JP2012067506A - Water section member - Google Patents

Water section member Download PDF

Info

Publication number
JP2012067506A
JP2012067506A JP2010213141A JP2010213141A JP2012067506A JP 2012067506 A JP2012067506 A JP 2012067506A JP 2010213141 A JP2010213141 A JP 2010213141A JP 2010213141 A JP2010213141 A JP 2010213141A JP 2012067506 A JP2012067506 A JP 2012067506A
Authority
JP
Japan
Prior art keywords
area ratio
area
large protrusion
degrees
protrusions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2010213141A
Other languages
Japanese (ja)
Other versions
JP5609486B2 (en
Inventor
Yasuhiro Sumita
安弘 住田
Akira Kojima
啓 小嶋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Corp
Original Assignee
Panasonic Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Panasonic Corp filed Critical Panasonic Corp
Priority to JP2010213141A priority Critical patent/JP5609486B2/en
Publication of JP2012067506A publication Critical patent/JP2012067506A/en
Application granted granted Critical
Publication of JP5609486B2 publication Critical patent/JP5609486B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Sink And Installation For Waste Water (AREA)
  • Bathtubs, Showers, And Their Attachments (AREA)
  • Floor Finish (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a water section member which has drainage performance and drying performance, with satisfiable stain proof properties and gloss.SOLUTION: A water section member is made from a material of which mirror surface has a contact angle of 75 degrees to less than 90 degrees. On a surface of the material, irregularities having an average irregularity spacing Sm of 20 to 500 μm and a ten-point average roughness Rz of 8 to 70 μm are formed. Protrusions of the irregularities are defined as large projections. Small projections are formed on the surface of the large projections such that the ratio of the surface area to the plan view area of a measured place is 1.0 to 1.6 at a recess of the large projections and 1.6 to 2.4 at a protrusion, when arbitrary 10 places in a 5 μm square measurement area of the large projection surface are measured with a laser microscope having a set resolution of 0.044 μm in length-width (X-Y) directions and a set resolution of 0.01 μm in height (Z) direction. Recesses of the large projections have an area ratio of 20 to 40% of the total.

Description

本発明は、水廻り部材に関するものである。   The present invention relates to a watering member.

浴室の床パンや浴槽等に用いる水廻り部材は、ＦＲＰ（繊維強化プラスチック）のような親水性が低い材料により形成されている。ここで、「親水性が低い材料」とは、水の接触角が大きい材料である。このように親水性が低い材料の表面上を水が流れて排水される場合、水が表面上で薄膜状に広がらないため連続して流れず、水滴が所々に残り易くなって排水性が悪く、これは、水廻り部材の表面に排水用の溝を設けるのみでは解決できなかった。また、表面に残った水は水滴状に盛り上がって表面積が小さいために乾燥するのに時間がかかり、乾燥性が悪いものであった。このため、例えば浴室の出入口や排水口付近の床がいつまでも乾燥しにくく、滑りやすかったり、カビを生じたりしていた。   A watering member used for a bathroom floor pan, a bathtub, or the like is formed of a material having low hydrophilicity such as FRP (fiber reinforced plastic). Here, the “material having low hydrophilicity” is a material having a large water contact angle. When water flows on the surface of a material having low hydrophilicity in this way, the water does not spread in a thin film on the surface, so it does not flow continuously, and water drops tend to remain in places, resulting in poor drainage. This could not be solved only by providing a drainage groove on the surface of the water circulating member. Moreover, since the water remaining on the surface swells in the form of water droplets and has a small surface area, it takes time to dry, and the drying property is poor. For this reason, for example, the floor near the entrance / exit of the bathroom and the drainage outlet has been difficult to dry forever, and is slippery and moldy.

