JP2013087105A - Bubble-generating bath agent - Google Patents

Bubble-generating bath agent Download PDF

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JP2013087105A
JP2013087105A JP2011231292A JP2011231292A JP2013087105A JP 2013087105 A JP2013087105 A JP 2013087105A JP 2011231292 A JP2011231292 A JP 2011231292A JP 2011231292 A JP2011231292 A JP 2011231292A JP 2013087105 A JP2013087105 A JP 2013087105A
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bath
bubbles
foam
bath agent
generating
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JP2013087105A5 (en
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Akira Fujii
侃 藤井
Yukinori Saeki
行紀 佐伯
Kunihiro Mizoguchi
訓弘 溝口
Kazumi Hayashi
和美 林
Yukako Fujikawa
友佳子 藤川
Kazuhiko Ishimoto
一彦 石本
Masako Kawabata
政子 川端
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Sankyo Manufacturing Co Ltd
Goshu Yakuhin Co Ltd
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Sankyo Manufacturing Co Ltd
Goshu Yakuhin Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a solid bath agent improved in a massage effect or the like by virtue of generating two kinds of bubbles with noticing the difference between air bubbles of carbon dioxide and bubbles of soaps.SOLUTION: This solid bath agent is such solid matter 5 that is formed by pressing a mixed powder 10 of the bath main component 2, a bath auxiliary component 3 and a surfactant 4, solidified at ordinary temperature, the solid matter being one of a columnar body 51, a polyhedral body 52, a globular body 53 and a character body 54, and this solid matter is characterized by enabling to be pulverized at a certain level of impact shock or higher and dissolving in a liquid of from cold water to warm water to generate the two kinds of bubbles of the air bubbles B of carbon dioxide and the soapy bubbles S, and by having a wall thickness t of the solid matter from 1 to 10 cm, and a recessed part 6 ingrowing into the inside from the surface 5a, with the recessed part increasing the surface area and uniformizng the whole density, and by having on the surface side thereof a decoration 7 visible from the outside.

Description

本発明は新規な泡発生浴用剤とその製造方法に関するものであり、特に、二種類の泡によってマッサージ効果と保温効果等を改善した泡発生浴用剤(バブルバス)とその製造方法に関する。   The present invention relates to a novel foam-generating bath agent and a method for producing the same, and more particularly to a foam-generating bath agent (bubble bath) in which a massage effect and a heat retaining effect are improved by two kinds of foams and a method for producing the same.

周知の入浴剤として、身体の洗浄、保湿、保温等の入浴効果を高めるために各種の成分を配合した浴用剤が数多く市販されている。代表的なものとしては、炭酸水素ナトリウム、無水硫酸ナトリウム、硼砂等の浴用成分に、色素、香料、安定剤、殺菌剤等を加えたものが一般に知られている。
また、泡によるマッサージ効果を得るために、発泡効果を増進させる成分として上記浴用原料にポリエチレングリコールを配合した発泡性浴用剤も使用されている。
As a well-known bath agent, many bath agents containing various components are commercially available in order to enhance bathing effects such as body washing, moisture retention, and heat retention. As a typical one, a bath component such as sodium hydrogen carbonate, anhydrous sodium sulfate, borax, etc., which is added with a dye, a fragrance, a stabilizer, a disinfectant, etc. is generally known.
Moreover, in order to obtain the massage effect by a foam, the foaming bath agent which mix | blended polyethylene glycol with the said raw material for baths as a component which improves a foaming effect is also used.

従来の発泡性浴用剤は、炭酸塩/重炭酸塩及び酸、好ましくはクエン酸- 又は酒石酸、結合剤(セルロース誘導体、でんぷん)、砕解- 及び滑沢剤(タルク、マクロゴル(ポリエチレングリコール))並びにエーテル性油- 添加物、香料、染料及び界面活性剤等から構成され、浴液中で炭酸ガスを放出するものである。
この炭酸ガスは、皮膚血管を拡張し、血液循環(血行)を促進し、保温効果を高めると共に、マッサージ効果があるとされている。
Conventional foaming bath agents include carbonate / bicarbonate and acids, preferably citric acid or tartaric acid, binders (cellulose derivatives, starch), disintegration and lubricants (talc, macrogol (polyethylene glycol)). In addition, it is composed of an etheric oil-additive, a fragrance, a dye, a surfactant, and the like, and releases carbon dioxide gas in the bath liquid.
This carbon dioxide gas is said to dilate skin blood vessels, promote blood circulation (blood circulation), enhance the heat retention effect, and have a massage effect.

従来の粉体固形物の内、口腔から体内に飲み込む錠剤やタブレット型サプリメントにあっては、打錠機、圧縮ロール、ブリケティングロール等を用いて個体化されていた。これらの打錠機による薬剤等の大きさは、直径8mm前後、錠厚さ4.0mm前後、打錠圧は最大3トンであり、通常1,000〜3,000Kg/cmであった。
発泡性浴用剤にあっては、口腔から体内に飲み込む必要がないので、直径40mm前後、錠厚さ20mm前後に打錠されている。
Among conventional powder solids, tablets and tablet supplements swallowed from the oral cavity into the body have been individualized using a tableting machine, a compression roll, a briquetting roll, and the like. The size of the drug or the like by these tableting machine, the front-rear diameter 8 mm, longitudinal JoAtsu of 4.0 mm, tableting pressure is up to 3 tons, a normal 1,000~3,000Kg / cm 2.
Since it is not necessary to swallow the foaming bath agent into the body from the oral cavity, the tablet is compressed to a diameter of about 40 mm and a tablet thickness of about 20 mm.

