JP2005334799A - 廃棄物処理方法および重金属固定化処理剤組成物 - Google Patents
廃棄物処理方法および重金属固定化処理剤組成物 Download PDFInfo
- Publication number
- JP2005334799A JP2005334799A JP2004158914A JP2004158914A JP2005334799A JP 2005334799 A JP2005334799 A JP 2005334799A JP 2004158914 A JP2004158914 A JP 2004158914A JP 2004158914 A JP2004158914 A JP 2004158914A JP 2005334799 A JP2005334799 A JP 2005334799A
- Authority
- JP
- Japan
- Prior art keywords
- heavy metal
- waste
- acid type
- nitrogen
- amines
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 81
- 239000002699 waste material Substances 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 24
- 230000003100 immobilizing effect Effects 0.000 title claims description 34
- 239000000203 mixture Substances 0.000 title claims description 18
- 150000001412 amines Chemical class 0.000 claims abstract description 75
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 57
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 33
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 32
- 239000001257 hydrogen Substances 0.000 claims abstract description 32
- 125000000524 functional group Chemical group 0.000 claims abstract description 31
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims abstract description 26
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 18
- 125000003277 amino group Chemical class 0.000 claims abstract 4
- 239000002253 acid Substances 0.000 claims description 19
- 239000010881 fly ash Substances 0.000 claims description 15
- 230000000694 effects Effects 0.000 claims description 6
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 abstract description 60
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 6
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 abstract description 5
- 239000010813 municipal solid waste Substances 0.000 abstract description 3
- 239000002341 toxic gas Substances 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 17
- 238000006467 substitution reaction Methods 0.000 description 15
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 14
- 150000003839 salts Chemical class 0.000 description 14
- -1 rivers Substances 0.000 description 13
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 10
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 10
- 229920002873 Polyethylenimine Polymers 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 5
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N 4-methylimidazole Chemical compound CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 description 4
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 4
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 4
- 229940073608 benzyl chloride Drugs 0.000 description 4
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 4
- 229910052793 cadmium Inorganic materials 0.000 description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 4
- VECZPMZNUKYYOJ-UHFFFAOYSA-N 1-n,2-n-diethylpropane-1,2-diamine Chemical compound CCNCC(C)NCC VECZPMZNUKYYOJ-UHFFFAOYSA-N 0.000 description 3
- LKQOFPMYXITRFI-UHFFFAOYSA-N 1-propan-2-ylpyrazolidine Chemical compound CC(C)N1CCCN1 LKQOFPMYXITRFI-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- SOZMSQQUOXHBCE-UHFFFAOYSA-N 3-propylpyrazolidine Chemical compound CCCC1CCNN1 SOZMSQQUOXHBCE-UHFFFAOYSA-N 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- UZOVIHCILYKHPQ-UHFFFAOYSA-N 1,3-diethylpiperazine Chemical compound CCC1CN(CC)CCN1 UZOVIHCILYKHPQ-UHFFFAOYSA-N 0.000 description 2
- FQUYSHZXSKYCSY-UHFFFAOYSA-N 1,4-diazepane Chemical compound C1CNCCNC1 FQUYSHZXSKYCSY-UHFFFAOYSA-N 0.000 description 2
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 2
- DCFOULIREWYDJM-UHFFFAOYSA-N 1-(2-methylpropyl)pyrazolidine Chemical compound CC(C)CN1CCCN1 DCFOULIREWYDJM-UHFFFAOYSA-N 0.000 description 2
- PVYDJRHPECQXDP-UHFFFAOYSA-N 1-butylimidazolidine Chemical compound CCCCN1CCNC1 PVYDJRHPECQXDP-UHFFFAOYSA-N 0.000 description 2
- VBRYAQVRADPLST-UHFFFAOYSA-N 1-butylpyrazolidine Chemical compound CCCCN1CCCN1 VBRYAQVRADPLST-UHFFFAOYSA-N 0.000 description 2
- PEXCBPMLLSAJAP-UHFFFAOYSA-N 1-ethylimidazolidine Chemical compound CCN1CCNC1 PEXCBPMLLSAJAP-UHFFFAOYSA-N 0.000 description 2
- KFMUXFQJUKRXFB-UHFFFAOYSA-N 1-ethylpyrazolidine Chemical compound CCN1CCCN1 KFMUXFQJUKRXFB-UHFFFAOYSA-N 0.000 description 2
- VGYLMOJQAHXYCK-UHFFFAOYSA-N 1-methylimidazolidine Chemical compound CN1CCNC1 VGYLMOJQAHXYCK-UHFFFAOYSA-N 0.000 description 2
- NFHQYWPOTLXIQP-UHFFFAOYSA-N 1-methylpyrazolidine Chemical compound CN1CCCN1 NFHQYWPOTLXIQP-UHFFFAOYSA-N 0.000 description 2
- SSPWJSZQVSFFSL-UHFFFAOYSA-N 1-propan-2-ylimidazolidine Chemical compound CC(C)N1CCNC1 SSPWJSZQVSFFSL-UHFFFAOYSA-N 0.000 description 2
- AKMXNJYHAZXCDT-UHFFFAOYSA-N 1-propylimidazolidine Chemical compound CCCN1CCNC1 AKMXNJYHAZXCDT-UHFFFAOYSA-N 0.000 description 2
- BQCAJEKCNYZHEZ-UHFFFAOYSA-N 1-propylpyrazolidine Chemical compound CCCN1CCCN1 BQCAJEKCNYZHEZ-UHFFFAOYSA-N 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- BDXJANJAHYKTMI-UHFFFAOYSA-N 2,3,4,5-tetramethyl-1h-pyrrole Chemical compound CC=1NC(C)=C(C)C=1C BDXJANJAHYKTMI-UHFFFAOYSA-N 0.000 description 2
- WTMJHBZSSSDBFQ-UHFFFAOYSA-N 2,3,4-trimethyl-1h-pyrrole Chemical compound CC1=CNC(C)=C1C WTMJHBZSSSDBFQ-UHFFFAOYSA-N 0.000 description 2
- LLPKQRMDOFYSGZ-UHFFFAOYSA-N 2,5-dimethyl-1h-imidazole Chemical compound CC1=CN=C(C)N1 LLPKQRMDOFYSGZ-UHFFFAOYSA-N 0.000 description 2
