JP2011184345A - Hair treatment agent and method for foaming the hair treatment agent - Google Patents
Hair treatment agent and method for foaming the hair treatment agent Download PDFInfo
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本発明は、毛髪処理剤および該毛髪処理剤の発泡方法に関する。さらに詳しくは、反応型成分が確実に反応した状態で泡を形成し、毛髪処理による効果をムラなく均等に得ることができる毛髪処理剤および該毛髪処理剤の発泡方法に関する。 The present invention relates to a hair treatment agent and a foaming method for the hair treatment agent. More specifically, the present invention relates to a hair treatment agent capable of forming bubbles in a state where the reactive component has reacted reliably and obtaining the effect of hair treatment evenly and uniformly, and a method for foaming the hair treatment agent.
特許文献１および特許文献２には、第１剤と第２剤を樹脂ボトルに充填してポンプフォーマーを取り付け、樹脂ボトルを上下に振って混合し、樹脂ボトルを強く握って収縮させることにより第１剤と第２剤の混合液がフォーマーを通過して発泡し、泡状で吐出される毛髪化粧料が開示されている。 In Patent Document 1 and Patent Document 2, a resin bottle is filled with the first agent and the second agent, a pump former is attached, the resin bottle is shaken up and down to mix, and the resin bottle is firmly grasped and contracted. A hair cosmetic is disclosed in which a mixed liquid of a first agent and a second agent is foamed through a former and discharged in a foam form.
また、泡は内部に気体を含むため混ざりにくく、頭髪に塗布し泡が液状化したときに反応するためムラができやすく、この問題を解決するために特許文献３には、第１剤と第２剤を泡状で少量ずつ吐出し塗布するための２液反応染毛剤の塗布用具が開示されている。 In addition, since the foam contains gas inside, it is difficult to mix, and since it reacts when the foam is applied to the hair and the foam is liquefied, unevenness is likely to occur. To solve this problem, Patent Document 3 describes the first agent and the first agent. An application tool for a two-component reactive hair dye for discharging and applying two agents in a foamy manner is disclosed.
しかしながら、特許文献１および特許文献２に記載の毛髪化粧料では、樹脂ボトルを上下に振って混合するため、振っているときに液が漏れないように、また混合液をフォーマーを通過させるためにはフォーマーの通路以外の部分（樹脂ボトルにフォーマーを取り付ける部分）に気密性が必要になるが、第１剤と第２剤が混ざると過酸化水素の一部が分解されて酸素ガスが発生するため、急激に反応して圧力が高くなる場合があり、また樹脂ボトルは収縮できるように薄く成型しているため、安全性が確保できない恐れがある。 However, in the hair cosmetics described in Patent Literature 1 and Patent Literature 2, the resin bottle is shaken up and down to mix, so that the liquid does not leak when shaking and the liquid mixture passes through the former. The airtightness is required for the parts other than the path of the former (the part where the former is attached to the resin bottle), but when the first agent and the second agent are mixed, part of the hydrogen peroxide is decomposed and oxygen gas is generated. For this reason, there is a case where the pressure increases due to a rapid reaction, and the resin bottle is thinly molded so that it can be shrunk.
また、特許文献３に記載の２液反応染毛剤の塗布用具では、少量ずつ吐出しなければならないため、利便性が悪いという問題がある。また、少量ずつ毛髪に順次塗布するためムラが生じやすく、頭部全体において均一に効果を付与するには高い技術を要するという問題がある。 In addition, the two-component reactive hair dye application tool described in Patent Document 3 has a problem in that it is inconvenient because it must be discharged little by little. Further, since it is sequentially applied to the hair little by little, unevenness is likely to occur, and there is a problem that a high technique is required to uniformly apply the effect to the entire head.
本発明は上記問題に鑑みてなされたものであり、反応による効果をムラなく均等に得ることができ、頭髪や皮膚から垂れ落ちにくく、塗り伸ばしやすい毛髪処理剤および該毛髪処理剤の発泡方法を提供することを目的とする。また、急激に反応が進んでガスが発生しても安全な毛髪処理剤の発泡方法を提供することを目的とする。 The present invention has been made in view of the above problems, and provides a hair treatment agent that can uniformly obtain the effect of the reaction without unevenness, is less likely to drip from the hair and the skin, and is easy to spread, and a method for foaming the hair treatment agent. The purpose is to provide. It is another object of the present invention to provide a method for foaming a hair treatment agent that is safe even if the reaction proceeds rapidly and gas is generated.
本発明の毛髪処理剤は、反応型成分を配合した第１剤と、反応型成分を配合した第２剤と、発泡剤とを含み、前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、前記発泡剤が、沸点が−５〜８０℃の油剤であることを特徴とする。 The hair treatment agent of the present invention includes a first agent containing a reactive component, a second agent containing a reactive component, and a foaming agent, and an interface with at least one of the first agent and the second agent. An activator and water are contained, and the foaming agent is an oil agent having a boiling point of −5 to 80 ° C.
前記第１剤および／または第２剤に炭酸塩が含まれてなることが好ましい。 It is preferable that carbonate is contained in the first agent and / or the second agent.