特開昭58−105910号公報、JP-A-58-105910, 特公昭63−28409号公報Japanese Patent Publication No. 63-28409 特許第2609816号Patent No. 2609816 特許第3900245号Japanese Patent No. 3900245 特許第4181238号Japanese Patent No. 4181238

現在知られている発泡性浴用剤の多くは、浴湯に入れると炭酸ガスの気泡を発生するものであるから、入浴の最初の時点では十分な気泡を形成するが、入浴が終了するまで十分な量の気泡を維持することができず、気泡発生の低下は急激で、気泡の発生は早々と終了してしまう問題点があった。即ち、気泡の破裂によるマッサージ効果等が不充分となり、且つ、炭酸ガスによる保湿性の向上が不充分になるなどの問題点があった。
成形型を用いて打錠する浴用剤は、成形型に面する表面側で最も硬く、内部に至るに従って硬度が低下し、中心部で最も柔らかくなるため、これを浴湯に投入した場合、溶け具合が硬度の低下に伴い早まり、均等な溶解が望めなかった。また、発泡性浴用剤は打錠された状態で販売されているのみであるから、美観に乏しかった。
そこでこの発明は、従来技術の有するこのような問題点に鑑みてなされたものであり、その目的とは、製造工程や流通過程で崩れない程度の硬度を有し、浴湯に投入した際には均等に崩壊し、且つ炭酸ガスの気泡と共に石鹸性泡を発生することで、独特の効果を発揮する泡発生浴用剤を提供することにある。
Many of the currently known foaming bath agents generate carbon dioxide bubbles when placed in bath water, so that sufficient bubbles are formed at the beginning of bathing, but sufficient until bathing is completed. There was a problem that a sufficient amount of bubbles could not be maintained, the bubble generation decreased rapidly, and the bubble generation ended prematurely. That is, there are problems such as insufficient massage effect due to bursting of bubbles, and insufficient improvement of moisture retention by carbon dioxide gas.
The bath preparation tableted with a mold is hardest on the surface facing the mold, decreases in hardness as it reaches the inside, and softens most in the center. The condition was accelerated as the hardness decreased, and uniform dissolution could not be expected. Moreover, since the foaming bath agent is only sold in a tableted state, it has poor aesthetics.
Therefore, the present invention has been made in view of such problems of the prior art, and its purpose is to have a hardness that does not collapse in the manufacturing process and distribution process, and when it is put into bath water. Is to provide a foam-generating bath agent that exhibits a unique effect by evenly disintegrating and generating soapy foam together with carbon dioxide gas bubbles.

上記目的を達成するために本発明の泡発生浴用剤は、請求項1として、浴用主成分と浴用補助成分と界面活性剤との混合粉体を加圧し、常温で固化している立体物であり、立体物は一定以上の衝撃で粉砕が可能であると共に、水からお湯までの液体により溶けて炭酸ガスの気泡と石鹸性泡の二様の泡を発生することを特徴とする。
請求項2は、請求項1記載の泡発生浴用剤において、浴用主成分は少なくとも基材と有機酸と炭酸塩からなり、浴湯にて溶けて炭酸ガスの気泡を発生することを特徴とする。
請求項3は、請求項1または2項記載の泡発生浴用剤において、界面活性剤としてラウリル硫酸ナトリウムとラウリルエーテル硫酸ナトリウムとポリエチレングリコールの少なくとも一方を全重量に対して0.5〜50重量%含有しており、この界面活性剤によって石鹸性泡を発生することを特徴とする。
In order to achieve the above object, the foam generating bath agent according to the present invention is a three-dimensional product as claimed in claim 1, wherein a mixed powder of a bath main component, a bath auxiliary component and a surfactant is pressurized and solidified at room temperature. The three-dimensional object is characterized by being capable of being pulverized by an impact of a certain level or more and being melted by a liquid from water to hot water to generate two bubbles such as bubbles of carbon dioxide gas and soapy bubbles.
A second aspect of the present invention is the foam generating bath agent according to the first aspect, wherein the main components for the bath are composed of at least a base material, an organic acid and a carbonate, and are dissolved in bath water to generate bubbles of carbon dioxide gas. .
[Claim 3] The foaming bath agent according to claim 1 or 2, wherein at least one of sodium lauryl sulfate, sodium lauryl ether sulfate and polyethylene glycol is used as a surfactant in an amount of 0.5 to 50% by weight based on the total weight. It contains, and it is characterized by generating soapy foam by this surfactant.

