JP2013193199A - Atomized powder for projection material of shot peening, surface-modified member using the same, and method of shot peening - Google Patents
Atomized powder for projection material of shot peening, surface-modified member using the same, and method of shot peening Download PDFInfo
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Abstract
Description
本発明は、高硬度でショットピーニングした部材の表面に高い摺動性を付与できるショットピーニングの投射材用アトマイズ粉末とこれを用いて表面改質された部材およびショットピーニングによる表面改質方法に関する。 The present invention relates to an atomized powder for a shot peening projection material capable of imparting high slidability to the surface of a shot peened member with high hardness, a member surface-modified using the same, and a surface modification method using shot peening.
従来、ショットピーニングは被処理材に投射材（または、「ショット」、「ショット材」、「メディア」、「研磨材」などとも呼ばれる）と呼ばれる粒子を投射し、被処理材に圧縮残留応力を付与するとともに表面硬さを上昇させ、疲労強度を改善できる有効な表面処理方法であり、ばねやギヤ等の自動車部品、あるいは金型材などにも適用されている。浸炭焼入れ処理を行なったギヤなど、被処理材の高硬度化が進んでおり、これら部材への投射材にも高硬度化が求められている。 Conventionally, shot peening projects particles called projection material (or “shot”, “shot material”, “media”, “abrasive material”, etc.) onto the material to be processed, and compresses residual stress on the material to be processed. It is an effective surface treatment method that can increase the surface hardness and improve the fatigue strength, and is also applied to automobile parts such as springs and gears or mold materials. Hardness of materials to be treated such as gears that have undergone carburizing and quenching has been increasing, and high hardness is also required for the projection material to these members.
すなわち、表面硬度の高い被処理材に対し、低硬度な投射材を用いたショットピーニングでは高い圧縮残留応力が得られない。また、自動車部品等の更なる軽量化要求に伴い、ますます高硬度な被処理材をショットピーニングする必要があるため、さらに高硬度を有する投射材が求められている。 That is, high compressive residual stress cannot be obtained by shot peening using a low hardness projection material for a material to be processed having a high surface hardness. In addition, along with demands for further weight reduction of automobile parts and the like, it is necessary to shot peening a material having higher hardness, so that a projection material having higher hardness is required.
ショットピーニングにより高い圧縮残留応力が付与され、表面が高硬度化した被処理材は、特に曲げ疲労破壊に対し優れた寿命を示すが、近年ではさらに面疲労破壊に対する寿命向上も求められるようになってきている。面疲労に関しては、曲げ疲労破壊と同様に、圧縮残留応力の付与と表面の高硬度化が効果的であると考えられるが、一方でショットピーニングによる面粗度の上昇により、相手材との摩擦係数が上昇し、疲労面における作用応力が増大することで疲労寿命が劣化する場合もある。このように、面疲労特性の改善には、被処理材表面に高い圧縮残留応力と高硬度を与えるとともに、相手材との摩擦係数の上昇を抑制できる投射材の開発が求められている。 Highly compressive residual stress is imparted by shot peening and the surface of the material to be hardened has a particularly excellent life against bending fatigue failure, but in recent years, further improvement in the life against surface fatigue failure has been required. It is coming. As for surface fatigue, as with bending fatigue failure, it is considered effective to apply compressive residual stress and increase the hardness of the surface, but on the other hand, due to the increase in surface roughness due to shot peening, friction with the counterpart material In some cases, the fatigue life may be deteriorated by increasing the coefficient and increasing the working stress on the fatigue surface. As described above, to improve the surface fatigue characteristics, it is required to develop a projection material capable of giving a high compressive residual stress and high hardness to the surface of the material to be processed and suppressing an increase in the friction coefficient with the counterpart material.
