JP2009235029A - Oil-in-water type cosmetic for eyelash - Google Patents
Oil-in-water type cosmetic for eyelash Download PDFInfo
- Publication number
- JP2009235029A JP2009235029A JP2008085762A JP2008085762A JP2009235029A JP 2009235029 A JP2009235029 A JP 2009235029A JP 2008085762 A JP2008085762 A JP 2008085762A JP 2008085762 A JP2008085762 A JP 2008085762A JP 2009235029 A JP2009235029 A JP 2009235029A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- water
- cosmetic
- fiber
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940118846 witch hazel Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、水中油型睫用化粧料に関し、更に詳しくは、ナイロン１２系の繊維と水不溶性皮膜形成ポリマーを配合し、かつその稠度を調整することにより、睫を長く見せ、目元を際立たせる化粧効果に優れ、睫への繊維の付着性が良好で束付きや枝分かれのない均一な化粧膜を形成させることができ、仕上がりの化粧膜のツヤ感に優れ、化粧膜の負担感がなく、さらには、繊維が睫からはがれずに目元に落ちてこないといった化粧持ちに優れた水中油型睫用化粧料に関するものである。 The present invention relates to an oil-in-water cosmetic for cosmetics, and more specifically, blends nylon 12 fibers and a water-insoluble film-forming polymer, and adjusts the consistency of the cosmetic to make the eyelids look longer and make the eyes stand out. Excellent makeup effect, good adhesion of fibers to wrinkles, can form uniform makeup film without bundling and branching, excellent gloss of finished makeup film, no burden of makeup film, Furthermore, the present invention relates to an oil-in-water cosmetic for cosmetics that is excellent in longevity such that the fibers do not come off the eyelids and do not fall into the eyes.
睫用化粧料は、睫を上にカールすることや、睫を太く、長くみせることで、目元をはっきりと美しく際立たせることを目的として使用される化粧料である。 Cosmetics for eyelids are cosmetics that are used for curling the eyelids upward and making the eyelashes thick and long to make the eyes clearly and beautifully stand out.
従来、このような睫用化粧料は、固形状油分、例えばワックスと、粉体、皮膜形成剤、水溶性高分子、繊維等を中心に構成されており、化粧品として求められる様々な使用性、使用感、および機能性をもたせるために、種々の剤型および原料の配合検討が行われてきた。 Conventionally, such cosmetics for wrinkles are mainly composed of solid oils such as waxes, powders, film forming agents, water-soluble polymers, fibers, etc., and various usability required for cosmetics, In order to give usability and functionality, various dosage forms and blending of raw materials have been studied.
特に、睫を長く見せ、目元を際立たせる化粧効果を演出する方法として、種々の繊維の配合検討が行われてきた。例えば、ポリプロピレン繊維と油溶性樹脂を配合することで、睫を長く見せ、目元を際立たせる化粧効果や睫を上にカールしたまま固定することで目元を際立たせるといった化粧効果を高める技術（例えば特許文献１参照）が知られていた。 In particular, various fiber blending studies have been conducted as a method of producing a makeup effect that makes the eyelids look longer and makes the eyes stand out. For example, by blending polypropylene fiber and oil-soluble resin, a technology that enhances the makeup effect that makes the eyelid look longer and makes the eye stand out, and the makeup effect that makes the eye stand out by fixing the eyelid while curling up (for example, patents) Reference 1) was known.
また、油溶性皮膜形成性樹脂と揮発性油剤および繊維を配合することで睫を長く見せ、目元を際立たせる化粧効果とその持続性の向上および均一な仕上がり膜を得る技術（例えば特許文献２参照）が知られていた。さらに、製品中での分散性を向上し、均一な化粧膜を形成させ、また繊維の付着性を均一にさせるためにフッ素化合物で表面処理した繊維を用いる技術（例えば特許文献３参照）が知られていた。 In addition, a technique for obtaining a uniform finish film by improving the long-lasting cosmetic effect and making the eyes stand out by blending an oil-soluble film-forming resin, a volatile oil agent, and fibers (for example, see Patent Document 2). ) Was known. Furthermore, a technique using a fiber surface-treated with a fluorine compound in order to improve dispersibility in a product, form a uniform decorative film, and make the adhesion of the fiber uniform (see, for example, Patent Document 3) is known. It was done.
しかしながら、特許文献１の技術では、睫を長く見せ、また睫を上にカールさせ目元を際立たせる化粧効果は得られるものの、配合するポリプロピレン繊維が固いため、配合量が増加すると化粧膜の負担感が大きくなるといった欠点があった。また、特許文献２の技術では、睫を長く見せ、目元を際立たせる化粧効果とその持続性の向上や、均一な仕上がり膜を得ることができるものの、樹脂の配合量が増加するにつれ、化粧膜の負担感が大きくなり、さらに、繊維の配合量を増加させると、化粧膜のにじみのなさは演出できるものの、繊維自体が目元に落ちてきてしまい、繊維の化粧持ちが悪化するといった欠点があった。さらに、特許文献３の技術では、均一な化粧膜と付着性の向上を演出することができるものの、繊維自体が白いため、分散性があがることにより、化粧膜が白ぼけてしまい、化粧膜のツヤ感が失われるといった欠点があった。また、これらの繊維を配合する際に、バルク粘度が高く、繊維を分散するために大きなせん断（シェア）力がかかると繊維が湾曲してしまい、繊維の化粧持ちが悪化したり、化粧膜の均一性が失われることがあった。 However, in the technique of Patent Document 1, although a cosmetic effect that makes the eyelids look longer and curls the eyelids to make the eyes stand out is obtained, the blended polypropylene fibers are hard, so if the amount added increases, the burden of the cosmetic film is felt. There was a drawback that became larger. Moreover, although the technique of patent document 2 can improve the makeup effect and its sustainability that make wrinkles look longer and make the eyes stand out, and obtain a uniform finished film, the cosmetic film increases as the blending amount of the resin increases. However, if the fiber content is increased, the non-bleeding of the decorative film can be produced, but the fibers themselves fall into the eyes and the makeup of the fibers deteriorates. It was. Furthermore, although the technique of Patent Document 3 can produce a uniform decorative film and improved adhesion, since the fiber itself is white, dispersibility increases, and the decorative film becomes blurred. There was a drawback that the glossiness was lost. In addition, when blending these fibers, the bulk viscosity is high, and if a large shearing (shear) force is applied to disperse the fibers, the fibers will bend and the makeup of the fibers will deteriorate, Uniformity may be lost.
従って、繊維を配合していながら、このものの睫への付着性が良好で、束付きや枝分かれのない均一な化粧膜を形成させることができ、仕上がりの化粧膜のツヤ感に優れ、化粧膜の負担感がなく、さらには、繊維が睫からはがれずに目元に落ちてこないといった化粧持ちに優れた睫用化粧料の開発が望まれており、このような化粧料を提供することが本発明の課題である。 Therefore, while blending the fiber, it has good adhesion to wrinkles, can form a uniform decorative film without bundling or branching, and has excellent gloss of the finished decorative film. There is a demand for the development of cosmetics for eyelashes that have excellent makeup durability, such that there is no feeling of burden and the fibers do not come off the eyelids and do not fall into the eyes. It is a subject of the invention.
本発明者は、上記課題を解決した睫用化粧料を得るべく鋭意研究を行った結果、繊維としてナイロン１２であるものを選び、これを水不溶性皮膜形成ポリマーと組み合わせ、更にその稠度を特定の範囲とした水中油型睫用化粧料は、湾曲することなく睫に付着し、睫を長く見せ、目元を際立たせる化粧効果に優れ、睫への繊維の付着性が良好で束付きや枝分かれのない均一な化粧膜を形成させることができるものであること、しかもこのものは化粧膜のツヤ感に優れ、化粧膜の負担感がなく、繊維が睫からはがれずに目元に落ちてこないものであることを見出し、本発明を完成するに至った。 As a result of intensive research to obtain a vaginal cosmetic that has solved the above-mentioned problems, the present inventor has selected nylon 12 as a fiber, combined it with a water-insoluble film-forming polymer, and further determined its consistency. The range of oil-in-water cosmetics for cocoons adheres to the cocoon without bending, has a cosmetic effect that makes the cocoon look longer and makes the eyes stand out, has good fiber adhesion to the cocoon, and is bundled and branched. It is capable of forming a uniform decorative film, and it is excellent in the gloss of the decorative film, there is no burden of the decorative film, and the fibers do not peel off the eyelids and do not fall into the eyes As a result, the present invention has been completed.