ここで泡発生浴用剤とは、常温で固体形状を成し、浴湯中で溶けて炭酸ガスの気泡と、概気泡より小泡のクリーミーな石鹸性泡を発生させ、石鹸性泡で湯面を覆うことで、炭酸ガスによる効果を向上し得るものである。
ここで炭酸ガスの気泡とは、主に浴用主成分が溶けて発生する炭酸ガスから成る泡を言い、石鹸性泡とは、主に界面活性剤が溶けて発生する泡を言う。
ここで浴用主成分の有機酸とは、炭酸塩と反応して炭酸ガスを発生させるために配合されるものであり、具体的には、クエン酸、コハク酸、フマール酸、リンゴ酸、酒石酸等が挙げられ、炭酸塩とは、入浴剤の十分な錠剤硬度を得るための成分であり、具体的には炭酸カリウム、炭酸カルシウム、炭酸マグネシウム、炭酸ナトリウム、炭酸マグネシウム、セスキ炭酸ナトリウム等が挙げられる。
ここで混合粉体とは、常温で粉状を成すものであり、本発明では浴用主成分と界面活性剤、及び浴用補助成分の一部を言い、一定以上の衝撃で粉砕とは、通常の製造工程及び流通過程で摩損することがなく、また、欠けたり割れたりしないものを言う。
ここで浴用補助成分とは、乳白剤、増粘剤、保湿剤、吸湿剤、保存料、pH調整剤、金属イオン封鎖剤、着色料、香料および香料希釈剤等を言う。
ここで界面活性剤とし、ラウリル硫酸ナトリウムとラウリルエーテル硫酸ナトリウムとポリエチレングリコール以外に、例えばポリオキシエチレンアルキルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、グリセリン脂肪酸エステル、高級脂肪酸アルカノールアミド等を、単独でも2種以上を混合して用いてもよい。
ここで全重量とは、本発明による泡発生浴用剤の重さを言い、採用し得る重さとして20〜300g、望ましくは50〜200gである。
Here, the foaming bath agent forms a solid form at room temperature, melts in the bath water to generate carbon dioxide bubbles and creamy soapy bubbles that are smaller than the approximate bubbles, By covering the surface, the effect of carbon dioxide can be improved.
Here, the bubble of carbon dioxide gas means a bubble made of carbon dioxide gas generated mainly by melting the main component for bath, and the soapy bubble means a bubble generated mainly by melting of the surfactant.
Here, the organic acid as the main component for bath is one that is blended in order to generate carbon dioxide gas by reacting with carbonate, specifically citric acid, succinic acid, fumaric acid, malic acid, tartaric acid, etc. The carbonate is a component for obtaining sufficient tablet hardness of the bath agent, and specifically includes potassium carbonate, calcium carbonate, magnesium carbonate, sodium carbonate, magnesium carbonate, sodium sesquicarbonate, etc. .
Here, the mixed powder is in a powder form at room temperature, and in the present invention, refers to a main component for bath, a surfactant, and a part of an auxiliary component for bath. It means that it is not worn out during the manufacturing process and distribution process, and does not chip or crack.
Here, the auxiliary bath ingredients refer to opacifiers, thickeners, humectants, hygroscopic agents, preservatives, pH adjusters, sequestering agents, coloring agents, fragrances and fragrance diluents.
Here, as surfactants, in addition to sodium lauryl sulfate, sodium lauryl ether sulfate and polyethylene glycol, for example, polyoxyethylene alkyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene hydrogenated castor oil, glycerin fatty acid ester, higher fatty acid alkanolamide Etc. may be used alone or in admixture of two or more.
Here, the total weight means the weight of the foam generating bath agent according to the present invention, and the weight that can be adopted is 20 to 300 g, preferably 50 to 200 g.

請求項4は、請求項1,2または3記載の泡発生浴用剤において、立体物は柱状体と多面体と球状体とキャラクタ体から選ばれた1つの形状を成し、少なくとも浴湯中で溶け得る硬度であることを特徴とする。
請求項5は、請求項1,2,3または4記載の泡発生浴用剤において、立体物の表面側に外部より目視可能な装飾物を備えていることを特徴とする。
請求項6は、請求項1,2,3,4または5記載の泡発生浴用剤において、立体物の肉厚が1〜10cmで、その表面より内部に食い込む凹部を備え、凹部によって表面積を増大すると共に、全体の密度を均一化したことを特徴とする。
A fourth aspect of the present invention is the foam generating bath agent according to the first, second, or third aspect, wherein the three-dimensional object has one shape selected from a columnar body, a polyhedron, a spherical body, and a character body, and is at least dissolved in bath water. It is characterized by having a hardness to obtain.
A fifth aspect of the present invention is the foam generating bath agent according to the first, second, third, or fourth aspect, characterized in that a decoration that is visible from the outside is provided on the surface side of the three-dimensional object.
Claim 6 is the foam generating bath agent according to claim 1, 2, 3, 4 or 5, wherein the three-dimensional product has a thickness of 1 to 10 cm, and has a recess that cuts into the inside from the surface, and the surface area is increased by the recess. In addition, the overall density is uniform.

ここで立体物の柱状体とは、断面が三角形〜八角形、又は円形、半円形、三日月形、楕円形、或は任意形状を成し、一定の長さを有するものを言い、多面体とは、4面以上の面を有するもので、例えば三角推、サイコロ体、8面体、14面体等を言い、球状体とは、球体、楕円体、ラクビーボール、円盤体等を言い、キャラクタ体とは、果物、乗物、フィギュア等を言い、その形状は上記例に限定されるものではない。
ここで装飾物とは、立体物の加圧方向側と、加圧方向の反対側に埋設する押し花、植物の葉、切り絵、キャラクタシール、キャラクタカード等と、混合粉体に添加する金粉、銀粉等の金属粉を言いうが、食しても害にならなず、略平面的な物が好ましい。
ここで凹部とは、立体物の表面から内部に食い込む凹みを言い、多面体立体物にあっては、少なくとも一表面の略中央部に形成され、その大きさと深さは、表面積と肉厚、及び硬度に左右される。例えば、凹部の大きさは、表面積に略比例し、凹部の食い込み深さは、浴用剤の肉厚が増大するに従って深くなる。尚、表面積が広く、肉厚が薄い立体物にあっては、表面に複数の凹部を分散して形成することも可能である。
また、浴湯中で溶け得る硬度とは、浴湯内に投入してから1〜10分、好ましくは3〜10分、更に好ましくは5〜10分で全量が溶ける程度の硬度を言い、硬度を高くするほど溶けにくくなる。
Here, the three-dimensional columnar body has a triangular to octagonal or circular, semicircular, crescent, elliptical, or arbitrary shape, and has a certain length. It has four or more faces, for example, triangulation, dice, octahedron, 14-hedron, etc., and a spherical body means a sphere, an ellipsoid, a rugby ball, a disk, etc. , Fruits, vehicles, figures, etc., the shape of which is not limited to the above example.
Here, the decorative objects are the pressure direction side of the three-dimensional object, pressed flowers embedded on the opposite side of the pressure direction, plant leaves, cutouts, character seals, character cards, etc., and gold powder added to the mixed powder, Although metal powders, such as silver powder, are said, even if it eats, it is not harmful and a substantially planar thing is preferable.
Here, the concave portion refers to a dent that penetrates from the surface of the three-dimensional object, and in the polyhedral three-dimensional object, it is formed at a substantially central portion of at least one surface, and its size and depth are the surface area, the thickness, and Depends on hardness. For example, the size of the concave portion is substantially proportional to the surface area, and the depth of the concave portion increases as the thickness of the bath agent increases. In the case of a three-dimensional object having a large surface area and a small wall thickness, a plurality of concave portions can be dispersed on the surface.
Moreover, the hardness which can be melted in bath water means the hardness of the extent that the whole amount can be melted in 1 to 10 minutes, preferably 3 to 10 minutes, more preferably 5 to 10 minutes after being put in the bath water. The higher the value, the harder it becomes to melt.

