JP2008143828A - Kit for hair-treating agent - Google Patents
Kit for hair-treating agent Download PDFInfo
- Publication number
- JP2008143828A JP2008143828A JP2006332371A JP2006332371A JP2008143828A JP 2008143828 A JP2008143828 A JP 2008143828A JP 2006332371 A JP2006332371 A JP 2006332371A JP 2006332371 A JP2006332371 A JP 2006332371A JP 2008143828 A JP2008143828 A JP 2008143828A
- Authority
- JP
- Japan
- Prior art keywords
- agent
- hair
- kit
- viscosity
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 118
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 10
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 8
- 239000007800 oxidant agent Substances 0.000 claims abstract description 8
- 230000001590 oxidative effect Effects 0.000 claims abstract description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 8
- 239000010452 phosphate Substances 0.000 claims abstract description 8
- 150000004676 glycans Chemical class 0.000 claims abstract description 7
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 7
- 239000005017 polysaccharide Substances 0.000 claims abstract description 7
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- 229940082509 xanthan gum Drugs 0.000 claims description 13
- RNPXCFINMKSQPQ-UHFFFAOYSA-N dicetyl hydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCOP(O)(=O)OCCCCCCCCCCCCCCCC RNPXCFINMKSQPQ-UHFFFAOYSA-N 0.000 claims description 11
- 229940093541 dicetylphosphate Drugs 0.000 claims description 11
- 230000037308 hair color Effects 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- 238000002156 mixing Methods 0.000 abstract description 33
- 238000004043 dyeing Methods 0.000 abstract description 7
- 238000004061 bleaching Methods 0.000 abstract description 3
- 238000004321 preservation Methods 0.000 abstract 1
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- 125000004432 carbon atom Chemical group C* 0.000 description 6
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- 238000003756 stirring Methods 0.000 description 4
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- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
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- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000004475 Arginine Substances 0.000 description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 2
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- 239000004698 Polyethylene Substances 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
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- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 2
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- 238000009472 formulation Methods 0.000 description 2
- 235000013922 glutamic acid Nutrition 0.000 description 2
- 239000004220 glutamic acid Substances 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 238000000034 method Methods 0.000 description 2
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- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 239000001341 hydroxy propyl starch Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 235000013828 hydroxypropyl starch Nutrition 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 229940025902 konjac mannan Drugs 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- ZTQDYDIRBKMMQB-UHFFFAOYSA-N n-(4-aminophenyl)nitramide Chemical compound NC1=CC=C(N[N+]([O-])=O)C=C1 ZTQDYDIRBKMMQB-UHFFFAOYSA-N 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- 239000001006 nitroso dye Substances 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- QXYMVUZOGFVPGH-UHFFFAOYSA-N picramic acid Chemical compound NC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O QXYMVUZOGFVPGH-UHFFFAOYSA-N 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
- ZZYXNRREDYWPLN-UHFFFAOYSA-N pyridine-2,3-diamine Chemical class NC1=CC=CN=C1N ZZYXNRREDYWPLN-UHFFFAOYSA-N 0.000 description 1
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 235000010491 tara gum Nutrition 0.000 description 1
- 239000000213 tara gum Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- DWKARHJHPSUOBW-UHFFFAOYSA-N trimethyl-[3-[(2e)-2-(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)hydrazinyl]phenyl]azanium;chloride Chemical compound [Cl-].CC1=NN(C=2C=CC=CC=2)C(O)=C1N=NC1=CC=CC([N+](C)(C)C)=C1 DWKARHJHPSUOBW-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、第１剤及び第２剤を含有する毛髪脱色用又は酸化染毛用の毛髪処理剤用キットに関する。さらに詳しくは、各剤の保存安定性に優れ、混合後は最適な粘度を有して毛髪からの液垂れを防止することができ、さらに毛髪上での延展性にも優れる、刺激臭を低減した毛髪処理剤用キットに関する。 The present invention relates to a hair treatment kit for hair bleaching or oxidative hair dyeing containing a first agent and a second agent. More specifically, each agent has excellent storage stability, has an optimal viscosity after mixing, can prevent dripping from the hair, and also has excellent extensibility on the hair, reducing irritating odors The present invention relates to a kit for treating hair.
２剤式、３剤式などの多剤式の脱色剤又は染毛剤の場合、各剤の保存安定性を向上させるとともに、毛髪への塗布のし易さ（液垂れ防止）、毛髪上での延展性（均一塗布）などの観点から、使用時の粘度を最適な粘度とすることが最も重要である。また、使用時のアルカリ剤などの原料由来の刺激臭を低減させることも重要である。 In the case of multi-component depigmenting agents or hair dyes such as two-component, three-component, etc., it improves the storage stability of each agent and is easy to apply to hair (prevents dripping) on the hair From the standpoint of spreadability (uniform coating), it is most important to set the viscosity at the time of use to an optimum viscosity. It is also important to reduce irritating odors derived from raw materials such as alkaline agents during use.
従来より、使用時の粘度を最適な粘度とする手段として、増粘性化合物を添加する試みがなされている。例えば、特許文献１ではキサンタンガムを配合することにより、粘度安定性を向上している。特許文献２では、粘度発現がｐＨに依存するカルボキシビニルポリマーを用いて、第１剤と第２剤の混合でｐＨを調整することにより粘性を付与している。特許文献３では、アルカリ性物質の添加により増粘化する増粘性共重合体を第２剤に配合して、アルカリ性物質を含有する第１剤と混合することにより、粘性を付与している。特許文献４ではヒドロキシプロピルスターチリン酸と水性増粘剤を配合することにより、良好な粘度安定性が得られている。 Conventionally, an attempt to add a thickening compound has been made as a means for making the viscosity in use optimum. For example, in patent document 1, viscosity stability is improved by mix | blending xanthan gum. In Patent Document 2, viscosity is imparted by adjusting pH by mixing a first agent and a second agent using a carboxyvinyl polymer whose viscosity depends on pH. In patent document 3, the viscosity is provided by mix | blending the thickening copolymer thickened by addition of an alkaline substance with the 2nd agent, and mixing with the 1st agent containing an alkaline substance. In patent document 4, favorable viscosity stability is obtained by mix | blending hydroxypropyl starch acid and an aqueous thickener.
