5 5 5 5 5 5 4 5 5 5 4 4 1 1 5 3 3 4
6-086 320 5 5 5 4 5 5 0 3 3 4 4 1 0 5 2 1 4
6-087 320 5 5 5 0 4 3 0 0 0 0 0 2 0 0 3 0 0 1
6-088 320 5 5 5 5 5 5 3 0 5 5 4 4 0 0 5 0 0 3
6-089 320 5 4 1 0 2 3 0 0 0 0 0 0 0 0 0 0 0 0
6-091 320 5 5 5 5 5 5 5 4 3 4 0 4 5 5 1 5 1 4
6-092 320 5 5 3 3 3 5 0 0 0 0 0 4 0 0 0 0 0
6-093 320 5 5 5 0 3 1 0 0 5 0 4 1 0 0 0 0 0
6-094 320 5 5 5 5 5 5 4 0 5 0 0 3 5 1 0 0 0 4
6-095 320 5 5 5 3 5 5 5 1 0 0 0 0 5 2 0 2 0 4
6-096 320 4 4 4 3 3 5 0 0 0 0 0 5 3 0 0 0 0
6-099 320 5 5 5 5 5 5 5 3 5 4 4 3 4 5 5 0 5 2 5
6-100 320 5 5 5 5 5 5 5 4 5 5 4 1 5 5 4 0 3 0 5
6-103 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 0 5 0 0
6-104 320 5 5 5 4 5 1 5 5 5 4 3 4 4 5 5 0 5 4 4
6-106 320 5 5 3 3 3 0 0 0 0 0 0 1 0 0 0 0 3
6-107 320 5 5 5 3 5 4 4 4 2 2 4 5 0 0 4 1 4
6-108 320 5 4 5 3 3 5 5 4 5 3 3 3 5 1 0 3 0 4
6-109 320 5 5 0 5 5 0 0 0 0 0 0 1 0 0 0 0 0
6-110 320 0 0 5 0 3 3 0 0 0 0 0 0 0 0 0 0 0 0
6-111 320 4 0 4 0 5 5 0 0 0 0 0 0 1 0 0 0 0 0
6-112 320 5 5 5 4 5 5 1 1 0 0 0 0 5 4 0 3 0 0
6-113 320 5 5 5 0 5 5 0 0 0 0 0 5 1 0 0 0 1
6-114 320 5 5 5 3 5 5 5 2 0 0 0 0 0 5 2 0 3 0 0
6-115 320 0 0 0 0 2 2 5 0 0 0 0 0 0 0 0 0 0 0
6-117 320 5 5 5 4 5 5 5 5 5 0 0 5 5 2 0 0 5
6-118 320 5 5 5 5 5 5 5 5 5 0 0 0 5 4 2 4 0 4
6-119 320 5 5 5 4 5 5 5 5 5 0 0 0 5 5 0 0 5
6-120 320 5 5 5 4 5 5 5 5 0 0 0 5 5 1 0 0 5
6-121 320 5 5 5 4 5 5 5 5 5 0 0 5 5 1 4 0 5
6-122 320 5 5 5 4 5 5 5 5 5 0 4 5 5 2 3 0 5
6-123 320 5 5 5 4 5 5 5 5 0 4 0 0 0 5 1 0 5 0 4
6-124 320 5 5 5 4 5 5 5 5 4 0 0 5 3 1 2 0 4
6-126 320 5 5 5 4 5 5 5 5 5 0 3 0 5 5 1 5 0 5
6-127 320 5 0 4 0 5 5 5 0 0 0 0 5 0 0 2 0 0
6-128 320 5 5 5 3 5 5 5 5 5 3 3 0 3 5 5 4 5 0 4
6-129 320 5 5 5 3 5 5 5 5 5 3 3 4 3 5 5 2 5 0 3
6-130 320 5 5 5 3 5 5 5 5 5 4 0 0 4 5 5 0 5 0 4
6-131 320 5 5 5 3 5 5 5 5 5 0 0 0 4 5 5 0 5 0 3
6-132 320 5 5 5 0 5 5 5 0 0 0 0 0 1 0 0 0 0 0
6-133 320 3 2 1 0 4 4 5 0 0 0 0 0 0 0 0 0 0 0 0
6-134 320 5 5 5 3 5 5 5 5 5 0 0 0 4 5 5 0 5 0 5
6-135 320 5 5 5 0 3 5 5 4 1 0 0 0 0 5 5 0 0 0 0
6-136 320 5 5 5 3 5 5 5 5 4 0 0 5 5 3 5 0 4
6-137 320 5 4 5 2 0 5 4 2 0 0 0 5 3 0 3 0 2
6-138 320 0 0 0 0 5 0 2 0 0 0 0 0 0 0 0 0 0 0
6-139 320 0 0 0 0 5 5 5 0 0 0 0 0 0 0 0 0 0 0
6-140 320 5 0 4 0 5 5 5 0 0 0 0 0 1 0 0 0 0 0
6-141 320 5 5 5 3 5 5 5 0 0 0 0 0 0 5 5 0 4 0 0
6-142 320 5 1 5 0 5 5 5 0 0 0 0 0 3 0 0 0 0 0
6-143 320 0 0 0 3 5 5 5 0 0 0 0 0 0 0 0 0 0 0
6-144 320 5 5 3 0 4 5 5 0 0 0 0 0 5 1 0 0 0 0
6-145 320 3 0 0 0 5 5 5 0 0 0 0 0 0 0 0 0 0 0
6-146 320 5 5 5 3 5 5 5 0 0 0 0 0 5 3 0 0 0 0
6-147 320 5 5 5 0 4 5 5 0 0 0 0 0 5 3 0 0 0 0
6-148 320 5 5 5 0 5 5 5 0 0 0 0 0 5 5 0 0 0 0
6-149 320 5 5 5 4 5 5 5 0 0 0 0 0 3 0 0 0 0 0
6-150 320 5 5 4 0 3 4 5 0 0 0 0 0 1 0 0 3 0 0
6-151 320 5 5 2 4 0 0 5 0 0 0 0 0 0 0 0 0 0 0
6-152 320 5 5 5 3 4 5 5 0 0 0 0 0 5 5 0 3 0 0
6-153 320 5 5 5 1 5 5 5 4 3 0 0 0 4 5 5 1 3 0 3
6-154 320 5 5 5 0 5 5 5 4 0 0 0 0 5 4 0 2 0 4
6-155 320 5 5 5 3 5 5 5 5 5 0 0 3 5 5 3 3 0 4
6-156 320 5 5 5 4 5 5 5 5 5 3 0 3 5 5 2 4 0 4
6-157 320 5 5 5 3 5 5 5 5 4 3 0 3 5 5 2 3 0 4
6-158 320 5 5 5 3 5 5 5 5 4 0 0 0 2 5 5 1 3 0 4
6-159 320 5 5 5 2 5 5 3 5 4 0 0 0 5 5 3 3 0 4
6-160 320 5 5 5 3 5 5 5 5 4 0 0 3 5 5 2 4 3 4
6-161 320 5 5 5 3 4 5 5 5 0 0 0 0 5 4 1 4 0 3
6-162 320 5 5 5 4 4 5 5 4 0 0 0 0 0 5 4 1 4 0 4
6-163 320 5 5 5 4 5 5 5 5 0 0 0 0 5 5 1 4 0 4
6-164 320 5 5 5 5 4 5 5 5 4 0 0 0 0 5 5 1 4 0 4
6-165 320 5 5 5 3 5 5 4 5 4 0 0 0 0 5 5 1 3 2 3
6-166 320 5 5 5 4 5 5 5 5 4 3 3 0 3 5 5 1 4 3 3
6-167 320 5 5 5 3 5 5 5 5 4 3 0 0 3 5 5 1 4 3 4
6-168 320 5 5 5 4 4 5 5 5 4 0 0 0 2 5 5 1 3 0 3
6-169 320 5 5 5 2 5 5 5 5 4 0 0 0 2 5 5 2 4 0 3
6-170 320 5 5 5 4 5 5 5 5 4 0 0 3 5 5 3 4 3 4
6-171 320 5 5 5 4 5 5 5 5 4 0 0 5 5 5 3 4 4 5
6-172 320 5 5 4 4 5 5 5 3 0 0 0 0 0 5 5 0 0 0 3
6-173 320 5 5 5 3 5 5 5 5 3 0 0 0 0 5 5 1 3 0 4
6-174 320 5 5 5 3 5 5 5 5 1 0 0 0 0 5 5 3 4 0 4
6-175 320 5 5 5 3 5 5 5 5 0 0 0 0 0 5 5 1 4 0 2
6-176 320 5 5 5 3 5 5 5 5 0 0 0 0 0 5 5 2 1 0 1
6-177 320 5 5 5 5 5 5 5 4 3 0 0 0 0 5 4 2 4 0 5
6-178 320 5 5 5 4 4 5 4 5 3 0 0 5 5 3 5 5 5
6-179 320 5 5 5 4 5 5 5 5 3 0 0 0 0 5 5 3 5 0 5
6-180 320 5 5 5 5 5 5 5 5 5 0 5 5 3 5 4 5
6-181 320 5 5 5 4 5 5 5 5 4 0 0 5 5 3 4 0 5
6-182 320 5 5 5 4 5 5 5 5 4 2 0 5 5 2 5 0 5
6-183 320 5 5 5 5 5 5 5 5 4 0 0 5 5 3 3 0 5
6-184 320 5 5 5 5 5 2 0 0 0 5 5 4 3 5
6-185 320 5 5 5 5 5 5 5 4 0 0 0 5 5 4 5 0 5
6-186 320 3 0 0 0 0 2 2 0 0 0 0 0 5 0 0 0 0 3
6-187 320 5 5 5 5 5 5 5 5 0 5 4 3 4 0 5
6-188 320 5 5 5 4 5 5 5 5 4 0 0 0 5 4 3 4 0 4
6-189 320 5 5 5 4 5 5 5 5 4 4 0 0 5 5 3 3 0 5
6-190 320 5 5 5 4 5 5 5 5 4 3 0 0 0 5 5 3 5 0 4
6-191 320 5 5 5 3 5 5 5 5 0 0 0 5 5 3 4 0
6-192 320 5 5 5 4 5 5 5 5 4 0 0 0 5 5 3 5 0 4
6-193 320 5 5 5 5 5 5 5 5 4 0 0 0 5 5 3 0 5
6-195 320 3 3 5 0 2 0 0 0 0 0 0 5 0 0 0 0 0
6-196 320 5 5 5 5 5 5 5 5 5 0 0 5 5 2 5 3 5
6-197 320 5 5 5 5 5 5 5 4 0 0 0 0 5 4 0 2 0 4
6-198 320 5 5 5 4 5 5 5 4 0 0 0 0 5 3 0 0 0 4
6-199 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 0 3 0 4
6-200 320 5 5 5 5 5 5 0 0 0 0 5 3 1 4 0 4
6-201 320 1 2 2 0 4 2 0 0 0 0 5 1 0 0 0 3
6-202 320 1 5 3 0 3 5 5 2 0 0 0 0 5 0 0 0 0 2
6-203 320 3 0 1 0 3 0 2 0 0 0 0 0 1 0 0 0 0 4
6-204 320 3 1 2 0 2 2 3 0 0 0 0 0 3 0 0 2 0 4
6-205 320 5 5 5 5 5 5 5 4 0 0 0 0 5 4 1 4 0 5
6-206 320 4 1 2 0 2 3 0 0 0 0 0 1 0 0 0 0 4
6-207 320 5 5 5 5 5 5 5 5 4 0 0 5 5 3 5 4 5
6-208 320 5 5 5 5 5 5 5 5 5 5 5 3 5 4 5
6-209 320 5 5 5 4 5 5 5 5 1 0 0 0 5 2 0 5 0 4
6-210 320 5 5 5 4 5 5 5 5 0 0 0 5 3 1 0 0 5
6-211 320 5 5 5 5 5 5 5 5 3 0 5 5 5 3 5 4 5
6-212 320 5 5 5 5 5 5 5 5 0 0 0 5 3 2 5 0 5
6-213 320 5 5 5 5 5 5 5 5 4 0 0 0 5 5 2 5 0 5
6-214 320 5 5 5 4 5 5 5 4 0 0 0 0 5 3 1 3 0 5
6-215 320 5 5 5 5 5 5 5 4 3 0 0 0 5 3 1 5 0 5
6-217 320 5 3 3 0 5 5 5 0 0 0 0 0 4 1 0 0 0 0
6-218 320 5 5 5 3 5 5 5 4 0 0 0 0 5 2 0 1 0 5
6-219 320 5 5 5 2 5 5 4 1 0 0 0 0 5 2 0 0 0 1
6-220 320 5 5 5 4 4 5 5 0 0 0 0 5 4 0 3 0 5
6-221 320 5 5 5 5 5 5 5 5 0 0 0 5 4 2 4 0 4
6-222 320 5 5 5 4 5 5 5 5 1 0 0 0 5 4 1 3 0 4
6-223 320 5 5 5 5 5 5 5 5 0 0 0 5 5 2 4 0 4
6-224 320 5 5 5 5 5 5 5 5 4 0 4 5 5 3 5 3 5
6-225 320 5 5 5 5 5 5 5 5 4 5 5 4 5 3 5
6-226 320 5 5 5 5 5 5 5 5 3 4 5 5 4 4 5 5
6-227 320 5 5 5 5 5 5 5 5 4 3 0 4 5 5 4 5 4 5
6-228 320 5 5 5 5 5 5 5 5 1 0 4 5 5 4 5 5 5
6-229 320 4 5 4 0 5 5 5 2 0 0 0 0 5 4 0 0 0 1
6-230 320 5 5 5 5 5 5 5 5 3 0 4 5 5 4 5 4 5
6-231 320 5 5 5 5 5 5 5 5 2 0 4 5 5 4 5 4 5
6-232 320 5 5 5 5 5 5 5 5 5 1 4 5 5 3 4 4 5
6-233 320 5 5 5 5 5 5 5 5 4 4 1 4 5 5 4 4 5 5
6-234 320 5 5 5 5 5 5 5 5 4 1 0 4 5 5 3 4 2 5
6-235 320 5 5 5 5 5 5 5 5 4 5 5 4 5 5 5
6-237 320 3 0 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0
6-239 320 5 5 5 5 5 5 5 5 5 3 3 4 5 5 2 5 4 5
6-240 320 5 5 5 5 5 5 5 5 4 1 2 4 5 4 2 5 3 5
6-241 320 5 5 5 5 5 5 5 5 5 4 4 4 5 5 4 5 4 4
6-242 320 5 5 5 5 5 5 5 5 5 0 1 4 5 5 3 5 2 4
6-243 320 5 5 5 4 5 5 5 5 5 4 5 5 5 5 3 5 4 5
6-244 320 5 5 5 4 5 5 5 5 1 0 0 0 5 3 1 3 0 1
6-245 320 5 5 5 4 5 5 5 5 0 0 0 1 4 1 0 4 0 4
6-246 320 5 5 5 4 5 5 5 5 4 0 0 0 5 3 0 3 0 3
6-247 320 5 5 5 5 5 5 5 5 5 4 4 4 5 5 1 5 0 4
6-248 320 5 5 5 3 5 5 5 5 3 0 0 0 5 3 0 4 0 4
6-249 320 5 5 5 4 5 5 5 5 5 0 0 4 5 5 2 5 2 4
6-250 320 5 5 5 5 5 5 5 5 5 0 0 1 5 5 4 5 1 4
6-251 320 5 5 5 4 5 5 5 5 5 1 1 2 5 5 4 5 2 5
6-252 320 5 5 5 5 5 5 5 5 4 4 4 4 5 5 4 5 2 5
6-253 320 5 5 5 4 5 5 5 5 5 3 4 4 5 4 3 5 4 4
6-254 320 5 5 5 4 5 5 5 5 5 0 0 1 5 4 2 5 1 4
6-255 320 5 5 5 4 4 5 5 5 5 0 1 1 5 2 2 4 1 4
6-256 320 5 5 5 4 5 5 5 5 4 0 1 2 5 4 2 4 1 5
6-257 320 5 2 5 1 5 5 5 4 1 0 0 0 5 0 1 4 0 4
6-258 320 3 0 1 0 4 5 3 3 0 0 0 0 3 0 0 0 0 4
6-259 320 5 5 5 0 2 5 3 3 0 0 0 0 5 1 0 0 0 1
6-260 320 5 5 5 4 5 5 5 5 5 3 3 4 5 5 3 5 1 4
6-261 320 5 5 5 4 5 5 5 5 5 4 5 5 5 2 4 5
6-262 320 5 5 5 4 5 5 5 5 5 4 4 4 5 5 3 5 3 5
6-263 320 5 5 5 5 5 5 5 5 5 4 5 4 5 5 3 4 4 5
6-264 320 5 5 5 4 5 5 5 5 5 3 3 2 5 5 3 5 3 5
6-265 320 1 4 3 0 0 1 3 0 0 0 0 0 3 0 0 0 0 0
6-266 320 4 0 1 0 4 5 5 0 0 0 0 0 0 4 0 0 0 0 0
6-267 320 5 5 5 5 5 5 5 5 3 0 0 0 2 5 4 2 4 2 5
7-001 320 5 4 4 3 0 5 0 0 0 0 4 0 0 0 0 0
7-002 320 5 4 5 0 3 5 5 0 0 0 0 0 5 0 0 0 0 0
7-003 320 5 5 5 4 5 5 5 0 0 0 0 0 0 5 0 0 0 0 0
7-004 320 5 5 5 0 5 5 5 3 2 0 0 0 5 4 0 0 0 3
7-005 320 5 0 0 0 0 2 0 0 0 0 0 0 0 1 0 0 0 0 0
7-006 320 0 0 0 0 0 2 0 0 0 0 0 0 3 0 1 0 0 0
7-007 320 4 4 5 0 5 5 5 0 0 0 0 0 0 4 3 0 0 0 0
7-008 320 5 5 5 3 5 5 5 0 0 0 0 0 5 4 0 1 0 0
7-010 320 5 5 5 2 5 5 5 4 0 0 0 3 5 5 2 4 0 3
7-011 320 5 0 4 0 3 4 3 0 0 0 0 0 5 3 0 0 0 4
7-012 320 5 5 5 0 2 2 0 0 0 0 0 0 0 5 0 0 0 0 0
7-013 320 3 0 0 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0
7-014 320 3 2 0 0 0 3 0 0 0 0 0 0 4 0 0 0 0 0
7-015 320 5 5 5 3 5 5 4 0 0 0 0 0 5 5 0 4 0 2
7-016 320 3 2 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-017 320 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-018 320 3 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-019 320 3 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-020 320 3 2 0 0 3 3 0 0 0 0 0 0 0 5 0 0 0 0 0
7-024 320 4 0 0 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0
7-027 320 5 5 5 0 5 5 5 0 0 0 0 0 0 5 3 0 2 0 0
7-029 320 0 4 2 0 1 3 0 0 0 0 0 0 1 0 0 0 0 0
7-032 320 5 4 5 0 3 5 4 0 0 0 0 0 5 4 0 0 0
7-033 320 5 5 5 3 4 5 4 0 0 0 0 0 5 5 0 0 0 0
7-035 320 4 4 5 0 3 5 3 0 0 0 0 0 0 5 4 0 0 0 0
7-036 320 3 5 5 2 5 0 0 0 0 5 1 0 0 0 0
7-037 320 4 3 5 3 4 5 4 0 0 0 0 0 5 1 0 2 0 0
8-001 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
8-002 320 3 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0
8-003 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
9-001 320 4 4 5 0 3 5 4 0 1 0 0 4 0 0 0 0 0
9-002 320 5 5 5 3 5 5 5 0 0 0 0 0 5 3 0 0 0 0
9-003 320 5 5 5 3 5 5 5 0 0 0 0 0 0 5 5 0 4 0 5
9-004 320 5 5 5 2 5 4 5 0 0 0 0 0 0 0 0 0 0 0 0
9-005 320 1 0 0 0 1 4 4 0 0 0 0 1 0 0 0 0 0
9-006 320 5 5 5 4 5 5 5 0 2 0 0 0 4 5 5 0 5 0 3
9-007 320 5 5 3 3 5 5 5 0 0 0 0 0 0 5 0 0 0 0 0
9-008 320 5 5 5 3 5 5 5 4 4 0 0 0 3 5 4 0 5 0 4
9-009 320 5 4 0 0 4 5 4 0 0 0 1 0 0 0 0 0 0
9-010 320 5 5 5 4 5 5 5 0 0 0 0 0 5 1 0 0 0 0
9-011 320 5 5 5 3 5 5 5 3 0 0 0 0 5 5 0 4 0 4
9-012 320 5 5 5 0 5 5 5 0 0 0 0 2 5 2 0 0 0 0
9-013 320 5 5 5 5 5 5 5 3 1 0 4 5 5 0 4 5 4
9-014 320 4 3 1 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0
9-015 320 5 5 5 1 5 5 5 0 0 0 0 0 5 0 0 3 0 0
9-016 320 5 5 5 2 5 5 4 0 0 0 0 5 3 0 0 0 0
9-017 320 4 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0
9-019 320 0 5 0 0 5 3 0 0 0 0 0 5 0 0 0 0 0
9-020 320 4 5 0 0 3 5 4 3 0 0 3 0 0 0 0 0
9-021 320 5 5 5 1 5 5 5 1 0 0 0 0 3 5 3 0 3 0 2
9-022 320 5 5 5 0 0 0 0 0 0 0 0 0 4 1 0 0 0 0
9-023 320 5 5 5 2 3 3 5 0 5 0 0 0 0 5 3 0 3 0 4
9-024 320 5 5 5 3 5 5 5 0 3 0 4 0 4 5 0 0 2 0 0
9-025 320 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
9-027 320 5 5 5 4 5 5 5 0 3 3 3 0 3 5 0 0 2 0 1
9-028 320 5 5 5 3 5 5 5 0 0 0 0 0 0 3 1 0 3 0 4
9-029 320 3 4 3 0 3 4 0 0 0 0 0 0 1 0 0 0 0 0
9-030 320 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
9-034 320 4 3 4 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0
9-045 320 0 0 0 0 0 1 4 0 0 0 0 0 0 2 0 0 0 0 0
10-002 320 4 4 4 3 0 4 3 0 0 0 0 0 4 0 0 0 0 0
10-003 320 0 4 5 0 3 4 3 0 0 0 0 0 0 4 0 0 0 0 0
10-004 320 5 5 5 3 5 5 5 0 0 0 0 0 5 5 0 0 0 0
11-002 320 0 1 3 3 3 5 4 0 0 0 0 0 0 4 1 0 0 0 2
12-002 320 4 5 5 4 4 5 3 0 0 0 0 0 0 4 3 0 0 0 1
13-001 320 5 5 2 4 5 5 0 0 0 0 0 0 5 5 0 0 0 0
13-002 320 5 5 5 4 4 5 0 0 0 0 0 5 5 1 3 0 1
13-003 320 5 5 5 1 5 5 4 0 0 0 0 0 5 5 0 0 0 3
13-004 320 5 5 5 3 5 5 5 0 4 0 1 0 3 5 5 1 5 0 4
13-005 320 4 0 1 0 4 5 0 0 0 0 0 0 1 0 0 1 0 0
13-006 320 5 5 5 0 5 5 5 0 0 0 0 5 1 0 4 0 3
13-007 320 5 0 4 3 4 5 4 0 0 0 0 0 0 0 0 0 0
13-008 320 0 0 0 0 3 3 0 0 0 0 0 0 0 0 0 0 0
13-009 320 5 5 5 3 5 5 5 4 0 0 0 0 5 4 0 3 0 3
13-010 320 5 5 5 4 5 5 5 4 0 0 0 0 0 5 5 1 3 0 3
13-011 320 5 5 5 3 5 5 5 3 1 0 0 0 0 5 4 0 4 0 0
13-012 320 5 5 5 3 5 5 5 4 3 0 0 0 5 5 0 0 0 3
13-013 320 4 3 4 3 2 5 0 3 1 0 0 0 0 5 0 0 0 0 2
13-014 320 0 0 0 0 0 4 0 4 0 0 0 0 4 0 0 0 0 3
13-015 320 5 5 5 3 5 5 5 5 4 0 5 5 0 4 4
13-016 320 5 5 5 3 5 5 5 5 5 0 0 5 5 1 4 0 4
13-017 320 5 5 5 2 5 5 5 4 5 0 0 0 0 5 5 0 5 0 4
13-018 320 5 5 5 4 5 5 5 4 4 0 0 0 0 5 4 1 5 0 4
13-019 320 4 5 5 2 5 5 5 0 0 0 0 0 0 5 4 0 2 0 0
13-020 320 0 0 0 0 0 5 3 0 0 0 0 1 0 0 0 0 0 0 0
13-021 320 5 5 5 0 5 5 5 0 0 0 0 0 0 5 3 0 0 0 0
13-022 320 4 4 4 3 5 5 5 0 0 0 0 1 4 3 0 0 0 0
13-023 320 4 5 5 0 5 5 5 0 0 0 0 0 2 5 1 0 3 0 0
13-024 320 0 0 0 0 3 4 4 0 0 0 0 0 0 0 0 0 0 0 0
14-001 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 0 0 0 0
14-002 320 5 5 5 0 4 5 5 0 0 0 0 0 0 5 1 0 3 0 0
14-003 320 5 5 5 3 5 5 0 0 0 0 5 5 0 3 0 4
14-004 320 4 5 5 0 0 5 5 0 0 0 0 0 0 5 2 0 0 0 0
15-019 320 5 3 5 3 5 5 0 0 0 5 0 0 3 0 0
15-001 320 5 5 5 5 5 5 5 5 0 0 0 0 2 5 4 1 2 0 4
15-002 320 5 5 5 4 4 5 5 5 4 0 0 0 3 5 4 1 3 0 4
15-003 320 5 5 5 4 5 5 5 5 0 0 0 0 0 5 3 0 3 0 2
15-004 320 5 5 5 4 5 5 5 5 0 0 0 0 5 5 1 5 0 4
15-005 320 5 5 5 4 5 5 5 5 3 0 0 0 1 5 2 0 3 0 4
15-006 320 5 5 5 3 5 5 5 5 0 0 0 0 5 1 0 3 0 0
15-007 320 5 5 5 4 5 5 5 0 0 0 0 0 0 4 0 0 0 0 0
15-009 320 5 5 5 3 5 5 5 5 0 0 0 0 0 5 3 0 4 0 0
15-010 320 0 0 0 0 5 5 5 0 0 0 0 0 0 0 0 0 0 0 0
15-011 320 5 5 5 0 4 3 5 0 0 0 0 5 0 0 0 0 0
15-012 320 0 0 0 0 2 2 5 0 0 0 0 0 0 0 0 0 0 0
15-013 320 5 5 5 4 5 5 5 5 0 0 0 5 5 5 0 4
15-014 320 5 5 5 3 5 5 5 5 0 0 0 5 0 0 0 0 0
15-015 320 5 5 5 4 4 5 5 4 0 0 0 0 5 1 0 5 0 3
15-016 320 5 0 1 0 4 4 5 0 0 0 0 5 0 0 0 0 0
15-017 320 0 0 0 0 0 1 3 0 0 0 0 3 0 0 0 0 0
15-018 320 4 0 5 0 3 3 5 0 0 0 0 0 0 0 0 0 0
15-020 320 5 5 5 0 4 5 0 0 0 0 5 0 0 0 0 0
15-021 320 5 5 5 3 5 5 0 0 0 5 0 0 0 0
15-022 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 0 5 0 5
15-023 320 5 5 5 5 5 5 5 5 5 0 0 3 5 5 4 5 4 5
15-024 320 5 5 5 4 5 5 5 3 0 0 0 0 5 0 0 0 0 2
15-025 320 5 5 5 4 5 5 5 4 0 0 0 0 5 2 2 4 0 1
15-026 320 5 5 5 3 4 5 5 0 0 0 0 0 5 0 0 0 0 0
15-027 320 5 5 5 3 4 5 5 4 0 0 0 0 5 0 0 3 0 1
15-028 320 5 5 5 4 5 5 5 5 4 0 0 4 5 4 3 5 1 4
15-029 320 5 5 5 5 5 5 5 5 4 4 1 4 5 5 4 5 1 5
15-030 320 5 5 5 4 5 5 5 5 4 1 0 1 5 5 4 5 0 4
15-031 320 5 5 5 4 5 5 5 5 3 2 0 2 5 5 2 5 0 5
15-032 320 5 5 5 4 5 5 5 5 1 0 0 1 5 3 1 5 0 4
15-033 320 5 5 5 4 5 5 5 5 2 0 0 2 5 5 2 5 0 5
15-034 320 5 5 5 4 5 5 5 5 4 2 0 0 5 4 2 5 0 4
17-001 320 5 5 5 4 5 5 5 4 4 0 0 3 5 4 0 4 0 5
17-002 320 5 5 5 3 5 5 5 4 3 2 0 2 5 5 0 2 1 4
――――――――――――――――――――――――――――
〔第２５表〕
――――――――――――――――――――――――――――
処理薬量
No. (g/ha) F G H I J K L M N O P Q R b c d e f g
――――――――――――――――――――――――――――
1-001 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-002 320 5 5 5 5 5 5 5 4 5 4 4 4 4 5 5 4 5 5 5
1-003 320 5 5 5 5 5 5 5 4 3 3 2 3 3 5 5 3 5 3 4
1-004 320 5 5 5 5 5 5 5 4 4 3 3 4 5 5 4 5 3 4
1-005 320 5 5 5 5 5 5 5 4 4 3 4 4 3 5 5 4 5 3 4
1-006 320 5 5 5 5 5 5 5 4 3 0 0 0 2 5 3 4 3 0 3
1-007 320 0 0 0 3 3 5 1 0 0 0 0 0 0 0 0 0 0 0 0
1-008 320 5 5 4 4 5 5 4 2 0 0 0 0 0 4 0 2 0 0 3
1-009 320 0 0 0 0 1 4 0 1 0 0 0 0 0 0 0 0 0 0 0
1-010 320 5 5 5 5 5 5 5 4 4 4 4 4 4 5 5 4 5 4 4
1-011 320 3 0 0 0 4 5 5 0 0 0 0 2 0 0 0 0 4
1-012 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-013 320 0 0 0 0 4 5 4 0 0 0 0 0 2 0 0 0 0 4
1-014 320 5 5 5 5 5 5 5 5 5 3 3 5 5 5 5 3 4
1-015 320 5 5 5 5 5 5 5 4 4 3 4 4 4 5 5 5 5 3 4
1-016 320 5 5 5 5 5 5 5 4 4 2 4 5 4 4 5 3 4
1-017 320 5 5 5 5 5 5 5 4 4 2 3 5 4 4 5 2 4
1-018 320 5 5 5 5 5 5 5 3 0 4 4 4 5 5 3 5 4 4
1-019 320 5 5 5 5 5 5 5 4 2 4 4 4 5 5 3 5 4 4
1-020 320 5 5 5 4 5 5 5 3 4 4 5 1 0 5 3 4
1-021 320 1 1 3 0 3 4 4 0 0 0 0 3 0 0 0 0 2
1-022 320 5 5 5 5 5 5 5 1 1 3 3 4 3 5 3 3 5 0 4
1-023 320 2 1 4 1 4 4 4 0 0 0 0 2 0 4 1 0 0 0 2
1-024 320 5 5 5 5 5 5 5 1 0 1 3 3 5 5 2 5 0 4
1-025 320 5 4 4 5 5 5 5 1 0 4 4 4 3 4 3 3 4 0 4
1-026 320 5 5 4 1 5 5 5 0 0 3 1 5 3 0 2 4
1-027 320 5 5 5 5 5 5 5 2 0 1 1 3 5 5 3 4 0 4
1-028 320 5 5 5 4 5 5 5 3 0 3 3 3 5 4 2 3 0 4
1-029 320 5 5 5 5 5 5 5 1 0 3 3 3 1 5 3 1 5 0 4
1-030 320 4 5 4 3 4 5 4 0 0 0 0 0 0 5 1 0 0 0 3
1-031 320 1 1 1 3 3 4 0 0 0 0 0 0 3 0 0 0 0 3
1-032 320 5 5 5 5 5 5 5 4 3 3 4 4 5 5 4 5 3 4
1-033 320 5 5 5 5 5 5 5 4 4 3 1 2 5 4 4 5 3 4
1-034 320 5 5 5 5 5 5 5 4 3 5 5 4 4 5 4 5
1-035 320 5 5 5 5 5 5 5 4 3 5 4 4 5 2 4
1-036 320 5 5 5 5 5 5 5 4 4 2 0 5 4 4 5 3 4
1-037 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-038 320 5 5 5 5 5 5 5 4 2 0 0 0 1 5 4 4 4 1 4
1-039 320 5 5 5 5 5 5 5 4 4 3 5 4 4 5 3 4
1-040 320 4 4 5 4 5 5 5 1 0 0 0 0 5 3 0 0 0 4
1-041 320 5 5 5 5 5 5 5 4 3 3 3 3 3 5 5 4 5 1 4
1-042 320 5 5 5 5 5 5 5 3 0 0 0 0 1 5 4 3 5 1 4
1-043 320 5 5 5 5 5 5 5 4 3 2 4 3 2 5 5 4 5 3 4
1-044 320 5 5 5 5 5 5 5 4 2 0 0 0 5 4 4 5 2 4
1-045 320 4 5 5 5 5 5 5 0 0 0 0 0 0 5 3 1 0 0 2
1-046 320 4 5 5 5 5 5 5 3 2 2 2 0 4 5 5 3 4 0 4
1-047 320 1 1 3 0 3 4 1 0 0 0 0 0 0 4 0 0 0 0 3
1-048 320 4 4 5 4 5 5 5 3 1 3 3 1 3 5 4 0 0 1 3
1-049 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-050 320 3 5 5 3 4 5 3 3 0 0 0 0 0 5 0 0 0 0 4
1-051 320 5 5 5 5 5 5 5 4 1 0 3 0 5 5 4 5 0 4
1-052 320 5 5 5 5 5 5 5 3 0 1 0 3 5 4 4 5 0 4
1-053 320 3 3 4 2 4 5 3 0 0 1 0 2 5 3 3 0 0 4
1-054 320 2 3 4 3 4 5 3 0 0 0 0 0 0 4 0 0 0 0 3
1-055 320 3 3 4 4 4 5 5 0 0 1 0 5 3 2 0 0 3
1-056 320 5 5 5 5 5 5 5 4 2 1 0 5 4 4 5 0 4
1-057 320 3 3 4 2 3 5 1 1 0 0 0 0 3 0 3 0 1 4
1-058 320 5 5 5 5 5 5 5 4 1 0 0 5 4 3 5 0 4
1-059 320 1 4 4 4 4 5 4 0 0 0 0 0 4 4 0 0 0 3
1-060 320 5 5 5 5 5 5 5 3 0 3 3 3 5 4 4 5 0 4
1-062 320 1 4 4 4 5 5 5 0 0 0 0 0 0 5 4 0 0 0 3
1-063 320 1 5 5 5 5 5 5 2 0 0 0 4 5 5 3 4 0 4
1-064 320 5 5 5 5 5 5 5 4 2 0 1 3 5 5 4 5 1 4
1-065 320 5 5 5 5 5 5 5 4 2 2 0 3 5 5 4 5 0 4
1-066 320 4 5 5 4 5 5 4 1 0 1 0 3 5 4 0 0 0 3
1-067 320 5 5 5 5 5 5 5 5 4 2 3 2 3 5 5 4 5 1 4
1-068 320 5 5 5 5 5 5 5 5 4 1 3 3 5 5 4 5 3 4
1-069 320 5 5 5 5 5 5 5 5 5 2 3 3 5 5 4 5 1 4
1-070 320 1 5 3 5 5 5 4 0 0 1 0 2 2 5 4 0 0 0 3
1-071 320 5 5 5 5 5 5 5 4 0 1 0 2 1 5 5 4 5 0 4
1-072 320 5 5 5 5 5 5 5 5 5 1 2 2 3 5 5 2 5 1 4
1-073 320 5 5 5 5 5 5 5 4 2 2 3 5 4 3 5 1 4
1-074 320 5 5 5 5 5 5 5 3 0 2 1 1 5 5 4 5 0 4
1-075 320 5 5 5 5 5 5 5 4 4 1 0 0 5 4 1 5
1-076 192 5 5 5 5 5 5 5 4 0 3 3 5 4 4 5 0 4
1-078 320 1 5 5 1 4 5 3 0 0 0 0 0 5 3 0 0 0 3
1-079 320 5 5 5 5 5 5 5 4 0 0 1 3 5 5 4 4 0 5
1-080 320 5 5 5 5 5 5 5 4 0 3 0 1 5 5 4 4 0 4
1-081 320 5 5 5 5 5 5 5 4 5 3 0 0 0 5 5 5 4 0 5
1-082 320 5 5 5 5 5 5 5 4 0 1 0 0 0 5 5 4 5 0 4
1-083 320 5 5 5 5 5 5 5 4 4 0 4 0 0 5 5 4 5 0 4
1-085 320 3 5 5 3 3 3 3 0 0 0 0 0 0 4 5 0 3 0 1
1-086 320 0 3 5 4 4 5 4 0 0 0 0 0 2 4 3 0 0 0 3
1-087 320 5 5 5 5 5 5 5 5 4 0 3 4 3 5 5 3 5 4 4
1-088 320 5 5 5 5 5 5 5 4 1 2 3 0 3 5 5 3 5 0 4
1-089 320 5 5 5 5 5 5 5 4 2 1 0 0 3 5 5 2 5 0 4
1-090 320 5 5 5 5 5 5 5 4 1 2 3 0 3 5 5 3 5 0 4
1-091 320 5 5 5 5 5 5 5 4 3 0 0 1 5 5 1 5 0 4
1-092 320 5 5 5 2 4 5 5 3 3 0 0 0 5 5 0 4 0 4
1-093 320 5 5 5 5 5 5 5 4 4 0 2 0 3 5 5 3 5 0 4
1-094 320 5 5 5 5 5 5 5 4 2 0 3 0 3 5 5 2 5 0 4
1-095 320 5 5 5 5 5 5 5 4 3 0 2 3 5 5 2 5 0 4
1-096 320 5 5 5 5 5 5 5 4 2 2 2 3 5 5 3 5 0 4
1-097 320 5 5 5 3 5 5 4 3 1 0 3 5 5 3 2 3
1-098 320 5 5 5 5 5 5 5 4 0 0 3 0 3 5 5 3 5 1 5
1-099 320 5 5 5 5 5 5 5 4 0 3 3 3 3 5 5 4 5 1 5
1-100 320 5 5 5 5 5 5 5 4 0 1 0 3 5 5 3 5 0 5
1-101 320 5 5 5 5 5 5 5 5 5 3 3 0 3 5 5 3 5 0 5
1-102 320 5 5 5 5 5 5 5 0 0 3 0 0 2 5 5 0 4 0 2
1-103 320 5 5 5 5 5 5 5 4 0 2 2 3 5 5 3 5 0 4
1-104 320 5 5 5 5 5 5 5 3 0 2 1 1 5 4 1 0 0 4
1-105 320 5 5 5 5 5 5 5 1 0 2 1 2 3 5 4 1 5 0 4
1-106 320 5 5 5 5 5 5 5 1 5 2 2 0 1 5 5 0 4 0 3
1-107 320 4 5 5 5 5 5 5 1 0 0 0 0 5 2 3 2 0 4
1-108 320 5 5 5 5 5 5 5 4 5 0 3 1 5 5 3 3 1 4
1-109 320 5 5 5 5 5 5 5 3 0 3 3 3 5 5 0 5 0 4
1-110 320 5 5 5 5 5 5 5 0 0 2 3 3 3 5 5 0 5 0 5
1-111 320 5 5 5 5 5 5 5 1 0 1 3 2 1 5 5 3 5 0 5
1-112 320 5 4 5 5 5 5 5 1 0 3 1 3 3 5 4 0 5 0 4
1-113 320 5 4 4 4 4 5 5 1 0 2 3 0 4 4 0 0 3 0 5
1-114 320 5 5 5 5 4 5 5 1 1 3 3 0 2 5 1 0 4 0 4
1-115 320 2 1 1 2 3 3 4 0 0 0 1 0 1 1 0 0 0 0 5
1-116 320 5 5 5 4 5 5 5 1 0 3 2 1 3 4 5 3 3 0 5
1-117 320 5 5 5 5 5 5 5 1 1 0 3 0 3 5 3 0 5 0 5
1-118 320 0 0 2 3 4 5 3 0 0 3 3 3 3 4 4 0 0 0 4
1-119 320 5 5 5 5 5 5 5 1 0 3 1 0 3 5 2 0 4 0 5
1-120 320 3 4 5 4 3 5 3 0 0 4 4 5 3 1 1 2 0 0 5
1-121 320 5 5 5 5 5 5 5 3 0 3 2 0 3 5 5 2 3 0 5
1-122 320 4 5 5 5 5 5 5 4 1 0 1 0 0 5 5 4 4 0 5
1-123 320 5 5 5 5 5 5 5 4 0 0 3 0 4 5 5 2 5 0 5
1-124 320 0 2 5 2 3 4 3 0 0 3 2 0 0 3 4 0 3 0 4
1-125 320 5 5 5 5 5 5 5 0 0 1 2 3 2 5 3 0 5 0 3
1-126 320 3 4 4 3 5 5 3 0 0 0 0 0 4 0 0 0 0 4
1-127 320 0 0 0 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0
1-130 320 4 5 5 5 5 5 5 0 0 0 0 0 5 1 1 2 0 5
1-131 320 0 5 4 4 5 5 5 0 0 0 0 0 4 4 3 0 2 0 5
1-132 320 0 0 0 1 2 3 1 0 0 0 0 0 0 1 0 0 0 0 3
1-133 320 0 4 4 3 4 5 2 0 0 0 3 0 3 1 0 3 0 3 4
1-134 320 5 5 5 5 5 5 5 2 1 4 2 4 1 5 5 2 5 0 4
1-135 320 5 5 5 5 5 5 5 3 0 5 1 0 3 5 4 1 2 0 4
1-136 320 5 5 5 4 5 5 5 3 0 1 4 2 5 3 1 3 0 4
1-137 320 5 5 5 5 5 5 5 4 3 0 0 2 5 3 0 3 0 4
1-138 320 5 5 5 5 5 5 5 3 0 0 1 3 3 5 2 0 3 0 4
1-139 320 5 5 5 5 5 5 5 2 0 1 3 3 2 5 5 1 5 0 4
1-140 320 5 5 5 5 5 5 5 4 3 2 3 2 3 5 4 3 5 3 5
1-142 320 5 5 5 5 5 5 5 4 0 2 3 3 3 5 5 3 4 3 4
1-143 320 5 5 5 5 5 5 5 1 1 0 0 0 0 2 3 1 3 0 4
1-144 320 5 5 5 5 5 5 5 4 1 0 2 2 3 5 5 3 4 2 4
1-145 320 5 5 5 5 5 5 5 3 0 1 2 2 3 5 5 2 5 2 4
1-146 320 5 5 5 5 5 5 5 5 0 2 3 3 3 5 5 4 5 4 5
1-147 320 5 5 5 5 5 5 5 4 1 1 3 4 4 5 5 3 5 3 4
1-148 320 5 5 5 5 5 5 5 4 2 1 3 3 3 5 4 3 5 3 5
1-149 320 5 5 5 5 5 5 5 4 0 2 3 3 2 5 4 2 5 2 4
1-150 320 5 4 5 5 5 5 5 3 0 0 0 0 0 5 4 0 4 0 4
1-151 320 5 5 5 5 5 5 5 3 0 0 0 0 1 4 4 2 3 2 4
1-152 320 5 5 5 4 5 5 5 4 3 0 0 0 0 5 2 1 3 0 4
1-153 320 5 5 5 5 5 5 5 4 4 0 0 3 0 5 3 1 5 0 4
1-154 320 5 5 5 5 5 5 5 4 3 1 2 3 3 5 3 3 5 1 4
1-155 320 5 5 5 5 5 5 5 4 2 0 2 0 3 5 4 3 5 2 4
1-156 320 5 5 5 5 5 5 5 4 3 2 3 3 4 5 4 3 5 3 4
1-158 320 0 0 1 3 1 4 0 0 0 0 0 0 0 1 0 0 0 0 2
1-159 320 5 1 4 5 5 5 5 4 3 0 0 0 0 3 0 1 2 2 4
1-160 320 5 5 5 5 5 5 5 4 0 2 3 4 3 5 4 2 5 5 5
1-161 320 4 0 4 4 5 5 5 0 0 0 0 0 0 3 1 0 2 0 3
1-162 320 5 5 5 5 5 5 5 4 1 4 4 4 3 5 4 2 5 3 4
1-163 320 5 5 5 5 5 5 5 4 3 3 3 3 3 5 4 2 5 4 5
1-166 320 1 1 4 5 4 5 5 3 0 0 0 0 0 3 1 1 1 0 4
1-167 320 5 5 5 5 5 5 5 4 0 0 4 4 5 5 3 5 2 5
1-168 320 5 5 5 5 5 5 5 4 0 1 3 3 5 5 4 5 2 4
1-169 320 5 5 5 5 5 5 5 4 0 0 3 3 5 5 3 5 0 4
1-170 320 5 5 5 5 5 5 5 0 0 0 0 5 0 1 2 0 4
1-171 320 3 0 5 5 5 5 5 0 0 0 5 2 0 3 0 3
1-172 320 5 5 5 5 5 5 5 4 0 3 3 0 4 5 2 5 0 5
1-173 320 5 5 5 5 5 5 5 3 1 0 0 3 5 5 2 5 0 5
1-174 320 5 5 5 5 5 5 5 3 2 0 0 0 5 5 2 5 0 4
1-175 320 5 5 5 5 5 5 5 2 1 1 1 2 5 5 2 5 0 4
1-176 320 5 5 5 5 5 5 5 4 1 3 3 0 2 5 5 3 5 0 5
1-177 320 5 5 5 5 5 5 5 3 0 0 2 0 5 4 2 5 0 4
1-178 320 5 5 5 5 5 5 5 2 0 0 2 0 5 5 2 5 0 4
1-179 320 5 5 5 5 5 5 5 4 1 1 1 1 5 5 3 5 0 4
1-180 320 5 5 5 5 5 5 5 4 1 0 0 2 5 5 1 5 1 5
1-181 320 5 5 5 5 5 5 5 5 1 0 0 3 5 5 1 5 0 5
1-182 320 5 5 5 5 5 5 5 4 1 0 0 0 5 4 2 3 0 4
1-183 320 5 5 5 5 5 5 5 4 0 0 1 0 2 5 5 1 5 2 5
1-184 320 5 5 5 5 5 5 5 3 0 0 1 0 2 5 5 1 5 1 4
1-185 320 0 0 0 0 3 4 0 0 0 0 0 0 0 0 0 0 0 1
1-186 320 4 4 4 3 5 5 5 1 0 0 0 0 0 5 1 1 0 0 3
1-187 320 5 5 5 5 5 5 5 5 5 0 0 0 0 5 5 3 5 0 5
1-188 320 4 4 5 5 5 5 5 1 0 0 3 0 1 4 1 3 0 0 4
1-189 320 3 0 0 5 4 5 5 0 0 0 0 0 0 5 3 2 0 0 4
1-190 320 0 0 4 5 5 5 5 1 1 0 0 0 0 5 1 2 0 0 3
1-191 320 5 5 5 5 5 5 5 3 0 0 0 0 4 5 4 3 5 3 4
1-192 320 4 4 2 2 5 5 3 0 0 0 0 0 0 4 0 2 0 0 4
1-193 320 5 5 5 5 5 5 5 4 0 0 1 3 5 3 5 2 4