- SLLDUURXGMDOCY-UHFFFAOYSA-N 2-butyl-1h-imidazole Chemical compound CCCCC1=NC=CN1 SLLDUURXGMDOCY-UHFFFAOYSA-N 0.000 description 2
- LTHNHFOGQMKPOV-UHFFFAOYSA-N 2-ethylhexan-1-amine Chemical compound CCCCC(CC)CN LTHNHFOGQMKPOV-UHFFFAOYSA-N 0.000 description 2
- JOMNTHCQHJPVAZ-UHFFFAOYSA-N 2-methylpiperazine Chemical compound CC1CNCCN1 JOMNTHCQHJPVAZ-UHFFFAOYSA-N 0.000 description 2
- JYBYRRDIXAOBCA-UHFFFAOYSA-N 3-ethylpyrazolidine Chemical compound CCC1CCNN1 JYBYRRDIXAOBCA-UHFFFAOYSA-N 0.000 description 2
- ZZIXNGRDILYTIK-UHFFFAOYSA-N 3-methylpyrazolidine Chemical compound CC1CCNN1 ZZIXNGRDILYTIK-UHFFFAOYSA-N 0.000 description 2
- QVNLKSRRRUIPSH-UHFFFAOYSA-N 3-propan-2-ylpyrazolidine Chemical compound C(C)(C)C1NNCC1 QVNLKSRRRUIPSH-UHFFFAOYSA-N 0.000 description 2
- GPEXBQCGPVLXKH-UHFFFAOYSA-N 4-(2-methylpropyl)imidazolidine Chemical compound CC(C)CC1CNCN1 GPEXBQCGPVLXKH-UHFFFAOYSA-N 0.000 description 2
- OGIUACIOOQQSIB-UHFFFAOYSA-N 4-butylimidazolidine Chemical compound CCCCC1CNCN1 OGIUACIOOQQSIB-UHFFFAOYSA-N 0.000 description 2
- BYPJHNPMZYKOAD-UHFFFAOYSA-N 4-ethylimidazolidine Chemical compound CCC1CNCN1 BYPJHNPMZYKOAD-UHFFFAOYSA-N 0.000 description 2
- VGBASMXDKFZLAK-UHFFFAOYSA-N 4-methylimidazolidine Chemical compound CC1CNCN1 VGBASMXDKFZLAK-UHFFFAOYSA-N 0.000 description 2
- DSJQGQQPGWELOJ-UHFFFAOYSA-N 4-propan-2-ylimidazolidine Chemical compound CC(C)C1CNCN1 DSJQGQQPGWELOJ-UHFFFAOYSA-N 0.000 description 2
- VNEGVQZLMXOZPM-UHFFFAOYSA-N 4-propylimidazolidine Chemical compound CCCC1CNCN1 VNEGVQZLMXOZPM-UHFFFAOYSA-N 0.000 description 2
- YNKYMFZRRGASLV-UHFFFAOYSA-N 5-(2-methylpropyl)-1h-imidazole Chemical compound CC(C)CC1=CN=CN1 YNKYMFZRRGASLV-UHFFFAOYSA-N 0.000 description 2
- KLQAJWMVWOATSI-UHFFFAOYSA-N 5-(2-methylpropyl)-1h-pyrazole Chemical compound CC(C)CC=1C=CNN=1 KLQAJWMVWOATSI-UHFFFAOYSA-N 0.000 description 2
- GFJCGXFXOXSUJX-UHFFFAOYSA-N 5-butyl-1h-pyrazole Chemical compound CCCCC1=CC=NN1 GFJCGXFXOXSUJX-UHFFFAOYSA-N 0.000 description 2
- NJQHZENQKNIRSY-UHFFFAOYSA-N 5-ethyl-1h-imidazole Chemical compound CCC1=CNC=N1 NJQHZENQKNIRSY-UHFFFAOYSA-N 0.000 description 2
- CBNLNXLAIMQSTR-UHFFFAOYSA-N 5-ethyl-1h-pyrazole Chemical compound CCC1=CC=NN1 CBNLNXLAIMQSTR-UHFFFAOYSA-N 0.000 description 2
- XKVUYEYANWFIJX-UHFFFAOYSA-N 5-methyl-1h-pyrazole Chemical compound CC1=CC=NN1 XKVUYEYANWFIJX-UHFFFAOYSA-N 0.000 description 2
- HINMGNHBDCADKG-UHFFFAOYSA-N 5-propan-2-yl-1h-imidazole Chemical compound CC(C)C1=CNC=N1 HINMGNHBDCADKG-UHFFFAOYSA-N 0.000 description 2
- ZICRALLMHKILDG-UHFFFAOYSA-N 5-propan-2-yl-1h-pyrazole Chemical compound CC(C)C1=CC=NN1 ZICRALLMHKILDG-UHFFFAOYSA-N 0.000 description 2
- HPSJFXKHFLNPQM-UHFFFAOYSA-N 5-propyl-1h-imidazole Chemical compound CCCC1=CNC=N1 HPSJFXKHFLNPQM-UHFFFAOYSA-N 0.000 description 2
- XHASQVPZVKLTTB-UHFFFAOYSA-N CC(C)CC1CCNN1 Chemical compound CC(C)CC1CCNN1 XHASQVPZVKLTTB-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- CJKRXEBLWJVYJD-UHFFFAOYSA-N N,N'-diethylethylenediamine Chemical compound CCNCCNCC CJKRXEBLWJVYJD-UHFFFAOYSA-N 0.000 description 2
- QCOGKXLOEWLIDC-UHFFFAOYSA-N N-methylbutylamine Chemical compound CCCCNC QCOGKXLOEWLIDC-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- NLZXQOOZQAGNCY-UHFFFAOYSA-L dipotassium;piperazine-1,4-dicarbodithioate Chemical compound [K+].[K+].[S-]C(=S)N1CCN(C([S-])=S)CC1 NLZXQOOZQAGNCY-UHFFFAOYSA-L 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 2
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 2
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 2
- AQGNVWRYTKPRMR-UHFFFAOYSA-N n'-[2-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCNCCN AQGNVWRYTKPRMR-UHFFFAOYSA-N 0.000 description 2
- IMENJLNZKOMSMC-UHFFFAOYSA-N n'-[2-[2-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCNCCNCCN IMENJLNZKOMSMC-UHFFFAOYSA-N 0.000 description 2
- KVKFRMCSXWQSNT-UHFFFAOYSA-N n,n'-dimethylethane-1,2-diamine Chemical compound CNCCNC KVKFRMCSXWQSNT-UHFFFAOYSA-N 0.000 description 2
- GVWISOJSERXQBM-UHFFFAOYSA-N n-methylpropan-1-amine Chemical compound CCCNC GVWISOJSERXQBM-UHFFFAOYSA-N 0.000 description 2
- DPBLXKKOBLCELK-UHFFFAOYSA-N pentan-1-amine Chemical compound CCCCCN DPBLXKKOBLCELK-UHFFFAOYSA-N 0.000 description 2
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 description 2
- 229920000083 poly(allylamine) Polymers 0.000 description 2
- 229920000333 poly(propyleneimine) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- 125000000213 sulfino group Chemical group [H]OS(*)=O 0.000 description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- XBTRYWRVOBZSGM-UHFFFAOYSA-N (4-methylphenyl)methanediamine Chemical compound CC1=CC=C(C(N)N)C=C1 XBTRYWRVOBZSGM-UHFFFAOYSA-N 0.000 description 1
- OTJFQRMIRKXXRS-UHFFFAOYSA-N (hydroxymethylamino)methanol Chemical compound OCNCO OTJFQRMIRKXXRS-UHFFFAOYSA-N 0.000 description 1
- CDHYSFKPWCVXHZ-UHFFFAOYSA-N 1,2,5-trimethylpiperazine Chemical compound CC1CN(C)C(C)CN1 CDHYSFKPWCVXHZ-UHFFFAOYSA-N 0.000 description 1
- BROQXILFDWZSAC-UHFFFAOYSA-N 1,2-dimethylimidazolidine Chemical compound CC1NCCN1C BROQXILFDWZSAC-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- RXBQLSLRTRYYGG-UHFFFAOYSA-N 1,3-dipropylimidazolidine Chemical compound CCCN1CCN(CCC)C1 RXBQLSLRTRYYGG-UHFFFAOYSA-N 0.000 description 1
- KQIXMZWXFFHRAQ-UHFFFAOYSA-N 1-(2-hydroxybutylamino)butan-2-ol Chemical compound CCC(O)CNCC(O)CC KQIXMZWXFFHRAQ-UHFFFAOYSA-N 0.000 description 1
