JP2012072088A - Bathing agent composition - Google Patents
Bathing agent composition Download PDFInfo
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- JP2012072088A JP2012072088A JP2010218633A JP2010218633A JP2012072088A JP 2012072088 A JP2012072088 A JP 2012072088A JP 2010218633 A JP2010218633 A JP 2010218633A JP 2010218633 A JP2010218633 A JP 2010218633A JP 2012072088 A JP2012072088 A JP 2012072088A
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- Prior art keywords
- component
- bathing
- feeling
- agent composition
- zinc
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- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 238000003287 bathing Methods 0.000 title abstract description 52
- 150000003752 zinc compounds Chemical class 0.000 claims abstract description 22
- 229920001586 anionic polysaccharide Polymers 0.000 claims abstract description 12
- 150000004836 anionic polysaccharides Chemical class 0.000 claims abstract description 12
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 12
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000013040 bath agent Substances 0.000 claims description 24
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 12
- 239000000679 carrageenan Substances 0.000 claims description 10
- 235000010418 carrageenan Nutrition 0.000 claims description 10
- 229920001525 carrageenan Polymers 0.000 claims description 10
- 229940113118 carrageenan Drugs 0.000 claims description 10
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 10
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 9
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 9
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 9
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 9
- 239000001569 carbon dioxide Substances 0.000 claims description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 6
- 150000007524 organic acids Chemical class 0.000 claims description 5
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 4
- 239000000661 sodium alginate Substances 0.000 claims description 4
- 235000010413 sodium alginate Nutrition 0.000 claims description 4
- 229940005550 sodium alginate Drugs 0.000 claims description 4
- 229940105329 carboxymethylcellulose Drugs 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 9
- 239000011701 zinc Substances 0.000 description 9
- 229910052725 zinc Inorganic materials 0.000 description 9
- 239000003788 bath preparation Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 108091003079 Bovine Serum Albumin Proteins 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229940098773 bovine serum albumin Drugs 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000011670 zinc gluconate Substances 0.000 description 4
- 235000011478 zinc gluconate Nutrition 0.000 description 4
- 229960000306 zinc gluconate Drugs 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 235000005985 organic acids Nutrition 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 235000011087 fumaric acid Nutrition 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- -1 zinc sulfocolate Chemical class 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000004373 Pullulan Substances 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- CANRESZKMUPMAE-UHFFFAOYSA-L Zinc lactate Chemical compound [Zn+2].CC(O)C([O-])=O.CC(O)C([O-])=O CANRESZKMUPMAE-UHFFFAOYSA-L 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000004520 agglutination Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000004845 protein aggregation Effects 0.000 description 1
- 239000012460 protein solution Substances 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 description 1
- 230000024883 vasodilation Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011746 zinc citrate Substances 0.000 description 1
- 235000006076 zinc citrate Nutrition 0.000 description 1
- 229940068475 zinc citrate Drugs 0.000 description 1
- 239000011576 zinc lactate Substances 0.000 description 1
- 235000000193 zinc lactate Nutrition 0.000 description 1
- 229940050168 zinc lactate Drugs 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- VRGNUPCISFMPEM-ZVGUSBNCSA-L zinc;(2r,3r)-2,3-dihydroxybutanedioate Chemical compound [Zn+2].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O VRGNUPCISFMPEM-ZVGUSBNCSA-L 0.000 description 1
- AGFGXVAAIXIOFZ-UHFFFAOYSA-L zinc;butanedioate Chemical compound [Zn+2].[O-]C(=O)CCC([O-])=O AGFGXVAAIXIOFZ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、夏場の入浴に適した浴用剤組成物に関する。 The present invention relates to a bath agent composition suitable for bathing in summer.
