JP2016505402A - Agricultural product storage polymer film, container made therefrom, and agricultural product storage related method - Google Patents
Agricultural product storage polymer film, container made therefrom, and agricultural product storage related method Download PDFInfo
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- JP2016505402A JP2016505402A JP2015541980A JP2015541980A JP2016505402A JP 2016505402 A JP2016505402 A JP 2016505402A JP 2015541980 A JP2015541980 A JP 2015541980A JP 2015541980 A JP2015541980 A JP 2015541980A JP 2016505402 A JP2016505402 A JP 2016505402A
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Abstract
本発明は、ポリマー積層材料、それから作製された容器及び農産物などを貯蔵する方法を含む。【選択図】なしThe present invention includes a method for storing polymer laminate materials, containers made therefrom, produce and the like. [Selection figure] None
Description
本発明は、ポリマー積層材料に関し、さらに具体的には、機能特性を示すポリマー積層材料に関する。本発明は、さらに、バリア及び緩衝フィルム、特に、限定されないが、食品貯蔵に特に関係する悪条件の管理に有用であると立証された機能特性を示すバリア及び緩衝フィルムに関する。本発明は、さらに、接触時に効果的に利用できる有効成分を内部の空洞内に含む緩衝フィルムに関する。本発明は、さらに、機能特性を高めるための緩衝フィルムの積層形成に関する。 The present invention relates to a polymer laminate material, and more specifically to a polymer laminate material exhibiting functional characteristics. The present invention further relates to barrier and cushioning films, particularly but not limited to barriers and cushioning films that exhibit functional properties that have proven useful in managing adverse conditions particularly associated with food storage. The present invention further relates to a buffer film containing an active ingredient that can be effectively used in contact in an internal cavity. The present invention further relates to the formation of a buffer film for enhancing functional properties.
機能特性を示すポリマー積層体は、保健医療から調整雰囲気包装や建築業界等にまでに及ぶ複数の産業において様々な用途がある。本発明においては、より具体的には、食品貯蔵においては、フレキシブル包装材料及びバリア膜の近年の技術的進展により、吸湿性、臭気吸収性、臭気遮断、酸素透過性、及び水蒸気透過性の管理などの貯蔵製品及び最終ユーザーの利益がもたらされており、これら全てが、新鮮さの保持、耐汚染性に寄与している。 Polymer laminates exhibiting functional properties have a variety of uses in multiple industries ranging from health care to controlled atmosphere packaging and the building industry. In the present invention, more specifically, in food storage, management of hygroscopicity, odor absorption, odor blocking, oxygen permeability, and water vapor permeability due to recent technological progress of flexible packaging materials and barrier membranes. Such as storage products and end user benefits, all of which contribute to freshness preservation and stain resistance.
収穫後の慣行は、人と動物の健康、ならびに、農業関連産業及び農家や全体的食の安全の経済的持続に大きな影響を及ぼす。人又は動物の摂取を目的とした食糧中に含まれる場合、悪い取扱、劣悪な保存状態に起因する、侵入昆虫、カビ、細菌、真菌、及び／又はその他の混入物は、深刻な健康上のリスクを提起する。このような侵入による収穫後の損害は、サハラ砂漠以南のアフリカ諸国の小規模農家に対しては、特に顕著に所得創出を妨害する。国連食糧農業機関の収穫後に関するＦＡＯ報告書：虫害によると、「タンザニアにおけるトウモロコシの３５％もの損害が、不適切に貯蔵された場合の５〜６ヶ月以内のオオコナナガシンクイムシ（Ｌａｒｇｅｒ Ｇｒａｉｎ Ｂｏｒｅｒ）に起因し（Ｍａｌｌｙａ、１９９２年）、また、６０％もの損害が、貯蔵の９ヶ月後に発生すると想定され（Ｋｅｉｌ、１９８８年）、この状況は深刻な飢饉に繋がる可能性がある」。ケニアの高原では、トウモロコシの害虫による全損害は５７％と推定され、病気よりも昆虫の方が重要であった（Ｇｒｉｓｌｅｙ、１９９７年）。ジンバブエでは、貯蔵トウモロコシの穀物損害の９２％が害虫によるものであり、マラチオンでの処理により損害が１０％まで減少したと報告された（Ｍａｔｒｉｏ、１９９２年）。貯蔵中のササゲ豆への害虫侵入は、市場と村落での貯蔵中に９０％にもなる場合がある（Ａｌａｂｅｅｋ、１９９６年）。様々な食糧が昆虫侵入の影響を受けており、カビ、及び真菌の侵入は、トウモロコシ粒や豆類に限らない。菌類病に加えて害虫がキャッサバの損害の５０％の原因である（Ｍａｎｉｎｅｋ、１９９４）。貯蔵４ヶ月後の乾燥キャッサバの根のオオコナナガシンクイムシによる７０％もの損害が報告された（Ｈｏｄｇｅｓら、１９８５年）。 Post-harvest practices have a significant impact on human and animal health, and the economic sustainability of agriculture-related industries and farms and overall food safety. When included in foods intended for human or animal consumption, invasive insects, molds, bacteria, fungi, and / or other contaminants resulting from poor handling, poor storage conditions are serious health hazards. Raise the risk. Post-harvest damage due to such invasions is a significant obstacle to income generation, especially for small-scale farmers in sub-Saharan Africa. The UN Food and Agriculture Organization's Post-harvest FAO Report: According to Insect Damage, “Larger Grain Borer within 5-6 months when 35% of maize damage in Tanzania is improperly stored (Mallya, 1992) and as much as 60% of damage is assumed to occur nine months after storage (Keil, 1988), which can lead to severe famine. " In the Kenyan plateau, the total damage caused by maize pests was estimated at 57%, with insects more important than diseases (Grisley, 1997). In Zimbabwe, 92% of crop damage in stored corn was due to pests, and treatment with malathion was reported to reduce damage to 10% (Matrio, 1992). Pest invasion into cowpea beans during storage can be as high as 90% during storage in markets and villages (Alabeek, 1996). Various foods are affected by insect invasion, and the invasion of mold and fungi is not limited to corn grains and beans. In addition to fungal diseases, pests are responsible for 50% of cassava damage (Maninek, 1994). As much as 70% damage was reported in the dried cassava roots after 4 months of storage due to the giant beetle (Hodges et al., 1985).
害虫は、主に直接摂取により貯蔵産物に損害を与える。一部の種は、内胚乳を常食して重量と品質に損害を与え、他の種は、胚芽を常食し、不良種子発芽と低い生存率をもたらす（Ｍａｌｅｋ ＆ Ｐａｒｖｅｅｎ、１９８９年； Ｓａｎｔｕｓら、１９９０年）。産物の直接摂取に加えて、害虫は、産物中の***物、脱皮、死体及び自らの存在により自分たちの食生活環境を汚染する。これは商業的に望ましいことではない。害虫により与えられた損傷は、生殖細胞の伝染を介して細菌及び菌類病の感染を容易にする（Ｃｒａｖｅｄｉ ＆ Ｑｕａｒｏｎｉ、１９８２年；Ｅ．Ｋｕｎｄａｙｏ、１９８８年；Ｄｕｎｋｅｌ、１９８０年）。また、昆虫の存在は、摂食活動により貯蔵産物の温度を上昇させ、高温部を生ずる（Ａｐｐｅｒｔ、１９８７年；Ｍｉｌｌｓ、１９８９年）。これらの「高温部」は、凝縮と過剰湿気に繋がり、カビ又は真菌の成長が起こる可能性がある。昆虫の活動は、生殖細胞の伝染と真菌感染を受けやすい表面積の増加により菌類病の蔓延に重大な影響を与え、これが最終的にカビ毒の生成を増やす可能性がある（Ｄｕｎｋｅｌ、１９８８年）。 Pests damage stored products primarily through direct consumption. Some species eat the endosperm and damage weight and quality, while other species eat the germ, resulting in poor seed germination and low viability (Malek & Parveen, 1989; Santus et al., 1990). In addition to direct ingestion of products, pests contaminate their dietary habits by excrement, molting, corpses and their presence in the product. This is not commercially desirable. Damage caused by pests facilitates bacterial and fungal infections through germline transmission (Cravedi & Quaroni, 1982; E. Kundayo, 1988; Dunkel, 1980). Also, the presence of insects raises the temperature of the stored product due to feeding activity, creating a hot zone (Appert, 1987; Mills, 1989). These “hot spots” can lead to condensation and excess moisture, and mold or fungal growth can occur. Insect activity has a significant impact on the prevalence of fungal diseases by increasing germinal cell transmission and increased surface area susceptible to fungal infection, which can ultimately increase the production of mold toxins (Dunkel, 1988). .
害虫の物理的損害は別として、劣悪な収穫後貯蔵から生ずる侵入が、トウモロコシ、小麦、及びその他の食糧品の輸出に応じて、農家、地域社会、及びいくつかの国々の経済、ならびに最終的に国際的食糧安全保障に対し経済的に壊滅的な影響を与える可能性がある。例えば、タンザニアは、消費又は輸出目的のトウモロコシのオオコナナガシンクイムシによる損害で年間ほぼ９１００万ＵＳドルを失う（Ｂｉｏｎｅｔ Ｉｎｔｅｒｎａｔｉｏｎａｌ ＆ Ｇｌｏｂａｌ Ｉｎｖａｓｉｏｎ Ｓｐｅｃｉｅｓ Ｐｒｏｇｒａｍ）。サハラ砂漠以南のアフリカ諸国の農家は、貯蔵期間が長くなると発生する虫害による劣化が避けられないために、成熟前に貯蔵産物を売らざるを得ないことが多い（Ｇｌｏｂａｌら、１９９６年；Ｂｒｉｃｅら、１９９６年；Ｍａｒｓｌａｎｄ ＆ Ｇｏｌｏｂ、１９９６年；Ｄｏｎａｌｄｓｏｎら、１９９６年）。市場の変動に伴うより高い価格を待つという柔軟性を持てないので、収穫後の貯蔵と保護ができないことが大きな収入の減少に繋がる。農場での食品貯蔵と収穫後損失により経済的負担という２重の困難は、特に、昆虫とげっ歯類を防ぐ貯蔵設備の構築に利用可能な原資の欠如、殺虫剤／駆除剤使用の知識の欠如、ならびに、外部環境及び気候条件を緩和することができる資材の費用の負担能力の欠如に起因して、発展途上国の農家に大被害を及ぼす。 Apart from pest physical damage, invasions resulting from poor post-harvest storage may depend on the exports of corn, wheat, and other food products, as well as the economy of farmers, communities, and some countries, and ultimately Could have an economic devastating impact on international food security. For example, Tanzania loses nearly US $ 91 million a year due to damage caused by corn giant beetles on corn for consumption or export (Bionet International & Global Innovation Specs Program). Farmers in sub-Saharan Africa are often forced to sell their stored products before maturity due to the inevitable degradation caused by insect damage that occurs during longer storage periods (Global et al., 1996; Brice). 1996; Marsland & Golob, 1996; Donaldson et al., 1996). The lack of flexibility to wait for higher prices due to market fluctuations, and the lack of post-harvest storage and protection can lead to significant revenue reductions. The double difficulty of economic burden due to on-farm food storage and post-harvest losses, especially the lack of resources available to build storage facilities to prevent insects and rodents, knowledge of pesticide / pesticide use knowledge Causes serious damage to farmers in developing countries due to the lack and lack of ability to pay for materials that can mitigate external environment and climatic conditions.
農場での貯蔵の困難さ及び収穫後の損害は、現在使われている容器の酸素透過性と水蒸気透過性の欠如に起因する、主として、貯蔵含有物の温度、湿気、呼吸、昆虫の侵入、カビと真菌増殖によるげっ歯類ならびにフモニシン、マイコトキシン、アフラトキシンの侵入の結果として発生する。人の摂食が目的であっても、又は動物の食糧ストックであっても、貯蔵産物の汚染は、深刻な健康上のリスクを提起する。酪農牛によるアフラトキシン摂取は、牛の体内で変化するが、それでも、有毒性のままであり、ミルク中で検出される（Ｃｈｒｉｓｔｅｎｓｅｎ ＆ Ｍｅｒｏｎｕｃｋ、１９８６年；Ｇｗｉｎｎｅｒら、１９９６年）。Ａ．フミガーティス（ｆｕｍａｇａｔｉｓ）は、汚染食糧を摂食した牛で高レベルの流産を生じ、また、人の肺にも侵入すると報告されている（Ｄａｒｗｉｓｈら、１９９１年；Ｐａｎｄｅｙ ＆ Ｐｒａｓａｄ、１９９３年；Ａｂｕｄら、１９９５年）。 Farm storage difficulties and post-harvest damage are mainly due to the temperature, humidity, respiration, insect infestation of stored contents, due to the lack of oxygen and water vapor permeability of currently used containers. Occurs as a result of the invasion of rodents and fumonisins, mycotoxins, aflatoxins by mold and fungal growth. Whether for human consumption or animal food stock, contamination of stored products poses a serious health risk. Aflatoxin intake by dairy cows varies in the cow's body, but it remains toxic and is detected in milk (Christensen & Meronuck, 1986; Gwinner et al., 1996). A. Fumigatis has been reported to cause high levels of miscarriages in cattle fed contaminated food and also invade human lungs (Darwish et al., 1991; Pandey & Prasad, 1993; Abud et al. 1995).
プラスチックの袋、バッグ貯蔵、プレハブの鉄ホール、及びフレキシブルプラスチックサイロが、短期貯蔵用として農家の間で徐々に普及してきている（Ｐｅｔｅｒｓｏｎ ＆ Ｓｉｍｉｌａ；１９９０年；Ｃｏｍｐｔｏｎら、１９９３年；Ｂａｒｔａｌｉ、１９９４年）。しかし、現在の貯蔵機構のいずれも湿気管理、酸素に対するバリア又は酸素の効果的な透過、及び有効成分の接触放出機構などの包括的な一連の因子に効果的に対処できない。前記接触放出機構は、さらに具体的には、適切に放出されると、限定されないが、昆虫及び／又はげっ歯類忌避性及び／又は湿気管理及び／又は静菌性もしくは殺真菌性特性などの所望の効果を促進するものである。 Plastic bags, bag storage, prefabricated iron halls, and flexible plastic silos are becoming increasingly popular among farmers for short-term storage (Peterson &Simila;1990; Compton et al., 1993; Bartali, 1994) ). However, none of the current storage mechanisms can effectively address a comprehensive set of factors, such as moisture management, effective permeation of oxygen or barrier to oxygen, and contact release mechanisms of active ingredients. The contact release mechanism more specifically, when properly released, includes but is not limited to insect and / or rodent repellency and / or moisture management and / or bacteriostatic or fungicidal properties, etc. It promotes the desired effect.
従って、許容可能な、かつ、ＦＡＯ推奨の貯蔵産物及び乾燥食糧の農場貯蔵用湿気レベルを維持し収穫後の損害の防止と低減を行える最適貯蔵状態を得るための改善された高分子材料への要求が存在する。 Therefore, to an improved polymeric material to achieve an optimal storage condition that maintains acceptable and FAO-recommended stored product and dry food farm moisture levels and prevents and reduces post-harvest damage. A request exists.
加えて、食物容器で使用されるものなどの積層構造物内での殺虫剤又は駆除剤の効果的添加に対する要求が残されている。 In addition, there remains a need for the effective addition of insecticides or pesticides in laminated structures such as those used in food containers.
突起、膜構造、エアポケット、ギャップ、キルティング、ピローイング、３次元的突起状、円錐形、円形ハニカム膜、及び異なる形状、寸法で、積層体内で相互接続された空気通路を備えたポリマー積層体は、様々な用途があり、米国特許第３，１４２，５９９号、「Ｍｅｔｈｏｄ ｆｏｒ Ｍａｋｉｎｇ Ｌａｍｉｎａｔｅｄ Ｃｕｓｈｉｏｎｉｎｇ Ｍａｔｅｒｉａｌ」として１９６８年７月に権利化され、商標が取得されて「バブルラップ」としてよく知られている。製品ラインは、そこから、帯電防止性及び難燃性などの機能特性を示すフィルムを含むまでに拡張された。 Polymer laminates with protrusions, membrane structures, air pockets, gaps, quilting, pillowing, three-dimensional protrusions, cones, circular honeycomb membranes and air passages that are interconnected in the laminate in different shapes and dimensions Has a variety of uses and was patented in July 1968 as U.S. Pat. No. 3,142,599, “Method for Making Laminated Cushioning Material”, and well-known as “bubble wrap” after the trademark was acquired. Yes. The product line was expanded from there to include films that exhibit functional properties such as antistatic properties and flame retardancy.
