JP2015224199A - Hair cosmetic - Google Patents
Hair cosmetic Download PDFInfo
- Publication number
- JP2015224199A JP2015224199A JP2014108484A JP2014108484A JP2015224199A JP 2015224199 A JP2015224199 A JP 2015224199A JP 2014108484 A JP2014108484 A JP 2014108484A JP 2014108484 A JP2014108484 A JP 2014108484A JP 2015224199 A JP2015224199 A JP 2015224199A
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- JP
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- Prior art keywords
- mass
- component
- hair
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- hair cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 46
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims description 35
- 125000004432 carbon atom Chemical group C* 0.000 claims description 28
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- 239000003676 hair preparation Substances 0.000 claims description 11
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- 239000004006 olive oil Substances 0.000 description 1
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- 229960005323 phenoxyethanol Drugs 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
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- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
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- 229930003231 vitamin Natural products 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
本発明は、シャンプー洗髪後に使用される、ヘアリンス、ヘアコンディショナー、ヘアトリートメント、ヘアパック等の毛髪化粧料に関する。 The present invention relates to hair cosmetics such as hair rinses, hair conditioners, hair treatments and hair packs used after shampooing.
洗髪中の指通り性能を高めるために、シャンプーには“コアセルベーション”と呼ばれる技術が応用されている。コアセルベーションは、シャンプー中に含まれるアニオン界面活性剤とカチオン化ポリマーが洗髪後水ですすがれる過程で、不溶性の複合体を形成し、毛髪表面に吸着することで、洗髪及びすすぎの際における毛髪表面の摩擦を低減し、滑らかな指通りを与えることができる技術である。 A technique called “coacervation” is applied to shampoos in order to improve the fingering performance during shampooing. Coacervation is a process in which an anionic surfactant and a cationized polymer contained in a shampoo are rinsed with water after washing, forming an insoluble complex and adsorbing to the hair surface during washing and rinsing. It is a technique that can reduce the friction of the hair surface and give a smooth finger passage.
一方、シャンプーによる洗髪に続いて使用される、ヘアリンスやヘアコンディショナー、ヘアトリートメント、ヘアマスク(以後、まとめてヘアコンディショナーと称する)は、シリコーンなどの油性成分と一般的にアルキル鎖長16以上のカチオン界面活性剤と高級アルコールを含有し、ダメージを受けた毛髪に柔らかさや滑らかな指通りといった性能を与えることができる(例えば、特許文献1参照)。これは、カチオン界面活性剤や高級アルコール、シリコーンなどの潤滑成分が毛髪表面に効率よく吸着するためである。 On the other hand, hair rinses, hair conditioners, hair treatments, and hair masks (hereinafter collectively referred to as hair conditioners) that are used following shampooing shampoos are oily components such as silicone and cationic interfaces that generally have an alkyl chain length of 16 or more. It contains an active agent and a higher alcohol, and can give performance such as softness and smooth fingering to damaged hair (see, for example, Patent Document 1). This is because lubricating components such as cationic surfactants, higher alcohols, and silicones are efficiently adsorbed on the hair surface.
ヘアコンディショナーに含まれる前記潤滑成分は、洗髪に用いたシャンプーがコアセルベーション技術を利用したものではない場合(すなわちカチオン化ポリマーを含有しない場合)には、毛髪に十分に吸着し、本来のコンディショニング性能を発揮することができる。しかし、洗髪に用いたシャンプーがコアセルベーション技術を利用したもの(以下、「コアセルベーションシャンプー」と称する)である場合には、前記潤滑成分は、毛髪への吸着が阻害され、コンディショニング性能が著しく低下する。これは、コアセルベーションシャンプーによる摩擦低減性能が高いほど顕著であった。つまり、コアセルベーションシャンプーによる摩擦低減性能とヘアコンディショナーのコンディショニング性能とはトレードオフの関係にあり、従来の技術ではこれらを両立することは困難であった。 When the shampoo used for washing the hair does not use coacervation technology (that is, when it does not contain a cationized polymer), the lubricating component contained in the hair conditioner is sufficiently adsorbed to the hair and is the original conditioning. Performance can be demonstrated. However, when the shampoo used for washing the hair uses a coacervation technique (hereinafter referred to as “coacervation shampoo”), the lubricating component is inhibited from adsorbing to the hair and has a conditioning performance. It drops significantly. This was more remarkable as the friction reduction performance by the coacervation shampoo was higher. That is, there is a trade-off relationship between the friction reduction performance by the coacervation shampoo and the conditioning performance of the hair conditioner, and it has been difficult to achieve both of them with the conventional technology.
従って本発明は、コアセルベーションシャンプーにより洗髪した毛髪であっても、高いコンディショニング性能を発揮するヘアコンディショナー等の毛髪化粧料に関するものである。 Accordingly, the present invention relates to a hair cosmetic composition such as a hair conditioner that exhibits high conditioning performance even for hair that has been washed with a coacervation shampoo.
コアセルベーションシャンプーによる毛髪の処理によってヘアコンディショナーの性能が低下する原因は、前記シャンプーの濯ぎ後に毛髪表面に残留するアニオン界面活性剤/カチオン化ポリマー複合体が、ヘアコンディショナー成分である潤滑成分の吸着を阻害しているためであると考えられる。そこで本発明者は、シャンプー後の毛髪表面に残留する前記複合体の影響を受けにくいヘアコンデショナーの開発を行った。 The reason why the performance of the hair conditioner is deteriorated by the treatment of the hair with the coacervation shampoo is that the anionic surfactant / cationized polymer complex remaining on the hair surface after the shampoo is rinsed is adsorbed to the lubricating component. It is thought that this is because of the inhibition. Therefore, the present inventor has developed a hair conditioner that is not easily affected by the complex remaining on the hair surface after shampooing.
その結果、特定のアルキル鎖を持つ3種類のカチオン界面活性剤を組み合わせることで、コアセルベーションシャンプーによる性能低下を抑制し、ヘアコンディショナー本来の潤滑性能を維持できることを発見した。 As a result, it was discovered that by combining three kinds of cationic surfactants having specific alkyl chains, the performance degradation due to coacervation shampoo can be suppressed and the original lubrication performance of the hair conditioner can be maintained.
本発明は、次の成分(A)〜(C)を含有し、成分(A)と成分(C)の質量比(A)/(C)が3以上200以下、成分(B)と成分(C)の質量比(B)/(C)が1を超え100以下である毛髪化粧料を提供するものである。
(A):炭素数18〜24のアルキル基を1つ有するモノ長鎖アルキル型カチオン界面活性剤
0.05質量%以上15質量%以下
(B):炭素数10〜18のアルキル鎖を2つ有するジ長鎖アルキル型カチオン界面活性剤
0.01質量%以上5質量%以下
(C):炭素数12〜17のアルキル基を1つ有するモノ長鎖アルキル型カチオン界面活性剤
The present invention contains the following components (A) to (C), the mass ratio (A) / (C) of the component (A) to the component (C) is 3 or more and 200 or less, the component (B) and the component ( The present invention provides a hair cosmetic composition wherein the mass ratio (B) / (C) of C) is more than 1 and 100 or less.
