JP2008006039A - Carpet - Google Patents

Carpet Download PDF

Info

Publication number
JP2008006039A
JP2008006039A JP2006179026A JP2006179026A JP2008006039A JP 2008006039 A JP2008006039 A JP 2008006039A JP 2006179026 A JP2006179026 A JP 2006179026A JP 2006179026 A JP2006179026 A JP 2006179026A JP 2008006039 A JP2008006039 A JP 2008006039A
Authority
JP
Japan
Prior art keywords
polyethylene
carpet
polyethylene film
film
halogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2006179026A
Other languages
Japanese (ja)
Other versions
JP5138184B2 (en
Inventor
Hiroshi Endo
浩 遠藤
Shinichi Suzuki
真一 鈴木
Tetsuji Saito
徹司 斎藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dynic Corp
Original Assignee
Dynic Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dynic Corp filed Critical Dynic Corp
Priority to JP2006179026A priority Critical patent/JP5138184B2/en
Publication of JP2008006039A publication Critical patent/JP2008006039A/en
Application granted granted Critical
Publication of JP5138184B2 publication Critical patent/JP5138184B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Carpets (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a carpet with the linoleum-like luster/outside appearance and the flame resistant performance satisfying a standard, and suitable for the use in an exhibition or event place. <P>SOLUTION: The carpet has a polyethylene film 2 laminated on the surface of a non-halogen-containing punched carpet structure 1. The carpet is characterized by the quantity of adhesion of polyethylene to the polyethylene film being 80-200 g/m<SP>2</SP>, or preferably, 100-180 g/m<SP>2</SP>, and the MFR value being 25-40 g/10 min. The polyethylene film may be formed from a polyethylene blended material with a different MFR value. The surface of the polyethylene film may be embossed, or may be further laminated with a printed film formed from a non-halogen-containing resin material. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、主として展示会場やイベント会場などで使用するに好適な、光沢感があり且つ防炎性能を有するカーペットに関する。   The present invention relates to a carpet having glossiness and flameproofing performance, which is suitable for use mainly in exhibition halls and event halls.

このような用途としては、従来より塩化ビニル樹脂を使用したもの(リノリウムなど)が多用されてきたが、重量が重いことから巻きメートルが少なく、幅も狭くならざるを得ないため、大面積の施工に多大な手間を要していた。また、塩化ビニル樹脂は燃焼時にダイオキシンや塩化水素などの有毒ガスを発生するため、塩化ビニル樹脂を用いたカーペットは焼却処理することができず、使用後の処理費用がかさむという大きな問題があった。   As such an application, those using vinyl chloride resin (such as linoleum) have been widely used in the past, but because the weight is heavy, there are few winding meters and the width must be narrow, so a large area It took a lot of work to construct. In addition, since vinyl chloride resin generates toxic gases such as dioxin and hydrogen chloride when burned, carpets using vinyl chloride resin cannot be incinerated, resulting in a large problem that the processing cost after use is increased. .

このため、現在では、ポリプロピレンなどのハロゲン非含有樹脂繊維から製造したニードルパンチカーペットが広く普及するに至っている。その一例を非特許文献1として挙げる。
日東紡建材事業部門オンラインカタログ「ダンペット エコナイス」インターネット(URL http://www.nittobo.jp/kw/flooring/danpet en.html)
For this reason, at present, needle punch carpets manufactured from halogen-free resin fibers such as polypropylene have come into widespread use. An example is given as Non-Patent Document 1.
Nittobo Building Materials Division Online Catalog “Damppet Eco-Nice” Internet (URL http://www.nittobo.jp/kw/flooring/danpet en.html)

このようなニードルパンチカーペットは、リノリウムのような表面光沢感がなく、展示会場やイベント会場などで用いる際の外観上の要求を必ずしも満足することができない。   Such a needle punch carpet does not have a glossy surface like linoleum and does not necessarily satisfy the appearance requirements when used in an exhibition hall or an event hall.