これまでに高硬度な投射材として、本発明者は特開２００７−８４８５８号公報（特許文献１）において、Ｆｅ2Ｂ系硼化物とＢＣＣおよび／またはＦＣＣの鉄基固溶体よりなる投射材を提案してきた。この投射材は高硬度硼化物であるＦｅ2Ｂと高延性相であるＢＣＣおよび／またはＦＣＣの鉄基固溶体により、高硬度と高靭性を両立した投射材である。このような高硬度投射材をベースとし、面疲労を受ける相手材となる鋼材と固溶しにくく、凝着が抑制される低融点金属（Ｃｕ、Ａｇ、Ａｕ、Ｚｎ、Ｇａ、Ｉｎ、Ｓｎ、Ｐｂ、Ｓｂ、Ｂｉ）を添加することにより、被処理材表面に高い圧縮残留応力および高硬度と、摩擦係数を低くする表面改質を同時に与えられる投射材を見い出し、本発明に至った。 As a high-hardness projection material, the present inventor proposed in JP-A-2007-84858 (Patent Document 1) a projection material made of Fe 2 B boride and an iron-based solid solution of BCC and / or FCC. I have done it. This blasting material is a blasting material that achieves both high hardness and high toughness by Fe 2 B, which is a high-hardness boride, and an iron-based solid solution of BCC and / or FCC, which is a highly ductile phase. A low melting point metal (Cu, Ag, Au, Zn, Ga, In, Sn, which is based on such a high-hardness projection material, hardly dissolves in steel with a counterpart material subjected to surface fatigue, and suppresses adhesion. By adding Pb, Sb, Bi), a projection material capable of simultaneously imparting high compressive residual stress and high hardness to the surface of the material to be treated and surface modification that lowers the friction coefficient has been found, and the present invention has been achieved.
また、特開２０１１−２５３４８号公報（特許文献２）には、軟質金属をめっきなどの方法で被覆した投射材が提案されている。
上述したような特許文献１に開示されているＦｅ−Ｂ系高硬度投射材の場合は、Ｃｕ，Ｓｎなど低融点金属無添加のため、低摩擦係数が得られないという問題がある。また、特許文献２に開示されている投射材に軟質金属をめっき被覆した投射材は、ショットピーニングの使用中の破砕により生成した新生面に軟質金属が存在しないことから、使用とともに軟質金属の被処理材表面への移着が困難になってしまう。さらに、粉体へのめっきするコスト高が課題となる。 In the case of the Fe-B type high-hardness projection material disclosed in Patent Document 1 as described above, there is a problem that a low friction coefficient cannot be obtained because a low melting point metal such as Cu or Sn is not added. In addition, since the projection material disclosed in Patent Document 2 is coated with a soft metal by plating, the soft metal does not exist on the new surface generated by crushing during the use of shot peening. Transfer to the surface of the material becomes difficult. Furthermore, the high cost of plating on powder becomes a problem.
上述したような問題を解消するために発明者は鋭意開発を進めた結果、面疲労強度のアップには、残留応力、表面硬さ、低摩擦係数が必要であることから、Ｆｅ−Ｂ系硬質合金に低融点金属を添加し、アトマイズにより高硬度でショットピーニングした部材の表面に高い摺動性を付与できるショットピーニング用投射材とこれを用いて表面改質された部材およびショットピーニングによる表面改質方法を提供するものである。 As a result of diligent development by the inventors to solve the above-described problems, the residual stress, surface hardness, and low coefficient of friction are required to increase the surface fatigue strength. A shot peening projection material that can impart high slidability to the surface of a shot-peened member with high hardness by atomizing by adding a low-melting point metal to the alloy, a surface-modified member using this, and surface modification by shot peening It provides a quality method.
その本発明の第１の特徴は、低融点金属（Ｃｕ、Ａｇ、Ａｕ、Ｚｎ、Ｇａ、Ｉｎ、Ｓｎ、Ｐｂ、Ｓｂ、Ｂｉ）を含む投射材をショットピーニングに用いることにより、被処理材表面をこれら元素を含む表面に改質でき、この表面は相手材との摩擦時に低い摩擦係数を示すことを見い出したことである。 The first feature of the present invention is that the surface of the material to be treated is obtained by using a projection material containing a low melting point metal (Cu, Ag, Au, Zn, Ga, In, Sn, Pb, Sb, Bi) for shot peening. Has been found to have a low coefficient of friction when it is rubbed against the mating material.
さらに、本発明の第２の特徴は、この投射材を所定の硬さとすることにより、被処理材の表面近傍に高い圧縮残留応力を同時に付与でき面疲労寿命を改善できることである。また、一般にショットピーニングした被処理材表面は、ショットピーニング前より上昇することが知られている。これは、投射材の衝突により導入された格子欠陥により、被処理材の表面が加工硬化することと加工変態が誘起されるためであると考えられる。ここで、低融点金属（Ｃｕ、Ａｇ、Ａｕ、Ｚｎ、Ｇａ、Ｉｎ、Ｓｎ、Ｐｂ、Ｓｂ、Ｂｉ）を含み、所定の硬さを有する投射材をショットピーニングした場合、これら低融点金属を含まず同じ硬さを有する投射材を用いた場合と比較し、被処理材の表面硬さの上昇幅が大きくなることを明らかにした。 Further, the second feature of the present invention is that, by setting the projection material to a predetermined hardness, a high compressive residual stress can be simultaneously applied in the vicinity of the surface of the material to be processed, and the surface fatigue life can be improved. Further, it is generally known that the surface of a material to be treated that has undergone shot peening rises before the shot peening. This is considered to be because the surface of the material to be processed is work-hardened and the work transformation is induced by the lattice defects introduced by the collision of the projection material. Here, when a low-melting-point metal (Cu, Ag, Au, Zn, Ga, In, Sn, Pb, Sb, Bi) is shot-peened a projection material having a predetermined hardness, these low-melting-point metals are included. Compared with the case where the projection material having the same hardness is used, it has been clarified that the increase in the surface hardness of the material to be treated becomes larger.
