JP2014043424A - Shampoo composition - Google Patents
Shampoo composition Download PDFInfo
- Publication number
- JP2014043424A JP2014043424A JP2012187208A JP2012187208A JP2014043424A JP 2014043424 A JP2014043424 A JP 2014043424A JP 2012187208 A JP2012187208 A JP 2012187208A JP 2012187208 A JP2012187208 A JP 2012187208A JP 2014043424 A JP2014043424 A JP 2014043424A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- shampoo composition
- fatty acid
- good
- polyoxyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 239000002453 shampoo Substances 0.000 title claims abstract description 48
- -1 arginyl fructosyl glucose Chemical compound 0.000 claims abstract description 66
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229960003237 betaine Drugs 0.000 claims abstract description 12
- 229920002907 Guar gum Polymers 0.000 claims abstract description 11
- 239000001913 cellulose Substances 0.000 claims abstract description 11
- 229920002678 cellulose Polymers 0.000 claims abstract description 11
- 239000000665 guar gum Substances 0.000 claims abstract description 11
- 235000010417 guar gum Nutrition 0.000 claims abstract description 11
- 229960002154 guar gum Drugs 0.000 claims abstract description 11
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 8
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 40
- 239000000194 fatty acid Substances 0.000 claims description 40
- 229930195729 fatty acid Natural products 0.000 claims description 40
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 33
- 150000004665 fatty acids Chemical class 0.000 claims description 30
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 27
- 235000011187 glycerol Nutrition 0.000 claims description 17
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 12
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 229920006322 acrylamide copolymer Polymers 0.000 claims description 8
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 8
- 108010077895 Sarcosine Proteins 0.000 claims description 6
- 229940043230 sarcosine Drugs 0.000 claims description 6
- 238000005406 washing Methods 0.000 abstract description 20
- 238000005187 foaming Methods 0.000 abstract description 17
- 238000001035 drying Methods 0.000 abstract description 14
- 206010019049 Hair texture abnormal Diseases 0.000 abstract 1
- 239000000284 extract Substances 0.000 description 23
- 240000007594 Oryza sativa Species 0.000 description 9
- 235000007164 Oryza sativa Nutrition 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 8
- 235000009566 rice Nutrition 0.000 description 8
- 235000019482 Palm oil Nutrition 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 239000002540 palm oil Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000003240 coconut oil Substances 0.000 description 6
- 235000019864 coconut oil Nutrition 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- 239000004475 Arginine Substances 0.000 description 5
- 239000004166 Lanolin Substances 0.000 description 5
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 5
- 235000009697 arginine Nutrition 0.000 description 5
- 230000003750 conditioning effect Effects 0.000 description 5
- 238000007796 conventional method Methods 0.000 description 5
- 235000019388 lanolin Nutrition 0.000 description 5
- 229940039717 lanolin Drugs 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- 239000003346 palm kernel oil Substances 0.000 description 5
- 235000019865 palm kernel oil Nutrition 0.000 description 5
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 4
- 241000371652 Curvularia clavata Species 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 4
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 4
- 229920006317 cationic polymer Polymers 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000000419 plant extract Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 108700004121 sarkosyl Proteins 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000000213 tara gum Substances 0.000 description 4
- 235000010491 tara gum Nutrition 0.000 description 4
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 3
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 3
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 3
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 3
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 3
- 235000019774 Rice Bran oil Nutrition 0.000 description 3
- 241000235070 Saccharomyces Species 0.000 description 3
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 3
- 229960000583 acetic acid Drugs 0.000 description 3
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 3
- 235000013736 caramel Nutrition 0.000 description 3
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 3
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 3
- 230000037308 hair color Effects 0.000 description 3
- 229940075468 lauramidopropyl betaine Drugs 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000008165 rice bran oil Substances 0.000 description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 3
- 239000004299 sodium benzoate Substances 0.000 description 3
- 235000010234 sodium benzoate Nutrition 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 229940057950 sodium laureth sulfate Drugs 0.000 description 3
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 240000001548 Camellia japonica Species 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 2
- 101710199886 Protein 0.5 Proteins 0.000 description 2
- 241000580955 Sapindus mukorossi Species 0.000 description 2
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- 150000001298 alcohols Chemical class 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000000637 arginyl group Chemical group N[C@@H](CCCNC(N)=N)C(=O)* 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
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Abstract
Description
本発明はシャンプー組成物に関し、詳しくは、洗髪時に泡立ちが良く、髪が絡まない滑り性に優れ、すすぎ時に髪のきしみがなく指通り性に優れ、乾燥後に髪がぱさつかず、まとまりが良好であるシャンプー組成物に関する。 The present invention relates to a shampoo composition, and in particular, it has good foaming properties when washing hair, excellent slipperiness that does not get tangled in hair, excellent crispness without squeezing of hair when rinsing, good hairiness after drying, and good unity Relates to a shampoo composition.
近年、ファッションとしてヘアスタイルや髪の色を楽しむようになり、ヘアカラーやパーマを行うことは日常的になっている。ヘアカラーやパーマなどによって毛髪はダメージを受け、シャンプー時に髪が絡まったり、すすぎ時に指通りが悪くギシギシとした感触となったり、洗髪後のタオルドライの時にも髪が絡まるなどの問題点が発生している。そのため、シャンプーに対して、本来の目的である洗浄性に加えて、スムーズに泡立て、またすすぎ時に指通りが良く、洗浄後に髪がぱさつかず、まとまりがよいなどの良好な仕上がり感が求められている。洗髪時やすすぎ時の髪の良好な指通りを改善する方法として、従来、アニオン性界面活性剤や両性界面活性剤等の洗浄基剤にカチオン化セルロースや、カチオン化グアガム、カチオン化タラガム、カチオン化ローカストビーンガムなどのカチオン化ガラクトマンナン系ポリマー、あるいは塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体などのカチオン性のポリマーを組合せること(例えば、特許文献1〜6参照。)が広く用いられている。 In recent years, hairstyles and hair colors have come to be enjoyed as fashion, and hair coloring and permanents have become commonplace. The hair is damaged by hair color and perm, etc., causing problems such as tangling hair during shampooing, touching badly when rinsing, and tangling hair when towel drying after washing doing. For this reason, in addition to the original cleanability, shampoo is required to have a good finish such as smooth foaming, good fingering during rinsing, no loose hair after washing, and good cohesion. ing. As a method for improving the good fingering of hair during washing and rinsing, conventionally, cationized cellulose, cationized guar gum, cationized tara gum, cation are used as a washing base such as anionic surfactant and amphoteric surfactant. Combining cationic polymers such as cationized galactomannan-based polymers such as calcified locust bean gum or cationic polymers such as dimethyldiallylammonium chloride / acrylamide copolymer (see, for example, Patent Documents 1 to 6) is widely used. .