- KVWBCXLATKOHFO-UHFFFAOYSA-N 1-(2-methylpropyl)imidazolidine Chemical compound CC(C)CN1CCNC1 KVWBCXLATKOHFO-UHFFFAOYSA-N 0.000 description 1
- PVOAHINGSUIXLS-UHFFFAOYSA-N 1-Methylpiperazine Chemical compound CN1CCNCC1 PVOAHINGSUIXLS-UHFFFAOYSA-N 0.000 description 1
- KODLUXHSIZOKTG-UHFFFAOYSA-N 1-aminobutan-2-ol Chemical compound CCC(O)CN KODLUXHSIZOKTG-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- YKSVXVKIYYQWBB-UHFFFAOYSA-N 1-butylpiperazine Chemical compound CCCCN1CCNCC1 YKSVXVKIYYQWBB-UHFFFAOYSA-N 0.000 description 1
- WGCYRFWNGRMRJA-UHFFFAOYSA-N 1-ethylpiperazine Chemical compound CCN1CCNCC1 WGCYRFWNGRMRJA-UHFFFAOYSA-N 0.000 description 1
- CSIJTGWLPDZGIG-UHFFFAOYSA-N 1-methyl-4-propylimidazolidine Chemical compound CN1CNC(C1)CCC CSIJTGWLPDZGIG-UHFFFAOYSA-N 0.000 description 1
- QLEIDMAURCRVCX-UHFFFAOYSA-N 1-propylpiperazine Chemical compound CCCN1CCNCC1 QLEIDMAURCRVCX-UHFFFAOYSA-N 0.000 description 1
- ARHQRIUITSZVPU-UHFFFAOYSA-N 2,3,4,5,6-pentamethylpiperidine Chemical compound CC1NC(C)C(C)C(C)C1C ARHQRIUITSZVPU-UHFFFAOYSA-N 0.000 description 1
- OILCKFMEPIHVTL-UHFFFAOYSA-N 2,3,4,5-tetramethylpyrrolidine Chemical compound CC1NC(C)C(C)C1C OILCKFMEPIHVTL-UHFFFAOYSA-N 0.000 description 1
- YFZJBYQBYKUDMK-UHFFFAOYSA-N 2,3,4-trimethylpyrrolidine Chemical compound CC1CNC(C)C1C YFZJBYQBYKUDMK-UHFFFAOYSA-N 0.000 description 1
- XSEYKUIEZMGNQZ-UHFFFAOYSA-N 2,3,5,6-tetraethylmorpholine Chemical compound CCC1NC(CC)C(CC)OC1CC XSEYKUIEZMGNQZ-UHFFFAOYSA-N 0.000 description 1
- ICGDKKACLISIAM-UHFFFAOYSA-N 2,3,5,6-tetramethylpiperazine Chemical compound CC1NC(C)C(C)NC1C ICGDKKACLISIAM-UHFFFAOYSA-N 0.000 description 1
- PNFWGQYGVJGJDX-UHFFFAOYSA-N 2,3,5,6-tetramethylthiomorpholine Chemical compound CC1NC(C)C(C)SC1C PNFWGQYGVJGJDX-UHFFFAOYSA-N 0.000 description 1
- IWLHRDCNRSUCER-UHFFFAOYSA-N 2,3,5-triethyl-1h-pyrrole Chemical compound CCC1=CC(CC)=C(CC)N1 IWLHRDCNRSUCER-UHFFFAOYSA-N 0.000 description 1
- XDAMZGXFTHZDFD-UHFFFAOYSA-N 2,3,5-trimethylmorpholine Chemical compound CC1COC(C)C(C)N1 XDAMZGXFTHZDFD-UHFFFAOYSA-N 0.000 description 1
- OMEMBAXECFIRSG-UHFFFAOYSA-N 2,3,5-trimethylpiperazine Chemical compound CC1CNC(C)C(C)N1 OMEMBAXECFIRSG-UHFFFAOYSA-N 0.000 description 1
- VDTSBJQZTFOENL-UHFFFAOYSA-N 2,3,5-trimethylthiomorpholine Chemical compound CC1CSC(C)C(C)N1 VDTSBJQZTFOENL-UHFFFAOYSA-N 0.000 description 1
- OUYLXVQKVBXUGW-UHFFFAOYSA-N 2,3-dimethyl-1h-pyrrole Chemical compound CC=1C=CNC=1C OUYLXVQKVBXUGW-UHFFFAOYSA-N 0.000 description 1
- COWPTMLRSANSMQ-UHFFFAOYSA-N 2,3-dimethylpiperazine Chemical compound CC1NCCNC1C COWPTMLRSANSMQ-UHFFFAOYSA-N 0.000 description 1
- DRLFSUDDXLQHJT-UHFFFAOYSA-N 2,3-dimethylpiperidine Chemical compound CC1CCCNC1C DRLFSUDDXLQHJT-UHFFFAOYSA-N 0.000 description 1
- ZKCLHJUZGZWTNA-UHFFFAOYSA-N 2,3-dimethylpyrrolidine Chemical compound CC1CCNC1C ZKCLHJUZGZWTNA-UHFFFAOYSA-N 0.000 description 1
- OSKSVESWLSCULX-UHFFFAOYSA-N 2,3-dimethylthiomorpholine Chemical compound CC1NCCSC1C OSKSVESWLSCULX-UHFFFAOYSA-N 0.000 description 1
- CMAMPIMEOWYCDC-UHFFFAOYSA-N 2,4,5-triethyl-1h-imidazole Chemical compound CCC1=NC(CC)=C(CC)N1 CMAMPIMEOWYCDC-UHFFFAOYSA-N 0.000 description 1
- PTBPTNCGZUOCBK-UHFFFAOYSA-N 2,4,5-trimethyl-1h-imidazole Chemical compound CC1=NC(C)=C(C)N1 PTBPTNCGZUOCBK-UHFFFAOYSA-N 0.000 description 1
- GORCXFWGWOLMFL-UHFFFAOYSA-N 2,4,5-trimethylimidazolidine Chemical compound CC1NC(C)C(C)N1 GORCXFWGWOLMFL-UHFFFAOYSA-N 0.000 description 1
- GELXVDNNZSIRQA-UHFFFAOYSA-N 2,4,6-trimethylpiperidine Chemical compound CC1CC(C)NC(C)C1 GELXVDNNZSIRQA-UHFFFAOYSA-N 0.000 description 1
- KWUHMVHTFKVQQI-UHFFFAOYSA-N 2,4-diethylimidazolidine Chemical compound CCC1CNC(CC)N1 KWUHMVHTFKVQQI-UHFFFAOYSA-N 0.000 description 1
- JGSUVQJWOZRVIY-UHFFFAOYSA-N 2,4-diethylpyrrolidine Chemical compound CCC1CNC(CC)C1 JGSUVQJWOZRVIY-UHFFFAOYSA-N 0.000 description 1
- NTTDIFSMQCJOJJ-UHFFFAOYSA-N 2,4-dipropyl-1h-pyrrole Chemical compound CCCC1=CNC(CCC)=C1 NTTDIFSMQCJOJJ-UHFFFAOYSA-N 0.000 description 1
- ZOQVDXYAPXAFRW-UHFFFAOYSA-N 2,5-diethyl-1h-imidazole Chemical compound CCC1=CNC(CC)=N1 ZOQVDXYAPXAFRW-UHFFFAOYSA-N 0.000 description 1
- CIKZQBMEPDKJHF-UHFFFAOYSA-N 2,5-diethyl-1h-pyrrole Chemical compound CCC1=CC=C(CC)N1 CIKZQBMEPDKJHF-UHFFFAOYSA-N 0.000 description 1
- ZJXYOGYQMICNSB-UHFFFAOYSA-N 2,5-diethylmorpholine Chemical compound CCC1COC(CC)CN1 ZJXYOGYQMICNSB-UHFFFAOYSA-N 0.000 description 1
- IZLHISLQJGXQCV-UHFFFAOYSA-N 2,5-diethylpiperidine Chemical compound CCC1CCC(CC)NC1 IZLHISLQJGXQCV-UHFFFAOYSA-N 0.000 description 1
- RBUHUZRLXXOQLB-UHFFFAOYSA-N 2,5-diethylthiomorpholine Chemical compound CCC1CSC(CC)CN1 RBUHUZRLXXOQLB-UHFFFAOYSA-N 0.000 description 1
- YSMLZMWPDIHEJO-UHFFFAOYSA-N 2,5-dipropyl-1h-imidazole Chemical compound CCCC1=CNC(CCC)=N1 YSMLZMWPDIHEJO-UHFFFAOYSA-N 0.000 description 1
- RFXJLECGYGFJCI-UHFFFAOYSA-N 2-(2-methylpropyl)-1h-imidazole Chemical compound CC(C)CC1=NC=CN1 RFXJLECGYGFJCI-UHFFFAOYSA-N 0.000 description 1
- GABVVEAQQFIHHQ-UHFFFAOYSA-N 2-(2-methylpropyl)-1h-pyrrole Chemical compound CC(C)CC1=CC=CN1 GABVVEAQQFIHHQ-UHFFFAOYSA-N 0.000 description 1
- HNDXEVBVCNVVOW-UHFFFAOYSA-N 2-(2-methylpropyl)morpholine Chemical compound CC(C)CC1CNCCO1 HNDXEVBVCNVVOW-UHFFFAOYSA-N 0.000 description 1
- BYYCSTYYULCJLQ-UHFFFAOYSA-N 2-(2-methylpropyl)piperazine Chemical compound CC(C)CC1CNCCN1 BYYCSTYYULCJLQ-UHFFFAOYSA-N 0.000 description 1
