JP2008044970A - Foaming type cleaning tool and method for foaming type cleaning - Google Patents
Foaming type cleaning tool and method for foaming type cleaning Download PDFInfo
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- JP2008044970A JP2008044970A JP2006218647A JP2006218647A JP2008044970A JP 2008044970 A JP2008044970 A JP 2008044970A JP 2006218647 A JP2006218647 A JP 2006218647A JP 2006218647 A JP2006218647 A JP 2006218647A JP 2008044970 A JP2008044970 A JP 2008044970A
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- 238000004140 cleaning Methods 0.000 title claims abstract description 168
- 238000005187 foaming Methods 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims description 19
- 239000007788 liquid Substances 0.000 claims abstract description 80
- 239000004744 fabric Substances 0.000 claims abstract description 62
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 14
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 11
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 10
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims description 32
- 238000005470 impregnation Methods 0.000 claims description 22
- 239000006260 foam Substances 0.000 claims description 20
- QPQANCNBWQXGTQ-UHFFFAOYSA-N trihydroxy(trimethylsilylperoxy)silane Chemical compound C[Si](C)(C)OO[Si](O)(O)O QPQANCNBWQXGTQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005871 repellent Substances 0.000 abstract description 14
- -1 alkyl glucoside Chemical class 0.000 abstract description 13
- 229930182478 glucoside Natural products 0.000 abstract description 9
- 239000004615 ingredient Substances 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 description 13
- 229920006395 saturated elastomer Polymers 0.000 description 9
- 239000002453 shampoo Substances 0.000 description 9
- 239000012459 cleaning agent Substances 0.000 description 8
- 239000004745 nonwoven fabric Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229920003023 plastic Polymers 0.000 description 7
- 239000004033 plastic Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 5
- 230000005587 bubbling Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000002354 daily effect Effects 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 108700042658 GAP-43 Proteins 0.000 description 3
- 239000005001 laminate film Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 2
- JDRSMPFHFNXQRB-IBEHDNSVSA-N decyl glucoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JDRSMPFHFNXQRB-IBEHDNSVSA-N 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000010813 municipal solid waste Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- 229920006310 Asahi-Kasei Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229940073499 decyl glucoside Drugs 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- SIYLLGKDQZGJHK-UHFFFAOYSA-N dimethyl-(phenylmethyl)-[2-[2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy]ethyl]ammonium Chemical compound C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 SIYLLGKDQZGJHK-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 1
- 229940048848 lauryl glucoside Drugs 0.000 description 1
- 239000008258 liquid foam Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 125000001453 quaternary ammonium group Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Vehicle Cleaning, Maintenance, Repair, Refitting, And Outriggers (AREA)
- Detergent Compositions (AREA)
Abstract
Description
本発明は、自動車やバイク、自転車、家屋、建築物などの塗装面を含む表面、ガラスや金属、化粧ボード、石、陶磁器、ゴム製品やプラスチック製品などで、水を吸収しないかもしくは吸収しても悪い影響が見られない硬質の対象物の表面など、の洗浄に用いる発泡型洗浄具及び発泡型洗浄方法に関し、詳しくは、これらの対象物の表面を洗浄する際、洗浄液を含浸した基布としてのクロスを用いて泡を立てながら洗浄することのできる上記洗浄具及び洗浄方法に関する。また、本発明は、洗浄後に水ですすいだ対象物の表面に水はじき性の被膜が自然に形成される上記洗浄具及び洗浄方法に関する。 The present invention does not absorb or absorb water on surfaces such as automobiles, motorcycles, bicycles, houses, buildings, etc., including painted surfaces, glass, metal, decorative boards, stones, ceramics, rubber products, plastic products, etc. In particular, the present invention relates to a foam-type cleaning tool and a foam-type cleaning method used for cleaning a hard object surface that does not have a bad influence, and more specifically, a base cloth impregnated with a cleaning liquid when cleaning the surface of these objects. It is related with the said cleaning tool and the washing | cleaning method which can be wash | cleaned, making foam using the cloth as. The present invention also relates to the cleaning tool and the cleaning method described above, wherein a water-repellent film is naturally formed on the surface of an object rinsed with water after cleaning.
従来、自動車の外装部の洗浄には、界面活性剤を水に溶解した液体洗浄剤を用いることが提案されていた(たとえば、特許文献1、特許文献2参照)。これらの特許文献1又は同2に記載されている液体洗浄剤を用いる洗車作業では、バケツ内で液体洗浄剤を薄め、その洗浄剤でスポンジやタオル、ブラシなどを濡らして自動車の外装部を洗った後、水ですすぎ、仕上げ拭きをしていた。また、液体洗浄剤の入ったスプレー容器を片手に持ってその洗浄剤を自動車の外装部にスプレーしながら、他の片手でその場所をスポンジやタオルで洗浄するということも行われていた。このような洗浄方法は、家庭のガラスや壁紙、網戸、化粧ボード、タイル、塗装表面などの汚れ取りにも通常利用されている。 Conventionally, it has been proposed to use a liquid cleaning agent in which a surfactant is dissolved in water for cleaning an exterior portion of an automobile (see, for example, Patent Document 1 and Patent Document 2). In the car washing operation using the liquid detergent described in these Patent Documents 1 and 2, the liquid detergent is diluted in a bucket, and the sponge, towel, brush, etc. are wetted with the detergent to wash the exterior of the automobile. After that, it was rinsed with water and wiped with finish. Also, it has been practiced to hold a spray container containing a liquid cleaning agent in one hand and spray the cleaning agent on the exterior of an automobile while washing the place with a sponge or towel with the other hand. Such a cleaning method is usually used for removing stains on glass, wallpaper, screen doors, decorative boards, tiles, painted surfaces, and the like at home.
他方、洗車後にはつ撥水性や艶出し性を発揮するワックス被膜を残すことのできる洗浄液を含浸させたクロスを用いて洗車作業を簡単にすることも提案されていた(たとえば、特許文献3、特許文献4参照)。 On the other hand, it has also been proposed to simplify a car wash operation using a cloth impregnated with a cleaning liquid that can leave a wax film exhibiting water repellency and gloss after car washing (for example, Patent Document 3, (See Patent Document 4).