1-194 320 5 5 5 5 5 5 5 3 0 0 0 3 5 5 1 4 0 4
1-195 320 5 5 5 5 5 5 5 3 0 0 0 0 5 4 2 4 0 4
1-196 320 5 5 5 5 5 5 5 1 1 0 0 0 3 5 3 0 5 0 4
1-197 320 5 5 5 4 5 5 5 3 0 0 0 2 5 3 0 2 0 4
1-198 320 5 5 4 5 5 5 5 3 0 2 2 0 3 5 2 3 3 3 5
1-199 320 5 5 5 5 5 5 5 4 1 2 3 4 4 5 4 0 5 3 4
1-200 320 5 5 5 5 5 5 5 3 0 3 0 1 3 5 5 3 5 0 4
1-201 320 5 5 5 5 5 5 5 0 0 0 0 0 3 5 3 1 5 0 4
1-202 320 5 5 5 5 5 5 5 0 0 0 0 1 5 4 0 5 0 4
1-203 320 5 5 5 5 5 5 5 3 0 0 0 0 1 5 3 2 1 0 4
1-204 320 5 5 5 5 5 5 5 4 0 0 0 0 3 5 5 3 4 0 4
1-205 320 5 5 5 5 5 5 5 4 3 0 0 0 3 5 4 2 2 0 4
1-206 320 5 5 1 5 5 5 5 2 0 0 0 0 1 5 4 2 2 0 4
1-207 320 5 5 5 5 5 5 5 3 1 0 0 0 2 5 5 2 2 0 4
1-208 320 5 5 5 5 5 5 5 3 0 0 0 0 1 5 5 2 5 0 4
1-209 320 5 5 5 5 5 5 5 4 3 0 0 0 2 5 5 3 1 0 4
1-210 320 5 5 5 5 5 5 5 2 1 0 0 4 4 5 5 2 5 0 5
1-211 320 1 1 2 2 5 5 5 0 0 0 1 0 3 4 0 0 0 3 4
1-212 320 5 5 5 5 5 5 5 0 0 0 0 0 4 5 5 1 5 0 4
1-213 320 5 5 5 5 5 5 5 0 0 0 3 5 5 0 5 3 4
1-214 320 4 5 3 5 5 5 5 0 0 0 0 0 0 5 2 1 3 0 2
1-215 320 5 4 5 5 5 5 5 1 0 0 0 0 1 5 3 2 1 0 4
1-216 320 5 5 5 5 5 5 5 1 0 0 0 0 1 5 3 2 4 0 4
1-217 320 5 5 5 5 5 5 5 4 0 0 0 1 5 4 2 3 0 3
1-218 320 5 5 5 5 5 5 5 2 0 0 0 0 2 5 3 3 4 0 4
1-219 320 5 5 5 5 5 5 5 4 1 0 0 0 1 5 4 3 4 0 4
1-220 320 0 0 5 5 5 5 0 0 0 0 0 0 2 4 1 0 0 5
1-221 320 5 5 5 5 5 5 5 0 0 0 1 0 4 5 5 0 5 0 4
1-222 320 4 0 3 5 5 5 3 1 0 3 4 1 3 1 3 1 0 2 5
1-223 320 5 5 5 5 5 5 5 3 2 0 4 5 5 0 5 0 4
1-224 320 5 5 5 5 5 5 5 0 0 0 1 0 3 5 3 0 5 2 4
1-225 320 5 4 1 5 5 5 5 0 0 0 0 0 0 5 2 0 2 0 4
1-226 320 5 5 5 5 5 5 5 4 1 0 0 0 3 5 5 3 5 1 4
1-227 320 5 5 5 5 5 5 5 4 0 0 0 0 2 5 5 3 5 0 4
1-228 320 5 5 5 5 5 5 5 3 0 1 3 0 3 5 5 3 5 3 4
1-229 320 5 5 5 5 5 5 5 2 0 0 0 0 3 5 4 2 5 0 4
1-230 320 5 5 5 5 5 5 5 1 0 0 3 0 3 5 4 2 3 0 5
1-231 320 5 5 5 5 5 5 5 3 0 0 0 0 4 5 4 3 4 0 4
1-232 320 5 1 2 5 5 5 5 2 0 0 0 0 0 4 3 1 0 0 4
1-233 320 5 5 5 5 5 5 5 3 0 0 0 0 1 5 2 2 4 0 4
1-234 320 5 3 3 5 5 5 5 2 0 0 0 0 0 5 4 2 0 0 5
1-235 320 5 5 5 5 5 5 5 2 1 0 0 0 2 5 3 3 0 0 5
1-236 320 4 3 2 3 4 5 5 1 0 0 0 0 0 4 1 0 0 0 5
1-237 320 4 4 1 2 5 5 4 0 0 0 0 0 0 5 2 0 0 0 4
1-238 320 5 5 5 5 5 5 5 4 3 3 3 4 3 5 5 3 5 4 5
1-239 320 5 5 5 5 5 5 5 3 0 0 0 4 5 5 3 5 0 5
1-240 320 5 5 5 5 5 5 5 4 1 0 0 0 2 5 5 3 5 4 5
1-241 320 5 5 5 5 5 5 5 4 0 0 0 0 1 5 5 3 5 1 5
1-242 320 5 3 2 5 5 5 5 0 0 0 0 0 4 3 1 2 0 5
1-243 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 5 0 4
1-244 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 3 5 0 5
1-245 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 5 0 5
1-246 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 3 5 0 5
1-247 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 4 4 5 0 5
1-248 320 5 5 5 5 5 5 5 4 0 0 0 5 5 3 1 0 4
1-249 320 5 3 4 5 5 5 4 3 0 0 0 0 0 5 4 3 1 0 5
1-250 320 4 4 4 4 5 5 5 3 0 0 0 0 0 5 4 2 2 0 4
1-251 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 4 4 2 0 4
1-252 320 5 5 5 5 5 5 5 3 0 0 0 0 5 5 3 5 0 4
1-253 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 3 0 5
1-254 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 3 5 3 5
1-255 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 4 3 5
1-256 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 4 5 3 5
1-257 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 4 4 4 1 5
1-258 320 5 5 5 5 5 5 5 4 0 0 0 5 5 3 5 1 5
1-259 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 3 5 4
1-260 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 4 3 4
1-261 320 5 5 5 5 5 5 5 4 0 0 5 5 4 5 3 5
1-262 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 4 2 5
1-296 320 5 0 5 3 4 5 5 0 0 0 4 3 0 0 5
1-297 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 0 5
1-298 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 5 0 5
1-299 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 5 0 5
1-300 320 5 5 5 5 5 5 5 3 0 0 0 0 0 5 5 4 5 3 4
1-301 320 5 5 5 5 5 5 5 0 0 0 5 5 3 5 1 4
1-302 320 5 5 5 5 5 5 5 2 0 0 0 5 5 3 5 3 5
1-303 320 5 5 5 5 5 5 5 3 0 0 0 5 5 3 4 0 4
1-304 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 0 4
1-305 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 3 5 4 4
1-306 320 5 5 5 5 5 5 5 1 0 1 5 5 4 5 1 5
1-307 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 0 5
1-308 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 2 5
1-309 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 2 5
1-310 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 0 3 0 3
1-311 320 5 5 5 5 5 5 5 3 0 0 0 5 5 3 5 3 4
1-312 320 5 5 5 5 5 5 5 2 0 0 0 5 5 3 5 5 5
1-313 320 5 5 1 1 4 5 1 0 0 0 0 3 1 0 0 0 2
1-314 320 5 5 4 1 4 5 0 0 0 0 0 0 3 1 0 0 0 1
2-001 102 5 4 5 4 5 5 4 1 2 3 3 3 2 4 3 0 0 1 4
2-002 320 4 4 3 1 4 5 2 0 0 3 2 2 1 4 0 0 0 0 3
2-003 320 4 5 5 5 5 5 4 1 0 0 0 0 3 5 3 0 0 0 3
2-005 269 3 4 5 3 5 5 3 0 0 0 0 0 0 5 3 0 0 2 4
2-006 320 3 3 4 3 4 5 3 0 0 0 0 0 0 4 0 0 0 0 0
2-007 320 1 0 1 0 4 4 3 0 0 0 2 0 3 1 0 0 0 1
2-008 320 2 3 3 0 3 4 0 0 1 0 0 0 4 1 1 0 0 3
2-009 320 0 0 3 0 1 1 0 0 0 0 0 0 0 4 0 0 0 0 0
2-010 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2-011 320 0 0 2 0 1 2 0 0 0 0 0 0 0 3 0 0 0 0 0
2-012 320 0 0 1 0 1 3 0 0 0 0 0 0 0 4 0 0 0 0 0
2-013 320 4 5 5 3 5 5 4 0 0 1 1 1 2 5 4 0 0 0 4
2-014 320 3 5 5 4 5 5 4 3 0 0 0 0 3 5 3 0 0 0 4
2-015 320 5 5 5 4 5 5 3 1 0 0 0 0 0 5 4 1 0 0 4
2-016 320 5 5 5 4 5 5 4 4 3 0 0 0 0 5 4 3 0 0 4
2-017 320 5 5 5 4 4 5 3 1 0 0 0 5 2 0 0 0 4
2-018 320 1 1 1 0 1 4 1 0 0 0 0 2 0 0 0 0 0
2-020 320 3 5 4 0 4 5 0 0 0 0 0 0 4 1 0 0 0 0
2-021 320 4 4 4 3 5 5 0 0 0 0 0 0 0 4 3 0 0 0 3
2-022 320 0 0 1 0 3 5 2 0 0 0 0 0 5 3 0 0 0 1
2-023 320 0 0 1 0 0 1 0 0 0 0 0 0 3 0 0 0 0 0
2-024 320 4 5 5 2 4 5 2 0 0 0 0 2 5 3 0 0 0 3
2-025 320 4 5 4 0 4 5 3 0 0 0 0 0 0 4 1 0 0 0 3
2-026 320 4 5 4 4 4 5 3 0 0 0 0 0 0 5 2 0 0 0 3
2-027 320 0 5 3 1 2 4 0 0 0 0 0 0 4 1 0 0 0 1
2-028 320 2 5 5 0 4 5 1 0 0 0 0 0 0 5 4 0 0 0 3
2-029 320 0 0 0 2 0 1 0 0 0 0 0 0 0 2 0 0 0 0 0
2-030 320 4 5 4 1 3 5 2 0 0 0 0 0 1 5 2 0 0 0 3
2-031 320 5 5 5 5 5 5 4 0 0 0 0 0 4 5 5 0 0 0 4
2-032 320 2 5 5 3 4 5 5 0 0 0 0 0 0 5 1 0 1 0 4
2-034 320 5 4 4 0 4 5 1 0 0 0 0 0 4 1 0 0 0 2
2-035 320 5 5 4 5 5 5 5 0 0 0 0 0 5 5 0 2 0 2
3-001 320 4 3 4 2 3 4 3 0 0 0 0 0 4 2 0 0 0 0
3-002 320 0 2 1 0 0 1 0 0 0 0 0 0 0 3 0 0 0 0 0
4-001 320 3 1 2 4 5 5 2 0 0 0 0 4 1 0 0 0
5-001 320 4 3 3 4 5 5 4 0 0 0 0 0 4 2 0 0 0
5-002 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
6-001 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 5 0 2
6-002 320 5 5 5 5 5 5 5 1 0 0 0 0 5 5 0 0 0 0
6-003 320 5 5 5 5 5 5 5 3 0 1 2 3 0 5 5 3 0 0 4
6-004 320 5 5 5 4 5 5 5 3 2 3 3 3 5 4 1 0 4
6-005 320 5 5 5 5 5 5 5 5 4 3 3 5 5 4 4 0 0
6-006 320 3 3 4 1 5 4 3 0 0 0 0 4 1 0 5 4
6-007 320 5 5 5 3 5 5 4 1 0 0 0 5 5 2 5 0
6-008 320 0 5 5 0 5 3 3 0 0 0 0 0 3 3 1 4 0 0
6-009 320 5 5 5 4 5 5 5 3 0 2 0 5 5 3 5 2 4
6-010 320 5 5 5 3 5 4 5 0 0 3 0 0 5 4 3 4 0 0
6-015 320 5 5 5 4 5 5 5 2 2 4 3 2 5 5 3 0 0 4
6-016 320 5 5 5 4 4 5 5 0 0 3 0 3 5 5 0 0 0 1
6-017 320 5 5 5 5 5 5 5 0 0 4 1 0 3 5 5 0 1 0 3
6-018 320 5 5 5 4 5 5 5 0 0 3 3 4 5 5 3 2 1 3
6-023 320 5 5 5 5 5 5 4 0 0 0 0 1 5 3 0 3 3
6-024 320 0 3 1 1 3 5 1 0 0 0 0 0 0 0 0 0 0 0 3
6-025 320 4 5 5 5 5 5 5 0 0 0 0 0 0 5 4 0 1 0 3
6-026 320 5 5 5 5 5 5 3 0 0 0 0 0 1 5 5 0 3 0 3
6-027 320 3 4 4 1 0 0 0 0 0 0 0 0 0 1 1 0 0 0 0
6-029 320 5 5 5 5 5 5 5 4 5 4 3 5 4 5 5 0 5 0 4
6-030 320 4 4 1 0 1 1 0 0 0 0 0 0 0 1 0 0 0 0 3
6-031 320 5 5 5 5 5 5 4 2 0 3 0 1 5 4 0 0 0 3
6-032 320 4 3 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0
6-033 320 0 0 1 3 0 5 0 0 0 0 0 0 3 3 0 0 0 1
6-034 320 5 5 5 5 5 4 5 3 3 3 3 5 3 5 5 0 0 0 4
6-035 320 5 5 5 5 5 5 5 4 5 3 3 4 4 5 5 2 4 0 4
6-036 320 4 4 5 3 3 5 3 0 0 0 1 0 3 4 4 0 0 0 3
6-037 320 5 5 5 5 5 5 5 5 5 3 4 3 5 5 4 5 3 5
6-038 320 5 5 5 5 5 5 5 5 5 3 4 0 3 5 5 4 3 0 5
6-049 320 5 5 5 0 5 5 5 3 4 5 5 5 5 5 5 2 5 4 5
6-050 320 4 2 4 3 5 5 4 0 0 3 3 3 3 5 4 0 0 2 5
6-051 320 5 5 5 4 5 5 5 1 3 5 4 4 4 5 5 1 4 3 5
6-052 320 5 5 5 2 4 5 4 0 0 0 0 0 0 5 3 0 0 0 3
6-053 320 5 5 5 3 3 5 4 0 0 0 0 0 0 3 2 0 0 0 3
6-054 320 4 5 5 3 5 4 5 0 0 4 0 0 0 3 4 0 0 0 1
6-055 320 5 5 5 5 5 5 5 1 0 3 4 3 4 5 5 3 3 0 5
6-056 320 5 5 4 3 3 4 3 0 0 3 0 0 2 1 0 0 0 3
6-057 320 5 5 5 5 5 5 5 1 1 4 4 3 4 5 5 3 5 0 5
6-058 320 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 2 5 5 5
6-059 320 5 5 5 5 5 5 5 5 5 5 4 4 5 5 5 0 5 0 5
6-060 320 5 4 5 5 5 5 5 5 4 4 4 4 4 5 5 1 4 2 5
6-061 320 5 5 5 5 5 5 5 4 1 4 3 3 4 5 5 3 5 3 4
6-062 320 5 5 5 5 5 4 5 3 1 3 5 5 5 5 0 5 0 4
6-063 320 5 5 5 5 3 5 5 2 0 0 3 0 3 5 0 4 0 4
6-064 320 5 5 5 5 3 5 5 4 0 4 5 5 0 5 0 3
6-065 320 5 5 5 5 5 5 5 2 0 1 3 3 3 5 5 1 5 3 4
6-066 320 5 5 5 5 5 5 5 3 3 4 3 4 4 5 5 3 5 0 4
6-068 320 0 3 3 0 0 0 0 0 0 0 2 0 0 1 4 0 0 0 2
6-071 320 0 0 0 0 3 4 2 0 0 0 0 0 0 1 0 0 2 0 0
6-072 320 0 4 1 3 0 2 0 0 0 0 0 0 0 2 3 0 0 0 0
6-073 320 5 5 5 5 5 5 3 0 0 3 2 3 3 5 4 0 3 0 4
6-074 320 0 4 3 1 0 2 0 0 0 0 0 0 0 2 0 0 0 0 0
6-075 320 1 0 2 5 5 5 5 0 0 0 0 0 0 4 4 0 2 0 3
6-076 320 5 5 5 5 5 5 5 5 1 2 2 3 2 5 5 1 5 0 4
6-077 320 5 5 5 5 5 5 5 5 1 4 4 4 4 5 5 2 5 4 5
6-078 320 5 5 5 5 5 4 5 4 0 1 3 3 5 0 5 0 4
6-079 320 5 5 5 5 5 5 5 4 0 3 3 4 3 5 5 1 5 0 4
6-080 320 5 5 5 5 5 5 5 4 0 0 0 4 4 5 5 1 5 0 3
6-081 320 4 0 4 5 3 4 5 0 0 0 0 0 0 0 5 0 3 0 3
6-082 320 5 5 5 5 5 5 5 4 1 1 4 4 5 5 0 5 0 4
6-083 320 5 5 5 5 5 4 5 5 3 5 1 4 5 5 0 4 3 4
6-084 320 5 5 5 5 5 5 5 3 3 4 3 3 4 5 0 5 4 0 4
6-085 320 5 5 5 5 5 5 5 4 3 5 3 4 4 5 3 5 5 4 5
6-086 320 5 5 5 5 5 5 5 3 0 5 4 5 5 3 5 5 3 4
6-087 320 5 5 5 0 4 4 3 0 0 0 1 4 1 0 3 1 0 4
6-088 320 5 5 5 5 5 5 5 3 0 5 4 4 5 5 2 5 4 0 4
6-089 320 5 5 4 5 4 4 3 4 4 0 4
6-090 320 5 5 4 4 3 4 2 0 0 0 0 0 0 1 2 0 0 0 4
6-091 320 5 5 5 5 5 5 5 4 2 3 4 3 4 5 5 4 5 3 5
6-092 320 5 5 4 5 5 5 3 0 0 5 3 4 4 4 2 1 0 0 4
6-093 320 5 5 5 5 5 5 5 3 3 5 4 5 5 4 5 2 5 3 4
6-094 320 5 5 5 5 5 5 5 4 0 5 3 5 4 5 5 4 4 4
6-095 320 5 5 5 5 5 5 5 4 0 5 1 0 3 5 5 3 4 0 4
6-096 320 5 4 5 3 1 1 0 3 3 0 4
6-098 320 3 3 2 1 3 5 4 0 0 0 0 0 0 2 1 0 2 0 0
6-099 320 5 5 5 5 5 5 5 3 4 5 4 5 5 5 5 4 5 4 5
6-100 320 5 5 5 5 5 5 5 3 4 4 3 4 3 5 5 3 5 0 5
6-103 320 5 5 5 5 5 5 5 2 0 0 1 0 2 5 5 0 5 0 4
6-104 320 5 5 5 5 5 5 5 5 5 4 4 4 4 5 5 3 5 4 4
6-105 320 5 5 5 2 2 4 2 0 0 0 0 3 3 3 3 0 0 0 4
6-106 320 5 5 5 3 5 5 5 0 0 0 3 3 3 3 5 1 3 0 5
6-107 320 5 5 5 5 5 5 5 3 2 4 2 5 4 5 5 1 5 2 4
6-108 320 5 5 5 5 5 5 5 5 5 2 3 3 2 5 5 3 3 0 5
6-109 320 5 5 5 5 5 5 5 4 4 0 0 0 1 5 5 2 4 0 4
6-110 320 5 5 5 5 5 5 5 4 0 0 1 3 2 5 5 2 4 0 4
6-111 320 5 5 5 5 5 5 5 2 2 0 1 0 2 5 5 1 4 0 4
6-112 320 5 5 5 5 5 5 5 4 1 0 1 0 1 5 5 3 4 0 4
6-113 320 5 5 5 5 5 5 5 0 0 2 0 0 0 5 5 0 5 0 4
6-114 320 5 5 5 5 5 5 5 3 0 3 3 3 3 5 5 2 5 0 4
6-115 320 5 2 5 5 5 5 5 0 0 0 0 0 0 5 5 2 5 0 4
6-116 320 0 0 0 0 0 3 0 0 0 0 0 0 0 2 0 0 0 0 0
6-117 320 5 5 5 5 5 5 5 5 4 3 3 2 3 5 5 5 5 3 5
6-118 320 5 5 5 5 5 5 5 5 2 2 3 2 3 5 5 4 5 3 4
6-119 320 5 5 5 5 5 5 5 5 4 2 2 3 3 5 5 5 5 5 5
6-120 320 5 5 5 5 5 5 5 5 2 2 3 3 4 5 5 5 5 0 5
6-121 320 5 5 5 5 5 5 5 5 2 3 3 3 4 5 5 5 5 3 5
6-122 320 5 5 5 5 5 5 5 5 3 2 4 4 5 5 5 5 3 5
6-123 320 5 5 5 3 5 5 5 4 0 4 3 0 3 5 3 3 5 5
6-124 320 5 5 5 5 5 5 5 5 3 3 4 3 4 5 5 5 5 3 5
6-125 320 0 0 0 0 3 3 3 0 0 0 0 0 0 0 0 0 2 0 0
6-126 320 5 5 5 5 5 5 5 5 3 3 4 3 5 5 5 5 3 5
6-127 320 4 5 5 5 5 5 5 0 0 0 0 0 0 5 3 0 3 0 4
6-128 320 5 5 5 5 5 5 5 5 0 3 4 5 5 5 2 5 0 5
6-129 320 5 5 5 5 5 5 5 5 0 3 4 5 4 5 5 3 5 2 5
6-130 320 5 5 5 5 5 5 5 5 2 3 3 3 4 5 5 4 5 2 5
6-131 320 5 5 5 5 5 5 5 5 0 3 3 3 4 5 5 4 5 0 5
6-132 320 5 5 5 5 5 5 5 3 0 3 3 2 3 5 5 3 5 0 4
6-133 320 5 5 5 5 5 5 5 3 0 0 0 0 5 5 0 5 0 4
6-134 320 5 5 5 5 5 5 5 4 0 2 0 0 3 5 5 1 5 0 4
6-135 320 5 5 5 4 5 5 5 4 0 3 0 0 3 5 5 3 5 0 4
6-136 320 5 5 5 5 5 5 5 5 1 1 1 4 4 5 5 4 5 0 5
6-137 320 5 5 5 5 5 5 5 3 0 0 0 0 3 5 5 2 5 0 4
6-138 320 5 0 5 5 5 5 5 1 0 3 0 0 2 5 2 3 0 0 3
6-139 320 5 1 5 5 5 5 5 2 0 0 0 0 0 5 5 2 0 0 4
6-140 320 5 0 5 5 5 5 5 4 0 0 0 0 0 5 4 1 2 0 4
6-141 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 0 5 0 3
6-142 320 1 5 5 5 5 5 5 0 0 0 0 0 5 5 0 0 0 2
6-143 320 1 0 5 5 5 5 5 0 0 0 0 0 5 3 0 1 0 0
6-144 320 4 5 5 5 5 5 5 0 0 0 0 0 5 5 0 1 0 0
6-145 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 1 0 0
6-146 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 3 0 3
6-147 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 5 0 3
6-148 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 2 0 3
6-149 320 5 5 5 5 5 5 5 3 1 0 0 4 5 4 0 5 0 3
6-150 320 5 5 5 5 5 5 5 3 1 0 1 4 5 5 2 4 0 4
6-151 320 5 5 5 5 5 5 5 2 0 0 0 5 4 5 0 3 0 3
6-152 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 4 0 4
6-153 320 5 5 5 5 5 5 5 5 3 3 5 3 5 5 4 5 3 5
6-154 320 5 5 5 5 5 5 5 3 0 1 3 5 3 5 0 4
6-155 320 5 5 5 5 5 5 5 5 1 1 2 5 5 4 5 2 4
6-156 320 5 5 5 5 5 5 5 5 3 2 3 0 3 5 5 5 5 3 5
6-157 320 5 5 5 5 5 5 5 5 4 1 4 0 4 5 5 5 5 3 5
6-158 320 5 5 5 5 5 5 5 5 4 2 3 3 5 5 5 5 3 4
6-159 320 0 0 0 5 5 5 5 5 4 3 4 4 3 0 0 4 5 3 4
6-160 320 5 5 5 5 5 5 5 5 3 2 4 4 5 5 4 5 3 5
6-161 320 5 5 5 5 5 5 5 4 1 3 3 4 5 5 4 5 2 5
6-162 320 5 5 5 5 5 5 5 4 1 2 2 0 3 5 5 3 5 3 4
6-163 320 5 5 5 5 5 5 5 4 1 0 1 0 4 5 5 4 5 3 5
6-164 320 5 5 5 5 5 5 5 4 2 0 4 5 5 4 5 3 4
6-165 320 5 5 5 5 5 5 5 5 3 3 4 5 5 4 5 3 4
6-166 320 5 5 5 5 5 5 5 4 4 2 3 5 5 5 4 5 3 4
6-167 320 5 5 5 5 5 5 5 5 2 1 0 5 5 5 4 5 3 5
6-168 320 5 5 5 5 5 5 5 5 2 1 3 0 3 5 5 4 5 3 4
6-169 320 5 5 5 5 5 5 5 5 4 3 3 3 4 5 5 4 5 4 4
6-170 320 5 5 5 5 5 5 5 5 0 0 3 5 5 4 5 3 4
6-171 320 5 5 5 5 5 5 5 5 4 0 0 1 4 5 5 4 5 3 5
6-172 320 5 5 5 5 5 5 5 4 5 0 0 3 3 5 5 3 5 3 4
6-173 320 5 5 5 5 5 5 5 5 0 0 0 3 5 5 4 5 1 4
6-174 320 5 5 5 5 5 5 5 4 1 0 0 0 3 5 5 4 5 0 4
6-175 320 5 5 5 5 5 5 5 4 0 1 1 0 3 5 5 4 5 0 4
6-176 320 5 5 5 5 5 5 5 4 1 0 0 0 1 5 5 4 5 0 4
6-177 320 5 5 5 5 5 5 5 4 1 0 0 0 0 5 5 4 5 4 5
6-178 320 5 5 5 5 5 5 5 4 3 2 5 3 1 5 5 4 5 4 5
6-179 320 5 5 5 5 5 5 5 4 3 0 3 0 1 5 5 4 5 4 5
6-180 320 5 5 5 5 5 5 5 4 1 4 5 4 5 5 4 5 5 5
6-181 320 5 5 5 5 5 5 5 5 2 0 0 1 3 5 5 4 5 2 5
6-182 320 5 5 5 5 5 5 5 4 2 3 3 3 3 5 5 3 5 3 5
6-183 320 5 5 5 5 5 5 5 5 0 5 5 4 5 4
6-184 320 5 5 5 5 5 5 5 5 0 5 5 4 5 5
6-185 320 5 5 5 5 5 5 5 5 0 5 5 5 5 4
6-186 320 5 5 5 5 5 5 5 5 0 0 5 5 3 5 5
6-187 320 5 5 5 5 5 5 5 4 0 0 5 5 3 5 0 4
6-188 320 5 5 5 5 5 5 5 4 0 0 0 5 5 3 5 0 4
6-189 320 5 5 5 5 5 5 5 4 0 3 0 0 5 5 3 5 0 4
6-190 320 5 5 5 5 5 5 5 4 0 0 0 5 5 3 5 4
6-191 320 5 5 5 5 5 5 5 4 0 0 0 5 5 3 5 5
6-192 320 5 5 5 5 5 5 5 5 0 0 0 5 5 4 5 2 5
6-193 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 0 4
6-194 320 1 2 1 0 0 0 0 0 0 0 0 0 1 0 0 0 0 3
6-195 320 5 5 5 5 5 5 5 3 0 0 0 0 5 0 0 2 0 5
6-196 320 5 5 5 5 5 5 5 4 1 0 0 5 5 4 4 3 5
6-197 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 2 5 0 5
6-198 320 5 5 5 5 5 5 5 4 1 0 0 0 5 5 4 4 0 5
6-199 320 5 5 5 5 5 5 5 4 1 0 0 0 5 4 3 3 0 4
6-200 320 5 5 5 5 5 5 5 4 0 0 0 5 5 4 5 4 4
6-201 320 1 2 2 0 4 2 0 0 0 0 5 1 0 0 0 3
6-202 320 5 5 5 5 5 5 5 2 0 0 0 5 5 3 5 0 4
6-203 320 5 3 5 5 5 5 5 4 0 0 0 5 4 1 2 5
6-204 320 5 3 5 5 5 5 3 4 0 0 0 5 5 3 0 3 5
6-205 320 5 5 5 5 5 5 5 4 0 0 0 0 5 3 3 5 0 5
6-206 320 5 1 5 4 5 5 1 4 0 0 0 5 5 3 0 0 4
6-207 320 5 5 5 5 5 5 5 5 1 1 5 5 4 5 4 5
6-208 320 5 5 5 5 5 5 5 5 0 5 5 4 5 4 5
6-209 320 5 5 5 5 5 5 5 4 3 0 0 5 5 3 5 4 5
6-210 320 5 5 5 5 5 5 5 3 1 2 5 5 3 1 0 5
6-211 320 5 5 5 5 5 5 5 5 2 0 5 5 4 4 5 5
6-212 320 5 5 5 5 5 5 5 4 2 0 5 3 3 5 0 5
6-213 320 5 5 5 5 5 5 5 4 1 0 0 5 5 3 4 0 5
6-214 320 5 5 5 5 5 5 5 4 0 0 5 5 3 5 0 5
6-215 320 5 5 5 5 5 5 5 5 1 0 5 4 3 5 2 5
6-216 320 5 4 5 4 5 5 5 3 0 0 0 0 5 5 3 0 0 4
6-217 320 5 5 5 2 5 5 5 3 0 0 0 0 5 1 2 0 0 5
6-218 320 5 5 5 5 5 5 5 5 3 0 0 5 5 3 5 0 5
6-219 320 5 5 5 4 5 5 4 2 0 0 0 5 3 2 0 0 5
6-220 320 5 5 5 5 5 5 5 2 0 0 0 5 5 4 3 0 5
6-221 320 5 5 5 5 5 5 5 4 2 0 0 5 5 3 1 2 5
6-222 320 5 5 5 5 5 5 5 2 0 0 0 5 5 4 3 0 5
6-223 320 5 5 5 5 5 5 5 4 0 0 0 5 5 4 1 0 5
6-224 320 5 5 5 5 5 5 5 2 1 0 5 5 4 5 3 5
6-225 320 5 5 5 5 5 5 5 4 2 1 3 5 5 4 5 3 5
6-226 320 5 5 5 5 5 5 5 4 1 0 5 5 4 5 4 5
6-227 320 5 5 5 5 5 5 5 2 0 0 5 5 4 5 3 5
6-228 320 5 5 5 5 5 5 5 2 1 5 5 4 4 3 5
6-229 320 5 5 5 5 5 5 5 1 0 0 5 5 4 1 1 5
6-230 320 5 5 5 5 5 5 5 2 0 0 5 5 4 5 3 5
6-231 320 5 5 5 5 5 5 5 2 0 5 5 4 5 4 5
6-232 320 5 5 5 5 5 5 5 4 0 0 3 5 5 4 5 3 5
6-233 320 5 5 5 5 5 5 5 5 3 1 0 4 5 5 4 5 3 5
6-234 320 5 5 5 5 5 5 5 5 4 1 0 5 5 4 5 3 5
6-235 320 5 5 5 5 5 5 5 5 5 3 5 5 4 5 4 5
6-237 320 5 1 2 2 3 5 5 2 0 0 0 0 5 1 2 0 0 3
6-239 320 5 5 5 5 5 5 5 5 4 3 3 4 5 5 5 5 3 4
6-240 320 5 5 5 5 5 5 5 5 5 0 3 3 5 5 5 5 3 4
6-241 320 5 5 5 5 5 5 5 5 5 3 3 4 5 5 5 5 4 4
6-242 320 5 5 5 5 5 5 5 5 5 1 3 3 5 5 5 5 4 4
6-243 320 5 5 5 5 5 5 5 5 4 2 4 4 5 5 5 5 4 4
6-244 320 5 5 5 5 5 5 5 4 1 0 0 3 5 5 4 4 0 4
6-245 320 5 5 5 5 5 5 5 5 3 3 3 3 5 5 4 3 0 4
6-246 320 5 5 5 5 5 5 5 5 1 1 0 2 5 5 4 5 0 4
6-247 320 5 5 5 5 5 5 5 5 4 3 4 3 5 5 4 4 1 4
6-248 320 5 5 5 5 5 5 5 4 2 2 0 1 5 4 3 2 1 4
6-249 320 5 5 5 5 5 5 5 5 3 1 1 2 5 5 4 5 5 5
6-250 320 5 5 5 5 5 5 5 5 3 0 0 2 5 5 4 5 5 5
6-251 320 5 5 5 5 5 5 5 5 4 1 3 4 5 5 4 5 4 4
6-252 320 5 5 5 5 5 5 5 5 4 1 4 4 5 5 5 5 5 5
6-253 320 5 5 5 5 5 5 5 5 4 3 4 3 5 4 4 5 3 4
6-254 320 5 5 5 5 5 5 5 5 0 0 2 2 5 4 4 5 4 5
6-255 320 5 5 5 5 5 5 5 5 0 0 2 1 5 4 4 4 1 4
6-256 320 5 5 5 5 5 5 5 5 2 0 1 1 5 4 4 4 1 4
6-257 320 5 5 5 5 5 5 5 2 0 0 0 0 5 3 1 1 0 4
6-258 320 0 0 1 3 4 5 3 0 0 0 0 0 3 0 0 0 0 4
6-259 320 4 5 5 3 5 5 5 0 0 0 1 5 3 1 0 0 4
6-260 320 5 5 5 5 5 5 5 5 4 3 3 3 5 5 5 5 4 5
6-261 320 5 5 5 5 5 5 5 5 4 3 4 4 5 5 5 5 4 5
6-262 320 5 5 5 5 5 5 5 5 4 3 3 4 5 5 4 5 4 4
6-263 320 5 5 5 5 5 5 5 5 5 4 4 4 5 5 5 5 4 5
6-264 320 5 5 5 5 5 5 5 5 5 3 4 4 5 5 4 5 4 5
6-265 320 0 0 0 0 0 1 5 0 0 0 0 0 3 0 0 0 0 3
6-266 320 3 5 5 4 5 5 4 0 0 0 0 0 0 5 5 0 3 0 4
6-267 320 5 5 5 5 5 5 5 5 4 0 3 0 5 5 4 4 2 5
7-001 320 5 3 4 3 3 5 3 0 0 0 1 2 0 0 0 0
7-002 320 5 3 5 4 4 5 3 0 0 0 0 0 0 5 3 0 0 0 0
7-003 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 2 0 0 0
7-004 320 5 4 5 2 5 5 5 0 0 2 0 0 5 5 4 0 0 3
7-005 320 5 4 5 2 2 5 4 0 0 3 1 0 0 4 4 0 0 0 0
7-006 320 5 5 5 3 3 5 4 0 0 3 0 0 0 5 4 0 0 0 3
7-007 320 5 5 5 4 5 5 5 0 0 2 0 0 5 5 0 2 0 0
7-008 320 5 5 5 5 5 5 5 1 0 2 1 3 5 5 0 4 0 3
7-010 320 5 5 5 4 5 5 5 3 1 2 0 0 4 5 5 3 5 0 4
7-011 320 4 3 5 3 4 5 3 4 5 3 3 0 1 5 2 0 0 0 4
7-012 320 5 5 5 1 3 5 0 0 0 3 3 2 5 3 2 1 0 3
7-013 320 4 2 1 1 3 3 0 0 5 0 0 0 1 0 0 0 0 1
7-014 320 5 0 5 1 0 5 0 0 0 0 0 0 3 3 0 0 0 1
7-015 320 5 5 5 5 5 5 5 2 0 3 1 4 5 5 0 5 0 5
7-016 320 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-017 320 5 5 5 0 2 3 3 0 0 0 0 0 5 0 0 0 0 0
7-018 320 5 4 4 0 0 2 2 0 0 0 0 0 0 2 1 0 0 0 0
7-019 320 3 3 4 0 2 3 3 0 0 0 0 0 1 2 0 0 0 2
7-020 320 5 3 4 0 4 4 3 0 0 0 0 0 0 3 0 0 0 0 2
7-022 320 0 0 1 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0
7-024 320 0 0 5 2 2 3 1 0 0 0 0 0 0 3 1 0 0 0 2
7-025 320 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-026 320 0 0 1 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0
7-027 320 5 5 5 5 4 5 5 0 0 0 0 0 0 3 5 0 0 0 2
7-029 320 3 3 5 3 0 0 0 0 2 0 1
7-031 320 4 5 5 3 3 5 5 0 0 0 0 0 0 4 1 0 0 0 0
7-032 320 5 5 5 4 5 5 5 0 0 0 0 0 0 4 5 0 0 0 0
7-033 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 0 0 0 3
7-034 320 2 1 4 4 4 5 4 0 0 0 0 0 0 0 0 0 0
7-035 320 5 5 5 5 5 5 5 0 0 0 3 5 3 0 0 0 4
7-036 320 5 5 5 5 5 5 5 0 0 0 5 5 0 1 3
7-037 320 5 5 5 4 5 5 5 0 0 0 0 0 5 1 0 1 0 0
7-042 320 0 4 4 3 3 5 1 0 0 0 0 0 0 0 1 0 0 0 4
8-001 320 1 1 1 0 0 1 0 0 0 0 0 0 2 0 0 0 0 0
8-002 320 0 0 3 3 4 5 3 0 0 0 0 0 4 0 0 0 0 1
8-003 320 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0
9-001 320 4 4 5 5 3 5 3 0 0 0 0 0 3 4 0 0 0 2
9-002 320 5 5 5 5 5 5 5 4 3 0 0 1 5 5 0 3 0 4
9-003 320 5 5 5 4 5 5 5 4 0 3 3 0 4 5 5 4 4 1 4
9-004 320 5 5 5 5 5 5 4 0 1 2 0 5 5 0 3 0 3
9-005 320 4 4 5 5 4 5 5 0 0 0 0 0 0 4 3 0 0 0 3
9-006 320 5 5 5 4 5 5 5 0 0 2 3 0 4 5 5 0 5 0 4
9-007 320 5 5 5 5 5 5 5 0 0 3 3 1 4 5 5 0 4 0 4
9-008 320 5 5 5 4 5 5 5 4 0 3 4 2 4 5 5 3 5 0 4
9-009 320 4 5 5 5 4 5 5 0 0 0 0 0 5 3 0 0 0 3
9-010 320 5 5 5 4 5 5 5 0 3 3 3 3 3 5 3 2 0 0 3
9-011 320 5 5 5 5 5 5 5 2 2 1 0 1 3 5 5 2 5 0 4
9-012 320 5 5 5 5 5 5 5 1 4 2 4 4 3 5 5 1 2 0 3
9-013 320 5 5 5 5 5 5 5 4 0 3 2 4 5 5 0 4 4 4
9-014 320 5 5 5 4 4 4 3 0 0 0 0 0 2 5 5 0 1 0 2
9-015 320 5 5 5 4 5 5 5 0 0 3 3 2 4 5 5 0 3 0 5
9-016 320 5 5 5 5 5 5 5 0 0 2 3 2 1 5 5 3 3 0 3
9-017 320 4 5 5 4 3 5 3 0 0 0 0 0 0 5 5 0 3 0 3
9-018 320 0 3 3 3 1 1 0 0 0 0 1 0 0 3 3 0 0 0 0
9-019 320 4 5 5 4 4 5 1 0 0 0 0 0 0 3 5 0 0 0 1
9-020 320 5 5 5 5 5 5 4 4 5 3 3 3 5 5 1 2 0 4
9-021 320 5 5 5 4 5 5 5 2 2 3 1 4 5 5 1 4 0 4
9-022 320 5 5 5 0 2 2 2 0 0 0 0 0 0 5 2 0 0 0 0
9-023 320 5 5 5 4 5 5 5 0 0 3 3 0 3 5 5 0 1 0 5
9-024 320 5 5 5 5 5 5 5 3 1 4 4 4 4 5 5 0 3 0 4
9-025 320 5 4 1 3 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0
9-026 320 5 4 0 3 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0
9-027 320 5 5 5 5 5 5 5 0 0 2 3 3 2 5 5 0 4 0 4
9-028 320 5 5 5 4 5 5 5 1 4 2 3 4 4 5 5 1 4 3 4
9-029 320 3 3 3 5 4 5 4 0 0 0 0 0 0 3 4 0 4 0 4
9-030 320 3 0 1 2 0 3 0 0 0 0 0 0 0 1 0 0 0 0 3
9-034 320 0 3 0 0 3 3 0 0 0 0 0 0 1 1 0 0 0 0
9-039 320 0 1 3 0 2 5 1 0 0 0 0 0 1 0 0 2 0 3
9-040 320 0 0 0 2 1 5 4 0 0 0 0 0 0 0 0 0 0 4
9-041 320 5 5 5 0 1 2 1 0 0 0 0 0 2 2 0 2 0 3
9-042 320 0 3 1 0 4 1 1 0 0 0 0 0 2 0 0 4 0 3
9-043 320 0 1 3 0 0 1 0 0 0 0 0 0 2 2 0 0 0 0
9-044 320 0 0 0 0 3 3 1 0 0 0 0 0 0 0 0 0 0 0 0
9-045 320 0 0 0 5 3 5 2 0 0 0 0 0 3 0 0 0 4
10-001 320 3 2 4 1 1 3 0 0 0 0 0 0 0 2 1 0 0 0 0
10-002 320 5 5 5 5 4 5 4 0 0 0 0 0 4 5 0 0 0 0
10-003 320 3 5 5 3 3 4 3 0 0 0 0 0 0 4 2 0 0 0 0
10-004 320 5 5 5 5 5 5 5 3 0 0 0 3 5 5 0 4 0 4
11-002 320 4 4 5 5 5 5 5 0 0 0 0 0 0 5 2 1 2 0 4
12-002 320 5 5 5 5 5 5 5 1 0 2 4 4 4 5 5 1 2 3 5
13-001 320 5 5 5 5 5 5 5 1 0 0 0 0 0 5 5 0 5 0 4
13-002 320 5 5 5 5 5 5 5 2 0 5 3 4 4 5 5 2 5 3 4
13-003 320 5 5 5 5 5 5 5 4 0 0 1 3 1 5 5 3 5 0 4
13-004 320 5 5 5 5 5 5 5 1 0 4 2 4 3 5 5 1 5 0 4
13-005 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 4 0 5 0 3
13-006 320 5 5 5 5 5 5 5 4 3 2 3 2 5 5 2 5 3 4
13-007 320 5 5 5 5 5 5 4 1 0 0 0 5 3 1 1 0 2
13-008 320 3 0 5 5 5 5 5 1 0 0 0 5 0 0 0 0 4
13-009 320 5 5 5 5 5 5 5 4 0 3 3 1 5 5 3 5 3 4
13-010 320 5 5 5 5 5 5 5 3 0 2 3 5 5 3 5 1 4
13-011 320 5 5 5 5 5 5 5 4 0 0 1 0 5 5 4 5 0 4
13-012 320 5 5 5 5 5 5 5 3 0 0 1 0 5 5 2 3 0 4
13-013 320 4 5 5 5 5 5 5 3 0 0 1 0 5 3 1 3 1 4
13-014 320 0 0 2 1 3 5 3 4 1 0 0 1 3 0 1 0 0 4
13-015 320 5 5 5 5 5 5 5 5 4 3 4 5 5 3 5 3 4
13-016 320 5 5 5 3 5 5 5 5 5 3 4 4 5 4 3 5 4 4
13-017 320 5 5 5 5 5 5 5 5 5 0 4 4 5 5 1 5 3 4
13-018 320 5 5 5 5 5 5 5 5 4 1 3 4 4 5 5 2 5 3 4
13-019 320 3 5 5 5 5 5 5 0 0 0 0 3 5 5 0 3 0 4
13-020 320 0 4 5 4 5 5 5 0 0 1 0 4 0 4 4 0 0 0 3
13-021 320 3 5 5 5 5 5 5 0 0 0 4 5 5 0 3 0 4
13-022 320 3 5 5 5 5 5 5 0 0 1 3 0 4 5 5 1 3 0 4
13-023 320 4 5 5 5 5 5 5 0 0 3 3 0 4 5 5 1 4 0 4
13-024 320 0 4 4 5 5 5 5 0 0 2 2 0 0 5 5 0 0 0 3
14-001 320 5 5 5 5 5 5 5 4 0 0 0 0 2 5 5 2 4 0 4
14-002 320 5 5 5 5 5 5 5 4 0 0 0 0 0 4 5 1 3 0 4
14-003 320 5 5 5 5 5 5 5 4 0 0 2 0 5 5 0 3 0 5
14-004 320 0 5 5 4 5 5 5 3 0 0 0 0 5 5 5 0 0 0 4
14-006 320 1 4 3 1 0 4 3 0 0 0 0 2 0 0 0 0 4