さらに発熱剤を含み、該発熱剤が、前記第１剤および前記第２剤の少なくとも一方に含まれる水により発熱することが好ましい。 Furthermore, it is preferable that an exothermic agent is included, and the exothermic agent generates heat due to water contained in at least one of the first agent and the second agent.
さらに、本発明の毛髪処理剤は、反応型成分を配合した第１剤と、反応型成分を配合した第２剤とを含み、前記第１剤および前記第２剤の少なくとも一方に炭酸塩が含まれてなり、前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、前記第１剤および前記第２剤の少なくとも一方に含まれる水により発熱する発熱剤が含まれてなる。 Furthermore, the hair treatment agent of the present invention includes a first agent containing a reactive component and a second agent containing a reactive component, and carbonate is contained in at least one of the first agent and the second agent. An exothermic agent containing at least one of the first agent and the second agent and containing a surfactant and water, and generating heat by water contained in at least one of the first agent and the second agent. Will be included.
前記反応型成分が、酸化染料と過酸化水素とからなる２剤式染毛剤であることが好ましい。 It is preferable that the reactive component is a two-component hair dye composed of an oxidation dye and hydrogen peroxide.
本発明の毛髪処理剤の発泡方法は、反応型成分を配合した第１剤と、反応型成分を配合した第２剤と、発泡剤とを含み、前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、前記発泡剤が、沸点が−５〜８０℃の油剤であり、（１）前記第１剤と前記第２剤とを開放容器内で混合する工程と、（２）該混合物に発泡剤を添加し混合する工程と、（３）（２）の工程により得られた混合物を発泡させる工程と有する。 The foaming method of the hair treatment agent of the present invention includes a first agent containing a reactive component, a second agent containing a reactive component, and a foaming agent, and includes at least one of the first agent and the second agent. A surfactant and water are contained on one side, and the foaming agent is an oil agent having a boiling point of −5 to 80 ° C. (1) The first agent and the second agent are mixed in an open container. A step, (2) a step of adding and mixing a foaming agent to the mixture, and (3) a step of foaming the mixture obtained by the steps of (2).
加温する工程を含むことが好ましい。 It is preferable to include a step of heating.
加温する工程が、前記第１剤および／または前記第２剤中の水により発熱する発熱剤を添加する工程であることが好ましい。 It is preferable that the heating step is a step of adding a heat generating agent that generates heat due to water in the first agent and / or the second agent.
また本発明の毛髪処理剤の発泡方法は、反応型成分を配合した第１剤と、反応型成分を配合した第２剤とを含み、前記第１剤および前記第２剤の少なくとも一方に炭酸塩が含まれてなり、前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、前記第１剤および第２剤の少なくとも一方に含まれる水により発熱する発熱剤が含まれてなり、（１）前記第１剤と前記第２剤とを開放容器内で混合する工程と、（２）該混合物に発熱剤を添加し混合する工程と、（３）（２）の工程により得られた混合物を発泡させる工程とを有する。 Moreover, the foaming method of the hair treatment agent of this invention contains the 1st agent which mix | blended the reaction type component, and the 2nd agent which mix | blended the reaction type component, and carbonates at least one of the said 1st agent and the said 2nd agent. A salt is contained, and at least one of the first agent and the second agent contains a surfactant and water, and heat is generated by water contained in at least one of the first agent and the second agent. (1) a step of mixing the first agent and the second agent in an open container, (2) a step of adding an exothermic agent to the mixture and mixing, and (3) ( And 2) foaming the mixture obtained by the step 2).
前記反応型成分が、酸化染料と過酸化水素とからなる２剤式染毛剤であることが好ましい。 It is preferable that the reactive component is a two-component hair dye composed of an oxidation dye and hydrogen peroxide.
本発明の毛髪処理剤および該毛髪処理剤の発泡方法によれば、反応による効果をムラなく均等に得ることができ、頭髪や皮膚から垂れ落ちにくく、塗り伸ばしやすい毛髪処理剤および該毛髪処理剤の発泡方法を提供することができる。また、本発明の毛髪処理剤の発泡方法によれば、開放型容器で発泡させるため、急激に反応が進んでガスが発生しても安全な毛髪処理剤の発泡方法を提供することができる。 According to the hair treatment agent of the present invention and the foaming method of the hair treatment agent, the effect of the reaction can be obtained evenly and uniformly, and the hair treatment agent that is difficult to drip from the hair and skin and is easy to spread and the hair treatment agent The foaming method can be provided. Moreover, according to the foaming method of the hair treatment agent of this invention, since it foams with an open container, even if reaction advances rapidly and gas is generated, the foaming method of a hair treatment agent safe can be provided.
本発明の毛髪処理剤は、反応型成分を配合した第１剤と、反応型成分を配合した第２剤と、発泡剤とを含み、前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、前記発泡剤が、沸点が−５〜８０℃の油剤である。 The hair treatment agent of the present invention includes a first agent containing a reactive component, a second agent containing a reactive component, and a foaming agent, and an interface with at least one of the first agent and the second agent. An activator and water are contained, and the foaming agent is an oil agent having a boiling point of −5 to 80 ° C.
