JP2008163059A - Method for producing aqueous dispersion of pigment-containing polymer particle and water-based pigment ink composition - Google Patents
Method for producing aqueous dispersion of pigment-containing polymer particle and water-based pigment ink composition Download PDFInfo
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Abstract
Description
本発明は顔料含有ポリマー粒子水分散体の製造方法及び水系顔料インク組成物に関し、より詳しくは、インクジェット記録用水系顔料インク組成物の調製に用いるのに適した顔料含有ポリマー粒子水分散体の製造方法及び該製造方法で得られる顔料含有ポリマー粒子水分散体を含有する水系顔料インク組成物に関する。 TECHNICAL FIELD The present invention relates to a method for producing an aqueous dispersion of pigment-containing polymer particles and an aqueous pigment ink composition, and more specifically, production of an aqueous dispersion of pigment-containing polymer particles suitable for use in the preparation of an aqueous pigment ink composition for inkjet recording. The present invention relates to a method and an aqueous pigment ink composition containing an aqueous dispersion of pigment-containing polymer particles obtained by the production method.
インクジェット記録方式は記録部材として普通紙を使用することができ、また、カラー化が容易であるので、近年広く用いられている。 Inkjet recording methods have been widely used in recent years because plain paper can be used as a recording member and colorization is easy.
インクジェットに使用されるインクとして、インクがノズルに目詰まりするのを防止するために、水溶性染料及び多価アルコールを用いたものがある。しかし、この種のインクは耐水性や耐光性に劣り、特に熱ジェット方式のインクとして使用した場合には、ヒーター面の熱により染料が酸化され、インクがヒーター面に焦げつきやすく、吐出性が低下するという欠点がある。 As an ink used for inkjet, there is an ink using a water-soluble dye and a polyhydric alcohol in order to prevent the ink from clogging the nozzle. However, this type of ink is inferior in water resistance and light resistance, especially when used as a heat jet ink, the dye is oxidized by the heat of the heater surface, the ink tends to scorch on the heater surface, and the discharge property is reduced. There is a drawback of doing.
このような欠点を解消するために、顔料インクが提案されている。顔料インクには、界面活性剤や水溶性ポリマーにより顔料を水中へ分散させた顔料分散型インクと、水不溶性ポリマーの粒子中に顔料を含有させ、それを水中に分散させた顔料内包型インクとが提案されている。 In order to eliminate such drawbacks, pigment inks have been proposed. The pigment ink includes a pigment-dispersed ink in which a pigment is dispersed in water with a surfactant or a water-soluble polymer, and a pigment-encapsulated ink in which a pigment is contained in water-insoluble polymer particles and dispersed in water. Has been proposed.
顔料分散型インクを用いた場合には、前記欠点がかなり改善されるものの、耐水性及び耐光性が不十分であるという欠点がある。これに対して、顔料内包型インクは、耐水性及び耐光性に優れている。 In the case of using a pigment-dispersed ink, the above-mentioned drawbacks are considerably improved, but there is a disadvantage that water resistance and light resistance are insufficient. On the other hand, the pigment-containing ink is excellent in water resistance and light resistance.
本発明の目的は、顔料内包型のインクジェット記録用水系顔料インク組成物の調製に用いるのに適した顔料含有ポリマー粒子水分散体の製造方法及び該製造方法で得られる顔料含有ポリマー粒子水分散体を含有する水系顔料インク組成物を提供することである。 An object of the present invention is to provide a method for producing a pigment-containing polymer particle aqueous dispersion suitable for use in preparing a pigment-encapsulated water-based pigment ink composition for inkjet recording, and a pigment-containing polymer particle aqueous dispersion obtained by the production method. An aqueous pigment ink composition containing
本発明の顔料含有ポリマー粒子水分散体の製造方法は、
（１）エチレン性不飽和モノマー中にビニル系樹脂を溶解させて樹脂溶液を調製する工程、
（２）該樹脂溶液に顔料を添加し、ホモジナイズ処理により顔料分散樹脂溶液を調製する工程、
（３）該顔料分散樹脂溶液を乳化剤水溶液中に添加し、ホモジナイズ処理により顔料分散樹脂溶液を水中に分散させてミニエマルションを調製する工程、及び
（４）該ミニエマルションにラジカル開始剤を添加し、重合させる工程
からなることを特徴とする。
The method for producing the pigment-containing polymer particle aqueous dispersion of the present invention comprises:
(1) A step of preparing a resin solution by dissolving a vinyl resin in an ethylenically unsaturated monomer,
(2) A step of adding a pigment to the resin solution and preparing a pigment-dispersed resin solution by homogenization treatment;
(3) adding the pigment-dispersed resin solution into an aqueous emulsifier solution and dispersing the pigment-dispersed resin solution in water by homogenization to prepare a miniemulsion; and (4) adding a radical initiator to the miniemulsion. , Characterized by comprising a step of polymerizing.
