JP2012106205A - Method for forming patterned surface - Google Patents

Method for forming patterned surface Download PDF

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JP2012106205A
JP2012106205A JP2010258527A JP2010258527A JP2012106205A JP 2012106205 A JP2012106205 A JP 2012106205A JP 2010258527 A JP2010258527 A JP 2010258527A JP 2010258527 A JP2010258527 A JP 2010258527A JP 2012106205 A JP2012106205 A JP 2012106205A
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colored
paint
weight
pattern
transparent
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JP5420521B2 (en
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Masashi Adachi
将司 足立
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Beck Co Ltd
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Beck Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a simple coating method by which a pattern to similar to a natural stone material such as marble is formed in a building or the like.SOLUTION: A method for forming a patterned surface performs, onto a base material, (1) a step of applying at least one or more kinds of a colored coating materials in granules to form an under coating surface where colored granules are scattered and (2) a step of applying a transparent colored coating material onto the under coating surface in stripes to form a stripe patterned surface.

Description

本発明は、新規な模様面の形成方法に関するものである。本発明は、主に建築物や土木構造物等に対して適用することができる。   The present invention relates to a novel pattern surface forming method. The present invention can be applied mainly to buildings, civil engineering structures, and the like.

従来、建築物の内外装等における壁材の一つとして、大理石等の天然石材が使用されている。このような天然石材は、多彩な色柄模様を有しており、美観性に優れたものである。但し、天然石材を加工して得られる壁材は、一般に重く、厚いため、基材への負荷が大きくなりやすい。また、このような壁材は、価格が高いという短所もある。
そこで、大理石等の天然石材に類似した模様を形成させる方法が、種々提案されている。
Conventionally, natural stone materials such as marble have been used as one of the wall materials in the interior and exterior of buildings. Such natural stone materials have various color patterns and are excellent in aesthetics. However, since the wall material obtained by processing natural stone is generally heavy and thick, the load on the base material tends to increase. In addition, such a wall material has a disadvantage that it is expensive.
Therefore, various methods for forming a pattern similar to natural stone such as marble have been proposed.

例えば、特開平10−183030号公報(特許文献1)には、大理石調の模様を形成する手法として、複数の顔料成分を含む塗料組成物を塗装した後、溶剤を含む混合液体を吹き付ける方法が記載されている。
特開平10−216626号公報(特許文献2)には、下層塗料を塗装後、下層塗料が乾燥する前に、上層塗料を水滴状に散布する方法が記載されている。
また、特開平4−277056号公報(特許文献3)には、真綿を引き伸ばして作製したマスキング材を用いて、塗装を行う方法が記載されている。
しかしながら、このような方法は、いずれも、ぼかし模様を形成するために行われるものであり、大理石等に特有の筋状模様を表現することについては、考慮されていない。
For example, Japanese Patent Laid-Open No. 10-183030 (Patent Document 1) discloses a method of spraying a mixed liquid containing a solvent after applying a coating composition containing a plurality of pigment components as a technique for forming a marble-like pattern. Are listed.
Japanese Patent Application Laid-Open No. 10-216626 (Patent Document 2) describes a method of spraying the upper layer paint in the form of water droplets after the lower layer paint is applied and before the lower layer paint is dried.
JP-A-4-277056 (Patent Document 3) describes a method of coating using a masking material produced by stretching true cotton.
However, all of these methods are performed to form a blurred pattern, and no consideration is given to expressing a streak pattern unique to marble or the like.

天然石材の筋状模様を再現する方法として、特開平1−127148号公報(特許文献4)には、塗料を用いて模様を描いた後、その模様が乾燥する前に、異色の塗料を塗り重ねる方法が記載されている。
また、特開2001−26058号公報(特許文献5)には、着色アクリルシロップを吹き付けて、所望の模様を形成することが記載されている。
しかしながら、このような特許文献の方法では、塗料の粘度、吐出圧、吐出量、あるいは被塗面までの距離等について、厳密な調整が不可欠であるため、塗装作業が非常に繁雑となる。
As a method of reproducing a streak pattern of natural stone, Japanese Patent Application Laid-Open No. 1-127148 (Patent Document 4) applies a paint of a different color after a pattern is drawn using a paint and before the pattern is dried. A method of overlapping is described.
Japanese Patent Laid-Open No. 2001-26058 (Patent Document 5) describes that a desired pattern is formed by spraying colored acrylic syrup.
However, in such a method of the patent document, since it is indispensable to strictly adjust the viscosity, discharge pressure, discharge amount, distance to the surface to be coated, and the like, the painting work becomes very complicated.

この他、天然石材の筋状模様を再現する方法としては、特開2003−127148号公報(特許文献6)、特開2001−114546号公報(特許文献7)等に記載の方法も挙げられる。しかし、これらは、いずれも金型を用いて成型体を製造する場合に限定される技術であり、実際の建築物等に対して適用できるものではない。   In addition, examples of a method for reproducing a streak pattern of natural stone include the methods described in JP-A No. 2003-127148 (Patent Document 6), JP-A No. 2001-114546 (Patent Document 7), and the like. However, these are techniques limited to the case where a molded body is manufactured using a mold, and are not applicable to an actual building or the like.

特開平10−183030号公報JP-A-10-183030 特開平10−216626号公報JP-A-10-216626 特開平4−277056号公報JP-A-4-277056 特開平1−127148号公報Japanese Patent Laid-Open No. 1-127148 特開2001−26058号公報JP 2001-26058 A 特開2003−127148号公報JP 2003-127148 A 特開2001−114546号公報JP 2001-114546 A

本発明は、上述のような問題点に鑑みなされたものであり、建築物等において、大理石等の天然石材に類似した模様が形成できる、簡便な塗装方法を提供することを目的とするものである。   The present invention has been made in view of the above problems, and an object of the present invention is to provide a simple coating method capable of forming a pattern similar to a natural stone material such as marble in a building or the like. is there.

