JP2006511626A - 粉末塗料におけるメタロセンワックスの用途 - Google Patents
粉末塗料におけるメタロセンワックスの用途 Download PDFInfo
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- JP2006511626A JP2006511626A JP2003584189A JP2003584189A JP2006511626A JP 2006511626 A JP2006511626 A JP 2006511626A JP 2003584189 A JP2003584189 A JP 2003584189A JP 2003584189 A JP2003584189 A JP 2003584189A JP 2006511626 A JP2006511626 A JP 2006511626A
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- Prior art keywords
- wax
- polyolefin
- additives
- polyolefin wax
- additive
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
- C09D123/30—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by oxidation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
- C08L91/08—Mineral waxes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
- バインダー;例えばエポキシド、トリグリシジルイソシアヌレート(TGIC)、β-ヒドロキシアルキルアミンまたはブロックドイソシアネート(ウレトジオン類)を用いて架橋されるポリエステル樹脂;
・ クリヤーラッカーでない限り、顔料および充填剤; 顔料は高い熱安定性を有していなければならない。それらの例にはフタロシアニン類、キナクリドン類、アゾ顔料、ペリレン−およびペリノン顔料、ベンズイミダゾーロン顔料、アントラキノン顔料、イソインドリノン−およびイソインドリン顔料、アントアントロン顔料、ジオキサジン顔料、キノフタロン顔料およびジケトピローロピロール顔料がある。
・ 添加物;例えば脱気剤、艶消し剤、酸化防止剤、潤滑用添加物、展延剤および耐引掻き性向上剤;
で組成されている。
− 摩砕性の改善、
− 噴霧装置およびそれのホースラインでの付着の防止、
− 耐引掻き性の向上、
− 耐磨耗性の向上、
− 顔料成分の分散困難性の改善、
− エフェクト顔料の場合の顔料粒子の配向
− 色強度の向上
− 艶消し効果の取得、
− 感触の改善 (“柔らかな感触”)
− 潤滑性の向上、
− 金属マーキングの改善
− エフェクト顔料の混入性の改善
− 流動特性への影響
− 耐ブロッキング性の改善
− 押出成形過程での脱気(devolatilization)の向上
− 押出成形過程での生産性の向上。
a) ポリエチレングリコール、
b) PE− ワックス、
c) PTFE− ワックス、
d) PP −ワックス、
e) アミドワックス、
f) FT −パラフィン、
g) モンタンワックス、
h) 天然ワックス、
i) マクロ結晶質-および微小結晶質パラフィン、
j) 極性ポリオレフィンワックス、または
k) ソルビタンエステル、
l) ポリアミド、
m) ポリオレフィン、
n) PTFE、
o) 湿潤剤、
p) 珪酸塩。
2) ヨーロッパ特許出願公開第0 890 584号明細書(A)に従って製造
3) ヨーロッパ特許出願公開第0 890 583号明細書(A)に従って製造
*) 環球法による軟化点
V = 比較例
全ての試験体がDV50約8μm に微細化されている。
実施例96 〜120のいずれの場合にも、本発明の試験体は比較例よりも良好な結果 (高い生産量) を示した。
Claims (7)
- 粉末塗料においての添加物としての、メタロセン触媒によって合成されたポリオレフィンワックスの用途。
- ポリオレフィンワックスが炭素原子数3〜6のオレフィンまたはスチレンから誘導されている、請求項1に記載の用途。
- ポリオレフィンワックスが70〜165°Cの滴り点、140°Cで10〜 10, 000 mPa・s の溶融粘度および 0.85〜 0.98 g/cm3の密度を有する、請求項1または2に記載の用途。
- ポリオレフィンワックスが極性変性されている請求項1〜3のいずれか一つに記載の用途。
- ポリオレフィンワックスが以下の
a) ポリエチレングリコール、
b) PE- ワックス、
c) PTFE -ワックス、
d) PP- ワックス、
e) アミドワックス、
f) FT -パラフィン、
g) モンタンワックス、
h) 天然ワックス、
i) マクロ結晶質-および微小結晶質パラフィン、
j) 極性ポリオレフィンワックス、または
k) ソルビタンエステル、
l) ポリアミド、
m) ポリオレフィン、
n) PTFE、
o) 湿潤剤、
p) 珪酸塩
からなる群から選択される1種類以上の助剤および添加物と、ポリオレフィンワックス:助剤および添加物の重量比 1:50〜50:1 (重量%)でブレンドした状態で存在する請求項1〜4のいずれか一つに記載の用途: - ポリオレフィンワックスおよび場合によっては混入された助剤および添加物がd90 < 40 mmの粒度分布を有する超微細粉末として存在する、請求項1〜5のいずれか一つに記載の用途。
- バインダー、顔料および充填剤並びに通例の助剤よりなる粉末塗料を製造する方法において、添加物を請求項1〜6のいずれか一つに記載に従って添加することを特徴とする、上記方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10216118A DE10216118A1 (de) | 2002-04-12 | 2002-04-12 | Verwendung von Metallocenwachsen in Pulverlacken |
PCT/EP2003/003518 WO2003087242A1 (de) | 2002-04-12 | 2003-04-04 | Verwendung von metallocenwachsen in pulverlacken |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006511626A true JP2006511626A (ja) | 2006-04-06 |
JP2006511626A5 JP2006511626A5 (ja) | 2006-05-25 |
Family
ID=29224476
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003584189A Pending JP2006511626A (ja) | 2002-04-12 | 2003-04-04 | 粉末塗料におけるメタロセンワックスの用途 |
Country Status (5)
Country | Link |
---|---|
US (1) | US20050176866A1 (ja) |
EP (1) | EP1497384A1 (ja) |
JP (1) | JP2006511626A (ja) |
DE (1) | DE10216118A1 (ja) |
WO (1) | WO2003087242A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2020090663A (ja) * | 2018-11-22 | 2020-06-11 | 株式会社トウペ | 艶消し粉体塗料組成物および塗装品 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004035837A1 (de) * | 2004-07-23 | 2006-02-16 | Clariant Gmbh | Verwendung von Polyolefinwachsen in Polykondensaten |