この現象についての詳細は明らかでないが、以下のことが推定される。被処理材表面において、低融点金属が移着すると同時に、投射材の衝突により大きな加工が加えられるため、低融点金属元素が被処理材の合金に固溶したり、メカニカルアロイングのような機械的合金化が進み、被処理材の合金に対し、固溶限以上に低融点金属が過飽和固溶したり、あるいは、低融点金属と被処理材中の元素が新たな化合物を生成することに起因すると推定される。なお、これらの低融点金属はいずれもＦｅに対し包晶系もしくは偏晶系の状態図を持ち、硼化物の生成エネルギーが高く硼化物を生成しにくいことから、アトマイズで粉末を作製すると、Ｆｅに固溶あるいはＦｅと化合物を作るほか、添加量の一部は投射材の最終凝固部に概ね純粋な低融点金属相として残存する。このような純粋な低融点金属相は軟質であるため、ショットピーニングの際の被処理材との衝突時にその表面と合金化しやすいものと推察される。 The details of this phenomenon are not clear, but the following is presumed. At the same time, the low melting point metal is transferred to the surface of the material to be processed, and at the same time, a large amount of processing is applied due to the collision of the projection material, so that the low melting point metal element is dissolved in the alloy of the material to be processed or a machine such as mechanical alloying. As the alloying process progresses, the low melting point metal becomes supersaturated and exceeds the solubility limit of the alloy of the material to be treated, or the low melting point metal and the element in the material to be treated form a new compound. Presumed to be due. Note that these low melting point metals all have peritectic or orthorhombic phase diagrams with respect to Fe, and the formation energy of borides is high and it is difficult to form borides. In addition to forming a solid solution or Fe and a compound, a part of the added amount remains as a substantially pure low melting point metal phase in the final solidified portion of the projection material. Since such a pure low-melting-point metal phase is soft, it is presumed that it easily forms an alloy with the surface at the time of collision with the material to be treated during shot peening.
以上述べたように、本発明は高硬度でショットピーニングした部材の表面に高い摺動性を付与できるショットピーニング用投射材とこれを用いて表面改質された部材およびショットピーニングによる表面改質方法を提供するものである。 As described above, the present invention is a shot peening projection material capable of imparting high slidability to the surface of a shot peened member having high hardness, a member surface-modified using the same, and a surface modification method by shot peening. Is to provide.
以下、本発明について、成分組成および処理条件を限定した理由を述べる。
Ｂ：２〜８％
本発明の投射材において、Ｂは高い硬度を実現するための必須元素であり、２％未満では高い硬度が得られず、８％を超えると投射材が脆化する。好ましくは３〜７％、より好ましくは４〜６．５％である。ここで、脆い投射材をショットピーニングに用いると、繰り返し被処理材と衝突することにより、投射材が著しく破砕、消耗し、ランニングコスト高に繋がる。
Hereinafter, the reason why the component composition and processing conditions are limited will be described.
B: 2-8%
In the projection material of the present invention, B is an essential element for realizing high hardness. If less than 2%, high hardness cannot be obtained, and if it exceeds 8%, the projection material becomes brittle. Preferably it is 3 to 7%, more preferably 4 to 6.5%. Here, when a fragile projecting material is used for shot peening, the projecting material is crushed and consumed remarkably by repeatedly colliding with the material to be processed, leading to high running costs.
また、本発明の投射材はアトマイズ粉末を用いているため、低融点金属をめっきなどにより被覆した投射材と異なり、破砕で出来た新生面にも低融点金属が存在するため、使用中に破砕した場合でも、被処理材表面への低融点金属の移着および合金化が可能である。さらに、低融点金属からなる粉末と他の粉末を混合した投射材においては、異種の投射材の破砕の頻度が異なるため、使用している間に異種の投射材の比率が変化するため、安定したショットピーニングが不可能である。 In addition, since the projection material of the present invention uses atomized powder, unlike the projection material coated with a low melting point metal by plating or the like, since the low melting point metal exists also on the new surface made by crushing, it was crushed during use. Even in this case, it is possible to transfer and alloy the low melting point metal to the surface of the material to be treated. Furthermore, in the case of a projection material that is a mixture of a low-melting-point metal powder and other powders, the frequency of dissimilar projection materials is different, so the ratio of the different types of projection materials changes during use. Shot peening is impossible.