アルギニルフルコトシルグルコースには、抗酸化作用、チロシナーゼ活性阻害作用、メラニン産生抑制作用、美白作用などがあり、化粧料、飲食品組成物及医薬品組成物などに使用すること(例えば、特許文献7、8参照。)が知られている。しかしながら、アルギニルフルコトシルグルコースを特定の界面活性剤及びカチオン性ポリマーと組合わせてシャンプーに配合することによって、洗髪時、すすぎ時及び乾燥後に優れた指通りを示すことは知られていなかった。 Arginyl flucotosyl glucose has an antioxidant action, a tyrosinase activity inhibitory action, a melanin production inhibitory action, a whitening action, and the like, and is used in cosmetics, food and beverage compositions, pharmaceutical compositions and the like (for example, Patent Document 7) , 8). However, it has not been known that arginyl flucotosyl glucose exhibits excellent fingering during shampooing, rinsing and drying by combining it with a specific surfactant and cationic polymer in a shampoo.
上記従来技術を背景とした本発明の目的は、洗髪時に泡立ちが良く髪が絡まない滑り性に優れ、すすぎ時に髪のきしみがなく指通り性に優れ、乾燥後に髪がぱさつかず、まとまりが良好であるシャンプー組成物を提供することにある。 The purpose of the present invention against the background of the above prior art is excellent in slipperiness that does not entangle with hair when shampooing, has no squeaky hair when rinsing, has excellent fingering, and does not clump after drying. It is to provide a shampoo composition that is good.
本発明者等は、本発明の目的を達成するために鋭意研究した結果、アルギニンフルクトシルグルコースを特定の界面活性剤及び特定のカチオン性ポリマーとを組み合わせて配合したシャンプー組成物が上記目的を達成できることを見出し、本発明を完成した。すなわち
、本発明は、下記成分(A)〜(C)を含有するシャンプー組成物である。
(A)アルギニルフルクトシルグルコース
(B)エーテル硫酸塩型アニオン性界面活性剤及びベタイン型両性界面活性剤から選ばれる1種以上
(C)カチオン化セルロース及びカチオン化グアガムから選ばれる1種以上
As a result of intensive studies to achieve the object of the present invention, the present inventors have achieved the above object by using a shampoo composition containing arginine fructosyl glucose in combination with a specific surfactant and a specific cationic polymer. The present invention has been completed by finding out what can be done. That is, the present invention is a shampoo composition containing the following components (A) to (C).
(A) one or more selected from arginyl fructosyl glucose (B) ether sulfate type anionic surfactant and betaine type amphoteric surfactant (C) one or more selected from cationized cellulose and cationized guar gum
本発明のシャンプー組成物には、成分(D)25℃で液状のポリオキシエチレン脂肪酸グリセリンを含有することが好ましい。また成分(E)N−アシルサルコシントリエタノールアミンを含有することも好ましい。さらに成分(F)塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体を含有することも好ましい。 The shampoo composition of the present invention preferably contains component (D) polyoxyethylene fatty acid glycerin that is liquid at 25 ° C. It is also preferable to contain component (E) N-acyl sarcosine triethanolamine. Furthermore, it is also preferable to contain a component (F) dimethyl diallyl ammonium chloride acrylamide copolymer.
本発明によれば、洗髪時に泡立ちが良く髪が絡まない滑り性に優れ、すすぎ時に髪のきしみがなく指通り性に優れ、乾燥後に髪がぱさつかず、まとまりが良好であるシャンプー組成物を提供することができる。 According to the present invention, there is provided a shampoo composition that has good foaming properties when shampooing, excellent slipperiness without tangling hair, excellent squeezing property without squeezing of hair when rinsing, no looseness of hair after drying, and good unity. Can be provided.
以下、本発明のシャンプー組成物について詳細に説明する。 Hereinafter, the shampoo composition of the present invention will be described in detail.
本発明のシャンプー組成物に用いられる成分(A)アルギニルフルクトシルグルコースは下記一般式(1)で表される化合物である。 Component (A) arginyl fructosyl glucose used in the shampoo composition of the present invention is a compound represented by the following general formula (1).
本発明では、アルギニルフルクトシルグルコースの配合量は特に限定されるものではないが、シャンプー組成物全体に対して0.00001〜1質量%(以下、単に%という。)が好ましく、特に0.0001〜1%が好ましい。この配合量の範囲であれば洗髪時およびすすぎ時の指通り性に優れ、また乾燥後の仕上がり感触においても好ましく、良好な安定性を有する。 In the present invention, the blending amount of arginyl fructosyl glucose is not particularly limited, but is preferably 0.00001 to 1% by mass (hereinafter simply referred to as “%”) with respect to the entire shampoo composition. 0001 to 1% is preferable. When the amount is within this range, it is excellent in fingering property during shampooing and rinsing, is preferable in the finished feel after drying, and has good stability.
本発明に用いられるアルギニルフルクトシルグルコースは公知の方法で製造したもので良いが、例えば、アルギニンを用いて、マルトースと酸の存在下で加温することにより製造することができる。具体的には、アルギニンとマルトースとを溶媒としての酸に溶解させ、70℃で30分間加温する。アルギニンとマルトースとの反応は、アルギニン100質量部に対して、マルトース1〜1000質量部、好ましくは50〜300質量部とする。上記反応の溶媒としては、有機酸が好ましく、例えば、酢酸、酪酸などが挙げられる。特に酢酸が好ましい。なお、水溶液中で両物質を反応させると、効率が低下するので、氷酢酸などの無水状態で液状を示す酸を溶媒として用いることが好ましい。上記反応の温度条件としては、常温から沸点までの任意の温度で行えるが、反応速度及び効率の面から60〜80℃の温度条件が好ましい。反応時間は温度や溶媒としての酸の種類によって異なるが、通常5〜300分程度であり、10〜60分が好ましい。反応後、冷却したのち不溶
性物質をろ過または遠心分離して除去し、得られたろ液または上清から反応溶媒としての酸を留去することにより、アルギニルフルクトシルグルコースを含む混合物を得ることができる。アルギニルフルクトシルグルコースを含む混合物のままでも使用可能であるが、必要に応じて、常法によりアルギニルフルクトシルグルコースを含む混合物からアルギニルフルクトシルグルコースを精製して使用する。
Arginyl fructosyl glucose used in the present invention may be produced by a known method. For example, arginyl fructosyl glucose can be produced by heating using arginine in the presence of maltose and an acid. Specifically, arginine and maltose are dissolved in an acid as a solvent and heated at 70 ° C. for 30 minutes. The reaction between arginine and maltose is from 1 to 1000 parts by weight, preferably from 50 to 300 parts by weight, based on 100 parts by weight of arginine. The solvent for the above reaction is preferably an organic acid, and examples thereof include acetic acid and butyric acid. Acetic acid is particularly preferable. In addition, when both substances are made to react in aqueous solution, efficiency will fall, Therefore It is preferable to use the acid which shows liquid state in anhydrous states, such as a glacial acetic acid, as a solvent. As the temperature condition of the above reaction, it can be carried out at any temperature from room temperature to the boiling point, but a temperature condition of 60 to 80 ° C. is preferable from the viewpoint of reaction rate and efficiency. The reaction time varies depending on the temperature and the type of acid as a solvent, but is usually about 5 to 300 minutes, preferably 10 to 60 minutes. After the reaction, the insoluble substance is removed by filtration or centrifugation after cooling, and an acid as a reaction solvent is distilled off from the obtained filtrate or supernatant to obtain a mixture containing arginyl fructosyl glucose. it can. The mixture containing arginyl fructosyl glucose can be used as it is, but if necessary, arginyl fructosyl glucose is purified from the mixture containing arginyl fructosyl glucose by a conventional method and used.