入浴後、特に夏場の入浴後には、発汗を抑えてサッパリ感を得ることのできる浴用剤が望まれる。こうした中、入浴後のサッパリ感の持続性を改善した浴用剤組成物として、スルホ石炭酸亜鉛やグルコン酸亜鉛等の有機亜鉛化物を特定の量で配合したものが報告されている（特許文献１参照）。また、酸化亜鉛の粒径を特定することにより、優れた爽快感が付与された入浴剤も報告されている（特許文献２参照）。さらに、製造時においてはスティッキングを起こさず、また保存中においても崩壊しない圧縮成形型浴用剤を提供すべく、水溶性亜鉛化合物と特定の水溶性高分子とを特定量で配合した浴用剤も報告されている（特許文献３参照）。 After bathing, especially after bathing in summer, a bath preparation that can suppress sweating and provide a refreshing feeling is desired. Under these circumstances, as a bath agent composition that improves the sustainability of a refreshing feeling after bathing, a composition containing a specific amount of an organic zinc compound such as zinc sulfocolate or zinc gluconate has been reported (see Patent Document 1). ). Moreover, the bath agent to which the outstanding refreshing feeling was provided by specifying the particle size of zinc oxide is also reported (refer patent document 2). Furthermore, in order to provide a compression molding bath agent that does not cause sticking during production and does not disintegrate during storage, a bath agent containing a specific amount of a water-soluble zinc compound and a specific water-soluble polymer is also reported. (See Patent Document 3).
しかしながら、近年の夏場における激しい気温上昇等に伴い、こうしたサッパリ感にもさらに高い効果を発揮し得る浴用剤が強く求められている。また、上記いずれの浴用剤も入浴中の肌感触については何ら検討されておらず、優れたサッパリ感と入浴中の良好な肌感触とを共にもたらす浴用剤については検討の余地があった。 However, with the rapid increase in temperature in summer in recent years, there is a strong demand for bath preparations that can exert even higher effects on such a refreshing feeling. In addition, none of the above bath preparations has been studied for the skin feel during bathing, and there is room for investigation regarding bath preparations that provide both an excellent refreshing feeling and a good skin feel during bathing.
従って、本発明の課題は、入浴後のサッパリ感を著しく向上させるとともに、入浴中に極めて良好な肌のしっとり感を生じさせる浴用剤組成物を提供することにある。なお、本発明における「入浴中の肌のしっとり感」とは、入浴中に滑らかな肌感触が生じることをいう。 Accordingly, an object of the present invention is to provide a bath agent composition that remarkably improves the refreshing feeling after bathing and produces an extremely good skin moist feeling during bathing. The “moist skin feeling during bathing” in the present invention means that a smooth skin feel occurs during bathing.
本発明者は、入浴後のサッパリ感、すなわち収斂作用について鋭意検討を行っていたところ、亜鉛化合物と、硫酸基もしくはカルボキシル基を有するアニオン性の多糖類とを特定の比で含有する浴用剤組成物であれば、入浴後におけるサッパリ感が飛躍的に向上する上に、入浴中には、極めて良好な肌のしっとり感を生じさせることを見出した。 The inventor has been diligently studying the refreshing feeling after bathing, that is, the astringent action. The bath composition contains a zinc compound and an anionic polysaccharide having a sulfate group or a carboxyl group in a specific ratio. If it is a thing, it found out that the refreshing feeling after bathing improved remarkably, and the very moist feeling of skin was produced during bathing.
すなわち、本発明は、次の成分（Ａ）及び（Ｂ）：
（Ａ）亜鉛化合物
（Ｂ）硫酸基もしくはカルボキシル基を有するアニオン性の多糖類
を含有し、かつ成分（Ａ）の含有量に対する成分（Ｂ）の含有量が、質量比で０．１０〜０．９８である浴用剤組成物を提供するものである。
That is, the present invention includes the following components (A) and (B):
(A) Zinc compound (B) An anionic polysaccharide having a sulfate group or a carboxyl group, and the content of component (B) relative to the content of component (A) is 0.10 to 0 by mass ratio A bath composition that is .98 is provided.
上記成分（Ｂ）の硫酸基もしくはカルボキシル基を有するアニオン性の多糖類である、カラギーナンやカルボキシメチルセルロース等は、結合剤等の用途で浴用剤に添加されることはあるものの、上記のような入浴後のサッパリ感を奏するものではないため、これらの多糖類と亜鉛化合物とを特定の比で組み合わせることにより、入浴後のサッパリ感が飛躍的に向上する効果が奏されるのは予想外のことである。 The above component (B) anionic polysaccharide having a sulfate group or carboxyl group, such as carrageenan or carboxymethyl cellulose, may be added to the bath agent for use as a binder, but the bath as described above. Since it does not give a refreshing feeling afterwards, it is unexpected that combining these polysaccharides and zinc compounds in a specific ratio has the effect of dramatically improving the refreshing feeling after bathing. It is.