すなわち、本発明は、次の成分（Ａ）、（Ｂ）、（Ｃ）および（Ｄ）
（Ａ）ナイロン１２繊維
（Ｂ）水不溶性皮膜形成ポリマー
（Ｃ）水
（Ｄ）油性成分
を配合し、２号アルミコーンを用いて３０℃にて測定した稠度値が１７０〜３５０であることを特徴とする水中油型睫用化粧料を提供するものである。
That is, the present invention comprises the following components (A), (B), (C) and (D)
(A) Nylon 12 fiber (B) Water-insoluble film-forming polymer (C) Water (D) Oil component is blended, and the consistency value measured at 30 ° C. using No. 2 aluminum cone is 170-350. An oil-in-water type cosmetic for salmon characterized by the above is provided.
本発明の水中油型睫用化粧料は、柔軟性に富み、睫に塗布する際、湾曲することなく均一に睫に付着するナイロン１２繊維を使用し、かつその稠度を上記の範囲としたものであるため、湾曲することなく睫に付着し、睫を長く見せ、目元を際立たせる化粧効果に優れ、睫への繊維の付着性が良好で束付きや枝分かれのない均一な化粧膜を形成させることができるものである。また、仕上がりの化粧膜のツヤ感に優れ、化粧膜の負担感がなく、さらには、繊維が睫からはがれずに目元に落ちてこないといった化粧持ちに優れた睫用化粧料となる。 The oil-in-water cosmetic for cosmetics of the present invention is rich in flexibility, and uses nylon 12 fiber that adheres uniformly to the cocoon without bending when applied to the cocoon, and its consistency is in the above range. Therefore, it adheres to the wrinkles without curving, has an excellent makeup effect that makes the wrinkles look longer, makes the eyes stand out, has good fiber adhesion to the wrinkles, and forms a uniform makeup film without bundling or branching It is something that can be done. In addition, the finished cosmetic film is excellent in gloss, has no burden on the cosmetic film, and further has a cosmetic makeup with excellent makeup, such as fibers not coming off the eyelids and falling into the eyes.
本発明の水中油型睫用化粧料に用いられる成分（Ａ）は、柔軟性に富み、睫に塗布する際、湾曲することなく均一に睫に付着するため、睫を長く見せ、目元を際立たせる化粧効果、束付きや枝分かれのない均一な化粧膜の形成、仕上がりの化粧膜のツヤ感、化粧膜の負担感のなさ、および繊維が睫からはがれずに目元に落ちてこないといった化粧持ちを演出するものである。ここで、「ナイロン１２」とは、ラウリルラクタムを開環重縮合したポリアミドである。 The component (A) used in the oil-in-water cosmetic for cosmetics according to the present invention is rich in flexibility and uniformly adheres to the cocoon without bending when applied to the cocoon, so that the cocoon looks long and the eyes are conspicuous. Make-up effect, uniform bundling with no bundling or branching, glossiness of finished cosmetic film, no burden of cosmetic film, and long-lasting makeup that fibers do not peel off the eyelids Is to produce. Here, “nylon 12” is a polyamide obtained by ring-opening polycondensation of lauryl lactam.
本発明に用いられる成分（Ａ）の繊維は、ＪＩＳ−Ｌ１０１５に記載の方法でその伸度を測定したときに、７０％以上の伸度を示すものであることが、化粧膜の負担感のなさや、繊維が睫からはがれずに目元に落ちてこないといった化粧持ちを演出する点で好ましく、特に伸度８０％以上のものであることがより好ましい。 The fiber of the component (A) used in the present invention exhibits an elongation of 70% or more when measured for elongation by the method described in JIS-L1015. It is preferable from the standpoint of producing a long lasting appearance such that the fibers do not come off the eyelids without falling off the eyelids, and more preferably those having an elongation of 80% or more.
また、本発明に用いられる成分（Ａ）の繊維の太さは、０.１〜２０デシテックス（以下、単に「ｄｔｅｘ」と示す）であることが、睫を長く見せ、目元を際立たせる化粧効果や、化粧膜の負担感のなさの点で好ましく、１〜１０ｄｔｅｘがより好ましい。 In addition, the fiber thickness of the component (A) used in the present invention is 0.1 to 20 dtex (hereinafter, simply referred to as “dtex”), and the makeup effect that makes the eyelids look longer and makes the eyes stand out. In addition, it is preferable from the viewpoint of lack of burden on the decorative film, and more preferably 1 to 10 dtex.
更に、本発明に用いられる成分（Ａ）の繊維の長さは、０.１〜５ｍｍであることが、睫を長く見せ、目元を際立たせる化粧効果や、化粧膜の負担感がなく、さらには、繊維が睫からはがれずに目元に落ちてこないといった化粧持ちの点で好ましく、０.５〜３ｍｍであることがより好ましい。 Furthermore, the length of the fiber of the component (A) used in the present invention is 0.1 to 5 mm, there is no cosmetic effect that makes the eyelids look long and the eyes are conspicuous, and there is no feeling of burden on the decorative film, Is preferable from the standpoint of having a makeup such that the fibers do not come off the eyelids without falling off the eyelids, and more preferably 0.5 to 3 mm.
更にまた、本発明に用いられる成分（Ａ）の繊維の断面形状は特に制限されず、様々な形状の繊維が使用できる。この様々な形状の中には、通常の繊維の断面形状である円やだ円とは違う形の形状のもの、すなわち異形のものが含まれる。そして、例えば、断面形状がＴ型やＹ型の異形のものを用いると、光の乱反射が生じることにより、仕上がりの化粧膜のツヤ感が著しく向上する。また更に、成分（Ａ）の繊維は、フッ素化合物、シリコーン系油剤、金属石ケン、界面活性剤、油脂、炭化水素、無水ケイ酸等を用いて公知の方法により表面処理したものを使用することもでき、このような表面処理したものを利用することが、分散性や付着性が向上し、束付きや枝分かれのない均一な化粧膜の形成や、繊維が睫からはがれずに目元に落ちてこないといった化粧持ちを向上の点から好ましい。これら表面処理剤の中でも、特に、無水ケイ酸が好ましい。 Furthermore, the cross-sectional shape of the component (A) fiber used in the present invention is not particularly limited, and fibers of various shapes can be used. Among these various shapes, a shape different from a circle or an ellipse, which is a cross-sectional shape of a normal fiber, that is, an irregular shape is included. For example, when a T-shaped or Y-shaped irregular shape is used, irregular reflection of light occurs, and the gloss of the finished decorative film is remarkably improved. Furthermore, the component (A) fibers should be surface-treated by a known method using a fluorine compound, silicone oil, metal soap, surfactant, fats and oils, hydrocarbons, silicic anhydride, or the like. Using such a surface-treated product improves dispersibility and adhesion, forms a uniform decorative film without bundling and branching, and fibers fall into the eyes without peeling from the eyelids. It is preferable from the viewpoint of improving makeup retention such that it does not come off. Among these surface treatment agents, silicic anhydride is particularly preferable.
上記した成分（Ａ）の繊維は、本発明の水中油型睫用化粧料中に０.１〜６質量％（以下、単に「％」と示す）程度配合することが、睫を長く見せ、目元を際立たせる化粧効果、束付きや枝分かれのない均一な化粧膜の形成、仕上がりの化粧膜のツヤ感、および化粧膜の負担感のなさの点で好ましく、１〜４％がより好ましい。 The fiber of the component (A) described above is blended in the oil-in-water type cosmetic for cosmetics of the present invention in an amount of 0.1 to 6% by mass (hereinafter simply referred to as “%”), so that the cocoon appears long. It is preferable in terms of the makeup effect that makes the eyes stand out, the formation of a uniform decorative film without bundling or branching, the glossiness of the finished decorative film, and the lack of burden on the decorative film, and more preferably 1 to 4%.
本発明に用いられる、成分（Ｂ）の水不溶性皮膜形成ポリマーは、化粧料を塗布した際に皮膜を形成する樹脂や重合体であれば特に限定されず、天然、半合成、合成であっても、水不溶性であればいずれのものも使用することができる。また、水不溶性皮膜形成ポリマーを成分（Ｃ）を含む水性溶媒に分散して用いることもできる。 The water-insoluble film-forming polymer of component (B) used in the present invention is not particularly limited as long as it is a resin or polymer that forms a film when a cosmetic is applied, and is natural, semi-synthetic or synthetic. Any water-insoluble material can be used. Further, the water-insoluble film forming polymer can be dispersed in an aqueous solvent containing the component (C).
本発明においてポリマーエマルションは、乳化重合法や、コアシェル重合法、ラジカル重合法等の一般的な重合法で重合物を得ることができる。なお、水性溶媒とは、水を主成分とし、多価アルコール等の親水性成分を含有してもよい溶媒を意味する。 In the present invention, a polymer emulsion can be obtained from the polymer emulsion by a general polymerization method such as an emulsion polymerization method, a core-shell polymerization method, or a radical polymerization method. In addition, an aqueous solvent means the solvent which has water as a main component and may contain hydrophilic components, such as a polyhydric alcohol.