水廻り部材の排水性及び乾燥性の向上を図って、浴室の床パンや浴槽底面等の水廻り部材表面に親水性を付与することが試みられてきた。例えば、水廻り部材成形用の金型の表面に小突起（微細凹凸）を設けることによって水廻り部材表面に小突起（微細凹凸）を形成し、親水性を付与することが行われている。   Attempts have been made to impart hydrophilicity to the surfaces of water-circulating members such as bathroom floor pans and bathtub bottoms in order to improve drainage and drying properties of the water-circulating members. For example, by providing small protrusions (fine irregularities) on the surface of a mold for molding a water-borne member, small protrusions (fine irregularities) are formed on the surface of the water-circulating member to impart hydrophilicity.

しかし、このように金型表面に小突起（微細凹凸）を設けて生産を繰り返すと、金型表面に磨耗が生じやすく、製品に光沢ムラが発生するという問題があった。   However, when the production is repeated by providing small protrusions (fine irregularities) on the mold surface in this way, there is a problem that the mold surface is easily worn and gloss unevenness occurs in the product.

このような問題点を解決すべく、特許文献１等に記載された水廻り部材が提案されているが、防汚性や光沢性が不十分であり、まだ満足できるものではなかった。   In order to solve such a problem, a watering member described in Patent Document 1 and the like has been proposed, but the antifouling property and glossiness are insufficient, and it is not yet satisfactory.

特開２００７−１５４４９１号公報JP 2007-154491 A

本発明は、上記問題点に鑑み、水廻り部材表面に小突起（微細凹凸）が全面になくても親水性を有して排水性・乾燥性を確保でき、防汚性、光沢性をも満足する水廻り部材を提供することを、解決すべき課題とする。   In view of the above problems, the present invention has hydrophilicity to ensure drainage and drying properties even when there are no small protrusions (fine irregularities) on the surface of the water-circulating member, and has antifouling properties and glossiness. Providing a satisfactory watering member is a problem to be solved.

上記課題を解決するための請求項１の発明は、鏡面における水の接触角が７５度以上９０度未満の材料の表面を凹凸の平均間隔Ｓｍが２０乃至５００μｍとなると共に十点平均粗さＲｚが８乃至７０μｍとなる凹凸を形成してその凸部を大突起とし、前記大突起の表面に、該表面の５μｍ四方の測定範囲の任意の１０箇所をレーザー顕微鏡で横縦（Ｘ−Ｙ）方向の分解能を０．０４４μｍ及び高さ（Ｚ）方向の分解能を０．０１μｍに設定して測定した時に測定箇所の平面視の面積に対する表面積の比が大突起の凹部で１．０以上１．６以下、凸部で１．６以上２．４以下となる小突起を形成して成り、大突起の凹部の面積比率は全体の２０〜４０％であることを特徴とする水廻り部材である。   The invention of claim 1 for solving the above problem is that the surface of the material having a water contact angle of 75 degrees or more and less than 90 degrees on the mirror surface has an average spacing Sm of 20 to 500 μm and a ten-point average roughness Rz. Is formed into a large protrusion, and the surface of the large protrusion is arranged in a horizontal and vertical direction (XY) on the surface of the large protrusion by using a laser microscope at any 10 points within a 5 μm square measurement range. When the resolution in the direction is set to 0.044 μm and the resolution in the height (Z) direction is set to 0.01 μm, the ratio of the surface area to the area in plan view of the measurement location is 1.0 or more in the concave portion of the large protrusion. 6 or less, formed by forming small projections having a convex portion of 1.6 or more and 2.4 or less, and the area ratio of the concave portion of the large projection is 20 to 40% of the whole water-surrounding member .

本発明により、排水性・乾燥性、防汚性、光沢性に優れた水廻り部材を提供することができる。また、生産途上での金型シボ面の光沢ムラが発生し難くなる。   According to the present invention, it is possible to provide a watering member excellent in drainage / drying property, antifouling property, and glossiness. In addition, uneven glossiness on the surface of mold dies during production is less likely to occur.