しかしながら、特許文献1や特許文献2によって提案されている液体洗浄剤を用いる洗浄方法では、液体洗浄剤を薄めて溜めておくバケツを用意したり、液体洗浄剤の入った重たいスプレー容器を手に持ったり、高価なスポンジなどを用意したりする必要があるために、十分な洗浄効果を期待することができる反面で、作業手間で面倒であるという問題があった。 However, in the cleaning method using the liquid cleaning agent proposed by Patent Document 1 or Patent Document 2, a bucket for thinning and storing the liquid cleaning agent is prepared, or a heavy spray container containing the liquid cleaning agent is held in the hand. Since it is necessary to hold or prepare an expensive sponge or the like, a sufficient cleaning effect can be expected, but there is a problem that it is troublesome to work.
これに対し、特許文献3や特許文献4によって提案されている洗浄作業によると、作業手間の面倒さをそれほど感じなくなるけれども、洗浄作業中に洗浄液が満足できるほど泡立たないために、ユーザにとっては、有効な洗浄が行われているか否かを感覚的につかみにくくなって洗浄後の満足感を得にくいという問題があった。 On the other hand, according to the cleaning work proposed by Patent Document 3 and Patent Document 4, although the user does not feel much troublesome work, the cleaning liquid does not foam to a satisfactory level during the cleaning work. There is a problem that it is difficult to get a sense of satisfaction after cleaning because it is difficult to grasp whether or not effective cleaning is performed.
本発明は以上の状況や問題に鑑みてなされたものであり、液体洗浄液を含浸させたクロスなどの基布を用いて洗浄作業を行うことを基本とし、洗浄作業中の洗浄液の泡立ち性を改善することによって、ユーザが楽な作業で泡を立てながら満足のいく洗浄を行うことのできる発泡型洗浄具及び発泡型洗浄方法を提供することを目的とする。 The present invention has been made in view of the above situation and problems, and is based on performing a cleaning operation using a cloth such as a cloth impregnated with a liquid cleaning solution, and improves the foaming property of the cleaning solution during the cleaning operation. Accordingly, it is an object of the present invention to provide a foam type cleaning tool and a foam type cleaning method that enable a user to perform satisfactory cleaning while creating bubbles in an easy operation.
加えて、本発明は、洗浄中の洗浄液の泡立ち性を犠牲にすることなく、洗浄後の対象物の表面に水はじき性の被膜を形成することのできる発泡型洗浄具及び発泡型洗浄方法を提供することを目的とする。 In addition, the present invention provides a foam type cleaning tool and a foam type cleaning method capable of forming a water-repellent film on the surface of an object after cleaning without sacrificing the foaming property of the cleaning liquid during cleaning. The purpose is to provide.
本発明に係る発泡型洗浄具は、洗浄用基布に洗浄液を含浸させてなり、上記基布がその重量の2.5倍以上の重量の洗浄液の含浸能力を有していて、その基布にその重量の2.5倍以上の重量の洗浄液を含浸させてなる、というものである。この発明によれば、基布にあらかじめ十分に多くの洗浄液が含浸されているために、洗浄作業中にその基布をバケツに溜めた希薄洗浄液で濡らすという作業を行う必要がなく、しかも、洗浄作業中には、基布に含浸されている十分な量の洗浄液が基布中で泡立ったり、基布から絞り出されて泡立ったりするので、ユーザが楽な作業で泡を立てながら満足のいく洗浄を行うことができるようになる。 The foam-type cleaning tool according to the present invention is obtained by impregnating a cleaning base cloth with a cleaning liquid, and the base cloth has a cleaning liquid impregnation capacity of 2.5 times or more of the weight. Is impregnated with a washing liquid having a weight of 2.5 times or more. According to this invention, since the base cloth is sufficiently impregnated with a large amount of cleaning liquid in advance, it is not necessary to perform the operation of wetting the base cloth with the diluted cleaning liquid stored in the bucket during the cleaning operation. During the work, a sufficient amount of cleaning liquid impregnated in the base fabric foams in the base fabric or is squeezed out from the base fabric and foams. Cleaning can be performed.
本発明に係る発泡型洗浄具において、上記洗浄液の主成分が、アルキルグルコシド系ノニオン性界面活性剤と、第4級アンモニウム塩型カチオン性界面活性剤と、トリメチルシロキシケイ酸を含有するシリコーンエマルジョンと、でなるものであることが望ましい。これによれば、洗浄作業中に洗浄液を十分に泡立たせながら一気に洗浄することが可能になることは勿論、洗浄後に水ですすぐことによって水はじき性の被膜が対象物の表面に形成されるために、洗浄後の対象物の表面がきれいな状態に仕上がるという作用が発揮される。 In the foam-type cleaning tool according to the present invention, the main components of the cleaning liquid are an alkyl glucoside nonionic surfactant, a quaternary ammonium salt cationic surfactant, and a silicone emulsion containing trimethylsiloxysilicate. It is desirable that According to this, since it becomes possible to wash at a stretch while sufficiently bubbling the cleaning liquid during the cleaning operation, a water-repellent film is formed on the surface of the object by rinsing with water after cleaning. Moreover, the effect that the surface of the object after washing is finished in a clean state is exhibited.
本発明に係る発泡型洗浄方法は、上記の発泡型洗浄具の基布に含浸されている洗浄液又はその基布から流出した洗浄液を泡立たせながらその基布で対象物の表面を拭くというものであるので、上記したところと同様に、ユーザが楽な作業で泡を立てながら満足のいく洗浄を行うことができるようになる。 The foam-type cleaning method according to the present invention is a method of wiping the surface of an object with the base cloth while foaming the cleaning liquid impregnated in the base cloth of the foam-type cleaning tool or the cleaning liquid flowing out from the base cloth. Thus, as described above, the user can perform satisfactory cleaning while creating bubbles in an easy operation.
また、この発泡型洗浄方法では、上記洗浄液が泡立ちにくくなったときに水を基布又は対象物の表面に補給して泡立ちを回復させるという手段を採用することが可能である。このため、小さなサイズから大きなサイズに至ってどの型のサイズの対象物の表面の洗浄を行う際にも、洗浄液を泡立たせながらユーザが最後まで楽な作業で満足のいく洗浄を行うことができる。 Further, in this foaming type cleaning method, it is possible to employ means for replenishing foaming by replenishing water to the base fabric or the surface of the object when the cleaning liquid becomes difficult to foam. For this reason, even when cleaning the surface of an object of any type from a small size to a large size, the user can perform satisfactory cleaning with easy work to the end while bubbling the cleaning liquid.