また、リノリウム外観を持ちハロゲン非含有樹脂から成るカーペットは、消防法施行規則第4条の3第3項ないし第7項に規定する防炎性能試験基準を満たすことができず、防炎性能が不十分である。   In addition, carpets that have a linoleum appearance and are made of a halogen-free resin cannot meet the flameproof performance test standards stipulated in Article 4-3, Paragraphs 3 to 7 of the Fire Service Act Enforcement Regulations. It is insufficient.

したがって、本発明が解決しようとする課題は、リノリウム様の光沢感・外観を呈することができると共に基準を満たす防炎性能を有し、展示会場やイベント会場などで使用するに好適な、カーペットを提供することである。   Therefore, the problem to be solved by the present invention is to provide a carpet that can exhibit a linoleum-like glossy appearance and has a flameproof performance that meets the standards, and is suitable for use in exhibition halls and event halls. Is to provide.

この課題を解決するため、本発明によるカーペットは、ハロゲン非含有のパンチカーペット構造体の表面にポリエチレン膜をラミネートしたものであって、該ポリエチレン膜におけるポリエチレンの付着量が80〜200g/mであり、MFR値が25〜40g/10minであることを特徴とする(請求項1)。 In order to solve this problem, the carpet according to the present invention is obtained by laminating a polyethylene film on the surface of a halogen-free punch carpet structure, and the polyethylene adhesion amount on the polyethylene film is 80 to 200 g / m 2 . And the MFR value is 25 to 40 g / 10 min (claim 1).

ポリエチレン膜におけるポリエチレンの付着量は、好ましくは100〜180g/mである(請求項2)。 The amount of polyethylene deposited on the polyethylene film is preferably 100 to 180 g / m 2 (Claim 2).

本発明の一つの好適な実施形態によれば、異なるMFR値のポリエチレンの混合材料からポリエチレン膜が形成される(請求項3)   According to one preferred embodiment of the present invention, a polyethylene film is formed from a mixed material of polyethylene having different MFR values (Claim 3).

ポリエチレン膜の表面にさらに、ハロゲン非含有樹脂材料から形成される印刷フィルムをラミネートしても良い(請求項4)。   A print film formed from a halogen-free resin material may be further laminated on the surface of the polyethylene film.

ポリエチレン膜の表面または印刷フィルムの表面にエンボス加工を施しても良い(請求項5)。   The surface of the polyethylene film or the surface of the printing film may be embossed (Claim 5).

本発明のカーペットは、ハロゲン非含有のパンチカーペット構造体の表面にポリエチレン膜をラミネートして成るので、比較的軽量であって施工性に優れ、使用後は焼却により安価で且つ大気汚染の問題を生ずることなく処分可能であり、リノリウム様の光沢感・外観を呈することができ、また、消防法上の基準を満たす防炎性能を確保することができる。   Since the carpet of the present invention is formed by laminating a polyethylene film on the surface of a halogen-free punch carpet structure, it is relatively light and excellent in workability, is inexpensive by incineration after use, and has the problem of air pollution. It can be disposed of without causing linoleum-like gloss and appearance, and it can ensure flameproof performance that meets the standards of the Fire Service Act.

図1は本発明の好適な一実施形態によるカーペットを示し、ハロゲン非含有のパンチカーペット構造体1の表面にポリエチレン膜2がラミネートされている。製法の一例としては、低密度ポリエチレン(LDPE)をTダイにより押し出してポリエチレン膜2を成形すると共に、この押し出し速度に同期した速度であらかじめ作成したパンチカーペット構造体1を移送し、パンチカーペット構造体1上にポリエチレン膜2をラミネートする。ポリエチレン膜2の表面には必要に応じてエンボス加工が施され、リノリウム様の外観により近づけると共に、水ぬれなどの場合に滑り止め効果を与える。   FIG. 1 shows a carpet according to a preferred embodiment of the present invention, in which a polyethylene film 2 is laminated on the surface of a halogen-free punch carpet structure 1. As an example of the manufacturing method, a low-density polyethylene (LDPE) is extruded by a T-die to form a polyethylene film 2, and a punch carpet structure 1 prepared in advance is transferred at a speed synchronized with the extrusion speed. A polyethylene film 2 is laminated on 1. The surface of the polyethylene film 2 is embossed as necessary to bring it closer to the linoleum-like appearance and to provide an anti-slip effect in the case of water wetting.