前記反応型成分としては、たとえば、酸化還元反応として、パラフェニレンジアミンなどの酸化染料と過酸化水素、亜硫酸ナトリウムと過酸化水素、チオ硫酸ナトリウムと過酸化水素、中和反応として、水溶性高分子とｐＨ調整剤（酸性成分またはアルカリ性成分）、たとえばカルボキシビニルポリマーとアルカリ成分、アクリル酸／スレアレス共重合体やアクリル酸／セテス共重合体とアルカリ成分、アクリル酸／アミノアクリル酸／ＰＥＧ・アルキル（炭素数１０〜２０）共重合体と酸性成分、溶解反応として、尿素と水などがあげられる。前記反応型成分は第１剤と第２剤にそれぞれ別々に配合される。 Examples of the reactive component include an oxidation-reduction reaction such as an oxidation dye such as paraphenylenediamine and hydrogen peroxide, sodium sulfite and hydrogen peroxide, sodium thiosulfate and hydrogen peroxide, and a water-soluble polymer as a neutralization reaction. And pH adjuster (acidic component or alkaline component), such as carboxyvinyl polymer and alkaline component, acrylic acid / slealess copolymer, acrylic acid / cetes copolymer and alkaline component, acrylic acid / aminoacrylic acid / PEG alkyl ( Examples of the C10-20 copolymer and acidic component and dissolution reaction include urea and water. The reactive component is blended separately into the first agent and the second agent.
前記第１剤と第２剤の少なくとも一方が界面活性剤と水を含有する液体である。第１剤と第２剤は両方が液体でもよく、いずれか一方がパウダー状でもよい。 At least one of the first agent and the second agent is a liquid containing a surfactant and water. Both the first agent and the second agent may be liquid, and one of them may be powdery.
前記界面活性剤は、後述する発泡剤により混合液を泡状にするものであり、公知の界面活性剤を使用することができる。前記界面活性剤としては、たとえば、ポリオキシエチレンポリオキシプロピレンアルキルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンアルキルエーテル、ポリエチレングリコール脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンソルビット脂肪酸エステルなどの、ＨＬＢが１０〜１９、好ましくは１１〜１８である親水性の非イオン性界面活性剤、アルキル硫酸塩、ポリオキシエチレンアルキルエーテル硫酸塩などのアニオン性界面活性剤、塩化アルキルトリメチルアンモニウム、塩化ジアルキルジメチルアンモニウムなどのカチオン性界面活性剤、脂肪酸アミドプロピルベタイン、アルキルジメチルアミンオキサイド、アルキルジメチルアミノ酢酸ベタイン、スルホベタインなどの両性界面活性剤、シリコーン系界面活性剤、アミノ酸系界面活性剤などがあげられる。 The said surfactant makes a liquid mixture foam with the foaming agent mentioned later, and can use a well-known surfactant. Examples of the surfactant include polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene alkyl ether, polyethylene glycol fatty acid ester, Hydrophilic nonionic surfactants having an HLB of 10 to 19, preferably 11 to 18, such as polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester , Anionic surfactants such as alkyl sulfates, polyoxyethylene alkyl ether sulfates, alkyl trimethyl ammonium chlorides, dialkyl dimethyl chlorides Examples include cationic surfactants such as ruammonium, amphoteric surfactants such as fatty acid amidopropyl betaine, alkyldimethylamine oxide, alkyldimethylaminoacetic acid betaine, and sulfobetaine, silicone surfactants, and amino acid surfactants. .
前記水は反応型成分の溶媒であり、前記界面活性剤と発泡剤により発泡して泡になる。前記水としては特に限定がなく、たとえば、精製水、イオン交換水、滅菌水などを用いることができる。 The water is a solvent of a reactive component, and foams into bubbles by the surfactant and the foaming agent. There is no limitation in particular as said water, For example, purified water, ion-exchange water, sterilized water, etc. can be used.
前記第１剤と第２剤は、必要に応じて、たとえば、ヒドロシキエチルセルロース、ヒドロシキプロピルセルロース、ゼラチン、キサンタンガムなどの水溶性高分子、エタノール、プロパノールなどの低級アルコール、グリセリン、１，３−ブチレングリコール、プロピレングリコールなどの多価アルコール、ラウリルアルコール、セチルアルコール、ステアリルアルコールなどの高級アルコール、カチオン性ポリマー、両性ポリマーなどの重合体、シリコーンオイル、リン酸、水酸化ナトリウムなどのｐＨ調整剤、安定化剤、防腐剤、香料などを配合することができる。 The first agent and the second agent are, for example, water-soluble polymers such as hydroxyethyl cellulose, hydroxypropyl cellulose, gelatin and xanthan gum, lower alcohols such as ethanol and propanol, glycerol, 1,3- Polyhydric alcohols such as butylene glycol and propylene glycol, higher alcohols such as lauryl alcohol, cetyl alcohol and stearyl alcohol, polymers such as cationic polymers and amphoteric polymers, pH adjusters such as silicone oil, phosphoric acid and sodium hydroxide, Stabilizers, preservatives, fragrances and the like can be blended.