また、アルカリ剤などの刺激臭を低減する手段として、特定油剤の配合が提案されている。例えば、特許文献５ではイソパラフィンと非イオン性界面活性剤と高分子化合物を配合することにより、刺激臭を低減している。特許文献６ではトリグリセリドを構成成分とする油剤と高級アルコールとエステル型非イオン性界面活性剤を配合することにより、刺激臭を低減している。特許文献７では炭素数２０〜２５の高級アルコールと炭素数１０〜１９の高級アルコールと界面活性剤を配合することにより、刺激臭を低減している。
しかしながら、これら試みに拠って使用時に最適な粘度とすることや刺激臭を低減することができるものの、各剤においては、粘度低下、粘度上昇あるいは分離などが生じ、経時保存安定性に劣るといった問題があった。また、各剤の混合後、粘性の変動が生じ、粘度安定性が低下しやすくなることから、使用時の毛髪からの液垂れや毛髪上での延展性に劣るといった問題や、刺激臭の低減効果が発揮され難くなるという問題もあった。 However, although it is possible to achieve an optimum viscosity at the time of use or to reduce the irritating odor based on these attempts, in each agent, there is a problem that the viscosity is lowered, the viscosity is increased or separated, and the storage stability with time is poor. was there. In addition, after mixing each agent, viscosity fluctuations occur and viscosity stability tends to decrease, reducing problems such as dripping from the hair during use and inferior extensibility on the hair, and irritating odors There was also a problem that it was difficult to achieve the effect.
本発明者らは、前記課題を解決するために鋭意検討した結果、多剤式の毛髪処理剤用キットが、リン酸ジアルキルと水溶性多糖類を含有することにより、各剤の経時保存安定性に優れ、かつ、混合後は最適な粘度を有して毛髪からの液垂れを防止して毛髪上での延展性に優れること、さらにアルカリ剤などの刺激臭を低減することも見出し、本発明を完成するに至った。 As a result of intensive studies to solve the above problems, the present inventors have found that a multi-agent hair treatment agent kit contains dialkyl phosphate and a water-soluble polysaccharide, so that the storage stability of each agent over time is improved. It has also been found that it has an optimum viscosity after mixing, prevents dripping from the hair and is excellent in spreadability on the hair, and further reduces an irritating odor such as an alkaline agent. It came to complete.
すなわち、本発明は、アルカリ剤を含有する第１剤と、酸化剤を含有する第２剤とを含む毛髪処理剤用キットであって、非イオン性界面活性剤を含有せず、（Ａ）リン酸ジアルキル、及び（Ｂ）水溶性多糖類を含有してなる毛髪脱色用又は酸化染毛用の毛髪処理剤用キット、に関する。 That is, this invention is a kit for hair treatment agents containing the 1st agent containing an alkaline agent, and the 2nd agent containing an oxidizing agent, Comprising: A nonionic surfactant is not contained, (A) The present invention relates to a hair treatment agent kit for hair bleaching or oxidative hair coloring, comprising a dialkyl phosphate and (B) a water-soluble polysaccharide.
本発明の毛髪処理剤用キットは、各剤の経時保存安定性に優れるとともに、混合時に最適な粘度とし、その粘度安定性に優れた効果を奏する。また、最適な粘度とすることで毛髪からの液垂れを防止して毛髪上での延展性に優れることから、脱色性や染色性を向上させることができる。さらには、アルカリ剤などの原料由来の刺激臭を低減させることができるという優れた効果も奏する。 The kit for hair treatment agent of the present invention is excellent in storage stability with time of each agent, has an optimum viscosity at the time of mixing, and has an effect of excellent viscosity stability. Moreover, since it is excellent in the spreadability on hair by preventing the dripping from hair by setting it as the optimal viscosity, decoloring property and dyeing | staining property can be improved. Furthermore, the outstanding effect that the pungent odor derived from raw materials, such as an alkaline agent, can be reduced is also show | played.
本発明の毛髪処理剤用キットは、アルカリ剤を含有する第１剤と、酸化剤を含有する第２剤とを含むキットであって、非イオン性界面活性剤成分を含有せず、（Ａ）リン酸ジアルキル成分、及び（Ｂ）水溶性多糖類成分を含有することに大きな特徴を有する。 The kit for hair treatment agent of this invention is a kit containing the 1st agent containing an alkaline agent, and the 2nd agent containing an oxidizing agent, Comprising: A nonionic surfactant component is not included, (A It has a great feature in that it contains a) a dialkyl phosphate component and (B) a water-soluble polysaccharide component.
（Ａ）リン酸ジアルキル成分としては、式（Ｉ）： (A) As a dialkyl phosphate component, the formula (I):
（式中、Ｒ１及びＲ２は、それぞれ独立して、炭素数１２〜２２の飽和又は不飽和直鎖のアルキル基を示す）
で表される化合物が挙げられる。
(Wherein R 1 and R 2 each independently represents a saturated or unsaturated linear alkyl group having 12 to 22 carbon atoms)
The compound represented by these is mentioned.
本発明では、式（Ｉ）で表される化合物のなかでも、Ｒ１及びＲ２が炭素数１４〜１８の飽和又は不飽和直鎖のアルキル基であるリン酸ジアルキルを用いるのが好ましく、Ｒ１及びＲ２が炭素数１６の飽和アルキル基であるリン酸ジセチルを用いるのがより好ましい。 In the present invention, among the compounds represented by the formula (I), it is preferable to use a dialkyl phosphate in which R 1 and R 2 are a saturated or unsaturated linear alkyl group having 14 to 18 carbon atoms. It is more preferable to use dicetyl phosphate in which 1 and R 2 are saturated alkyl groups having 16 carbon atoms.
式（Ｉ）で表される化合物の市販品としては、例えば、Ｒ１及びＲ２が炭素数１６の飽和アルキル基である「ＤＰ−１０」（リン酸ジセチル、日光ケミカルズ社製）が挙げられる。 As a commercial item of the compound represented by the formula (I), for example, “DP-10” (dicetyl phosphate, manufactured by Nikko Chemicals Co., Ltd.) in which R 1 and R 2 are a saturated alkyl group having 16 carbon atoms may be mentioned. .
（Ａ）成分の含有量は、所望の効果が付与されるのであれば特に限定されないが、通常、混合時に最適な粘度とする観点、毛髪からの液垂れを抑制し、延展性を向上させる観点、及びアルカリ剤などの原料由来の刺激臭を低減させる観点から、毛髪処理剤用キット中、０．０１〜４重量％が好ましく、０．１〜２重量％がより好ましい。 The content of the component (A) is not particularly limited as long as a desired effect is imparted. Usually, from the viewpoint of obtaining an optimum viscosity at the time of mixing, from the viewpoint of suppressing dripping from the hair and improving the spreadability. From the viewpoint of reducing irritating odors derived from raw materials such as alkaline agents, 0.01 to 4% by weight is preferable in the kit for hair treatment agents, and 0.1 to 2% by weight is more preferable.
