JP2013193254A - Slip-resistant decorative sheet - Google Patents

Slip-resistant decorative sheet Download PDF

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JP2013193254A
JP2013193254A JP2012060297A JP2012060297A JP2013193254A JP 2013193254 A JP2013193254 A JP 2013193254A JP 2012060297 A JP2012060297 A JP 2012060297A JP 2012060297 A JP2012060297 A JP 2012060297A JP 2013193254 A JP2013193254 A JP 2013193254A
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decorative sheet
slip
convex
point
convex portions
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JP6102069B2 (en
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Takeken Sugita
剛謙 杉田
Koichi Sagawa
浩一 佐川
Hajime Harima
一 播磨
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Toppan Cosmo Inc
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Toppan Cosmo Inc
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Abstract

PROBLEM TO BE SOLVED: To provide a slip-resistant decorative sheet that has slip resistance, particularly, can prevent a slip during a walk, particularly, a decorative sheet used for a floor material indoors.SOLUTION: There is provided a slip-resistant decorative sheet which has many projections formed on a surface, the decorative sheet being characterized in that the projections have a height h of 10-100 μm and a width w of 15-300 μm from an optional side end to an opposite side end of a projection, a distance d from one point of an optional projection to another projection at the shortest distance is 50-1,000 μm, and the projections have a dot density of 1-300 dots/mm.

Description

本発明は、歩行時のスリップを防止できる防滑性化粧シートに関し、特に屋内において床材に使用される化粧シートに関する。   The present invention relates to an anti-slip decorative sheet that can prevent slipping during walking, and more particularly to a decorative sheet used for flooring indoors.

近年の屋内や屋外の建造物床面にはフローリング材が多く用いられている。フローリング材には突板に塗装したものが一般的であったが、実用上の観点から耐傷性、耐汚染性などの様々な表面性能が要求されることから、木質系基材や樹脂系基材に化粧シートをラミネートしたものなどが用いられるようになってきた。   In recent years, flooring materials are often used for indoor and outdoor building floors. The flooring material is generally painted on a veneer, but from the practical point of view, various surface performances such as scratch resistance and contamination resistance are required. A laminate made of a decorative sheet has been used.

これらのような化粧シートを用いた床材は、実用上の要求や化粧シートの製造技術の発達により、耐候性、耐傷性、耐汚染性などの様々な性能を併せ持つようになってきている。   Floor materials using such decorative sheets have come to have various performances such as weather resistance, scratch resistance and stain resistance due to practical requirements and development of manufacturing technology of decorative sheets.

ところで、近年では利用者の住環境に対する意識の高まりから、床材に関しては上述したような実用上の性能だけでなく、安全性や快適性などの新たな性能が求められるようになってきている。   By the way, in recent years, due to heightened awareness of the living environment of users, not only the above-mentioned practical performance but also new performance such as safety and comfort have been required for flooring. .

それら求められる性能の一つとして、防滑性があげられる。この場合の防滑性とは屋内用のスリッパや木綿靴下と床材表面間における摩擦係数によって表現される。   One of the required performances is slip resistance. The slip resistance in this case is expressed by the coefficient of friction between the indoor slippers and cotton socks and the floor surface.

屋外、特に階段やバルコニー、マンション廊下等に用いられる床用のシートに関しては、従来、表面に凹凸を付与した種々の防滑性床材が提案されている。その一つとして、基材上に盛り上がり印刷模様部を形成し、この印刷模様部の表面に架橋樹脂からなる点状防滑小突起群を印刷して一体的に固着したノンスリップ床材が知られている。   As for floor sheets used outdoors, especially for stairs, balconies, and condominium corridors, various anti-slip floor materials having surface irregularities have been proposed. As one of them, there is known a non-slip floor material in which a raised printed pattern portion is formed on a base material, and a point-shaped anti-skid small protrusion group made of a crosslinked resin is printed on the surface of the printed pattern portion and fixed integrally. Yes.

