JP2009292809A - Skin touch feeling improver and skin cosmetic compounded with the same, and method for improving skin touch feeling - Google Patents
Skin touch feeling improver and skin cosmetic compounded with the same, and method for improving skin touch feeling Download PDFInfo
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Abstract
Description
本発明は感触改善剤及びそれを配合した皮膚化粧料並びに感触改善方法に関する。詳しくは、ケイ酸関連物質を有効成分として含有する肌のすべり性が優れた状態となる感触改善剤及びそれを配合した皮膚化粧料と、当該感触改善剤を使用した感触改善方法に関する。 The present invention relates to a feeling improving agent, a skin cosmetic containing the same, and a feeling improving method. More specifically, the present invention relates to a touch-improving agent containing a silicic acid-related substance as an active ingredient and having excellent skin slipperiness, a skin cosmetic containing the same, and a touch-improving method using the feel-improving agent.
従来、皮膚化粧料に、保湿効果や殺菌効果を高めるため、温泉水やその成分を使用することは知られている。温泉水には特有の臭気があったり、泉質によって効果にばらつきがあるため、源泉を指定して使用する必要がある。また、温泉水の成分である炭酸水素ナトリウムやメタケイ酸塩などの無機塩を用いる場合、その水溶液は高アルカリ性で皮膚刺激性が高いので、クエン酸等の酸で中和して使用する必要がある。 Conventionally, it is known to use hot spring water and its components in skin cosmetics in order to enhance the moisturizing effect and the bactericidal effect. Hot spring water has a specific odor and effects vary depending on the quality of the spring, so it is necessary to specify the source and use it. In addition, when using an inorganic salt such as sodium hydrogen carbonate or metasilicate, which is a component of hot spring water, the aqueous solution is highly alkaline and highly irritating to the skin, so it must be neutralized with an acid such as citric acid. is there.
例えば、温泉水含有の皮膚化粧料の技術（特許文献１参照）や、アセロラ果汁と炭酸水素ナトリウム含有温泉水の組み合わせである化粧料の技術（特許文献２参照）や、特定の鉱泉水、湯の花を含有する皮膚外用剤（特許文献３参照）や、ケイ酸関連物質を含有するコラーゲン代謝改善剤（特許文献４参照）や、ケイ酸関連物質とカルシウムを含有した表皮角化促進剤（特許文献５参照）があった。 For example, the technology of skin cosmetics containing hot spring water (see Patent Document 1), the technology of cosmetics that is a combination of acerola fruit juice and sodium bicarbonate-containing hot spring water (see Patent Document 2), specific mineral spring water, hot spring flowers Skin external preparations containing selenium (see Patent Document 3), collagen metabolism improving agents containing silicate-related substances (see Patent Document 4), and epidermis keratinization promoters containing silicate-related substances and calcium (Patent Documents) 5).
一方、従来の感触改善剤としては、例えば、動植物エキス、３−１−メトキシプロパン−１，２−ジオール等（特許文献６参照）や、シリコーン類、加水分解蛋白、リン脂質等（特許文献７参照）のように化粧料等の任意成分として用いられるもののほかに、ヒドロキシカルボン酸遷移金属塩を有効成分とする毛髪感触改善剤（特許文献８参照）や、植物油脱臭留出物からトコフェロールを抽出、分離、精製する際に得られる副産物を蒸留、脂肪酸エステル化、脱色、脱臭して調製される組成物及び植物由来の油脂を含有する毛髪化粧料用感触向上剤（特許文献９参照）などがある。 On the other hand, examples of conventional feel-improving agents include animal and plant extracts, 3-1-methoxypropane-1,2-diol (see Patent Document 6), silicones, hydrolyzed proteins, phospholipids, and the like (Patent Document 7). In addition to those used as optional ingredients such as cosmetics as in (see Fig.), Tocopherols are extracted from hair feel improving agents containing hydroxycarboxylic acid transition metal salts as active ingredients (see Patent Document 8) and vegetable oil deodorized distillates. , A composition prepared by distillation, fatty acid esterification, decolorization, and deodorization of by-products obtained during separation and purification, and a hair cosmetic feel improver containing plant-derived fats and oils (see Patent Document 9) is there.