本発明に用いられるアルギニルフルクトシルグルコースは化学合成品に限らず、植物抽出物に含まれるものを使用しても良く、シャンプー組成物に配合する際は、アルギニルフルクトシルグルコースの精製物、混合物のまま、精製物と混合物が混在するもの、いずれのものでも使用が可能である。アルギニルフルクトシルグルコースを多く含有する植物抽出物はコメヌカ発酵エキスが上げられ、植物抽出物としてはそれを使用することが好ましい。 Arginyl fructosyl glucose used in the present invention is not limited to a chemically synthesized product, but may be one contained in a plant extract. When blended in a shampoo composition, a purified product of arginyl fructosyl glucose, Any mixture of the purified product and the mixture can be used as the mixture. As a plant extract containing a large amount of arginyl fructosyl glucose, a rice bran fermented extract is raised, and it is preferable to use it as a plant extract.
本発明のシャンプー組成物に用いられる成分(B)エーテル硫酸塩型アニオン性界面活性剤及びベタイン型両性界面活性剤としては、例えばラウリル硫酸ナトリウム、ラウリル硫酸トリエタノールアミン、ラウリル硫酸アンモニウム、ラウレス硫酸ナトリウム、ラウレス硫酸トリエタノールアミン、ラウレス硫酸アンモニウム、ラウリルベタイン、ラウロイルアミドプロピルベタイン、2−アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、パーム核油脂肪酸アミドプロピルベタイン等が挙げられる。本発明では、これらエーテル硫酸塩型アニオン性界面活性剤及びベタイン型両性界面活性剤の中から適宜選択し、1種単独または2種以上を組み合わせて配合できる。これらの中でも好ましくはラウレス硫酸ナトリウム、ラウレス硫酸トリエタノールアミン、ラウレス硫酸アンモニウム、ラウラミドプロピルベタイン、パーム核油脂肪酸アミドプロピルベタインである。エーテル硫酸塩型アニオン性界面活性剤及びベタイン型両性界面活性剤の配合量は特に限定されるものではないが、シャンプー組成物全体に対して3〜30%が好ましく、特に5〜20%が好ましい。これは、エーテル硫酸塩型アニオン性界面活性剤及びベタイン型両性界面活性剤の配合量を増やすと、泡立ちが良くなるが、コンディショニング効果(例えば、洗浄中の使用感および洗浄後の仕上り感の良さ等)が低くなり、また、粘性も高くなるため、充分起泡性を得るには3%以上が好ましく、また、適度な粘性を保ち、充分なコンディショニング効果を得るには30%以下が好ましいからである。 Examples of the component (B) ether sulfate type anionic surfactant and betaine type amphoteric surfactant used in the shampoo composition of the present invention include sodium lauryl sulfate, triethanolamine lauryl sulfate, ammonium lauryl sulfate, sodium laureth sulfate, Examples include laureth sulfate triethanolamine, laureth ammonium sulfate, lauryl betaine, lauroylamidopropyl betaine, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, palm kernel oil fatty acid amidopropyl betaine, and the like. In this invention, it can select suitably from these ether sulfate type | mold anionic surfactant and betaine type | mold amphoteric surfactant, and can mix | blend 1 type individually or in combination of 2 or more types. Of these, sodium laureth sulfate, triethanolamine laureth sulfate, ammonium laureth sulfate, lauramidopropyl betaine, and palm kernel oil fatty acid amidopropyl betaine are preferable. The blending amount of the ether sulfate type anionic surfactant and the betaine type amphoteric surfactant is not particularly limited, but is preferably 3 to 30%, particularly preferably 5 to 20%, based on the total shampoo composition. . This is because when the blending amount of ether sulfate type anionic surfactant and betaine type amphoteric surfactant is increased, foaming is improved, but the conditioning effect (for example, the feeling of use during washing and the feeling of finishing after washing) Etc.) and also the viscosity is increased. Therefore, 3% or more is preferable for obtaining sufficient foaming property, and 30% or less is preferable for maintaining an appropriate viscosity and obtaining a sufficient conditioning effect. It is.
本発明のシャンプー組成物に用いられる成分(C)カチオン化セルロース及びカチオン化グアガムのカチオン化度を示す電荷密度は、0.5〜2.5meq/gの範囲が好ましく、0.7〜2meq/gの範囲が更に好ましい。本発明では、これらカチオン化セルロース及びカチオン化グアガムの中から適宜選択し、1種単独または2種以上を組み合わせて配合できる。カチオン化セルロース及びカチオン化グアガムの配合量は特に限定されるものではないが、シャンプー組成物全体に対して0.05〜2%が好ましく、特に0.1〜0.7%が好ましい。この配合量の範囲であれば、洗髪時およびすすぎ時の指通り性に優れ、また乾燥後の仕上がり感触においても好ましい。 The charge density indicating the cationization degree of the component (C) cationized cellulose and cationized guar gum used in the shampoo composition of the present invention is preferably in the range of 0.5 to 2.5 meq / g, and 0.7 to 2 meq / g. The range of g is more preferable. In this invention, it can select suitably from these cationized cellulose and cationized guar gum, and can mix | blend 1 type individually or in combination of 2 or more types. Although the compounding quantity of cationized cellulose and cationized guar gum is not specifically limited, 0.05-2% is preferable with respect to the whole shampoo composition, and 0.1-0.7% is especially preferable. When the amount is within this range, it is excellent in fingering property at the time of shampooing and rinsing, and is preferable in the finished touch after drying.
