JP2006096699A - Foamy detergent composition - Google Patents
Foamy detergent composition Download PDFInfo
- Publication number
- JP2006096699A JP2006096699A JP2004284453A JP2004284453A JP2006096699A JP 2006096699 A JP2006096699 A JP 2006096699A JP 2004284453 A JP2004284453 A JP 2004284453A JP 2004284453 A JP2004284453 A JP 2004284453A JP 2006096699 A JP2006096699 A JP 2006096699A
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- Prior art keywords
- formula
- foam
- group
- carbon atoms
- component
- Prior art date
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- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 37
- 239000003599 detergent Substances 0.000 title claims abstract description 25
- 239000006260 foam Substances 0.000 claims abstract description 95
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 31
- 239000000194 fatty acid Substances 0.000 claims abstract description 31
- 229930195729 fatty acid Natural products 0.000 claims abstract description 31
- -1 fatty acid salt Chemical class 0.000 claims abstract description 29
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 32
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 238000004140 cleaning Methods 0.000 claims description 16
- 150000001340 alkali metals Chemical group 0.000 claims description 15
- 229910052783 alkali metal Inorganic materials 0.000 claims description 14
- 125000002252 acyl group Chemical group 0.000 claims description 10
- 150000001342 alkaline earth metals Chemical group 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 7
- 150000001408 amides Chemical class 0.000 claims description 6
- 229960003237 betaine Drugs 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- LWLHCZLCSDUDEL-UHFFFAOYSA-O C[N+](C)(C)CC(O)=P(=O)CCOC(=O)C=C Chemical compound C[N+](C)(C)CC(O)=P(=O)CCOC(=O)C=C LWLHCZLCSDUDEL-UHFFFAOYSA-O 0.000 claims description 3
- 239000002585 base Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 abstract description 29
- 238000005187 foaming Methods 0.000 abstract description 28
- 230000014759 maintenance of location Effects 0.000 abstract description 19
- 238000003860 storage Methods 0.000 abstract description 17
- 238000002156 mixing Methods 0.000 abstract description 8
- 239000004094 surface-active agent Substances 0.000 abstract description 7
- 229920001577 copolymer Polymers 0.000 abstract description 5
- 210000002374 sebum Anatomy 0.000 abstract description 5
- 229920001519 homopolymer Polymers 0.000 abstract description 2
- 239000012459 cleaning agent Substances 0.000 description 24
- 150000004665 fatty acids Chemical class 0.000 description 20
- 238000011156 evaluation Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 11
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 10
- 238000001035 drying Methods 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 8
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 8
- 239000003760 tallow Substances 0.000 description 7
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 239000005642 Oleic acid Substances 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000005639 Lauric acid Substances 0.000 description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 235000015278 beef Nutrition 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 5
- 235000019865 palm kernel oil Nutrition 0.000 description 5
- 239000003346 palm kernel oil Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZSZRUEAFVQITHH-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 2-(trimethylazaniumyl)ethyl phosphate Chemical compound CC(=C)C(=O)OCCOP([O-])(=O)OCC[N+](C)(C)C ZSZRUEAFVQITHH-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 235000021313 oleic acid Nutrition 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 150000004671 saturated fatty acids Chemical class 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 3
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 3
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- 239000004475 Arginine Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 239000004472 Lysine Substances 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N alpha-Methyl-n-butyl acrylate Natural products CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 2
- ZXVOCOLRQJZVBW-UHFFFAOYSA-N azane;ethanol Chemical compound N.CCO ZXVOCOLRQJZVBW-UHFFFAOYSA-N 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 229960004488 linolenic acid Drugs 0.000 description 2
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 125000002560 nitrile group Chemical group 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
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- 235000003441 saturated fatty acids Nutrition 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
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- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
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- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
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- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
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- 230000007794 irritation Effects 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229940049920 malate Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- VVGIYYKRAMHVLU-UHFFFAOYSA-N newbouldiamide Natural products CCCCCCCCCCCCCCCCCCCC(O)C(O)C(O)C(CO)NC(=O)CCCCCCCCCCCCCCCCC VVGIYYKRAMHVLU-UHFFFAOYSA-N 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005064 octadecenyl group Chemical group C(=CCCCCCCCCCCCCCCCC)* 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229950004354 phosphorylcholine Drugs 0.000 description 1
- PYJNAPOPMIJKJZ-UHFFFAOYSA-N phosphorylcholine chloride Chemical compound [Cl-].C[N+](C)(C)CCOP(O)(O)=O PYJNAPOPMIJKJZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 125000005063 tetradecenyl group Chemical group C(=CCCCCCCCCCCCC)* 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
本発明は、泡立ち、泡の保持性、泡質に優れ、すすぎ時の泡切れがよく、洗浄後にぬめり感がなく、さっぱりと洗い上がり、乾燥後にはつっぱり感が残らないとともに、メイクや皮脂等に対する洗浄力に優れ、保存安定性にも優れる泡状洗浄剤組成物に関する。 The present invention is excellent in foaming, foam retention, foam quality, good defoaming at the time of rinsing, no slimy feeling after washing, freshly washed up, no feeling of tension after drying, makeup, sebum, etc. It is related with the foam detergent composition which is excellent in the detergency with respect to water, and is excellent in storage stability.
従来、洗浄料（洗浄剤）は使用時に水やお湯を加えて、手やタオルで泡立てて使用されてきたが、近年では、トリガー式、スクイズ式、エアゾール式又はポンプ式等のフォーマー容器から吐出させ、起泡させて用いる泡状洗浄剤が使用されている。このフォーマー容器は、洗浄剤を空気と混合し、泡生成手段（例えば、多孔体）を通過させることにより、泡沫として吐出するものである。 Conventionally, cleaning agents (cleaning agents) have been used by adding water or hot water and foaming with hands or towels when used, but in recent years they have been discharged from former containers such as trigger type, squeeze type, aerosol type or pump type. A foam-like cleaning agent that is used after foaming is used. This former container mixes a cleaning agent with air and discharges it as a foam by passing a foam production | generation means (for example, porous body).
しかし、泡状洗浄剤において、泡立ち、泡の保持性及び泡質に優れ、さらに洗浄後の使用感にも優れた泡沫を得ることは容易ではない。例えば、泡立ちを向上させるべく多量の界面活性剤を配合した場合には洗浄剤の粘性が上がり、フォーマー容器による泡立て（起泡）に支障が生じる場合がある。一方、このような不具合を軽減するために洗浄剤の粘性を下げるべく多量の溶剤を配合した場合には、泡の保持性、泡質が悪くなり、洗浄後にぬめり感が生じる等の問題がある。 However, it is not easy to obtain a foam having excellent foaming, foam retention and foam quality, and excellent usability after washing. For example, when a large amount of a surfactant is blended to improve foaming, the viscosity of the cleaning agent increases, which may hinder foaming (foaming) by the former container. On the other hand, when a large amount of solvent is blended in order to reduce the viscosity of the cleaning agent in order to reduce such problems, there is a problem that the foam retention and foam quality are deteriorated and a slimy feeling is generated after washing. .
下記特許文献１には、エーテルリン酸塩と一価アルコール、多価アルコールを配合し、泡質や吐出し後の泡保持性を改良した泡状洗浄剤が、また、下記特許文献２及び下記特許文献３には、アミノ酸系界面活性剤や脂肪酸塩を特定量配合することで泡質を改良した泡状洗浄剤が提案されている。しかしながら、これら洗浄剤の泡質や泡の持続性は充分に改良されているとは言い難く、洗浄後のぬめり感や乾燥後のつっぱり感を有し、また、泡切れや洗浄後のさっぱり感も充分でなかった。 The following Patent Document 1 includes a foam cleaning agent in which ether phosphate, monohydric alcohol, and polyhydric alcohol are blended to improve foam quality and foam retention after discharge. Patent Document 3 proposes a foam cleaning agent having improved foam quality by blending a specific amount of an amino acid surfactant or a fatty acid salt. However, it is difficult to say that the foam quality and foam persistence of these cleaning agents are sufficiently improved. They have a slimy feeling after washing and a feeling of tension after drying. Was not enough.