水不溶性皮膜形成ポリマーとしては、例えば、アクリル酸アルキル共重合体、アクリル酸アルキル重合体、メタクリル酸アルキル共重合体、メタクリル酸アルキル重合体、アクリル酸アルキル・メタクリル酸アルキル共重合体、酢酸ビニル重合体、アクリル酸アルキル・スチレン共重合、メタアクリル酸アルキル・スチレン共重合体、ビニルピロリドン・スチレン共重合体、オルガノポリシロキサン重合体等が挙げられる。 Examples of water-insoluble film-forming polymers include alkyl acrylate copolymers, alkyl acrylate polymers, alkyl methacrylate copolymers, alkyl methacrylate polymers, alkyl acrylate / alkyl methacrylate copolymers, vinyl acetate polymer. Examples thereof include alkyl acrylate / styrene copolymer, alkyl methacrylate / styrene copolymer, vinylpyrrolidone / styrene copolymer, and organopolysiloxane polymer.
また、上記の重合体または共重合体の１種または２種以上を水性溶媒に分散したポリマーエマルションとして、例えば、アクリル酸アルキル共重合体、アクリル酸アルキル重合体、メタクリル酸アルキル共重合体、メタクリル酸アルキル重合体、アクリル酸アルキル・メタクリル酸アルキル共重合体、酢酸ビニル重合体、アクリル酸アルキル・スチレン共重合体、メタアクリル酸アルキル・スチレン共重合体、ビニルピロリドン・スチレン共重合体、オルガノポリシロキサン重合体等が挙げられ、これらの１種又は２種以上を水性溶媒に分散したポリマーエマルションとしては、例えば、アクリル酸アルキル共重合体エマルション、アクリル酸アルキル重合体エマルション、メタクリル酸アルキル共重合体エマルション、メタクリル酸アルキル重合体エマルション、アクリル酸・アクリル酸アルキル共重合体エマルション、アクリル酸・メタクリル酸アルキル共重合体エマルション、メタクリル酸・アクリル酸アルキル共重合体エマルション、メタクリル酸・メタクリル酸アルキル共重合体エマルション、アクリル酸アルキル・スチレン共重合体エマルション、メタクリル酸アルキル・スチレン共重合体エマルション、酢酸ビニル重合体エマルション、酢酸ビニル含有共重合体エマルション、ビニルピロリドン・スチレン共重合体エマルション、オルガノポリシロキサン重合体エマルション等が挙げられ、これらの１種又は２種以上を使用することができる。 In addition, as a polymer emulsion in which one or more of the above polymers or copolymers are dispersed in an aqueous solvent, for example, an alkyl acrylate copolymer, an alkyl acrylate polymer, an alkyl methacrylate copolymer, Alkyl acid polymer, alkyl acrylate / alkyl methacrylate copolymer, vinyl acetate polymer, alkyl acrylate / styrene copolymer, alkyl methacrylate / styrene copolymer, vinyl pyrrolidone / styrene copolymer, organopoly Examples of polymer emulsions in which one or more of these are dispersed in an aqueous solvent include, for example, alkyl acrylate copolymer emulsions, alkyl acrylate polymer emulsions, alkyl methacrylate copolymers. Emulsion, alkyl methacrylate Polymer emulsion, acrylic acid / alkyl acrylate copolymer emulsion, acrylic acid / alkyl methacrylate copolymer emulsion, methacrylic acid / alkyl acrylate copolymer emulsion, methacrylic acid / alkyl methacrylate copolymer emulsion, acrylic acid Alkyl / styrene copolymer emulsion, alkyl methacrylate / styrene copolymer emulsion, vinyl acetate polymer emulsion, vinyl acetate-containing copolymer emulsion, vinyl pyrrolidone / styrene copolymer emulsion, organopolysiloxane polymer emulsion, etc. 1 type, or 2 or more types of these can be used.
本発明に用いられる、成分（Ｂ）の水不溶性皮膜形成ポリマーの中でも、酢酸ビニル重合体、ビニルピロリンドン・スチレン共重合体エマルションが好ましい。 Among the water-insoluble film-forming polymers of component (B) used in the present invention, vinyl acetate polymers and vinyl pyrrolindone / styrene copolymer emulsions are preferred.
本発明に用いられる、成分（Ｂ）の市販品として、アクリル酸アルキル共重合体エマルションとしてはＡＣＵＲＹＮ３３Ａ（ロームアンドハース社製）、ヨドゾールＧＨ８００、ヨドゾールＧＨ８１０、ヨドゾールＧＨ４１Ｆ（日本エヌエスシー社製）、酢酸ビニル重合体エマルションとしては、ビニブランＧＶ−５６５１（日信化学工業社製）、ビニルピロリドン・酢酸ビニル共重合体としてはＰＶＰ／ＶＡＥ−７３５（ＩＳＰ社製）、アクリル酸・メタクリル酸・アクリル酸エチルヘキシル共重合体としてはダイトゾール５０００ＳＪ（大東化成工業社製）、ビニルピロリドン・スチレン共重合体としては、ＡＮＴＡＲＡ４３０（ＩＳＰ社製）等が挙げられる。 As a commercial item of the component (B) used in the present invention, as an alkyl acrylate copolymer emulsion, ACURYN33A (made by Rohm and Haas), Yodosol GH800, Yodosol GH810, Yodosol GH41F (made by NSC Japan), acetic acid As vinyl polymer emulsion, VINIBRAN GV-5651 (manufactured by Nissin Chemical Industry Co., Ltd.), as vinylpyrrolidone / vinyl acetate copolymer, PVP / VAE-735 (manufactured by ISP), acrylic acid / methacrylic acid / ethyl hexyl acrylate Examples of the copolymer include Daitosol 5000SJ (manufactured by Daito Kasei Kogyo Co., Ltd.), and examples of the vinylpyrrolidone / styrene copolymer include ANTARA430 (manufactured by ISP).
この成分（Ｂ）である水不溶性皮膜形成ポリマーの本発明の水中油型睫用化粧料中での配合量は、固形分濃度として０.５〜２５％が好ましく、１〜１５％がより好ましい。この範囲であれば、仕上がりの化粧膜のツヤ感、および繊維が睫からはがれずに目元に落ちてこないといった化粧持ちが飛躍的に向上する。 The blending amount of the water-insoluble film-forming polymer as the component (B) in the oil-in-water cosmetic for cosmetics of the present invention is preferably 0.5 to 25%, more preferably 1 to 15% as a solid content concentration. . Within this range, the gloss of the finished decorative film and the durability of the makeup such that the fibers do not peel off the eyelids and do not fall into the eyes are dramatically improved.
本発明に用いられる、成分（Ｃ）である水の本発明の水中油型睫用化粧料中での配合量は、特に限定されないが、３０〜７５％が好ましく、３５〜６５％が更に好ましい。この範囲であれば、睫への付着性や使用時のなめらかさ、化粧膜の均一性の点で満足のいくものが得られる。 Although the compounding quantity in the oil-in-water type cosmetic for cosmetics of this invention of the water which is the component (C) used for this invention is not specifically limited, 30 to 75% is preferable and 35 to 65% is still more preferable. . Within this range, satisfactory results can be obtained in terms of adhesion to wrinkles, smoothness during use, and uniformity of the decorative film.
本発明に用いられる、成分（Ｄ）の油性成分としは、動物油、植物油、合成油等の起源、および、固形油、半固形油、液体油等の性状を問わず、炭化水素類、油脂類、ロウ類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、シリコーン油類、フッ素系油類、ラノリン誘導体類、油性ゲル化剤類、油溶性樹脂、揮発性油剤等が挙げられる。 The oil component of component (D) used in the present invention includes hydrocarbons, fats and oils, regardless of the origin, such as animal oil, vegetable oil, synthetic oil, and the properties of solid oil, semi-solid oil, liquid oil, etc. Waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oily gelling agents, oil-soluble resins, volatile oils and the like.