(A): Mono long chain alkyl type cationic surfactant having one alkyl group having 18 to 24 carbon atoms
0.05% to 15% by mass
(B): Di-long-chain alkyl cationic surfactant having two alkyl chains having 10 to 18 carbon atoms
0.01% to 5% by mass
(C): Mono long chain alkyl type cationic surfactant having one alkyl group having 12 to 17 carbon atoms
本発明の毛髪化粧料は、カチオン化ポリマーを含まないシャンプーと組み合わせ使用した場合に、十分なコンデショニング効果を発揮するのみならず、コアセルベーションシャンプーと組み合わせて使用した場合でもコンディショニング性能を十分発揮することができる。これにより、毛髪への塗布時の濃厚感、馴染み易さ、すすぎ時の柔らかさ、指通りの良さ、タオルドライ時の柔らかさ、指通りの良さ、ドライヤーによるブロー時の乾かしやすさ、指通りの良さ、乾燥後の指通りの良さ、均質感、ダメージにより親水化してしまった毛髪表面の疎水化、次の洗髪時の指通りの良さ、均質感等の種々の効果を効果的に発揮することができる。 The hair cosmetic composition of the present invention not only exhibits a sufficient conditioning effect when used in combination with a shampoo containing no cationized polymer, but also exhibits a sufficient conditioning performance when used in combination with a coacervation shampoo. can do. As a result, it has a rich feeling when applied to hair, ease of familiarization, softness when rinsing, good fingering, softness when towel is dried, goodness when fingering, ease of drying when drying with a dryer, Effectively exhibits various effects such as goodness of fingers, goodness of fingering after drying, homogeneity, hydrophobicity of hair surface that has become hydrophilic due to damage, goodness of fingering during the next shampoo, homogeneity, etc. be able to.
〔成分(A):炭素数18〜24のアルキル基を1つ有するモノ長鎖アルキル型カチオン界面活性剤〕
成分(A)としては、下記一般式(1)に示すモノ長鎖アルキル型四級アンモニウム塩が挙げられる。
[Component (A): Mono long-chain alkyl cationic surfactant having one alkyl group having 18 to 24 carbon atoms]
Examples of the component (A) include mono long-chain alkyl quaternary ammonium salts represented by the following general formula (1).
〔式中、R1は炭素数18〜24のアルキル基を示し、X-は陰イオンを示す。〕 [Wherein, R 1 represents an alkyl group having 18 to 24 carbon atoms, and X − represents an anion. ]
R1としては、炭素数18〜22のアルキル基が好ましく、また直鎖のアルキル基が好ましい。陰イオンX-としては、塩化物イオン、臭化物イオン等のハロゲン化物イオン;メトサルフェートイオン、エトサルフェートイオン、メトフォスフェートイオン、エトフォスフェートイオン、メトカーボナートイオン等の無機・有機陰イオン等が挙げられ、メトサルフェートイオン、エトサルフェートイオン、塩化物イオンが好ましい。 R 1 is preferably an alkyl group having 18 to 22 carbon atoms, and is preferably a linear alkyl group. Examples of the anion X − include halide ions such as chloride ion and bromide ion; inorganic and organic anions such as methosulfate ion, ethosulfate ion, methophosphate ion, ethophosphate ion, methocarbonate ion, etc. And methosulphate ion, ethosulphate ion and chloride ion are preferable.
成分(A)の好ましい具体例としては、ステアリルトリメチルアンモニウム塩、アラキルトリメチルアンモニウム塩、ベヘニルトリメチルアンモニウム塩が挙げられ、ステアリルトリメチルアンモニウム塩、ベヘニルトリメチルアンモニウム塩が好ましい。 Preferred specific examples of component (A) include stearyl trimethyl ammonium salt, aralkyl trimethyl ammonium salt, and behenyl trimethyl ammonium salt, and stearyl trimethyl ammonium salt and behenyl trimethyl ammonium salt are preferred.
成分(A)は単独で又は2種類以上を組み合わせて使用することができる。本発明の毛髪化粧料中における成分(A)の含有量は、塗布・濯ぎ・タオルドライ時の毛髪を柔らかくする観点から、0.05質量%以上、好ましくは0.1質量%以上、より好ましくは0.5質量%以上であり、また、15質量%以下、好ましくは5質量%以下、より好ましくは3質量%以下である。 Component (A) can be used alone or in combination of two or more. The content of the component (A) in the hair cosmetic composition of the present invention is 0.05% by mass or more, preferably 0.1% by mass or more, more preferably 0.5% by mass, from the viewpoint of softening the hair during application, rinsing and towel drying. Further, it is 15% by mass or less, preferably 5% by mass or less, more preferably 3% by mass or less.
〔成分(B):炭素数10〜18のアルキル基を2つ有するジ長鎖アルキル型カチオン界面活性剤〕
成分(B)としては、下記一般式(2)に示すジ長鎖アルキル型四級アンモニウム塩が挙げられる。
[Component (B): Dilong-chain alkyl-type cationic surfactant having two alkyl groups having 10 to 18 carbon atoms]
Examples of the component (B) include dilong chain alkyl quaternary ammonium salts represented by the following general formula (2).
〔式中、R2及びR3は独立して、炭素数10〜18のアルキル基を示し、Y-は陰イオンを示す。〕 [Wherein, R 2 and R 3 independently represent an alkyl group having 10 to 18 carbon atoms, and Y − represents an anion. ]
R2及びR3としては、炭素数12〜18のアルキル基が好ましい。陰イオンY-としては、塩化物イオン、臭化物イオン等のハロゲン化物イオン;メトサルフェートイオン、エトサルフェートイオン、メトフォスフェートイオン、エトフォスフェートイオン、メトカーボナートイオン等の無機・有機陰イオン等が挙げられ、ハロゲン化物イオンが好ましく、塩化物イオンが更に好ましい。 R 2 and R 3 are preferably alkyl groups having 12 to 18 carbon atoms. Examples of the anion Y − include halide ions such as chloride ions and bromide ions; inorganic and organic anions such as methosulfate ions, ethosulfate ions, methophosphate ions, ethophosphate ions, and methocarbonate ions. Halide ions are preferred, and chloride ions are more preferred.
成分(B)の好ましい具体例としては、ジステアリルジメチルアンモニウム塩、ジセチルジメチルアンモニウム塩、ジイソステアリルジメチルアンモニウム塩、ジアルキル(C12-15)ジメチルアンモニウム塩、ジアルキル(C12-18)ジメチルアンモニウム塩、イソステアリルラウリルジメチルアンモニウム塩が挙げられ、ジアルキル(C12-15)ジメチルアンモニウム塩、ジアルキル(C12-18)ジメチルアンモニウム塩が好ましい。 Preferred specific examples of component (B) include distearyl dimethyl ammonium salt, dicetyl dimethyl ammonium salt, diisostearyl dimethyl ammonium salt, dialkyl (C12-15) dimethyl ammonium salt, dialkyl (C12-18) dimethyl ammonium salt, An isostearyl lauryl dimethyl ammonium salt is mentioned, A dialkyl (C12-15) dimethyl ammonium salt and a dialkyl (C12-18) dimethyl ammonium salt are preferable.