この実施形態におけるパンチカーペット構造体1は、ポリプロピレンなどの短繊維ウエブから成る層1aと、ポリプロピレン織布などから成る層1bと、ポリプロピレンなどの短繊維層がSBR系樹脂などで裏面コーティングされて成る層1cとを有する3層構造のニードルパンチカーペットとして示されている。なお、パンチカーペット構造体1はこれに限定されるものではなく、単層または任意数の積層構造体であって良く、各層の材料もハロゲン非含有の条件を満たすものであれば特に限定されない。   The punch carpet structure 1 in this embodiment is formed by coating a back surface with a layer 1a made of a short fiber web such as polypropylene, a layer 1b made of a polypropylene woven fabric, and the like, and a short fiber layer made of polypropylene or the like with an SBR resin or the like. It is shown as a three-ply needle punch carpet with layer 1c. The punch carpet structure 1 is not limited to this, and may be a single layer or an arbitrary number of laminated structures, and the material of each layer is not particularly limited as long as it satisfies the halogen-free condition.

パンチカーペット構造体1の表面にポリエチレン膜2をラミネートするに際しては、消防法に規定される基準を上回る防炎性能を確保するよう配慮しなければならない。本発明者による試験研究の結果、ポリエチレン膜2におけるポリエチレンの付着量およびJIS K−7210によるMFR値(Melt Flow Rate、溶融指数)を各々所定の範囲とすることによって所期の防炎性能が得られることが見出された。   When laminating the polyethylene film 2 on the surface of the punch carpet structure 1, consideration must be given to ensuring a flameproof performance exceeding the standards defined in the Fire Service Law. As a result of the test research by the present inventor, the desired flameproof performance is obtained by setting the polyethylene adhesion amount on the polyethylene film 2 and the MFR value (Melt Flow Rate) according to JIS K-7210 within a predetermined range. It was found that

すなわち、図1に示すような3層構造のパンチカーペット構造体1を用い、ポリエチレンの付着量とMFR値を様々に変えてポリエチレン膜2を形成したカーペットについて、防炎性能および耐久性についての試験を行ったところ、表1に示す結果が得られた。なお、パンチカーペット構造体1を作成するに当たっては、織度6.6dtex、織度長76mmのポリプロピレン短繊維100%をカード機により開繊して200g/mの短繊維ウエブを形成した後、その表面から、ポリプロピレンテープヤーン織布を針密度200パンチ/cmのニードルパンチによりラミネートすることにより、表面にポリプロピレン短繊維ウエブから成る層1a、中間にポリプロピレン織布から成る層1b、裏面にはポリプロピレン織布層1bからニードルパンチによって飛び出したポリプロピレン短繊維から成る層を有する3層構造のニードルパンチカーペットを得、その後、裏面にSBR系樹脂をコーティングし乾燥熱処理して、ポリプロピレン短繊維層がSBR系樹脂コーティングされて成る層1cを形成し、図1に示すようなパンチカーペット構造体1を作成した。このパンチカーペット構造体の重量は600g/mであった。 That is, for a carpet in which a polyethylene film 2 is formed by using a three-layer punch carpet structure 1 as shown in FIG. As a result, the results shown in Table 1 were obtained. In preparing the punch carpet structure 1, after forming 100 g of polypropylene short fibers having a weaving degree of 6.6 dtex and a weaving length of 76 mm by a card machine to form a short fiber web of 200 g / m 2 , From the surface, a polypropylene tape yarn woven fabric is laminated by a needle punch having a needle density of 200 punch / cm 2 , so that a layer 1a composed of a polypropylene short fiber web on the surface, a layer 1b composed of a polypropylene woven fabric in the middle, A needle punch carpet having a three-layer structure having a layer made of polypropylene short fibers protruding from the polypropylene woven fabric layer 1b by needle punching is obtained, and then the back surface is coated with an SBR resin and dried and heat-treated. A layer 1c formed by coating with a resin And to prepare a punched carpet structure 1 as shown in FIG. The weight of this punch carpet structure was 600 g / m 2 .

