JP2009221362A - 光触媒塗膜及び光触媒組成物 - Google Patents
光触媒塗膜及び光触媒組成物 Download PDFInfo
- Publication number
- JP2009221362A JP2009221362A JP2008067792A JP2008067792A JP2009221362A JP 2009221362 A JP2009221362 A JP 2009221362A JP 2008067792 A JP2008067792 A JP 2008067792A JP 2008067792 A JP2008067792 A JP 2008067792A JP 2009221362 A JP2009221362 A JP 2009221362A
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- JP
- Japan
- Prior art keywords
- photocatalyst
- coating film
- titanium oxide
- type titanium
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 139
- 150000001875 compounds Chemical class 0.000 claims abstract description 60
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- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 79
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- 239000010931 gold Substances 0.000 description 1
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- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
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Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Catalysts (AREA)
- Paints Or Removers (AREA)
Abstract
【解決手段】ルチル型酸化チタン及び高い光触媒能を示す化合物を含む光触媒塗膜であって、前記ルチル型酸化チタンの含有割合が下記式(1)で表される条件を満足する光触媒塗膜。4/X≦a≦100/X(1)ここで、Xは前記光触媒塗膜の膜厚(単位:μm)を示し、aは前記ルチル型酸化チタンの前記光触媒塗膜の総量に対する含有割合(単位:質量%)を示す。
【選択図】なし
Description
4/X≦a≦100/X (1)
ここで、式(1)中、Xは前記光触媒塗膜の膜厚(単位:μm)を示し、aは前記ルチル型酸化チタンの前記光触媒塗膜の総量に対する含有割合(単位:質量%)を示す。
(2)前記ルチル型酸化チタンの含有割合が下記式(1a)で表される条件を満足する、(1)の光触媒塗膜。
4/X≦a≦60/X (1a)
ここで、式(1)中、Xは前記光触媒塗膜の膜厚(単位:μm)を示し、aは前記ルチル型酸化チタンの前記光触媒塗膜の総量に対する含有割合(単位:質量%)を示す。
(3)前記ルチル型酸化チタンに対する前記高い光触媒能を示す化合物の質量比が0.10〜2.0である、(1)又は(2)の光触媒塗膜。
(4)前記ルチル型酸化チタン及び前記高い光触媒能を示す化合物の粒子径が、一次粒子径で共に100nm以下である、(1)〜(3)のいずれか一つの光触媒塗膜。
(5)前記高い光触媒能を示す化合物がアナターゼ型酸化チタンである、請求項1〜4のいずれか一項に記載の光触媒塗膜。
(6)水系バインダーを含む、(1)〜(5)のいずれか一つの光触媒塗膜。
(1)〜(6)のいずれか一つの光触媒塗膜を形成するために用いられる光触媒組成物。
上述の高い光触媒能を示す化合物は1種を単独で又は2種以上を組み合わせて用いられる。
6/X≦a≦40/X (1b)
ここで、式(1b)におけるX、aはそれぞれ上記式(1)におけるものと同義である。
水系バインダーは、光触媒塗膜の全質量に対して、30質量%〜99.9質量%含まれることが好ましく、50質量%〜99質量%含まれることがより好ましい。当該範囲で水系バインダーを含むことで、光触媒塗膜は、成膜性に一層優れると共に、その成膜性と光触媒の活性とを更にバランスよく両立することができる。
SiWxRy (2)
ここで、式中、Wは炭素数1〜20のアルコキシ基、水酸基、炭素数1〜20のアセトキシ基、ハロゲン原子、水素原子、炭素数1〜20のオキシム基、フェノキシ基、アミノキシ基、アミド基からなる群より選ばれる基を示す。Rは、直鎖状若しくは分岐状の炭素数1〜30のアルキル基、炭素数5〜20のシクロアルキル基、炭素数6〜20のアリール基からなる群より選ばれる炭化水素基を示す。なお、炭素数6〜20のアリール基は、炭素数1〜20のアルキル基、炭素数1〜20のアルコキシ基又はハロゲン原子で置換されていてもよい。また、xは1〜4の整数であり、yは0〜3の整数であり、x+y=4である。さらに、xが2以上のとき、複数のWは互いに同一でも異なっていてもよく、yが2以上のとき、複数のRは互いに同一でも異なっていてもよい。
上記基体材料の種類や膜厚は用途に応じて使い分けることができる。
