JP2005519151A - Liquid cleaning composition - Google Patents
Liquid cleaning composition Download PDFInfo
- Publication number
- JP2005519151A JP2005519151A JP2003571379A JP2003571379A JP2005519151A JP 2005519151 A JP2005519151 A JP 2005519151A JP 2003571379 A JP2003571379 A JP 2003571379A JP 2003571379 A JP2003571379 A JP 2003571379A JP 2005519151 A JP2005519151 A JP 2005519151A
- Authority
- JP
- Japan
- Prior art keywords
- antioxidant
- cleaning composition
- hydrogen peroxide
- liquid cleaning
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 239000000203 mixture Substances 0.000 title claims abstract description 103
- 238000004140 cleaning Methods 0.000 title claims abstract description 53
- 239000007788 liquid Substances 0.000 title claims abstract description 39
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 76
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 70
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 61
- 239000002689 soil Substances 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
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- 150000001875 compounds Chemical class 0.000 claims description 21
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- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 claims description 19
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- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- LCAZOMIGFDQMNC-FORWCCJISA-N rosmanol Chemical compound C1CCC(C)(C)[C@@H]2[C@H]3[C@@H](O)C(C=C(C(=C4O)O)C(C)C)=C4[C@]21C(=O)O3 LCAZOMIGFDQMNC-FORWCCJISA-N 0.000 description 1
- WIEOUDNBMYRSRD-UHFFFAOYSA-N rosmaridiphenol Chemical compound C1CC2C(C)(C)CCCC2C(=O)C2=C1C=C(C(C)C)C(O)=C2O WIEOUDNBMYRSRD-UHFFFAOYSA-N 0.000 description 1
- 235000005493 rutin Nutrition 0.000 description 1
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- PCMORTLOPMLEFB-UHFFFAOYSA-N sinapinic acid Natural products COC1=CC(C=CC(O)=O)=CC(OC)=C1O PCMORTLOPMLEFB-UHFFFAOYSA-N 0.000 description 1
- KZJWDPNRJALLNS-VJSFXXLFSA-N sitosterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](CC)C(C)C)[C@@]1(C)CC2 KZJWDPNRJALLNS-VJSFXXLFSA-N 0.000 description 1
- 235000015500 sitosterol Nutrition 0.000 description 1
- NLQLSVXGSXCXFE-UHFFFAOYSA-N sitosterol Natural products CC=C(/CCC(C)C1CC2C3=CCC4C(C)C(O)CCC4(C)C3CCC2(C)C1)C(C)C NLQLSVXGSXCXFE-UHFFFAOYSA-N 0.000 description 1
- 229950005143 sitosterol Drugs 0.000 description 1
- IWMMSZLFZZPTJY-UHFFFAOYSA-M sodium;3-(dodecylamino)propane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCNCCCS([O-])(=O)=O IWMMSZLFZZPTJY-UHFFFAOYSA-M 0.000 description 1
- HWCHICTXVOMIIF-UHFFFAOYSA-M sodium;3-(dodecylamino)propanoate Chemical compound [Na+].CCCCCCCCCCCCNCCC([O-])=O HWCHICTXVOMIIF-UHFFFAOYSA-M 0.000 description 1
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- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- YIBXWXOYFGZLRU-UHFFFAOYSA-N syringic aldehyde Natural products CC12CCC(C3(CCC(=O)C(C)(C)C3CC=3)C)C=3C1(C)CCC2C1COC(C)(C)C(O)C(O)C1 YIBXWXOYFGZLRU-UHFFFAOYSA-N 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229960001367 tartaric acid Drugs 0.000 description 1
- 229940092665 tea leaf extract Drugs 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical group C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
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- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Biochemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Abstract
本発明は、(a)ラジカル捕捉用酸化防止剤と過酸化水素とを含む液体洗浄組成物で硬質表面を処理する段階と、(b)脂肪質汚れの付着を放置する段階と、(c)脂肪質汚れを除去するために表面を洗浄する段階とを順次に含む硬質表面から脂肪質汚れを除去する方法を提供する。本発明はまた、天然ラジカル捕捉用酸化防止剤と過酸化水素と好ましくは界面活性剤とを含む硬質表面用液体洗浄組成物を提供する。The present invention includes (a) treating a hard surface with a liquid cleaning composition comprising an antioxidant for scavenging radicals and hydrogen peroxide, (b) leaving the deposits of fat stains, (c) A method is provided for removing fatty soils from a hard surface comprising sequentially cleaning the surface to remove the fatty soils. The present invention also provides a hard surface liquid cleaning composition comprising an antioxidant for scavenging natural radicals, hydrogen peroxide and preferably a surfactant.
Description
本発明は、酸化防止剤と過酸化物とを含む液体洗浄組成物、及び、これらの組成物を使用する硬質表面の洗浄方法に関する。 The present invention relates to a liquid cleaning composition comprising an antioxidant and a peroxide, and a method for cleaning a hard surface using these compositions.
家庭用器具の表面の洗浄には、脂肪質/油性/油脂性の汚れ及び/または付着固体屑もしくは有色物のような目に見える汚染の除去を促進する1種または複数の成分を含有している組成物を使用するのが普通である。このような組成物を、そのまま薄めないでまたは希釈溶液として、トリガスプレーディスペンサーまたは別のエアロゾルアプリケーターから分注または噴霧によって塗布し、クロスまたはその他の拭取り用品によって磨き、場合によってはその後にすすぎ落とす。 Cleaning the surface of household appliances contains one or more ingredients that facilitate the removal of fatty / oily / greasy soils and / or visible contamination such as adhering solid debris or colored matter. It is common to use compositions that are present. Such compositions are applied neat or as a diluting solution by dispensing or spraying from a trigger spray dispenser or another aerosol applicator, polished with a cloth or other wiping article, and optionally rinsed off thereafter. .
日本特許公開JP−A−07/228,892は、アニオン性及び両性の界面活性剤と、一価または多価のアルコールと、0.1−7重量%の茶の葉エキスとを含む硬質表面洗浄組成物を開示している。タンニンは茶の成分として公知であるが、タンニン酸(酸化防止剤)はこのようなエキス中に極めて少量しか存在しない。タンニンは一般に洗浄、特に油性汚れの洗浄には逆効果を与えると言われている。 Japanese Patent Publication JP-A-07 / 228,892 is a hard surface comprising anionic and amphoteric surfactants, mono- or polyhydric alcohols, and 0.1-7 wt% tea leaf extract. A cleaning composition is disclosed. Although tannin is known as a component of tea, tannic acid (antioxidant) is present in very small amounts in such extracts. Tannins are generally said to have an adverse effect on cleaning, especially on oily soils.
硬質表面の洗浄用及び/または消毒用の製品に茶の葉またはその他の植物の葉のエキスを使用することは他にも、日本特許公開JP−A−07/228,890及び’’891、JP−A−08/104,893、JP−A−10/273,698、JP−A−11/100,596、JP−A−06/340,897、JP−A−63/196,693、JP−A−62/167,400、JP−A−59/047,300及び米国特許US4,220,676などに開示されている。但し、最後の2つの特許に開示された製品は界面活性剤を含有しない。 The use of tea leaves or other plant leaf extracts in hard surface cleaning and / or disinfecting products is also known from JP-A-07 / 228,890 and '' 891, JP-A-08 / 104,893, JP-A-10 / 273,698, JP-A-11 / 100,596, JP-A-06 / 340,897, JP-A-63 / 196,693, JP-A-62 / 167,400, JP-A-59 / 047,300 and U.S. Pat. No. 4,220,676. However, the products disclosed in the last two patents do not contain a surfactant.
米国特許US5,965,514は、アミンオキシド界面活性剤と第四級消毒剤と窒素含有キレート化剤とを含有している弱酸性の硬質表面洗浄組成物を開示している。アスコルビン酸は酸性度を与えることが可能な多くの酸の1つであると記載されているが好ましい酸には含まれていない。タンニン酸は表面張力低下剤として場合によっては使用することが可能な多くの酸の1つであると記載されている。 US Pat. No. 5,965,514 discloses a weakly acidic hard surface cleaning composition containing an amine oxide surfactant, a quaternary disinfectant and a nitrogen-containing chelating agent. Ascorbic acid is described as one of many acids capable of imparting acidity, but is not included in the preferred acids. Tannic acid is described as one of many acids that can optionally be used as a surface tension reducing agent.
ガラス防曇剤は日本特許公開JP−A−49/113,811に記載されている。これは、3重量%のジアルキルスルホスクシネートアニオン性界面活性剤と、4重量%の高級第二級アルコキシエチルスルフェートアニオン性界面活性剤と、1重量%のタンニン酸と、10重量%のプロピレングリコールと、5重量%のイソプロピルアルコールと、77重量%の水とを含む。 Glass antifogging agents are described in Japanese Patent Publication JP-A-49 / 113,811. This comprises 3% by weight dialkyl sulfosuccinate anionic surfactant, 4% by weight higher secondary alkoxyethyl sulfate anionic surfactant, 1% by weight tannic acid and 10% by weight Contains propylene glycol, 5 wt% isopropyl alcohol, and 77 wt% water.
米国特許US5,602,090は、リモネンのような容易に酸化し得るテルペンと過酸化水素とを含有している洗浄組成物を開示している。実施例の配合物は0.02%のブチル化ヒドロキシアニソールを酸化防止剤として含有している。 US Pat. No. 5,602,090 discloses a cleaning composition containing an easily oxidizable terpene such as limonene and hydrogen peroxide. The example formulations contain 0.02% butylated hydroxyanisole as an antioxidant.