具体的には、流動パラフィン、スクワラン、ワセリン、パラフィンワックス、セレシンワックス、マイクロクリスタリンワックス、エチレンプロピレンコポリマー、モンタンワックス、フィッシャトロプスワックス等の炭化水素類、モクロウ、オリーブ油、ヒマシ油、ミンク油、マカデミアンナッツ油等の油脂類、ミツロウ、カルナウバワックス、キャンデリラワックス、ゲイロウ等のロウ類、ホホバ油、セチルイソオクタネート、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、トリオクタン酸グリセリル、ジイソステアリン酸ポリグリセリル、トリイソステアリン酸ジグリセリル、トリベヘン酸グリセリル、リンゴ酸ジイソステアリル、ジオクタン酸ネオペンチルグリコール、コレステロール脂肪酸エステル、Ｎ−ラウロイル−Ｌ−グルタミン酸ジ（コレステリル・ベヘニル・オクチルドデシル）等のエステル類、ステアリルアルコール、セチルアルコール、ラウリルアルコール、オレイルアルコール、イソステアリルアルコール、ベヘニルアルコール等の高級アルコール類、メチルフェニルポリシロキサン、フッ素変性オルガノポリシロキサン等のシリコーン類、パーフルオロデカン、パーフルオロオクタン、パーフルオロポリエーテル等のフッ素系油剤類、ラノリン、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ラノリンアルコール等のラノリン誘導体、オクタン酸デキストリン、ラウリン酸デキストリン、パルミチン酸デキストリン、ミリスチン酸デキストリン、ステアリン酸デキストリン、ベヘニン酸デキストリン、ヤシ油脂肪酸デキストリン、（
パルミチン酸／ オクタン酸） デキストリン、蔗糖脂肪酸エステル、デンプン脂肪酸エステル、１２−ヒドロキシステアリン酸、ステアリン酸カルシウム等の油性ゲル化剤類、テルペン酸系樹脂（ロジン酸ペンタエリスリット等）、トリメチルシロキシケイ酸、キャンデリラレジン（ここで、キャンデリラレジンとは、キャンデリラワックスを有機溶剤にて分別抽出して得られる樹脂分で、樹脂分が好ましくは６５％以上、更に好ましくは８５％以上の割合で含有されるものである。）、ポリイソブチレン、水添ロジン酸ペンタエリスリチル、特定のアクリル酸アルキルメチルポリシロキサンエステル等の油溶性樹脂、軽質流動イソパラフィン、イソドデカン等の炭化水素油、デカメチルシクロペンタシロキサン、オクタメチルシクロテトラシロキサン、メチルトリメチコン、低重合度ジメチルポリシロキサン等のシリコーン類等の揮発性油剤等が挙げられる。
Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, montan wax, fisher trops wax, molasses, olive oil, castor oil, mink oil, macadamia Oils such as peanut oil, beeswax, carnauba wax, candelilla wax, waxes such as gay wax, jojoba oil, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, diisostearate Polyglyceryl acid, diglyceryl triisostearate, glyceryl tribehenate, diisostearyl malate, neopentyl glycol dioctanoate, cholesterol fat Acid esters, esters such as N-lauroyl-L-glutamate di (cholesteryl, behenyl, octyldodecyl), stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol and other higher alcohols, methylphenyl poly Silicones such as siloxane and fluorine-modified organopolysiloxane, fluorinated oils such as perfluorodecane, perfluorooctane and perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, dextrin octoate , Dextrin laurate, dextrin palmitate, dextrin myristate, dextrin stearate, dextrin behenate, coconut oil Fatty acid dextrin, (
Palmitic acid / octanoic acid) dextrin, sucrose fatty acid ester, starch fatty acid ester, 12-hydroxystearic acid, oily gelling agents such as calcium stearate, terpenic acid-based resin (eg, rosin acid pentaerythritol), trimethylsiloxysilicic acid, Candelilla resin (Here, the candelilla resin is a resin component obtained by fractional extraction of candelilla wax with an organic solvent. The resin content is preferably 65% or more, more preferably 85% or more. ), Oil-soluble resins such as polyisobutylene, hydrogenated pentaerythrityl rosin acid, specific alkyl methylpolysiloxane esters of acrylic acid, light liquid isoparaffin, hydrocarbon oils such as isododecane, decamethylcyclopentasiloxane , Octamethylcyclotetra Rokisan, methyl trimethicone, volatile oil such as silicone such as low polymerization degree dimethylpolysiloxane.
上記した成分（Ｄ）の油性成分のうち、固形油および油溶性樹脂が好ましく、睫を長く見せ、目元をきわだたせる効果と繊維の化粧持ちの点で良好である。また、成分（Ｄ）である油性成分の本発明の水中油型睫用化粧料中での配合量は、１〜２５％が好ましい。この範囲であると、睫を長く見せ、目元を際立たせる効果と繊維の化粧持ちの点で良好である。 Of the oily components of component (D) described above, solid oils and oil-soluble resins are preferable, and they are good in terms of long-lasting wrinkles and outstanding eye-feel and fiber makeup. Moreover, as for the compounding quantity in the oil-in-water type cosmetic for cosmetics of this invention of the oil-based component which is a component (D), 1 to 25% is preferable. If it is within this range, it is good in terms of the effect of making the eyelids look long and making the eyes stand out, and the longevity of the fiber.
本発明の水中油型睫用化粧料は、上記成分を配合する他、水中油型睫用化粧料とした後の稠度が、ＪＩＳ−Ｋ２２２０に基づき、２号アルミコーンを用いて３０℃で測定した稠度値（以下、「稠度値（３０℃）」という）として１７０〜３５０であるものであり、好ましくは、稠度値（３０℃）として１８０〜３００であるものである。この範囲とすることで、成分（Ａ）の繊維が、湾曲することなく睫に付着し、睫を長く見せ、目元を際立たせる化粧効果、束付きや枝分かれのない均一な化粧膜の形成、および繊維が睫からはがれずに目元に落ちてこないといった化粧持ちを演出することができる。 The oil-in-water cosmetic for cosmetics according to the present invention is blended with the above components, and the consistency after the oil-in-water cosmetic for cosmetics is measured at 30 ° C. using No. 2 aluminum cone based on JIS-K2220. The consistency value (hereinafter referred to as “consistency value (30 ° C.)”) is 170 to 350, and preferably the consistency value (30 ° C.) is 180 to 300. By making it within this range, the fiber of the component (A) adheres to the wrinkles without bending, makes the wrinkles look longer, makes the eyes stand out, the formation of a uniform decorative film without bundling and branching, and This makes it possible to create a makeup that the fibers do not fall off the eyelids and do not fall into the eyes.
本発明の水中油型睫用化粧料は、液状、半固形状又は固形状の油剤や油溶性化合物である油性成分を水系に分散、乳化した睫用化粧料であって、上記した成分（Ａ）、（Ｂ）、（Ｃ）および（Ｄ）を含み、その稠度値（３０℃）を上記範囲としたものである。この水中油型睫用化粧料の製造は、公知の水中油型化粧料の製造方法に従って実施することができる。 The oil-in-water cosmetic for cosmetics of the present invention is a cosmetic for cosmetics obtained by dispersing and emulsifying an oily component that is a liquid, semi-solid or solid oil agent or an oil-soluble compound in an aqueous system, and the components (A ), (B), (C) and (D), and the consistency value (30 ° C.) is within the above range. The production of the oil-in-water cosmetic for cosmetics can be carried out according to a known method for producing an oil-in-water cosmetic.
本発明の水中油型睫用化粧料の製造に当たっては、上記の成分（Ａ）、（Ｂ）、（Ｃ）および（Ｄ）の他に、通常化粧料に使用される成分、例えば感触調整や着色成分としての粉体、ロングラッシュ効果を得る成分として繊維、乳化剤としての界面活性剤、保湿としての水性成分、紫外線吸収剤、保湿剤、褪色防止剤、酸化防止剤、消泡剤、美容成分、防腐剤、香料などを本発明の効果を損なわない範囲で適宜配合することができる。 In the production of the oil-in-water cosmetic for cosmetics of the present invention, in addition to the above components (A), (B), (C) and (D), components usually used in cosmetics such as touch adjustment and Powder as coloring component, fiber as long lash effect component, surfactant as emulsifier, aqueous component as moisturizer, UV absorber, moisturizer, anti-fading agent, antioxidant, antifoaming agent, beauty ingredient Further, preservatives, fragrances and the like can be appropriately blended within a range not impairing the effects of the present invention.