本発明者は、上記目的を達成するため鋭意検討を行った結果、着色粒状物が散在した下塗面を形成した後に、透明着色塗料を筋状に塗付する方法に想到し、本発明を完成させるに到った。   As a result of diligent studies to achieve the above object, the present inventors have conceived a method for applying a transparent colored paint in a streak form after forming an undercoat surface on which colored particles are scattered, and completed the present invention. It came to let you.

すなわち、本発明は以下の特徴を有するものである。   That is, the present invention has the following characteristics.

1.基材に対し、
(1)少なくとも1種以上の着色塗料を粒状に塗付して、着色粒状物が散在した下塗面を形成する工程、
(2)当該下塗面に対し、透明着色塗料を筋状に塗付して、筋状模様面を形成する工程、を行うことを特徴とする模様面の形成方法。
2.筋状模様面を形成する工程において、
紐状の吸液部材を備えた回転具、及び/または紐状の吸液部材を備えた押圧具、
を用いて透明着色塗料を筋状に塗付する1.記載の模様面の形成方法。
1. For substrate
(1) A step of applying at least one or more kinds of colored paints in a granular form to form an undercoat surface in which colored granular materials are scattered,
(2) A method of forming a pattern surface, comprising: applying a transparent colored paint in a streak pattern to the undercoat surface to form a streak pattern surface.
2. In the process of forming the streaked pattern surface,
A rotating tool provided with a string-like liquid-absorbing member, and / or a pressing tool provided with a string-like liquid-absorbing member,
Apply transparent colored paint in a streaky pattern using 1. The formation method of the described pattern surface.

本発明によれば、天然石材に類似した模様、特に筋状模様を有する大理石等に類似した模様を、簡便に形成することができる。本発明は、建築物、土木構造物の壁面等に対し、美観性を付与する塗装方法として、好ましく適用することができる。   According to the present invention, it is possible to easily form a pattern similar to natural stone, particularly a pattern similar to marble having a streak pattern. INDUSTRIAL APPLICABILITY The present invention can be preferably applied as a coating method for imparting aesthetics to a wall of a building or a civil engineering structure.

以下、本発明を実施するための形態について説明する。   Hereinafter, modes for carrying out the present invention will be described.

本発明は、基材に対し、
(1)少なくとも1種以上の着色塗料を粒状に塗付して、着色粒状物が散在した下塗面を形成する工程(以下「工程(1)ともいう」)を行った後、
(2)当該下塗面に対し、透明着色塗料を筋状に塗付して、筋状模様面を形成する工程(以下「工程(2)」ともいう)、
を行うものである。
The present invention relates to a substrate,
(1) After applying at least one or more kinds of colored paints in a granular form to form an undercoat surface in which colored granular materials are scattered (hereinafter also referred to as “process (1)”),
(2) A step of applying a transparent colored paint in a streak pattern to the undercoat surface to form a streak pattern surface (hereinafter also referred to as “step (2)”),
Is to do.

本発明では、このような方法を用いることにより、単調な筋状模様ではなく、各々の筋において、その太さ、濃さ等が変化した模様を得ることができる。すなわち、筋状模様に視覚的な強弱を付与することができ、人工的ではなく、自然感の高い仕上りを得ることが可能となる。
このような効果は、工程(2)で用いる着色塗料が透明性を有するため、下塗面における着色粒状物との重なり状態等によって、筋の見え方に変化が生じることに起因するものである。
なお、本発明における「透明」とは、可視光透過性を有し、下層が視認できる性質のことである。
In the present invention, by using such a method, it is possible to obtain not a monotonous streak pattern but a pattern in which the thickness, the darkness, etc. are changed in each streak. That is, visual strength can be given to the streak pattern, and it is possible to obtain a finish that is not artificial and has a high natural feeling.
Such an effect is due to the change in the appearance of the streaks due to the overlapping state with the colored granular materials on the undercoat surface, etc., because the colored paint used in the step (2) has transparency.
In the present invention, “transparent” means a property having visible light transparency and allowing the lower layer to be visually recognized.

本発明は、主に、建築物、土木構造物等に適用することができる。このような部位を構成する基材としては、例えば、コンクリート、モルタル、サイディングボード、押出成形板、石膏ボード、パーライト板、合板、プラスチック板、金属板、木工板、ガラス、煉瓦、陶磁器タイル等の各種基材が挙げられる。
これら基材は、何らかの表面処理(フィラー処理、サーフェーサー処理、シーラー処理等)が施されたものや、予め着色塗料等で着色されたものでもよく、既に塗膜が形成されたものや、壁紙が貼り付けられたものであってもよい。
The present invention is mainly applicable to buildings, civil engineering structures, and the like. As a base material constituting such a part, for example, concrete, mortar, siding board, extrusion board, gypsum board, pearlite board, plywood board, plastic board, metal board, wood board, glass, brick, ceramic tile, etc. Various base materials are mentioned.
These base materials may have been subjected to some surface treatment (filler treatment, surfacer treatment, sealer treatment, etc.), or may be pre-colored with a colored paint or the like. It may be affixed.