じゅうたん等についての防炎性能試験基準は、消防法施行規則第4条の3第3項ないし第7項を根拠法令として、40×22cmの試験体6体(縦3体、横3体)について、45度エアーミックスバーナー法による試験(火炎長24mm、加熱時間30秒)を行って、残炎時間20秒以下且つ炭化長10cm以下の場合に防炎性能あり(防炎物品)と認められる。上記のようにして作成したパンチカーペット構造体1について、この試験を行ったところ、表1に示す結果が得られた。表1中の○は防炎性能が十分に認められたこと、△は試験体によって防炎性能を満たすものと満たないものがあったこと、×は防炎性能を満たさなかったことをそれぞれ示している。   Fireproof performance test standards for carpets, etc. are based on the laws and regulations of Article 4-3, Paragraphs 3 to 7 of the Fire Service Law Enforcement Regulations for six 40 x 22 cm test specimens (3 vertical and 3 horizontal) When a 45-degree air mix burner test (flame length: 24 mm, heating time: 30 seconds) is performed, if the afterflame time is 20 seconds or less and the carbonization length is 10 cm or less, it is recognized that there is flameproof performance (flameproof article). When this test was performed on the punch carpet structure 1 produced as described above, the results shown in Table 1 were obtained. In Table 1, ◯ indicates that the flameproof performance was sufficiently recognized, △ indicates that there were those that satisfy the flameproof performance depending on the specimen, and × indicates that the flameproof performance was not satisfied. ing.

また、各試験体について、JIS L−1023による耐摩耗性試験において、摩耗輪H−38で1000回摩耗を行い、摩耗減量により評価を行った。表1中の◎は摩耗減量130mg未満、○は摩耗減量130mg以上150mg未満、×は摩耗減量150mg以上であったことをそれぞれ示している。   Moreover, about each test body, in the abrasion resistance test by JISL-1023, it was worn 1000 times with the wear wheel H-38 and evaluated by wear reduction. In Table 1, ◎ indicates that the wear loss is less than 130 mg, ○ indicates that the wear loss is 130 mg or more and less than 150 mg, and x indicates that the wear loss is 150 mg or more.

Figure 2008006039
Figure 2008006039

表1の結果から、ポリエチレン膜2におけるポリエチレンの付着量については、180g/mの場合に最も優れた効果を発揮することが分かった。ポリエチレン付着量についてはあまりに少なすぎると光沢感を現出することができず、JIS L−1023耐摩耗性試験による耐久性に劣るため、その下限値は80g/m、好ましくは100g/m以上であることを要するが、表1にも示されるように、180g/mを超える付着量とするとポリエチレンが燃焼するので、200g/mを上限とする。 From the results in Table 1, it was found that the most excellent effect was exhibited when the amount of polyethylene adhered to the polyethylene film 2 was 180 g / m 2 . When the polyethylene adhesion amount is too small, glossiness cannot be exhibited, and the durability by the JIS L-1023 abrasion resistance test is inferior, so the lower limit is 80 g / m 2 , preferably 100 g / m 2. Although it is necessary to be above, as shown in Table 1, if the adhesion amount exceeds 180 g / m 2 , polyethylene burns, so 200 g / m 2 is the upper limit.