Ｃｕ、Ａｇ、Ａｕ、Ｚｎ、Ｇａ、Ｉｎ、Ｓｎ、Ｐｂ、Ｓｂ、Ｂｉの１種または２種以上を合計で０．１〜２０％
本発明の投射材において、Ｃｕ、Ａｇ、Ａｕ、Ｚｎ、Ｇａ、Ｉｎ、Ｓｎ、Ｐｂ、Ｓｂ、Ｂｉは、被処理材の表面の摩擦係数を低く抑えるとともに被処理材の表面硬度を大幅に上昇させるための必須元素であり、その１種または２種以上の合計が、０．１％未満ではこの効果が得られず、２０％を超えると投射材が脆化する。好ましくは５〜１７％、より好ましくは８〜１５％である。
0.1 to 20% in total of one or more of Cu, Ag, Au, Zn, Ga, In, Sn, Pb, Sb, Bi
In the projection material of the present invention, Cu, Ag, Au, Zn, Ga, In, Sn, Pb, Sb, and Bi keep the surface friction coefficient of the material to be treated low and greatly increase the surface hardness of the material to be treated. This effect cannot be obtained if the total of one or more of the elements is less than 0.1%, and the projection material becomes brittle if the total exceeds 20%. Preferably it is 5 to 17%, more preferably 8 to 15%.
Ｔｉ、Ｃｒ、Ｍｏ、Ｗ、Ｎｉ、Ａｌ、Ｃの１種または２種以上を、（Ｔｉ％／１０）＋（Ｃｒ％／２５）＋（Ｍｏ％／１０）＋（Ｗ％／６）＋（Ｎｉ％／１０）＋（Ａｌ％／１０）＋（Ｃ％／１） … （Ａ）が０を超え、１以下の範囲
本発明の投射材において、Ｔｉ、Ｍｏ、Ｗ、Ｃは硬度上昇に効果のある添加元素であり、Ｃｒ、Ｎｉ、Ａｌは耐食性を改善する効果のある添加元素であり、いずれの元素も必要に応じて添加することができる。しかしながら、（Ｔｉ％／１０）＋（Ｃｒ％／２５）＋（Ｍｏ％／１０）＋（Ｗ％／６）＋（Ｎｉ％／１０）＋（Ａｌ％／１０）＋（Ｃ％／１）…（Ａ）が１を超える範囲で添加してしまうと、投射材が著しく脆化する。なお、これらの添加元素は硬度上昇や耐食性改善の効果があるが、いずれも過添加すると投射材が脆化する。著しく脆化する添加量の限度は元素の種類によって異なり、Ｔｉが１０％、Ｃｒが２５％、Ｍｏが１０％、Ｗが６％、Ｎｉが１０％、Ａｌが１０％、Ｃが１％である。したがって、複合添加する場合は、各元素の添加量をその限度の濃度で規格化し、合計した値が１を超えない範囲で添加できる。
One or two or more of Ti, Cr, Mo, W, Ni, Al, and C are added to (Ti% / 10) + (Cr% / 25) + (Mo% / 10) + (W% / 6) + (Ni% / 10) + (Al% / 10) + (C% / 1) (A) is more than 0 and less than or equal to 1 In the projection material of the present invention, Ti, Mo, W, and C are increased in hardness. And Cr, Ni, and Al are additive elements that have the effect of improving corrosion resistance, and any of these elements can be added as necessary. However, (Ti% / 10) + (Cr% / 25) + (Mo% / 10) + (W% / 6) + (Ni% / 10) + (Al% / 10) + (C% / 1) ... If (A) is added in a range exceeding 1, the projection material becomes extremely brittle. These additive elements have the effect of increasing the hardness and improving the corrosion resistance, but if any of them is added excessively, the projection material becomes brittle. The limit of the amount to be significantly embrittled depends on the type of element: Ti is 10%, Cr is 25%, Mo is 10%, W is 6%, Ni is 10%, Al is 10%, and C is 1%. is there. Therefore, in the case of complex addition, the addition amount of each element can be normalized at the limit concentration, and the total value can be added within a range not exceeding 1.