しかしながら、特許文献１の技術では、温泉水の成分中の陽イオンによる効果の提案であり、本発明のケイ酸関連物質については何ら触れられていなかった。特許文献２の技術では、ビタミンＣの安定化による美肌効果の提案であり、本発明の感触改善に関する記載はなかった。特許文献３の技術では、リパーゼ阻害及び抗菌効果の提案であり、本発明の感触改善に関する記載はなかった。特許文献４の技術では、コラーゲン代謝を改善する化粧品の技術であり、本発明の感触改善に関する記載はなかった。特許文献５の技術では、皮膚バリアー機能を改善する化粧料の技術であり、本発明の感触改善に関する記載はなかっ
た。
However, the technique of Patent Document 1 is a proposal of an effect by a cation in a component of hot spring water, and the silicic acid related substance of the present invention is not mentioned at all. The technique of Patent Document 2 is a proposal of a skin beautifying effect by stabilizing vitamin C, and there is no description about the touch improvement of the present invention. The technique of Patent Document 3 is a proposal of lipase inhibition and antibacterial effect, and there is no description about the touch improvement of the present invention. The technique of Patent Document 4 is a cosmetic technique for improving collagen metabolism, and there is no description regarding the improvement in touch of the present invention. The technique of Patent Document 5 is a cosmetic technique for improving the skin barrier function, and there is no description about the touch improvement of the present invention.
また、上記特許文献６〜９のいずれにおいても、ケイ酸関連物質による感触改善効果について何ら示唆されていなかった。特に特許文献８、９は毛髪の感触改善を目的とするものであり、他の多くの技術も毛髪を対象とするものであった。 Moreover, in any of the above Patent Documents 6 to 9, there is no suggestion about the touch improving effect by the silicic acid related substance. In particular, Patent Documents 8 and 9 are intended to improve the feel of hair, and many other techniques are also intended for hair.
上記の状況に鑑み、本発明は、べた付かず、なめらかな使用感で、肌のすべり性に優れた、低刺激で安全性の優れる感触改善剤及びそれを配合した皮膚化粧料を提供することを課題とする。さらに、当該感触改善剤を使用した感触改善方法を提供することを課題とする。 In view of the above situation, the present invention is to provide a touch-improving agent that is non-sticky, has a smooth feeling of use, is excellent in slipperiness of the skin, is low in irritation and excellent in safety, and a skin cosmetic containing the same. Is an issue. It is another object of the present invention to provide a feel improving method using the feel improving agent.
本発明者は、上記課題を解決するために鋭意研究を重ねた結果、特定のケイ酸関連物質が肌のすべり性が優れた状態となる感触改善剤としての効果を有することを見いだした。すなわち本発明の第１の要旨は、メタケイ酸ナトリウム、オルトケイ酸ナトリウム、水ガラスからなる群より選ばれる１種または２種以上のケイ酸関連物質を有効成分として含有することを特徴とする感触改善剤である。 As a result of intensive studies in order to solve the above problems, the present inventor has found that a specific silicic acid-related substance has an effect as a touch-improving agent that makes the skin slippery. That is, the first gist of the present invention is a touch improvement characterized by containing, as an active ingredient, one or more silicate-related substances selected from the group consisting of sodium metasilicate, sodium orthosilicate, and water glass. It is an agent.
また、皮膚化粧料に上記感触改善剤を配合すると、刺激が無く、しっとり感、肌のすべり性、保存安定性に優れたものとなることを見いだした。すなわち、本発明の第２の要旨は、メタケイ酸ナトリウム、オルトケイ酸ナトリウム、水ガラスからなる群より選ばれる１種または２種以上のケイ酸関連物質を有効成分として含有する感触改善剤を配合した皮膚化粧料である。 Further, it has been found that when the above-mentioned feel-improving agent is added to the skin cosmetic, there is no irritation and the skin feels moist, smooth on the skin, and excellent in storage stability. That is, the second gist of the present invention is a blend of a feel improver containing as an active ingredient one or more silicate-related substances selected from the group consisting of sodium metasilicate, sodium orthosilicate, and water glass. It is a skin cosmetic.