一方、ポリエチレン膜2におけるポリエチレンのMFR値については、MFR値=45g/10minとした場合には付着量を180g/mにしても防炎性能を満たすことができず、MFR値=25g/10minとした場合には付着量180g/mのときに防炎性能が基準を満たすか否かのボーダーラインにあり、MFR値=45g/10minのポリエチレンとMFR値=25g/10minのポリエチレンを混合してポリエチレン膜2を形成した場合(混合割合50:50、混合ポリエチレンとしてのMFR値=38g/10min)には付着量180g/mのときに十分に基準を満たす防炎性能が得られた。このことから、ポリエチレン膜2におけるポリエチレンのMFR値は25〜40g/10minの範囲内であることが必要である。 On the other hand, regarding the MFR value of polyethylene in the polyethylene film 2, when the MFR value = 45 g / 10 min, the flameproof performance cannot be satisfied even if the adhesion amount is 180 g / m 2 , and the MFR value = 25 g / 10 min. In this case, when the adhesion amount is 180 g / m 2 , it is in the borderline whether or not the flameproof performance meets the standard, and polyethylene with MFR value = 45 g / 10 min and polyethylene with MFR value = 25 g / 10 min are mixed. Thus, when the polyethylene film 2 was formed (mixing ratio 50:50, MFR value as mixed polyethylene = 38 g / 10 min), flameproof performance sufficiently satisfying the standard was obtained when the adhesion amount was 180 g / m 2 . For this reason, the MFR value of polyethylene in the polyethylene film 2 needs to be in the range of 25 to 40 g / 10 min.

なお、MFR値はポリエチレン樹脂の流動性を示すところ、MFR値が高すぎると、着火した部分が溶融軟化して隣接部に移動し、着火部分のポリエチレンが少なくなって残炎時間が短くなるものの、着火したポリエチレンが移動した後の隣接部をも発炎させてしまうこととなり、炭化長が長くなってしまうものと推測される。反対にMFR値が低いと、溶融軟化したポリエチレンが移動することによる隣接部の発火は少なくなるものの、ポリエチレン自身が可燃性であることから着火部分での残炎時間が長くなり、その結果として防炎性能が低下するものと推測される。   The MFR value indicates the fluidity of the polyethylene resin. If the MFR value is too high, the ignited part melts and softens and moves to the adjacent part, but the polyethylene in the ignited part decreases and the afterflame time is shortened. Therefore, it is presumed that the adjacent portion after the ignited polyethylene is moved also flares, and the carbonization length becomes long. On the other hand, if the MFR value is low, the ignition of the adjacent part due to the movement of the melt-softened polyethylene is reduced, but since the polyethylene itself is flammable, the afterflame time in the ignition part becomes longer, and as a result, It is estimated that the flame performance is reduced.

また、MFR値=45g/10minのポリエチレンとMFR値=25g/10minのポリエチレンを混合してポリエチレン膜2を形成した場合は、その混合ポリエチレンとしてのMFR値がこれらの中間的な好ましい値となるだけでなく、異なるMFR値を有する2種のポリエチレンの溶融開始温度にずれが生ずることによってさらに防炎性能を向上させる効果が発揮されるものと推測される。   Moreover, when the polyethylene film 2 is formed by mixing polyethylene having an MFR value = 45 g / 10 min and polyethylene having an MFR value = 25 g / 10 min, the MFR value as the mixed polyethylene is only an intermediate preferred value between these. In addition, it is presumed that the effect of further improving the flameproof performance is exhibited by the occurrence of a deviation in the melting start temperatures of two types of polyethylene having different MFR values.