本発明の浴用剤組成物は、入浴中に極めて良好な肌のしっとり感を生じさせるとともに、入浴後のサッパリ感を著しく向上させるものである。 The bath agent composition of the present invention produces a very moist skin feeling during bathing and significantly improves the refreshing feeling after bathing.
以下、本発明について詳細に説明する。
本発明の浴用剤組成物における成分（Ａ）亜鉛化合物としては、例えば、炭酸亜鉛、リン酸亜鉛、硫酸亜鉛、塩化亜鉛等の無機酸の亜鉛化合物；クエン酸亜鉛、酒石酸亜鉛、コハク酸亜鉛、スルホ石炭酸亜鉛、乳酸亜鉛、グルコン酸亜鉛等の有機酸の亜鉛化合物；酸化亜鉛等が挙げられる。これらは１種単独で用いてもよく、２種以上組み合わせて用いてもよい。中でも、入浴後のサッパリ感及び後述する成分（Ｂ）との併用により入浴中の肌のしっとり感が良好な点から、有機酸の亜鉛化合物が好ましく、特にグルコン酸亜鉛、スルホ石炭酸亜鉛がより好ましく、スルホ石炭酸亜鉛が最も好ましい。
Hereinafter, the present invention will be described in detail.
Examples of the component (A) zinc compound in the bath agent composition of the present invention include zinc compounds of inorganic acids such as zinc carbonate, zinc phosphate, zinc sulfate, zinc chloride; zinc citrate, zinc tartrate, zinc succinate, Examples include zinc compounds of organic acids such as zinc sulfocolate, zinc lactate, and zinc gluconate; zinc oxide and the like. These may be used alone or in combination of two or more. Among them, a zinc compound of an organic acid is preferable, and zinc gluconate and zinc sulfococolate are more preferable, because the refreshing feeling after bathing and the moist feeling of the skin during bathing are favorable due to the combined use with the component (B) described later. Zinc sulfocoborate is most preferred.
本発明の浴用剤組成物１００質量％中、成分（Ａ）亜鉛化合物の含有量は、入浴後のサッパリ感及び後述する成分（Ｂ）との併用による入浴中の肌のしっとり感が良好な点から、好ましくは０．０５〜３．０質量％、より好ましくは０．１〜２．５質量％、最も好ましくは０．２〜２．０質量％である。成分（Ａ）の含有量が上記範囲内であると、入浴後の身体にとって極めて心地良いサッパリ感が奏されるとともに、後述する成分（Ｂ）との併用により入浴中の肌感触が変化してより良好なしっとり感が奏されるため好ましい。 In 100% by mass of the bath agent composition of the present invention, the content of the component (A) zinc compound is good for the refreshing feeling after bathing and the moist feeling of the skin during bathing in combination with the component (B) described later. Therefore, it is preferably 0.05 to 3.0% by mass, more preferably 0.1 to 2.5% by mass, and most preferably 0.2 to 2.0% by mass. When the content of the component (A) is within the above range, a refreshing feeling that is extremely comfortable for the body after bathing is produced, and the skin feel during bathing is changed by the combined use with the component (B) described later. This is preferable because a better moist feeling is exhibited.
また、入浴時の本発明組成物の１回の使用量は、浴湯中の亜鉛化合物の濃度が０．１〜８ｐｐｍとなる量とするのが好ましい。 Moreover, it is preferable that the usage-amount of this invention composition at the time of bathing shall be the quantity from which the density | concentration of the zinc compound in bath water will be 0.1-8 ppm.
本発明の浴用剤組成物における成分（Ｂ）硫酸基もしくはカルボキシル基を有するアニオン性の多糖類の種類は、入浴中の肌のしっとり感及び入浴後のサッパリ感が良好な点から、カルボキシメチルセルロース、カラギーナン、アルギン酸ナトリウムが好ましい。これらは１種単独で用いてもよく、２種以上組み合わせて用いてもよい。中でも、成分（Ａ）と相まって入浴後のサッパリ感をより向上させ得る点から、特にカルボキシメチルセルロース、カラギーナンが好ましい。 The component (B) of the anionic polysaccharide having a sulfate group or a carboxyl group in the bath agent composition of the present invention has a good feeling of moist skin during bathing and a refreshing feeling after bathing. Carrageenan and sodium alginate are preferred. These may be used alone or in combination of two or more. Among these, carboxymethyl cellulose and carrageenan are particularly preferable from the viewpoint that the refreshing feeling after bathing can be further improved in combination with the component (A).