本発明の工程(1)では、上述の基材に対し、少なくとも1種以上の着色塗料を粒状に塗付する。これにより、着色粒状物が散在した下塗面が形成される。
下塗面においては、2種以上の異色の着色粒状物が散在した形態、すなわち2色以上(より好ましくは3〜8色)の着色粒状物が散在した形態が望ましい。着色粒状物の色調は、最終的に形成される模様に応じて適宜設定すればよい。
着色粒状物の粒径は、好ましくは0.1〜20mm(より好ましくは1〜10mm)である。本発明では、粒径が異なる着色粒状物を種々組み合せることによって、意匠性の幅を広げることもできる。
In the step (1) of the present invention, at least one kind of colored paint is applied in a granular form to the above-mentioned substrate. Thereby, the undercoat surface in which the colored particulate matter is scattered is formed.
In the undercoat surface, a form in which two or more kinds of colored particles having different colors are scattered, that is, a form in which colored particles having two or more colors (more preferably 3 to 8 colors) are scattered is desirable. What is necessary is just to set suitably the color tone of a colored granular material according to the pattern finally formed.
The particle size of the colored granular material is preferably 0.1 to 20 mm (more preferably 1 to 10 mm). In the present invention, the range of designability can be expanded by combining various colored granular materials having different particle diameters.

工程(1)では、特に、
工程(2)における透明着色塗料との色差が相対的に大きい着色粒状物(p)(以下単に「着色粒状物(p)」ともいう)と、
着色粒状物(p)に比べ、工程(2)における透明着色塗料との色差が相対的に小さい着色粒状物(q)(以下単に「着色粒状物(q)」ともいう)、が散在した形態が好適である。このような下塗面は、美観性向上化の点で好適である。
In step (1), in particular,
A colored granular material (p) having a relatively large color difference from the transparent colored paint in the step (2) (hereinafter also simply referred to as “colored granular material (p)”);
Form in which colored granular material (q) (hereinafter, also simply referred to as “colored granular material (q)”) having a relatively small color difference from the transparent colored paint in step (2) compared to colored granular material (p) is scattered. Is preferred. Such an undercoat surface is suitable in terms of improving aesthetics.

着色粒状物(p)は、工程(2)の透明着色塗料と異色であることが認識できるものであればよい。着色粒状物(p)と、工程(2)の透明着色塗料との色差は、好ましくは5を超える(より好ましくは6以上、さらに好ましくは8以上)程度であればよい。
着色粒状物(q)は、着色粒状物(p)よりも、工程(2)の透明着色塗料に近い色調を有するものである。すなわち、着色粒状物(q)と、工程(2)の透明着色塗料との色差は、着色粒状物(p)と、工程(2)の透明着色塗料との色差よりも小さい状態であればよい。
下塗面において、3種以上の着色粒状物を用いる場合は、工程(2)の透明着色塗料との色差が最も大きい(p)と、最も小さい(q)に加え、その中間の色差を有する着色粒状物を複数種用いればよい。
The colored granular material (p) only needs to be recognized as having a different color from the transparent colored paint in the step (2). The color difference between the colored granular material (p) and the transparent colored paint in the step (2) is preferably more than 5 (more preferably 6 or more, still more preferably 8 or more).
The colored granular material (q) has a color tone closer to that of the transparent colored paint in the step (2) than the colored granular material (p). In other words, the color difference between the colored granular material (q) and the transparent colored paint in the step (2) may be smaller than the color difference between the colored granular material (p) and the transparent colored paint in the step (2). .
In the case of using three or more kinds of colored granular materials on the undercoat surface, in addition to the largest (p) and smallest (q) color difference from the transparent colored paint in step (2), coloring having an intermediate color difference A plurality of types of granular materials may be used.

なお、本発明における色差(△E)は、白紙を背景として用い、対象物の色データ(L、a、b)を測定することにより、算出することができる。色差(△E)は、色差計を用いて測定することができる。測定時の対象物の膜厚は、50μm程度とすればよい。 The color difference (ΔE) in the present invention can be calculated by measuring the color data (L * , a * , b * ) of the object using a blank paper as the background. The color difference (ΔE) can be measured using a color difference meter. What is necessary is just to let the film thickness of the target object at the time of a measurement be about 50 micrometers.

下塗面の着色粒状物は、結合材、及び顔料を含む着色塗料によって形成されることが望ましい。
このうち、結合材としては、各種の樹脂成分が使用できる。樹脂成分としては、例えば、溶剤可溶型樹脂、非水分散型樹脂、無溶剤型樹脂、水分散型樹脂、水溶性樹脂等が挙げられる。樹脂の種類としては、例えば、アクリル樹脂、ウレタン樹脂、エポキシ樹脂、塩化ビニル樹脂、酢酸ビニル樹脂、アクリルシリコン樹脂、フッ素樹脂、ポリビニルアルコール、セルロース誘導体等、あるいはこれらの複合物等が挙げられる。このような樹脂成分は、塗膜形成後に架橋反応を生じる性質を有するものであってもよい。
It is desirable that the colored granular material of the undercoat surface is formed by a colored paint including a binder and a pigment.
Among these, as the binder, various resin components can be used. Examples of the resin component include solvent-soluble resins, non-water-dispersed resins, solvent-free resins, water-dispersed resins, and water-soluble resins. Examples of the resin include acrylic resins, urethane resins, epoxy resins, vinyl chloride resins, vinyl acetate resins, acrylic silicon resins, fluororesins, polyvinyl alcohol, cellulose derivatives, and composites thereof. Such a resin component may have a property of causing a crosslinking reaction after the coating film is formed.