特開平3−144061号公報Japanese Patent Laid-Open No. 3-144061

社団法人 日本建築学会著「床の性能評価方法の概要と性能の推奨値(案)」 2008年6月Japan Architectural Institute “Outline of performance evaluation method and recommended value (draft)” June 2008

本発明は上記の問題に対処すべくなされたもので、防滑性能、特に、歩行時のスリップを防止できる防滑性化粧シート、特に屋内において床材に使用される化粧シートを提供するものである。   The present invention has been made to cope with the above-described problems, and provides an anti-slip performance, particularly an anti-slip decorative sheet capable of preventing slipping during walking, particularly a decorative sheet used for flooring indoors.

本発明はこれらの課題を解決したものであり、すなわちその請求項1記載の発明は、表面に多数の凸部を形成してなる防滑性化粧シートにおいて、前記凸部の高さhが10〜100μmであり、凸部の任意の側端から対向する側端までの凸部の幅wが15〜300μmであり、任意の凸部の1点から最短距離にある他の凸部の1点までの距離dが50〜1000μmであり、凸部の点密度が1〜300点/mmであることを特徴とする防滑性化粧シートである。 The present invention solves these problems, that is, the invention according to claim 1 is a slip-proof decorative sheet formed with a large number of convex portions on the surface, wherein the height h of the convex portions is 10 to 10. 100 μm, the width w of the convex portion from any side end of the convex portion to the opposite side end is 15 to 300 μm, and from one point of the arbitrary convex portion to one point of the other convex portion at the shortest distance The distance d is 50 to 1000 μm, and the point density of the convex portions is 1 to 300 points / mm 2 .

またその請求項2記載の発明は、前記防滑性化粧シートの表面に、熱硬化型樹脂または紫外線硬化型樹脂もしくはこれらの混合物からなる樹脂による表面保護層を設けたことを特徴とする、請求項1記載の防滑性化粧シートである。   The invention described in claim 2 is characterized in that a surface protective layer made of a thermosetting resin, an ultraviolet curable resin or a mixture thereof is provided on the surface of the anti-slip decorative sheet. 1. A slip-proof decorative sheet according to 1.

本発明はその請求項1記載の発明により、凸部の高さ、大きさ、間隔、密度を限定することで、防滑性能、特に、歩行時のスリップを防止できる性能を有しつつ、耐候性、耐傷性、耐汚染性などにも問題のない防滑性化粧シートを提供することが可能となるという作用効果を奏する。   According to the first aspect of the present invention, the height, size, interval, and density of the projections are limited to provide anti-slip performance, in particular, performance that can prevent slipping during walking, and weather resistance. In addition, there is an effect that it is possible to provide a slip-proof decorative sheet having no problem in scratch resistance, stain resistance, and the like.

またその請求項2記載の発明により、表面保護層によりさらに耐候性、耐傷性、耐汚染性が向上した防滑性化粧シートを提供することが可能となるという作用効果を奏する。   Further, according to the invention described in claim 2, there is an effect that it is possible to provide an anti-slip decorative sheet that is further improved in weather resistance, scratch resistance and contamination resistance by the surface protective layer.

本発明の防滑性化粧シートの一実施例の断面の構造を示す説明図である。It is explanatory drawing which shows the structure of the cross section of one Example of the slip-proof decorative sheet of this invention.

以下本発明を図面に基づき詳細に説明する。図1に本発明の防滑性化粧シートの一実施例の断面の構造を示す。任意の積層構造からなる化粧シート1の表面に多数の凸部2を有してなり、適宜表面保護層3を設けてなる。   Hereinafter, the present invention will be described in detail with reference to the drawings. FIG. 1 shows a cross-sectional structure of an embodiment of the slip-proof decorative sheet of the present invention. The decorative sheet 1 having an arbitrary laminated structure has a large number of convex portions 2 on the surface and is appropriately provided with a surface protective layer 3.