米国公開特許第２０１００１４３６１４号「Ｈｏｌｉｄａｙ ａｎｄ Ｅｖｅｎｔ Ｂｕｂｂｌｅ Ｗｒａｐ」に記載のようなホリデープリントに関係する祝日紙吹雪やグラフィティの封入用の特許、及び１９９７年２月２１日出願の第８０６２５５号、「Ｓｃｅｎｔｅｄ Ｂｕｂｂｌｅ Ｗｒａｐ」に見られるような祝日又はイベントに因んだバブルラップ用香水に関する特許が存在する。同様に、エアポケットのポケット構造、負荷強度、及び膜厚、バブル寸法と形状、及びエアポケットの相互接続度、空気通路、構造設計、ならびに他の封じ込め単位及び自立型封じ込め単位への組込みにおける差異について詳細に記載した複数の特許も存在する。 Patents for the inclusion of holiday confetti and graffiti related to holiday prints, such as those described in US Patent Publication No. 20130014314 “Holiday and Event Bubble Wrap”, and No. 806255, “Scented Bubble” filed on Feb. 21, 1997. There are patents relating to bubble wrap perfumes due to holidays or events such as those found in Wrap. Similarly, differences in the pocket structure of air pockets, load strength and film thickness, bubble size and shape, and air pocket interconnectivity, air passages, structural design, and integration into other containment units and self-contained containment units There are also a number of patents that describe in detail.
前述の特許は、参照により本明細書に組み込まれる。 The aforementioned patents are incorporated herein by reference.
しかし、限定されないが、貯蔵産物条件に関連する困難に対処する目的のための化学の、無機及び／又は有機材料、及び／又はあらゆる天然もしくは合成材料の誘導体の混合物及び組み合わせの、蒸気、液体、油、フェロモン、ゲル、ヒドロゲル、ガス、もしくはガス状成分、固形物、ワックス、粉末もしくはあらゆる寸法の粒子、などのいかなる状態の有効成分をも含む物質を放出するための接触放出機構としてポケットを使用する先行技術は存在しない。 However, without limitation, vapors, liquids, mixtures and combinations of chemical, inorganic and / or organic materials and / or derivatives of any natural or synthetic material for the purpose of addressing difficulties associated with storage product conditions Use pockets as a contact release mechanism to release substances containing active ingredients in any state, such as oils, pheromones, gels, hydrogels, gases or gaseous components, solids, waxes, powders or particles of any size There is no prior art to do.
接触放出機構を示すバリア層又は代替積層基材を有する場合又は有さない場合のこのような積層体を、収穫穀物、トウモロコシ、ササゲ豆、及び貯蔵生牧草などの農産物等の貯蔵に使用し、それにより、このような積層体が、害虫、げっ歯類、及び昆虫に対する機械的なバリアとして機能し、同時に、空気緩衝膜中に含まれる食品に安全な有効成分の放出を可能とする接触圧力の結果としての温度と湿度の変化の影響、貯蔵産物蒸散と湿気の管理を軽減できる。 Such laminates with or without a barrier layer or alternative laminate substrate exhibiting a contact release mechanism are used to store crops, corn, cowpeas, and agricultural products such as stored fresh grass, etc. Thereby, such a laminate acts as a mechanical barrier against pests, rodents, and insects, and at the same time, enables the release of active ingredients safe for food contained in the air buffer membrane. As a result, the effects of temperature and humidity changes, storage product transpiration and moisture management can be reduced.
農場での乾燥食糧品（例えば、穀物やトウモロコシ）の貯蔵に伴って容器の最内層に隣接する穀物の表面層中の水の進入とその後の湿気蓄積及び外部温度と湿度の内部貯蔵産物雰囲気に対する影響などのいくつかの付随する問題が存在する。これらの条件が、カビ、真菌、及び細菌汚染を作りだし、アフラトキシン、マイコトキシン、フモニシンなどの毒素を生成する。 With the storage of dry food items (eg cereals and corn) on the farm, water ingress in the surface layer of the grain adjacent to the innermost layer of the container and subsequent moisture accumulation and internal storage product atmosphere of external temperature and humidity There are several accompanying issues such as impact. These conditions create mold, fungi, and bacterial contamination and produce toxins such as aflatoxins, mycotoxins, fumonisins.
刈り取って束ねた農産物用の自立型貯蔵設備は、昆虫やげっ歯類の侵入を受けやすい。昆虫侵入は、昆虫の呼吸、***物、及び伝染ならびに貯蔵産物中を移動する間のカビ、真菌、及び細菌性生殖細胞の追加の分布によりカビの増殖及び菌類増殖を悪化させる可能性がある。従って、両方の侵入を防ぐか、又は減らし、菌類増殖を防ぐための湿気の伝搬を管理する農場での貯蔵容器を提供することは有益である。菌類増殖を抑えるために、容器は、相補的水蒸気拡散を許容するようにある程度の酸素透過性を維持するか、又は、密封手法の一要素として本明細書で詳述の新規基材を使用してある種の密封貯蔵を維持し、それにより、ポリマー層が湿気を維持するか、又は許容可能なレベルの外部温度と内部温度との間の差異及び相対湿度を得て、湿気の蓄積及びそれに関連する影響、例えば、集中化した湿気による高温部及び食糧品分解領域の形成を防ぐように機能するべきである。 Free-standing storage facilities for harvested and bundled agricultural products are susceptible to insects and rodents. Insect infestation can exacerbate mold growth and fungal growth due to insect respiration, excretion, and transmission, and the additional distribution of mold, fungi, and bacterial germ cells while traveling through storage products. Therefore, it would be beneficial to provide a storage container on the farm that manages the propagation of moisture to prevent or reduce both intrusions and prevent fungal growth. To control fungal growth, the container maintains some oxygen permeability to allow complementary water vapor diffusion or uses the new substrate detailed herein as part of the sealing procedure. Maintain some sort of sealed storage, so that the polymer layer maintains moisture or obtains an acceptable level of difference between external and internal temperature and relative humidity, and accumulates moisture and It should function to prevent associated effects, such as the formation of hot areas and food product degradation areas due to concentrated moisture.
これらの目的に即したこのタイプの高分子材料の調製において、人又は動物の摂取を目的とした食糧品用として貯蔵時のＦＡＯにより推奨された湿分含量に関する貯蔵条件パラメータを観察している対象の貯蔵産物に対する異なった種分化の昆虫及び／又はげっ歯類集団の侵入、ならびに真菌、細菌性及びカビ増殖を組み合わせた有害作用を管理する試みを行った先行技術には、欠陥があった。 In the preparation of this type of polymeric material for these purposes, subjects observing storage condition parameters related to moisture content recommended by FAO during storage for foodstuffs intended for human or animal consumption Prior art that attempted to manage the invasion of differently differentiated insect and / or rodent populations and the combined adverse effects of fungal, bacterial and fungal growth on the stocks of these products was deficient.
空気緩衝型の、空洞のある、キルト風の、突起があり、非平滑化された、又はあらゆるタイプの３次元ポリマー材料の調製では、有効成分、成分、又はこれらの組み合わせの接触放出制御（ｃｏｎｔｒｏｌｌｅｄ−ｂｙ−ｃｏｎｔａｃｔ ｒｅｌｅａｓｅ）のために、より具体的には、採用された場合には、貯蔵産物、より具体的には乾燥食糧品の保護に最適な条件を促進するという所望の効果を有する有効成分の制御放出のために、バブル又は突起部に穿通した結果として所望の効果を促進する目的で有効成分を封入する先行技術では、欠陥があった。 In the preparation of air-buffered, hollow, quilted, protrusive, non-smoothed or any type of three-dimensional polymeric material, contact controlled release of the active ingredients, ingredients, or combinations thereof. -By-contact release), more specifically, when employed, effective with the desired effect of promoting optimal conditions for the protection of stored products, more specifically dry food products Due to the controlled release of ingredients, prior art that encapsulates active ingredients for the purpose of promoting the desired effect as a result of penetrating bubbles or protrusions has been flawed.
従って、本発明の目的は、穿通接触による有効成分放出の時点で、放出の間に、又は放出の結果として、有効成分の目的の効果を与えるように、接触時に放出される有効成分を組み込むか、封入するか、又は他の方法で含む新規ポリマー積層体を提供することである。 Accordingly, the object of the present invention is to incorporate an active ingredient that is released upon contact so as to give the desired effect of the active ingredient at the time of release of the active ingredient by the penetrating contact, during or as a result of the release. Providing a new polymer laminate that is encapsulated or otherwise contained.
本発明は、単独でインサートとして又は組み込みにより、コーティングにより、積層により、注入により、共押し出しにより、もしくは、何らかの方法で有効成分を含む高分子フィルムと組み合わせて穿通による放出の目的で使用される、有効成分又は生理活性の物質又はその成分を封入するか、又は他の方法で含み、所望の効果を促進するか、又は促進に寄与する異なる目的のために、下記の内の１つ又は下記の組み合わせを提供する空気緩衝型フィルムの使用を特徴とする：湿気管理、酸素透過性、水蒸気透過性、天然又は合成の真菌、細菌性、及びカビ増殖阻害剤、又はあらゆる性質の捕捉剤、及びあらゆる性質と種類又は系列の殺虫剤で、限定されないが、昆虫滅菌法、興奮毒、乾燥剤、フェロモン、誘引剤、香気、及びあらゆる性質のげっ歯類忌避剤、ならびにＵＶ遮断薬、又は安定剤、色素、又はあらゆる性質の添加物などの材料特性に寄与するか、又は関係する添加物。 The present invention is used for the purpose of release by penetration alone or as an insert, by incorporation, by coating, by lamination, by injection, by coextrusion, or in any way in combination with a polymer film containing the active ingredient, For different purposes encapsulating or otherwise including the active ingredient or bioactive substance or its ingredient to promote or contribute to the desired effect, one of the following or Characterized by the use of an air-buffered film to provide a combination: moisture management, oxygen permeability, water vapor permeability, natural or synthetic fungal, bacterial, and fungal growth inhibitors, or any property scavenger, and any Nature and type or family of insecticides, including but not limited to insect sterilization, excitotoxins, desiccants, pheromones, attractants, aromas, and any sex Rodent repellents and UV blockers, or stabilizers, dyes, or contribute to the material properties of such additives of any nature, or related additives that.
本発明は、突起部の穿通により接触時に放出される有効成分を封入した、多層構造、積層体、共押出フィルム又は基材及び／又は空気緩衝フィルム、及び／又は突起を有し、キルト風の又はポケットのある構造又はあらゆる特性の特殊加工基材を有する３次元フィルムを含む。このような積層体は、フィルムとして単独で、ライナー、インサート、特殊留置ストリップ、又は既存の貯蔵機構に対する追加の成分として、１種又は複数種のポリマー層を組み合わせた又は収穫穀物、トウモロコシ、サイレージ、及び供給原料、などの人もしくは動物の摂取用の農産物などの貯蔵のために前記を含む容器として製造された多次元積層体として使用できる。さらに、本発明は、農場での貯蔵を許容する期間食糧品を貯蔵し、最終的にその後のタイムリーな市場アプローチに関連して経済的利益を高める方法を含む。 The present invention has a multilayer structure, a laminate, a coextruded film or substrate and / or an air cushion film, and / or a protrusion, in which an active ingredient released upon contact by the penetration of the protrusion is enclosed. Or a three-dimensional film having a pocketed structure or a specially processed substrate of any characteristic. Such laminates can be used alone as a film, combined with one or more polymer layers as liners, inserts, special indwelling strips, or additional components to existing storage mechanisms, or harvested grains, corn, silage, And can be used as a multi-dimensional laminate manufactured as a container containing the above for storage of agricultural products for human or animal consumption such as feedstock. Furthermore, the present invention includes a method of storing food items for a period that allows storage on the farm and ultimately increasing economic benefits in connection with subsequent timely market approaches.
本発明の別の態様では、所与の大きさの形状の昆虫を一定量の殺虫剤と接触するように構成されたポリマー積層体は、少なくとも１種の殺虫剤を含むバブルを含むバブルプラスチック熱可塑性ポリマー材料層を含む最内層を含み、バブルはその近辺の昆虫の動きを阻止するように構成された形状とバブル間距離を有する。バブルは内側に向いていても、外側に向いていてもよく、二重層として組み込まれても良い。 In another aspect of the invention, a polymer laminate configured to contact an insect of a given size with an amount of insecticide comprises a bubble plastic heat comprising a bubble comprising at least one insecticide. Including an innermost layer that includes a layer of plastic polymeric material, the bubble has a shape and an inter-bubble distance configured to prevent movement of insects in the vicinity thereof. The bubble may be inward or outward and may be incorporated as a double layer.
この関連で、形、大きさ、及び／又はバブル間距離は、昆虫のバブル周辺の動きを阻止するように、昆虫がバブルからかじる距離以内にいる滞在時間を相対的に増やすように、選択できることが明らかになった。多くの穿孔性害虫は、近くの物質をかじる又は穴を開けることを続けるので、標的昆虫の物理的寸法に基づいて昆虫が空間環境を進むのをより困難にするようにこれらのパラメータを調節するのが望ましい。 In this regard, the shape, size, and / or distance between the bubbles can be selected to relatively increase the residence time within which the insects are gnawed from the bubble so as to prevent movement around the insect bubble. Became clear. Many perforating pests continue to gnaw or pierce nearby material, so adjust these parameters to make it more difficult for insects to navigate the spatial environment based on the physical dimensions of the target insect Is desirable.
好ましい実施形態では、殺虫剤は粉末形態であり、好ましくは珪藻土及び角皮乾燥剤からなる群から選択される物質を含む。 In a preferred embodiment, the insecticide is in powder form and preferably comprises a material selected from the group consisting of diatomaceous earth and keratin desiccant.
また、バブルプラスチック熱可塑性ポリマー材料の熱可塑性樹脂バブルの破裂強度は、昆虫が少なくとも１種の殺虫剤に曝露されるように、昆虫が熱可塑性樹脂バブルを破裂させることができるのが好ましい。バブル層は昆虫がかじる、穴を開ける又は別の方法で突き刺すことを可能とするように設計されたいずれかの好適なポリマー材料で作製できるが、バブルプラスチック熱可塑性ポリマー材料は、ＬＤＰＥ、ＬＬＤＰＥ、ＶＬＤＰＥからなる群から選択されるポリマーを含むのが好ましく、また、その他の熱可塑性ポリマー群の内の１種又は複数種を含んでもよい。 Also, the burst strength of the thermoplastic bubble of the bubble plastic thermoplastic polymer material is preferably such that the insect can burst the thermoplastic bubble so that the insect is exposed to at least one insecticide. The bubble layer can be made of any suitable polymer material designed to allow insects to bite, puncture or otherwise pierce, but bubble plastic thermoplastic polymer materials include LDPE, LLDPE, It is preferable to include a polymer selected from the group consisting of VLDPE, and it may also include one or more of the other thermoplastic polymer groups.
多機能特性を示す能力を備えた新規ポリマー積層体を提供し、同時に、フィルムの機械的なバリアの有効性に直接に寄与する以下の種々の新規及び相互接続パラメータの発見をもたらす様々な種分化及び／又は多様な侵入及び／又は不規則な昆虫挙動を考慮した結果として、昆虫と貯蔵食品の種類に無差別に攻撃する害虫と昆虫に対する効果的バリアを提供することも本発明のさらなる目的である：フィルムの突起状エアポケットの中間の窪んだ溝の深さと幅、下顎の位置決め及び／又は摂食モード、下顎強度と口器構造、脚の幅、突き刺し能力、移動度、柔軟性と機動性、しっかり付いて離れない力、及び引っ掻き、穿孔などの非平滑化された基材と昆虫との全体的相互作用、ならびに、限定されないが異なった穿通技術と方法による突起部の穿通速度とその後の有効成分放出速度、及び昆虫の体の寸法に対応する容積、下顎位置決めと昆虫寸法に起因する異なる形状に対する穿通性の差異、及びそれによる機動性、及び本明細書で記載の構成や性質と異なる有効成分放出前の初期のバリアとして作用するその他の機械的性質を含む穿通の影響。 Various speciations that provide new polymer laminates with the ability to exhibit multi-functional properties, while at the same time finding the various new and interconnect parameters that directly contribute to the effectiveness of the mechanical barrier of the film It is a further object of the present invention to provide an effective barrier against insects and insects that indiscriminately attacks insect and stored food types as a result of considering various invasions and / or irregular insect behavior. There are: depth and width of the recessed groove in the middle of the projecting air pocket of the film, positioning and / or feeding mode of the lower jaw, strength and mouth structure of the lower jaw, leg width, piercing ability, mobility, flexibility and mobility Sex, firm and unseparable forces, and the overall interaction of the insect with non-smooth substrates such as scratches, perforations, and protrusions, but not limited to, different penetration techniques and methods Penetration rate and subsequent active ingredient release rate, and volume corresponding to insect body dimensions, mandible positioning and penetration differences for different shapes due to insect dimensions, and maneuverability thereby, and described herein Penetration effects including other mechanical properties that act as an initial barrier prior to active ingredient release that differ from the composition and properties of
特に、侵入モード時に、くっついて離れず、それを持続するという昆虫の生来の挙動が積層体に組み込まれた殺虫剤又は駆除剤への捕捉と曝露を生じさせ、最終的に単一の小室化エアポケット中で窒息させる昆虫に対して、有効成分の放出直前に、放出時に、放出中に、又は放出直後に昆虫の機動性を変える及び／又は妨害するためのあらゆる捕捉及び／又は反応方法を提供することは、本発明のさらなる目的の一変形例である。 In particular, during the intrusion mode, the insect's natural behavior of sticking to and sustaining it results in capture and exposure to pesticides or pesticides embedded in the laminate, ultimately resulting in a single chamber For insects to be suffocated in air pockets, any capture and / or reaction methods to alter and / or interfere with insect mobility immediately before, during, during or immediately after release of the active ingredient Providing is a variant of a further object of the present invention.