本発明の発泡型洗浄具及び発泡型洗浄方法によれば、ユーザにとっては、スポンジ、ブラシ、バケツなどの洗浄用具を余分に必要とすることなく、また、液体洗浄剤を入れたスプレー容器を片手で持って作業をするといった面倒さがなくなるだけでなく、洗浄液を泡立てながら一気に満足のいく洗浄作業を行うことができるようになる。しかも、洗浄後に水ですすぐことによって水はじき性の被膜を形成させることもできるので、洗浄後の対象物の表面をきれいな状態に仕上げることができるという効果が奏される。 According to the foam-type cleaning tool and the foam-type cleaning method of the present invention, the user does not need extra cleaning tools such as a sponge, a brush, and a bucket, and the spray container containing the liquid cleaning agent is held in one hand. In addition to eliminating the hassle of having to carry it in, it is possible to perform a satisfactory cleaning operation at a stretch while bubbling the cleaning liquid. In addition, since a water-repellent film can be formed by rinsing with water after washing, an effect is achieved that the surface of the object after washing can be finished in a clean state.
本発明に係る発泡型洗浄具及び発泡型洗浄方法に用い得る基布は、洗浄作業に一般的に汎用されている親水性繊維、親油性繊維のいずれかの繊維を用いた織布又は不織布であっても、それらの混合繊維を用いた織布又は不織布であってもよい。繊維は特に加工する必要はないが、分割やスパイラル構造にしておくことは、洗浄液の含浸保持能力(含浸性能)を高める上で有益である。 The base fabric that can be used in the foam-type cleaning tool and the foam-type cleaning method according to the present invention is a woven or non-woven fabric using any one of hydrophilic fibers and lipophilic fibers generally used for cleaning operations. Even if it exists, the woven fabric or nonwoven fabric using those mixed fibers may be sufficient. The fiber does not need to be processed in particular, but it is beneficial to improve the impregnation holding ability (impregnation performance) of the cleaning liquid to have a split or spiral structure.
繊維の大きさには特に限定がなく、天然のパルプや綿などと同様の扱いをする慣用サイズであってもかまわないけれども、好ましくは洗浄液の含浸保持能力の高い方がよい。たとえば、基布の重量の2.5倍以上の重量の洗浄液が垂れずに保持される程度の含浸保持能力を有しているものが特に適している。基布についての洗浄液含浸保持能力が上記の2.5倍より小さいと、洗浄液を泡立てながら洗浄作業をするときに早期に洗浄液が消化されてしまって十分に満足のいく洗浄作業を行えなくなるおそれがある。この点を改善するための対策として、洗浄液の有効成分濃度を高くする手段が考えられるけれども、そのようにすると、洗浄作業の初期に濃厚液が消化され、終期には淡白液で洗浄作業が行われるようになる傾向が生じやすいために、初期から終期まで一定に泡を立てながら安定した洗浄作業を行うことが難しくなる。基布についての洗浄液含浸保持能力が上記の2.5倍より大きいと、洗浄液を飽和状態に含浸させなくても、飽和含浸量以下の量の洗浄液を含浸させた状態で満足のいく洗浄作業を行うことができるようになる。すなわち、飽和含浸量以下の量の洗浄液を含浸させた基布、たとえば不織布では、空気の出入りがスムーズに起こり易い空間が保持されるために洗浄液の泡立ち性が改善され、しかも、洗浄液を保持能力も高く保たれるために、洗浄作業の初期から終期にかけて一定の有効濃度で広い面積を泡立たせながら満足のいく洗浄作業を行うことが可能になる。 The size of the fiber is not particularly limited, and may be a conventional size that can be handled in the same manner as natural pulp or cotton. However, it is preferable that the washing liquid has a high impregnation capacity. For example, a material having an impregnation holding capacity to such an extent that a washing liquid having a weight of 2.5 times or more the weight of the base fabric is held without dripping is particularly suitable. If the washing liquid impregnation holding capacity of the base fabric is less than 2.5 times the above, there is a risk that the washing liquid will be digested at an early stage and the washing work cannot be performed sufficiently satisfactorily when foaming the washing liquid. is there. As a measure to improve this point, a means to increase the concentration of the active ingredient in the cleaning solution can be considered. However, in such a case, the concentrated solution is digested at the beginning of the cleaning operation, and the cleaning operation is performed with a pale white solution at the end. Since it tends to occur, it becomes difficult to perform a stable cleaning operation while constantly foaming bubbles from the beginning to the end. If the washing liquid impregnation holding capacity of the base fabric is larger than 2.5 times the above, a satisfactory washing operation can be performed in a state where the washing liquid is impregnated with an amount equal to or less than the saturated impregnation amount without being saturated with the washing liquid. Will be able to do. That is, in a base fabric impregnated with a cleaning liquid in an amount equal to or less than the saturated impregnation amount, for example, a non-woven fabric, the foaming property of the cleaning liquid is improved because the space where air easily enters and exits is maintained, and the cleaning liquid is retained. Therefore, a satisfactory cleaning operation can be performed while bubbling a large area with a constant effective concentration from the beginning to the end of the cleaning operation.
なお、飽和含浸量以上の量の洗浄液を含浸させた基布を用いることを必ずしも否定するものではなく、そのような基布では洗浄作業前に少し絞り込んで余分な洗浄液を取り除くことによって空気が入りやすさを改善することが望まれる。しかしながら、そのようにすると、洗浄液が無駄に捨てられるということが起こり得るので、目的作業面積に相応する量の洗浄液を含浸させておくということを前提として、たとえば飽和含浸量の70重量%以下程度の量の洗浄液を含浸させておくことが好ましい。 Note that it is not necessarily denied to use a base cloth impregnated with a cleaning liquid in an amount equal to or greater than the saturated impregnation amount. In such a base cloth, air is introduced by squeezing a little before cleaning to remove excess cleaning liquid. It is desirable to improve ease. However, in such a case, it is possible that the cleaning liquid is wasted. Therefore, on the assumption that the cleaning liquid is impregnated in an amount corresponding to the target work area, for example, about 70% by weight or less of the saturated impregnation amount. It is preferable to impregnate the amount of the cleaning liquid.