15-001 320 5 5 5 5 5 5 5 5 2 3 3 4 5 5 4 5 0 5
15-002 320 5 5 5 5 5 5 5 4 1 0 0 0 4 5 5 4 5 0 4
15-003 320 5 5 5 5 5 5 5 4 0 2 2 0 3 5 5 4 5 0 4
15-004 320 5 5 5 5 5 5 5 4 0 4 4 3 4 5 5 4 5 0 4
15-005 320 5 5 5 5 5 5 5 3 0 0 3 4 5 5 2 5 0 4
15-006 320 5 5 5 5 5 5 5 3 0 0 0 0 3 5 5 3 5 0 3
15-007 320 5 5 5 5 5 5 5 1 0 0 0 0 3 5 5 1 5 0 3
15-009 320 5 5 5 5 5 5 5 4 1 0 0 0 3 5 5 3 5 0 4
15-010 320 0 1 5 5 5 5 5 0 0 0 0 0 0 4 1 0 0 0 0
15-011 320 5 5 5 5 5 5 5 1 0 0 0 0 0 5 1 0 3 0 3
15-012 320 5 5 5 5 5 5 5 0 0 0 0 0 0 1 0 0 5 0 0
15-013 320 5 5 5 5 5 5 5 5 1 2 1 1 3 5 5 5 5 0 5
15-014 320 5 5 5 5 5 5 5 4 0 3 2 4 4 5 5 3 5 0 4
15-015 320 5 5 5 5 5 5 5 3 0 0 1 2 3 5 5 1 4 0 5
15-016 320 5 5 5 5 5 5 5 1 0 0 0 0 5 1 0 3 0 2
15-017 320 5 5 5 5 5 5 5 0 0 0 0 0 5 1 0 4 0 4
15-018 320 5 5 5 5 4 5 5 0 0 0 0 0 5 2 0 0 0 4
15-019 320 5 5 5 5 5 5 5 2 0 0 0 5 3 1 3 0 3
15-020 320 5 5 5 5 5 5 5 0 0 0 0 5 5 0 3 0 3
15-021 320 5 5 5 5 5 5 5 1 0 0 0 5 5 0 3 0 0
15-022 320 5 5 5 5 5 5 5 2 0 0 0 0 5 5 0 5 0 3
15-023 320 5 5 5 5 5 5 5 5 3 2 2 4 5 5 4 5 4 4
15-024 320 5 5 5 5 5 5 5 3 3 0 0 0 5 5 3 5 0 4
15-025 320 5 5 5 5 5 5 5 4 3 0 0 1 5 4 4 5 1 4
15-026 320 5 5 5 5 5 5 5 1 0 0 0 0 5 3 2 5 0 4
15-027 320 5 5 5 5 5 5 5 3 0 0 0 1 5 2 0 5 0 4
15-028 320 5 5 5 5 5 5 5 5 2 0 0 4 5 5 4 5 1 4
15-029 320 5 5 5 5 5 5 5 4 4 3 2 4 5 5 4 5 4 5
15-030 320 5 5 5 5 5 5 5 4 4 2 1 3 5 5 4 5 1 4
15-031 320 5 5 5 5 5 5 5 4 0 0 1 4 5 5 4 5 1 4
15-032 320 5 5 5 5 5 5 5 4 0 0 1 3 5 5 4 5 0 4
15-033 320 5 5 5 5 5 5 5 4 0 0 0 4 5 5 3 5 1 4
15-034 320 5 5 5 5 5 5 5 4 0 1 1 4 5 5 3 5 1 4
16-001 320 0 0 0 0 2 2 0 0 0 0 0 0 1 0 0 3 0 1
17-001 320 5 5 5 5 5 5 5 3 0 1 1 3 5 3 5 1 5
17-002 320 5 5 5 5 5 5 5 4 0 3 2 4 5 5 3 5 2 5
―――――――――――――――――――――――――――― [Table 21]
―――――――――――――――――――――――――
No. Treatment dose A B C a
(G / ha)
―――――――――――――――――――――――――
1-001 320 0 0 0 0
1-002 320 5 4 4 5
1-003 320 5 4 5 5
1-004 320 5 5 4 5
1-005 320 5 5 5 5
1-006 320 5 3 3 4
1-007 320 0 0 0 0
1-008 320 5 3 0 0
1-009 320 0 0 0 0
1-010 320 5 5 2 5
1-011 320 0 0 0 0
1-012 320 0 0 0 0
1-013 320 0 0 0 0
1-014 320 5 5 2 5
1-015 320 5 5 2 5
1-016 320 5 5 4 5
1-017 320 5 5 2 5
1-018 320 5 5 2 5
1-019 320 5 5 2 5
1-020 320 5 5 4 5
1-021 320 0 0 0 0
1-022 320 5 5 2 5
1-023 320 4 0 0 1
1-024 320 5 5 2 5
1-025 320 4 2 0 3
1-026 320 5 5 5 5
1-027 320 4 3 3 4
1-028 320 5 5 1 5
1-029 320 4 0 0 5
1-030 320 2 0 0 1
1-031 320 5 4 2 0
1-032 320 5 5 3 5
1-033 320 5 4 1 5
1-034 320 5 4 2 5
1-035 320 5 5 2 5
1-036 320 5 4 1 5
1-037 320 0 0 0 0
1-038 320 5 5 3 5
1-039 320 5 5 2 5
1-040 320 3 2 0 4
1-041 320 5 5 0 5
1-042 320 5 5 4 5
1-043 320 5 5 2 5
1-044 320 5 5 4 5
1-045 320 5 2 0 3
1-046 320 5 5 4 5
1-047 320 4 0 0 1
1-048 320 5 4 1 5
1-049 320 0 0 0 0
1-050 320 4 2 3 4
1-051 320 5 5 0 5
1-052 320 5 5 0 5
1-053 320 5 3 0 5
1-054 320 5 0 0 5
1-055 320 5 3 0 5
1-056 320 5 5 4 5
1-057 320 5 3 2 4
1-058 320 5 0 0 5
1-059 320 5 3 2 4
1-060 320 5 4 3 5
1-062 320 5 2 1 5
1-063 320 5 3 0 5
1-064 320 5 5 1 4
1-065 320 5 5 0 5
1-066 320 4 0 0 5
1-067 320 5 5 1 5
1-068 320 5 4 3 5
1-069 320 5 4 2 5
1-070 320 4 0 0 4
1-071 320 5 4 0 5
1-072 320 5 4 5
1-073 320 5 5 1 5
1-074 320 5 5 4 5
1-075 320 5 4 5
1-076 192 4 4 0 5
1-077 320 1 2 0 1
1-078 320 5 2 0 5
1-079 320 5 5 3 5
1-080 320 5 5 3 5
1-081 320 5 5 2 5
1-082 320 5 5 2 5
1-083 320 5 4 1 5
1-085 320 4 0 0 3
1-086 320 5 0 0 3
1-087 320 5 5 1 5
1-088 320 5 5 0 5
1-089 320 5 5 3 5
1-090 320 5 5 1 5
1-091 320 5 5 0 4
1-092 320 5 5 0 5
1-093 320 5 5 2 5
1-094 320 5 5 1 5
1-095 320 5 5 2 5
1-096 320 5 5 0 5
1-097 320 3 0 0 3
1-098 320 5 5 4 5
1-099 320 5 4 2 5
1-100 320 5 5 3 5
1-101 320 5 5 2 5
1-102 320 5 3 5
1-103 320 5 5 1 5
1-104 320 5 4 1 3
1-105 320 5 5 4 5
1-106 320 5 3 5
1-107 320 5 4 1 3
1-108 320 5 4 3 5
1-109 320 5 5 3 5
1-110 320 3 0 0 5
1-111 320 5 2 1 5
1-112 320 5 5 5 5
1-113 320 5 4 4 3
1-114 320 5 5 5 5
1-115 320 5 3 4 1
1-116 320 5 4 5 3
1-117 320 5 5 5 5
1-118 320 5 1 2 4
1-119 320 1 0 0 3
1-120 320 4 5 3 0
1-121 320 5 5 3 5
1-122 320 5 5 0 5
1-123 320 5 4 3 5
1-124 320 1 0 0 0
1-125 320 3 0 1 5
1-126 320 4 0 0 3
1-130 320 3 0 0 3
1-131 320 5 4 1 4
1-133 320 4 0 0 1
1-134 320 5 5 1 5
1-135 320 5 5 1 5
1-136 320 5 5 5 5
1-137 320 5 5 5 5
1-138 320 5 5 5 5
1-139 320 5 4 1 5
1-140 320 5 5 1 5
1-142 320 5 5 2 5
1-143 320 4 4 1 5
1-144 320 5 5 3 5
1-145 320 5 5 1 5
1-146 320 5 5 1 5
1-147 320 5 5 1 5
1-148 320 5 4 3 5
1-149 320 5 5 1 5
1-150 320 5 3 0 5
1-151 320 5 3 0 4
1-152 320 4 0 0 2
1-153 320 5 3 0 4
1-154 320 5 4 2 5
1-155 320 5 5 1 5
1-156 320 5 5 1 5
1-159 320 5 0 0 1
1-160 320 5 4 2 5
1-161 320 5 4 1 4
1-162 320 5 4 3 5
1-163 320 5 4 0 5
1-166 320 5 0 0 0
1-167 320 5 5 2 5
1-168 320 5 5 3 5
1-169 320 5 4 3 5
1-170 320 5 0 0 4
1-171 320 5 0 0 4
1-172 320 5 3 2 5
1-173 320 5 3 2 5
1-174 320 5 4 3 5
1-175 320 5 4 2 5
1-176 320 5 4 1 5
1-177 320 5 5 2 5
1-178 320 5 4 2 5
1-179 320 5 4 1 5
1-180 320 5 1 5
1-181 320 4 1 5
1-182 320 5 0 5
1-183 320 5 2 5
1-184 320 2 0 5
1-186 320 5 0 0 3
1-187 320 5 4 0 5
1-188 320 5 0 0 1
1-189 320 5 2 0 0
1-190 320 4 0 0 0
1-191 320 5 4 1 5
1-192 320 5 4 2 4
1-193 320 5 5 5 5
1-194 320 5 2 0 5
1-195 320 5 5 5 5
1-196 320 5 5 5 5
1-197 320 5 4 5 5
1-198 320 5 4 3 5
1-199 320 5 5 4 5
1-200 320 5 4 0 5
1-201 320 5 4 3 4
1-202 320 5 5 5 5
1-203 320 5 4 1 5
1-204 320 5 4 2 5
1-205 320 5 5 3 5
1-206 320 4 0 0 2
1-207 320 5 5 1 5
1-208 320 5 5 2 5
1-209 320 5 4 3 5
1-210 320 5 4 0 5
1-211 320 5 4 0 4
1-212 320 5 3 0 4
1-213 320 5 3 0 5
1-214 320 5 4 3 5
1-215 320 5 5 1 5
1-216 320 5 4 0 4
1-217 320 5 4 1 5
1-218 320 5 4 3 5
1-219 320 5 4 0 5
1-220 320 5 4 0 4
1-221 320 5 5
1-222 320 5 2 0
1-223 320 3 0 0 1
1-224 320 5 1 0 4
1-225 320 5 4 4
1-226 320 5 4 3 5
1-227 320 5 5 1 5
1-228 320 5 5 4 5
1-229 320 5 5 1 5
1-230 320 5 5 3 5
1-231 320 5 5 1 5
1-232 320 5 5 1 4
1-233 320 5 5 0 5
1-234 320 5 5 1 5
1-235 320 5 5 3 4
1-236 320 5 2 0 3
1-237 320 5 4 0 3
1-238 320 5 5 0 5
1-239 320 5 4 3 5
1-240 320 5 4 1 5
1-241 320 5 4 2 5
1-242 320 5 2 0 3
1-243 320 5 5 2 5
1-244 320 5 4 0 5
1-245 320 5 4 0 5
1-246 320 5 5 1 5
1-247 320 5 4 1 5
1-248 320 5 5 0 5
1-249 320 5 4 1 5
1-250 320 5 3 0 5
1-251 320 5 5 3 5
1-252 320 5 5 0 5
1-253 320 5 5 1 5
1-254 320 5 5 2 5
1-255 320 5 5 0 5
1-256 320 5 4 4 5
1-257 320 5 5 1 5
1-258 320 5 5 5 5
1-259 320 5 5 1 5
1-260 320 5 5 1 5
1-261 320 5 3 0 5
1-262 320 5 4 2 5
1-263 320 5 4 2 5
1-264 320 5 4 2 5
1-265 320 4 3 0 5
1-266 320 5 5 4 5
1-267 320 5 5 1 5
1-268 320 5 4 3 5
1-269 320 5 5 2 5
1-270 320 5 5 3 5
1-271 320 5 4 1 5
1-272 320 5 4 0 5
1-273 320 5 5 1 5
1-296 320 4 0 0 4
1-297 320 5 5 2 5
1-298 320 5 5 4 5
1-299 320 5 4 3 5
1-300 320 5 5 2 5
1-301 320 5 4 3 5
1-302 320 5 4 2 5
1-303 320 5 3 2 5
1-304 320 5 4 1 5
1-305 320 5 3 0 4
1-306 320 5 4 2 5
1-307 320 5 4 0 4
1-308 320 5 5 2 5
1-309 320 5 4 1 5
1-310 320 5 4 2
1-311 320 5 3 2 5
1-312 320 5 4 0 5
1-314 320 5 0 0 3
2-001 102 4 0 0 4
2-002 320 0 0 0 0
2-003 320 0 0 0 0
2-005 269 3 0 0 4
2-006 320 5 2 3 3
2-007 320 3 2 0 4
2-008 320 0 0 0 0
2-009 320 0 0 0 0
2-010 320 0 0 0 0
2-011 320 0 0 0 0
2-012 320 0 0 0 0
2-013 320 0 0 0 0
2-014 320 4 3 1 1
2-015 320 0 4 0 0
2-016 320 4 0 0 4
2-017 320 5 5 3 5
2-018 320 5 2 1 4
2-020 320 2 0 0 3
2-021 320 4 4 2 5
2-022 320 1 0 0 3
2-024 320 2 0 0 4
2-025 320 3 0 0 2
2-026 320 3 3 0 4
2-028 320 3 0 0 3
2-030 320 4 0 0 3
2-031 320 4 4 2 5
2-032 320 4 4 1 5
2-034 320 2 1 0 2
2-035 320 5 2 0 3
3-001 320 0 0 0 0 0
3-002 320 0 0 0 0
4-001 320 0 0 0 0
5-001 320 0 0 0 0
5-002 320 0 0 0 0
6-001 320 5 0 0 5
6-002 320 3 0 0 3
6-003 320 5 4 1 5
6-004 320 5 5 2 5
6-005 320 5 5 3 5
6-006 320 5 5 1 5
6-007 320 5 5 1 5
6-008 320 5 5 5 5
6-009 320 5 2 0 3
6-010 320 5 4 1 5
6-015 320 5 5 5 5
6-016 320 5 0 0 4
6-017 320 5 1 0 5
6-018 320 5 5 4 5
6-023 320 0 0 0 4
6-024 320 3 2 3
6-025 320 2 0 0 3
6-026 320 1 0 0 3
6-029 320 5 3 3 5
6-030 320 3 0 0 2
6-031 320 3 0 0 1
6-034 320 5 5 4 5
6-035 320 5 4 1 5
6-037 320 5 5 4 5
6-038 320 5 4 3 5
6-049 320 5 5 4 5
6-050 320 3 1 0 4
6-051 320 4 4 2 5
6-052 320 4 1 0 3
6-053 320 4 2 1 3
6-054 320 1 0 0 2
6-055 320 4 1 0 5
6-056 320 3 0 0 0
6-057 320 3 3 1 5
6-058 320 5 5 5 5
6-059 320 5 5 4 5
6-060 320 5 5 5 5
6-061 320 5 1 1 5
6-062 320 5 4 4 5
6-063 320 5 2 3 4
6-064 320 5 0 0 5
6-065 320 4 2 3 4
6-066 320 5 3 2 3
6-071 320 4 0 0 0
6-072 320 4 0 0 0
6-073 320 4 1 1 5
6-074 320 1 0 0 2
6-075 320 4 1 2 3
6-076 320 5 3 2 5
6-077 320 5 3 3 5
6-078 320 5 5 4 5
6-079 320 4 0 2 5
6-080 320 5 1 2 5
6-081 320 5 0 1 3
6-082 320 5 4 4 5
6-083 320 5 4 4 5
6-084 320 5 3 0 5
6-085 320 5 3 0 5
6-086 320 5 2 0 5
6-087 320 5 0 0 2
6-088 320 4 1 0 3
6-089 320 5 3 3 5
6-090 320 5 0 0 0
6-091 320 5 5 4 5
6-092 320 3 0 0 0
6-093 320 5 5 4 5
6-094 320 5 5 3 5
6-095 320 5 4 0 5
6-096 320 1 0 0 5
6-098 320 0 1 0 1
6-099 320 5 5 5 5
6-100 320 5 5 5 5
6-103 320 5 0 0 5
6-104 320 5 5 5 5
6-106 320 5 5 4 5
6-107 320 5 5 5 5
6-108 320 4 3 0 5
6-109 320 5 3 3 5
6-110 320 5 3 0 5
6-111 320 5 5 2 5
6-112 320 5 0 0 4
6-113 320 4 0 0 5
6-114 320 5 4 0 5
6-115 320 5 1 0 5
6-117 320 5 5 4 5
6-118 320 5 5 2 5
6-119 320 5 4 3 5
6-120 320 5 5 2 5
6-121 320 5 5 4 5
6-122 320 5 5 2 5
6-123 320 5 5 2 5
6-124 320 5 5 4 5
6-126 320 5 5 2 5
6-127 320 5 1 2 5
6-128 320 5 5 4 5
6-129 320 5 5 4 5
6-130 320 5 5 4 5
6-131 320 5 5 4 5
6-132 320 5 5 1 5
6-133 320 5 0 0 5
6-134 320 5 5 4 5
6-135 320 5 4 3 5
6-136 320 5 5 4 5
6-137 320 5 4 3 5
6-138 320 5 0 0 3
6-139 320 5 3 0 3
6-140 320 5 2 2 5
6-141 320 5 3 0 5
6-142 320 5 3 2
6-143 320 5 0 0 3
6-144 320 5 0 0 5
6-145 320 5 0 0 5
6-146 320 5 0 0 5
6-147 320 5 0 0 5
6-148 320 5 0 0 5
6-149 320 5 4 4 5
6-150 320 5 0 0 5
6-151 320 5 2 0 4
6-152 320 5 0 0 5
6-153 320 5 5 5 5
6-154 320 5 4 4 5
6-155 320 5 4 3 5
6-156 320 5 5 1 5
6-157 320 5 5 2 5
6-158 320 5 5 3 5
6-159 320 5 5 2 5
6-160 320 5 4 3 5
6-161 320 5 4 2 5
6-162 320 5 5 3 5
6-163 320 5 4 2 5
6-164 320 5 5 1 5
6-165 320 5 5 3 5
6-166 320 5 4 3 5
6-167 320 5 5 4 5
6-168 320 5 5 4 5
6-169 320 5 5 5 5
6-170 320 5 5 4 5
6-171 320 5 5 3 5
6-172 320 5 3 3 4
6-173 320 5 5 4 5
6-174 320 5 5 4 5
6-175 320 5 5 3 5
6-176 320 5 5 4 5
6-177 320 5 5 3 5
6-178 320 5 5 3 5
6-179 320 5 5 2 5
6-180 320 5 5 4 5
6-181 320 5 5 3 5
6-182 320 5 5 3 5
6-183 320 5 5 1 5
6-184 320 5 5 5 5
6-185 320 5 5 2 5
6-186 320 5 5 4 5
6-187 320 5 5 2 5
6-188 320 5 5 3 5
6-189 320 5 5 2 5
6-190 320 5 5 4 5
6-191 320 5 4 5 5
6-192 320 5 5 3 5
6-193 320 5 5 4 5
6-195 320 5 1 0 1
6-196 320 5 5 4 5
6-197 320 5 2 0 1
6-198 320 5 2 0 3
6-199 320 5 3 2 5
6-200 320 5 3 1 4
6-201 320 5 3 0 3
6-202 320 5 3 0 4
6-203 320 5 3 4 4
6-204 320 5 3 1 1
6-205 320 5 4 3 5
6-206 320 5 3 3 1
6-207 320 5 5 4 5
6-208 320 5 5 4 5
6-209 320 5 4 0 5
6-210 320 5 4 3 5
6-211 320 5 5 4 5
6-212 320 5 4 3 5
6-213 320 5 4 1 5
6-214 320 5 4 4 5
6-215 320 5 5 5 5
6-216 320 5 1 0 1
6-217 320 5 3 2 0
6-218 320 5 3 4 5
6-219 320 5 4 1 5
6-220 320 5 4 1 5
6-221 320 5 4 1 5
6-222 320 5 4 3 5
6-223 320 5 3 3 5
6-224 320 5 5 4 5
6-225 320 5 5 4 5
6-226 320 5 4 1 5
6-227 320 5 4 2 5
6-228 320 5 4 2 5
6-229 320 5 3 2 5
6-230 320 5 5 4 5
6-231 320 5 5 4 5
6-232 320 5 5 4 5
6-233 320 5 3 4 5
6-234 320 5 5 4 5
6-235 320 5 5 5 5
6-239 320 5 5 3 5
6-240 320 5 5 4 5
6-241 320 5 4 3 5
6-242 320 5 5 3 5
6-243 320 5 5 3 5
6-244 320 5 4 2 5
6-245 320 5 4 3 5
6-246 320 5 3 2 5
6-247 320 5 4 2 5
6-248 320 5 4 3 2
6-249 320 5 4 4 5
6-250 320 5 5 3 5
6-251 320 5 5 4 5
6-252 320 5 4 4 5
6-253 320 5 4 4 5
6-254 320 5 5 2 5
6-255 320 5 3 3 5
6-256 320 5 4 4 5
6-257 320 5 5 2 4
6-258 320 5 3 0 3
6-260 320 5 5 4 5
6-261 320 5 5 3 5
6-262 320 5 5 4 5
6-263 320 5 4 4 5
6-264 320 5 4 4 5
6-265 320 3 0 0 2
6-266 320 5 5 0 5
6-267 320 5 5 3 5
7-001 320 0 0 0 0
7-002 320 0 0 0 2
7-003 320 5 0 0 0
7-004 320 5 3 0 5
7-005 320 3 0 0 1
7-006 320 3 0 0 2
7-007 320 5 1 3 5
7-008 320 4 2 0 5
7-010 320 5 5 1 5
7-011 320 2 1 0 1
7-012 320 3 0 0 1
7-015 320 5 1 2 5
7-018 320 2 0 0 2
7-019 320 1 0 0 0
7-020 320 2 0 0 2
7-022 320 4 2 3 3
7-023 320 2 0 0 1
7-024 320 2 1 2 2
7-026 320 3 0 0 0
7-027 320 4 0 2 3
7-029 320 2 0 0 0
7-032 320 5 3 2 4
7-033 320 5 0 5
7-034 320 4 0 0 4
7-035 320 5 0 0 5
7-036 320 5 2 0 5
7-037 320 5 0 0 3
8-001 320 0 0 0 0
8-002 320 0 0 0 0
8-003 320 0 0 0 0
9-001 320 4 0 0 4
9-002 320 5 2 0 5
9-003 320 5 4 1 5
9-004 320 5 2 0 5
9-005 320 4 0 0 4
9-006 320 5 4 0 5
9-007 320 5 4 0 5
9-008 320 5 5 4 5
9-009 320 4 0 0 5
9-010 320 5 5 4 5
9-011 320 5 5 4 5
9-012 320 5 4 2 5
9-013 320 5 5 1 5
9-014 320 5 4 2 5
9-015 320 5 5 1 5
9-016 320 5 5 2 5
9-017 320 4 2 0 4
9-018 320 1 0 0 2
9-019 320 4 0 0 4
9-020 320 5 4 1 5
9-021 320 5 5 2 5
9-022 320 5 3 0 5
9-023 320 5 5 4 5
9-024 320 5 4 2 5
9-025 320 5 1 1 0
9-026 320 4 0 0 0
9-027 320 5 2 1 5
9-028 320 5 5 5 5
10-002 320 1 0 0 1
10-003 320 1 0 0 3
10-004 320 5 0 0 5
11-002 320 2 0 0 2
12-002 320 5 3 2 3
13-001 320 5 2 0 5
13-002 320 5 4 0 5
13-003 320 5 5 0 5
13-004 320 5 5 5 5
13-005 320 5 0 2 5
13-006 320 5 5 4 5
13-007 320 5 4 2 3
13-008 320 5 1 2 0
13-009 320 5 5 3 5
13-010 320 5 3 1 5
13-011 320 5 4 1 5
13-012 320 4 3 0 5
13-013 320 4 0 0 4
13-015 320 5 4 4 5
13-016 320 5 5 2 5
13-017 320 5 3 5
13-018 320 5 4 5
13-019 320 5 3 1 5
13-020 320 5 0 2
13-021 320 5 1 0 5
13-022 320 5 4 0 5
13-023 320 5 4 0 5
13-024 320 5 0 0 1
14-001 320 4 3 3 5
14-002 320 4 1 2 2
14-003 320 5 2 0 5
14-004 320 5 2 0 4
14-006 320 2 3 0 1
15-001 320 4 5 3 5
15-002 320 5 5 2 5
15-003 320 5 4 1 5
15-004 320 5 2 3 5
15-005 320 5 4 2 5
15-006 320 5 3 3 5
15-007 320 5 4 2 5
15-009 320 5 5 4 5
15-010 320 5 0 0 1
15-011 320 5 0 0 4
15-013 320 5 4 1 5
15-014 320 5 5 4 5
15-015 320 5 0 0 5
15-016 320 5 1 0 5
15-017 320 3 0 0 2
15-018 320 5 0 0 3
15-019 320 5 4 1 5
15-020 320 5 4 3 5
15-021 320 5 3 0 5
15-022 320 5 3 4 5
15-023 320 5 5 4 5
15-024 320 5 2 2 5
15-025 320 5 1 2 5
15-026 320 5 0 0 5
15-027 320 5 2 3 5
15-028 320 5 5 3 5
15-029 320 5 5 4 5
15-030 320 5 5 2 5
15-031 320 5 5 3 5
15-032 320 5 5 3 5
15-033 320 5 3 3 5
15-034 320 5 5 2 5
17-001 320 5 5 5 5
17-002 320 5 5 3 5
―――――――――――――――――――――――――
[Table 22]
―――――――――――――――――――――――――
No. Treatment dose A B C
(G / ha)
―――――――――――――――――――――――――
1-001 320 0 0 0
1-002 320 5 3 3
1-003 320 5 3 3
1-004 320 5 4 4
1-005 320 5 4 4
1-006 320 5 3 3
1-007 320 0 0 0
1-008 320 5 2 0
1-009 320 0 0 0
1-010 320 5 5 2
1-011 320 0 0 0
1-012 320 0 0 0
1-013 320 0 0 0
1-014 320 5 3 3
1-015 320 5 4 4
1-016 320 5 4 3
1-017 320 5 4 3
1-018 320 5 5 3
1-019 320 5 5 2
1-020 320 5 3 2
1-021 320 0 0 0
1-022 320 4 5 3
1-023 320 4 0 0
1-024 320 5 5 3
1-025 320 1 0 0
1-026 320 5 3 3
1-027 320 4 3 0
1-028 320 5 4 0
1-029 320 4 0 0
1-030 320 2 0 0
1-031 320 5 2 0
1-032 320 5 4 3
1-033 320 5 4 2
1-034 320 5 3 3
1-035 320 5 4 4
1-036 320 5 4 2
1-037 320 0 0 0
1-038 320 5 5 4
1-039 320 5 5 3
1-040 320 4 0 0
1-041 320 5 0 0
1-042 320 5 4 3
1-043 320 5 5 3
1-044 320 5 4 3
1-045 320 3 0 0
1-046 320 5 5 3
1-047 320 2 0 0
1-048 320 5 4 2
1-049 320 0 0 0
1-050 320 3 0 0
1-051 320 5 5 3
1-052 320 5 2 0
1-053 320 4 0 0
1-054 320 3 0 0
1-055 320 2 0 0
1-056 320 5 5 4
1-057 320 2 0 0
1-058 320 5 0 0
1-059 320 4 0 0
1-060 320 5 4 0
1-062 320 3 0 0
1-063 320 4 2 0
1-064 320 5 4 1
1-065 320 4 5 0
1-066 320 2 0 0
1-067 320 4 4 2
1-068 320 5 5 3
1-069 320 4 4 3
1-070 320 4 0 0
1-071 320 5 3
1-072 320 5 3 0
1-073 320 5 5 2
1-074 320 5 4
1-075 320 5 4
1-076 192 5 4 0
1-078 320 4 0 0
1-079 320 5 4 3
1-080 320 4 4 2
1-081 320 5 4 3
1-082 320 5 5 3
1-083 320 5 4 3
1-085 320 3 0 0
1-086 320 5 0
1-087 320 5 5 1
1-088 320 5 5 3
1-089 320 5 4 3
1-090 320 5 5 3
1-091 320 5 3 0
1-092 320 5 4 0
1-093 320 5 5 3
1-094 320 5 5 4
1-095 320 5 4 1
1-096 320 5 5
1-097 320 1 0 0
1-098 320 5 4 3
1-099 320 4 4 2
1-100 320 5 5 3
1-101 320 5 5 2
1-102 320 5 2 2
1-103 320 5 4 0
1-104 320 5 4 0
1-105 320 5 5 3
1-106 320 5 0 0
1-107 320 5 2 0
1-108 320 5 3 1
1-109 320 5 5 2
1-110 320 2 0 0
1-111 320 5 1 0
1-112 320 4 4 4
1-113 320 3 3 0
1-114 320 4 3 4
1-115 320 3 2 0
1-116 320 2 3 2
1-117 320 4 3 3
1-118 320 2 0
1-120 320 1 5 3
1-121 320 5 4 1
1-122 320 5 5 0
1-123 320 5 3 2
1-124 320 2 0 0
1-125 320 2 0 0
1-130 320 1 0 0
1-131 320 4 4 0
1-133 320 1 0 0
1-134 320 5 4 3
1-135 320 5 4 0
1-136 320 4 4 5
1-137 320 4 4 3
1-138 320 3 4 2
1-139 320 5 4 1
1-140 320 5 5 3
1-142 320 5 4
1-143 320 4 4 3
1-144 320 5 4 2
1-145 320 5 5 3
1-146 320 5 5 4
1-147 320 5 5 3
1-148 320 5 4 4
1-149 320 5 4 3
1-150 320 5 3 1
1-151 320 5 1 2
1-152 320 2 0 0
1-153 320 4 1 0
1-154 320 5 4 4
1-155 320 5 5 3
1-156 320 5 5 3
1-159 320 4 1 3
1-160 320 5 4 4
1-161 320 5 4 3
1-162 320 5 1 2
1-163 320 5 4 3
1-166 320 3 0 0
1-167 320 5 3 1
1-168 320 5 3 2
1-169 320 5 4 2
1-170 320 5 1 0
1-171 320 5 0 0
1-172 320 4 2
1-173 320 5 2
1-174 320 5 3
1-175 320 5 3
1-176 320 5 4
1-177 320 5 4 1
1-178 320 5 3
1-179 320 5 4
1-180 320 5 5 4
1-181 320 5 5 4
1-182 320 5 4 3
1-183 320 5 4
1-184 320 5 0 0
1-186 320 2 0 0
1-187 320 5 3 2
1-189 320 2 0 0
1-190 320 2 0 0
1-191 320 5 3 3
1-192 320 4 0 0
1-193 320 5 5 3
1-194 320 4 2 0
1-195 320 4 0 0
1-196 320 4 4 3
1-197 320 4 1 4
1-198 320 3 4 3
1-199 320 5 4 3
1-200 320 5 2 0
1-201 320 4 3 3
1-202 320 5 4 0
1-203 320 3 3 0
1-204 320 4 3 1
1-205 320 4 3 2
1-206 320 3 0 0
1-207 320 4 4 0
1-208 320 4 3 0
1-209 320 4 3 2
1-210 320 5 4 2
1-211 320 4 2 0
1-212 320 5 3 2
1-213 320 5 2 0
1-214 320 4 3 4
1-215 320 4 3 2
1-216 320 4 3 1
1-217 320 5 2 0
1-218 320 3 4 2
1-219 320 5 4 2
1-220 320 5 4 1
1-221 320 5 3 2
1-222 320 4 0 0
1-223 320 3 0 0
1-224 320 5 0 0
1-225 320 4 2 0
1-226 320 5 4 3
1-227 320 5 4 0
1-228 320 5 4 2
1-229 320 5 3 2
1-230 320 5 3 0
1-231 320 5 3 0
1-232 320 4 2 0
1-233 320 5 4 3
1-234 320 5 4 2
1-235 320 5 3 2
1-236 320 3 0 0
1-237 320 4 1 0
1-238 320 5 4 2
1-239 320 5 4 2
1-240 320 5 4 3
1-241 320 5 4 3
1-242 320 5 2 0
1-243 320 5 5 2
1-244 320 5 4 3
1-245 320 5 3 3
1-246 320 5 5 2
1-247 320 5 4 3
1-248 320 5 4 2
1-249 320 5 3 0
1-250 320 5 3 0
1-251 320 5 5 0
1-252 320 5 5 0
1-253 320 5 4 2
1-254 320 5 4 1
1-255 320 5 5 4
1-256 320 5 4 2
1-257 320 5 5 3
1-258 320 5 5 1
1-259 320 5 5 3
1-260 320 5 4 0
1-261 320 5 4 0
1-262 320 5 5 1
1-263 320 5 5 3
1-264 320 5 5 4
1-265 320 5 0 0
1-266 320 5 5 3
1-267 320 5 4 0
1-268 320 5 4 1
1-269 320 5 4 2
1-270 320 5 5 0
1-271 320 5 4 2
1-272 320 5 4 0
1-273 320 5 4 1
1-296 320 4 0 0
1-297 320 5 4 2
1-298 320 5 4 3
1-299 320 5 3 1
1-300 320 4 3 2
1-301 320 5 4 2
1-302 320 5 4 2
1-303 320 4 3 1
1-304 320 5 4 1
1-305 320 4 3 0
1-306 320 5 4 3
1-307 320 5 4 0
1-308 320 5 4 2
1-309 320 5 3 1
1-310 320 4 2 0
1-311 320 5 3 1
1-312 320 5 3 0
1-314 320 4 0 0
2-001 102 0 0 0
2-002 320 0 0 0
2-003 320 0 0 0
2-005 269 3 0 0
2-006 320 5 2 2
2-007 320 3 0 0
2-008 320 0 0 0
2-009 320 0 0 0
2-010 320 0 0 0
2-011 320 0 0 0
2-012 320 0 0 0
2-013 320 0 0 0
2-014 320 4 3 0
2-015 320 0 0 0
2-016 320 4 0 0
2-017 320 5 4 4
2-018 320 4 0 0
2-020 320 1 0 0
2-021 320 5 2 1
2-022 320 1 0 0
2-024 320 1 0 0
2-026 320 4 3 0
2-028 320 3 0 0
2-030 320 3 0 0
2-031 320 4 0 0
2-032 320 4 1 0
2-034 320 3 0 0
2-035 320 4 0 0
3-001 320 0 0 0
3-002 320 0 0 0
4-001 320 0 0 0
5-001 320 0 0 0
5-002 320 0 0 0
6-001 320 4 0 0
6-002 320 0 0 0
6-003 320 4 1 3
6-004 320 5 4
6-005 320 5 2 3
6-006 320 5 5 1
6-007 320 5 3 2
6-008 320 5 5 5
6-009 320 3 0 0
6-010 320 5 3 0
6-015 320 5 5 5
6-016 320 3 0 0
6-017 320 4 3 0
6-018 320 5 4 3
6-024 320 1 0 0
6-025 320 2 0 0
6-029 320 5 3 2
6-030 320 2 0 0
6-031 320 4 0 0
6-034 320 5 5 3
6-035 320 5 4 0
6-036 320 3 0 0
6-037 320 5 4 4
6-038 320 4 4 1
6-049 320 5 4 3
6-050 320 3 0 0
6-051 320 5 4 2
6-052 320 3 0 0
6-053 320 3 1 2
6-054 320 2 1 0
6-055 320 5 2 0
6-056 320 1 0 0
6-057 320 3 2 0
6-058 320 5 5 5
6-059 320 5 4 4
6-060 320 5 4 4
6-061 320 5 4 2
6-062 320 5 3 3
6-063 320 2 3 2
6-064 320 4 0 0
6-065 320 5 1 2
6-066 320 5 0 0
6-071 320 2 0 0
6-072 320 1 0 0
6-073 320 4 2 1
6-074 320 1 0 0
6-075 320 1 0 1
6-076 320 5 1 1
6-077 320 5 4 3
6-078 320 4 2 3
6-079 320 3 2 3
6-080 320 5 4 3
6-081 320 1 0 0
6-082 320 4 3 5
6-083 320 5 3 4
6-084 320 4 3 0
6-085 320 5 4 1
6-086 320 4 4 3
6-087 320 2 0 0
6-088 320 4 2 0
6-089 320 5 2 3
6-090 320 3 0 0
6-091 320 5 5 3
6-092 320 1 0 0
6-093 320 5 3 3
6-094 320 5 2 1
6-095 320 5 3 2
6-096 320 4 0 0
6-099 320 5 5 5
6-100 320 5 5 5
6-103 320 5 0 0
6-104 320 5 5 5
6-106 320 5 5 4
6-107 320 5 5 5
6-108 320 4 1 2
6-109 320 5 2 2
6-110 320 5 1 0
6-111 320 5 3 4
6-112 320 3 0 0
6-113 320 5 0 3
6-114 320 5 3 0
6-117 320 5 4 5
6-118 320 5 4 2
6-119 320 5 3 3
6-120 320 5 4 3
6-121 320 5 5 4
6-122 320 5 5 3
6-123 320 5 5 3
6-124 320 5 4 4
6-126 320 5 4 4
6-127 320 3 0 0
6-128 320 5 5 4
6-129 320 5 4 4
6-130 320 5 4 4
6-131 320 5 3 3
6-132 320 5 4 1
6-133 320 3 4 4
6-134 320 5 4 4
6-135 320 5 2 3
6-136 320 5 5 4
6-137 320 5 4 4
6-138 320 2 0 0
6-139 320 4 2 0
6-140 320 4 0 2
6-141 320 5 0 0
6-142 320 3 0 0
6-143 320 1 0 0
6-144 320 5 0 0
6-145 320 5 0 0
6-146 320 5 0 0
6-147 320 5 0 0
6-148 320 5 0 0
6-149 320 3 2 2
6-150 320 3 0 0
6-151 320 2 0 0
6-152 320 5 0 0
6-153 320 5 4 4
6-154 320 5 3 3
6-155 320 5 4 2
6-156 320 5 5 3
6-157 320 5 4 3
6-158 320 5 5 3
6-159 320 5 5 4
6-160 320 5 4 3
6-161 320 5 4 4
6-162 320 5 5 4
6-163 320 5 4 3
6-164 320 5 5 4
6-165 320 5 5 4
6-166 320 5 4 4
6-167 320 5 5 4
6-168 320 5 5 4
6-169 320 5 5 4
6-170 320 5 4 2
6-171 320 5 5 3
6-172 320 5 3 2
6-173 320 5 5 4
6-174 320 5 5 4
6-175 320 5 4 4
6-176 320 5 5 3
6-177 320 5 4 4
6-178 320 5 5 4
6-179 320 5 4 3
6-180 320 5 5 4
6-181 320 5 4 2
6-182 320 5 5 3
6-183 320 5 4 2
6-184 320 5 5 3
6-185 320 5 5 3
6-186 320 5 4 0
6-187 320 5 4 2
6-188 320 5 4 1
6-189 320 5 2 0
6-190 320 5 4 1
6-191 320 5 1 1
6-192 320 5 5 4
6-193 320 5 5 3
6-195 320 3 0 0
6-196 320 5 4 3
6-197 320 3 1 0
6-198 320 5 3 0
6-199 320 5 1 0
6-200 320 5 0 0
6-201 320 5 2 0
6-202 320 5 0 0
6-203 320 5 2 2
6-204 320 5 2 0
6-205 320 5 3 3
6-206 320 4 0 0
6-207 320 5 5 4
6-208 320 5 5 4
6-209 320 4 3 3
6-210 320 5 3 3
6-211 320 5 5 4
6-212 320 5 4 2
6-213 320 5 3 3
6-214 320 5 3 2
6-215 320 5 3 3
6-216 320 4 0 0
6-217 320 4 0 0
6-218 320 5 1 1
6-219 320 5 4 2
6-220 320 5 3 0
6-221 320 5 2 1
6-222 320 5 3 3
6-223 320 5 4 3
6-224 320 5 4 4
6-225 320 5 4 4
6-226 320 5 4 3
6-227 320 5 4 3
6-228 320 5 4 4
6-229 320 5 1 1
6-230 320 5 5 4
6-231 320 5 4 3
6-232 320 5 5 4
6-233 320 5 3 3
6-234 320 5 4 4
6-235 320 5 4 4
6-239 320 5 5 4
6-240 320 5 5 4
6-241 320 5 4 4
6-242 320 5 5 4
6-243 320 5 3 4
6-244 320 5 2 3
6-245 320 5 3 3
6-246 320 5 3 3
6-247 320 5 4 3
6-248 320 5 3 3
6-249 320 5 4 3
6-250 320 5 4 4
6-251 320 5 3 3
6-252 320 5 4 3
6-253 320 5 4 2
6-254 320 5 4 4
6-255 320 4 3 2
6-256 320 5 4 3
6-257 320 5 4 2
6-258 320 4 3 3
6-260 320 5 5 4
6-261 320 5 4 4
6-262 320 5 5 4
6-263 320 5 5 4
6-264 320 5 4 4
6-266 320 4 3 0
6-267 320 5 3 2
7-001 320 0 0 0
7-002 320 0 0 0
7-003 320 2 0 0
7-004 320 4 0 0
7-005 320 1 0 0
7-006 320 2 0 0
7-007 320 5 0 3
7-008 320 4 0 0
7-010 320 5 5 1
7-011 320 3 2 0
7-012 320 3 0 0
7-013 320 2 0 0
7-015 320 5 0 0
7-018 320 1 0 0
7-020 320 1 0 0
7-024 320 1 0 0
7-027 320 3 0 2
7-031 320 0 1 2
7-032 320 5 0 0
7-033 320 5 0
7-034 320 3 0 0
7-035 320 5 0 0
7-036 320 4 0 0
7-037 320 5 0 0
8-001 320 0 0 0
8-002 320 0 0 0
8-003 320 0 0 0
9-001 320 4 0 0
9-002 320 5 0 0