いくつかの実施形態で、穿通により接触時に放出される多様な１種又は複数種の有効成分の封入を可能とすることは、さらなる本発明の別の目的の別の変形例である。これは、フィルムが効果的に利用される気候と既存の貯蔵条件及び環境中に存在する昆虫種分化に応じて、可能である場合も、そうでない場合もあるが、１つのエアポケット中に複数有効成分の添加、又は１つのフィルムが単一の有効成分を封入した複数のエアポケットを含むことができるか、又は選択されたエアポケットが複数の有効成分を含むことができ、同時に、その他のエアポケットが有効成分を含まないように、代替単一有効成分もしくは異なる有効成分の組み合わせを含むことができるエアポケットになお近接近又は隣接して配置された単一の有効成分を含む単一のエアポケットを必要とする。 In some embodiments, allowing the inclusion of various active ingredient (s) released upon contact by penetration is another variation of another object of the present invention. This may or may not be possible depending on the climate in which the film is effectively utilized and the existing storage conditions and insect species differentiation present in the environment, but it may be multiple in one air pocket. Addition of active ingredients, or one film can contain multiple air pockets encapsulating a single active ingredient, or selected air pockets can contain multiple active ingredients, while other A single containing a single active ingredient that is placed in close proximity or adjacent to an air pocket that may contain alternative single active ingredients or a combination of different active ingredients such that the air pocket does not contain any active ingredients Need an air pocket.
放出時に有効性を高めるために、空気通路の相互接続によって所定の方式で又は正確な位置に有効成分を分配できるように、所望に応じて配列中のエアポケットの昆虫特異的形状、容積、高さ、及び戦略的位置決めを提供することは、本発明の別の目的の別のさらなる実施形態である。前述その他の Insect-specific shape, volume, and height of the air pockets in the array as desired so that the active ingredient can be distributed in a predetermined manner or at a precise location by air passage interconnections to increase effectiveness upon release. And providing strategic positioning is another further embodiment of another object of the present invention. Other mentioned above
放出時混合能力を提供し、それにより、１種の有効成分を含むエアポケット及び代替成分を含むエアポケットが、このような結果を所望する場合に、空気通路を介して相互接続され、同時穿通を可能とし、それにより、放出時に別の有効成分が混合されるのは、本発明のさらに別の目的である。 Provides a mixing capability on discharge, whereby an air pocket containing one active ingredient and an air pocket containing an alternative ingredient are interconnected via an air passage when such a result is desired, and simultaneous penetration It is yet another object of the present invention that allows another active ingredient to be mixed upon release.
本発明のフィルム及び本明細書で記載の少し変形例のフィルムは、穀物又は食品貯蔵倉庫フロア用途、天井又は地役権のカバリング、又は住宅建築内の侵入を緩和し、同時に断熱を得るための使用などの穀物貯蔵設備のような建築用途で有益な使い方を見つけることもできる。 Films of the present invention and slightly modified films described herein are intended to mitigate intrusion in grain or food storage warehouse flooring applications, ceiling or easement coverage, or residential construction while simultaneously obtaining thermal insulation. You can also find useful uses in architectural applications such as grain storage facilities.
また、本発明の関連実施形態には、限定されないが、下記を含む特性を示す代替有効成分又は有効成分の組み合わせを使って、穴をあける木材害虫及びその他の樹病のバリア用に木の幹周辺で効果的に利用できるラップとして使用される高分子フィルムを含むことができる：忌避性、滅菌、増殖調節剤、接触致死剤、角皮乾燥剤、育成剤もしくは他のタイプの有効成分又は天然もしくは合成又は特定の適応性及び有効性のために、ベクター株、種分化、昆虫挙動、耐性、生殖作用、作用モード、ならびに、環境条件及び適用要件に耐える材料特性として必要な修正などを考慮して、機械的もしくは化学的に操作されたあらゆる混合物もしくは組み合わせ。 Also, related embodiments of the present invention include, but are not limited to, tree trunks for use as barriers for wood pests and other tree diseases that are drilled using alternative active ingredients or combinations of active ingredients that exhibit properties including: Can include polymeric films used as wraps that can be effectively utilized in the surroundings: repellent, sterilization, growth regulators, contact lethals, cuticle desiccants, growth agents or other types of active ingredients or natural Or consider vector strains, speciation, insect behavior, tolerance, reproductive action, mode of action, and modifications necessary as material properties to withstand environmental conditions and application requirements for synthesis or specific adaptability and effectiveness. Any mixture or combination that has been mechanically or chemically manipulated.
本発明の別の関連する実施形態は、限定されないが、肥料、農業資材、駆除剤、除草剤、及び／又は他の有効成分を含む接触放出用の有効成分を添加した高分子フィルム基材であってよく、それにより有効成分の直接放出が、限定されないが土壌の質などの所望の結果を高めるか、又は何らかの形で所望の結果を付与し、植物の栄養素取込み又は接触放出に有益な他の性質を高める。このようなフィルムは集水装置又は保護カバリングとしてフィルムを土壌の下に使用できる。 Another related embodiment of the present invention is a polymeric film substrate with the addition of active ingredients for contact release including, but not limited to, fertilizers, agricultural materials, pesticides, herbicides, and / or other active ingredients. Others where direct release of the active ingredient may enhance desired results such as, but not limited to, soil quality, or provide some form of desired results, beneficial for plant nutrient uptake or contact release Enhance the nature of. Such films can be used under soil as a water collector or protective covering.
本発明の高分子基材及びこれらの組み合わせは、共押出、共押出吹込フィルム、西洋ナシ形の吹込フィルム、特殊加工ジオメンブレンフィルム押出成形、熱成形、真空成形、空洞充填成形（ｖｏｉｄ ｆｉｌｌ ｆｏｒｍｉｎｇ）、フィルム押出、フィルム積層形成、幅出し機によるコーティング、飽和成形、噴霧、パウダー散布、熱ロールプレス、又は組み込み、含浸、又は注入の他の手段により作製でき、それにより、最終製品の有効性を高めるために、所望に応じて、ラミネート基材は、限定されないが、熱定着、熱点接着、シート接着、基材に接着させることを意図した当業者に既知のコーティング機構及び／又は他のコーティング機構による静電接着、及び／又は熱シーミング、熱エンボス加工、カレンダー加工、幅出し機固定、及び／又は当該技術分野において既知で、使用されている本明細書で記載されなかった接着方法などのあらゆるタイプの接着を含むさらなる製造プロセスに供される。 The polymeric substrate of the present invention and combinations thereof can be co-extruded, co-extruded blown film, pear-shaped blown film, specially processed geomembrane film extrusion, thermoforming, vacuum forming, void filling forming. , Film extrusion, film lamination, coating with tenter, saturation molding, spraying, powder spreading, hot roll press, or other means of incorporation, impregnation, or injection, thereby increasing the effectiveness of the final product To enhance, as desired, the laminate substrate may be, but is not limited to, thermal fusing, hot spot bonding, sheet bonding, coating mechanisms and / or other coatings known to those skilled in the art intended to bond to the substrate. Electrostatic bonding and / or thermal seaming, thermal embossing, calendering, tenter fixing, It is known / or in the art, is subjected to further manufacturing processes including adhesion of all types, such as bonding methods have not been described herein in use.
環境条件に応じて別の積層体を使うことができ、また、このような環境又は経費検討を考慮して、さらなる接合又は積層形成を行うことができる。 Different laminates can be used depending on environmental conditions, and further bonding or lamination can be performed in view of such environmental or cost considerations.
代替物固定方法を利用した別の製品には、粘着物、接着剤、もしくはその他のエポキシ、樹脂、又はこれらの混合物又はシール形成に適する及びあらゆる寸法の１つの積層基材のいずれかの部分及び／又はシートを別のものに固定するのを目的とする他の物質の使用を挙げることができる。粘着物、接着剤、エポキシ、及び／又は樹脂又は本明細書で記載されない基材を固定するその他の物質のこのような配置位置は、製造後のバッグ状構造又は型封じ込め装置の消費者による組み立て方法として後で使用するために、製造中に、縁部に置くことができる。 Other products utilizing alternative fixing methods include any part of one laminated substrate suitable for adhesives, adhesives, or other epoxies, resins, or mixtures or seals thereof and of any size and And / or the use of other substances intended to fix the sheet to another. Such placement of adhesives, adhesives, epoxies, and / or resins or other materials that secure substrates not described herein is the assembly by the consumer of the bag-like structure or mold containment device after manufacture. It can be placed on the edge during manufacture for later use as a method.
エアポケット内への有効成分添加のために採用される方法は、有効成分が、粉末、液体、ゲル、又はそれぞれのフローレートや他の物理的及び化学の性質などが何であってもそのほかの物質のいずれであっても、有効成分の組成、粘度、熱指数、及びその他の性質に依存し、有効成分のこのような添加は、好ましくは、フィルム製造の非常に重要な段階で行われる必要がある。この段階は、ホットメルトプラスチックシートが所望のくぼみ及び寸法に合致し、穿孔ローラーから剥離後ホットプラスチック中に有効成分を完全には包埋しないように適切な温度で十分に冷却が加えられているが、有効成分を突起部と平坦積層体との間で浮遊させるように第２のシートを置き、それにより、穿通時に突起部から放出されるために十分な手法で有効成分を囲い込んで封入するか、又は他の方法で含有させるプロセスに移行する前の段階である。 The method used to add the active ingredient into the air pocket is that the active ingredient is a powder, liquid, gel, or any other substance, whatever its flow rate or other physical and chemical properties. Depending on the composition, viscosity, thermal index, and other properties of the active ingredient, such addition of the active ingredient should preferably take place at a very important stage of film production. is there. This stage is sufficiently cooled at an appropriate temperature so that the hot melt plastic sheet meets the desired indentation and dimensions and does not completely embed the active ingredient in the hot plastic after peeling from the perforation roller. However, the second sheet is placed so that the active ingredient is suspended between the protrusion and the flat laminate, thereby enclosing and enclosing the active ingredient in a manner sufficient to be released from the protrusion during penetration. This is the stage prior to the transition to a process for inclusion or other methods.
この技術に適する計量分配機構は、所望の有効成分添加量の正確さ及び／又は配置精度及び最終製品としての価格的な対応可能性に基づいて、単純から複雑の範囲まで包含することができる。有効成分を精密にかつ正確に添加する、医薬品業界でよく使われるような自動化オーバーヘッドマウント重力測定計量分配装置、ならびに、インラインスプレーコーティング、湿式又は乾式粉末コーティング及びその他の高精度の計量分配装置は、最も好ましくは有効成分が液体、ゲル、又は乾燥粉又は粒子以外の形態である場合に使用される本発明のいくつかの変形例としての効果的製造装置の例である。しかし、発展途上経済の収穫後損害の軽減を目的とする価格的に入手可能な解を提供するためには、このような高精度充填機構は最も効果的な製造方法ではないであろう。 Appropriate dispensing mechanisms for this technology can range from simple to complex ranges based on the accuracy and / or placement accuracy of the desired active ingredient additions and the price availability as the final product. Automated overhead-mount gravity metering and dispensing devices, such as those commonly used in the pharmaceutical industry, to accurately and accurately add active ingredients, as well as in-line spray coating, wet or dry powder coating and other high precision dispensing devices, Most preferably, it is an example of an effective production device as some variant of the invention used when the active ingredient is in a form other than liquid, gel, or dry powder or particles. However, such a high-precision filling mechanism may not be the most effective manufacturing method in order to provide a cost-effective solution aimed at reducing post-harvest damage in developing economies.
バブルフィルムのエアポケット内の有効成分の計量分配のための製造コスト、従って最終製品コストを下げる好ましい方法では、金属ドラムローラーセット、最も好ましくは、帯電防止コーティング又は前処理をしてあってもよい粘着しない金属、及び最も好ましくは、穿孔とメッシュを備えたローラーセットを採用する。それにより、このようなドラムローラーセットは、他のローラーセットと交換可能とする機械骨組みに筋交い溶接で取り付けた計量分配装置として使用するように設計され、最も好ましくは、穿孔真空吸引ローラーの後ろに配置され、更により好ましくは、計量分配ドラムローラーセットに送られる前に、突起を十分に冷却するように配置された冷却装置の直後に配置され、最も好ましくは、１つは外側、１つは内側の２つのドラムを含み、最も好ましくは、外側金属ドラムが放出される粉末及び／又は粒子の大きさに対し十分大きな直径、形状、寸法の穿孔を備え、最も好ましくは、円形形状であり、それによって、外側ドラムに対する有効成分の分配器として作用する内側ドラムが取り付けられるが、まだ、独立に回転し、さらに、最も好ましくは、内部ドラムを外側ドラムと反対に回転させるように取り付けられ、内側ドラムは、最も好ましくは、回転時に粉末又は粒子を濾過し、均一混合と分布を可能とするように、より小さいメッシュサイズを有する。 In a preferred way of reducing the manufacturing costs for dispensing active ingredients in the air pockets of the bubble film and thus the final product cost, a metal drum roller set, most preferably an antistatic coating or pre-treatment may be provided. A non-stick metal and most preferably a roller set with perforations and mesh is employed. Thereby, such a drum roller set is designed to be used as a dispensing device attached by bracing to a mechanical framework that can be exchanged with other roller sets, most preferably behind a perforated vacuum suction roller Arranged, even more preferably, immediately after a cooling device arranged to sufficiently cool the protrusions before being sent to the dispensing drum roller set, most preferably one is outside and one is Comprising two inner drums, most preferably the outer metal drum is provided with perforations of a diameter, shape and dimensions that are large enough for the size of the powder and / or particles to be discharged, most preferably circular in shape; Thereby, an inner drum is attached which acts as a distributor of the active ingredient to the outer drum, but still rotates independently and most Preferably, the inner drum is mounted to rotate counter to the outer drum, and the inner drum is most preferably a smaller mesh to filter powder or particles during rotation, allowing for uniform mixing and distribution. Have a size.
粉末又は粒子寸法に応じて、添加は、内側ドラムに取り付けた自動重力測定及び／又は加圧ポンプ装置から行うことができ、穿孔中央管を通して有効成分の定量を内側ドラム中へ分配し、それにより、加圧で粉末及び／又は粒子を有効成分を放出する穿孔を通して内側ドラムに送り込む。逆方向回転の間に、両ドラムの間の孔及び／又はメッシュアパーチャの配列を通して、外側ドラムは、最終的に、有効成分をエアポケット中に放出する。 Depending on the powder or particle size, the addition can be made from an automatic gravity measurement and / or a pressure pump device attached to the inner drum, which distributes a quantity of active ingredient into the inner drum through the perforated central tube, thereby , Under pressure, powder and / or particles are fed into the inner drum through perforations that release the active ingredient. During reverse rotation, through the arrangement of holes and / or mesh apertures between both drums, the outer drum eventually releases the active ingredient into the air pocket.
複数の有効成分を計量分配するための別の製造方法は、１つの中央ホッパー及び外部供給装置を通して一緒に添加された複数の有効成分を含むことができ、及び／又は外部計量分配装置が複数の有効成分を含む分割ホッパーを備えて、別々のそれぞれのチャンバ中に複数の有効成分を分配する分離機構により、それぞれのホースを通って有効成分が堆積した内側ドラム内の分離された穿孔管に圧送して内側ドラムの分離されたチャンバ中に送り、逆回転中に両ドラム間の孔及び／又はメッシュの配列を通って有効成分が放出される。さらに広い幅のフィルムを製造するより大規模産業に対しては、有効成分の均一分布のために、有効成分の移動距離を短くする目的でドラムの両側に配置した２つの別の外部計量分配装置を備えて、添加工程下のフィルムの滞留時間を減らすようにエア供給と製造速度を効率よく利用するのが最も好ましい。このような計量分配装置の２重配置はまた、有効成分のさらなる差別化及び／又は多様化を可能とする。 Another manufacturing method for dispensing a plurality of active ingredients may include a plurality of active ingredients added together through one central hopper and an external feeder and / or a plurality of external dispensers A separation mechanism that includes a split hopper containing the active ingredients and distributes multiple active ingredients in separate chambers, and pumps them through each hose to a separate perforated tube in the inner drum where the active ingredients are deposited. It is then fed into a separate chamber of the inner drum and the active ingredient is released through an array of holes and / or mesh between the two drums during reverse rotation. For larger industries that produce wider films, two separate external dispensing devices located on both sides of the drum for the purpose of shortening the distance traveled by the active ingredient for a uniform distribution of the active ingredient It is most preferable to efficiently use the air supply and the production rate so as to reduce the residence time of the film under the addition step. Such a double arrangement of the dispensing devices also allows further differentiation and / or diversification of the active ingredients.
