JP2009161755A - Anisotropically electrically conductive adhesive composition, method for connecting circuit terminal using it and connected structure - Google Patents
Anisotropically electrically conductive adhesive composition, method for connecting circuit terminal using it and connected structure Download PDFInfo
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本発明は、異方導電性接着剤組成物、それを用いた回路端子の接結方法及びその接続構造に関し、特にCHIP ON GLASS実装(以下COG実装と称す)またはCHIP ON FILM(以下COF実装と称す)における回路端子の接続方法及び回路端子の接続構造体に関する。 The present invention relates to an anisotropic conductive adhesive composition, a method of connecting a circuit terminal using the same, and a connection structure thereof, and in particular, CHIP ON GLASS mounting (hereinafter referred to as COG mounting) or CHIP ON FILM (hereinafter referred to as COF mounting). The circuit terminal connection method and the circuit terminal connection structure.
液晶表示用ガラスパネルへの液晶駆動用ICの実装は,液晶駆動用ICを直接ガラスパネル上に回路接続部材で接合するCOG実装方法や、液晶駆動用ICを、金属配線を有するフレキシブルテープに接合しガラスパネルと回路接続部材で接合するCOF実装方法が用いられる。液晶表示の高精細化に伴い、液晶駆動用ICの電極である金バンプは狭ピッチ化、狭面積化している。このため、接合材料中の導電粒子が隣接電極間に流出し、ショートを発生させるといった問題や、バンプ上に捕捉される接合材料中の導電粒子数が減少し、その結果回路間の接続抵抗が上昇し接続不良を起こすといった問題がある。そこで、これらの問題を解決するため、接合材料の少なくとも片面に絶縁性の接着層を形成することで、COG実装及びCOF実装における接合品質の低下を防ぐ方法(例えば特開平8−279371号公報)や、導電粒子の表面を電気的絶縁性の皮膜で被覆する方法(例えば特許第2794009号公報)が提案されている。 The liquid crystal driving IC is mounted on the glass panel for liquid crystal display by a COG mounting method in which the liquid crystal driving IC is directly bonded to the glass panel with a circuit connecting member, or the liquid crystal driving IC is bonded to a flexible tape having metal wiring. A COF mounting method in which the glass glass panel and the circuit connecting member are joined is used. Along with the high definition of the liquid crystal display, the gold bumps which are the electrodes of the liquid crystal driving IC are becoming narrower in pitch and area. As a result, the conductive particles in the bonding material flow out between adjacent electrodes, causing a short circuit, and the number of conductive particles in the bonding material captured on the bumps is reduced. As a result, the connection resistance between the circuits is reduced. There is a problem of rising and causing poor connection. Therefore, in order to solve these problems, a method for preventing deterioration in bonding quality in COG mounting and COF mounting by forming an insulating adhesive layer on at least one surface of the bonding material (for example, JP-A-8-279371) In addition, a method (for example, Japanese Patent No. 2794409) in which the surface of conductive particles is coated with an electrically insulating film has been proposed.
しかしながら、片面に絶縁性の接着層を形成する方法では、バンプ面積が3000μm2未満となった場合、安定した接続抵抗値を得るために粒子の充填量を増やすと、隣接回路間でのショート発生率が上昇し、絶縁不良が発生するという問題があった。また、導電粒子の表面を電気的絶縁性の皮膜で被覆する方法では、接続抵抗値が上昇し、安定した電気抵抗が得られないという問題があった。本発明は、COG実装やCOF実装に対して低抵抗の電気接続が得られ、かつ隣接電極間でショート発生のない電気・電子用の異方導電性接着剤組成物、それを用いた回路端子の接続方法及び回路端子の接続構造体を提供するものである。 However, in the method of forming an insulating adhesive layer on one side, when the bump area is less than 3000 μm 2 , if the filling amount of particles is increased to obtain a stable connection resistance value, a short circuit occurs between adjacent circuits. There was a problem that the rate increased and insulation failure occurred. Further, the method of coating the surface of the conductive particles with an electrically insulating film has a problem that the connection resistance value increases and a stable electric resistance cannot be obtained. The present invention relates to an anisotropic conductive adhesive composition for electric and electronic use that can provide a low resistance electrical connection to COG mounting and COF mounting, and that does not cause a short circuit between adjacent electrodes, and a circuit terminal using the same The connection method and circuit terminal connection structure are provided.