欧州特許EP209228、国際特許WO97/02331、欧州特許EP844302、EP1069178は、界面活性剤と、過酸化水素のような過酸化物漂白剤と、種々のラジカル捕捉剤とを含む布漂白用組成物を開示している。プロピルガレート、ブチル−ヒドロキシアニソール及び部分的に束縛された置換ヒドロキシベンゼンが記載されている。アスコルビン酸及びアスコルビルエステルが追加成分として記載されている。米国特許US6,110,883は、8よりも高いpHを有している同様の組成物を開示している。 European Patent EP209228, International Patent WO97 / 02331, European Patent EP844302, EP1069178 disclose a fabric bleaching composition comprising a surfactant, a peroxide bleaching agent such as hydrogen peroxide, and various radical scavengers. doing. Propyl gallate, butyl-hydroxyanisole and partially constrained substituted hydroxybenzene are described. Ascorbic acid and ascorbyl esters are listed as additional components. US Pat. No. 6,110,883 discloses a similar composition having a pH higher than 8. US Pat.
米国特許US6,296,880は、種々の皮膚異常を治療するための薬用皮膚洗浄組成物を開示している。組成物は、好ましくは少なくとも1%の量のタンニン酸のような酸性化合物と、ある量の過酸化水素と、皮膚の微生物を減少させるために十分な量の抗菌剤とを含有している。組成物は更に酸化防止剤を含み得る。 US Pat. No. 6,296,880 discloses medicinal skin cleansing compositions for treating various skin abnormalities. The composition preferably contains an amount of an acidic compound such as tannic acid in an amount of at least 1%, an amount of hydrogen peroxide, and an antimicrobial agent sufficient to reduce skin microorganisms. The composition may further comprise an antioxidant.
しかしながら、酸化防止剤による表面の処理が、その後に該表面に付着した油性汚れの除去に確実な効果を有し得ることは従来技術の何処にも開示されていない。 However, it is not disclosed anywhere in the prior art that treatment of a surface with an antioxidant can have a positive effect on the removal of oily soils subsequently adhered to the surface.
欧州特許EP447553は、過酸化水素またはその前駆物質と、過酸化水素と共に過酸を生成する過酸前駆物質と、場合によっては界面活性剤とを含む硬質表面洗浄用の漂白組成物を開示した。過酸前駆物質は、アルコキシル化した脂肪族またはアリール脂肪族(araliphatic)のカルボン酸である。過酸は過酸化水素(または前駆物質)と過酸前駆物質とをpH5−13で混合することによって組成物の使用直前に生成される。従って、過酸化水素と過酸前駆物質とを別々に保存しなければならない。時期尚早な酸化を防止するために場合によっては過酸前駆物質に酸化防止剤を添加する。 European patent EP447553 disclosed a bleaching composition for hard surface cleaning comprising hydrogen peroxide or a precursor thereof, a peracid precursor that forms a peracid with hydrogen peroxide, and optionally a surfactant. The peracid precursor is an alkoxylated aliphatic or arylaliphatic carboxylic acid. Peracid is generated immediately prior to use of the composition by mixing hydrogen peroxide (or precursor) and peracid precursor at pH 5-13. Therefore, hydrogen peroxide and peracid precursors must be stored separately. In order to prevent premature oxidation, an antioxidant is optionally added to the peracid precursor.
硬質表面上の有色の汚れ及びしみを漂白するために過酸化水素を使用できることは公知であるが、過酸化水素が全般的に硬質表面からの汚れ(有色であるか無色であるかにかかわりなく)の除去を促進することが意外にも知見された。 It is known that hydrogen peroxide can be used to bleach colored stains and stains on hard surfaces, but hydrogen peroxide is generally soiled from hard surfaces (whether colored or colorless). It was unexpectedly found to promote the removal of).
また、ある種の酸化防止剤が硬質表面上に存在するとき、該酸化防止剤は後で該表面に付着した油性汚れが該表面に粘着することを防止し、従って油性汚れのその後の除去を容易にするという意外な知見も得られた。 Also, when certain antioxidants are present on a hard surface, the antioxidants prevent oily soils that subsequently adhere to the surface from sticking to the surface, thus preventing subsequent removal of oily soils. The surprising knowledge of making it easy was also obtained.
もっと意外なことにはまた、過酸化水素とこれらの酸化防止剤とが1つの液体洗浄組成物中に一緒に存在するときには、過酸化水素が酸化防止剤の活性を妨害することも逆に酸化防止剤が過酸化水素の活性を妨害することもなく双方の活性が独立に維持されることが知見された。組成物は、貯蔵中に過酸化水素または酸化防止剤の活性を喪失することなく貯蔵安定である。 More surprisingly, when hydrogen peroxide and these antioxidants are present together in one liquid cleaning composition, it is also oxidized that hydrogen peroxide interferes with the activity of the antioxidant. It has been found that the inhibitor maintains both activities independently without interfering with the activity of hydrogen peroxide. The composition is storage stable without loss of hydrogen peroxide or antioxidant activity during storage.
更に、消費者は洗浄組成物の成分として刺激の少ない成分を好むが、天然の成分、より特定的には天然の酸化防止剤が刺激の少ない成分であることは一般に認められている。 Further, although consumers prefer less irritating ingredients as components of cleaning compositions, it is generally accepted that natural ingredients, and more particularly natural antioxidants, are less irritating ingredients.
従って1つの目的によれば本発明は、
(a)ラジカル捕捉用酸化防止剤と過酸化水素とを含む液体洗浄組成物で硬質表面を処理する段階と、
(b)脂肪質汚れの付着を放置する段階と、
(c)脂肪質汚れを除去するために表面を洗浄する段階と、
を順次に含む硬質表面から脂肪質汚れを除去する方法を提供する。
Thus, according to one object, the present invention provides:
(A) treating the hard surface with a liquid cleaning composition comprising a radical scavenging antioxidant and hydrogen peroxide;
(B) leaving the deposits of fatty dirt;
(C) cleaning the surface to remove fatty soils;
The present invention provides a method for removing fatty soils from a hard surface that sequentially contains.
本発明の第二の目的は、過酸化水素と天然のラジカル捕捉用酸化防止剤とを含む液体洗浄組成物を提供することである。 A second object of the present invention is to provide a liquid cleaning composition comprising hydrogen peroxide and a natural radical scavenging antioxidant.
本発明の第三の目的は、硬質表面から脂肪質汚れを除去するためにラジカル捕捉用酸化防止剤と過酸化水素との併用を提案することである。 The third object of the present invention is to propose the combined use of radical scavenging antioxidant and hydrogen peroxide to remove fatty soils from hard surfaces.
何らかの特定の理論または説明に拘束はされないが、ラジカル捕捉用酸化防止剤が段階(a)で表面に維持されることによってその効果を発揮し、その結果としてその後に段階(b)で表面に付着した油脂性汚れが強固になったりまたは重合したりせず、従って段階(c)における汚れ除去が容易になると考えられる。従って、本発明の第一の目的の1つの実施態様では、例えば酸化防止剤と過酸化水素とを含む溶液または液体組成物が表面で乾燥することによって段階(a)において酸化防止剤を含む膜が形成される。段階(c)は、同じく酸化防止剤と過酸化水素とを含む硬質表面洗浄組成物を使用して行うのが有利であり、その結果として汚れが除去され同時に新しい酸化防止剤が塗布される。即ち、本発明の第一目的による第一方法の段階(c)と本発明のこの目的による後続方法の段階(a)とが効果的に合併する。場合によっては段階(c)の後で通常は水によるすすぎ段階を行ってもよい。 Without being bound by any particular theory or explanation, the radical scavenging antioxidant is exerted by maintaining it on the surface in step (a) and as a result subsequently deposited on the surface in step (b) It is believed that the oleaginous soil does not become strong or does not polymerize, thus facilitating soil removal in step (c). Accordingly, in one embodiment of the first object of the present invention, a film comprising an antioxidant in step (a), for example by drying on the surface a solution or liquid composition comprising an antioxidant and hydrogen peroxide. Is formed. Step (c) is advantageously performed using a hard surface cleaning composition that also contains an antioxidant and hydrogen peroxide, so that the soil is removed and a new antioxidant is applied at the same time. That is, step (c) of the first method according to the first object of the present invention and step (a) of the subsequent method according to this object of the present invention are effectively merged. In some cases, step (c) may be followed by a normal water rinsing step.
やはり何らかの理論または説明に拘束はされないが、過酸化水素が汚れ除去を促進するのは一般的に、硬質表面上の過酸化水素の分解によって極めて小さい酸素気泡が発生しこの気泡が汚れを弛緩させ表面から汚れを除去するからであると考えられる。 Again, without being bound by any theory or explanation, hydrogen peroxide generally facilitates soil removal, with the decomposition of hydrogen peroxide on a hard surface generally generating very small oxygen bubbles that relax the soil. This is considered to be because the dirt is removed from the surface.
方法に使用される液体組成物中の酸化防止剤は本文中で後述するように合成または天然のいかなるラジカル捕捉用酸化防止剤でもよい。好ましくは、酸化防止剤は天然の酸化防止剤である。液体組成物は好ましくは少なくとも0.05重量%、より好ましくは0.1−10重量%、いっそう好ましくは少なくとも0.2重量%の酸化防止剤を含む。一般的に2%を上回る量、または1%を上回る量さえも不要であり、一般的に1%未満または多くても0.5%で十分である。また、酸化防止剤の混合物を使用してもよい。 The antioxidant in the liquid composition used in the process may be any synthetic or natural antioxidant for scavenging radicals as described later in the text. Preferably, the antioxidant is a natural antioxidant. The liquid composition preferably comprises at least 0.05 wt%, more preferably 0.1-10 wt%, even more preferably at least 0.2 wt% antioxidant. In general, amounts greater than 2%, or even greater than 1% are not required, and generally less than 1% or at most 0.5% is sufficient. A mixture of antioxidants may also be used.