本発明の製造方法で得られる顔料含有ポリマー粒子水分散体は、耐水性及び耐光性に優れた顔料内包型のインクジェット記録用水系顔料インク組成物の調製に用いるのに特に適している。 The pigment-containing polymer particle aqueous dispersion obtained by the production method of the present invention is particularly suitable for use in the preparation of a pigment-encapsulated water-based pigment ink composition for inkjet recording excellent in water resistance and light resistance.
本発明の顔料含有ポリマー粒子水分散体の製造方法の第一工程は、エチレン性不飽和モノマー中にビニル系樹脂を溶解させて樹脂溶液を調製する工程である。エチレン性不飽和モノマー中にビニル系樹脂を添加し、攪拌することにより容易に樹脂溶液を得ることができる。 The first step of the method for producing a pigment-containing polymer particle aqueous dispersion of the present invention is a step of preparing a resin solution by dissolving a vinyl resin in an ethylenically unsaturated monomer. A resin solution can be easily obtained by adding a vinyl resin to an ethylenically unsaturated monomer and stirring the mixture.
本発明の製造方法で用いるエチレン性不飽和モノマーとして、例えば、（メタ）アクリル酸メチル、（メタ）アクリル酸エチル、（メタ）アクリル酸ｎ−プロピル、（メタ）アクリル酸イソプロピル、（メタ）アクリル酸（ｎ−、ｉ−、ｔ−）ブチル、（メタ）アクリル酸へキシル、（メタ）アクリル酸２−エチルへキシル、（メタ）アクリル酸ｎ−オクチル、（メタ）アクリル酸デシル、（メタ）アクリル酸ラウリル、（メタ）アクリル酸ステアリル、（メタ）アクリル酸シクロヘキシル等のアクリル酸又はメタクリル酸のアルキルエステル又はシクロアルキルエステル；（メタ）アクリル酸メトキシエチル、（メタ）アクリル酸エトキシエチル、（メタ）アクリル酸エトキシブチル等のアクリル酸又はメタクリル酸のアルコキシアルキル；アクリル酸、メタクリル酸、クロトン酸、イタコン酸、マレイン酸、フマル酸等のカルボキシル基含有不飽和モノマー；２−ヒドロキシエチル（メタ）アクリレート、２−又は３−ヒドロキシプロピル（メタ）アクリレート等のアクリル樹脂又はメタクリル酸の炭素数２〜８のヒドロキシアルキルエステル；Ｎ，Ｎ−ジメチルアミノエチル（メタ）アクリレート、Ｎ，Ｎ−ジエチルアミノエチル（メタ）アクリレート等の含窒素アルキル（メタ）アクリレート；アクリルアミド、メタクリルアミド、Ｎ−ブトキシメチル（メタ）アクリルアミド、Ｎ，Ｎ−ジメチルアミノプロピル（メタ）アクリルアミド、Ｎ，Ｎ−ジメチルアミノエチル（メタ）アクリルアミド等の重合性アミド類；グリシジル（メタ）アクリレート、アリルグリシジルエーテル等のエポキシ基含有不飽和モノマー；酢酸ビニル、スチレン、α−クロロスチレン、アクリロニトリル等を挙げることができる。 Examples of the ethylenically unsaturated monomer used in the production method of the present invention include, for example, methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl (meth) acrylate, and (meth) acrylic. Acid (n-, i-, t-) butyl, hexyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, n-octyl (meth) acrylate, decyl (meth) acrylate, (meth ) Acrylic acid or methacrylic acid alkyl ester or cycloalkyl ester such as lauryl acrylate, stearyl (meth) acrylate, cyclohexyl (meth) acrylate; methoxyethyl (meth) acrylate, ethoxyethyl (meth) acrylate, ( Alkoxyalkyl of acrylic acid or methacrylic acid such as methacrylic acid ethoxybutyl Carboxyl group-containing unsaturated monomers such as acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid, fumaric acid; acrylic resins such as 2-hydroxyethyl (meth) acrylate, 2- or 3-hydroxypropyl (meth) acrylate Or a C2-C8 hydroxyalkyl ester of methacrylic acid; nitrogen-containing alkyl (meth) acrylates such as N, N-dimethylaminoethyl (meth) acrylate and N, N-diethylaminoethyl (meth) acrylate; acrylamide, methacrylamide , N-butoxymethyl (meth) acrylamide, N, N-dimethylaminopropyl (meth) acrylamide, polymerizable amides such as N, N-dimethylaminoethyl (meth) acrylamide; glycidyl (meth) acrylate, allyl glycidyl ester Epoxy group-containing unsaturated monomers such as ether, vinyl acetate, styrene, alpha-chlorostyrene, and acrylonitrile.
本発明の製造方法で用いるビニル系樹脂として、塩化ビニル系樹脂、酢酸ビニル系樹脂等を挙げることができ、例えば、塩化ビニルの単独重合体のほか、主成分の塩化ビニルと他の共重合可能なコモノマーとの共重合体等、塩化ビニルを主な構成単位とする樹脂を挙げることができる。共重合可能なコモノマーとしては、エチレン、プロピレン、アクリロニトリル、酢酸ビニル、マレイン酸またはそのエステル、アクリル酸またはそのエステル、メタクリル酸またはそのエステル等を挙げることができる。 Examples of vinyl resins used in the production method of the present invention include vinyl chloride resins and vinyl acetate resins. For example, in addition to vinyl chloride homopolymers, the main component vinyl chloride can be copolymerized with other resins. Examples thereof include resins having vinyl chloride as a main structural unit, such as copolymers with various comonomers. Examples of the copolymerizable comonomer include ethylene, propylene, acrylonitrile, vinyl acetate, maleic acid or its ester, acrylic acid or its ester, methacrylic acid or its ester, and the like.
本発明の顔料含有ポリマー粒子水分散体の製造方法の第二工程は、上記のようにして得た樹脂溶液に顔料を添加し、ホモジナイズ処理により顔料分散樹脂溶液を調製する工程である。ホモジナイズ処理は、例えば、超音波、ビーズミル、剪断混合装置等で実施することができる。このホモジナイズ処理により、顔料を樹脂溶液中に均一に分散させることができる。 The second step of the method for producing a pigment-containing polymer particle aqueous dispersion of the present invention is a step of adding a pigment to the resin solution obtained as described above and preparing a pigment-dispersed resin solution by homogenization treatment. The homogenization treatment can be performed with, for example, an ultrasonic wave, a bead mill, a shear mixing device, or the like. By this homogenization treatment, the pigment can be uniformly dispersed in the resin solution.
本発明の製造方法で用いる顔料は、無機顔料及び有機顔料のいずれであってもよい。また、必要により、これらの顔料と体質顔料とを併用することもできる。無機顔料として、カーボンブラック、金属酸化物、金属硫化物、金属塩化物等を挙げることができる。これらの中では、特に黒色系インクでは、カーボンブラックが好ましい。カーボンブラックとして、ファーネスブラック、サーマルブラック、アセチレンブラック、チャンネルブラック等を挙げることができる。 The pigment used in the production method of the present invention may be either an inorganic pigment or an organic pigment. If necessary, these pigments and extender pigments can be used in combination. Examples of the inorganic pigment include carbon black, metal oxide, metal sulfide, and metal chloride. Among these, carbon black is particularly preferable for black ink. Examples of carbon black include furnace black, thermal black, acetylene black, and channel black.