本発明の異方導電性接着剤組成物は、相対峙する回路電極間に介在され、相対向する回路電極を加熱加圧し、加圧方向の電極間を電気的に接続する接着剤組成物であり、[1](1)エポキシ樹脂、(2)潜在性硬化剤、(3)フィルム形成材、(4)表面が有機高分子化合物で被覆された導電粒子を必須成分としで含有する接着剤組成物であって、下記構造式(1)で示されるエポキシ樹脂を含み、前記フィルム形成材がフェノキシ樹脂である異方導電性接着剤組成物である。本発明で用いる導電粒子は、表面が、金、銀、白金族の金属から選ばれる少なくとも一種で構成され、さらにその金属表面を有機高分子化合物で被覆されていると好ましい。有機高分子化合物は水溶性であると被覆作業性が良好で好ましい。本発明の異方導電性接着剤組成物は、導電粒子を含有する層とその他の層とに分離した多層構成とすることができ、この時、導電粒子を含有する接着層の厚みは、導電粒子の粒径の3倍未満であるのが好ましく,2倍未満がより好ましい。導電粒子を含有する接着層の厚みが3倍以上の場合、導電粒子が隣接電極間に流出する量が多くなり、絶縁性が低下するので好ましくない。
また、本発明は、[2] フェノキシ樹脂が、分子内に多環芳香族化合物に起因する分子構造を有する上記[1]に記載の異方導電性接着剤組成物である。さらに、本発明は、[3]第一の接続端子を有する第一の回路部材と、第二の接続端子を有する第二の回路部材とを、第一の接続端子と第二の接続端子を対向して配置し、前記対向配置した第一の接続端子と第二の接続端子の間に上記[1]または上記[2]に記載の異方導電性接着剤組成物を介在させ、加熱加圧して前記対向配置した第一の接続端子と第二の接続端子を電気的に接続させる回路端子の接続方法である。また、本発明は、[4]上記[3]に記載の回路端子の接続方法により得られる回路接続構造体であって、回路端子に直流50V印加した際に隣接電極間の絶縁抵抗が109Ω以上である回路接続構造体である。また、本発明は、[5]少なくとも一方の接続端子を有する回路部材が、ICチップである上記[4]に記載の回路接続構造体である。また、本発明は、[6]ICチップの接続端子と、第二の回路部材上との接続端子間の接続抵抗が、1Ω以下である上記[4]または上記[5]に記載の回路接続構造体である。また、本発明は、[7]少なくとも一方の接続端子の表面が金、銀、錫、白金族の金属、インジユウム−錫酸化物(ITO)から選ばれる少なくとも一種で構成される上記[4]ないし上記[6]のいずれかに記載の回路接続構造体である。また、本発明は、[8]少なくとも一方の回路部材表面が窒化シリコン、シリコーン化合物、ポリイミド樹脂から選ばれる少なくとも一種でコーティングまたは付着されている上記[4]ないし上記[7]のいずれかに記載の回路接続構造体である。
The anisotropic conductive adhesive composition of the present invention is an adhesive composition that is interposed between circuit electrodes facing each other, heats and presses opposite circuit electrodes, and electrically connects the electrodes in the pressing direction. Yes, [1] (1) epoxy resin, (2) latent curing agent, (3) film-forming material, (4) adhesive containing conductive particles whose surface is coated with an organic polymer compound as an essential component It is a composition, Comprising: The anisotropic conductive adhesive composition which contains the epoxy resin shown by following Structural formula (1), and the said film formation material is a phenoxy resin. The surface of the conductive particles used in the present invention is preferably composed of at least one selected from gold, silver, and platinum group metals, and the metal surface is coated with an organic polymer compound. It is preferable that the organic polymer compound is water-soluble because the coating workability is good. The anisotropic conductive adhesive composition of the present invention can have a multi-layer structure separated into a layer containing conductive particles and another layer. At this time, the thickness of the adhesive layer containing conductive particles The particle size is preferably less than 3 times the particle size, more preferably less than 2 times. When the thickness of the adhesive layer containing the conductive particles is three times or more, the amount of the conductive particles flowing out between the adjacent electrodes is increased, which is not preferable.
Moreover, this invention is an anisotropic conductive adhesive composition as described in said [1] in which [2] phenoxy resin has the molecular structure resulting from a polycyclic aromatic compound in a molecule | numerator. Furthermore, the present invention provides [3] a first circuit member having a first connection terminal, a second circuit member having a second connection terminal, a first connection terminal and a second connection terminal. The anisotropic conductive adhesive composition according to the above [1] or [2] is interposed between the first connection terminal and the second connection terminal that are disposed to face each other, and heated. This is a circuit terminal connection method in which the first connection terminal and the second connection terminal that are arranged to face each other are electrically connected. The present invention is also [4] a circuit connection structure obtained by the circuit terminal connection method described in [3] above, wherein the insulation resistance between adjacent electrodes is 10 9 when a DC voltage of 50 V is applied to the circuit terminals. The circuit connection structure is Ω or more. [5] The circuit connection structure according to [4], wherein the circuit member having at least one connection terminal is an IC chip. [6] The circuit connection according to [4] or [5], wherein the connection resistance between the connection terminal of the IC chip and the connection terminal on the second circuit member is 1Ω or less. It is a structure. [7] The above [4] to [7], wherein the surface of at least one of the connection terminals is composed of at least one selected from gold, silver, tin, platinum group metals, and indium-tin oxide (ITO). The circuit connection structure according to any one of [6] above. In addition, the present invention is [8] any one of the above [4] to [7], wherein the surface of at least one circuit member is coated or adhered with at least one selected from silicon nitride, silicone compound, and polyimide resin. This is a circuit connection structure.
本発明によれば、COG実装やCOF実装において、バンプ間距離の狭い駆動用ICであっても、低抵抗かつ隣接電極間では絶縁性の高い電気接続が得られ、高信頼性の電気・電子用接着剤組成物の提供が可能となる。 According to the present invention, even in a driving IC with a short distance between bumps in COG mounting or COF mounting, an electrical connection with low resistance and high insulation can be obtained between adjacent electrodes, and highly reliable electric / electronic It is possible to provide an adhesive composition for use.
本発明で使用するエポキシ樹脂は、下記構造式(1)で示され、ナフタレン系ヒドロキシ化合物とエピクロルヒドリンとを反応させて得られる。
さらに、エピクロルヒドリンとビスフェノールAやビスフェノールF、ビスフェノールAD等から誘導されるビスフェノール型エポキシ樹脂、エピクロルヒドリンとフェノールノボラックやクレゾールノボラックから誘導されるエポキシノボラック樹脂やグリシジルアミン、グリシジルエーテル、ビフェニル、脂環式等の1分子内に2個以上のグリシジル基を有する各種のエポキシ化合物等を混合して用いることが可能である。この時、構造式(1)で示されるエポキシ樹脂は、接着剤組成中3重量%以上用いられるのが好ましく、更に好ましくは10重量%以上である。 Furthermore, bisphenol-type epoxy resins derived from epichlorohydrin and bisphenol A, bisphenol F, bisphenol AD, etc., epoxy novolac resins derived from epichlorohydrin and phenol novolac or cresol novolak, glycidylamine, glycidyl ether, biphenyl, alicyclic, etc. It is possible to mix and use various epoxy compounds having two or more glycidyl groups in one molecule. At this time, the epoxy resin represented by the structural formula (1) is preferably used in an amount of 3% by weight or more in the adhesive composition, more preferably 10% by weight or more.