前記発泡剤は第１剤と第２剤の混合液を発泡させ、第１剤と第２剤の反応を促進する成分であって、沸点が−５〜８０℃の油剤などがあげられる。 The foaming agent is a component that foams a mixed solution of the first agent and the second agent and promotes the reaction between the first agent and the second agent, and includes an oil agent having a boiling point of −5 to 80 ° C.
前記油剤としては、たとえば、ノルマルブタン（沸点：−０．５℃）、イソペンタン（沸点：２７．９℃）、ノルマルペンタン（沸点：３６．１℃）、ノルマルヘキサン（沸点：６８．７℃）、イソヘキザン（沸点：６０．３℃）などの脂肪族炭化水素、メチルパーフルオロブチルエーテル（沸点：６１℃）、エチルパーフルオロブチルエーテル（沸点：６１℃）などのハイドロフルオロエーテルなどがあげられる。 Examples of the oil include normal butane (boiling point: −0.5 ° C.), isopentane (boiling point: 27.9 ° C.), normal pentane (boiling point: 36.1 ° C.), and normal hexane (boiling point: 68.7 ° C.). And aliphatic hydrocarbons such as isohexane (boiling point: 60.3 ° C.) and hydrofluoroethers such as methyl perfluorobutyl ether (boiling point: 61 ° C.) and ethyl perfluorobutyl ether (boiling point: 61 ° C.).
前記発泡剤として沸点が−５〜４０℃である油剤を用いる場合は、沸点が外気温と類似しているため第１剤と第２剤の混合液に滴下し混ぜるとゆっくりと気化し、混合液をゆっくりと発泡させながら第１剤と第２剤の反応型成分の反応を促進することができる。発泡剤の沸点が−５℃よりも低い場合は滴下と同時に気化するため、大気圧下にある混合液を発泡させることができない。なお、沸点が４０〜８０℃である油剤を用いる場合は、電子レンジやお湯などで加温したり、発熱剤を添加して加温することが好ましく、混合液が温められてゆっくりと発泡する。沸点が８０℃よりも高い場合は高温にならないと発泡しないため、塗布するときに火傷する恐れがある。 When an oil agent having a boiling point of −5 to 40 ° C. is used as the foaming agent, the boiling point is similar to the outside air temperature. Therefore, when the oil agent is dropped into the liquid mixture of the first agent and the second agent and mixed, it is slowly vaporized and mixed. The reaction of the reactive component of the first agent and the second agent can be promoted while the liquid is slowly foamed. When the boiling point of the foaming agent is lower than −5 ° C., the liquid mixture is vaporized at the same time as the dropping, so that the liquid mixture under atmospheric pressure cannot be foamed. In addition, when using the oil agent whose boiling point is 40-80 degreeC, it is preferable to heat with a microwave oven, hot water, etc., or to add and heat a heating agent, and a liquid mixture is warmed and it foams slowly. . When the boiling point is higher than 80 ° C., it does not foam unless the temperature is high, and there is a risk of burns when it is applied.
前記発泡剤の添加量は、第１剤と第２剤の混合液に対して１〜３０重量％、さらには２〜２０重量％であることが好ましい。なお、発泡剤として沸点が−５〜４０℃である油剤を用いる場合、２０℃において０．０５〜０．２ＭＰａの蒸気圧を有するため、バルブを備えた耐圧容器に充填することが好ましい。この場合、バルブを開放し発泡剤を液滴状に滴下するアクチエーターを備えることが好ましい。 The amount of the foaming agent added is preferably 1 to 30% by weight, more preferably 2 to 20% by weight with respect to the mixed solution of the first agent and the second agent. In addition, when using the oil agent whose boiling point is -5-40 degreeC as a foaming agent, since it has a vapor pressure of 0.05-0.2 MPa in 20 degreeC, it is preferable to fill the pressure-resistant container provided with the valve | bulb. In this case, it is preferable to provide an actuator that opens the valve and drops the foaming agent into droplets.
前記発熱剤は、混合液中の水により発熱して混合液の温度を上げ、発泡を促進する成分である。前記発熱剤としては、たとえば、グリセリン、ジエチレングリコール、プロピレングリコールなどの多価アルコール、塩化マグネシウムなどの無機塩、ゼオライトなどがあげられる。その中でも、水に溶解して発熱し使用感に影響が少ない点から無機塩が好ましい。 The exothermic agent is a component that generates heat by water in the mixed solution to raise the temperature of the mixed solution and promote foaming. Examples of the exothermic agent include polyhydric alcohols such as glycerin, diethylene glycol, and propylene glycol, inorganic salts such as magnesium chloride, and zeolite. Among these, an inorganic salt is preferable from the viewpoint that it dissolves in water and generates heat and has little influence on the feeling in use.
前記発熱剤の添加量は、第１剤と第２剤の混合液に対して１〜２０重量％、さらには２〜１０重量％であることが好ましい。配合量が１重量％よりも少ない場合は前述の効果が得られにくく、２０重量％を超えると熱くなりすぎる恐れがある。 The amount of the exothermic agent added is preferably 1 to 20% by weight, more preferably 2 to 10% by weight, based on the mixed solution of the first agent and the second agent. When the blending amount is less than 1% by weight, it is difficult to obtain the above-described effect. When the blending amount exceeds 20% by weight, there is a possibility of becoming too hot.