一方、下記特許文献４及び下記特許文献５には、脂肪酸のトリエタノールアミン塩とこれ以外の塩を配合する、或いは、アミノ酸系界面活性剤と塩をそれぞれ配合することにより、低温での使用性（低温でのフォーマー容器による泡立ち性）を改良した泡状洗浄剤が提案されているが、これらの洗浄剤も、泡質、泡の持続性は充分でなく、また、洗浄後のぬめり感や乾燥後のつっぱり感を有し、泡切れや洗浄後のさっぱり感も充分でなかった。また、これらの泡状洗浄剤組成物は低温下での保存安定性やメイク等の汚れに対する洗浄力が充分でなかった。
また、下記特許文献６及び下記特許文献７には、フォーマー容器自体を改良することにより、洗浄剤の起泡のしやすさや泡質等を改善することが試みられているが、洗浄力や洗浄時（使用時）および使用後の感触の問題を解消することはできなかった。
Further, in Patent Document 6 and Patent Document 7 below, attempts have been made to improve the foaming ease and foam quality of the cleaning agent by improving the former container itself. The problem of touch at the time (during use) and after use could not be solved.
本発明は上記事情に鑑み成されたもので、その解決しようとする課題は、泡立ち、泡の保持性及び泡質に優れ、すすぎ時の泡切れが良く、洗浄後にぬめり感がなく、さっぱりと洗い上がり、乾燥後にはつっぱり感が残らないとともに、メイクや皮脂等に対する洗浄力に優れ、保存安定性にも優れる泡状洗浄剤組成物を提供することである。 The present invention has been made in view of the above circumstances, and the problems to be solved are excellent in foaming, foam retention and foam quality, good in foaming at the time of rinsing, no slimy feeling after washing, and refreshing An object of the present invention is to provide a foam detergent composition that does not leave a feeling of tension after being washed and dried, has an excellent detergency for makeup, sebum and the like, and also has excellent storage stability.
本発明者等は、上記課題を解決すべく鋭意研究を重ねた結果、脂肪酸塩、特定の両性界面活性剤及び特定の陰イオン性界面活性剤を特定割合で混合した特定の界面活性剤混合物を、特定の多価アルコールと特定の割合で組み合わせて得られる組成物によれば、上記の課題を解決し得ることを見出し、本発明を完成させた。 As a result of intensive studies to solve the above problems, the present inventors have obtained a specific surfactant mixture in which a fatty acid salt, a specific amphoteric surfactant and a specific anionic surfactant are mixed at a specific ratio. The present inventors have found that the above-mentioned problems can be solved by using a composition obtained by combining a specific polyhydric alcohol and a specific ratio, and thus completed the present invention.
すなわち、本発明は以下の通りである。
［１］下記のａを１〜１０重量％、ｂを０．５〜５重量％、ｃを０．１〜３重量％、ｄを２〜２０重量％含有し、ａ、ｂ及びｃの合計含有量（ａ＋ｂ＋ｃ）が３〜１２重量％、ａの含有量とｂとｃの合計含有量との重量比（ａ／（ｂ＋ｃ））が１／１〜１０／１、ａ、ｂ及びｃの合計含有量とｄの含有量との重量比（（ａ＋ｂ＋ｃ）／ｄ）が１／５〜１／１である、泡状洗浄剤組成物。
ａ．炭素数１２〜２２の脂肪酸塩
ｂ．式（１）：
That is, the present invention is as follows.
[1] 1 to 10 wt% of the following, b is 0.5 to 5 wt%, c is 0.1 to 3 wt%, d is 2 to 20 wt%, and a total of a, b and c The content (a + b + c) is 3 to 12% by weight, the weight ratio of the content of a to the total content of b and c (a / (b + c)) is 1/1 to 10/1, a, b and c The foam detergent composition whose weight ratio ((a + b + c) / d) of the total content and the content of d is 1/5 to 1/1.
a. Fatty acid salt having 12 to 22 carbon atoms b. Formula (1):
（式中のＲ１は炭素数８〜２０のアシル基を示す。）
で示されるアミドベタイン型両性界面活性剤、
式（２）：
(R 1 in the formula represents an acyl group having 8 to 20 carbon atoms.)
An amide betaine amphoteric surfactant represented by
Formula (2):
（式中のＲ２は炭素数８〜２０のアルキル基又はアルケニル基を示し、Ｍ１、Ｍ２は水素原子又はアルカリ金属原子を示す。ｍおよびｎはそれぞれ１〜３の整数を示す。）
で示されるアルキルアミノジカルボン酸型両性界面活性剤及び
式（３）：
(R 2 in the formula represents an alkyl group or alkenyl group having 8 to 20 carbon atoms, M 1 and M 2 represent a hydrogen atom or an alkali metal atom, and m and n each represents an integer of 1 to 3)
An alkylaminodicarboxylic acid type amphoteric surfactant represented by formula (3):
（式中のＲ３は炭素数８〜２０のアシル基を示し、Ｍ３は水素原子、アルカリ金属原子、１／２アルカリ土類金属原子、アンモニウム、有機アンモニウム又は塩基性アミノ酸陽イオン基を示す。）
で示されるアミドアミノ酸型両性界面活性剤の中から選ばれる１種又は２種以上
ｃ．式（４）：
(In the formula, R 3 represents an acyl group having 8 to 20 carbon atoms, and M 3 represents a hydrogen atom, an alkali metal atom, a 1/2 alkaline earth metal atom, ammonium, an organic ammonium, or a basic amino acid cation group. .)
1 or 2 or more types selected from amide amino acid type amphoteric surfactants represented by c. Formula (4):
（式中、Ｒ４は炭素数８〜２０のアシル基、Ｒ５は炭素数１〜３のアルキル基、Ｍ４はアルカリ金属原子、１／２アルカリ土類金属原子、アンモニウム、有機アンモニウム又は塩基性アミノ酸陽イオン基を示す。）
で示されるアシルアルキルタウリン塩型陰イオン性界面活性剤
ｄ．炭素数２〜６の２価アルコール
［２］さらに、下記ｅを０．００１〜１重量％含有する、上記 [１]記載の泡状洗浄剤組成物。
ｅ．式（５）：
(In the formula, R 4 is an acyl group having 8 to 20 carbon atoms, R 5 is an alkyl group having 1 to 3 carbon atoms, M 4 is an alkali metal atom, 1/2 alkaline earth metal atom, ammonium, organic ammonium or base. An amino acid cationic group.)
An acylalkyl taurine salt type anionic surfactant represented by d. C2-C6 dihydric alcohol [2] The foam cleaning composition according to [1] above, further containing 0.001 to 1% by weight of the following e.
e. Formula (5):
（式中Ｒ６は水素原子又はメチル基、Ｒ７、Ｒ８及びＲ９は炭素数１〜８のアルキル基、ｐは２〜４の整数である。）
で示される２−（メタ）アクリロイルオキシエチルホスホリルコリン由来の構成単位Ａ及び（メタ）アクリル酸アルキルエステル由来の構成単位Ｂを１００／０〜１０／９０（Ａ／Ｂ）の重量比で含有し、これら構成単位の含有量が６０〜１００重量％であるポリマー
(Wherein R 6 is a hydrogen atom or a methyl group, R 7 , R 8 and R 9 are alkyl groups having 1 to 8 carbon atoms, and p is an integer of 2 to 4)
A structural unit A derived from 2- (meth) acryloyloxyethyl phosphorylcholine and a structural unit B derived from (meth) acrylic acid alkyl ester represented by a weight ratio of 100/0 to 10/90 (A / B), Polymer in which content of these structural units is 60 to 100% by weight
本発明でいう「泡状洗浄剤組成物」とは、フォーマー容器から吐出させることで起泡して泡状となり、該泡状の状態で使用する洗浄剤組成物のことであり、「起泡性洗浄剤組成物」とも呼ばれるものである。 The “foamed detergent composition” as used in the present invention is a detergent composition that is foamed by being discharged from a former container and becomes foamed, and is used in the foamed state. This is also referred to as a “cleaning detergent composition”.
本発明の泡状洗浄剤組成物は、泡立ち、泡の保持性及び泡質の何れもが良好で、しかも、すすぎ時の泡切れがよく、洗浄後の肌のぬめり感がなく、かつ、つっぱらずにさっぱりと洗い上げるとともに、メイクや皮脂等の汚れを落とす効果に優れ、さらに保存安定性にも優れるという、効果を奏する。 The foam detergent composition of the present invention is good in foaming, foam retention and foam quality, has good foam breakage during rinsing, does not feel slimy after washing, and It has the effect of washing cleanly and excelling in removing dirt such as makeup and sebum, and also having excellent storage stability.
