JP2009218560A - 太陽電池用リード線及びその製造方法並びに太陽電池 - Google Patents
太陽電池用リード線及びその製造方法並びに太陽電池 Download PDFInfo
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- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 title claims abstract description 99
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000004020 conductor Substances 0.000 claims abstract description 167
- 229910000679 solder Inorganic materials 0.000 claims abstract description 140
- 238000007747 plating Methods 0.000 claims abstract description 75
- 239000004065 semiconductor Substances 0.000 claims description 70
- 239000000758 substrate Substances 0.000 claims description 70
- 238000010438 heat treatment Methods 0.000 claims description 29
- 229910052802 copper Inorganic materials 0.000 claims description 16
- 229910052709 silver Inorganic materials 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 238000005096 rolling process Methods 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052737 gold Inorganic materials 0.000 claims description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 229910052787 antimony Inorganic materials 0.000 claims description 5
- 229910052797 bismuth Inorganic materials 0.000 claims description 5
- 229910052738 indium Inorganic materials 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 239000011574 phosphorus Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 229910052745 lead Inorganic materials 0.000 claims description 4
- 230000001629 suppression Effects 0.000 abstract description 3
- 230000001788 irregular Effects 0.000 abstract 2
- 210000004027 cell Anatomy 0.000 description 157
- 239000010949 copper Substances 0.000 description 42
- 238000005336 cracking Methods 0.000 description 19
- 238000012545 processing Methods 0.000 description 13
- 238000000034 method Methods 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000002994 raw material Substances 0.000 description 9
- 238000005476 soldering Methods 0.000 description 7
- 230000035882 stress Effects 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000005304 joining Methods 0.000 description 4
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000008646 thermal stress Effects 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
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- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
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Abstract
【解決手段】帯板状導電材をダイス加工することによって、上下面a、bには凹面2a、2bを有すると共に側面c、dには凸面3c、3dを有する凹凸導電材4を形成し、凹凸導電材4の凹面2a、2bに溶融はんだを供給して溶融はんだめっき層5を平坦に形成した。
【選択図】図1
Description
原料導電材であるCu材料を圧延加工して幅2.0mm、厚さ0.16mmの平角線状の帯板状導電材を形成した。この帯板状導電材をダイス加工して凹面2a、2bを有する凹凸導電材4を作成した。この凹凸導電材4をバッチ式加熱設備で熱処理し、さらに、この凹凸導電材4の周囲にSn−3%Ag−0.5Cuはんだめっきを施して凹凸導電材4の凹面2a、2bに溶融はんだめっき層5を平坦に形成した(導体は熱処理Cu)。以上により、図1の太陽電池用リード線1を得た。
実施例1の太陽電池用リード線1の構成に加え、側面c、dの凸面3c、3dに側部溶融はんだめっき層22c、22dを形成して図2の太陽電池用リード線21を得た。
原料導電材であるCu−インバー−Cu(比率2:1:2)材料をスリット加工して幅2.0mm、厚さ0.16mmの平角線状の帯板状導電材を形成した。この帯板状導電材をダイス加工して凹面2a、2bを有する凹凸導電材4を作成した。この凹凸導電材4の周囲にはんだめっきを施して凹凸導電材4の凹面2a、2bに溶融はんだめっき層5を平坦に形成した。以上により、図1の太陽電池用リード線1を得た。
原料導電材であるCu材料を圧延加工して幅2.0mm、厚さ0.16mmの平角線状の帯板状導電材112を形成した。この帯板状導電材112をバッチ式加熱設備で熱処理し、さらに、この帯板状導電材112の周囲にはんだめっきを施して帯板状導電材112の平坦な上下面に山形に膨らんだ溶融はんだめっき層113を形成した(導体は熱処理Cu)。以上により、図5の太陽電池用リード線111を得た。