本発明による泡発生浴用剤は上記のとおりであるから、次に記載する効果を奏する。
請求項1の泡発生浴用剤は、浴湯中に投入して溶けた時、自発的に炭酸ガスの気泡と石鹸性泡の二様の泡を発生する。即ち、炭酸ガスの気泡は、人体に触れ、強くはじけ割れるか、浴湯面まで上昇した後、はじけ割れて消滅するが、石鹸性泡は、人体に触れても破裂することがなく、浴湯面の全域にわたって消えることなく漂う。
そのことにより、炭酸ガスの気泡の一部は、浴湯面を漂う石鹸性泡によって空中への放出が妨げられ、石鹸性泡の下に留まり、人体に触れて強くはじけ割れる。その結果、炭酸ガスの気泡の多くが人体に適度のマッサージ効果を与える。
一方、石鹸性泡は、人体に付着するが、やわらかく、滑りがよく、粘着性が無く、皮膚に優しく、簡単に洗い落とすことができる。
Since the foaming bath agent according to the present invention is as described above, the following effects are exhibited.
The foam-generating bath agent according to claim 1 spontaneously generates two kinds of bubbles, that is, carbon dioxide bubbles and soapy bubbles, when it is dissolved in bath water. That is, the bubbles of carbon dioxide gas touch the human body and rupture strongly or rise to the surface of the bath, and then rip off and disappear, but the soapy bubbles do not rupture even when touched by the human body. It floats without disappearing over the entire surface.
As a result, a part of the bubbles of carbon dioxide gas is prevented from being released into the air by the soapy bubbles drifting on the bath surface, stays under the soapy bubbles, and is strongly broken by touching the human body. As a result, many of the bubbles of carbon dioxide give an appropriate massage effect to the human body.
On the other hand, soapy foam adheres to the human body, but is soft, slippery, non-sticky, gentle to the skin, and can be easily washed off.

請求項2の泡発生浴用剤は、請求項1の特徴に加えて、浴用主成分として少なくとも基材と有機酸と炭酸塩を含有するので、従来の発泡性浴用剤と同様に、浴湯にて溶けて炭酸ガスの気泡を発生する。この炭酸ガスの気泡は、弾け割れるときの弾発力が強く、マッサージ効果を発揮する。
請求項3の泡発生浴用剤は、請求項1,2記載の特徴に加えて、界面活性剤が浴湯にて溶けて石鹸性泡を発生する。この石鹸性泡は、本来有している洗浄性、保湿性、乳化性が皮膚に作用するので、垢や毛穴の汚れが落ち易く、湯上り後の肌にしっとり感となめらかさを与える。即ち、肌を良く洗浄しながら、しかも肌のなめらかさ、しっとり感を与えるので、浴用剤としての効果が総合的に向上する。特に石鹸性泡は、炭酸ガスの気泡と異なり破裂することがなく湯面に漂い、炭酸ガスの気泡の上昇を阻止し、湯面での破裂を防ぎ、人体に触れた時にのみに破裂するため、マッサージ効果が向上する。
請求項4の泡発生浴用剤は、請求項1,2,3記載の特徴に加えて、立体物が種々の形状に形成し得るので、ニーズに応じた形態の泡発生浴用剤を提供し得る。しかも、形態が異なっても、浴湯中で溶け得る特徴を有している。
In addition to the features of claim 1, the foam generating bath agent of claim 2 contains at least a base material, an organic acid, and a carbonate as the main components for bath. Melts and generates carbon dioxide bubbles. This carbon dioxide gas bubble has a strong resilience when it breaks and exhibits a massage effect.
In addition to the features of claims 1 and 2, the foam generating bath agent of claim 3 dissolves the surfactant in bath water to generate soapy foam. The soapy foam has inherent cleansing, moisturizing and emulsifying properties on the skin, so that dirt and pores are easily removed, and the skin after bathing is moistened and smooth. In other words, the effect as a bath preparation is comprehensively improved because the skin is well washed and the skin is smooth and moist. Unlike soap bubbles, especially soapy bubbles float on the surface of the water without rupturing, preventing the rise of carbon dioxide bubbles, preventing explosion on the surface of the water, and bursting only when touching the human body. The massage effect is improved.
In addition to the features of claims 1, 2 and 3, the foam generating bath agent of claim 4 can form a three-dimensional object in various shapes, so that it can provide a foam generating bath agent according to the needs. . Moreover, even if the form is different, it has a feature that it can be dissolved in bath water.

請求項5の泡発生浴用剤は、請求項1,2,3,4記載の特徴に加えて、立体物の表面側に押花等の装飾物を埋設すれば、浴用剤の美観を向上し得るし、金属粉等の装飾物を表面に出現するようにすれば、高級感を与えることができる。また、非水溶性の装飾物は、固形物が溶けた時、浴湯面に浮遊するので、装飾物として押花やキャラクタカード等を埋設すれば、それらを回収して収集することも可能である。
請求項6の泡発生浴用剤は、請求項1,2,3,4,5記載の特徴に加えて、立体物に表面より内部に食い込む凹部を備えることで、凹部の大きさや数によって表面積を調整し、溶け具合(溶ける時間)を加減し得るばかりか、浴用剤全体の密度を均一化し、均等に溶けるようにし得る。
In addition to the features of claims 1, 2, 3 and 4, the foam generating bath agent of claim 5 can improve the aesthetics of the bath agent by embedding decorative objects such as pressed flowers on the surface side of the three-dimensional object. However, if a decorative object such as metal powder appears on the surface, a high-class feeling can be given. In addition, water-insoluble decorations float on the bath surface when the solids melt, so if you embed a flower or character card as decorations, they can be collected and collected. .
In addition to the features of claims 1, 2, 3, 4 and 5, the foam generating bath agent of claim 6 has a concave portion that digs into the interior of the three-dimensional object from the surface, so that the surface area depends on the size and number of the concave portions. In addition to adjusting and adjusting the melting condition (melting time), the density of the whole bath preparation can be made uniform so as to melt evenly.