本発明の浴用剤組成物１００質量％中、成分（Ｂ）の含有量は、入浴中の肌のしっとり感及び入浴後のサッパリ感が良好な点から、好ましくは０．０１〜３．０質量％であり、より好ましくは０．０１５〜２．５質量％であり、更に好ましくは０．０２〜２．０質量％であり、殊更好ましくは０．０２５〜０．９質量％であり、最も好ましくは０．０３〜０．４質量％である。成分（Ｂ）の含有量が上記範囲内であると、入浴中により良好なしっとり感が奏されるとともに、入浴後の身体にとって極めて心地よいサッパリ感が奏されるため好ましい。 The content of the component (B) in 100% by mass of the bath agent composition of the present invention is preferably 0.01 to 3.0% by mass because the moist feeling of the skin during bathing and the refreshing feeling after bathing are good. %, More preferably 0.015 to 2.5% by mass, still more preferably 0.02 to 2.0% by mass, even more preferably 0.025 to 0.9% by mass, Preferably it is 0.03-0.4 mass%. It is preferable that the content of the component (B) is within the above range because a good moist feeling is exhibited during bathing and a refreshing feeling that is extremely comfortable for the body after bathing.
本発明の浴用剤組成物における成分（Ａ）亜鉛化合物の含有量に対する、成分（Ｂ）硫酸基もしくはカルボキシル基を有するアニオン性の多糖類の含有量の質量比は、入浴中の肌のしっとり感および入浴後のサッパリ感がより良好な点から、０．１０〜０．９８である。さらに０．１５〜０．７０が好ましく、中でも０．２０〜０．６０、特に０．３０〜０．５０が特に好ましい。このような比率で成分（Ａ）と成分（Ｂ）とを含有させた浴用剤組成物であれば、入浴中に極めて良好な肌のしっとり感が生じ、なおかつ、成分（Ａ）と成分（Ｂ）とが相まって入浴後のサッパリ感が飛躍的に向上することとなる。 The mass ratio of the content of the anionic polysaccharide having a sulfate group or a carboxyl group to the content of the component (A) zinc compound in the bath agent composition of the present invention is the moist feeling of the skin during bathing. And from the point that the refreshing feeling after bathing is better, it is 0.10 to 0.98. Furthermore, 0.15 to 0.70 is preferable, and 0.20 to 0.60, particularly 0.30 to 0.50 is particularly preferable. If it is a bath agent composition containing the component (A) and the component (B) at such a ratio, a very good skin moist feeling is produced during bathing, and the component (A) and the component (B) ) And the refreshing feeling after bathing will dramatically improve.
本発明の浴用剤組成物には、さらに成分（Ｃ）炭酸ガス発生物を含有させてもよい。炭酸ガス発生物を含有させると、血管拡張による入浴後の熱放散が加わり、入浴後のサッパリ感の持続効果がもたらされるため好ましい。炭酸ガス発生物は、浴用剤組成物を浴湯に投入したときに炭酸ガスを発生させるものであり、酸と炭酸塩とを組み合わせたものが好ましい。酸としては、有機酸及び無機酸の何れでも使用できるが、水溶性で固体のものが好ましく、中でも、例えばコハク酸、フマル酸、リンゴ酸、アジピン酸、酒石酸、安息香酸、クエン酸、ピロリドンカルボン酸、サリチル酸などの有機酸が特に好ましい。無機酸としてはホウ酸、メタケイ酸、無水ケイ酸等が挙げられる。また炭酸塩としては、炭酸ナトリウム、炭酸水素ナトリウム、炭酸カリウムなどが好ましい。これらの酸及び炭酸塩は、それぞれから選ばれる１種又は２種以上を混合して用いることができる。 The bath agent composition of the present invention may further contain a component (C) a carbon dioxide gas generator. It is preferable to contain a carbon dioxide gas generator since heat dissipation after bathing due to vasodilation is added, and a refreshing feeling after bathing is brought about. The carbon dioxide generator is one that generates carbon dioxide when the bath agent composition is poured into bath water, and is preferably a combination of an acid and a carbonate. As the acid, any of organic acids and inorganic acids can be used, but those which are water-soluble and solid are preferable. Among them, for example, succinic acid, fumaric acid, malic acid, adipic acid, tartaric acid, benzoic acid, citric acid, pyrrolidonecarboxylic acid. Particularly preferred are organic acids such as acids and salicylic acid. Examples of inorganic acids include boric acid, metasilicic acid, and silicic anhydride. Moreover, as carbonate, sodium carbonate, sodium hydrogencarbonate, potassium carbonate, etc. are preferable. These acids and carbonates can be used alone or in combination of two or more.