なお、前記第１剤および／または第２剤に発泡補助剤として炭酸塩を含んでもよい。前記炭酸塩としては、たとえば、炭酸ナトリウム、炭酸水素ナトリウム、炭酸アンモニウム、炭酸カリウムなどがあげられる。炭酸塩は混合液中の水に溶解して炭酸ガスを発生し、混合液を発泡させる。炭酸塩を添加した後で前記発熱剤を添加することで混合液の温度が上がり、炭酸塩が水に溶解しやすく、発泡しやすくなる。 The first agent and / or the second agent may contain a carbonate as a foaming aid. Examples of the carbonate include sodium carbonate, sodium hydrogen carbonate, ammonium carbonate, and potassium carbonate. The carbonate is dissolved in water in the mixed solution to generate carbon dioxide gas, and the mixed solution is foamed. By adding the exothermic agent after adding the carbonate, the temperature of the mixed solution rises, and the carbonate easily dissolves in water and foams easily.
また、本発明の毛髪処理剤は、反応型成分を配合した第１剤と、反応型成分を配合した第２剤とを含み、前記第１剤および前記第２剤の少なくとも一方に炭酸塩を含み、前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、前記第１剤および第２剤の少なくとも一方に含まれる水により発熱する発熱剤を含む。 Moreover, the hair treatment agent of this invention contains the 1st agent which mix | blended the reaction type component, and the 2nd agent which mix | blended the reaction type component, and carbonate is added to at least one of the said 1st agent and the said 2nd agent. In addition, at least one of the first agent and the second agent includes a surfactant and water, and includes a heat generating agent that generates heat due to water contained in at least one of the first agent and the second agent.
この実施の形態では、前記第１剤および前記第２剤の少なくとも一方に含まれる炭酸塩が発熱剤による加温により水に溶解しやすくなり、発泡しやすい。そのため沸点が−５〜８０℃である油剤を発泡剤として用いなくてもよいが、任意に添加することができる。 In this embodiment, the carbonate contained in at least one of the first agent and the second agent is easily dissolved in water by heating with the exothermic agent and easily foams. Therefore, an oil agent having a boiling point of −5 to 80 ° C. may not be used as a foaming agent, but can be arbitrarily added.
本発明の毛髪処理剤は、たとえばパーマネント、ストレートパーマ、縮毛矯正、ヘアカラーなどの各種理美容用途に使用することができる。中でも熟練した技術を要さずに一般消費者が均等に頭部に塗布できる点から、染毛剤（ヘアカラー）に使用した場合に格別顕著な効果が得られる。 The hair treatment agent of the present invention can be used for various hairdressing and cosmetic applications such as permanent, straight permanent, curly hair correction, and hair color. Among them, since a general consumer can apply evenly to the head without requiring a skilled technique, a particularly remarkable effect can be obtained when used for a hair dye (hair color).
次に本発明の毛髪処理剤の発泡方法について説明する。 Next, the foaming method of the hair treatment agent of the present invention will be described.
本発明の毛髪処理剤の発泡方法は、反応型成分を配合した第１剤と、反応型成分を配合した第２剤と、発泡剤とを含み、前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、前記発泡剤が、沸点が−５〜８０℃の油剤であり、（１）前記第１剤と前記第２剤とを開放容器内で混合する工程と、（２）該混合物に発泡剤を添加し混合する工程と、（３）（２）の工程により得られた混合物を発泡させる工程とを有する。 The foaming method of the hair treatment agent of the present invention includes a first agent containing a reactive component, a second agent containing a reactive component, and a foaming agent, and includes at least one of the first agent and the second agent. A surfactant and water are contained on one side, and the foaming agent is an oil agent having a boiling point of −5 to 80 ° C. (1) The first agent and the second agent are mixed in an open container. A step, (2) a step of adding and mixing a foaming agent to the mixture, and (3) a step of foaming the mixture obtained by the steps of (2).
（１）の工程は、図１（ａ）に示されるように、反応型成分を配合した前記第１剤と反応型成分を配合した前記第２剤とを開放容器内で混合する工程である。このとき反応型成分は反応を開始する。反応型成分、第１剤および第２剤としては、毛髪処理剤の説明時に述べたものを使用することができる。参照符号１は開放容器、参照符号２は第１剤、参照符号３は第２剤を示している。 As shown in FIG. 1A, the step (1) is a step of mixing the first agent mixed with a reactive component and the second agent mixed with a reactive component in an open container. . At this time, the reactive component starts to react. As the reactive component, the first agent and the second agent, those described in the description of the hair treatment agent can be used. Reference numeral 1 indicates an open container, reference numeral 2 indicates a first agent, and reference numeral 3 indicates a second agent.