本発明による泡発生浴用剤の混合粉体の製造例を示す概略図である。It is the schematic which shows the manufacture example of the mixed powder of the agent for foam generation baths by this invention. 混合粉体の加圧前(イ)と加圧後(ロ)の断面図である。It is sectional drawing before pressurization (I) and after pressurization (B) of mixed powder. 本発明による泡発生浴用剤の第一実施形態を示す多面体の斜視図である。It is a perspective view of the polyhedron which shows 1st embodiment of the agent for foam generation baths by this invention. 泡発生浴用剤の浴用主成分(イ)と浴用補助成分(ロ)、及び界面活性剤(ハ)の類例図である。It is an example figure of the main component for bath (I) of the foam generation bath agent, the auxiliary component for bath (B), and the surfactant (C). 泡発生浴用剤の溶け具合を示す初期作用図である。It is an initial action figure which shows the melt | dissolution condition of the agent for foam generation baths. 泡発生浴用剤の溶け具合を示す中期作用図である。It is a medium-term action figure which shows the melt | dissolution condition of the foam generation bath agent. 立体物の形状を示す斜視図で、(イ)は柱状体を、(ロ)は球状体、(ハ)はキャラクタ体を示す。It is a perspective view which shows the shape of a solid object, (A) shows a columnar body, (B) shows a spherical body, and (C) shows a character body. 本発明による泡発生浴用剤の第二実施形態を示す一部切欠斜視図である。It is a partially notched perspective view which shows 2nd embodiment of the agent for foam generation baths by this invention. 本発明による泡発生浴用剤の第三実施形態を示す一部切欠斜視図である。It is a partially notched perspective view which shows 3rd embodiment of the foaming bath agent by this invention.

本発明による泡発生浴用剤の第一実施形態を図1乃至図3に基づき説明すれば、浴用主成分2と浴用補助成分3と界面活性剤4との混合粉体10を5〜70トンで加圧し、常温で固化している立体物5を形成する。
図の立体物5は6面体のサイコロ状多面体52を成し、浴用主成分2は少なくとも基材2aと有機酸2bと炭酸塩2cからなり、浴湯Wに溶けて泡の一つである炭酸ガスの気泡Bを生じ、界面活性剤4はラウリル硫酸ナトリウム4aとラウリルエーテル硫酸ナトリウム4bとポリエチレングリコール4cの少なくとも一方を全重量に対して0.5〜50重量%含有し、浴湯Wに溶けて泡の一つである石鹸性泡Sを生じ、全体として二様の泡を発生する。
The first embodiment of the foam generating bath agent according to the present invention will be described with reference to FIGS. 1 to 3. The mixed powder 10 of the main component 2 for bath, auxiliary component 3 for bath and surfactant 4 is 5 to 70 tons. Pressurized to form a three-dimensional object 5 solidified at room temperature.
The three-dimensional object 5 in the figure forms a hexahedral dihedral polyhedron 52, and the bath main component 2 is composed of at least a base material 2a, an organic acid 2b, and a carbonate 2c, and is dissolved in the bath water W and is one of bubbles. Gas bubbles B are generated, and the surfactant 4 contains at least one of sodium lauryl sulfate 4a, sodium lauryl ether sulfate 4b, and polyethylene glycol 4c in an amount of 0.5 to 50% by weight based on the total weight, and is dissolved in the bath water W. As a result, a soapy foam S, which is one of the foams, is generated, and two foams are generated as a whole.

浴用補助成分3として、乳白剤、増粘剤、保湿剤、吸湿剤、保存料、pH調整剤、金属イオン封鎖剤、着色料、香料および希釈剤から選択される少なくとも1種を添加する。
立体物5の形状は、柱状体51と多面体52と球状体43とキャラクタ体54とに大別した場合、柱状体51として、例えば三角柱〜八角柱、円柱、楕円柱、任意形状断面柱とがあり、多面体52として、例えば三角推4面、サイコロ状6面、8面体、14面体等があり、球状体43として、例えば楕円体、ラクビーボール、円盤等があり、キャラクタ体54として、例えば果物、乗物、フィギュア等がある。
泡発生浴用剤1の全重量は20〜300g、望ましくは50〜200gである。
As bath auxiliary component 3, at least one selected from opacifiers, thickeners, humectants, hygroscopic agents, preservatives, pH adjusters, sequestering agents, coloring agents, fragrances and diluents is added.
When the shape of the three-dimensional object 5 is roughly divided into a columnar body 51, a polyhedron 52, a spherical body 43, and a character body 54, the columnar body 51 includes, for example, a triangular column to an octagonal column, a cylinder, an elliptical column, and an arbitrarily shaped cross-sectional column. The polyhedron 52 includes, for example, a triangular quadruple plane, a dice-shaped six plane, an octahedron, and a fourteen plane. The spherical body 43 includes, for example, an ellipsoid, a rugby ball, a disk, and the like. , Vehicles, figures, etc.
The total weight of the foam generating bath agent 1 is 20 to 300 g, desirably 50 to 200 g.