本発明に係る発泡型洗浄具及び発泡型洗浄方法に用い得る洗浄液は、発泡性に優れた洗浄液として慣用されているアルキルグルコシド系ノニオン性界面活性剤と、第4級アンモニウム塩型カチオン性界面活性剤と、トリメチルシロキシケイ酸を含有するシリコーンエマルジョンと、を主成分として含んでいて、その主成分を水に溶解又は分散させることによって得られる。 The cleaning liquid that can be used in the foam-type cleaning tool and the foam-type cleaning method according to the present invention includes an alkyl glucoside nonionic surfactant commonly used as a cleaning liquid excellent in foamability and a quaternary ammonium salt-type cationic surfactant. And a silicone emulsion containing trimethylsiloxysilicic acid as main components, and obtained by dissolving or dispersing the main components in water.
アルキルグルコシド系ノニオン性界面活性剤の含有量は有効成分濃度で1〜3重量%が適切であって、一般に発泡洗浄用として用いられるものであれば、そのメーカーやグレードについては特に限定されない。また、この成分の一部を、発泡洗浄用として慣用されるその他のノニオン性界面活性剤に置き換えて代用しても構わない。ただし、この場合、塗装やプラスチックなどを害する性質を有するノニオン性界面活性剤で一部代用することは避けるべきである。言い換えると、ノニオン性界面活性剤としてアルキルグルコシド系ノニオン性界面活性剤だけを用いると、塗装やプラスチックなどを害するおそれがないという点で優れている。アルキルグルコシド系ノニオン性界面活性剤の含有量が1重量%より少ないと、洗浄液が泡立ちにくくなって大きなサイズの対象物を洗浄するときの初期から終期にかけての泡立ち性が不足しがちになり、3重量%より多いと、泡立ち性はよいが、洗浄後の水はじき性の被膜を形成することが阻害されることがあるために好ましくない。 The content of the alkyl glucoside nonionic surfactant is appropriately 1 to 3% by weight in terms of active ingredient concentration, and the manufacturer and grade thereof are not particularly limited as long as they are generally used for foam cleaning. Further, a part of this component may be replaced with another nonionic surfactant commonly used for foam cleaning. However, in this case, partial substitution with a nonionic surfactant having a property of detrimental to coating or plastic should be avoided. In other words, the use of only an alkylglucoside nonionic surfactant as the nonionic surfactant is excellent in that there is no possibility of harming the paint or plastic. If the content of the alkyl glucoside nonionic surfactant is less than 1% by weight, the cleaning liquid is less likely to foam, and the foaming property tends to be insufficient from the beginning to the end when washing a large size object. When the amount is more than% by weight, the foaming property is good, but it is not preferable since the formation of a water-repellent coating after washing may be inhibited.
第4級アンモニウム塩型カチオン性界面活性剤は、洗浄後の被膜形成用として含有されている成分であり、その好ましい有効成分濃度は0.5〜2.5重量%である。この第4級アンモニウム塩型カチオン性界面活性剤は、洗浄後の被膜形成用として用い得るのであれば、メーカーやグレードの違いについては特に限定されないけれども、好ましくは、溶解性のよいモノアルキルタイプのもの、特にアルキルがラウリルのように短い鎖長になっているものが適している。第4級アンモニウム塩型カチオン性界面活性剤の含有量が0.5重量%より少ないと、水はじき性を発揮する被膜を満足のいく程度に十分に形成させることができなくなるおそれがあり。2.5重量%より多い場合は、水はじき性の被膜が十分に形成されて性能上の不都合は生じないけれども、当該成分を無駄に含有させることにつながる。すなわち、第4級アンモニウム塩型カチオン性界面活性剤はその含有量が2.5重量%より少なくても水はじき性の被膜が十分に形成されるために無駄な消費を防ぐ上で2.5重量%より少なく抑えることが好ましい。 The quaternary ammonium salt type cationic surfactant is a component contained for forming a film after washing, and the preferred active ingredient concentration is 0.5 to 2.5% by weight. The quaternary ammonium salt type cationic surfactant is not particularly limited as long as it can be used for forming a film after washing, but the difference between manufacturers and grades is not particularly limited. In particular, those in which alkyl has a short chain length such as lauryl are suitable. If the content of the quaternary ammonium salt type cationic surfactant is less than 0.5% by weight, there is a possibility that a film exhibiting water repellency cannot be satisfactorily formed. When the amount is more than 2.5% by weight, a water-repellent film is sufficiently formed and no inconvenience in performance occurs, but the component is contained wastefully. That is, the quaternary ammonium salt type cationic surfactant has a water repellent film sufficiently formed even if its content is less than 2.5% by weight. It is preferable to keep it less than% by weight.
トリメチルシロキシケイ酸を含有するシリコーンエマルジョンは、水はじき被膜用として慣用されるものであれば、メーカーやグレードの違いについては特に限定されない。このシリコーンエマルジョンの好ましい有効成分濃度は0.2〜2重量%であり、0.2重量%より少ないと、洗浄後に形成される被膜の水はじき性が弱くなりやすく、また、2重量%より多いと、上記被膜の水はじき性がよくなる反面で、付着ムラが生じやすくなる。 The silicone emulsion containing trimethylsiloxysilicic acid is not particularly limited in terms of manufacturer and grade as long as it is commonly used for water repellent coating. The preferable active ingredient concentration of this silicone emulsion is 0.2 to 2% by weight, and if it is less than 0.2% by weight, the water repellency of the film formed after washing tends to be weak and more than 2% by weight. On the other hand, the water repellency of the coating is improved, but uneven adhesion tends to occur.
洗浄液には、通常に慣用されるpH調整剤、凍結防止剤、防腐剤、洗浄用溶剤などを必要に応じて添加してもかまわない。 A pH adjuster, antifreezing agent, preservative, cleaning solvent and the like that are commonly used may be added to the cleaning liquid as necessary.
本発明に係る発泡型洗浄具は、上記したクロスなどの基布に上記した洗浄液の飽和含浸量以下の量を含浸させたものである。 The foam-type cleaning tool according to the present invention is obtained by impregnating a base cloth such as cloth described above with an amount equal to or less than the saturated impregnation amount of the cleaning liquid described above.