方法に使用される組成物はまた、過酸化水素を、好ましくは0.1−10%、より好ましくは少なくとも1%の量で含む。一般的に5%よりも多い量は不要であり、多すぎる量は敏感な表面を傷つけることもあり得る。 The composition used in the process also comprises hydrogen peroxide, preferably in an amount of 0.1-10%, more preferably at least 1%. In general, amounts greater than 5% are not required, and amounts that are too high can damage sensitive surfaces.
方法に使用される組成物が場合によっては、後述するような界面活性剤を1種または複数種含有するのが好ましい。更に、組成物が洗浄組成物に慣用のその他の任意成分を含有してもよい。 In some cases, the composition used in the method preferably contains one or more surfactants as described below. In addition, the composition may contain other optional ingredients commonly used in cleaning compositions.
本文中に使用した“汚れ”という用語は、肉眼で見えるか見えないかにかかわりなく固体屑の汚れ及び/または細菌もしくはその他の病原体による汚れのような有機系または無機系のあらゆる種類の汚染または汚れを包含する。概説したように、本発明は、脂肪質汚れ、より特定的には古くなったりまたは焼き付いたりした脂肪質汚れをより容易に除去するために特に効果的である。例えば調理場の表面にしばしば見出されるこのような汚れは通常は、油/脂肪成分とデンプン質及び/またはタンパク質性の食物滓、塵埃、石灰質の水垢(lime scale)などのような別の汚れ成分との組合せを含む。本発明はまた、石灰質の水垢、水跡及び同様のしみの除去にも効果的である。 As used herein, the term “dirt” refers to any kind of organic or inorganic contamination or dirt, such as solid waste dirt and / or dirt from bacteria or other pathogens, whether visible or invisible to the naked eye. Is included. As outlined, the present invention is particularly effective for more easily removing fatty soils, and more particularly, old or seized fat soils. For example, such soils often found on the surface of a kitchen are usually oil / fat components and other soil components such as starchy and / or proteinaceous food baskets, dust, lime scales, etc. Including combinations. The present invention is also effective in removing calcareous scale, water marks and similar stains.
本発明はまた、洗浄中及び/または洗浄後の表面の触質性(例えば、滑らかさ)の改善、酸敗臭の抑制、洗浄前の汚れの黒ずみの抑制、表面腐食の抑制及び洗浄中の騒音の抑制のような1つまたは複数の他の利点を与え得る。 The present invention also improves surface texture (eg, smoothness) during and / or after cleaning, controls acid odor, controls darkening of dirt before cleaning, controls surface corrosion, and noise during cleaning. One or more other advantages such as suppression of
本発明による方法、使用、組成物及びその他の製品は、例えば調理場及び寝室にある家財の硬質表面、例えば、調理台、換気扇、作業用表面、調理器具、陶器類、タイル、床、浴槽、便器、洗面台、シャワー、皿洗い機、蛇口、流し台、並びに、ガラス表面及び琺瑯表面全般の手入れに使用し得る。これらの表面が、例えば、塗料(例えば、塗装木材またはラッカー仕上げ木材)、プラスチック、ガラス、セラミックまたは金属(例えば、ステンレススチールまたはクロム)から成っていてもよい。 The methods, uses, compositions and other products according to the invention are for example hard surfaces of household goods, such as in kitchens and bedrooms, such as worktops, exhaust fans, work surfaces, cookware, ceramics, tiles, floors, bathtubs, It can be used to clean toilet bowls, washbasins, showers, dishwashers, faucets, sinks, and general glass and basket surfaces. These surfaces may be made of, for example, paint (eg painted wood or lacquered wood), plastic, glass, ceramic or metal (eg stainless steel or chrome).
酸化防止剤
Ingold K.V.Adv.Chem.Ser.75,296−305(1968)“Inhibition of Auto−oxidation”に開示されているように、酸化防止剤は2つのグループ、即ち、脂質ラジカルと反応してより安定なラジカルを形成する一次的酸化防止剤即ち鎖破壊性酸化防止剤と、種々のメカニズムによる連鎖開始の速度を減速させる二次的(または予防的)酸化防止剤とに分類される。酸化防止剤はまた、合成の酸化防止剤または“天然の”、即ち、天然産物に由来の酸化防止剤に分類し得る。
Antioxidant Ingold K.K. V. Adv. Chem. Ser. 75 , 296-305 (1968) "Inhibition of Auto-oxidation", antioxidants are primary groups that react with lipid radicals to form more stable radicals. Categorized into agents, ie chain-breaking antioxidants, and secondary (or prophylactic) antioxidants that slow down the rate of chain initiation by various mechanisms. Antioxidants can also be classified as synthetic antioxidants or "natural", ie, antioxidants derived from natural products.
本発明の方法、使用、加工品及び組成物に使用し得る酸化防止剤のクラス、サブクラス及び特定例を以下に示す。本文中に使用した単数形の“酸化防止剤”という用語は1種類の酸化防止剤及び2種以上の酸化防止剤の併用を意味する。 The classes, subclasses and specific examples of antioxidants that can be used in the methods, uses, processed articles and compositions of the present invention are shown below. As used herein, the term “antioxidant” in the singular means a combination of one type of antioxidant and two or more types of antioxidants.
A.合成酸化防止剤
一般に、一次的酸化防止剤は更に鎖破壊アクセプターと鎖破壊ドナーとに細分される。
A. Synthetic antioxidants In general, primary antioxidants are further subdivided into chain break acceptors and chain break donors.
鎖破壊アクセプター(ときには“予防的酸化防止剤”と呼ばれる)はヒドロペルオキシドを(非ラジカルの)安定な最終生成物に分解することによって酸化速度を減速させる。 Chain break acceptors (sometimes referred to as “prophylactic antioxidants”) slow the rate of oxidation by breaking down hydroperoxides into (non-radical) stable end products.
“水素供与性酸化防止剤またはラジカル捕捉剤”とも呼ばれる鎖破壊ドナーはペルオキシラジカルに対して有機物と競合することによって機能する。 Chain-breaking donors, also called “hydrogen-donating antioxidants or radical scavengers”, function by competing with organics for peroxy radicals.
B.天然酸化防止剤
天然の抗酸化性化合物が特に好ましい。天然成分は多くの消費者に極めて好評である。調理中の食物に接触する可能性のある表面に安全に使用できると考えられる酸化防止剤が特に好ましい。
B. Natural antioxidants Natural antioxidant compounds are particularly preferred. Natural ingredients are very popular with many consumers. Antioxidants that are considered safe to use on surfaces that may come into contact with food being cooked are particularly preferred.
抗酸化活性を示す種々の天然材料資源が報告されており、例えば、香草、香辛料、穀物、コーヒーとコーヒー豆、油と種子、茶の葉及びタンパク質加水分解物がある。抗酸化活性を示す成分としてエキスから単離された活性化合物としては、化学的クラスの化合物、例えば、トコフェロール、フラボノイド、リン脂質、有機酸とそれらの誘導体、タンニン、メラノイジン、テルペノイド、ステロール、メイラード反応生成物及びアミノ酸がある。酸化防止剤はその構造次第で水溶性または油溶性である。双方の種類が本発明に有用である。 Various natural material resources that exhibit antioxidant activity have been reported, such as herbs, spices, cereals, coffee and coffee beans, oil and seeds, tea leaves and protein hydrolysates. Active compounds isolated from extracts as components exhibiting antioxidant activity include chemical classes of compounds such as tocopherols, flavonoids, phospholipids, organic acids and their derivatives, tannins, melanoidins, terpenoids, sterols, Maillard reactions There are products and amino acids. Antioxidants are water-soluble or oil-soluble depending on their structure. Both types are useful in the present invention.
カルノソール、カルノシン酸、ロスマノール、ロスマリン酸、ロスマリキノン及びロスマリジフェノールは抗酸化活性を示すローズマリーの葉の有効成分として知られている。更に、2種類の主要なフェノール系抗酸化成分、没食子酸及びオイゲノールはクローブに由来する。セージ、マジョラム、オルガノ及びタイムのような香草及び香辛料のエキスから単離された多くの成分のうちの幾つかは潜在的な抗酸化性を有することが知られている。その他の天然酸化防止剤としては、β−カロテン、カフェー酸、キニン酸及びフェルラ酸並びにカフェー酸とステロール(シトステロール、カンペステロール、グラミステロール及びシクロアルテノール)とのエステルがある。ステロール及びカフェー酸のトリテルペンアルコールエステルは適当でない。潜在的抗酸化活性を示すことが知られているこのような化合物の別の例はシンナミン酸、シナピン酸、バニリン酸、シリンギン酸及びクマリン酸である。 Carnosol, carnosic acid, rosmanol, rosmarinic acid, rosmariquinone and rosmaridiphenol are known as active ingredients of rosemary leaves exhibiting antioxidant activity. In addition, two major phenolic antioxidant components, gallic acid and eugenol are derived from cloves. Some of the many ingredients isolated from herbal and spice extracts such as sage, marjoram, organo and thyme are known to have potential antioxidant properties. Other natural antioxidants include β-carotene, caffeic acid, quinic acid and ferulic acid, and esters of caffeic acid and sterols (sitosterol, campesterol, glamisterol and cycloartenol). Triterpene alcohol esters of sterols and caffeic acids are not suitable. Other examples of such compounds known to exhibit potential antioxidant activity are cinnamic acid, sinapinic acid, vanillic acid, syringic acid and coumaric acid.