以下、本発明をより詳細に説明する。
本発明の泡状洗浄剤組成物（以下、単に「洗浄剤」とも略称する。）に使用されるａ成分は炭素数１２〜２２の脂肪酸塩である。当該脂肪酸塩は、直鎖若しくは分岐鎖状の飽和若しくは不飽和の炭素数が１２〜２２の脂肪酸の塩であり、炭素数が同一の単一化合物（単一脂肪酸）の塩であっても、炭素数が異なる化合物の混合物よりなる混合脂肪酸の塩であってもよい。
炭素数が１２〜２２の脂肪酸としては、例えば、飽和脂肪酸としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸等が挙げられ、不飽和脂肪酸としては、パルミトオレイン酸、オレイン酸、エライジン酸、リノール酸、リノレン酸等が挙げられ、混合脂肪酸としては、牛脂脂肪酸、硬化牛脂脂肪酸等が挙げられる。当該脂肪酸は炭素数１２〜１８のものがより好ましい。
脂肪酸塩を形成するアルカリ化合物としてはアルカリ金属原子、１／２アルカリ土類金属原子、アンモニウム、有機アンモニウム又は塩基性アミノ酸陽イオン基が挙げられる。アルカリ金属原子としては、例えばリチウム、ナトリウム、カリウム等が挙げられ、１／２アルカリ土類金属原子としては、１／２カルシウム、１／２マグネシウムが挙げられ、有機アンモニウムとしては、モノエタノールアンモニウム、ジエタノールアンモニウム、トリエタノールアンモニウムが挙げられ、塩基性アミノ酸陽イオン基としては、リジンの陽イオン性残基、アルギニンの陽イオン性残基が挙げられる。好ましくはナトリウム、カリウム又はトリエタノールアミンである。
当該ａ成分の脂肪酸塩は１種又は２種以上が使用される。
Hereinafter, the present invention will be described in more detail.
The component a used in the foam cleaning composition of the present invention (hereinafter also simply referred to as “cleaning agent”) is a fatty acid salt having 12 to 22 carbon atoms. The fatty acid salt is a salt of a linear or branched saturated or unsaturated fatty acid having 12 to 22 carbon atoms, and even a single compound (single fatty acid) having the same carbon number, It may be a salt of a mixed fatty acid composed of a mixture of compounds having different carbon numbers.
Examples of fatty acids having 12 to 22 carbon atoms include lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid and the like as saturated fatty acids, and palmitic oleic acid and oleic acid as unsaturated fatty acids. , Elaidic acid, linoleic acid, linolenic acid and the like, and examples of the mixed fatty acid include beef tallow fatty acid and hardened tallow fatty acid. More preferably, the fatty acid has 12 to 18 carbon atoms.
Alkali compounds that form fatty acid salts include alkali metal atoms, 1/2 alkaline earth metal atoms, ammonium, organic ammonium, or basic amino acid cation groups. Examples of the alkali metal atom include lithium, sodium, potassium and the like. Examples of the ½ alkaline earth metal atom include ½ calcium and ½ magnesium. Examples of the organic ammonium include monoethanol ammonium, Examples of the basic amino acid cationic group include a lysine cationic residue and an arginine cationic residue. Sodium, potassium or triethanolamine is preferred.
1 type (s) or 2 or more types are used for the fatty acid salt of the said a component.
本発明で使用するｂ成分は、前記の式（１）で示されるアミドベタイン型両性界面活性剤、前記の式（２）で示されるアルキルアミノジカルボン酸型両性界面活性剤及び前記の式（３）で示されるアミドアミノ酸型両性界面活性剤の中から選ばれる１種又は２種以上である。 The component b used in the present invention includes an amide betaine type amphoteric surfactant represented by the above formula (1), an alkylaminodicarboxylic acid type amphoteric surfactant represented by the above formula (2), and the above formula (3). ) Or one or more selected from amide amino acid type amphoteric surfactants represented by
式（１）で示されるアミドベタイン型両性界面活性剤において、式中のＲ１は炭素数８〜２０のアシル基であり、直鎖状でも分岐鎖状でもよく、また、飽和でも不飽和でもよい。例えば、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸等の飽和脂肪酸、パルミトオレイン酸、オレイン酸、エライジン酸、リノール酸、リノレン酸等の不飽和脂肪酸、ヤシ油脂肪酸、パーム核油脂肪酸、牛脂脂肪酸、硬化牛脂脂肪酸等の混合脂肪酸の残基が挙げられ、中でも、ラウリン酸、ミリスチン酸、オレイン酸、ヤシ油脂肪酸、パーム核油脂肪酸、牛脂脂肪酸の残基が好ましい。該アシル基の炭素数が８未満であると、洗浄剤の起泡性が悪くなり、また、炭素数が２０を超えると、洗浄剤の安定性が悪くなる。当該アミドベタイン型両性界面活性剤は１種を使用しても、２種以上を併用してもよい。 In the amide betaine amphoteric surfactant represented by the formula (1), R 1 in the formula is an acyl group having 8 to 20 carbon atoms, which may be linear or branched, and may be saturated or unsaturated. Good. For example, saturated fatty acids such as caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, unsaturated fatty acids such as palmitooleic acid, oleic acid, elaidic acid, linoleic acid, linolenic acid, palm Residues of mixed fatty acids such as oil fatty acid, palm kernel oil fatty acid, beef tallow fatty acid, hardened beef tallow fatty acid are mentioned, among others, residues of lauric acid, myristic acid, oleic acid, palm oil fatty acid, palm kernel oil fatty acid, beef tallow fatty acid Is preferred. When the carbon number of the acyl group is less than 8, the foaming property of the cleaning agent is deteriorated, and when the carbon number exceeds 20, the stability of the cleaning agent is deteriorated. The amide betaine amphoteric surfactant may be used alone or in combination of two or more.
式（２）で示されるアルキルアミノジカルボン酸型両性界面活性剤において、式中のＲ２は炭素数８〜２０のアルキル基又はアルケニル基であり、直鎖状でも分岐鎖状でもよい。例えば、オクチル基、ノニル基、デシル基、ウンデシル基、ドデシル基、トリデシル基、テトラデシル基、ペンタデシル基、ヘキサデシル基、ヘプタデシル基、オクタデシル基、イソオクタデシル基、ノナデシル基、エイコシル基等のアルキル基；テトラデセニル基、ヘキサデセニル基、オクタデセニル基、イソオクタデセニル基、エイコセニル基等のアルケニル基；およびヤシ油アルキル基、パーム核油アルキル基、牛脂アルキル基等の混合アルキル基等が挙げられ、これらの中でも炭素数１２〜１８のものが好ましい。炭素数が８未満の場合、洗浄剤の起泡性および泡質が悪くなり、炭素数が２０を超えると洗浄剤の保存安定性が悪くなる。
また、式（２）中のＭ１とＭ２は水素原子又はアルカリ金属原子であり、アルカリ金属原子としては、カリウム、ナトリウム等が挙げられる。好ましくは水素原子又はナトリウムである。Ｍ１とＭ２は同一でも、異なっていてもよい。また、式（２）中のｍおよびｎは１〜３の整数であり、好ましくは１ないし２の整数であり、より好ましくはｍ、ｎがともに１である。ｍ、ｎの少なくとも一方が０の場合は洗浄剤の安定性が悪くなり、ｍ、ｎの少なくとも一方が３を超える場合は洗浄剤の泡質が悪くなる。
当該アルキルアミノジカルボン酸型両性界面活性剤１種を使用しても、２種以上を併用してもよい。
In the alkylaminodicarboxylic acid type amphoteric surfactant represented by the formula (2), R 2 in the formula is an alkyl group or alkenyl group having 8 to 20 carbon atoms, and may be linear or branched. For example, alkyl groups such as octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, isooctadecyl group, nonadecyl group, eicosyl group, etc .; tetradecenyl Groups, hexadecenyl groups, octadecenyl groups, isooctadecenyl groups, eicocenyl groups and other alkenyl groups; and coconut oil alkyl groups, palm kernel oil alkyl groups, mixed alkyl groups such as tallow alkyl groups, and the like. Those having 12 to 18 carbon atoms are preferred. When the carbon number is less than 8, the foamability and foam quality of the cleaning agent are deteriorated, and when the carbon number exceeds 20, the storage stability of the cleaning agent is deteriorated.
Further, M 1 and M 2 in formula (2) is a hydrogen atom or an alkali metal atom, the alkali metal atom, potassium, sodium and the like. Preferably it is a hydrogen atom or sodium. M 1 and M 2 may be the same or different. In the formula (2), m and n are integers of 1 to 3, preferably an integer of 1 to 2, and more preferably m and n are both 1. When at least one of m and n is 0, the stability of the cleaning agent is deteriorated, and when at least one of m and n exceeds 3, the foam quality of the cleaning agent is deteriorated.