開放容器としては特に限定されないが、たとえば、図２（ａ）に示すような開口部を有するカップ状の樹脂容器や防水処理などをした紙容器などがあげられる。開放容器は、毛髪処理製品として販売される際には、第１剤、第２剤、発泡剤、攪拌具、補助具などを入れておく収容容器として利用され、開口部にはフタを装着する。参照符号４はフタ、参照符号５は発泡剤、参照符号６は撹拌・塗布具を示している。
Although it does not specifically limit as an open container, For example, the cup-shaped resin container which has an opening part as shown to Fig.2 (a), the paper container etc. which waterproofed etc. are mention | raise | lifted. When an open container is sold as a hair treatment product, it is used as a storage container for storing the first agent, the second agent, a foaming agent, a stirrer, an auxiliary tool, etc., and a lid is attached to the opening. .
第１剤や第２剤を充填する容器としては特に限定されないが、たとえば、第１剤や第２剤が液体である場合は樹脂製ボトルや金属製容器などが（図１（ａ）、図２（ｂ）および図２（ｃ）参照）、クリームやゲル状である場合は樹脂製チューブやアルミチューブなどが（図３（ａ）参照）、パウダー状である場合は樹脂製パウチやアルミパウチなど（図３（ｂ）、図３（ｃ）、図４（ａ）および図４（ｂ）参照）があげられる。参照符号Ａはアルミ製のフタ、参照符号Ｔ１はチューブ、参照符号Ｔ２、Ｔ２ａ、Ｔ２ｂはトレイ、参照符号Ｐ１およびＰ２はパウチを示している。トレイＴ２ａおよびＴ２ｂには、たとえばそれぞれ第１剤および第２剤を充填することができる。 Although it does not specifically limit as a container filled with a 1st agent or a 2nd agent, For example, when a 1st agent or a 2nd agent is a liquid, a resin bottle, a metal container, etc. (FIG. 1 (a), figure) 2 (b) and FIG. 2 (c)), if it is cream or gel, a resin tube or aluminum tube (see FIG. 3 (a)), and if it is powder, it is a resin pouch or aluminum pouch. (Refer to FIG. 3B, FIG. 3C, FIG. 4A, and FIG. 4B). Reference symbol A is an aluminum lid, reference symbol T1 is a tube, reference symbols T2, T2a and T2b are trays, and reference symbols P1 and P2 are pouches. The trays T2a and T2b can be filled with, for example, a first agent and a second agent, respectively.
（２）の工程は、（１）の工程を経て得られた混合物に対して発泡剤および発泡補助剤を添加し混合する工程である。発泡剤として沸点が−５〜４０℃である油剤を用いる場合は室温に近い沸点を有するため、混合液と液体状態で混合され均一に分散する。発泡および発泡助剤としては、毛髪処理剤の説明時に述べたものを使用することができる。 The step (2) is a step of adding and mixing a foaming agent and a foaming auxiliary agent to the mixture obtained through the step (1). When an oil agent having a boiling point of −5 to 40 ° C. is used as the foaming agent, the oil agent has a boiling point close to room temperature, so that it is mixed with the mixed solution in a liquid state and uniformly dispersed. As foaming and foaming aids, those mentioned in the description of the hair treatment agent can be used.
発泡剤を充填する容器としては特に限定されないが、たとえば、バルブを備えた耐圧容器などがあげられる（図１（ｂ）および図２（ｄ）参照）。耐圧容器としては、アルミニウムやブリキなどの金属、ポリエチレンテレフタレートなどの合成樹脂、耐圧ガラスなどを用いることができる。 Although it does not specifically limit as a container filled with a foaming agent, For example, the pressure | voltage resistant container provided with the valve | bulb etc. are mention | raise | lifted (refer FIG.1 (b) and FIG.2 (d)). As the pressure vessel, a metal such as aluminum or tin, a synthetic resin such as polyethylene terephthalate, a pressure resistant glass, or the like can be used.
発熱剤を充填する容器としては、たとえば、発熱剤が液体である場合は樹脂製ボトルや金属製容器などが（図１（ａ）、図２（ｂ）および図２（ｃ）参照）、パウダー状である場合は樹脂製パウチやアルミパウチなど（図３（ｂ）、図３（ｃ）、図４（ａ）および図４（ｂ）参照）があげられる。なお、水分を遮断できる点からアルミパウチやアルミ箔層を備えた樹脂パウチを用いることが好ましい。 As the container for filling the exothermic agent, for example, when the exothermic agent is a liquid, a resin bottle, a metal container or the like (see FIGS. 1 (a), 2 (b) and 2 (c)), powder In the case of the shape, a resin pouch, an aluminum pouch, etc. (see FIG. 3B, FIG. 3C, FIG. 4A and FIG. 4B) can be mentioned. In addition, it is preferable to use the resin pouch provided with the aluminum pouch and the aluminum foil layer from the point which can interrupt | block a water | moisture content.