浴室の床パンにおいて、出入口、排水口付近に本発明の水廻り部材を用いれば、足を滑らせることやカビの発生を防止でき、好適である。   In a bathroom floor pan, the use of the water-circulating member of the present invention in the vicinity of the doorway and the drainage port is preferable because it can prevent the foot from slipping and the generation of mold.

実施例、比較例における表面形状の説明図である。It is explanatory drawing of the surface shape in an Example and a comparative example.

以下、本発明の実施形態について図面に基づいて説明する。本発明の水廻り部材は、浴室の床パンや浴槽の底面等、排水性が求められる部分に用いられるもので、ＦＲＰのように鏡面における水の接触角が７５度以上９０度未満の親水性が低い材料で形成される。水の接触角の計測は、上方を向く鏡面に滴下させた水滴を側方から観察してその角度を計測することで行う。   Hereinafter, embodiments of the present invention will be described with reference to the drawings. The watering member of the present invention is used in parts where drainage is required, such as a floor pan of a bathroom or the bottom of a bathtub, and has a water contact angle of 75 degrees or more and less than 90 degrees on a mirror surface like FRP. Is formed of a low material. The contact angle of water is measured by observing a water droplet dropped on a mirror surface facing upward and measuring the angle.

材料の表面に、まず、大突起を、表面粗さ計による表面粗さ計測にて平均間隔Ｓｍが２０乃至５００μｍとなると共に十点平均粗さＲｚが８乃至７０μｍとなるように形成する。且つ、前記大突起の表面に、５μｍ四方を測定範囲とし、この測定範囲の任意の１０箇所をレーザー顕微鏡で、横縦（Ｘ−Ｙ）方向の分解能を０．０４４μｍとすると共に高さ（Ｚ）方向の分解能を０．０１μｍになるように設定して測定した時に、測定箇所の平面視の面積Ｓ1に対する表面積Ｓ2の比Ｒ（＝Ｓ2／Ｓ1）が１．０≦Ｒ≦２．４となるように小突起を形成する。 First, large protrusions are formed on the surface of the material so that the average interval Sm is 20 to 500 μm and the ten-point average roughness Rz is 8 to 70 μm by surface roughness measurement with a surface roughness meter. Further, on the surface of the large protrusion, 5 μm square is set as a measurement range, and any 10 points in the measurement range are measured with a laser microscope, the resolution in the horizontal and vertical (XY) directions is set to 0.044 μm, and the height (Z ) When the resolution in the direction is set to 0.01 μm, the ratio R (= S 2 / S 1 ) of the surface area S 2 to the area S 1 in plan view of the measurement location is 1.0 ≦ R ≦ A small protrusion is formed so as to be 2.4.

レーザー顕微鏡による計測においては、横縦（Ｘ−Ｙ）の計測位置における高さ（Ｚ）が計測されるもので、この二次元の計測範囲における高さを計測することで表面積Ｓ2が計算される。なお平面視の面積Ｓ1は高さ一定とした時の表面積に等しい。すなわち鏡面での表面積の比Ｒ＝１となる。 In measurement with a laser microscope, the height (Z) at the horizontal and vertical (XY) measurement position is measured, and the surface area S 2 is calculated by measuring the height in this two-dimensional measurement range. The The area S 1 in plan view is equal to the surface area when the height is constant. That is, the surface area ratio R = 1 at the mirror surface.

大突起及び小突起の形成は、金型にシボ加工にて形成する。本実施形態では、金型の大突起凸部（製品凹部）に形成された小突起をミガキ加工にて表面積率１．０〜１．６に加工する。製品凸部に形成された小突起は表面積率１．６〜２．４、大突起の凹部の面積比率は全体の２０〜４０％とする。ミガキ用具は＃１５００、＃３０００を使用し、金型シボ表面を均一に加工する。   The large protrusions and small protrusions are formed on the mold by embossing. In the present embodiment, the small protrusions formed on the large protrusion protrusions (product recesses) of the mold are processed to a surface area ratio of 1.0 to 1.6 by stamping. The small protrusions formed on the product protrusions have a surface area ratio of 1.6 to 2.4, and the area ratio of the recesses of the large protrusions is 20 to 40% of the whole. Migaki tools use # 1500 and # 3000 to uniformly process the surface of the mold.