成分(B)は単独で又は2種類以上を組み合わせて使用することができる。本発明の毛髪化粧料中における成分(B)の含有量は、タオルドライ時、ドライヤー時、乾燥後の指通り性能を高める観点から、0.01質量%以上、好ましくは0.05質量%以上、より好ましくは0.1質量%以上であり、また、5質量%以下、好ましくは2.5質量%以下、より好ましくは1質量%以下、更に好ましくは0.38質量%以下である。 Component (B) can be used alone or in combination of two or more. The content of the component (B) in the hair cosmetic composition of the present invention is 0.01% by mass or more, preferably 0.05% by mass or more, more preferably from the viewpoint of improving the fingering performance after towel drying, at the time of drying, and drying. It is 0.1% by mass or more, 5% by mass or less, preferably 2.5% by mass or less, more preferably 1% by mass or less, and further preferably 0.38% by mass or less.
〔成分(C):炭素数12〜17のアルキル基を1つ有するモノ長鎖アルキル型カチオン界面活性剤〕
成分(C)としては、下記一般式(3)に示すモノ長鎖アルキル型四級アンモニウム塩が挙げられる。
[Component (C): Mono long chain alkyl type cationic surfactant having one alkyl group having 12 to 17 carbon atoms]
Examples of the component (C) include mono long chain alkyl quaternary ammonium salts represented by the following general formula (3).
〔式中、R4は炭素数12〜17のアルキル基を示し、Z-は陰イオンを示す。〕 [Wherein, R 4 represents an alkyl group having 12 to 17 carbon atoms, and Z − represents an anion. ]
R4としては、炭素数14〜16のアルキル基が好ましく、また直鎖のアルキル基が好ましい。陰イオンZ-としては、塩化物イオン、臭化物イオン等のハロゲン化物イオン;メトサルフェートイオン、エトサルフェートイオン、メトフォスフェートイオン、エトフォスフェートイオン、メトカーボナートイオン等の無機・有機陰イオン等が挙げられ、ハロゲン化物イオンが好ましく、塩化物イオンが更に好ましい。 R 4 is preferably an alkyl group having 14 to 16 carbon atoms, and is preferably a linear alkyl group. Examples of the anion Z − include halide ions such as chloride ions and bromide ions; inorganic and organic anions such as methosulfate ions, ethosulfate ions, methophosphate ions, ethophosphate ions, and methocarbonate ions. Halide ions are preferred, and chloride ions are more preferred.
成分(C)の好ましい具体例としては、ラウリルトリメチルアンモニウム塩、ミリスチルトリメチルアンモニウム塩、セチルトリメチルアンモニウム塩が挙げられ、セチルトリメチルアンモニウム塩が好ましい。 Preferable specific examples of component (C) include lauryltrimethylammonium salt, myristyltrimethylammonium salt and cetyltrimethylammonium salt, with cetyltrimethylammonium salt being preferred.
成分(C)は単独で又は2種類以上を組み合わせて使用することができる。本発明の毛髪化粧料中における成分(C)の含有量は、後述する成分(A)との質量比(A)/(C)、成分(B)との質量比(B)/(C)が所定の範囲内となるように決定されるが、塗布時の馴染みの良さと柔らかさを高める観点から、好ましくは0.005質量%以上、より好ましくは0.01質量%以上、更に好ましくは0.02質量%以上であり、また、好ましくは5質量%以下、より好ましくは2質量%以下、更に好ましくは1質量%以下、更に好ましくは0.4質量%以下である。 Component (C) can be used alone or in combination of two or more. The content of the component (C) in the hair cosmetic composition of the present invention is such that the mass ratio (A) / (C) with the component (A) described later, and the mass ratio (B) / (C) with the component (B). Is determined to be within a predetermined range, but from the viewpoint of improving the familiarity and softness at the time of application, preferably 0.005 mass% or more, more preferably 0.01 mass% or more, still more preferably 0.02 mass% or more Moreover, it is preferably 5% by mass or less, more preferably 2% by mass or less, further preferably 1% by mass or less, and further preferably 0.4% by mass or less.
本発明においては、成分(A)、(B)及び(C)の各カチオン界面活性剤の共存下で、成分(C)アルキル鎖長の短いカチオン界面活性剤が、毛髪表面上に残留するアニオン界面活性剤/カチオン化ポリマー複合体を収縮させる。このことにより、成分(A)アルキル鎖長の長いカチオン界面活性剤の毛髪への吸着が促進される。更に成分(B)ジ長鎖アルキル型カチオン界面活性剤が、残留するアニオン界面活性剤/カチオン化ポリマー複合体の潤滑性能を高めることでき、相乗的にヘアコンディショナーとしての高い潤滑性能を発揮できるものと推定される。 In the present invention, in the presence of each of the cationic surfactants of the components (A), (B) and (C), the component (C) a cationic surfactant having a short alkyl chain length remains on the hair surface. Shrink the surfactant / cationized polymer complex. This promotes the adsorption of the component (A) cationic surfactant having a long alkyl chain length to the hair. Furthermore, the component (B) di-long-chain alkyl cationic surfactant can enhance the lubricating performance of the remaining anionic surfactant / cationized polymer complex, and can synergistically exhibit high lubricating performance as a hair conditioner. It is estimated to be.
本発明の毛髪化粧料中における成分(A)と成分(C)との質量比(A)/(C)は、成分(A)の吸着を高め、タオルドライ時、ドライヤー時、乾燥後の指通り性能を高める観点から、3以上、好ましくは5以上、より好ましくは10以上であり、また、200以下、好ましくは100以下、より好ましくは50以下である。 The mass ratio (A) / (C) of the component (A) to the component (C) in the hair cosmetic composition of the present invention increases the adsorption of the component (A), and the finger after drying with a towel, drying with a dryer, From the viewpoint of improving the performance, it is 3 or more, preferably 5 or more, more preferably 10 or more, and 200 or less, preferably 100 or less, more preferably 50 or less.
本発明の毛髪化粧料中における成分(B)と成分(C)との質量比(B)/(C)は、成分(B)の吸着を高め、タオルドライ時、ドライヤー時、乾燥後の指通り性能を高める観点から、1を超え、好ましくは2以上、より好ましくは3以上であり、また、100以下、好ましくは50以下、より好ましくは25以下である。 The mass ratio (B) / (C) of the component (B) to the component (C) in the hair cosmetic composition of the present invention enhances the adsorption of the component (B), and the finger after drying with a towel, drying with a dryer, From the viewpoint of improving the performance, it is more than 1, preferably 2 or more, more preferably 3 or more, and 100 or less, preferably 50 or less, more preferably 25 or less.
〔(D):アミノ変性シリコーン〕
アミノ変性シリコーンとしては、下記一般式で表されるものが挙げられる。
[(D): amino-modified silicone]
Examples of the amino-modified silicone include those represented by the following general formula.