The alkylaminodicarboxylic acid type amphoteric surfactant may be used alone or in combination of two or more.
式（３）で示されるアミドアミノ酸型両性界面活性剤において、式中のＲ３は炭素数８〜２０のアシル基であり、直鎖状でも分岐鎖状でもよく、また、飽和でも不飽和でもよい。具体例としては、式（１）のＲ１と同様のものが挙げられ、中でも、ラウリン酸、ミリスチン酸、オレイン酸、ヤシ油脂肪酸、パーム核油脂肪酸等の残基が好ましい。炭素数が８未満の場合、洗浄剤による洗浄後の感触が悪くなり、炭素数が２０を超えると洗浄剤の起泡性が悪くなる。
また、式（３）中のＭ３は水素原子、アルカリ金属原子、１／２アルカリ土類金属原子、アンモニウム、有機アンモニウム又は塩基性アミノ酸陽イオン基であり、アルカリ金属原子としては、例えばリチウム、ナトリウム、カリウム等が挙げられ、１／２アルカリ土類金属原子としては、例えば１／２カルシウム、１／２マグネシウムが挙げられ、有機アンモニウムとしては、例えばモノエタノールアンモニウム、ジエタノールアンモニウム、トリエタノールアンモニウムが挙げられ、塩基性アミノ酸陽イオン基としては、例えばリジンの陽イオン性残基、アルギニンの陽イオン性残基が挙げられる。好ましくはアルカリ金属原子であり、特に好ましくはナトリウム、カリウムである。
当該アミドアミノ酸型両性界面活性剤は１種を使用しても、２種以上を併用してもよい。
In the amide amino acid type amphoteric surfactant represented by the formula (3), R 3 in the formula is an acyl group having 8 to 20 carbon atoms, which may be linear or branched, and may be saturated or unsaturated. Good. Specific examples include those similar to R 1 in formula (1), and among these, residues such as lauric acid, myristic acid, oleic acid, coconut oil fatty acid, and palm kernel oil fatty acid are preferred. When the number of carbon atoms is less than 8, the feel after cleaning with the cleaning agent is deteriorated, and when the number of carbon atoms exceeds 20, the foaming property of the cleaning agent is deteriorated.
M 3 in the formula (3) is a hydrogen atom, an alkali metal atom, a 1/2 alkaline earth metal atom, ammonium, an organic ammonium or a basic amino acid cation group. Examples of the alkali metal atom include lithium, Examples of the ½ alkaline earth metal atom include ½ calcium and ½ magnesium. Examples of the organic ammonium include monoethanol ammonium, diethanol ammonium, and triethanol ammonium. Examples of the basic amino acid cationic group include a cationic residue of lysine and a cationic residue of arginine. An alkali metal atom is preferable, and sodium and potassium are particularly preferable.
The amide amino acid type amphoteric surfactant may be used alone or in combination of two or more.
本発明の泡状洗浄剤組成物に使用するｃ成分は、前記の式（４）で示されるアシルアルキルタウリン塩型陰イオン性界面活性剤である。
式（４）中のＲ４は炭素数８〜２０のアシル基であり、直鎖状でも分岐鎖状でもよく、また、飽和でも不飽和でもよい。具体例としては、式（１）のＲ１と同様のものが挙げられ、中でも、ラウリン酸、ミリスチン酸、オレイン酸、ヤシ油脂肪酸、パーム核油脂肪酸等の残基が好ましい。炭素数が８未満の場合、洗浄剤の皮膚への刺激が強くなり、炭素数が２０を超えると起泡力が低下する。
また、式（４）中のＲ５は炭素数１〜３のアルキル基であり、メチル基、エチル基、プロピル基等が挙げられる。また、Ｍ４はアルカリ金属原子、１／２アルカリ土類金属原子、アンモニウム、有機アンモニウム又は塩基性アミノ酸陽イオン基であり、これらの具体例としては、式（３）のＭ３で挙げたものと同様のものが挙げられる。該Ｍ４は好ましくはアルカリ金属原子、１／２アルカリ土類金属原子であり、特に好ましくはナトリウム、カリウム、１／２カルシウム、１／２マグネシウムである。
当該アシルアルキルタウリン塩型陰イオン性界面活性剤は１種を使用しても、２種以上を併用してもよい。
The component c used in the foam detergent composition of the present invention is an acylalkyl taurine salt type anionic surfactant represented by the above formula (4).
R 4 in Formula (4) is an acyl group having 8 to 20 carbon atoms, and may be linear or branched, and may be saturated or unsaturated. Specific examples include those similar to R 1 in formula (1), and among these, residues such as lauric acid, myristic acid, oleic acid, coconut oil fatty acid, and palm kernel oil fatty acid are preferred. When carbon number is less than 8, irritation | stimulation to the skin of a cleaning agent becomes strong, and when carbon number exceeds 20, foaming power will fall.
Also, R 5 in the formula (4) is an alkyl group having 1 to 3 carbon atoms, a methyl group, an ethyl group, a propyl group. M 4 is an alkali metal atom, ½ alkaline earth metal atom, ammonium, organic ammonium or a basic amino acid cation group, and specific examples thereof include those listed for M 3 in formula (3). The same thing is mentioned. The M 4 is preferably an alkali metal atom or a ½ alkaline earth metal atom, and particularly preferably sodium, potassium, ½ calcium, or ½ magnesium.
The acylalkyl taurine salt type anionic surfactant may be used alone or in combination of two or more.
本発明の泡状洗浄剤組成物に使用するｄ成分は、炭素数２〜６の２価アルコールである。具体的には、エチレングリコール、プロピレングリコール、ジエチレングリコール、１，３−ブチレングリコール、１，２−ペンタンジオール、ヘキシレングリコール、ジプロピレングリコール等が挙げられ、中でも洗浄剤のメイク汚れに対する洗浄性や、泡質の点から１，２−ペンタンジオール、１，３−ブチレングリコール、ジプロピレングリコールが好ましい。当該２価アルコールは１種を使用しても、２種以上を併用してもよい。 The d component used in the foam cleaning composition of the present invention is a dihydric alcohol having 2 to 6 carbon atoms. Specifically, ethylene glycol, propylene glycol, diethylene glycol, 1,3-butylene glycol, 1,2-pentanediol, hexylene glycol, dipropylene glycol, and the like, among them, the cleaning properties of the detergent against makeup stains, From the viewpoint of foam quality, 1,2-pentanediol, 1,3-butylene glycol and dipropylene glycol are preferred. The dihydric alcohol may be used alone or in combination of two or more.
本発明の泡状洗浄剤組成物においては、泡質、洗浄後の感触をさらに向上させるために、上記ａ〜ｄ成分に加えて、さらにｅ成分を配合するのが好ましい。
該ｅ成分は、前記の式（５）で示される２−(メタ)アクリロイルオキシエチルホスホリルコリン（以下、ＰＣとも略称する。）の単独重合体若しくはＰＣと（メタ）アクリル酸アルキルエステルの共重合体、又はＰＣと（メタ）アクリル酸アルキルエステルとこれらに共重合性を示す他の単量体との共重合体からなるポリマーである。
In the foam cleaning composition of the present invention, in order to further improve the foam quality and the feel after washing, it is preferable to further add an e component in addition to the above components a to d.
The component e is a homopolymer of 2- (meth) acryloyloxyethyl phosphorylcholine (hereinafter also abbreviated as PC) represented by the above formula (5) or a copolymer of PC and (meth) acrylic acid alkyl ester. Or a polymer composed of a copolymer of PC, (meth) acrylic acid alkyl ester and other monomers copolymerizable therewith.
式（５）で示されるＰＣにおいて、式中、Ｒ６は水素原子又はメチル基である。また、Ｒ７、Ｒ８およびＲ９は炭素数１〜８のアルキル基であり、例えば、メチル基、エチル基、ｎ−プロピル基、イソプロピル基等が挙げられる。Ｒ７、Ｒ８およびＲ９は同一でも、異なっていてもよい。また、ｐは２〜４の整数である。特に好ましいＰＣは、式中のＲ６、Ｒ７、Ｒ８およびＲ９がメチル基で、ｐが２の２−メタクリロイルオキシエチルホスホリルコリンである。 In the PC represented by the formula (5), R 6 is a hydrogen atom or a methyl group. Further, R 7, R 8 and R 9 is an alkyl group having 1 to 8 carbon atoms, such as methyl group, ethyl group, n- propyl group, an isopropyl group, and the like. R 7 , R 8 and R 9 may be the same or different. Moreover, p is an integer of 2-4. Particularly preferred PC is 2-methacryloyloxyethyl phosphorylcholine in which R 6 , R 7 , R 8 and R 9 are methyl groups and p is 2.