本発明による泡発生浴用剤は、以下の手順で製造する。
先ず、浴用主成分2と浴用補助成分3と界面活性剤4から、各々から少なくとも1成分を選択し、その浴用主成分2と浴用補助成分3と界面活性剤4を図1の如く一つの器に入れ、これを攪拌混合し、pH4.5〜7.5の混合粉体10を得る。
次いで、その混合粉体10を雌金型9のキャビティ9a内に入れ、これを雄金型8にて30〜60トンの力で加圧し、サイコロ状多面体52を形成する。
具体的には、約200gの混合粉体10を50,000kg/cm2で加圧し、縦50mm、横50mm、高さ40mmのサイコロ状多面体52(以下、本発明試料とする。)を形成する。
サイコロ状多面体52は、通常の浴用剤と同様に、包装して販売される。
The foam generation bath agent according to the present invention is produced by the following procedure.
First, at least one component is selected from each of the bath main component 2, the bath auxiliary component 3 and the surfactant 4, and the bath main component 2, the bath auxiliary component 3 and the surfactant 4 are combined into one container as shown in FIG. And mixed with stirring to obtain a mixed powder 10 having a pH of 4.5 to 7.5.
Next, the mixed powder 10 is put into the cavity 9 a of the female die 9, and this is pressed with a male die 8 with a force of 30 to 60 tons to form a dice polyhedron 52.
Specifically, about 200 g of the mixed powder 10 is pressurized at 50,000 kg / cm 2 to form a dihedral polyhedron 52 (hereinafter referred to as a sample of the present invention) having a length of 50 mm, a width of 50 mm, and a height of 40 mm.
The dice-shaped polyhedron 52 is packaged and sold in the same manner as a normal bath preparation.

評価法1
ガラス製又はアクリル製の透明水槽(310×180×26mm、13リットル入り)に41゜Cのお湯Wを10リットル入れ、お湯W内に本発明試料を投入し、泡立ち状態を観察した所、本発明試料から炭酸ガスの気泡Bと石鹸性泡Sの二種類の泡が発生することが確認できた。
炭酸ガスの気泡Bは、図5(イ)の如く本発明試料の投入初期にはそのまま湯面まで上昇して弾け、浴湯W内に留まることがなかった。
石鹸性泡Sは、湯面まで上昇しても弾けることがなく、図5(ロ)の如く湯面に留まり、やがて湯面を覆うため、炭酸ガスの気泡Bは、湯面を覆う石鹸性泡Sによって浴湯内に留まった。
Evaluation method 1
10 liters of 41 ° C. hot water W was placed in a glass or acrylic transparent water tank (310 × 180 × 26 mm, 13 liters), the sample of the present invention was placed in the hot water W, and the bubbling state was observed. It was confirmed that two kinds of bubbles, carbon dioxide bubbles B and soapy bubbles S, were generated from the inventive sample.
As shown in FIG. 5 (a), the bubbles B of carbon dioxide gas bounced up to the surface of the molten metal as it was at the beginning of charging the sample of the present invention, and did not stay in the bath water W.
The soapy foam S does not flip even when it rises up to the surface of the hot water, and stays on the surface of the hot water as shown in FIG. The foam S stayed in the bath.

評価法2
本発明による泡発生浴用剤は、浴槽のお湯Wに投入するだけで自然に泡立つが、お湯Wを人手等で撹拌することにより泡立たちが増大するし、湯循環装置を使用するとなお一層優れた効果が得られる。
そこで、ヒトが入浴する状態での泡立ち状態を観察するために、気泡発生装置を作動させて泡立たせた。
浴槽に温度:38℃の浴湯Wを100リットル入れ、その浴湯W内に本発明試料を入れた後、気泡発生装置を作動させた所、数秒で高さ18cm程度に達する泡が形成され、その多くが石鹸性泡Sであった。その結果、炭酸ガスの気泡Bが湯面まで上昇して弾けること少なくなり、石鹸性泡Sの下に留まっている。
Evaluation method 2
The foam-generating bath agent according to the present invention naturally foams just by adding it to the hot water W of the bathtub, but the foaming is increased by stirring the hot water W manually, and the use of the hot water circulation device is even better. An effect is obtained.
Therefore, in order to observe the bubbling state in a state where a human bathes, the bubble generating device is operated to bubble.
When 100 liters of bath water W at a temperature of 38 ° C. is placed in the bath and the sample of the present invention is placed in the bath water W, the bubble generating device is activated, and bubbles reaching a height of about 18 cm are formed in a few seconds. Most of them were soapy foam S. As a result, the bubbles B of the carbon dioxide gas are less likely to rise to the hot water surface and play, and remain under the soapy bubbles S.

評価法3
テスト日から前2ケ月の間に病気をしたことのない健康な男性パネラーと女性パネラーを年代別に2名づつ募集した。男女パネラーの構成は表1の通りである。
浴槽に40℃の浴湯Wを100リットル入れ、その浴湯W内に本発明試料を入れた後、各パネラーに各々10分間入浴してもらい、泡が弾け割れるときのマッサージ効果、入浴中の肌のなめらかさ、入浴後の肌のしっとり感、体臭除去感等を下記の基準で評価した。

Figure 2013087105
Evaluation method 3
We recruited two healthy male panelists and two female panelists by age group who have not been ill in the previous two months from the test date. The composition of male and female panelists is shown in Table 1.
100 liters of 40 ° C. bath water W is put in the bathtub, and after putting the sample of the present invention in the bath water W, each paneler takes a bath for 10 minutes each, and the massage effect when the foam breaks, during bathing The following criteria evaluated skin smoothness, moist feeling after bathing, body odor removal feeling, and the like.
Figure 2013087105

「マッサージ効果」(肌に付着した泡の弾け方)についての基準を、
+2: 泡が多く、マッサージ幸かが強い。
+1: 泡がやや少なく、僅かにマッサージ効果がある。
0:泡が少なく、マッサージ効果が弱い。
-1:マッサージ効果がない。
の4区分で評価する。
The standard for "massage effect" (how to bounce bubbles attached to the skin)
+2: There are a lot of bubbles, and massage happiness is strong.
+1: There are few bubbles and there is a slight massage effect.
0: There are few bubbles and the massage effect is weak.
-1: There is no massage effect.
The four categories are evaluated.