カルダノールはフェノール環にメタ(3−)15−炭素鎖をもつモノヒドロキシルフェノールの混合物である。これは、カシューナッツ殻の液体から蒸留物として単離される。アナカルジン酸(3−n−ペンタデシルサリチル酸)が主成分(80−85%)であり、カルダノール(3−n−ペンタデシル−フェノール)及びカルドール(3−n−ペンタデシル−レゾルシノール)及びメチルカルダノール(2−メチル−5−n−ペンタデシル−レゾルシノール)が少量ずつ存在している。カルドール及びカルダノールは市販されている。オリザノールは、高分子量及び低揮発度を有しているフェルラ酸(4−ヒドロキシ−3−メトキシシンナミン酸)と反応したエステル化ステロールのグループを意味する。セサモール、セサミノール及びセサモリノ化合物はゴマ油の成分であり抗酸化性を有している。セサモールは容易に酸化してセサモールダイマーとなり、更に酸化するとセサモールキノンダイマーとなる。 Cardanol is a mixture of monohydroxylphenols with a meta (3-) 15-carbon chain in the phenolic ring. It is isolated as a distillate from cashew nut shell liquid. Anacardic acid (3-n-pentadecylsalicylic acid) is the main component (80-85%), cardanol (3-n-pentadecyl-phenol) and cardol (3-n-pentadecyl-resorcinol) and methylcardanol (2 -Methyl-5-n-pentadecyl-resorcinol) is present in small amounts. Cardol and cardanol are commercially available. Oryzanol means a group of esterified sterols that have reacted with ferulic acid (4-hydroxy-3-methoxycinnamic acid) having a high molecular weight and low volatility. Sesamol, sesaminol and sesamolino compounds are components of sesame oil and have antioxidant properties. Sesamol is easily oxidized to sesamol dimer, and further oxidized to sesamol quinone dimer.
トコフェロールは強力な抗酸化活性を示す。ある種の条件下でトコフェロールは油中でより高い分子量の材料、例えば、ダイマー、トライマー、などを形成し得る。トコトリエノールは近縁クラスの化合物であり、構造的な違いは、飽和フィチル鎖の代わりに不飽和側鎖を有していることである。トコトリエノールの抗酸化活性はトコフェロールが示す抗酸化活性よりも弱い。 Tocopherol exhibits strong antioxidant activity. Under certain conditions, tocopherols can form higher molecular weight materials in oils such as dimers, trimers, and the like. Tocotrienols are a closely related class of compounds, and the structural difference is that they have unsaturated side chains instead of saturated phytyl chains. The antioxidant activity of tocotrienol is weaker than that of tocopherol.
フラボノイドのクラスは、フラボノール、フラボン、イソフラボン、アントシアニン、カテキン、プロアントシアニジン及びアウロンなどを主な構成員とするサブグループに分類される。近縁化合物にはシンナミン酸及びフェルラ酸とそれらのエステルがある。これらのあるものはフラボノイドの前駆物質である。茶の葉は廉価で入手容易な豊富なフラボノイド(主としてカテキン)資源である。フラボノイドは酸化されると、それ自体が抗酸化活性を示す複合ポリフェノール構造と共にポリマーを形成する。没食子酸エピガロカテキンはアスコルビン酸、トコフェロール、クエン酸及び酒石酸と共に茶の葉から協同抽出され得る。 The flavonoid class is classified into subgroups mainly composed of flavonols, flavones, isoflavones, anthocyanins, catechins, proanthocyanidins and aurones. Related compounds include cinnamic acid and ferulic acid and their esters. Some of these are flavonoid precursors. Tea leaves are an abundant and readily available flavonoid (mainly catechin) resource. When flavonoids are oxidized, they form polymers with complex polyphenolic structures that themselves exhibit antioxidant activity. Epigallocatechin gallate can be extracted from tea leaves together with ascorbic acid, tocopherol, citric acid and tartaric acid.
ルチン及びクロロゲン酸もまた抗酸化活性を示し、芳香族官能基に結合した糖部分を有している。この種の化合物は水相と有機(脂質)相との間で分配できるので特に重要である。 Rutin and chlorogenic acid also exhibit antioxidant activity and have a sugar moiety attached to an aromatic functional group. This type of compound is particularly important because it can partition between the aqueous phase and the organic (lipid) phase.
別のグループの天然酸化防止剤はタンニン、タンニン酸及び近縁化合物である。これは植物由来のポリフェノール化合物の大グループである。タンニンの特徴はタンパク質を沈殿させる能力を有していることである。 Another group of natural antioxidants are tannins, tannic acid and related compounds. This is a large group of plant-derived polyphenol compounds. The characteristic of tannin is that it has the ability to precipitate proteins.
酸化防止剤の構造
本発明の目的に適う好ましい酸化防止剤は、1,2−ジヒドロキシベンゼンもしくは1,4−ジヒドロキシベンゼンの下部構造または1つのOHのHが有機基で置換されたその誘導体を含有する天然の酸化防止剤である。有機基は−Rまたは−CORでよく、このRは好ましくは(置換)アルキル基、アルケニル基、炭素環基または複素環基である。
Antioxidant Structure Preferred antioxidants suitable for the purposes of the present invention include 1,2-dihydroxybenzene or 1,4-dihydroxybenzene substructure or derivatives thereof in which one OH H is replaced by an organic group. Is a natural antioxidant. The organic group may be -R or -COR, where R is preferably a (substituted) alkyl group, an alkenyl group, a carbocyclic group or a heterocyclic group.
1,2−ジヒドロキシベンゼン(誘導体)の下部構造を有している化合物の適例は、カフェー酸、フェルラ酸、ロスマリン酸及びバニリン酸とそれらのアミド、エステル、塩及び同様の誘導体、並びに、セサモール及びその誘導体である。1,4−ジヒドロキシベンゼン誘導体の下部構造を有している化合物の適例は、トコフェロール及びトコトリエノールであり、該化合物中でベンゼン環の一部とフェノール酸素の1つとが一緒に縮合複素環の一部を形成している。 Suitable examples of compounds having a substructure of 1,2-dihydroxybenzene (derivatives) are caffeic acid, ferulic acid, rosmarinic acid and vanillic acid and their amides, esters, salts and similar derivatives, and sesamol And its derivatives. Suitable examples of compounds having a substructure of 1,4-dihydroxybenzene derivatives are tocopherols and tocotrienols, in which a part of the benzene ring and one of the phenol oxygens together form a condensed heterocyclic ring. Forming part.
1,2−ジヒドロキシベンゼンの下部構造を有している化合物の極めて有用な特定のサブクラスは、3,4,5−トリヒドロキシベンゾイル構造またはその置換誘導体を有している化合物から形成される。即ち、没食子酸及びその天然誘導体が適当である。タンニン酸及びタンニンが特に適当である。タンニン酸及びタンニンは複数の3,4,5−トリヒドロキシベンゾイル構造単位を含有し、1つの構造単位のベンゾイル基が次の構造単位のフェノール酸素と共にエステル結合を形成している。 A very useful specific subclass of compounds having a 1,2-dihydroxybenzene substructure is formed from compounds having a 3,4,5-trihydroxybenzoyl structure or substituted derivatives thereof. That is, gallic acid and its natural derivatives are suitable. Tannic acid and tannin are particularly suitable. Tannic acid and tannin contain a plurality of 3,4,5-trihydroxybenzoyl structural units, and the benzoyl group of one structural unit forms an ester bond with the phenol oxygen of the next structural unit.
タンニン酸は本発明の目的に最も好ましい酸化防止剤である。タンニン酸はときには、ガロタンニン酸またはペンタ−(m−ジガロイル)−グルコース(C76H52O46)と呼ばれる。しかしながら、市販のタンニン酸は通常は植物または没食子、樹皮及びその他の植物部分から得られる。本文中で使用した“タンニン酸”という用語はこのような材料をすべて包含すると理解されたい。既述のように、茶のタンニン含有エキス(例えば日本特許公開JP−A−07/228,892の組成物で使用されたようなエキス)はタンニン酸含量が極めて低い。 Tannic acid is the most preferred antioxidant for the purposes of the present invention. Tannic acid is sometimes referred to as gallotannic acid or penta- (m-digaloyl) -glucose (C 76 H 52 O 46 ). However, commercially available tannic acid is usually obtained from plants or gallic, bark and other plant parts. It should be understood that the term “tannic acid” as used herein encompasses all such materials. As already mentioned, tea tannin-containing extracts (such as those used in the composition of JP-A-07 / 228,892) have a very low tannic acid content.
酸化防止剤の別の好ましいグループはトコフェロール、特にδ−トコフェロールである。 Another preferred group of antioxidants is tocopherols, especially δ-tocopherol.
液体組成物
組成物は薄めない形態または希釈した形態で表面に塗布し得る。適当な液体組成物は、溶媒中の抗酸化性材料の溶液、分散液またはエマルジョンである。溶媒は好ましくは水であるかまたは有機溶媒と水との混合物である。
The liquid composition composition can be applied to the surface in an undiluted or diluted form. Suitable liquid compositions are solutions, dispersions or emulsions of antioxidant materials in solvents. The solvent is preferably water or a mixture of an organic solvent and water.
好ましい組成物は中性または弱酸性のpH、即ち、7以下、好ましくは6以下、特に5.5以下または4.5かそれよりも低いpHを有している。しかしながら、酸感受性表面が損傷されることを避けるためには組成物が過度に酸性でないのが好ましい。好ましくはpHか少なくとも1.5または2であり、より好ましくは少なくとも2.5である。最も好ましくはpHが3−4.5の範囲である。 Preferred compositions have a neutral or slightly acidic pH, i.e. 7 or less, preferably 6 or less, in particular 5.5 or less or 4.5 or less. However, it is preferred that the composition not be too acidic to avoid damaging the acid sensitive surface. Preferably the pH is at least 1.5 or 2, more preferably at least 2.5. Most preferably, the pH is in the range of 3-4.5.