（Ｂ）水溶性多糖類成分としては、例えば、種子粘質物、樹液粘質物、産生粘質物及びセルロース系成分などが例示される。 (B) Examples of the water-soluble polysaccharide component include seed mucilage, sap mucilage, production mucilage, and cellulosic component.
種子粘質物としては、グアーガム、クインスシード、コンニャクマンナン、タマリンドガム、タラガム、デキストリン、デンプン、ローカストビーンガムなどが挙げられる。樹液粘質物としては、アラビアガム、ガッティガム、カラヤガム、トンガカントガムなどが挙げられる。 Examples of seed mucilage include guar gum, quince seed, konjac mannan, tamarind gum, tara gum, dextrin, starch, locust bean gum and the like. Examples of the sap mucilage include gum arabic, gati gum, karaya gum, and tongan cant gum.
産生粘質物としては、カードラン、キサンタンガム、ジェランガム、シクロデキストリン、デキストラン、プルランなどが挙げられる。セルロース系成分としては、結晶セルロース、メチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、カルボキシメチルセルロース、カチオン化セルロースなどが挙げられる。 Examples of the product mucilage include curdlan, xanthan gum, gellan gum, cyclodextrin, dextran, pullulan and the like. Examples of the cellulose component include crystalline cellulose, methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, carboxymethyl cellulose, and cationized cellulose.
上記化合物は、単独で又は２種以上を適宜組合せて用いることができるが、本発明においてはキサンタンガムが好ましい。また、キサンタンガムの誘導体も好ましく、具体的には、アセチル化キサンタンガム、オキシアルキレン化キサンタンガム（ヒドロキシプロピルキサンタンガムなど）などが例示される。 Although the said compound can be used individually or in combination of 2 or more types, a xanthan gum is preferable in this invention. Further, derivatives of xanthan gum are also preferable, and specific examples include acetylated xanthan gum and oxyalkylenated xanthan gum (such as hydroxypropyl xanthan gum).
（Ｂ）成分の含有量は、所望の効果が付与されるのであれば特に限定されないが、通常、混合時に最適な粘度とする観点から、毛髪処理剤用キット中、０．０１〜２重量％が好ましく、０．０５〜１重量％がより好ましい。 The content of the component (B) is not particularly limited as long as a desired effect is imparted, but is usually 0.01 to 2% by weight in the hair treatment kit from the viewpoint of obtaining an optimum viscosity at the time of mixing. Is preferable, and 0.05 to 1 weight% is more preferable.
なお、本発明の毛髪処理剤用キットは、非イオン性界面活性剤成分を含有しない。その理由は、前記（Ａ）成分と非イオン性界面活性剤成分を併用すると、各剤での経時安定性は優れるが、混合後の粘度が高くなりすぎることにより、毛髪での延展性、粘度安定性に劣り、ひいては、脱色性・染毛性に劣ることになるからである。 In addition, the kit for hair treatment agents of this invention does not contain a nonionic surfactant component. The reason is that, when the component (A) and the nonionic surfactant component are used in combination, the stability with time of each agent is excellent, but the viscosity after mixing becomes too high, so that the extensibility and viscosity in hair are increased. This is because it is inferior in stability and, in turn, inferior in decolorization and hair dyeing properties.
また、本発明の毛髪処理剤用キットは、各剤の経時保存安定性及び混合後の粘度安定性を向上させる観点から、前記（Ａ）及び（Ｂ）成分以外に、さらに（Ｃ）多価アルコール成分を含有することが好ましい。 Moreover, the kit for hair treatment agents of this invention is further (C) multivalent from the viewpoint of improving the time-dependent storage stability of each agent, and the viscosity stability after mixing other than the said (A) and (B) component. It is preferable to contain an alcohol component.
（Ｃ）多価アルコール成分としては、グリコール類、グリセリン類などを例示される。グリコール類としては、エチレングリコール、ジエチレングリコール、トリエチレングリコール、プロピレングリコール、ジプロピレングリコール、イソプレングリコール、１，３−ブチレングリコール、１，２−ブタンジオール、１，２−ペンタンジオール、１，２−ヘキサンジオール、１，２−オクタンジオール、１，２−デカンジオールが挙げられ、グリセリン類としては、グリセリン、ジグリセリン、ポリグリセリン、濃グリセリンが挙げられる。これら成分は、単独で又は２種以上を適宜組合せて用いることができる。 (C) As a polyhydric alcohol component, glycols, glycerol, etc. are illustrated. Glycols include ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, 1,3-butylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexane. Examples include diol, 1,2-octanediol, and 1,2-decanediol. Examples of glycerins include glycerin, diglycerin, polyglycerin, and concentrated glycerin. These components can be used individually or in combination of 2 or more types as appropriate.
（Ｃ）成分の含有量は、所望の効果が付与されるのであれば特に限定されないが、通常、混合後の粘度安定性を向上させる観点から、毛髪処理剤用キット中、０．１〜８重量％が好ましく、１〜６重量％がより好ましい。 Although content of (C) component will not be specifically limited if a desired effect is provided, Usually, 0.1-8 in the kit for hair treatment agents from a viewpoint of improving the viscosity stability after mixing. % By weight is preferable, and 1 to 6% by weight is more preferable.
第１剤におけるアルカリ剤としては、アンモニア、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、モノイソプロパノールアミン、２−アミノ−２−メチル−１−プロパノール、炭酸アンモニウム、炭酸水素アンモニウム、炭酸ナトリウムなどが挙げられ、これらは、それぞれ単独で又は２種以上を混合して用いることができる。 Examples of the alkaline agent in the first agent include ammonia, monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, 2-amino-2-methyl-1-propanol, ammonium carbonate, ammonium bicarbonate, sodium carbonate and the like. These can be used alone or in admixture of two or more.
第１剤におけるアルカリ剤の含有量は、所望の効果が付与されるのであれば特に限定されないが、通常、脱色・染毛効果を向上させる観点から、０．１〜１５重量％が好ましく、０．５〜１０重量％がより好ましい。 The content of the alkali agent in the first agent is not particularly limited as long as a desired effect is imparted, but is usually preferably 0.1 to 15% by weight from the viewpoint of improving the decolorization / hair dyeing effect, and 0 More preferably, it is 5 to 10% by weight.