本発明のシャンプー組成物に用いられる成分(D)25℃で液状のポリオキシエチレン脂肪酸グリセリンは、非イオン界面活性剤として知られている既知物質であって、25℃において液状の性状を有するものである。ポリオキシエチレンの付加モル数としては5〜10が好ましく、脂肪酸としては炭素数12〜20のものが好ましい。このようなポリオキシエチレン脂肪酸グリセリンを例示すると、ポリオキシエチレン(5)ヤシ油脂肪酸グリセリン、ポリオキシエチレン(7)ヤシ油脂肪酸グリセリン、ポリオキシエチレン(10)ヤシ油脂肪酸グリセリン、ポリオキシエチレン(5)パーム核油脂肪酸グリセリン、ポリオキシエチレン(7)パーム核脂肪酸グリセリン、ポリオキシエチレン(10)パーム核脂肪酸グリセリン、ポリオキシエチレン(5)グリセリルモノオレート、ポリオキシエチレン(7)グリセリルモノオレート、ポリオキシエチレン(10)グリセリルモノオレ
ート、ポリオキシエチレン(5)イソステアリン酸グリセリン、ポリオキシエチレン(7)イソステアリン酸グリセリン、ポリオキシエチレン(10)イソステアリン酸グリセリン等が挙げられる。これらの中でもポリオキシエチレン(7)ヤシ油脂肪酸グリセリンが特に好ましい。本発明では、これらポリオキシエチレン脂肪酸グリセリンエステルの中から適宜選択し、1種単独または2種以上を組み合わせて配合できる。ポリオキシエチレン脂肪酸グリセリンエステルの配合量は特に限定されるものではないが、シャンプー組成物全体に対して0.3〜10%が好ましく、特に0.5〜5%が好ましい。この配合量の範囲であれば、洗髪中の起泡性や使用感触を損なわない範囲で十分な洗浄性とコンディショニング効果を得られるため好ましい。
Component (D) used in the shampoo composition of the present invention is a polyoxyethylene fatty acid glycerin that is liquid at 25 ° C., which is a known substance known as a nonionic surfactant and has liquid properties at 25 ° C. It is. The added mole number of polyoxyethylene is preferably 5 to 10, and the fatty acid preferably has 12 to 20 carbon atoms. Examples of such polyoxyethylene fatty acid glycerin include polyoxyethylene (5) coconut oil fatty acid glycerin, polyoxyethylene (7) coconut oil fatty acid glycerin, polyoxyethylene (10) coconut oil fatty acid glycerin, polyoxyethylene (5 ) Palm kernel oil fatty acid glycerin, polyoxyethylene (7) Palm kernel fatty acid glycerin, polyoxyethylene (10) Palm kernel fatty acid glycerin, polyoxyethylene (5) glyceryl monooleate, polyoxyethylene (7) glyceryl monooleate, poly Examples include oxyethylene (10) glyceryl monooleate, polyoxyethylene (5) glyceryl isostearate, polyoxyethylene (7) glyceryl isostearate, polyoxyethylene (10) glycerin isostearate. It is. Among these, polyoxyethylene (7) coconut oil fatty acid glycerin is particularly preferable. In this invention, it can select suitably from these polyoxyethylene fatty-acid glycerol esters, and can mix | blend 1 type individually or in combination of 2 or more types. The blending amount of the polyoxyethylene fatty acid glycerin ester is not particularly limited, but is preferably 0.3 to 10%, particularly preferably 0.5 to 5% with respect to the entire shampoo composition. If it is the range of this compounding quantity, since sufficient washing | cleaning property and a conditioning effect are acquired in the range which does not impair the foamability and use feeling during hair washing, it is preferable.
本発明のシャンプー組成物に用いられる成分(E)N−アシルサルコシントリエタノールアミンとしては、例えばN−ラウロイルサルコシントリエタノールアミン、N−ミリストイルサルコシントリエタノールアミン等が挙げられる。本発明では、これらN−アシルサルコシントリエタノールアミンの中から適宜選択し、1種単独または2種以上を組み合わせて配合できる。N−アシルサルコシントリエタノールアミンの配合量は特に限定されるものではないが、シャンプー組成物全体に対して1%〜30%が好ましく、特に5〜20%が好ましい。これは、N−アシルサルコシントリエタノールアミンの配合量を増やすと、コンディショニング効果(例えば、洗浄中の使用感および洗浄後の仕上り感の良さ等)が高くなるが、粘性が低くなるため、充分なコンディショニング効果を得るには1%以上が好ましく、また、適度な粘性を保ち、充分な起泡性を得るには30%以下が好ましいからである。 Examples of component (E) N-acyl sarcosine triethanolamine used in the shampoo composition of the present invention include N-lauroyl sarcosine triethanolamine, N-myristoyl sarcosine triethanolamine, and the like. In this invention, it can select suitably from these N-acyl sarcosine triethanolamine, and can mix | blend 1 type individually or in combination of 2 or more types. Although the compounding quantity of N-acyl sarcosine triethanolamine is not specifically limited, 1%-30% are preferable with respect to the whole shampoo composition, and 5-20% is especially preferable. This is because when the blending amount of N-acyl sarcosine triethanolamine is increased, the conditioning effect (for example, the feeling of use during washing and the feeling of finishing after washing, etc.) is increased, but the viscosity is lowered. This is because 1% or more is preferable for obtaining the conditioning effect, and 30% or less is preferable for maintaining a suitable viscosity and obtaining sufficient foaming properties.
本発明のシャンプー組成物に用いられる成分(F)塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体は、表示名称ポリクオタニウム−7(日本化粧品表示名称辞典、薬事日報社、2007年)として記載された公知の高分子成分である。本発明では、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体の配合量は特に限定されるものではないが、シャンプー組成物全体に対して0.01〜1%が好ましく、特に0.02〜0.5%が好ましい。この配合量の範囲であれば、洗髪時およびすすぎ時の指通り性に優れ、また乾燥後の仕上がり感触においても好ましい。 The component (F) dimethyldiallylammonium chloride / acrylamide copolymer used in the shampoo composition of the present invention is a known high molecular weight polyquaternium-7 (Japanese Cosmetic Label Name Dictionary, Yakuji Nippo, 2007). It is a molecular component. In the present invention, the amount of the dimethyldiallylammonium chloride / acrylamide copolymer is not particularly limited, but is preferably 0.01 to 1%, particularly 0.02 to 0.5%, based on the entire shampoo composition. % Is preferred. When the amount is within this range, it is excellent in fingering property at the time of shampooing and rinsing, and is preferable in the finished touch after drying.
本発明のシャンプー組成物は、常法により製造することができ、pH3〜10のシャンプーとして提供され、使用部位や使用場面に合わせて、固体、粉体、液体、ジェル、クリーム、エアゾール、フォーム等様々な態様をとることができる。 The shampoo composition of the present invention can be produced by a conventional method, and is provided as a shampoo having a pH of 3 to 10, and is solid, powder, liquid, gel, cream, aerosol, foam, etc. according to the use site and use scene. Various aspects can be taken.