液体組成物は、薄いまたは粘性の液体またはゲルの形態でもよく、フォーム、ムースまたはペーストの形態でもよい。液体は、粘性であるかまたは21s−1の剪断速度(ブルックフィールド粘度計、20℃)で測定して少なくとも100mPas、好ましくは少なくとも150または200mPasの粘度を有しているが、好ましくは5,000mPas以下、より好ましくは2,000mPas以下の粘度を有しているゲル様液体であれば特に好ましい。剪断減粘性の液体またはゲルは硬質表面洗浄中の酸化防止剤の心地よい官能効果を増進し、特に消費者に好評であり、従って本発明の好ましい実施態様である。粘度は、1種または複数の界面活性剤と水と(通常は)電解質とを使用する“内部構造化系”によってもたらされ、組成物内部に秩序相または液晶相が生じるであろう。代替的にまたは付加的に、増粘性ポリマーを添加してもよい。多数のこのようなポリマーが当業界で公知であり、例えば、ポリ(メタ)アクリレート、ポリマレイン酸のようなポリカルボキシレート型ポリマー、(メタ)アクリル酸及び/または無水マレイン酸と種々の別のビニルモノマーとのコポリマー、または、セルロース誘導体のような多糖類、または、植物性もしくは微生物性ガム、例えばキサンタンガム、グアーガムなどが挙げられる。勿論、増粘性ポリマーは過酸化水素の存在下で安定でなければならない。 The liquid composition may be in the form of a thin or viscous liquid or gel, and may be in the form of a foam, mousse or paste. The liquid is viscous or has a viscosity of at least 100 mPas, preferably at least 150 or 200 mPas as measured at a shear rate of 21 s −1 (Brookfield viscometer, 20 ° C.), but preferably 5,000 mPas. Hereinafter, a gel-like liquid having a viscosity of 2,000 mPas or less is more preferable. Shear thinning liquids or gels enhance the pleasant sensory effect of antioxidants during hard surface cleaning and are particularly popular with consumers and are therefore a preferred embodiment of the present invention. Viscosity is provided by an “internal structuring system” that uses one or more surfactants, water, and (usually) an electrolyte, resulting in an ordered or liquid crystalline phase within the composition. Alternatively or additionally, a thickening polymer may be added. A number of such polymers are known in the art, such as poly (meth) acrylates, polycarboxylate type polymers such as polymaleic acid, (meth) acrylic acid and / or maleic anhydride and various other vinyls. Copolymers with monomers, polysaccharides such as cellulose derivatives, or vegetable or microbial gums such as xanthan gum, guar gum and the like. Of course, the thickening polymer must be stable in the presence of hydrogen peroxide.
フォーム及びムースは通常はディペンサーから供給される。ディペンサーは製品にガスまたは空気を混ぜ込んで分注する。 Foam and mousse are usually supplied by a dispenser. The dispenser mixes and dispenses gas or air into the product.
好ましい組成物は低発泡性である。または、組成物が発泡性であるかもしくはフォームとして使用されるときは泡が容易に崩壊し、泡を除去するために後で表面を再度すすいだり拭き取ったりする必要のないものが好ましい。そうすれば最大量の酸化防止剤が表面に残留する。 Preferred compositions are low foaming. Alternatively, it is preferred that the composition is foamable or that when used as a foam, the foam easily disintegrates and the surface need not be re-rinsed or wiped later to remove the foam. This will leave the maximum amount of antioxidant on the surface.
界面活性剤:
本発明の(または本発明に使用される)組成物は、洗浄用界面活性剤を含み得る。これらは一般に、アニオン性、非イオン性、両性、双イオン性またはカチオン性の界面活性剤から選択される。組成物は一般に少なくとも0.05重量%、好ましくは少なくとも0.1、0.2、0.5または1重量%であるが45重量%以下、通常は25、15または10重量%以下の総量の界面活性剤を含む。好ましくは組成物が少なくとも1種類のアニオン性及び/または非イオン性界面活性剤、より好ましくは少なくとも1種類の非イオン性界面活性剤を含む。
Surfactant :
The composition of the present invention (or used in the present invention) may comprise a cleaning surfactant. These are generally selected from anionic, nonionic, amphoteric, zwitterionic or cationic surfactants. The composition generally has a total amount of at least 0.05% by weight, preferably at least 0.1, 0.2, 0.5 or 1% by weight but no more than 45% by weight, usually no more than 25, 15 or 10% by weight. Contains a surfactant. Preferably the composition comprises at least one anionic and / or nonionic surfactant, more preferably at least one nonionic surfactant.
適当な合成(ノンソープ)アニオン性界面活性剤は、分子構造中に8−22個の炭素原子を含むアルキル基を有している有機硫酸エステル及びスルホン酸の水溶性塩である。 Suitable synthetic (non-soap) anionic surfactants are water-soluble salts of organic sulfates and sulfonic acids having an alkyl group containing 8-22 carbon atoms in the molecular structure.
このようなアニオン性界面活性剤の例は、以下のような化合物の水溶性塩である:
−(第一級)長鎖(例えば、炭素原子数8−22)アルコールスルフェート(本文中で以後PASと呼ぶ)、特に、牛脂またはココヤシ油のグリセリドの還元によって得られた脂肪アルコールの硫酸化によって得られたもの;
−アルキルベンゼンスルホネート、例えば、アルキル基が6−20個の炭素原子を含有しているもの;
−第二級アルカンスルホネート。
Examples of such anionic surfactants are water-soluble salts of the following compounds:
Sulfation of fatty alcohols obtained by reduction of (primary) long chain (eg 8-22 carbon atoms) alcohol sulfate (hereinafter referred to as PAS), in particular beef tallow or coconut oil glycerides Obtained by:
Alkyl benzene sulfonates, for example those in which the alkyl group contains 6-20 carbon atoms;
Secondary alkane sulfonate.
以下の化合物の塩も適当である:
−アルキルグリセリルエーテルスルフェート、特に、牛脂及びココヤシ油に由来の脂肪アルコールから得られたこのようなエーテル;
−脂肪酸モノグリセリドスルフェート;
−1モルの脂肪アルコールと1−6モルのエチレンオキシドとの反応生成物のスルフェート;
−1分子あたり1−8個のエチレンオキシ単位を有しておりアルキル基が4−14個の炭素原子を含んでいるアルキルフェノールエチレンオキシ−エーテルスルフェートの塩;
−イセチオン酸でエステル化しアルカリで中和した脂肪酸の反応生成物;
及びそれらの混合物。
Also suitable are salts of the following compounds:
Alkyl glyceryl ether sulfates, in particular such ethers obtained from fatty alcohols derived from beef tallow and coconut oil;
-Fatty acid monoglyceride sulfates;
Sulfate of the reaction product of -1 mol fatty alcohol and 1-6 mol ethylene oxide;
A salt of an alkylphenol ethyleneoxy-ether sulfate having 1-8 ethyleneoxy units per molecule and the alkyl group containing 4-14 carbon atoms;
A reaction product of a fatty acid esterified with isethionic acid and neutralized with alkali;
And mixtures thereof.
好ましい水溶性合成アニオン性界面活性剤は、アルキル−ベンゼンスルホネート及びオレフィンスルホネートとの混合物、及び、アルキルスルフェート、及び、脂肪酸モノ−グリセリドスルフェートのアルカリ金属(例えば、ナトリウム及びカリウム)塩及びアルカリ土類金属(例えば、カルシウム及びマグネシウム)塩である。最も好ましいアニオン性界面活性剤は、直鎖または分枝鎖のアルキル基に6−20個の炭素原子を含んでいるアルキルベンゼンスルホネートのようなアルキル−芳香族スルホネートであり、その特定例は、アルキルベンゼンスルホン酸ナトリウムまたはアルキル−トルエン−、−キシレン−もしくは−フェノールスルホン酸ナトリウム、アルキルナフタレン−スルホン酸ナトリウム、ジアミルナフタレン−スルホン酸アンモニウム、ジノニル−ナフタレン−スルホン酸ナトリウムである。 Preferred water-soluble synthetic anionic surfactants include mixtures of alkyl-benzene sulfonates and olefin sulfonates, and alkali metal (eg, sodium and potassium) salts and alkaline earths of alkyl sulfates and fatty acid mono-glyceride sulfates. Metal salts (for example, calcium and magnesium). The most preferred anionic surfactants are alkyl-aromatic sulfonates, such as alkyl benzene sulfonates containing 6-20 carbon atoms in a linear or branched alkyl group, specific examples of which are alkyl benzene sulfonates. Sodium acid or alkyl-toluene-, -xylene- or -phenolsulfonic acid sodium, alkylnaphthalene-sodium sulfonate, diamyl naphthalene-ammonium sulfonate, dinonyl-naphthalene-sodium sulfonate.
合成アニオン性界面活性剤を使用する場合、本発明の組成物中に存在する量は一般には少なくとも0.2%、好ましくは少なくとも0.5%、より好ましくは少なくとも1.0%であるが、20%以下、好ましくは10%以下、より好ましくは8%以下であろう。 When using synthetic anionic surfactants, the amount present in the composition of the present invention is generally at least 0.2%, preferably at least 0.5%, more preferably at least 1.0%, It will be 20% or less, preferably 10% or less, more preferably 8% or less.
適当な非イオン性界面活性剤は広義には、親水性の性質をもつアルキレンオキシド基と脂肪族またはアルキル芳香族の性質をもつ有機疎水性化合物との縮合によって生成される化合物であると記述できる。特定の疎水性基に結合した親水性またはポリオキシアルキレンラジカルの長さは、親水性要素と疎水性要素との間に所望のバランスを有する水溶性化合物が生じるように容易に調節できる。これによって、正しいHLBをもつ非イオン性界面活性剤の選択が可能になる。 A suitable nonionic surfactant can be broadly described as a compound formed by the condensation of an alkylene oxide group with hydrophilic properties and an organic hydrophobic compound with aliphatic or alkylaromatic properties. . The length of the hydrophilic or polyoxyalkylene radical attached to a particular hydrophobic group can be easily adjusted to produce a water soluble compound having the desired balance between the hydrophilic and hydrophobic elements. This allows the selection of nonionic surfactants with the correct HLB.