（３）の工程は、（２）の工程を経て得られた混合物を発泡させる工程である。（３）の工程では、（２）の工程の後に、１〜５分間放置することにより、発泡剤が気化し、ゆっくりと発泡することとなる。そして、撹拌・塗布具で混ぜると滑らかな泡になり、頭髪や皮膚に塗布しても垂れ落ちずに保持され、反応型成分の効果を付与することができる。なお、発泡剤として沸点が４０〜７０℃である油剤を用いる場合は混合液に添加し混合してから電子レンジやお湯で、あるいは発熱剤で加温して油剤を気化させることが好ましい。後は１〜５分間放置して発泡させ、最後に混合具で混ぜる。参照符号７は、（３）の工程を経て得られた泡状の毛髪処理剤を示している。
The step (3) is a step of foaming the mixture obtained through the step (2). In the step (3), after the step (2), the foaming agent is vaporized and allowed to foam slowly by being left for 1 to 5 minutes. And if it mixes with a stirring and applicator, it will become a smooth foam, and even if it applies to hair and skin, it will be held without dripping, and the effect of the reactive component can be imparted. In addition, when using the oil agent whose boiling point is 40-70 degreeC as a foaming agent, after adding and mixing to a liquid mixture, heating with a microwave oven, hot water, or a heat generating agent, it is preferable to vaporize an oil agent. Then leave it for 1 to 5 minutes to foam, and finally mix with a mixing tool.
なお、前述のとおり、沸点が−５〜８０℃である油剤を用いない本発明の毛髪処理剤の発泡方法の別の態様では、反応型成分を配合した第１剤と、反応型成分を配合した第２剤とを含み、前記第１剤および前記第２剤の少なくとも一方に炭酸塩が含まれてなり、前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、前記第１剤および第２剤の少なくとも一方に含まれる水により発熱する発熱剤が含まれてなり、（１）前記第１剤と前記第２剤とを開放容器内で混合する工程と、（２）該混合物に発熱剤を添加し混合する工程と、（３）（２）の工程により得られた混合物を発泡させる工程とを有する。 In addition, as described above, in another aspect of the foaming method of the hair treatment agent of the present invention that does not use an oil agent having a boiling point of −5 to 80 ° C., the first agent containing the reactive component and the reactive component are combined. And at least one of the first agent and the second agent contains a carbonate, and at least one of the first agent and the second agent contains a surfactant and water. An exothermic agent that generates heat due to water contained in at least one of the first agent and the second agent, and (1) a step of mixing the first agent and the second agent in an open container. And (2) adding and mixing an exothermic agent to the mixture, and (3) foaming the mixture obtained by the steps (2).
すなわち、この実施の形態では炭酸塩があらかじめ第１剤および／または第２剤に含まれているため、いずれかの工程で発泡剤を添加することは必須ではないが、添加することを排除するものではない。 That is, in this embodiment, since the carbonate is contained in the first agent and / or the second agent in advance, it is not essential to add the foaming agent in any step, but the addition is excluded. It is not a thing.
また、前述のとおり、毛髪処理剤が染毛剤であることが好ましく、そのため、本発明の毛髪処理剤の発泡方法も、染毛剤の発泡方法であることが好ましい。 Further, as described above, the hair treatment agent is preferably a hair dye, and therefore, the method for foaming the hair treatment agent of the present invention is also preferably the method for foaming the hair dye.
以下、実施例によって本発明をより具体的に説明するが、本発明はこれに限定されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention more concretely, this invention is not limited to this.
実施例１ ２剤式染毛剤
下記の第１剤４０ｇと下記の第２剤６０ｇを開放容器に充填し、ヘラでかき混ぜた。次いで発泡剤としてイソペンタンを５ｇ添加し、ヘラでかき混ぜた。室温で３分間静置してヘラでかき混ぜ、１分間静置した。
第１剤
パラフェニレンジアミン ３．０
レゾルシン ０．５
ポリオキシエチレンラウリルエーテル ２．０
塩化ステアリルトリメチルアンモニウム １．０
プロピレングリコール ５．０
アンモニア水（２８％） ６．０
香料 ０．１
精製水 ８２．４
合計 １００．０重量％
第２剤
過酸化水素水（３５％） １６．０
ポリオキシエチレンラウリルエーテル硫酸ナトリウム ０．５
ラウリルヒドロキシスルホベタイン ０．１
リン酸 ｐＨを３．５に調整
精製水 残部
合計 １００．０重量％
Example 1 Two-component hair dye 40 g of the following first agent and 60 g of the following second agent were filled in an open container and stirred with a spatula. Next, 5 g of isopentane was added as a foaming agent and stirred with a spatula. The mixture was allowed to stand at room temperature for 3 minutes, stirred with a spatula and allowed to stand for 1 minute.