コストを意識して考慮した分離方式で添加される複数の有効成分を提供する別の製造法は、所望の割り付け量の分配により内側ドラムが分離され、マニュアルで供給される分割チャンバが生成される機構を含むことができる。 Another manufacturing method that provides a plurality of active ingredients added in a cost-sensitive separation manner, separates the inner drum by dispensing the desired amount of allocation, creating a manually fed split chamber A mechanism can be included.
分離方式で添加される複数の有効成分を提供する別の製造法は、分割された内側ドラム内のチャンバ当たりの所望有効成分のマニュアル充填を含むことができる。 Another manufacturing method that provides a plurality of active ingredients that are added in a separate manner can include manual filling of the desired active ingredients per chamber in a divided inner drum.
ドラムのチャンバの分割と分離は、水平又は垂直方式で行い、任意の単一の、及び／又は複数の有効成分、及び／又は有効成分の混合物を含めてこれを添加することにより、目的のパターンの有効成分添加を行うことができる。 The drum chamber can be divided and separated in a horizontal or vertical manner, including any single and / or multiple active ingredients, and / or mixtures of active ingredients, thereby adding the desired pattern. The active ingredient can be added.
添加環境が必要とする場合には、ポリマー積層体及び空気緩衝型積層体の一部が異なる又は組み合わせた有効成分を含み、異なる又は全体的性質を積層体の異なる部分に付与することができる。これは、設計上の特徴、例えば、限定されないが、エアポケット寸法、構造、異なる配置のポケット又はキルティング形状を含んでもよく、また、種々の産業で一般に使われる相互接続空気通路又は美しさ、例えば、カラーフィルムパッケージング、又は種々の性質のブランド識別又は絵文字表現又は画像又は設計の印刷及びラミネート加工などの他のカラー及びテキスト関連物を含んでもよく、それによって、このような特定領域の印刷は、異なる活性の組み合わせを１つの基材上に提供するように、有効成分を含むインク、塗料、溶剤、積層体、及び／又は接着剤を使って行うことができる。 If the additive environment requires, some of the polymer laminate and air-buffered laminate may contain different or combined active ingredients to impart different or overall properties to different portions of the laminate. This may include design features such as, but not limited to, air pocket dimensions, structure, differently arranged pockets or quilted shapes, and interconnect air passages or aesthetics commonly used in various industries, such as , Color film packaging, or other color and text related items such as brand identification or pictographic representations of various properties or printing or laminating images or designs, whereby printing of such specific areas It can be done with inks, paints, solvents, laminates, and / or adhesives containing active ingredients to provide different active combinations on one substrate.
さらなる好ましい実施形態では、ポリマー積層体は、該寸法形状の昆虫を保持するようにメッシュ材料を通る昆虫の部分的な通過を許容する十分な大きさの開口部を備えたメッシュ材料に隣接して配置されたメッシュ材料層をさらに含む。メッシュ材料を通る昆虫の部分的な通過のみを許容することにより最内層とメッシュ材料層との間に該寸法形状の昆虫を保持するように、最内層とメッシュ材料層との間の層間距離が昆虫の長さよりも小さいことが好ましい。 In a further preferred embodiment, the polymer laminate is adjacent to the mesh material with an opening large enough to allow partial passage of the insect through the mesh material to retain the size-shaped insect. It further includes a disposed mesh material layer. The interlayer distance between the innermost layer and the mesh material layer is such that only a partial passage of insects through the mesh material is allowed to keep the insect of that size shape between the innermost layer and the mesh material layer. It is preferably smaller than the length of the insect.
ポリマー積層体は、本発明の態様と矛盾しないいずれの特徴及び本明細書の別のところで記載の層を組み込んでもよい。任意選択で、ポリマー積層体は、少なくとも１種の紫外線遮断物質を含む熱可塑性ポリマー材料を含む最外層をさらに含んでもよい。また、超吸収ポリマーを含むバイオ複合材料吸収剤層及び活性「竹」炭と相溶化剤を含むバイオ複合材料相溶化剤層を含んでもよい。同様に、さらに、熱可塑性ポリマー材料、げっ歯類忌避物質及びエチルビニルアセテートを含むげっ歯類忌避剤中間層をさらに含む。また、エチレンビニルアルコールとＥＭＭＡ無機／有機添加物を含む酸素バリア中間層を組み込んでもよい。例えば、ポリマー積層体は、（ａ）少なくとも１種のげっ歯類忌避物質と紫外線遮断物質を含む織物熱可塑性ポリマー材料、及び少なくとも１種の駆除剤及び／又は殺虫剤を含む層を含む最外層と、（ｂ）食品等級ポリマーと接着剤を含む最内層と、最外層と最内層との間に挿入される次の層：少なくとも１種の超吸収ポリマーと活性炭を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層とをさらに含んでもよい。バイオ複合材料層は、少なくとも１種の超吸収ポリマーを含むＨＤＰＥメッシュ、及びバイオ複合材料と活性竹炭を含むＨＤＰＥメッシュを含む第２層から構成されてもよい。ポリマー積層体は、（ａ）少なくとも１種のげっ歯類忌避物質を含む熱可塑性ポリマー材料を含む最外層と、（ｂ）食品等級ポリマーと接着剤を含む最内層と、最外層と最内層との間に挿入される次の層：（１）織物熱可塑性ポリマー材料、（２）本明細書で記載の少なくとも１種の殺虫剤を含むバブルを含むバブルプラスチック熱可塑性ポリマー材料層、及び（３）少なくとも１種の超吸収ポリマーと活性炭とを含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層とを含む多層積層体中に組み込まれてもよい。 The polymer laminate may incorporate any feature consistent with aspects of the present invention and layers described elsewhere herein. Optionally, the polymer laminate may further comprise an outermost layer comprising a thermoplastic polymer material comprising at least one UV blocking material. It may also include a biocomposite absorbent layer comprising a superabsorbent polymer and a biocomposite compatibilizer layer comprising active “bamboo” charcoal and a compatibilizer. Similarly, it further includes a rodent repellent interlayer comprising a thermoplastic polymeric material, a rodent repellent and ethyl vinyl acetate. An oxygen barrier interlayer comprising ethylene vinyl alcohol and EMMA inorganic / organic additives may also be incorporated. For example, the polymer laminate comprises (a) an outermost layer comprising a fabric thermoplastic polymer material comprising at least one rodent repellent and an ultraviolet blocking material, and a layer comprising at least one pesticide and / or insecticide. And (b) an innermost layer comprising a food grade polymer and an adhesive, and a next layer inserted between the outermost layer and the innermost layer: a thermoplastic yarn mesh comprising at least one superabsorbent polymer and activated carbon. A biocomposite material layer may be further included. The biocomposite layer may be composed of an HDPE mesh comprising at least one superabsorbent polymer and a second layer comprising an HDPE mesh comprising biocomposite and activated bamboo charcoal. The polymer laminate comprises: (a) an outermost layer comprising a thermoplastic polymer material comprising at least one rodent repellent; (b) an innermost layer comprising a food grade polymer and an adhesive; an outermost layer and an innermost layer; The following layers inserted between: (1) a woven thermoplastic polymer material, (2) a bubble plastic thermoplastic polymer material layer comprising bubbles comprising at least one insecticide as described herein, and (3 ) It may be incorporated into a multilayer laminate comprising a biocomposite layer comprising a thermoplastic yarn mesh comprising at least one superabsorbent polymer and activated carbon.
ポリマー積層体−共押出タイプ
一般論として、本発明は、（ａ）少なくとも１種の次の、多層シート又は多層からなる基材内の、最も好ましくは、げっ歯類忌避物質、少なくとも１種の駆除剤及び／又は殺虫剤、及び紫外線遮断物質の組み合わせを含む熱可塑性ポリマー材料を含む最外層と、（ｂ）食品等級ポリマー及び接着剤を含む最内層と、順番に関わりなく最外層と最内層の間に挿入される次の層：（ｃ）少なくとも１種の乾燥剤として機能する添加物を含む熱可塑性ポリマー材料、フリーラジカル捕捉剤又は酸素バリアを含む酸素バリア中間層と、（ｄ）少なくとも１種の超吸収ポリマーを含む熱可塑性ポリマー材料及び活性竹炭又は別の抗真菌添加物（例えば、トリクロサン）を含むバイオ複合材料吸収剤／相溶化剤層とを含むポリマー積層体を含む。実施例は、図１〜１ｅに示される。
As a polymer laminate-coextrusion type general theory, the present invention provides: (a) at least one of the following multi-layer sheets or multi-layer substrates, most preferably rodent repellents, at least one An outermost layer comprising a thermoplastic polymer material comprising a combination of an insecticide and / or insecticide and a UV blocking substance; (b) an innermost layer comprising a food grade polymer and an adhesive; and an outermost layer and an innermost layer, regardless of order. A next layer inserted between: (c) an oxygen barrier intermediate layer comprising at least one additive that functions as a desiccant, a thermoplastic polymer material, a free radical scavenger or an oxygen barrier; and (d) at least A biocomposite absorbent / compatibilizer layer comprising a thermoplastic polymeric material comprising one superabsorbent polymer and activated bamboo charcoal or another antifungal additive (eg, triclosan). Including mer laminate. Examples are shown in FIGS.
最外層がポリオレフィン、げっ歯類忌避剤（使用領域の環境要求事項に応じて）及び紫外線遮断物質を含む第１層と、熱可塑性ポリマー材料及び少なくとも１種の殺虫物質又は駆除物質を含む第２層とを含むのが好ましい。バイオ複合材料吸収剤／相溶化剤層が少なくとも１種の超吸収ポリマーを含む第１層と、活性竹炭などの吸湿性及び抗真菌性の両方を示す抗真菌物質又は別の有機物質又はこれらの組み合わせを含む第２相とを含むのがさらに好ましい。 A first layer comprising a polyolefin, a rodent repellent (depending on the environmental requirements of the application area) and a UV blocking substance, and a second layer comprising a thermoplastic polymer material and at least one insecticide or control substance. And a layer. A first layer in which the biocomposite absorbent / compatibilizer layer comprises at least one superabsorbent polymer, an antifungal substance or another organic substance exhibiting both hygroscopic and antifungal properties, such as activated bamboo charcoal, or these More preferably, it comprises a second phase comprising a combination.
多層基材内の最外層及びその他の層は、ポリオレフィン、ポリマー；ポリプロピレン、ＨＤＰＥ、ＬＤＰＥ、ＬＬＤＰＥ、ＶＬＤＰＥ及びこれらの共重合体とホモポリマー又はその他の材料とのブレンドもしくは種々の比率のブレンドからなる群から選択される熱可塑性又は熱硬化性樹脂を含むことができ、これらには、回収材料、又は製造を容易にして所望の特性を付与してさらなる機械的なバリアを害虫に与える相溶化剤、環境条件と貯蔵産物条件に従って湿度、温度、害虫挙動、及び害虫侵入及び移動方法により決定される添加物を含む。 The outermost layer and other layers in the multilayer substrate consist of blends of polyolefins, polymers; polypropylene, HDPE, LDPE, LLDPE, VLDPE and their copolymers with homopolymers or other materials or blends in various proportions. Thermoplastic or thermosetting resins selected from the group, which may include recovered materials, or compatibilizers that facilitate manufacturing and impart desired properties to provide additional mechanical barriers to pests Including additives determined by humidity, temperature, pest behavior, and pest infestation and transfer methods according to environmental and stored product conditions.
害虫駆除及び殺虫剤用の有効成分は、害虫挙動に応じて、合成ピレトリン類似化合物、例えば、ペルメトリン及びデルタメトリン及び／又は有機燐化合物：ピリミホスメチル、クロロピリホスエチル、フェニトロチオン、マラチオン、及び／又はこれらの配合物又は混合物からなる群から選択でき、及び／又は他の適切で適用可能な殺虫剤ファミリー及び／又は民族植物学的混合物から選択でき、これらには、有機的な方法が好ましい環境において、限定されないが、インドセンダン植物又はオイル、菖蒲駆虫草及びコショウ、ゼラニウムオイル及びメントールならびにその誘導体、及び／又は忌避性又は害虫駆除効力が報告され、当業者に示されて既知となっている他の植物ベース又は天然由来物質が含まれる。 Depending on the pest behavior, the active ingredient for pest control and insecticide can be synthetic pyrethrin analogues such as permethrin and deltamethrin and / or organophosphorus compounds: pyrimifosmethyl, chloropyrifosethyl, fenitrothion, malathion, and / or these It can be selected from the group consisting of formulations or mixtures and / or can be selected from other suitable and applicable pesticide families and / or ethnobotanical mixtures, which are limited in environments where organic methods are preferred. But not neem plant or oil, helminthic grass and pepper, geranium oil and menthol and their derivatives, and / or other plants whose repellency or pest control efficacy is reported and known to those skilled in the art Base or naturally derived materials are included.
本発明の別の関連変形例では、ポリマー積層体は、（ａ）ポリオレフィン、げっ歯類忌避物質、及び紫外線遮断物質を含む最外層と、（ｂ）食品等級ポリマー及び接着剤を含む最内層と、順番に関わりなく最外層と最内層の間に挿入される次の層：（ｃ）熱可塑性ポリマー材料及び殺虫物質又は駆除物質を含む殺虫剤／駆除剤中間層と、（ｄ）エチレンビニルアルコール及び好ましくは無機／有機添加物を含むＥＭＭＡを含む酸素バリア中間層と、（ｅ）超吸収ポリマーを含むバイオ複合材料吸収剤層と、（ｆ）天然の抗真菌剤、及び活性竹炭カポックファイバーなどの吸収剤を含むバイオ複合材料相溶化剤層とを含む。 In another related variation of the invention, the polymer laminate comprises: (a) an outermost layer comprising a polyolefin, a rodent repellent material, and an ultraviolet blocking material; and (b) an innermost layer comprising a food grade polymer and an adhesive. The next layer inserted between the outermost layer and the innermost layer, in any order: (c) an insecticide / disinfectant intermediate layer comprising a thermoplastic polymer material and an insecticide or disinfectant; and (d) ethylene vinyl alcohol. And preferably an oxygen barrier intermediate layer comprising EMMA containing inorganic / organic additives, (e) a biocomposite absorbent layer comprising a superabsorbent polymer, (f) a natural antifungal agent, and an activated bamboo charcoal fiber, etc. And a biocomposite compatibilizer layer comprising an absorbent.
本発明により使われる相溶化剤は、添加物に周辺ポリマーとの相溶性を付与するために効果的な任意の相溶化剤を含むことができ、これには、エチレンビニルコポリマー又は粒状活性竹炭などの天然由来成分との相溶性の付与するためのキチン及びクエン酸からなる群から選択されるものなどが挙げられる。 The compatibilizer used in accordance with the present invention can include any compatibilizer effective to impart an additive compatibility with the surrounding polymer, such as ethylene vinyl copolymer or granular activated bamboo charcoal. And those selected from the group consisting of chitin and citric acid for imparting compatibility with naturally occurring components.
本発明のさらに別の変形例では、本発明は、（ａ）ポリオレフィン、殺虫物質／駆除物質、角皮乾燥剤及び紫外線遮断物質を含む最外層と、（ｂ）食品等級ポリマー及び接着剤を含む最内層と、最外層と最内層の間に挿入されても、挿入されなくてもよいが、順番に関わりなく、最も好ましくは高湿気領域中に含まれる次の層：（ｃ）熱可塑性ポリマー材料、げっ歯類忌避物質及びエチルビニルアセテートを含むげっ歯類忌避剤中間層と、（ｄ）エチレンビニルアルコール及び／又はＥＭＭＡ及び少なくとも１種の無機／有機添加物、（ｅ）少なくとも１種の超吸収ポリマーを含むバイオ複合材料吸収剤層と、（ｆ）活性竹炭又は別の抗真菌添加物、及び相溶化剤を含むバイオ複合材料相溶化剤層とを含むポリマー積層体を含む。 In yet another variation of the present invention, the present invention comprises (a) an outermost layer comprising a polyolefin, an insecticide / control substance, a keratin desiccant and an ultraviolet blocking substance, and (b) a food grade polymer and an adhesive. The innermost layer and the next layer, which may or may not be inserted between the outermost layer and the innermost layer, regardless of order, most preferably included in the high-humidity region: (c) thermoplastic polymer A rodent repellent interlayer comprising materials, rodent repellent and ethyl vinyl acetate; (d) ethylene vinyl alcohol and / or EMMA and at least one inorganic / organic additive; (e) at least one A polymer composite comprising a biocomposite absorbent layer comprising a superabsorbent polymer and (f) a biocomposite compatibilizer layer comprising activated bamboo charcoal or another antifungal additive and a compatibilizer.