特定例は、8−22個の炭素原子を有している直鎖形状または分枝鎖形状の脂肪族アルコールとエチレンオキシドとの縮合生成物、例えばココヤシアルコール1モルあたり2−15モルのエチレンオキシドを有しているココヤシ油エチレンオキシド縮合物;アルキル基に6−12個の炭素原子を有しているアルキルフェノールとアルキルフェノール1モルあたり5−25モルのエチレンオキシドとの縮合物;エチレンジアミンとプロピレンオキシドとの反応生成物とエチレンオキシドとの縮合物、この縮合物は40−80重量%のエチレンオキシ基を含んでおり5,000−11,000の分子量を有している。 Specific examples include condensation products of linear or branched aliphatic alcohols having 8-22 carbon atoms with ethylene oxide, such as 2-15 moles of ethylene oxide per mole of coconut alcohol. Coconut oil ethylene oxide condensate; condensate of alkylphenol having 6-12 carbon atoms in the alkyl group with 5-25 moles of ethylene oxide per mole of alkylphenol; reaction product of ethylenediamine and propylene oxide And a condensate of ethylene oxide, which contains 40-80% by weight of ethyleneoxy groups and has a molecular weight of 5,000-11,000.
別の例は:長鎖脂肪族アルコールと糖との縮合生成物であるアルキルグリコシド;RRRNOで表される構造を有しており、1つのRが炭素原子数8−18のアルキル基を表し、残りのRの各々が炭素原子数1−3のアルキル基またはヒドロキシアルキル基を表す第三級アミンオキシド、例えばジメチルドデシルアミンオキシド;RRRPOで表される構造を有しており、1つのRが炭素原子数8−18のアルキル基を表し、残りのRの各々が炭素原子数1−3のアルキル基またはヒドロキシアルキル基を表す第三ホスフィンオキシド、例えば、ジメチル−ドデシルホスフィンオキシド;及び、RRSOで表される構造を有しており、一方のRが炭素原子数10−18のアルキル基を表し、他方のRがメチルまたはエチルを表すジアルキルスルホキシド、例えば、メチルテトラデシルスルホキシド;脂肪酸アルキロールアミド;脂肪酸アルキロールアミドとアルキルメルカプタンとのアルキレンオキシド縮合物である。エトキシル化脂肪族アルコールが特に好ましい。 Another example is: an alkyl glycoside that is a condensation product of a long-chain aliphatic alcohol and a sugar; having a structure represented by RRRNO, wherein one R represents an alkyl group having 8 to 18 carbon atoms, Each of the remaining Rs has a structure represented by a tertiary amine oxide such as dimethyldodecylamine oxide; RRRPO, each of which represents an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group; A tertiary phosphine oxide, such as dimethyl-dodecylphosphine oxide, which represents an alkyl group of 8-18 atoms and each remaining R represents an alkyl group of 1-3 carbon atoms or a hydroxyalkyl group; In which one R represents an alkyl group having 10 to 18 carbon atoms and the other R represents methyl or ethyl. Sulfoxide, e.g., methyl tetradecyl sulphoxide; an alkylene oxide condensates of fatty acid alkylolamides and alkyl mercaptans; fatty alkylol amide. Ethoxylated fatty alcohols are particularly preferred.
本発明の洗浄組成物中に使用すべき非イオン性界面活性剤の量は好ましくは少なくとも0.1重量%、より好ましくは少なくとも0.2重量%、最も好ましくは少なくとも0.5重量%または1重量%であろう。最大量は適正には15%、好ましくは10%、最も好ましくは7%である。 The amount of nonionic surfactant to be used in the cleaning composition of the present invention is preferably at least 0.1 wt%, more preferably at least 0.2 wt%, most preferably at least 0.5 wt% or 1 % By weight. The maximum amount is suitably 15%, preferably 10%, most preferably 7%.
組成物は、電解質の存在レベルを考慮した上で構造化液体洗剤組成物即ち“自己増粘”組成物が得られるように選択された量でアニオン性及び非イオン性の双方の界面活性剤を含有してもよい。こうすれば、有機溶媒の存在にもかかわらず、追加の増粘剤の使用を全く要せずに増粘液体洗浄組成物を製造でき、しかも得られた組成物が広い温度範囲にわたって長期間の保存寿命を有し得る。 The composition contains both anionic and nonionic surfactants in amounts selected to give a structured liquid detergent composition or "self-thickening" composition taking into account the level of electrolyte present. You may contain. In this way, a thickened liquid cleaning composition can be produced in the presence of an organic solvent without the need for any additional thickener, and the resulting composition can be used over a wide temperature range for a long period of time. Can have a shelf life.
アニオン性界面活性剤対非イオン性界面活性剤の重量比は、上記の条件を考慮して変更でき、またそれらの種類に左右されるが、好ましくは1:9−9:1、より好ましくは1:4−4:1の範囲である。本発明の目的を例示する実施態様によれば、組成物は0.1−2重量%の(1種または複数の)酸化防止剤と、1−4重量%の過酸化水素と、8−22個の炭素原子を有しているアルキルラジカルを分子中に含む0−20重量%、好ましくは0.2−10重量%の水溶性合成アニオン性スルフェートまたはスルホネート界面活性剤塩と、0.2−7重量%のエトキシル化非イオン性界面活性剤とを含み得る。このエトキシル化非イオン性界面活性剤は、分子中に8−22個の炭素原子を有している脂肪族アルコールとエチレンオキシドとの縮合によって得ることができ、縮合物は脂肪族アルコール1モルあたり2−15モルのエチレンオキシドを有している。組成物の残分はその他の任意成分と水とから成る。 The weight ratio of anionic surfactant to nonionic surfactant can be varied in view of the above conditions and depends on their type, but preferably 1: 9-9: 1, more preferably The range is 1: 4-4: 1. According to an embodiment illustrating the purpose of the present invention, the composition comprises 0.1-2% by weight antioxidant (s), 1-4% by weight hydrogen peroxide, and 8-22. 0-20% by weight, preferably 0.2-10% by weight of a water-soluble synthetic anionic sulfate or sulfonate surfactant salt, containing an alkyl radical having 1 carbon atom in the molecule; 7% by weight ethoxylated nonionic surfactant. This ethoxylated nonionic surfactant can be obtained by condensation of an aliphatic alcohol having 8-22 carbon atoms in the molecule with ethylene oxide, and the condensate is 2 per mole of aliphatic alcohol. It has -15 moles of ethylene oxide. The balance of the composition consists of other optional ingredients and water.
場合によっては使用できる適当な両性界面活性剤は、炭素原子数8−18のアルキル基とアニオン性水可溶化基によって置換された脂肪族基とを有している脂肪族の第二級及び第三級アミンの誘導体、例えば、3−ドデシルアミノプロピオン酸ナトリウム、3−ドデシルアミノプロパンスルホン酸ナトリウム及びN−2−ヒドロキシドデシル−N−メチルタウリン酸ナトリウムである。 Suitable amphoteric surfactants that can optionally be used are aliphatic secondary and primary having an alkyl group of 8-18 carbon atoms and an aliphatic group substituted by an anionic water solubilizing group. Derivatives of tertiary amines, such as sodium 3-dodecylaminopropionate, sodium 3-dodecylaminopropanesulfonate and sodium N-2-hydroxydodecyl-N-methyltaurate.
場合によっては使用できる適当なカチオン性界面活性剤は、炭素原子数8−18の1個または2個の脂肪族基と2個または3個の小さい脂肪族(例えば、メチル)基を有している第四級アンモニウム塩、例えば、セチルトリメチルアンモニウムブロミドである。 Suitable cationic surfactants that may be used in some cases have 1 or 2 aliphatic groups of 8 to 18 carbon atoms and 2 or 3 small aliphatic (eg methyl) groups. Quaternary ammonium salts such as cetyltrimethylammonium bromide.
場合によっては使用できる適当な双イオン性界面活性剤は、炭素原子数8−18の脂肪族基とアニオン性水可溶化基で置換された脂肪族基とを有している脂肪族第四級アンモニウム、スルホニウム及びホスホニウム化合物の誘導体、例えば、3−(N,N−ジメチル−N−ヘキサデシルアンモニウム)プロパン−1−スルホネートベタイン、3−(ドデシルメチルスルホニウム)プロパン−1−スルホネートベタイン及び3−(セチルメチルホスホニウム)エタンスルホネートベタインである。 Suitable zwitterionic surfactants that can optionally be used are aliphatic quaternary having an aliphatic group of 8-18 carbon atoms and an aliphatic group substituted with an anionic water solubilizing group. Derivatives of ammonium, sulfonium and phosphonium compounds such as 3- (N, N-dimethyl-N-hexadecylammonium) propane-1-sulfonate betaine, 3- (dodecylmethylsulfonium) propane-1-sulfonate betaine and 3- ( Cetylmethylphosphonium) ethanesulfonate betaine.
適当な界面活性剤の別の例は、公知の文献“Surface Active Agents”Vol.1,Schwartz & Perry,Interscience 1949,Vol.2,Schwartz,Perry & Berch,Interscience 1958,最新版の“McCutcheon’s Emulsifiers and Detergents”,Manufacturing Confectioners Company発行、または、“Tenside−Taschenbuch”,H.Stache,2nd Edn.,Carl Hauser Verlag,1981に与えられた界面活性剤として常用の化合物である。 Another example of suitable surfactants is described in the known document “Surface Active Agents” Vol. 1, Schwartz & Perry, Interscience 1949, Vol. 2, published by Schwartz, Perry & Berch, Interscience 1958, the latest edition of “McCutcheon's Emulsifiers and Detergents”, Manufacturing Factories, Company, or “Tenside-Tch. Stache, 2nd Edn. , Carl Hauser Verlag, 1981, a commonly used compound as a surfactant.