「入浴後の肌のなめらかさ」及び「入浴後の肌のしっとり感」についての基準を、
+2:非常に優れている。
+1:かなり優れている。
0:やや劣る。
−1: 非常に劣る。
の4区分で評価する。
Standards for "smoothness after bathing" and "moist skin after bathing"
+2: Very good.
+1: It is quite excellent.
0: Slightly inferior.
-1: Very inferior.
The four categories are evaluated.

「体臭除去感」についての基準を、
+2:無臭。
+1:臭気を感じない。
0: 僅かに臭気を感じる。
−1: 臭気を感じる。
の4区分で評価する。
The standard for “feeling of removing body odor”
+2: Odorless.
+1: No odor is felt.
0: Slight odor is felt.
-1: I feel odor.
The four categories are evaluated.

以上の結果を男女別に平均値で表2と表3に示す。
その結果、マッサージ効果等を期待する場合、炭酸ガスの気泡Bが湯面まで上昇して弾けるまでの間に、身体を炭酸ガスの気泡Bに触れるようにする必要があるも、多数の炭酸ガスの気泡Bは、湯面まで上昇して弾ける。
石鹸性泡Sは、特に浴湯W内で身体を動かす程に多く発生する。

Figure 2013087105

Figure 2013087105
The above results are shown in Tables 2 and 3 as average values by gender.
As a result, when expecting a massage effect, etc., it is necessary to make the body touch the carbon dioxide bubbles B before the bubbles B rise to the surface of the hot water and bounce. Bubble B rises up to the hot water surface and can be played.
The soapy bubbles S are generated as much as the body moves, particularly in the bath water W.
Figure 2013087105

Figure 2013087105

本発明による泡発生浴用剤の第二実施形態を、第一実施形態と相違する点について説明すると、第二実施形態の泡発生浴用剤1は図7の如く、立体物5の表面側に外部より目視可能な装飾物7を備えるもので、立体物5がサイコロ状多面体52である場合、先ず雌金型8のキャビティ9aの底に装飾物7を配置し、次いで混合粉体10を入れ、混合粉体10の上に装飾物7を配置し、加圧を行う。即ち、装飾物7を、加圧方向側と、加圧方向の反対側に配置する。
装飾物7として、加圧に耐え、非水溶性で、食しても害にならない物が好ましい。例えば押し花、切り絵、切り文字、キャラクタカード、金属粉等。
The second embodiment of the foam generating bath agent according to the present invention will be described with respect to the differences from the first embodiment. The foam generating bath agent 1 of the second embodiment is externally attached to the surface side of the three-dimensional object 5 as shown in FIG. When the three-dimensional object 5 is a dice-shaped polyhedron 52, the decoration object 7 is first placed on the bottom of the cavity 9a of the female mold 8, and then the mixed powder 10 is placed. The decoration 7 is placed on the mixed powder 10 and is pressurized. That is, the ornament 7 is arranged on the pressure direction side and on the opposite side of the pressure direction.
The decoration 7 is preferably an article that can withstand pressure, is insoluble in water, and does not cause harm when eaten. For example, pressed flowers, cut pictures, cut letters, character cards, metal powder, etc.

本発明による泡発生浴用剤の第三実施形態を、第一・第二実施形態と相違する点について説明すると、第三実施形態の泡発生浴用剤1は図8の如く、立体物5がサイコロ状多面体52であり、その肉厚tが3〜10cmである場合、サイコロ状多面体52の表面5aより内部に食い込む凹部6を備えている。
凹部6はサイコロ状多面体52を形成する6面に総て設けることが好ましいが、6面の少なくとも1箇所以上に設けることも可能である。
この凹部6の形成によってサイコロ状多面体52の表面積を増大すると共に、全体の密度を均一化することができる。
The third embodiment of the foam generating bath agent according to the present invention will be described in terms of differences from the first and second embodiments. The foam generating bath agent 1 of the third embodiment is as shown in FIG. When the wall thickness t is 3 to 10 cm, a concave portion 6 that bites into the inside from the surface 5a of the dice-shaped polyhedron 52 is provided.
The recesses 6 are preferably provided on all six surfaces forming the dice-shaped polyhedron 52, but may be provided on at least one of the six surfaces.
The formation of the recesses 6 can increase the surface area of the dice polyhedron 52 and make the entire density uniform.

本発明は実施例に限定されるものではない。例えば乳白剤、増粘剤、植物性または鉱物性のオイルのような肌のコンディショナー、ワックスやセラミド、カチオン性または両性のポリマー、シリコーン、ソルビトールのような保湿剤、保存料、pH調整剤、金属イオン封鎖剤、着色料、香料および香料の希釈剤から選択される少なくとも1つの添加剤を含有するのが好ましい。また、界面活性剤4としてラウリルエーテル硫酸ナトリウムを使用するのが好ましい。
更に、乳白剤として、例えば長鎖の脂肪アルコール、ポリオールの脂肪エステル、ジステアリルエーテルのような脂肪ジエーテルを挙げることができる。
また、白濁させるために酸化チタン(TiO2)を適量配合してもよいし、増粘剤として、非イオン性のセルロース系増粘剤(ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース)、組成物の全重量に対して1から2重量%使用するのが好ましい。
浴用主成分は、浴剤として使用可能なものであればいかなるものでもよい。
The present invention is not limited to the examples. Skin conditioners such as opacifiers, thickeners, vegetable or mineral oils, waxes or ceramides, cationic or amphoteric polymers, humectants such as silicone or sorbitol, preservatives, pH adjusters, metals It preferably contains at least one additive selected from sequestering agents, colorants, fragrances and fragrance diluents. Further, it is preferable to use sodium lauryl ether sulfate as the surfactant 4.
Furthermore, examples of opacifiers include long-chain fatty alcohols, fatty esters of polyols, and fatty diethers such as distearyl ether.
Further, an appropriate amount of titanium oxide (TiO2) may be blended to make it cloudy, and as a thickener, a nonionic cellulose-based thickener (hydroxyethylcellulose, hydroxypropylcellulose), based on the total weight of the composition It is preferable to use 1 to 2% by weight.
The main component for bath may be any as long as it can be used as a bath agent.