また、第１剤に酸化染料を含有させてもよく、かかる酸化染料としては、染料中間体及びカップラーが挙げられ、これらは、それぞれ単独で又は２種以上を適宜組合せて用いることができる。 The first agent may contain an oxidative dye. Examples of the oxidative dye include a dye intermediate and a coupler, and these can be used alone or in combination of two or more.
染料中間体の代表例としては、フェニレンジアミン類、アミノフェノール類、ジアミノピリジン類及びそれらの塩類などが挙げられ、その具体例としては、パラフェニレンジアミン、Ｎ，Ｎ−ビス（２−ヒドロキシエチル）−ｐ−フェニレンジアミン、硫酸オルトクロロパラフェニレンジアミン、硫酸４，４'−ジアミノジフェニルアミン、硫酸トルエン−２，５−ジアミン、硫酸パラメチルアミノフェノール、パラアミノフェノール、オルトアミノフェノールなどが挙げられ、これらは、それぞれ単独で又は２種以上を適宜組合せて用いることができる。 Representative examples of the dye intermediate include phenylenediamines, aminophenols, diaminopyridines and salts thereof, and specific examples thereof include paraphenylenediamine, N, N-bis (2-hydroxyethyl). -P-phenylenediamine, orthochloroparaphenylenediamine sulfate, 4,4'-diaminodiphenylamine sulfate, toluene-2,5-diamine sulfate, paramethylaminophenol sulfate, paraaminophenol, orthoaminophenol and the like. These may be used alone or in appropriate combination of two or more.
カップラーの具体例としては、レゾルシン、メタアミノフェノール、２，６−ジアミノピリジン、メタフェニレンジアミン、硫酸メタフェニレンジアミン、塩酸メタフェニレンジアミン、５−アミノオルトクレゾール、塩酸２，４−ジアミノフェノキシエタノール、５−（２−ヒドロキシエチルアミノ）−２−メチルフェノール、β−ナフトール、カテコールなどが挙げられ、これらは、それぞれ単独で又は２種以上を適宜組合せて用いることができる。 Specific examples of couplers include resorcin, metaaminophenol, 2,6-diaminopyridine, metaphenylenediamine, metaphenylenediamine sulfate, metaphenylenediamine hydrochloride, 5-aminoorthocresol, 2,4-diaminophenoxyethanol hydrochloride, 5- (2-Hydroxyethylamino) -2-methylphenol, β-naphthol, catechol and the like can be mentioned, and these can be used alone or in combination of two or more.
また、色調を調色するために、第１剤にさらに直接染料を含有することができる。直接染料の具体例としては、パラニトロオルトフェニレンジアミン、ニトロパラフェニレンジアミン、硫酸パラニトロメタフェニレンジアミン、２−アミノ−５−ニトロフェノール、ピクラミン酸などをはじめ、医薬品、医薬部外品又は化粧品の着色に使用することが許されている「医薬品等に使用することができるタール色素を定める省令」（昭和４１年告示、厚生省）に記載されている酸性染料、例えば、黄色４０３号（１）などのニトロ系色素、だいだい色２０５号、黄色４号、黒色４０１号などのアゾ染料、緑色４０１号などのニトロソ染料、青色２０５号などのトリフェニルメタン染料、赤色１０６号、黄色２０２号の（１）などのキサンテン染料、黄色２０３号などのキノリン染料、紫色４０１号、緑色２０１号などのアントラキノン染料、青色２号などのインジゴ染料、緑色２０４号などのピレン系タール染料などが挙げられ、これらは、それぞれ単独で又は２種以上を適宜組合せて用いることができる。 Further, in order to adjust the color tone, the first agent can further contain a dye directly. Specific examples of direct dyes include paranitroorthophenylenediamine, nitroparaphenylenediamine, paranitrometaphenylenediamine sulfate, 2-amino-5-nitrophenol, picramic acid, pharmaceuticals, quasi drugs or cosmetics. Acid dyes described in “Ministerial Ordinance for Determining Tar Colors that can be Used in Pharmaceuticals” (Notification of Showa 41, Ministry of Health and Welfare) permitted to be used for coloring, such as yellow 403 (1), etc. Nitro dyes, azo dyes such as orange 205, yellow 4 and black 401, nitroso dyes such as green 401, triphenylmethane dyes such as blue 205, red 106 and yellow 202 (1 ), Xanthene dyes such as yellow No. 203, quinoline dyes such as yellow No. 203, anthrax such as purple No. 401 and green No. 201 Non dyes, indigo dyes, such as Blue No. 2, pyrene tar dyes such as green No. 204, and these may be used alone or in combination of two or more appropriately.
なお、本発明においては、必要により、例えば、Ｂａｓｉｃ Ｂｌｕｅ ９９、Ｂａｓｉｃ Ｙｅｌｌｏｗ ５７、Ｂａｓｉｃ Ｂｒｏｗｎ １６、Ｂａｓｉｃ Ｂｒｏｗｎ １７、Ｂａｓｉｃ Ｒｅｄ ７６などの塩基性染料、ＨＣ Ｂｌｕｅ Ｎｏ．２、ＨＣ Ｙｅｌｌｏｗ Ｎｏ．２、ＨＣ Ｙｅｌｌｏｗ Ｎｏ．４、ＨＣ Ｙｅｌｌｏｗ Ｎｏ．５、ＨＣ Ｒｅｄ Ｎｏ．１、ＨＣ Ｒｅｄ Ｎｏ．３、ＨＣ Ｏｒａｎｇｅ Ｎｏ．１などのＨＣ染料、ＤＩＳＰＥＲＳＥ ＢＬＡＣＫ ９、ＤＩＳＰＥＲＳＥ ＶＩＯＬＥＴ １などの分散染料を本発明の目的が阻害されない範囲内で適宜、前記第１剤に配合することができる。 In the present invention, for example, basic dyes such as Basic Blue 99, Basic Yellow 57, Basic Brown 16, Basic Brown 17, Basic Red 76, and HC Blue No. 2, HC Yellow No. 2, HC Yellow No. 4, HC Yellow No. 4 5, HC Red No. 5 1, HC Red No. 1 3, HC Orange No. HC dyes such as 1 and disperse dyes such as DISPERSE BLACK 9, DISPERSE VIOLET 1 can be appropriately blended with the first agent within the range in which the object of the present invention is not inhibited.