〔式中、R5はメチル基、水酸基又はR7−T(R7は炭素数3〜6のアルキレン基、Tは1〜3級アミノ基含有基又はアンモニウム基含有基)を示し、R6は−R8−Q(R8は炭素数3〜6のアルキレン基、Qは1〜3級アミノ基含有基又はアンモニウム基含有基)を示し、aは1以上の整数を示し、bは0以上の整数を示す。ただし、bが0である場合、R5は、−R7−Tである。また好ましい平均分子量は3000〜100000である。〕 [Wherein, R 5 represents a methyl group, a hydroxyl group or R 7 -T (R 7 is an alkylene group having 3 to 6 carbon atoms, T is a primary to tertiary amino group-containing group or an ammonium group-containing group), and R 6 -R 8 -Q (R 8 is an alkylene group having 3 to 6 carbon atoms, Q is a primary to tertiary amino group-containing group or ammonium group-containing group), a is an integer of 1 or more, and b is 0 The above integers are shown. However, if b is 0, R 5 is -R 7 -T. Moreover, a preferable average molecular weight is 3000-100,000. ]
上記一般式で表されるアミノ変性シリコーンとして、例えば、SS-3551、SF8452C(以上、東レ・ダウコーニング社製)、XF42-B1989(モメンティブ・パフォーマンス・マテリアルズ社製)等が挙げられる。アミノ変性シリコーンを水性乳濁液として用いる場合、該水性乳濁液中に含まれるアミノ変性シリコーンの量は20〜60質量%が好ましく、30〜50質量%が更に好ましい。好ましいアミノ変性シリコーン水性乳濁液としては、SM8904CE(東レ・ダウコーニング社製)、XS65-C0032(モメンティブ・パフォーマンス・マテリアルズ社製)が挙げられる。 Examples of the amino-modified silicone represented by the above general formula include SS-3551, SF8452C (manufactured by Toray Dow Corning), XF42-B1989 (manufactured by Momentive Performance Materials), and the like. When amino-modified silicone is used as an aqueous emulsion, the amount of amino-modified silicone contained in the aqueous emulsion is preferably 20 to 60% by mass, and more preferably 30 to 50% by mass. Preferred amino-modified silicone aqueous emulsions include SM8904CE (manufactured by Toray Dow Corning) and XS65-C0032 (manufactured by Momentive Performance Materials).
その他のアミノ変性シリコーンとしては、例えば下記一般式で表される「JP-8500 Conditioning Agent」(CAS No.237753-63-8、東レダウ・コーニング社製)、アミノ変性ポリシロキサン−ポリオキシアルキレンブロック共重合体が挙げられる。 Other amino-modified silicones include, for example, “JP-8500 Conditioning Agent” (CAS No.237753-63-8, manufactured by Toray Dow Corning) represented by the following general formula, amino-modified polysiloxane-polyoxyalkylene block A copolymer is mentioned.
〔式中、R9は炭素数13〜15の直鎖又は分岐鎖のアルキル基を示し、Wのうち75%は基−CH2CH(OH)CH2OHを、25%は水素原子を示す。〕 [Wherein R 9 represents a linear or branched alkyl group having 13 to 15 carbon atoms, 75% of W represents a group —CH 2 CH (OH) CH 2 OH, and 25% represents a hydrogen atom. . ]
アミノ変性ポリシロキサン−ポリオキシアルキレンブロック共重合体の好ましい例としては、下記一般式で表されるものが挙げられる。 Preferable examples of the amino-modified polysiloxane-polyoxyalkylene block copolymer include those represented by the following general formula.
〔式中、cは2以上の整数を示し、dは1以上の整数を示し、eは4以上の整数を示し、fは0〜30の整数を示し、gは2以上の整数を示す。〕 [Wherein, c represents an integer of 2 or more, d represents an integer of 1 or more, e represents an integer of 4 or more, f represents an integer of 0 to 30, and g represents an integer of 2 or more. ]
上記一般式において、好ましくは、cは2〜1,000の数、dは1〜50の数、eは4〜200の数、fは2〜100の数を示す。また、−O(C2H4O)e(C3H6O)f−はブロック共重合及びランダム共重合のいずれであってもよい。市販品の例としては、FZ-3789、シリコーンSS-3588(東レ・ダウコーニング社製)を挙げることができる。 In the above general formula, preferably, c is a number of 2 to 1,000, d is a number of 1 to 50, e is a number of 4 to 200, and f is a number of 2 to 100. Further, -O (C 2 H 4 O ) e (C 3 H 6 O) f - may be either a block copolymer or random copolymer. Examples of commercially available products include FZ-3789 and silicone SS-3588 (manufactured by Toray Dow Corning).
成分(D)は単独で又は2種類以上を組み合わせて使用することができる。本発明の毛髪化粧料中における成分(D)の含有量は、タオルドライ時、ドライヤー時、乾燥後の指通り性能、及び毛髪表面の疎水化を高める観点より、好ましくは0.01質量%以上、より好ましくは0.03質量%以上、更に好ましくは0.05質量%以上であり、また、好ましくは5質量%以下、より好ましくは3質量%以下、更に好ましくは1.5質量%以下である。 Component (D) can be used alone or in combination of two or more. The content of the component (D) in the hair cosmetic composition of the present invention is preferably 0.01% by mass or more, from the viewpoint of enhancing the fingering performance after drying with a towel, at the time of drying, and the hydrophobicity of the hair surface. Preferably it is 0.03 mass% or more, More preferably, it is 0.05 mass% or more, Preferably it is 5 mass% or less, More preferably, it is 3 mass% or less, More preferably, it is 1.5 mass% or less.
〔成分(E):高級アルコール〕
本発明の毛髪化粧料には、感触改善、安定性の観点から、更に成分(E)として、炭素数12以上の高級アルコールを含有させることができる。これらは、界面活性剤と構造体を形成して分離を防ぐと共に、すすぎ時の感触を改善する効果がある。
[Component (E): Higher alcohol]
The hair cosmetic composition of the present invention may further contain a higher alcohol having 12 or more carbon atoms as the component (E) from the viewpoint of improving touch and stability. These have the effect of forming a structure with a surfactant to prevent separation and improving the feel during rinsing.
高級アルコールとしては、炭素数12以上、更には16以上のものが好ましく、また、炭素数30以下、更には22以下のものが好ましい。具体的には、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、アラキルアルコール、ベヘニルアルコール、イソステアリルアルコール、2-オクチルドデカノール、オレイルアルコール等、及びこれらの混合物が挙げられる。 As the higher alcohol, those having 12 or more carbon atoms, more preferably 16 or more carbon atoms are preferable, and those having 30 or less carbon atoms, further 22 or less carbon atoms are preferable. Specific examples include myristyl alcohol, cetyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, isostearyl alcohol, 2-octyldodecanol, oleyl alcohol, and the like, and mixtures thereof.
成分(E)は単独で又は2種類以上を組み合わせて使用することができる。本発明の毛髪化粧料中における成分(E)の含有量は、ヘアコンディショナー製剤の粘度と安定性の観点より、好ましくは0.5質量%以上、より好ましくは1質量%以上、更に好ましくは2質量%以上であり、また、好ましくは20質量%以下、より好ましくは15質量%以下、更に好ましくは10質量%以下である。 Component (E) can be used alone or in combination of two or more. The content of the component (E) in the hair cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 1% by mass or more, and further preferably 2% by mass, from the viewpoint of the viscosity and stability of the hair conditioner preparation. Further, it is preferably 20% by mass or less, more preferably 15% by mass or less, and still more preferably 10% by mass or less.