また、本発明のシャンプー組成物には、上記成分のほかに本発明の効果を損なわない範囲で公知の成分を適宜配合することができる。公知の成分としては、脂肪酸グリセリンエステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ポリグリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ペンタエリトリトール脂肪酸エステル、モノグリセリド誘導体、高級アルコール酸化エチレン付加物、ポリオキシエチレンアルキルアリルエーテル、ポリオキシエチレンラノリンアルコール、アルキルフェノールホルマリン縮合物の酸化エチレン誘導体、プルロニック型界面活性剤、ポリオキシエチレンアルキルチオエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレングリセリンモノ脂肪酸エステル、ポリオキシエチレンプロピレングリコールモノ脂肪酸エステル、ポリオキシエチレンソルビトール脂肪酸エステル、ポリオキシエチレンヒマシ油、硬化ヒマシ油誘導体、ポリオキシエチレンラノリン誘導体、脂肪族アルキル基を含むブロックポリマー、ポリオキシエチレン脂肪酸アミド、ポリオキシエチレンアルキルアミン、アルキルアミンオキシド、アルキルポリグルコシドに代表されるノニオン性界面活性剤、塩化アルキルトリメチルアンモニウム、塩化ジアルキルジメチルアンモニウム、脂肪酸アミドアミン塩、エチル硫酸ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウム、ジココイルエチルヒドロキシエチルモニウムメトサルフェート、ステアロキシプロピルジメ
チルアミン、ステアロキシプロピルトリモニウムクロリド、ステアリルPGジメチルアミン、ステアリルPGトリモニウムクロリド、ベヘニルPGトリモニウムクロリドに代表されるカチオン性界面活性剤が挙げられる。
Moreover, a well-known component can be suitably mix | blended with the shampoo composition of this invention in the range which does not impair the effect of this invention other than the said component. Known components include fatty acid glycerin esters, sorbitan fatty acid esters, sucrose fatty acid esters, polyglycerin fatty acid esters, propylene glycol fatty acid esters, pentaerythritol fatty acid esters, monoglyceride derivatives, higher alcohol ethylene oxide adducts, polyoxyethylene alkyl allyl ethers. , Polyoxyethylene lanolin alcohol, ethylene oxide derivatives of alkylphenol formalin condensate, pluronic surfactant, polyoxyethylene alkyl thioether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin monofatty acid ester, polyoxyethylene propylene glycol monofatty acid Esters, polyoxyethylene sorbitol fatty acid esters, polyoxyethylene Castor oil, hydrogenated castor oil derivative, polyoxyethylene lanolin derivative, block polymer containing aliphatic alkyl group, polyoxyethylene fatty acid amide, polyoxyethylene alkylamine, alkylamine oxide, nonionic surfactant represented by alkylpolyglucoside Agent, alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, fatty acid amidoamine salt, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium, dicocoylethylhydroxyethylmonium methosulfate, stearoxypropyldimethylamine, stearoxypropyltrimonium chloride, stearyl PG Cations represented by dimethylamine, stearyl PG trimonium chloride, behenyl PG trimonium chloride Surfactants.
さらにアボカド油、アルモンド油、オリーブ油、グレープシード油、コメヌカ油、コメ胚芽油、月見草油、ツバキ油、サザンカ油、マカデミアナッツ油、メドフォーム油、ローズヒップ油、アンズ核油、シアバター、卵黄油、馬脂等の油脂類、ホホバ油、カルナウバロウ、キャンデリラロウ、ラノリン、ミツロウ等のロウ類、オゾケライト、流動パラフィン、スクワレン、ワセリン等の炭化水素類、イソステアリルアルコール、オクチルドデカノール、ラノリンアルコール、フィトステロール、セタノール、オレイルアルコール等の高級アルコール類、ミリスチン酸イソプロピル、オレイン酸エチル、ステアリン酸オクチル、2−エチルヘキサン酸セチル、イソノナン酸イソノニル、パルミチン酸オクチル、ジオレイン酸エチレングリコール、トリイソステアリン酸グリセリル、乳酸セチル、アジピン酸ジイソプロピル、イソステアリン酸コレステリル等のエステル油類等、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール、ポリエチレングリコール、グリセリン、グリコシルトレハロース、ジグリセリン、イソプレングリコール、1,3−ブチレングリコール等の多価アルコール、エチルアルコール、イソプロパノール等の低級アルコール、キサンタンガム、グアガム、デンプン等の天然高分子及びその誘導体、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、メチルセルロース等のセルロール系高分子、カルボキシビニルポリマーやポリビニルピロリドン等の合成高分子等、ジステアリン酸エチレングリコール、ジステアリン酸トリエチレングリコール等のパール化剤、カオリン、無水ケイ酸、ケイ酸アルミニウムマグネシウム、タルク、マイカ、セルロース末、シルク末、デンプン、ポリエチレン末、ナイロン末、架橋ポリスチレン等の顔料、防腐剤、金属イオン封鎖剤、噴射剤、無機塩、有機酸及びその塩、ピロリドンカルボン酸及びその塩、ヒアルロン酸及びその塩、ソルビトールやマルチトールやトレハロース等の糖類、トリメチルグリシン等の保湿剤、塩化ベンザルコニウム、塩化ベンゼトニウム、イソプロピルメチルフェノール、ピロクトンオラミン、クララエキス、ジンクピリチオン、ヒノキチオール等の殺菌剤、その他、センブリエキス、塩化カプロニウム、セファランチン、サリチル酸、イノシット、ヨウ化ニンニクエキス、レゾルシン、エストラジオール、エチニルエストラジオール、オキセンドロン、パントテン酸及びその誘導体、プラセンタエキス、ビオチン、モノニトログアヤコール、感光素301、ウシヘマチン、グリチルリチン酸ジカリウム、塩酸ピリドキシン、冷感剤、温感剤、動植物抽出物、ビタミン、紫外線吸収剤、アミノ酸及びその誘導体、タンパク質及びその誘導体、酸化防止剤、着色剤、香料等である。 Avocado oil, almond oil, olive oil, grape seed oil, rice bran oil, rice germ oil, evening primrose oil, camellia oil, sasanqua oil, macadamia nut oil, medfoam oil, rosehip oil, apricot kernel oil, shea butter, egg yolk oil, Fats and oils such as horse fat, jojoba oil, carnauba wax, candelilla wax, waxes such as lanolin and beeswax, hydrocarbons such as ozokerite, liquid paraffin, squalene and petrolatum, isostearyl alcohol, octyldodecanol, lanolin alcohol, phytosterol , Higher alcohols such as cetanol and oleyl alcohol, isopropyl myristate, ethyl oleate, octyl stearate, cetyl 2-ethylhexanoate, isononyl isononanoate, octyl palmitate, ethylene glycol dioleate Ester oils such as glyceryl triisostearate, cetyl lactate, diisopropyl adipate, cholesteryl isostearate, propylene glycol, dipropylene glycol, polypropylene glycol, polyethylene glycol, glycerin, glycosyl trehalose, diglycerin, isoprene glycol, 1,3- Polyhydric alcohols such as butylene glycol, lower alcohols such as ethyl alcohol and isopropanol, natural polymers such as xanthan gum, guar gum and starch, and derivatives thereof, cellulose polymers such as hydroxypropylmethylcellulose, hydroxyethylcellulose, methylcellulose, carboxyvinyl polymers, Synthetic polymers such as polyvinylpyrrolidone, ethylene glycol distearate, distearin Pearling agents such as triethylene glycol, kaolin, silicic anhydride, magnesium aluminum silicate, talc, mica, cellulose powder, silk powder, starch, polyethylene powder, nylon powder, cross-linked polystyrene pigments, preservatives, sequestering metal ions Agent, propellant, inorganic salt, organic acid and salt thereof, pyrrolidone carboxylic acid and salt thereof, hyaluronic acid and salt thereof, saccharides such as sorbitol, maltitol and trehalose, humectant such as trimethylglycine, benzalkonium chloride, chloride Disinfectants such as benzethonium, isopropylmethylphenol, piroctone olamine, Clara extract, zinc pyrithione, hinokitiol, etc., assembly extract, capronium chloride, cephalanthin, salicylic acid, inosit, garlic iodide extract, resorcin, estra Diol, ethinylestradiol, oxendron, pantothenic acid and its derivatives, placenta extract, biotin, mononitroguaiacol, photosensitizer 301, bovine hematin, dipotassium glycyrrhizinate, pyridoxine hydrochloride, cooling sensate, warming sensate, animal and plant extract, vitamins, ultraviolet light Absorbents, amino acids and derivatives thereof, proteins and derivatives thereof, antioxidants, colorants, fragrances and the like.