図2は本発明の他の好適な実施形態によるカーペットを示し、ポリエチレン膜2の表面にさらに印刷フィルム3がラミネートされている。印刷フィルム3はポリエチレン、ポリプロピレンなどのハロゲン非含有樹脂材料から形成されるので、この実施形態の場合も、ポリエチレン膜2におけるポリエチレンの付着量およびMFR値が上述の範囲内にあれば、消防法上の防炎性能基準を満たすことができると共に、印刷フィルム3によって任意の意匠性を付与することができる。   FIG. 2 shows a carpet according to another preferred embodiment of the present invention, in which a printing film 3 is further laminated on the surface of the polyethylene film 2. Since the printing film 3 is formed from a halogen-free resin material such as polyethylene and polypropylene, in the case of this embodiment, as long as the polyethylene adhesion amount and the MFR value in the polyethylene film 2 are within the above-mentioned ranges, In addition to satisfying the flameproof performance standard, any design can be imparted by the printed film 3.

なお、図には示されていないが、カーペットを作成後、ディンプル柄やストライプ柄など任意に所望する柄をエンボス加工することができ、この場合の加工条件は適宜選択することができる。   Although not shown in the figure, after creating the carpet, a desired pattern such as a dimple pattern or a stripe pattern can be embossed, and the processing conditions in this case can be selected as appropriate.

本発明の好適な一実施形態によるカーペットを示す積層断面図である。1 is a cross-sectional view illustrating a carpet according to a preferred embodiment of the present invention. 本発明の他の好適な実施形態によるカーペットを示す積層断面図である。FIG. 6 is a cross-sectional view showing a carpet according to another preferred embodiment of the present invention.

符号の説明Explanation of symbols

1 パンチカーペット構造体
2 ポリエチレン膜
3 印刷フィルム
1 Punch carpet structure 2 Polyethylene film 3 Print film

Claims (5)

ハロゲン非含有のパンチカーペット構造体の表面にポリエチレン膜をラミネートしたものであって、該ポリエチレン膜におけるポリエチレンの付着量が80〜200g/mであり、MFR値が25〜40g/10minであることを特徴とするカーペット。 A polyethylene film is laminated on the surface of a halogen-free punch carpet structure, and the polyethylene adhesion amount on the polyethylene film is 80 to 200 g / m 2 and the MFR value is 25 to 40 g / 10 min. Carpet featuring. ポリエチレン膜におけるポリエチレンの付着量が100〜180g/mである、請求項1記載のカーペット。 The carpet of Claim 1 whose adhesion amount of the polyethylene in a polyethylene film is 100-180 g / m < 2 >. 異なるMFR値のポリエチレンの混合材料からポリエチレン膜が形成される、請求項1または2記載のカーペット。 The carpet according to claim 1 or 2, wherein the polyethylene film is formed from a mixed material of polyethylene having different MFR values. ポリエチレン膜の表面にさらに、ハロゲン非含有樹脂材料から形成される印刷フィルムがラミネートされる、請求項1ないし3のいずれか記載のカーペット。 The carpet according to any one of claims 1 to 3, wherein a printed film formed of a halogen-free resin material is further laminated on the surface of the polyethylene film. ポリエチレン膜の表面または印刷フィルムの表面にエンボス加工が施される、請求項1ないし3のいずれか記載のカーペット。 The carpet according to any one of claims 1 to 3, wherein the surface of the polyethylene film or the surface of the printing film is embossed.
JP2006179026A 2006-06-29 2006-06-29 carpet Active JP5138184B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006179026A JP5138184B2 (en) 2006-06-29 2006-06-29 carpet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006179026A JP5138184B2 (en) 2006-06-29 2006-06-29 carpet

Publications (2)

Publication Number Publication Date
JP2008006039A true JP2008006039A (en) 2008-01-17
JP5138184B2 JP5138184B2 (en) 2013-02-06

Family

ID=39064781

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006179026A Active JP5138184B2 (en) 2006-06-29 2006-06-29 carpet

Country Status (1)