顔料としては、着色顔料が使用できる。具体的に、着色顔料としては、例えば、酸化チタン、酸化亜鉛、アルミナ、カーボンブラック、酸化第二鉄(弁柄)、黄色酸化鉄、酸化鉄、群青、コバルトグリーン等の無機着色顔料、アゾ系、ナフトール系、ピラゾロン系、アントラキノン系、ペリレン系、キナクリドン系、ジスアゾ系、イソインドリノン系、ベンゾイミダゾール系、フタロシアニン系、キノフタロン系等の有機着色顔料、パール顔料、アルミニウム顔料、蛍光顔料等が挙げられる。このような着色顔料の1種または2種以上を組み合わせることにより、着色塗料を所望の色調に調製することができる。
着色塗料においては、このような着色顔料に加え、体質顔料を使用することもできる。体質顔料としては、例えば、炭酸カルシウム、硫酸バリウム、クレー、カオリン、陶土、タルク、珪石粉、珪藻土等が挙げられる。
Color pigments can be used as the pigment. Specifically, examples of the color pigment include titanium oxide, zinc oxide, alumina, carbon black, ferric oxide (valve), yellow iron oxide, iron oxide, ultramarine, cobalt green, and other inorganic color pigments, azo series Organic pigments such as naphthol, pyrazolone, anthraquinone, perylene, quinacridone, disazo, isoindolinone, benzimidazole, phthalocyanine, quinophthalone, pearl pigment, aluminum pigment, fluorescent pigment, etc. It is done. By combining one or more of these color pigments, a colored paint can be prepared in a desired color tone.
In the colored paint, an extender can be used in addition to such a colored pigment. Examples of extender pigments include calcium carbonate, barium sulfate, clay, kaolin, porcelain clay, talc, quartzite powder, and diatomaceous earth.

この着色塗料における着色顔料の濃度は、好ましくは40重量%以下(より好ましくは0.001重量%以上30重量%以下)である。着色粒状物に隠ぺい性を付与する場合、着色塗料における着色顔料の濃度は、好ましくは3重量%を超える(より好ましくは5重量%を超え40重量%以下、さらに好ましくは6重量%以上30重量%以下)程度とすればよい。   The concentration of the color pigment in the colored paint is preferably 40% by weight or less (more preferably 0.001% by weight or more and 30% by weight or less). When concealing the colored granular material, the concentration of the colored pigment in the colored paint is preferably more than 3% by weight (more preferably more than 5% by weight and 40% by weight or less, more preferably 6% by weight or more and 30% by weight). % Or less).

本発明では、着色粒状物を形成する着色塗料として、透明着色塗料を使用することもできる。このような透明着色塗料を用いることにより、美観性向上を図ることが可能となる。透明着色塗料における着色顔料の濃度は、着色粒状物が透明性を示す範囲内で適宜設定すればよいが、好ましくは5重量%以下(より好ましくは0.001重量%以上3重量%以下、さらに好ましくは0.01重量%以上2重量%以下)である。透明着色塗料の色調は、最終的に形成される模様に応じて適宜設定すればよい。   In the present invention, a transparent colored paint can also be used as a colored paint for forming a colored granular material. By using such a transparent colored paint, it is possible to improve aesthetics. The concentration of the color pigment in the transparent coloring paint may be appropriately set within a range in which the colored granular material exhibits transparency, but is preferably 5% by weight or less (more preferably 0.001% by weight to 3% by weight, Preferably, it is 0.01% by weight or more and 2% by weight or less. What is necessary is just to set suitably the color tone of a transparent coloring paint according to the pattern finally formed.

工程(1)では、着色粒状物が形成可能な塗装方法を採用することができ、特に吹付け塗装が好適である。2種以上の着色塗料を使用する場合、これら着色塗料は同時に、または順に塗装すればよい。複数種の着色塗料を同時に塗装する場合には、塗装器具として多頭型吹付け塗装機等を使用することができる。着色塗料の塗付け量は、好ましくは0.01〜0.8kg/m程度である。 In the step (1), a coating method capable of forming a colored granular material can be employed, and spray coating is particularly suitable. When two or more kinds of colored paints are used, these colored paints may be applied simultaneously or sequentially. When a plurality of types of colored paints are applied simultaneously, a multi-head spray coating machine or the like can be used as a painting tool. The amount of the colored paint applied is preferably about 0.01 to 0.8 kg / m 2 .

下塗面の乾燥は、通常、常温(0〜40℃程度)で行えばよい。本発明では、下塗面が乾燥した後に、工程(2)を行えばよい。   The undercoat surface may be usually dried at room temperature (about 0 to 40 ° C.). In the present invention, the step (2) may be performed after the undercoat surface is dried.

本発明の工程(2)では、上記下塗面に対し、透明着色塗料を筋状に塗付して、筋状模様面を形成する。
工程(2)で用いる透明着色塗料としては、結合材、及び顔料を含むものが使用できる。透明着色塗料の色調は、所望の筋状模様に応じて、適宜設定すればよい。
In the step (2) of the present invention, a transparent colored paint is applied in a streak pattern to the undercoat surface to form a streak pattern surface.
As the transparent colored paint used in the step (2), a paint containing a binder and a pigment can be used. What is necessary is just to set the color tone of a transparent coloring paint suitably according to a desired streak pattern.

透明着色塗料における結合材、顔料としては、工程(1)で説明したものと同様のものが使用できる。
透明着色塗料の透明性は、着色顔料の濃度を低く設定することにより付与することができる。透明着色塗料における着色顔料の濃度は、好ましくは5重量%以下(より好ましくは0.001重量%以上3重量%以下、さらに好ましくは0.01重量%以上2重量%以下)に設定すればよい。
As the binder and the pigment in the transparent coloring paint, the same materials as described in the step (1) can be used.
The transparency of the transparent coloring paint can be imparted by setting the concentration of the color pigment low. The concentration of the color pigment in the transparent colored paint is preferably set to 5% by weight or less (more preferably 0.001% by weight to 3% by weight, and still more preferably 0.01% by weight to 2% by weight). .

工程(2)の塗装においては、筋状模様が形成される限り、種々の塗装方法を採用することができる。この際、用いる器具としては、例えば、ローラー、スタンプ、刷毛、筆等が挙げられる。
工程(2)では、筋状模様の穴を開けた型紙を用いて、塗装を行うこともできる。この場合は、下塗面に型紙を貼着し、その上から透明着色塗料をスプレー等によって塗付した後、型紙を除去すればよい。
In the coating in the step (2), various coating methods can be adopted as long as a streak pattern is formed. At this time, examples of the instrument to be used include a roller, a stamp, a brush, and a brush.
In the step (2), painting can be performed using a paper pattern in which a streak pattern is perforated. In this case, the pattern paper may be removed after sticking the pattern paper to the undercoating surface and applying a transparent colored paint from above by spraying or the like.