（メタ）アクリル酸アルキルエステル（「（メタ）アクリル」はメタクリル又はアクリルを示す。）を構成するアルコール残基（アルキル基）は炭素数１〜６であり、好ましくは炭素数２〜５、より好ましくは炭素数３〜４である。該（メタ）アクリル酸アルキルエステルの具体例としては、例えば、メタクリル酸メチル、アクリル酸エチル、メタクリル酸エチル、アクリル酸プロピル、メタクリル酸プロピル、アクリル酸イソプロピル、メタクリル酸イソプロピル、アクリル酸ｎ−ブチル等が挙げられる。 The alcohol residue (alkyl group) constituting the (meth) acrylic acid alkyl ester ("(meth) acryl" represents methacryl or acryl) has 1 to 6 carbon atoms, preferably 2 to 5 carbon atoms. Preferably it is C3-C4. Specific examples of the (meth) acrylic acid alkyl ester include, for example, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, isopropyl acrylate, isopropyl methacrylate, n-butyl acrylate, and the like. Is mentioned.
ＰＣと（メタ）アクリル酸アルキルエステルに共重合性を示す他の単量体としては、付加重合可能な二重結合を有する化合物であり、例えば、エチレン、プロピレン、ブテン、イソブテン、スチレン等のオレフィン系炭化水素およびそれらの異性化オレフィン、多量化オレフィン、又はこれらに各種誘導体を導入したオレフィン性化合物；アクリル酸、メタクリル酸、ビニル酢酸、イタコン酸、クロトン酸、マレイン酸、フマル酸等のエチレン性不飽和カルボン酸およびそれらの多量体、無水物、炭素数１〜６の多価アルコールとのエステル、又はカルボニル基、アミノ基、シアノ基、ニトリル基等を導入したエチレン性不飽和カルボン酸誘導体；ビニルアルコールおよびこれらと各種カルボン酸とのエステル、各種アルコールとのエーテル、又はこれらにカルボニル基、アミノ基、シアノ基、ニトリル基等を導入したビニルアルコール誘導体等が挙げられる。 Other monomers that are copolymerizable with PC and (meth) acrylic acid alkyl ester are compounds having a double bond capable of addition polymerization, such as olefins such as ethylene, propylene, butene, isobutene, and styrene. Hydrocarbons and their isomerized olefins, multimerized olefins, or olefinic compounds obtained by introducing various derivatives thereof; ethylenic properties such as acrylic acid, methacrylic acid, vinyl acetic acid, itaconic acid, crotonic acid, maleic acid, and fumaric acid Unsaturated carboxylic acids and their multimers, anhydrides, esters with polyhydric alcohols having 1 to 6 carbon atoms, or ethylenically unsaturated carboxylic acid derivatives introduced with a carbonyl group, amino group, cyano group, nitrile group, etc .; Vinyl alcohol and esters thereof with various carboxylic acids, ethers with various alcohols Or these carbonyl group, an amino group, a cyano group, vinyl alcohol derivatives obtained by introducing a nitrile group and the like.
該ｅ成分のポリマーは、ＰＣ由来の構成単位（構成単位Ａ）と（メタ）アクリル酸アルキルエステル由来の構成単位（構成単位Ｂ）を１００／０〜１０／９０（Ａ／Ｂ）の重量比で含有することが重要であり、好ましくは１００／０〜３０／７０、さらに好ましくは９５／５〜５０／５０である。また、ＰＣ由来の構成単位（構成単位Ａ）と（メタ）アクリル酸アルキルエステル由来の構成単位（構成単位Ｂ）の合計含有量が６０〜１００重量％であることが重要であり、好ましくは７０〜１００重量％、さらに好ましくは８０〜１００重量％である。なお、ここでの「合計含有量」とは、当該ポリマーが（メタ）アクリル酸アルキルエステル由来の構成単位（構成単位Ｂ）を含まない場合、ＰＣ由来の構成単位（構成単位Ａ）の含有量である。 The polymer of component e is a weight ratio of 100/0 to 10/90 (A / B) of a structural unit derived from PC (structural unit A) and a structural unit derived from (meth) acrylic acid alkyl ester (structural unit B). It is important that it is contained, preferably 100/0 to 30/70, more preferably 95/5 to 50/50. Further, it is important that the total content of the structural unit derived from PC (structural unit A) and the structural unit derived from (meth) acrylic acid alkyl ester (structural unit B) is 60 to 100% by weight, preferably 70. -100% by weight, more preferably 80-100% by weight. In addition, "total content" here is content of the structural unit (structural unit A) derived from PC, when the said polymer does not contain the structural unit (structural unit B) derived from the (meth) acrylic acid alkylester. It is.
また、該ｅ成分のポリマーの分子量は１０，０００〜１０，０００，０００が好ましく、より好ましくは５０，０００〜５，０００，０００である。なお、ここでの「分子量」とは、ゲルパーミエーションクロマトグラフィー（ＧＰＣ）による標準ポリエチレングリコールを用いた検量線により換算した「重量平均分子量」のことである。 The molecular weight of the polymer of component e is preferably 10,000 to 10,000,000, more preferably 50,000 to 5,000,000. Here, “molecular weight” is “weight average molecular weight” converted by a calibration curve using standard polyethylene glycol by gel permeation chromatography (GPC).
本発明の泡状洗浄剤組成物において、ａ成分（炭素数１２〜２２の脂肪酸塩）の配合量は１〜１０重量％であり、好ましくは３〜１０重量％、更に好ましくは５〜９重量％である。１重量％未満では、充分な、泡立ち、泡の保持性、泡質、洗浄力およびさっぱり感が得られない。また、１０重量％を超えると洗浄後のつっぱり感が強くなり、また、保存安定性が悪くなる場合がある。また、ｂ成分（式（１）で示されるアミドベタイン型両性界面活性剤、式（２）で示されるアルキルアミノジカルボン酸型両性界面活性剤及び式（３）で示されるアミドアミノ酸型両性界面活性剤から選ばれる１種又は２種以上の両性界面活性剤）の配合量は０．５〜５重量％であり、好ましくは１〜５重量％、さらに好ましくは２〜４％である。０．５重量％未満では泡質が悪く、洗浄後につっぱり感が残り、５重量％を超えるとぬめり感が残り、すすぎ性が悪い。また、ｃ成分（式（４）で示されるアシルアルキルタウリン塩型陰イオン性界面活性剤）の配合量は０．１〜３重量％であり、好ましくは０．５〜３％である。０．１重量％未満では泡質が悪く、洗浄後につっぱり感が残り、３重量％を超えるとぬめり感が残り、すすぎ性が悪くなる。 In the foam detergent composition of the present invention, the amount of component a (fatty acid salt having 12 to 22 carbon atoms) is 1 to 10% by weight, preferably 3 to 10% by weight, more preferably 5 to 9% by weight. %. If it is less than 1% by weight, sufficient foaming, foam retention, foam quality, detergency and refreshing feeling cannot be obtained. On the other hand, if it exceeds 10% by weight, the feeling of tension after washing becomes strong, and the storage stability may deteriorate. In addition, component b (an amide betaine type amphoteric surfactant represented by the formula (1), an alkylaminodicarboxylic acid type amphoteric surfactant represented by the formula (2) and an amide amino acid type amphoteric surfactant represented by the formula (3) The blending amount of one or more amphoteric surfactants selected from the agents is 0.5 to 5% by weight, preferably 1 to 5% by weight, and more preferably 2 to 4%. If it is less than 0.5% by weight, the foam quality is poor, and a feeling of tension remains after washing, and if it exceeds 5% by weight, a slimy feeling remains and the rinsing property is poor. Moreover, the compounding quantity of c component (The acylalkyl taurine salt type anionic surfactant shown by Formula (4)) is 0.1 to 3 weight%, Preferably it is 0.5 to 3%. If it is less than 0.1% by weight, the foam quality is poor, and a feeling of stickiness remains after washing. If it exceeds 3% by weight, a slimy feeling remains and the rinsing property becomes worse.