原料導電材であるCu−インバー−Cu(比率2:1:2)材料をスリット加工して幅2.0mm、厚さ0.16mmの下凹面導電材123を形成した。この下凹面導電材123の周囲にはんだめっきを施して下凹面導電材123の凹面122に平坦な溶融はんだめっき層124を形成すると共に、平坦な側面には山形に膨らんだ溶融はんだめっき層125を形成した。以上により、図6の太陽電池用リード線121を得た。
[(割れが生じないセル枚数)
/(はんだ付け試験を行ったセル枚数)]×100
表2に示されるように、実施例1〜3の太陽電池用リード線は、ダイス加工によって上下面a、bに凹面2a、2bを有し側面に凸面3c、3dを有する凹凸導電材4を形成し、凸面3c、3dに溶融はんだを供給して溶融はんだめっき層5を平坦に形成したので、優れた接合力が得られることが確認された。
2a、2b 凹面
3c、3d 凸面
4 凹凸導電材
5 溶融はんだめっき層
Claims (8)
- 導電材の表面に溶融はんだを供給して溶融はんだめっき層を形成した太陽電池用リード線において、帯板状導電材をダイス加工することによって、上下面には凹面を有すると共に側面には凸面を有する凹凸導電材を形成し、該凹凸導電材の上記凹面に溶融はんだを供給して上記溶融はんだめっき層を平坦に形成したことを特徴とする太陽電池用リード線。
- 導電材の表面に溶融はんだを供給して溶融はんだめっき層を形成した太陽電池用リード線において、帯板状導電材をダイス加工することによって、上下面には凹面を有すると共に側面には凸面を有する凹凸導電材を形成し、該凹凸導電材の上記凹面に溶融はんだを供給し、上記上下面の凹面に溶融はんだめっき層を平坦に形成したことを特徴とする太陽電池用リード線。
- 上記帯板状導電材は、体積抵抗率が50μΩ・mm以下の平角線であることを特徴とする請求項1又は2記載の太陽電池用リード線。
- 上記帯板状導電材は、Cu、Al、Ag、Auのいずれかからなることを特徴とする請求項1〜3いずれか記載の太陽電池用リード線。
- 上記帯板状導電材は、タフピッチCu、低酸素Cu、無酸素Cu、リン脱酸Cu、高純度Cu(99.9999%以上)のいずれかからなることを特徴とする請求項1〜4いずれか記載の太陽電池用リード線。
- 上記溶融はんだめっき層は、Sn系はんだ、又は、第1成分としてSnを用い、第2成分としてPb、In、Bi、Sb、Ag、Zn、Ni、Cuから選択される少なくとも1つの元素を0.1wt%以上含むSn系はんだ合金からなることを特徴とする請求項1〜5いずれか記載の太陽電池用リード線。
- 原料導電材を圧延加工又はスリット加工することにより帯板状導電材を形成し、この帯板状導電材をダイス加工することによって、上下面には凹面を有すると共に側面には凸面を有する凹凸導電材を形成し、該凹凸導電材を連続通電加熱炉又は連続式加熱炉又はバッチ式加熱設備で熱処理し、その後、上記凹面に溶融はんだを供給して溶融はんだめっき層を平坦に形成することを特徴とする太陽電池用リード線の製造方法。
- 請求項1〜6いずれか記載の太陽電池用リード線を上記溶融はんだめっき層のはんだによって半導体基板の表面電極及び裏面電極にはんだ付けしたことを特徴とする太陽電池。
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US12/385,417 US20090260689A1 (en) | 2008-02-13 | 2009-04-07 | Solar cell lead wire, method of making the same, and solar cell |
CN2009101584818A CN101740642B (zh) | 2008-11-11 | 2009-07-08 | 太阳电池用引线及其制造方法以及太阳电池 |
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JP2012182271A (ja) * | 2011-03-01 | 2012-09-20 | Hitachi Cable Ltd | 太陽電池用リード線およびその製造方法並びにそれを用いた太陽電池 |
WO2013187234A1 (ja) * | 2012-06-13 | 2013-12-19 | 東洋鋼鈑株式会社 | 太陽電池用インターコネクタ、およびインターコネクタ付き太陽電池セル |
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WO2004105141A1 (ja) * | 2003-05-22 | 2004-12-02 | Neomax Materials Co., Ltd. | 電極線材およびその線材によって形成された接続用リード線を備えた太陽電池 |
WO2005114751A1 (ja) * | 2004-05-21 | 2005-12-01 | Neomax Materials Co., Ltd. | 太陽電池用電極線材 |
JP2006054355A (ja) * | 2004-08-13 | 2006-02-23 | Hitachi Cable Ltd | 太陽電池用平角導体及びその製造方法並びに太陽電池用リード線 |
JP2007141930A (ja) * | 2005-11-15 | 2007-06-07 | Neomax Material:Kk | 太陽電池用電極線材及びその製造方法 |
JP2010027867A (ja) * | 2008-07-18 | 2010-02-04 | Hitachi Cable Ltd | 太陽電池用リード線及びその製造方法 |
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WO2004105141A1 (ja) * | 2003-05-22 | 2004-12-02 | Neomax Materials Co., Ltd. | 電極線材およびその線材によって形成された接続用リード線を備えた太陽電池 |
WO2005114751A1 (ja) * | 2004-05-21 | 2005-12-01 | Neomax Materials Co., Ltd. | 太陽電池用電極線材 |
JP2006054355A (ja) * | 2004-08-13 | 2006-02-23 | Hitachi Cable Ltd | 太陽電池用平角導体及びその製造方法並びに太陽電池用リード線 |
JP2007141930A (ja) * | 2005-11-15 | 2007-06-07 | Neomax Material:Kk | 太陽電池用電極線材及びその製造方法 |
JP2010027867A (ja) * | 2008-07-18 | 2010-02-04 | Hitachi Cable Ltd | 太陽電池用リード線及びその製造方法 |
Cited By (3)
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JP2011091168A (ja) * | 2009-10-21 | 2011-05-06 | Hitachi Cable Fine Tech Ltd | 太陽電池用リード線およびその製造方法並びにそれを用いた太陽電池 |
JP2012182271A (ja) * | 2011-03-01 | 2012-09-20 | Hitachi Cable Ltd | 太陽電池用リード線およびその製造方法並びにそれを用いた太陽電池 |
WO2013187234A1 (ja) * | 2012-06-13 | 2013-12-19 | 東洋鋼鈑株式会社 | 太陽電池用インターコネクタ、およびインターコネクタ付き太陽電池セル |
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