JP2014179598A5 - - Google Patents

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JP2014179598A5
JP2014179598A5 JP2014027549A JP2014027549A JP2014179598A5 JP 2014179598 A5 JP2014179598 A5 JP 2014179598A5 JP 2014027549 A JP2014027549 A JP 2014027549A JP 2014027549 A JP2014027549 A JP 2014027549A JP 2014179598 A5 JP2014179598 A5 JP 2014179598A5
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plasma
film
processing
power
processing method
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Priority to KR1020140018594A priority patent/KR102181419B1/en
Priority to TW103105352A priority patent/TWI606514B/en
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また、本実施形態に係るプラズマ処理方法は、1つの実施形態において、バイアス用電力の周波数が400kHz〜13.56MHzである。 In one embodiment, the plasma processing method according to the present embodiment has a bias power frequency of 400 kHz to 13.56 MHz.

また、下部電極31には、例えば周波数が100MHz〜150MHzの高周波電力を供給する第1の高周波電源45aと、例えば第1の高周波電源45aよりも周波数の低い400kHz〜13.56MHzの高周波電力を供給する第2の高周波電源45bと、が夫々整合器46a、46bを介して接続されている。第1の高周波電源45aより供給される高周波電力は、後述する処理ガスをプラズマ化する役割を果たし、第2の高周波電源45bより供給される高周波電力は、ウエハWにバイアス電力を印加することでプラズマ中のイオンをウエハW表面に引き込む役割を果たす。以下では、説明の便宜を図るため、第1の高周波電源45aより供給される高周波電力をプラズマ生成用電力と呼び、第2の高周波電源45bより供給される高周波電力をバイアス用電力と呼ぶことがあるものとする。 The lower electrode 31 is supplied with a first high-frequency power supply 45a that supplies high-frequency power with a frequency of 100 MHz to 150 MHz, for example, and a high-frequency power with a frequency lower than that of the first high-frequency power supply 45a, for example 400 kHz to 13.56 MHz The second high-frequency power supply 45b to be supplied is connected via matching units 46a and 46b, respectively. The high-frequency power supplied from the first high-frequency power supply 45a plays a role in converting a processing gas, which will be described later, into plasma, and the high-frequency power supplied from the second high-frequency power supply 45b applies bias power to the wafer W. It plays a role of drawing ions in the plasma to the surface of the wafer W. Hereinafter, for convenience of explanation, the high frequency power supplied from the first high frequency power supply 45a is referred to as plasma generation power, and the high frequency power supplied from the second high frequency power supply 45b is referred to as bias power. It shall be.

また、本実施形態によれば、バイアス用電力の周波数が400kHz〜13.56MHzである。その結果、プラズマ中のイオンを効率良く引き込むことができるので、被処理体の被処理面の均一性を更に精度良く維持するようにプロセス条件の設定範囲、つまり、処理装置及び処理のマージン(許容範囲)を広く出来、装置を停止することなく処理することが可能となる。 Further, according to the present embodiment, the frequency of the bias power is 400 kHz to 13.56 MHz. As a result, ions in the plasma can be efficiently drawn, so that the process condition setting range, that is, the processing apparatus and the processing margin (allowable) can be maintained so as to maintain the uniformity of the surface of the object to be processed with higher accuracy. Range) can be widened and processing can be performed without stopping the apparatus.

Claims (13)