ポリマー積層体−メッシュタイプ
本発明のさらに別の変形例では、本発明は、例えば、図２に示すような、（ａ）少なくとも１種のげっ歯類忌避物質及び紫外線遮断物質を含む織物熱可塑性ポリマー材料、ならびに、少なくとも１種の駆除剤を含む層を含む最外層と、（ｂ）食品等級ポリマー及び接着剤を含む最内層と、順番に関わりなく最外層と最内層との間に挿入される次の層：（ｃ）少なくとも１種の超吸収ポリマー及び活性竹炭などの活性炭又は別の抗真菌添加物を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層とを含むポリマー積層体を含む。
Polymer Laminate-Mesh Type In yet another variation of the present invention, the present invention provides, for example, a fabric thermoplastic comprising (a) at least one rodent repellent and an ultraviolet blocking material, as shown in FIG. An outermost layer comprising a polymeric material and a layer comprising at least one pesticide; (b) an innermost layer comprising a food grade polymer and an adhesive, and inserted between the outermost and innermost layers, in any order; A polymer laminate comprising: (c) a biocomposite layer comprising a thermoplastic yarn mesh comprising at least one superabsorbent polymer and activated carbon such as activated bamboo charcoal or another antifungal additive.
バイオ複合材料層は、熱可塑性樹脂、ポリエステル、もしくはＨＤＰＥ、ＰＰ、ＰＥ、ＰＥＴのいずれかの単繊維ヤーンから構成されるメッシュ構造体又は少なくとも１種の超吸収ポリマーを含むその他のメッシュと、バイオ複合材料及び活性竹炭などの抗真菌添加物を含む熱可塑性樹脂メッシュ、より好ましくは、ＨＤＰＥメッシュを含む第２層とから構成されるのが好ましい。 The biocomposite layer is composed of a mesh structure composed of thermoplastic resin, polyester, or any single fiber yarn of HDPE, PP, PE, PET, or other mesh containing at least one superabsorbent polymer, It is preferably composed of a thermoplastic resin mesh containing a composite material and an antifungal additive such as activated bamboo charcoal, more preferably a second layer containing an HDPE mesh.
本発明の別の変形例は、（ａ）少なくとも１種のげっ歯類忌避物質を含む熱可塑性ポリマー材料を含む最外層と、（ｂ）食品等級ポリマー及び接着剤を含む最内層と、順番に関わりなく最外層と最内層との間に挿入される次の層：（ｃ）織物熱可塑性ポリマー材料、及び（ｄ）少なくとも１種の駆除剤を含む熱可塑性ポリマー層と、（ｅ）少なくとも１種の超吸収ポリマー及び活性炭を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層とを含むポリマー積層体である。 Another variation of the present invention includes: (a) an outermost layer comprising a thermoplastic polymer material comprising at least one rodent repellent; and (b) an innermost layer comprising a food grade polymer and an adhesive, in order. Regardless of the next layer inserted between the outermost and innermost layers: (c) a woven thermoplastic polymer material, and (d) a thermoplastic polymer layer comprising at least one pesticide, and (e) at least one A polymer laminate comprising a seed superabsorbent polymer and a biocomposite layer comprising a thermoplastic yarn mesh comprising activated carbon.
一変形例では、バイオ複合材料層は、少なくとも１種の超吸収ポリマーを含むＨＤＰＥメッシュ、又はポリプロピレンメッシュなどの熱可塑性樹脂メッシュと、バイオ複合材料及び活性竹炭を含むＨＤＰＥメッシュ又はポリプロピレンメッシュを含む第２層とを含む。 In one variation, the biocomposite layer includes a HDPE mesh comprising at least one superabsorbent polymer or a thermoplastic resin mesh such as a polypropylene mesh and a HDPE mesh or polypropylene mesh comprising a biocomposite and activated bamboo charcoal. 2 layers.
本発明のさらに別の変形例は（図２ｂと２ｃに例示されるように）、（ａ）少なくとも１種のげっ歯類忌避物質及び紫外線遮断物質を含む織物熱可塑性ポリマー材料、ならびに、少なくとも１種の駆除剤を含む層を含む最外層と、（ｂ）食品等級ポリマー及び接着剤を含む最内層と、順番に関わりなく最外層と最内層との間に挿入される次の層：（ｃ）少なくとも１種の超吸収ポリマー及び活性竹炭などの活性炭又は別の抗真菌添加物を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層とを含むポリマー積層体である。 Yet another variation of the present invention (as illustrated in FIGS. 2b and 2c) is that (a) a woven thermoplastic polymer material comprising at least one rodent repellent and UV blocking material, and at least one An outermost layer comprising a layer containing a seed control agent, (b) an innermost layer comprising a food grade polymer and an adhesive, and a next layer inserted between the outermost layer and the innermost layer, regardless of order: (c A polymer laminate comprising at least one superabsorbent polymer and a biocomposite layer comprising a thermoplastic yarn mesh comprising activated carbon such as activated bamboo charcoal or another antifungal additive.
ポリマー積層体のさらなる変形例は（図３参照）、（ａ）少なくとも１種の紫外線遮断物質、ならびに、任意選択で、げっ歯類忌避物質及び少なくとも１種の駆除剤を含む織物熱可塑性ポリマー材料を含む最外層と、（ｂ）食品等級ポリマー及び接着剤を含む最内層と、順番に関わりなく最外層と最内層との間に挿入される次の層：（ｃ）少なくとも１種のげっ歯類忌避物質を含むバブルを含む第１のバブルプラスチック熱可塑性ポリマー材料層と、（ｄ）少なくとも１種の駆除剤を含むバブルを含む第２のバブルプラスチック熱可塑性ポリマー材料層と、（ｅ）セルロース系又はその他の天然吸収性材料及び／又は超吸収ポリマーを封入する不織層又は他のフィルター膜などの等価層と、（ｆ）少なくとも１種の超吸収ポリマー及び活性炭又はその他の抗真菌添加物を含む熱可塑性樹脂ヤーンメッシュを含む任意のバイオ複合材料層とを含むポリマー積層体である。 A further variation of the polymer laminate is (see FIG. 3): (a) a woven thermoplastic polymer material comprising at least one UV-blocking substance, and optionally a rodent repellent and at least one pesticide. An outermost layer comprising: (b) an innermost layer comprising a food grade polymer and an adhesive; and a next layer inserted between the outermost layer and the innermost layer, regardless of order: (c) at least one rodent A first bubble plastic thermoplastic polymer material layer containing bubbles containing repellents; (d) a second bubble plastic thermoplastic polymer material layer containing bubbles containing at least one pesticide; and (e) cellulose. An equivalent layer, such as a nonwoven layer or other filter membrane, enclosing the system or other natural absorbent material and / or superabsorbent polymer, and (f) at least one superabsorbent polymer and activated carbon Is a polymer laminate and an optional biocomposite layer containing a thermoplastic resin yarn mesh include other anti-fungal additives.
この実施形態の変形例は、炭酸カルシウム又は充填剤／ブロック剤としての等価材料を含む熱可塑性ポリマー材料から構成され、第２のバブルプラスチック熱可塑性ポリマー材料層と不織層又はその他の等価層の間、又は共押出フィルムの層内に配置される層をさらに含む。 A variation of this embodiment is composed of a thermoplastic polymer material that includes calcium carbonate or an equivalent material as a filler / blocking agent, and includes a second bubble plastic thermoplastic polymer material layer and a nonwoven or other equivalent layer. It further includes a layer disposed between or within the layers of the coextruded film.
好ましくは、第１のバブルプラスチック層は、ＬＤＰＥ、ＶＬＤＰＥ、ポリプロピレン又はその他の好適なポリマー材料からなる群から選択されて、ＥＶＯＨなどの接着剤により最外層に接着され、また、第２のバブルプラスチック層バブルは、珪藻土又はその他の角皮乾燥剤又は異なるファミリー由来の異なる殺虫剤の混合物などの粉末形態の殺虫剤を付与されて、限定されないが、ピレトリン類似化合物、有機リン酸エステル、又は混合物及び様々な殺虫剤混合物を含有し、効果的結果を実現し、反復接触に対する耐性を回避する。 Preferably, the first bubble plastic layer is selected from the group consisting of LDPE, VLDPE, polypropylene or other suitable polymer material and adhered to the outermost layer with an adhesive such as EVOH, and the second bubble plastic layer The layer bubble is provided with a pesticide in powder form such as diatomaceous earth or other cuticle desiccant or a mixture of different pesticides from different families, including but not limited to pyrethrin analogs, organophosphates, or mixtures and Contains various insecticide mixtures to achieve effective results and avoid resistance to repeated contact.
本発明のまた別の実施形態は、（ａ）少なくとも１種の紫外線遮断物質、ならびに、任意選択で、げっ歯類忌避剤及び少なくとも１種の駆除剤を含む熱可塑性ポリマー材料を含む最外層と、（ｂ）食品等級ポリマー及び接着剤を含む最内層と、順番に関わりなく最外層と最内層との間に挿入される次の層：（ｃ）少なくとも１種のげっ歯類忌避物質を含むバブルを含む第１のバブルプラスチック熱可塑性ポリマー材料層と、（ｄ）少なくとも１種の駆除剤を含むバブルを含む第２のバブルプラスチック熱可塑性ポリマー材料層と、（ｅ）少なくとも１種の超吸収ポリマーを含むバイオ複合材料吸収剤層と、（ｆ）竹炭などの活性炭及び相溶化剤を含むバイオ複合材料相溶化剤層とを含むポリマー積層体を含む。 Yet another embodiment of the present invention provides: (a) an outermost layer comprising a thermoplastic polymeric material comprising at least one UV-blocking material, and optionally a rodent repellent and at least one pesticide; (B) an innermost layer comprising a food grade polymer and an adhesive and a next layer inserted between the outermost and innermost layers, regardless of order, (c) comprising at least one rodent repellent A first bubble plastic thermoplastic polymer material layer comprising bubbles; (d) a second bubble plastic thermoplastic polymer material layer comprising bubbles comprising at least one pesticide; and (e) at least one superabsorbent. A polymer laminate comprising a biocomposite absorbent layer comprising a polymer and (f) a biocomposite compatibilizer layer comprising activated carbon such as bamboo charcoal and a compatibilizer.
本発明の全ての実施形態に関して、層状基材、又はこれらの混合物は、バイオベース材料に置き換えて、又はそれに加えて、バイオベース材料の１００％までの量で回収材料を含めることができることを理解されたい。本発明で使用する場合、「回収」材料は、消費者使用済品回収（ｐｏｓｔ−ｃｏｎｓｕｍｅｒ ｒｅｃｙｃｌｅｄ：ＰＣＲ）材料、産業使用済品回収（ｐｏｓｔ−ｉｎｄｕｓｔｒｉａｌ ｒｅｃｙｃｌｅｄ：ＰＩＲ）材料、及びこれらの混合物を包含する。 For all embodiments of the present invention, it is understood that the layered substrate, or mixture thereof, can include the recovered material in an amount of up to 100% of the biobased material, in addition to or in addition to the biobased material. I want to be. As used herein, “recovery” materials include consumer-used recycled (PCR) materials, industrial-post-recycled (PIR) materials, and mixtures thereof. To do.
収穫農産物用ポリマー貯蔵容器
また、本発明は、収穫農産物用のポリマー貯蔵容器も含み、容器は、本発明のいずれかの実施形態によるポリマー積層体を含む。これらは、任意の方法で、高分子シート又は織物シート材料から作製される、又はそれらを組み込んだポリマーバッグ及びその他の容器を作るために、当該技術分野において既知であり、使われている機械装置を使用して製造でき、骨組構造に適合しても、又は骨組構造内で支えられても、そうでなくてもよい。
Polymer Storage Container for Harvested Agricultural Products The present invention also includes a polymer storage container for harvested agricultural products, the container including a polymer laminate according to any embodiment of the present invention. These are mechanical devices known and used in the art to make polymer bags and other containers made of or incorporating polymeric sheets or woven sheet materials in any way. May be manufactured using and may or may not be adapted to the frame structure or supported within the frame structure.
収穫農産物の貯蔵システム
収穫農産物の貯蔵システムであって、このシステムは、前述の積層体、積層体の断片又は部分を含み、これらを既存の貯蔵容器内に戦略的に配置して、空間の有効活用又はそれらから作製された容器及び／又は農場における現地貯蔵のためのバッグを提供する。
Harvested Agricultural Storage System Harvested Agricultural Storage System, which includes the aforementioned laminates, laminate fragments or parts, and strategically arranges them in existing storage containers to save space Provide containers for use or made from them and / or bags for on-site storage on the farm.
本発明の積層体は、例えば、米国特許第８，１４１，３２８号に記載のような、ばら積み、箱入り、又はバッグ入り物品の自立型密封貯蔵のためのシステムと方法に使用できる。この特許は参照により本明細書に組み込まれる。 The laminates of the present invention can be used in systems and methods for self-contained sealed storage of bulk, boxed, or bag items, for example, as described in US Pat. No. 8,141,328. This patent is incorporated herein by reference.
また、本発明は、韓国特許出願第ＫＲ１０１０９２６７号に記載の材料と方法に対する改善と見なすことができる。この特許は参照により本明細書に組み込まれる。 The present invention can also be regarded as an improvement over the materials and methods described in Korean Patent Application No. KR10109267. This patent is incorporated herein by reference.
前述及びその他の本発明の目的、特徴及び利点は、添付図面を参照しながら進められる以下の好ましい実施形態の詳細説明から容易に明らかになるであろう。そこでは、本発明の好ましい実施形態が本発明の実施を意図した単なる最良の形態の実例として示され、説明される。 The foregoing and other objects, features and advantages of the present invention will become readily apparent from the following detailed description of the preferred embodiments, which proceeds with reference to the accompanying drawings. There, preferred embodiments of the invention are shown and described as merely exemplary of the best mode contemplated for carrying out the invention.
明らかなように、本発明は他の異なる実施形態が可能で、また、そのいくつかの詳細は、種々の明らかな点で修正が可能であり、これらは全て本発明を逸脱することなく行うことができる。したがって、図面及び説明は、制限的なものではなく、本質的に例示的なものと見なされるべきである。詳細説明は、本発明の好ましい実施形態を示し、本発明のプロセスの個々のステップは、類似した結果を得るために独立に実施でき、また同様に、記載の積層体及び容器の変形例は、設計又は製造プロセス上の修正を行って類似の結果を得ることができることも理解されよう。 As will be apparent, the invention is capable of other and different embodiments, and its several details are capable of modifications in various obvious respects, all without departing from the invention. Can do. Accordingly, the drawings and descriptions are to be regarded as illustrative in nature and not as restrictive. The detailed description shows preferred embodiments of the present invention, the individual steps of the process of the present invention can be carried out independently to obtain similar results, and similarly, the described laminate and container variants are It will also be appreciated that design or manufacturing process modifications can be made to achieve similar results.
前述の発明の概要に従って、次に好ましい実施形態の詳細な説明を提供する。この実施形態は、現時点の最良の形態であると見なされる。望ましい特性の複数の変形例又は組み合わせは、環境と気候の条件、タイプ、昆虫の存在と生活環、貯蔵産物の呼吸速度と蒸散強度に応じて異なることは理解されよう。 In accordance with the foregoing summary of the invention, a detailed description of the preferred embodiments will now be provided. This embodiment is considered to be the best mode at the present time. It will be appreciated that variations or combinations of desirable characteristics will vary depending on environmental and climatic conditions, type, insect presence and life cycle, respiration rate and transpiration intensity of stored products.
本発明の特徴と利点は、以降で必要に応じて特定の実施形態を参照して説明される。しかし、本発明は異なる形態で実施でき、本明細書に記述の実施形態に限定されると解釈されるべきではない。むしろ、これらの実施形態は、本開示を全体を通してまとまったものとして、本発明の範囲を当業者に十分に伝えるように提供されている。 The features and advantages of the invention will be described hereinafter with reference to specific embodiments as needed. However, the present invention can be implemented in different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art.
本出願の全体を通して使われる用語の「ポリマー」は、天然、合成モノマー及び／又はコモノマー、又は天然と合成モノマー及び／又はコモノマーの組み合わせの重合又は共重合反応の生成物である材料を意味し、ホモポリマー、コポリマー、ターポリマー、などを含む。一般に、本出願で記載の多層フィルムの層は、単一ポリマー、単一ポリマーと非ポリマー材料の混合物、２種以上の一緒にブレンドされたポリマーの組み合わせ、又は２種以上のポリマーと非ポリマー材料のブレンドの混合物を含むことができる。多くのポリマーが相補的なモノマーの相互の反応により合成できることは理解されよう。同様に、一部のポリマーは、その他のポリマーの化学的修飾により得られ、それにより、得られるポリマーを構成する高分子の構造は、仮定上のモノマーの単独重合により形成されたものと考えることができる。 The term “polymer” as used throughout this application means a material that is the product of a polymerization or copolymerization reaction of natural, synthetic monomers and / or comonomers, or a combination of natural and synthetic monomers and / or comonomers, Including homopolymers, copolymers, terpolymers, and the like. In general, the layers of the multilayer film described in this application are comprised of a single polymer, a mixture of a single polymer and a non-polymer material, a combination of two or more polymers blended together, or two or more polymers and a non-polymer material. A blend of the following: It will be appreciated that many polymers can be synthesized by the mutual reaction of complementary monomers. Similarly, some polymers are obtained by chemical modification of other polymers, so that the structure of the macromolecules that make up the resulting polymer is considered to have been formed by homopolymerization of hypothetical monomers. Can do.