粉体成分としては、板状、紡錘状、針状等の形状、煙霧状、微粒子、顔料級などの粒子径、多孔質、無孔質等の粒子構造等により特に限定されず、無機粉体類、光輝性粉体類、有機粉体類、色素粉体類、複合粉体類等が挙げられる。具体的には、コンジョウ、群青、ベンガラ、黄酸化鉄、黒酸化鉄、酸化チタン、酸化亜鉛、酸化アルミニウム、酸化セリウム、酸化マグネシウム、酸化ジルコニウム、炭酸マグネシウム、炭酸カルシウム、酸化クロム、水酸化クロム、カーボンブラック、ケイ酸アルミニウム、ケイ酸マグネシウム、ケイ酸アルミニウムマグネシウム、マイカ、合成マイカ、合成セリサイト、セリサイト、タルク、カオリン、シリカ、炭化珪素、硫酸バリウム、窒化硼素等の無機粉体類、オキシ塩化ビスマス、雲母チタン、酸化鉄コーティング雲母、酸化鉄雲母チタン、有機顔料処理雲母チタン、アルミニウムパウダー等の光輝性粉体類、ステアリン酸マグネシウム、ステアリン酸亜鉛、Ｎ−アシルリジン、ナイロン等の有機粉体類、有機タール系顔料、有機色素のレーキ顔料等の色素粉体類、微粒子酸化チタン被覆雲母チタン、微粒子酸化亜鉛被覆雲母チタン、硫酸バリウム被覆雲母チタン、酸化チタン含有二酸化珪素、酸化亜鉛含有二酸化珪素等の複合粉体、ポリエチレンテレフタレート・アルミニウム・エポキシ積層末、ポリエチレンテレフタレート・ポリオレフィン積層フィルム末、ポリエチレンテレフタレート・ポリメチルメタクリレート積層フィルム末等が挙げられ、これらを１種又は２種以上を用いることができる。また、これら粉体は１種又は２種以上の複合化したものを用いても良く、フッ素化合物、シリコーン系油剤、金属石ケン、界面活性剤、油脂、炭化水素等を用いて公知の方法により表面処理したものを用いても良い。 The powder component is not particularly limited by the shape of plates, spindles, needles, etc., the particle size of fumes, fine particles, pigment grades, the particle structure of porous, nonporous, etc. , Glitter powders, organic powders, pigment powders, composite powders, and the like. Specifically, conch, ultramarine, bengara, yellow iron oxide, black iron oxide, titanium oxide, zinc oxide, aluminum oxide, cerium oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide, chromium hydroxide, Carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, synthetic sericite, sericite, talc, kaolin, silica, silicon carbide, barium sulfate, boron nitride and other inorganic powders, oxy Bright powders such as bismuth chloride, titanium mica, iron oxide coated mica, iron oxide mica titanium, organic pigment-treated mica titanium, aluminum powder, organic powders such as magnesium stearate, zinc stearate, N-acyl lysine, nylon , Organic tar pigments, organic Pigment powders such as elementary lake pigments, fine particles of titanium oxide-coated mica titanium, fine particles of zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and the like, polyethylene terephthalate -Aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, and the like, and one or more of them can be used. In addition, these powders may be used singly or in combination of two or more, and by a known method using a fluorine compound, a silicone-based oil agent, a metal soap, a surfactant, fats and oils, etc. A surface-treated product may be used.
成分（Ａ）以外の繊維としては、化粧料に一般に使用されるものであれば特に制限されず、ポリエステル等の合成繊維、レーヨン等の人造繊維、セルロース等の天然繊維、アセテート人絹等の半合成繊維等が挙げられる。これらの繊維は、必要に応じて表面処理を施して使用される。表面処理剤としてはフッ素化合物、シリコーン油、粉体、油剤、ゲル化剤、エマルションポリマー、界面活性剤等が挙げられる。 The fibers other than the component (A) are not particularly limited as long as they are generally used in cosmetics. Synthetic fibers such as polyester, artificial fibers such as rayon, natural fibers such as cellulose, half of acetate human silk, etc. Examples include synthetic fibers. These fibers are used after being surface-treated as necessary. Examples of the surface treatment agent include a fluorine compound, silicone oil, powder, oil agent, gelling agent, emulsion polymer, and surfactant.
水を分散させる乳化剤として使用される界面活性剤としては、水中油型化粧料一般に用いられている界面活性剤であればいずれのものも使用でき、非イオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤等が挙げられる。 As the surfactant used as an emulsifier for dispersing water, any surfactant that is generally used in oil-in-water cosmetics can be used. Nonionic surfactants, anionic surfactants , Cationic surfactants, amphoteric surfactants and the like.
非イオン界面活性剤としては、例えば、例えば、ステアリン酸、ラウリン酸のような脂肪酸の無機および有機塩、グリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ポリグリセリン脂肪酸エステル及びそのアルキレングリコール付加物、プロピレングリコール脂肪酸エステル及びそのアルキレングリコール付加物、ソルビタン脂肪酸エステル及びそのアルキレングリコール付加物、ソルビトールの脂肪酸エステル及びそのアルキレングリコール付加物、ポリアルキレングリコール脂肪酸エステル、蔗糖脂肪酸エステル、ポリオキシアルキレンアルキルエーテル、グリセリンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレン硬化ヒマシ油、ラノリンのアルキレングリコール付加物、ポリオキシアルキレンアルキル共変性オルガノポリシロキサン、ポリエーテル変性オルガノポリシロキサン等が挙げられる。 Nonionic surfactants include, for example, inorganic and organic salts of fatty acids such as stearic acid and lauric acid, glycerin fatty acid esters and alkylene glycol adducts thereof, polyglycerin fatty acid esters and alkylene glycol adducts thereof, and propylene glycol. Fatty acid esters and alkylene glycol adducts thereof, sorbitan fatty acid esters and alkylene glycol adducts thereof, fatty acid esters of sorbitol and alkylene glycol adducts thereof, polyalkylene glycol fatty acid esters, sucrose fatty acid esters, polyoxyalkylene alkyl ethers, glycerin alkyl ethers, Polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, alkylene glycol adduct of lanolin, Sialic sharp emission alkyl co-modified organopolysiloxane, polyether-modified organopolysiloxane and the like.
アニオン性界面活性剤としては、例えば、ステアリン酸、ラウリン酸のような脂肪酸の無機及び有機塩、アルキルベンゼン硫酸塩、アルキルスルホン酸塩、α−オレフィンスルホン酸塩、ジアルキルスルホコハク酸塩、α−スルホン化脂肪酸塩、アシルメチルタウリン塩、Ｎ−メチル−Ｎ−アルキルタウリン塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシエチレンアルキルフェニルエーテル硫酸塩、アルキル燐酸塩、ポリオキシエチレンアルキルエーテル燐酸塩、ポリオキシエチレンアルキルフェニルエーテル燐酸塩、Ｎ−アシルアミノ酸塩、Ｎ−アシル−Ｎ−アルキルアミノ酸塩、ο−アルキル置換リンゴ酸塩、アルキルスルホコハク酸塩等が挙げられる。 Examples of anionic surfactants include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfates, alkyl sulfonates, α-olefin sulfonates, dialkyl sulfosuccinates, α-sulfonates. Fatty acid salt, acylmethyl taurine salt, N-methyl-N-alkyl taurine salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene Examples thereof include alkyl phenyl ether phosphates, N-acyl amino acid salts, N-acyl-N-alkyl amino acid salts, o-alkyl substituted malates, alkyl sulfosuccinates and the like.
カチオン界面活性剤としては、例えば、アルキルアミン塩、ポリアミン及びアルカノールアミン脂肪酸誘導体、アルキル四級アンモニウム塩、環式四級アンモニウム塩等が挙げられる。 Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts.
両性界面活性剤としては、アミノ酸タイプやベタインタイプのカルボン酸型、硫酸エステル型、スルホン酸型、リン酸エステル型のものがあり、人体に対して安全とされるものが使用できる。例えば、Ｎ，Ｎ−ジメチル−Ｎ−アルキル−Ｎ−カルボキシルメチルアンモニウムベタイン、Ｎ，Ｎ−ジアルキルアミノアルキレンカルボン酸、Ｎ，Ｎ，Ｎ−トリアルキル−Ｎ−スルフォアルキレンアンモニウムベタイン、Ｎ，Ｎ−ジアルキル−Ｎ，Ｎ−ビス（ポリオキシエチレン硫酸）アンモニウムベタイン、２−アルキル−１−ヒドロキシエチル−１−カルボキシメチルイミダゾリニウムベタイン、レシチン等が挙げられる。 Examples of amphoteric surfactants include amino acid type and betaine type carboxylic acid types, sulfate ester types, sulfonic acid types, and phosphate ester types, and those that are safe for the human body can be used. For example, N, N-dimethyl-N-alkyl-N-carboxylmethylammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N- Examples include dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, and lecithin.
水性成分としては、水に可溶な成分であれば何れでもよく、例えば、エチルアルコール、ブチルアルコール等の低級アルコール、プロピレングリコール、１，３−ブチレングリコール、ジプロピレングリコール、ポリエチレングリコール等のグリコール類、グリセリン、ジグリセリン、ポリグリセリン等のグリセロール類、アロエベラ、ウイッチヘーゼル、ハマメリス、キュウリ、レモン、ラベンダー、ローズ等の植物抽出液が挙げられる。水溶性高分子としては、グアーガム、コンドロイチン硫酸ナトリウム、ヒアルロン酸ナトリウム、アラビアガム、アルギン酸ナトリウム、カラギーナン等の天然系のもの、メチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース等の半合成系のもの、カルボキシビニルポリマー、アルキル付加カルボキシビニルポリマー、ポリアクリル酸ナトリウム等の合成系のものを挙げることができる。タンパク質、ムコ多糖、コラーゲン、エラスチン、ケラチン等の他の保湿剤を含有する事もできる。 The aqueous component may be any component that is soluble in water, for example, lower alcohols such as ethyl alcohol and butyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, and polyethylene glycol. Glycerols such as glycerin, diglycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose. Examples of water-soluble polymers include guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, carrageenan, and other semi-synthetic materials such as methyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose, carboxyvinyl polymer, Synthetic compounds such as alkyl-added carboxyvinyl polymer and sodium polyacrylate can be mentioned. Other moisturizing agents such as protein, mucopolysaccharide, collagen, elastin, keratin and the like can also be contained.