有機顔料として、アゾ顔料、ジアゾ顔料、フタロシアニン顔料、キナクリドン顔料、イソインドリノン顔料、ジオキサジン顔料、ペリレン顔料、ペリノン顔料、チオインジゴ顔料、アンソラキノン顔料、キノフタノン顔料等を挙げることができる。また、体質顔料として、シリカ、炭酸カルシウム、タルク等を挙げることができる。 Examples of organic pigments include azo pigments, diazo pigments, phthalocyanine pigments, quinacridone pigments, isoindolinone pigments, dioxazine pigments, perylene pigments, perinone pigments, thioindigo pigments, anthoraquinone pigments, and quinophthalone pigments. Examples of extender pigments include silica, calcium carbonate, and talc.
本発明の顔料含有ポリマー粒子水分散体の製造方法の第三工程は、上記のようにして得た顔料分散樹脂溶液を乳化剤水溶液中に添加し、ホモジナイズ処理により顔料分散樹脂溶液を水中に分散させてミニエマルションを調製する工程である。このホモジナイズ処理は第二工程におけるホモジナイズ処理と同様に実施することができ、このホモジナイズ処理により、上記のようにして得た顔料分散樹脂溶液が水中に微分散されてミニエマルションとなる。 In the third step of the method for producing the pigment-containing polymer particle aqueous dispersion of the present invention, the pigment-dispersed resin solution obtained as described above is added to an aqueous emulsifier solution, and the pigment-dispersed resin solution is dispersed in water by homogenization treatment. This is a step of preparing a miniemulsion. This homogenization treatment can be carried out in the same manner as the homogenization treatment in the second step. By this homogenization treatment, the pigment-dispersed resin solution obtained as described above is finely dispersed in water to form a miniemulsion.
本発明の製造方法では種々の乳化剤を用いることができる。例えば、ステアリルアミン塩酸塩、ラウリルトリメチルアンモニウムクロライド、トリメチルオクタデシルアンモニウムクロライド等のカチオン乳化剤、オレイン酸カリウム、ラウリル酸ナトリウム、ドデシルベンゼンスルホン酸ナトリウム、アルカンスルホン酸ナトリウム、アルキルナフタレンスルホン酸ナトリウム、ジアルキルスルホコハク酸ナトリウム、ポリオキシエチレンアルキルエーテル硫酸ナトリウム、ポリオキシエチレンアルキルアリルエーテル硫酸ナトリウム、ポリオキシエチレンアルキル燐酸エステル、ポリオキシエチレンアルキルアリル燐酸エステル等のアニオン系乳化剤、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルアリルエーテル、ポリオキシエチレンプロピルブロックポリマー、ポリエチレングリコール脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル等のノニオン系乳化剤、ラウリルペタイン、ラウリルジメチルアミンオキサイド等の両イオン性乳化剤等を用いることができる。しかし、本発明の製造方法ではアニオンノニオンタイプの乳化剤、特に反応性乳化剤を用いることが好ましい。 Various emulsifiers can be used in the production method of the present invention. For example, cationic emulsifiers such as stearylamine hydrochloride, lauryltrimethylammonium chloride, trimethyloctadecylammonium chloride, potassium oleate, sodium laurate, sodium dodecylbenzenesulfonate, sodium alkanesulfonate, sodium alkylnaphthalenesulfonate, sodium dialkylsulfosuccinate Anionic emulsifiers such as sodium polyoxyethylene alkyl ether sulfate, sodium polyoxyethylene alkyl allyl ether sulfate, polyoxyethylene alkyl phosphate ester, polyoxyethylene alkyl allyl phosphate ester, polyoxyethylene alkyl ether, polyoxyethylene alkyl allyl ether , Polyoxyethylenepropyl block polymer, polyethylene Glycol fatty acid ester, nonionic emulsifiers such as polyoxyethylene sorbitan fatty acid esters, lauryl betaine, may be used both ionic emulsifiers such as lauryl dimethyl amine oxide. However, it is preferable to use an anionic nonionic emulsifier, particularly a reactive emulsifier, in the production method of the present invention.