本発明で使用する潜在性硬化剤としては、イミダゾール系、ヒドラジド系、三フッ化ホウ素−アミン錯体、スルホニウム塩、アミンイミド、ポリアミンの塩、ジシアンジアミド等が拳げられる。これらは、単独または混合して使用することができ、分解促進剤、抑制剤等を混合して用いてもよい。また、これらの硬化剤をポリウレタン系、ポリエステル系の高分子物質等で被覆してマイクロカプセル化したものは、可使時間が延長されるために好ましい。 Examples of the latent curing agent used in the present invention include imidazole series, hydrazide series, boron trifluoride-amine complex, sulfonium salt, amine imide, polyamine salt, dicyandiamide and the like. These can be used alone or in combination, and may be used by mixing a decomposition accelerator, an inhibitor and the like. In addition, those encapsulating these curing agents with polyurethane-based or polyester-based polymeric substances and the like and microencapsulated are preferable because the pot life is extended.
本発明で使用するフィルム形成材としては、フェノキシ樹脂、ポリビニルホルマール樹脂、ポリスチレン樹脂、ポリビニルブチラール樹脂、ポリエステル樹脂、ポリアミド樹脂、キシレン樹脂、ポリウレタン樹脂等が拳げられる。フィルム形成材は、液状物を固形化し、構成組成物をフィルム形状とした場合に、そのフィルムの取り扱いが容易で、容易に裂けたり、割れたり、ベたついたりしない機械特性等を付与するものであり、通常の状態でフィルムとしての取り扱いができるものである。フィルム形成材の中でも接着性、相溶性、耐熱性、機械強度に優れることからフェノキシ樹脂が好ましい。フェノキシ樹脂は2官能フェノール類とエピハロヒドリンを高分子量まで反応させるか、又は2官能エポキシ樹脂と2官能フェノール類を重付加させることにより得られる樹脂である。具体的には、2官能フェノール類1モルとエピハロヒドリン0.985〜1.015とをアルカリ金属水酸化物の存在下で非反応性溶媒中で40〜120℃の温度で反応させることにより得ることができる。また、樹脂の機械的特性や熱的特性の点からは、特に2官能性エポキシ樹脂と2官能性フェノール類の配合等量比をエポキシ基/フェノール水酸基=1/0.9〜1/1.1としアルカリ金属化合物、有機リン系化合物、環状アミン系化合物等の触媒の存在下で沸点が120℃以上のアミド系、エーテル系、ケトン系、ラクトン系、アルコール系等の有機溶剤中で反応固形分が50重量部以下で50〜200℃に加熱して重付加反応させて得たものが好ましい。2官能エポキシ樹脂としては、ビスフェノールA型エポキシ樹脂、ビスフェノールF型エポキシ樹脂、ビスフェノールAD型エポキシ樹脂、ビスフェノールS型エポキシ樹脂などがある。2官能フェノール類は2個のフェノール性水酸基を持つもので、例えば、ハイドロキノン類、ビスフェノールA、ビスフェノールF、ビスフェノールAD、ビスフェノールS等のビスフェノール類などが挙げられる。フェノキシ樹脂はラジカル重合性の官能基により変性されていてもよい。本発明で使用するフェノキシ樹脂は、その分子内に多環芳香族化合物に起因する分子構造を有することが好ましい。例えばナフタレン、ビフェニル、アセナフテン、フルオレン、ジベンゾフラン、アントラセン、フェナンスレン等のジヒドロキシ化合物であり、特に好ましくは9,9’−ビス(4−ヒドロキシフェニル)フルオレンである。このフェノキシ樹脂もラジカル重合性の官能基により変性されていてもよく、フェノキシ樹脂は、単独で用いても、2種類以上を混合して用いてもよい。 Examples of the film forming material used in the present invention include phenoxy resin, polyvinyl formal resin, polystyrene resin, polyvinyl butyral resin, polyester resin, polyamide resin, xylene resin, polyurethane resin and the like. A film-forming material is a material that solidifies a liquid material and forms a constituent composition into a film shape, so that the film is easy to handle and imparts mechanical properties that are not easily torn, cracked, or sticky. It can be handled as a film in a normal state. Among the film forming materials, a phenoxy resin is preferable because it is excellent in adhesiveness, compatibility, heat resistance, and mechanical strength. The phenoxy resin is a resin obtained by reacting a bifunctional phenol and epihalohydrin to a high molecular weight or by polyaddition of a bifunctional epoxy resin and a bifunctional phenol. Specifically, it is obtained by reacting 1 mol of a bifunctional phenol and epihalohydrin 0.985 to 1.015 in a non-reactive solvent at a temperature of 40 to 120 ° C. in the presence of an alkali metal hydroxide. Can do. Further, from the viewpoint of the mechanical properties and thermal properties of the resin, the blending equivalence ratio of the bifunctional epoxy resin and the bifunctional phenols is particularly determined as epoxy group / phenol hydroxyl group = 1 / 0.9 to 1/1. 1 in the presence of a catalyst such as an alkali metal compound, organic phosphorus compound, cyclic amine compound, etc. in an amide, ether, ketone, lactone, alcohol or other organic solvent having a boiling point of 120 ° C. or higher. What is obtained by heating to 50 to 200 ° C. and subjecting it to a polyaddition reaction with a content of 50 parts by weight or less is preferred. Examples of the bifunctional epoxy resin include bisphenol A type epoxy resin, bisphenol F type epoxy resin, bisphenol AD type epoxy resin, and bisphenol S type epoxy resin. Bifunctional phenols have two phenolic hydroxyl groups, and examples include hydroquinones, bisphenols such as bisphenol A, bisphenol F, bisphenol AD, and bisphenol S. The phenoxy resin may be modified with a radical polymerizable functional group. The phenoxy resin used in the present invention preferably has a molecular structure resulting from a polycyclic aromatic compound in the molecule. Examples thereof include dihydroxy compounds such as naphthalene, biphenyl, acenaphthene, fluorene, dibenzofuran, anthracene and phenanthrene, and 9,9'-bis (4-hydroxyphenyl) fluorene is particularly preferable. This phenoxy resin may also be modified with a radical polymerizable functional group, and the phenoxy resin may be used alone or in combination of two or more.