さらに、上記感触改善剤を皮膚に塗布して使用することで、皮膚のｐＨ緩衝力により、ケイ酸関連物質が弱酸性下でケイ酸として析出、皮膚上に均一に付着して上記課題を解決し得ることを見いだし、本発明を完成するに至った。すなわち本発明の第２の要旨は、メタケイ酸ナトリウム、オルトケイ酸ナトリウム、水ガラスからなる群より選ばれる１種または２種以上のケイ酸関連物質を有効成分として含有する感触改善剤を皮膚に塗布して使用することを特徴とする感触改善方法である。 Furthermore, by applying the above-mentioned feel-improving agent to the skin, the pH buffering power of the skin causes the silicic acid-related substance to precipitate as silicic acid under weak acidity and adhere uniformly on the skin, thus solving the above-mentioned problems. As a result, the present invention has been completed. That is, the second gist of the present invention is to apply to the skin a feel improving agent containing as an active ingredient one or more silicate-related substances selected from the group consisting of sodium metasilicate, sodium orthosilicate, and water glass. It is the touch improvement method characterized by using it.
本発明は、ケイ酸関連物質を有効成分として含有する感触改善剤により、べた付かず、なめらかな使用感で、肌のすべり性に優れた、低刺激で安全性の優れる感触改善剤を提供することができる。そして、上記感触改善剤を配合した皮膚化粧料も、べた付かず、なめらかな使用感で、肌のすべり性に優れた、低刺激で安全性の優れる効果が得られる。また、上記感触改善剤を皮膚に塗布することで、べた付かず、なめらかな使用感で、肌のすべり性に優れた、低刺激で安全性の優れる感触改善方法を提供することができる。 The present invention provides a feel-improving agent that is non-sticky, has a smooth feeling of use, has excellent skin slipperiness, and is low in irritation and excellent in safety by using a feel-improving agent containing a silicate-related substance as an active ingredient. be able to. And the skin cosmetics which mix | blended the said feeling improving agent are also non-sticky, and the smooth feeling of use is excellent in the slipperiness of the skin, and the effect which is excellent in the low irritation | stimulation and safety | security is acquired. In addition, by applying the above-mentioned feel improving agent to the skin, it is possible to provide a touch improving method which is smooth and has a smooth feeling of use, excellent skin slipperiness, low irritation and excellent safety.
一般にケイ酸関連物質としては、メタケイ酸，オルトケイ酸，メタ二ケイ酸，メタ三ケイ酸等のケイ酸及びそれらのナトリウム塩，カリウム塩，マグネシウム塩，アルミニウム塩，カルシウム塩等が挙げられるが、ケイ酸塩は、水に不溶であること、メタケイ酸、オルトケイ酸は溶液中にしか存在しないこと、メタケイ酸塩、オルトケイ酸塩のカルシウム塩、マグネシウム塩は水に不溶であることから、本発明の感触改善剤に用いるケイ酸関連物質としては、水溶性のメタケイ酸ナトリウム、オルトケイ酸ナトリウム、水ガラスが挙げられ、これらの１種または２種以上を配合する。 In general, silicic acid-related substances include silicic acid such as metasilicic acid, orthosilicic acid, metadisilicic acid, metatrisilicic acid, and sodium salts, potassium salts, magnesium salts, aluminum salts, and calcium salts thereof. Since silicate is insoluble in water, metasilicate and orthosilicate are only present in solution, metasilicate, calcium salt of orthosilicate, and magnesium salt are insoluble in water. Examples of the silicic acid-related substance used for the feel-improving agent include water-soluble sodium metasilicate, sodium orthosilicate, and water glass, and one or more of these are blended.