次に本発明のシャンプー組成物について実施例をもって詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で採用した試験法及び評価基準を説明する。 Next, although the shampoo composition of this invention is demonstrated in detail with an Example, this invention is not limited by this. Prior to the examples, test methods and evaluation criteria employed in each example will be described.
(1)起泡力試験
1,000mL容器の攪拌機つき円筒形シリンダーに、実施例および比較例のシャンプー組成物の5%水溶液を50mL入れ、5,000rpmで1分間攪拌した後の泡容積を測定した。また、評価の基準を次のように設定した。
◎:泡立ち極めて良好 泡容積600mL以上
○:泡立ち良好 泡容積500mL以上,600mL未満
△:泡立ち普通 泡容積400mL以上,500mL未満
×:泡立ち不良 泡容積400mL未満
(1) Foaming force test 50 mL of a 5% aqueous solution of the shampoo compositions of Examples and Comparative Examples was placed in a cylindrical cylinder with a stirrer in a 1,000 mL container, and the foam volume after stirring at 5,000 rpm for 1 minute was measured. did. The evaluation criteria were set as follows.
◎: Foaming extremely good Foam volume 600 mL or more ○: Foaming good Foam volume 500 mL or more, less than 600 mL △: Foaming normal Foam volume 400 mL or more, less than 500 mL ×: Poor foaming Foam volume less than 400 mL
(2)洗髪時及びすすぎ時の使用感試験(ハーフヘッド法)
10名の専門パネルにより、実施例および比較例のシャンプー組成物を使用し、洗髪中の
指通り、すすぎ時の指通り、すすぎ後のきしみの有無を官能評価した。尚、評価基準は以下の通りである。
[洗髪中の指通り]
◎:極めて良好 洗髪中の指通りが良いと答えた被験者の数が8人以上
○:良好 洗髪中の指通りが良いと答えた被験者の数が6人以上、8人未満
△:やや悪い 洗髪中の指通りが良いと答えた被験者の数が4人以上、6人未満
×:悪い 洗髪中の指通りが良いと答えた被験者の数が4人未満
[すすぎ時の指通り]
◎:極めて良好 すすぎ時の指通りが良いと答えた被験者の数が8人以上
○:良好 すすぎ時の指通りが良いと答えた被験者の数が6人以上、8人未満
△:やや悪い すすぎ時の指通りが良いと答えた被験者の数が4人以上、6人未満
×:悪い すすぎ時の指通りが良いと答えた被験者の数が4人未満
[すすぎ後のきしみ]
◎:極めて良好 きしまないと答えた被験者の数が8人以上
○:良好 きしまないと答えた被験者の数が6人以上、8人未満
△:やや悪い きしまないと答えた被験者の数が4人以上、6人未満
×:悪い きしまないと答えた被験者の数が4人未満
(2) Usability test during shampooing and rinsing (half head method)
The shampoo compositions of Examples and Comparative Examples were used by 10 specialist panels to perform sensory evaluation on the presence of squeaks after rinsing, passing through fingers during rinsing, passing through fingers during rinsing. The evaluation criteria are as follows.
[Following fingers during hair washing]
◎: Very good The number of subjects who answered good fingering during hair washing was 8 or more ○: Good The number of subjects who answered good fingering during hair washing was 6 or more and less than 8 △: Slightly bad hair washing The number of subjects who answered that the fingering in the middle was good was 4 or more and less than 6 ×: Bad The number of subjects who answered that the fingering during hair washing was good was less than 4 [fingering during rinsing]
◎: Very good The number of subjects who answered good fingering during rinsing was 8 or more ○: Good The number of subjects who answered good fingering during rinsing was 6 or more and less than 8 △: Slightly bad rinsing The number of subjects who answered that the fingering was good was 4 or more and less than 6 ×: Bad The number of subjects who answered that the fingering was good when rinsing was less than 4 [squeak after rinsing]
◎: The number of subjects who answered that it was extremely good is 8 or more ○: The number of subjects who answered that it is not good is 6 or more and less than 8 △: The number of subjects who answered that it is somewhat bad 4 or more and less than 6 ×: The number of subjects who answered that it was not bad is less than 4
(3)洗髪乾燥後の髪の仕上がり感試験
10名の専門パネルが上記と同様の方法で洗髪した後、毛髪を乾燥させ、毛髪のぱさつき、まとまり易さの良否等の仕上がり感を官能評価した。尚、評価基準は以下の通りである。
[ぱさつき]
◎:極めて良好 ぱさつきがないと答えた被験者の数が8人以上
○:良好 ぱさつきがないと答えた被験者の数が6人以上、8人未満
△:やや悪い ぱさつきがないと答えた被験者の数が4人以上、6人未満
×:悪い ぱさつきがないと答えた被験者の数が4人未満
[まとまり]
◎:極めて良好 髪のまとまりが良いと答えた被験者の数が8人以上
○:良好 髪のまとまりが良いと答えた被験者の数が6人以上、8人未満
△:やや悪い 髪のまとまりが良いと答えた被験者の数が4人以上、6人未満
×:悪い 髪のまとまりが良いと答えた被験者の数が4人未満
(3) Hair finish feeling test after hair washing and drying After 10 specialist panels washed their hair in the same way as above, they dried the hair and sensory evaluated the finish feeling such as the crispness of the hair and the ease of uniting. . The evaluation criteria are as follows.
[Patsuki]
◎: The number of subjects who answered that there was no very good texture was 8 or more. ○: The number of subjects who answered that there was no good texture was 6 or more and less than 8. Is 4 or more and less than 6 ×: The number of subjects who answered that there is no bad pap
◎: Very good The number of subjects who answered that the hair was well-organized was 8 or more ○: Good The number of subjects who answered that the hair was well-organized was 6 or more and less than 8 △: Slightly poor The number of subjects who replied 4 or more and less than 6 ×: Bad The number of subjects who replied that the hair was well organized was less than 4
実施例1〜8及び比較例1〜4
表1に示す組成のシャンプー組成物を調製し、これらを使用したときの起泡性、洗髪時の指通り、すすぎ時の使用感、乾燥後のぱさつきおよびまとまりについて評価し、その結果を表1に示した。なお、以下の実施例の組成における配合量は質量%である。
Examples 1-8 and Comparative Examples 1-4
A shampoo composition having the composition shown in Table 1 was prepared, and foaming properties when using these, evaluation of fingering at the time of shampooing, feeling of use at the time of rinsing, crispness and unity after drying were evaluated, and the results are shown in Table 1. It was shown to. In addition, the compounding quantity in the composition of a following example is the mass%.