また、ａ成分の含有量とｂ成分とｃ成分の合計含有量との重量比（ａ／（ｂ＋ｃ））は１／１〜１０／１であり、好ましくは、１／１〜８／１、さらに好ましくは１／１〜６／１である。該重量比が１／１より小さい場合、洗浄後にぬめり感が残り、さっぱり感が充分でなく、また、該重量比が１０／１より大きい場合、保存安定性が悪く、つっぱり感を生じる場合がある。 The weight ratio (a / (b + c)) of the content of the component a and the total content of the components b and c is 1/1 to 10/1, preferably 1/1 to 8/1. More preferably, it is 1/1 to 6/1. When the weight ratio is less than 1/1, the feeling of slimness remains after washing, and the feeling of refreshing is not sufficient, and when the weight ratio is greater than 10/1, the storage stability is poor and may cause a feeling of tension. is there.
また、ａ成分、ｂ成分およびｃ成分の合計含有量（ａ＋ｂ＋ｃ）は３〜１２重量％、好ましくは、６〜１１重量％である。３重量％未満の場合は泡保持性、泡質が不良であり、１２重量％を超える場合は、洗浄剤組成物の粘性が高くなりやすく、泡立ち、泡質が悪くなる。 The total content (a + b + c) of the component a, component b and component c is 3 to 12% by weight, preferably 6 to 11% by weight. When it is less than 3% by weight, the foam retention and foam quality are poor, and when it exceeds 12% by weight, the viscosity of the cleaning composition tends to be high, and foaming and foam quality are deteriorated.
また、ｄ成分（炭素数２〜６の２価アルコール）の配合量は２〜２０重量であり、好ましくは３〜１８重量％、更に好ましくは５〜１５重量％である。２重量％未満では洗浄力が充分でない。２０重量％を超えると泡立ち、泡保持性、および泡質が悪くなるとともに、ぬめり感が残り、すすぎ性が悪く、さっぱり感が充分でなくなる。 Moreover, the compounding quantity of d component (C2-C6 dihydric alcohol) is 2-20 weight, Preferably it is 3-18 weight%, More preferably, it is 5-15 weight%. If it is less than 2% by weight, the detergency is not sufficient. When it exceeds 20% by weight, foaming, foam retention and foam quality are deteriorated and a slimy feeling remains, rinsing properties are poor, and a refreshing feeling becomes insufficient.
また、ａ成分、ｂ成分およびｃ成分の合計含有量とｄ成分の重量比（（ａ＋ｂ＋ｃ）／ｄ）は、１／５〜１／１である。該重量比が１／５より小さい場合は、泡立ち、泡保持性及び泡質が不良となり、洗浄後にぬめりが残り、すすぎ性が悪く、さっぱり感が充分でなない。また、該重量比が１／１より大きい場合は、保存安定性が悪くなる。 The total content of the a component, the b component and the c component and the weight ratio of the d component ((a + b + c) / d) is 1/5 to 1/1. When the weight ratio is less than 1/5, foaming, foam retention and foam quality are poor, sliminess remains after washing, rinsing properties are poor, and a refreshing feeling is not sufficient. On the other hand, when the weight ratio is larger than 1/1, the storage stability is deteriorated.
また、本発明において、泡質の改善、洗浄後の感触の向上のために添加することが好ましいｅ成分の配合量は０．００１〜１重量％が好ましく、より好ましくは０．０１〜０．５重量％である。０．００１重量％未満の場合は、泡質の改善や洗浄後の感触改善効果が充分でなく、１重量％を超える場合は配合自体が困難になる場合がある。 In the present invention, the amount of the e component that is preferably added to improve foam quality and feel after washing is preferably 0.001 to 1% by weight, more preferably 0.01 to 0.00%. 5% by weight. When the amount is less than 0.001% by weight, the effect of improving the foam quality and feeling after washing is not sufficient, and when it exceeds 1% by weight, the blending itself may be difficult.
本発明の泡状洗浄剤組成物においては、洗浄剤に常用されている添加剤を本発明の性能を損なわない範囲で配合することも可能である。例えば、エタノール、イソプロピルアルコール等の低級アルコール、流動パラフィン、流動イソパラフィン、スクワラン等の炭化水素系油、牛脂、豚脂、魚油等の天然油脂類、トリ２−エチルヘキサン酸グリセリル等の合成トリグリセライド、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル等のエステル油、ミツロウ、カルナバロウ等のロウ類、直鎖及び環状のジメチルポリシロキサン、ポリエーテル変性ジメチルポリシロキサン、アミノ変性ジメチルポリシロキサン等のシリコーン誘導体、セラミド、コレステロール、レシチン等の油性基剤、ポリオキシエチレンアルキルエーテル、ポリエチレングリコールの脂肪酸エステル、アルキルポリグルコシド等の非イオン性界面活性剤、塩化アルキルトリメチルアンモニウム等の陽イオン性界面活性剤、アルキルジメチルアミンオキシド等の半極性界面活性剤、アルギン酸、カルボキシビニルポリマー、キサンタンガム等の水溶性高分子、クエン酸塩、リンゴ酸塩、食塩等の有機又は無機塩類、ｐＨ調製剤である酸及びアルカリ、殺菌剤、キレート剤、抗酸化剤、紫外線吸収剤、動植物由来の天然エキス、色素及び香料等を配合できる。 In the foam cleaning composition of the present invention, additives commonly used in cleaning agents can be blended within a range that does not impair the performance of the present invention. For example, lower alcohols such as ethanol and isopropyl alcohol, hydrocarbon oils such as liquid paraffin, liquid isoparaffin and squalane, natural fats and oils such as beef tallow, lard and fish oil, synthetic triglycerides such as glyceryl tri-2-ethylhexanoate, and myristic Ester oils such as isopropyl acid, isopropyl palmitate, octyldodecyl myristate, waxes such as beeswax and carnauba wax, silicone derivatives such as linear and cyclic dimethylpolysiloxane, polyether-modified dimethylpolysiloxane, amino-modified dimethylpolysiloxane, Oily bases such as ceramide, cholesterol and lecithin, polyoxyethylene alkyl ethers, fatty acid esters of polyethylene glycol, nonionic surfactants such as alkyl polyglucosides, alkyl chlorides Cationic surfactants such as methylammonium, semipolar surfactants such as alkyldimethylamine oxide, water-soluble polymers such as alginic acid, carboxyvinyl polymer, and xanthan gum, organic such as citrate, malate, and salt Inorganic salts, acids and alkalis that are pH adjusting agents, bactericides, chelating agents, antioxidants, ultraviolet absorbers, natural extracts derived from animals and plants, pigments and fragrances can be blended.
本発明の泡状洗浄剤組成物に使用する各配合成分は市販品を使用しても、公知の方法（定法）で製造して使用してもよい。本発明の泡状洗浄剤組成物は、定法に従って、上記の各配合成分と必要に応じて配合する添加剤を所定量の精製水と攪拌・混合することにより調製される。 Each compounding component used for the foam detergent composition of the present invention may be a commercially available product, or may be produced by a known method (ordinary method). The foam detergent composition of the present invention is prepared by stirring and mixing each of the above-described blending components and an additive blended as necessary with a predetermined amount of purified water according to a conventional method.
本発明の洗浄剤組成物を起泡させるために使用するフォーマー容器は、単数又は複数の一定孔径の多孔体を用い、所定の割合で洗浄剤組成物と空気を混合し、該洗浄剤組成物を起泡させて泡状物として吐出させるものである。これにより、クリーミィな泡を形成することができ、洗浄時に良好な感触を得ることができる。多孔体としては、ネット、スポンジ等があげられるが、目詰り解消の点からネットを用いることが好ましい。ネットのメッシュとしては、１００〜４００メッシュが好ましい。本発明の洗浄剤組成物をフォーマー容器に充填する場合、上記のように泡を形成することができる容器であれば、その種類は特に制限されるものではなく、公知の各種フォーマー容器を好適に使用することができるが、これらの中でも、使用性の点を考慮すれば、キャップの頭部を手指で押圧することにより使用するポンプ式フォーマーがより好ましい。 The former container used for foaming the cleaning composition of the present invention uses one or a plurality of porous bodies having a constant pore diameter, and the cleaning composition and air are mixed at a predetermined ratio, and the cleaning composition Is foamed and discharged as a foam. Thereby, creamy foam can be formed, and a good touch can be obtained during cleaning. Examples of the porous body include a net and a sponge, but it is preferable to use a net from the viewpoint of eliminating clogging. The net mesh is preferably 100 to 400 mesh. When filling the former container with the cleaning composition of the present invention, the type is not particularly limited as long as it is a container capable of forming bubbles as described above, and various known former containers are preferably used. Among these, in consideration of usability, a pump-type former that is used by pressing the head of the cap with a finger is more preferable.
