JP2015522674A - フィッシャートロプシュ合成および排ガス利用方法 - Google Patents
フィッシャートロプシュ合成および排ガス利用方法 Download PDFInfo
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- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
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- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/108—Hydrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
- B01D2257/7022—Aliphatic hydrocarbons
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
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- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/20—Capture or disposal of greenhouse gases of methane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
- Y02P20/156—Methane [CH4]
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Abstract
Description
Claims (10)
- フィッシャートロプシュ合成および排ガス利用方法であって、
1) フィッシャートロプシュ合成原料ガスを変換浄化してからフィッシャートロプシュ合成反応装置に送り、該フィッシャートロプシュ合成反応装置の操作条件を、温度150〜300℃、圧力2〜4MPa(A)として、鉄系またはコバルト系触媒を利用してフィッシャートロプシュ合成を行い、液体炭化水素生成物および水を生成し、水を前記装置から排出させる工程と、
2) 工程1で生成されたフィッシャートロプシュ合成の排ガスを圧力スイング吸着水素分離装置に導入し、フィッシャートロプシュ合成排ガスから水素を回収するとともに、水素の純度を80〜99%に制御する工程と、
3) 工程2の排ガスを圧力スイング吸着メタン分離装置に導入してメタンを回収するとともに、メタンの純度を80〜95%に制御する工程と、
4) 工程2の圧力スイング吸着から得られた水素の一部を工程1に戻してフィッシャートロプシュ合成の原料ガスと混合させ、再度変換浄化工程に送り、フィッシャートロプシュ合成原料ガスの水素/炭素比を調整する工程と、
5) 工程3で生成されたメタンをメタン改質装置に導入して改質を行うことにより、水素/炭素比が高い合成ガスを生成し、工程1に送りフィッシャートロプシュ合成原料ガスと混合させ、再度変換浄化工程に送り、フィッシャートロプシュ合成原料ガスの水素/炭素比を調整する工程と
を含む方法。 - 前記工程2の圧力スイング吸着により回収され、工程1のフィッシャートロプシュ合成原料ガスと混合され、変換浄化工程に送られ、フィッシャートロプシュ合成原料ガスの水素/炭素比が調整される水素の一部は、回収された水素の30〜60%を占め、回収された水素の2〜8%がフィッシャートロプシュ合成触媒の活性化および還元工程に送られ、残りの水素がフィッシャートロプシュ合成による液体炭化水素生成物の後続加工工程に送られる、請求項1のフィッシャートロプシュ合成および排ガス利用方法。
- 前記工程3で生成されるCH4が除去された排ガスは炭化水素改質ユニットに導入されて、炭化水素改質ユニットの燃料として用いられ、或いは、燃焼用に送られて給熱或いは発電を行う、請求項1または2のフィッシャートロプシュ合成および排ガス利用方法。
- 前記工程2では、水素の純度は85〜95%に制御される、請求項1または2のフィッシャートロプシュ合成および排ガス利用方法。
- 前記工程3では、メタンの純度は90〜95%に制御される、請求項1または2のフィッシャートロプシュ合成および排ガス利用方法。
- 前記工程5では、メタン改質反応により生成された水素/炭素比が高い合成ガスは、H2/CO体積比が2〜5である、請求項1または2のフィッシャートロプシュ合成および排ガス利用方法。
- 前記工程5では、メタン改質反応により生成された水素/炭素比が高い合成ガスは、H2/CO体積比が3〜4である、請求項1または2のフィッシャートロプシュ合成および排ガス利用方法。
- 前記工程3では、メタンの純度は90〜95%に制御される、請求項4のフィッシャートロプシュ合成および排ガス利用方法。
- 前記工程5では、メタン改質反応により生成された水素/炭素比が高い合成ガスは、H2/CO体積比が3〜4である、請求項4のフィッシャートロプシュ合成および排ガス利用方法。
- 前記工程5では、メタン改質反応により生成された水素/炭素比が高い合成ガスは、H2/CO体積比が3〜4である、請求項5のフィッシャートロプシュ合成および排ガス利用方法。
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CN201210213566.3 | 2012-06-26 | ||
CN201210213566.3A CN102703108B (zh) | 2012-06-26 | 2012-06-26 | 一种费托合成及尾气利用的工艺方法 |