表面近傍の最大圧縮残留応力が７００ＭＰａ以上で、表面にＣｕ、Ａｇ、Ａｕ、Ｚｎ、Ｇａ、Ｉｎ、Ｓｎ、Ｐｂ、Ｓｂ、Ｂｉの１種または２種以上の元素の合計が１％以上、１００％以下
本発明の鋼製部品の表面において、最大圧縮残留応力および検出される低融点金属（Ｃｕ、Ａｇ、Ａｕ、Ｚｎ、Ｇａ、Ｉｎ、Ｓｎ、Ｐｂ、Ｓｂ、Ｂｉ）は、いずれも面疲労寿命を向上させる因子である。最大圧縮残留応力が７００ＭＰａ未満または／および低融点金属が１％未満では、面疲労寿命の改善が十分ではない。最大圧縮残留応力の好ましい範囲は１０００以上、より好ましくは１５００ＭＰａ以上である。
The maximum compressive residual stress in the vicinity of the surface is 700 MPa or more, and the total of one or more elements of Cu, Ag, Au, Zn, Ga, In, Sn, Pb, Sb, Bi on the surface is 1% or more, 100 % On the surface of steel parts of the present invention, the maximum compressive residual stress and the low melting point metals (Cu, Ag, Au, Zn, Ga, In, Sn, Pb, Sb, Bi) detected are all surface fatigue. It is a factor that improves the service life. When the maximum compressive residual stress is less than 700 MPa or / and the low melting point metal is less than 1%, the surface fatigue life is not sufficiently improved. A preferable range of the maximum compressive residual stress is 1000 or more, more preferably 1500 MPa or more.
なお、上限については特に制限はないが、通常、２５００ＭＰａ以上の圧縮残留応力を付与することは困難である。被処理材表面における低融点金属の好ましい範囲は１０％以上、より好ましくは２０％以上である。また、ショットピーニングにより付与される圧縮残留応力分布において最大値が得られる部位は投射条件によるが、ショットピーニングした表面から概ね３００μｍの深さまでであり、本発明における表面近傍とは最表面から３００μｍ深さのことである。 In addition, although there is no restriction | limiting in particular about an upper limit, Usually, it is difficult to provide the compressive residual stress of 2500 Mpa or more. The preferable range of the low melting point metal on the surface of the material to be processed is 10% or more, more preferably 20% or more. In addition, the portion where the maximum value is obtained in the distribution of compressive residual stress applied by shot peening depends on the projection conditions, but is approximately 300 μm deep from the surface subjected to shot peening, and the vicinity of the surface in the present invention is 300 μm deep from the outermost surface. That's it.
投射速度５０〜２００ｍ／ｓ
投射速度については、一般に用いられているショットピーニング装置の範囲でよく、５０〜２００ｍ／ｓでよい。
Projection speed 50-200m / s
About a projection speed, the range of the shot peening apparatus generally used may be sufficient, and 50-200 m / s may be sufficient.
以下、本発明について実施例によって具体的に説明する。
投射材の製造方法としたは、表１の組成に秤量した原料を耐火物製坩堝でアルゴン雰囲気中にて誘導溶解し、坩堝底部の出湯ノズルより出湯し、アルゴンガスを噴霧し、ガスアトマイズ法により投射材を製造した。得られた投射材を４５〜１２５μｍに分級し、評価に用いた。
Hereinafter, the present invention will be specifically described with reference to examples.
The production method of the projection material is as follows. The raw materials weighed to the composition shown in Table 1 are induction-dissolved in an argon atmosphere with a refractory crucible, discharged from a hot water nozzle at the bottom of the crucible, sprayed with argon gas, and gas atomized. A projectile was produced. The obtained projection material was classified into 45-125 micrometers, and was used for evaluation.
また、投射材の硬さ、脆さとしては、投射材を樹脂埋め、研磨した試料を用い、ビッカース硬さ計により荷重３００ｇで硬さを測定した。脆さは、前述の樹脂埋め試料を用い、ビッカース硬さ計にて３００ｇの荷重で５点圧痕を打ち、５点中１点もクラックを発生しなかった場合は○、１点でもクラックが発生した場合は脆いと判断し×とした。
また、投射材の耐食性としては、ガラス板に貼った両面テープ上に投射材を敷詰め、これを温度７０℃、湿度９５％の条件で９６時間保持し、全面に発銹したものを△、一部の発銹に留まったものを○とした。
Further, as the hardness and brittleness of the projection material, the hardness was measured with a load of 300 g with a Vickers hardness tester using a sample in which the projection material was filled with resin and polished. For brittleness, if the above-mentioned resin-embedded sample was used, a 5-point indentation was made with a load of 300 g with a Vickers hardness tester, and no crack occurred at any one of the 5 points. In such a case, it was determined that the material was brittle and was marked as x.