本発明の浴用剤組成物中における成分（Ｃ）炭酸ガス発生物の含有量について、入浴後のサッパリ感の持続効果の点から、より好ましい酸の含有量は、本発明の浴用剤組成物１００質量％中、１０〜８０質量％であり、特に好ましくは１５〜５０質量％であり、殊更好ましくは２０〜４９質量％である。また、より好ましい炭酸塩の含有量は、５〜８０質量％、特に好ましくは１０〜５０質量％であり、殊更好ましくは１５〜４９質量％である。 About content of the component (C) carbon dioxide generation product in the bath agent composition of this invention, from the point of the sustained effect of the refreshing feeling after bathing, content of a more preferable acid is the bath agent composition 100 of this invention. In the mass%, it is 10-80 mass%, Most preferably, it is 15-50 mass%, Most preferably, it is 20-49 mass%. Further, the carbonate content is more preferably 5 to 80% by mass, particularly preferably 10 to 50% by mass, and still more preferably 15 to 49% by mass.
さらに、本発明の浴用剤組成物中には上記以外の成分、例えば酸化マグネシウム、ケイ酸カルシウム、メタリン酸ナトリウム、塩化ナトリウム、塩化カルシウム、塩化マグネシウム等の無機塩類；トレハロース、エリスリトール、乳糖、還元水飴、ブドウ糖等の成分（Ｂ）以外の糖類；生薬類；油脂類；アルコール類；多価アルコール類；界面活性剤；香料；色素；保湿剤；冷感剤等を、本発明に影響を与えない範囲で適宜添加してもよい。 Furthermore, in the bath agent composition of the present invention, components other than the above, for example, inorganic salts such as magnesium oxide, calcium silicate, sodium metaphosphate, sodium chloride, calcium chloride, magnesium chloride; trehalose, erythritol, lactose, reduced starch syrup , Sugars other than component (B) such as glucose; crude drugs; oils and fats; alcohols; polyhydric alcohols; surfactants; fragrances; pigments; moisturizers; You may add suitably in the range.
本発明の浴用剤組成物は、成分（Ａ）亜鉛化合物に成分（Ｂ）硫酸基もしくはカルボキシル基を有するアニオン性の多糖類、必要により成分（Ｃ）等の前記任意成分を加え、常法によって混合することにより調製される。また、剤型としては、粉末、顆粒、錠剤等が挙げられる。なお、これらの剤型に通常使用されている賦形剤、滑沢剤等を添加することができる。 In the bath agent composition of the present invention, the component (A) zinc compound is added to the component (B) an anionic polysaccharide having a sulfate group or a carboxyl group, and if necessary, the above optional components such as the component (C), and the conventional method is used. Prepared by mixing. Examples of the dosage form include powder, granules, tablets and the like. In addition, excipients, lubricants and the like that are usually used in these dosage forms can be added.
以下、本発明について、実施例に基づき具体的に説明するが、本発明はこれら実施例に限定されるものではない。 EXAMPLES Hereinafter, although this invention is demonstrated concretely based on an Example, this invention is not limited to these Examples.
[参考試験１]
《収斂作用の評価方法》
収斂作用の評価については、J. Agric. Food Chem., 1998, 46, 2590-2595に記載の方法を一部改変して実施した。
[Reference Test 1]
<Evaluation method of convergence effect>
The astringent action was evaluated by partially modifying the method described in J. Agric. Food Chem., 1998, 46, 2590-2595.