DE102004056875A1 (de) * | 2004-11-25 | 2006-06-01 | Clariant Gmbh | Verwendung von polar modifizierten Polyolefinwachsen zur Verbesserung der Haftung von Dichtstoffen auf Pulverlacken |
DE102007022118A1 (de) * | 2007-05-11 | 2008-11-13 | Clariant International Limited | Metallocen-katalysierte Polyolefine in Wachsformulierungen und deren Verwendung für den Genauguss / Feinguss-Prozess |
DE102007028308A1 (de) * | 2007-06-20 | 2008-12-24 | Clariant International Limited | Mikronisierte Wachsmischungen mit reduzierter Staubentwicklung enthaltend Polyethylenglykolverbindungen (PEG) |
DE102009013902A1 (de) * | 2009-03-19 | 2010-09-23 | Clariant International Limited | Verwendung von Copolymerisaten als Additive für Lacke |
US10472487B2 (en) | 2015-12-30 | 2019-11-12 | Greenmantra Recycling Technologies Ltd. | Reactor for continuously treating polymeric material |
WO2017136957A1 (en) | 2016-02-13 | 2017-08-17 | Greenmantra Recycling Technologies Ltd. | Polymer-modified asphalt with wax additive |
AU2017239181B2 (en) | 2016-03-24 | 2020-12-10 | Greenmantra Recycling Technologies Ltd. | Wax as a melt flow modifier and processing aid for polymers |
CA3036136A1 (en) | 2016-09-29 | 2018-04-05 | Greenmantra Recycling Technologies Ltd. | Reactor for treating polystyrene material |
FR3057875B1 (fr) * | 2016-10-24 | 2020-06-12 | Arkema France | Composition auto-adherente pour le revetement de surfaces metalliques |
CN108504007B (zh) * | 2018-04-19 | 2021-01-05 | 苏州诺升功能高分子材料股份有限公司 | 一种聚四氟乙烯/酰胺蜡的复合微粉及其制备方法 |
CN110423498B (zh) * | 2019-09-05 | 2021-10-29 | 安徽省华安进出口有限公司 | 一种haa体系粉末涂料用消光剂及其应用 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19648895A1 (de) * | 1996-11-26 | 1998-05-28 | Clariant Gmbh | Polar modifizierte Polypropylen-Wachse |
ES2227747T3 (es) * | 1997-07-11 | 2005-04-01 | Clariant Gmbh | Utilizacion de ceras de poliolefinas. |
ES2209008T3 (es) * | 1997-07-11 | 2004-06-16 | Clariant Gmbh | Procedimiento para la oxidacion de ceras polietilenicas. |
DE19729833A1 (de) * | 1997-07-11 | 1999-01-14 | Clariant Gmbh | Polypropylenwachs |
DE19750663A1 (de) * | 1997-11-15 | 1999-05-20 | Clariant Gmbh | Verwendung von Polyolefinwachsen in Lösemittelpasten |
DE19860174A1 (de) * | 1998-12-24 | 2000-06-29 | Clariant Gmbh | Polymeroxidate und ihre Verwendung |
DE19960991C1 (de) * | 1999-12-17 | 2001-03-22 | Clariant Gmbh | Formmasse zur Herstellung pulvermetallischer oder keramischer Erzeugnisse |
DE10023441B4 (de) * | 2000-05-12 | 2006-02-09 | Clariant Gmbh | Verwendung von Wachsmischungen für Lacke |
US6761764B2 (en) * | 2000-05-12 | 2004-07-13 | Clariant Gmbh | Use of wax mixtures for coatings |
DE10063422A1 (de) * | 2000-12-20 | 2001-08-02 | Clariant Gmbh | Verwendung von Wachsmischungen für Lacke |
-
2002
- 2002-04-12 DE DE10216118A patent/DE10216118A1/de not_active Withdrawn
-
2003
- 2003-04-04 WO PCT/EP2003/003518 patent/WO2003087242A1/de not_active Application Discontinuation
- 2003-04-04 JP JP2003584189A patent/JP2006511626A/ja active Pending
- 2003-04-04 US US10/511,358 patent/US20050176866A1/en not_active Abandoned
- 2003-04-04 EP EP03718731A patent/EP1497384A1/de not_active Withdrawn
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2020090663A (ja) * | 2018-11-22 | 2020-06-11 | 株式会社トウペ | 艶消し粉体塗料組成物および塗装品 |
Also Published As
Publication number | Publication date |
---|---|
EP1497384A1 (de) | 2005-01-19 |
WO2003087242A1 (de) | 2003-10-23 |
DE10216118A1 (de) | 2004-04-22 |
US20050176866A1 (en) | 2005-08-11 |
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