Moreover, as the corrosion resistance of the projection material, the projection material is laid on a double-sided tape affixed to a glass plate, and this is held for 96 hours under conditions of a temperature of 70 ° C. and a humidity of 95%. The ones that remained in a part of the discovery were marked with ○.
また、ローラーピッチング試験片の製造方法およびショットピーニング表面と面疲労特性の評価としては、市販のＳＣＭ４２０を用い、９３０℃で浸炭、８４０℃からの焼入および１４０℃で焼戻処理を行った。試験片の形状はコマツエンジニアリング製ローラーピッチング試験機（型式ＲＰＴ−２０２０）のシャフト試験片で、直径２４ｍｍ、長さ１３０ｍｍのシャフトに試験部である直径２６ｍｍ、幅２８ｍｍの段差が付いたものである。この試験部にショットピーニングを行った。ショットピーニングには直圧式エアタイプの投射装置を用い、投射圧０．２〜０．３ＭＰａ、投射時間１ｍｉｎで実施した。なお、試験片は１０ｒｐｍで回転させ、試験部にムラなく投射するようにした。この試験片を用い、投射表面の残留応力、硬さ、成分分析および面疲労特性を評価した。 Moreover, as a manufacturing method of a roller pitching test piece and evaluation of shot peening surface and surface fatigue characteristics, a commercially available SCM420 was used, carburizing at 930 ° C., quenching from 840 ° C., and tempering treatment at 140 ° C. The shape of the test piece is a shaft test piece of a roller pitching tester (model RPT-2020) manufactured by Komatsu Engineering Co., Ltd., which is a shaft having a diameter of 24 mm and a length of 130 mm with a step of 26 mm in diameter and 28 mm in width as a test part. . Shot peening was performed on this test section. For shot peening, a direct pressure air type projection device was used, and the projection pressure was 0.2 to 0.3 MPa and the projection time was 1 min. The test piece was rotated at 10 rpm and projected onto the test part without unevenness. Using this test piece, the residual stress, hardness, component analysis, and surface fatigue characteristics of the projection surface were evaluated.
試験片表面の残留応力はＸ線回折法により評価した。最表面から１０μｍずつ電解研磨でエッチングし、１００μｍ深さまで１０μｍごとに測定し、その最大値を最大圧縮残留応力とした。なお、残留応力値の正負について、例えば「−１０００ＭＰａの残留応力」を「１０００ＭＰａの圧縮残留応力」と記している。試験片表面の硬さはビッカース硬さ計にて、荷重１００ｇで試験片表面に垂直に圧痕を打ち測定した。 The residual stress on the surface of the test piece was evaluated by the X-ray diffraction method. Etching was carried out by electrolytic polishing 10 μm from the outermost surface and measured every 10 μm up to a depth of 100 μm, and the maximum value was taken as the maximum compressive residual stress. For example, “−1000 MPa residual stress” is described as “1000 MPa compressive residual stress” for positive and negative of the residual stress value. The hardness of the surface of the test piece was measured with a Vickers hardness tester with an indentation perpendicular to the surface of the test piece at a load of 100 g.
試験片表面の成分分析は、ＥＤＸにより行った。試験片表面において１００×１００μｍの範囲を分析した。面疲労特性はローラーピッチング試験により評価した。用いた装置は上述の通りで、相手ローラーにも市販のＳＣＭ４２０を上述と同条件で熱処理したものを用い、直径１３０ｍｍ、厚さ１８ｍｍ、試験部の曲率半径はＲ１５０である。試験面圧は３．３ＧＰａ、すべり率は−４０％、回転数は２０００ｒｐｍ、潤滑油はベスコトランスアクスル５Ｗ−３０、油温度は８０℃、油流量は３０００ｃｃ／ｍｉｎの条件で実施した。なお、試験時にはトルクを測定し、摩擦係数の評価とした。なお、ショットピーニングする前の試験片の最大圧縮残留応力は２００ＭＰａ、表面硬さは６５０ＨＶであった。 The component analysis of the test piece surface was performed by EDX. A range of 100 × 100 μm was analyzed on the surface of the test piece. The surface fatigue characteristics were evaluated by a roller pitching test. The apparatus used was the same as described above, and a commercially available SCM420 heat treated under the same conditions as described above was used as the counter roller. The diameter was 130 mm, the thickness was 18 mm, and the radius of curvature of the test part was R150. The test surface pressure was 3.3 GPa, the slip rate was −40%, the rotation speed was 2000 rpm, the lubricating oil was Besco Transaxle 5W-30, the oil temperature was 80 ° C., and the oil flow rate was 3000 cc / min. During the test, torque was measured to evaluate the friction coefficient. The test piece before shot peening had a maximum compressive residual stress of 200 MPa and a surface hardness of 650 HV.
