JP2010083948A5 - - Google Patents
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- JP2010083948A5 JP2010083948A5 JP2008252932A JP2008252932A JP2010083948A5 JP 2010083948 A5 JP2010083948 A5 JP 2010083948A5 JP 2008252932 A JP2008252932 A JP 2008252932A JP 2008252932 A JP2008252932 A JP 2008252932A JP 2010083948 A5 JP2010083948 A5 JP 2010083948A5
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- producing
- polybutylene terephthalate
- diol
- esterification reaction
- added
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Description
本発明者らは、上記の目的を達成するために鋭意検討を重ねた結果、本発明に至った。すなわち、本発明は、
(1)テレフタル酸を主成分とするジカルボン酸と1,4−ブタンジオールを主成分とするジオールとを、エステル化反応させた後、次いで重縮合反応させてポリブチレンテレフタレートを製造する方法であって、ジオール化合物含有量が5重量%以下である有機チタン化合物をエステル化反応槽へ添加するポリブチレンテレフタレートの製造方法、
(2)エステル化反応槽へ添加する有機チタン化合物を、エステル化反応槽付属の精留塔底部から還流されるジオール中、及び/または、ジカルボン酸とジオールとのスラリー中へ添加する(1)記載のポリブチレンテレフタレートの製造方法、
(3)ジオール化合物が、1,4−ブタンジオールである(1)または(2)に記載のポリブチレンテレフタレートの製造方法、
(4)有機チタン化合物がテトラ−n−ブチルチタネートである(1)から(3)のいずれかに記載のポリブチレンテレフタレートの製造方法を提供するものである。
As a result of intensive studies to achieve the above object, the present inventors have reached the present invention. That is, the present invention
(1) A method for producing polybutylene terephthalate by subjecting a dicarboxylic acid containing terephthalic acid as a main component to a diol containing 1,4-butanediol as a main component, followed by a polycondensation reaction. Te method of manufacturing Lupo polybutylene terephthalate to adding the organic titanium compound diol compound content is 5 wt% or less to the esterification reaction tank,
(2) The organotitanium compound to be added to the esterification reaction tank is added to the diol refluxed from the bottom of the rectifying column attached to the esterification reaction tank and / or to the slurry of dicarboxylic acid and diol (1) A process for producing the polybutylene terephthalate according to the description,
(3) di-ol compound, a method for manufacturing polybutylene terephthalate described in 1,4-butanediol (1) or (2),
(4) The method for producing polybutylene terephthalate according to any one of (1) to (3), wherein the organic titanium compound is tetra-n-butyl titanate.
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008252932A JP5401897B2 (en) | 2008-09-30 | 2008-09-30 | Method for producing polybutylene terephthalate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008252932A JP5401897B2 (en) | 2008-09-30 | 2008-09-30 | Method for producing polybutylene terephthalate |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2010083948A JP2010083948A (en) | 2010-04-15 |
JP2010083948A5 true JP2010083948A5 (en) | 2011-10-27 |
JP5401897B2 JP5401897B2 (en) | 2014-01-29 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008252932A Active JP5401897B2 (en) | 2008-09-30 | 2008-09-30 | Method for producing polybutylene terephthalate |
Country Status (1)
Country | Link |
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JP (1) | JP5401897B2 (en) |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5015759A (en) * | 1989-12-08 | 1991-05-14 | E. I. Du Pont De Nemours And Company | Process for increasing the direct esterification reaction rate of a diacid with a glycol |
JP2001200045A (en) * | 2000-01-17 | 2001-07-24 | Toray Ind Inc | Catalyst for manufacturing polyester and method for manufacturing polyester |
JP4329567B2 (en) * | 2003-02-28 | 2009-09-09 | 三菱化学株式会社 | Polybutylene terephthalate and polybutylene terephthalate composition |
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2008
- 2008-09-30 JP JP2008252932A patent/JP5401897B2/en active Active
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