- BGMFNTCQUCUODA-UHFFFAOYSA-N 2-(2-methylpropyl)piperidine Chemical compound CC(C)CC1CCCCN1 BGMFNTCQUCUODA-UHFFFAOYSA-N 0.000 description 1
- GNUABXXBKUNKNU-UHFFFAOYSA-N 2-(2-methylpropyl)pyrrolidine Chemical compound CC(C)CC1CCCN1 GNUABXXBKUNKNU-UHFFFAOYSA-N 0.000 description 1
- JOAMFAXCDSRQQY-UHFFFAOYSA-N 2-(2-methylpropyl)thiomorpholine Chemical compound CC(C)CC1CNCCS1 JOAMFAXCDSRQQY-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- NNWUEBIEOFQMSS-UHFFFAOYSA-N 2-Methylpiperidine Chemical compound CC1CCCCN1 NNWUEBIEOFQMSS-UHFFFAOYSA-N 0.000 description 1
- OTZWITHPRWRMMX-UHFFFAOYSA-N 2-butyl-1h-pyrrole Chemical compound CCCCC1=CC=CN1 OTZWITHPRWRMMX-UHFFFAOYSA-N 0.000 description 1
- BAMYKTWQZOABNK-UHFFFAOYSA-N 2-butylimidazolidine Chemical compound CCCCC1NCCN1 BAMYKTWQZOABNK-UHFFFAOYSA-N 0.000 description 1
- KEJDUUFWAWCFEE-UHFFFAOYSA-N 2-butylmorpholine Chemical compound CCCCC1CNCCO1 KEJDUUFWAWCFEE-UHFFFAOYSA-N 0.000 description 1
- CTEGAXWZJISNOR-UHFFFAOYSA-N 2-butylpiperazine Chemical compound CCCCC1CNCCN1 CTEGAXWZJISNOR-UHFFFAOYSA-N 0.000 description 1
- PCNXNSPEWIRGJO-UHFFFAOYSA-N 2-butylpiperidine Chemical compound CCCCC1CCCCN1 PCNXNSPEWIRGJO-UHFFFAOYSA-N 0.000 description 1
- CKHOSERPJPIUIL-UHFFFAOYSA-N 2-butylpyrrolidine Chemical compound CCCCC1CCCN1 CKHOSERPJPIUIL-UHFFFAOYSA-N 0.000 description 1
- RVRJFUUCVPPSGQ-UHFFFAOYSA-N 2-butylthiomorpholine Chemical compound CCCCC1CNCCS1 RVRJFUUCVPPSGQ-UHFFFAOYSA-N 0.000 description 1
- PQAMFDRRWURCFQ-UHFFFAOYSA-N 2-ethyl-1h-imidazole Chemical compound CCC1=NC=CN1 PQAMFDRRWURCFQ-UHFFFAOYSA-N 0.000 description 1
- XRPDDDRNQJNHLQ-UHFFFAOYSA-N 2-ethyl-1h-pyrrole Chemical compound CCC1=CC=CN1 XRPDDDRNQJNHLQ-UHFFFAOYSA-N 0.000 description 1
- VZTIXZKWQRGCGS-UHFFFAOYSA-N 2-ethyl-3,4,5-trimethylpyrrolidine Chemical compound CCC1NC(C)C(C)C1C VZTIXZKWQRGCGS-UHFFFAOYSA-N 0.000 description 1
- KKFCTXAMFCFNHL-UHFFFAOYSA-N 2-ethyl-3,5,6-trimethylmorpholine Chemical compound CCC1OC(C)C(C)NC1C KKFCTXAMFCFNHL-UHFFFAOYSA-N 0.000 description 1
- KRWLHJKHRJHIEJ-UHFFFAOYSA-N 2-ethyl-3-methylpyrrolidine Chemical compound CCC1NCCC1C KRWLHJKHRJHIEJ-UHFFFAOYSA-N 0.000 description 1
- GALBJULHRGPJEG-UHFFFAOYSA-N 2-ethyl-4-methyl-1h-pyrrole Chemical compound CCC1=CC(C)=CN1 GALBJULHRGPJEG-UHFFFAOYSA-N 0.000 description 1
- WISZZHKHSREDOZ-UHFFFAOYSA-N 2-ethyl-5-methylmorpholine Chemical compound CCC1CNC(C)CO1 WISZZHKHSREDOZ-UHFFFAOYSA-N 0.000 description 1
- FZJPNVAITGJFRT-UHFFFAOYSA-N 2-ethylimidazolidine Chemical compound CCC1NCCN1 FZJPNVAITGJFRT-UHFFFAOYSA-N 0.000 description 1
- RGNFMQJLAOONTP-UHFFFAOYSA-N 2-ethylmorpholine Chemical compound CCC1CNCCO1 RGNFMQJLAOONTP-UHFFFAOYSA-N 0.000 description 1
- DXOHZOPKNFZZAD-UHFFFAOYSA-N 2-ethylpiperazine Chemical compound CCC1CNCCN1 DXOHZOPKNFZZAD-UHFFFAOYSA-N 0.000 description 1
- JFZLDRUSMYBXRI-UHFFFAOYSA-N 2-ethylpyrrolidine Chemical compound CCC1CCCN1 JFZLDRUSMYBXRI-UHFFFAOYSA-N 0.000 description 1
- HBLYPCZZIIUFRO-UHFFFAOYSA-N 2-ethylthiomorpholine Chemical compound CCC1CNCCS1 HBLYPCZZIIUFRO-UHFFFAOYSA-N 0.000 description 1
- FPWOREZRJBDLRW-UHFFFAOYSA-N 2-methyl-4-propylpiperidine Chemical compound CCCC1CCNC(C)C1 FPWOREZRJBDLRW-UHFFFAOYSA-N 0.000 description 1
- TWPXTLLVNPZMRW-UHFFFAOYSA-N 2-methyl-5-propyl-1h-imidazole Chemical compound CCCC1=CNC(C)=N1 TWPXTLLVNPZMRW-UHFFFAOYSA-N 0.000 description 1
- NJBCRXCAPCODGX-UHFFFAOYSA-N 2-methyl-n-(2-methylpropyl)propan-1-amine Chemical compound CC(C)CNCC(C)C NJBCRXCAPCODGX-UHFFFAOYSA-N 0.000 description 1
- JUDVCTHUDHRSSD-UHFFFAOYSA-N 2-methylimidazolidine Chemical compound CC1NCCN1 JUDVCTHUDHRSSD-UHFFFAOYSA-N 0.000 description 1
- LQMMFVPUIVBYII-UHFFFAOYSA-N 2-methylmorpholine Chemical compound CC1CNCCO1 LQMMFVPUIVBYII-UHFFFAOYSA-N 0.000 description 1
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 1
- RGHPCLZJAFCTIK-UHFFFAOYSA-N 2-methylpyrrolidine Chemical compound CC1CCCN1 RGHPCLZJAFCTIK-UHFFFAOYSA-N 0.000 description 1
- MHHCLPHGZOISFK-UHFFFAOYSA-N 2-methylthiomorpholine Chemical compound CC1CNCCS1 MHHCLPHGZOISFK-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- FUOZJYASZOSONT-UHFFFAOYSA-N 2-propan-2-yl-1h-imidazole Chemical compound CC(C)C1=NC=CN1 FUOZJYASZOSONT-UHFFFAOYSA-N 0.000 description 1
- YYUISDWOKJLVMA-UHFFFAOYSA-N 2-propan-2-yl-1h-pyrrole Chemical compound CC(C)C1=CC=CN1 YYUISDWOKJLVMA-UHFFFAOYSA-N 0.000 description 1
- LQNJNYJJUZFGPD-UHFFFAOYSA-N 2-propan-2-ylimidazolidine Chemical compound CC(C)C1NCCN1 LQNJNYJJUZFGPD-UHFFFAOYSA-N 0.000 description 1
- HBCSNWKQNPKIHK-UHFFFAOYSA-N 2-propan-2-ylpiperazine Chemical compound CC(C)C1CNCCN1 HBCSNWKQNPKIHK-UHFFFAOYSA-N 0.000 description 1
- UGZMDPJPZIDCOA-UHFFFAOYSA-N 2-propan-2-ylpiperidine Chemical compound CC(C)C1CCCCN1 UGZMDPJPZIDCOA-UHFFFAOYSA-N 0.000 description 1
- UOADRGAJWNJVGC-UHFFFAOYSA-N 2-propan-2-ylpyrrolidine Chemical compound CC(C)C1CCCN1 UOADRGAJWNJVGC-UHFFFAOYSA-N 0.000 description 1
- PZXQCEVMESPTFU-UHFFFAOYSA-N 2-propan-2-ylthiomorpholine Chemical compound CC(C)C1CNCCS1 PZXQCEVMESPTFU-UHFFFAOYSA-N 0.000 description 1
- MKBBSFGKFMQPPC-UHFFFAOYSA-N 2-propyl-1h-imidazole Chemical compound CCCC1=NC=CN1 MKBBSFGKFMQPPC-UHFFFAOYSA-N 0.000 description 1
- BPPNDUBGLQQQBY-UHFFFAOYSA-N 2-propyl-1h-pyrrole Chemical compound CCCC1=CC=CN1 BPPNDUBGLQQQBY-UHFFFAOYSA-N 0.000 description 1
- KVAJLCAFIKOTEV-UHFFFAOYSA-N 2-propylimidazolidine Chemical compound CCCC1NCCN1 KVAJLCAFIKOTEV-UHFFFAOYSA-N 0.000 description 1