本発明の異方導電性接着剤組成物には、アクリル酸、アクリル酸エステル、メタクリル酸エステルまたはアクリロニトリルのうち少なくとも一つをモノマー成分とした重合体又は共重合体を使用することができ、グリシジルエーテル基を含有するグリシジルアクリレートやグリシジルメタクリレートを含む共重合体系アクリルゴムを併用した場合、応力援和に優れるので好ましい。これらアクリルゴムの分子量(重量平均)は接着剤の凝集力を高める点から20万以上が好ましい。 In the anisotropic conductive adhesive composition of the present invention, a polymer or copolymer containing at least one of acrylic acid, acrylic ester, methacrylic ester or acrylonitrile as a monomer component can be used. When a copolymer acrylic rubber containing glycidyl acrylate or glycidyl methacrylate containing an ether group is used in combination, it is preferable because stress compensation is excellent. The molecular weight (weight average) of these acrylic rubbers is preferably 200,000 or more from the viewpoint of increasing the cohesive strength of the adhesive.
本発明の異方導電性接着剤組成物には、さらに、充填剤、軟化剤、促進剤、老化防止剤、着色剤、難燃化剤、チキソトロピック剤、カップリング剤及びフェノール樹脂やメラミン樹脂、イソシアネート類等を含有することもできる。充填剤を含有した場合、接続信頼性等の向上が得られるので好ましい。充填剤の最大径が導電粒子の粒径未満であれば使用でき、5〜60体積部(接着剤樹脂成分100体積部に対して)の範囲が好ましい。60体積部を超えると信頼性向上の効果が飽和することがあり、5体積部未満では添加の効果が少ない。カップリング剤としてはケチミン、ビニル基、アクリル基、アミノ基、エポキシ基及びイソシアネート基含有物が、接着性の向上の点から好ましい。具体的には、アミノ基を有するシランカップリング剤として、N−β(アミノエチル)γ−アミノプロピルトリメトキシシラン、N−β(アミノエチル)γ−アミノプロピルメチルジメトキシシラン、γ−アミノプロピルトリエトキシシラン、N−フェニル−γ−アミノプロピルトリメトキシシラン等が挙げられる。ケチミンを有するシランカップリング剤として、上記のアミノ基を有するシランカップリング剤に、アセトン、メチルエチルケトン、メチルイソブチルケトン等のケトン化合物を反応させて得られたものが挙げられる。 The anisotropic conductive adhesive composition of the present invention further includes a filler, a softener, an accelerator, an anti-aging agent, a colorant, a flame retardant, a thixotropic agent, a coupling agent, a phenol resin, and a melamine resin. , Isocyanates and the like can also be contained. The inclusion of a filler is preferable because improvement in connection reliability and the like can be obtained. If the maximum diameter of a filler is less than the particle size of an electroconductive particle, it can be used, and the range of 5-60 volume parts (with respect to 100 volume parts of adhesive resin components) is preferable. If it exceeds 60 parts by volume, the effect of improving the reliability may be saturated, and if it is less than 5 parts by volume, the effect of addition is small. As the coupling agent, ketimine, vinyl group, acrylic group, amino group, epoxy group and isocyanate group-containing material are preferable from the viewpoint of improving adhesiveness. Specifically, as the silane coupling agent having an amino group, N-β (aminoethyl) γ-aminopropyltrimethoxysilane, N-β (aminoethyl) γ-aminopropylmethyldimethoxysilane, γ-aminopropyltrimethoxysilane. Examples include ethoxysilane, N-phenyl-γ-aminopropyltrimethoxysilane, and the like. Examples of the silane coupling agent having ketimine include those obtained by reacting the above silane coupling agent having an amino group with a ketone compound such as acetone, methyl ethyl ketone, and methyl isobutyl ketone.
本発明の異方導電性接着剤組成物は、有機高分子化合物で被覆された導電粒子を必須として用い、接続時に相対向する回路電極を導電粒子を介して電気的に接続することにより安定した接続が得られる。有機高分子化合物で被覆する前の導電粒子としては、Au、Ag、Ni、Cu、はんだ等の金属粒子やカーボン等であり、十分なポットライフを得るためには、表層はNi、Cu等の遷移金属類ではなくAu、Ag、白金属の貴金属類が好ましくAuがより好ましい。また、Ni等の遷移金属類の表面をAu等の貴金属類で被覆したものでもよい。また、非導電性のガラス、セラミック、プラスチック等に前記した導通層を被覆等により形成し最外層を貴金属類とした場合や熱溶融金属粒子の場合、加熱加圧により変形性を有するので電極の高さばらつきを吸収し、接続時に電極との接触面積が増加して信頼性が向上するので好ましい。貴金属類の被覆層の厚みは良好な抵抗を得るためには、100オングストローム以上が好ましい。しかし、Ni等の遷移金属の上に貴金属類の層をもうける場合では、貴金属類層の欠損や導電粒子の混合分散時に生じる貴金属類層の欠損等により生じる酸化還元作用で遊離ラジカルが発生し保存性低下を引き起こすため、300オングストローム以上が好ましい。そして、厚くなるとそれらの効果が飽和してくるので最大1μmにするのが望ましいが制限するものではない。これらの導電粒子の表面を有機高分子化合物で被覆する。有機高分子化合物は水溶性であると被覆作業性が良好で好ましい。水溶性高分子として、アルギン酸、ペクチン酸、カルボキシメチルセルロース、寒天、カードラン及びプルラン等の多糖類;ポリアスパラギン酸、ポリグルタミン酸、ポリリシン、ポリリンゴ酸、ポリメタクリル酸、ポリメタクリル酸アンモニウム塩、ポリメタクリル酸ナトリウム塩、ポリアミド酸、ポリマレイン酸、ポリイタコン酸、ポリフマル酸、ポリ(p−スチレンカルボン酸)、ポリアクリル酸、ポリアクリルアミド、ポリアクリル酸メチル、ポリアクリル酸エチル、ポリアクリル酸アンモニウム塩、ポリアクリル酸ナトリウム塩、ポリアミド酸、ポリアミド酸アンモニウム塩、ポリアミド酸ナトリウム塩及びポリグリオキシル酸等のポリカルボン酸、ポリカルボン酸エステル及びその塩;ポリビニルアルコール、ポリビニルピロリドン及びポリアクロレイン等のビニル系モノマー等が挙げられるこれらは単一の化合物を用いてもよく、二以上の化合物を併用してもよい。被覆の厚みは、1μm以下が好ましく、この被覆を排除して導電粒子が接続端子と接続端子を電気的に接続するので、加熱、加圧時には接続端子と接触する部分の被覆が排除されることが必要である。導電性粒子は、接着剤樹脂成分100体積部に対して0.1〜30体積部の範囲で用途により使い分ける。過剰な導電性粒子による隣接回路の短絡等を防止するためには0.1〜10体積部とするのがより好ましい。 The anisotropic conductive adhesive composition of the present invention uses conductive particles coated with an organic polymer compound as an essential component, and is stabilized by electrically connecting circuit electrodes facing each other through the conductive particles at the time of connection. A connection is obtained. The conductive particles before coating with the organic polymer compound are metal particles such as Au, Ag, Ni, Cu, and solder, carbon, and the like, and in order to obtain a sufficient pot life, the surface layer is made of Ni, Cu, or the like. Au, Ag, and white metal noble metals are preferred, and Au is more preferred, rather than transition metals. Further, the surface of a transition metal such as Ni may be coated with a noble metal such as Au. In addition, when the conductive layer is formed on a non-conductive glass, ceramic, plastic, etc. by coating or the like and the outermost layer is made of noble metals, or in the case of hot-melt metal particles, it is deformable by heating and pressurization. It