PCT/CN2013/074719 WO2014000502A1 (zh) | 2012-06-26 | 2013-04-25 | 一种费托合成及尾气利用的工艺方法 |
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JP2015522674A true JP2015522674A (ja) | 2015-08-06 |
JP6040309B2 JP6040309B2 (ja) | 2016-12-07 |
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US (1) | US9255226B2 (ja) |
EP (1) | EP2865731B1 (ja) |
JP (1) | JP6040309B2 (ja) |
CN (1) | CN102703108B (ja) |
DK (1) | DK2865731T3 (ja) |
RU (1) | RU2594723C2 (ja) |
WO (1) | WO2014000502A1 (ja) |
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CN102703108B (zh) * | 2012-06-26 | 2014-12-03 | 武汉凯迪工程技术研究总院有限公司 | 一种费托合成及尾气利用的工艺方法 |
CN104357078A (zh) * | 2014-11-10 | 2015-02-18 | 华玉叶 | 一种固定床费托合成方法 |
CN105154125A (zh) * | 2015-07-10 | 2015-12-16 | 北京宝塔三聚能源科技有限公司 | 一种由合成气联产甲烷、石蜡和高碳烯烃的转化工艺 |
CN106221720B (zh) * | 2016-08-19 | 2018-03-13 | 武汉凯迪工程技术研究总院有限公司 | 选择性催化氧化转化费托合成尾气的综合利用工艺 |
CN108384572B (zh) * | 2018-03-12 | 2020-04-24 | 国家能源投资集团有限责任公司 | 一种费托合成气联产氢气的氢碳比调节方法及*** |
CN109762589B (zh) * | 2019-03-21 | 2019-12-27 | 北京大学 | 利用co和水制备烃类产物的方法 |
GB2586867A (en) * | 2019-09-06 | 2021-03-10 | English Michael | Process for producing one or more hydrocarbon products |
CN110776941B (zh) * | 2019-10-25 | 2020-07-31 | 菏泽学院 | 一种带有甲烷三重整的生物质制氢装置及方法 |
DE102020128868A1 (de) | 2020-11-03 | 2022-05-05 | Karlsruher Institut für Technologie | Umwandlung von CO2 in chemische Energieträger und Produkte |
CN115055028B (zh) * | 2022-08-08 | 2022-11-29 | 中国华能集团清洁能源技术研究院有限公司 | 碳捕集***及方法 |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2007517084A (ja) * | 2003-11-25 | 2007-06-28 | シェブロン ユー.エス.エー. インコーポレイテッド | 複数の反応器を用いたフィッシャー・トロプシュ装置からのco2放出の制御 |
US7300642B1 (en) * | 2003-12-03 | 2007-11-27 | Rentech, Inc. | Process for the production of ammonia and Fischer-Tropsch liquids |
US20080132588A1 (en) * | 2003-12-03 | 2008-06-05 | Rentech, Inc. | Apparatus and methods for the production of ammonia and fischer-tropsch liquids |
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Publication number | Publication date |
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EP2865731A1 (en) | 2015-04-29 |
WO2014000502A1 (zh) | 2014-01-03 |
EP2865731B1 (en) | 2017-10-04 |
US9255226B2 (en) | 2016-02-09 |
US20150099813A1 (en) | 2015-04-09 |
CN102703108A (zh) | 2012-10-03 |
RU2015102091A (ru) | 2016-08-10 |
JP6040309B2 (ja) | 2016-12-07 |
RU2594723C2 (ru) | 2016-08-20 |
DK2865731T3 (en) | 2018-01-15 |
EP2865731A4 (en) | 2016-03-09 |
CN102703108B (zh) | 2014-12-03 |
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