被処理体が配置された処理容器の内部に処理ガスを供給するガス供給工程と、
前記処理容器の内部に供給された処理ガスのプラズマを生成するための電力であり、周波数が100MHz〜150MHzであるプラズマ生成用電力と、前記プラズマ生成用電力よりも周波数が低い電力であるバイアス用電力とを供給する電力供給工程と、
デューティ比が10%〜70%となり、かつ、周波数が5kHz〜20kHzとなるように前記バイアス用電力をパルス変調しながら、前記処理ガスのプラズマにより被処理体をエッチングするエッチング工程と
を含むことを特徴とするプラズマ処理方法。
A gas supply step for supplying a processing gas into the processing container in which the target object is disposed;
The power for generating plasma of the processing gas supplied to the inside of the processing container, the power for plasma generation having a frequency of 100 MHz to 150 MHz, and the power for bias having a frequency lower than the power for plasma generation A power supply process for supplying power;
An etching step of etching the object to be processed with plasma of the processing gas while pulse-modulating the bias power so that the duty ratio is 10% to 70% and the frequency is 5 kHz to 20 kHz. A plasma processing method.
前記エッチング工程は、デューティ比が40%〜60%となり、かつ、周波数が5kHz〜10kHzとなるように前記バイアス用電力をパルス変調しながら、前記処理ガスのプラズマにより被処理体をエッチングすることを特徴とする請求項1に記載のプラズマ処理方法。   In the etching step, the object to be processed is etched by plasma of the processing gas while pulse-modulating the bias power so that the duty ratio is 40% to 60% and the frequency is 5 kHz to 10 kHz. The plasma processing method according to claim 1, wherein: 前記バイアス用電力の周波数が400kHz〜13.56MHzであることを特徴とする請求項1又は2に記載のプラズマ処理方法。 The plasma processing method according to claim 1 or 2, wherein a frequency of the bias power is 400 kHz to 13.56 MHz. 前記被処理体は、ポリシリコン膜と、SiO2膜又は有機膜とを含み、
前記エッチング工程は、前記SiO2膜又は前記有機膜をマスクとして前記処理ガスのプラズマにより前記ポリシリコン膜をエッチングすることを特徴とする請求項1〜3のいずれか一つに記載のプラズマ処理方法。
The object to be processed includes a polysilicon film and a SiO2 film or an organic film,
4. The plasma processing method according to claim 1, wherein in the etching step, the polysilicon film is etched by plasma of the processing gas using the SiO 2 film or the organic film as a mask. 5.
前記被処理体は、SiO2膜と、有機膜又はポリシリコン膜とを含み、
前記エッチング工程は、前記有機膜又は前記ポリシリコン膜をマスクとして前記処理ガスのプラズマにより前記SiO2膜をエッチングすることを特徴とする請求項1〜3のいずれか一つに記載のプラズマ処理方法。
The object to be processed includes a SiO2 film and an organic film or a polysilicon film,
4. The plasma processing method according to claim 1, wherein in the etching step, the SiO 2 film is etched by plasma of the processing gas using the organic film or the polysilicon film as a mask. 5.
前記被処理体は、SiO2膜とポリシリコン膜との積層膜と、有機膜とを含み、
前記エッチング工程は、前記有機膜をマスクとして前記処理ガスのプラズマにより前記積層膜をエッチングすることを特徴とする請求項1〜3のいずれか一つに記載のプラズマ処理方法。
The object to be processed includes a laminated film of a SiO2 film and a polysilicon film, and an organic film,
The plasma processing method according to claim 1, wherein in the etching step, the stacked film is etched by plasma of the processing gas using the organic film as a mask.
前記積層膜は、少なくとも24層以上積層されることを特徴とする請求項6に記載のプラズマ処理方法。   The plasma processing method according to claim 6, wherein at least 24 layers of the laminated film are laminated. 前記処理ガスは、臭素又は塩素と、フッ素と、酸素とを含むことを特徴とする請求項1〜7のいずれか一つに記載のプラズマ処理方法。   The plasma processing method according to claim 1, wherein the processing gas contains bromine or chlorine, fluorine, and oxygen. 前記処理ガスは、アルゴンをさらに含むことを特徴とする請求項8に記載のプラズマ処理方法。   The plasma processing method according to claim 8, wherein the processing gas further contains argon. 前記処理ガスは、CF系ガスを含むことを特徴とする請求項1〜7のいずれか一つに記載のプラズマ処理方法。   The plasma processing method according to claim 1, wherein the processing gas includes a CF-based gas. 前記バイアス用電力は、500W〜3000Wであることを特徴とする請求項1〜10のいずれか一つに記載のプラズマ処理方法。   The plasma processing method according to claim 1, wherein the bias power is 500 W to 3000 W. 前記エッチング工程によってエッチングされた前記被処理体の中心位置のエッチングレートと、当該被処理体の中心位置から径方向に沿って周縁側に所定距離だけシフトした位置のエッチングレートとの差は、−1.2(nm/min)〜1.2(nm/min)であることを特徴とする請求項1〜11のいずれか一つに記載のプラズマ処理方法。   The difference between the etching rate at the center position of the object to be processed etched by the etching step and the etching rate at a position shifted from the center position of the object to be processed along the radial direction by a predetermined distance along the radial direction is − It is 1.2 (nm / min)-1.2 (nm / min), The plasma processing method as described in any one of Claims 1-11 characterized by the above-mentioned. 被処理体が配置された処理容器と、
前記処理容器の内部を減圧するための排気部と、
前記処理容器の内部に処理ガスを供給するためのガス供給部と、
前記処理容器の内部に処理ガスを供給する工程と、前記処理容器の内部に供給された処理ガスのプラズマを生成するための電力であり、周波数が100MHz〜150MHzであるプラズマ生成用電力と、前記プラズマ生成用電力よりも周波数が低い電力であるバイアス用電力とを供給する工程と、デューティ比が10%〜70%となり、かつ、周波数が5kHz〜20kHzとなるように前記バイアス用電力をパルス変調しながら、前記処理ガスのプラズマにより被処理体をエッチングする工程とを実行する制御部と
を備えたことを特徴とするプラズマ処理装置。
A processing container in which an object is disposed;
An exhaust part for depressurizing the inside of the processing vessel;
A gas supply unit for supplying a processing gas into the processing container;
A step of supplying a processing gas to the inside of the processing container; a power for generating plasma of the processing gas supplied to the inside of the processing container; and a power for generating a plasma having a frequency of 100 MHz to 150 MHz; Supplying a bias power having a frequency lower than that of the plasma generating power; and pulse modulating the bias power so that the duty ratio is 10% to 70% and the frequency is 5 kHz to 20 kHz. And a control unit that executes a step of etching the object to be processed with the plasma of the processing gas.
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JP2014027549A JP6267989B2 (en) 2013-02-18 2014-02-17 Plasma processing method and capacitively coupled plasma processing apparatus
US14/182,707 US9653316B2 (en) 2013-02-18 2014-02-18 Plasma processing method and plasma processing apparatus
KR1020140018594A KR102181419B1 (en) 2013-02-18 2014-02-18 Plasma processing method and plasma processing apparatus
TW103105352A TWI606514B (en) 2013-02-18 2014-02-18 Plasma processing method and plasma processing device

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