前記各染料の種類やそれらの配合比率は、第１剤が所望の色彩を有するように調整することが好ましい。第１剤における酸化染料の含有量は、充分な染毛効果を発現させる観点から、０．００１〜１０重量％が好ましく、０．０１〜５重量％がより好ましい。 It is preferable to adjust the kind of each dye and the blending ratio thereof so that the first agent has a desired color. The content of the oxidation dye in the first agent is preferably 0.001 to 10% by weight, more preferably 0.01 to 5% by weight, from the viewpoint of expressing a sufficient hair dyeing effect.
第２剤における酸化剤としては、過酸化水素、過酸化尿素、過硫酸塩、過ホウ酸塩、過炭酸塩、臭素酸塩、過ヨウ素酸塩などが挙げられ、これらは、それぞれ単独で又は２種以上を適宜組合せて用いることができる。 Examples of the oxidizing agent in the second agent include hydrogen peroxide, urea peroxide, persulfate, perborate, percarbonate, bromate, periodate, and the like. Two or more kinds can be used in appropriate combination.
第２剤における酸化剤の含有量は、充分な酸化力を得る観点から、０．１〜２０重量％が好ましく、１〜１６重量％がより好ましい。 The content of the oxidizing agent in the second agent is preferably 0.1 to 20% by weight, more preferably 1 to 16% by weight, from the viewpoint of obtaining sufficient oxidizing power.
なお、本発明の効果が損なわれない範囲内であれば、第１剤及び第２剤には、油性成分、非イオン性界面活性剤以外の界面活性剤、低級アルコール、高級アルコール、金属封鎖剤、ｐＨ調整剤、動植物抽出物などを適宜配合することができる。また、各剤において、（Ａ）〜（Ｃ）成分及び上記成分の残部は、精製水などの水である。 As long as the effects of the present invention are not impaired, the first agent and the second agent include oily components, surfactants other than nonionic surfactants, lower alcohols, higher alcohols, metal sequestering agents. , PH adjusters, animal and plant extracts, and the like can be appropriately blended. In each agent, the components (A) to (C) and the remainder of the components are water such as purified water.
第１剤及び第２剤の製造方法としては、従来公知の方法が挙げられる。例えば、加熱して溶解させた（Ａ）成分を含有する油相に、同様に加熱した（Ｂ）、（Ｃ）成分などを含有する水相を混合・攪拌し、乳化を行う。乳化後、冷却し、第１剤はアルカリ剤を、第２剤は酸化剤を添加して製造することができる。 A conventionally well-known method is mentioned as a manufacturing method of a 1st agent and a 2nd agent. For example, the oil phase containing the component (A) dissolved by heating is mixed and stirred in the same manner as the aqueous phase containing the components (B) and (C) heated, and emulsified. After emulsification, the mixture can be cooled, and the first agent can be produced by adding an alkaline agent and the second agent by adding an oxidizing agent.
第１剤と第２剤の重量比（第１剤／第２剤）は、混合時に最適な粘度となる観点から、好ましくは３／１〜１／４、より好ましくは２／１〜１／３となるように調整される。 The weight ratio of the first agent to the second agent (first agent / second agent) is preferably 3/1 to 1/4, more preferably 2/1 to 1/1, from the viewpoint of achieving an optimum viscosity during mixing. It is adjusted to be 3.
本発明の毛髪処理剤用キットは、前記第１剤と第２剤を、そのまま混合して用いる２剤式毛髪処理剤として、又は過硫酸塩などの第３剤と混合して３剤式毛髪処理剤として用いることができる。 The kit for a hair treatment agent of the present invention is a three-component hair, as a two-component hair treatment agent used by mixing the first agent and the second agent as they are, or mixed with a third agent such as persulfate. It can be used as a treating agent.
実施例１〜６及び比較例１〜６
表１又は表２に示す組成の第１剤及び第２剤を下記方法により製造し、実施例１〜６及び比較例１〜６の毛髪処理剤用キットを得た。
Examples 1-6 and Comparative Examples 1-6
The 1st agent and 2nd agent of the composition shown in Table 1 or Table 2 were manufactured by the following method, and the kit for hair treatment agents of Examples 1-6 and Comparative Examples 1-6 was obtained.
＜第１剤製造方法＞
油相を８０℃に加熱して十分溶解させたところに、同様に８０℃に加熱した水相を徐々に投入する。ホモミキサーで３０００ｒ／ｍｉｎ、１０分間攪拌し、乳化を行う。乳化後、３５℃まで冷却し、アルカリ剤を投入する。投入後、十分に均一攪拌する。
<First agent production method>
When the oil phase is heated to 80 ° C. and sufficiently dissolved, the water phase similarly heated to 80 ° C. is gradually added. The mixture is stirred with a homomixer at 3000 r / min for 10 minutes to emulsify. After emulsification, it is cooled to 35 ° C. and an alkali agent is added. After the addition, stir sufficiently uniformly.
＜第２剤製造方法＞
油相を８０℃に加熱して十分溶解させたところに、同様に８０℃に加熱した水相を徐々に投入する。ホモミキサーで３０００ｒｐｍ、１０分間攪拌し、乳化を行う。乳化後、３５℃まで冷却し、酸化剤を投入する。投入後、十分に均一攪拌する。
<Second agent production method>
When the oil phase is heated to 80 ° C. and sufficiently dissolved, the water phase similarly heated to 80 ° C. is gradually added. Stir with a homomixer at 3000 rpm for 10 minutes to emulsify. After emulsification, it is cooled to 35 ° C. and an oxidizing agent is added. After the addition, stir sufficiently uniformly.
次に、得られた毛髪処理剤用キットについて、以下の試験例１〜５の評価を行った。結果を表１及び２に示す。 Next, the following test examples 1-5 were evaluated about the obtained kit for hair treatment agents. The results are shown in Tables 1 and 2.