is preferable because it absorbs the height variation and increases the contact area with the electrode at the time of connection to improve the reliability. The thickness of the noble metal coating layer is preferably 100 angstroms or more in order to obtain good resistance. However, when a noble metal layer is formed on a transition metal such as Ni, free radicals are generated and stored due to redox action caused by defects in the noble metal layer or defects in the noble metal layer generated when the conductive particles are mixed and dispersed. In order to cause deterioration of the properties, 300 angstroms or more is preferable. When the thickness is increased, these effects are saturated, so that the maximum thickness is preferably 1 μm, but is not limited. The surface of these conductive particles is coated with an organic polymer compound. It is preferable that the organic polymer compound is water-soluble because the coating workability is good. As water-soluble polymers, polysaccharides such as alginic acid, pectic acid, carboxymethylcellulose, agar, curdlan and pullulan; polyaspartic acid, polyglutamic acid, polylysine, polymalic acid, polymethacrylic acid, polymethacrylic acid ammonium salt, polymethacrylic acid Sodium salt, polyamic acid, polymaleic acid, polyitaconic acid, polyfumaric acid, poly (p-styrenecarboxylic acid), polyacrylic acid, polyacrylamide, polymethyl acrylate, ethyl polyacrylate, ammonium polyacrylate, polyacrylic acid Polycarboxylic acids such as sodium salt, polyamic acid, polyamic acid ammonium salt, polyamic acid sodium salt and polyglyoxylic acid, polycarboxylic acid esters and salts thereof; polyvinyl alcohol, polyvinyl pyrrole These vinyl-based monomers such as emissions and polyacrolein the like may be used a single compound may be used in combination of two or more compounds. The thickness of the coating is preferably 1 μm or less. Since the conductive particles electrically connect the connection terminal and the connection terminal by excluding this coating, the coating of the portion that contacts the connection terminal during heating and pressurization is excluded. is required. The conductive particles are properly used in the range of 0.1 to 30 parts by volume with respect to 100 parts by volume of the adhesive resin component. In order to prevent a short circuit of an adjacent circuit due to excessive conductive particles, the content is more preferably 0.1 to 10 parts by volume.
本発明の接着剤組成物をフィルムに成形し、接着剤組成物を2層以上に分割し、導電粒子を含有しない層と導電粒子を含有する層に分割したり、エポキシ樹脂と潜在性硬化剤をそれぞれ別の層に分けた場合、ポットライフの向上が得られる。本発明の異方導電性接着剤組成物は、ICチップとチップ搭載基板との接着や電気回路相互の接着用のフィルム状接着剤として使用することもできる。すなわち、第一の接続端子を有する第一の回路部材と、第二の接続端子を有する第二の回路部材とを第一の接続端子と第二の接続端子を対向して配置し、前記対向配置した第一の接続端子と第二の接続端子の間に本発明の異方導電性接着剤組成物(フィルム状接着剤)を介在させ、加熱、加圧して前記対向配置した第一の接続端子と第二の接続端子を電気的に接続させることができる。このような回路部材としては半導体チップ、抵抗体チップ、コンデンサチップ等のチップ部品、プリント基板等の基板等が用いられる。これらの回路部材には接続端子が通常は多数(場合によっては単数でもよい)設けられており、前記回路部材の少なくとも1組をそれらの回路部材に設けられた接続端子の少なくとも一部を対向配置し、対向配置した接続端子間に本発明の異方導電性接着剤組成物を介在させ、加熱、加圧して対向配置した接続端子同士を電気的に接続して回路接続体とする。回路部材の少なくとも1組を加熱、加圧することにより、対向配置した接続端子同士は、接着剤組成物中の導電粒子を介して電気的に接続することができる。本発明の接着剤組成物は、COG実装やCOF実装における、フレキシブルテープやガラス基板とICチップとの接着用のフィルム状接着剤として使用することができる。第一の接続端子を有する第一の回路部材と、第二の接続端子を有する第二の回路部材とを第一の接続端子と第二の接続端子を対向して配置し、前記対向配置した第一の接続端子と第二の接続端子の間に本発明の異方導電性接着剤組成物(フィルム状接着剤)を介在させ、加熱、加圧して前記対向配置した第一の接続端子と第二の接続端子を電気的に接続させることができる。本発明の回路端子の接続方法は、接着剤組成物を接続端子の表面が、金、銀、錫、白金族の金属、インジュウム−錫酸化物(ITO)から選ばれる少なくとも一種から構成される接続端子(電極回路)に形成した後、もう一方の接続端子(回路電極)を位置合わせし加熱、加圧して接続することができる。 The adhesive composition of the present invention is formed into a film, the adhesive composition is divided into two or more layers, and divided into a layer containing no conductive particles and a layer containing conductive particles, or an epoxy resin and a latent curing agent. If each is divided into different layers, pot life can be improved. The anisotropic conductive adhesive composition of the present invention can also be used as a film adhesive for adhesion between an IC chip and a chip mounting substrate or between electric circuits. That is, the first circuit member having the first connection terminal and the second circuit member having the second connection terminal are arranged so that the first connection terminal and the second connection terminal are opposed to each other, and the opposing The anisotropic conductive adhesive composition (film adhesive) of the present invention is interposed between the arranged first connection terminal and the second connection terminal, and heated and pressurized to place the first connection opposite to each other. The terminal and the second connection terminal can be electrically connected. As such a circuit member, a chip component such as a semiconductor chip, a resistor chip or a capacitor chip, a substrate such as a printed circuit board, or the like is used. These circuit members are usually provided with a large number of connection terminals (or a single connection terminal in some cases), and at least one set of the circuit members is arranged so that at least a part of the connection terminals provided on the circuit members are opposed to each other