9-003 320 5 4
9-004 320 5 2 0
9-005 320 3 0 0
9-006 320 5 4
9-007 320 5 4
9-008 320 5 4 3
9-009 320 2 0 0
9-010 320 4 4 1
9-011 320 5 5 4
9-012 320 5 4 2
9-013 320 5 5 3
9-014 320 2 0 0
9-015 320 5 3
9-016 320 5 4 1
9-017 320 1 0 0
9-018 320 1 0 0
9-019 320 3 0 0
9-020 320 4 4 0
9-021 320 5 5
9-022 320 4 0 0
9-023 320 5 4 1
9-024 320 3 3 1
9-027 320 3 0 0
9-028 320 5 4 4
9-029 320 0 0 0
10-002 320 1 0 0
10-003 320 3 0 0
10-004 320 5 0 0
11-002 320 2 0 0
12-002 320 5 3 1
13-001 320 5 0 0
13-002 320 5 5 2
13-003 320 5 4 3
13-004 320 5 5 4
13-005 320 5 2
13-006 320 5 3 4
13-007 320 5 4 1
13-008 320 3 0 0
13-009 320 5 4 4
13-010 320 5 2 0
13-011 320 5 4 3
13-012 320 5 2 0
13-013 320 3 0 0
13-015 320 5 3 4
13-016 320 5 4 4
13-017 320 5 5 4
13-018 320 5 4 4
13-019 320 5 2 1
13-020 320 4 0 0
13-021 320 4 0 0
13-022 320 5 3 0
13-023 320 5 3 2
13-024 320 3 0 0
14-001 320 5 0 1
14-002 320 5 0 0
14-003 320 5 2 0
14-004 320 5 1 0
14-006 320 4 0 0
15-001 320 5 3 3
15-002 320 5 2 0
15-003 320 5 2 0
15-004 320 5 1 0
15-005 320 5 0 0
15-006 320 5 2 1
15-007 320 5 0 0
15-009 320 5 3 3
15-010 320 4 0 0
15-011 320 5 0 3
15-013 320 5 4 3
15-014 320 5 4 4
15-015 320 5 0
15-016 320 2 1 0
15-018 320 3 2 0
15-019 320 5 0 0
15-020 320 5 2 0
15-021 320 4 2 0
15-022 320 4 0 0
15-023 320 5 3 4
15-024 320 5 2 3
15-025 320 5 3 3
15-026 320 5 0 0
15-027 320 5 1 2
15-028 320 5 5 2
15-029 320 5 4 4
15-030 320 5 1 3
15-031 320 5 4 3
15-032 320 5 3 2
15-033 320 5 2 1
15-034 320 5 3 2
17-001 320 5 5 3
17-002 320 5 5 2
―――――――――――――――――――――――――
[Table 23]
―――――――――――――――――――――――――
No. Treatment dose H D E b
(G / ha)
―――――――――――――――――――――――――
1-001 320 0 0 0 0
1-002 320 5 5 5 5
1-003 320 5 5 5 5
1-004 320 5 5 5 5
1-005 320 5 5 5 5
1-006 320 5 5 5 5
1-007 320 0 5 0 0
1-008 320 5 5 4 5
1-009 320 0 0 0 0
1-010 320 5 5 5 5
1-011 320 0 5 0 0
1-012 320 0 0 0 0
1-013 320 0 2 0 0
1-014 320 5 5 5 5
1-015 320 5 5 5 5
1-016 320 5 5 5 5
1-017 320 5 5 5 5
1-018 320 5 5 3 5
1-019 320 5 5 5 5
1-020 320 5 5 2 5
1-021 320 2 0 0 0
1-022 320 5 5 4 5
1-023 320 5 5 0 4
1-024 320 5 5 5 5
1-025 320 5 5 5 5
1-026 320 5 5 5 5
1-027 320 5 5 5 5
1-028 320 5 5 5 5
1-029 320 5 5 4 5
1-030 320 5 5 3 5
1-031 320 3 4 0 5
1-032 320 5 5 5 5
1-033 320 5 5 5 5
1-034 320 5 5 5 5
1-035 320 5 5 5 5
1-036 320 5 5 5 5
1-037 320 0 0 0 0
1-038 320 5 5 5 5
1-039 320 5 5 5 5
1-040 320 5 4 4 5
1-041 320 5 5 5 5
1-042 320 5 5 5 5
1-043 320 5 5 5 5
1-044 320 5 5 5 5
1-045 320 5 4 0 3
1-046 320 5 5 5 5
1-047 320 1 3 0 2
1-048 320 5 4 5 5
1-049 320 0 0 0 0
1-050 320 5 4 5 5
1-051 320 5 5 5 5
1-052 320 5 5 5 5
1-053 320 5 5 4 5
1-054 320 5 5 0 5
1-055 320 5 5 4 5
1-056 320 5 5 5 5
1-057 320 4 3 3 5
1-058 320 5 5 5 5
1-059 320 4 1 3 5
1-060 320 5 5 5 5
1-062 320 4 3 4 5
1-063 320 5 5 5 5
1-064 320 5 5 5 5
1-065 320 5 5 5 5
1-066 320 5 2 5 5
1-067 320 5 5 5 5
1-068 320 5 5 5 5
1-069 320 5 5 5 5
1-070 320 5 4 4 5
1-071 320 5 5 5 5
1-072 320 4 5 4 5
1-073 320 5 5 5 5
1-074 320 5 5 5 5
1-075 320 5 5 5 5
1-076 192 5 5 5 5
1-078 320 5 4 0 5
1-079 320 5 5 5 5
1-080 320 5 5 5 5
1-081 320 5 5 5 5
1-082 320 5 5 5 5
1-083 320 5 5 5 5
1-084 320 2 0 0 1
1-085 320 5 4 0 5
1-086 320 5 4 4 5
1-087 320 5 5 5 5
1-088 320 5 5 5 5
1-089 320 5 5 5 5
1-090 320 5 5 5 5
1-091 320 5 5 5 5
1-092 320 5 5 5 5
1-093 320 5 5 5 5
1-094 320 5 5 4 5
1-095 320 5 5 5 5
1-096 320 5 5 5 5
1-098 320 5 5 5 5
1-099 320 5 5 5 5
1-100 320 5 5 5 5
1-101 320 5 5 5 5
1-102 320 5 5 5 5
1-103 320 5 5 5 5
1-104 320 5 5 5 5
1-105 320 5 5 5 5
1-106 320 5 5 5 5
1-107 320 5 5 5 5
1-108 320 5 5 5 5
1-109 320 5 5 5 5
1-110 320 5 5 5 5
1-111 320 5 5 5 5
1-112 320 5 5 5 5
1-114 320 5 5 2 5
1-116 320 5 3 4 5
1-117 320 5 4 5 5
1-118 320 4 0 0 5
1-119 320 5 4 0 5
1-120 320 5 0 4 3
1-121 320 5 5 4 5
1-122 320 5 5 5 5
1-123 320 5 5 4 5
1-124 320 5 5 0 5
1-125 320 5 5 2 5
1-126 320 3 5 2 5
1-130 320 4 5 4 5
1-131 320 5 5 5 5
1-132 320 2 1 0 1
1-133 320 3 0 0 0
1-134 320 5 5 5 5
1-135 320 5 4 5
1-136 320 5 2 5
1-137 320 5 5 5
1-138 320 3 2 5
1-139 320 5 5 5 5
1-140 320 5 5 5
1-141 320 2 0 1
1-142 320 5 5 5
1-143 320 4 4 5
1-144 320 5 5 5
1-145 320 5 5 5
1-146 320 5 5 5
1-147 320 5 5 5
1-148 320 5 5 4 5
1-149 320 5 5 5 5
1-150 320 5 4 5
1-151 320 4 4 5
1-152 320 5 5 5 5
1-153 320 5 5 4 5
1-154 320 5 5 5 5
1-155 320 5 5 5 5
1-156 320 5 5 5 5
1-157 320 0 4 0
1-158 320 0 2 0 2
1-159 320 4 5 4 5
1-160 320 5 5 5 5
1-161 320 4 5 4 5
1-162 320 5 5 5 5
1-163 320 5 5 5 5
1-164 320 2 3 0 4
1-166 320 4 4 3
1-167 320 5 5 5 5
1-168 320 5 5 5 5
1-169 320 5 5 5 5
1-170 320 5 5 4 5
1-171 320 5 4 4 5
1-172 320 5 5 5 5
1-173 320 5 5 5 5
1-174 320 5 5 5 5
1-175 320 5 5 5 5
1-176 320 5 5 5 5
1-177 320 5 5 5 5
1-178 320 5 5 5 5
1-179 320 5 5 5 5
1-180 320 5 5 5 5
1-181 320 5 5 5 5
1-182 320 4 5 5 5
1-183 320 5 5 5 5
1-184 320 5 5 4 5
1-186 320 4 5 4 5
1-187 320 5 5 4 5
1-188 320 4 4 4 4
1-189 320 4 5 5 4
1-190 320 4 3 0 5
1-191 320 5 5 4 5
1-192 320 2 4 0 4
1-193 320 5 5 5 5
1-194 320 5 5 4 5
1-195 320 5 5 4 5
1-196 320 5 5 5 5
1-197 320 5 5 4 5
1-198 320 5 5 4 5
1-199 320 5 5 5 5
1-200 320 5 5 4 5
1-201 320 5 5 4 5
1-202 320 5 5 2 5
1-203 320 5 5 5 5
1-204 320 5 5 5 5
1-205 320 5 5 5 5
1-206 320 5 5 4 5
1-207 320 5 5 5 5
1-208 320 5 5 4 5
1-209 320 5 5 5 5
1-210 320 5 5 5 5
1-212 320 5 5 0 5
1-213 320 5 5 2 5
1-214 320 5 5 3 5
1-215 320 5 5 5 5
1-216 320 5 5 5 5
1-217 320 5 5 5 5
1-218 320 5 5 5 5
1-219 320 5 5 3 5
1-221 320 5 5 0 5
1-222 320 3 2 0 4
1-223 320 5 5 3 5
1-224 320 5 2 0 5
1-225 320 4 5 2 5
1-226 320 5 5 5 5
1-227 320 5 5 5 5
1-228 320 5 5 5 5
1-229 320 5 5 5 5
1-230 320 5 4 3 5
1-231 320 5 4 4 5
1-232 320 3 3 0 4
1-233 320 5 3 3 5
1-234 320 3 2 0 5
1-235 320 3 2 0 5
1-236 320 2 0 0 0
1-238 320 5 5 4 5
1-239 320 5 5 4 5
1-240 320 5 5 4 5
1-241 320 5 5 3 5
1-242 320 5 5 3 4
1-243 320 5 5 5 5
1-244 320 5 5 5 5
1-245 320 5 5 5 5
1-246 320 5 5 5 5
1-247 320 5 5 5 5
1-248 320 5 5 5 5
1-249 320 4 5 4 5
1-250 320 5 5 5 5
1-251 320 5 5 5 5
1-252 320 5 5 5 5
1-253 320 5 5 5 5
1-254 320 5 5 5 5
1-255 320 5 5 5 5
1-256 320 5 5 5 5
1-257 320 5 5 5 5
1-258 320 5 5 5 5
1-259 320 5 5 5 5
1-260 320 5 5 5 5
1-261 320 5 5 5 5
1-262 320 5 5 5 5
1-263 320 5 5 5 5
1-264 320 5 5 5 5
1-265 320 5 5 5 5
1-266 320 5 5 5 5
1-267 320 5 5 5 5
1-268 320 5 5 5 5
1-269 320 5 5 5 5
1-270 320 5 5 5 5
1-271 320 5 5 5 5
1-272 320 5 5 5 5
1-273 320 5 5 5 5
1-296 320 5 5 4 5
1-297 320 5 5 5 5
1-298 320 5 5 5 5
1-299 320 5 5 5 5
1-300 320 5 5 5 5
1-301 320 5 5 5 5
1-302 320 5 5 5 5
1-303 320 5 5 5 5
1-304 320 5 5 5 5
1-305 320 5 5 5 5
1-306 320 5 5 5 5
1-307 320 5 5 5 5
1-308 320 5 5 5 5
1-309 320 5 5 5 5
1-310 320 5 5 4 5
1-311 320 5 5 5 5
1-312 320 5 5 5 5
1-313 320 3 3 0 4
1-314 320 4 3 0 4
2-001 102 5 5 5 5
2-002 320 0 0 0 0
2-003 320 5 5 4 4
2-005 269 5 5 4 5
2-006 320 5 5 5 5
2-007 320 5 5 5 5
2-008 320 0 0 0 0
2-009 320 3 0 0 1
2-010 320 3 0 0 1
2-011 320 0 0 0 0
2-012 320 0 0 0 0
2-013 320 0 0 0 0
2-014 320 5 4 5 5
2-015 320 1 0 0 4
2-016 320 5 5 4 5
2-017 320 5 5 5 5
2-018 320 5 5 5 5
2-020 320 2 2 0 2
2-021 320 5 3 3 5
2-022 320 1 4 2 5
2-024 320 5 3 0 5
2-025 320 3 1 0 4
2-026 320 5 4 5 5
2-027 320 3 0 0 5
2-028 320 5 5 4 5
2-029 320 0 0 0 4
2-030 320 4 5 0 5
2-031 320 5 5 5 5
2-032 320 5 3 4 5
2-034 320 4 4 4 5
2-035 320 5 5 3 5
3-001 320 3 2 0 2
3-002 320 0 0 0 0
4-001 320 2 3 0 4
5-001 320 2 3 0 5
5-002 320 0 0 0 0
6-001 320 5 5 0 5
6-002 320 4 4 0 5
6-003 320 5 5 5 5
6-004 320 5 5 5 5
6-005 320 5 5 3 5
6-006 320 5 5 5 5
6-007 320 5 5 5 5
6-008 320 5 5 5 5
6-009 320 5 5 0 5
6-010 320 5 5 5 5
6-015 320 5 5 5 5
6-016 320 5 5 1 5
6-017 320 5 5 4 5
6-018 320 5 5 5 5
6-023 320 5 5 4 5
6-024 320 3 2 3 3
6-025 320 5 5 4 5
6-026 320 5 5 5 5
6-027 320 2 3 0 0
6-029 320 5 5 5 5
6-030 320 4 5 0 2
6-031 320 3 2 2 4
6-033 320 0 0 3 0
6-034 320 5 5 4 5
6-035 320 5 5 5 5
6-036 320 4 5 3 4
6-037 320 5 5 5 5
6-038 320 5 5 5 5
6-049 320 5 5 5 5
6-050 320 5 5 5 5
6-051 320 5 5 5 5
6-052 320 5 5 3 5
6-053 320 5 5 3 5
6-054 320 5 5 3 5
6-055 320 5 5 5 5
6-056 320 4 5 3 5
6-057 320 5 5 5 5
6-058 320 5 5 5 5
6-059 320 5 5 5 5
6-060 320 5 5 5 5
6-061 320 5 5 5 5
6-062 320 5 5 5 5
6-063 320 4 5 1 5
6-064 320 5 5 0 4
6-065 320 5 5 5 5
6-066 320 5 5 5 5
6-068 320 0 2 0 0
6-070 320 0 4 0 0
6-071 320 4 5 0 1
6-072 320 5 5 0 0
6-073 320 5 5 5 5
6-074 320 4 5 2 1
6-075 320 3 3 3 4
6-076 320 5 5 5 5
6-077 320 5 5 5 5
6-078 320 5 5 0 5
6-079 320 5 5 4 5
6-080 320 5 5 5 5
6-081 320 1 3 0 0
6-082 320 5 5 5 5
6-083 320 5 5 5 5
6-084 320 5 5 5 5
6-085 320 5 5 5 5
6-086 320 5 5 5 5
6-087 320 5 5 0 5
6-088 320 5 5 5 5
6-089 320 5 5 4 5
6-090 320 0 5 0 0
6-091 320 5 5 5 5
6-092 320 5 5 4 5
6-093 320 5 5 4 5
6-094 320 5 5 5 5
6-095 320 5 5 5 5
6-096 320 5 4 5 5
6-098 320 3 5 4 5
6-099 320 5 5 5 5
6-100 320 5 5 5 5
6-103 320 5 5 5 5
6-104 320 5 5 5
6-105 320 3 4 4
6-106 320 4 5 5
6-107 320 5 5 5
6-108 320 5 5 5
6-109 320 5 4 5
6-110 320 5 5 5
6-111 320 5 5 5
6-112 320 5 5 4 5
6-113 320 5 5 5 5
6-114 320 5 5 5 5
6-115 320 5 5 4 5
6-117 320 5 5 5 5
6-118 320 5 5 4 5
6-119 320 5 5 5 5
6-120 320 5 5 4 5
6-121 320 5 5 5 5
6-122 320 5 5 4 5
6-123 320 5 5 5 5
6-124 320 5 5 5 5
6-125 320 0 3 0 0
6-126 320 5 5 5 5
6-127 320 5 5 4 5
6-128 320 5 5 5 5
6-129 320 5 5 3 5
6-130 320 5 5 4 5
6-131 320 5 5 5 5
6-132 320 5 5 5 5
6-133 320 5 5 0 5
6-134 320 5 5 3 5
6-135 320 5 3 3 5
6-136 320 5 5 5 5
6-137 320 5 5 5 5
6-138 320 5 0 0 5
6-139 320 5 0 0 5
6-140 320 5 2 0 5
6-141 320 5 4 4 5
6-142 320 5 0 0 5
6-143 320 5 0 0 5
6-144 320 4 0 0 5
6-145 320 4 0 0 5
6-146 320 5 4 0 5
6-147 320 5 4 1 5
6-148 320 5 2 0 5
6-149 320 5 4 2 5
6-150 320 5 4 0 5
6-151 320 5 3 0 5
6-152 320 5 5 0 5
6-153 320 5 5 5 5
6-154 320 5 5 4 5
6-155 320 5 5 5 5
6-156 320 5 5 5 5
6-157 320 5 5 5 5
6-158 320 5 5 5 5
6-159 320 5 5 5 5
6-160 320 5 5 5 5
6-161 320 5 5 4 5
6-162 320 5 5 4 5
6-163 320 5 5 4 5
6-164 320 5 5 5 5
6-165 320 5 5 5 5
6-166 320 5 5 5 5
6-167 320 5 5 5 5
6-168 320 5 5 4 5
6-169 320 5 5 5 5
6-170 320 5 5 5 5
6-171 320 5 5 5 5
6-172 320 5 5 5 5
6-173 320 5 5 4 5
6-174 320 5 5 5 5
6-175 320 5 5 4 5
6-176 320 5 5 5 5
6-177 320 5 5 5 5
6-178 320 5 5 5 5
6-179 320 5 5 5 5
6-180 320 5 5 5 5
6-181 320 5 5 4 5
6-182 320 5 5 4 5
6-183 320 5 5 5 5
6-184 320 5 5 5 5
6-185 320 5 5 5 5
6-186 320 5 5 4 5
6-187 320 5 5 5 5
6-188 320 5 5 4 5
6-189 320 5 5 5 5
6-190 320 5 5 5 5
6-191 320 5 5 5 5
6-192 320 5 5 4 5
6-193 320 5 5 5 5
6-195 320 5 5 5 5
6-196 320 5 5 5 5
6-197 320 5 5 5 5
6-198 320 5 5 5 5
6-199 320 5 5 5 5
6-200 320 5 5 5 5
6-201 320 5 5 4 5
6-202 320 5 5 5 5
6-203 320 5 5 5 5
6-204 320 5 5 5 5
6-205 320 5 5 5 5
6-206 320 5 5 4 5
6-207 320 5 5 5 5
6-208 320 5 5 5 5
6-209 320 5 5 5 5
6-210 320 5 5 5 5
6-211 320 5 5 5 5
6-212 320 5 5 5 5
6-213 320 5 5 5 5
6-214 320 5 5 4 5
6-215 320 5 5 5 5
6-216 320 5 4 4 5
6-217 320 5 5 4 5
6-218 320 5 5 5 5
6-219 320 5 5 4 5
6-220 320 5 5 5 5
6-221 320 5 5 5 5
6-222 320 5 5 5 5
6-223 320 5 5 5 5
6-224 320 5 5 5 5
6-225 320 5 5 5 5
6-226 320 5 5 5 5
6-227 320 5 5 5 5
6-228 320 5 5 5 5
6-229 320 5 5 5 5
6-230 320 5 5 5 5
6-231 320 5 5 5 5
6-232 320 5 5 5 5
6-233 320 5 5 5 5
6-234 320 5 5 5 5
6-235 320 5 5 5 5
6-237 320 2 5 4 5
6-239 320 5 5 5 5
6-240 320 5 5 5 5
6-241 320 5 5 5 5
6-242 320 5 5 5 5
6-243 320 5 5 5 5
6-244 320 5 5 5 5
6-245 320 5 5 5 5
6-246 320 5 5 5 5
6-247 320 5 5 5 5
6-248 320 5 5 4 5
6-249 320 5 5 5 5
6-250 320 5 5 5 5
6-251 320 5 5 5 5
6-252 320 5 5 5 5
6-253 320 5 5 5 5
6-254 320 5 5 5 5
6-255 320 5 5 5 5
6-256 320 5 5 5 5
6-257 320 5 5 5 5
6-258 320 4 4 3 4
6-259 320 5 5 5 5
6-260 320 5 5 5 5
6-261 320 5 5 5 5
6-262 320 5 5 5 5
6-263 320 5 5 5 5
6-264 320 5 5 5 5
6-265 320 4 4 4 0
6-266 320 5 2 0 5
6-267 320 5 5 5 5
7-001 320 4 5 0 2
7-002 320 5 5 3 5
7-003 320 5 5 0 5
7-004 320 5 5 5 5
7-005 320 5 5 0 5
7-006 320 5 5 0 5
7-007 320 5 5 4 5
7-008 320 5 5 5 5
7-010 320 5 5 5 5
7-011 320 5 4 5 5
7-012 320 5 5 4 5
7-014 320 4 5 2 5
7-015 320 5 5 5 5
7-016 320 0 5 0 0
7-017 320 5 5 4 5
7-018 320 3 5 3 3
7-019 320 5 4 2 3
7-020 320 4 5 3 4
7-021 320 2 2 0 0
7-022 320 0 4 0 0
7-023 320 0 5 0 0
7-024 320 5 5 2 3
7-025 320 1 3 0 0
7-026 320 0 3 0 0
7-027 320 5 5 4 5
7-028 320 0 0 0 0
7-029 320 3 4 0 0
7-031 320 4 5 3 5
7-032 320 5 0 0 4
7-033 320 5 4 3 5
7-034 320 4 2 0 3
7-035 320 5 5 0 5
7-036 320 5 5 4 5
7-037 320 5 5 4 5
7-042 320 3 0 0 0
8-001 320 0 0 0 0
8-002 320 0 0 0 0
8-003 320 0 0 0 0
9-001 320 5 4 2 5
9-002 320 5 5 5 5
9-003 320 5 5 5 5
9-004 320 5 5 5 5
9-005 320 5 5 2 4
9-006 320 5 5 5 5
9-007 320 5 5 5 5
9-008 320 5 5 5 5
9-009 320 5 5 4 5
9-010 320 5 5 5 5
9-011 320 5 5 5 5
9-012 320 5 5 5 5
9-013 320 5 5 5 5
9-014 320 5 5 5 5
9-015 320 5 5 5 5
9-016 320 5 5 5 5
9-017 320 5 5 3 5
9-018 320 2 0 0 4
9-019 320 5 5 4 5
9-020 320 5 5 5 5
9-021 320 5 5 5 5
9-022 320 5 5 5 5
9-023 320 5 5 5 5
9-024 320 5 5 5 5
9-025 320 0 5 0 2
9-026 320 0 3 0 0
9-027 320 5 5 5 3
9-028 320 5 5 5
9-029 320 4 4 3
9-030 320 4 5 4 1
9-034 320 2 5 3 3
9-039 320 3 3 0 3
9-040 320 3 4 0 3
9-041 320 4 4 2 4
9-042 320 4 5 3 4
9-043 320 2 4 3 2
9-044 320 3 0 0 3
9-045 320 4 5 0 5
10-001 320 5 4 0 3
10-002 320 5 5 3 5
10-003 320 5 4 0 5
10-004 320 5 5 5 5
11-002 320 5 5 4 5
12-002 320 5 5 5 5
13-001 320 5 5 4 5
13-002 320 5 5 5 5
13-003 320 5 5 5 5
13-004 320 5 5 5 5
13-005 320 5 5 5 5
13-006 320 5 5 5 5
13-007 320 5 4 4 5
13-008 320 5 4 1 5
13-009 320 5 5 4 5
13-010 320 5 5 5 5
13-011 320 5 5 5 5
13-012 320 5 5 5 5
13-013 320 4 5 4 5
13-014 320 2 3 4 2
13-015 320 5 5 5 5
13-016 320 5 5 5 5
13-017 320 5 5 5 5
13-018 320 5 5 5 5
13-019 320 5 3 0 5
13-020 320 5 0 0 5
13-021 320 5 3 1 5
13-022 320 5 2 0 5
13-023 320 5 1 3 5
13-024 320 5 0 0 5
14-001 320 5 5 5 5
14-002 320 5 5 5 5
14-003 320 5 5 5 5
14-004 320 4 2 0 5
14-005 320 2 0 0 1
14-006 320 4 0 0 0
15-001 320 5 5 5 5
15-002 320 5 5 4 5
15-003 320 5 5 4 5
15-004 320 5 5 5 5
15-005 320 5 5 5 5
15-006 320 5 5 4 5
15-007 320 5 5 4 5
15-009 320 5 5 4 5
15-010 320 5 5 4 5
15-011 320 5 5 5 5
15-012 320 5 5 4 2
15-013 320 5 5 5 5
15-014 320 5 5 5 5
15-015 320 5 5 5 5
15-016 320 5 5 5 5
15-017 320 5 5 5 5
15-018 320 5 5 5 5
15-019 320 5 5 4 5
15-020 320 5 5 4 5
15-021 320 5 5 5 5
15-022 320 5 5 4 5
15-023 320 5 5 5 5
15-024 320 5 5 5 5
15-025 320 5 5 5 5
15-026 320 5 5 5 5
15-027 320 5 5 5 5
15-028 320 5 5 5 5
15-029 320 5 5 5 5
15-030 320 5 5 5 5
15-031 320 5 5 5 5
15-032 320 5 5 5 5
15-033 320 5 5 5 5
15-034 320 5 5 5 5
17-001 320 5 5 5 5
17-002 320 5 5 5 5
―――――――――――――――――――――――――
[Table 24]
―――――――――――――――――――――――――――
Treatment dose
No. (g / ha) FGHIJKLMNOPQR bcdefg
―――――――――――――――――――――――――――
1-001 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-002 320 5 5 5 5 5 5 5 5 5 5 3 1 5 5 4 0 4 5 5
1-003 320 5 5 5 4 5 5 5 4 3 3 0 5 5 3 5 2 4
1-004 320 5 5 5 5 5 5 5 5 5 0 0 0 5 4 3 3 4 4
1-005 320 5 5 5 5 5 5 5 5 5 0 0 0 5 4 2 4 4 4
1-006 320 5 4 5 3 4 5 5 4 4 0 0 0 0 5 1 0 0 0 0
1-007 320 0 0 0 0 0 2 3 0 0 0 0 0 0 0
1-008 320 5 4 4 0 5 5 5 0 0 3 0 0 0 0
1-009 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-010 320 5 5 5 5 5 5 5 5 5 4 2 4 5 4 4 4 4 4
1-011 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-012 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-013 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-014 320 5 5 5 5 5 5 5 4 5 4 4 4
1-015 320 5 5 5 5 5 5 5 5 5 3 5 4 3 3 4
1-016 320 5 5 5 5 5 5 5 5 5 5 4 3 2 0 4
1-017 320 5 5 5 5 5 5 5 5 5 5 4 2 2 0 4
1-018 320 5 5 5 4 5 5 5 4 2 5 4 0 4 0 4
1-019 320 5 5 5 5 5 5 5 4 3 5 4 3 3 0 4
1-020 320 5 5 5 4 5 5 5 3 0 0 0 5 1 0 2 0 4
1-021 320 0 0 0 0 0 2 0 0 0 0 0 2 0 0 0 0 0
1-022 320 5 5 5 4 5 5 5 0 0 5 0 0 4 3
1-023 320 4 3 3 0 0 3 4 0 0 0 0 0 5 0 0 0 0 0
1-024 320 5 5 5 4 5 5 5 3 4 0 5 1 1 4 0 3
1-025 320 5 5 5 3 4 5 5 0 0 0 0 5 0 0 0 0 4
1-026 320 5 5 5 3 5 5 5 0 0 0 4 0 0 2 3
1-027 320 5 5 5 4 5 5 5 0 0 0 5 4 0 3 0 4
1-028 320 5 5 5 4 5 5 5 3 3 5 0 0 4 0 4
1-029 320 5 5 5 4 3 5 5 0 0 0 5 0 0 0 0 3
1-030 320 3 2 2 0 3 5 3 0 0 4 0 0 0 0
1-031 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3
1-032 320 5 5 5 5 5 5 5 4 4 5 4 0 5 4 5
1-033 320 5 5 5 4 5 5 5 5 5 0 3 4 5 4 0 5 4 5
1-034 320 5 5 5 5 5 5 5 5 5 5 4 5 4 0 4 4 5
1-035 320 5 5 5 4 5 5 5 5 5 0 5 4 0 4 3 5
1-036 320 5 5 5 5 5 5 5 5 5 5 3 0 3 3 5
1-037 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-038 320 5 5 5 0 5 5 5 4 3 0 0 0 0 5 3 1 3 0 4
1-039 320 5 5 5 4 5 5 5 5 5 5 4 0 4 3 4
1-040 320 4 4 5 3 4 4 5 0 0 0 5 0 0 0 0 3
1-041 320 5 5 5 5 5 5 5 3 3 0 3 5 4 1 4 4
1-042 320 5 5 5 3 5 5 5 5 4 0 0 5 3 0 1 0 4
1-043 320 5 5 5 4 5 5 5 4 4 0 5 4 1 4 4 5
1-044 320 5 5 5 2 5 5 5 5 4 5 4 0 2 4
1-045 320 0 0 0 0 0 4 0 0 0 0 0 0 0 0 0 0
1-046 320 5 4 5 5 5 5 5 4 2 0 5 4 0 4 0 4
1-047 320 3 0 3 0 0 3 0 0 0 0 0 0 0 4 0 0 0 0
1-048 320 5 5 5 1 5 5 5 3 1 0 0 0 0 5 3 0 2 0 0
1-049 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-050 320 5 4 4 0 0 4 0 1 0 0 0 5 0 0 0 0 0
1-051 320 5 5 5 3 5 5 5 5 4 0 0 0 5 4 3 2 0 4
1-052 320 5 5 5 4 5 5 5 4 3 0 0 0 5 3 0 5 0 3
1-053 320 5 4 5 0 3 5 3 1 0 0 0 0 5 1 0 0 0 3
1-054 320 5 5 4 0 1 5 1 0 0 0 0 0 5 0 0 0 0 1
1-055 320 5 4 4 0 1 5 2 0 0 0 0 0 5 0 0 0 0 0
1-056 320 5 5 5 3 5 5 5 4 3 0 0 5 3 0 5 0 4
1-057 320 4 4 4 0 4 5 4 3 1 0 0 5 0 0 0 0 4
1-058 320 5 5 5 1 5 5 4 4 2 0 0 0 5 4 0 0 0 3
1-059 320 4 4 4 0 3 5 5 1 0 0 4 3 0 0 0 0
1-060 320 5 5 5 3 5 5 5 4 5 0 0 0 5 4 0 2 0 3
1-062 320 5 5 5 0 5 5 4 0 0 0 0 0 0 5 4 0 0 0 3
1-063 320 5 5 5 3 5 5 5 2 0 0 5 4 0 3 0
1-064 320 5 5 5 3 5 5 5 5 4 0 0 5 5 2 3 0 4
1-065 320 5 5 5 3 5 5 5 4 5 0 0 5 5 0 4 0 4
1-066 320 4 4 5 0 5 5 5 0 0 0 0 0 0 5 4 0 0 0 0
1-067 320 5 5 5 3 5 5 5 5 5 0 0 0 5 3 0 5 0 4
1-068 320 5 5 5 3 5 5 5 4 4 0 0 0 5 5 0 4 0 4
1-069 320 5 4 5 3 5 5 5 4 4 0 0 5 5 0 4 0 4
1-070 320 4 4 4 0 5 5 5 0 0 0 0 0 0 5 1 0 0 0 0
1-071 320 5 5 5 4 5 5 5 4 4 0 0 0 5 4 0 4 4
1-072 320 5 5 5 4 5 5 5 4 5 0 0 0 5 5 0 4 0 4
1-073 320 5 5 5 4 5 5 5 5 5 5 4 0 4 4
1-074 320 5 5 5 4 5 5 5 5 5 0 0 0 0 5 4 0 4 0 4
1-075 320 5 5 5 5 5 5 5 5 0 0 5 5 0 4
1-076 192 5 5 5 4 4 5 5 4 4 0 0 0 5 2 0 4 0 4
1-078 320 5 5 2 0 3 5 4 0 0 0 0 5 4 0 0 0 1
1-079 320 5 5 5 3 5 5 5 5 4 0 0 0 5 4 1 4 0 4
1-080 320 5 5 5 3 5 5 5 4 5 0 0 5 4 1 4 0 4
1-081 320 5 5 5 3 5 5 5 4 4 0 0 0 5 4 1 4 0 4
1-082 320 5 5 5 3 5 5 5 5 5 0 0 5 4 2 3 0 4
1-083 320 5 5 5 3 5 5 5 4 5 0 0 0 5 4 1 4 0 4
1-085 320 0 5 1 0 3 3 3 0 0 0 0 0 5 0 0 0 0 0
1-086 320 2 4 4 3 3 5 3 0 0 0 0 0 5 1 0 0 0 2
1-087 320 5 5 5 3 5 5 5 5 5 0 0 0 5 3 2 5 4 5
1-088 320 5 5 5 3 5 5 5 0 1 0 0 0 5 4 0 3 0 4
1-089 320 5 5 5 2 5 5 5 2 3 0 0 0 5 5 0 4 0 4
1-090 320 5 5 5 3 5 5 5 4 0 0 0 0 5 3 0 4 0 4
1-091 320 5 5 5 3 5 5 5 1 0 0 0 0 5 5 0 4 0 3
1-092 320 5 5 5 2 4 5 5 3 3 0 0 5 5 0 4 0 4
1-093 320 5 5 5 3 5 5 5 4 3 0 0 0 0 5 5 0 4 0 4
1-094 320 5 5 5 3 5 5 5 2 4 0 0 0 5 4 1 3 0 4
1-095 320 5 5 5 3 5 5 5 4 4 0 0 0 1 5 5 0 4 0 4
1-096 320 5 5 4 3 5 5 5 4 4 0 0 0 5 4 1 3 0 3
1-097 320 0 2 2 1 2 2 0 0 0 3 0 0 0 2 1 0 0 0 3
1-098 320 5 5 5 2 5 5 5 4 4 0 0 0 5 5 2 3 0 5
1-099 320 5 5 5 2 5 5 5 5 3 0 0 0 5 5 3 3 2 5
1-100 320 5 5 5 3 5 5 5 4 2 0 0 1 5 5 2 5 0 3
1-101 320 5 5 5 3 5 5 5 5 3 0 0 0 0 5 5 2 3 3 5
1-102 320 4 5 5 0 5 5 5 0 0 0 0 5 0 0 0 0 0
1-103 320 5 5 5 3 5 5 4 5 5 0 0 0 0 5 5 1 4 0 3
1-104 320 5 5 5 3 5 5 5 4 0 0 0 0 5 1 0 1 0 2
1-105 320 5 5 5 1 5 5 5 1 4 0 0 0 0 5 1 0 3 0 3
1-106 320 5 5 5 3 5 5 5 0 0 0 0 0 0 5 1 0 3 0 3
1-107 320 5 3 5 0 5 5 5 0 0 0 0 5 0 0 0 0 2
1-108 320 5 5 5 3 5 5 5 4 0 0 0 0 5 5 0 4 0 4
1-109 320 5 5 5 2 5 5 5 4 3 0 0 0 2 5 1 0 2 0 4
1-110 320 5 5 5 4 5 5 5 0 0 0 0 0 0 5 4 0 5 0 1
1-111 320 5 5 5 3 5 5 5 4 0 0 0 0 0 5 1 1 5 0 4
1-112 320 4 5 4 3 5 5 5 0 0 0 0 0 0 5 1 0 0 0 0
1-113 320 1 0 0 3 3 5 5 0 0 0 0 0 0 2 0 0 0 0 0
1-114 320 5 5 0 3 4 5 5 0 0 0 0 0 0 3 0 0 0 0 1
1-116 320 1 3 3 3 4 4 3 2 5 0 0 0 0 1 0 0 0 0 2
1-117 320 4 5 5 0 4 4 5 0 0 0 0 0 0 5 0 0 0 0 2
1-118 320 3 2 4 0 3 3 3 0 0 0 0 0 0 5 0 0 0 0 1
1-119 320 4 4 5 4 4 5 5 0 0 0 0 0 0 5 0 0 0 0 3
1-120 320 0 0 0 0 0 4 3 0 0 0 0 0 0 0 0 0 0 0 0
1-121 320 5 5 5 4 5 5 5 0 0 0 0 0 0 5 1 0 0 0 3
1-122 320 2 3 4 2 5 5 4 0 0 0 0 0 0 4 2 0 0 0 0
1-123 320 5 5 5 4 5 5 5 3 0 0 0 0 0 5 3 0 0 0 3
1-124 320 0 3 1 0 2 3 0 0 0 0 0 0 0 1 0 0 0 0 0
1-125 320 5 5 5 3 0 5 5 0 0 0 0 0 0 5 2 0 3 0 0
1-126 320 0 0 0 0 3 4 0 0 0 0 0 0 0 0 0 0 0 0 0
1-130 320 0 0 0 0 3 3 3 0 0 0 0 0 0 0 0 0 0 0 0
1-131 320 4 5 5 3 5 5 5 0 0 0 0 3 5 0 0 0 0 4
1-133 320 4 4 4 0 5 3 0 0 0 0 0 0 0 4 0 0 0
1-134 320 5 5 5 2 5 5 3 4 0 0 0 0 5 5 0 2 0 0
1-135 320 5 5 5 3 5 5 0 0 0 0 0 2 5 0 0 0 0 2
1-136 320 5 5 5 3 5 5 0 0 0 0 0 2 0 0 3 0 3
1-137 320 5 5 5 2 5 5 0 0 0 0 0 5 0 0 0 0 0
1-138 320 4 5 0 5 5 0 0 0 0 0 0 5 0 0 0 0 0
1-139 320 5 5 5 4 5 5 5 4 3 0 0 0 5 5 0 3 0 4
1-140 320 5 5 5 4 5 5 5 5 5 0 0 0 0 5 4 1 5 0 4
1-142 320 5 5 5 3 5 5 0 0 0 0 0 5 0 0 3 0 3
1-143 320 1 1 0 2 2 4 5 0 0 0 0 0 0 0 0 2 0 0
1-144 320 5 5 5 2 4 4 0 0 0 0 0 0 5 3 0 0 0 2
1-145 320 5 5 5 4 5 5 5 4 4 0 3 0 3 5 5 0 5 0 4
1-146 320 5 5 5 4 5 5 5 5 5 0 1 0 5 5 1 0 5 3 5
1-147 320 5 5 5 5 5 5 5 5 5 0 2 0 3 5 5 0 5 0 4
1-148 320 5 5 5 0 5 5 5 5 2 0 0 0 5 3 0 0 0 4
1-149 320 5 5 5 0 5 5 5 5 4 0 0 0 5 2 0 5 0 4
1-150 320 5 0 0 2 5 5 0 0 0 0 0 0 0 1 0 0
1-151 320 5 0 3 5 5 0 0 0 0 0 0 1 0 0 0 0 0
1-152 320 0 0 0 0 3 2 0 0 0 0 0 0 0 0 0 0 0 0
1-153 320 5 1 0 0 3 4 0 0 0 0 0 0 1 0 0 2 0 0
1-154 320 5 5 5 0 5 5 5 4 4 0 0 0 0 5 0 0 3 0 4
1-155 320 5 5 5 4 5 5 5 5 0 0 0 5 3 0 3 0 4
1-156 320 5 5 5 4 5 5 5 5 0 2 5 1 0 5 1 4
1-159 320 4 3 3 0 4 5 0 0 0 0 0 0 3 0 0 1 0 0
1-160 320 5 5 5 0 5 5 4 4 0 0 0 0 5 0 0 2 0 4
1-161 320 5 0 0 0 3 3 0 0 0 0 0 3 0 0 3 0 2
1-162 320 5 5 5 3 5 5 5 4 0 0 0 0 5 2 0 4 0 4
1-163 320 5 5 5 3 5 5 4 0 0 0 0 5 1 0 0 0 4
1-167 320 5 5 5 3 5 5 5 4 3 0 0 0 5 4 0 0 0 4
1-168 320 5 5 5 4 4 5 5 4 5 0 4 5 4 1 3 0 4
1-169 320 5 5 5 4 4 5 5 4 1 0 0 0 0 5 4 0 4 0 4
1-171 320 0 0 0 0 0 3 4 0 0 0 0 0 0 0 0 0 1 0 0
1-172 320 5 5 5 4 5 5 5 5 4 0 0 0 0 5 5 0 4 0 5
1-173 320 5 5 5 5 5 5 5 5 4 0 0 0 5 3 0 3 0 5
1-174 320 5 5 5 3 5 5 5 5 4 0 0 0 0 5 4 0 4 0 4
1-175 320 5 5 5 4 5 5 5 5 5 0 0 0 5 4 0 4 0 4
1-176 320 5 5 5 3 5 5 5 5 5 0 0 0 5 5 0 4 0 4
1-177 320 5 5 5 2 5 5 5 5 5 0 0 0 0 5 5 0 0 0 4
1-178 320 5 5 5 3 5 5 5 5 4 0 0 5 5 0 0 0 4
1-179 320 5 5 5 3 5 5 5 5 5 0 0 0 0 5 5 1 0 0 4
1-180 320 5 5 5 4 5 5 5 4 4 0 0 0 0 5 4 0 5 0 4
1-181 320 5 5 5 1 5 5 5 4 4 0 0 0 0 5 5 1 4 0 4
1-182 320 5 5 5 4 5 5 5 4 5 0 0 0 0 5 4 0 3 0 4
1-183 320 5 5 5 3 5 5 5 4 5 0 0 0 0 5 4 0 4 0 4
1-184 320 5 5 5 2 5 5 5 4 4 0 0 0 0 5 4 0 3 0 4
1-186 320 5 1 4 0 3 5 5 0 0 0 0 0 0 5 0 0 0 0 0
1-187 320 5 5 4 0 0 5 4 4 1 0 0 0 5 3 1 4 0 4
1-188 320 5 5 0 5 5 3 0 0 0 0 0 5 0 0 0 0 0
1-189 320 0 0 0 0 2 2 3 0 0 0 0 0 3 0 0 0 0 0
1-191 320 5 5 3 2 5 5 5 0 0 0 0 0 5 0 0 3 0 2
1-193 320 5 5 5 4 4 5 5 4 4 0 0 0 5 4 1 3 0 4
1-194 320 5 5 5 0 5 5 4 0 0 0 0 3 5 5 0 0 0 1
1-195 320 5 5 5 0 5 5 5 0 0 0 0 0 5 3 0 0 0 1
1-196 320 5 5 5 0 5 5 5 1 3 0 0 0 5 1 0 0 0 1
1-197 320 5 5 5 0 2 3 3 0 0 0 0 0 5 1 0 2 0 0
1-198 320 5 5 5 0 3 5 0 0 0 0 0 0 5 0 0 0 0 2
1-199 320 5 5 5 3 5 5 5 3 4 0 1 5 5 4 0 3 0 3
1-200 320 5 5 5 3 5 5 5 1 0 0 0 0 3 5 5 0 4 0 3
1-201 320 0 1 0 0 5 5 0 0 0 0 0 0 0 1 0 0 0 0 0
1-202 320 0 0 0 0 5 5 5 0 0 0 0 0 0 0 0 3 0 4
1-203 320 5 4 3 3 4 5 5 3 0 0 0 0 0 3 3 1 0 0 4
1-204 320 5 5 3 4 5 5 5 3 0 0 0 0 0 5 3 0 0 0 4
1-205 320 5 5 5 4 5 5 5 4 3 0 0 0 1 5 4 2 0 0 4