表1より明らかなように、本発明の成分を用いた実施例1〜8のシャンプーは比較例1〜4の組成物に比べていずれも優れた性能を見出した。 As is clear from Table 1, the shampoos of Examples 1 to 8 using the components of the present invention found excellent performance as compared with the compositions of Comparative Examples 1 to 4.
以下、本発明のシャンプー組成物のその他の処方例を実施例として挙げる。なお、これらの実施例のシャンプー組成物についても、上記の起泡性、洗髪時の指通り、すすぎ時の使用感、乾燥後のぱさつきおよびまとまりなどの各項目を評価したところ、いずれの実施例においても、優れた特性を有しており良好であった。 Hereinafter, other formulation examples of the shampoo composition of the present invention will be given as examples. As for the shampoo compositions of these examples, each of the above-mentioned foaming property, fingering at the time of shampooing, feeling of use at the time of rinsing, crispness after drying, and unity were evaluated. Also had excellent characteristics.
実施例9 シャンプー
(1)ラウレス硫酸ナトリウム 9.0
(2)ラウラミドプロピルベタイン 3.0
(3)ラウロイルメチルアラニンナトリウム 2.0
(4)N−ラウロイルサルコシントリエタノールアミン 2.0
(5)ヤシ油脂肪酸モノエタノールアミド 2.0
(6)アルギニルフルクトシルグルコース 0.1
(7)サッカロミセス/コメヌカ発酵液エキス 1.0
(8)塩化ナトリウム 0.1
(9)カチオン化セルロース(電荷密度:1.3meq/g) 0.2
(10)カチオン化グアガム(電荷密度:0.7meq/g) 0.1
(11)カチオン化タラガム(電荷密度:1.5meq/g) 0.1
(12)ポリオキシエチレン(7)ヤシ油脂肪酸グリセリン 4.0
(13)ヤシ油脂肪酸N−メチルエタノールアミド 2.0
(14)塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体 0.1
(15)ジステアリン酸エチレングリコール 2.0
(16)桃葉エキス 0.5
(17)海藻エキス 0.1
(18)セリシン 0.1
(19)アロエベラ葉エキス 0.1
(20)グリコシルトレハロース 0.5
(21)N−アセチルグルコサミン 0.3
(22)D−パントテニルアルコール 0.1
(23)加水分解コラーゲン液 0.5
(24)ヒアルロン酸ナトリウム 0.1
(25)シルクエキス 0.5
(26)加水分解コムギ 0.1
(27)L−アルギニン 0.1
(28)グルタミン酸ナトリウム 0.5
(29)L−プロリン 0.1
(30)ローズヒップ油 0.1
(31)グレープシード油 0.1
(32)ラウロイルグルタミン酸ジ(フィトステリル/オクチルドデシル) 0.1
(33)ポリクオタニウムー64 0.1
(34)加水分解カラスムギタンパク 0.2
(35)海水 0.5
(36)クエン酸 0.4
(37)安息香酸ナトリウム 0.5
(38)EDTA 0.1
(39)カラメル 0.2
(40)香料 0.5
(41)精製水 バランス
Example 9 Shampoo (1) Sodium Laureth Sulfate 9.0
(2) Lauramidopropylbetaine 3.0
(3) Sodium lauroylmethylalanine 2.0
(4) N-lauroyl sarcosine triethanolamine 2.0
(5) Palm oil fatty acid monoethanolamide 2.0
(6) Arginyl fructosyl glucose 0.1
(7) Saccharomyces / Komenuka Fermented Liquid Extract 1.0
(8) Sodium chloride 0.1
(9) Cationized cellulose (charge density: 1.3 meq / g) 0.2
(10) Cationized guar gum (charge density: 0.7 meq / g) 0.1
(11) Cationized tara gum (charge density: 1.5 meq / g) 0.1
(12) Polyoxyethylene (7) Palm oil fatty acid glycerin 4.0
(13) Palm oil fatty acid N-methylethanolamide 2.0
(14) Dimethyldiallylammonium chloride / acrylamide copolymer 0.1
(15) Ethylene glycol distearate 2.0
(16) Peach leaf extract 0.5
(17) Seaweed extract 0.1
(18) Sericin 0.1
(19) Aloe vera leaf extract 0.1
(20) Glycosyl trehalose 0.5
(21) N-acetylglucosamine 0.3
(22) D-pantothenyl alcohol 0.1
(23) Hydrolyzed collagen solution 0.5
(24) Sodium hyaluronate 0.1
(25) Silk extract 0.5
(26) Hydrolyzed wheat 0.1
(27) L-arginine 0.1
(28) Sodium glutamate 0.5
(29) L-proline 0.1
(30) Rosehip oil 0.1
(31) Grape seed oil 0.1
(32) Lauroyl glutamate di (phytosteryl / octyldodecyl) 0.1
(33) Polyquaternium-64 0.1
(34) Hydrolyzed oat protein 0.2
(35) Seawater 0.5
(36) Citric acid 0.4
(37) Sodium benzoate 0.5
(38) EDTA 0.1
(39) Caramel 0.2
(40) Fragrance 0.5
(41) Balance of purified water
常法により上記組成のシャンプーを調製し、洗髪中の使用感、洗髪乾燥後の仕上がり感、起泡性を評価したところ、いずれの特性も優れており良好な結果を得た。 A shampoo having the above composition was prepared by a conventional method, and the feeling of use during shampooing, the finished feeling after drying the shampoo, and the foaming property were evaluated, and all the characteristics were excellent and good results were obtained.