工程(2)において好適な器具としては、紐状の吸液部材を備えた回転具(ローラー)、及び/または紐状の吸液部材を備えた押圧具(スタンプ)が挙げられる。このような器具を用いることにより、塗装作業性が高まり、効率的に筋状模様を形成することができる。
上記回転具としては、例えば、プラスチック、金属等からなる円筒体の表面に、紐状の吸液部材が複数取り付けられたもの等が使用できる。一方、上記押圧具としては、例えば、プラスチック、木材、金属等からなる部材の平坦面に、紐状の吸液部材が複数取り付けられたもの等が使用できる。
紐状の吸液部材としては、繊維質材またはスポンジ質材からなるものが好適である。
Suitable tools in the step (2) include a rotating tool (roller) having a string-like liquid absorbing member and / or a pressing tool (stamp) having a string-like liquid absorbing member. By using such an instrument, the painting workability is improved and a streak pattern can be efficiently formed.
As the rotating tool, for example, a tool in which a plurality of string-like liquid absorbing members are attached to the surface of a cylindrical body made of plastic, metal, or the like can be used. On the other hand, as the pressing tool, for example, a member in which a plurality of string-like liquid absorbing members are attached to a flat surface of a member made of plastic, wood, metal or the like can be used.
As the string-like liquid-absorbing member, those made of a fibrous material or a sponge material are suitable.

工程(2)では、上記透明着色塗料により、筋状模様面を形成する。筋状模様は、1本または2本以上の筋の組み合わせにより形成することができる。筋の幅、長さ等は、所望の模様形状に応じて、適宜設定することができる。通常、筋の幅は0.5〜50mm(好ましくは1〜20mm)程度である。   In step (2), a streak pattern surface is formed by the transparent coloring paint. The streak pattern can be formed by one or a combination of two or more streaks. The width, length, and the like of the streaks can be appropriately set according to the desired pattern shape. Usually, the width of the line is about 0.5 to 50 mm (preferably 1 to 20 mm).

本発明では、筋状模様面が乾燥した後、必要に応じ透明塗料を塗付することもできる。特に耐候性が要求される構造物外部の部位に施工する際には、保護の目的で透明塗料を塗付するのが好ましい。この透明塗料として、透明着色塗料を使用することもできる。このような透明塗料として、親水性被膜が形成できるものを使用すれば、耐汚染性を高めることもできる。
また、本発明では、目地棒や目地型枠等の目地材の使用によって、格子状、幾何学模様状等の目地部を形成することもできる。この場合は、目地色となる色調で塗装を施した基材に、目地材を貼り付けた後、必要に応じ中塗材等を塗付した後、上記工程を行い、その後に目地材を除去すればよい。
In the present invention, after the streaky pattern surface is dried, a transparent paint can be applied as necessary. In particular, it is preferable to apply a transparent paint for the purpose of protection when constructing a part outside the structure where weather resistance is required. A transparent colored paint can also be used as the transparent paint. If such a transparent coating material that can form a hydrophilic film is used, the stain resistance can be improved.
Moreover, in this invention, joint parts, such as a grid | lattice shape and a geometric pattern shape, can also be formed by using joint materials, such as a joint rod and a joint form. In this case, after applying the joint material to the base material that has been painted in the color tone that becomes the joint color, apply the intermediate coating material, etc., if necessary, and then perform the above steps, and then remove the joint material. That's fine.

以下に実施例を示し、本発明の特徴をより明確にする。   Examples are given below to clarify the features of the present invention.

(筋状模様形成用塗料)
筋状模様形成用塗料として、以下の塗料を用意した。
・透明着色塗料P
アクリル樹脂エマルション(固形分50重量%)350重量部、黄色顔料液(黄色酸化鉄50重量%分散液)0.6重量部、赤色顔料液(弁柄50重量%分散液)0.6重量部、黒色顔料液(カーボンブラック20重量%分散液)0.5重量部、水130重量部、造膜助剤16重量部、消泡剤2重量部を均一に混合することにより、透明着色塗料P(着色顔料濃度0.14重量%)を得た。
(Stripe pattern forming paint)
The following paints were prepared as the stripe pattern forming paints.
・ Transparent coloring paint P
350 parts by weight of acrylic resin emulsion (solid content: 50% by weight), 0.6 parts by weight of yellow pigment liquid (yellow iron oxide 50% by weight dispersion), 0.6 parts by weight of red pigment liquid (50% by weight dispersion of petal) A transparent coloring paint P is prepared by uniformly mixing 0.5 parts by weight of a black pigment liquid (carbon black 20% by weight dispersion), 130 parts by weight of water, 16 parts by weight of a film-forming aid, and 2 parts by weight of an antifoaming agent. (Colored pigment concentration 0.14% by weight) was obtained.

・透明着色塗料Q
アクリル樹脂エマルション(固形分50重量%)350重量部、白色顔料液(酸化チタン60重量%分散液)6重量部、黄色顔料液(黄色酸化鉄50重量%分散液)3重量部、黒色顔料液(カーボンブラック30重量%分散液)1重量部、水122重量部、造膜助剤16重量部、消泡剤2重量部を均一に混合することにより、透明着色塗料Q(着色顔料濃度1.1重量%)を得た。
・ Transparent coloring paint Q
350 parts by weight of acrylic resin emulsion (solid content 50% by weight), 6 parts by weight of white pigment liquid (60% by weight of titanium oxide dispersion), 3 parts by weight of yellow pigment liquid (50% by weight of yellow iron oxide dispersion), black pigment liquid By uniformly mixing 1 part by weight (carbon black 30% by weight dispersion), 122 parts by weight of water, 16 parts by weight of a film-forming aid, and 2 parts by weight of an antifoaming agent, the transparent colored paint Q (color pigment concentration 1. 1% by weight) was obtained.