接触角は、光触媒塗膜の表面に脱イオン水の滴を載せ、23℃で1分間放置した後、協和界面科学社製、CA−X150型接触角計を用いて測定した。塗膜に対する水の接触角が小さいほど、塗膜表面は親水性が高い。
2.透明性
光触媒塗膜の透明性は、後述のようにしてPETフィルム上に光触媒塗膜を形成し、その状態で日本電色工業社製濁度計(商品名「NDH2000」)を用いて、JIS−K7105に準じてヘイズ値を測定して評価した。
オーク製作所製の紫外線照射装置(商品名「HandyUV300」)を用いて高圧水銀灯の光を光触媒塗膜に照射した。照射を開始してから15時間経過後の塗膜及びPETフィルムの積層体のヘイズ値を上記2と同様に測定して、PETフィルム及び光触媒塗膜の耐久性を評価した。耐久性に劣るとヘイズ値が上昇し、さらに劣化が進行することによって、光触媒塗膜が剥離する。
4.光触媒活性(分解指数)
JIS R 1703−2に準拠して光触媒塗膜の湿式分解性能試験を実施し、波長664nmの吸光度から分解指数を求めた。このとき、メチレンブルーとして、和光純薬工業社製のメチレンブルー三水和物を用いた。吸光度の測定には、日本分光社製紫外・可視分光光度計(商品名「V−550」)を用いた。
(水系バインダーの作成)
還流冷却器、滴下槽、温度計及び撹拌装置を有する反応器に、イオン交換水400g、10質量%のドデシルベンゼンスルホン酸水溶液2.57gを投入した後、撹拌下で温度を80℃に加温した。この反応器中に、ジメチルジメトキシシラン54.5g、フェニルトリメトキシシラン34.4g及びメチルトリメトキシシラン1.0gの混合液と、過硫酸アンモニウムの2質量%水溶液15.0gとを、反応器中の温度を80℃に保った状態で約2時間かけて同時に滴下した。その後、反応器中の温度を80℃に維持した状態で約1時間撹拌を続行した。次に、アクリル酸ブチル12.3g、フェニルトリメトキシシラン13。5g、テトラエトキシシラン31.4g及び3−メタクリロキシプロピルトリメトキシシラン1.2gの混合液と、ジエチルアクリルアミド24.6g、アクリル酸1g、反応性乳化剤(商品名「アデカリアソープSR−1025」、旭電化(株)製、固形分25%水溶液)1.2g、反応性乳化剤(商品名「アクアロンKH−1025」、第一工業製薬(株)製、固形分25%水溶液)0.7g、過硫酸アンモニウムの2質量%水溶液8.5g及びイオン交換水255gの混合液とを、反応器中の温度を80℃に保った状態で約2時間かけて同時に滴下した。さらに、反応器中の温度を80℃に維持した状態で約2時間撹拌を続行した。その後、反応器中の液を室温まで冷却し、100メッシュの金網で濾過して、固形分12.8質量%の重合体エマルジョン水分散体を得た。そして、イオン交換水で固形分が10.0質量%となるように調整して重合体エマルジョン水分散体(a)を得た。重合体エマルジョン粒子の数平均粒子径は183nmであった。
水系バインダー水分散体(A)に対して、ルチル型酸化チタン(石原産業社製、商品名「TTO−W−05」、固形分30質量%)1.67gとアナターゼ型酸化チタン(石原産業社製、商品名「MPT−422」、固形分20質量%)2.5gとを混合し、光触媒組成物を調製した。この光触媒組成物を20cm四方のPETフィルム(膜厚:90μm)の表面にバーコート法により塗布し、70℃で10分間乾燥して、膜厚2.1μmの光触媒塗膜を得た。各種評価結果を表1に示す。なお、表1中、「ルチル型酸化チタン量(%)」は、光触媒塗膜の総量に対するルチル型酸化チタンの含有割合(単位:質量%)を示し、「アナターゼ型酸化チタン量(%)」は、光触媒塗膜の総量に対するアナターゼ型酸化チタンの含有割合(単位:質量%)を示す。また、「透明性」、「耐光性試験後の透明性」はいずれもヘイズ値を示す。
光触媒塗膜の総量に対するルチル型酸化チタン及びアナターゼ型酸化チタンの含有割合を表1に示すように変更した以外は実施例1と同様にして、光触媒塗膜を得た。各種評価結果を表1に示す。なお、表1中「−」は、光触媒塗膜中にルチル型酸化チタン及び/又はアナターゼ型酸化チタンを含まないことを意味する。また、「剥離」は光触媒塗膜がPETフィルムから剥離したことを示す。
Claims (7)
- ルチル型酸化チタン及び高い光触媒能を示す化合物を含む光触媒塗膜であって、前記ルチル型酸化チタンの含有割合が下記式(1)で表される条件を満足する、光触媒塗膜。
4/X≦a≦100/X (1)
(式中、Xは前記光触媒塗膜の膜厚(単位:μm)を示し、aは前記ルチル型酸化チタンの前記光触媒塗膜の総量に対する含有割合(単位:質量%)を示す。) - 前記ルチル型酸化チタンの含有割合が下記式(1a)で表される条件を満足する、請求項1記載の光触媒塗膜。
4/X≦a≦60/X (1a)
(式中、Xは前記光触媒塗膜の膜厚(単位:μm)を示し、aは前記ルチル型酸化チタンの前記光触媒塗膜の総量に対する含有割合(単位:質量%)を示す。) - 前記ルチル型酸化チタンに対する前記高い光触媒能を示す化合物の質量比が0.10〜2.0である、請求項1又は2に記載の光触媒塗膜。
- 前記ルチル型酸化チタン及び前記高い光触媒能を示す化合物の粒子径が、一次粒子径で共に100nm以下である、請求項1〜3のいずれか一項に記載の光触媒塗膜。
- 前記高い光触媒能を示す化合物がアナターゼ型酸化チタンである、請求項1〜4のいずれか一項に記載の光触媒塗膜。
- 水系バインダーを含む、請求項1〜5のいずれか一項に記載の光触媒塗膜。
- 請求項1〜6のいずれか一項に記載の光触媒塗膜を形成するために用いられる光触媒組成物。
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