試験例１（各剤の保存安定性（性状・粘度安定性））
各実施例及び各比較例の毛髪処理剤用キットについて、第１剤と第２剤の製造直後の外観及び粘性を目視で観察し、その後、第１剤をポリエチレンチューブに、第２剤をポリエチレン容器にそれぞれ充填し、４５℃の恒温槽内にて４週間放置した。４週間後、各剤の中身を取り出し、系の外観及び粘性を目視観察してそれぞれ、以下の評価基準に従って性状及び粘度安定性を評価した。
Test Example 1 (Storage stability (property / viscosity stability) of each agent)
About the hair treatment agent kit of each example and each comparative example, the appearance and viscosity immediately after the production of the first agent and the second agent were visually observed, and then the first agent was put in a polyethylene tube and the second agent was made in polyethylene. Each container was filled and left in a constant temperature bath at 45 ° C. for 4 weeks. After 4 weeks, the contents of each agent were taken out, the appearance and viscosity of the system were visually observed, and the properties and viscosity stability were evaluated according to the following evaluation criteria, respectively.
〔性状の評価基準〕
◎：製造直後と変化無し
○：僅かに生地あれが認められる
△：明らかに生地あれが認められる
×：著しい生地あれ又は分離が認められる
[Evaluation criteria for properties]
◎: Immediately after production and no change ○: Slightly dough is observed
△: Obviously fabric dough is recognized x: Significant dough over or separated
〔粘度安定性の評価基準〕
◎：製造直後と粘度変動無し
○：僅かに粘度上昇若しくは低下が認められる
△：明らかな粘度上昇若しくは低下が認められる
×：著しい粘度上昇若しくは低下が認められる
[Viscosity stability evaluation criteria]
A: Immediately after production and no change in viscosity B: Slight increase or decrease in viscosity is observed
Δ: Obvious increase or decrease in viscosity is observed ×: Remarkable increase or decrease in viscosity is observed
試験例２（混合時の最適粘度）
専門パネル２０名により実施した。２３℃、湿度６０％の恒温恒湿下で一晩放置した試験用毛束（長さ１０ｃｍ、重量１ｇ）に、各実施例及び各比較例の毛髪処理剤用キットについて、第１剤及び第２剤を１：２の比率（重量比）でトレー上で混合して調製した毛髪処理剤を２ｇ塗布し、垂れ落ち及び延展性について以下の評価基準に従って評価した。
Test example 2 (optimum viscosity during mixing)
The training was conducted by 20 specialist panels. For the test hair bundles (length 10 cm, weight 1 g) left overnight at 23 ° C. and humidity 60%, the first agent and the 2 g of a hair treatment agent prepared by mixing two agents on a tray at a ratio (weight ratio) of 1: 2 was applied, and sagging and spreadability were evaluated according to the following evaluation criteria.
〔垂れ落ちの評価基準〕
◎：２０名中１６名以上が毛束からの垂れ落ちが全くないと回答
○：２０名中１１〜１５名が毛束からの垂れ落ちが全くないと回答
△：２０名中６〜１０名が毛束からの垂れ落ちが全くないと回答
×：２０名中５名以下が毛束からの垂れ落ちが全くないと回答
[Evaluation criteria for dripping]
◎: 16 or more of 20 people answered that there was no dripping from the hair bundle ○: 11-15 of 20 people answered that there was no dripping from the hair bundle Δ: 6-10 of 20 people answered Answer that there is no dripping from the hair bundle ×: 5 or less of 20 people answered that there is no dripping from the hair bundle
〔延展性の評価基準〕
◎：２０名中１６名以上が毛髪上での延展性に優れると回答
○：２０名中１１〜１５名が毛髪上での延展性に優れると回答
△：２０名中６〜１０名が毛髪上での延展性に優れると回答
×：２０名中５名以下が毛髪上での延展性に優れると回答
[Evaluation criteria for extensibility]
◎: More than 16 out of 20 responded that extensibility on hair was excellent ○: 11-15 out of 20 responded that extensibility on hair was excellent Δ: 6-10 out of 20 responded to hair Answer that extensibility on the top is excellent ×: 5 or less of 20 responded that extensibility on the hair is excellent
試験例３（粘度安定性）
試験例２で得られた各毛髪処理剤について、トレー上でかき混ぜることにより、混合直後の粘度と、室温で１時間放置後の粘度とを比較し、粘度の変動を以下の評価基準に従って評価した。
Test Example 3 (Viscosity stability)
For each hair treatment agent obtained in Test Example 2, the viscosity immediately after mixing was compared with the viscosity after standing for 1 hour at room temperature by stirring on a tray, and the change in viscosity was evaluated according to the following evaluation criteria. .
〔粘度安定性の評価基準〕
◎：混合直後と粘度変動無し
○：混合直後と比べ、僅かに粘度上昇若しくは低下が認められる
△：混合直後と比べ、明らかな粘度上昇若しくは低下が認められる
×：混合直後と比べ、著しい粘度上昇若しくは低下が認められる
[Viscosity stability evaluation criteria]
◎: Immediately after mixing and no change in viscosity ○: Slightly increased or decreased in viscosity compared to immediately after mixing
Δ: A clear increase or decrease in viscosity is observed compared to immediately after mixing. ×: A significant increase or decrease in viscosity is observed compared to immediately after mixing.
試験例４（刺激臭の抑制及び脱色性・染色性の評価）
専門パネル２０名により実施した。試験例２で各毛髪処理剤を塗布した毛束を、塗布後３０℃で３０分間放置し、その後、水道水で洗浄しドライヤーを用いて毛束を乾燥した。施術中の刺激臭及び乾燥後の毛束の脱色性・染毛性について以下の評価基準に従って評価した。
Test Example 4 (Suppression of irritating odor and evaluation of decolorization / dyeability)
The training was conducted by 20 specialist panels. The hair bundle to which each hair treatment agent was applied in Test Example 2 was allowed to stand at 30 ° C. for 30 minutes after application, then washed with tap water, and the hair bundle was dried using a dryer. The pungent odor during the treatment and the decolorization / hair dyeing property of the hair bundle after drying were evaluated according to the following evaluation criteria.