1 泡発生浴用剤
2 浴用主成分、2a 基材、2b 有機酸、2c 炭酸塩
3 浴用補助成分
4 界面活性剤、4a ラウリル硫酸ナトリウム
4b ラウリルエーテル硫酸ナトリウム、4c ポリエチレングリコール
5 立体物、5a 表面
51 柱状体、52 多面体、53 球状体、54 キャラクタ体
6 凹部
7 装飾物(押花、カード、シール、金粉)
8 雄金型
9 雌金型
10 混合粉体
t 立体物の肉厚
W 浴湯(お湯)
B 炭酸ガスの気泡
S 石鹸性泡
DESCRIPTION OF SYMBOLS 1 Foam generation bath agent 2 Bath main component, 2a base material, 2b Organic acid, 2c carbonate 3 Bath auxiliary component 4 Surfactant, 4a Sodium lauryl sulfate 4b Sodium lauryl ether sulfate, 4c Polyethylene glycol 5 Solid, 5a Surface 51 Columnar body, 52 Polyhedron, 53 Spherical body, 54 Character body 6 Recessed part 7 Decoration (pressed flower, card, seal, gold powder)
8 Male mold 9 Female mold 10 Mixed powder t Thickness of solid object W Bath (hot water)
B Carbon dioxide bubbles S Soapy foam

Claims (6)

浴用主成分と浴用補助成分と界面活性剤との混合粉体を加圧し、常温で固化している立体物であり、立体物は一定以上の衝撃で粉砕が可能であると共に、水からお湯までの液体により溶けて炭酸ガスの気泡と石鹸性泡の二様の泡を発生することを特徴とする泡発生浴用剤。 Pressurized mixed powder of bath main component, bath auxiliary component and surfactant, solidified at room temperature, solid can be crushed with a certain impact or more, from water to hot water A foam-generating bath agent characterized by being dissolved in a liquid and generating two types of bubbles, carbon dioxide bubbles and soapy bubbles. 浴用主成分は少なくとも基材と有機酸と炭酸塩からなり、浴湯にて溶けて炭酸ガスの気泡を発生することを特徴とする請求項1記載の泡発生浴用剤。 2. The foam-generating bath agent according to claim 1, wherein the main component for bath is composed of at least a base material, an organic acid and a carbonate, and dissolves in bath water to generate bubbles of carbon dioxide gas. 界面活性剤としてラウリル硫酸ナトリウムとラウリルエーテル硫酸ナトリウムとポリエチレングリコールの少なくとも一方を全重量に対して0.5〜50重量%含有しており、この界面活性剤によって石鹸性泡を発生することを特徴とする請求項1または2項記載の泡発生浴用剤。 The surfactant contains at least one of sodium lauryl sulfate, sodium lauryl ether sulfate, and polyethylene glycol in an amount of 0.5 to 50% by weight based on the total weight, and the surfactant generates soapy foam. The foam generating bath agent according to claim 1 or 2. 立体物は柱状体と多面体と球状体とキャラクタ体から選ばれた1つの形状を成し、少なくとも浴湯中で溶け得る硬度であることを特徴とする請求項1,2または3記載の泡発生浴用剤。 4. The foam generation according to claim 1, 2 or 3, wherein the three-dimensional object has one shape selected from a columnar body, a polyhedron, a spherical body and a character body, and has a hardness which can be at least dissolved in bath water. Bath agent. 立体物の表面側に外部より目視可能な装飾物を備えていることを特徴とする請求項1,2,3または4記載の泡発生浴用剤。 The foam-generating bath agent according to claim 1, 2, 3 or 4, further comprising a decorative object visible on the surface side of the three-dimensional object. 立体物の肉厚が1〜10cmで、その表面より内部に食い込む凹部を備え、凹部によって表面積を増大すると共に、全体の密度を均一化したことを特徴とする請求項1,2,3,4または5記載の泡発生浴用剤。 The three-dimensional object has a thickness of 1 to 10 cm and is provided with a concave portion that digs into the inside from the surface thereof, and the surface area is increased by the concave portion and the entire density is made uniform. Or the foam generation bath agent of 5.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110693731A (en) * 2019-10-18 2020-01-17 惠州兆婷化妆品有限公司 High-hardness and long-lasting-foaming explosive salt and preparation method thereof

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Publication number Priority date Publication date Assignee Title
JPH092942A (en) * 1995-06-21 1997-01-07 Kao Corp Foaming tablet type bathing agent
JP2005200350A (en) * 2004-01-15 2005-07-28 Asahi Kasei Life & Living Corp Carbonated leg bath preparation
JP2006219417A (en) * 2005-02-10 2006-08-24 Kao Corp Solid foamable bathing agent composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH092942A (en) * 1995-06-21 1997-01-07 Kao Corp Foaming tablet type bathing agent
JP2005200350A (en) * 2004-01-15 2005-07-28 Asahi Kasei Life & Living Corp Carbonated leg bath preparation
JP2006219417A (en) * 2005-02-10 2006-08-24 Kao Corp Solid foamable bathing agent composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110693731A (en) * 2019-10-18 2020-01-17 惠州兆婷化妆品有限公司 High-hardness and long-lasting-foaming explosive salt and preparation method thereof

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