なお、突起の形成方法については、上記の他に、大突起は上記材料の表面にブラストを打つ方法、エッチング処理を施す方法等が挙げられるが、特に限定されない。小突起は、大突起を形成した表面にブラストを打つ方法、エッチング処理を施す方法、逆電解法、酸洗い処理法、等様々な方法が挙げられるが、特に限定されない。例えば大突起の上からブラストを打つ場合には、ブラストの番手（大突起形成に使用したものより大きい番手）、吹き付けるエアー圧、表面との距離等を変更することにより、表面積の比を種々に変更することができる。   In addition to the above, the method of forming the protrusion includes, but not limited to, a method of blasting the surface of the material and a method of performing an etching process for the large protrusion. The small protrusions include various methods such as a method of blasting the surface on which the large protrusions are formed, a method of performing an etching process, a reverse electrolysis method, and a pickling method, but are not particularly limited. For example, when blasting from the top of a large protrusion, the surface area ratio can be varied by changing the blast count (the count greater than that used to form the large protrusion), the air pressure to be sprayed, the distance from the surface, etc. Can be changed.

以下、実施例に基づいて説明する。
＜実施例＞
表１及び図１に示す実施例と比較例１〜３について、試験を行った。全ての実施例・比較例において、材質はＦＲＰ（水の接触角７９度〜８３度）とした。また、全ての実施例・比較例において、上述のＳｍは２０乃至５００μｍ、Ｒｚは８乃至７０μｍとした。すなわち、全ての実施例・比較例において、大突起を形成した。 Hereinafter, a description will be given based on examples.
<Example>
Tests were performed on the examples shown in Table 1 and FIG. 1 and Comparative Examples 1 to 3. In all Examples and Comparative Examples, the material was FRP (water contact angle 79 degrees to 83 degrees). In all of the examples and comparative examples, the above Sm was 20 to 500 μm, and Rz was 8 to 70 μm. That is, large protrusions were formed in all the examples and comparative examples.

図１における形状は模式的なものである。符号１は大突起の凸部、符号２は大突起の凹部を示す。   The shape in FIG. 1 is schematic. Reference numeral 1 indicates a convex portion of the large protrusion, and reference numeral 2 indicates a concave portion of the large protrusion.

図表中、「面積比率」と記したのは、表面積率１．６〜２．４である部分の面積の、全体の面積に対する比率である。   In the figure, “area ratio” is the ratio of the area of the portion having a surface area ratio of 1.6 to 2.4 to the entire area.

比較例１においては、大突起の全表面について表面積率１．０〜１．４としたので、上述した面積比率は０％である（図中形状Ａ）。比較例２，３、実施例においては、表面積率が１．６〜２．４である部分を形成した。すなわち、比較例２においては、大突起凸部を表面積率１．６〜２．４とし、大突起凹部を表面積率１．０〜１．６とし、凸部の面積比率を５０％とした（図中形状Ｂ）。比較例３においては、全表面を表面積率１．６〜２．４としたので、面積比率は１００％である（図中形状Ｃ）。   In Comparative Example 1, since the surface area ratio was set to 1.0 to 1.4 for the entire surface of the large protrusion, the above-described area ratio was 0% (shape A in the figure). In Comparative Examples 2, 3 and Examples, a portion having a surface area ratio of 1.6 to 2.4 was formed. That is, in Comparative Example 2, the large protrusion convex portion had a surface area ratio of 1.6 to 2.4, the large protrusion concave portion had a surface area ratio of 1.0 to 1.6, and the area ratio of the convex portion was 50% ( Shape B). In Comparative Example 3, since the entire surface area was set to 1.6 to 2.4, the area ratio was 100% (shape C in the figure).