ポリマーと熱可塑性原材料は、それらのバリア性質、機械的性質、流動学的性質、又は気候条件、貯蔵産物の意図された条件、昆虫、害虫、及び／又は真菌汚染のリスクなどのバリア機能に影響を与えるその他の因子を考慮して選択できる。 Polymers and thermoplastic raw materials affect their barrier properties such as barrier properties, mechanical properties, rheological properties, or climatic conditions, intended conditions of stored products, risk of insect, pest and / or fungal contamination Can be selected in consideration of other factors that give
本出願全体を通して使われる用語の「熱可塑性樹脂」は、熱への暴露時に軟化し、その後、室温に冷却時に元の状態に戻るポリマー又はポリマー混合物を意味する。一般に、熱可塑性材料は、天然又は合成ポリマーを含むことができる。 The term “thermoplastic resin” as used throughout this application means a polymer or polymer mixture that softens upon exposure to heat and then returns to its original state upon cooling to room temperature. In general, thermoplastic materials can include natural or synthetic polymers.
別段の指示がない限り、本明細書及び請求項において使用される分子量、反応条件などの成分量、特性を表す全ての数値は、全ての場合において、「約」という語で修飾されるものとして理解されるべきである。したがって、特に指示がない限り、本明細書及び添付の請求項に記載される数値特性は、本発明の実施形態で取得しようとしている所望の性質に応じて変化する可能性のある近似値である。本発明の広範囲に記載の数値範囲及びパラメータは近似値であるが、具体例に記載の数値は可能な限り正確に報告されている。しかしながら、いずれの数値も、各測定値において認められる誤差から必然的に生じる一定の誤差を本質的に含む。 Unless otherwise indicated, all numerical values representing molecular weights, amounts of components such as reaction conditions, properties, etc. used in the specification and claims are to be modified in all cases with the word “about”. Should be understood. Thus, unless indicated otherwise, the numerical characteristics set forth in this specification and the appended claims are approximations that can vary depending on the desired properties sought to be obtained in the embodiments of the present invention. . Although the numerical ranges and parameters described extensively in the present invention are approximate, the numerical values described in the specific examples are reported as accurately as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the error found in each measuring value.
図１は、本発明の一実施形態によるポリマー積層体の模式図である。この積層体は、例えば、多層共押出吹込フィルム設備を使用することにより、共押出及びフィルムブローイングにより製造できる。これは、多層共押出として作製できる。この場合、基材及び使われる異なる有効成分は、その層の数又は順番に限定されない。 FIG. 1 is a schematic view of a polymer laminate according to an embodiment of the present invention. This laminate can be produced by coextrusion and film blowing, for example, by using a multilayer coextrusion blown film facility. This can be made as a multilayer coextrusion. In this case, the substrate and the different active ingredients used are not limited to the number or order of the layers.
共押出により調製される本発明の単一層として、又は多層として使われる典型的な積層体の厚さの範囲は、約５０ミクロン〜６００ミクロンであるが、その他の厚さも製造できる。個別の層の厚さは、積層体全体の寸法を得るために測定することができるが、通常、８０〜１５０ミクロンの一般的な範囲内にある。 A typical laminate thickness range used as a single layer or as a multilayer of the present invention prepared by coextrusion is about 50 microns to 600 microns, although other thicknesses can be made. The thickness of the individual layers can be measured to obtain the overall laminate dimensions, but is usually in the general range of 80 to 150 microns.
最外層１は、ポリプロピレン、ＨＤＰＥ、ＬＤＰＥ、ＬＬＤＰＥ、ＶＬＤＰＥ及びこれらのコポリマーとホモポリマーからなる群から選択されるポリオレフィンなどの熱可塑性材料から作製できる。ＬＬＤＰＥの例は、ライオンデルバセルから市販されているＰＬＥＸＡＲ８００である。
The
本発明によりに使用できるげっ歯類忌避剤は、ポリオレフィン及び／又は熱可塑性ベース層と部分的に又は完全にと混合できる任意の合成又は天然げっ歯類忌避剤、例えば、安息香酸デナトニウム、トリニトロベンゼン−アリールアミン錯体、及び塩化トリブチルスズを含むことができるがこれらに限定されない。天然げっ歯類忌避剤は、限定されないが、サリチル酸エステル、メントール、コーンミントオイル、ユ−カリ油、樟脳、テルペン、ペパーミント油、シトロネラ油、ローズマリー油、チョウジ油、ゼラニウム油、唐辛子、メチルノニルケトン、又はこれらの組み合わせを含むことができる。 Rodent repellents that can be used in accordance with the present invention are any synthetic or natural rodent repellent that can be mixed partially or fully with the polyolefin and / or thermoplastic base layer, such as, for example, denatonium benzoate, trinitrobenzene. -Include but are not limited to arylamine complexes and tributyltin chloride. Natural rodent repellents include, but are not limited to, salicylic acid ester, menthol, corn mint oil, eucalyptus oil, camphor, terpene, peppermint oil, citronella oil, rosemary oil, clove oil, geranium oil, chili, methylnonyl Ketones, or combinations thereof can be included.
紫外線遮断物質は、例えば、約２重量％〜約５重量％の当該技術分野において既知の有効量で、ベースポリマーと効果的に混合できる任意の材料であってよい。このような材料の一例は、Ｓｐｅｃｉａｌｔｙ Ｍｉｎｅｒａｌｓ，Ｉｎｃ．から市販されているＯｐｔｉｂｌｏｃｋ １０である。カーボンブラック又は二酸化チタンなどのＵＶ反射又は吸収性を付与する１８〜１５０ｎｍの粒径のその他の物質又は紫外線安定剤を使用してもよい。 The UV blocking material can be any material that can be effectively mixed with the base polymer in an effective amount known in the art, for example, from about 2% to about 5% by weight. An example of such a material is Specialty Minerals, Inc. Optiblock 10 available from Other materials or UV stabilizers with a particle size of 18-150 nm that impart UV reflection or absorption such as carbon black or titanium dioxide may be used.
駆除剤中間層２は、熱可塑性ポリマー材料又はポリオレフィン、及び少なくとも１種の殺虫又は駆除物質を含むことができ、殺虫又は駆除物質は、任意の合成もしくは天然殺虫剤もしくは駆除剤又はポリマー材料と部分的もしくは完全相溶性の又は混合可能な組み合わせを含めて、有効量を供給して侵入を低減又は排除できる。例には、合成ピレトリン類似化合物、例えば、ペルメトリン、又はデルタメトリンからなる群から選択されるものが含まれる。最も好ましくは、殺虫剤は、限定されないが、ピリミホスメチル（Ａｃｔｅｌｌｉｃ Ｓｕｐｅｒｄｕｓｔの名称で市販されている）を３重量％の濃度のペルメトリン及び１４重量％のピリミホスメチルとして含むか、又は特にトウモロコシ貯蔵用として熱帯及び亜熱帯のオオナガシンクイムシ及びコクゾウムシを特異的に撃退するその他の二酸化ケイ素＋合成ピレトリン類似化合物もしくはこれらの混合物を含む、合成又は天然の化合物の組み合わせ、又はそれらの混合物である。限定されないが、マラチオン＋ペルメトリン、フェニトロチオン＋デルタメトリン、又は類似殺虫剤ファミリーの代替物と混合したこのような化合物のいずれかを含むその他の有効成分の混合物を使用できることが理解されよう。
The pesticide
また、殺虫剤には、角皮乾燥物質、又は昆虫を無力化する、それらの増殖を阻害する、又はそれらの生殖作用を遅らせる物質、又は忌避性を促進し、死滅させ、又は移動と伝播を抑える、及びこれらの組み合わせを行う物質を含めることができる。 Insecticides also include dry cuticles, or substances that neutralize insects, inhibit their growth, or slow their reproductive action, or promote repellency, kill, or transfer and spread. Substances that suppress and combinations thereof can be included.
熱可塑性ポリマー材料は、共押出を受けると同時に効果的な量の有効成分を含むことができる任意の材料からから選択できる。例には、バイオ複合材料を形成できるように天然デンプンと混合されるエチルビニルアセテート又は熱可塑性ポリマーを含めることができる。このようなデンプンをブレンドしたポリエステルの一例は、ＢＡＳＦから入手できるＥｃｏｆｌｅｘである。 The thermoplastic polymer material can be selected from any material that can be co-extruded and contain an effective amount of the active ingredient at the same time. Examples can include ethyl vinyl acetate or a thermoplastic polymer mixed with natural starch so that a biocomposite can be formed. An example of such a starch blended polyester is Ecoflex available from BASF.
酸素バリア中間層３は、好ましくは、任意の熱可塑性材料を含んでよいが、他の層との高い接着性の理由で、エチルビニルアルコール（ＥＶＯＨ）、エチレンメチルアクリル酸コポリマー（ＥＭＭＡ）又はエチレンメタクリル酸（ＥＭＡＡ）を使用するのが好ましい。このようなＥＭＭＡの例は、ライオンデルバセルからＰＬＥＸＡＲとして市販されているＰＸＬ１６４である。この層は、酸素進入を抑制するために有効な量で供給される、少なくとも１種の酸素バリア材料、例えば、無機もしくは有機添加物又は乾燥剤、フリーラジカル捕捉剤、又は酸素バリアとして機能する物質を含む。この量は、特定の用途の積層体表面積に対する食糧品容量の比率と共に変化するが、一般に、約２重量％〜から７５重量％の範囲にある。このような無機の添加物には、粒子、粉末、マスターバッチ形態の、鉄、アスコルビン酸、水酸化カルシウム、活性炭、塩化ナトリウム、塩化カリウム、酸化マグネシウム、酸化チタン、酸化アルミニウム、酸化クロム、酸化カルシウム、シリカ、ベントナイト、ゼオライト、モンモリロナイト、ムライト、ウォラストナイト、及びアガルマトライト粘土、又はこれらの混合物を挙げることができる。 The oxygen barrier intermediate layer 3 may preferably comprise any thermoplastic material, but for reasons of high adhesion to other layers, ethyl vinyl alcohol (EVOH), ethylene methyl acrylic acid copolymer (EMMA) or ethylene It is preferred to use methacrylic acid (EMAA). An example of such an EMMA is PXL164, which is commercially available as PLEXAR from Lion Del Bassell. This layer is provided with at least one oxygen barrier material, such as an inorganic or organic additive or desiccant, a free radical scavenger, or a substance that functions as an oxygen barrier, provided in an amount effective to inhibit oxygen entry. including. This amount varies with the ratio of food product volume to laminate surface area for the particular application, but generally ranges from about 2% to 75% by weight. Such inorganic additives include particles, powder, masterbatch form, iron, ascorbic acid, calcium hydroxide, activated carbon, sodium chloride, potassium chloride, magnesium oxide, titanium oxide, aluminum oxide, chromium oxide, calcium oxide , Silica, bentonite, zeolite, montmorillonite, mullite, wollastonite, and agarmatite clay, or mixtures thereof.
有機添加物には、当分野で知られている物質、例えば、限定されないが、金属アルコラート及びアルコキシシランなどの相溶化剤を含めることができる。これらの材料の典型的な含量は、約１重量％〜約２５重量％、又はポリマー構造層に組み込まれる材料の粘着性及び／又は混和性に応じて、その他の範囲である。 Organic additives can include materials known in the art, such as, but not limited to, compatibilizers such as metal alcoholates and alkoxysilanes. Typical contents of these materials range from about 1% to about 25% by weight, or other ranges depending on the tackiness and / or miscibility of the material incorporated into the polymeric structural layer.
バイオ複合材料吸収剤層４は、１種又は複数種の超吸収ポリマー、例えば、Ｓｈａｎｇｈａｉ Ｄｉｎｇｈａｎ Ｃｈｅｍｉｃａｌ Ｃｏ．，Ｓｈａｎｇｈａｉ，ＰＲＣ、又はＴｅｉｊｉｎ Ｌｉｍｉｔｅｄ ｏｆ Ｔａｉｗａｎ、から市販されているポリアクリル酸ナトリウムを含み、収容されている乾燥食糧品からの湿気、又は相対湿度と温度の変化に起因する水分拡散由来の湿気を吸収するために効果的な量で供給される。この量は、多層共押出物内又は層状構造内の局所的気候条件に関連する配置に対する優先度と、より冷たい気候で貯蔵される小麦又は穀物に比較して異なる蒸散強度を有する熱帯地域での屋外貯蔵コーン又はトウモロコシという状況下などの貯蔵産物の蒸散により生成される湿気の量の両方により決定できる。
The biocomposite
バイオ複合材料吸収剤層４は、好ましくは、弁タイプの、角度がついて円錐形の、又は他の形状の構造の微小な穿孔を備えて、当該技術分野において既知の方法により、酸素透過性及び水蒸気透過性を管理できる。好ましくは積層体表面に対し約４５°の角度で配置される場合、このような弁穿孔は、この層から積層体の外側に達するまでの湿気の移動を許容するのに効果的である。
The biocomposite
バイオ複合材料相溶化剤層５は、ベース材料として熱可塑性ポリマーを含み、抗真菌剤、好ましくは活性竹炭、及び効果的量の相溶化剤、例えば、キチン、Ｃｉｒｏｆｌｅｘ Ａ４などのクエン酸（Ｖｅｒｔｅｌｌｕｓから市販されている）が添加される。これらの材料の典型的な含量は、約１重量％〜約２５重量％の範囲である。
The
前述の層３、４、又は５は、ブロック成分又は有効成分の移動を妨害する添加物、例えば、炭酸カルシウム、シリカ、又は滑石を含んでもよく、これらは、駆除剤又はげっ歯類忌避剤成分の移動を制限し、含まれている乾燥食糧品に到達するのを防ぐ。また、ＦＤＡ認可のＵｖｉｎｕｌ ４０５０Ｈなどの安定剤を含めることができる。
The
最内層６は、好ましくは、食品等級ポリマー、及び層５などのすぐ隣の中間層にこの層を取り付けるように適合された接着剤を含む。食品等級ポリマーの例は、Ｓａｂｉｃ６１３５ＮＥを挙げることができる。
The innermost layer 6 preferably comprises a food grade polymer and an adhesive adapted to attach this layer to an immediately adjacent intermediate layer such as
示し、記載した個別層のそれぞれは、構成層の一体化及び有効成分の機能と整合する機能性積層体を生成するように、それぞれのこのような層内の、又はこのような層に接着された有効成分と一緒に組み合わせても、及び／又は併合してもよい。このような変形例を以下に記載する。 Each of the individual layers shown and described is bonded to or within each such layer to produce a functional laminate that matches the integration of the constituent layers and the function of the active ingredient. The active ingredients may be combined and / or combined. Such modifications are described below.
図１ａは、本発明の代替実施形態によるポリマー積層体の模式図である。この実施形態は、最外層が駆除剤及びＵＶ遮断成分を含むが、第１の中間層がげっ歯類忌避成分を含むことを除いて図１の実施形態に類似である。 FIG. 1a is a schematic diagram of a polymer laminate according to an alternative embodiment of the present invention. This embodiment is similar to the embodiment of FIG. 1 except that the outermost layer includes a pesticide and a UV blocking component, but the first intermediate layer includes a rodent repellent component.
図１ｂは、本発明のさらに別の代替実施形態によるポリマー積層体の模式図である。この実施形態は、層１と層２が共押出により単一層として効果的に組み合わされていることを除いて、図１の実施形態に類似である。
FIG. 1b is a schematic view of a polymer laminate according to yet another alternative embodiment of the present invention. This embodiment is similar to the embodiment of FIG. 1 except that
図１ｃは、本発明のさらに別の代替実施形態によるポリマー積層体の模式図である。この実施形態は、層４と層５の配置が逆転していること除いて、図１の実施形態に類似である。
FIG. 1c is a schematic view of a polymer laminate according to yet another alternative embodiment of the present invention. This embodiment is similar to the embodiment of FIG. 1 except that the arrangement of
図１ｄは、本発明のさらに別の代替実施形態によるポリマー積層体の模式図である。この実施形態は、層４と層５が共押出により単一層として効果的に組み合わされていることを除いて、図１の実施形態に類似である。
FIG. 1d is a schematic view of a polymer laminate according to yet another alternative embodiment of the present invention. This embodiment is similar to the embodiment of FIG. 1 except that
図１ｅは、本発明のさらに別の代替実施形態によるポリマー積層体の模式図である。この実施形態は、水平又は垂直方向配置、充填及び密封などの技術を使って、又はマニュアル方式でフィルムがバッグに変換される場合に、層６が単一層として作製され、ライナーとして挿入されることを除いて、図１〜１ｄの実施形態に類似である。 FIG. 1e is a schematic diagram of a polymer laminate according to yet another alternative embodiment of the present invention. In this embodiment, the layer 6 is made as a single layer and inserted as a liner, using techniques such as horizontal or vertical alignment, filling and sealing, or when the film is converted into a bag in a manual manner. Is similar to the embodiment of FIGS.