本発明における化粧シート1としては、例えば、木目柄、抽象柄等の柄が印刷等により形成されたシートを用いることができる。化粧シート1の材質としては、例えば、ポリプロピレン、ポリエチレン、ポリエステル、アクリル等の樹脂材、紙材等が挙げられる。化粧シート1は、これらの材質のうち1種の単層構成であってもよく、2種以上の複層構成であってもよい。   As the decorative sheet 1 in the present invention, for example, a sheet in which a pattern such as a wood grain pattern or an abstract pattern is formed by printing or the like can be used. Examples of the material of the decorative sheet 1 include resin materials such as polypropylene, polyethylene, polyester, and acrylic, and paper materials. The decorative sheet 1 may have a single-layer configuration of these materials, or may have two or more multilayer configurations.

本発明における多数の凸部2としては、前記化粧シートの表面側の層に設けられるものであって、平滑な面の上に凸部2を設けるものでも良いが、最初から凸部2を有する層を溶融押出エンボスなどにより設けるものであるほうが設計上好適である。凸部2の材質としては前記化粧シート1の材質と同等のものか、後述する表面保護層3を設けない場合は表面の耐久性、耐傷付き性を有するものであれば特に限定するものではなく、適宜選択すればよい。   As many convex parts 2 in this invention, it is provided in the surface side layer of the said decorative sheet, Comprising: You may provide the convex part 2 on a smooth surface, but it has the convex part 2 from the beginning. It is preferable in design that the layer is provided by melt extrusion embossing or the like. The material of the convex part 2 is not particularly limited as long as it is equivalent to the material of the decorative sheet 1 or has surface durability and scratch resistance when the surface protective layer 3 described later is not provided. It may be selected as appropriate.

本発明における多数の凸部2は、その高さhが10〜100μmであり、凸部の任意の側端から対向する側端までの凸部の幅wが15〜300μmであり、任意の凸部の1点から最短距離にある他の凸部の1点までの距離dが50〜1000μmであり、凸部の点密度が1〜300点/mm2であるものとする。
前記高さhが10μmより低いと十分な防滑性が発現できず、1000μmより高いと防滑性が高すぎて引っ掛かる感じになり歩行性が悪いものとなる。また、表面の耐性も脆いものとなる可能性が高くなる。
前記幅wは凸部の直径あるいはおおよその大きさに該当する値であり、15μmより小さいものや300μmより大きいものであると十分な防滑性が発現できない。また、転写方式で設ける場合などでは大きすぎると形状の転写がうまく行えない。
前記距離dはおおよその凸部間距離に該当する値であり、50μmより短かったり1000μmより長かったりすると十分な防滑性が発現できない。また転写方式で設ける場合などでは短すぎると形状の転写がうまく行えない。
前記点密度はそのまま凸部の密度を示す値であり、1点/mmより少なかったり300点/mmより多かったりすると十分な防滑性が発現できない。また、転写方式で設ける場合などでは多すぎると形状の転写がうまく行えない。
A number of convex portions 2 in the present invention has a height h of 10 to 100 μm, a convex portion width w from an arbitrary side end of the convex portion to an opposing side end is 15 to 300 μm, and an arbitrary convex shape. The distance d from one point of the part to one point of the other convex part at the shortest distance is 50 to 1000 μm, and the point density of the convex part is 1 to 300 points / mm 2.
When the height h is lower than 10 μm, sufficient anti-slip properties cannot be exhibited, and when it is higher than 1000 μm, the anti-slip properties are too high and the haptic feeling becomes poor. In addition, the surface resistance is likely to be brittle.
The width w is a value corresponding to the diameter or approximate size of the convex portion, and if it is smaller than 15 μm or larger than 300 μm, sufficient anti-slip property cannot be exhibited. In addition, when the transfer method is used, the shape cannot be transferred well if it is too large.
The distance d is a value corresponding to the approximate distance between convex portions, and if it is shorter than 50 μm or longer than 1000 μm, sufficient anti-slip property cannot be exhibited. If the transfer method is used, the shape cannot be transferred well if it is too short.
The point density is a value indicating the density of the protrusions as it is, and if it is less than 1 point / mm 2 or more than 300 points / mm 2 , sufficient anti-slip properties cannot be expressed. In addition, when the transfer method is used, the shape cannot be transferred well if it is too much.