紫外線吸収剤としては、例えばベンゾフェノン系、ＰＡＢＡ系、ケイ皮酸系、サリチル酸系、４−ｔｅｒｔ−ブチル−４’−メトキシジベンゾイルメタン、オキシベンゾン等、保湿剤としては、例えばタンパク質、ムコ多糖、コラーゲン、エラスチン、ケラチン等、酸化防止剤としては、例えばα−トコフェロール、アスコルビン酸等、美容成分としては、例えばビタミン類、消炎剤、生薬等、防腐剤としては、例えばパラオキシ安息香酸エステル、フェノキシエタノール等が挙げられる。 Examples of ultraviolet absorbers include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone. Examples of humectants include protein, mucopolysaccharide, and collagen. , Elastin, keratin, etc., antioxidants such as α-tocopherol, ascorbic acid, etc., cosmetic ingredients such as vitamins, anti-inflammatory agents, herbal medicines, etc., antiseptics such as paraoxybenzoic acid esters, phenoxyethanol, etc. Can be mentioned.
斯くして得られる本発明の水中油型睫毛用化粧料は、マスカラ、マスカラ下地、マスカラオーバーコートなどに応用でき、その形態としては、クリーム状、ゲル状、液状等が挙げられるが、中でもクリーム状が好ましく、外観は、半透明、不透明それぞれの化粧料として使用することができる。 The oil-in-water type eyelash cosmetic of the present invention thus obtained can be applied to mascara, mascara base, mascara overcoat and the like, and the form includes cream, gel, liquid, etc. The appearance is preferable, and the appearance can be used as a translucent or opaque cosmetic.
以下に実施例をあげて本発明を詳細に説明する。尚、これらは本発明を何ら限定するものではない。 Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.
実 施 例 １
水中油型睫用化粧料：
表１に示す処方および下記製法で、本発明品１〜９および比較品１〜６の油性睫用化粧料を調製した。これらの化粧料について、下記ａ〜ｆの評価項目について、評価した。その結果も併せて表１に示す。
Example 1
Oil-in-water cosmetic for salmon:
According to the formulation shown in Table 1 and the following production method, oily wrinkle cosmetics of the present invention products 1 to 9 and comparative products 1 to 6 were prepared. About these cosmetics, the evaluation item of following af was evaluated. The results are also shown in Table 1.
※1：ビニブランＧＶ−５６５１（日信化学工業（株）製）固形分３５％
※2：４.５ｄｔｅｘ、２ｍｍ、伸度８２％、断面丸型、未処理
※3：１３.５ｄｔｅｘ、２ｍｍ、伸度９７％、断面丸型、未処理
※4：４.５ｄｔｅｘ、２ｍｍ、伸度８２％、断面Ｔ型、未処理
※5：４.５ｄｔｅｘ、２ｍｍ、伸度８２％、断面丸型、無水ケイ酸２％処理
※6：３ｄｔｅｘ、２ｍｍ、伸度５９％、断面丸型、未処理
※7：６.５ｄｔｅｘ、２ｍｍ、伸度６９％、断面丸型、未処理
※8：１６.５ｄｔｅｘ、２ｍｍ、伸度７９％、断面丸型、未処理
※9：６.５ｄｔｅｘ、２ｍｍ、伸度５５％、断面丸型、未処理
※10：６.５ｄｔｅｘ、２ｍｍ、伸度２０％、断面丸型、未処理
* 1: Vinibrand GV-5651 (Nissin Chemical Industry Co., Ltd.) solid content 35%
* 2: 4.5dtex, 2mm, elongation 82%, round section, untreated * 3: 13.5dtex, 2mm, elongation 97%, round section, untreated * 4: 4.5dtex, 2mm, stretched Degree 82%, T-section, untreated * 5: 4.5 dtex, 2 mm, elongation 82%, round section, 2% silicic acid treatment * 6: 3 dtex, 2 mm, elongation 59%, round section, Untreated * 7: 6.5 dtex, 2 mm, elongation 69%, round section, untreated * 8: 16.5 dtex, 2 mm, elongation 79%, round section, untreated * 9: 6.5 dtex, 2 mm , 55% elongation, round cross section, untreated * 10: 6.5 dtex, 2 mm, 20% elongation, round cross section, untreated
（ 製 法 ）
Ａ．成分（１）〜（４）を８０℃で均一に加熱溶解する。
Ｂ．成分（５）〜（１８）を均一に混合し８０℃に加熱する。
Ｃ．ＢにＡを加え乳化する。
Ｄ．Ｃを容器に充填し水中油型睫用化粧料を得た。
(Production method)
A. Components (1) to (4) are uniformly heated and dissolved at 80 ° C.
B. Components (5) to (18) are mixed uniformly and heated to 80 ° C.
C. A is added to B and emulsified.
D. C was filled into a container to obtain an oil-in-water cosmetic for cosmetics.
（ 評価項目 ）
ａ．睫を長く見せ、目元を際立たせる化粧効果
ｂ．束付きや枝分かれのない化粧膜の均一性
ｃ．化粧膜のツヤ感
ｄ．化粧膜の負担感のなさ
ｅ．繊維の化粧持ち
ｆ．稠度値（３０℃）
( Evaluation item )
a. Makeup effect that makes the eyelids look longer and makes the eyes stand out b. Uniformity of decorative film without bundling or branching c. Glossiness of the decorative film d. No burden of cosmetic film e. Fiber makeup f. Consistency value (30 ° C)
（ 評価方法 ）
ａ〜ｅの項目については、各試料について専門パネル２０名による使用テストを行った。パネル各人が下記絶対評価にて７段階に評価し評点をつけ、各試料についてパネル全員の評点合計からその平均値を算出し、下記４段階判定基準により判定した。尚、ｅの繊維の化粧持ちについては各試料を睫に塗布し、パネルに通常の生活をしてもらった後、６時間後に繊維が睫から落ちて下瞼や他の部位に付着していないかどうかで評価した。また、項目ｆについては、稠度計（日本油試験機工業株式会社製）を用い、ＪＩＳ−Ｋ２２２０に基づき、２号アルミコーンを用いて測定した値を示した。
( Evaluation methods )
Regarding the items a to e, a use test was conducted by 20 specialist panels for each sample. Each panel member gave a rating based on the following absolute evaluation and assigned a score, and the average value was calculated from the total score of all the panel members for each sample, and the determination was made according to the following 4-step criteria. In addition, after applying each sample to the heel and having the panel have a normal life, the fiber falls off the heel after 6 hours and does not adhere to the lower heel or other parts. It was evaluated by whether or not. Moreover, about the item f, the value measured using the No. 2 aluminum cone based on JIS-K2220 was shown using the consistency meter (made by Nippon Oil Testing Machine Co., Ltd.).