〔刺激臭の評価基準〕
◎：２０名中１６名以上がアルカリ剤などの刺激臭を全く感じないと回答
○：２０名中１１〜１５名がアルカリ剤などの刺激臭を全く感じないと回答
△：２０名中６〜１０名がアルカリ剤などの刺激臭を全く感じないと回答
×：２０名中５名以下がアルカリ剤などの刺激臭を全く感じないと回答
[Evaluation criteria for pungent odors]
◎: 16 or more of 20 respondents do not feel any irritating odor such as alkaline agent ○: 11-15 of 20 respondents do not feel any irritating odor such as alkaline agent Δ: 6 to 20 of 20 respondents 10 respondents who do not feel any irritating odors such as alkaline agents x: 5 or less of 20 respondents who do not feel any irritating odors such as alkaline agents
〔脱色性・染色性の評価基準〕
◎：２０名中１６名以上が毛束にムラがなく均一に脱色・染色されていると回答
○：２０名中１１〜１５名が毛束にムラがなく均一に脱色・染色されていると回答
△：２０名中６〜１０名が毛束にムラがなく均一に脱色・染色されていると回答
×：２０名中５名以下が毛束にムラがなく均一に脱色・染色されていると回答
[Evaluation criteria for decolorization / dyeability]
◎: More than 16 out of 20 people answered that the hair bundles were uniformly decolored and dyed ○: 11 to 15 out of 20 people were uniformly decolored and dyed without uneven hair bundles Answer △: 6 to 10 out of 20 hair bundles have no unevenness and are uniformly decolored and dyed x: 5 out of 20 people have uniform hair colors and are uniformly decolored and dyed Answer
以上の結果より、実施例の毛髪処理剤用キットは、各剤の保存安定性にも優れ、かつ混合後の垂れ落ち・粘度安定性など全ての特性において優れていることが分かる。一方、水溶性多糖類成分を含有しない比較例２及び５は、リン酸ジアルキル成分との相乗効果が得られないために、粘性の低下が認められ、混合後の粘度安定性に劣るものと考えられる。また、非イオン性界面活性剤成分を含有する比較例３及び６は、粘性が高くなりすぎることにより、延展性に劣ると考えられる。 From the above results, it can be seen that the hair treatment agent kits of the examples are excellent in storage stability of each agent and excellent in all properties such as dripping and viscosity stability after mixing. On the other hand, Comparative Examples 2 and 5 that do not contain a water-soluble polysaccharide component are considered to be inferior in viscosity stability after mixing because a synergistic effect with the dialkyl phosphate component is not obtained and a decrease in viscosity is observed. It is done. Moreover, it is thought that the comparative examples 3 and 6 containing a nonionic surfactant component are inferior in spreadability because viscosity becomes high too much.
以下、本発明の毛髪処理剤用キットの処方例１〜４を示す。なお、含有量は重量％である。 Hereinafter, Formulation Examples 1 to 4 of the kit for hair treatment agent of the present invention are shown. The content is% by weight.
（処方例１：２剤式染毛剤）
（第１剤：クリーム状）
パラフェニレンジアミン ０．１５
レゾルシン ０．１
メタアミノフェノール ０．０５
リン酸ジセチル ２．０
セチルアルコール ３．０
ジプロピレングリコール ３．０
キサンタンガム ０．２
グルタミン酸 ０．５
アルギニン ０．５
プロリン ０．５
メチルポリシロキサン １．０
香料 適 量
アンモニア水（２８％） ５．０
モノエタノールアミン ２．０
炭酸アンモニウム ０．５
精製水 残 部
合計 １００．０
（第２剤：クリーム状）
過酸化水素（３５％） １６．０
リン酸ジセチル １．０
セチルアルコール ２．０
ヒドロキシエタンジホスホン酸 ０．５
ピロリン酸四ナトリウム ０．５
精製水 残 部
合計 １００．０
(Formulation Example 1: Two-component hair dye)
(First agent: cream)
Paraphenylenediamine 0.15
Resorcinol 0.1
Metaaminophenol 0.05
Dicetyl phosphate 2.0
Cetyl alcohol 3.0
Dipropylene glycol 3.0
Xanthan gum 0.2
Glutamic acid 0.5
Arginine 0.5
Proline 0.5
Methyl polysiloxane 1.0
Perfume appropriate amount Ammonia water (28%) 5.0
Monoethanolamine 2.0
Ammonium carbonate 0.5
Purified water balance
Total 100.0
(Second agent: cream)
Hydrogen peroxide (35%) 16.0
Dicetyl phosphate 1.0
Cetyl alcohol 2.0
Hydroxyethanediphosphonic acid 0.5
Tetrasodium pyrophosphate 0.5
Purified water balance
Total 100.0
（処方例２：２剤式染毛剤）
（第１剤：クリーム状）
パラフェニレンジアミン ０．１５
レゾルシン ０．１
メタアミノフェノール ０．０５
リン酸ジセチル １．０
セチルアルコール ３．０
ステアリルアルコール ２．０
ジプロピレングリコール ２．０
濃グリセリン ５．０
キサンタンガム ０．５
グルタミン酸 ０．２
プロリン ０．３
メチルフェニルポリシロキサン １．０
香料 適 量
アンモニア水（２８％） ５．０
モノエタノールアミン ２．０
炭酸アンモニウム ０．５
精製水 残 部
合計 １００．０
（第２剤：クリーム状）
過酸化水素（３５％） １６．０
リン酸ジセチル ２．０
セチルアルコール ３．０
ヒドロキシエタンジホスホン酸 ０．５
ピロリン酸四ナトリウム ０．５
精製水 残 部
合計 １００．０
(Prescription Example 2: Two-component hair dye)
(First agent: cream)
Paraphenylenediamine 0.15
Resorcinol 0.1
Metaaminophenol 0.05
Dicetyl phosphate 1.0
Cetyl alcohol 3.0
Stearyl alcohol 2.0
Dipropylene glycol 2.0
Concentrated glycerin 5.0
Xanthan gum 0.5
Glutamic acid 0.2
Proline 0.3
Methylphenylpolysiloxane 1.0
Perfume appropriate amount Ammonia water (28%) 5.0
Monoethanolamine 2.0
Ammonium carbonate 0.5
Purified water balance
Total 100.0
(Second agent: cream)
Hydrogen peroxide (35%) 16.0
Dicetyl phosphate 2.0
Cetyl alcohol 3.0
Hydroxyethanediphosphonic acid 0.5
Tetrasodium pyrophosphate 0.5
Purified water balance
Total 100.0
（処方例３：２剤式染毛剤）
（第１剤：クリーム状）
パラフェニレンジアミン ０．１５
レゾルシン ０．１
メタアミノフェノール ０．０５
リン酸ジセチル ０．５
ステアリルアルコール ５．０
濃グリセリン ７．０
キサンタンガム ０．１５
アルギニン ０．５
プロリン １．０
アミノ変性シリコーン ０．５
香料 適 量
アンモニア水（２８％） ５．０
モノエタノールアミン ２．０
炭酸アンモニウム ０．５
精製水 残 部
合計 １００．０
（第２剤：クリーム状）
過酸化水素（３５％） １６．０
リン酸ジセチル １．５
セチルアルコール １．０
ヒドロキシエタンジホスホン酸 ０．５
ピロリン酸四ナトリウム ０．５
精製水 残 部
合計 １００．０
(Prescription Example 3: Two-component hair dye)
(First agent: cream)
Paraphenylenediamine 0.15
Resorcinol 0.1