本発明の顔料含有ポリマー粒子水分散体の製造方法の第四工程は、上記のようにして得たミニエマルションにラジカル開始剤を添加し、重合させる工程である。この重合工程を好ましくは３０〜９５℃の範囲内の温度で実施することができる。この重合により顔料の周りに樹脂が付着した顔料含有ポリマー粒子が形成され、この顔料含有ポリマー粒子は水中に分散している。即ち、顔料含有ポリマー粒子水分散体が得られる。 The fourth step of the method for producing the pigment-containing polymer particle aqueous dispersion of the present invention is a step of adding a radical initiator to the miniemulsion obtained as described above and polymerizing it. This polymerization step can be carried out preferably at a temperature in the range of 30-95 ° C. By this polymerization, pigment-containing polymer particles having a resin attached around the pigment are formed, and the pigment-containing polymer particles are dispersed in water. That is, a pigment-containing polymer particle aqueous dispersion is obtained.
本発明の製造方法で用いるラジカル開始剤として、例えば、２，２’−アゾビスイソブチロニトリル、２，２’− アゾビス−（２−メチルプロパンニトリル） 、２，２’−アゾビス−（２，４−ジメチルペンタンニトリル）、２，２’−アゾビス−（２−メチルブタンニトリル）、１，１’−アゾビス−（シクロヘキサンカルボニトリル）、２，２’−アゾビス−（２，４−ジメチル−４−メトキシバレロニトリル）、２，２’−アゾビス−（２，４−ジメチルバレロニトリル）、２，２’−アゾビス−（２−アミジノプロパン）ヒドロクロリド等のアゾ（アゾビスニトリル）タイプの開始剤、過酸化ベンゾイル、クメンヒドロペルオキシド、過酸化水素、過酸化アセチル、過酸化ラウロイル、過硫酸塩（例えば過硫酸アンモニウム）、過酸エステル（例えばｔ−ブチルペルオクテート、α−クミルペルオキシピバレート及びｔ−ブチルペルオクテート）等の過酸化物タイプの開始剤を挙げることができる。 Examples of the radical initiator used in the production method of the present invention include 2,2′-azobisisobutyronitrile, 2,2′-azobis- (2-methylpropanenitrile), 2,2′-azobis- (2 , 4-dimethylpentanenitrile), 2,2′-azobis- (2-methylbutanenitrile), 1,1′-azobis- (cyclohexanecarbonitrile), 2,2′-azobis- (2,4-dimethyl-) Initiation of azo (azobisnitrile) types such as 4-methoxyvaleronitrile), 2,2′-azobis- (2,4-dimethylvaleronitrile), 2,2′-azobis- (2-amidinopropane) hydrochloride Agents, benzoyl peroxide, cumene hydroperoxide, hydrogen peroxide, acetyl peroxide, lauroyl peroxide, persulfates (eg ammonium persulfate) It can be mentioned esters (for example, t- butyl peroxide octoate, alpha-cumyl peroxypivalate and t- butyl per octoate) peroxide type initiators such as.
上記のようにして得た顔料含有ポリマー粒子水分散体に、必要に応じて湿潤剤、分散剤、消泡剤、キレート剤、防黴剤等の添加剤を適量で添加することにより、水系顔料インク組成物を得ることができる。かくして得られた水系顔料インク組成物は、分散安定性、耐水性、耐光性及び印字特性に優れたものである。 By adding an appropriate amount of additives such as a wetting agent, a dispersing agent, an antifoaming agent, a chelating agent, and an antifungal agent to the pigment-containing polymer particle aqueous dispersion obtained as described above, an aqueous pigment is obtained. An ink composition can be obtained. The water-based pigment ink composition thus obtained is excellent in dispersion stability, water resistance, light resistance and printing characteristics.