本発明により適宜設ける表面保護層3としては、前記凸部2を設けた化粧シート1の表面全面に設けて面の耐久性、耐傷付き性を向上させるために設ける。層厚としては前記凸部2の形状に影響しない範囲で設けられれば良く、具体的には1〜7μm程度であれば良い。材質としては表面の耐久性、耐傷付き性を向上するものであれば特に限定するものではないが、2液硬化型樹脂、熱効果型樹脂、電離放射線硬化型樹脂などを塗工後硬化させたものなどが好適である。   The surface protective layer 3 provided according to the present invention is provided in order to improve the durability and scratch resistance of the surface by providing it on the entire surface of the decorative sheet 1 provided with the convex portions 2. The layer thickness may be provided in a range that does not affect the shape of the convex portion 2, and specifically, about 1 to 7 μm. The material is not particularly limited as long as it improves the durability and scratch resistance of the surface. However, a two-component curable resin, a thermal effect resin, an ionizing radiation curable resin, etc. are cured after coating. A thing etc. are suitable.

化粧シート1として、厚さ70μmの顔料配合ランダムポリプロピレンシートにグラビア印刷によりウレタンインキにて木目印刷を施し、ホモポリプロピレン樹脂をこの印刷上にエクストルージョンラミネート法により押し出す。押し出すと同時に、セル形状が正方形であり、凹エンボス版を用いて表面に凸部2をもつエンボス加工を施した。施したシートの表面を観察したところ、表面の凸部2の点密度は11個/mm2であり、凸部2の平均高さは50μm、凸部2の形状は正方形でその一辺の最大長さは100μmであり、任意の凸部2の1点から最短距離にある他の凸部2の1点までの平均距離は200μmであった。   As the decorative sheet 1, a pigment-containing random polypropylene sheet having a thickness of 70 μm is subjected to wood grain printing with urethane ink by gravure printing, and a homopolypropylene resin is extruded onto the printing by an extrusion laminating method. Simultaneously with the extrusion, the cell shape was square, and embossing having a convex portion 2 on the surface was performed using a concave embossed plate. When the surface of the applied sheet was observed, the point density of the convex portions 2 on the surface was 11 pieces / mm 2, the average height of the convex portions 2 was 50 μm, the shape of the convex portions 2 was a square, and the maximum length of one side thereof Was 100 μm, and the average distance from one point of any convex part 2 to one point of the other convex part 2 at the shortest distance was 200 μm.

前記凸部2を設けた化粧シート1の表面に、表面保護層3としてウレタンアクリレート100部に対してペンタエリスリトールテトラアクリレート20部、ベンゾフェノン系光開始剤0.5部、ベンゾトリアゾール系紫外線吸収剤0.5部、ヒンダードアミン系光安定剤0.5部、粒径1μmの燐片状石英系フィラーを2重量部添加した紫外線硬化型樹脂を厚さ5μmになるように塗布した後、メタルハライドランプにて紫外線照射を行い硬化させた。以上により、防滑性化粧シートを得た。   On the surface of the decorative sheet 1 provided with the convex portion 2, as a surface protective layer 3, 20 parts of pentaerythritol tetraacrylate, 0.5 part of benzophenone photoinitiator, and 0 part of benzotriazole ultraviolet absorber 0 with respect to 100 parts of urethane acrylate. 5 parts, 0.5 part of hindered amine light stabilizer, 2 parts by weight of flake quartz filler with a particle size of 1 μm was applied to a thickness of 5 μm, and then applied with a metal halide lamp. It was cured by UV irradiation. Thus, an anti-slip decorative sheet was obtained.

<比較例1>
エンボスによって凸部形状を設けなかった以外は実施例1と同様の方法で化粧シートを得た。
<Comparative Example 1>
A decorative sheet was obtained in the same manner as in Example 1 except that the convex shape was not provided by embossing.