〔その他の任意成分〕
本発明の毛髪化粧料には更に、毛髪化粧料に一般に使用されるその他の成分を、目的に応じて配合することができる。例えば、ジメチルポリシロキサン、ジメチコノール、ポリエーテル変性シリコーン、ポリグリシドール変性シリコーン、メチルフェニルポリシロキサン、脂肪酸変性シリコーン、アルコール変性シリコーン、アルコキシ変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、アルキル変性シリコーン等の成分(D)以外のシリコーン類;カチオン化セルロース、ヒドロキシ化セルロース、高重合ポリエチレンオキサイド等の高分子化合物;ポリオキシエチレンアルキルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、グリセリンモノ脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ショ糖脂肪酸エステル、ポリグリセリンアルキルエーテル、脂肪酸アルカノールアミド、アルキルグリコシド等の非イオン界面活性剤;スクワレン、スクワラン、流動パラフィン、流動イソパラフィン、シクロパラフィン等の炭化水素;ヒマシ油、カカオ油、ミンク油、アボカド油、オリーブ油等のグリセリド類;ミツロウ、鯨ロウ、ラノリン、カルナウバロウ等のロウ類;パルミチン酸イソプロピル、ミリスチン酸イソプロピル、ミリスチン酸オクチルドデシル、ラウリン酸ヘキシル、乳酸セチル、モノステアリン酸プロピレングリコール、オレイン酸オレイル、2-エチルヘキサン酸ヘキサデシル、イソノナン酸イソノニル、イソノナン酸トリデシル等のエステル;カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、オレイン酸、ヤシ油脂肪酸、イソステアリル酸、イソパルミチン酸等の高級脂肪酸、イソステアリルグリセリルエーテル、ポリオキシプロピレンブチルエーテルなどの油剤;エタノール、1-プロパノール、2-プロパノール、ブタノール、エチレングリコール、プロピレングリコール、ベンジルアルコール、フェノキシエタノール、2-ベンジルオキシエタノール、メチルカルビトール、エチルカルビトール、プロピルカルビトール、ブチルカルビトール、トリエチレングリコールモノエチルエーテル、トリエチレングリコールモノブチルエーテル、グリセリン等のアルコール類;ジンクピリチオン、塩化ベンザルコニウム等の抗フケ剤;pH調整剤;ビタミン剤;殺菌剤;抗炎症剤;防腐剤;キレート剤;パンテノール等の保湿剤;染料、顔料等の着色剤;ユーカリの極性溶媒抽出物、真珠層を有する貝殻又は真珠から得られる蛋白質又はその加水分解物、シルクから得られる蛋白質又はその加水分解物、マメ科植物の種子から得られる蛋白含有抽出物、オタネニンジン抽出物、米胚芽抽出物、ヒバマタ抽出物、ツバキ抽出物、アロエ抽出物、月桃葉抽出物、クロレラ抽出物等のエキス類;雲母チタン等のパール粉体;メントール等の清涼剤:香料;色素;紫外線吸収剤;酸化防止剤;その他エンサイクロペディア・オブ・シャンプー・イングリーディエンツ(ENCYCLOPEDIA OF SHAMPOO INGREDIENTS (MICELLE PRESS))に記載されている成分等が挙げられる。
[Other optional ingredients]
The hair cosmetic of the present invention may further contain other components generally used in hair cosmetics depending on the purpose. For example, components such as dimethylpolysiloxane, dimethiconol, polyether-modified silicone, polyglycidol-modified silicone, methylphenylpolysiloxane, fatty acid-modified silicone, alcohol-modified silicone, alkoxy-modified silicone, epoxy-modified silicone, fluorine-modified silicone, and alkyl-modified silicone ( Silicones other than D); polymer compounds such as cationized cellulose, hydroxylated cellulose, and highly polymerized polyethylene oxide; polyoxyethylene alkyl ether, polyoxyethylene sorbitan fatty acid ester, glycerin monofatty acid ester, polyglycerin fatty acid ester, polyoxy Ethylene hydrogenated castor oil, sucrose fatty acid ester, polyglycerin alkyl ether, fatty acid alkanolamide, alkylglycol Nonionic surfactants such as sid; hydrocarbons such as squalene, squalane, liquid paraffin, liquid isoparaffin, cycloparaffin; glycerides such as castor oil, cacao oil, mink oil, avocado oil, olive oil; beeswax, whale wax, lanolin Waxes such as carnauba wax; isopropyl palmitate, isopropyl myristate, octyldodecyl myristate, hexyl laurate, cetyl lactate, propylene glycol monostearate, oleyl oleate, hexadecyl 2-ethylhexanoate, isononyl isononanoate, isononanoic acid Esters such as tridecyl; higher fatty acids such as capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, coconut oil fatty acid, isostearyl acid, isopalmitic acid, isos Oils such as tearyl glyceryl ether and polyoxypropylene butyl ether; ethanol, 1-propanol, 2-propanol, butanol, ethylene glycol, propylene glycol, benzyl alcohol, phenoxyethanol, 2-benzyloxyethanol, methyl carbitol, ethyl carbitol, Alcohols such as propyl carbitol, butyl carbitol, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, glycerin; anti-dandruff agents such as zinc pyrithione and benzalkonium chloride; pH adjusters; vitamins; bactericides; Preservatives; chelating agents; moisturizers such as panthenol; colorants such as dyes and pigments; polar solvent extract of eucalyptus, shells or nacres with nacre, Hydrolyzate, protein obtained from silk or hydrolyzate thereof, protein-containing extract obtained from legume seeds, ginseng extract, rice germ extract, hibamata extract, camellia extract, aloe extract, Extracts such as moon peach leaf extract and chlorella extract; Pearl powder such as titanium mica; Refreshing agent such as menthol: Fragrance; Dye; Ultraviolet absorber; Antioxidant; Other encyclopedia of shampoo, Ingredient Ingredients described in ENZCLOPEDIA OF SHAMPOO INGREDIENTS (MICELLE PRESS) are listed.
〔pH〕
本発明の毛髪化粧料のpHは、2以上が好ましく、更には2.5以上が好ましく、また7.5以下が好ましく、更には6.5以下、更には5.5以下が好ましい。なお、本発明において、毛髪化粧料のpHは、水で20質量倍希釈したときの25℃における値をいう。
[PH]
The pH of the hair cosmetic composition of the present invention is preferably 2 or more, more preferably 2.5 or more, and preferably 7.5 or less, more preferably 6.5 or less, and further preferably 5.5 or less. In the present invention, the pH of the hair cosmetic refers to a value at 25 ° C. when diluted 20 times by weight with water.
〔毛髪化粧料の形態〕
本発明の毛髪化粧料の形態としては、ヘアリンス、ヘアコンディショナー、ヘアトリートメント、ヘアパック等の浴室内でシャンプー洗髪後に使用されるもの、すなわち毛髪に塗布後、良くなじませて、洗い流して使用されるものが挙げられる。
[Form of hair cosmetic]
The form of the hair cosmetic composition of the present invention is used after shampooing in a bathroom such as a hair rinse, hair conditioner, hair treatment, hair pack, etc., that is, applied to the hair, then thoroughly blended and used after washing. Things.
以上述べた実施形態に関し、以下に本発明の好ましい態様を更に開示する。 With respect to the embodiments described above, preferred aspects of the present invention will be further disclosed below.