Then, the anisotropic conductive adhesive composition of the present invention is interposed between the connection terminals arranged opposite to each other, and the connection terminals arranged opposite to each other by heating and pressurization are electrically connected to obtain a circuit connection body. By heating and pressurizing at least one set of circuit members, the connection terminals arranged opposite to each other can be electrically connected via the conductive particles in the adhesive composition. The adhesive composition of the present invention can be used as a film adhesive for bonding a flexible tape or a glass substrate to an IC chip in COG mounting or COF mounting. The first circuit member having the first connection terminal and the second circuit member having the second connection terminal are arranged so that the first connection terminal and the second connection terminal are opposed to each other, and the opposite arrangement is made. An anisotropic conductive adhesive composition (film adhesive) of the present invention is interposed between the first connection terminal and the second connection terminal, and the first connection terminal disposed oppositely by heating and pressurizing. The second connection terminal can be electrically connected. The circuit terminal connection method of the present invention is a connection in which the surface of the connection terminal of the adhesive composition is composed of at least one selected from gold, silver, tin, a platinum group metal, and indium-tin oxide (ITO). After forming the terminal (electrode circuit), the other connection terminal (circuit electrode) can be aligned, heated and pressurized to be connected.
本発明においては、接続端子を支持する基板がポリイミド樹脂等の有機絶縁物質、ガラスから選ばれる少なくとも一種からなる回路部材及び表面が窒化シリコン、シリコーン化合物、ポリイミド樹脂、シリコーン樹脂から選ばれる少なくとも一種でコーティングもしくは付着した回路部材に対して特に良好な接着強度が得られる電気・電子用の異方導電性接着剤組成物の提供が可能となる。 In the present invention, the substrate supporting the connection terminal is an organic insulating material such as polyimide resin, at least one circuit member selected from glass, and the surface is at least one selected from silicon nitride, silicone compound, polyimide resin, and silicone resin. It is possible to provide an anisotropic conductive adhesive composition for electric and electronic use that can provide particularly good adhesive strength to a coated or adhered circuit member.
(実施例1)ビスフェノールA型エポキシ樹脂と9,9’−ビス(4−ヒドロキシフェニル)フルオレンからガラス転移温度が80℃のフェノキシ樹脂を合成した。この樹脂50gを、重量比でトルエン/酢酸エチル=50/50の混合溶剤に溶解して、固形分40重量%の溶液とした。固形重量比でフェノキシ樹脂40g、1−クロロ−2,3−エポキシプロパン・2,7−ナフタレンジオール・ホルムアルデヒド重縮合物からなるエポキシ樹脂(エポキシ当量163)10g、マイクロカプセル型潜在性硬化剤を含有する液状エポキシ(エポキシ当量185)50gとなるように配合し、表面を有機高分子化合物であるポリビニルアルコールで0.01〜0.2μmとなるように被覆した導電粒子(ポリスチレンを核とする粒子の表面に、厚み0.2μmのニッケル層を設け、このニッケル層の外側に、厚み0.04μmの金層を設け、平均粒径5μmの導電粒子を使用)を5体積%配合分散させ、厚み80μmの片面を表面処理したPET(ポリエチレンテレフタレート)フィルムに塗工装置を用いて塗布し、70℃、10分の熱風乾燥により、接着剤層の厚みが10μmのフィルム状接着剤組成物を得た。また、固形重量比でフェノキシ樹脂40g、l−クロロ−2,3−エポキシプロパン・2,7−ナフタレンジオール・ホルムアルデヒド重縮合物からなるエポキシ樹脂(エポキシ当量163)10g、マイクロカプセル型潜在性硬化剤を含有する液状エポキシ(エポキシ当量185)50gとなるように配合し、厚み80μmの片面を表面処理したPET(ポリエチレンテレフタレート)フィルムに塗工装置を用いて塗布し、70℃、10分の熱風乾燥により、接着剤層の厚みが10μmのフィルム状接着剤組成物を得た。これらの接着剤組成物を、ラミネーターを用い貼り合わせ、二層構成のフィルム状接着剤組成物を得た。 (Example 1) A phenoxy resin having a glass transition temperature of 80 ° C was synthesized from bisphenol A type epoxy resin and 9,9'-bis (4-hydroxyphenyl) fluorene. 50 g of this resin was dissolved in a mixed solvent of toluene / ethyl acetate = 50/50 by weight to obtain a solution having a solid content of 40% by weight. Contains 40 g of phenoxy resin by solid weight ratio, 10 g of epoxy resin (epoxy equivalent 163) composed of 1-chloro-2,3-epoxypropane, 2,7-naphthalenediol, formaldehyde polycondensate, and microcapsule-type latent curing agent Conductive particles (polystyrene-based particles) coated with 50 g of liquid epoxy (epoxy equivalent 185) and coated with 0.01 to 0.2 μm on the surface with polyvinyl alcohol, which is an organic polymer compound. A nickel layer having a thickness of 0.2 μm is provided on the surface, a gold layer having a thickness of 0.04 μm is provided on the outside of the nickel layer, and conductive particles having an average particle size of 5 μm are mixed and dispersed at a volume of 80 μm. It is applied to a PET (polyethylene terephthalate) film whose surface has been surface-treated using a coating apparatus, at 70 ° C. for 10 minutes. Was dried with hot air to obtain a film-like adhesive composition having an adhesive layer thickness of 10 μm. Moreover, 40 g of phenoxy resin by solid weight ratio, 10 g of epoxy resin (epoxy equivalent 163) consisting of 1-chloro-2,3-epoxypropane, 2,7-naphthalenediol and formaldehyde polycondensate, microcapsule type latent curing agent Liquid epoxy (epoxy equivalent 185) containing 50 g, coated on a PET (polyethylene terephthalate) film having a surface treated on one side of 80 μm thickness using a coating device, and dried with hot air at 70 ° C. for 10 minutes Thus, a film adhesive composition having an adhesive layer thickness of 10 μm was obtained. These adhesive compositions were bonded together using a laminator to obtain a two-layer film adhesive composition.