本発明の組成物はその洗浄性能を補助する他の成分を含有できる。例えば、組成物は、ニトリロトリアセテート、ポリカルボキシレート、シトレート、ジカルボン酸、水溶性ホスフェート(特に、オルト−、ピロ−またはポリ−ホスフェートまたはそれらの混合物)、ゼオライト及びそれらの混合物のような洗浄力ビルダーを25%までの量で含有できる。ビルダーが存在する場合、ビルダーは好ましくは組成物の少なくとも0.1%を形成するであろう。 The composition of the present invention may contain other ingredients that assist its cleaning performance. For example, the composition may be a detergency builder such as nitrilotriacetate, polycarboxylate, citrate, dicarboxylic acid, water-soluble phosphate (especially ortho-, pyro- or poly-phosphate or mixtures thereof), zeolites and mixtures thereof. In an amount up to 25%. If a builder is present, the builder will preferably form at least 0.1% of the composition.
エチレンジアミン四酢酸、ポリホスホネート(DEQUEST[TM]−シリーズ)及び(オルト、ピロ、ポリ)リン酸/ホスフェート(以後の記載ではまとめて“ホスフェート”と呼ぶ)、多様な種類の多官能有機酸(特に、クエン酸)と塩のような金属イオン封鎖剤も酸化防止剤と適合性であるならば場合によっては使用し得る。このような金属イオン封鎖剤は、タンニン酸、タンニン、没食子酸及び誘導体の場合のような金属と共に有色の錯体を形成し得る酸化防止剤と併用するときに特に有用である。このような金属イオン封鎖剤が存在する場合、その有用な量は組成物の0.05−5重量%であり、好ましくは0.1−1重量%である。 Ethylenediaminetetraacetic acid, polyphosphonates (DEQUEST [TM] -series) and (ortho, pyro, poly) phosphate / phosphate (collectively referred to as “phosphate” in the following description), various types of polyfunctional organic acids (especially Sequestering agents such as citrate) and salts may optionally be used provided that they are compatible with the antioxidant. Such sequestering agents are particularly useful when used in combination with antioxidants that can form colored complexes with metals such as in the case of tannic acid, tannin, gallic acid and derivatives. When such a sequestering agent is present, its useful amount is 0.05-5% by weight of the composition, preferably 0.1-1%.
本発明の組成物の別の任意成分は泡調節材料であり、これは使用中に過度の泡を生じる傾向のある組成物に使用できる。 Another optional component of the composition of the present invention is a foam control material, which can be used in compositions that tend to produce excessive foam during use.
泡調節材料の一例はセッケンである。セッケンは脂肪酸の塩であり、約8−約24個の炭素原子、好ましくは約10−約20個の炭素原子を含有している脂肪酸のナトリウム塩、カリウム塩及びアンモニウム塩のようなアルカリ金属セッケンである。ココヤシ油及びピーナツ油に由来の脂肪酸の混合物のナトリウム塩、カリウム塩並びにモノ−、ジ−及びトリエタノールアミン塩が特に有用である。セッケンを使用するとき、セッケンの量は、組成物の少なくとも0.005重量%、好ましくは少なくとも0.1重量%を形成し得る。Prifac 7901[TM]のような脂肪酸セッケンがこの目的に適していることが知見された。 An example of a foam control material is soap. The soap is a salt of a fatty acid and an alkali metal soap such as sodium, potassium and ammonium salts of fatty acids containing from about 8 to about 24 carbon atoms, preferably from about 10 to about 20 carbon atoms. It is. Particularly useful are the sodium, potassium and mono-, di- and triethanolamine salts of mixtures of fatty acids derived from coconut oil and peanut oil. When using soap, the amount of soap may form at least 0.005%, preferably at least 0.1% by weight of the composition. It has been found that fatty acid soaps such as Prifac 7901 [TM] are suitable for this purpose.
泡調節材料の別の例はシリコーン油である。炭化水素助溶媒が十分に高いレベルで存在するときは、炭化水素自体が所望の抑泡活性の一部または全部を提供する。 Another example of a foam control material is silicone oil. When the hydrocarbon co-solvent is present at a sufficiently high level, the hydrocarbon itself provides some or all of the desired foam suppression activity.
本発明の組成物はまた、既述の成分に加えて、色素、白色体質顔料、蛍光増白剤、汚れ懸濁化剤、洗浄性酵素、ゲルコントロール剤、凍結−解凍安定剤、防腐剤(例えば、1,2−ベンズイソチアゾリン−3−オン)、及び、ヒドロトロープのような他の種々の任意成分を含有できる。しかしながら本発明の組成物は、皮膚に抗菌作用を与えるために適当な量の抗菌剤(過酸化水素以外)を含有しない。抗菌剤が存在するときは一般に、抗菌剤は組成物の微生物汚染を防止するために必要な量だけで存在する。 In addition to the components described above, the composition of the present invention also contains a dye, a white extender pigment, a fluorescent brightener, a soil suspending agent, a detersive enzyme, a gel control agent, a freeze-thaw stabilizer, a preservative ( For example, 1,2-benzisothiazolin-3-one) and various other optional components such as hydrotropes can be included. However, the compositions of the present invention do not contain an appropriate amount of antimicrobial agent (other than hydrogen peroxide) to impart antimicrobial activity to the skin. When present, the antimicrobial agent is generally present only in an amount necessary to prevent microbial contamination of the composition.
本発明の組成物及び硬質表面を洗浄するための組成物の使用は過酸化水素の存在に依存するので、組成物はアルコキシル化脂肪族またはアリール脂肪族カルボン酸を対応する過酸の前駆物質として含有しない。 Since the use of the composition of the present invention and the composition for cleaning hard surfaces is dependent on the presence of hydrogen peroxide, the composition can be an alkoxylated aliphatic or arylaliphatic carboxylic acid as the corresponding peracid precursor. Does not contain.
分注
液体組成物はスプレーアプリケーターのような任意の適当な手段に収納されて分注され得る。ポンプディスペンサー(噴霧ポンプまたは非噴霧ポンプ)及び注出アプリケーター(びん、など)も可能である。組成物はまた、液体組成物を含浸させた布巾によって表面に塗布され得る。
The dispensing liquid composition can be dispensed by being contained in any suitable means such as a spray applicator. Pump dispensers (spray pumps or non-spray pumps) and dispensing applicators (bottles, etc.) are also possible. The composition can also be applied to the surface by a cloth impregnated with the liquid composition.
以下の実施例中、異なる記述が特にない限りパーセンテージはすべて重量%である。 In the following examples, all percentages are by weight unless otherwise stated.
実施例1:汎用洗浄組成物
Biodac L6S50(非イオン性) 1.2%
LAS(アニオン性) 3.5%
タンニン酸 0.50%
過酸化水素 3.0%
リン酸 0.42%
水酸化ナトリウム 0.046%
尿素 1.0%
香料 0.35%
Dequest 2046 0.10%
ココヤシ脂肪酸(Prifac 7907TM) 0.30%
水 100%まで
Example 1 : General purpose cleaning composition Biodac L6S50 (non-ionic) 1.2%
LAS (anionic) 3.5%
Tannic acid 0.50%
Hydrogen peroxide 3.0%
Phosphoric acid 0.42%
Sodium hydroxide 0.046%
Urea 1.0%
Fragrance 0.35%
Dequest 2046 0.10%
Coco fatty acid (Prifac 7907 ™ ) 0.30%
Up to 100% water
対照1
タンニン酸を含有しない以外は実施例1と同じ。
Control 1
Same as Example 1 except not containing tannic acid.
評価
基板の詳細
洗浄試験にはステンレススチール基板を使用した。この基板は寸法380mm×300mmのつや消しステンレススチール(グレード 304 シート BS 1449 Pt2 1983、 Merseyside Metal Services Ltd社から提供)であった。この寸法があるとタイルの左側及び右側に各1つの2つの洗浄領域を設けることができる。各洗浄領域は215mm×150mmである。
Details of Evaluation Substrate A stainless steel substrate was used for the cleaning test. The substrate was brushed stainless steel (grade 304 sheet BS 1449 Pt2 1983, provided by Mercyside Metal Services Ltd) with dimensions of 380 mm x 300 mm. With this dimension, two wash areas, one each on the left and right sides of the tile, can be provided. Each cleaning area is 215 mm × 150 mm.
ステンレスタイルの予備洗浄
洗浄実験に先立ってタイルを以下の手順で予備洗浄した:
・市販の液体研磨洗浄剤(Jifクリームクリーナー)、
湿ったJ−クロスで磨き、湯ですすぐ;
・液体食器洗剤(Persil液体食器洗剤)、
湿ったJ−クロスで磨き、湯ですすぐ;
・炭酸カルシウム(calcite)、湿ったJ−クロスで磨き、湯ですすぎ、最後に脱イオン水ですすぐ;
・タイルを水切り乾燥し、紙タオルで拭い、炭酸カルシウム沈着物を完全に除去する。
Pre-cleaning of stainless steel tiles Prior to the cleaning experiment, the tiles were pre-cleaned as follows:
-Commercially available liquid abrasive cleaner (Jif cream cleaner),
Polish with moist J-cloth and rinse with hot water;
・ Liquid dish detergent (Persil liquid dish detergent),
Polish with moist J-cloth and rinse with hot water;
・ Polish with calcium carbonate, wet J-cloth, rinse with hot water and finally rinse with deionized water;
-Drain the tiles, dry them with a paper towel, and remove the calcium carbonate deposits completely.