<比較例2>
エンボスによって設けた凸部形状の点密度が350個/mmとなるようにした以外は実施例と同様の方法で比較例2の化粧シートの作製を試みたが点密度が高すぎるために前述したような凸部形状の配列を作ることができず、所望の化粧シートを得ることはできなかった。
<Comparative example 2>
An attempt was made to produce a decorative sheet of Comparative Example 2 in the same manner as in Example except that the point density of the convex shape provided by embossing was 350 pieces / mm 2. As a result, it was impossible to make an array of convex shapes as described above, and a desired decorative sheet could not be obtained.

<比較例3>
エンボスによって設けた凸部形状の高さが5μmとなるようにした以外は実施例と同様の方法で比較例3の化粧シートを得た。
<Comparative Example 3>
A decorative sheet of Comparative Example 3 was obtained in the same manner as in Example except that the height of the convex shape provided by embossing was 5 μm.

<比較例4>
エンボスによって設けた凸部形状の高さが150μmとなるようにした以外は実施例と同様の方法で比較例4の化粧シートを得た。
<Comparative example 4>
A decorative sheet of Comparative Example 4 was obtained in the same manner as in Example except that the height of the convex shape provided by embossing was 150 μm.

<比較例5>
エンボスによって設けた凸部の任意の側端から対向する側端までの凸部の幅が10μmとなるようにした以外は実施例と同様の方法で比較例5の化粧シートを得た。
<Comparative Example 5>
A decorative sheet of Comparative Example 5 was obtained in the same manner as in Example except that the width of the convex portion from any side end of the convex portion provided by embossing to the opposite side end was 10 μm.

<比較例6>
エンボスによって設けた凸部の任意の側端から対向する側端までの凸部の幅が400μmとなるようにした以外は実施例と同様の方法で比較例6の化粧シートの作製を試みたが、エンボス版の凹部容積が大きすぎるためか形状の転写がうまく行われず、所望の化粧シートを得ることはできなかった。
<Comparative Example 6>
Although the production of the decorative sheet of Comparative Example 6 was attempted in the same manner as in Example, except that the width of the convex portion from any side end of the convex portion provided by embossing to the opposite side end was 400 μm. The shape of the embossed plate was too large to transfer the shape, and the desired decorative sheet could not be obtained.

<比較例7>
エンボスによって設けた任意の凸部の1点から最短距離にある他の凸部の1点までの距離が30μmとなるようにした以外は実施例と同様の方法で比較例7の化粧シートの作製を試みたが、凸部間隔が狭すぎるためか形状の転写がうまく行われず、所望の化粧シートを得ることはできなかった。
<Comparative Example 7>
Production of a decorative sheet of Comparative Example 7 in the same manner as in Example except that the distance from one point of any convex part provided by embossing to one point of the other convex part at the shortest distance is 30 μm However, the shape was not transferred well because the interval between the convex portions was too narrow, and the desired decorative sheet could not be obtained.

<比較例8>
エンボスによって設けた任意の凸部の1点から最短距離にある他の凸部の1点までの距離が1200μmとなるようにした以外は実施例と同様の方法で比較例8の化粧シートを得た。
<Comparative Example 8>
A decorative sheet of Comparative Example 8 was obtained in the same manner as in Example except that the distance from one point of any convex part provided by embossing to one point of the other convex part at the shortest distance was 1200 μm. It was.

<性能比較>
上記実施例および比較例1〜8により得られた化粧シートを、それぞれ床用基材として市販の厚さ12mmの合板に対して変性酢酸ビニル系接着剤(塗布量80g/m wet)を用いて張り合わせ、性能比較用の評価サンプルを得た。
<Performance comparison>
A decorative vinyl acetate adhesive (coating amount 80 g / m 2 wet) was applied to the commercially available plywood having a thickness of 12 mm for the decorative sheets obtained in the above Examples and Comparative Examples 1 to 8, respectively. And an evaluation sample for performance comparison was obtained.