(実施例2)固形重量比でフェノキシ樹脂40g、エポキシ樹脂に1−クロロ−2,3−エポキシプロパン・2,7−ナフタレンジオールと1−クロロ−2,3−エポキシプロパン・7−ナフタレンジオールとのホルムアルデヒド重縮合物からなるエポキシ樹脂(エポキシ当量182)10g、マイクロカプセル型潜在性硬化剤を含有する液状エポキシ(エポキシ当量185)50gになるように配合した他は実施例1と同様にしてフィルム状接着剤組成物を得た。 (Example 2) 40 g of phenoxy resin by solid weight ratio, 1-chloro-2,3-epoxypropane · 2,7-naphthalenediol and 1-chloro-2,3-epoxypropane · 7-naphthalenediol as epoxy resin A film was prepared in the same manner as in Example 1 except that 10 g of an epoxy resin (epoxy equivalent 182) of the formaldehyde polycondensate was mixed with 50 g of liquid epoxy (epoxy equivalent 185) containing a microcapsule type latent curing agent. A shaped adhesive composition was obtained.
(比較例1)導電粒子に、表面を有機高分子化合物で被覆しない導電粒子を用いた他は実施例1と同様にしてフィルム状接着剤組成物を得た。 (Comparative Example 1) A film adhesive composition was obtained in the same manner as in Example 1 except that conductive particles whose surfaces were not coated with an organic polymer compound were used.
(比較例2)固形重量比でフェノキシ樹脂40g、ビスフェノールA型液状エポキシ樹脂(エポキシ当量180)10g、マイクロカプセル型潜在性硬化剤を含有する液状エポキシ(エポキシ当量185)60gとなるように配合した他は実施例1と同様にしてフィルム状接着剤組成物を得た。 (Comparative example 2) It mix | blended so that it might become 60g of liquid epoxy (epoxy equivalent 185) containing a phenoxy resin 40g by solid weight ratio, 10g of bisphenol A type liquid epoxy resins (epoxy equivalent 180), and a microcapsule-type latent hardener. Others were carried out similarly to Example 1, and obtained the film adhesive composition.
(回路の接続)バンプ面積50μm×50μm、ピッチ100μm、高さ20μmの金バンプを配置したICチップと厚み1.1mmのガラス上にインジュウム−錫酸化物(ITO)を蒸着により形成したITO基板(表面抵抗<20Ω/□)とを、上記接着剤組成物を用い、石英ガラスと加圧ヘッドで挟み、200℃、100MPa(金バンプ面積換算)で10秒間加熱、加圧して接続し回路接続構造体を得た。このとき、フィルム状接着剤組成物はあらかじめITO基板上に、接着剤組成物の導電粒子がある接着面を70℃、0.5MPaで5秒間加熱加圧して貼り付け、その後、PETフィルムを剥離してICチップと接続した。 (Circuit connection) ITO substrate formed by vapor deposition of indium-tin oxide (ITO) on an IC chip on which gold bumps having a bump area of 50 μm × 50 μm, a pitch of 100 μm, and a height of 20 μm are arranged and a glass of 1.1 mm in thickness. A circuit connection structure in which a surface resistance <20Ω / □) is sandwiched between quartz glass and a pressure head using the above adhesive composition, and heated and pressurized at 200 ° C. and 100 MPa (in terms of gold bump area) for 10 seconds. Got the body. At this time, the film-like adhesive composition is applied to the ITO substrate in advance by heating and pressing the adhesive surface with the conductive particles of the adhesive composition at 70 ° C. and 0.5 MPa for 5 seconds, and then the PET film is peeled off. And connected to the IC chip.
(接続抵抗の測定)回路の接続後、接続部の電気抵抗値を、初期と、−40℃/30minと100℃/30minの温度サイクル槽中に500サイクル保持した後に2端子測定法を用いマルチメータで測定した。 (Measurement of connection resistance) After connection of the circuit, the electrical resistance value of the connection portion is maintained at the initial stage and 500 cycles in a temperature cycle bath of −40 ° C./30 min and 100 ° C./30 min. Measured with a meter.