本発明の感触改善剤で用いるケイ酸関連物質の製剤への配合量は、感触改善剤に対して０．０００１〜０．５質量％の範囲にあることが好ましく、さらに好ましくは０．００１〜
０．１質量％の範囲である。０．５質量％以上であると、皮膚のｐＨ緩衝力を超えてしまい、ケイ酸関連物質が高アルカリ性のまま皮膚上に残って刺激が生じるため好ましくない場合がある。また、０．０００１質量％未満では、ケイ酸が皮膚上に均一に付着しないため十分な効果を得ることができない場合がある。
The blending amount of the silicic acid-related substance used in the feel-improving agent of the present invention in the preparation is preferably in the range of 0.0001 to 0.5% by mass, more preferably 0.001 to 0.001%.
The range is 0.1% by mass. If it is 0.5% by mass or more, the pH buffering power of the skin may be exceeded, and the silicate-related substance may remain on the skin while remaining highly alkaline, resulting in irritation. Moreover, if it is less than 0.0001 mass%, since silicic acid does not adhere uniformly on the skin, a sufficient effect may not be obtained.
本発明の感触改善剤のｐＨは、特に限定されるものではないが、２０℃でのｐＨが８〜１２であることが望ましい。ケイ酸関連物質の水溶液は高アルカリ性であるため、ＰＨ８以下であると、クエン酸等の酸で中和する必要が生じ、べた付いたり、保存時に結晶が析出する場合があること。また、ｐＨ１２以上であると、高アルカリ性のまま皮膚上に残って刺激が生じるため好ましくない場合がある。 The pH of the feel improving agent of the present invention is not particularly limited, but it is desirable that the pH at 20 ° C. is 8-12. Since the aqueous solution of silicic acid-related substances is highly alkaline, it must be neutralized with an acid such as citric acid if the pH is 8 or less, and it may become sticky or crystals may precipitate during storage. Further, if the pH is 12 or more, it may be unpreferable because irritation occurs on the skin while remaining highly alkaline.
本発明の感触改善剤の使用方法としては、皮膚に直接塗布してもよいが、コットン、ティッシュペーパー、不織布等の含浸可能な材質のものに適量含ませて、ふき取って使用する方法が好ましい。コットン等でふき取ることにより、析出したケイ酸が皮膚上に均一に付着しやすくなり、肌実感において好感触を得ることができる。また、本発明の感触改善剤を皮膚に塗布した後に、化粧水、乳液等を使用することも出来る。 As a method of using the feel-improving agent of the present invention, it may be applied directly to the skin, but a method of wiping and using an appropriate amount of an impregnable material such as cotton, tissue paper, and non-woven fabric is preferred. By wiping with cotton or the like, the precipitated silicic acid easily adheres uniformly to the skin, and a good feel can be obtained in terms of skin feeling. In addition, after applying the feel-improving agent of the present invention to the skin, a lotion, emulsion, or the like can be used.
本発明の感触改善剤には、上記原料の他、一般に化粧料に適用される各種の原料や成分を、本発明の効果を損ねない範囲で適宜配合することができる。このような原料・成分としては、多価アルコール、水、界面活性剤、紫外線吸収剤、香料、防腐剤、殺菌剤、酸化防止剤、キレート剤、薬剤、植物エキス、色素等が挙げられる。 In addition to the above raw materials, various raw materials and components that are generally applied to cosmetics can be appropriately blended with the feel improving agent of the present invention as long as the effects of the present invention are not impaired. Examples of such raw materials / components include polyhydric alcohols, water, surfactants, ultraviolet absorbers, fragrances, preservatives, bactericides, antioxidants, chelating agents, drugs, plant extracts, and pigments.
本発明の感触改善剤は、化粧水、美容液、乳液、クリーム、ボディローション等の皮膚化粧料に配合することが出来る。さらに、製品の形態についても特に制限はないが液状、二層状、ジェル状、乳液状等に適用が可能である。 The feel-improving agent of the present invention can be blended in skin cosmetics such as lotions, cosmetic liquids, emulsions, creams, body lotions and the like. Further, the form of the product is not particularly limited, but can be applied to liquid, double-layered, gel-like, and emulsion.