- QGJFIIKVYPIQAZ-UHFFFAOYSA-N 2-propylmorpholine Chemical compound CCCC1CNCCO1 QGJFIIKVYPIQAZ-UHFFFAOYSA-N 0.000 description 1
- FNJWLOHHZVGUIX-UHFFFAOYSA-N 2-propylpiperazine Chemical compound CCCC1CNCCN1 FNJWLOHHZVGUIX-UHFFFAOYSA-N 0.000 description 1
- VVEIRUXYIHIMNS-UHFFFAOYSA-N 2-propylthiomorpholine Chemical compound CCCC1CNCCS1 VVEIRUXYIHIMNS-UHFFFAOYSA-N 0.000 description 1
- ZAXCZCOUDLENMH-UHFFFAOYSA-N 3,3,3-tetramine Chemical compound NCCCNCCCNCCCN ZAXCZCOUDLENMH-UHFFFAOYSA-N 0.000 description 1
- JCHPLYNRJAYHQP-UHFFFAOYSA-N 3,4,5-triethyl-1h-pyrazole Chemical compound CCC1=NNC(CC)=C1CC JCHPLYNRJAYHQP-UHFFFAOYSA-N 0.000 description 1
- HUVAAOZUPLEYBH-UHFFFAOYSA-N 3,4,5-trimethyl-1h-pyrazole Chemical compound CC1=NNC(C)=C1C HUVAAOZUPLEYBH-UHFFFAOYSA-N 0.000 description 1
- BDCIRWNKBQKFTP-UHFFFAOYSA-N 3,4,5-trimethylpyrazolidine Chemical compound C1(C(C)NNC1C)C BDCIRWNKBQKFTP-UHFFFAOYSA-N 0.000 description 1
- VQTVFIMEENGCJA-UHFFFAOYSA-N 3,4-dimethyl-1H-pyrazole Chemical compound CC=1C=NNC=1C VQTVFIMEENGCJA-UHFFFAOYSA-N 0.000 description 1
- DMARKLLBOLWDJQ-UHFFFAOYSA-N 3,4-dimethylpyrazolidine Chemical compound CC1CNNC1C DMARKLLBOLWDJQ-UHFFFAOYSA-N 0.000 description 1
- UFLLSVUGUWBXJA-UHFFFAOYSA-N 3,5-diethyl-1h-pyrazole Chemical compound CCC=1C=C(CC)NN=1 UFLLSVUGUWBXJA-UHFFFAOYSA-N 0.000 description 1
- GCUDANCEKWHJRX-UHFFFAOYSA-N 3-(2-methylpropyl)-1h-pyrrole Chemical compound CC(C)CC=1C=CNC=1 GCUDANCEKWHJRX-UHFFFAOYSA-N 0.000 description 1
- INIRYZSIQPENMR-UHFFFAOYSA-N 3-(2-methylpropyl)morpholine Chemical compound CC(C)CC1COCCN1 INIRYZSIQPENMR-UHFFFAOYSA-N 0.000 description 1
- HIYDGLLISXSAIC-UHFFFAOYSA-N 3-(2-methylpropyl)pyrrolidine Chemical compound CC(C)CC1CCNC1 HIYDGLLISXSAIC-UHFFFAOYSA-N 0.000 description 1
- HVYMDUDIDYTIHS-UHFFFAOYSA-N 3-(2-methylpropyl)thiomorpholine Chemical compound C(C(C)C)C1NCCSC1 HVYMDUDIDYTIHS-UHFFFAOYSA-N 0.000 description 1
- KXKXSYDPJSQSPP-UHFFFAOYSA-N 3-butylmorpholine Chemical compound CCCCC1COCCN1 KXKXSYDPJSQSPP-UHFFFAOYSA-N 0.000 description 1
- HWWOYRDUDOPLLL-UHFFFAOYSA-N 3-butylpiperidine Chemical compound CCCCC1CCCNC1 HWWOYRDUDOPLLL-UHFFFAOYSA-N 0.000 description 1
- ITXHMAKWUAAKMJ-UHFFFAOYSA-N 3-butylpyrazolidine Chemical compound C(CCC)C1NNCC1 ITXHMAKWUAAKMJ-UHFFFAOYSA-N 0.000 description 1
- KJQYMASXDMSGQU-UHFFFAOYSA-N 3-butylpyrrolidine Chemical compound CCCCC1CCNC1 KJQYMASXDMSGQU-UHFFFAOYSA-N 0.000 description 1
- QWCOYLHSPLONNI-UHFFFAOYSA-N 3-butylthiomorpholine Chemical compound CCCCC1CSCCN1 QWCOYLHSPLONNI-UHFFFAOYSA-N 0.000 description 1
- RLLBWIDEGAIFPI-UHFFFAOYSA-N 3-ethyl-1h-pyrrole Chemical compound CCC=1C=CNC=1 RLLBWIDEGAIFPI-UHFFFAOYSA-N 0.000 description 1
- ZXYASTYREUECCW-UHFFFAOYSA-N 3-ethyl-5-methyl-1h-pyrazole Chemical compound CCC=1C=C(C)NN=1 ZXYASTYREUECCW-UHFFFAOYSA-N 0.000 description 1
- JBQWQBSRIAGTJT-UHFFFAOYSA-N 3-ethylmorpholine Chemical compound CCC1COCCN1 JBQWQBSRIAGTJT-UHFFFAOYSA-N 0.000 description 1
- YLUDSYGJHAQGOD-UHFFFAOYSA-N 3-ethylpiperidine Chemical compound CCC1CCCNC1 YLUDSYGJHAQGOD-UHFFFAOYSA-N 0.000 description 1
- DZFFQSFNUBWNSF-UHFFFAOYSA-N 3-ethylpyrrolidine Chemical compound CCC1CCNC1 DZFFQSFNUBWNSF-UHFFFAOYSA-N 0.000 description 1
- YJJLBCDRIUBMQF-UHFFFAOYSA-N 3-ethylthiomorpholine Chemical compound CCC1CSCCN1 YJJLBCDRIUBMQF-UHFFFAOYSA-N 0.000 description 1
- XYUINKARGUCCQJ-UHFFFAOYSA-N 3-imino-n-propylpropan-1-amine Chemical compound CCCNCCC=N XYUINKARGUCCQJ-UHFFFAOYSA-N 0.000 description 1
- FEKWWZCCJDUWLY-UHFFFAOYSA-N 3-methyl-1h-pyrrole Chemical compound CC=1C=CNC=1 FEKWWZCCJDUWLY-UHFFFAOYSA-N 0.000 description 1
- WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 description 1
- SFWWGMKXCYLZEG-UHFFFAOYSA-N 3-methylmorpholine Chemical compound CC1COCCN1 SFWWGMKXCYLZEG-UHFFFAOYSA-N 0.000 description 1
- JEGMWWXJUXDNJN-UHFFFAOYSA-N 3-methylpiperidine Chemical compound CC1CCCNC1 JEGMWWXJUXDNJN-UHFFFAOYSA-N 0.000 description 1
- KYINPWAJIVTFBW-UHFFFAOYSA-N 3-methylpyrrolidine Chemical compound CC1CCNC1 KYINPWAJIVTFBW-UHFFFAOYSA-N 0.000 description 1
- KZZPRWYOUNLBQK-UHFFFAOYSA-N 3-methylthiomorpholine Chemical compound CC1CSCCN1 KZZPRWYOUNLBQK-UHFFFAOYSA-N 0.000 description 1
- LYUQWQRTDLVQGA-UHFFFAOYSA-N 3-phenylpropylamine Chemical compound NCCCC1=CC=CC=C1 LYUQWQRTDLVQGA-UHFFFAOYSA-N 0.000 description 1
- DVCXAZNRWJRKHF-UHFFFAOYSA-N 3-propan-2-yl-1h-pyrrole Chemical compound CC(C)C=1C=CNC=1 DVCXAZNRWJRKHF-UHFFFAOYSA-N 0.000 description 1
- ICNOQWMTDGMVGW-UHFFFAOYSA-N 3-propan-2-ylmorpholine Chemical compound CC(C)C1COCCN1 ICNOQWMTDGMVGW-UHFFFAOYSA-N 0.000 description 1
- FKEYLVBZOQMOOV-UHFFFAOYSA-N 3-propan-2-ylpiperidine Chemical compound CC(C)C1CCCNC1 FKEYLVBZOQMOOV-UHFFFAOYSA-N 0.000 description 1
- QFHZPMOJWIBZCS-UHFFFAOYSA-N 3-propan-2-ylpyrrolidine Chemical compound CC(C)C1CCNC1 QFHZPMOJWIBZCS-UHFFFAOYSA-N 0.000 description 1
- NSRDOAOPORIBFB-UHFFFAOYSA-N 3-propan-2-ylthiomorpholine Chemical compound CC(C)C1CSCCN1 NSRDOAOPORIBFB-UHFFFAOYSA-N 0.000 description 1
- FAOPZUAEZGKQNC-UHFFFAOYSA-N 3-propyl-1h-pyrrole Chemical compound CCCC=1C=CNC=1 FAOPZUAEZGKQNC-UHFFFAOYSA-N 0.000 description 1
- ACDQSRFDVDVZRK-UHFFFAOYSA-N 3-propylmorpholine Chemical compound CCCC1COCCN1 ACDQSRFDVDVZRK-UHFFFAOYSA-N 0.000 description 1
- CRZUKKNUMNKBFJ-UHFFFAOYSA-N 3-propylpiperidine Chemical compound CCCC1CCCNC1 CRZUKKNUMNKBFJ-UHFFFAOYSA-N 0.000 description 1