1-206 320 5 5 5 4 5 5 5 4 3 0 0 0 5 4 1 0 0 4
1-207 320 5 5 5 4 5 5 5 4 4 0 0 2 5 4 2 0 0 4
1-208 320 5 5 5 4 5 5 5 4 4 0 0 0 1 5 4 2 0 0 4
1-209 320 5 5 5 5 5 5 5 4 4 0 0 0 5 5 2 0 0 4
1-210 320 5 5 5 3 5 5 5 4 1 0 0 1 5 4 0 3 0 4
1-211 320 3 1 0 0 5 5 5 0 0 0 0 0 2 0 0 0 0 2
1-212 320 5 5 5 0 5 5 5 0 0 0 0 3 5 3 0 2 0 3
1-213 320 5 5 1 0 5 5 4 0 0 0 0 0 5 1 0 1 0 0
1-214 320 5 4 0 1 3 4 4 0 0 0 0 0 0 5 1 0 0 0 1
1-215 320 5 5 5 2 5 5 5 3 0 0 0 0 0 5 3 0 0 0 1
1-216 320 5 5 4 3 5 5 5 1 0 0 0 0 0 5 2 0 0 0 1
1-217 320 5 5 5 5 5 5 5 3 0 0 0 5 4 3 0 0 3
1-218 320 5 5 5 3 5 5 5 3 0 0 0 0 0 5 3 0 0 0 3
1-219 320 5 5 4 0 5 5 5 4 0 0 0 5 4 0 3 0 4
1-221 320 5 0 0 3 5 5 5 0 0 0 0 0 1 4 0 0 4 0 2
1-222 320 0 0 0 0 0 5 5 0 0 0 0 0 0 0 0 0 0 0
1-223 320 5 5 0 0 5 5 5 0 0 0 0 0 1 0 0 0 0 0
1-224 320 5 0 1 0 3 5 0 0 0 0 0 0 3 1 0 0 0 4
1-225 320 1 0 1 0 5 5 5 0 0 0 0 0 0 2 0 0 0 0 0
1-226 320 5 5 5 4 5 5 5 5 4 0 0 0 0 5 5 3 5 0 4
1-227 320 5 5 5 5 5 5 5 5 4 0 0 0 4 5 5 3 0 0 4
1-228 320 5 5 5 4 5 5 5 4 4 0 0 0 5 4 1 4 0 4
1-229 320 5 4 2 3 5 5 5 1 0 0 0 0 0 3 1 0 0 0 0
1-230 320 5 5 2 1 5 5 5 0 0 0 0 0 3 1 0 0 0 1
1-231 320 1 1 1 3 3 5 5 0 0 0 0 0 0 4 2 0 0 0 2
1-232 320 1 1 1 0 3 4 3 0 0 0 0 0 0 0 0 0 0 0 0
1-233 320 0 0 0 0 4 5 5 0 0 0 0 0 0 3 0 0 0 0 0
1-234 320 5 5 4 2 5 0 0 0 0 0 4 2 0 0 0 0
1-235 320 5 5 5 3 5 5 4 0 0 0 0 0 5 2 0 0 0 3
1-236 320 4 2 2 3 5 5 5 0 0 0 0 0 4 0 0 0 0 4
1-237 320 5 4 1 2 4 5 5 0 0 0 0 0 0 5 0 0 0 0 2
1-238 320 5 5 5 4 5 5 5 4 2 0 2 0 0 5 4 1 3 1 5
1-239 320 5 5 5 4 5 5 5 4 3 0 0 5 4 2 1 0 5
1-240 320 5 5 5 3 5 5 5 4 2 0 0 0 5 4 2 4 0 5
1-241 320 4 5 5 4 5 5 5 4 1 0 0 0 0 5 4 1 5 0 5
1-242 320 3 0 0 3 3 0 0 0 0 0 5 0 0 4 0 4
1-243 320 5 5 5 5 5 5 4 4 0 0 0 5 5 3 5 0 5
1-244 320 5 5 5 5 5 5 5 5 4 0 0 0 5 5 3 5 0 5
1-245 320 5 5 5 5 5 5 5 4 3 0 0 0 5 4 3 4 0 5
1-246 320 5 5 5 4 5 5 5 5 4 0 0 0 5 4 3 5 0 5
1-247 320 5 5 5 5 5 5 5 4 3 0 0 0 5 5 3 4 0 5
1-248 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 1 2 0 5
1-249 320 5 5 5 4 4 4 5 0 0 0 5 4 1 0 0 5
1-250 320 5 5 5 4 5 5 4 0 0 0 5 4 1 4 0 5
1-251 320 5 5 5 4 5 5 5 3 0 0 0 0 5 4 1 2 0 4
1-252 320 5 5 5 5 5 5 5 5 3 0 0 5 5 3 3 0 5
1-253 320 5 5 5 5 5 5 5 5 3 0 0 5 5 2 3 0 5
1-254 320 5 5 5 5 5 5 5 4 3 0 0 0 5 4 3 4 3 5
1-255 320 5 5 5 5 5 5 5 5 2 0 0 5 4 3 4 3 5
1-256 320 5 5 5 5 5 5 5 3 0 0 5 5 2 4 3 5
1-257 320 5 5 5 5 5 5 5 5 2 0 0 0 5 4 2 3 0 5
1-258 320 5 5 5 5 5 5 5 5 0 0 0 0 5 4 2 4 3 5
1-259 320 5 5 5 5 5 5 4 1 0 0 5 4 2 4 3 5
1-260 320 5 5 5 5 5 5 5 5 0 0 0 5 4 3 3 1 5
1-261 320 5 5 5 5 5 5 5 5 4 0 0 5 5 4 5 1 5
1-262 320 5 5 5 5 5 5 5 5 3 0 0 5 5 4 5 2 5
1-296 320 5 5 5 3 5 4 0 0 5 3 0 0 0 5
1-297 320 5 5 5 5 5 5 5 5 5 0 0 0 5 5 3 5 0 5
1-298 320 5 5 5 5 5 5 5 4 4 0 0 0 5 5 1 5 3 5
1-299 320 5 5 5 5 5 5 5 4 5 0 0 0 5 5 2 4 3 5
1-300 320 5 5 5 5 5 5 5 4 4 0 0 0 5 5 2 5 2 5
1-301 320 5 5 5 5 5 5 5 4 4 0 0 0 5 5 1 5 0 5
1-302 320 5 5 5 5 5 5 5 4 5 0 0 0 5 5 2 4 3 5
1-303 320 5 5 5 5 5 5 5 4 4 0 0 0 5 4 1 1 0 5
1-304 320 5 5 5 5 5 5 5 0 0 0 5 5 2 5 2 5
1-305 320 5 5 5 5 5 5 5 4 0 0 0 5 5 2 4 0 5
1-306 320 5 5 5 5 5 5 5 4 4 3 0 0 5 5 2 5 3 5
1-307 320 5 5 5 5 5 5 5 5 0 0 0 5 5 2 5 0 5
1-308 320 5 5 5 5 5 5 5 4 5 0 0 5 5 2 5 2 5
1-309 320 5 5 5 5 5 5 5 5 5 0 0 5 5 2 5 2 5
1-310 320 5 5 5 5 5 5 5 0 0 0 0 0 5 1 0 0 0 0
1-311 320 5 5 5 5 5 5 5 4 5 4 1 4 4 5
1-312 320 5 5 5 5 5 5 5 5 4 0 0 0 5 3 1 4 5
1-313 320 3 5 3 0 1 5 3 0 0 0 0 0 1 0 0 0 0 0
1-314 320 2 4 1 0 1 4 3 0 0 0 0 3 0 0 0 0 0
2-001 102 5 4 5 0 4 5 2 3 1 0 0 0 5 4 0 0 0 3
2-002 320 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0
2-003 320 4 0 0 0 4 5 5 0 0 0 0 2 0 0 0 0 0
2-005 269 5 4 5 0 4 5 1 0 0 0 0 5 0 0 0 0 4
2-006 320 5 5 5 3 5 5 5 4 0 0 0 0 0 5 2 0 0 0 4
2-007 320 5 4 5 0 3 5 3 0 0 0 0 0 5 0 0 0 0 4
2-008 320 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0
2-009 320 2 0 1 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0
2-010 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2-011 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2-012 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2-013 320 1 1 1 0 0 1 0 0 0 0 0 0 0 5 0 0 0 0 0
2-014 320 5 5 5 0 2 4 2 0 0 0 0 0 5 3 0 0 0 0
2-015 320 3 3 1 0 2 5 3 0 0 0 0 4 0 0 0 0 0
2-016 320 5 5 5 0 4 5 2 0 0 5 3 0 0 2
2-017 320 5 5 5 0 3 5 3 4 0 0 0 0 5 0 0 0 0 5
2-018 320 5 5 5 0 3 5 2 4 3 0 0 5 2 0 0 0 3
2-020 320 5 5 4 0 0 4 0 0 1 0 5 3 0 0 0 0
2-021 320 5 5 4 0 5 5 0 1 2 0 0 0 5 4 0 0 0 1
2-022 320 0 4 0 0 0 4 0 0 0 0 0 0 4 0 0 0 0 0
2-024 320 5 5 4 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0
2-025 320 4 5 4 0 0 4 0 0 0 0 0 0 0 5 0 0 0 0 0
2-026 320 5 5 5 0 3 5 2 0 0 0 0 5 1 0 0 0 4
2-027 320 3 5 3 0 1 2 0 0 0 0 0 4 1 0 0 0 0
2-028 320 4 5 1 0 3 5 2 1 0 0 0 0 0 5 2 0 0 0 0
2-030 320 4 5 1 0 3 4 4 0 0 0 0 0 0 5 1 0 0 0 0
2-031 320 5 5 5 0 3 5 2 1 0 0 0 0 5 5 0 3 0 3
2-032 320 4 5 4 0 5 5 0 0 0 0 0 0 5 1 0 0 0 1
2-034 320 5 4 4 0 0 5 0 0 0 0 0 0 5 2 0 0 0 0
2-035 320 5 5 5 3 5 5 5 0 0 0 0 5 1 0 5 0 0
3-001 320 2 0 0 0 1 4 5 0 0 0 0 0 0 2 0 0 0 0 0
3-002 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
4-001 320 2 0 0 0 3 5 5 0 0 0 5 0 0 0 0 1
5-001 320 4 0 1 0 2 5 5 0 0 0 5 0 0 0 0
5-002 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
6-001 320 5 5 5 5 5 5 5 0 0 0 0 5 5 0 5 0 2
6-002 320 2 3 2 0 2 5 4 0 0 0 5 0 0 0 0 0
6-003 320 5 5 5 3 5 5 5 5 3 0 0 5 4 0 0 0 4
6-004 320 5 5 5 4 5 5 5 0 4 0 5 2 0 0 4
6-005 320 5 5 5 4 5 5 5 0 0 0 0 0 5 3 1 4 0 0
6-006 320 5 5 5 4 5 5 5 4 3 0 0 2 5 5 0 5 0 4
6-007 320 5 5 5 4 5 5 5 4 3 0 0 0 5 5 0 5 0
6-008 320 5 5 5 4 4 5 5 0 0 0 0 0 5 3 0 4 0 0
6-009 320 5 5 5 4 5 5 5 5 5 4 5 5 0 5 2 4
6-010 320 5 5 5 3 5 5 5 3 1 0 5 4 0 4 0 0
6-015 320 5 5 5 0 5 5 5 3 5 3 2 5 5 0 0 0 4
6-016 320 5 5 4 0 0 0 5 0 2 0 0 0 0 2 0 0 0 0 0
6-017 320 5 5 3 0 4 5 0 1 0 0 0 0 3 0 0 0 0 0
6-018 320 5 5 5 0 5 5 5 0 0 0 0 0 0 3 0 0 0 0 0
6-023 320 1 3 0 0 4 5 4 0 0 0 0 5 1 0 0 3
6-025 320 3 4 0 2 2 5 4 0 0 0 0 0 5 0 0 0 0 0
6-026 320 4 4 1 0 1 1 0 0 2 0 0 0 0 5 0 0 0 0 0
6-029 320 5 5 5 4 5 5 5 0 0 3 4 5 2 0 4 0 2
6-031 320 0 0 0 0 0 3 0 0 4 0 0 0 0 0 0 0 3
6-034 320 5 5 5 4 5 5 5 1 2 0 0 4 2 1 0 0 0 1
6-035 320 5 5 5 3 4 5 5 0 0 3 0 3 5 2 0 0 0 0
6-037 320 5 5 5 5 5 5 5 5 3 0 0 0 1 5 5 2 5 0 3
6-038 320 5 4 5 2 5 5 5 5 4 0 0 1 5 5 1 1 0 5
6-049 320 5 5 5 5 5 5 5 4 4 4 4 3 4 5 5 0 5 3 5
6-050 320 5 4 4 2 4 5 0 0 0 3 0 5 1 0 0 0 2
6-051 320 5 5 5 1 5 5 5 1 5 0 2 0 0 5 1 1 2 0 4
6-052 320 4 3 4 0 0 0 5 0 0 0 2 0 0 1 0 0 0 0 3
6-053 320 4 3 2 1 0 0 0 0 0 0 0 2 1 0 0 0 0
6-055 320 5 5 5 0 4 5 5 3 0 0 0 0 0 5 5 0 0 0 0
6-056 320 0 2 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0
6-057 320 5 5 5 0 3 5 4 0 0 0 0 0 0 5 1 0 1 0 1
6-058 320 5 5 5 5 5 5 5 5 5 5 5 5 5 5 0 5 4 5
6-059 320 5 5 2 3 5 1 5 0 0 0 0 3 3 0 0 0 0 0 0
6-060 320 5 5 4 0 3 3 0 0 5 0 0 0 2 3 0 0 0 0 0
6-061 320 5 5 5 4 5 5 5 1 3 3 4 5 0 0 2 0 3
6-062 320 3 5 5 0 4 0 5 0 0 3 0 3 0 0 0 0 0 0
6-063 320 5 1 0 0 0 0 5 0 0 0 0 0 0 0 0 0 0 0 0
6-064 320 5 5 5 0 4 0 5 0 0 0 0 0 0 0 0 0 0 0 0
6-065 320 5 5 5 4 5 5 5 0 4 3 4 4 3 5 5 0 5 2 3
6-066 320 5 5 5 5 5 5 5 0 2 0 0 0 3 5 4 0 4 0 2
6-073 320 5 5 5 3 2 5 0 0 0 0 0 0 0 5 3 0 2 0 3
6-074 320 0 2 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0
6-075 320 0 0 0 0 4 4 3 0 0 0 0 0 0 0 0 0 0 0 0
6-076 320 5 5 5 3 0 5 5 5 1 0 0 0 0 5 5 0 0 0 2
6-077 320 5 5 5 4 5 5 5 5 5 4 3 4 4 5 0 0 0 1 4
6-078 320 5 5 0 3 0 0 3 1 0 0 0 0 1 0 1 0 0 0
6-079 320 5 5 5 0 3 5 5 1 4 0 0 0 3 3 0 0 3 0 0
6-080 320 5 5 5 0 5 5 5 0 1 0 0 0 0 0 0 0 0 0 0
6-082 320 5 5 5 3 5 5 5 2 0 0 0 3 1 0 0 0 0 0
6-083 320 5 5 0 0 5 1 5 0 0 0 0 0 3 0 0 0 0 0 0
6-084 320 5 5 5 5 5 5 0 4 3 3 3 4 2 0 5 2 0 1
6-085 320 5 5 5 5 5 5 4 5 5 5 4 4 1 1 5 3 3 4
6-086 320 5 5 5 4 5 5 0 3 3 4 4 1 0 5 2 1 4
6-087 320 5 5 5 0 4 3 0 0 0 0 0 2 0 0 3 0 0 1
6-088 320 5 5 5 5 5 5 3 0 5 5 4 4 0 0 5 0 0 3
6-089 320 5 4 1 0 2 3 0 0 0 0 0 0 0 0 0 0 0 0
6-091 320 5 5 5 5 5 5 5 4 3 4 0 4 5 5 1 5 1 4
6-092 320 5 5 3 3 3 5 0 0 0 0 0 4 0 0 0 0 0
6-093 320 5 5 5 0 3 1 0 0 5 0 4 1 0 0 0 0 0
6-094 320 5 5 5 5 5 5 4 0 5 0 0 3 5 1 0 0 0 4
6-095 320 5 5 5 3 5 5 5 1 0 0 0 0 5 2 0 2 0 4
6-096 320 4 4 4 3 3 5 0 0 0 0 0 5 3 0 0 0 0
6-099 320 5 5 5 5 5 5 5 3 5 4 4 3 4 5 5 0 5 2 5
6-100 320 5 5 5 5 5 5 5 4 5 5 4 1 5 5 4 0 3 0 5
6-103 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 0 5 0 0
6-104 320 5 5 5 4 5 1 5 5 5 4 3 4 4 5 5 0 5 4 4
6-106 320 5 5 3 3 3 0 0 0 0 0 0 1 0 0 0 0 3
6-107 320 5 5 5 3 5 4 4 4 2 2 4 5 0 0 4 1 4
6-108 320 5 4 5 3 3 5 5 4 5 3 3 3 5 1 0 3 0 4
6-109 320 5 5 0 5 5 0 0 0 0 0 0 1 0 0 0 0 0
6-110 320 0 0 5 0 3 3 0 0 0 0 0 0 0 0 0 0 0 0
6-111 320 4 0 4 0 5 5 0 0 0 0 0 0 1 0 0 0 0 0
6-112 320 5 5 5 4 5 5 1 1 0 0 0 0 5 4 0 3 0 0
6-113 320 5 5 5 0 5 5 0 0 0 0 0 5 1 0 0 0 1
6-114 320 5 5 5 3 5 5 5 2 0 0 0 0 0 5 2 0 3 0 0
6-115 320 0 0 0 0 2 2 5 0 0 0 0 0 0 0 0 0 0 0
6-117 320 5 5 5 4 5 5 5 5 5 0 0 5 5 2 0 0 5
6-118 320 5 5 5 5 5 5 5 5 5 0 0 0 5 4 2 4 0 4
6-119 320 5 5 5 4 5 5 5 5 5 0 0 0 5 5 0 0 5
6-120 320 5 5 5 4 5 5 5 5 0 0 0 5 5 1 0 0 5
6-121 320 5 5 5 4 5 5 5 5 5 0 0 5 5 1 4 0 5
6-122 320 5 5 5 4 5 5 5 5 5 0 4 5 5 2 3 0 5
6-123 320 5 5 5 4 5 5 5 5 0 4 0 0 0 5 1 0 5 0 4
6-124 320 5 5 5 4 5 5 5 5 4 0 0 5 3 1 2 0 4
6-126 320 5 5 5 4 5 5 5 5 5 0 3 0 5 5 1 5 0 5
6-127 320 5 0 4 0 5 5 5 0 0 0 0 5 0 0 2 0 0
6-128 320 5 5 5 3 5 5 5 5 5 3 3 0 3 5 5 4 5 0 4
6-129 320 5 5 5 3 5 5 5 5 5 3 3 4 3 5 5 2 5 0 3
6-130 320 5 5 5 3 5 5 5 5 5 4 0 0 4 5 5 0 5 0 4
6-131 320 5 5 5 3 5 5 5 5 5 0 0 0 4 5 5 0 5 0 3
6-132 320 5 5 5 0 5 5 5 0 0 0 0 0 1 0 0 0 0 0
6-133 320 3 2 1 0 4 4 5 0 0 0 0 0 0 0 0 0 0 0 0
6-134 320 5 5 5 3 5 5 5 5 5 0 0 0 4 5 5 0 5 0 5
6-135 320 5 5 5 0 3 5 5 4 1 0 0 0 0 5 5 0 0 0 0
6-136 320 5 5 5 3 5 5 5 5 4 0 0 5 5 3 5 0 4
6-137 320 5 4 5 2 0 5 4 2 0 0 0 5 3 0 3 0 2
6-138 320 0 0 0 0 5 0 2 0 0 0 0 0 0 0 0 0 0 0
6-139 320 0 0 0 0 5 5 5 0 0 0 0 0 0 0 0 0 0 0
6-140 320 5 0 4 0 5 5 5 0 0 0 0 0 1 0 0 0 0 0
6-141 320 5 5 5 3 5 5 5 0 0 0 0 0 0 5 5 0 4 0 0
6-142 320 5 1 5 0 5 5 5 0 0 0 0 0 3 0 0 0 0 0
6-143 320 0 0 0 3 5 5 5 0 0 0 0 0 0 0 0 0 0 0
6-144 320 5 5 3 0 4 5 5 0 0 0 0 0 5 1 0 0 0 0
6-145 320 3 0 0 0 5 5 5 0 0 0 0 0 0 0 0 0 0 0
6-146 320 5 5 5 3 5 5 5 0 0 0 0 0 5 3 0 0 0 0
6-147 320 5 5 5 0 4 5 5 0 0 0 0 0 5 3 0 0 0 0
6-148 320 5 5 5 0 5 5 5 0 0 0 0 0 5 5 0 0 0 0
6-149 320 5 5 5 4 5 5 5 0 0 0 0 0 3 0 0 0 0 0
6-150 320 5 5 4 0 3 4 5 0 0 0 0 0 1 0 0 3 0 0
6-151 320 5 5 2 4 0 0 5 0 0 0 0 0 0 0 0 0 0 0
6-152 320 5 5 5 3 4 5 5 0 0 0 0 0 5 5 0 3 0 0
6-153 320 5 5 5 1 5 5 5 4 3 0 0 0 4 5 5 1 3 0 3
6-154 320 5 5 5 0 5 5 5 4 0 0 0 0 5 4 0 2 0 4
6-155 320 5 5 5 3 5 5 5 5 5 0 0 3 5 5 3 3 0 4
6-156 320 5 5 5 4 5 5 5 5 5 3 0 3 5 5 2 4 0 4
6-157 320 5 5 5 3 5 5 5 5 4 3 0 3 5 5 2 3 0 4
6-158 320 5 5 5 3 5 5 5 5 4 0 0 0 2 5 5 1 3 0 4
6-159 320 5 5 5 2 5 5 3 5 4 0 0 0 5 5 3 3 0 4
6-160 320 5 5 5 3 5 5 5 5 4 0 0 3 5 5 2 4 3 4
6-161 320 5 5 5 3 4 5 5 5 0 0 0 0 5 4 1 4 0 3
6-162 320 5 5 5 4 4 5 5 4 0 0 0 0 0 5 4 1 4 0 4
6-163 320 5 5 5 4 5 5 5 5 0 0 0 0 5 5 1 4 0 4
6-164 320 5 5 5 5 4 5 5 5 4 0 0 0 0 5 5 1 4 0 4
6-165 320 5 5 5 3 5 5 4 5 4 0 0 0 0 5 5 1 3 2 3
6-166 320 5 5 5 4 5 5 5 5 4 3 3 0 3 5 5 1 4 3 3
6-167 320 5 5 5 3 5 5 5 5 4 3 0 0 3 5 5 1 4 3 4
6-168 320 5 5 5 4 4 5 5 5 4 0 0 0 2 5 5 1 3 0 3
6-169 320 5 5 5 2 5 5 5 5 4 0 0 0 2 5 5 2 4 0 3
6-170 320 5 5 5 4 5 5 5 5 4 0 0 3 5 5 3 4 3 4
6-171 320 5 5 5 4 5 5 5 5 4 0 0 5 5 5 3 4 4 5
6-172 320 5 5 4 4 5 5 5 3 0 0 0 0 0 5 5 0 0 0 3
6-173 320 5 5 5 3 5 5 5 5 3 0 0 0 0 5 5 1 3 0 4
6-174 320 5 5 5 3 5 5 5 5 1 0 0 0 0 5 5 3 4 0 4
6-175 320 5 5 5 3 5 5 5 5 0 0 0 0 0 5 5 1 4 0 2
6-176 320 5 5 5 3 5 5 5 5 0 0 0 0 0 5 5 2 1 0 1
6-177 320 5 5 5 5 5 5 5 4 3 0 0 0 0 5 4 2 4 0 5
6-178 320 5 5 5 4 4 5 4 5 3 0 0 5 5 3 5 5 5
6-179 320 5 5 5 4 5 5 5 5 3 0 0 0 0 5 5 3 5 0 5
6-180 320 5 5 5 5 5 5 5 5 5 0 5 5 3 5 4 5
6-181 320 5 5 5 4 5 5 5 5 4 0 0 5 5 3 4 0 5
6-182 320 5 5 5 4 5 5 5 5 4 2 0 5 5 2 5 0 5
6-183 320 5 5 5 5 5 5 5 5 4 0 0 5 5 3 3 0 5
6-184 320 5 5 5 5 5 2 0 0 0 5 5 4 3 5
6-185 320 5 5 5 5 5 5 5 4 0 0 0 5 5 4 5 0 5
6-186 320 3 0 0 0 0 2 2 0 0 0 0 0 5 0 0 0 0 3
6-187 320 5 5 5 5 5 5 5 5 0 5 4 3 4 0 5
6-188 320 5 5 5 4 5 5 5 5 4 0 0 0 5 4 3 4 0 4
6-189 320 5 5 5 4 5 5 5 5 4 4 0 0 5 5 3 3 0 5
6-190 320 5 5 5 4 5 5 5 5 4 3 0 0 0 5 5 3 5 0 4
6-191 320 5 5 5 3 5 5 5 5 0 0 0 5 5 3 4 0
6-192 320 5 5 5 4 5 5 5 5 4 0 0 0 5 5 3 5 0 4
6-193 320 5 5 5 5 5 5 5 5 4 0 0 0 5 5 3 0 5
6-195 320 3 3 5 0 2 0 0 0 0 0 0 5 0 0 0 0 0
6-196 320 5 5 5 5 5 5 5 5 5 0 0 5 5 2 5 3 5
6-197 320 5 5 5 5 5 5 5 4 0 0 0 0 5 4 0 2 0 4
6-198 320 5 5 5 4 5 5 5 4 0 0 0 0 5 3 0 0 0 4
6-199 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 0 3 0 4
6-200 320 5 5 5 5 5 5 0 0 0 0 5 3 1 4 0 4
6-201 320 1 2 2 0 4 2 0 0 0 0 5 1 0 0 0 3
6-202 320 1 5 3 0 3 5 5 2 0 0 0 0 5 0 0 0 0 2
6-203 320 3 0 1 0 3 0 2 0 0 0 0 0 1 0 0 0 0 4
6-204 320 3 1 2 0 2 2 3 0 0 0 0 0 3 0 0 2 0 4
6-205 320 5 5 5 5 5 5 5 4 0 0 0 0 5 4 1 4 0 5
6-206 320 4 1 2 0 2 3 0 0 0 0 0 1 0 0 0 0 4
6-207 320 5 5 5 5 5 5 5 5 4 0 0 5 5 3 5 4 5
6-208 320 5 5 5 5 5 5 5 5 5 5 5 3 5 4 5
6-209 320 5 5 5 4 5 5 5 5 1 0 0 0 5 2 0 5 0 4
6-210 320 5 5 5 4 5 5 5 5 0 0 0 5 3 1 0 0 5
6-211 320 5 5 5 5 5 5 5 5 3 0 5 5 5 3 5 4 5
6-212 320 5 5 5 5 5 5 5 5 0 0 0 5 3 2 5 0 5
6-213 320 5 5 5 5 5 5 5 5 4 0 0 0 5 5 2 5 0 5
6-214 320 5 5 5 4 5 5 5 4 0 0 0 0 5 3 1 3 0 5
6-215 320 5 5 5 5 5 5 5 4 3 0 0 0 5 3 1 5 0 5
6-217 320 5 3 3 0 5 5 5 0 0 0 0 0 4 1 0 0 0 0
6-218 320 5 5 5 3 5 5 5 4 0 0 0 0 5 2 0 1 0 5
6-219 320 5 5 5 2 5 5 4 1 0 0 0 0 5 2 0 0 0 1
6-220 320 5 5 5 4 4 5 5 0 0 0 0 5 4 0 3 0 5
6-221 320 5 5 5 5 5 5 5 5 0 0 0 5 4 2 4 0 4
6-222 320 5 5 5 4 5 5 5 5 1 0 0 0 5 4 1 3 0 4
6-223 320 5 5 5 5 5 5 5 5 0 0 0 5 5 2 4 0 4
6-224 320 5 5 5 5 5 5 5 5 4 0 4 5 5 3 5 3 5
6-225 320 5 5 5 5 5 5 5 5 4 5 5 4 5 3 5
6-226 320 5 5 5 5 5 5 5 5 3 4 5 5 4 4 5 5
6-227 320 5 5 5 5 5 5 5 5 4 3 0 4 5 5 4 5 4 5
6-228 320 5 5 5 5 5 5 5 5 1 0 4 5 5 4 5 5 5
6-229 320 4 5 4 0 5 5 5 2 0 0 0 0 5 4 0 0 0 1
6-230 320 5 5 5 5 5 5 5 5 3 0 4 5 5 4 5 4 5
6-231 320 5 5 5 5 5 5 5 5 2 0 4 5 5 4 5 4 5
6-232 320 5 5 5 5 5 5 5 5 5 1 4 5 5 3 4 4 5
6-233 320 5 5 5 5 5 5 5 5 4 4 1 4 5 5 4 4 5 5
6-234 320 5 5 5 5 5 5 5 5 4 1 0 4 5 5 3 4 2 5
6-235 320 5 5 5 5 5 5 5 5 4 5 5 4 5 5 5
6-237 320 3 0 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0
6-239 320 5 5 5 5 5 5 5 5 5 3 3 4 5 5 2 5 4 5
6-240 320 5 5 5 5 5 5 5 5 4 1 2 4 5 4 2 5 3 5
6-241 320 5 5 5 5 5 5 5 5 5 4 4 4 5 5 4 5 4 4
6-242 320 5 5 5 5 5 5 5 5 5 0 1 4 5 5 3 5 2 4
6-243 320 5 5 5 4 5 5 5 5 5 4 5 5 5 5 3 5 4 5
6-244 320 5 5 5 4 5 5 5 5 1 0 0 0 5 3 1 3 0 1
6-245 320 5 5 5 4 5 5 5 5 0 0 0 1 4 1 0 4 0 4
6-246 320 5 5 5 4 5 5 5 5 4 0 0 0 5 3 0 3 0 3
6-247 320 5 5 5 5 5 5 5 5 5 4 4 4 5 5 1 5 0 4
6-248 320 5 5 5 3 5 5 5 5 3 0 0 0 5 3 0 4 0 4
6-249 320 5 5 5 4 5 5 5 5 5 0 0 4 5 5 2 5 2 4
6-250 320 5 5 5 5 5 5 5 5 5 0 0 1 5 5 4 5 1 4
6-251 320 5 5 5 4 5 5 5 5 5 1 1 2 5 5 4 5 2 5
6-252 320 5 5 5 5 5 5 5 5 4 4 4 4 5 5 4 5 2 5
6-253 320 5 5 5 4 5 5 5 5 5 3 4 4 5 4 3 5 4 4
6-254 320 5 5 5 4 5 5 5 5 5 0 0 1 5 4 2 5 1 4
6-255 320 5 5 5 4 4 5 5 5 5 0 1 1 5 2 2 4 1 4
6-256 320 5 5 5 4 5 5 5 5 4 0 1 2 5 4 2 4 1 5
6-257 320 5 2 5 1 5 5 5 4 1 0 0 0 5 0 1 4 0 4
6-258 320 3 0 1 0 4 5 3 3 0 0 0 0 3 0 0 0 0 4
6-259 320 5 5 5 0 2 5 3 3 0 0 0 0 5 1 0 0 0 1
6-260 320 5 5 5 4 5 5 5 5 5 3 3 4 5 5 3 5 1 4
6-261 320 5 5 5 4 5 5 5 5 5 4 5 5 5 2 4 5
6-262 320 5 5 5 4 5 5 5 5 5 4 4 4 5 5 3 5 3 5
6-263 320 5 5 5 5 5 5 5 5 5 4 5 4 5 5 3 4 4 5
6-264 320 5 5 5 4 5 5 5 5 5 3 3 2 5 5 3 5 3 5
6-265 320 1 4 3 0 0 1 3 0 0 0 0 0 3 0 0 0 0 0
6-266 320 4 0 1 0 4 5 5 0 0 0 0 0 0 4 0 0 0 0 0
6-267 320 5 5 5 5 5 5 5 5 3 0 0 0 2 5 4 2 4 2 5
7-001 320 5 4 4 3 0 5 0 0 0 0 4 0 0 0 0 0
7-002 320 5 4 5 0 3 5 5 0 0 0 0 0 5 0 0 0 0 0
7-003 320 5 5 5 4 5 5 5 0 0 0 0 0 0 5 0 0 0 0 0
7-004 320 5 5 5 0 5 5 5 3 2 0 0 0 5 4 0 0 0 3
7-005 320 5 0 0 0 0 2 0 0 0 0 0 0 0 1 0 0 0 0 0
7-006 320 0 0 0 0 0 2 0 0 0 0 0 0 3 0 1 0 0 0
7-007 320 4 4 5 0 5 5 5 0 0 0 0 0 0 4 3 0 0 0 0
7-008 320 5 5 5 3 5 5 5 0 0 0 0 0 5 4 0 1 0 0
7-010 320 5 5 5 2 5 5 5 4 0 0 0 3 5 5 2 4 0 3
7-011 320 5 0 4 0 3 4 3 0 0 0 0 0 5 3 0 0 0 4
7-012 320 5 5 5 0 2 2 0 0 0 0 0 0 0 5 0 0 0 0 0
7-013 320 3 0 0 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0
7-014 320 3 2 0 0 0 3 0 0 0 0 0 0 4 0 0 0 0 0
7-015 320 5 5 5 3 5 5 4 0 0 0 0 0 5 5 0 4 0 2
7-016 320 3 2 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-017 320 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-018 320 3 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-019 320 3 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-020 320 3 2 0 0 3 3 0 0 0 0 0 0 0 5 0 0 0 0 0
7-024 320 4 0 0 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0 0
7-027 320 5 5 5 0 5 5 5 0 0 0 0 0 0 5 3 0 2 0 0
7-029 320 0 4 2 0 1 3 0 0 0 0 0 0 1 0 0 0 0 0
7-032 320 5 4 5 0 3 5 4 0 0 0 0 0 5 4 0 0 0
7-033 320 5 5 5 3 4 5 4 0 0 0 0 0 5 5 0 0 0 0
7-035 320 4 4 5 0 3 5 3 0 0 0 0 0 0 5 4 0 0 0 0
7-036 320 3 5 5 2 5 0 0 0 0 5 1 0 0 0 0
7-037 320 4 3 5 3 4 5 4 0 0 0 0 0 5 1 0 2 0 0
8-001 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
8-002 320 3 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0
8-003 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
9-001 320 4 4 5 0 3 5 4 0 1 0 0 4 0 0 0 0 0
9-002 320 5 5 5 3 5 5 5 0 0 0 0 0 5 3 0 0 0 0
9-003 320 5 5 5 3 5 5 5 0 0 0 0 0 0 5 5 0 4 0 5
9-004 320 5 5 5 2 5 4 5 0 0 0 0 0 0 0 0 0 0 0 0
9-005 320 1 0 0 0 1 4 4 0 0 0 0 1 0 0 0 0 0
9-006 320 5 5 5 4 5 5 5 0 2 0 0 0 4 5 5 0 5 0 3
9-007 320 5 5 3 3 5 5 5 0 0 0 0 0 0 5 0 0 0 0 0
9-008 320 5 5 5 3 5 5 5 4 4 0 0 0 3 5 4 0 5 0 4
9-009 320 5 4 0 0 4 5 4 0 0 0 1 0 0 0 0 0 0
9-010 320 5 5 5 4 5 5 5 0 0 0 0 0 5 1 0 0 0 0
9-011 320 5 5 5 3 5 5 5 3 0 0 0 0 5 5 0 4 0 4
9-012 320 5 5 5 0 5 5 5 0 0 0 0 2 5 2 0 0 0 0
9-013 320 5 5 5 5 5 5 5 3 1 0 4 5 5 0 4 5 4
9-014 320 4 3 1 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0
9-015 320 5 5 5 1 5 5 5 0 0 0 0 0 5 0 0 3 0 0
9-016 320 5 5 5 2 5 5 4 0 0 0 0 5 3 0 0 0 0
9-017 320 4 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0
9-019 320 0 5 0 0 5 3 0 0 0 0 0 5 0 0 0 0 0
9-020 320 4 5 0 0 3 5 4 3 0 0 3 0 0 0 0 0
9-021 320 5 5 5 1 5 5 5 1 0 0 0 0 3 5 3 0 3 0 2
9-022 320 5 5 5 0 0 0 0 0 0 0 0 0 4 1 0 0 0 0
9-023 320 5 5 5 2 3 3 5 0 5 0 0 0 0 5 3 0 3 0 4
9-024 320 5 5 5 3 5 5 5 0 3 0 4 0 4 5 0 0 2 0 0
9-025 320 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
9-027 320 5 5 5 4 5 5 5 0 3 3 3 0 3 5 0 0 2 0 1
9-028 320 5 5 5 3 5 5 5 0 0 0 0 0 0 3 1 0 3 0 4
9-029 320 3 4 3 0 3 4 0 0 0 0 0 0 1 0 0 0 0 0
9-030 320 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
9-034 320 4 3 4 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0
9-045 320 0 0 0 0 0 1 4 0 0 0 0 0 0 2 0 0 0 0 0
10-002 320 4 4 4 3 0 4 3 0 0 0 0 0 4 0 0 0 0 0
10-003 320 0 4 5 0 3 4 3 0 0 0 0 0 0 4 0 0 0 0 0
10-004 320 5 5 5 3 5 5 5 0 0 0 0 0 5 5 0 0 0 0
11-002 320 0 1 3 3 3 5 4 0 0 0 0 0 0 4 1 0 0 0 2
12-002 320 4 5 5 4 4 5 3 0 0 0 0 0 0 4 3 0 0 0 1
13-001 320 5 5 2 4 5 5 0 0 0 0 0 0 5 5 0 0 0 0
13-002 320 5 5 5 4 4 5 0 0 0 0 0 5 5 1 3 0 1
13-003 320 5 5 5 1 5 5 4 0 0 0 0 0 5 5 0 0 0 3
13-004 320 5 5 5 3 5 5 5 0 4 0 1 0 3 5 5 1 5 0 4
13-005 320 4 0 1 0 4 5 0 0 0 0 0 0 1 0 0 1 0 0
13-006 320 5 5 5 0 5 5 5 0 0 0 0 5 1 0 4 0 3
13-007 320 5 0 4 3 4 5 4 0 0 0 0 0 0 0 0 0 0
13-008 320 0 0 0 0 3 3 0 0 0 0 0 0 0 0 0 0 0
13-009 320 5 5 5 3 5 5 5 4 0 0 0 0 5 4 0 3 0 3
13-010 320 5 5 5 4 5 5 5 4 0 0 0 0 0 5 5 1 3 0 3
13-011 320 5 5 5 3 5 5 5 3 1 0 0 0 0 5 4 0 4 0 0
13-012 320 5 5 5 3 5 5 5 4 3 0 0 0 5 5 0 0 0 3
13-013 320 4 3 4 3 2 5 0 3 1 0 0 0 0 5 0 0 0 0 2
13-014 320 0 0 0 0 0 4 0 4 0 0 0 0 4 0 0 0 0 3
13-015 320 5 5 5 3 5 5 5 5 4 0 5 5 0 4 4
13-016 320 5 5 5 3 5 5 5 5 5 0 0 5 5 1 4 0 4
13-017 320 5 5 5 2 5 5 5 4 5 0 0 0 0 5 5 0 5 0 4
13-018 320 5 5 5 4 5 5 5 4 4 0 0 0 0 5 4 1 5 0 4
13-019 320 4 5 5 2 5 5 5 0 0 0 0 0 0 5 4 0 2 0 0
13-020 320 0 0 0 0 0 5 3 0 0 0 0 1 0 0 0 0 0 0 0
13-021 320 5 5 5 0 5 5 5 0 0 0 0 0 0 5 3 0 0 0 0
13-022 320 4 4 4 3 5 5 5 0 0 0 0 1 4 3 0 0 0 0
13-023 320 4 5 5 0 5 5 5 0 0 0 0 0 2 5 1 0 3 0 0
13-024 320 0 0 0 0 3 4 4 0 0 0 0 0 0 0 0 0 0 0 0
14-001 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 0 0 0 0
14-002 320 5 5 5 0 4 5 5 0 0 0 0 0 0 5 1 0 3 0 0
14-003 320 5 5 5 3 5 5 0 0 0 0 5 5 0 3 0 4
14-004 320 4 5 5 0 0 5 5 0 0 0 0 0 0 5 2 0 0 0 0
15-019 320 5 3 5 3 5 5 0 0 0 5 0 0 3 0 0
15-001 320 5 5 5 5 5 5 5 5 0 0 0 0 2 5 4 1 2 0 4
15-002 320 5 5 5 4 4 5 5 5 4 0 0 0 3 5 4 1 3 0 4
15-003 320 5 5 5 4 5 5 5 5 0 0 0 0 0 5 3 0 3 0 2
15-004 320 5 5 5 4 5 5 5 5 0 0 0 0 5 5 1 5 0 4
15-005 320 5 5 5 4 5 5 5 5 3 0 0 0 1 5 2 0 3 0 4
15-006 320 5 5 5 3 5 5 5 5 0 0 0 0 5 1 0 3 0 0
15-007 320 5 5 5 4 5 5 5 0 0 0 0 0 0 4 0 0 0 0 0
15-009 320 5 5 5 3 5 5 5 5 0 0 0 0 0 5 3 0 4 0 0
15-010 320 0 0 0 0 5 5 5 0 0 0 0 0 0 0 0 0 0 0 0
15-011 320 5 5 5 0 4 3 5 0 0 0 0 5 0 0 0 0 0
15-012 320 0 0 0 0 2 2 5 0 0 0 0 0 0 0 0 0 0 0
15-013 320 5 5 5 4 5 5 5 5 0 0 0 5 5 5 0 4
15-014 320 5 5 5 3 5 5 5 5 0 0 0 5 0 0 0 0 0
15-015 320 5 5 5 4 4 5 5 4 0 0 0 0 5 1 0 5 0 3
15-016 320 5 0 1 0 4 4 5 0 0 0 0 5 0 0 0 0 0
15-017 320 0 0 0 0 0 1 3 0 0 0 0 3 0 0 0 0 0
15-018 320 4 0 5 0 3 3 5 0 0 0 0 0 0 0 0 0 0
15-020 320 5 5 5 0 4 5 0 0 0 0 5 0 0 0 0 0
15-021 320 5 5 5 3 5 5 0 0 0 5 0 0 0 0
15-022 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 0 5 0 5
15-023 320 5 5 5 5 5 5 5 5 5 0 0 3 5 5 4 5 4 5
15-024 320 5 5 5 4 5 5 5 3 0 0 0 0 5 0 0 0 0 2
15-025 320 5 5 5 4 5 5 5 4 0 0 0 0 5 2 2 4 0 1
15-026 320 5 5 5 3 4 5 5 0 0 0 0 0 5 0 0 0 0 0
15-027 320 5 5 5 3 4 5 5 4 0 0 0 0 5 0 0 3 0 1
15-028 320 5 5 5 4 5 5 5 5 4 0 0 4 5 4 3 5 1 4
15-029 320 5 5 5 5 5 5 5 5 4 4 1 4 5 5 4 5 1 5
15-030 320 5 5 5 4 5 5 5 5 4 1 0 1 5 5 4 5 0 4
15-031 320 5 5 5 4 5 5 5 5 3 2 0 2 5 5 2 5 0 5
15-032 320 5 5 5 4 5 5 5 5 1 0 0 1 5 3 1 5 0 4
15-033 320 5 5 5 4 5 5 5 5 2 0 0 2 5 5 2 5 0 5
15-034 320 5 5 5 4 5 5 5 5 4 2 0 0 5 4 2 5 0 4
17-001 320 5 5 5 4 5 5 5 4 4 0 0 3 5 4 0 4 0 5
17-002 320 5 5 5 3 5 5 5 4 3 2 0 2 5 5 0 2 1 4
――――――――――――――――――――――――――――
[Table 25]
――――――――――――――――――――――――――――
Treatment dose
No. (g / ha) FGHIJKLMNOPQR bcdefg
――――――――――――――――――――――――――――
1-001 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-002 320 5 5 5 5 5 5 5 4 5 4 4 4 4 5 5 4 5 5 5
1-003 320 5 5 5 5 5 5 5 4 3 3 2 3 3 5 5 3 5 3 4
1-004 320 5 5 5 5 5 5 5 4 4 3 3 4 5 5 4 5 3 4
1-005 320 5 5 5 5 5 5 5 4 4 3 4 4 3 5 5 4 5 3 4
1-006 320 5 5 5 5 5 5 5 4 3 0 0 0 2 5 3 4 3 0 3
1-007 320 0 0 0 3 3 5 1 0 0 0 0 0 0 0 0 0 0 0 0
1-008 320 5 5 4 4 5 5 4 2 0 0 0 0 0 4 0 2 0 0 3
1-009 320 0 0 0 0 1 4 0 1 0 0 0 0 0 0 0 0 0 0 0
1-010 320 5 5 5 5 5 5 5 4 4 4 4 4 4 5 5 4 5 4 4
1-011 320 3 0 0 0 4 5 5 0 0 0 0 2 0 0 0 0 4
1-012 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-013 320 0 0 0 0 4 5 4 0 0 0 0 0 2 0 0 0 0 4
1-014 320 5 5 5 5 5 5 5 5 5 3 3 5 5 5 5 3 4
1-015 320 5 5 5 5 5 5 5 4 4 3 4 4 4 5 5 5 5 3 4
1-016 320 5 5 5 5 5 5 5 4 4 2 4 5 4 4 5 3 4
1-017 320 5 5 5 5 5 5 5 4 4 2 3 5 4 4 5 2 4
1-018 320 5 5 5 5 5 5 5 3 0 4 4 4 5 5 3 5 4 4
1-019 320 5 5 5 5 5 5 5 4 2 4 4 4 5 5 3 5 4 4
1-020 320 5 5 5 4 5 5 5 3 4 4 5 1 0 5 3 4
1-021 320 1 1 3 0 3 4 4 0 0 0 0 3 0 0 0 0 2
1-022 320 5 5 5 5 5 5 5 1 1 3 3 4 3 5 3 3 5 0 4
1-023 320 2 1 4 1 4 4 4 0 0 0 0 2 0 4 1 0 0 0 2