実施例１
メタクリル酸メチル６０ｇ、アクリル酸ブチル２０ｇ及びメタクリル酸ラウリル２０ｇからなるエチレン性不飽和モノマー１００ｇに塩化ビニル／酢酸ビニル共重合体２０ｇを添加し、攪拌して均一に溶解させて樹脂溶液を得た。
Example 1
20 g of vinyl chloride / vinyl acetate copolymer was added to 100 g of ethylenically unsaturated monomer consisting of 60 g of methyl methacrylate, 20 g of butyl acrylate and 20 g of lauryl methacrylate, and stirred to dissolve uniformly to obtain a resin solution.
上記の樹脂溶液に顔料としてフタロシアニンブルー（Ｃｉｂａ Ｓ.Ｃ.社製、ＰＴＢ８７００）３０ｇを添加し、ビーズミルに３０分間かけ、分散させて顔料分散樹脂溶液を調製した。分散後の顔料の平均粒子径は、 日機装株式会社製マイクロトラックＭＴ３３００ＥＸで測定して、１８０ナノメートルであった。 30 g of phthalocyanine blue (manufactured by Ciba S.C., PTB8700) was added as a pigment to the resin solution, and the mixture was dispersed in a bead mill for 30 minutes to prepare a pigment-dispersed resin solution. The average particle size of the pigment after dispersion was 180 nanometers as measured with Nikkiso Microtrack MT3300EX.
上記の顔料分散樹脂溶液を乳化剤水溶液中に添加し、超音波ホモジナイザー（日機装株式会社製、ＵＳ−６００ＴＣＶＰ）にかけて顔料分散樹脂溶液が水中に分散したＯ／Ｗ型ミニエマルションを得た。この乳化剤水溶液として反応性乳化剤ＳＥ１０２５Ａ（アデカ社製）の２％水溶液を３００ｇ使用した 。 The above pigment dispersion resin solution was added to an emulsifier aqueous solution, and an ultrasonic homogenizer (manufactured by Nikkiso Co., Ltd., US-600TCVP) was used to obtain an O / W type miniemulsion in which the pigment dispersion resin solution was dispersed in water. As this emulsifier aqueous solution, 300 g of a 2% aqueous solution of reactive emulsifier SE1025A (manufactured by Adeka) was used.
攪拌機、温度センサー及びコンデンサーを備えた反応器をウォーターバス中にセットし、この反応器に上記のミニエマルションを移し、撹拌しながら７０℃まで昇温させた。７０℃に到達した時点で、過硫酸アンモニウム０．８ｇを溶解した水溶液を注入して重合をスタートさせた。その後５時間、７０℃に保ち、更に８０℃に昇温させて３時間保って重合を完結させた。 A reactor equipped with a stirrer, a temperature sensor and a condenser was set in a water bath, and the above-mentioned mini-emulsion was transferred to this reactor, and the temperature was raised to 70 ° C. while stirring. When the temperature reached 70 ° C., an aqueous solution in which 0.8 g of ammonium persulfate was dissolved was injected to start polymerization. Thereafter, the temperature was maintained at 70 ° C. for 5 hours, further heated to 80 ° C. and maintained for 3 hours to complete the polymerization.
このようにして得られた顔料含有ポリマー粒子（顔料−ポリマー複合粒子）水分散体は、固形分濃度３２.５％で、固形分の平均粒子径２３０ナノメートルであった。また、この顔料含有ポリマー粒子水分散体に分散剤、消泡剤を適量添加した水系顔料インク組成物は、分散安定性、耐水性、耐光性及び印字特性に優れたものであった。 The pigment-containing polymer particles (pigment-polymer composite particles) aqueous dispersion thus obtained had a solid content concentration of 32.5% and an average particle size of solids of 230 nanometers. Further, the water-based pigment ink composition in which appropriate amounts of a dispersant and an antifoaming agent were added to the pigment-containing polymer particle aqueous dispersion was excellent in dispersion stability, water resistance, light resistance and printing characteristics.