本発明の泡状洗浄剤組成物は、例えば、洗顔フォーム、クレンジングフォーム、シェービングフォーム、ボディーフォーム、ヘアフォーム等に使用でき、中でも、洗顔フォーム、クレンジングフォーム等に好適である。 The foamy detergent composition of the present invention can be used for, for example, a face-washing foam, a cleansing foam, a shaving foam, a body foam, a hair foam, and the like, and is particularly suitable for a face-washing foam, a cleansing foam, and the like.
以下、実施例と比較例を示して、本発明をより具体的に説明するが、本発明は以下の実施例に限定されるものではない。 EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated more concretely, this invention is not limited to a following example.
（実施例１〜５、比較例１〜７）
表１及び表２の上欄に示す各成分を定法に従って攪拌・混合することにより、実施例１〜５、比較例１〜７の各泡状洗浄剤組成物を調製し、それぞれについて性能評価を行った。なお、ｅ成分のポリメタクリロイルオキシエチルホスホリルコリンの重量平均分子量は８０，０００、２−メタクリロイルオキシエチルホスホリルコリン・メタクリル酸ブチル共重合体の共重合比（２−メタクリロイルオキシエチルホスホリルコリン／メタクリル酸ブチル共重合体）は９０／１０（重量比）、重量平均分子量は６００，０００である。
評価項目と評価方法は以下の通りであり、評価結果は表１及び表２の下欄に示す。
(Examples 1-5, Comparative Examples 1-7)
Each foam cleaning composition of Examples 1-5 and Comparative Examples 1-7 was prepared by stirring and mixing each component shown in the upper column of Table 1 and Table 2 according to a conventional method, and performance evaluation was performed about each. went. The weight average molecular weight of the polymethacryloyloxyethyl phosphorylcholine of component e is 80,000, and the copolymerization ratio of 2-methacryloyloxyethyl phosphorylcholine / butyl methacrylate copolymer (2-methacryloyloxyethyl phosphorylcholine / butyl methacrylate copolymer) ) Is 90/10 (weight ratio) and the weight average molecular weight is 600,000.
Evaluation items and evaluation methods are as follows, and the evaluation results are shown in the lower columns of Tables 1 and 2.
（１）泡立ちの評価
２０ｍｌビーカーに大和製罐株式会社製のポンプフォーマー容器（型番 Ｆ２）で１回吐出した直後に、ビーカー中の泡の高さを測定した。この操作を３回繰り返し、平均の泡の高さが１５ｍｍ以上の場合を、泡立ちが良好な泡状洗浄剤と評価した。
(1) Evaluation of foaming Immediately after discharging into a 20 ml beaker with a pump former container (model number F2) manufactured by Daiwa Seikan Co., Ltd., the height of the foam in the beaker was measured. This operation was repeated three times, and the case where the average foam height was 15 mm or more was evaluated as a foam detergent having good foaming.
（２）泡の保持性の評価
２０ｍｌビーカーに大和製罐株式会社製のポンプフォーマー容器（型番 Ｆ２）で１回吐出した直後に、ビーカー中の泡の高さを測定した。ビーカーを放置し５分後の泡の高さを測定し次の式から泡の保持性を評価した。３回操作の平均値を算出し、９０％以上の場合を泡の保持性が良好な泡状洗浄剤と評価した。
泡の保持性（％）＝{(５分後の泡の高さ)／(直後)}×１００
なお、ここでの「吐出した直後」とは、吐出から５秒以内のことである。
(2) Evaluation of foam retention The height of the foam in the beaker was measured immediately after it was discharged once in a 20 ml beaker with a pump former container (model No. F2) manufactured by Daiwa Steel Co., Ltd. The beaker was allowed to stand and the foam height was measured after 5 minutes, and the foam retention was evaluated from the following formula. The average value of three operations was calculated, and the case of 90% or more was evaluated as a foam cleaning agent with good foam retention.
Foam retention (%) = {(bubble height after 5 minutes) / (immediately)} × 100
Here, “immediately after ejection” means within 5 seconds from ejection.
（３）泡質の評価
１０名の男女をパネラーとし、大和製罐(株)製ポンプフォーマー容器（型番 Ｆ２）で吐出した時の泡質について下記のように判定し、１０名の平均値が１．５点以上を泡質が優れていると評価した。
(3) Evaluation of foam quality Assuming that 10 men and women are panelists, the foam quality when discharged with a pump former container (model number F2) manufactured by Daiwa Steel Co., Ltd. is determined as follows, and the average value of 10 people Evaluated that the foam quality was excellent at 1.5 points or more.
２点：泡質が良好であると感じた場合
１点：泡質が若干粗いと感じた場合
０点：泡質が粗いと感じた場合
2 points: When feeling foam quality is good 1 point: When feeling foam quality is slightly rough 0 Point: When feeling foam quality is rough
（４）メイクに対する洗浄性の評価
１０名の女性をパネラーとし、口紅およびファンデーションを使用した状態で大和製罐(株)製ポンプフォーマー容器（型番 Ｆ２）を３プッシュして吐出した洗浄剤を用いて洗顔した時の洗浄感を下記のように判定し、１０名の平均値が１．５点以上をメイク落ちが良いと評価した。
２点：メイクが充分落ちると感じた場合
１点：メイクが若干残ると感じた場合
０点：メイクの落ちが悪いと感じた場合
(4) Evaluation of cleansing properties for makeup A cleaning agent discharged by pushing 10 pump former containers (model No. F2) made by Daiwa Seisaku Co., Ltd. with 10 women as panelists and using lipstick and foundation. When the face was washed using, the feeling of washing was determined as follows, and the average value of 10 people was evaluated as having a makeup removal of 1.5 points or more.
2 points: When the makeup feels to fall well 1 point: When the makeup feels to remain a little 0 points: When the makeup feels bad
（５）すすぎ性の評価
１０名の男女をパネラーとし、大和製罐(株)製ポンプフォーマー容器（型番 Ｆ２）を３プッシュして吐出した洗浄剤を用いて洗顔し、すすぎ時のすすぎのし易さについて下記のように判定し、１０名の平均値が１．５点以上をすすぎ性良好と評価した。
２点：すすぎやすいと感じた場合
１点：若干すすぎにくいと感じた場合
０点：非常にすすぎにくいと感じた場合
(5) Evaluation of rinsing properties 10 men and women are panelists, and the face is washed with the detergent discharged by pushing 3 pump former containers (model No. F2) manufactured by Daiwa Steel Co., Ltd. The ease was determined as follows, and the average value of 10 people was evaluated as having good rinsing properties when the average value was 1.5 points or more.
2 points: When it feels easy to rinse 1 point: When it feels slightly difficult to rinse 0 point: When it feels very difficult to rinse
（６）洗顔後のぬめり感の評価
１０名の男女をパネラーとし、大和製罐(株)製ポンプフォーマー容器（型番 Ｆ２）を３プッシュして吐出した洗浄剤を用いて洗顔し、すすいだ後のぬめり感について下記のように判定し、１０名の平均値が１．５点以上をぬめりが少ないと評価した。
２点：ぬめり感が無いと感じた場合
１点：ぬめり感が若干あると感じた場合
０点：ぬめり感が非常にあると感じた場合
(6) Evaluation of slimy feeling after face washing 10 men and women are panelists, and face wash is performed using the detergent discharged by pushing 3 pump former containers (model number F2) manufactured by Daiwa Steel Co., Ltd. and rinsed. The following feeling of sliminess was determined as follows, and an average value of 10 or more people was evaluated to be less than 1.5 points.
2 points: When feeling that there is no sliminess 1 point: When feeling that there is a little sliminess 0 point: When feeling that there is very sliminess
（７）洗顔後のさっぱり感の評価
１０名の男女をパネラーとし、大和製罐(株)製ポンプフォーマー容器（型番 Ｆ２）を３プッシュして吐出した洗浄剤を用いて洗顔した後のさっぱり感について下記のように判定し、１０名の平均値が１．５点以上をさっぱり感があると判定した。
２点：洗顔後にさっぱりすると感じた場合
１点：洗顔後にややさっぱりすると感じた場合
０点：洗顔後にさっぱり感が無いと感じた場合
(7) Evaluation of refreshing feeling after face washing Refreshing after washing face using 10 men and women panelists and 3 pumps made by Daiwa Steel Co., Ltd. (model No. F2). The feeling was determined as follows, and it was determined that the average value of 10 persons had a refreshing feeling of 1.5 points or more.
