JP2015017037A - バイオマスを用いて水素ガスを生成するための装置 - Google Patents
バイオマスを用いて水素ガスを生成するための装置 Download PDFInfo
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- 239000002028 Biomass Substances 0.000 title claims abstract description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000007789 gas Substances 0.000 claims abstract description 110
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 39
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000001257 hydrogen Substances 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- 238000001704 evaporation Methods 0.000 claims abstract 2
- 230000015572 biosynthetic process Effects 0.000 claims description 26
- 238000003786 synthesis reaction Methods 0.000 claims description 26
- 238000002485 combustion reaction Methods 0.000 claims description 23
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 16
- 238000000926 separation method Methods 0.000 claims description 10
- 238000000197 pyrolysis Methods 0.000 claims description 9
- 239000001569 carbon dioxide Substances 0.000 claims description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 8
- 150000002431 hydrogen Chemical class 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000005201 scrubbing Methods 0.000 claims description 2
- 238000002309 gasification Methods 0.000 abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 8
- 238000001035 drying Methods 0.000 abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000001939 inductive effect Effects 0.000 abstract 1
- 238000006722 reduction reaction Methods 0.000 description 50
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 13
- 239000000446 fuel Substances 0.000 description 13
- 239000000571 coke Substances 0.000 description 11
- 238000004140 cleaning Methods 0.000 description 9
- 239000012528 membrane Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012717 electrostatic precipitator Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000011946 reduction process Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000002551 biofuel Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
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Abstract
【解決手段】バイオマスの乾燥とガス化と水性ガスシフト反応よりなる。そこにおいて発生ガス(CO2、N2及びH2O)が冷却されるガス化の段階から第1熱交換へ発生ガス(CO2、N2及びH2O)を受けさせる段階と、発生ガスからの熱で水を蒸発する段階と、そこにおいて蒸気が加熱される熱交換に蒸気を受けさせる段階と、そこにおいて合成ガスSが冷却されそしてガス化に供給される空気が加熱される合成ガスSの蒸気を還元する段階と、合成ガスSを水素の流れと一酸化炭素の流れに分離する段階と、一酸化炭素を水の流れと反応させて一酸化炭素水素にする段階と、これらの副次的流れを水素の流れと一酸化炭素の流れにまた分離する段階と、水素の主および副の流れを共に製品の流れにする段階とを含む追加の段階を含む。
【選択図】図1
Description
酸素を加えて再燃焼段階を強めることにより、本装置をさらに改善することが可能である。還元段階で必要な熱に対して発生ガスの熱負荷を合わせることが必要である。CO2のより高い濃度はガス洗浄までの結果であり、より低い物質移動の洗浄を幾分より容易にかつよりエネルギ効率のよい洗浄を可能にする。
3 反応ユニット
5 燃焼チャンバ
6 再燃焼チャンバ
7 第1リジェネレータ装置
8 第1送風機
9 蒸発器
12 還元シャフト
13A〜13C 還元区画
15 第2リジェネレータ
17 圧縮機
20 サイクロン
21 触媒反応器
23 機械的フィルタ
24 タンク
25 メンブラン
28,29 ガス洗浄器
S 合成ガス
Claims (4)
- 貯蔵ユニット(1)とバイオマスの熱分解および熱分解ガスの燃焼を実施する反応ユニット(3)とを含む、バイオマスから水素(H2)を製造するための方法を実施するための装置であって、反応ユニット(3)から出るガス(CO2、N2およびH2O)を受容する第1熱交換手段(7、9)と、第1熱交換手段(7、9)で冷却された発生ガス(CO2、N2およびH2O)を受容するガス洗浄ユニット(21、28、29)と、水(H2O(l))を蒸発するための手段(9)と、第1熱交換手段(7、9)に水蒸気(H2O(g))を供給するための手段(9)と、合成ガス(S)を得るために水蒸気(H2O(g))のいくつかの段階で還元を行うように反応ユニット(3)に接続された還元シャフト(12)と、水素(H2)および二酸化炭素(CO2)を得るように合成ガス(S)のガス分離を行う手段(WGS)と、水蒸気を一酸化炭素(CO)と還元させて二酸化炭素(CO2)の形体を伴う水素(H2)にするための装置(WGS)と、水素(H2)と二酸化炭素(CO2)に分離するための手段とをまた含む、装置。
- 第1熱交換手段は第1リジェネレータ装置(7)を含む、請求項1に記載の装置。
- 第2熱交換手段は第2リジェネレータ(15)を含む、請求項1または2に記載の装置。
- 還元シャフト(12)は少なくとも2つの還元区画(13Aから13C)を含む、請求項1、2または3に記載の装置。
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KR20230071804A (ko) * | 2021-11-15 | 2023-05-24 | 예상철 | 폐기물 분해를 통한 수소 정제 생산 시스템 및 이를 이용한 수소 가스 정제 생산 방법 |
KR102585318B1 (ko) * | 2021-11-15 | 2023-10-05 | 예상철 | 폐기물 분해를 통한 수소 정제 생산 시스템 및 이를 이용한 수소 가스 정제 생산 방법 |
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ES2551555T3 (es) | 2015-11-19 |
HUE026101T2 (en) | 2016-05-30 |
PT2291492E (pt) | 2015-11-17 |
DK2291492T3 (en) | 2015-11-02 |
SE0801369L (sv) | 2009-12-13 |
EP2291492A4 (en) | 2013-02-27 |
SE533049C2 (sv) | 2010-06-15 |
CA2727263C (en) | 2016-11-22 |
WO2009151368A1 (en) | 2009-12-17 |
JP2011522951A (ja) | 2011-08-04 |
EP2291492B1 (en) | 2015-07-29 |
PL2291492T3 (pl) | 2016-01-29 |
CY1116866T1 (el) | 2017-04-05 |
US8932374B2 (en) | 2015-01-13 |
EP2291492A1 (en) | 2011-03-09 |
CA2727263A1 (en) | 2009-12-17 |
US20110117006A1 (en) | 2011-05-19 |
JP5830142B2 (ja) | 2015-12-09 |
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