・着色塗料R
アクリル樹脂エマルション(固形分50重量%)350重量部、黄色顔料液(黄色酸化鉄50重量%分散液)30重量部、赤色顔料液(弁柄50重量%分散液)30重量部、黒色顔料液(カーボンブラック20重量%分散液)25重量部、水47重量部、造膜助剤16重量部、消泡剤2重量部を均一に混合することにより、着色塗料R(着色顔料濃度7.0重量%)を得た。
・ Coloring paint R
350 parts by weight of acrylic resin emulsion (solid content 50% by weight), 30 parts by weight of yellow pigment liquid (dispersion of 50% by weight of yellow iron oxide), 30 parts by weight of red pigment liquid (dispersion of 50% by weight of dial), black pigment liquid By uniformly mixing 25 parts by weight (carbon black 20% by weight dispersion), 47 parts by weight of water, 16 parts by weight of a film-forming aid, and 2 parts by weight of an antifoaming agent, a colored paint R (color pigment concentration 7.0) % By weight).

(実施例1)
下塗面形成用塗料として、着色塗料A(アクリル樹脂、酸化チタン、脂肪族炭化水素系溶剤を主成分とする白色塗料、着色顔料濃度14重量%)と、着色塗料B(アクリル樹脂、黄色酸化鉄、酸化チタン、脂肪族炭化水素系溶剤を主成分とする淡黄色塗料、着色顔料濃度13重量%)と、着色塗料C(アクリル樹脂、酸化チタン、黒色酸化鉄、脂肪族炭化水素系溶剤を主成分とする淡灰色塗料、着色顔料濃度14重量%)を用意した。
予めシーラー(白色)が塗装されたスレート板に対し、着色塗料Aと着色塗料Bと着色塗料Cをそれぞれ塗付け量0.1kg/mにて粒状(約2〜4mm)に吹き付け塗装し、4時間乾燥した。
次に、ローラーを用いて、透明着色塗料Pによる筋状模様を形成させ、24時間乾燥した。ここで、ローラーとしては、プラスチック製の筒の表面に、紐状のスポンジ(長さ60〜200mm、幅2〜4mm)を複数貼り付けたものを使用した。
なお、塗装及び乾燥は、すべて標準状態(気温23℃、相対湿度50%)にて行った。下塗面形成用の各着色塗料(着色塗料A、着色塗料B、着色塗料C)と、透明着色塗料Pとの色差は、それぞれ18、12、11であった。
以上の方法により得られた模様面は、筋状模様に視覚的な強弱が付与された仕上りとなり、大理石調の美観性を有するものであった。
Example 1
As paint for forming the undercoat surface, colored paint A (acrylic resin, titanium oxide, white paint mainly containing aliphatic hydrocarbon solvent, colored pigment concentration 14% by weight) and colored paint B (acrylic resin, yellow iron oxide) , Light yellow paint mainly composed of titanium oxide and aliphatic hydrocarbon solvent, color pigment concentration 13% by weight) and color paint C (mainly acrylic resin, titanium oxide, black iron oxide, aliphatic hydrocarbon solvent) A light gray paint as a component and a color pigment concentration of 14% by weight were prepared.
The slate plate previously coated with a sealer (white) is sprayed in a granular form (about 2 to 4 mm) with a paint A, a paint B and a paint C at a coating amount of 0.1 kg / m 2 . Dried for 4 hours.
Next, the streak pattern by the transparent coloring paint P was formed using the roller, and it dried for 24 hours. Here, as a roller, what stuck a plurality of string-like sponges (length 60-200 mm, width 2-4 mm) on the surface of a plastic cylinder was used.
The coating and drying were all performed in standard conditions (temperature 23 ° C., relative humidity 50%). The color differences between the colored paints for forming the undercoat surface (colored paint A, colored paint B, colored paint C) and the transparent colored paint P were 18, 12, and 11, respectively.
The pattern surface obtained by the above method has a finish in which visual strength is given to the streaky pattern, and has a marble-like aesthetics.

(実施例2)
実施例1と同様の方法で、下塗面を形成した。
次に、スタンプを用いて、透明着色塗料Pによる筋状模様を形成させ、24時間乾燥した。ここで、スタンプとしては、把手付き合板の平坦面に、紐状のスポンジ(長さ40〜250mm、幅4〜6mm)を複数貼り付けたものを使用した。
以上の方法により得られた模様面は、実施例1と同様に、筋状模様に視覚的な強弱が付与された仕上りとなり、大理石調の美観性を有するものであった。
(Example 2)
An undercoat surface was formed in the same manner as in Example 1.
Next, the streak pattern by the transparent coloring paint P was formed using the stamp, and it dried for 24 hours. Here, as a stamp, what stuck a plurality of string-like sponges (length 40-250 mm, width 4-6 mm) on the flat surface of a plywood with a handle was used.
The pattern surface obtained by the above method had a finish in which visual strength was given to the streak pattern as in Example 1, and had a marble-like aesthetics.