図２は、本発明の一実施形態による織物積層体の模式図である。この図は、最外層１を示す。この層は、駆除剤を含有するＥＭＭＡ熱可塑性層８と加熱により積層させた駆除剤及びげっ歯類忌避成分を含むＨＤＰＥ（又はポリプロピレン）フラットヤーンのテープ織物層７である。層７の縦糸又は横糸中の駆除剤が、層８のものとは異なるのが好ましい。さらに、層７の縦糸（又は横糸）は、駆除剤を含むことができ、層７の横糸（又は縦糸）はげっ歯類忌避剤を含む。さらに、層７の縦糸（又は横糸）は層７の横糸（又は縦糸）とは異なる有効成分を含むことにより、隣接有効成分に対する１種の相補的有効成分を使って２種の異なる有効成分及び所望の異なる性質を１つの基材に含有させて、所望の組み合わせ効果を形成するか、又は片方の有効成分が他方の効果を高める、もしくは低下させることができる。ＨＤＰＥ（又はポリプロピレン）フラットヤーンは、産業使用済又は消費者使用済回収材料由来であってもよく、また、この回収材料が有効成分を含んでいても、そうでなくてもよい。
FIG. 2 is a schematic view of a woven fabric laminate according to an embodiment of the present invention. This figure shows the
また、図２は、ＨＤＰＥ単繊維ヤーンメッシュ層９も示す。この層は、ヤーン中に化学的に組み込まれた超吸収性ポリマーを含有する。層１０は、ポリマー中に活性炭を含むＨＤＰＥの単繊維ヤーンから調製されたバイオ複合材料メッシュである。層１１は、メッシュ層１０に接着するための接着剤を有する食品等級ポリマーのシートである。図２の積層体は、最初に、それぞれ、層７〜８、及び層９〜１１の下位積層体を組み立てて、続けて、図２の一連のＸで示すように、２つの下位積層体を一緒に熱点接着することにより作製される。 FIG. 2 also shows an HDPE monofilament yarn mesh layer 9. This layer contains a superabsorbent polymer chemically incorporated into the yarn. Layer 10 is a biocomposite mesh prepared from HDPE monofilament yarn with activated carbon in the polymer. Layer 11 is a sheet of food grade polymer having an adhesive to adhere to mesh layer 10. The stack of FIG. 2 first assembles the sub-stacks of layers 7-8 and layers 9-11, respectively, followed by two sub-stacks, as shown by a series of X in FIG. It is made by hot spot bonding together.
図２ａは、本発明の代替実施形態による織物積層体の模式図である。この実施形態は、層１と層２が共押出により単一層として効果的に組み合わされていることを除いて、図２の実施形態に類似である。
FIG. 2a is a schematic diagram of a woven laminate according to an alternative embodiment of the present invention. This embodiment is similar to the embodiment of FIG. 2 except that
図２ａは、本発明の代替実施形態による織物積層体の模式図である。この実施形態は、織物層１３が有効成分を含まず、織物層１３の外側に積層された追加の層１２がげっ歯類忌避剤を含み、層１４が殺虫剤を含むこと以外は、図２の実施形態に類似である。また、この実施形態は、水平又は垂直方向配置、充填及び密封などの技術を使って、又はマニュアル方式でフィルムがバッグに変換される場合に、単一層として形成され、ライナーとして挿入される、図２の層９と１０に類似の層１５と１６、及び層１７を示す。
FIG. 2a is a schematic diagram of a woven laminate according to an alternative embodiment of the present invention. This embodiment is similar to FIG. 2 except that the fabric layer 13 does not contain an active ingredient, the
図２ｂは、本発明のさらに別の代替実施形態による織物積層体の模式図である。また、この実施形態は、層９と１０が単一層２０として組み合わされていること、及び水平又は垂直方向配置、充填及び密封などの技術を使って、又はマニュアル方式でフィルムがバッグに変換される場合に、単一層として形成され、ライナーとして挿入される層２１を除いて、図２の実施形態に類似であり、層７と８に類似の層１８と１９を含む。
FIG. 2b is a schematic view of a woven laminate according to yet another alternative embodiment of the present invention. This embodiment also allows layers 9 and 10 to be combined as a
図２ｃは、本発明のさらに別の代替実施形態による織物積層体の模式図である。この実施形態は、図２ｂの実施形態に類似であり、単一下位積層体として熱点接着の前に共押出された層２４と層２５を含む。
FIG. 2c is a schematic view of a woven laminate according to yet another alternative embodiment of the present invention. This embodiment is similar to the embodiment of FIG. 2b, and includes
図３は、本発明のさらに別の代替実施形態によるポリマー積層体の製作配置図である。図３は、図２の層７と８と同じ構成であってもよい最外層３０を示す。層３１は、ＬＤＰＥ、ＶＬＤＰＥ、ポリプロピレン、又はその他の好適なポリマー材料のバブルプラスチック層で、ＥＭＭＡ、又はＥＶＯＨなどの接着剤により層３０に接着されており、このバブルプラスチック層では、バブルが粉末、粒子又は顆粒形態の珪藻土（Ｈｅａｄｌｅｙ Ｔｅｃｈｎｏｌｏｇｉｅｓから商標名Ｐｒｏｔｅｃｔ−Ｉｔとして販売されているものなど）又はその他の角皮乾燥剤及び殺虫剤混合物などの殺虫剤を封入しており、好ましい性質を示す１種又は複数種の合成ピレトリン類似化合物又は合成有機リン酸エステル殺虫剤又はこれらの殺虫剤のファミリーを含んでも、含まなくてもよく、また、前記好ましい性質には、滅菌効果、増殖調節効果、忌避効果、伝搬効果又はその他の害虫及び昆虫駆除に望まれる効果を含んでも、含まなくてもよい。層３２は、バブルプラスチックに対向する層（例えば、層３１と組み合わせて熱成形により作製できる）であり、バブルは、本明細書で記載のげっ歯類忌避剤を充填されている。層３３は、遊離したげっ歯類忌避剤及び／又は殺虫剤／駆除剤のどれもが食品等級層に向けて移動しないようにするために設けられている充填剤／ブロック剤（炭酸カルシウムなど）を含む熱可塑性材料からなる別の層である。
FIG. 3 is a fabrication layout of a polymer laminate according to yet another alternative embodiment of the present invention. FIG. 3 shows an outermost layer 30 that may be the same configuration as
層３４は、不織層又は他のフィルター膜又は多孔質基材などの等価層である。この層は、超吸収性ポリマーなどのセルロース系又はその他の天然吸収性材料（例えば、竹線維、カポックファイバー、やし殻、杏の種）及び／又は合成吸収剤を封入して湿気バリアを形成し、同時に、例えば、穀物等の蒸散及び相対湿度、蒸散、呼吸強度、及び湿気に繋がるその他の条件の変化に起因する収容食糧品からの水分拡散を保持及び吸収する。 Layer 34 is an equivalent layer such as a non-woven layer or other filter membrane or porous substrate. This layer encloses a cellulosic or other natural absorbent material such as a superabsorbent polymer (eg bamboo fiber, kapok fiber, coconut shell, apricot seed) and / or a synthetic absorbent to form a moisture barrier. At the same time, it retains and absorbs moisture diffusion from contained food items due to, for example, transpiration of grains and the like, and changes in relative humidity, transpiration, respiratory strength, and other conditions that lead to moisture.
層３５は、接着剤層で、ＥＶＯＨ又は本明細書で記載のものなどのその他の等価物質である。層３６は、食品等級ポリマーで、接着剤層３５により層３４に接着されている。層３４／３５／３６は、その後、層３０〜３３に熱点接着される。
Layer 35 is an adhesive layer and is EVOH or other equivalent material such as those described herein.
図３ａは、本発明のさらに別の代替実施形態により形成されたポリマー積層体の製作配置図である。この実施形態は、図３に類似で、層３０、３１及び３２と等価の層３７、３８及び３９を備え、層３４と３５は、図１の層４と５と同じ層４０と４１で置き換えられ、また、層４３は図１の層６と同じであり、任意選択で接着剤層４２を備え、この場合、食品等級層は別に形成される。
FIG. 3a is a fabrication layout of a polymer laminate formed according to yet another alternative embodiment of the present invention. This embodiment is similar to FIG. 3 and comprises
図４は、図３ａに示す構成のポリマー積層体の製作略図であり、類似の参照番号は、それぞれの層を示し、本発明の一実施形態に従って、バッグに形成され、穀物４４を含む。この模式図は、協調層３８と３９の詳細構成を示す。この層は、粉末形態の殺虫剤、及びげっ歯類忌避剤をそれぞれ供給する。
FIG. 4 is a schematic representation of the fabrication of a polymer laminate configured as shown in FIG. 3a, with like reference numerals indicating the respective layers, formed in a bag and including
ステップの論理的順序は、説明する目的のみのために使用されていること、及び構成層、それらの測定値及び有効成分の測定値は、本発明の実施の目的と得られた結果と他の点で矛盾しない場合には、変えることができることは理解されよう。 The logical order of steps is used for illustrative purposes only, and the measurement of constituent layers, their measurements and active ingredients is the purpose of practicing the invention and the results obtained and other It will be appreciated that changes can be made if they are consistent in that respect.
本発明は、本発明の趣旨又は基本的な特徴を逸脱することなく、その他の特定の形態で実施できる。従って、前述の実施形態は、本明細書で記載の発明に限定するのではなく、すべての点で、例証であると見なすべきである。従って、本発明の範囲は、前述の説明によるのではなく、添付の請求項に示されており、請求項に等価な意味及び範囲内の全ての変更はその中に包含されることが意図されている。 The present invention can be implemented in other specific forms without departing from the spirit or basic characteristics of the present invention. Accordingly, the foregoing embodiments should not be construed as limited to the invention described herein but are to be considered in all respects illustrative. The scope of the invention is, therefore, indicated by the appended claims rather than by the foregoing description, and all modifications that come within the meaning and scope equivalent to the claims are intended to be embraced therein. ing.
図５は、１つの基材上に添加した複数の有効成分を示す模式図であり、図５ａは、１種のみの有効成分を含む別のバブル（図５ｂに示す）に隣接する複数種の有効成分を封入した１つのバブルを示す。 FIG. 5 is a schematic diagram showing a plurality of active ingredients added on one substrate, and FIG. 5a shows a plurality of types adjacent to another bubble (shown in FIG. 5b) containing only one type of active ingredient. One bubble encapsulating the active ingredient is shown.
図６は、両側の突起部内に封入した又は他の方法で含有した有効成分の模式図で、フィルムが両側に複数の有効成分を封入する能力を有することを表している。 FIG. 6 is a schematic view of an active ingredient encapsulated in protrusions on both sides or contained in another manner, and shows that the film has the ability to enclose a plurality of active ingredients on both sides.
図７は、１つの基材上に複数の有効成分を添加するための一方法である金属ドラムローラーの水平間仕切りを示す模式図である。図７ａ、７ｂ、７ｃは、中央に配置されているが分割されている格納装置を示し、これは、図７ｄに示すように同様に分割されている外部供給装置から有効成分を受ける。それぞれの格納装置中に有効成分を移した後で、図７ｅ、７ｆ及び７ｇに示すように有効成分をそれぞれの装置に分配する格納装置の穿孔パイプを通って有効成分が放出され、次に、ドラムが回転している間に、有効成分が通過して基材上に添加される。 FIG. 7 is a schematic diagram showing a horizontal partition of a metal drum roller, which is one method for adding a plurality of active ingredients on one substrate. FIGS. 7a, 7b, 7c show a storage device that is centrally arranged but divided, which receives the active ingredient from an external supply device that is also divided as shown in FIG. 7d. After transferring the active ingredient into the respective containment device, the active ingredient is released through the perforated pipe of the containment device that distributes the active ingredient to the respective device as shown in FIGS. 7e, 7f and 7g. While the drum is rotating, the active ingredient passes through and is added onto the substrate.
図８は、図８ａ、８ｂ、８ｃ、８ｄ、８ｅに示すように、加圧自動添加装置を使って有効成分の供給を分離して複数の有効成分を１つの基材上で組み合わせて、その後、溝のあるコアを通して移し、図８ｆ、８ｇ、８ｈ、８ｉ、及び８ｊに示すように分別放出して添加する別の方法の模式図である。 FIG. 8 illustrates a combination of multiple active ingredients on a single substrate after separating the active ingredient supply using a pressure auto-adder as shown in FIGS. 8a, 8b, 8c, 8d, and 8e. FIG. 9 is a schematic view of another method of transferring through a grooved core and adding by separate release as shown in FIGS.
図９は、図９ａ、９ｂ、及び９ｃに示すように、オーバーヘッド組み付け格納装置から供給される垂直間仕切りしたドラムローラーの模式図である。格納装置は、図９ｅに示すように同様に分割されている外部装置から有効成分を受ける。９ｆと９ｇに示すように、２つのドラムは、反対方向に回転し、穿孔及び／又はメッシュアパーチャが整列すると、有効成分が放出される。 FIG. 9 is a schematic view of a vertically partitioned drum roller supplied from an overhead assembly storage device as shown in FIGS. 9a, 9b, and 9c. The storage device receives active ingredients from external devices that are similarly divided as shown in FIG. 9e. As shown in 9f and 9g, the two drums rotate in opposite directions and the active ingredient is released when the perforations and / or mesh apertures are aligned.
図１０は、ドラムロールセットの模式図である。これは、図１０ａに示されるように外部供給装置により１種類の有効成分が供給され、それにより、有効成分が中空のコア（図１０ｂ）を通って内側ドラム（図１０ｃ）に移動し、図１０ｅに示すように一方向に回転し、穿孔を通って有効成分を放出し、それにより、有効成分が図１０ｄで示される第２のドラムに流入する。第２のドラムは、図１０ｆに示すように逆方向に回転し、そのときに、有効成分が基材表面上に添加される。 FIG. 10 is a schematic diagram of a drum roll set. This is because, as shown in FIG. 10a, one type of active ingredient is supplied by the external supply device, so that the active ingredient moves through the hollow core (FIG. 10b) to the inner drum (FIG. 10c). Rotate in one direction as shown in 10e and release the active ingredient through the perforations, whereby the active ingredient flows into the second drum shown in FIG. 10d. The second drum rotates in the opposite direction as shown in FIG. 10f, at which time the active ingredient is added onto the substrate surface.
Claims (51)
（ｂ）食品等級ポリマー及び接着剤を含む最内層と、
前記最外層と前記最内層との間に挿入される次の層：少なくとも１種の超吸収ポリマー及び活性炭を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層と
をさらに含む、請求項１に記載のポリマー積層体。 (A) an outermost layer comprising a textile thermoplastic polymer material comprising at least one rodent repellent and a UV blocking substance, and a layer comprising at least one pesticide and / or insecticide;
(B) an innermost layer comprising a food grade polymer and an adhesive;
2. The further layer inserted between the outermost layer and the innermost layer: a biocomposite layer comprising a thermoplastic yarn mesh comprising at least one superabsorbent polymer and activated carbon. Polymer laminate.
ｂ）食品等級ポリマー及び接着剤を含む最内層と、前記最外層と前記最内層との間に挿入される次の層：
ｃ）織物熱可塑性ポリマー材料、及び
ｄ）少なくとも１種の殺虫剤を含むバブルを含むバブルプラスチック熱可塑性ポリマー材料層と、
ｅ）少なくとも１種の超吸収ポリマー及び活性炭を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層と
を含む、
請求項１に記載のポリマー積層体。
ポリマー積層体−共押出タイプ a) an outermost layer comprising a thermoplastic polymer material comprising at least one rodent repellent;
b) The innermost layer comprising food grade polymer and adhesive and the next layer inserted between the outermost layer and the innermost layer:
a bubble plastic thermoplastic polymer material layer comprising c) a woven thermoplastic polymer material, and d) a bubble comprising at least one pesticide.
e) a biocomposite layer comprising a thermoplastic yarn mesh comprising at least one superabsorbent polymer and activated carbon;
The polymer laminate according to claim 1.
Polymer laminate-coextrusion type
ｂ）食品等級ポリマー及び接着剤を含む最内層と、
前記最外層と前記最内層との間に挿入される次の層：
ｃ）乾燥剤、フリーラジカル捕捉剤又は酸素バリアとして機能する少なくとも１種の添加物を含む熱可塑性ポリマー材料を含む酸素バリア中間層と、
ｄ）少なくとも１種の超吸収ポリマー及び活性炭を含む熱可塑性ポリマー材料を含むバイオ複合材料吸収剤／相溶化剤層と
を含むポリマー積層体。 a) an outermost layer comprising a thermoplastic polymeric material comprising at least one rodent repellent, at least one pesticide and / or insecticide, and a UV blocking substance;
b) an innermost layer comprising a food grade polymer and an adhesive;
The next layer inserted between the outermost layer and the innermost layer:
c) an oxygen barrier interlayer comprising a thermoplastic polymer material comprising a desiccant, a free radical scavenger or at least one additive that functions as an oxygen barrier;
d) A polymer laminate comprising a biocomposite absorbent / compatibilizer layer comprising a thermoplastic polymer material comprising at least one superabsorbent polymer and activated carbon.