表１に示すように、Ｎｏ．１〜１６の投射材は本発明の投射材であり、低融点金属を合計で０．１〜２０％含むとともに、硬さ、脆さに優れる。さらにＣｒ、Ｎｉ、Ａｌが添加されたＮｏ．１３〜１５は耐食性にも優れる。また、Ｔｉ、Ｍｏ、Ｗ、Ｃが添加されたＮｏ．１２、１４、１６は、これら元素が添加されていないＮｏ．１、３、２と比較し、それぞれ硬さが高い。 As shown in Table 1, no. Projection materials 1 to 16 are the projection materials of the present invention, and contain 0.1 to 20% of low melting point metals in total, and are excellent in hardness and brittleness. Further, No. 1 to which Cr, Ni and Al were added. 13-15 are excellent also in corrosion resistance. Further, No. to which Ti, Mo, W, and C were added was added. Nos. 12, 14, and 16 are No. to which these elements are not added. Compared with 1, 3, and 2, the hardness is high.
Ｎｏ．１〜１６の投射材を用い、ショットピーニングしたＮｏ．２７〜４２の試験片は、いずれも高い圧縮残留応力を有し、表面からは１％以上の低融点金属が検出され、ローラーピッチング試験におけるトルクが小さい。また、同等の硬さを有しているＮｏ．１と１７、Ｎｏ．２と１８、Ｎｏ．３と１９、Ｎｏ．４と２０の投射材をショットピーニングしたＮｏ．２７と４３、Ｎｏ．２８と４４、Ｎｏ．２９と４５、Ｎｏ．３０と４６の表面硬さを比較すると、低融点金属を１０％含む投射材を用いたＮｏ．２７〜３０のほうが、低融点金属を無添加もしくは０．１％未満の添加としたＮｏ．４３〜４６より著しく高い。これらの結果として、本発明例であるＮｏ２７〜４２はローラーピッチング寿命に優れている。 No. No. 1-16 shot peened using No. The test pieces 27 to 42 all have a high compressive residual stress, 1% or more of a low melting point metal is detected from the surface, and the torque in the roller pitching test is small. Moreover, No. which has equivalent hardness. 1 and 17, no. 2 and 18, no. 3 and 19, no. No. 4 and 20 shot peened No. 27 and 43, no. 28 and 44, no. 29 and 45, no. Comparing the surface hardness of 30 and 46, No. 30 using a projection material containing 10% of low melting point metal. Nos. 27 to 30 were No. with no low melting point metal added or less than 0.1% added. Significantly higher than 43-46. As a result of these, Nos. 27 to 42, which are examples of the present invention, are excellent in roller pitting life.
一方、Ｎｏ．１７〜２０の投射材は低融点金属の添加量が少ないため、これをショットピーニングしたＮｏ．４３〜４６の試験片は表面の低融点金属検出量が少なく、ローラーピッチング試験時のトルクが大きいため、ピッチング寿命に劣る。これは、ローラーピッチング試験における摩擦係数が大きく、ピッチング破壊を起こす作用応力が大きいためであると考えられる。Ｎｏ．２１の投射材はＢ量が少ないため投射材硬さが低く、これをショットピーニングしたＮｏ．４７の試験片は最大圧縮残留応力が低く、表面の低融点金属検出量も少なく、ローラーピッチング試験時のトルクが大きいため、ピッチング寿命に劣る。 On the other hand, no. Nos. 17 to 20 were shot peened because the amount of low melting point metal added was small. The test pieces 43 to 46 are inferior in the pitching life because the detected amount of the low melting point metal on the surface is small and the torque during the roller pitching test is large. This is presumably because the friction coefficient in the roller pitching test is large and the acting stress causing the pitching failure is large. No. Since the projection material of No. 21 has a small amount of B, the projection material hardness is low. The test piece 47 has a low maximum compressive residual stress, a small amount of low melting point metal detected on the surface, and a large torque during the roller pitching test, so that the pitching life is inferior.