以下、実施例及び比較例をもって本発明をさらに詳しく説明する。本発明は、以下の実施例によって何ら限定されるものではない。なお、以下の実施例を含め、本発明の全説明において、配合割合は全て質量％である。 Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples. The present invention is not limited in any way by the following examples. In addition, in all description of this invention including a following example, all the mixture ratios are the mass%.
《実施例１〜１１、比較例１〜２》
（感触改善剤の製法）
精製水に表１に示す各成分を室温にて溶解して実施例１〜１１及び比較例１〜２の感触改善剤を調製した。
<< Examples 1-11, Comparative Examples 1-2 >>
(Production method of feel improver)
The components shown in Table 1 were dissolved in purified water at room temperature to prepare the feel improvers of Examples 1 to 11 and Comparative Examples 1 and 2.
（官能評価）
この１３種類の感触調整剤を、熟練したパネラー２０名がそれぞれ使用し、（イ）使用感（肌のなめらか感、べたつきの無さ及びすべり性の３項目）、（ロ）刺激感の無さ（１項目）の４項目について官能評価を実施し、表１に示す評価を得た。なお、評価基準は下記に示す。
(sensory evaluation)
Thirteen experienced panelists use each of these 13 types of feel modifiers. (I) Feeling of use (smooth skin feeling, non-stickiness and slipperiness), (b) No irritation Sensory evaluation was performed on four items (one item), and the evaluations shown in Table 1 were obtained. The evaluation criteria are shown below.
２０名中「良い」と答えた人数 評 価
１５人以上 ◎
１０〜１４人 ○
５〜９人 △
０〜４人 ×
Number of people who answered “good” among 20 people Evaluation 15 people or more ◎
10-14 people ○
5-9 people △
0-4 people ×
（保存安定性評価）
実施例および比較例のサンプルをガラスビンに入れ、５℃と４０℃で１ヶ月間放置後の状
態及び外観を観察し、異常が認められる場合（変色、析出）を×で表し、異常が認められない場合を○で表した。
(Storage stability evaluation)
Samples of Examples and Comparative Examples were placed in glass bottles and observed after standing for 1 month at 5 ° C and 40 ° C. When abnormalities were observed (discoloration, precipitation), x was indicated and abnormalities were observed. The case where there was no is represented by ○.
表１から明らかなように、比較例の感触改善剤は、使用感に関する３項目（肌のなめらか感、べたつきの無さ及びすべり性）のうち２項目以上が実施例より劣っていた。 As is apparent from Table 1, the feel improving agent of the comparative example was inferior to the examples in 2 items or more out of 3 items (smooth skin feeling, non-stickiness and slipperiness) regarding the feeling of use.
以下、本発明の感触改善剤を配合した各種皮膚化粧料の処方例を実施例として示す。 Hereinafter, formulation examples of various skin cosmetics containing the feel improving agent of the present invention will be shown as examples.
《実施例１２》
化粧水
エタノール １０．０
メタケイ酸ナトリウム ０．０１
オレンジ果汁（香栄興業（株）製） １．０
炭酸水素ナトリウム ０．０１
炭酸ナトリウム ０．０１
ＥＤＴＡ−４Ｎａ ０．０１
フェノキシエタノール ０．０５
香料 適 量
精製水 残 余
（合計１００）
Example 12
Lotion Ethanol 10.0
Sodium metasilicate 0.01
Orange juice (manufactured by Koei Kogyo Co., Ltd.) 1.0
Sodium bicarbonate 0.01
Sodium carbonate 0.01
EDTA-4Na 0.01
Phenoxyethanol 0.05
Perfume appropriate amount Purified water residue
(100 in total)
常法により調製した実施例１２の化粧水は、刺激が無く、肌のなめらかさ、すべり性、保存安定性に優れたものであった。 The lotion of Example 12 prepared by a conventional method had no irritation and was excellent in skin smoothness, slipperiness and storage stability.