2 points: If you feel refreshed after washing your face 1 point: If you feel refreshed after washing your face 0 points: If you feel you feel refreshed after washing your face
（８）乾燥後のつっぱり感の評価
１０名の男女をパネラーとし、大和製罐(株)製ポンプフォーマー容器（型番 Ｆ２）を３プッシュして吐出した洗浄剤を用いて洗顔した後の肌のつっぱり感について下記のように判定し、１０名の平均値が１．５点以上をつっぱり感が無いと判定した。
２点：乾燥後の肌がつっぱらないと感じた場合
１点：乾燥後の肌がややつっぱると感じた場合
０点：乾燥後の肌が非常につっぱると感じた場合
(8) Evaluation of the feeling of dryness after drying Skin after washing with 10 detergents, using a cleaning agent discharged by pushing 3 pump former containers (model No. F2) manufactured by Daiwa Steel Co., Ltd. It was determined as follows about the feeling of being stuck, and it was judged that there was no feeling of feeling when the average value of 10 persons was 1.5 points or more.
2 points: When the skin feels dry after drying 1 point: When the skin feels dry after drying 0 points: When the skin feels very dry after drying
（９）保存安定性の評価
各組成物を透明ガラス容器に密封して−５℃、２５℃、４５℃で１ヶ月間保存し、その外観を観察して、下に示す３段階で評価した。
○：保存安定性良好（いずれの温度条件においても液状を保ち、外観の変化がない。）
△：保存安定性やや不良（いずれかの温度条件において外観が若干変化する。）
×：保存安定性不良（いずれかの温度条件において外観の変化が著しい。）
(9) Evaluation of storage stability Each composition was sealed in a transparent glass container and stored at −5 ° C., 25 ° C. and 45 ° C. for 1 month, and its appearance was observed and evaluated in the following three stages. .
○: Storage stability is good (the liquid state is maintained at any temperature condition and there is no change in appearance)
Δ: Slightly poor storage stability (appearance changes slightly at any temperature condition)
X: Storage stability defect (change in appearance is remarkable under any temperature condition)
実施例１〜５より、本発明の泡状洗浄剤組成物はいずれも泡立ち、泡質、泡の保持性に優れ、すすぎ時の泡切れ、洗浄後にぬめり感がなく、さっぱりと洗い上がり、乾燥後にはつっぱり感が残らないとともに、メイクや皮脂等に対する洗浄力に優れ、保存安定性にも優れていた。 From Examples 1 to 5, the foam detergent composition of the present invention is all foamed, excellent in foam quality, foam retention, no foaming at the time of rinsing, no slimy feeling after washing, freshly washed up, dried Later, there was no feeling of tension, and it was excellent in detergency against makeup, sebum and the like, and excellent in storage stability.
一方、比較例１〜７では充分な性能が得られなかった。比較例１では、ａ成分の含有量、ａ、ｂ及びｃ成分の合計含有量（ａ＋ｂ＋ｃ）が多すぎ、また、ａ、ｂ及びｃ成分の合計含有量とｄ成分の含有量との重量比（（ａ＋ｂ＋ｃ）／ｄ）が大き過ぎるため、泡立ち、泡質が悪く、乾燥後につっぱり感があった。また、保存安定性が悪かった。比較例２では、ｂ、ｃおよびｄ成分の各含有量と、ａ、ｂ及びｃ成分の合計含有量（ａ＋ｂ＋ｃ）が多すぎ、ａの含有量とｂとｃの合計含有量との重量比（ａ／（ｂ＋ｃ））が小さい（すなわち、ａ成分の割合が少な過ぎる）ため、泡立ち、泡の保持性、泡質、すすぎ性、さっぱり感が悪く、ぬめり感が残った。また保存安定性が悪かった。比較例３では、ｄ成分を含有しないため、洗浄力が悪かった。比較例４では、ａ成分を含有しないため、泡立ち、泡の保持性、泡質及び洗浄力が悪く、洗浄後のさっぱり感が悪かった。比較例５では、ｂ成分を含有しないため、また、比較例６では、ｃ成分を含有しないため、泡質が悪く、乾燥後につっぱり感が残った。比較例７では、ｄ成分のかわりに他の成分を含有するため、泡の保持性、洗浄力が悪く、保存安定性も充分でなかった。
On the other hand, in Comparative Examples 1-7, sufficient performance was not obtained. In Comparative Example 1, the content of component a, the total content of components a, b and c (a + b + c) is too large, and the weight ratio of the total content of components a, b and c to the content of component d Since ((a + b + c) / d) was too large, foaming and foam quality were poor, and there was a feeling of tension after drying. In addition, the storage stability was poor. In Comparative Example 2, each content of the components b, c and d and the total content (a + b + c) of the components a, b and c are too much, and the weight ratio of the content of a and the total content of b and c Since (a / (b + c)) is small (that is, the proportion of the component a is too small), foaming, foam retention, foam quality, rinsing properties, and refreshing feeling are poor, and a slimy feeling remains. In addition, the storage stability was poor. In Comparative Example 3, since the d component was not contained, the detergency was poor. In Comparative Example 4, since the component a was not contained, foaming, foam retention, foam quality and detergency were poor, and the refreshing feeling after washing was poor. In Comparative Example 5, the b component was not contained, and in Comparative Example 6, the c component was not contained. Therefore, the foam quality was poor and a feeling of tension remained after drying. In Comparative Example 7, since other components were contained instead of the d component, the foam retention and detergency were poor, and the storage stability was not sufficient.
Claims (2)
ａ．炭素数１２〜２２の脂肪酸塩
ｂ．式（１）：
で示されるアミドベタイン型両性界面活性剤、
式（２）：
で示されるアルキルアミノジカルボン酸型両性界面活性剤及び
式（３）：
で示されるアミドアミノ酸型両性界面活性剤の中から選ばれる１種又は２種以上
ｃ．式（４）：
で示されるアシルアルキルタウリン塩型陰イオン性界面活性剤
ｄ．炭素数２〜６の２価アルコール The following a contains 1 to 10 wt%, b contains 0.5 to 5 wt%, c contains 0.1 to 3 wt%, d contains 2 to 20 wt%, and the total content of a, b and c (a + b + c ) Is 3 to 12% by weight, the weight ratio of the content of a and the total content of b and c (a / (b + c)) is 1/1 to 10/1, and the total content of a, b and c A foamy detergent composition having a weight ratio ((a + b + c) / d) of 1/5 to 1/1 with respect to the content of d.
a. Fatty acid salt having 12 to 22 carbon atoms b. Formula (1):
An amide betaine amphoteric surfactant represented by
Formula (2):
An alkylaminodicarboxylic acid type amphoteric surfactant represented by formula (3):
1 or 2 or more types selected from amide amino acid type amphoteric surfactants represented by c. Formula (4):
An acylalkyl taurine salt type anionic surfactant represented by d. C2-C6 dihydric alcohol
ｅ．式（５）：
で示される２−（メタ）アクリロイルオキシエチルホスホリルコリン由来の構成単位（構成単位Ａ）及び（メタ）アクリル酸アルキルエステル由来の構成単位（構成単位Ｂ）を１００／０〜１０／９０（Ａ／Ｂ）の重量比で含有し、これら構成単位の含有量が６０〜１００重量％であるポリマー
Furthermore, the foam cleaning composition of Claim 1 which contains 0.001 to 1weight% of following e.
e. Formula (5):
The structural unit derived from 2- (meth) acryloyloxyethyl phosphorylcholine (structural unit A) and the structural unit derived from (meth) acrylic acid alkyl ester (structural unit B) represented by 100/0 to 10/90 (A / B) ) In a weight ratio of 60 to 100% by weight.
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Cited By (5)
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| JP2012131951A (en) * | 2010-12-24 | 2012-07-12 | Lion Corp | Liquid detergent product |
| JP2013133302A (en) * | 2011-12-27 | 2013-07-08 | Nof Corp | Detergent composition for skin |
| WO2013141118A1 (en) * | 2012-03-19 | 2013-09-26 | ライオン株式会社 | Liquid detergent composition |
| JP2017002242A (en) * | 2015-06-15 | 2017-01-05 | 日油株式会社 | Liquid detergent composition |
| JP2017007963A (en) * | 2015-06-18 | 2017-01-12 | 日油株式会社 | Cleanser composition for pump foamer |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4830305B2 (en) * | 2005-01-27 | 2011-12-07 | 日油株式会社 | Weakly acidic foam detergent composition |
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