＜絶対評価基準＞
評 点 ： 評 価
６ ： 非常に良い
５ ： 良い
４ ： やや良い
３ ： 普通
２ ： やや悪い
１ ： 悪い
０ ： 非常に悪い
<Absolute evaluation criteria>
Score: Rating 6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad
＜４段階判定基準＞
判 定 ： 評点の平均点
◎ ： ５点を超える（非常に良好）
○ ： ３.５点を超え５点以下（良好）
△ ： １点を超え３.５点以下（やや不良）
× ： １点以下（不良）
<4 step criteria>
Judgment: Average score ◎: Over 5 points (very good)
○: Over 3.5 points and below 5 points (good)
Δ: Over 1 point and under 3.5 points (slightly poor)
×: 1 point or less (defect)
表１の結果から明らかな如く、本発明品１〜９の水中油型睫用化粧料は、比較品１〜６の水中油型睫用化粧料に比べ、睫を長く見せ、目元を際立たせる化粧効果、束付きや枝分かれのない化粧膜の均一性、化粧膜のツヤ感、化粧膜の負担感のなさ、繊維の化粧持ちの全てにおいて優れたものであった。これに対して、成分（Ｂ）の水不溶性皮膜形成ポリマーが配合されていない比較品１では、束付きや枝分かれのない化粧膜の均一性、繊維の化粧持ちの点で、ナイロン−６繊維を配合した比較品２、３、４では、束付きや枝分かれのない化粧膜の均一性、化粧膜のツヤ感、化粧膜の負担感のなさの点で、ポリプロピレン繊維を配合した比較例５では、化粧膜の負担感のなさの点で、レーヨン繊維を配合した比較品６では、化粧膜のツヤ感、化粧膜の負担感のなさ、繊維の化粧持ちの点で満足のいくものが得られなかった。 As is apparent from the results in Table 1, the oil-in-water type eyelid cosmetics of the present invention products 1-9 show longer wrinkles and make the eyes stand out than the oil-in-water type eyelash cosmetics of comparative products 1-6. It was excellent in all of the makeup effect, uniformity of the makeup film without bundling or branching, glossiness of the makeup film, no burden of the makeup film, and the makeup of the fiber. On the other hand, in the comparative product 1 in which the water-insoluble film-forming polymer of the component (B) is not blended, nylon-6 fiber is used in terms of the uniformity of the decorative film without bundling and branching and the longevity of the fiber. In the comparative products 2, 3 and 4 blended, in the comparative example 5 in which polypropylene fiber is blended in terms of uniformity of the decorative film without bundling and branching, glossiness of the decorative film, and no burden of the decorative film, In comparison product 6 containing rayon fiber in terms of lack of burden of makeup film, satisfactory results cannot be obtained in terms of gloss of makeup film, lack of burden of makeup film, and longevity of fiber makeup. It was.
具体的には、比較品１のものでは、繊維が目元に落ちてきてしまうという問題が、比較品２〜４においては、化粧膜が白ぼけてしまい、ツヤ感がなくなり目元を際立たせる化粧効果が落ちる、繊維が曲がって付いてしまうためきれいな化粧膜を形成しない等の問題があった。また、比較品５においては、繊維が硬いため、違和感を感じる化粧膜になるという問題が、比較品６においては、化粧膜が白ぼけてしまい、ツヤ感がなくなり目元を際立たせる化粧効果が落ちるという問題や、さらに繊維が曲がって付いてしまうためきれいな化粧膜を形成しないという問題があった。 Specifically, the comparative product 1 has a problem that the fibers fall into the eyes. In the comparative products 2 to 4, the cosmetic film is blurred, the glossy feeling is lost, and the makeup effect that makes the eyes stand out. There are problems such as falling, and fibers are bent and attached, so that a beautiful decorative film is not formed. Further, the comparative product 5 has a problem that the makeup film feels uncomfortable because the fibers are hard. In the comparative product 6, the cosmetic film is blurred, and the makeup effect that makes the eyes stand out is lost. In addition, there is a problem that a beautiful decorative film is not formed because fibers are bent and attached.
実 施 例 ２
水中油型睫用化粧料：
下記組成および製法により、水中油型睫毛用化粧料を調製した。
Example 2
Oil-in-water cosmetic for salmon:
An oil-in-water cosmetic for eyelashes was prepared by the following composition and production method.
（ 処 方 ） （％）
（１）カルナウバワックス １０
（２）セスキオレイン酸ソルビタン ２
（３）モノオレイン酸ポリオキシエチレンソルビタン（２０Ｅ.Ｏ） ４
（４）軽質流動イソパラフィン ５
（５）精製水 残量
（６）アクリル酸アルキル共重合体ポリマーエマルション※１１ １０
（７）ナイロン−１２繊維※１２ ８
（８）ベンガラ ３
（９）シリコーン処理雲母チタン※１３ １０
（１０）エタノール ５
（１１）ローズマリーエキス ０.１
（１２）パラオキシ安息香酸メチルエステル ０.１
（１３）香料 ０.２
※11：ＹＯＤＯＳＯＬ ＧＨ８１０（日本エヌエスシー（株）製）固形分４５％
※12：４.５ｄｔｅｘ、１ｍｍ、伸度８２％、断面Ｙ型、無水ケイ酸５％処理
※13：ジメチコン２％処理 ＦＬＡＭＥＮＣＯ ＲＥＤ（エンゲルハート社製）
(Treatment) (%)
(1) Carnauba wax 10
(2) Sorbitan sesquioleate 2
(3) Polyoxyethylene sorbitan monooleate (20E.O) 4
(4) Light liquid isoparaffin 5
(5) Remaining amount of purified water (6) Alkyl acrylate copolymer polymer emulsion * 11 10
(7) Nylon-12 fiber * 12 8
(8) Bengala 3
(9) Silicone-treated mica titanium * 13 10
(10) Ethanol 5
(11) Rosemary extract 0.1
(12) Methyl ester of paraoxybenzoic acid 0.1
(13) Fragrance 0.2
* 11: YODOSOL GH810 (manufactured by NSC Japan) 45% solid content
* 12: 4.5 dtex, 1 mm, elongation 82%, cross section Y-type, silicic acid 5% treated * 13: dimethicone 2% treated FLAMENCO RED (manufactured by Engelhardt)
（ 製 法 ）
Ａ．成分（１）〜（４）を８０℃で均一に加熱溶解する。
Ｂ．成分（５）〜（１３）を均一に混合し８０℃に加熱する。
Ｃ．ＢにＡを加え乳化する。
Ｄ．Ｃを容器に充填し水中油型睫用化粧料を得た。
(Production method)
A. Components (1) to (4) are uniformly heated and dissolved at 80 ° C.
B. Components (5) to (13) are mixed uniformly and heated to 80 ° C.
C. A is added to B and emulsified.
D. C was filled into a container to obtain an oil-in-water cosmetic for cosmetics.
以上のようにして得られた水中油型睫用化粧料は、睫を長く見せ、目元を際立たせる化粧効果、束付きや枝分かれのない化粧膜の均一性、化粧膜のツヤ感、化粧膜の負担感のなさ、繊維の化粧持ちの全てにおいて優れたものであった。また、実施例１のようにして測定した水中油型睫用化粧料の３０℃における稠度値は１７０であった。 The oil-in-water vaginal cosmetic obtained as described above has a cosmetic effect that makes the vaginal appearance longer and makes the eyes stand out, uniformity of the cosmetic film without bundling or branching, glossiness of the cosmetic film, There was no feeling of burden, and it was excellent in all of the makeup of fibers. Further, the consistency value at 30 ° C. of the oil-in-water cosmetic for cosmetics measured as in Example 1 was 170.
実 施 例 ３
水中油型マスカラ下地：
下記組成および製法により、水中油型マスカラ下地を調製した。
Example 3
Oil-in-water mascara substrate:
An oil-in-water mascara substrate was prepared by the following composition and production method.
（ 処 方 ） （％）
（１）ステアリン酸 １
（２）キャンデリラワックス ３
（３）アクリル酸アルキル共重合体ポリマーエマルション※１１ ５
（４）ビニルピロリドン・スチレン共重合体ポリマーエマルション※１４ ２０
（５）ポリ酢酸ビニルポリマーエマルション※１ １
（６）ポリオキシエチレン硬化ヒマシ油 ０.１
（７）精製水 残量
（８）水酸化ナトリウム ０.１
（９）着色ナイロン−１２繊維※１５ ０.１
（１０）黄色４号 ０.０５
（１１）酸化チタン ０.５
（１２）炭酸カルシウム １
※14：ＡＮＴＡＲＡ４３０（ＩＳＰ社製）固形分４０％
※15：４.５ｄｔｅｘ、４ｍｍ、伸度８２％、断面丸型、未処理、青色１号０.０５％
で染色
(Treatment) (%)
(1) Stearic acid 1
(2) Candelilla wax 3
(3) Alkyl acrylate copolymer polymer emulsion * 11 5
(4) Vinylpyrrolidone / styrene copolymer polymer emulsion * 14 20
(5) Polyvinyl acetate polymer emulsion * 1 1
(6) Polyoxyethylene hydrogenated castor oil 0.1
(7) Purified water remaining amount (8) Sodium hydroxide 0.1
(9) Colored nylon-12 fiber * 15 0.1
(10) Yellow No. 0.05
(11) Titanium oxide 0.5
(12) Calcium carbonate 1
* 14: ANTARA430 (ISP) 40% solids
* 15: 4.5 dtex, 4 mm, elongation 82%, round cross section, untreated, blue No. 1 0.05%
Stained with
（ 製 法 ）
Ａ．成分（１）〜（２）を８０℃で均一に加熱溶解する。
Ｂ．成分（３）〜（１２）を均一に混合し８０℃に加熱する。
Ｃ．ＢにＡを加え乳化する。
Ｄ．Ｃを容器に充填し水中油型マスカラ下地を得た。
(Production method)
A. Ingredients (1) and (2) are uniformly dissolved by heating at 80 ° C.
B. Components (3) to (12) are mixed uniformly and heated to 80 ° C.
C. A is added to B and emulsified.
D. C was filled into a container to obtain an oil-in-water mascara substrate.
以上のようにして得られた水中油型マスカラ下地は、睫を長く見せ、目元を際立たせる化粧効果、束付きや枝分かれのない化粧膜の均一性、化粧膜のツヤ感、化粧膜の負担感のなさ、繊維の化粧持ちの全てにおいて優れたものであった。また、実施例１のようにして測定した水中油型マスカラ下地の３０℃における稠度値は３５０であった。 The oil-in-water mascara substrate obtained as described above has a makeup effect that makes the eyelids look longer and makes the eyes stand out, the uniformity of the makeup film without bundling and branching, the glossiness of the makeup film, the feeling of burden of the makeup film In other words, it was excellent in all the fiber makeup. Further, the consistency value at 30 ° C. of the oil-in-water mascara substrate measured as in Example 1 was 350.