- RKFKEXKTXWGBCN-UHFFFAOYSA-N 3-propylpyrrolidine Chemical compound CCCC1CCNC1 RKFKEXKTXWGBCN-UHFFFAOYSA-N 0.000 description 1
- WTKRIUOKJBVJRN-UHFFFAOYSA-N 3-propylthiomorpholine Chemical compound CCCC1CSCCN1 WTKRIUOKJBVJRN-UHFFFAOYSA-N 0.000 description 1
- UEWZEKSDNFZZIX-UHFFFAOYSA-N 4,4-dipropylpiperidine Chemical compound CCCC1(CCC)CCNCC1 UEWZEKSDNFZZIX-UHFFFAOYSA-N 0.000 description 1
- GKACWKBRMVLLQV-UHFFFAOYSA-N 4,5-dipropyl-1H-pyrazole Chemical compound CCCC=1C=NNC=1CCC GKACWKBRMVLLQV-UHFFFAOYSA-N 0.000 description 1
- NKYDATLMFPYEJM-UHFFFAOYSA-N 4-(2-methylpropyl)-1h-pyrazole Chemical compound CC(C)CC=1C=NNC=1 NKYDATLMFPYEJM-UHFFFAOYSA-N 0.000 description 1
- FUUJPVISQYKVAX-UHFFFAOYSA-N 4-(2-methylpropyl)piperidine Chemical compound CC(C)CC1CCNCC1 FUUJPVISQYKVAX-UHFFFAOYSA-N 0.000 description 1
- NFZNTHKHEVTUTB-UHFFFAOYSA-N 4-(2-methylpropyl)pyrazolidine Chemical compound CC(C)CC1CNNC1 NFZNTHKHEVTUTB-UHFFFAOYSA-N 0.000 description 1
- XIQSPCJCAJVNJL-UHFFFAOYSA-N 4-butylpiperidine Chemical compound CCCCC1CCNCC1 XIQSPCJCAJVNJL-UHFFFAOYSA-N 0.000 description 1
- IICLXIBRBDMFIC-UHFFFAOYSA-N 4-butylpyrazole Chemical compound CCCCC1=CN=N[CH]1 IICLXIBRBDMFIC-UHFFFAOYSA-N 0.000 description 1
- WZQSFHYYVUHUNU-UHFFFAOYSA-N 4-butylpyrazolidine Chemical compound CCCCC1CNNC1 WZQSFHYYVUHUNU-UHFFFAOYSA-N 0.000 description 1
- IHNXHUNMFYXQCG-UHFFFAOYSA-N 4-ethyl-1h-pyrazole Chemical compound CCC=1C=NNC=1 IHNXHUNMFYXQCG-UHFFFAOYSA-N 0.000 description 1
- KWHPWBXOLZTZMJ-UHFFFAOYSA-N 4-ethylpiperidine Chemical compound CCC1CCNCC1 KWHPWBXOLZTZMJ-UHFFFAOYSA-N 0.000 description 1
- CQIKLEHEXOGHRN-UHFFFAOYSA-N 4-ethylpyrazolidine Chemical compound CCC1CNNC1 CQIKLEHEXOGHRN-UHFFFAOYSA-N 0.000 description 1
- SPPFMFXKGYNRER-UHFFFAOYSA-N 4-methylpyrazolidine Chemical compound CC1CNNC1 SPPFMFXKGYNRER-UHFFFAOYSA-N 0.000 description 1
- WVMBISZHWMJNNM-UHFFFAOYSA-N 4-propan-2-yl-1h-pyrazole Chemical compound CC(C)C=1C=NNC=1 WVMBISZHWMJNNM-UHFFFAOYSA-N 0.000 description 1
- XLZMWNWNBXSZKF-UHFFFAOYSA-N 4-propan-2-ylmorpholine Chemical compound CC(C)N1CCOCC1 XLZMWNWNBXSZKF-UHFFFAOYSA-N 0.000 description 1
- YBPWIUSXQXYTSR-UHFFFAOYSA-N 4-propan-2-ylpiperidine Chemical compound CC(C)C1CCNCC1 YBPWIUSXQXYTSR-UHFFFAOYSA-N 0.000 description 1
- YAXKXMVDJJMGRY-UHFFFAOYSA-N 4-propyl-1h-pyrazole Chemical compound CCCC=1C=NNC=1 YAXKXMVDJJMGRY-UHFFFAOYSA-N 0.000 description 1
- RQGBFVLTFYRYKB-UHFFFAOYSA-N 4-propylpiperidine Chemical compound CCCC1CCNCC1 RQGBFVLTFYRYKB-UHFFFAOYSA-N 0.000 description 1
- JOKUNFNEMQJMSH-UHFFFAOYSA-N 4-propylpyrazolidine Chemical compound CCCC1CNNC1 JOKUNFNEMQJMSH-UHFFFAOYSA-N 0.000 description 1
- MGCDHLCYJZAAKL-UHFFFAOYSA-N 4-propylthiomorpholine Chemical compound CCCN1CCSCC1 MGCDHLCYJZAAKL-UHFFFAOYSA-N 0.000 description 1
- YOTBOYFKPMRBAG-UHFFFAOYSA-N 5-butyl-1h-imidazole Chemical compound CCCCC1=CNC=N1 YOTBOYFKPMRBAG-UHFFFAOYSA-N 0.000 description 1
- VZNUCJOYPXKLTA-UHFFFAOYSA-N 5-chlorobenzene-1,3-diamine Chemical compound NC1=CC(N)=CC(Cl)=C1 VZNUCJOYPXKLTA-UHFFFAOYSA-N 0.000 description 1
- KJIXYUGPFRMNHL-UHFFFAOYSA-N 5-ethyl-2,3-dimethylpyrrolidine Chemical compound CCC1CC(C)C(C)N1 KJIXYUGPFRMNHL-UHFFFAOYSA-N 0.000 description 1
- QBNRQCHCKIIYGV-UHFFFAOYSA-N 5-propyl-1h-pyrazole Chemical compound CCCC1=CC=NN1 QBNRQCHCKIIYGV-UHFFFAOYSA-N 0.000 description 1
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical compound CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 description 1
- YASWPPDTDPHHQD-UHFFFAOYSA-N 6-ethyl-2,3-dimethylmorpholine Chemical compound CCC1CNC(C)C(C)O1 YASWPPDTDPHHQD-UHFFFAOYSA-N 0.000 description 1
- LWZGDLDSCSOWNN-UHFFFAOYSA-N C(C(C)C)C1NCCN1 Chemical compound C(C(C)C)C1NCCN1 LWZGDLDSCSOWNN-UHFFFAOYSA-N 0.000 description 1
- TXRBLUMOBHWYIH-UHFFFAOYSA-N C(C)C1C(NC(C(S1)C)C)C Chemical compound C(C)C1C(NC(C(S1)C)C)C TXRBLUMOBHWYIH-UHFFFAOYSA-N 0.000 description 1
- XDMWLWRMSQUKMT-UHFFFAOYSA-N C(C)C1C(NCC(S1)CC)CC Chemical compound C(C)C1C(NCC(S1)CC)CC XDMWLWRMSQUKMT-UHFFFAOYSA-N 0.000 description 1
- FCXMJBNTRRMMKH-UHFFFAOYSA-N C(C)C1C(NCCS1)C Chemical compound C(C)C1C(NCCS1)C FCXMJBNTRRMMKH-UHFFFAOYSA-N 0.000 description 1
- UBJQMPCRHORCBZ-UHFFFAOYSA-N C(C)C1NC(C(C(C1CC)CC)CC)CC Chemical compound C(C)C1NC(C(C(C1CC)CC)CC)CC UBJQMPCRHORCBZ-UHFFFAOYSA-N 0.000 description 1
- YFOIZGJILPNHAU-UHFFFAOYSA-N C(C)C1NC(C(NC1C)C)C Chemical compound C(C)C1NC(C(NC1C)C)C YFOIZGJILPNHAU-UHFFFAOYSA-N 0.000 description 1
- GYATZTQPZFBCMG-UHFFFAOYSA-N C(C)C1NNC(C1)CC Chemical compound C(C)C1NNC(C1)CC GYATZTQPZFBCMG-UHFFFAOYSA-N 0.000 description 1
- IBRXLRKYMYVXAW-UHFFFAOYSA-N C(C)N1CNC(C1CC)CCC Chemical compound C(C)N1CNC(C1CC)CCC IBRXLRKYMYVXAW-UHFFFAOYSA-N 0.000 description 1
- QTSOEFANNWSBNZ-UHFFFAOYSA-N C(C)N1NC(C(C1)CC)CCC Chemical compound C(C)N1NC(C(C1)CC)CCC QTSOEFANNWSBNZ-UHFFFAOYSA-N 0.000 description 1
- ZMHSDPMGAMZJNN-UHFFFAOYSA-N C(C)N1NC(C(C1CCC)CC)CCC Chemical compound C(C)N1NC(C(C1CCC)CC)CCC ZMHSDPMGAMZJNN-UHFFFAOYSA-N 0.000 description 1
- LYGKFFLYRIAMRA-UHFFFAOYSA-N C(CC)N1CC(NC(C1CCC)CCC)CCC Chemical compound C(CC)N1CC(NC(C1CCC)CCC)CCC LYGKFFLYRIAMRA-UHFFFAOYSA-N 0.000 description 1
- ICKARPHMVNGWOS-UHFFFAOYSA-N C(CC)N1NC(CC1)CCC Chemical compound C(CC)N1NC(CC1)CCC ICKARPHMVNGWOS-UHFFFAOYSA-N 0.000 description 1
- NMDIOKNDSFBHEB-UHFFFAOYSA-N CC1CNCC(S1)CCC Chemical compound CC1CNCC(S1)CCC NMDIOKNDSFBHEB-UHFFFAOYSA-N 0.000 description 1