<1>
次の成分(A)〜(C)を含有し、成分(A)と成分(C)の質量比(A)/(C)が3以上200以下、成分(B)と成分(C)の質量比(B)/(C)が1を超え100以下である毛髪化粧料。
(A):炭素数18〜24のアルキル基を1つ有するモノ長鎖アルキル型カチオン界面活性剤
0.05質量%以上15質量%以下
(B):炭素数10〜18のアルキル鎖を2つ有するジ長鎖アルキル型カチオン界面活性剤
0.01質量%以上5質量%以下
(C):炭素数12〜17のアルキル基を1つ有するモノ長鎖アルキル型カチオン界面活性剤
<1>
Contains the following components (A) to (C), the mass ratio (A) / (C) of component (A) to component (C) is 3 to 200, and the mass of component (B) to component (C) Hair cosmetics having a ratio (B) / (C) of more than 1 and not more than 100.
(A): Mono long chain alkyl type cationic surfactant having one alkyl group having 18 to 24 carbon atoms
0.05% to 15% by mass
(B): Di-long-chain alkyl cationic surfactant having two alkyl chains having 10 to 18 carbon atoms
0.01% to 5% by mass
(C): Mono long chain alkyl type cationic surfactant having one alkyl group having 12 to 17 carbon atoms
<2>
好ましくは、更に成分(D)として、アミノ変性シリコーンを含有し、その含有量が、好ましくは0.01質量%以上、より好ましくは0.03質量%以上、更に好ましくは0.05質量%以上であり、また、好ましくは5質量%以下、より好ましくは3質量%以下、更に好ましくは1.5質量%である<1>に記載の毛髪化粧料。
<2>
Preferably, amino-modified silicone is further contained as component (D), and the content thereof is preferably 0.01% by mass or more, more preferably 0.03% by mass or more, further preferably 0.05% by mass or more, and preferably Is 5 mass% or less, More preferably, it is 3 mass% or less, More preferably, it is 1.5 mass%.
<3>
好ましくは、更に成分(E)として、高級アルコールを含有し、その含有量が、好ましくは0.5質量%以上、より好ましくは1質量%以上、更に好ましくは2質量%以上であり、また、好ましくは20質量%以下、より好ましくは15質量%以下、更に好ましくは10質量%以下である<1>又は<2>に記載の毛髪化粧料。
<3>
Preferably, it further contains a higher alcohol as component (E), and the content thereof is preferably 0.5% by mass or more, more preferably 1% by mass or more, further preferably 2% by mass or more, and preferably The hair cosmetic according to <1> or <2>, which is 20% by mass or less, more preferably 15% by mass or less, and still more preferably 10% by mass or less.
<4>
成分(A)の含有量が、好ましくは0.1質量%以上、より好ましくは0.5質量%以上であり、また、好ましくは5質量%以下、より好ましくは3質量%以下である<1>〜<3>のいずれか1項に記載の毛髪化粧料。
<4>
The content of the component (A) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and preferably 5% by mass or less, more preferably 3% by mass or less <1> to <3. > The hair cosmetic composition according to any one of the above.
<5>
成分(B)の含有量が、好ましくは0.05質量%以上、より好ましくは0.1質量%以上であり、また、好ましくは2.5質量%以下、より好ましくは1質量%以下、更に好ましくは0.38質量%以下である<1>〜<4>のいずれか1項に記載の毛髪化粧料。
<5>
The content of component (B) is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, preferably 2.5% by mass or less, more preferably 1% by mass or less, and further preferably 0.38% by mass or less. The hair cosmetic composition according to any one of <1> to <4>, wherein
<6>
成分(C)の含有量が、好ましくは0.005質量%以上、より好ましくは0.01質量%以上、更に好ましくは0.02質量%以上であり、また、好ましくは5質量%以下、より好ましくは2質量%以下、更に好ましくは1質量%以下、更に好ましくは0.4質量%以下である<1>〜<5>のいずれか1項に記載の毛髪化粧料。
<6>
The content of component (C) is preferably 0.005% by mass or more, more preferably 0.01% by mass or more, still more preferably 0.02% by mass or more, and preferably 5% by mass or less, more preferably 2% by mass or less. The hair cosmetic according to any one of <1> to <5>, more preferably 1% by mass or less, and further preferably 0.4% by mass or less.
<7>
成分(A)と成分(C)との質量比(A)/(C)が、好ましくは5以上、より好ましくは10以上であり、また好ましくは100以下、より好ましくは50以下である<1>〜<6>のいずれか1項に記載の毛髪化粧料。
<7>
The mass ratio (A) / (C) between component (A) and component (C) is preferably 5 or more, more preferably 10 or more, and preferably 100 or less, more preferably 50 or less <1. The hair cosmetic composition according to any one of> to <6>.
<8>
成分(B)と成分(C)との質量比(B)/(C)が、好ましくは2以上、より好ましくは3以上であり、また、好ましくは50以下、より好ましくは25以下である<1>〜<7>のいずれか1項に記載の毛髪化粧料。
<8>
The mass ratio (B) / (C) of the component (B) to the component (C) is preferably 2 or more, more preferably 3 or more, and preferably 50 or less, more preferably 25 or less < The hair cosmetic composition according to any one of 1> to <7>.
<9>
毛髪化粧料の25℃における水で20質量倍希釈したときのpHが、好ましくは2以上、より好ましくは2.5以上であり、また、好ましくは7.5以下、より好ましくは6.5以下、更に好ましくは5.5以下である<1>〜<8>のいずれか1項に記載の毛髪化粧料。
<9>
The pH when the hair cosmetic is diluted 20 times by mass with water at 25 ° C. is preferably 2 or more, more preferably 2.5 or more, and preferably 7.5 or less, more preferably 6.5 or less, still more preferably 5.5 or less. The hair cosmetic composition according to any one of <1> to <8>, wherein
<10>
成分(A)が、好ましくはステアリルトリメチルアンモニウム塩、アラキルトリメチルアンモニウム塩及びベヘニルトリメチルアンモニウム塩から選ばれる1種以上であり、より好ましくはステアリルトリメチルアンモニウム塩及びベヘニルトリメチルアンモニウム塩から選ばれる1種以上である<1>〜<9>のいずれか1項に記載の毛髪化粧料。
<10>
Component (A) is preferably at least one selected from stearyl trimethyl ammonium salt, aralkyl trimethyl ammonium salt and behenyl trimethyl ammonium salt, more preferably at least one selected from stearyl trimethyl ammonium salt and behenyl trimethyl ammonium salt. The hair cosmetic composition according to any one of <1> to <9>, wherein
<11>
成分(B)が、好ましくはジステアリルジメチルアンモニウム塩、ジセチルジメチルアンモニウム塩、ジイソステアリルジメチルアンモニウム塩、ジアルキル(C12-15)ジメチルアンモニウム塩、ジアルキル(C12-18)ジメチルアンモニウム塩及びイソステアリルラウリルジメチルアンモニウム塩から選ばれる1種以上であり、より好ましくはジアルキル(C12-15)ジメチルアンモニウム塩及びジアルキル(C12-18)ジメチルアンモニウム塩から選ばれる1種以上である<1>〜<10>のいずれか1項に記載の毛髪化粧料。
<11>
Component (B) is preferably distearyl dimethyl ammonium salt, dicetyl dimethyl ammonium salt, diisostearyl dimethyl ammonium salt, dialkyl (C12-15) dimethyl ammonium salt, dialkyl (C12-18) dimethyl ammonium salt and isostearyl lauryl. <1> to <10> which is at least one selected from dimethylammonium salts, and more preferably at least one selected from dialkyl (C12-15) dimethylammonium salts and dialkyl (C12-18) dimethylammonium salts. Hair cosmetics given in any 1 paragraph.