すなわち、１％牛血清アルブミン（ＢＳＡ）溶液に図１及び２に示す各サンプルをそれぞれ添加し、混合後、３８℃、２０分間インキュベートした後に吸光度（ＯＤ５５０：TECAN Austria GmbH 製の SUNRISE RAINBOW THERMO にて光路長６ｍｍ、波長５５０ｎｍ、９６穴型プレートを用いた測定時の濁度）を測定し、吸光度（ＯＤ５５０）の数値の大きさを収斂作用（サッパリ感）の指標として評価した。結果を図１〜２に示す。 Specifically, each sample shown in FIGS. 1 and 2 was added to a 1% bovine serum albumin (BSA) solution, mixed, incubated at 38 ° C. for 20 minutes, and then absorbance (OD550: SUNRISE RAINBOW THERMO manufactured by TECAN Austria GmbH). The turbidity at the time of measurement using an optical path length of 6 mm, a wavelength of 550 nm, and a 96-well plate was measured, and the numerical value of the absorbance (OD550) was evaluated as an index of the convergence effect (smooth feeling). The results are shown in FIGS.
なお、この評価方法は、下記のとおりタンパク質凝集度（濁度）を指標にして収斂作用の度合いが評価できることに基づくものである。
１）亜鉛化合物は、タンパク（ここではＢＳＡ：牛血清アルブミン）と混合するとタンパク質と亜鉛化合物が結合する結果、凝集反応を起こし、タンパク溶液は白濁する。
２）収斂作用が高いと凝集の程度が高くなるため、溶液の濁度も高くなる。
３）他方、収斂作用が低いと凝集の程度は低くなるため、濁度も低くなる。
This evaluation method is based on the fact that the degree of convergence can be evaluated using protein aggregation (turbidity) as an index as described below.
1) When a zinc compound is mixed with a protein (here, BSA: bovine serum albumin), the protein and the zinc compound bind to each other, thereby causing an agglutination reaction, and the protein solution becomes cloudy.
2) Since the degree of agglomeration is high when the astringent action is high, the turbidity of the solution is also high.
3) On the other hand, if the astringent action is low, the degree of agglomeration is low, and the turbidity is also low.
図１より、カルボキシメチルセルロース、カラギーナン、アルギン酸ナトリウム単独では収斂作用（サッパリ感）が認められないことがわかる。しかし、スルホ石炭酸亜鉛とこれらカルボキシメチルセルロース、カラギーナンやアルギン酸ナトリウムとを組み合わせると、スルホ石炭酸亜鉛の収斂作用（サッパリ感）が飛躍的に増強されることがわかる。これに対し、炭酸ナトリウム、フマル酸、ヒドロキシエチルセルロース、プルランをスルホ石炭酸亜鉛と組み合わせても、スルホ石炭酸亜鉛の収斂作用（サッパリ感）は増強されないことがわかる。 From FIG. 1, it can be seen that carboxymethylcellulose, carrageenan, and sodium alginate alone do not show an astringent action (a refreshing feeling). However, it can be seen that the combination of zinc sulfocolate with these carboxymethylcellulose, carrageenan and sodium alginate dramatically enhances the astringent action (smooth feeling) of zinc sulfocolate. On the other hand, it can be seen that even when sodium carbonate, fumaric acid, hydroxyethyl cellulose, and pullulan are combined with zinc sulfocolate, the astringent action (smooth feeling) of zinc sulfocolate is not enhanced.
また図２より、グルコン酸亜鉛にカルボキシメチルセルロースやカラギーナンを組み合わせた場合も、収斂作用（サッパリ感）が飛躍的に増強されることがわかる。これに対し、アルミニウム化合物であるミョウバンにカルボキシメチルセルロースやカラギーナンを組み合わせても、収斂作用（サッパリ感）は増強されないことがわかる。 In addition, it can be seen from FIG. 2 that, when carboxymethyl cellulose or carrageenan is combined with zinc gluconate, the astringent action (smooth feeling) is remarkably enhanced. On the other hand, it can be seen that even when carboxymethylcellulose or carrageenan is combined with alum, which is an aluminum compound, the astringent action (feeling of refreshing) is not enhanced.