を含む、請求項１５に記載のポリマー積層体。 16. The outermost layer comprises a first layer comprising a polyolefin, a rodent repellent and a UV blocking substance, and a second layer comprising a thermoplastic polymer material and at least one insecticide or control substance. The polymer laminate described.
ｂ）食品等級ポリマー及び接着剤を含む最内層と、前記最外層と前記最内層との間に挿入される次の層：
ｃ）熱可塑性ポリマー材料及び殺虫物質又は駆除物質を含む殺虫剤／駆除剤中間層と、
ｄ）エチレンビニルアルコール及びＥＭＭＡ及び無機／有機添加物を含む酸素バリア中間層と、
ｅ）超吸収ポリマーを含むバイオ複合材料吸収剤層と、
ｆ）活性竹炭及び相溶化剤を含むバイオ複合材料相溶化剤層と
を含むポリマー積層体。 a) an outermost layer comprising a polyolefin, a rodent repellent and an ultraviolet blocking substance;
b) The innermost layer comprising food grade polymer and adhesive and the next layer inserted between the outermost layer and the innermost layer:
c) an insecticide / disinfectant interlayer comprising a thermoplastic polymer material and an insecticide or disinfectant;
d) an oxygen barrier interlayer comprising ethylene vinyl alcohol and EMMA and inorganic / organic additives;
e) a biocomposite absorbent layer comprising a superabsorbent polymer;
f) Polymer laminate comprising a biocomposite compatibilizer layer comprising activated bamboo charcoal and a compatibilizer.
ポリマー積層体−タイプ２ 21. The polymer laminate of claim 20, wherein the biocomposite compatibilizer layer comprises a compatibilizer selected from the group consisting of chitin and citric acid.
Polymer laminate-type 2
ｂ）食品等級ポリマー及び接着剤を含む最内層と、前記最外層と前記最内層との間に挿入される次の層：
ｃ）熱可塑性ポリマー材料、げっ歯類忌避物質及びエチルビニルアセテートを含むげっ歯類忌避剤中間層と、
ｄ）エチレンビニルアルコール及びＥＭＭＡ無機／有機添加物を含む酸素バリア中間層と、
ｅ）超吸収ポリマーを含むバイオ複合材料吸収剤層と、
ｆ）活性竹炭及び相溶化剤を含むバイオ複合材料相溶化剤層と
を含むポリマー積層体。
ポリマー積層体−メッシュタイプ a) outermost layer comprising polyolefin, insecticide / control substance, cuticle desiccant and UV blocking substance;
b) The innermost layer comprising food grade polymer and adhesive and the next layer inserted between the outermost layer and the innermost layer:
c) a rodent repellent intermediate layer comprising a thermoplastic polymer material, a rodent repellent and ethyl vinyl acetate;
d) an oxygen barrier intermediate layer comprising ethylene vinyl alcohol and EMMA inorganic / organic additives;
e) a biocomposite absorbent layer comprising a superabsorbent polymer;
f) Polymer laminate comprising a biocomposite compatibilizer layer comprising activated bamboo charcoal and a compatibilizer.
Polymer laminate-mesh type
ｂ）食品等級ポリマー及び接着剤を含む最内層と、前記最外層と前記最内層との間に挿入される次の層：
ｃ）少なくとも１種の超吸収ポリマー及び活性炭を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層と
を含むポリマー積層体。 a) an outermost layer comprising a textile thermoplastic polymer material comprising at least one rodent repellent and an ultraviolet blocking substance, and a layer comprising at least one pesticide and / or insecticide;
b) The innermost layer comprising food grade polymer and adhesive and the next layer inserted between the outermost layer and the innermost layer:
c) A polymer laminate comprising a biocomposite layer comprising a thermoplastic yarn mesh comprising at least one superabsorbent polymer and activated carbon.
ｂ）食品等級ポリマー及び接着剤を含む最内層と、
前記最外層と前記最内層との間に挿入される次の層：
ｃ）織物熱可塑性ポリマー材料と、
ｄ）少なくとも１種の駆除剤及び／又は殺虫剤を含む熱可塑性ポリマー層と、
ｅ）少なくとも１種の超吸収ポリマー及び活性炭を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層と
を含むポリマー積層体。 a) an outermost layer comprising a thermoplastic polymer material comprising at least one rodent repellent;
b) an innermost layer comprising a food grade polymer and an adhesive;
The next layer inserted between the outermost layer and the innermost layer:
c) a woven thermoplastic polymer material;
d) a thermoplastic polymer layer comprising at least one pesticide and / or insecticide;
e) A polymer laminate comprising a biocomposite layer comprising a thermoplastic yarn mesh comprising at least one superabsorbent polymer and activated carbon.
ｂ）食品等級ポリマー及び接着剤を含む最内層と、前記最外層と前記最内層との間に挿入される次の層：
ｃ）少なくとも１種の超吸収ポリマー及び活性炭を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層と
を含むポリマー積層体。 a) an outermost layer comprising a textile thermoplastic polymer material comprising at least one rodent repellent and an ultraviolet blocking substance, and a layer comprising at least one pesticide and / or insecticide;
b) The innermost layer comprising food grade polymer and adhesive and the next layer inserted between the outermost layer and the innermost layer:
c) A polymer laminate comprising a biocomposite layer comprising a thermoplastic yarn mesh comprising at least one superabsorbent polymer and activated carbon.
ｂ）食品等級ポリマー及び接着剤を含む最内層と、前記最外層と前記最内層との間に挿入される次の層：
ｃ）少なくとも１種のげっ歯類忌避物質を含むバブルを含む第１のバブルプラスチック熱可塑性ポリマー材料層と、
ｄ）少なくとも１種の駆除剤及び／又は殺虫剤を含むバブルを含む第２のバブルプラスチック熱可塑性ポリマー材料層と、
ｅ）セルロース系又はその他の天然の吸収性材料及び／又は超吸収性ポリマーを封入する不織層又はその他のフィルター膜などの等価層と、
ｆ）少なくとも１種の超吸収ポリマー及び活性炭を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層と
を含むポリマー積層体。 a) an outermost layer comprising a thermoplastic polymer material comprising at least one UV blocking substance;
b) The innermost layer comprising food grade polymer and adhesive and the next layer inserted between the outermost layer and the innermost layer:
c) a first bubble plastic thermoplastic polymer material layer comprising a bubble comprising at least one rodent repellent;
d) a second bubble plastic thermoplastic polymer material layer comprising bubbles containing at least one pesticide and / or insecticide;
e) an equivalent layer such as a nonwoven layer or other filter membrane encapsulating cellulosic or other natural absorbent material and / or superabsorbent polymer;
f) A polymer laminate comprising a biocomposite layer comprising a thermoplastic yarn mesh comprising at least one superabsorbent polymer and activated carbon.
ｂ）食品等級ポリマー及び接着剤を含む最内層と、前記最外層と前記最内層との間に挿入される次の層：
ｃ）少なくとも１種のげっ歯類忌避物質を含むバブルを含む第１のバブルプラスチック熱可塑性ポリマー材料層と、
ｄ）少なくとも１種の駆除剤及び／又は殺虫剤を含むバブルを含む第２のバブルプラスチック熱可塑性ポリマー材料層と、
ｅ）「超吸収ポリマー」を含むバイオ複合材料吸収剤層と、
ｆ）活性「竹」炭及び相溶化剤を含むバイオ複合材料相溶化剤層と
を、含むポリマー積層体。
収穫農産物用ポリマー貯蔵容器 a) an outermost layer comprising a thermoplastic polymer material comprising at least one UV blocking substance;
b) The innermost layer comprising food grade polymer and adhesive and the next layer inserted between the outermost layer and the innermost layer:
c) a first bubble plastic thermoplastic polymer material layer comprising a bubble comprising at least one rodent repellent;
d) a second bubble plastic thermoplastic polymer material layer comprising bubbles containing at least one pesticide and / or insecticide;
e) a biocomposite absorbent layer comprising a “superabsorbent polymer”;
f) Polymer laminate comprising an active “bamboo” charcoal and a biocomposite compatibilizer layer comprising a compatibilizer.
Polymer storage container for harvested agricultural products
収穫農産物の貯蔵システム It is a polymer storage container for harvested agricultural products, Comprising: The container containing the polymer laminated body of any one of Claims 1-21.
Harvested produce storage system
殺虫剤積層体を含むバブルプラスチック材料 A system for storage of harvested agricultural products, comprising a container made from the polymer laminate of any one of claims 1-21.
Bubble plastic material containing pesticide laminates
（ｂ）食品等級ポリマー及び接着剤を含む最内層と、
前記最外層と前記最内層との間に挿入される次の層：
少なくとも１種の超吸収ポリマー及び活性炭を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層と
をさらに含む、請求項３８に記載のポリマー積層体。 (A) an outermost layer comprising a textile thermoplastic polymer material comprising at least one rodent repellent and a UV blocking substance, and a layer comprising at least one pesticide and / or insecticide;
(B) an innermost layer comprising a food grade polymer and an adhesive;
The next layer inserted between the outermost layer and the innermost layer:
39. The polymer laminate of claim 38, further comprising a biocomposite layer comprising a thermoplastic yarn mesh comprising at least one superabsorbent polymer and activated carbon.
ｂ）食品等級ポリマー及び接着剤を含む最内層と、前記最外層と前記最内層との間に挿入される次の層：
ｃ）織物熱可塑性ポリマー材料、及び
ｄ）少なくとも１種の殺虫剤を含むバブルを含むバブルプラスチック熱可塑性ポリマー材料層と、
ｅ）少なくとも１種の超吸収ポリマー及び活性炭を含む熱可塑性樹脂ヤーンメッシュを含むバイオ複合材料層と
を含む、請求項４９に記載のポリマー積層体。
a) an outermost layer comprising a thermoplastic polymer material comprising at least one rodent repellent;
b) The innermost layer comprising food grade polymer and adhesive and the next layer inserted between the outermost layer and the innermost layer:
a bubble plastic thermoplastic polymer material layer comprising c) a woven thermoplastic polymer material, and d) a bubble comprising at least one pesticide.
50. The polymer laminate of claim 49, comprising: e) a biocomposite layer comprising a thermoplastic yarn mesh comprising at least one superabsorbent polymer and activated carbon.
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| US61/811,324 | 2013-04-12 | ||
| PCT/US2013/069446 WO2014074992A2 (en) | 2012-11-09 | 2013-11-11 | Polymeric film for agricultural product storage, containers made therefrom and related methods of agricultural product storage |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20200036138A (en) * | 2018-09-27 | 2020-04-07 | 한국생산기술연구원 | Method for preparing multilayered polymeric sheet capable of degassing comprising foamed polymeric layer |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20180117886A1 (en) * | 2014-04-30 | 2018-05-03 | The Wilpak Group Pty Ltd | Pest repellent and/or recyclable multilayer sheet material and packaging made therefrom |
| GB201418924D0 (en) * | 2014-10-24 | 2014-12-10 | A To Z Textile Mills Ltd | Storage bag |
| US10638671B2 (en) | 2016-04-05 | 2020-05-05 | Fresh Cut Tech Llc | Adhesive membrane used to preserve the fresh cut characteristics of a christmas tree base |
| MX2020005253A (en) * | 2017-11-21 | 2020-11-09 | Vestergaard S A R L | A hermetic, insecticidal food storage bag, use of it and a method for its production. |
| KR101888320B1 (en) * | 2017-12-26 | 2018-09-10 | 박훈 | The grain sack with blocking UV |
| KR101882150B1 (en) * | 2017-12-26 | 2018-07-25 | 박훈 | The grain sack with blocking UV |
| US11926123B2 (en) | 2019-05-17 | 2024-03-12 | Mucell Extrusion, Llc | Multi-layer polymer foam film for packaging applications and the method of making the same |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3576051A (en) * | 1969-05-14 | 1971-04-27 | Petro Tex Chem Corp | Apparatus for producing thermoplastic film |
| JPS57205117A (en) * | 1981-06-15 | 1982-12-16 | Nippon Petrochem Co Ltd | Manufacture of laminated film |
| JPS62230702A (en) * | 1986-03-31 | 1987-10-09 | Nippon Petrochem Co Ltd | Film containing rodenticide |
| US6852328B1 (en) * | 1989-09-01 | 2005-02-08 | Battelle Memorial Institute K1-53 | Method and device for protection of wooden objects proximate soil from pest invasion |
| AU9201498A (en) * | 1997-08-22 | 1999-03-16 | Cryovac, Inc. | Pesticidal packaging materials |
| US5906825A (en) * | 1997-10-20 | 1999-05-25 | Magellan Companies, Inc. | Polymers containing antimicrobial agents and methods for making and using same |
| US5985304A (en) * | 1998-02-25 | 1999-11-16 | Battelle Memorial Institute | Barrier preventing wood pest access to wooden structures |
| IL123665A (en) * | 1998-03-13 | 2000-08-13 | Atifon Ltd | Container for agricultural produce |
| BR0005598B1 (en) * | 1999-09-16 | 2013-03-19 | Method to protect a growing plant against creeping insects. | |
| US6322873B1 (en) * | 1999-09-17 | 2001-11-27 | Furio Orologio | Fire retardant cavity filled insulation pack |
| IL139388A (en) * | 2000-11-01 | 2005-09-25 | Makhteshim Chem Works Ltd | Pest control sheet |
| US20110240064A1 (en) * | 2002-09-09 | 2011-10-06 | Reactive Surfaces, Ltd. | Polymeric Coatings Incorporating Bioactive Enzymes for Cleaning a Surface |
| US8383549B2 (en) * | 2007-07-20 | 2013-02-26 | Bayer Cropscience Lp | Methods of increasing crop yield and controlling the growth of weeds using a polymer composite film |
| CN103477922B (en) * | 2007-07-20 | 2017-10-10 | 伊玛弗莱克斯股份有限公司 | Polymer composites with biocide functionality |
| US8141328B2 (en) * | 2009-01-26 | 2012-03-27 | Grainpro, Inc. | System and method for free-standing storage of agricultural commodities using a hermetic lightweight sleeve |
-
2013
- 2013-11-11 SG SG11201503536YA patent/SG11201503536YA/en unknown
- 2013-11-11 CA CA2890932A patent/CA2890932A1/en not_active Abandoned
- 2013-11-11 AP AP2015008490A patent/AP2015008490A0/en unknown
- 2013-11-11 KR KR1020157015343A patent/KR20150083912A/en not_active Application Discontinuation
- 2013-11-11 MX MX2015005826A patent/MX2015005826A/en unknown
- 2013-11-11 JP JP2015541980A patent/JP2016505402A/en active Pending
- 2013-11-11 AU AU2013342066A patent/AU2013342066A1/en not_active Abandoned
- 2013-11-11 CN CN201380068964.3A patent/CN105579002A/en active Pending
- 2013-11-11 EP EP13853952.3A patent/EP2916787A4/en not_active Withdrawn
- 2013-11-11 RU RU2015118061A patent/RU2015118061A/en unknown
- 2013-11-11 WO PCT/US2013/069446 patent/WO2014074992A2/en active Application Filing
- 2013-11-11 PE PE2015000608A patent/PE20151082A1/en not_active Application Discontinuation
-
2015
- 2015-05-07 IL IL238707A patent/IL238707A0/en unknown
- 2015-05-08 CL CL2015001251A patent/CL2015001251A1/en unknown
- 2015-06-05 ZA ZA2015/04059A patent/ZA201504059B/en unknown
-
2016
- 2016-03-14 HK HK16102927.6A patent/HK1214941A1/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20200036138A (en) * | 2018-09-27 | 2020-04-07 | 한국생산기술연구원 | Method for preparing multilayered polymeric sheet capable of degassing comprising foamed polymeric layer |
| KR102132345B1 (en) * | 2018-09-27 | 2020-07-10 | 한국생산기술연구원 | Method for preparing multilayered polymeric sheet capable of degassing comprising foamed polymeric layer |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20150083912A (en) | 2015-07-20 |
| CA2890932A1 (en) | 2014-05-15 |
| AU2013342066A1 (en) | 2015-05-21 |
| MX2015005826A (en) | 2015-12-17 |
| PE20151082A1 (en) | 2015-08-27 |
| EP2916787A2 (en) | 2015-09-16 |
| AP2015008490A0 (en) | 2015-05-31 |
| CN105579002A (en) | 2016-05-11 |
| RU2015118061A (en) | 2016-12-27 |
| IL238707A0 (en) | 2015-06-30 |
| EP2916787A4 (en) | 2016-04-27 |
| ZA201504059B (en) | 2016-04-28 |
| CL2015001251A1 (en) | 2016-01-15 |
| WO2014074992A3 (en) | 2014-10-02 |
| HK1214941A1 (en) | 2016-08-12 |
| WO2014074992A2 (en) | 2014-05-15 |
| SG11201503536YA (en) | 2015-06-29 |
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