洗浄作業は、上記発泡型洗浄具の基布で汚れた対象物の表面を直接に軽くこすって拭くことによって行われる。そして、そのような洗浄作業は、基布に含浸されている洗浄液又はその基布から流出した洗浄液を泡立たせながら行う。すなわち、基布で対象物の表面を直接に軽くこすって拭くことによって洗浄液が発泡して泡立ち、高い洗浄効果を発揮する。また、洗浄作業中に水分が消化されて洗浄液が泡立ちにくくなったときには、水を基布又は対象物の表面に補給して泡立ちを回復させるようにすればよく、そのようにすると、再び泡が立つようになる。さらに、網戸などのように泡が立ちにくい対象物や、汚れが極めて多大な対象物の表面等を洗浄する場合、予め、対象物に水をかけて濡らしておくと効果的に発泡して洗浄しやすくなる。
このように作業して泡が立たなくなった時点を効果の終点として作業を終了することができる。そして、この作業の終了後に、対象物の表面に付着している汚れや洗浄液を水ですすぎ、次に水を拭き取って仕上げる。又は、対象物の表面に付着している汚れや洗浄液を湿らせたタオルや布で取って仕上げることもできる。このようにすると、対象物の表面に水はじき性の被膜が形成されて、その表面が洗浄する前よりも水をよくはじくようになる。
The cleaning operation is performed by lightly rubbing and wiping the surface of the object soiled with the base cloth of the foam-type cleaning tool directly. Such a cleaning operation is performed while foaming the cleaning liquid impregnated in the base fabric or the cleaning liquid flowing out of the base fabric. That is, when the surface of the object is lightly rubbed and wiped directly with a base cloth, the cleaning liquid foams and foams, and exhibits a high cleaning effect. In addition, when water is digested during the cleaning operation and the cleaning liquid becomes difficult to foam, it is sufficient to replenish water by replenishing the surface of the base fabric or object, and in such a case, bubbles are again generated. To stand. In addition, when cleaning objects such as screen doors that are difficult to foam or the surface of objects that are extremely dirty, it is effective to foam and clean the objects in advance by moistening them with water. It becomes easy to do.
The work can be finished with the end point of the effect as the end point of the bubbles after working in this way. And after completion | finish of this operation | work, the stain | pollution | contamination and washing | cleaning liquid adhering to the surface of a target object are rinsed with water, and then water is wiped off and it finishes. Alternatively, it can be finished by removing dirt or cleaning liquid adhering to the surface of the object with a damp towel or cloth. In this way, a water-repellent film is formed on the surface of the object, and the surface repels water better than before cleaning.
以上の説明では、本発明に係る発泡型洗浄具や発泡型洗浄方法は、汚れた自動車の塗装やガラス、プラスチック、金属メッキ、タイヤなどの外装部の洗車作業に極めて効果を発揮し、その他のバイクや自転車、家屋、建築物などの家庭用又は産業用などの塗装、ガラス、金属、化粧ボード、石、陶磁器、ゴム製品、プラスチック製品などで、水を吸収しない、もしくは、吸収しても悪い影響が見られない硬質の対象物の表面の洗浄に用いることができる。 In the above description, the foam-type cleaning tool and foam-type cleaning method according to the present invention are extremely effective for dirty automobile painting and car wash work of exterior parts such as glass, plastic, metal plating, tires, etc. Does not absorb water or absorbs water with paint for home or industrial use such as motorcycles, bicycles, houses, buildings, etc., glass, metal, decorative boards, stones, ceramics, rubber products, plastic products, etc. It can be used for cleaning the surface of a hard object that is not affected.
以下に、実施例および比較例を挙げて、本発明を詳細に説明する。なお、本発明は何らこれらに限定されるものではない。
含浸用洗浄液1
成分名 配合割合 重量%
水 88.0
カチオーゲンL 7.0
R2701 1.5
マイドール12 3.0
ノイゲンET−143L 0.5
─────────
100.0
上記成分および配合割合において、水にカチオーゲンL、R2701,マイドール12、ノイゲンET−143Lの順に混合して淡乳白色液体を得た。
含浸用洗浄液2
成分名 配合割合 重量%
水 85.99
カチオーゲンL 4.0
乳酸 0.01
R2701 1.0
マイドール10 5.0
サニゾールB−50 0.5
プロピレングリコール 3.5
─────────
100.0
上記成分および配合割合において、水にカチオーゲンL、乳酸、R2701,マイドール10、サニゾールB−50、プロピレングリコールの順に混合して淡乳白色液体を得た。
含浸用洗浄液3
成分名 配合割合 重量%
水 84.0
カチオーゲンL 1.0
カチオーゲンTMP 2.0
R2701 3.0
プランタケア2000up 5.0
ソルフィット 5.0
─────────
100.0
上記成分および配合割合において、水にカチオーゲンL、カチオーゲンTMP、R2701,プランタケア2000up、ソルフィットの順に混合して淡乳白色液体を得た。
Hereinafter, the present invention will be described in detail with reference to Examples and Comparative Examples. In addition, this invention is not limited to these at all.
Impregnation cleaning solution 1
Ingredient name Mixing ratio Weight%
Water 88.0
Kachiogen L 7.0
R2701 1.5
Mydoll 12 3.0
Neugen ET-143L 0.5
─────────
100.0
In the above components and mixing ratio, water was mixed in the order of Cathogen L, R2701, Mydol 12, Neugen ET-143L to obtain a light milky white liquid.
Impregnation cleaning solution 2
Ingredient name Mixing ratio Weight%
Water 85.99
Kachiogen L 4.0
Lactic acid 0.01
R2701 1.0
Mydoll 10 5.0
SANISOL B-50 0.5
Propylene glycol 3.5
─────────
100.0
In the above components and blending ratio, water was mixed in the order of cationogen L, lactic acid, R2701, mydol 10, sanizol B-50, and propylene glycol to obtain a light milky white liquid.
Impregnation cleaning solution 3
Ingredient name Mixing ratio Weight%
Water 84.0
Kachiogen L 1.0
Kachiogen TMP 2.0
R2701 3.0
Plantacare 2000up 5.0
Solfit 5.0
─────────
100.0
In the above components and mixing ratio, water was mixed in the order of cationogen L, cationogen TMP, R2701, plantacare 2000 up, and solfit to obtain a light milky white liquid.