実施例においては、大突起凸部を表面積率１．６〜２．４とし、大突起凹部を表面積率１．０〜１．６とし、凸部の面積比率を６０％とした（図中形状Ｄ）。   In the examples, the large protrusion convex part has a surface area ratio of 1.6 to 2.4, the large protrusion concave part has a surface area ratio of 1.0 to 1.6, and the area ratio of the convex part is 60% (the shape in the figure). D).

なお、凹凸の平均間隔Ｓｍおよび十点平均粗さＲｚの計測は例えばミツトヨ（株）製「サーフテスト３０１」等の表面粗さ計にて行い、表面積の比Ｒの計測は例えばキーエンス（株）製「ＶＫ−９５００」等のレーザー顕微鏡を用いるが、特に限定されない。   The average spacing Sm and the ten-point average roughness Rz are measured with a surface roughness meter such as “Surf Test 301” manufactured by Mitutoyo Corporation, and the surface area ratio R is measured, for example, with Keyence Corporation. Although a laser microscope such as “VK-9500” manufactured by the company is used, it is not particularly limited.

そして、上記実施例、比較例１〜３について排水性および乾燥性、防汚性、光沢性の評価を行った。その結果を表１に示す。なお、表中では、「排水性および乾燥性」を「乾燥性」と記している。   And about the said Example and Comparative Examples 1-3, drainage property, drying property, antifouling property, and glossiness were evaluated. The results are shown in Table 1. In the table, “drainage and drying” is described as “drying”.

排水性および乾燥性は三段階評価とし、表面を勾配１／５０となるように傾けてシャワーで散水後、６０秒後の排水状態について目視により判断した。そして、表面が広い水膜状（表中◎）又は水膜状（表中○）になれば合格、水膜と水滴の混在（表中△）もしくは水滴が多数残った状態（表中×）は不合格とした。なお、シャワーの散水条件は、流量を１５Ｌ／分、距離を３０ｃｍ、スピードを７ｃｍ／秒とした。   The drainage and drying properties were evaluated in three stages, and the surface was tilted so as to have a gradient of 1/50, sprinkled with a shower, and the drainage state after 60 seconds was judged visually. And if the surface becomes wide water film (in the table ◎) or water film (in the table ○), it is acceptable, a mixture of water film and water droplets (△ in the table) or many water droplets remain (× in the table) Was rejected. The shower watering conditions were a flow rate of 15 L / min, a distance of 30 cm, and a speed of 7 cm / sec.

また、防汚性については、カーボンブラック試験を実施し、カーボン回復率９０％以上（表中◎）もしくは８５〜９０％（表中○）を合格とし、８５％未満（表中×）を不合格とした。   As for antifouling properties, a carbon black test was conducted, and a carbon recovery rate of 90% or more (in the table) or 85 to 90% (in the table) was accepted, and less than 85% (in the table x) was unacceptable. Passed.

光沢性及び総合評価は、良好（表中◎）、可（表中○）が合格、不可（表中×）が不合格とした。   As for glossiness and comprehensive evaluation, good (◎ in the table), acceptable (◯ in the table) passed, and unacceptable (× in the table) failed.