[実施例１〜６、比較例１〜３]
表１〜２に示す処方に基づいて混合することにより調製した入浴剤（１回の使用量５０ｇ）を用い、専門パネラー５人に１５０〜２００Ｌのお湯（３８〜４０℃）に入浴剤を溶解後、入浴させ、入浴中の肌のしっとり感、入浴後のサッパリ感を下記に示す基準にて評価を行い、スコアの平均値を算出し比較した。結果を表１〜２に示す。
[Examples 1-6, Comparative Examples 1-3]
Using a bath preparation prepared by mixing based on the prescriptions shown in Tables 1-2 (one use amount of 50 g), dissolve the bath preparation in 150 to 200 L of hot water (38 to 40 ° C.) for five professional panelists. Thereafter, bathing was performed, and the moist feeling of the skin during bathing and the refreshing feeling after bathing were evaluated according to the following criteria, and the average values of the scores were calculated and compared. The results are shown in Tables 1-2.
《入浴中の肌のしっとり感》
５：非常にしっとりする
４：しっとりする
３：ややしっとりする
２：どちらでもない
１：しっとりしない
"Moist skin feeling during bathing"
5: Very moist 4: Moist 3: Moist 2: 2: Neither 1: Moist
《入浴後（０〜５分）の肌のサッパリ感》
５：非常に良好にサッパリする。
４：良好にサッパリする
３：ややサッパリする
２：サッパリしない
１：べたべたする
<Skin refreshing after bathing (0-5 minutes)>
5: Very good refreshing.
4: Good refreshing 3: Slightly refreshing 2: Not refreshing 1: Sticky
表１〜２より明らかなように、亜鉛化合物にカルボキシメチルセルロース、カラギーナンなどの硫酸基やカルボキシル基を有するアニオン性の多糖類を特定量ずつ組み合わせることにより、入浴後のサッパリ感、入浴中の肌のしっとり感が十分に認知されることがわかる。また、当該評価の結果は、前記参考試験１における結果と正の相関性を示した。 As is clear from Tables 1 and 2, by combining specific amounts of zinc compounds with anionic polysaccharides having sulfate groups or carboxyl groups such as carboxymethyl cellulose and carrageenan, the refreshing feeling after bathing, the skin feeling during bathing It can be seen that the moist feeling is fully recognized. Moreover, the result of the said evaluation showed a positive correlation with the result in the reference test 1.
[実施例７〜８]
表３〜４に示す処方に従って、各入浴剤を得た。これら入浴剤を１５０〜２００Ｌのお湯（３８〜４０℃）に溶解して入浴したところ、入浴中の肌のしっとり感及び入浴後のサッパリ感が十分に認知された。
[Examples 7 to 8]
Each bath agent was obtained according to the formulation shown in Tables 3-4. When these bathing agents were dissolved in 150 to 200 L of hot water (38 to 40 ° C.) and bathed, the moist feeling of the skin during bathing and the refreshing feeling after bathing were sufficiently recognized.
Claims (6)
（Ａ）亜鉛化合物
（Ｂ）硫酸基もしくはカルボキシル基を有するアニオン性の多糖類
を含有し、かつ成分（Ａ）の含有量に対する成分（Ｂ）の含有量が、質量比で０．１０〜０．９８である浴用剤組成物。 The following components (A) and (B):
(A) Zinc compound (B) An anionic polysaccharide having a sulfate group or a carboxyl group is contained, and the content of the component (B) with respect to the content of the component (A) is 0.10 to 0 by mass ratio. A bath composition which is .98.
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Cited By (2)
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| JP2015113321A (en) * | 2013-12-13 | 2015-06-22 | 花王株式会社 | Bathing agent composition |
| JP2020534248A (en) * | 2017-07-17 | 2020-11-26 | コスメティック ウォリアーズ エルティーディーＣｏｓｍｅｔｉｃ Ｗａｒｒｉｏｒｓ Ｌｔｄ | Composition |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2015113321A (en) * | 2013-12-13 | 2015-06-22 | 花王株式会社 | Bathing agent composition |
| JP2020534248A (en) * | 2017-07-17 | 2020-11-26 | コスメティック ウォリアーズ エルティーディーＣｏｓｍｅｔｉｃ Ｗａｒｒｉｏｒｓ Ｌｔｄ | Composition |
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| JP5679752B2 (en) | 2015-03-04 |
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