(実施例3)
下塗面形成用塗料として、着色塗料D(アクリル樹脂、黒色酸化鉄、黄色酸化鉄、弁柄、酸化チタン、脂肪族炭化水素系溶剤を主成分とする黒色塗料、着色顔料濃度16重量%)と、着色塗料E(アクリル樹脂、黒色酸化鉄、酸化チタン、脂肪族炭化水素系溶剤を主成分とする灰色塗料、着色顔料濃度13重量%)と、着色塗料F(アクリル樹脂、弁柄、フタロシアニンブルー、酸化チタン、脂肪族炭化水素系溶剤を主成分とする灰紫色塗料、着色顔料濃度17重量%)を用意した。
予めシーラー(白色)が塗装されたスレート板に対し、着色塗料Dと着色塗料Eと着色塗料Fをそれぞれ塗付け量0.1kg/mにて粒状(約2〜4mm)に吹き付け塗装し、4時間乾燥した。
次に、実施例1と同様のローラーを用いて、透明着色塗料Qによる筋状模様を形成させ、24時間乾燥した。
なお、下塗面形成用の各着色塗料(着色塗料D、着色塗料E、着色塗料F)と、透明着色塗料Qとの色差は、それぞれ18、20、15であった。
以上の方法により得られた模様面は、筋状模様に視覚的な強弱が付与された仕上りとなり、大理石調の美観性を有するものであった。
(Example 3)
As a paint for forming the undercoat surface, a colored paint D (acrylic resin, black iron oxide, yellow iron oxide, petal, titanium oxide, black paint mainly containing an aliphatic hydrocarbon solvent, color pigment concentration 16% by weight) and , Colored paint E (Acrylic resin, Black iron oxide, Titanium oxide, Gray paint mainly composed of aliphatic hydrocarbon solvent, Color pigment concentration 13 wt%) and Colored paint F (Acrylic resin, petal, phthalocyanine blue , A gray-purple paint mainly composed of titanium oxide and an aliphatic hydrocarbon solvent, and a color pigment concentration of 17% by weight).
The slate plate previously coated with a sealer (white) is spray-coated with granular paint D, colored paint E and colored paint F at a coating amount of 0.1 kg / m 2 in a granular form (about 2 to 4 mm), Dried for 4 hours.
Next, the streak pattern by the transparent coloring paint Q was formed using the roller similar to Example 1, and it dried for 24 hours.
The color differences between the colored paints for forming the undercoat surface (colored paint D, colored paint E, colored paint F) and the transparent colored paint Q were 18, 20, and 15, respectively.
The pattern surface obtained by the above method has a finish in which visual strength is given to the streaky pattern, and has a marble-like aesthetics.

(実施例4)
下塗面形成用塗料として、着色塗料G(アクリル樹脂、酸化チタン、弁柄、脂肪族炭化水素系溶剤を主成分とする濃赤色塗料、着色顔料濃度23重量%)と、着色塗料H(アクリル樹脂、酸化チタン、弁柄、脂肪族炭化水素系溶剤を主成分とする淡赤色塗料、着色顔料濃度18重量%)を用意した。
予めシーラー(白色)が塗装されたスレート板に対し、着色塗料Gと着色塗料Hをそれぞれ塗付け量0.1kg/mにて粒状(約3〜5mm)に吹き付け塗装し、4時間乾燥した。
次に、実施例1と同様のローラーを用いて、透明着色塗料Qによる筋状模様を形成させ、24時間乾燥した。
なお、下塗面形成用の各着色塗料(着色塗料G、着色塗料H)と、透明着色塗料Qとの色差は、それぞれ26、29であった。
以上の方法により得られた模様面は、筋状模様に視覚的な強弱が付与された仕上りとなり、大理石調の美観性を有するものであった。
Example 4
As a paint for forming the undercoat surface, a colored paint G (acrylic resin, titanium oxide, dial, dark red paint mainly composed of aliphatic hydrocarbon solvent, colored pigment concentration 23% by weight) and colored paint H (acrylic resin) And a light red paint mainly composed of a titanium oxide, a petite, an aliphatic hydrocarbon solvent, and a color pigment concentration of 18% by weight).
Colored paint G and colored paint H were each sprayed in a granular form (about 3 to 5 mm) at a coating amount of 0.1 kg / m 2 on a slate plate previously coated with a sealer (white) and dried for 4 hours. .
Next, the streak pattern by the transparent coloring paint Q was formed using the roller similar to Example 1, and it dried for 24 hours.
The color differences between the colored paints for forming the undercoat surface (colored paint G and colored paint H) and the transparent colored paint Q were 26 and 29, respectively.
The pattern surface obtained by the above method has a finish in which visual strength is given to the streaky pattern, and has a marble-like aesthetics.

(実施例5)
下塗面形成用塗料として、着色塗料I(アクリル樹脂、酸化チタン、脂肪族炭化水素系溶剤を主成分とする透明白色塗料、着色顔料濃度0.6重量%)と、着色塗料J(アクリル樹脂、酸化チタン、脂肪族炭化水素系溶剤を主成分とする透明白色塗料、着色顔料濃度1.3重量%)を用意した。
予めシーラー(黒色)が塗装されたスレート板に対し、着色塗料Iと着色塗料Jをそれぞれ塗付け量0.1kg/mにて粒状(約1〜3mm)に吹き付け塗装し、4時間乾燥した。
次に、実施例1と同様のローラーを用いて、透明着色塗料Pによる筋状模様を形成させ、24時間乾燥した。
なお、下塗面形成用の各着色塗料(着色塗料I、着色塗料J)と、透明着色塗料Pとの色差は、それぞれ13、14であった。
以上の方法により得られた模様面は、筋状模様に視覚的な強弱が付与された仕上りとなり、大理石調の美観性を有するものであった。
(Example 5)
As the paint for forming the undercoat surface, colored paint I (transparent white paint mainly composed of acrylic resin, titanium oxide, aliphatic hydrocarbon solvent, colored pigment concentration 0.6% by weight) and colored paint J (acrylic resin, A transparent white paint mainly composed of titanium oxide and an aliphatic hydrocarbon solvent and a color pigment concentration of 1.3% by weight were prepared.
Colored paint I and colored paint J are each sprayed in a granular form (about 1 to 3 mm) at a coating amount of 0.1 kg / m 2 on a slate plate previously coated with a sealer (black) and dried for 4 hours. .
Next, the streaky pattern by the transparent coloring paint P was formed using the roller similar to Example 1, and it dried for 24 hours.
The color differences between the colored paints for forming the undercoat surface (colored paint I and colored paint J) and the transparent colored paint P were 13 and 14, respectively.
The pattern surface obtained by the above method has a finish in which visual strength is given to the streaky pattern, and has a marble-like aesthetics.