Country Link
JP (1) JP5138184B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102846172A (en) * 2012-09-21 2013-01-02 郭心仪 Noctilucent carpet
CN112592533A (en) * 2020-11-25 2021-04-02 浙江万美地毯有限公司 Construction method of carpet surface layer

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH059876A (en) * 1991-07-03 1993-01-19 Lonseal Corp Floor material
JPH0796792A (en) * 1993-09-29 1995-04-11 Hayashi Gijutsu Kenkyusho:Kk Formed laying material and manufacture thereof
JPH08134281A (en) * 1994-11-09 1996-05-28 Nakata Coating:Kk Flame retardant resin composition
JPH11300909A (en) * 1998-04-15 1999-11-02 Nakagawa Chem:Kk Flame retardant resin molded product and method for molding flame retardant resin molded product
JP2002283904A (en) * 2001-03-28 2002-10-03 Suminoe Textile Co Ltd Automobile floor mat

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH059876A (en) * 1991-07-03 1993-01-19 Lonseal Corp Floor material
JPH0796792A (en) * 1993-09-29 1995-04-11 Hayashi Gijutsu Kenkyusho:Kk Formed laying material and manufacture thereof
JPH08134281A (en) * 1994-11-09 1996-05-28 Nakata Coating:Kk Flame retardant resin composition
JPH11300909A (en) * 1998-04-15 1999-11-02 Nakagawa Chem:Kk Flame retardant resin molded product and method for molding flame retardant resin molded product
JP2002283904A (en) * 2001-03-28 2002-10-03 Suminoe Textile Co Ltd Automobile floor mat

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102846172A (en) * 2012-09-21 2013-01-02 郭心仪 Noctilucent carpet
CN112592533A (en) * 2020-11-25 2021-04-02 浙江万美地毯有限公司 Construction method of carpet surface layer

Also Published As

Publication number Publication date
JP5138184B2 (en) 2013-02-06

Similar Documents

Publication Publication Date Title
CN101175881B (en) Non-woven material with barrier skin
US8216660B2 (en) Halogen and plasticizer free permeable laminate
ES2711228T3 (en) Plasterboard coated with non-woven fiberglass mat and manufacturing process
DE60117344D1 (en) FIRE-RESISTANT COMPOSITE PANELS AND THESE USING DECORATIVE FIRE RESISTANT COMPOSITE PANELS
AU2009243456A1 (en) Fabric including low-melting fibre
EP3429841A1 (en) Multi-layered flame retardant and chemical resistant composites and methods of making and using the same
JP5138184B2 (en) carpet
JPH0534921Y2 (en)
JP2014201024A (en) Natural lighting nonflammable sheet
JPWO2005001187A1 (en) Flame-retardant nonwoven fabric and method for producing the same
JP4934848B2 (en) Incombustible or flame retardant insulation resin duct
JP4933183B2 (en) Insulated mat for folded board and insulated folded roof using the same
JP2016166429A (en) Wallpaper and its manufacturing method
JP2004225387A (en) Non-halogen flooring with excellent antistatic property
JP2017180084A (en) House wrap material
US10137662B2 (en) Flexible lightweight arc flash and flash fire resistant polyvinylchloride fabric and garments and methods therefor
JP2004174869A (en) Flame-retardant laminate
JP2017170785A (en) Nonflammable sheet
KR20170010145A (en) eco-friendly flame resisting sheet
JP2002052654A (en) Non-halogen type floor material
JP2002337284A (en) Fire-retardant polyolefinic composite sheet
JP4395877B2 (en) Polyester flame retardant fiber wallpaper
US7094715B2 (en) Non-halogen series floor material
JP6922518B2 (en) Non-combustible decorative board, manufacturing method of non-combustible decorative board
JPH10195774A (en) Flame retardant tarpaulin

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20090324

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20120112

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20120207

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20120406

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20121030

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20121114

R150 Certificate of patent or registration of utility model

Ref document number: 5138184

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20151122

Year of fee payment: 3

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250