上記の含浸用洗浄液に用いた原料成分の内容は以下の通りである。
・カチオーゲンL(第4級アンモニウム塩カチオン性界面活性剤)
塩化ラウリルトリメチルアンモニウム 有効成分29%
第一工業製薬(株)製
・カチオーゲンTMP(第4級アンモニウム塩カチオン性界面活性剤)
塩化セチルトリメチルアンモニウム 有効成分29%
第一工業製薬(株)製
・R2701(シリコーンエマルジョン)
トリメチルシロキシケイ酸を含有するシリコーンエマルジョン 有効成分40%
旭化成ワッカーシリコーン(株)製
・マイドール12(アルキルグルコシド系ノニオン性界面活性剤)
ラウリルグルコシド 有効成分40%
花王(株)製
・マイドール10(アルキルグルコシド系ノニオン性界面活性剤)
デシルグルコシド 有効成分40%
花王(株)製
・ノイゲンET−143L(ノニオン性界面活性剤)
ポリオキシエチレンラウリルエーテル 有効成分100%
HLB12.1 第一工業製薬(株)製
・プランタケア2000up(アルキルグルコシド系ノニオン性界面活性剤)
アルキルグルコシド 有効成分50%
コグニスジャパン(株)製
・サニゾールB−50(第4級アンモニウム塩カチオン性界面活性剤)
アルキルベンジルジメチルアンモニウムクロライド 有効成分50%
花王(株)製
・ソルフィット(水溶性洗浄用溶剤)
3−メチル−3−メトキシブタノール 有効成分100%
(株)クラレ製
The contents of the raw material components used in the above-described impregnation cleaning liquid are as follows.
・ Katiogen L (quaternary ammonium salt cationic surfactant)
29% lauryltrimethylammonium chloride active ingredient
Daiichi Kogyo Seiyaku Co., Ltd. ・ Katiogen TMP (quaternary ammonium salt cationic surfactant)
Cetyltrimethylammonium chloride active ingredient 29%
Daiichi Kogyo Seiyaku Co., Ltd. ・ R2701 (silicone emulsion)
Silicone emulsion containing trimethylsiloxysilicic acid 40% active ingredient
Asahi Kasei Wacker Silicone Co., Ltd. ・ Mydol 12 (alkyl glucoside nonionic surfactant)
Lauryl glucoside 40% active ingredient
Made by Kao Corporation ・ Mydol 10 (alkyl glucoside nonionic surfactant)
Decylglucoside 40% active ingredient
・ Keio Co., Ltd. ・ Neugen ET-143L (nonionic surfactant)
Polyoxyethylene lauryl ether 100% active ingredient
HLB12.1 made by Daiichi Kogyo Seiyaku Co., Ltd.
・ Plant Care 2000up (alkyl glucoside nonionic surfactant)
Alkyl glucoside 50% active ingredient
Cognis Japan Co., Ltd. ・ Sanisol B-50 (quaternary ammonium salt cationic surfactant)
Alkylbenzyldimethylammonium chloride 50% active ingredient
Made by Kao Corporation ・ Solfit (water-soluble cleaning solvent)
3-methyl-3-methoxybutanol active ingredient 100%
Made by Kuraray Co., Ltd.
上記の各含浸用洗浄液を下記の通り、各不織布に含浸させた。
洗浄液含浸クロス1
含浸用洗浄液1を:ポリエステルの分割繊維単層の目付70g/m2 、サイズ230mm×600mm、飽和含浸量が基布の6倍重量の不織布(ダイワボウポリテック株式会社製)に基布重量の4倍重量を含浸させ、ラミネートフィルムで包装した。
洗浄液含浸クロス2
含浸用洗浄液2を中層がレーヨン繊維で、外層がスパイラル構造のポリエステル繊維で包んだ構造の目付70g/m2 、サイズ350mm×500mm、飽和含浸量が基布の9倍重量の不織布(ダイワボウポリテック株式会社製)に基布重量の5倍重量を含浸させ、ラミネートフィルムで包装した。
洗浄液含浸クロス3
含浸用洗浄液3を中層がパルプ繊維で、外層がポリエステルの分割繊維で包んだ構造の、目付70g/m2 、サイズ300mm×560mm、飽和含浸量が基布の10倍重量の不織布(ダイワボウポリテック株式会社製)に基布重量の6倍重量を含浸させ、ラミネートフィルムで包装した。
Each nonwoven fabric was impregnated with each of the above impregnation cleaning solutions as follows.
Cleaning liquid impregnated cloth 1
The impregnating cleaning solution 1 is a non-woven fabric (manufactured by Daiwabo Polytech Co., Ltd.) having a weight of 70 g / m @ 2 of a polyester monofilament monolayer, a size of 230 mm.times.600 mm, and a saturated impregnation amount of 6 times the weight of the base fabric. And impregnated with a laminate film.
Cleaning liquid impregnated cloth 2
Nonwoven fabric with a weight per unit area of 70 g / m @ 2, a size of 350 mm.times.500 mm, and a saturated impregnation amount of 9 times the weight of the base fabric. (Daiwabo Polytech Co., Ltd.) Manufactured) was impregnated with 5 times the weight of the base fabric and packaged with a laminate film.
Cleaning liquid impregnated cloth 3
Nonwoven fabric (Daiwabo Polytech Co., Ltd.) having a structure in which the impregnating cleaning liquid 3 is wrapped with pulp fibers in the middle layer and split fibers of the outer layer in polyester, with a basis weight of 70 g / m @ 2, size 300 mm x 560 mm, and saturated impregnation amount 10 times the weight of the base fabric. Manufactured) was impregnated with 6 times the weight of the base fabric and packaged with a laminate film.
上記の各洗浄液含浸クロスを用いて、屋外駐車で汚れた自動車(メーカ/車種:トヨタ/アリオン)に用いて洗浄した。 Each of the cleaning liquid impregnated cloths described above was used to clean an automobile (manufacturer / model: Toyota / Allion) that was soiled in an outdoor parking lot.
比較例として、特許文献2(特開平11−116988号)に記載されている「洗浄剤」に該当する「ソフト99洗うだけ超撥水シャンプー(750mlポリ容器入り液体シャンプー、ウレタンスポンジ付)」と、特許文献3(特開2000−256969号)に記載されている「塗膜の洗浄、撥水、艶出しウエットクロス」に該当する「ソフト99フクピカ(フィルム包装、液含浸不織布タイプウェットクロス)」を取り上げ、本発明の発泡型洗浄具及び発泡型洗浄方法と比較して本発明の効果を実証した。
実施例1〜3(洗浄液含浸クロス1,2,3を用いた洗浄方法)
As a comparative example, “soft 99 washable super water-repellent shampoo (750 ml liquid shampoo in a plastic container, with urethane sponge)” corresponding to “cleaning agent” described in Patent Document 2 (Japanese Patent Laid-Open No. 11-116898) "Soft 99 Fukupika (film packaging, liquid-impregnated non-woven type wet cloth)" corresponding to "Cleaning, water repellency, polishing wet cloth" of Patent Document 3 (Japanese Patent Laid-Open No. 2000-256969) The effect of the present invention was demonstrated in comparison with the foam type cleaning tool and the foam type cleaning method of the present invention.