- SGPJCTKTURVVGI-UHFFFAOYSA-N CC1N(C(C(N1)C)C)C Chemical compound CC1N(C(C(N1)C)C)C SGPJCTKTURVVGI-UHFFFAOYSA-N 0.000 description 1
- AWWRZXNOKSAWSI-UHFFFAOYSA-N CC1NCC(NC1C)CC Chemical compound CC1NCC(NC1C)CC AWWRZXNOKSAWSI-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WRYCSMQKUKOKBP-UHFFFAOYSA-N Imidazolidine Chemical compound C1CNCN1 WRYCSMQKUKOKBP-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OJGMBLNIHDZDGS-UHFFFAOYSA-N N-Ethylaniline Chemical compound CCNC1=CC=CC=C1 OJGMBLNIHDZDGS-UHFFFAOYSA-N 0.000 description 1
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- QLBRROYTTDFLDX-UHFFFAOYSA-N [3-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCCC(CN)C1 QLBRROYTTDFLDX-UHFFFAOYSA-N 0.000 description 1
- FNRPJSOYBBTUAY-UHFFFAOYSA-N [K].N1(CCNCC1)C(=S)S Chemical compound [K].N1(CCNCC1)C(=S)S FNRPJSOYBBTUAY-UHFFFAOYSA-N 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- BELZJFWUNQWBES-UHFFFAOYSA-N caldopentamine Chemical compound NCCCNCCCNCCCNCCCN BELZJFWUNQWBES-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 125000005265 dialkylamine group Chemical group 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UPCIBFUJJLCOQG-UHFFFAOYSA-L ethyl-[2-[2-[ethyl(dimethyl)azaniumyl]ethyl-methylamino]ethyl]-dimethylazanium;dibromide Chemical compound [Br-].[Br-].CC[N+](C)(C)CCN(C)CC[N+](C)(C)CC UPCIBFUJJLCOQG-UHFFFAOYSA-L 0.000 description 1
- LIWAQLJGPBVORC-UHFFFAOYSA-N ethylmethylamine Chemical compound CCNC LIWAQLJGPBVORC-UHFFFAOYSA-N 0.000 description 1
- RIKMMFOAQPJVMX-UHFFFAOYSA-N fomepizole Chemical compound CC=1C=NNC=1 RIKMMFOAQPJVMX-UHFFFAOYSA-N 0.000 description 1
- 229960004285 fomepizole Drugs 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Substances OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- KMBPCQSCMCEPMU-UHFFFAOYSA-N n'-(3-aminopropyl)-n'-methylpropane-1,3-diamine Chemical compound NCCCN(C)CCCN KMBPCQSCMCEPMU-UHFFFAOYSA-N 0.000 description 1
- QHJABUZHRJTCAR-UHFFFAOYSA-N n'-methylpropane-1,3-diamine Chemical compound CNCCCN QHJABUZHRJTCAR-UHFFFAOYSA-N 0.000 description 1
- QKYWADPCTHTJHQ-UHFFFAOYSA-N n,2-dimethylpropan-1-amine Chemical compound CNCC(C)C QKYWADPCTHTJHQ-UHFFFAOYSA-N 0.000 description 1
- CCRUHKGZAQXBKC-UHFFFAOYSA-N n-(2-methylpropyl)butan-1-amine Chemical compound CCCCNCC(C)C CCRUHKGZAQXBKC-UHFFFAOYSA-N 0.000 description 1
- VSHTWPWTCXQLQN-UHFFFAOYSA-N n-butylaniline Chemical compound CCCCNC1=CC=CC=C1 VSHTWPWTCXQLQN-UHFFFAOYSA-N 0.000 description 1
- FNLUJDLKYOWMMF-UHFFFAOYSA-N n-ethyl-2-methylpropan-1-amine Chemical compound CCNCC(C)C FNLUJDLKYOWMMF-UHFFFAOYSA-N 0.000 description 1
- QHCCDDQKNUYGNC-UHFFFAOYSA-N n-ethylbutan-1-amine Chemical compound CCCCNCC QHCCDDQKNUYGNC-UHFFFAOYSA-N 0.000 description 1
- PYLYAOCAPJNZKM-UHFFFAOYSA-N n-ethylethanamine;potassium Chemical compound [K].CCNCC PYLYAOCAPJNZKM-UHFFFAOYSA-N 0.000 description 1
- XCVNDBIXFPGMIW-UHFFFAOYSA-N n-ethylpropan-1-amine Chemical compound CCCNCC XCVNDBIXFPGMIW-UHFFFAOYSA-N 0.000 description 1
- RIVIDPPYRINTTH-UHFFFAOYSA-N n-ethylpropan-2-amine Chemical compound CCNC(C)C RIVIDPPYRINTTH-UHFFFAOYSA-N 0.000 description 1
- XHFGWHUWQXTGAT-UHFFFAOYSA-N n-methylpropan-2-amine Chemical compound CNC(C)C XHFGWHUWQXTGAT-UHFFFAOYSA-N 0.000 description 1
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 description 1
- FRCFWPVMFJMNDP-UHFFFAOYSA-N n-propan-2-ylaniline Chemical compound CC(C)NC1=CC=CC=C1 FRCFWPVMFJMNDP-UHFFFAOYSA-N 0.000 description 1
- VLSTXUUYLIALPB-UHFFFAOYSA-N n-propan-2-ylpropan-1-amine Chemical compound CCCNC(C)C VLSTXUUYLIALPB-UHFFFAOYSA-N 0.000 description 1
- CWYZDPHNAGSFQB-UHFFFAOYSA-N n-propylbutan-1-amine Chemical compound CCCCNCCC CWYZDPHNAGSFQB-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 150000004885 piperazines Chemical class 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- USPWKWBDZOARPV-UHFFFAOYSA-N pyrazolidine Chemical compound C1CNNC1 USPWKWBDZOARPV-UHFFFAOYSA-N 0.000 description 1
- 150000003218 pyrazolidines Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- BHRZNVHARXXAHW-UHFFFAOYSA-N sec-butylamine Chemical compound CCC(C)N BHRZNVHARXXAHW-UHFFFAOYSA-N 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- BRNULMACUQOKMR-UHFFFAOYSA-N thiomorpholine Chemical compound C1CSCCN1 BRNULMACUQOKMR-UHFFFAOYSA-N 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Landscapes
- Processing Of Solid Wastes (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
【解決手段】アミン類の窒素に結合した活性水素のうちの50%を超える活性水素と置換して導入されたジチオ酸型官能基を有するジチオカルバミン酸型重金属固定化処理剤と、アミン類の窒素に結合した活性水素のうちの50%以下の活性水素と置換して導入されたN−置換基を有するアミン類誘導体とを廃棄物に添加し、廃棄物中の重金属を不溶化する。
【選択図】 なし
Description
(1)アミン類の窒素に結合した活性水素のうちの50%を超える活性水素と置換して導入されたジチオ酸型官能基を有するジチオカルバミン酸型重金属固定化処理剤と、アミン類の窒素に結合した活性水素のうちの50%以下の活性水素と置換して導入されたN−置換基を有するアミン誘導体とを廃棄物に添加し、廃棄物中の重金属を不溶化することを特徴とする廃棄物処理方法、
(2)廃棄物が飛灰である上記(1)記載の廃棄物処理方法、
(3)アミン類の窒素に結合した活性水素のうちの50%を超える活性水素と置換して導入されたジチオ酸型官能基を有するジチオカルバミン酸型重金属固定化処理剤と、アミン類の窒素に結合した活性水素のうちの50%以下の活性水素と置換して導入されたN−置換基を有するアミン誘導体とからなることを特徴とする重金属固定化処理剤組成物、
を要旨とするものである。