それぞれの評価サンプルに対し、JIS―K―1454に規定された方法に準拠して、携帯型すべり試験機「ONO:PPMS」(東北測器(株)製)を用いて滑り性試験を行った。滑り片については発泡ウレタンゴムシート(ショアA硬度10 厚さ10mm)に対し木綿靴下をかぶせた物を使用した。また、前記滑り片と錘をあわせた重量は20kgとした。同じ試験片に対して三回試験を行った後、それらの値を平均したものをそのシートのC.S.R’値とした。評価結果を下記に示す。   Each evaluation sample was subjected to a slip property test using a portable slip tester “ONO: PPMS” (manufactured by Tohoku Sokki Co., Ltd.) in accordance with the method defined in JIS-K-1454. . As the sliding piece, a foamed urethane rubber sheet (Shore A hardness 10 thickness 10 mm) covered with cotton socks was used. The total weight of the sliding piece and the weight was 20 kg. After performing the test three times on the same test piece, the average of those values is the C.I. S. R 'value was used. The evaluation results are shown below.

上記の通り、実施例に示す化粧シートは床用防滑化粧シートとしての性能が認められたが比較例1〜8については防滑性化粧シートとしては適さないものであった。   As described above, the decorative sheets shown in the examples were recognized as having performance as anti-slip decorative sheets for floors, but Comparative Examples 1 to 8 were not suitable as anti-slip decorative sheets.

本発明の防滑性化粧シートは、特に屋内において床材用途として利用可能である。   The anti-slip decorative sheet of the present invention can be used particularly as a flooring material indoors.

1…化粧シート
2…凸部
3…表面保護層
DESCRIPTION OF SYMBOLS 1 ... Cosmetic sheet 2 ... Convex part 3 ... Surface protective layer

Claims (2)

表面に多数の凸部を形成してなる防滑性化粧シートにおいて、前記凸部の高さhが10〜100μmであり、凸部の任意の側端から対向する側端までの凸部の幅wが15〜300μmであり、任意の凸部の1点から最短距離にある他の凸部の1点までの距離dが50〜1000μmであり、凸部の点密度が1〜300点/mmであることを特徴とする防滑性化粧シート。 In the anti-slip decorative sheet formed on the surface with a large number of convex portions, the height h of the convex portions is 10 to 100 μm, and the width w of the convex portions from any side end of the convex portions to the opposite side ends Is 15 to 300 μm, the distance d from one point of any convex part to one point of the other convex part at the shortest distance is 50 to 1000 μm, and the point density of the convex part is 1 to 300 points / mm 2. An anti-slip decorative sheet characterized by being 前記防滑性化粧シートの表面に、熱硬化型樹脂または紫外線硬化型樹脂もしくはこれらの混合物からなる樹脂による表面保護層を設けたことを特徴とする、請求項1記載の防滑性化粧シート。   2. The anti-slip decorative sheet according to claim 1, wherein a surface protective layer made of a thermosetting resin, an ultraviolet curable resin or a mixture thereof is provided on the surface of the anti-slip decorative sheet.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016217033A (en) * 2015-05-22 2016-12-22 凸版印刷株式会社 Floor decorative sheet
JP2017053132A (en) * 2015-09-09 2017-03-16 凸版印刷株式会社 Decorative sheet for floor and decorative material for floor
JP2017145583A (en) * 2016-02-16 2017-08-24 凸版印刷株式会社 Decorative material for flooring

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011047221A (en) * 2009-08-28 2011-03-10 Toppan Cosmo Inc Decorative sheet for floor
JP2011093298A (en) * 2009-09-30 2011-05-12 Dainippon Printing Co Ltd Decorative sheet

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011047221A (en) * 2009-08-28 2011-03-10 Toppan Cosmo Inc Decorative sheet for floor
JP2011093298A (en) * 2009-09-30 2011-05-12 Dainippon Printing Co Ltd Decorative sheet

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016217033A (en) * 2015-05-22 2016-12-22 凸版印刷株式会社 Floor decorative sheet
JP2017053132A (en) * 2015-09-09 2017-03-16 凸版印刷株式会社 Decorative sheet for floor and decorative material for floor
JP2017145583A (en) * 2016-02-16 2017-08-24 凸版印刷株式会社 Decorative material for flooring

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