ステンレススチールタイルに対する前処理塗布
前処理すべきタイルの2つの領域を露出させる厚紙枠をステンレススチールタイルの上に配置した。一方の215mm×150mm領域に、ピペットで採取した1.0mlの被験組成物アリコートのほぼ半量を、前処理領域の150mmの上辺に沿って線状に塗布した。1.0mlの被験組成物の残りの量は該領域の150mmの下辺に沿って同様に塗布した。塗布した標本を前処理領域全体に容易に塗り拡げられるように厚紙枠を慎重に取り外した。濡らして手で絞ったJ−clothTM(脱イオン水)を150mmのプラスチック定規を囲んで折り畳んだ。これを使用して試験中の組成物の1.0mlのアリコートをスチール表面全体に拡げた。下向きに2回、上向きに2回の4回の直線塗りで標本を指定領域全体に塗り拡げ、各場合に4つの重複する洗浄標本を準備した。前処理塗布が終わった後、タイルを2時間乾燥させてから、脱水したヒマシ油汚れを噴霧した。
Pretreatment for stainless steel tiles A cardboard frame was placed on top of the stainless steel tiles to expose the two areas of the tile to be pretreated. On one 215 mm × 150 mm area, approximately half of the 1.0 ml aliquot of the test composition collected with a pipette was applied linearly along the 150 mm upper side of the pretreatment area. The remaining amount of 1.0 ml of the test composition was applied in the same manner along the 150 mm lower side of the area. The cardboard frame was carefully removed so that the applied specimen could be easily spread over the entire pretreatment area. Wet and squeezed by hand, J-close ™ (deionized water) was folded around a 150 mm plastic ruler. This was used to spread a 1.0 ml aliquot of the composition under test across the steel surface. The specimen was spread over the entire designated area with four straight lines, two downwards and two upwards, and in each case four overlapping washed specimens were prepared. After the pretreatment application was completed, the tiles were dried for 2 hours and then sprayed with dehydrated castor oil stains.
前処理したステンレススチールタイルに対する汚れの付着及び熟成
ヒマシ油汚れの噴霧は、異なる実験間で良好な再現性を確保するために通風室で標準条件下に行った。汚れは0.2%脂肪レッド7B染料を伴う脱水ヒマシ油であった。使用しないときはこれを冷蔵庫に保管した。噴霧前に周囲温度に平衡させた。
Stain adhesion and aging on pretreated stainless steel tiles Castor oil stain spraying was performed under standard conditions in a ventilated chamber to ensure good reproducibility between different experiments. The soil was dehydrated castor oil with 0.2% fat red 7B dye. This was stored in the refrigerator when not in use. Equilibrated to ambient temperature before spraying.
通風室の壁/床及び実験用ジャッキを紙タオルで覆った。実験用ジャッキはタイルを実際の噴霧高度に押し上げるために使用した。実験用ジャッキの高さは200mmであり、通風室の奥の中央に配置した。通風室の後部壁から40mm離れた一本の線を実験用ジャッキの頂部の上に記入した。これを噴霧前の各ステンレススチールタイルの位置決め線として使用した。実験用ジャッキの上の40mm線から270mmの平行な線を通風室の床面に記入した。噴霧のときにはPerspexスプレーガイドをこの場所に位置合わせした。 Ventilation chamber walls / floor and laboratory jacks were covered with paper towels. A laboratory jack was used to push the tiles up to the actual spray height. The height of the experimental jack was 200 mm, and was placed in the center of the back of the ventilation chamber. A line 40 mm away from the rear wall of the ventilation chamber was marked on the top of the experimental jack. This was used as the positioning line for each stainless steel tile before spraying. A parallel line of 40 mm to 270 mm above the experimental jack was written on the floor of the ventilation chamber. The Perspex spray guide was aligned to this location when spraying.
市販の重力充填スプレーガンを使用して油性汚れをスチールタイルに噴霧した。重力充填ガンのリアダイヤルを閉位置から逆時計回りに360度回転させ、サイドダイヤルをやはり閉位置から逆時計回りに270度回転させた。重力充填スプレーガンを床置きエアコンプレッサ装置につなぎ、25p.s.i.の圧力を使用してこの汚れをスチールタイルに噴霧した。使用していないときのスプレーガンを保持するために通風室にクランプ台を配置した。脱水したヒマシ油汚れをスプレーガンのオープンボウルに注入した。 Oily soil was sprayed onto the steel tile using a commercially available gravity filled spray gun. The rear dial of the gravity filling gun was rotated 360 degrees counterclockwise from the closed position, and the side dial was also rotated 270 degrees counterclockwise from the closed position. Connect the gravity filled spray gun to the floor-mounted air compressor device, 25p. s. i. The soil was sprayed onto the steel tile using a pressure of. A clamp base was placed in the ventilation chamber to hold the spray gun when not in use. Dehydrated castor oil stain was poured into an open bowl of a spray gun.
厚紙スプレー枠をステンレススチールタイルにクリップで留め、通風室の後部壁から40mmの線に沿って実験用ジャッキの中央のよく見える場所に配置した。厚紙スプレー枠はステンレススチールタイルと同じ寸法の長方形カード片であり、215mm×150mmの2つの切り抜き領域があり、一方の窓は左側、他方の窓は右側にあり、2つの窓の間にカード分離帯がある。噴霧されるタイルの第一窓の前方の270mm線上にPerspexスプレーガイドを直接的に位置決めした。頂部から開始し、スプレーガイドの線に従ってタイルのこの領域に合計35秒間の噴霧を行った。頂部から底部までの噴霧に要した時間は約9秒間であり、従って、215mm×150mmの被噴霧領域の各々にスプレーガイドの軌跡が4回描かれる。タイルの第一領域の噴霧後、Perspexスプレーガイドを第二領域の前方に位置合わせし隣接領域を全く同様に噴霧した。タイル全体に2回の噴霧を行った後、タイルを通風室から取り出して、厚紙スプレー枠を慎重に取り外した。噴霧されたタイルをオーブンシェルフに直接積み重ねた。ステンレススチールタイルの各々を隔てるために、該タイルの各隅に配置したアルミニウム製リングスペーサーを使用した。これらのスペーサーは各タイルを10mmずつ離間させた。全部のタイルの噴霧が終わると、これらをまとめてオーブンに入れて熟成させた。 A cardboard spray frame was clipped to the stainless steel tile and placed in the center of the laboratory jack at a well-viewed location along a 40 mm line from the rear wall of the ventilation chamber. The cardboard spray frame is a rectangular card piece with the same dimensions as a stainless steel tile, with two cutout areas of 215mm x 150mm, with one window on the left and the other on the right, separating the card between the two windows There is a belt. The Perspex spray guide was positioned directly on the 270 mm line in front of the first window of the tile to be sprayed. Starting from the top, this area of the tile was sprayed for a total of 35 seconds following the spray guide line. The time required for spraying from the top to the bottom is about 9 seconds. Therefore, the trajectory of the spray guide is drawn four times in each area to be sprayed of 215 mm × 150 mm. After spraying the first area of the tile, the Perspex spray guide was positioned in front of the second area and the adjacent areas were sprayed in exactly the same way. After spraying the entire tile twice, the tile was removed from the ventilation chamber and the cardboard spray frame was carefully removed. Sprayed tiles were stacked directly on the oven shelf. An aluminum ring spacer placed at each corner of the tile was used to separate each of the stainless steel tiles. These spacers separated each tile by 10 mm. When all the tiles had been sprayed, they were put together in an oven and aged.
タイルを85℃で1.5時間熟成させた。準備したタイルは翌日まで洗浄しなかった。 The tile was aged at 85 ° C. for 1.5 hours. The prepared tile was not washed until the next day.
セルローススポンジクロスを使用して試験表面から汚れを除去するために要した力を、Nsで表される力を測定することを特定目的として製造された装置で測定した。汚れを除去するために使用した洗浄組成物は対照2の組成物であった。従って、洗浄に要した力の減少は、前処理組成物中の酸化防止剤だけに起因すると判断できる。 The force required to remove dirt from the test surface using a cellulose sponge cloth was measured with a device manufactured for the specific purpose of measuring the force represented by Ns. The cleaning composition used to remove the soil was the Control 2 composition. Therefore, it can be judged that the reduction in the force required for cleaning is caused solely by the antioxidant in the pretreatment composition.
実施例1及び対照1(実施例1からタンニン酸を除去した組成物に対応)に関する結果を表Iに示す。表に示した結果は4つの重複実験の幾何平均である。 The results for Example 1 and Control 1 (corresponding to the composition from Example 1 with tannic acid removed) are shown in Table I. The results shown in the table are the geometric mean of four duplicate experiments.
Claims (21)
(b)脂肪質汚れの付着を放置する段階と、
(c)脂肪質汚れを除去するために表面を洗浄する段階と、
を順次に含む硬質表面から脂肪質汚れを除去する方法。 (A) treating the hard surface with a liquid cleaning composition comprising a radical scavenging antioxidant and hydrogen peroxide;
(B) leaving the deposits of fatty dirt;
(C) cleaning the surface to remove fatty soils;
A method for removing fatty dirt from a hard surface that sequentially contains.
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EP02251405 | 2002-02-28 | ||
PCT/EP2003/000988 WO2003072689A1 (en) | 2002-02-28 | 2003-01-31 | Liquid cleaning compositions |
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JP (1) | JP2005519151A (en) |
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AU (1) | AU2003248334B2 (en) |
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CA (1) | CA2472183A1 (en) |
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CA2472183A1 (en) | 2003-09-04 |
ATE327310T1 (en) | 2006-06-15 |
ZA200405016B (en) | 2005-06-24 |
WO2003072689A1 (en) | 2003-09-04 |
EP1478722B1 (en) | 2006-05-24 |
ES2261952T3 (en) | 2006-11-16 |
DE60305452D1 (en) | 2006-06-29 |
DE60305452T2 (en) | 2006-10-12 |
AU2003248334B2 (en) | 2006-06-08 |
AR038855A1 (en) | 2005-01-26 |
EP1478722A1 (en) | 2004-11-24 |
BR0307024A (en) | 2004-11-03 |
AU2003248334A1 (en) | 2003-09-09 |
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