Metaaminophenol 0.05
Dicetyl phosphate 0.5
Stearyl alcohol 5.0
Concentrated glycerin 7.0
Xanthan gum 0.15
Arginine 0.5
Proline 1.0
Amino-modified silicone 0.5
Perfume appropriate amount Ammonia water (28%) 5.0
Monoethanolamine 2.0
Ammonium carbonate 0.5
Purified water balance
Total 100.0
(Second agent: cream)
Hydrogen peroxide (35%) 16.0
Dicetyl phosphate 1.5
Cetyl alcohol 1.0
Hydroxyethanediphosphonic acid 0.5
Tetrasodium pyrophosphate 0.5
Purified water balance
Total 100.0
（処方例４：３剤式脱色剤）
（第１剤：クリーム状）
リン酸ジセチル ２．０
セチルアルコール ２．０
ステアリルアルコール ２．０
ジプロピレングリコール ６．０
キサンタンガム ０．３
プロリン １．０
メチルフェニルポリシロキサン １．０
アミノ変性シリコーン ２．０
香料 適 量
アンモニア水（２８％） ５．０
モノエタノールアミン ２．０
炭酸アンモニウム ０．５
精製水 残 部
合計 １００．０
（第２剤：クリーム状）
過酸化水素（３５％） １６．０
リン酸ジセチル １．０
セチルアルコール ３．０
ヒドロキシエタンジホスホン酸 ０．５
ピロリン酸四ナトリウム ０．５
精製水 残 部
合計 １００．０
（第３剤：粉末状）
過硫酸カリウム ２５．０
過硫酸アンモニウム ２０．０
メタケイ酸ナトリウム ２０．０
ステアリン酸マグネシウム １０．０
カルボキシメチルセルロースナトリウム １０．０
無水ケイ酸 １３．５
ＥＤＴＡ １．０
酸化クロム ０．５
合計 １００．０
(Prescription Example 4: Three-part bleaching agent)
(First agent: cream)
Dicetyl phosphate 2.0
Cetyl alcohol 2.0
Stearyl alcohol 2.0
Dipropylene glycol 6.0
Xanthan gum 0.3
Proline 1.0
Methylphenylpolysiloxane 1.0
Amino-modified silicone 2.0
Perfume appropriate amount Ammonia water (28%) 5.0
Monoethanolamine 2.0
Ammonium carbonate 0.5
Purified water balance
Total 100.0
(Second agent: cream)
Hydrogen peroxide (35%) 16.0
Dicetyl phosphate 1.0
Cetyl alcohol 3.0
Hydroxyethanediphosphonic acid 0.5
Tetrasodium pyrophosphate 0.5
Purified water balance
Total 100.0
(Third agent: powder)
Potassium persulfate 25.0
Ammonium persulfate 20.0
Sodium metasilicate 20.0
Magnesium stearate 10.0
Sodium carboxymethyl cellulose 10.0
Silica anhydride 13.5
EDTA 1.0
Chromium oxide 0.5
Total 100.0
本発明の毛髪処理剤用キットは、第１剤と第２剤の保存安定性に優れ、かつ混合後に最適な粘度を有することから、脱色剤又は染毛剤などに好適に用いられるものである。 The hair treatment kit of the present invention is excellent in the storage stability of the first agent and the second agent and has an optimum viscosity after mixing, and is therefore suitably used for a decoloring agent or hair dye. .
Claims (4)
Furthermore, the kit for hair treatment agents in any one of Claims 1-3 formed by containing (C) polyhydric alcohol.
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|---|---|---|---|
| JP2006332371A JP5158744B2 (en) | 2006-12-08 | 2006-12-08 | Hair treatment kit |
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| JP5158744B2 JP5158744B2 (en) | 2013-03-06 |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2013515678A (en) * | 2009-10-13 | 2013-05-09 | ロレアル | Composition comprising fatty substance and organic phosphonic acid or salt thereof, coloring or lightening method and kit using the same |
| WO2016021425A1 (en) * | 2014-08-08 | 2016-02-11 | 株式会社マンダム | Oxidative hair dye, production method for oxidative hair dye mixture, and oxidative hair dye method |
| CN106924056A (en) * | 2009-08-25 | 2017-07-07 | 莱雅公司 | For the make-up composition of keratin fiber |
| JP2018012678A (en) * | 2016-07-22 | 2018-01-25 | ホーユー株式会社 | Oxidation hair dye first agent and color tone stabilization method for oxidation hair dye composition |
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| CN106924056B (en) * | 2009-08-25 | 2021-03-09 | 莱雅公司 | Cosmetic composition for keratin fibers |
| JP2013515678A (en) * | 2009-10-13 | 2013-05-09 | ロレアル | Composition comprising fatty substance and organic phosphonic acid or salt thereof, coloring or lightening method and kit using the same |
| CN106102702B (en) * | 2014-08-08 | 2019-09-17 | 株式会社漫丹 | Oxide hair dye, the manufacturing method of oxidation hair-dye intermixture and oxidation hair-dye method |
| WO2016021425A1 (en) * | 2014-08-08 | 2016-02-11 | 株式会社マンダム | Oxidative hair dye, production method for oxidative hair dye mixture, and oxidative hair dye method |
| CN106102702A (en) * | 2014-08-08 | 2016-11-09 | 株式会社漫丹 | Oxide hair dye, the manufacture method of oxidation hair-dye intermixture and oxidation hair-dye method |
| JPWO2016021425A1 (en) * | 2014-08-08 | 2017-04-27 | 株式会社マンダム | Oxidative hair dye, method for producing oxidative hair dye mixture, and oxidative hair dyeing method |
| JP2018012678A (en) * | 2016-07-22 | 2018-01-25 | ホーユー株式会社 | Oxidation hair dye first agent and color tone stabilization method for oxidation hair dye composition |
| CN107638301A (en) * | 2016-07-22 | 2018-01-30 | 朋友株式会社 | The tone stabilization method of first dose of oxide hair dye and oxide hair dye composition |
| CN107638301B (en) * | 2016-07-22 | 2022-10-14 | 朋友株式会社 | First agent for oxidative hair dye and method for stabilizing color tone of oxidative hair dye composition |
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