First agent paraphenylenediamine 3.0
Resorcin 0.5
Polyoxyethylene lauryl ether 2.0
Stearyltrimethylammonium chloride 1.0
Propylene glycol 5.0
Ammonia water (28%) 6.0
Fragrance 0.1
Purified water 82.4
Total 100.0% by weight
Second agent hydrogen peroxide solution (35%) 16.0
Sodium polyoxyethylene lauryl ether sulfate 0.5
Lauryl hydroxysulfobetaine 0.1
Adjust phosphoric acid pH to 3.5
Purified water balance
Total 100.0% by weight
１ 開放容器
２ 第１剤
３ 第２剤
４ フタ
５ 発泡剤
６ 撹拌・塗布具
７ 泡状の毛髪処理剤
Ａ アルミ製のフタ
Ｔ１ チューブ
Ｔ２、Ｔ２ａ、Ｔ２ｂ トレイ
Ｐ１、Ｐ２ パウチ
DESCRIPTION OF SYMBOLS 1 Open container 2 1st agent 3
Claims (10)
前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、
前記発泡剤が、沸点が−５〜８０℃の油剤である毛髪処理剤。 Including a first agent formulated with a reactive component, a second agent formulated with a reactive component, and a foaming agent,
A surfactant and water are contained in at least one of the first agent and the second agent,
A hair treatment agent, wherein the foaming agent is an oil having a boiling point of -5 to 80C.
前記第１剤および前記第２剤の少なくとも一方に炭酸塩が含まれてなり、
前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、
前記第１剤および前記第２剤の少なくとも一方に含まれる水により発熱する発熱剤が含まれてなる毛髪処理剤。 A first agent containing a reactive component and a second agent containing a reactive component;
Carbonate is contained in at least one of the first agent and the second agent,
A surfactant and water are contained in at least one of the first agent and the second agent,
A hair treatment agent comprising an exothermic agent that generates heat due to water contained in at least one of the first agent and the second agent.
前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、
前記発泡剤が、沸点が−５〜８０℃の油剤であり、
（１）前記第１剤と前記第２剤とを開放容器内で混合する工程と、
（２）該混合物に発泡剤を添加し混合する工程と、
（３）（２）の工程により得られた混合物を発泡させる工程と有する毛髪処理剤の発泡方法。 Including a first agent formulated with a reactive component, a second agent formulated with a reactive component, and a foaming agent,
A surfactant and water are contained in at least one of the first agent and the second agent,
The foaming agent is an oil agent having a boiling point of −5 to 80 ° C.,
(1) mixing the first agent and the second agent in an open container;
(2) adding and mixing a foaming agent to the mixture;
(3) A method for foaming a hair treatment agent, comprising a step of foaming the mixture obtained in the step (2).
前記第１剤および前記第２剤の少なくとも一方に炭酸塩が含まれてなり、
前記第１剤および前記第２剤の少なくとも一方に界面活性剤と水が含まれてなり、
前記第１剤および第２剤の少なくとも一方に含まれる水により発熱する発熱剤が含まれてなり、
（１）前記第１剤と前記第２剤とを開放容器内で混合する工程と、
（２）該混合物に発熱剤を添加し混合する工程と、
（３）（２）の工程により得られた混合物を発泡させる工程とを有する毛髪処理剤の発泡方法。 A first agent containing a reactive component and a second agent containing a reactive component;
Carbonate is contained in at least one of the first agent and the second agent,
A surfactant and water are contained in at least one of the first agent and the second agent,
An exothermic agent that generates heat by water contained in at least one of the first agent and the second agent;
(1) mixing the first agent and the second agent in an open container;
(2) adding and mixing an exothermic agent to the mixture;
(3) A method for foaming a hair treatment agent comprising the step of foaming the mixture obtained by the step (2).
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| JP2012006981A (en) * | 2011-10-11 | 2012-01-12 | Hoyu Co Ltd | Hair cosmetic composition and application method thereof |
| JP2012031111A (en) * | 2010-07-30 | 2012-02-16 | Hoyu Co Ltd | Hair cosmetic composition |
| JP2012031114A (en) * | 2010-07-30 | 2012-02-16 | Hoyu Co Ltd | Hair cosmetic composition |
| JPWO2011151880A1 (en) * | 2010-05-31 | 2013-07-25 | ホーユー株式会社 | Set of hair cosmetic composition and foaming tool, and method of using hair cosmetic composition |
| JP2013147279A (en) * | 2012-01-20 | 2013-08-01 | Daizo:Kk | Container body and method for manufacturing the same, and discharge container and discharge product using the container body |
| EP2771070B1 (en) | 2011-10-26 | 2021-07-07 | L'Oréal | Device for self-foaming oxidation dyeing, ready-for-use self-foaming composition and method for dyeing keratinous fibres |
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| JPWO2011151880A1 (en) * | 2010-05-31 | 2013-07-25 | ホーユー株式会社 | Set of hair cosmetic composition and foaming tool, and method of using hair cosmetic composition |
| JP2012031111A (en) * | 2010-07-30 | 2012-02-16 | Hoyu Co Ltd | Hair cosmetic composition |
| JP2012031114A (en) * | 2010-07-30 | 2012-02-16 | Hoyu Co Ltd | Hair cosmetic composition |
| JP2012006981A (en) * | 2011-10-11 | 2012-01-12 | Hoyu Co Ltd | Hair cosmetic composition and application method thereof |
| EP2771070B1 (en) | 2011-10-26 | 2021-07-07 | L'Oréal | Device for self-foaming oxidation dyeing, ready-for-use self-foaming composition and method for dyeing keratinous fibres |
| JP2013147279A (en) * | 2012-01-20 | 2013-08-01 | Daizo:Kk | Container body and method for manufacturing the same, and discharge container and discharge product using the container body |
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