(隣接電極間の絶縁抵抗測定)回路の接続後、接続部に、直流(DC)50Vの電圧を1min印加し、印加後の絶縁抵抗を2端子測定法を用いマルチメータで測定した。それらの測定結果を纏めて表1に示した。 (Measurement of insulation resistance between adjacent electrodes) After connecting the circuits, a direct current (DC) voltage of 50 V was applied to the connection portion for 1 min, and the insulation resistance after application was measured with a multimeter using a two-terminal measurement method. The measurement results are summarized in Table 1.
表1に示したように、本発明の実施例1、2で示す(1)構造式(1)で示されるエポキシ樹脂、(2)潜在性硬化剤、(3)フィルム形成材、(4)表面が有機高分子化合物で被覆された導電粒子を必須成分としで含有する接着剤組成物を含む異方導電性接着剤組成物を用いることで、COG接続の接続直後の接続抵抗や温度サイクル後の接続抵抗が小さく良好となる。また、隣接電極間の絶縁抵抗が高く、良好な接続性を示す。これに対し比較例1のように、導電粒子の表面が有機高分子化合物で被覆されていない導電粒子を含有した接着剤組成物を用いると、接続抵抗は小さく良好であるが、隣接電極間の絶縁抵抗があまりにも小さくなり良好な接続性を示さなくなる。また、比較例2のように、構造式(1)で示されるエポキシ樹脂を用いないと、導電粒子の表面が有機高分子化合物で被覆された導電粒子を含有する接着剤組成物を用いても、隣接電極間の絶縁抵抗は高く良好であるが、温度サイクル後の接続抵抗が非常に高くなり良好な接続性を示さなくなる。導電粒子の表面を有機高分子化合物で被覆することにより、接着剤の面方向(厚み方向に直角)で隣接する導電粒子間での接触による導通を絶縁し絶縁抵抗を高くし、また、構造式(1)で示されるエポキシ樹脂を用いることで、加熱加圧時に接着剤の厚みが徐々に薄くなり導電粒子が圧力により変形していく過程の中で電極と導電粒子の隙間から接着剤が排除される際の排除性が良好である結果、接続抵抗が小さく良好な接続性を示すものと思われる。これに対し、排除性が悪いと比較例2のように、接続直後は電極間の接触が保たれ小さな接続抵抗であるが、温度サイクルにより、接着剤中に加わる応力により接着剤が緩和される際の変形につられた導電粒子の微小な動きで接触が保てなくなったためと推定される。 As shown in Table 1, (1) epoxy resin represented by structural formula (1) shown in Examples 1 and 2 of the present invention, (2) latent curing agent, (3) film forming material, (4) By using an anisotropic conductive adhesive composition including an adhesive composition containing conductive particles whose surfaces are coated with an organic polymer compound as an essential component, connection resistance immediately after connection of COG connection or after temperature cycling The connection resistance is small and good. Moreover, the insulation resistance between adjacent electrodes is high and shows favorable connectivity. On the other hand, when an adhesive composition containing conductive particles whose surfaces are not coated with an organic polymer compound is used as in Comparative Example 1, the connection resistance is small and good, but between adjacent electrodes. The insulation resistance is too small to show good connectivity. Further, as in Comparative Example 2, if the epoxy resin represented by the structural formula (1) is not used, an adhesive composition containing conductive particles whose surfaces are coated with an organic polymer compound may be used. The insulation resistance between adjacent electrodes is high and good, but the connection resistance after the temperature cycle becomes very high and no good connectivity is exhibited. By covering the surface of the conductive particles with an organic polymer compound, the conduction due to contact between adjacent conductive particles in the surface direction of the adhesive (perpendicular to the thickness direction) is insulated and the insulation resistance is increased. By using the epoxy resin shown in (1), the adhesive is removed from the gap between the electrode and the conductive particles in the process where the thickness of the adhesive is gradually reduced and the conductive particles are deformed by pressure during heating and pressing. As a result of the good exclusion property, it is considered that the connection resistance is small and good connectivity is exhibited. On the other hand, if the rejection is poor, the contact between the electrodes is maintained immediately after connection as in Comparative Example 2, and the connection resistance is small, but the adhesive is relaxed by the stress applied to the adhesive due to the temperature cycle. It is presumed that the contact could not be maintained by the minute movement of the conductive particles caused by the deformation at the time.
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Cited By (4)
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JP2010166097A (en) * | 2010-04-28 | 2010-07-29 | Sony Chemical & Information Device Corp | Connection method and connection structure obtained by using connection apparatus and the connection method |
KR20160144604A (en) | 2015-06-09 | 2016-12-19 | 삼성에스디아이 주식회사 | Polymer resin having a chemical structure 1 or 2, adhesive film comprising the polymer resin, and semiconductive device connected by the adhesive film |
KR20170000486A (en) | 2015-06-24 | 2017-01-03 | 삼성에스디아이 주식회사 | Polymer resin having a chemical structure 1, adhesive film comprising the polymer resin, and semiconductive device connected by the adhesive film |
CN111508855A (en) * | 2014-01-16 | 2020-08-07 | 迪睿合株式会社 | Connection body, method for manufacturing connection body, connection method, and anisotropic conductive adhesive |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2010166097A (en) * | 2010-04-28 | 2010-07-29 | Sony Chemical & Information Device Corp | Connection method and connection structure obtained by using connection apparatus and the connection method |
CN111508855A (en) * | 2014-01-16 | 2020-08-07 | 迪睿合株式会社 | Connection body, method for manufacturing connection body, connection method, and anisotropic conductive adhesive |
CN111508855B (en) * | 2014-01-16 | 2024-01-02 | 迪睿合株式会社 | Connector, method for manufacturing the same, method for connecting the same, and anisotropic conductive adhesive |
KR20160144604A (en) | 2015-06-09 | 2016-12-19 | 삼성에스디아이 주식회사 | Polymer resin having a chemical structure 1 or 2, adhesive film comprising the polymer resin, and semiconductive device connected by the adhesive film |
KR20170000486A (en) | 2015-06-24 | 2017-01-03 | 삼성에스디아이 주식회사 | Polymer resin having a chemical structure 1, adhesive film comprising the polymer resin, and semiconductive device connected by the adhesive film |
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