Claims (6)
（２）該樹脂溶液に顔料を添加し、ホモジナイズ処理により顔料分散樹脂溶液を調製する工程、
（３）該顔料分散樹脂溶液を乳化剤水溶液中に添加し、ホモジナイズ処理により顔料分散樹脂溶液を水中に分散させてミニエマルションを調製する工程、及び
（４）該ミニエマルションにラジカル開始剤を添加し、重合させる工程
からなることを特徴とする顔料含有ポリマー粒子水分散体の製造方法。 (1) A step of preparing a resin solution by dissolving a vinyl resin in an ethylenically unsaturated monomer,
(2) A step of adding a pigment to the resin solution and preparing a pigment-dispersed resin solution by homogenization treatment;
(3) adding the pigment-dispersed resin solution into an aqueous emulsifier solution and dispersing the pigment-dispersed resin solution in water by homogenization to prepare a miniemulsion; and (4) adding a radical initiator to the miniemulsion. A method for producing an aqueous dispersion of pigment-containing polymer particles, characterized by comprising a step of polymerizing.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010083968A (en) * | 2008-09-30 | 2010-04-15 | Dainippon Toryo Co Ltd | Preparation of sublimable dye-containing polymer particle aqueous dispersion, and water-based sublimable dye ink composition |
| US10538681B2 (en) | 2017-04-10 | 2020-01-21 | Seiko Epson Corporation | Aqueous ink for ink jet recording |
| US10787585B2 (en) | 2017-08-07 | 2020-09-29 | Seiko Epson Corporation | Aqueous ink for ink jet recording |
| WO2022202045A1 (en) * | 2021-03-26 | 2022-09-29 | 株式会社ミマキエンジニアリング | Aqueous ink composition |
| WO2023068378A1 (en) * | 2021-10-20 | 2023-04-27 | 株式会社Adeka | Pigment-in-water dispersing agent, method for dispersing pigment in water, and aqueous coating material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003089757A (en) * | 2001-06-29 | 2003-03-28 | Canon Inc | Colored resin fine particle and method for producing the same, aqueous dispersion of colored resin particle, ink, ink cartridge, recording unit, ink jet recording device, and ink jet recording method |
| JP2004264629A (en) * | 2003-03-03 | 2004-09-24 | Canon Inc | Resin for toner and toner using same |
| JP2007156297A (en) * | 2005-12-08 | 2007-06-21 | Canon Inc | Toner |
-
2006
- 2006-12-26 JP JP2006350545A patent/JP4632314B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003089757A (en) * | 2001-06-29 | 2003-03-28 | Canon Inc | Colored resin fine particle and method for producing the same, aqueous dispersion of colored resin particle, ink, ink cartridge, recording unit, ink jet recording device, and ink jet recording method |
| JP2004264629A (en) * | 2003-03-03 | 2004-09-24 | Canon Inc | Resin for toner and toner using same |
| JP2007156297A (en) * | 2005-12-08 | 2007-06-21 | Canon Inc | Toner |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010083968A (en) * | 2008-09-30 | 2010-04-15 | Dainippon Toryo Co Ltd | Preparation of sublimable dye-containing polymer particle aqueous dispersion, and water-based sublimable dye ink composition |
| US10538681B2 (en) | 2017-04-10 | 2020-01-21 | Seiko Epson Corporation | Aqueous ink for ink jet recording |
| US10787585B2 (en) | 2017-08-07 | 2020-09-29 | Seiko Epson Corporation | Aqueous ink for ink jet recording |
| WO2022202045A1 (en) * | 2021-03-26 | 2022-09-29 | 株式会社ミマキエンジニアリング | Aqueous ink composition |
| WO2023068378A1 (en) * | 2021-10-20 | 2023-04-27 | 株式会社Adeka | Pigment-in-water dispersing agent, method for dispersing pigment in water, and aqueous coating material |
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