《実施例１３》
美容液
グリセリン ５．０
１．３ブチレングリコール ５．０
エタノール ３．０
メタケイ酸ナトリウム ０．００１
コモソルブルＳＡ（セーレン社製） ０．１
カルボマー ０．１２
水酸化カリウム ０．０５
ＥＤＴＡ−４Ｎａ ０．０１
ユーキシルＰＥ９０１０ ０．１
香料 適 量
精製水 残 余
（合計１００）
Example 13
Essence Glycerin 5.0
1.3 Butylene glycol 5.0
Ethanol 3.0
Sodium metasilicate 0.001
Como Soluble SA (manufactured by Seiren) 0.1
Carbomer 0.12
Potassium hydroxide 0.05
EDTA-4Na 0.01
Euxyl PE9010 0.1
Perfume appropriate amount Purified water residue
(100 in total)
常法により調製した実施例１３の美容液は、刺激が無く、しっとり感、肌のすべり性、保存安定性に優れたものであった。 The cosmetic liquid of Example 13 prepared by a conventional method had no irritation and was excellent in moist feeling, skin slipperiness and storage stability.
《実施例１４》
クリーム
メタケイ酸ナトリウム ０．００１
リン脂質（コートソームＮＣ−２１（日油（株）社製） １．０
コレステロール ０．３
ケルトロール ０．１
カルボマー ０．２
（アクリル酸／アクリル酸アルキル（Ｃ１０−３０））
コポリマー ０．１
グレープシード油 ５．０
グリセリン １０．０
１．３ブチレングリコール １２．０
水酸化カリウム ０．０６
ＥＤＴＡ−４Ｎａ ０．０１
フェノキシエタノール ０．１
香料 適 量
精製水 残 余
（合計１００）
Example 14
Cream sodium metasilicate 0.001
Phospholipid (Coatsome NC-21 (manufactured by NOF Corporation) 1.0
Cholesterol 0.3
Celtrol 0.1
Carbomer 0.2
(Acrylic acid / alkyl acrylate (C10-30))
Copolymer 0.1
Grape seed oil 5.0
Glycerin 10.0
1.3 Butylene glycol 12.0
Potassium hydroxide 0.06
EDTA-4Na 0.01
Phenoxyethanol 0.1
Perfume appropriate amount Purified water residue
(100 in total)
常法により調製した実施例１４のクリームは、刺激が無く、しっとり感、肌のすべり性、保存安定性に優れたものであった。 The cream of Example 14 prepared by a conventional method had no irritation and was excellent in moist feeling, skin slipperiness and storage stability.
《実施例１５》
ボディローション
１．３ブチレングリコール １５．０
メタケイ酸ナトリウム ０．０５
エタノール ５．０
アロエエキス（香栄興業（株）製） １．５
水溶性セラミドＲＣ（一丸ファルコス社製） ０．１
メチルパラベン ０．１
香料 適 量
精製水 残 余
（合計１００）
Example 15
Body Lotion 1.3 Butylene Glycol 15.0
Sodium metasilicate 0.05
Ethanol 5.0
Aloe extract (manufactured by Koei Kogyo Co., Ltd.) 1.5
Water-soluble ceramide RC (Ichimaru Falcos) 0.1
Methylparaben 0.1
Perfume appropriate amount Purified water residue
(100 in total)
常法により調製した実施例１５のボディローションは、べた付かず、肌のなめらかさ、肌のすべり性、保存安定性に優れたものであった。 The body lotion of Example 15 prepared by a conventional method was not sticky and had excellent skin smoothness, skin slipperiness and storage stability.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009095460A JP2009292809A (en) | 2008-05-09 | 2009-04-10 | Skin touch feeling improver and skin cosmetic compounded with the same, and method for improving skin touch feeling |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008123056 | 2008-05-09 | ||
| JP2009095460A JP2009292809A (en) | 2008-05-09 | 2009-04-10 | Skin touch feeling improver and skin cosmetic compounded with the same, and method for improving skin touch feeling |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2009292809A true JP2009292809A (en) | 2009-12-17 |
Family
ID=41541336