<12>
成分(C)が、好ましくはラウリルトリメチルアンモニウム塩、ミリスチルトリメチルアンモニウム塩及びセチルトリメチルアンモニウム塩から選ばれる1種以上であり、より好ましくはセチルトリメチルアンモニウム塩である<1>〜<11>のいずれか1項に記載の毛髪化粧料。
<12>
The component (C) is preferably one or more selected from lauryltrimethylammonium salt, myristyltrimethylammonium salt and cetyltrimethylammonium salt, more preferably any one of <1> to <11>, which is a cetyltrimethylammonium salt The hair cosmetic composition according to item 1.
<13>
成分(D)が、好ましくは下記一般式で表されるアミノ変性シリコーンである<2>に記載の毛髪化粧料。
<13>
The hair cosmetic composition according to <2>, wherein component (D) is preferably an amino-modified silicone represented by the following general formula.
〔式中、R5はメチル基、水酸基又はR7−T(R7は炭素数3〜6のアルキレン基、Tは1〜3級アミノ基含有基又はアンモニウム基含有基)を示し、R6は−R8−Q(R8は炭素数3〜6のアルキレン基、Qは1〜3級アミノ基含有基又はアンモニウム基含有基)を示し、aは1以上の整数を示し、bは0以上の整数を示す。ただし、bが0である場合、R5は、−R7−Tである。また好ましい平均分子量は3000〜100000である。〕 [Wherein, R 5 represents a methyl group, a hydroxyl group or R 7 -T (R 7 is an alkylene group having 3 to 6 carbon atoms, T is a primary to tertiary amino group-containing group or an ammonium group-containing group), and R 6 -R 8 -Q (R 8 is an alkylene group having 3 to 6 carbon atoms, Q is a primary to tertiary amino group-containing group or ammonium group-containing group), a is an integer of 1 or more, and b is 0 The above integers are shown. However, if b is 0, R 5 is -R 7 -T. Moreover, a preferable average molecular weight is 3000-100,000. ]
<14>
成分(E)が、好ましくはミリスチルアルコール、セチルアルコール、ステアリルアルコール、アラキルアルコール、ベヘニルアルコール、イソステアリルアルコール、2-オクチルドデカノール、オレイルアルコール及びこれらの混合物から選ばれるものである<3>に記載の毛髪化粧料。
<14>
<3> The component (E) is preferably selected from myristyl alcohol, cetyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, isostearyl alcohol, 2-octyldodecanol, oleyl alcohol and mixtures thereof. Hair cosmetics.
<15>
好ましくは、毛髪に塗布後、洗い流して使用される洗い流すタイプの毛髪化粧料である<1>〜<14>のいずれか1項に記載の毛髪化粧料。
<15>
Preferably, the hair cosmetic according to any one of <1> to <14>, which is a type of hair cosmetic that is used after being applied to the hair and then washed away.
<16>
<1>〜<15>のいずれか1項に記載の毛髪化粧料を、毛髪に塗布後、洗い流す毛髪化粧料の使用方法。
<16>
<1>-<15> The usage method of the hair cosmetics which wash away the hair cosmetics of any one of <15> after applying to hair.
実施例1〜6、比較例1〜6
表1に示す処方に従い、水とジプロピレングリコールを混合し、55℃で撹拌して均一溶解させた後、撹拌・冷却していく過程で、溶解又は融解した状態の高級アルコール、ベンジルアルコール、成分(A)〜(D)を添加し、ヘアコンディショナーを調製した。
Examples 1-6, Comparative Examples 1-6
In accordance with the formulation shown in Table 1, water and dipropylene glycol are mixed and stirred at 55 ° C. to uniformly dissolve, then in the process of stirring and cooling, dissolved or melted higher alcohol, benzyl alcohol, ingredients (A) to (D) were added to prepare a hair conditioner.
(評価方法)
30cm、20gの日本人毛トレスを用いて、官能評価を行った。シャンプーにはコアセルベーション技術が応用されている以下のシャンプーを用いた。
評価用シャンプー
(成分) (質量%)
ラウレス硫酸アンモニウム(エマール125A、花王社) 12
ポリクオタニウム-10(カチセロM-80、花王社) 0.14
グアーヒドロキシプロピルトリモニウムクロリド
(ジャガーC-17SK、Solvay社) 0.36
ポリクオタニウム-7
(マーコート550、Lubrizol Advanced Materials社)
0.18
ラウリルヒドロキシスルタイン(アンヒトール20HD、花王社) 1.7
PPG-7(アデカカーポールDL-30、アデカ社) 1.1
ベンジルアルコール 0.3
塩化ナトリウム 0.1
精製水 バランス
合計 100
(Evaluation method)
Sensory evaluation was performed using a 30cm, 20g Japanese hair tress. The following shampoos to which coacervation technology was applied were used as shampoos.
Shampoo for evaluation (component) (mass%)
Ammonium laureth sulfate (Emar 125A, Kao) 12
Polyquaternium-10 (Caticello M-80, Kao Corporation) 0.14
Guar hydroxypropyltrimonium chloride (Jaguar C-17SK, Solvay) 0.36
Polyquaternium-7
(Marcote 550, Lubrizol Advanced Materials)
0.18
Lauryl hydroxysultain (Amphithol 20HD, Kao) 1.7
PPG-7 (Adeka Carpole DL-30, Adeka) 1.1
Benzyl alcohol 0.3
Sodium chloride 0.1
Purified water balance total 100
まずトレスにシャンプー2gを塗布し、泡立て、濯いだ。その後、表1に記載のヘアコンディショナー2gをトレス全体に馴染ませ、濯ぎ、タオルで拭いた後、ドライヤーを用いて乾燥させるといった手順で毛髪を処理した。
コンディショナー塗布時、濯ぎ時、タオルドライ後、ドライヤー中、乾燥後、再度濡らした時における感触を評価した。評価は、パネラー5人に「5:良い」〜「1:悪い」の5段階で点数をつけてもらい、その合計点を表中に記載した。
First, 2 g of shampoo was applied to the tress, foamed and rinsed. Thereafter, 2 g of the hair conditioner shown in Table 1 was applied to the entire tress, rinsed, wiped with a towel, and then dried using a dryer.
The feeling when the conditioner was applied, rinsed, towel dried, in the dryer, dried and then wetted again was evaluated. For evaluation, five panelists scored in five stages from “5: good” to “1: bad”, and the total score was listed in the table.