(比較例1)
予めシーラー(白色)が塗装されたスレート板に対し、透明着色塗料Pを用いてローラー塗装を行い、筋状模様を形成させ、24時間乾燥した。ここで、ローラーとしては、実施例1と同様のものを使用した。なお、塗装及び乾燥は、すべて標準状態にて行った。
以上の方法により得られた模様面は、変化に乏しい筋状模様であった。
(Comparative Example 1)
A slate plate previously coated with a sealer (white) was roller-coated with a transparent colored paint P to form a streak pattern and dried for 24 hours. Here, the same roller as in Example 1 was used. In addition, all painting and drying were performed in the standard state.
The pattern surface obtained by the above method was a streak pattern with little change.

(比較例2)
筋状模様形成用塗料として、透明着色塗料Pに代えて着色塗料Rを使用した。これ以外は、実施例1と同様の方法で塗装を行った。
以上の方法により得られた模様面は、変化に乏しい筋状模様であった。
(Comparative Example 2)
Instead of the transparent colored paint P, the colored paint R was used as the streaky pattern forming paint. Except this, it painted by the method similar to Example 1. FIG.
The pattern surface obtained by the above method was a streak pattern with little change.

Claims (2)

基材に対し、
(1)少なくとも1種以上の着色塗料を粒状に塗付して、着色粒状物が散在した下塗面を形成する工程、
(2)当該下塗面に対し、透明着色塗料を筋状に塗付して、筋状模様面を形成する工程、
を行うことを特徴とする模様面の形成方法。
For substrate
(1) A step of applying at least one or more kinds of colored paints in a granular form to form an undercoat surface in which colored granular materials are scattered,
(2) A step of applying a transparent colored paint in a streak pattern to the undercoat surface to form a streak pattern surface;
A method for forming a pattern surface, comprising:
筋状模様面を形成する工程において、
紐状の吸液部材を備えた回転具、及び/または紐状の吸液部材を備えた押圧具、
を用いて透明着色塗料を筋状に塗付する請求項1記載の模様面の形成方法。
In the process of forming the streaked pattern surface,
A rotating tool provided with a string-like liquid-absorbing member, and / or a pressing tool provided with a string-like liquid-absorbing member,
The method for forming a pattern surface according to claim 1, wherein the transparent coloring paint is applied in a streak pattern using the stencil.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012106206A (en) * 2010-11-19 2012-06-07 Bekku Kk Method for forming patterned surface
JP2012106204A (en) * 2010-11-19 2012-06-07 Bekku Kk Method for forming patterned surface
JP2019025474A (en) * 2017-08-01 2019-02-21 ベック株式会社 Formation method of decorative coating surface

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0226671A (en) * 1988-07-15 1990-01-29 Matsushita Electric Works Ltd Preparation of building panel
JPH04349974A (en) * 1991-05-28 1992-12-04 Matsushita Electric Works Ltd Patterning
JPH0999261A (en) * 1995-10-05 1997-04-15 Nippon Paint Co Ltd Roll coater and coating method using the coater
JP2000135471A (en) * 1998-11-02 2000-05-16 Yamamoto Yogyo Kako Kk Formation of decorative material and coating material used for the same
JP2004223324A (en) * 2003-01-20 2004-08-12 Tomitsu Hiroyuki Coating method and material
JP2012106206A (en) * 2010-11-19 2012-06-07 Bekku Kk Method for forming patterned surface
JP2012106204A (en) * 2010-11-19 2012-06-07 Bekku Kk Method for forming patterned surface
JP5232834B2 (en) * 2009-07-11 2013-07-10 ベック株式会社 Pattern surface formation method

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0226671A (en) * 1988-07-15 1990-01-29 Matsushita Electric Works Ltd Preparation of building panel
JPH04349974A (en) * 1991-05-28 1992-12-04 Matsushita Electric Works Ltd Patterning
JPH0999261A (en) * 1995-10-05 1997-04-15 Nippon Paint Co Ltd Roll coater and coating method using the coater
JP2000135471A (en) * 1998-11-02 2000-05-16 Yamamoto Yogyo Kako Kk Formation of decorative material and coating material used for the same
JP2004223324A (en) * 2003-01-20 2004-08-12 Tomitsu Hiroyuki Coating method and material
JP5232834B2 (en) * 2009-07-11 2013-07-10 ベック株式会社 Pattern surface formation method
JP2012106206A (en) * 2010-11-19 2012-06-07 Bekku Kk Method for forming patterned surface
JP2012106204A (en) * 2010-11-19 2012-06-07 Bekku Kk Method for forming patterned surface

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012106206A (en) * 2010-11-19 2012-06-07 Bekku Kk Method for forming patterned surface
JP2012106204A (en) * 2010-11-19 2012-06-07 Bekku Kk Method for forming patterned surface
JP2019025474A (en) * 2017-08-01 2019-02-21 ベック株式会社 Formation method of decorative coating surface
JP7064959B2 (en) 2017-08-01 2022-05-11 ベック株式会社 How to form a decorative coating surface
JP2022097564A (en) * 2017-08-01 2022-06-30 ベック株式会社 Formation method of ornament coated surface
JP7299376B2 (en) 2017-08-01 2023-06-27 ベック株式会社 Method for forming decorative film surface

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