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009095460A Pending JP2009292809A (en) | 2008-05-09 | 2009-04-10 | Skin touch feeling improver and skin cosmetic compounded with the same, and method for improving skin touch feeling |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2009292809A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015009694A1 (en) * | 2013-07-15 | 2015-01-22 | The Procter & Gamble Company | Applied films for smoothing wrinkles and skin texture imperfections |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58152805A (en) * | 1982-03-06 | 1983-09-10 | Masayuki Shirai | Skin cosmetic containing hot spring water |
| JPS62194859A (en) * | 1986-02-21 | 1987-08-27 | 松下電器産業株式会社 | Bath furnace |
| JPS6322008A (en) * | 1986-05-09 | 1988-01-29 | エクソバ−，インコ−ポレイテイド | Wrinkle-removing cosmetic composition |
| JPH04364119A (en) * | 1991-06-11 | 1992-12-16 | Tsumura & Co | Bathing agent composition |
| JPH07188036A (en) * | 1993-12-27 | 1995-07-25 | Kanebo Ltd | Collagen metabolism improving agent, cosmetics and bathing medicine |
| JPH07238013A (en) * | 1994-02-25 | 1995-09-12 | Tsumura & Co | Bathing agent composition |
| JPH07309743A (en) * | 1994-05-16 | 1995-11-28 | Kanebo Ltd | Bathing agent composition |
| JPH09263529A (en) * | 1996-03-29 | 1997-10-07 | Kanebo Ltd | Epidermal cornification accelerator |
| JPH10316575A (en) * | 1997-05-16 | 1998-12-02 | Kanebo Ltd | Epidermis keratinization-promoting agent |
| JP2006069901A (en) * | 2004-08-31 | 2006-03-16 | Zaiho:Kk | Skin cosmetic and method for producing the same |
-
2009
- 2009-04-10 JP JP2009095460A patent/JP2009292809A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58152805A (en) * | 1982-03-06 | 1983-09-10 | Masayuki Shirai | Skin cosmetic containing hot spring water |
| JPS62194859A (en) * | 1986-02-21 | 1987-08-27 | 松下電器産業株式会社 | Bath furnace |
| JPS6322008A (en) * | 1986-05-09 | 1988-01-29 | エクソバ−，インコ−ポレイテイド | Wrinkle-removing cosmetic composition |
| JPH04364119A (en) * | 1991-06-11 | 1992-12-16 | Tsumura & Co | Bathing agent composition |
| JPH07188036A (en) * | 1993-12-27 | 1995-07-25 | Kanebo Ltd | Collagen metabolism improving agent, cosmetics and bathing medicine |
| JPH07238013A (en) * | 1994-02-25 | 1995-09-12 | Tsumura & Co | Bathing agent composition |
| JPH07309743A (en) * | 1994-05-16 | 1995-11-28 | Kanebo Ltd | Bathing agent composition |
| JPH09263529A (en) * | 1996-03-29 | 1997-10-07 | Kanebo Ltd | Epidermal cornification accelerator |
| JPH10316575A (en) * | 1997-05-16 | 1998-12-02 | Kanebo Ltd | Epidermis keratinization-promoting agent |
| JP2006069901A (en) * | 2004-08-31 | 2006-03-16 | Zaiho:Kk | Skin cosmetic and method for producing the same |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015009694A1 (en) * | 2013-07-15 | 2015-01-22 | The Procter & Gamble Company | Applied films for smoothing wrinkles and skin texture imperfections |
| CN105377219A (en) * | 2013-07-15 | 2016-03-02 | 宝洁公司 | Applied films for smoothing wrinkles and skin texture imperfections |
| US10307346B2 (en) | 2013-07-15 | 2019-06-04 | The Procter & Gamble Company | Applied films for smoothing wrinkles and skin texture imperfections |
| US10682292B2 (en) | 2013-07-15 | 2020-06-16 | The Procter & Gamble Company | Applied films for smoothing wrinkles and skin texture imperfections |
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