(接触角測定方法)
健常な日本人毛に1回ブリーチ処理と360回洗髪を繰り返したダメージ毛に対し、上記のシャンプー及びヘアコンディショナーを用いて同様に処理した後、水との前進接触角を測定した。水として蒸留水、測定装置としてKRUSS GmbH社のProcessor Tensiometer K100を用いて、水の表面張力:72.8 mN/m、水の密度:0.998 g/cm3、Maximum Immersion Depth:4 mm、Minimum Immersion Depth:1 mm、測定スピード:2 mm/minの条件下で測定した。接触角の数値が高いほど、毛髪表面が疎水化され、仕上がり時に高い均質感と優れた指通り性能を発揮する。
(Contact angle measurement method)
Damaged hair, which was once bleached and washed 360 times on healthy Japanese hair, was treated in the same manner using the above shampoo and hair conditioner, and then the advancing contact angle with water was measured. Distilled water as water, Processor Tensiometer K100 from KRUSS GmbH as measuring device, surface tension of water: 72.8 mN / m, water density: 0.998 g / cm 3 , Maximum Immersion Depth: 4 mm, Minimum Immersion Depth: The measurement was performed under the conditions of 1 mm and measurement speed: 2 mm / min. The higher the contact angle value, the more hydrophobic the hair surface, and the higher homogeneity and excellent fingering performance when finished.
*1:コータミン D2345P,花王株式会社製
*2:XS65-C0032,モメンティブ・パフォーマンス・マテリアルズ社製
*3:DOW CORNING TORAY SS-3588,東レ・ダウコーニング株式会社製
* 1: Cotamin D2345P, manufactured by Kao Corporation
* 2: XS65-C0032, manufactured by Momentive Performance Materials
* 3: DOW CORNING TORAY SS-3588, manufactured by Toray Dow Corning Co., Ltd.
参考例(実施例1'、比較例1'〜3')
参考のため、以下に示すプレーンシャンプー(コアセルベーション技術が応用されていないシャンプー)で洗浄した毛髪に対し、表1に記載の実施例1又は比較例1〜3のヘアコンディショナーで処理したときの評価を前記と同様にして行い、その結果を表2に示す(実施例1'、比較例1'〜3')。
まずトレスにシャンプー2gを塗布し、泡立て、濯いだ。その後、表1に記載のヘアコンディショナー2gをトレス全体に馴染ませ、濯ぎ、タオルで拭いた後、ドライヤーを用いて乾燥させるといった手順で毛髪を処理した。なお、使用した毛髪トレスは、前記と同様のものである。
コンディショナー塗布時、濯ぎ時、タオルドライ後、ドライヤー中、乾燥後、再度濡らした時における感触を評価した。評価は、パネラー5人に「5:良い」〜「1:悪い」の5段階で点数をつけてもらい、その合計点を表中に記載した。評価結果を表2に示す。
Reference Example (Example 1 ′, Comparative Examples 1 ′ to 3 ′)
For reference, the hair washed with the plain shampoo shown below (the shampoo to which the coacervation technique is not applied) is treated with the hair conditioner of Example 1 or Comparative Examples 1 to 3 described in Table 1. Evaluation was performed in the same manner as described above, and the results are shown in Table 2 (Example 1 ′, Comparative Examples 1 ′ to 3 ′).
First, 2 g of shampoo was applied to the tress, foamed and rinsed. Thereafter, 2 g of the hair conditioner shown in Table 1 was applied to the entire tress, rinsed, wiped with a towel, and then dried using a dryer. The hair tress used is the same as described above.
The feeling when the conditioner was applied, rinsed, towel dried, in the dryer, dried and then wetted again was evaluated. For evaluation, five panelists scored in five stages from “5: good” to “1: bad”, and the total score was listed in the table. The evaluation results are shown in Table 2.
(プレーンシャンプーの組成)
(成分) (質量%)
エマール170J(花王株式会社製、有効分70質量%) 18.6
(ポリオキシエチレンラウリルエーテル硫酸Naとして13.0質量%)
アミゾールCME(川研ファインケミカル株式会社製) 0.6
(ヤシ油脂肪酸モノエタノールアミドとして0.6質量%)
アンヒトール55AB(花王株式会社製、有効分30質量%) 4.7
(ヤシ油脂肪酸アミドプロピルカルボベタインとして1.4質量%)
クエン酸(pH調製剤) 適量
安息香酸ナトリウム 0.3
精製水 残量
計 100.0
(Plain shampoo composition)
(Ingredient) (mass%)
EMAL 170J (manufactured by Kao Corporation, effective 70% by mass) 18.6
(13.0% by mass as polyoxyethylene lauryl ether sulfate Na)
Amidol CME (manufactured by Kawaken Fine Chemical Co., Ltd.) 0.6
(0.6% by mass as palm oil fatty acid monoethanolamide)
Anhitoal 55AB (manufactured by Kao Corporation, effective 30% by mass) 4.7
(1.4% by mass as palm oil fatty acid amidopropyl carbobetaine)
Citric acid (pH adjuster) Appropriate amount Sodium benzoate 0.3
Purified water fuel gauge 100.0
Claims (16)
(A):炭素数18〜24のアルキル基を1つ有するモノ長鎖アルキル型カチオン界面活性剤
0.05質量%以上15質量%以下
(B):炭素数10〜18のアルキル鎖を2つ有するジ長鎖アルキル型カチオン界面活性剤
0.01質量%以上5質量%以下
(C):炭素数12〜17のアルキル基を1つ有するモノ長鎖アルキル型カチオン界面活性剤 Contains the following components (A) to (C), the mass ratio (A) / (C) of component (A) to component (C) is 3 to 200, and the mass of component (B) to component (C) Hair cosmetics having a ratio (B) / (C) of more than 1 and not more than 100.
(A): Mono long chain alkyl type cationic surfactant having one alkyl group having 18 to 24 carbon atoms
0.05% to 15% by mass
(B): Di-long-chain alkyl cationic surfactant having two alkyl chains having 10 to 18 carbon atoms
0.01% to 5% by mass
(C): Mono long chain alkyl type cationic surfactant having one alkyl group having 12 to 17 carbon atoms
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JP3910472B2 (en) * | 2002-03-13 | 2007-04-25 | 花王株式会社 | Hair cosmetics |
JP2006232796A (en) * | 2005-02-23 | 2006-09-07 | Estate Chemical Kk | Cosmetic |
US8728450B2 (en) * | 2007-05-23 | 2014-05-20 | The Procter & Gamble Company | Hair conditioning composition comprising quaternized silicone polymer, grafted silicone copolyol, and dialkyl cationic surfactant |
JP5575453B2 (en) * | 2009-10-28 | 2014-08-20 | 株式会社ミルボン | Hair treatment agent |
FR2964319B1 (en) * | 2010-09-06 | 2017-01-13 | Oreal | COSMETIC COMPOSITION COMPRISING AT LEAST ONE CATIONIC POLYMER AND AT LEAST TWO SURFACTANTS |
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JPH04108719A (en) * | 1990-08-24 | 1992-04-09 | Kao Corp | Hair cosmetic |
JPH0543438A (en) * | 1991-08-09 | 1993-02-23 | Mandamu:Kk | Dyeable hair treating agent |
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JP2020125257A (en) * | 2019-02-04 | 2020-08-20 | 株式会社アリミノ | Hair cosmetic |
JP7277902B2 (en) | 2019-02-04 | 2023-05-19 | 株式会社アリミノ | hair cosmetics |
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TW201601771A (en) | 2016-01-16 |
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