Ｎｏ．２２〜２５の投射材は、Ｂ量もしくは式（Ａ）の値もしくは低融点金属の合計量が大きいため、これらを投射したＮｏ．４８〜５１の試験片は優れたピッチング寿命を示すものの、投射材が脆く、消耗が激しいため、投射材コスト高となってしまう。Ｎｏ．２６の投射材はＢ量が少ないため投射材の硬さが低く、これらをショットピーニングしたＮｏ．５２の試験片は、最大圧縮残留応力が低いため、ピッチング寿命に劣る。 No. Since the projection materials of Nos. 22 to 25 have a large amount of B, the value of the formula (A), or the total amount of low melting point metals, No. Although the test pieces of 48 to 51 show an excellent pitching life, the projection material is fragile and exhausted so that the cost of the projection material becomes high. No. No. 26, which has a small amount of B, is low in the hardness of the projection material. The 52 test piece has a low maximum compressive residual stress and therefore has a poor pitching life.
以上のように、Ｆｅ−Ｂ系硬質合金に低融点金属（Ｃｕ、Ａｇ、Ａｕ、Ｚｎ、Ｇａ、Ｉｎ、Ｓｎ、Ｐｂ、Ｓｂ、Ｂｉ）を添加し、アトマイズにより得た投射材をショットピーニングに用いることにより、被処理材表面をこれら元素を含む表面に改質でき、この表面は相手材との摩擦時に低い摩擦係数を示す極めて優れた効果を奏するものである。
特許出願人 山陽特殊製鋼株式会社
代理人 弁理士 椎 名 彊
As described above, low melting point metals (Cu, Ag, Au, Zn, Ga, In, Sn, Pb, Sb, Bi) are added to the Fe-B hard alloy, and the projection material obtained by atomization is used for shot peening. By using it, the surface of the material to be treated can be modified to a surface containing these elements, and this surface exhibits an extremely excellent effect of exhibiting a low coefficient of friction during friction with the counterpart material.
Patent Applicant Sanyo Special Steel Co., Ltd.
Attorney: Attorney Shiina
Claims (4)
（Ｔｉ％／１０）＋（Ｃｒ％／２５）＋（Ｍｏ％／１０）＋（Ｗ％／６）＋（Ｎｉ％／１０）＋（Ａｌ％／１０）＋（Ｃ％／１） … （Ａ）が０を超え、１以下の範囲で含むことを特徴とした請求項１に記載のショットピーニングの投射材用アトマイズ粉末。 One or more of Ti, Cr, Mo, W, Ni, Al, and C
(Ti% / 10) + (Cr% / 25) + (Mo% / 10) + (W% / 6) + (Ni% / 10) + (Al% / 10) + (C% / 1) The atomized powder for a shot peening projection material according to claim 1, wherein A) is contained in a range of more than 0 and 1 or less.
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| JPH111706A (en) * | 1997-06-11 | 1999-01-06 | Akihisa Inoue | Impact resistant ferrous alloy spherical grain |
| JP2002004015A (en) * | 2000-06-21 | 2002-01-09 | Akihisa Inoue | Iron-based amorphous spherical grain |
| JP2002080949A (en) * | 2000-09-07 | 2002-03-22 | Akihisa Inoue | Amorphous iron-group alloy |
| JP2011025348A (en) * | 2009-07-24 | 2011-02-10 | Sanyo Special Steel Co Ltd | Shot peening powder coated with soft metal |
| JP2011063837A (en) * | 2009-09-16 | 2011-03-31 | Sanyo Special Steel Co Ltd | Soft-metal-mixed powder for shot peening |
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|---|---|---|---|---|
| JPH111706A (en) * | 1997-06-11 | 1999-01-06 | Akihisa Inoue | Impact resistant ferrous alloy spherical grain |
| JP2002004015A (en) * | 2000-06-21 | 2002-01-09 | Akihisa Inoue | Iron-based amorphous spherical grain |
| JP2002080949A (en) * | 2000-09-07 | 2002-03-22 | Akihisa Inoue | Amorphous iron-group alloy |
| JP2011025348A (en) * | 2009-07-24 | 2011-02-10 | Sanyo Special Steel Co Ltd | Shot peening powder coated with soft metal |
| JP2011063837A (en) * | 2009-09-16 | 2011-03-31 | Sanyo Special Steel Co Ltd | Soft-metal-mixed powder for shot peening |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2016216802A (en) * | 2015-05-26 | 2016-12-22 | 山陽特殊製鋼株式会社 | Hard powder high in productivity and corrosion resistance with inexpensive price and projection material for shot-peening and iron-based abrasion resistant sintered alloy having hard particle dispersed |
| US10265767B2 (en) | 2015-05-26 | 2019-04-23 | Sanyo Special Steel Co., Ltd. | Alloy powder, and shot material for shot peening, powder metallurgical composition and iron-based sintered alloy using the same |
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