実 施 例 ４
水中油型マスカラオーバーコート：
下記組成および製法により、水中油型マスカラ下地を調製した。
Example 4
Oil-in-water mascara overcoat:
An oil-in-water mascara substrate was prepared by the following composition and production method.
（ 処 方 ） （％）
（１）パルミチン酸 ２
（２）トリ２−エチルヘキサン酸グリセリル ５
（３）ポリブテン ５
（４）デカメチルシクロペンタシロキサン １
（５）デキストリン脂肪酸エステル ０.２
（６）アクリル酸アルキル共重合体ポリマーエマルション※１６ ６０
（７）精製水 残量
（８）トリエタノールアミン １.２
（９）着色ナイロン−１２繊維※３ ２
（１０）着色干渉繊維※１７ ０.３
（１１）酸化チタン被覆ガラス末 ５
（１２）ポリエチレンテレフタレート・アルミニウム・エポキシ積層末 １
（１３）カルボキシメチルセルロース ０.０５
（１４）キサンタンガム ０.５
（１５）トレハロース ０.１
（１６）ポリビニルアルコール １
（１７）酢酸トコフェロール ０.１
※16：ＹＯＤＯＳＯＬ ＧＨ８００（日本エヌエスシー（株）製）固形分４５％
※17：ポリエチレンテレフタレート、ナイロンを特開平１１−１８２９に従い、５１
層に積層したもの、５デニール、１ｍｍ、断面丸型、赤色１０２号０.１％で
染色
(Treatment) (%)
(1) Palmitic acid 2
(2) Glyceryl tri-2-ethylhexanoate 5
(3) Polybutene 5
(4) Decamethylcyclopentasiloxane 1
(5) Dextrin fatty acid ester 0.2
(6) Alkyl acrylate copolymer polymer emulsion * 16 60
(7) Purified water remaining amount (8) Triethanolamine 1.2
(9) Colored nylon-12 fiber * 3 2
(10) Colored interference fiber * 17 0.3
(11) Titanium oxide coated glass powder 5
(12) Polyethylene terephthalate / aluminum / epoxy laminated powder 1
(13) Carboxymethylcellulose 0.05
(14) Xanthan gum 0.5
(15) Trehalose 0.1
(16) Polyvinyl alcohol 1
(17) Tocopherol acetate 0.1
* 16: YODOSOL GH800 (made by NSC Corporation) solid content 45%
* 17: Polyethylene terephthalate and nylon according to JP-A-11-1829, 51
Layered, 5 denier, 1mm, round cross section, red 102 dyed 0.1%
（ 製 法 ）
Ａ．成分（１）〜（２）を８０℃で均一に加熱溶解する。
Ｂ．成分（３）〜（１２）を均一に混合し８０℃に加熱する。
Ｃ．ＢにＡを加え乳化する。
Ｄ．Ｃを容器に充填し水中油型マスカラオーバーコートを得た。
(Production method)
A. Ingredients (1) and (2) are uniformly dissolved by heating at 80 ° C.
B. Components (3) to (12) are mixed uniformly and heated to 80 ° C.
C. A is added to B and emulsified.
D. C was filled into a container to obtain an oil-in-water mascara overcoat.
以上のようにして得られた水中油型マスカラオーバーコートは、睫を長く見せ、目元を際立たせる化粧効果、束付きや枝分かれのない化粧膜の均一性、化粧膜のツヤ感、化粧膜の負担感のなさ、繊維の化粧持ちの全てにおいて優れたものであった。また、実施例１のようにして測定した、水中油型マスカラオーバーコートの３０℃における稠度値は３００であった。 The oil-in-water mascara overcoat obtained as described above has a makeup effect that makes the eyelashes long and stands out, the uniformity of the makeup film without bundling and branching, the glossiness of the makeup film, the burden of the makeup film There was no feeling and it was excellent in all of the makeup of the fiber. Moreover, the consistency value in 30 degreeC of the oil-in-water type mascara overcoat measured as in Example 1 was 300.
本願発明の水中油型睫毛用化粧料は、柔軟性に富む繊維を含み、睫に塗布する際、この繊維が湾曲することなく均一に睫に付着するため、睫を長く見せ、目元を際立たせる化粧効果に優れたものであり、更に、睫への繊維の付着性が良好で束付きや枝分かれのない均一な化粧膜を形成させることができる。 The oil-in-water cosmetic for eyelashes of the present invention contains a fiber rich in flexibility, and when applied to the cocoon, the fiber uniformly adheres to the cocoon without bending, so that the cocoon is made long and the eye is made to stand out. The cosmetic effect is excellent, and furthermore, a uniform decorative film having good adhesion of the fibers to the wrinkles and free from bundling or branching can be formed.
従って、本発明の水中油型睫毛用化粧料は、仕上がりの化粧膜のツヤ感に優れ、化粧膜の負担感がなく、繊維が睫からはがれずに目元に落ちてこないといった化粧持ちに優れたものとして、マスカラ、マスカラ下地、マスカラオーバーコートなどにすることのできるものである。
以 上
Therefore, the oil-in-water cosmetic for eyelashes of the present invention is excellent in the glossiness of the finished cosmetic film, has no feeling of burden on the cosmetic film, and has excellent makeup such that the fibers do not peel off the eyelids and do not fall into the eyes. For example, mascara, mascara base, mascara overcoat, etc. can be used.
more than
Claims (7)
（Ａ）ナイロン１２繊維
（Ｂ）水不溶性皮膜形成ポリマー
（Ｃ）水
（Ｄ）油性成分
を配合し、２号アルミコーンを用いて３０℃にて測定した稠度値が１７０〜３５０であることを特徴とする水中油型睫用化粧料。 The following components (A), (B), (C) and (D)
(A) Nylon 12 fiber (B) Water-insoluble film-forming polymer (C) Water (D) Oil component is blended, and the consistency value measured at 30 ° C. using No. 2 aluminum cone is 170-350. A featured oil-in-water cosmetic for salmon.
The oil-in-water cosmetic for cosmetics according to any one of claims 1 to 6, wherein the component (A) fiber has its surface treated with silicic anhydride.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150265507A1 (en) * | 2014-03-19 | 2015-09-24 | Mary Kay Inc. | Mascara formulation |
| KR20180067728A (en) * | 2015-11-17 | 2018-06-20 | 이엘씨 매니지먼트 엘엘씨 | Mascara composition and method |
| KR20180075676A (en) * | 2015-11-17 | 2018-07-04 | 이엘씨 매니지먼트 엘엘씨 | Mascara composition and method |
| US10806233B2 (en) | 2015-11-17 | 2020-10-20 | Elc Management Llc | Mascara composition and method |
| JP2021038170A (en) * | 2019-09-03 | 2021-03-11 | 理研ビタミン株式会社 | Oil gelling agent |
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| KR20160133559A (en) * | 2014-03-19 | 2016-11-22 | 마리 케이 인코포레이티드 | Mascara formulation |
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| KR102412339B1 (en) | 2014-03-19 | 2022-06-22 | 마리 케이 인코포레이티드 | Mascara formulation |
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| CN108697617A (en) * | 2015-11-17 | 2018-10-23 | Elc 管理有限责任公司 | Mascara and method |
| KR102144714B1 (en) * | 2015-11-17 | 2020-08-18 | 이엘씨 매니지먼트 엘엘씨 | Mascara composition and method |
| KR102144716B1 (en) * | 2015-11-17 | 2020-08-18 | 이엘씨 매니지먼트 엘엘씨 | Mascara composition and method |
| US10806233B2 (en) | 2015-11-17 | 2020-10-20 | Elc Management Llc | Mascara composition and method |
| CN108697617B (en) * | 2015-11-17 | 2021-08-13 | Elc 管理有限责任公司 | Mascara compositions and methods |
| JP2021038170A (en) * | 2019-09-03 | 2021-03-11 | 理研ビタミン株式会社 | Oil gelling agent |
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