Examples 1 to 3 (cleaning method using cleaning liquid impregnated cloth 1, 2, 3)
本発明に用いる各洗浄液含浸クロスについては、汚れた自動車のボディに直接用いて泡を立てながら洗浄した。途中泡が立ちにくくなったときに、クロスに少し水を補給して泡を立てながら洗浄した。この洗浄作業に於いて、洗浄作業を行えば自ずから泡が立ち、連続で作業を続けることができ、その後、水ですすぎ、仕上げ拭きを行うことによって自動車一台をきれいに洗うことができた。そして、汚れが落ちてきれいになっただけでなく、水はじき性の被膜が形成された。洗浄後は、使用後のクロスと包装袋をゴミとしてすてるだけで、面倒な洗浄道具や後かたづけが不要になり、楽でスピーディに作業できた。洗浄液含浸クロス1、同2、同3の相互の種類の違いにおいて、泡立ち洗浄作業については差は見られず、R2701の配合割合の違いにより水はじき性に差が見られ、その含有量の多い洗浄液を含浸した含浸クロス3がよく水をはじいた。 Each of the cleaning liquid impregnated cloths used in the present invention was directly used on a dirty automobile body and cleaned while foaming. When it was difficult for bubbles to form on the way, the cloth was washed with a little water added and bubbles were formed. In this cleaning operation, if the cleaning operation was carried out, bubbles naturally formed, and the operation could be continued continuously. Thereafter, the vehicle was rinsed with water and finished by wiping, so that one car could be cleaned cleanly. And not only was the dirt removed, but a water-repellent film was formed. After cleaning, all you need to do is clean the used cloth and packaging bag as trash, eliminating the need for cumbersome cleaning tools and back-fitting, making working easier and faster. In the difference between the types of the cleaning liquid impregnated cloths 1, 2 and 3, there is no difference in the foaming cleaning work, and there is a difference in water repellency due to the difference in the blending ratio of R2701, and the content is large. The impregnated cloth 3 impregnated with the cleaning liquid repelled water well.
比較例1
750mlポリ容器入り液体シャンプーの上記「ソフト99洗うだけ超撥水シャンプー」については、付属のウレタンスポンジを予め水で濡らし、これにシャンプー液を容器から少し移し採り、汚れた自動車のボディに予め水をかけてからボディを洗浄した。作業途中、何回もウレタンスポンジにシャンプー液を容器から移し採り作業を続けた。作業中は、泡立ちが悪いため、すぐシャンプー液を補充するようになり、洗浄作業が手間であった。洗浄後、水ですすぎ、仕上げ拭きをすることによってきれいに洗うことができた。その後には水はじきのよい被膜が形成された。洗浄後、残ったシャンプー液の入った容器のキャップをしっかりしめて保管し、作業に用いて汚れたウレタンスポンジをよく洗って水を切り保管した。作業中のシャンプー液のウレタンスポンジへの補充作業や洗浄用品の取扱いや保管作業など面倒な作業が多かった。
比較例2
ラミネートフィルム包装の不織布含浸タイプの「ソフト99フクピカ」については、包装よりクロスを取り出して汚れた自動車のボディに直接用いて洗浄作業をした。汚れが多いと汚れ落としを満足に行うには難しく、自動車一台につきクロス2枚以上が必要であった。作業中、泡が立つことはなく、洗浄をするというよりか、ワックスを掛ける方の性質が強く、作業中に、汚れとワックスが一体となって手に付着するため、作業後の手洗いがたいへんであった。作業後に、固形ワックスを掛けたような水はじき性のよい持続性のある被膜が形成された。
Comparative Example 1
For the above-mentioned “soft 99 super water-repellent shampoo” for liquid shampoo in a 750 ml plastic container, wet the supplied urethane sponge with water in advance, and transfer the shampoo solution from the container to a dirty car body in advance. After washing, the body was washed. During the work, the shampoo solution was transferred from the container to the urethane sponge and collected several times. During the work, foaming was bad, so the shampoo solution was immediately replenished, and the washing work was troublesome. After washing, it was rinsed with water, and was able to be washed clean by wiping the finish. After that, a water-repellent film was formed. After washing, the cap of the container containing the remaining shampoo solution was securely stored, and the dirty urethane sponge was thoroughly washed for use in the work. There were many troublesome work such as replenishment of urethane shampoo liquid during work and handling and storage of cleaning products.
Comparative Example 2
As for “Soft 99 Fuku Pika” of the nonwoven fabric impregnation type of laminated film packaging, the cloth was taken out from the packaging and directly used on a dirty automobile body for cleaning. When there is a lot of dirt, it is difficult to remove the dirt satisfactorily, and two or more crosses are required for each car. During work, there is no foaming, and it is stronger than waxing rather than washing, and during work, dirt and wax adhere to the hand, so it is difficult to wash hands after work Met. After the work, a long-lasting film having good water repellency such as a solid wax was formed.
なお、官能による評価は下記の基準による。
A.洗浄性
◎日常被っているホコリ、雨跡、泥ハネなどの汚れがよく落ちる。
○日常の汚れは落ちるが作業が面倒である。
△日常の汚れもやや落ちにくいことがたまにある。
×日常の汚れが落ちにくい。
B.泡立ち性
◎作業中よく泡が立つ。
○少し泡立ちが見られる。
△少し泡は見られるが消えやすい。
×全く泡は立たない。
C.作業性
◎スムーズに一気に短時間でできる。
○作業中手間になることがあるが、作業自体スムーズである。
△作業自体が重いが、仕上がりは満足できる。
×作業が重く、仕上がりも悪い。
D.洗浄用具や付属品の取扱いの面倒さ
◎用具や付属品がなく、取扱や作業、管理が楽である。
○用具や付属品はないが、取扱や作業、管理が面倒である。
△用具や付属品があり、面倒であるが、仕上がりよくがまんできる。
×用具や付属品が多く、取扱や作業、管理がたいへん面倒である。
E.洗浄作業によって汚れた手の洗浄性
◎手が汚れにくく、水で簡単に洗うだけでよい。
○手は少し汚れるが、水で洗える。
△汚れ易く、水では落ちにくく、せっけん洗いが必要である。
×汚れが酷く、せっけん洗いを十分にする必要がある。
The sensory evaluation is based on the following criteria.