Figure 2012067506
Figure 2012067506

表１より、比較例１（表面積率１．６〜２．４である部分がないもの）は、防汚性、光沢性は満足するものの、乾燥性に劣る。比較例２（大突起凸部の表面積率が１．６〜２．４であり、当該凸部の面積比率が全体の５０％のもの）は、防汚性、光沢性は満足するものの、乾燥性に劣る。一方、比較例３（表面積率１．６〜２．４である部分の比率が全体の１００％のもの）は、乾燥性は満足するものの、光沢性に劣り、防汚性も不十分である。   From Table 1, Comparative Example 1 (the one having no surface area ratio of 1.6 to 2.4) is inferior in drying property, although the antifouling property and glossiness are satisfied. Comparative Example 2 (the surface area ratio of the protrusions of the large protrusions is 1.6 to 2.4, and the area ratio of the protrusions is 50% of the whole) is satisfactory although antifouling properties and glossiness are satisfied, but is dry Inferior to sex. On the other hand, Comparative Example 3 (the ratio of the portion having a surface area ratio of 1.6 to 2.4 is 100% of the whole) is satisfactory in drying property but inferior in glossiness and insufficient in antifouling property. .

これらに対し、実施例は、大突起凸部の表面積率が１．６〜２．４であり、当該凸部の面積比率が全体の６０％のもので、乾燥性、防汚性、光沢性のいずれも満足し、総合評価は良好となった。   On the other hand, in the examples, the surface area ratio of the protrusions of the large protrusions is 1.6 to 2.4, and the area ratio of the protrusions is 60% of the entire area. Both were satisfied and the overall evaluation was good.

この結果から、大突起凹部の表面積率が１．０〜１．６、大突起凸部の表面積率が１．６〜２．４であり、凸部の面積比率が全体の６０％〜８０％程度（凹部の面積比率が全体の２０％〜４０％程度）であるものが最適と判断される。   From this result, the surface area ratio of the large protrusion concave part is 1.0 to 1.6, the surface area ratio of the large protrusion convex part is 1.6 to 2.4, and the area ratio of the convex part is 60% to 80% of the whole. It is judged to be optimal when the area ratio is about 20% to 40% of the overall recess area ratio.

１ 大突起の凸部
２ 大突起の凹部 1 Convex part of large protrusion 2 Concave part of large protrusion

Claims (1)

鏡面における水の接触角が７５度以上９０度未満の材料の表面を凹凸の平均間隔Ｓｍが２０乃至５００μｍとなると共に十点平均粗さＲｚが８乃至７０μｍとなる凹凸を形成してその凸部を大突起とし、前記大突起の表面に、該表面の５μｍ四方の測定範囲の任意の１０箇所をレーザー顕微鏡で横縦（Ｘ−Ｙ）方向の分解能を０．０４４μｍ及び高さ（Ｚ）方向の分解能を０．０１μｍに設定して測定した時に測定箇所の平面視の面積に対する表面積の比が大突起の凹部で１．０以上１．６以下、凸部で１．６以上２．４以下となる小突起を形成して成り、大突起の凹部の面積比率は全体の２０〜４０％であることを特徴とする水廻り部材。   The surface of the material having a water contact angle of 75 degrees or more and less than 90 degrees on the mirror surface is formed with irregularities having an average interval Sm of 20 to 500 μm and a ten-point average roughness Rz of 8 to 70 μm. Is a large protrusion, and on the surface of the large protrusion, an arbitrary 10 positions in a measurement area of 5 μm square on the surface is measured with a laser microscope with a resolution of 0.044 μm in the horizontal and vertical (XY) direction and a height (Z) direction. The ratio of the surface area to the area in plan view of the measurement location when measuring with a resolution of 0.01 μm is 1.0 or more and 1.6 or less for the concave portion of the large protrusion, and 1.6 or more and 2.4 or less for the convex portion A watering member characterized in that a small protrusion is formed, and the area ratio of the concave portion of the large protrusion is 20 to 40% of the whole.
JP2010213141A 2010-09-24 2010-09-24 Water-related parts Active JP5609486B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2010213141A JP5609486B2 (en) 2010-09-24 2010-09-24 Water-related parts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2010213141A JP5609486B2 (en) 2010-09-24 2010-09-24 Water-related parts

Publications (2)

Publication Number Publication Date
JP2012067506A true JP2012067506A (en) 2012-04-05
JP5609486B2 JP5609486B2 (en) 2014-10-22