1-024 320 5 5 5 5 5 5 5 1 0 1 3 3 5 5 2 5 0 4
1-025 320 5 4 4 5 5 5 5 1 0 4 4 4 3 4 3 3 4 0 4
1-026 320 5 5 4 1 5 5 5 0 0 3 1 5 3 0 2 4
1-027 320 5 5 5 5 5 5 5 2 0 1 1 3 5 5 3 4 0 4
1-028 320 5 5 5 4 5 5 5 3 0 3 3 3 5 4 2 3 0 4
1-029 320 5 5 5 5 5 5 5 1 0 3 3 3 1 5 3 1 5 0 4
1-030 320 4 5 4 3 4 5 4 0 0 0 0 0 0 5 1 0 0 0 3
1-031 320 1 1 1 3 3 4 0 0 0 0 0 0 3 0 0 0 0 3
1-032 320 5 5 5 5 5 5 5 4 3 3 4 4 5 5 4 5 3 4
1-033 320 5 5 5 5 5 5 5 4 4 3 1 2 5 4 4 5 3 4
1-034 320 5 5 5 5 5 5 5 4 3 5 5 4 4 5 4 5
1-035 320 5 5 5 5 5 5 5 4 3 5 4 4 5 2 4
1-036 320 5 5 5 5 5 5 5 4 4 2 0 5 4 4 5 3 4
1-037 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-038 320 5 5 5 5 5 5 5 4 2 0 0 0 1 5 4 4 4 1 4
1-039 320 5 5 5 5 5 5 5 4 4 3 5 4 4 5 3 4
1-040 320 4 4 5 4 5 5 5 1 0 0 0 0 5 3 0 0 0 4
1-041 320 5 5 5 5 5 5 5 4 3 3 3 3 3 5 5 4 5 1 4
1-042 320 5 5 5 5 5 5 5 3 0 0 0 0 1 5 4 3 5 1 4
1-043 320 5 5 5 5 5 5 5 4 3 2 4 3 2 5 5 4 5 3 4
1-044 320 5 5 5 5 5 5 5 4 2 0 0 0 5 4 4 5 2 4
1-045 320 4 5 5 5 5 5 5 0 0 0 0 0 0 5 3 1 0 0 2
1-046 320 4 5 5 5 5 5 5 3 2 2 2 0 4 5 5 3 4 0 4
1-047 320 1 1 3 0 3 4 1 0 0 0 0 0 0 4 0 0 0 0 3
1-048 320 4 4 5 4 5 5 5 3 1 3 3 1 3 5 4 0 0 1 3
1-049 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
1-050 320 3 5 5 3 4 5 3 3 0 0 0 0 0 5 0 0 0 0 4
1-051 320 5 5 5 5 5 5 5 4 1 0 3 0 5 5 4 5 0 4
1-052 320 5 5 5 5 5 5 5 3 0 1 0 3 5 4 4 5 0 4
1-053 320 3 3 4 2 4 5 3 0 0 1 0 2 5 3 3 0 0 4
1-054 320 2 3 4 3 4 5 3 0 0 0 0 0 0 4 0 0 0 0 3
1-055 320 3 3 4 4 4 5 5 0 0 1 0 5 3 2 0 0 3
1-056 320 5 5 5 5 5 5 5 4 2 1 0 5 4 4 5 0 4
1-057 320 3 3 4 2 3 5 1 1 0 0 0 0 3 0 3 0 1 4
1-058 320 5 5 5 5 5 5 5 4 1 0 0 5 4 3 5 0 4
1-059 320 1 4 4 4 4 5 4 0 0 0 0 0 4 4 0 0 0 3
1-060 320 5 5 5 5 5 5 5 3 0 3 3 3 5 4 4 5 0 4
1-062 320 1 4 4 4 5 5 5 0 0 0 0 0 0 5 4 0 0 0 3
1-063 320 1 5 5 5 5 5 5 2 0 0 0 4 5 5 3 4 0 4
1-064 320 5 5 5 5 5 5 5 4 2 0 1 3 5 5 4 5 1 4
1-065 320 5 5 5 5 5 5 5 4 2 2 0 3 5 5 4 5 0 4
1-066 320 4 5 5 4 5 5 4 1 0 1 0 3 5 4 0 0 0 3
1-067 320 5 5 5 5 5 5 5 5 4 2 3 2 3 5 5 4 5 1 4
1-068 320 5 5 5 5 5 5 5 5 4 1 3 3 5 5 4 5 3 4
1-069 320 5 5 5 5 5 5 5 5 5 2 3 3 5 5 4 5 1 4
1-070 320 1 5 3 5 5 5 4 0 0 1 0 2 2 5 4 0 0 0 3
1-071 320 5 5 5 5 5 5 5 4 0 1 0 2 1 5 5 4 5 0 4
1-072 320 5 5 5 5 5 5 5 5 5 1 2 2 3 5 5 2 5 1 4
1-073 320 5 5 5 5 5 5 5 4 2 2 3 5 4 3 5 1 4
1-074 320 5 5 5 5 5 5 5 3 0 2 1 1 5 5 4 5 0 4
1-075 320 5 5 5 5 5 5 5 4 4 1 0 0 5 4 1 5
1-076 192 5 5 5 5 5 5 5 4 0 3 3 5 4 4 5 0 4
1-078 320 1 5 5 1 4 5 3 0 0 0 0 0 5 3 0 0 0 3
1-079 320 5 5 5 5 5 5 5 4 0 0 1 3 5 5 4 4 0 5
1-080 320 5 5 5 5 5 5 5 4 0 3 0 1 5 5 4 4 0 4
1-081 320 5 5 5 5 5 5 5 4 5 3 0 0 0 5 5 5 4 0 5
1-082 320 5 5 5 5 5 5 5 4 0 1 0 0 0 5 5 4 5 0 4
1-083 320 5 5 5 5 5 5 5 4 4 0 4 0 0 5 5 4 5 0 4
1-085 320 3 5 5 3 3 3 3 0 0 0 0 0 0 4 5 0 3 0 1
1-086 320 0 3 5 4 4 5 4 0 0 0 0 0 2 4 3 0 0 0 3
1-087 320 5 5 5 5 5 5 5 5 4 0 3 4 3 5 5 3 5 4 4
1-088 320 5 5 5 5 5 5 5 4 1 2 3 0 3 5 5 3 5 0 4
1-089 320 5 5 5 5 5 5 5 4 2 1 0 0 3 5 5 2 5 0 4
1-090 320 5 5 5 5 5 5 5 4 1 2 3 0 3 5 5 3 5 0 4
1-091 320 5 5 5 5 5 5 5 4 3 0 0 1 5 5 1 5 0 4
1-092 320 5 5 5 2 4 5 5 3 3 0 0 0 5 5 0 4 0 4
1-093 320 5 5 5 5 5 5 5 4 4 0 2 0 3 5 5 3 5 0 4
1-094 320 5 5 5 5 5 5 5 4 2 0 3 0 3 5 5 2 5 0 4
1-095 320 5 5 5 5 5 5 5 4 3 0 2 3 5 5 2 5 0 4
1-096 320 5 5 5 5 5 5 5 4 2 2 2 3 5 5 3 5 0 4
1-097 320 5 5 5 3 5 5 4 3 1 0 3 5 5 3 2 3
1-098 320 5 5 5 5 5 5 5 4 0 0 3 0 3 5 5 3 5 1 5
1-099 320 5 5 5 5 5 5 5 4 0 3 3 3 3 5 5 4 5 1 5
1-100 320 5 5 5 5 5 5 5 4 0 1 0 3 5 5 3 5 0 5
1-101 320 5 5 5 5 5 5 5 5 5 3 3 0 3 5 5 3 5 0 5
1-102 320 5 5 5 5 5 5 5 0 0 3 0 0 2 5 5 0 4 0 2
1-103 320 5 5 5 5 5 5 5 4 0 2 2 3 5 5 3 5 0 4
1-104 320 5 5 5 5 5 5 5 3 0 2 1 1 5 4 1 0 0 4
1-105 320 5 5 5 5 5 5 5 1 0 2 1 2 3 5 4 1 5 0 4
1-106 320 5 5 5 5 5 5 5 1 5 2 2 0 1 5 5 0 4 0 3
1-107 320 4 5 5 5 5 5 5 1 0 0 0 0 5 2 3 2 0 4
1-108 320 5 5 5 5 5 5 5 4 5 0 3 1 5 5 3 3 1 4
1-109 320 5 5 5 5 5 5 5 3 0 3 3 3 5 5 0 5 0 4
1-110 320 5 5 5 5 5 5 5 0 0 2 3 3 3 5 5 0 5 0 5
1-111 320 5 5 5 5 5 5 5 1 0 1 3 2 1 5 5 3 5 0 5
1-112 320 5 4 5 5 5 5 5 1 0 3 1 3 3 5 4 0 5 0 4
1-113 320 5 4 4 4 4 5 5 1 0 2 3 0 4 4 0 0 3 0 5
1-114 320 5 5 5 5 4 5 5 1 1 3 3 0 2 5 1 0 4 0 4
1-115 320 2 1 1 2 3 3 4 0 0 0 1 0 1 1 0 0 0 0 5
1-116 320 5 5 5 4 5 5 5 1 0 3 2 1 3 4 5 3 3 0 5
1-117 320 5 5 5 5 5 5 5 1 1 0 3 0 3 5 3 0 5 0 5
1-118 320 0 0 2 3 4 5 3 0 0 3 3 3 3 4 4 0 0 0 4
1-119 320 5 5 5 5 5 5 5 1 0 3 1 0 3 5 2 0 4 0 5
1-120 320 3 4 5 4 3 5 3 0 0 4 4 5 3 1 1 2 0 0 5
1-121 320 5 5 5 5 5 5 5 3 0 3 2 0 3 5 5 2 3 0 5
1-122 320 4 5 5 5 5 5 5 4 1 0 1 0 0 5 5 4 4 0 5
1-123 320 5 5 5 5 5 5 5 4 0 0 3 0 4 5 5 2 5 0 5
1-124 320 0 2 5 2 3 4 3 0 0 3 2 0 0 3 4 0 3 0 4
1-125 320 5 5 5 5 5 5 5 0 0 1 2 3 2 5 3 0 5 0 3
1-126 320 3 4 4 3 5 5 3 0 0 0 0 0 4 0 0 0 0 4
1-127 320 0 0 0 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0
1-130 320 4 5 5 5 5 5 5 0 0 0 0 0 5 1 1 2 0 5
1-131 320 0 5 4 4 5 5 5 0 0 0 0 0 4 4 3 0 2 0 5
1-132 320 0 0 0 1 2 3 1 0 0 0 0 0 0 1 0 0 0 0 3
1-133 320 0 4 4 3 4 5 2 0 0 0 3 0 3 1 0 3 0 3 4
1-134 320 5 5 5 5 5 5 5 2 1 4 2 4 1 5 5 2 5 0 4
1-135 320 5 5 5 5 5 5 5 3 0 5 1 0 3 5 4 1 2 0 4
1-136 320 5 5 5 4 5 5 5 3 0 1 4 2 5 3 1 3 0 4
1-137 320 5 5 5 5 5 5 5 4 3 0 0 2 5 3 0 3 0 4
1-138 320 5 5 5 5 5 5 5 3 0 0 1 3 3 5 2 0 3 0 4
1-139 320 5 5 5 5 5 5 5 2 0 1 3 3 2 5 5 1 5 0 4
1-140 320 5 5 5 5 5 5 5 4 3 2 3 2 3 5 4 3 5 3 5
1-142 320 5 5 5 5 5 5 5 4 0 2 3 3 3 5 5 3 4 3 4
1-143 320 5 5 5 5 5 5 5 1 1 0 0 0 0 2 3 1 3 0 4
1-144 320 5 5 5 5 5 5 5 4 1 0 2 2 3 5 5 3 4 2 4
1-145 320 5 5 5 5 5 5 5 3 0 1 2 2 3 5 5 2 5 2 4
1-146 320 5 5 5 5 5 5 5 5 0 2 3 3 3 5 5 4 5 4 5
1-147 320 5 5 5 5 5 5 5 4 1 1 3 4 4 5 5 3 5 3 4
1-148 320 5 5 5 5 5 5 5 4 2 1 3 3 3 5 4 3 5 3 5
1-149 320 5 5 5 5 5 5 5 4 0 2 3 3 2 5 4 2 5 2 4
1-150 320 5 4 5 5 5 5 5 3 0 0 0 0 0 5 4 0 4 0 4
1-151 320 5 5 5 5 5 5 5 3 0 0 0 0 1 4 4 2 3 2 4
1-152 320 5 5 5 4 5 5 5 4 3 0 0 0 0 5 2 1 3 0 4
1-153 320 5 5 5 5 5 5 5 4 4 0 0 3 0 5 3 1 5 0 4
1-154 320 5 5 5 5 5 5 5 4 3 1 2 3 3 5 3 3 5 1 4
1-155 320 5 5 5 5 5 5 5 4 2 0 2 0 3 5 4 3 5 2 4
1-156 320 5 5 5 5 5 5 5 4 3 2 3 3 4 5 4 3 5 3 4
1-158 320 0 0 1 3 1 4 0 0 0 0 0 0 0 1 0 0 0 0 2
1-159 320 5 1 4 5 5 5 5 4 3 0 0 0 0 3 0 1 2 2 4
1-160 320 5 5 5 5 5 5 5 4 0 2 3 4 3 5 4 2 5 5 5
1-161 320 4 0 4 4 5 5 5 0 0 0 0 0 0 3 1 0 2 0 3
1-162 320 5 5 5 5 5 5 5 4 1 4 4 4 3 5 4 2 5 3 4
1-163 320 5 5 5 5 5 5 5 4 3 3 3 3 3 5 4 2 5 4 5
1-166 320 1 1 4 5 4 5 5 3 0 0 0 0 0 3 1 1 1 0 4
1-167 320 5 5 5 5 5 5 5 4 0 0 4 4 5 5 3 5 2 5
1-168 320 5 5 5 5 5 5 5 4 0 1 3 3 5 5 4 5 2 4
1-169 320 5 5 5 5 5 5 5 4 0 0 3 3 5 5 3 5 0 4
1-170 320 5 5 5 5 5 5 5 0 0 0 0 5 0 1 2 0 4
1-171 320 3 0 5 5 5 5 5 0 0 0 5 2 0 3 0 3
1-172 320 5 5 5 5 5 5 5 4 0 3 3 0 4 5 2 5 0 5
1-173 320 5 5 5 5 5 5 5 3 1 0 0 3 5 5 2 5 0 5
1-174 320 5 5 5 5 5 5 5 3 2 0 0 0 5 5 2 5 0 4
1-175 320 5 5 5 5 5 5 5 2 1 1 1 2 5 5 2 5 0 4
1-176 320 5 5 5 5 5 5 5 4 1 3 3 0 2 5 5 3 5 0 5
1-177 320 5 5 5 5 5 5 5 3 0 0 2 0 5 4 2 5 0 4
1-178 320 5 5 5 5 5 5 5 2 0 0 2 0 5 5 2 5 0 4
1-179 320 5 5 5 5 5 5 5 4 1 1 1 1 5 5 3 5 0 4
1-180 320 5 5 5 5 5 5 5 4 1 0 0 2 5 5 1 5 1 5
1-181 320 5 5 5 5 5 5 5 5 1 0 0 3 5 5 1 5 0 5
1-182 320 5 5 5 5 5 5 5 4 1 0 0 0 5 4 2 3 0 4
1-183 320 5 5 5 5 5 5 5 4 0 0 1 0 2 5 5 1 5 2 5
1-184 320 5 5 5 5 5 5 5 3 0 0 1 0 2 5 5 1 5 1 4
1-185 320 0 0 0 0 3 4 0 0 0 0 0 0 0 0 0 0 0 1
1-186 320 4 4 4 3 5 5 5 1 0 0 0 0 0 5 1 1 0 0 3
1-187 320 5 5 5 5 5 5 5 5 5 0 0 0 0 5 5 3 5 0 5
1-188 320 4 4 5 5 5 5 5 1 0 0 3 0 1 4 1 3 0 0 4
1-189 320 3 0 0 5 4 5 5 0 0 0 0 0 0 5 3 2 0 0 4
1-190 320 0 0 4 5 5 5 5 1 1 0 0 0 0 5 1 2 0 0 3
1-191 320 5 5 5 5 5 5 5 3 0 0 0 0 4 5 4 3 5 3 4
1-192 320 4 4 2 2 5 5 3 0 0 0 0 0 0 4 0 2 0 0 4
1-193 320 5 5 5 5 5 5 5 4 0 0 1 3 5 3 5 2 4
1-194 320 5 5 5 5 5 5 5 3 0 0 0 3 5 5 1 4 0 4
1-195 320 5 5 5 5 5 5 5 3 0 0 0 0 5 4 2 4 0 4
1-196 320 5 5 5 5 5 5 5 1 1 0 0 0 3 5 3 0 5 0 4
1-197 320 5 5 5 4 5 5 5 3 0 0 0 2 5 3 0 2 0 4
1-198 320 5 5 4 5 5 5 5 3 0 2 2 0 3 5 2 3 3 3 5
1-199 320 5 5 5 5 5 5 5 4 1 2 3 4 4 5 4 0 5 3 4
1-200 320 5 5 5 5 5 5 5 3 0 3 0 1 3 5 5 3 5 0 4
1-201 320 5 5 5 5 5 5 5 0 0 0 0 0 3 5 3 1 5 0 4
1-202 320 5 5 5 5 5 5 5 0 0 0 0 1 5 4 0 5 0 4
1-203 320 5 5 5 5 5 5 5 3 0 0 0 0 1 5 3 2 1 0 4
1-204 320 5 5 5 5 5 5 5 4 0 0 0 0 3 5 5 3 4 0 4
1-205 320 5 5 5 5 5 5 5 4 3 0 0 0 3 5 4 2 2 0 4
1-206 320 5 5 1 5 5 5 5 2 0 0 0 0 1 5 4 2 2 0 4
1-207 320 5 5 5 5 5 5 5 3 1 0 0 0 2 5 5 2 2 0 4
1-208 320 5 5 5 5 5 5 5 3 0 0 0 0 1 5 5 2 5 0 4
1-209 320 5 5 5 5 5 5 5 4 3 0 0 0 2 5 5 3 1 0 4
1-210 320 5 5 5 5 5 5 5 2 1 0 0 4 4 5 5 2 5 0 5
1-211 320 1 1 2 2 5 5 5 0 0 0 1 0 3 4 0 0 0 3 4
1-212 320 5 5 5 5 5 5 5 0 0 0 0 0 4 5 5 1 5 0 4
1-213 320 5 5 5 5 5 5 5 0 0 0 3 5 5 0 5 3 4
1-214 320 4 5 3 5 5 5 5 0 0 0 0 0 0 5 2 1 3 0 2
1-215 320 5 4 5 5 5 5 5 1 0 0 0 0 1 5 3 2 1 0 4
1-216 320 5 5 5 5 5 5 5 1 0 0 0 0 1 5 3 2 4 0 4
1-217 320 5 5 5 5 5 5 5 4 0 0 0 1 5 4 2 3 0 3
1-218 320 5 5 5 5 5 5 5 2 0 0 0 0 2 5 3 3 4 0 4
1-219 320 5 5 5 5 5 5 5 4 1 0 0 0 1 5 4 3 4 0 4
1-220 320 0 0 5 5 5 5 0 0 0 0 0 0 2 4 1 0 0 5
1-221 320 5 5 5 5 5 5 5 0 0 0 1 0 4 5 5 0 5 0 4
1-222 320 4 0 3 5 5 5 3 1 0 3 4 1 3 1 3 1 0 2 5
1-223 320 5 5 5 5 5 5 5 3 2 0 4 5 5 0 5 0 4
1-224 320 5 5 5 5 5 5 5 0 0 0 1 0 3 5 3 0 5 2 4
1-225 320 5 4 1 5 5 5 5 0 0 0 0 0 0 5 2 0 2 0 4
1-226 320 5 5 5 5 5 5 5 4 1 0 0 0 3 5 5 3 5 1 4
1-227 320 5 5 5 5 5 5 5 4 0 0 0 0 2 5 5 3 5 0 4
1-228 320 5 5 5 5 5 5 5 3 0 1 3 0 3 5 5 3 5 3 4
1-229 320 5 5 5 5 5 5 5 2 0 0 0 0 3 5 4 2 5 0 4
1-230 320 5 5 5 5 5 5 5 1 0 0 3 0 3 5 4 2 3 0 5
1-231 320 5 5 5 5 5 5 5 3 0 0 0 0 4 5 4 3 4 0 4
1-232 320 5 1 2 5 5 5 5 2 0 0 0 0 0 4 3 1 0 0 4
1-233 320 5 5 5 5 5 5 5 3 0 0 0 0 1 5 2 2 4 0 4
1-234 320 5 3 3 5 5 5 5 2 0 0 0 0 0 5 4 2 0 0 5
1-235 320 5 5 5 5 5 5 5 2 1 0 0 0 2 5 3 3 0 0 5
1-236 320 4 3 2 3 4 5 5 1 0 0 0 0 0 4 1 0 0 0 5
1-237 320 4 4 1 2 5 5 4 0 0 0 0 0 0 5 2 0 0 0 4
1-238 320 5 5 5 5 5 5 5 4 3 3 3 4 3 5 5 3 5 4 5
1-239 320 5 5 5 5 5 5 5 3 0 0 0 4 5 5 3 5 0 5
1-240 320 5 5 5 5 5 5 5 4 1 0 0 0 2 5 5 3 5 4 5
1-241 320 5 5 5 5 5 5 5 4 0 0 0 0 1 5 5 3 5 1 5
1-242 320 5 3 2 5 5 5 5 0 0 0 0 0 4 3 1 2 0 5
1-243 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 5 0 4
1-244 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 3 5 0 5
1-245 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 5 0 5
1-246 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 3 5 0 5
1-247 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 4 4 5 0 5
1-248 320 5 5 5 5 5 5 5 4 0 0 0 5 5 3 1 0 4
1-249 320 5 3 4 5 5 5 4 3 0 0 0 0 0 5 4 3 1 0 5
1-250 320 4 4 4 4 5 5 5 3 0 0 0 0 0 5 4 2 2 0 4
1-251 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 4 4 2 0 4
1-252 320 5 5 5 5 5 5 5 3 0 0 0 0 5 5 3 5 0 4
1-253 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 3 0 5
1-254 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 3 5 3 5
1-255 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 4 3 5
1-256 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 4 5 3 5
1-257 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 4 4 4 1 5
1-258 320 5 5 5 5 5 5 5 4 0 0 0 5 5 3 5 1 5
1-259 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 3 5 4
1-260 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 4 3 4
1-261 320 5 5 5 5 5 5 5 4 0 0 5 5 4 5 3 5
1-262 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 4 2 5
1-296 320 5 0 5 3 4 5 5 0 0 0 4 3 0 0 5
1-297 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 0 5
1-298 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 5 0 5
1-299 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 4 5 0 5
1-300 320 5 5 5 5 5 5 5 3 0 0 0 0 0 5 5 4 5 3 4
1-301 320 5 5 5 5 5 5 5 0 0 0 5 5 3 5 1 4
1-302 320 5 5 5 5 5 5 5 2 0 0 0 5 5 3 5 3 5
1-303 320 5 5 5 5 5 5 5 3 0 0 0 5 5 3 4 0 4
1-304 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 0 4
1-305 320 5 5 5 5 5 5 5 4 0 0 0 0 0 5 5 3 5 4 4
1-306 320 5 5 5 5 5 5 5 1 0 1 5 5 4 5 1 5
1-307 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 0 5
1-308 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 2 5
1-309 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 2 5
1-310 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 0 3 0 3
1-311 320 5 5 5 5 5 5 5 3 0 0 0 5 5 3 5 3 4
1-312 320 5 5 5 5 5 5 5 2 0 0 0 5 5 3 5 5 5
1-313 320 5 5 1 1 4 5 1 0 0 0 0 3 1 0 0 0 2
1-314 320 5 5 4 1 4 5 0 0 0 0 0 0 3 1 0 0 0 1
2-001 102 5 4 5 4 5 5 4 1 2 3 3 3 2 4 3 0 0 1 4
2-002 320 4 4 3 1 4 5 2 0 0 3 2 2 1 4 0 0 0 0 3
2-003 320 4 5 5 5 5 5 4 1 0 0 0 0 3 5 3 0 0 0 3
2-005 269 3 4 5 3 5 5 3 0 0 0 0 0 0 5 3 0 0 2 4
2-006 320 3 3 4 3 4 5 3 0 0 0 0 0 0 4 0 0 0 0 0
2-007 320 1 0 1 0 4 4 3 0 0 0 2 0 3 1 0 0 0 1
2-008 320 2 3 3 0 3 4 0 0 1 0 0 0 4 1 1 0 0 3
2-009 320 0 0 3 0 1 1 0 0 0 0 0 0 0 4 0 0 0 0 0
2-010 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
2-011 320 0 0 2 0 1 2 0 0 0 0 0 0 0 3 0 0 0 0 0
2-012 320 0 0 1 0 1 3 0 0 0 0 0 0 0 4 0 0 0 0 0
2-013 320 4 5 5 3 5 5 4 0 0 1 1 1 2 5 4 0 0 0 4
2-014 320 3 5 5 4 5 5 4 3 0 0 0 0 3 5 3 0 0 0 4
2-015 320 5 5 5 4 5 5 3 1 0 0 0 0 0 5 4 1 0 0 4
2-016 320 5 5 5 4 5 5 4 4 3 0 0 0 0 5 4 3 0 0 4
2-017 320 5 5 5 4 4 5 3 1 0 0 0 5 2 0 0 0 4
2-018 320 1 1 1 0 1 4 1 0 0 0 0 2 0 0 0 0 0
2-020 320 3 5 4 0 4 5 0 0 0 0 0 0 4 1 0 0 0 0
2-021 320 4 4 4 3 5 5 0 0 0 0 0 0 0 4 3 0 0 0 3
2-022 320 0 0 1 0 3 5 2 0 0 0 0 0 5 3 0 0 0 1
2-023 320 0 0 1 0 0 1 0 0 0 0 0 0 3 0 0 0 0 0
2-024 320 4 5 5 2 4 5 2 0 0 0 0 2 5 3 0 0 0 3
2-025 320 4 5 4 0 4 5 3 0 0 0 0 0 0 4 1 0 0 0 3
2-026 320 4 5 4 4 4 5 3 0 0 0 0 0 0 5 2 0 0 0 3
2-027 320 0 5 3 1 2 4 0 0 0 0 0 0 4 1 0 0 0 1
2-028 320 2 5 5 0 4 5 1 0 0 0 0 0 0 5 4 0 0 0 3
2-029 320 0 0 0 2 0 1 0 0 0 0 0 0 0 2 0 0 0 0 0
2-030 320 4 5 4 1 3 5 2 0 0 0 0 0 1 5 2 0 0 0 3
2-031 320 5 5 5 5 5 5 4 0 0 0 0 0 4 5 5 0 0 0 4
2-032 320 2 5 5 3 4 5 5 0 0 0 0 0 0 5 1 0 1 0 4
2-034 320 5 4 4 0 4 5 1 0 0 0 0 0 4 1 0 0 0 2
2-035 320 5 5 4 5 5 5 5 0 0 0 0 0 5 5 0 2 0 2
3-001 320 4 3 4 2 3 4 3 0 0 0 0 0 4 2 0 0 0 0
3-002 320 0 2 1 0 0 1 0 0 0 0 0 0 0 3 0 0 0 0 0
4-001 320 3 1 2 4 5 5 2 0 0 0 0 4 1 0 0 0
5-001 320 4 3 3 4 5 5 4 0 0 0 0 0 4 2 0 0 0
5-002 320 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
6-001 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 5 0 2
6-002 320 5 5 5 5 5 5 5 1 0 0 0 0 5 5 0 0 0 0
6-003 320 5 5 5 5 5 5 5 3 0 1 2 3 0 5 5 3 0 0 4
6-004 320 5 5 5 4 5 5 5 3 2 3 3 3 5 4 1 0 4
6-005 320 5 5 5 5 5 5 5 5 4 3 3 5 5 4 4 0 0
6-006 320 3 3 4 1 5 4 3 0 0 0 0 4 1 0 5 4
6-007 320 5 5 5 3 5 5 4 1 0 0 0 5 5 2 5 0
6-008 320 0 5 5 0 5 3 3 0 0 0 0 0 3 3 1 4 0 0
6-009 320 5 5 5 4 5 5 5 3 0 2 0 5 5 3 5 2 4
6-010 320 5 5 5 3 5 4 5 0 0 3 0 0 5 4 3 4 0 0
6-015 320 5 5 5 4 5 5 5 2 2 4 3 2 5 5 3 0 0 4
6-016 320 5 5 5 4 4 5 5 0 0 3 0 3 5 5 0 0 0 1
6-017 320 5 5 5 5 5 5 5 0 0 4 1 0 3 5 5 0 1 0 3
6-018 320 5 5 5 4 5 5 5 0 0 3 3 4 5 5 3 2 1 3
6-023 320 5 5 5 5 5 5 4 0 0 0 0 1 5 3 0 3 3
6-024 320 0 3 1 1 3 5 1 0 0 0 0 0 0 0 0 0 0 0 3
6-025 320 4 5 5 5 5 5 5 0 0 0 0 0 0 5 4 0 1 0 3
6-026 320 5 5 5 5 5 5 3 0 0 0 0 0 1 5 5 0 3 0 3
6-027 320 3 4 4 1 0 0 0 0 0 0 0 0 0 1 1 0 0 0 0
6-029 320 5 5 5 5 5 5 5 4 5 4 3 5 4 5 5 0 5 0 4
6-030 320 4 4 1 0 1 1 0 0 0 0 0 0 0 1 0 0 0 0 3
6-031 320 5 5 5 5 5 5 4 2 0 3 0 1 5 4 0 0 0 3
6-032 320 4 3 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0
6-033 320 0 0 1 3 0 5 0 0 0 0 0 0 3 3 0 0 0 1
6-034 320 5 5 5 5 5 4 5 3 3 3 3 5 3 5 5 0 0 0 4
6-035 320 5 5 5 5 5 5 5 4 5 3 3 4 4 5 5 2 4 0 4
6-036 320 4 4 5 3 3 5 3 0 0 0 1 0 3 4 4 0 0 0 3
6-037 320 5 5 5 5 5 5 5 5 5 3 4 3 5 5 4 5 3 5
6-038 320 5 5 5 5 5 5 5 5 5 3 4 0 3 5 5 4 3 0 5
6-049 320 5 5 5 0 5 5 5 3 4 5 5 5 5 5 5 2 5 4 5
6-050 320 4 2 4 3 5 5 4 0 0 3 3 3 3 5 4 0 0 2 5
6-051 320 5 5 5 4 5 5 5 1 3 5 4 4 4 5 5 1 4 3 5
6-052 320 5 5 5 2 4 5 4 0 0 0 0 0 0 5 3 0 0 0 3
6-053 320 5 5 5 3 3 5 4 0 0 0 0 0 0 3 2 0 0 0 3
6-054 320 4 5 5 3 5 4 5 0 0 4 0 0 0 3 4 0 0 0 1
6-055 320 5 5 5 5 5 5 5 1 0 3 4 3 4 5 5 3 3 0 5
6-056 320 5 5 4 3 3 4 3 0 0 3 0 0 2 1 0 0 0 3
6-057 320 5 5 5 5 5 5 5 1 1 4 4 3 4 5 5 3 5 0 5
6-058 320 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 2 5 5 5
6-059 320 5 5 5 5 5 5 5 5 5 5 4 4 5 5 5 0 5 0 5
6-060 320 5 4 5 5 5 5 5 5 4 4 4 4 4 5 5 1 4 2 5
6-061 320 5 5 5 5 5 5 5 4 1 4 3 3 4 5 5 3 5 3 4
6-062 320 5 5 5 5 5 4 5 3 1 3 5 5 5 5 0 5 0 4
6-063 320 5 5 5 5 3 5 5 2 0 0 3 0 3 5 0 4 0 4
6-064 320 5 5 5 5 3 5 5 4 0 4 5 5 0 5 0 3
6-065 320 5 5 5 5 5 5 5 2 0 1 3 3 3 5 5 1 5 3 4
6-066 320 5 5 5 5 5 5 5 3 3 4 3 4 4 5 5 3 5 0 4
6-068 320 0 3 3 0 0 0 0 0 0 0 2 0 0 1 4 0 0 0 2
6-071 320 0 0 0 0 3 4 2 0 0 0 0 0 0 1 0 0 2 0 0
6-072 320 0 4 1 3 0 2 0 0 0 0 0 0 0 2 3 0 0 0 0
6-073 320 5 5 5 5 5 5 3 0 0 3 2 3 3 5 4 0 3 0 4
6-074 320 0 4 3 1 0 2 0 0 0 0 0 0 0 2 0 0 0 0 0
6-075 320 1 0 2 5 5 5 5 0 0 0 0 0 0 4 4 0 2 0 3
6-076 320 5 5 5 5 5 5 5 5 1 2 2 3 2 5 5 1 5 0 4
6-077 320 5 5 5 5 5 5 5 5 1 4 4 4 4 5 5 2 5 4 5
6-078 320 5 5 5 5 5 4 5 4 0 1 3 3 5 0 5 0 4
6-079 320 5 5 5 5 5 5 5 4 0 3 3 4 3 5 5 1 5 0 4
6-080 320 5 5 5 5 5 5 5 4 0 0 0 4 4 5 5 1 5 0 3
6-081 320 4 0 4 5 3 4 5 0 0 0 0 0 0 0 5 0 3 0 3
6-082 320 5 5 5 5 5 5 5 4 1 1 4 4 5 5 0 5 0 4
6-083 320 5 5 5 5 5 4 5 5 3 5 1 4 5 5 0 4 3 4
6-084 320 5 5 5 5 5 5 5 3 3 4 3 3 4 5 0 5 4 0 4
6-085 320 5 5 5 5 5 5 5 4 3 5 3 4 4 5 3 5 5 4 5
6-086 320 5 5 5 5 5 5 5 3 0 5 4 5 5 3 5 5 3 4
6-087 320 5 5 5 0 4 4 3 0 0 0 1 4 1 0 3 1 0 4
6-088 320 5 5 5 5 5 5 5 3 0 5 4 4 5 5 2 5 4 0 4
6-089 320 5 5 4 5 4 4 3 4 4 0 4
6-090 320 5 5 4 4 3 4 2 0 0 0 0 0 0 1 2 0 0 0 4
6-091 320 5 5 5 5 5 5 5 4 2 3 4 3 4 5 5 4 5 3 5
6-092 320 5 5 4 5 5 5 3 0 0 5 3 4 4 4 2 1 0 0 4
6-093 320 5 5 5 5 5 5 5 3 3 5 4 5 5 4 5 2 5 3 4
6-094 320 5 5 5 5 5 5 5 4 0 5 3 5 4 5 5 4 4 4
6-095 320 5 5 5 5 5 5 5 4 0 5 1 0 3 5 5 3 4 0 4
6-096 320 5 4 5 3 1 1 0 3 3 0 4
6-098 320 3 3 2 1 3 5 4 0 0 0 0 0 0 2 1 0 2 0 0
6-099 320 5 5 5 5 5 5 5 3 4 5 4 5 5 5 5 4 5 4 5
6-100 320 5 5 5 5 5 5 5 3 4 4 3 4 3 5 5 3 5 0 5
6-103 320 5 5 5 5 5 5 5 2 0 0 1 0 2 5 5 0 5 0 4
6-104 320 5 5 5 5 5 5 5 5 5 4 4 4 4 5 5 3 5 4 4
6-105 320 5 5 5 2 2 4 2 0 0 0 0 3 3 3 3 0 0 0 4
6-106 320 5 5 5 3 5 5 5 0 0 0 3 3 3 3 5 1 3 0 5
6-107 320 5 5 5 5 5 5 5 3 2 4 2 5 4 5 5 1 5 2 4
6-108 320 5 5 5 5 5 5 5 5 5 2 3 3 2 5 5 3 3 0 5
6-109 320 5 5 5 5 5 5 5 4 4 0 0 0 1 5 5 2 4 0 4
6-110 320 5 5 5 5 5 5 5 4 0 0 1 3 2 5 5 2 4 0 4
6-111 320 5 5 5 5 5 5 5 2 2 0 1 0 2 5 5 1 4 0 4
6-112 320 5 5 5 5 5 5 5 4 1 0 1 0 1 5 5 3 4 0 4
6-113 320 5 5 5 5 5 5 5 0 0 2 0 0 0 5 5 0 5 0 4
6-114 320 5 5 5 5 5 5 5 3 0 3 3 3 3 5 5 2 5 0 4
6-115 320 5 2 5 5 5 5 5 0 0 0 0 0 0 5 5 2 5 0 4
6-116 320 0 0 0 0 0 3 0 0 0 0 0 0 0 2 0 0 0 0 0
6-117 320 5 5 5 5 5 5 5 5 4 3 3 2 3 5 5 5 5 3 5
6-118 320 5 5 5 5 5 5 5 5 2 2 3 2 3 5 5 4 5 3 4
6-119 320 5 5 5 5 5 5 5 5 4 2 2 3 3 5 5 5 5 5 5
6-120 320 5 5 5 5 5 5 5 5 2 2 3 3 4 5 5 5 5 0 5
6-121 320 5 5 5 5 5 5 5 5 2 3 3 3 4 5 5 5 5 3 5
6-122 320 5 5 5 5 5 5 5 5 3 2 4 4 5 5 5 5 3 5
6-123 320 5 5 5 3 5 5 5 4 0 4 3 0 3 5 3 3 5 5
6-124 320 5 5 5 5 5 5 5 5 3 3 4 3 4 5 5 5 5 3 5
6-125 320 0 0 0 0 3 3 3 0 0 0 0 0 0 0 0 0 2 0 0
6-126 320 5 5 5 5 5 5 5 5 3 3 4 3 5 5 5 5 3 5
6-127 320 4 5 5 5 5 5 5 0 0 0 0 0 0 5 3 0 3 0 4
6-128 320 5 5 5 5 5 5 5 5 0 3 4 5 5 5 2 5 0 5
6-129 320 5 5 5 5 5 5 5 5 0 3 4 5 4 5 5 3 5 2 5
6-130 320 5 5 5 5 5 5 5 5 2 3 3 3 4 5 5 4 5 2 5
6-131 320 5 5 5 5 5 5 5 5 0 3 3 3 4 5 5 4 5 0 5
6-132 320 5 5 5 5 5 5 5 3 0 3 3 2 3 5 5 3 5 0 4
6-133 320 5 5 5 5 5 5 5 3 0 0 0 0 5 5 0 5 0 4
6-134 320 5 5 5 5 5 5 5 4 0 2 0 0 3 5 5 1 5 0 4
6-135 320 5 5 5 4 5 5 5 4 0 3 0 0 3 5 5 3 5 0 4
6-136 320 5 5 5 5 5 5 5 5 1 1 1 4 4 5 5 4 5 0 5
6-137 320 5 5 5 5 5 5 5 3 0 0 0 0 3 5 5 2 5 0 4
6-138 320 5 0 5 5 5 5 5 1 0 3 0 0 2 5 2 3 0 0 3
6-139 320 5 1 5 5 5 5 5 2 0 0 0 0 0 5 5 2 0 0 4
6-140 320 5 0 5 5 5 5 5 4 0 0 0 0 0 5 4 1 2 0 4
6-141 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 0 5 0 3
6-142 320 1 5 5 5 5 5 5 0 0 0 0 0 5 5 0 0 0 2
6-143 320 1 0 5 5 5 5 5 0 0 0 0 0 5 3 0 1 0 0
6-144 320 4 5 5 5 5 5 5 0 0 0 0 0 5 5 0 1 0 0
6-145 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 1 0 0
6-146 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 3 0 3
6-147 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 5 0 3
6-148 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 2 0 3
6-149 320 5 5 5 5 5 5 5 3 1 0 0 4 5 4 0 5 0 3
6-150 320 5 5 5 5 5 5 5 3 1 0 1 4 5 5 2 4 0 4
6-151 320 5 5 5 5 5 5 5 2 0 0 0 5 4 5 0 3 0 3
6-152 320 5 5 5 5 5 5 5 0 0 0 0 0 5 5 0 4 0 4
6-153 320 5 5 5 5 5 5 5 5 3 3 5 3 5 5 4 5 3 5
6-154 320 5 5 5 5 5 5 5 3 0 1 3 5 3 5 0 4
6-155 320 5 5 5 5 5 5 5 5 1 1 2 5 5 4 5 2 4
6-156 320 5 5 5 5 5 5 5 5 3 2 3 0 3 5 5 5 5 3 5
6-157 320 5 5 5 5 5 5 5 5 4 1 4 0 4 5 5 5 5 3 5
6-158 320 5 5 5 5 5 5 5 5 4 2 3 3 5 5 5 5 3 4
6-159 320 0 0 0 5 5 5 5 5 4 3 4 4 3 0 0 4 5 3 4
6-160 320 5 5 5 5 5 5 5 5 3 2 4 4 5 5 4 5 3 5
6-161 320 5 5 5 5 5 5 5 4 1 3 3 4 5 5 4 5 2 5
6-162 320 5 5 5 5 5 5 5 4 1 2 2 0 3 5 5 3 5 3 4
6-163 320 5 5 5 5 5 5 5 4 1 0 1 0 4 5 5 4 5 3 5
6-164 320 5 5 5 5 5 5 5 4 2 0 4 5 5 4 5 3 4
6-165 320 5 5 5 5 5 5 5 5 3 3 4 5 5 4 5 3 4
6-166 320 5 5 5 5 5 5 5 4 4 2 3 5 5 5 4 5 3 4
6-167 320 5 5 5 5 5 5 5 5 2 1 0 5 5 5 4 5 3 5
6-168 320 5 5 5 5 5 5 5 5 2 1 3 0 3 5 5 4 5 3 4
6-169 320 5 5 5 5 5 5 5 5 4 3 3 3 4 5 5 4 5 4 4
6-170 320 5 5 5 5 5 5 5 5 0 0 3 5 5 4 5 3 4
6-171 320 5 5 5 5 5 5 5 5 4 0 0 1 4 5 5 4 5 3 5
6-172 320 5 5 5 5 5 5 5 4 5 0 0 3 3 5 5 3 5 3 4
6-173 320 5 5 5 5 5 5 5 5 0 0 0 3 5 5 4 5 1 4
6-174 320 5 5 5 5 5 5 5 4 1 0 0 0 3 5 5 4 5 0 4
6-175 320 5 5 5 5 5 5 5 4 0 1 1 0 3 5 5 4 5 0 4
6-176 320 5 5 5 5 5 5 5 4 1 0 0 0 1 5 5 4 5 0 4
6-177 320 5 5 5 5 5 5 5 4 1 0 0 0 0 5 5 4 5 4 5
6-178 320 5 5 5 5 5 5 5 4 3 2 5 3 1 5 5 4 5 4 5
6-179 320 5 5 5 5 5 5 5 4 3 0 3 0 1 5 5 4 5 4 5
6-180 320 5 5 5 5 5 5 5 4 1 4 5 4 5 5 4 5 5 5
6-181 320 5 5 5 5 5 5 5 5 2 0 0 1 3 5 5 4 5 2 5
6-182 320 5 5 5 5 5 5 5 4 2 3 3 3 3 5 5 3 5 3 5
6-183 320 5 5 5 5 5 5 5 5 0 5 5 4 5 4
6-184 320 5 5 5 5 5 5 5 5 0 5 5 4 5 5
6-185 320 5 5 5 5 5 5 5 5 0 5 5 5 5 4
6-186 320 5 5 5 5 5 5 5 5 0 0 5 5 3 5 5
6-187 320 5 5 5 5 5 5 5 4 0 0 5 5 3 5 0 4
6-188 320 5 5 5 5 5 5 5 4 0 0 0 5 5 3 5 0 4
6-189 320 5 5 5 5 5 5 5 4 0 3 0 0 5 5 3 5 0 4
6-190 320 5 5 5 5 5 5 5 4 0 0 0 5 5 3 5 4
6-191 320 5 5 5 5 5 5 5 4 0 0 0 5 5 3 5 5
6-192 320 5 5 5 5 5 5 5 5 0 0 0 5 5 4 5 2 5
6-193 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 3 5 0 4
6-194 320 1 2 1 0 0 0 0 0 0 0 0 0 1 0 0 0 0 3
6-195 320 5 5 5 5 5 5 5 3 0 0 0 0 5 0 0 2 0 5
6-196 320 5 5 5 5 5 5 5 4 1 0 0 5 5 4 4 3 5
6-197 320 5 5 5 5 5 5 5 4 0 0 0 0 5 5 2 5 0 5
6-198 320 5 5 5 5 5 5 5 4 1 0 0 0 5 5 4 4 0 5
6-199 320 5 5 5 5 5 5 5 4 1 0 0 0 5 4 3 3 0 4
6-200 320 5 5 5 5 5 5 5 4 0 0 0 5 5 4 5 4 4
6-201 320 1 2 2 0 4 2 0 0 0 0 5 1 0 0 0 3
6-202 320 5 5 5 5 5 5 5 2 0 0 0 5 5 3 5 0 4
6-203 320 5 3 5 5 5 5 5 4 0 0 0 5 4 1 2 5
6-204 320 5 3 5 5 5 5 3 4 0 0 0 5 5 3 0 3 5
6-205 320 5 5 5 5 5 5 5 4 0 0 0 0 5 3 3 5 0 5
6-206 320 5 1 5 4 5 5 1 4 0 0 0 5 5 3 0 0 4
6-207 320 5 5 5 5 5 5 5 5 1 1 5 5 4 5 4 5
6-208 320 5 5 5 5 5 5 5 5 0 5 5 4 5 4 5
6-209 320 5 5 5 5 5 5 5 4 3 0 0 5 5 3 5 4 5
6-210 320 5 5 5 5 5 5 5 3 1 2 5 5 3 1 0 5
6-211 320 5 5 5 5 5 5 5 5 2 0 5 5 4 4 5 5
6-212 320 5 5 5 5 5 5 5 4 2 0 5 3 3 5 0 5
6-213 320 5 5 5 5 5 5 5 4 1 0 0 5 5 3 4 0 5
6-214 320 5 5 5 5 5 5 5 4 0 0 5 5 3 5 0 5
6-215 320 5 5 5 5 5 5 5 5 1 0 5 4 3 5 2 5
6-216 320 5 4 5 4 5 5 5 3 0 0 0 0 5 5 3 0 0 4