A. Detergency ◎ Dust, rain marks, mud splashes, etc. that are covered daily are well removed.
○ Daily dirt is removed, but work is troublesome.
△ Occasional dirt is sometimes difficult to remove.
× Daily dirt is difficult to remove.
B. Foaming properties ◎ Foaming often occurs during work.
○ Some bubbling is seen.
△ Some bubbles are seen but easily disappear.
X No bubbles at all.
C. Workability ◎ Smooth and quick in a short time.
○ It may be troublesome during the work, but the work itself is smooth.
△ Work itself is heavy, but the finish is satisfactory.
× Work is heavy and the finish is poor.
D. Troublesome handling of cleaning tools and accessories ◎ There are no tools or accessories, and handling, work, and management are easy.
○ There are no tools or accessories, but handling, work, and management are troublesome.
△ There are tools and accessories, which are cumbersome, but can be finished well.
× There are many tools and accessories, and handling, work, and management are very troublesome.
E. Cleanability of hands soiled by cleaning work ◎ Hands are not easily soiled and can be easily washed with water.
○ Hands get a little dirty but can be washed with water.
△ Easily soiled, difficult to remove with water, requires soap washing.
× The soiling is severe and the soap must be washed thoroughly.
評価 洗浄用具や付属品の 洗浄作業によって
洗浄性 泡立ち性 作業性 取扱いの面倒さ 汚れた手の洗浄性
実施例1 ◎ ◎ ◎ ◎ ◎
実施例2 ◎ ◎ ◎ ◎ ◎
実施例3 ◎ ◎ ◎ ◎ ◎
比較例1 ○ △ ○ × △
比較例2 △ × △ ○ ×
実施例1・・・洗浄液含浸クロス1を用いた。
実施例2・・・洗浄液含浸クロス2を用いた。
実施例3・・・洗浄液含浸クロス3を用いた。
Evaluation By cleaning work of cleaning tools and accessories
Detergency Foamability Workability Troublesome handling Detergent hand detergency Example 1 ◎ ◎ ◎ ◎ ◎
Example 2 ◎ ◎ ◎ ◎ ◎
Example 3 ◎ ◎ ◎ ◎ ◎
Comparative Example 1 ○ △ ○ × △
Comparative Example 2 △ × △ ○ ×
Example 1 A cleaning liquid impregnated cloth 1 was used.
Example 2 A cleaning liquid impregnated cloth 2 was used.
Example 3 A cleaning liquid impregnated cloth 3 was used.
上記の自動車以外に日常の生活の中で汚れたアルミサッシ、網戸、塗装外壁、石外壁、タイル壁、ビニール製壁紙などを上記実施例3による洗浄液含浸クロス3を用いて洗浄した。いずれにおいても洗浄作業中によく泡が立ち、日常の生活の中で被っている埃や汚れをよく落し、その後、水ですすいでも湿らせたタオルで拭き上げても、きれいな状態に仕上げることができて一気に作業することができた。また、作業後、洗浄作業によっで汚れた手も水洗いで簡単に落ち、使用した含浸クロスをゴミとして捨てるだけで後の洗浄用具や付属品の取扱いの面倒がなく、たいへん楽な作業であった。この後、水をかけて観察すると軽い水はじき性が得られていることが判った。以上のように、自動車以外の水を吸収しない、もしくは、吸収しても悪い影響のない家庭用、産業用の硬質の製品にも自動車の場合同様に用いることができた。 In addition to the automobile, aluminum sashes, screen doors, painted outer walls, stone outer walls, tile walls, vinyl wallpaper, etc., which were soiled in daily life, were cleaned using the cleaning liquid impregnated cloth 3 according to Example 3 above. In either case, foaming often occurs during cleaning work, and it removes dust and dirt from everyday life. After that, it can be cleaned with water or wiped with a damp towel. I was able to work at once. In addition, after work, dirty hands can be easily washed with water, and the impregnated cloth used can be discarded as trash, so there is no trouble in handling subsequent cleaning tools and accessories. It was. Thereafter, it was found that light water repellency was obtained by observing with water. As described above, it can be used in the same manner as in the case of automobiles in hard products for household and industrial use that do not absorb water other than automobiles or that do not adversely affect absorption.
Claims (4)
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JP2011030793A (en) * | 2009-07-31 | 2011-02-17 | Daio Paper Corp | Water soluble wet sheet for cleaning |
JP2019163433A (en) * | 2018-03-20 | 2019-09-26 | ライオン株式会社 | Detergent composition |
JP2019182937A (en) * | 2018-04-04 | 2019-10-24 | 株式会社ダイフク | Vehicular coating agent and car washing machine including the same |
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JP2001120485A (en) * | 1999-10-26 | 2001-05-08 | Achilles Corp | Cleaner |
JP2002220568A (en) * | 2001-01-24 | 2002-08-09 | Kao Corp | Material for cleaning and polishing hard surface |
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JPH10147794A (en) * | 1996-11-19 | 1998-06-02 | Soft Kyukyu Corp:Kk | Detergent for automobile |
JPH11116988A (en) * | 1997-10-20 | 1999-04-27 | Soft 99 Corporation:Kk | Detergent composition for automobile |
JP2000256969A (en) * | 1999-03-06 | 2000-09-19 | Soft 99 Corporation:Kk | Wet cloth for cleaning, water-repelling and glazing of coated membrane |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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US20100221417A1 (en) * | 2007-09-14 | 2010-09-02 | Sadaharu Miyamoto | Aqueous cleaning composition for substrate for perpendicular magnetic recording hard disk |
US8901053B2 (en) * | 2007-09-14 | 2014-12-02 | Kao Corporation | Aqueous cleaning composition for substrate for perpendicular magnetic recording hard disk |
JP2011030793A (en) * | 2009-07-31 | 2011-02-17 | Daio Paper Corp | Water soluble wet sheet for cleaning |
JP2019163433A (en) * | 2018-03-20 | 2019-09-26 | ライオン株式会社 | Detergent composition |
JP7133954B2 (en) | 2018-03-20 | 2022-09-09 | ライオン株式会社 | Laundry detergent composition |
JP2019182937A (en) * | 2018-04-04 | 2019-10-24 | 株式会社ダイフク | Vehicular coating agent and car washing machine including the same |
JP7048393B2 (en) | 2018-04-04 | 2022-04-05 | 株式会社ダイフク | Vehicle coating agent and car wash machine using it |
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