Family

ID=46165084

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2010213141A Active JP5609486B2 (en) 2010-09-24 2010-09-24 Water-related parts

Country Status (1)

Country Link
JP (1) JP5609486B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015030106A (en) * 2013-07-31 2015-02-16 スリーエム イノベイティブ プロパティズ カンパニー Non-slip sheet for water section

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006224347A (en) * 2005-02-15 2006-08-31 Matsushita Electric Works Ltd Manufacturing method of mold for molding water section member and water section member
JP2007154491A (en) * 2005-12-02 2007-06-21 Matsushita Denko Bath & Life Kk Water section member
JP2008106554A (en) * 2006-10-26 2008-05-08 Matsushita Denko Bath & Life Kk Floor pan

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006224347A (en) * 2005-02-15 2006-08-31 Matsushita Electric Works Ltd Manufacturing method of mold for molding water section member and water section member
JP2007154491A (en) * 2005-12-02 2007-06-21 Matsushita Denko Bath & Life Kk Water section member
JP2008106554A (en) * 2006-10-26 2008-05-08 Matsushita Denko Bath & Life Kk Floor pan

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015030106A (en) * 2013-07-31 2015-02-16 スリーエム イノベイティブ プロパティズ カンパニー Non-slip sheet for water section
US10040268B2 (en) 2013-07-31 2018-08-07 3M Innovative Properties Company Anti-slip sheet to be used around water

Also Published As

Publication number Publication date
JP5609486B2 (en) 2014-10-22

Similar Documents

Publication Publication Date Title
Peng et al. Mechanically durable superoleophobic aluminum surfaces with microstep and nanoreticula hierarchical structure for self-cleaning and anti-smudge properties
Quéré et al. Non-adhesive lotus and other hydrophobic materials
EP3334541B1 (en) Article having a nanotextured surface with hydrophobic properties
Momen et al. A ZnO-based nanocomposite coating with ultra water repellent properties
Chu et al. Facile fabrication of a robust super-hydrophobic surface on magnesium alloy
TWI490375B (en) Mold, manufacturing method therefor product having fine uneven structure on its surface, manufacturing method therefor and display device
Guan et al. Characterization of multi-scale morphology and superhydrophobicity of water bamboo leaves and biomimetic polydimethylsiloxane (PDMS) replicas
JP6409497B2 (en) Water and oil repellent material
CN110049857A (en) Formed body
JP2017507037A (en) Workpiece with nanostructured surface
Afferrante et al. The effect of drop volume and micropillar shape on the apparent contact angle of ordered microstructured surfaces
JP2009138367A (en) Flooring material for bathroom
JP5609486B2 (en) Water-related parts
JP4591334B2 (en) Water-related parts
Yao et al. Impact of pillar configuration on the amphiphobicity of micro-patterned polymer surface
JP2005525923A (en) surface
Adithyavairavan et al. A morphological study on direct polymer cast micro-textured hydrophobic surfaces
Legrand et al. Quantification and modeling of anisotropic wetting of textured surfaces
JP5371337B2 (en) Washing place
JP2008106554A (en) Floor pan
US20210047746A1 (en) Home appliance including hairline and manufacturing method thereof
JP4696881B2 (en) Water-related parts
JP2007262761A (en) Floor pan
Lee Improving superhydrophobic textile materials
Zohra et al. The effect of macroscopic and microscopic patterns of stainless steel surface on the efficiency of dropwise condensation and precipitation

Legal Events

Date Code Title Description
A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A712

Effective date: 20120111

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20130312

RD01 Notification of change of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7421

Effective date: 20130412

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20131119

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20131203

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20131227

RD01 Notification of change of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7421

Effective date: 20140108

RD01 Notification of change of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7421

Effective date: 20140417

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20140805

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20140818

R151 Written notification of patent or utility model registration

Ref document number: 5609486

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R151