6-217 320 5 5 5 2 5 5 5 3 0 0 0 0 5 1 2 0 0 5
6-218 320 5 5 5 5 5 5 5 5 3 0 0 5 5 3 5 0 5
6-219 320 5 5 5 4 5 5 4 2 0 0 0 5 3 2 0 0 5
6-220 320 5 5 5 5 5 5 5 2 0 0 0 5 5 4 3 0 5
6-221 320 5 5 5 5 5 5 5 4 2 0 0 5 5 3 1 2 5
6-222 320 5 5 5 5 5 5 5 2 0 0 0 5 5 4 3 0 5
6-223 320 5 5 5 5 5 5 5 4 0 0 0 5 5 4 1 0 5
6-224 320 5 5 5 5 5 5 5 2 1 0 5 5 4 5 3 5
6-225 320 5 5 5 5 5 5 5 4 2 1 3 5 5 4 5 3 5
6-226 320 5 5 5 5 5 5 5 4 1 0 5 5 4 5 4 5
6-227 320 5 5 5 5 5 5 5 2 0 0 5 5 4 5 3 5
6-228 320 5 5 5 5 5 5 5 2 1 5 5 4 4 3 5
6-229 320 5 5 5 5 5 5 5 1 0 0 5 5 4 1 1 5
6-230 320 5 5 5 5 5 5 5 2 0 0 5 5 4 5 3 5
6-231 320 5 5 5 5 5 5 5 2 0 5 5 4 5 4 5
6-232 320 5 5 5 5 5 5 5 4 0 0 3 5 5 4 5 3 5
6-233 320 5 5 5 5 5 5 5 5 3 1 0 4 5 5 4 5 3 5
6-234 320 5 5 5 5 5 5 5 5 4 1 0 5 5 4 5 3 5
6-235 320 5 5 5 5 5 5 5 5 5 3 5 5 4 5 4 5
6-237 320 5 1 2 2 3 5 5 2 0 0 0 0 5 1 2 0 0 3
6-239 320 5 5 5 5 5 5 5 5 4 3 3 4 5 5 5 5 3 4
6-240 320 5 5 5 5 5 5 5 5 5 0 3 3 5 5 5 5 3 4
6-241 320 5 5 5 5 5 5 5 5 5 3 3 4 5 5 5 5 4 4
6-242 320 5 5 5 5 5 5 5 5 5 1 3 3 5 5 5 5 4 4
6-243 320 5 5 5 5 5 5 5 5 4 2 4 4 5 5 5 5 4 4
6-244 320 5 5 5 5 5 5 5 4 1 0 0 3 5 5 4 4 0 4
6-245 320 5 5 5 5 5 5 5 5 3 3 3 3 5 5 4 3 0 4
6-246 320 5 5 5 5 5 5 5 5 1 1 0 2 5 5 4 5 0 4
6-247 320 5 5 5 5 5 5 5 5 4 3 4 3 5 5 4 4 1 4
6-248 320 5 5 5 5 5 5 5 4 2 2 0 1 5 4 3 2 1 4
6-249 320 5 5 5 5 5 5 5 5 3 1 1 2 5 5 4 5 5 5
6-250 320 5 5 5 5 5 5 5 5 3 0 0 2 5 5 4 5 5 5
6-251 320 5 5 5 5 5 5 5 5 4 1 3 4 5 5 4 5 4 4
6-252 320 5 5 5 5 5 5 5 5 4 1 4 4 5 5 5 5 5 5
6-253 320 5 5 5 5 5 5 5 5 4 3 4 3 5 4 4 5 3 4
6-254 320 5 5 5 5 5 5 5 5 0 0 2 2 5 4 4 5 4 5
6-255 320 5 5 5 5 5 5 5 5 0 0 2 1 5 4 4 4 1 4
6-256 320 5 5 5 5 5 5 5 5 2 0 1 1 5 4 4 4 1 4
6-257 320 5 5 5 5 5 5 5 2 0 0 0 0 5 3 1 1 0 4
6-258 320 0 0 1 3 4 5 3 0 0 0 0 0 3 0 0 0 0 4
6-259 320 4 5 5 3 5 5 5 0 0 0 1 5 3 1 0 0 4
6-260 320 5 5 5 5 5 5 5 5 4 3 3 3 5 5 5 5 4 5
6-261 320 5 5 5 5 5 5 5 5 4 3 4 4 5 5 5 5 4 5
6-262 320 5 5 5 5 5 5 5 5 4 3 3 4 5 5 4 5 4 4
6-263 320 5 5 5 5 5 5 5 5 5 4 4 4 5 5 5 5 4 5
6-264 320 5 5 5 5 5 5 5 5 5 3 4 4 5 5 4 5 4 5
6-265 320 0 0 0 0 0 1 5 0 0 0 0 0 3 0 0 0 0 3
6-266 320 3 5 5 4 5 5 4 0 0 0 0 0 0 5 5 0 3 0 4
6-267 320 5 5 5 5 5 5 5 5 4 0 3 0 5 5 4 4 2 5
7-001 320 5 3 4 3 3 5 3 0 0 0 1 2 0 0 0 0
7-002 320 5 3 5 4 4 5 3 0 0 0 0 0 0 5 3 0 0 0 0
7-003 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 2 0 0 0
7-004 320 5 4 5 2 5 5 5 0 0 2 0 0 5 5 4 0 0 3
7-005 320 5 4 5 2 2 5 4 0 0 3 1 0 0 4 4 0 0 0 0
7-006 320 5 5 5 3 3 5 4 0 0 3 0 0 0 5 4 0 0 0 3
7-007 320 5 5 5 4 5 5 5 0 0 2 0 0 5 5 0 2 0 0
7-008 320 5 5 5 5 5 5 5 1 0 2 1 3 5 5 0 4 0 3
7-010 320 5 5 5 4 5 5 5 3 1 2 0 0 4 5 5 3 5 0 4
7-011 320 4 3 5 3 4 5 3 4 5 3 3 0 1 5 2 0 0 0 4
7-012 320 5 5 5 1 3 5 0 0 0 3 3 2 5 3 2 1 0 3
7-013 320 4 2 1 1 3 3 0 0 5 0 0 0 1 0 0 0 0 1
7-014 320 5 0 5 1 0 5 0 0 0 0 0 0 3 3 0 0 0 1
7-015 320 5 5 5 5 5 5 5 2 0 3 1 4 5 5 0 5 0 5
7-016 320 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-017 320 5 5 5 0 2 3 3 0 0 0 0 0 5 0 0 0 0 0
7-018 320 5 4 4 0 0 2 2 0 0 0 0 0 0 2 1 0 0 0 0
7-019 320 3 3 4 0 2 3 3 0 0 0 0 0 1 2 0 0 0 2
7-020 320 5 3 4 0 4 4 3 0 0 0 0 0 0 3 0 0 0 0 2
7-022 320 0 0 1 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0
7-024 320 0 0 5 2 2 3 1 0 0 0 0 0 0 3 1 0 0 0 2
7-025 320 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
7-026 320 0 0 1 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0
7-027 320 5 5 5 5 4 5 5 0 0 0 0 0 0 3 5 0 0 0 2
7-029 320 3 3 5 3 0 0 0 0 2 0 1
7-031 320 4 5 5 3 3 5 5 0 0 0 0 0 0 4 1 0 0 0 0
7-032 320 5 5 5 4 5 5 5 0 0 0 0 0 0 4 5 0 0 0 0
7-033 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 5 0 0 0 3
7-034 320 2 1 4 4 4 5 4 0 0 0 0 0 0 0 0 0 0
7-035 320 5 5 5 5 5 5 5 0 0 0 3 5 3 0 0 0 4
7-036 320 5 5 5 5 5 5 5 0 0 0 5 5 0 1 3
7-037 320 5 5 5 4 5 5 5 0 0 0 0 0 5 1 0 1 0 0
7-042 320 0 4 4 3 3 5 1 0 0 0 0 0 0 0 1 0 0 0 4
8-001 320 1 1 1 0 0 1 0 0 0 0 0 0 2 0 0 0 0 0
8-002 320 0 0 3 3 4 5 3 0 0 0 0 0 4 0 0 0 0 1
8-003 320 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0
9-001 320 4 4 5 5 3 5 3 0 0 0 0 0 3 4 0 0 0 2
9-002 320 5 5 5 5 5 5 5 4 3 0 0 1 5 5 0 3 0 4
9-003 320 5 5 5 4 5 5 5 4 0 3 3 0 4 5 5 4 4 1 4
9-004 320 5 5 5 5 5 5 4 0 1 2 0 5 5 0 3 0 3
9-005 320 4 4 5 5 4 5 5 0 0 0 0 0 0 4 3 0 0 0 3
9-006 320 5 5 5 4 5 5 5 0 0 2 3 0 4 5 5 0 5 0 4
9-007 320 5 5 5 5 5 5 5 0 0 3 3 1 4 5 5 0 4 0 4
9-008 320 5 5 5 4 5 5 5 4 0 3 4 2 4 5 5 3 5 0 4
9-009 320 4 5 5 5 4 5 5 0 0 0 0 0 5 3 0 0 0 3
9-010 320 5 5 5 4 5 5 5 0 3 3 3 3 3 5 3 2 0 0 3
9-011 320 5 5 5 5 5 5 5 2 2 1 0 1 3 5 5 2 5 0 4
9-012 320 5 5 5 5 5 5 5 1 4 2 4 4 3 5 5 1 2 0 3
9-013 320 5 5 5 5 5 5 5 4 0 3 2 4 5 5 0 4 4 4
9-014 320 5 5 5 4 4 4 3 0 0 0 0 0 2 5 5 0 1 0 2
9-015 320 5 5 5 4 5 5 5 0 0 3 3 2 4 5 5 0 3 0 5
9-016 320 5 5 5 5 5 5 5 0 0 2 3 2 1 5 5 3 3 0 3
9-017 320 4 5 5 4 3 5 3 0 0 0 0 0 0 5 5 0 3 0 3
9-018 320 0 3 3 3 1 1 0 0 0 0 1 0 0 3 3 0 0 0 0
9-019 320 4 5 5 4 4 5 1 0 0 0 0 0 0 3 5 0 0 0 1
9-020 320 5 5 5 5 5 5 4 4 5 3 3 3 5 5 1 2 0 4
9-021 320 5 5 5 4 5 5 5 2 2 3 1 4 5 5 1 4 0 4
9-022 320 5 5 5 0 2 2 2 0 0 0 0 0 0 5 2 0 0 0 0
9-023 320 5 5 5 4 5 5 5 0 0 3 3 0 3 5 5 0 1 0 5
9-024 320 5 5 5 5 5 5 5 3 1 4 4 4 4 5 5 0 3 0 4
9-025 320 5 4 1 3 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0
9-026 320 5 4 0 3 0 0 0 0 0 0 0 0 0 0 5 0 0 0 0
9-027 320 5 5 5 5 5 5 5 0 0 2 3 3 2 5 5 0 4 0 4
9-028 320 5 5 5 4 5 5 5 1 4 2 3 4 4 5 5 1 4 3 4
9-029 320 3 3 3 5 4 5 4 0 0 0 0 0 0 3 4 0 4 0 4
9-030 320 3 0 1 2 0 3 0 0 0 0 0 0 0 1 0 0 0 0 3
9-034 320 0 3 0 0 3 3 0 0 0 0 0 0 1 1 0 0 0 0
9-039 320 0 1 3 0 2 5 1 0 0 0 0 0 1 0 0 2 0 3
9-040 320 0 0 0 2 1 5 4 0 0 0 0 0 0 0 0 0 0 4
9-041 320 5 5 5 0 1 2 1 0 0 0 0 0 2 2 0 2 0 3
9-042 320 0 3 1 0 4 1 1 0 0 0 0 0 2 0 0 4 0 3
9-043 320 0 1 3 0 0 1 0 0 0 0 0 0 2 2 0 0 0 0
9-044 320 0 0 0 0 3 3 1 0 0 0 0 0 0 0 0 0 0 0 0
9-045 320 0 0 0 5 3 5 2 0 0 0 0 0 3 0 0 0 4
10-001 320 3 2 4 1 1 3 0 0 0 0 0 0 0 2 1 0 0 0 0
10-002 320 5 5 5 5 4 5 4 0 0 0 0 0 4 5 0 0 0 0
10-003 320 3 5 5 3 3 4 3 0 0 0 0 0 0 4 2 0 0 0 0
10-004 320 5 5 5 5 5 5 5 3 0 0 0 3 5 5 0 4 0 4
11-002 320 4 4 5 5 5 5 5 0 0 0 0 0 0 5 2 1 2 0 4
12-002 320 5 5 5 5 5 5 5 1 0 2 4 4 4 5 5 1 2 3 5
13-001 320 5 5 5 5 5 5 5 1 0 0 0 0 0 5 5 0 5 0 4
13-002 320 5 5 5 5 5 5 5 2 0 5 3 4 4 5 5 2 5 3 4
13-003 320 5 5 5 5 5 5 5 4 0 0 1 3 1 5 5 3 5 0 4
13-004 320 5 5 5 5 5 5 5 1 0 4 2 4 3 5 5 1 5 0 4
13-005 320 5 5 5 5 5 5 5 0 0 0 0 0 0 5 4 0 5 0 3
13-006 320 5 5 5 5 5 5 5 4 3 2 3 2 5 5 2 5 3 4
13-007 320 5 5 5 5 5 5 4 1 0 0 0 5 3 1 1 0 2
13-008 320 3 0 5 5 5 5 5 1 0 0 0 5 0 0 0 0 4
13-009 320 5 5 5 5 5 5 5 4 0 3 3 1 5 5 3 5 3 4
13-010 320 5 5 5 5 5 5 5 3 0 2 3 5 5 3 5 1 4
13-011 320 5 5 5 5 5 5 5 4 0 0 1 0 5 5 4 5 0 4
13-012 320 5 5 5 5 5 5 5 3 0 0 1 0 5 5 2 3 0 4
13-013 320 4 5 5 5 5 5 5 3 0 0 1 0 5 3 1 3 1 4
13-014 320 0 0 2 1 3 5 3 4 1 0 0 1 3 0 1 0 0 4
13-015 320 5 5 5 5 5 5 5 5 4 3 4 5 5 3 5 3 4
13-016 320 5 5 5 3 5 5 5 5 5 3 4 4 5 4 3 5 4 4
13-017 320 5 5 5 5 5 5 5 5 5 0 4 4 5 5 1 5 3 4
13-018 320 5 5 5 5 5 5 5 5 4 1 3 4 4 5 5 2 5 3 4
13-019 320 3 5 5 5 5 5 5 0 0 0 0 3 5 5 0 3 0 4
13-020 320 0 4 5 4 5 5 5 0 0 1 0 4 0 4 4 0 0 0 3
13-021 320 3 5 5 5 5 5 5 0 0 0 4 5 5 0 3 0 4
13-022 320 3 5 5 5 5 5 5 0 0 1 3 0 4 5 5 1 3 0 4
13-023 320 4 5 5 5 5 5 5 0 0 3 3 0 4 5 5 1 4 0 4
13-024 320 0 4 4 5 5 5 5 0 0 2 2 0 0 5 5 0 0 0 3
14-001 320 5 5 5 5 5 5 5 4 0 0 0 0 2 5 5 2 4 0 4
14-002 320 5 5 5 5 5 5 5 4 0 0 0 0 0 4 5 1 3 0 4
14-003 320 5 5 5 5 5 5 5 4 0 0 2 0 5 5 0 3 0 5
14-004 320 0 5 5 4 5 5 5 3 0 0 0 0 5 5 5 0 0 0 4
14-006 320 1 4 3 1 0 4 3 0 0 0 0 2 0 0 0 0 4
15-001 320 5 5 5 5 5 5 5 5 2 3 3 4 5 5 4 5 0 5
15-002 320 5 5 5 5 5 5 5 4 1 0 0 0 4 5 5 4 5 0 4
15-003 320 5 5 5 5 5 5 5 4 0 2 2 0 3 5 5 4 5 0 4
15-004 320 5 5 5 5 5 5 5 4 0 4 4 3 4 5 5 4 5 0 4
15-005 320 5 5 5 5 5 5 5 3 0 0 3 4 5 5 2 5 0 4
15-006 320 5 5 5 5 5 5 5 3 0 0 0 0 3 5 5 3 5 0 3
15-007 320 5 5 5 5 5 5 5 1 0 0 0 0 3 5 5 1 5 0 3
15-009 320 5 5 5 5 5 5 5 4 1 0 0 0 3 5 5 3 5 0 4
15-010 320 0 1 5 5 5 5 5 0 0 0 0 0 0 4 1 0 0 0 0
15-011 320 5 5 5 5 5 5 5 1 0 0 0 0 0 5 1 0 3 0 3
15-012 320 5 5 5 5 5 5 5 0 0 0 0 0 0 1 0 0 5 0 0
15-013 320 5 5 5 5 5 5 5 5 1 2 1 1 3 5 5 5 5 0 5
15-014 320 5 5 5 5 5 5 5 4 0 3 2 4 4 5 5 3 5 0 4
15-015 320 5 5 5 5 5 5 5 3 0 0 1 2 3 5 5 1 4 0 5
15-016 320 5 5 5 5 5 5 5 1 0 0 0 0 5 1 0 3 0 2
15-017 320 5 5 5 5 5 5 5 0 0 0 0 0 5 1 0 4 0 4
15-018 320 5 5 5 5 4 5 5 0 0 0 0 0 5 2 0 0 0 4
15-019 320 5 5 5 5 5 5 5 2 0 0 0 5 3 1 3 0 3
15-020 320 5 5 5 5 5 5 5 0 0 0 0 5 5 0 3 0 3
15-021 320 5 5 5 5 5 5 5 1 0 0 0 5 5 0 3 0 0
15-022 320 5 5 5 5 5 5 5 2 0 0 0 0 5 5 0 5 0 3
15-023 320 5 5 5 5 5 5 5 5 3 2 2 4 5 5 4 5 4 4
15-024 320 5 5 5 5 5 5 5 3 3 0 0 0 5 5 3 5 0 4
15-025 320 5 5 5 5 5 5 5 4 3 0 0 1 5 4 4 5 1 4
15-026 320 5 5 5 5 5 5 5 1 0 0 0 0 5 3 2 5 0 4
15-027 320 5 5 5 5 5 5 5 3 0 0 0 1 5 2 0 5 0 4
15-028 320 5 5 5 5 5 5 5 5 2 0 0 4 5 5 4 5 1 4
15-029 320 5 5 5 5 5 5 5 4 4 3 2 4 5 5 4 5 4 5
15-030 320 5 5 5 5 5 5 5 4 4 2 1 3 5 5 4 5 1 4
15-031 320 5 5 5 5 5 5 5 4 0 0 1 4 5 5 4 5 1 4
15-032 320 5 5 5 5 5 5 5 4 0 0 1 3 5 5 4 5 0 4
15-033 320 5 5 5 5 5 5 5 4 0 0 0 4 5 5 3 5 1 4
15-034 320 5 5 5 5 5 5 5 4 0 1 1 4 5 5 3 5 1 4
16-001 320 0 0 0 0 2 2 0 0 0 0 0 0 1 0 0 3 0 1
17-001 320 5 5 5 5 5 5 5 3 0 1 1 3 5 3 5 1 5
17-002 320 5 5 5 5 5 5 5 4 0 3 2 4 5 5 3 5 2 5
――――――――――――――――――――――――――――

本発明のケトン若しくはオキシム化合物は新規な化合物であり、イネ用、トウモロコシ用、ダイズ用、麦用、ビート用及びナタネ用の選択性除草剤として有用である。   The ketone or oxime compound of the present invention is a novel compound and is useful as a selective herbicide for rice, corn, soybean, wheat, beet and rapeseed.

Claims (10)

式（１）：

［式中、Ｂは、Ｂ−１、Ｂ−２又はＢ−３のいずれかで示される環を表し、

Ｑは、酸素原子、硫黄原子又はＮＯＲ^７を表し、
Ａは、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−Ｓ（Ｏ）_ｒ２Ｒ^１、−Ｃ（Ｏ）ＯＲ^１、−Ｃ（Ｓ）ＯＲ^１、−Ｃ（Ｏ）ＳＲ^１、−Ｃ（Ｓ）ＳＲ^１、−Ｃ（Ｏ）Ｒ^２、−Ｃ（Ｓ）Ｒ^２、−Ｃ（Ｏ）Ｎ（Ｒ^４）Ｒ^３、−Ｃ（Ｓ）Ｎ（Ｒ^４）Ｒ^３、−Ｓ（Ｏ）_２Ｎ（Ｒ^４）Ｒ^３、−Ｐ（Ｏ）（ＯＲ^１）_２又は−Ｐ（Ｓ）（ＯＲ^１）_２を表し、
Ｒ^１は、Ｃ_１〜Ｃ_８アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、フェニル又は（Ｚ^２）_ｑ２で置換されたフェニルを表し、
Ｒ^２は、水素原子、Ｃ_１〜Ｃ_８アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−Ｃ（＝ＮＯＲ^３１）Ｒ^３２、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル、ナフチル、（Ｚ^２）_ｑ２で置換されたナフチル、Ｄ１−１〜Ｄ１−４２、Ｄ１−８１又はＤ１−８４を表し、
Ｒ^３及びＲ^４は、各々独立して水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル、Ｄ１−３２、Ｄ１−３３又はＤ１−３４を表すか、或いは、Ｒ^３はＲ^４と一緒になってＣ_２〜Ｃ_７のアルキレン鎖又はＣ_２〜Ｃ_７のアルケニレン鎖を形成することにより、Ｒ^３及びＲ^４が結合する窒素原子と共に３〜８員環を形成してもよく、このときこのアルキレン鎖又はアルケニレン鎖は酸素原子、硫黄原子又は窒素原子を１個含んでもよく、且つＣ_１〜Ｃ_６アルキル、オキソ又はチオキソによって任意に置換されてもよく、
Ｒ^５は、ハロゲン原子、シアノ、ニトロ、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＲ^３１、−Ｓ（Ｏ）_ｒ２Ｒ^３１、−Ｃ（Ｏ）ＯＲ^３１、−Ｃ（Ｏ）Ｒ^３２、−Ｎ（Ｒ^３４）Ｒ^３３、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル、Ｄ１−１、Ｄ１−１０、Ｄ１−３２、Ｄ１−３３又はＤ１−３４を表すか、或いは、２つのＲ^５が同一の炭素上に置換している場合、２つのＲ^５は一緒になってオキソ、チオキソ、イミノ、Ｃ_１〜Ｃ_６アルキルイミノ、Ｃ_１〜Ｃ_６アルコキシイミノ又はＣ_１〜Ｃ_６アルキリデンを形成してもよく、
Ｒ^６は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^１５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^１５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^１５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^１５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^１５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−Ｃ（＝ＮＯＲ^１６）Ｒ^１７、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル、Ｄ１−１０、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４、Ｄ１−３６、Ｄ１−３７、Ｄ１−３８又はＤ１−８１を表し、
Ｒ^７は、水素原子、Ｃ_１〜Ｃ_８アルキル、Ｒ^１５bで任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^１５ｂで任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^１５bで任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^１５ｂで任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^１５ｂで任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、フェニル又は（Ｚ^１）_ｑ１で置換されたフェニルを表し、
Ｒ^８ａ、Ｒ^８ｂ、Ｒ^９ａ及びＲ^９ｂは、各々独立して水素原子、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、−ＯＲ^１６ａ、−Ｓ（Ｏ）_ｒ１Ｒ^１６ａ、−Ｃ（Ｏ）ＯＲ^１６ａ、−Ｃ（Ｏ）Ｒ^１７ａ、−Ｃ（Ｏ）Ｎ（Ｒ^１９ａ）Ｒ^１８ａ、−Ｃ（＝ＮＯＲ^１６ａ）Ｒ^１７ａ、フェニル又は（Ｚ^１）_ｑ１で置換されたフェニルを表し、
Ｒ^１０、Ｒ^１１及びＲ^１２は、各々独立して水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^１５は、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＲ^１６、−Ｓ（Ｏ）_ｒ１Ｒ^１６、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３又はＤ１−３４を表し、
Ｒ^１５ｂは、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、ハロ（Ｃ_３〜Ｃ_８）シクロアルキル、−ＯＲ^１６ｂ、−Ｓ（Ｏ）_ｒ１Ｒ^１６ｂ、−Ｃ（Ｏ）ＯＲ^１６ｂ、−Ｃ（Ｏ）Ｎ（Ｒ^１８ｂ）Ｒ^１９ｂ、−Ｃ（＝ＮＯＲ^１６ｂ）Ｒ^１７ｂ、−Ｎ（Ｒ^１８ｂ）Ｒ^１９ｂ、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４、Ｄ１−３６、Ｄ１−３７、Ｄ１−３８、Ｄ１−８１又はＤ１−８４を表すか、或いは、２つのＲ^１５ｂが同一の炭素上に置換している場合、２つのＲ^１５ｂは一緒になってオキソ、チオキソ、イミノ、Ｃ_１〜Ｃ_６アルキルイミノ、Ｃ_１〜Ｃ_６アルコキシイミノ又はＣ_１〜Ｃ_６アルキリデンを形成してもよく、
Ｒ^１６、Ｒ^１６ａ、Ｒ^１６ｂ、Ｒ^１７、Ｒ^１７ａ、Ｒ^１７ｂ、Ｒ^１８ａ及びＲ^１９ａは、各々独立して水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^１８ｂ及びＲ^１９ｂは、各々独立して水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^２０で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｃ_１〜Ｃ_６アルコキシ又はフェニルを表すか、或いは、Ｒ^１８ｂはＲ^１９ｂと一緒になってＣ_２〜Ｃ_７のアルキレン鎖又はＣ_２〜Ｃ_７のアルケレン鎖を形成することにより、Ｒ^１８ｂ及びＲ^１９ｂが結合する窒素原子と共に３〜８員環を形成してもよく、このときこのアルキレン鎖又はアルケニレン鎖は酸素原子、硫黄原子又は窒素原子を１個含んでもよく、且つオキソ又はチオキソによって任意に置換されてもよく、
Ｒ^２０は、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_６アルキルチオ、Ｃ_１〜Ｃ_６アルコキシカルボニル、フェニル又は（Ｚ^１）_ｑ１で置換されたフェニルを表し、
Ｄ１−１〜Ｄ１−４２、Ｄ１−８１、Ｄ１−８４は、各々下記の構造で表される環を表し、

Ｘ^１は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル又はＣ_３〜Ｃ_８シクロアルキルを表し、ｇ２、ｇ３又はｇ４が２以上の整数を表すとき、各々のＸ^１は互いに同一であっても又は互いに相異なってもよく、更に２つのＸ^１が隣接する場合には、隣接する２つのＸ^１は、−ＣＨ＝ＣＨＣＨ＝ＣＨ−を形成することにより、それぞれのＸ^１が結合する炭素原子と共に６員環を形成してもよく、このとき環を形成する各々の炭素原子に結合した水素原子は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_６アルキルチオ、Ｃ_１〜Ｃ_６アルキルスルフィニル又はＣ_１〜Ｃ_６アルキルスルホニルによって任意に置換されてもよく、
Ｘ^１ａは、水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｘ^１ｂは、Ｃ_１〜Ｃ_６アルキルを表し、
Ｚは、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、Ｒ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^４５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^４５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−ＯＲ^４１、−Ｓ（Ｏ）_ｒ３Ｒ^４１、−Ｃ（Ｏ）ＯＲ^４１、−Ｃ（Ｏ）Ｒ^４２、−Ｃ（Ｏ）Ｎ（Ｒ^４４ａ）Ｒ^４３ａ、−Ｃ（＝ＮＯＲ^４１）Ｒ^４２、−Ｎ（Ｒ^４４）Ｒ^４３、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−１、Ｄ１−２、Ｄ１−７、Ｄ１−１０、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４、Ｄ１−３６、Ｄ１−３７又はＤ１−３８を表し、ｑが２以上の整数を表すとき、各々のＺは互いに同一であっても又は互いに相異なってもよく、
Ｚ^１は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、ハロ（Ｃ_１〜Ｃ_６）アルコキシ又はＣ_１〜Ｃ_６アルコキシカルボニルを表し、ｑ１が２以上の整数を表すとき、各々のＺ^１は互いに同一であっても又は互いに相異なってもよく、
Ｚ^２は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、−ＯＲ^５１、−Ｓ（Ｏ）_ｒ２Ｒ^５１、−Ｃ（Ｏ）ＯＲ^５１ａ、−Ｃ（Ｏ）Ｒ^５２、−Ｃ（Ｏ）Ｎ（Ｒ^５４）Ｒ^５３、−Ｃ（Ｓ）Ｎ（Ｒ^５４）Ｒ^５３又は−Ｎ（Ｒ^５４）Ｒ^５３を表し、ｑ２が２以上の整数を表すとき、各々のＺ^２は互いに同一であっても又は互いに相異なってもよく、更に、２つのＺ^２が隣接する場合には、隣接する２つのＺ^２は−Ｎ＝ＣＨＣＨ＝ＣＨ−，−ＣＨ＝ＮＣＨ＝ＣＨ−，−Ｎ＝ＮＣＨ＝ＣＨ−，−ＣＨ＝ＮＮ＝ＣＨ−，−Ｎ＝ＣＨＣＨ＝Ｎ−、−Ｎ＝ＣＨＮ＝ＣＨ−又は−ＯＣＨ_２Ｏ−を形成することにより、それぞれのＺ^２が結合する炭素原子と共に５又は６員環を形成してもよく、このとき、環を形成する各々の炭素原子に結合した水素原子は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_６アルキルチオ、Ｃ_１〜Ｃ_６アルキルスルフィニル又はＣ_１〜Ｃ_６アルキルスルホニルによって任意に置換されてもよく、
Ｚ^３は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、ハロ（Ｃ_１〜Ｃ_６）アルコキシ、Ｃ_１〜Ｃ_６アルキルチオ、Ｃ_１〜Ｃ_６アルキルスルフィニル又はＣ_１〜Ｃ_６アルキルスルホニルを表し、ｑ３が２以上の整数を表すとき、各々のＺ^３は互いに同一であっても又は互いに相異なってもよく、
Ｒ^３１は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^３５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、−Ｃ（Ｏ）Ｒ^３７、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル、ナフチル又は（Ｚ^２）_ｑ２で置換されたナフチルを表し、
Ｒ^３２は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^３５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル又はフェニルを表し、
Ｒ^３２ａ、Ｒ^３２ｂ及びＲ^３２ｃは、各々独立してＣ_１〜Ｃ_６アルキルを表し、
Ｒ^３３及びＲ^３４は、各々独立して水素原子、Ｃ_１〜Ｃ_６アルキル、−Ｃ（Ｏ）ＯＲ^３６又は−Ｃ（Ｏ）Ｒ^３７を表し、
Ｒ^３５は、ハロゲン原子、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_６アルキルチオ、Ｃ_１〜Ｃ_６アルキルスルフィニル、Ｃ_１〜Ｃ_６アルキルスルホニル又はフェニルを表し、
Ｒ^３６は、Ｃ_１〜Ｃ_６アルキルを表し、
Ｒ^３７は、水素原子、Ｃ_１〜Ｃ_６アルキル、フェニル又は（Ｚ^２）_ｑ２で置換されたフェニルを表し、
Ｒ^４１は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_２〜Ｃ_６アルキニル、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−３２、Ｄ１−３３又はＤ１−３４を表し、
Ｒ^４２は、水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^４３及びＲ^４４は、各々独立して水素原子、Ｃ_１〜Ｃ_６アルキル、Ｃ_１〜Ｃ_６アルコキシカルボニル又はＣ_１〜Ｃ_６アルキルカルボニルを表し、
Ｒ^４３ａは、Ｃ_１〜Ｃ_６アルキル又はハロ（Ｃ_１〜Ｃ_６）アルキルを表し、
Ｒ^４４ａは、水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^４５は、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＨ、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_１０アルコキシカルボニル、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−１０、Ｄ１−３２、Ｄ１−３３又はＤ１−３４を表すか、或いは、２つのＲ^４５が同一の炭素上に置換している場合、２つのＲ^４５は一緒になってオキソ、チオキソ、イミノ、Ｃ_１〜Ｃ_６アルキルイミノ、Ｃ_１〜Ｃ_６アルコキシイミノ又はＣ_１〜Ｃ_６アルキリデンを形成してもよく、
Ｒ^５１は、水素原子、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、フェニル、ハロゲン原子によって任意に置換されたフェニル又はＤ１−３９を表し、
Ｒ^５１ａ及びＲ^５２は、各々独立して水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^５３及びＲ^５４は、各々独立して水素原子、Ｃ_１〜Ｃ_６アルキル又はＣ_１〜Ｃ_６アルキルカルボニルを表し、
ｆ５は、０、１、２、３、４又は５の整数を表し、
ｆ７は、０、１、２、３、４、５、６又は７の整数を表し、
ｇ１及びｐは、各々独立して０又は１の整数を表し、
ｇ２、ｍ、ｎ、ｒ１、ｒ２及びｒ３は、各々独立して０、１又は２の整数を表し、
ｇ３は、０、１、２又は３の整数を表し、
ｇ４は、０、１、２、３又は４の整数を表し、
ｑ、ｑ１、ｑ２及びｑ３は、各々独立して１、２、３、４又は５の整数を表す。〕で表されるケトン若しくはオキシム化合物又はそれらの塩。 Formula (1):

[Wherein, B represents a ring represented by any of B-1, B-2 and B-3,

Q represents an oxygen atom, a sulfur atom or NOR ⁷ ;
A is a hydrogen _atom, C 1 -C ₆ alkyl, optionally substituted with ^{R 5} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ cycloalkyl, optionally substituted with ^{R 5} _(C 3 ~ C _{8) cycloalkyl,} C 2 -C _{6 alkenyl,} C 3 -C ₈ cycloalkenyl, optionally substituted with ^{R 5} _(C 3 ~C ₈₎ cycloalkenyl, optionally substituted with ^{R 5} _{(C 2} -C _{6) alkenyl,} C 2 -C ₆ alkynyl, optionally substituted with ^{R 5} _(C 2 ~C _{6) ^{alkynyl, -S (O) r2 R 1}} , -C (O) OR 1, -C ( ^{S) OR 1, -C (O} ) SR 1, -C (S) SR 1, -C (O) R 2, -C (S) R 2, -C (O) N (R 4) R 3, _{^{-C (S) N (R 4}} ) R 3, -S (O) 2 N (R 4) R 3, -P (O) (oR 1) 2 or -P ( S) (OR ¹ ) ₂
R ¹ _is, C 1 -C ₈ alkyl, optionally substituted with ^{R 5} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ cycloalkyl, optionally substituted with ^{R 5} _(C 3 ~C ₈ ) _cycloalkyl, C 2 -C ₆ alkenyl, optionally substituted with ^{R 5} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ cycloalkenyl, optionally substituted with ^{R 5} _(C 3 ~C ₈ ) Represents cycloalkenyl, C ₂ -C ₆ alkynyl, (C ₂ -C ₆ ) alkynyl, phenyl optionally substituted with R ⁵ , phenyl or phenyl substituted with (Z ² ) _q ² ,
R ² is a hydrogen _atom, C 1 -C ₈ alkyl, optionally substituted with ^{R 5} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ cycloalkyl, optionally substituted with ^{R 5} _{(C 3} -C _{8) cycloalkyl,} C 2 -C ₆ alkenyl, optionally substituted with ^{R 5} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ cycloalkenyl, optionally substituted with ^{R 5} _{(C 3} -C _{8) cycloalkenyl,} C 2 -C ₆ alkynyl, optionally substituted with ^{R 5} _(C 2 ~C ₆₎ ^{alkynyl, -C (= NOR 31) R} 32, ^phenyl, substituted with (Z _{2) q2} Phenyl, naphthyl, (Z ² ) _q2- substituted naphthyl, D1-1 to D1-42, D1-81 or D1-84,
R ³ and R ⁴ are each independently a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ⁵ , C ₃ -C ₈ cycloalkyl, optional with R ⁵ substituted in _(C 3 ~C _{8) cycloalkyl,} C 2 -C ₆ alkenyl, optionally substituted with ^{R 5} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ cycloalkenyl, optionally ^{R 5} substituted in _(C 3 ~C _{8) cycloalkenyl,} substituted C 2 -C ₆ alkynyl, optionally with ^{R 5} _(C 2 ~C ₆₎ alkynyl, ^phenyl, phenyl substituted with (Z _{2) q2} , D1-32, or represents D1-33 or D1-34, or ^{by R 3} to form a alkenylene chain alkylene chain or _C 2 -C ₇ of _C 2 -C ₇ together with ^{R 4} , R ³ and R ⁴ are combined A 3- to 8-membered ring may be formed together with the child, in which case the alkylene chain or alkenylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and by C ₁ -C ₆ alkyl, oxo or thioxo Optionally substituted,
R ⁵ is a halogen atom, cyano, nitro, C ₃ -C ₈ cycloalkyl, —OR ³¹ , —S (O) _{r 2} R ³¹ , —C (O) OR ³¹ , —C (O) R ³² , —N ^{(R 34) R 33, -Si} (R 32a) (R 32b) R 32c, ^phenyl, (Z ₂₎ phenyl substituted with _{q2, D1-1, D1-10, D1-32,} D1-33 or D1 or represents -34, or when two ^{R 5} are substituted on the same carbon, two ^{R 5} oxo together, thioxo, _imino, C 1 -C _{6 alkylimino, C} 1 ~ C ₆ alkoxyimino or C ₁ -C ₆ alkylidene may be formed,
R ⁶ is a hydrogen _atom, C 1 -C ₆ ^alkyl, optionally substituted with ^{R 15} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ ^cycloalkyl, optionally substituted with ^{R 15} _{(C 3} -C _{8) cycloalkyl,} C 2 -C ₆ ^alkenyl, optionally substituted with ^{R 15} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ ^{cycloalkenyl,} optionally substituted with ^{R 15} _{(C 3} -C _{8) cycloalkenyl,} C 2 -C ₆ ^alkynyl, optionally substituted with ^{R 15} _(C 2 ~C ₆₎ ^{alkynyl, -C (= NOR 16) R} 17, ^phenyl, substituted with (Z _{1) q1} Represented by phenyl, D1-10, D1-32, D1-33, D1-34, D1-36, D1-37, D1-38 or D1-81,
R ⁷ is a hydrogen _atom, C 1 -C ₈ ^alkyl, optionally substituted with ^{R 15b} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ ^cycloalkyl, optionally substituted with ^{R 15b} _{(C 3} -C _{8) cycloalkyl,} C 2 -C ₆ ^alkenyl, optionally substituted with ^{R 15b} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ ^{cycloalkenyl,} optionally substituted with ^{R 15b} _{(C 3} -C ₈₎ represents _{cycloalkenyl,} C 2 -C ₆ ^alkynyl, optionally substituted with ^{R 15b} _(C 2 ~C ₆₎ alkynyl, phenyl substituted with phenyl or ^(Z _{1) q1,}
R ^8a , R ^8b , R ^9a and R ^9b are each independently a hydrogen atom, a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, —OR ^16a , —S (O) _r1 R ^16a , —C (O) OR ^16a , —C (O) R ^17a , —C (O) N (R ^19a ) R ^18a , —C (═NOR ^16a ) R ^17a , phenyl or (Z ¹ ) represents phenyl substituted with _q1 ,
R ¹⁰ , R ¹¹ and R ¹² each independently represent a hydrogen atom or C ₁ -C ₆ alkyl;
R ¹⁵ is a halogen atom, _cyano, C 3 -C _{8 ^{cycloalkyl, -OR 16, -S (O)}} r1 R 16, ^phenyl, phenyl substituted with _{(Z 1) q1, D1-7,} D1-11 , D1-22, D1-32, D1-33 or D1-34,
R ^15b is a halogen atom, cyano, C ₃ -C ₈ cycloalkyl, halo (C ₃ -C ₈ ) cycloalkyl, —OR ^16b , —S (O) _r1 R ^16b , —C (O) OR ^16b , — C (O) N (R ^18b ) R ^19b , -C (= NOR ^16b ) R ^17b , -N (R ^18b ) R ^19b , -Si (R ^32a ) (R ^32b ) R ^32c , phenyl, (Z ¹ ) _q1- substituted phenyl, D1-32, D1-33, D1-34, D1-36, D1-37, D1-38, D1-81 or D1-84, or two R ^15b are the same The two R ^15b together form oxo, thioxo, imino, C ₁ -C ₆ alkylimino, C ₁ -C ₆ alkoxyimino or C ₁ -C ₆ alkylidene. The Well,
R ¹⁶ , R ^16a , R ^16b , R ¹⁷ , R ^17a , R ^17b , R ^18a and R ^19a each independently represent a hydrogen atom or C ₁ -C ₆ alkyl;
R ^18b and R ^19b are each independently a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ²⁰ , C ₂ -C ₆ alkenyl, C ₂ -C _{6. alkynyl,} or represents C 1 -C ₆ alkoxy or phenyl, ^or by ^{R 18b} is to form the Arukeren chain alkylene chain or _C 2 -C ₇ of _C 2 -C ₇ together with ^{R 19b,} R ^18b and R ^19b may form a 3- to 8-membered ring together with the nitrogen atom to which R ^19b is bonded, in which case the alkylene chain or alkenylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and oxo or thioxo Optionally substituted by
R ²⁰ represents cyano, C ₃ -C ₈ cycloalkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ alkylthio, C ₁ -C ₆ alkoxycarbonyl, phenyl or phenyl substituted with (Z ¹ ) _q1. ,
D1-1 to D1-42, D1-81, and D1-84 each represent a ring represented by the following structure:

X ¹ represents a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl or C ₃ -C ₈ cycloalkyl, and g 2, g 3 or g 4 represents an integer of 2 or more. When each X ¹ may be the same as or different from each other, and when two X ¹ are adjacent to each other, the two adjacent X ¹ form —CH═CHCH═CH— By doing so, a 6-membered ring may be formed together with the carbon atom to which each X ¹ is bonded. At this time, the hydrogen atom bonded to each carbon atom forming the ring is a halogen atom, cyano, nitro, C _1. -C ₆ alkyl, halo _(C 1 ~C _{6) alkyl,} C 1 -C _{6 alkoxy,} C 1 -C _{6 alkylthio,} optionally by C 1 -C ₆ alkylsulfinyl or _C 1 -C ₆ alkylsulfonyl May be replaced,
X ^1a represents a hydrogen atom or C ₁ -C ₆ alkyl,
X ^1b represents C ₁ -C ₆ alkyl;
Z is a halogen atom, cyano, _nitro, substituted C 1 -C ₆ ^alkyl, which is optionally substituted with ^{R 45} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ ^cycloalkyl, optionally in ^{R 45} _(C 3 _{~C 8) cycloalkyl,} C 2 -C ₆ ^alkenyl, which is optionally substituted with ^{R 45} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ ^{cycloalkenyl,} optionally substituted with ^{R 45} _(C 3 _{~C 8) cycloalkenyl,} C 2 -C ₆ ^alkynyl, optionally substituted with ^{R 45} _(C 2 ~C _{6) ^{alkynyl, -OR 41, -S (O)}} r3 R 41, -C ( ^{O) OR 41, -C (O} ) R 42, -C (O) N (R 44a) R 43a, -C (= NOR 41) R 42, -N (R 44) R 43, phenyl, ^{(Z 3} ) phenyl substituted with _q3, D1-1, 1-2, D1-7, D1-10, D1-11, D1-22, D1-32, D1-33, D1-34, D1-36, D1-37 or D1-38, q is 2 or more Each Z may be the same as or different from each other,
Z ¹ is a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, C ₁ -C ₆ alkoxy, halo (C ₁ -C ₆ ) alkoxy or C ₁ -C _6. Represents alkoxycarbonyl, and when q1 represents an integer of 2 or more, each Z ¹ may be the same as or different from each other;
Z ² represents a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, —OR ⁵¹ , —S (O) _{r 2} R ⁵¹ , —C (O) OR ^51a , — C (O) R ⁵² , —C (O) N (R ⁵⁴ ) R ⁵³ , —C (S) N (R ⁵⁴ ) R ⁵³ or —N (R ⁵⁴ ) R ⁵³ , q2 is an integer of 2 or more when referring to, each of ^{Z 2} may be different or phase from each other be identical to each other, further, when two ^{Z 2} are adjacent, the two ^{Z 2} adjacent to each -N = CHCH = CH- , -CH = NCH = CH -, - N = NCH = CH -, - CH = NN = CH -, - N = CHCH = N -, - N = CHN = CH- or forming a -OCH ₂ O- May form a 5- or 6-membered ring with the carbon atom to which each Z ² is attached, And a hydrogen atom bonded to each carbon atom forming the ring is a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, C ₁ -C ₆ alkoxy, C ₁ -C _{6 alkylthio,} may be optionally substituted by C 1 -C ₆ alkylsulfinyl or _C 1 -C ₆ alkylsulfonyl,
Z ³ is a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, C ₁ -C ₆ alkoxy, halo (C ₁ -C ₆ ) alkoxy, C ₁ -C ₆ alkylthio represents a C ₁ -C ₆ alkylsulfinyl or C ₁ -C ₆ alkylsulfonyl, when q3 represents an integer of 2 or more, each of Z ³ may be or different from each other the same as each other,
R ³¹ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ³⁵ , C ₃ -C ₈ cycloalkyl, —C (O) R ³⁷ , phenyl, ( Z ²⁾ phenyl substituted with _q2, represents naphthyl substituted with naphthyl or ^(Z _{2) q2,}
R ³² represents a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl or phenyl optionally substituted with R ³⁵ ,
R ^32a , R ^32b and R ^32c each independently represent C ₁ -C ₆ alkyl;
R ³³ and R ³⁴ each independently represent a hydrogen atom, C ₁ -C ₆ alkyl, —C (O) OR ³⁶ or —C (O) R ³⁷ ,
R ³⁵ represents represents a halogen _atom, C 1 -C _{6 alkoxy,} C 1 -C _{6 alkylthio,} C 1 -C _{6 alkylsulfinyl,} a C 1 -C ₆ alkylsulfonyl or phenyl,
R ³⁶ represents C ₁ -C ₆ alkyl,
R ³⁷ represents a hydrogen atom, C ₁ -C ₆ alkyl, phenyl or phenyl substituted with (Z ² ) _q ² ,
R ⁴¹ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ⁴⁵ , C ₂ -C ₆ alkenyl, C ₂ -C ₆ alkynyl, phenyl, (Z ³ ) Represents phenyl, D1-32, D1-33 or D1-34 substituted with _q3 ;
R ⁴² represents a hydrogen atom or a _C 1 -C ₆ alkyl,
R ⁴³ and R ⁴⁴ each independently represent a hydrogen atom, C ₁ -C ₆ alkyl, C ₁ -C ₆ alkoxycarbonyl or C ₁ -C ₆ alkylcarbonyl,
R ^43a represents C ₁ -C ₆ alkyl or halo (C ₁ -C ₆ ) alkyl;
R ^44a represents a hydrogen atom or C ₁ -C ₆ alkyl;
R ⁴⁵ is a halogen atom, cyano, C ₃ -C ₈ cycloalkyl, —OH, C ₁ -C ₆ alkoxy, C ₁ -C ₁₀ alkoxycarbonyl, —Si (R ^32a ) (R ^32b ) R ^32c , phenyl, (Z ³ ) represents phenyl substituted with _q3 , D1-10, D1-32, D1-33 or D1-34, or when two R ⁴⁵ are substituted on the same carbon, R ⁴⁵ together may form oxo, thioxo, imino, C ₁ -C ₆ alkylimino, C ₁ -C ₆ alkoxyimino or C ₁ -C ₆ alkylidene;
R ⁵¹ represents a hydrogen atom, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, phenyl, phenyl optionally substituted with a halogen atom, or D1-39,
R ^51a and R ⁵² each independently represent a hydrogen atom or C ₁ -C ₆ alkyl;
R ⁵³ and R ⁵⁴ each independently represent a hydrogen atom, C ₁ -C ₆ alkyl or C ₁ -C ₆ alkylcarbonyl,
f5 represents an integer of 0, 1, 2, 3, 4 or 5,
f7 represents an integer of 0, 1, 2, 3, 4, 5, 6 or 7,
g1 and p each independently represent an integer of 0 or 1,
g2, m, n, r1, r2 and r3 each independently represents an integer of 0, 1 or 2;
g3 represents an integer of 0, 1, 2, or 3;
g4 represents an integer of 0, 1, 2, 3 or 4;
q, q1, q2 and q3 each independently represents an integer of 1, 2, 3, 4 or 5. ] The ketone or oxime compound represented by these, or those salts. Ｂは、Ｂ−１−ａ又はＢ−２−ａのいずれかで示される環を表し、

Ｚ^ａ、Ｚ^ｃ及びＺ^ｅは、各々独立して水素原子、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、Ｒ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^４５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−ＯＲ^４１、−Ｓ（Ｏ）_ｒ３Ｒ^４１、−Ｃ（Ｏ）ＯＲ^４１、−Ｃ（Ｏ）Ｒ^４２、−Ｃ（Ｏ）Ｎ（Ｒ^４４ａ）Ｒ^４３ａ、−Ｃ（＝ＮＯＲ^４１）Ｒ^４２、−Ｎ（Ｒ^４４）Ｒ^４３、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−１、Ｄ１−２、Ｄ１−７、Ｄ１−１０、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４、Ｄ１−３６、Ｄ１−３７又はＤ１−３８を表す請求項１記載のケトン若しくはオキシム化合物又はそれらの塩。 B represents a ring represented by either B-1-a or B-2-a;

Z ^a , Z ^c and Z ^e are each independently a hydrogen atom, a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ⁴⁵ , C ₃ -C ₈ ^cycloalkyl, optionally substituted with ^{R 45} _(C 3 ~C _{8) cycloalkyl,} C 2 -C ₆ ^alkenyl, optionally substituted with ^{R 45} _(C 2 ~C ₆₎ alkenyl, _{C 2} -C ₆ ^alkynyl, optionally substituted with ^{R 45} _(C 2 ~C _{6) ^{alkynyl, -OR 41, -S (O)}} r3 R 41, -C (O) OR 41, -C (O) R 42 ^{, -C (O) N (R} 44a) R 43a, -C (= NOR 41) R 42, -N (R 44) R 43, ^phenyl, (Z ₃₎ phenyl substituted with _q3, D1-1, D1-2, D1-7, D1-10, D1-11, D1- The ketone or oxime compound or a salt thereof according to claim 1, which represents 22, D1-32, D1-33, D1-34, D1-36, D1-37 or D1-38. Ｑは、酸素原子を表す請求項２記載のケトン化合物又はその塩。   The ketone compound or a salt thereof according to claim 2, wherein Q represents an oxygen atom. Ｑは、ＮＯＲ^７を表す請求項２記載のオキシム化合物又はその塩。 The oxime compound or a salt thereof according to claim 2, wherein Q represents NOR ⁷ . Ａは、水素原子、Ｃ_１〜Ｃ_６アルキル又は−Ｃ（Ｏ）Ｒ^２を表し、
Ｒ^２は、Ｃ_１〜Ｃ_８アルキルを表し、
Ｒ^６は、Ｃ_１〜Ｃ_６アルキル、Ｒ^１５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、−Ｃ（＝ＮＯＲ^１６）Ｒ^１７、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル又はＤ１−３２を表し、
Ｒ^８ａは、水素原子、Ｃ_１〜Ｃ_６アルキル、−Ｃ（Ｏ）ＯＲ^１６ａ又は−Ｃ（Ｏ）Ｒ^１７ａを表し、
Ｒ^９ａは、水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^８ｂ及びＲ^９ｂは、水素原子を表し、
Ｒ^１０、Ｒ^１１及びＲ^１２は、水素原子を表し、
Ｒ^１５は、ハロゲン原子、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＲ^１６又はフェニルを表し、
Ｒ^１６、Ｒ^１６ａ、Ｒ^１７及びＲ^１７ａは、各々独立してＣ_１〜Ｃ_６アルキルを表し、
Ｘ^１は、ハロ（Ｃ_１〜Ｃ_６）アルキルを表し、
Ｚ^ａ、Ｚ^ｃ及びＺ^ｅは、各々独立して水素原子、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、−ＯＲ^４１、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２又はＤ１−３７を表し、
Ｚ^１は、ハロゲン原子を表し、
Ｚ^３は、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、ハロ（Ｃ_１〜Ｃ_６）アルコキシ又はＣ_１〜Ｃ_６アルキルチオを表し、
Ｒ^４１は、Ｃ_１〜Ｃ_６アルキル、Ｒ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、フェニル、Ｄ１−３２又はＤ１−３４を表し、
Ｒ^４５は、ハロゲン原子、フェニル又はＤ１−３４を表し、
ｇ２、ｇ３及びｐは、０を表し、
ｑ１及びｑ３は、１の整数を表し、
ｇ４、ｍ及びｎは、各々独立して０又は１の整数を表す請求項３記載のケトン化合物又はその塩。 A represents a hydrogen _atom, a C 1 -C ₆ alkyl or -C (O) ^{R 2,}
R ² represents C ₁ -C ₈ alkyl,
R ⁶ is C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ¹⁵ , C ₃ -C ₈ cycloalkyl, C ₂ -C ₆ alkenyl, -C (= NOR ¹⁶ ). R ¹⁷ , phenyl, phenyl substituted with (Z ¹ ) _q1 or D1-32,
R ^8a represents a hydrogen atom, C ₁ -C ₆ alkyl, —C (O) OR ^16a or —C (O) R ^17a ,
R ^9a represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ^8b and R ^9b represent a hydrogen atom,
R ¹⁰ , R ¹¹ and R ¹² represent a hydrogen atom,
R ¹⁵ represents a halogen atom, C ₃ -C ₈ cycloalkyl, —OR ¹⁶ or phenyl,
R ¹⁶ , R ^16a , R ¹⁷ and R ^17a each independently represent C ₁ -C ₆ alkyl;
X ¹ represents halo (C ₁ -C ₆ ) alkyl;
Z ^a , Z ^c and Z ^e are each independently optionally substituted with a hydrogen atom, a halogen atom, C ₁ -C ₆ alkyl, C ₃ -C ₈ cycloalkyl, C ₂ -C ₆ alkenyl, R ⁴⁵ (C ₂ -C ₆ ) alkenyl, C ₂ -C ₆ alkynyl, —OR ⁴¹ , phenyl, phenyl substituted with (Z ³ ) _q3 , D1-7, D1-11, D1-22, D1-32 or D1 -37,
Z ¹ represents a halogen atom,
Z ³ represents a halogen atom, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, C ₁ -C ₆ alkoxy, halo (C ₁ -C ₆ ) alkoxy or C ₁ -C ₆ alkylthio,
R ⁴¹ represents C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ⁴⁵ , phenyl, D1-32 or D1-34,
R ⁴⁵ represents a halogen atom, phenyl or D1-34,
g2, g3 and p represent 0;
q1 and q3 represent an integer of 1,
The ketone compound or salt thereof according to claim 3, wherein g4, m and n each independently represents an integer of 0 or 1. Ｂは、Ｂ−１−ａを表し、
Ｚ^ａは、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル又はＣ_１〜Ｃ_６アルコキシを表し、
Ｚ^ｃは、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、−ＯＲ^４１、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２又はＤ１−３７を表し、
Ｚ^ｅは、ハロゲン原子又はＣ_１〜Ｃ_６アルキルを表す請求項５記載のケトン化合物又はその塩。 B represents B-1-a,
Z ^a represents a halogen atom, C ₁ -C ₆ alkyl or C ₁ -C ₆ alkoxy;
Z ^c is a halogen atom, C ₁ -C ₆ alkyl, C ₃ -C ₈ cycloalkyl, C ₂ -C ₆ alkenyl, (C ₂ -C ₆ ) alkenyl optionally substituted with R ⁴⁵ , C ₂ -C Represents ₆ alkynyl, —OR ⁴¹ , phenyl, (Z ³ ) _q3 substituted phenyl, D1-7, D1-11, D1-22, D1-32 or D1-37;
The ketone compound or salt thereof according to claim 5, wherein Z ^e represents a halogen atom or C ₁ -C ₆ alkyl. Ａは、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−Ｓ（Ｏ）_ｒ２Ｒ^１、−Ｃ（Ｏ）ＯＲ^１、−Ｃ（Ｏ）ＳＲ^１、−Ｃ（Ｓ）ＯＲ^１、−Ｃ（Ｏ）Ｒ^２、−Ｃ（Ｏ）Ｎ（Ｒ^４）Ｒ^３、−Ｃ（Ｓ）Ｎ（Ｒ^４）Ｒ^３又は−Ｓ（Ｏ）_２Ｎ（Ｒ^４）Ｒ^３を表し、
Ｒ^１は、Ｃ_１〜Ｃ_８アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、フェニル又は（Ｚ^２）_ｑ２で置換されたフェニルを表し、
Ｒ^２は、Ｃ_１〜Ｃ_８アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^５で任意に置換された（Ｃ_３〜Ｃ_８）シクロアルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−Ｃ（＝ＮＯＲ^３１）Ｒ^３２、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル、Ｄ１−５、Ｄ１−６、Ｄ１−８、Ｄ１−１０又はＤ１−８１を表し、
Ｒ^３は、Ｃ_１〜Ｃ_６アルキル、Ｒ^５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_２〜Ｃ_６アルケニル、フェニル又は（Ｚ^２）_ｑ２で置換されたフェニルを表すか、或いは、Ｒ^３はＲ^４と一緒になってＣ_４又はＣ_５のアルキレン鎖を形成することにより、Ｒ^３及びＲ^４が結合する窒素原子と共に５又は６員環を形成し、このときこのアルキレン鎖は酸素原子、硫黄原子又は窒素原子を１個含んでもよく、且つＣ_１〜Ｃ_６アルキルによって任意に置換されてもよく、
Ｒ^４は、Ｃ_１〜Ｃ_６アルキル、Ｃ_２〜Ｃ_６アルケニル又はフェニルを表し、
Ｒ^５は、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＲ^３１、−Ｓ（Ｏ）_ｒ２Ｒ^３１、−Ｃ（Ｏ）ＯＲ^３１、−Ｃ（Ｏ）Ｒ^３２、−Ｎ（Ｒ^３４）Ｒ^３３、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル又はＤ１−１を表すか、或いは、２つのＲ^５が同一の炭素上に置換している場合、２つのＲ^５は一緒になってＣ_１〜Ｃ_６アルコキシイミノを形成してもよく、
Ｒ^６は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^１５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、−Ｃ（＝ＮＯＲ^１６）Ｒ^１７、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル又はＤ１−３２を表し、
Ｒ^７は、水素原子、Ｃ_１〜Ｃ_７アルキル、Ｒ^１５bで任意に置換された（Ｃ_１〜Ｃ_６）アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_３〜Ｃ_８シクロアルケニル、Ｒ^１５bで任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル又はフェニルを表し、
Ｒ^８ａは、水素原子、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、−Ｃ（Ｏ）ＯＲ^１６ａ、−Ｃ（＝ＮＯＲ^１６ａ）Ｒ^１７ａ又は（Ｚ^１）_ｑ１で置換されたフェニルを表し、
Ｒ^９ａは、水素原子又はＣ_１〜Ｃ_６アルキルを表し、
Ｒ^８ｂ及びＲ^９ｂは、水素原子を表し、
Ｒ^１２は、水素原子を表し、
Ｒ^１５は、ハロゲン原子、Ｃ_３〜Ｃ_８シクロアルキル又は−ＯＲ^１６を表し、
Ｒ^１５ｂは、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、ハロ（Ｃ_３〜Ｃ_８）シクロアルキル、−ＯＲ^１６ｂ、−Ｓ（Ｏ）_ｒ１Ｒ^１６ｂ、−Ｃ（Ｏ）ＯＲ^１６ｂ、−Ｃ（Ｏ）Ｎ（Ｒ^１８ｂ）Ｒ^１９ｂ、−Ｃ（＝ＮＯＲ^１６ｂ）Ｒ^１７ｂ、−Ｎ（Ｒ^１８ｂ）Ｒ^１９ｂ、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル、（Ｚ^１）_ｑ１で置換されたフェニル、Ｄ１−３２又はＤ１−８４を表し、
Ｒ^１６、Ｒ^１６ａ、Ｒ^１７、Ｒ^１７ａ及びＲ^１７ｂは、各々独立してＣ_１〜Ｃ_６アルキルを表し、
Ｒ^１８ｂは、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^２０で任意に置換された（Ｃ_１〜Ｃ_６）アルキル又はフェニルを表すか、或いは、Ｒ^１８ｂはＲ^１９ｂと一緒になってＣ_５のアルキレン鎖を形成することにより、Ｒ^１８ｂ及びＲ^１９ｂが結合する窒素原子と共に６員環を形成し、このときこのアルキレン鎖は酸素原子を１個含んでおり、
Ｒ^１９ｂは、水素原子又はＣ_１〜Ｃ_６アルキル を表し、
Ｒ^２０は、（Ｚ^１）_ｑ１で置換されたフェニルを表し、
Ｘ^１は、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル又はＣ_３〜Ｃ_８シクロアルキルを表し、ｇ３が２の整数を表し、更に２つのＸ^１が隣接して−ＣＨ＝ＣＨＣＨ＝ＣＨ−を形成することにより、それぞれのＸ^１が結合する炭素原子と共に６員環を形成し、このとき環を形成する各々の炭素原子に結合した水素原子の一つは、ハロゲン原子によって置換されてもよく、
Ｘ^１ａは、Ｃ_１〜Ｃ_６アルキルを表し、
Ｚ^ａ、Ｚ^ｃ及びＺ^ｅは、各々独立して水素原子、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−ＯＲ^４１、−Ｓ（Ｏ）_ｒ３Ｒ^４１、−Ｃ（Ｏ）ＯＲ^４１、−Ｃ（Ｏ）Ｒ^４２、−Ｃ（Ｏ）Ｎ（Ｒ^４４ａ）Ｒ^４３ａ、−Ｃ（＝ＮＯＲ^４１）Ｒ^４２、−Ｎ（Ｒ^４４）Ｒ^４３、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−２、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４又はＤ１−３７を表し、
Ｚ^１は、ハロゲン原子、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ又はＣ_１〜Ｃ_６アルコキシカルボニルを表し、ｑ１が２以上の整数を表すとき、各々のＺ^１は互いに同一であっても又は互いに相異なってもよく、
Ｚ^２は、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、−ＯＲ^５１、−Ｓ（Ｏ）_ｒ２Ｒ^５１、−Ｃ（Ｏ）ＯＲ^５１ａ、−Ｃ（Ｏ）Ｒ^５２又は−Ｃ（Ｏ）Ｎ（Ｒ^５４）Ｒ^５３を表し、ｑ２が２以上の整数を表すとき、各々のＺ^２は互いに同一であっても又は互いに相異なってもよく、更に、２つのＺ^２が隣接する場合には、隣接する２つのＺ^２は−Ｎ＝ＣＨＣＨ＝ＣＨ−を形成することにより、それぞれのＺ^２が結合する炭素原子と共に６員環を形成してもよく、このとき、環を形成する各々の炭素原子に結合した水素原子の一つは、ハロゲン原子によって置換されてもよく、
Ｚ^３は、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、Ｃ_１〜Ｃ_６アルコキシ、ハロ（Ｃ_１〜Ｃ_６）アルコキシ又はＣ_１〜Ｃ_６アルキルチオを表し、ｑ３が２以上の整数を表すとき、各々のＺ^３は互いに同一であっても又は互いに相異なってもよく、
Ｒ^３１は、Ｃ_１〜Ｃ_６アルキル、Ｒ^３５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、−Ｃ（Ｏ）Ｒ^３７、フェニル、（Ｚ^２）_ｑ２で置換されたフェニル又はナフチルを表し、
Ｒ^３２は、Ｃ_１〜Ｃ_６アルキル又はＲ^３５で任意に置換された（Ｃ_１〜Ｃ_６）アルキルを表し、
Ｒ^３３は、−Ｃ（Ｏ）Ｒ^３７を表し、
Ｒ^３４は、Ｃ_１〜Ｃ_６アルキルを表し、
Ｒ^３５は、ハロゲン原子、Ｃ_１〜Ｃ_６アルキルチオ又はフェニルを表し、
Ｒ^３７は、Ｃ_１〜Ｃ_６アルキル又はフェニルを表し、
Ｒ^４１は、水素原子、Ｃ_１〜Ｃ_６アルキル、Ｒ^４５で任意に置換された（Ｃ_１〜Ｃ_６）アルキル、フェニル又はＤ１−３２を表し、
Ｒ^４２は、Ｃ_１〜Ｃ_６アルキルを表し、
Ｒ^４３は、Ｃ_１〜Ｃ_６アルコキシカルボニルを表し、
Ｒ^４４は、水素原子を表し、
Ｒ^４５は、ハロゲン原子、シアノ、Ｃ_３〜Ｃ_８シクロアルキル、−ＯＨ、Ｃ_１〜Ｃ_６アルコキシ、Ｃ_１〜Ｃ_１０アルコキシカルボニル、−Ｓｉ（Ｒ^３２ａ）（Ｒ^３２ｂ）Ｒ^３２ｃ、フェニル又はＤ１−３４を表し、
Ｒ^５１は、Ｃ_１〜Ｃ_６アルキル、ハロ（Ｃ_１〜Ｃ_６）アルキル、ハロゲン原子によって任意に置換されたフェニル又はＤ１−３９を表し、
Ｒ^５１ａは、Ｃ_１〜Ｃ_６アルキルを表し、
Ｒ^５３及びＲ^５４は、各々独立してＣ_１〜Ｃ_６アルキルを表し、
ｇ２は、０、１又は２の整数を表し、
ｇ３及びｒ１は、各々独立して０、１又は２の整数を表し、
ｇ４、ｍ及びｎは、各々独立して０又は１の整数を表し、
ｆ７、ｐ及びｒ３は、０を表し、
ｑは、２又は３の整数を表し、
ｑ１は、１又は２の整数を表し、
ｑ２は、１、２又は３の整数を表し、
ｑ３は、１、２又は３の整数を表し、
ｒ２は、０又は２の整数を表す請求項４記載のオキシム化合物又はその塩。 A is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ⁵ , C ₃ -C ₈ cycloalkyl, C ₂ -C ₆ alkenyl, optionally with R ⁵ substituted _(C 2 ~C _{6) alkenyl,} substituted C 2 -C ₆ alkynyl, optionally with ^{R 5} _(C 2 ~C _{6) ^{alkynyl, -S (O) r2 R 1}} , -C (O) OR ¹ , —C (O) SR ¹ , —C (S) OR ¹ , —C (O) R ² , —C (O) N (R ⁴ ) R ³ , —C (S) N (R ⁴ ) Represents R ³ or —S (O) ₂ N (R ⁴ ) R ³ ;
R ¹ is C ₁ -C ₈ alkyl, (C ₁ -C ₆ ) alkyl, C ₃ -C ₈ cycloalkyl, C ₂ -C ₆ alkenyl, phenyl or (Z ² ) _q2 optionally substituted with R ^5. Represents phenyl substituted with
R ² _is, C 1 -C ₈ alkyl, optionally substituted with ^{R 5} _(C 1 ~C _{6) alkyl,} C 3 -C ₈ cycloalkyl, optionally substituted with ^{R 5} _(C 3 ~C ₈ ) _cycloalkyl, C 2 -C ₆ alkenyl, optionally substituted with ^{R 5} _(C 2 ~C _{6) alkenyl,} C 3 -C ₈ cycloalkenyl, optionally substituted with ^{R 5} _(C 3 ~C ₈ ) _{cycloalkenyl,} C 2 -C ₆ alkynyl, optionally substituted with ^{R 5} _(C 2 ~C ₆₎ ^{alkynyl, -C (= NOR 31) R} 32, ^phenyl, phenyl substituted with (Z _{2) q2} , D1-5, D1-6, D1-8, D1-10 or D1-81,
R ³ represents C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ⁵ , C ₂ -C ₆ alkenyl, phenyl or phenyl substituted with (Z ² ) _q ² Alternatively, R ³ together with R ⁴ forms a C ₄ or C ₅ alkylene chain to form a 5 or 6 membered ring with the nitrogen atom to which R ³ and R ⁴ are attached, where The alkylene chain may contain one oxygen atom, sulfur atom or nitrogen atom, and may be optionally substituted by C ₁ -C ₆ alkyl,
R ⁴ represents C ₁ -C ₆ alkyl, C ₂ -C ₆ alkenyl or phenyl,
R ⁵ is a halogen atom, cyano, C ₃ -C ₈ cycloalkyl, —OR ³¹ , —S (O) _{r 2} R ³¹ , —C (O) OR ³¹ , —C (O) R ³² , —N (R ³⁴ ) R ³³ , —Si (R ^32a ) (R ^32b ) R ^32c , phenyl, phenyl substituted with (Z ² ) _q ² or D1-1, or two R ⁵ on the same carbon When substituted, the two R ⁵ together may form a C ₁ -C ₆ alkoxyimino,
R ⁶ is a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ¹⁵ , C ₃ -C ₈ cycloalkyl, C ₂ -C ₆ alkenyl, -C (= NOR ¹⁶ ) R ¹⁷ , phenyl, phenyl substituted with (Z ¹ ) _q1 or D1-32;
R ⁷ is hydrogen atom, C ₁ -C ₇ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ^15b , C ₃ -C ₈ cycloalkyl, C ₂ -C ₆ alkenyl, C ₃ -C _{8 represents} cycloalkenyl, (C ₂ -C ₆ ) alkenyl optionally substituted with R ^15b , C ₂ -C ₆ alkynyl or phenyl;
R ^8a is substituted with a hydrogen atom, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, —C (O) OR ^16a , —C (═NOR ^16a ) R ^17a or (Z ¹ ) _q1. Represents phenyl,
R ^9a represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ^8b and R ^9b represent a hydrogen atom,
R ¹² represents a hydrogen atom,
R ¹⁵ represents a halogen atom, C ₃ -C ₈ cycloalkyl or —OR ¹⁶ ;
R ^15b is a halogen atom, cyano, C ₃ -C ₈ cycloalkyl, halo (C ₃ -C ₈ ) cycloalkyl, —OR ^16b , —S (O) _r1 R ^16b , —C (O) OR ^16b , — C (O) N (R ^18b ) R ^19b , -C (= NOR ^16b ) R ^17b , -N (R ^18b ) R ^19b , -Si (R ^32a ) (R ^32b ) R ^32c , phenyl, (Z ¹ ) represents phenyl substituted with _q1 , D1-32 or D1-84,
R ¹⁶ , R ^16a , R ¹⁷ , R ^17a and R ^17b each independently represent C ₁ -C ₆ alkyl;
R ^18b represents a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl or phenyl optionally substituted with R ²⁰ , or R ^18b together with R ^19b is C ₅ To form a six-membered ring with the nitrogen atom to which R ^18b and R ^19b are bonded, and this alkylene chain contains one oxygen atom,
R ^19b represents a hydrogen atom or C ₁ -C ₆ alkyl,
R ²⁰ represents phenyl substituted with (Z ¹ ) _q ¹ ,
X ¹ represents a halogen atom, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl or C ₃ -C ₈ cycloalkyl, g 3 represents an integer of 2, and two X ¹ are adjacent to each other. By forming —CH═CHCH═CH—, a 6-membered ring is formed together with the carbon atom to which each X ¹ is bonded. At this time, one of the hydrogen atoms bonded to each carbon atom forming the ring is May be substituted by a halogen atom,
X ^1a represents C ₁ -C ₆ alkyl,
Z ^a , Z ^c and Z ^e are each independently a hydrogen atom, a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, C ₃ -C ₈ cycloalkyl, C ₂ -C ₆ alkenyl, R ⁴⁵ (C ₂ -C ₆ ) alkenyl substituted with, C ₂ -C ₆ alkynyl, (C ₂ -C ₆ ) alkynyl optionally substituted with R ⁴⁵ , —OR ⁴¹ , —S (O) _r 3 R ⁴¹ , ^{-C (O) OR 41, -C} (O) R 42, -C (O) N (R 44a) R 43a, -C (= NOR 41) R 42, -N (R 44) R 43, phenyl, (Z ³ ) represents _q3 substituted phenyl, D1-2, D1-7, D1-11, D1-22, D1-32, D1-33, D1-34 or D1-37,
Z ¹ represents a halogen atom, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, C ₁ -C ₆ alkoxy or C ₁ -C ₆ alkoxycarbonyl, and q ₁ represents an integer of 2 or more. When represented, each Z ¹ may be the same as or different from each other,
Z ² represents a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, —OR ⁵¹ , —S (O) _{r 2} R ⁵¹ , —C (O) OR ^51a , — C (O) R ⁵² or —C (O) N (R ⁵⁴ ) R ⁵³ is represented, and when q2 represents an integer of 2 or more, each Z ² may be the same as or different from each other. In addition, when two Z ² are adjacent to each other, the two adjacent Z ² form —N═CHCH═CH— to form a 6-membered ring together with the carbon atom to which each Z ² is bonded. In this case, one of the hydrogen atoms bonded to each carbon atom forming the ring may be substituted with a halogen atom,
Z ³ represents a halogen atom, C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, C ₁ -C ₆ alkoxy, halo (C ₁ -C ₆ ) alkoxy or C ₁ -C ₆ alkylthio, when q3 represents an integer of 2 or more, each Z ³ may be the same as or different from each other;
R ³¹ is C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ³⁵ , —C (O) R ³⁷ , phenyl, phenyl substituted with (Z ² ) _q ² or naphthyl Represents
R ³² represents C ₁ -C ₆ alkyl or (C ₁ -C ₆ ) alkyl optionally substituted with R ³⁵ ;
R ³³ represents -C (O) R ³⁷ ;
R ³⁴ represents C ₁ -C ₆ alkyl,
R ³⁵ represents a halogen atom, C ₁ -C ₆ alkylthio or phenyl,
R ³⁷ represents C ₁ -C ₆ alkyl or phenyl,
R ⁴¹ represents a hydrogen atom, C ₁ -C ₆ alkyl, (C ₁ -C ₆ ) alkyl optionally substituted with R ⁴⁵ , phenyl or D1-32;
R ⁴² represents C ₁ -C ₆ alkyl,
R ⁴³ represents C ₁ -C ₆ alkoxycarbonyl,
R ⁴⁴ represents a hydrogen atom,
R ⁴⁵ is a halogen atom, cyano, C ₃ -C ₈ cycloalkyl, —OH, C ₁ -C ₆ alkoxy, C ₁ -C ₁₀ alkoxycarbonyl, —Si (R ^32a ) (R ^32b ) R ^32c , phenyl or D1-34,
R ⁵¹ represents C ₁ -C ₆ alkyl, halo (C ₁ -C ₆ ) alkyl, phenyl optionally substituted by a halogen atom or D1-39,
R ^51a represents C ₁ -C ₆ alkyl;
R ⁵³ and R ⁵⁴ each independently represent C ₁ -C ₆ alkyl;
g2 represents an integer of 0, 1 or 2;
g3 and r1 each independently represents an integer of 0, 1 or 2;
g4, m and n each independently represent an integer of 0 or 1,
f7, p and r3 represent 0;
q represents an integer of 2 or 3,
q1 represents an integer of 1 or 2,
q2 represents an integer of 1, 2 or 3,
q3 represents an integer of 1, 2 or 3,
The oxime compound or a salt thereof according to claim 4, wherein r2 represents 0 or an integer of 2. Ｂは、Ｂ−１−ａを表し、
Ｚ^ａは、ハロゲン原子、ニトロ、Ｃ_１〜Ｃ_６アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｃ_１〜Ｃ_６アルコキシ又はＣ_１〜Ｃ_６アルキルチオを表し、
Ｚ^ｃは、水素原子、ハロゲン原子、シアノ、ニトロ、Ｃ_１〜Ｃ_６アルキル、Ｃ_３〜Ｃ_８シクロアルキル、Ｃ_２〜Ｃ_６アルケニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルケニル、Ｃ_２〜Ｃ_６アルキニル、Ｒ^４５で任意に置換された（Ｃ_２〜Ｃ_６）アルキニル、−ＯＲ^４１、−Ｓ（Ｏ）_ｒ３Ｒ^４１、−Ｃ（Ｏ）ＯＲ^４１、−Ｃ（Ｏ）Ｒ^４２、−Ｃ（Ｏ）Ｎ（Ｒ^４４ａ）Ｒ^４３ａ、−Ｃ（＝ＮＯＲ^４１）Ｒ^４２、−Ｎ（Ｒ^４４）Ｒ^４３、フェニル、（Ｚ^３）_ｑ３で置換されたフェニル、Ｄ１−２、Ｄ１−７、Ｄ１−１１、Ｄ１−２２、Ｄ１−３２、Ｄ１−３３、Ｄ１−３４又はＤ１−３７を表し、
Ｚ^ｅは、ハロゲン原子、Ｃ_１〜Ｃ_６アルキル又はＣ_１〜Ｃ_６アルコキシを表し、
Ｘ^１は、ハロゲン原子又はハロ（Ｃ_１〜Ｃ_６）アルキルを表し、
ｇ３は、０又は１の整数を表す請求項７記載のオキシム化合物又はその塩。 B represents B-1-a,
Z ^a represents a halogen atom, _nitro, C 1 -C _{6 alkyl,} C 3 -C _{8 cycloalkyl,} C 2 -C _{6 alkenyl,} a C 1 -C ₆ alkoxy or _C 1 -C ₆ alkylthio,
Z ^c is optionally substituted with a hydrogen atom, a halogen atom, cyano, nitro, C ₁ -C ₆ alkyl, C ₃ -C ₈ cycloalkyl, C ₂ -C ₆ alkenyl, R ⁴⁵ (C ₂ -C ₆ ) Alkenyl, C ₂ -C ₆ alkynyl, (C ₂ -C ₆ ) alkynyl optionally substituted with R ⁴⁵ , —OR ⁴¹ , —S (O) _r 3 R ⁴¹ , —C (O) OR ⁴¹ , —C ^{(O) R 42, -C (} O) N (R 44a) R 43a, -C (= NOR 41) R 42, -N (R 44) R 43, ^phenyl, phenyl substituted with (Z _{3) q3} , D1-2, D1-7, D1-11, D1-22, D1-32, D1-33, D1-34 or D1-37,
Z ^e represents a halogen _atom, C 1 -C ₆ alkyl or _C 1 -C ₆ alkoxy,
X ¹ represents a halogen atom or halo (C ₁ -C ₆ ) alkyl,
The oxime compound or a salt thereof according to claim 7, wherein g3 represents an integer of 0 or 1. 請求項１〜請求項８記載のケトン及びオキシム化合物並びにそれらの塩から選ばれる１種又は２種以上を有効成分として含有する農薬。   The agrochemical which contains 1 type, or 2 or more types chosen from the ketone and oxime compound of those of Claims 1-8, and those salts as an active ingredient. 請求項１〜請求項８記載のケトン及びオキシム化合物並びにそれらの塩から選ばれる１種又は２種以上を有効成分として含有する除草剤。   A herbicide containing, as an active ingredient, one or more selected from the ketone and oxime compounds according to claim 1 and a salt thereof.