実施例10 シャンプー
(1)ラウラミドプロピルベタイン 6.0
(2)パーム核油脂肪酸アミドプロピルベタイン 6.0
(3)N−ラウロイルサルコシントリエタノールアミン 3.0
(4)アルギニルフルクトシルグルコース 0.1
(5)サッカロミセス/コメヌカ発酵液エキス 1.0
(6)塩化ナトリウム 0.1
(7)カチオン化グアガム(電荷密度:1.1meq/g) 0.2
(8)カチオン化タラガム(電荷密度:0.7meq/g) 0.1
(9)カチオン化セルロース(電荷密度:1.3meq/g) 0.1
(10)ポリオキシエチレン(7)ヤシ油脂肪酸グリセリン 6.0
(11)塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体 0.2
(12)ヤシ油脂肪酸N−メチルエタノールアミド 3.0
(13)ラウラミドMIPA 1.0
(14)セテアレス−60ミリスチルグリコール 0.5
(15)ジステアリン酸エチレングリコール 2.0
(16)ムクロジエキス 0.5
(17)ヒオウギエキス 0.1
(18)ツバキエキス 0.1
(19)黒米エキス(商品名:黒米エキス−PC〔オリザ油化製〕) 0.1
(20)コメヌカエキス 0.1
(21)コメ胚芽油 0.1
(22)加水分解コメタンパク 0.5
(23)コメヌカ油脂肪酸フィトステリル 0.1
(24)クエン酸 0.2
(25)安息香酸ナトリウム 0.2
(26)EDTA 0.1
(27)カラメル 0.1
(28)香料 0.5
(29)精製水 バランス
Example 10 Shampoo (1) Lauramidopropylbetaine 6.0
(2) Palm kernel oil fatty acid amidopropyl betaine 6.0
(3) N-lauroyl sarcosine triethanolamine 3.0
(4) Arginyl fructosyl glucose 0.1
(5) Saccharomyces / Komenuka Fermented Liquid Extract 1.0
(6) Sodium chloride 0.1
(7) Cationized guar gum (charge density: 1.1 meq / g) 0.2
(8) Cationized tara gum (charge density: 0.7 meq / g) 0.1
(9) Cationized cellulose (charge density: 1.3 meq / g) 0.1
(10) Polyoxyethylene (7) Palm oil fatty acid glycerin 6.0
(11) Dimethyldiallylammonium chloride / acrylamide copolymer 0.2
(12) Coconut oil fatty acid N-methylethanolamide 3.0
(13) Lauramide MIPA 1.0
(14) Cetealess-60 myristyl glycol 0.5
(15) Ethylene glycol distearate 2.0
(16) Mukuroji extract 0.5
(17) Hinogi extract 0.1
(18) Camellia extract 0.1
(19) Black rice extract (trade name: black rice extract-PC [manufactured by Oriza Oil Co., Ltd.)] 0.1
(20) Rice bran extract 0.1
(21) Rice germ oil 0.1
(22) Hydrolyzed rice protein 0.5
(23) Rice bran oil fatty acid phytosteryl 0.1
(24) Citric acid 0.2
(25) Sodium benzoate 0.2
(26) EDTA 0.1
(27) Caramel 0.1
(28) Fragrance 0.5
(29) Balance of purified water
常法により上記組成のシャンプーを調製し、洗髪中の使用感、洗髪乾燥後の仕上がり感、起泡性を評価したところ、いずれの特性も優れており良好な結果を得た。 A shampoo having the above composition was prepared by a conventional method, and the feeling of use during shampooing, the finished feeling after drying the shampoo, and the foaming property were evaluated, and all the characteristics were excellent and good results were obtained.
実施例11 シャンプー
(1)N−ラウロイルサルコシントリエタノールアミン 9.0
(2)ココイルグルタミン酸TEA 3.0
(3)パーム核油脂肪酸アミドプロピルベタイン 6.0
(4)ポリオキシプロピレンヤシ油脂肪酸モノエタノールアミド 2.0
(5)ヤシ油脂肪酸モノエタノールアミド 1.0
(6)ヤシ油脂肪酸N−メチルエタノールアミド 2.0
(7)カチオン化セルロース(電荷密度:0.8meq/g) 0.2
(8)カチオン化グアガム(電荷密度:1.1meq/g) 0.2
(9)カチオン化タラガム(電荷密度:0.7meq/g) 0.1
(10)塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体 0.5
(11)ポリクオタニウム−49 0.1
(12)ポリオキシエチレン(7)ヤシ油脂肪酸グリセリン 2.0
(13)ジステアリン酸エチレングリコール 2.0
(14)ミリスチン酸 0.3
(15)アルギニルフルクトシルグルコース 0.1
(16)サッカロミセス/コメヌカ発酵液エキス 1.0
(17)ムクロジエキス 0.5
(18)ヒオウギエキス 0.1
(19)ツバキエキス 0.1
(20)チャ花エキス 0.1
(21)黒米エキス(商品名:黒米エキス−PC〔オリザ油化製〕) 0.1
(22)赤米エキス 0.1
(23)コメヌカエキス 0.1
(24)コメ胚芽油 0.1
(25)加水分解コメタンパク 0.5
(26)コメヌカ油脂肪酸フィトステリル 0.1
(27)アンズ核油 0.1
(28)イノシトール 0.3
(29)クエン酸 0.4
(30)安息香酸ナトリウム 0.5
(31)EDTA 0.1
(32)塩化ナトリウム 0.5
(33)カラメル 0.2
(34)香料 0.5
(35)精製水 バランス
Example 11 Shampoo (1) N-lauroyl sarcosine triethanolamine 9.0
(2) Cocoa glutamic acid TEA 3.0
(3) Palm kernel oil fatty acid amidopropyl betaine 6.0
(4) Polyoxypropylene coconut oil fatty acid monoethanolamide 2.0
(5) Palm oil fatty acid monoethanolamide 1.0
(6) Palm oil fatty acid N-methylethanolamide 2.0
(7) Cationized cellulose (charge density: 0.8 meq / g) 0.2
(8) Cationized guar gum (charge density: 1.1 meq / g) 0.2
(9) Cationized tara gum (charge density: 0.7 meq / g) 0.1
(10) Dimethyldiallylammonium chloride / acrylamide copolymer 0.5
(11) Polyquaternium-49 0.1
(12) Polyoxyethylene (7) Palm oil fatty acid glycerin 2.0
(13) Ethylene glycol distearate 2.0
(14) Myristic acid 0.3
(15) Arginyl fructosyl glucose 0.1
(16) Saccharomyces / Komenuka Fermented Liquid Extract 1.0
(17) Mukuroji extract 0.5
(18) Hinogi extract 0.1
(19) Camellia extract 0.1
(20) Cha Flower Extract 0.1
(21) Black rice extract (trade name: black rice extract-PC [manufactured by Oriza Oil Co., Ltd.)] 0.1
(22) Red rice extract 0.1
(23) Rice bran extract 0.1
(24) Rice germ oil 0.1
(25) Hydrolyzed rice protein 0.5
(26) Rice bran oil fatty acid phytosteryl 0.1
(27) Apricot kernel oil 0.1
(28) Inositol 0.3
(29) Citric acid 0.4
(30) Sodium benzoate 0.5
(31) EDTA 0.1
(32) Sodium chloride 0.5
(33) Caramel 0.2
(34) Fragrance 0.5
(35) Balance of purified water
常法により上記組成のシャンプーを調製し、洗髪中の使用感、洗髪乾燥後の仕上がり感、
起泡性を評価したところ、いずれの特性も優れており良好な結果を得た。
A shampoo having the above composition is prepared by a conventional method, a feeling of use during hair washing, a feeling of finish after hair washing,
When the foaming property was evaluated, all the characteristics were excellent and good results were obtained.
Claims (4)
(A)アルギニルフルクトシルグルコース
(B)エーテル硫酸塩型アニオン性界面活性剤及びベタイン型両性界面活性剤から選ばれる1種以上
(C)カチオン化セルロース及びカチオン化グアガムから選ばれる1種以上 A shampoo composition comprising the following components (A) to (C):
(A) one or more selected from arginyl fructosyl glucose (B) ether sulfate type anionic surfactant and betaine type amphoteric surfactant (C) one or more selected from cationized cellulose and cationized guar gum
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JP2016056144A (en) * | 2014-09-11 | 2016-04-21 | クラシエホームプロダクツ株式会社 | Hair shampoo |
JP2021046363A (en) * | 2019-09-18 | 2021-03-25 | クラシエホームプロダクツ株式会社 | Hair wash composition |
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JP2021046363A (en) * | 2019-09-18 | 2021-03-25 | クラシエホームプロダクツ株式会社 | Hair wash composition |
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