またチオモルホリン;2−メチルチオモルホリン、2−エチルチオモルホリン、2−プロピルチオモルホリン、2−イソプロピルチオモルホリン、2−ブチルチオモルホリン、2−イソブチルチオモルホリン、3−メチルチオモルホリン、3−エチルチオモルホリン、3−プロピルチオモルホリン、3−イソプロピルチオモルホリン、3−ブチルチオモルホリン、3−イソブチルチオモルホリン等のモノアルキルチオモルホリン、2,3−ジメチルチオモルホリン、2,5−ジエチルチオモルホリン、2,6−ジプロピルチオモルホリン、2−エチル−3−メチルチオモルホリン、2−メチル−6−プロピルチオモルホリン等のジアルキルチオモルホリン;2,3,5−トリメチルチオモルホリン、2,3,6−トリエチルチオモルホリン等のトリアルキルチオモルホリン;2,3,5,6−テトラメチルチオモルホリン、2−エチル−3,5,6−トリメチルチオモルホリン等のテトラアルキルチオモルホリン;イミダゾリジン;1−メチルイミダゾリジン、1−エチルイミダゾリジン、1−プロピルイミダゾリジン、1−イソプロピルイミダゾリジン、1−ブチルイミダゾリジン、1−イソブチルイミダゾリジン、2−メチルイミダゾリジン、2−エチルイミダゾリジン、2−プロピルイミダゾリジン、2−イソプロピルイミダゾリジン、2−ブチルイミダゾリジン、2−イソブチルイミダゾリジン、3−メチルイミダゾリジン、3−エチルイミダゾリジン、3−プロピルイミダゾリジン、3−イソプロピルイミダゾリジン、3−ブチルイミダゾリジン、3−イソブチルイミダゾリジン、4−メチルイミダゾリジン、4−エチルイミダゾリジン、4−プロピルイミダゾリジン、4−イソプロピルイミダゾリジン、4−ブチルイミダゾリジン、4−イソブチルイミダゾリジン、5−メチルイミダゾリジン、5−エチルイミダゾリジン、5−プロピルイミダゾリジン、5−イソプロピルイミダゾリジン、5−ブチルイミダゾリジン、5−イソブチルイミダゾリジン等のモノアルキルイミダゾリジン;2,3−ジメチルイミダゾリジン、2,5−ジエチルイミダゾリジン、4,5−ジプロピルイミダゾリジン、1−メチル−4−プロピルイミダゾリジン等のジアルキルイミダゾリジン;2,4,5−トリメチルイミダゾリジン、3,4−ジエチル−5−プロピルイミダゾリジン等のトリアルキルイミダゾリジン;2,3,4,5−テトラメチルイミダゾリジン、1,2,4,5−テトラメチルイミダゾリジン等のテトラアルキルイミダゾリジン;ピラゾリジン;1−メチルピラゾリジン、1−エチルピラゾリジン、1−プロピルピラゾリジン、1−イソプロピルピラゾリジン、1−ブチルピラゾリジン、1−イソブチルピラゾリジン、2−メチルピラゾリジン、2−エチルピラゾリジン、2−プロピルピラゾリジン、2−イソプロピルピラゾリジン、2−ブチルピラゾリジン、2−イソブチルピラゾリジン、3−メチルピラゾリジン、3−エチルピラゾリジン、3−プロピルピラゾリジン、3−イソプロピルピラゾリジン、3−ブチルピラゾリジン、3−イソブチルピラゾリジン、4−メチルピラゾリジン、4−エチルピラゾリジン、4−プロピルピラゾリジン、4−イソプロピルピラゾリジン、4−ブチルピラゾリジン、4−イソブチルピラゾリジン、5−メチルピラゾリジン、5−エチルピラゾリジン、5−プロピルピラゾリジン、5−イソプロピルピラゾリジン、5−ブチルピラゾリジン、5−イソブチルピラゾリジン等のモノアルキルピラゾリジン;3,4−ジメチルピラゾリジン、3,5−ジエチルピラゾリジン、2,5−ジプロピルピラゾリジン、3−メチル−5−プロピルピラゾリジン等のジアルキルピラゾリジン;3,4,5−トリメチルピラゾリジン、2,4−ジエチル−5−プロピルピラゾリジン等のトリアルキルピラゾリジン;2,3,4,5−テトラメチルピラゾリジン、1,4−ジエチル−3,5−ジプロピルピラゾリジン等のテトラアルキルピラゾリジン;ピロール;2−メチルピロール、2−エチルピロール、2−プロピルピロール、2−イソプロピルピロール、2−ブチルピロール、2−イソブチルピロール、3−メチルピロール、3−エチルピロール、3−プロピルピロール、3−イソプロピルピロール、3−ブチルピロール、3−イソブチルピロール等のモノアルキルピロール;2,3−ジメチルピロール、2,5−ジエチルピロール、2,4−ジプロピルピロール、2−エチル−4−メチルピロール、2−メチル−3−プロピルピロール等のジアルキルピロール;2,3,4−トリメチルピロール、2,3,5−トリエチルピロール等のトリアルキルピロール;2,3,4,5−テトラメチルピロール、2−エチル−3,4,5−トリメチルピロール等のテトラアルキルピロール;イミダゾール;2−メチルイミダゾール、2−エチルイミダゾール、2−プロピルイミダゾール、2−イソプロピルイミダゾール、2−ブチルイミダゾール、2−イソブチルイミダゾール、4−メチルイミダゾール、4−エチルイミダゾール、4−プロピルイミダゾール、4−イソプロピルイミダゾール、4−ブチルイミダゾール、4−イソブチルイミダゾール、5−メチルイミダゾール、5−エチルイミダゾール、5−プロピルイミダゾール、5−イソプロピルイミダゾール、5−ブチルイミダゾール、5−イソブチルイミダゾール等のモノアルキルイミダゾール、2,4−ジメチルイミダゾール、2,5−ジエチルイミダゾール、2,4−ジプロピルイミダゾール、2−エチル−4−メチルイミダゾール、2−メチル−5−プロピルイミダゾール等のジアルキルイミダゾール;2,4,5−トリメチルイミダゾール、2,4,5−トリエチルイミダゾール等のトリアルキルイミダゾール;ピラゾール;3−メチルピラゾール、3−エチルピラゾール、3−プロピルピラゾール、3−イソプロピルピラゾール、3−ブチルピラゾール、3−イソブチルピラゾール、4−メチルピラゾール、4−エチルピラゾール、4−プロピルピラゾール、4−イソプロピルピラゾール、4−ブチルピラゾール、4−イソブチルピラゾール、5−メチルピラゾール、5−エチルピラゾール、5−プロピルピラゾール、5−イソプロピルピラゾール、5−ブチルピラゾール、5−イソブチルピラゾール等のモノアルキルピラゾール、3,4−ジメチルピラゾール、3,5−ジエチルピラゾール、3,4−ジプロピルピラゾール、3−エチル−5−メチルピラゾール等のジアルキルピラゾール;3,4,5−トリメチルピラゾール、3,4,5−トリエチルピラゾール等のトリアルキルピラゾール;フェニレンジアミン、o−,m−,p−キシリレンジアミン、3,5−ジアミノクロロベンゼン、アニリン等の芳香族アミン;1,3−ビス(アミノメチル)シクロヘキサン等のシクロアルカン系ポリアミン;ポリエチレンイミン、ポリプロピレンイミン、ポリ−3−メチルプロピルイミン、ポリ−2−エチルプロピルイミン等の環状イミン重合体;ポリビニルアミン、ポリアリルアミン等の不飽和アミンの重合体が挙げられる。また、ビニルアミン、アリルアミン等の不飽和アミンと、ジメチルアクリルアミド、スチレン、アクリル酸メチル、メタクリル酸メチル、アクリル酸、メタクリル酸、スチレンスルホン酸等及びその塩類等の、不飽和アミンと共重合可能な不飽和結合を有する他のモノマーとの共重合体、ポリエチレンイミン・塩化ベンジル縮合物等も挙げられる。これらは2種以上の混合物を用いることもできる。
(1)重金属固定化処理剤A:N,N−ジエチルアミン−N−カルボジチオ酸カリウム(ジエチルアミンの窒素に結合した活性水素とジチオ酸基型官能基の置換率100%)。
(2)重金属固定化処理剤B:テトラエチレンペンタミン−N,N′,N′′,N′′′−テトラカルボジチオ酸ナトリウム(テトラエチレンペンタミンの窒素に結合した活性水素とジチオ酸基型官能基の置換率57%)。
(3)重金属固定化処理剤C:ピペラジン−N,N′−ビスカルボジチオ酸カリウム(ピペラジンの窒素に結合した活性水素とジチオ酸基型官能基の置換率100%)。
(4)重金属固定化処理剤D:ポリエチレンイミン・塩化ベンジル縮合物の窒素にジチオ酸ナトリウムを導入した化合物(ポリエチレンイミンの窒素に結合した活性水素とジチオ酸型官能基の置換率60%)とテトラエチレンペンタミン−N,N′,N′′,N′′′−テトラカルボジチオ酸ナトリウム(テトラエチレンペンタミンの窒素に結合した活性水素とジチオ酸基型官能基の置換率57%)の1:8(重量比)混合物。
(5)重金属固定化処理剤E:ポリエチレンイミン・塩化ベンジル縮合物の窒素にジチオ酸カリウムを導入した化合物(ポリエチレンイミンの窒素に結合した活性水素とジチオ酸型官能基の置換率60%)とピペラジン−N,N′−ビスカルボジチオ酸カリウム(ピペラジンの窒素に結合した活性水素とジチオ酸基型官能基の置換率100%)との1:10(重量比)混合物。
(1)アミン誘導体A:テトラエチレンペンタミンに対し1倍モルのホルムアルデヒドを反応させることで得られたテトラエチレンペンタミン−N−メタノール(テトラエチレンペンタミンの窒素に結合した活性水素と水酸基型官能基の置換率14%)
(2)アミン誘導体B:テトラエチレンペンタミンに対し1倍モルのアクリル酸メチルを反応させた後、水酸化ナトリウムでケン化分解することで得られた テトラエチレンペンタミン−N,−プロパン酸ナトリウム(テトラエチレンペンタミンの窒素に結合した活性水素とカルボキシル基型官能基の置換率14%)
(3)アミン誘導体C:ピペラジンに対し1倍モルの二硫化炭素と水酸化カリウムを反応させることで得られたピペラジン−N−カルボジチオ酸カリウム(ピペラジンの窒素に結合した活性水素とジチオ酸基型官能基の置換率50%)
(4)アミン誘導体D:テトラエチレンペンタミンに対し1倍モルの二硫化炭素と水酸化ナトリウムを反応させることで得られたテトラエチレンペンタミン−N−カルボジチオ酸ナトリウム(テトラエチレンペンタミンの窒素に結合した活性水素とジチオ酸基型官能基の置換率14%)
ゴミ焼却によって生じた飛灰100g当たり、表1に示すジチオカルバミン酸型重金属固定化処理剤とアミン誘導体とを同表に示す割合で混合した重金属固定化処理剤組成物0.8g(無水物として)と水を合計量20gとなるように添加して、10分間混練した。処理後の飛灰からの金属溶出量を環境庁告示13号試験法に基づいて測定した結果を、表1に示した。また、下記の測定方法にて二硫化炭素発生量を測定した結果を表1に合わせて示す。
密栓した500ml四つ口フラスコにアルカリ性飛灰を20.0g仕込み、窒素置換した後、0.4g(無水物として)の重金属固定化処理剤と水の合計量が30.0gに調整して均一に溶解し、飛灰に添加した。添加後、60℃で15分間攪拌した後、二硫化炭素検知管(株式会社ガステック製)にて二硫化炭素発生量を測定した。
飛灰100g当たり表1に示す重金属固定化処理剤100gを添加した他は実施例1〜6と同様に飛灰を処理した。処理後の飛灰からの金属溶出量を実施例1〜6と同様にして測定した。また二硫化炭素発生量の測定結果を表2にあわせて示す。
Claims (3)
- アミン類の窒素に結合した活性水素のうちの50%を超える活性水素と置換して導入されたジチオ酸型官能基を有するジチオカルバミン酸型重金属固定化処理剤と、アミン類の窒素に結合した活性水素のうちの50%以下の活性水素と置換して導入されたN−置換基を有するアミン類誘導体とを廃棄物に添加し、廃棄物中の重金属を不溶化することを特徴とする廃棄物処理方法。
- 廃棄物が飛灰である請求項1記載の廃棄物処理方法。
- アミン類の窒素に結合した活性水素のうちの50%を超える活性水素と置換して導入されたジチオ酸型官能基を有するジチオカルバミン酸型重金属固定化処理剤と、アミン類の窒素に結合した活性水素のうちの50%以下の活性水素と置換して導入されたN−置換基を有するアミン類誘導体とからなることを特徴とする重金属固定化処理剤組成物。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004158914A JP4632346B2 (ja) | 2004-05-28 | 2004-05-28 | 廃棄物処理方法および重金属固定化処理剤組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004158914A JP4632346B2 (ja) | 2004-05-28 | 2004-05-28 | 廃棄物処理方法および重金属固定化処理剤組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005334799A true JP2005334799A (ja) | 2005-12-08 |
JP4632346B2 JP4632346B2 (ja) | 2011-02-16 |
Family
ID=35488934
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004158914A Expired - Lifetime JP4632346B2 (ja) | 2004-05-28 | 2004-05-28 | 廃棄物処理方法および重金属固定化処理剤組成物 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4632346B2 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010095605A (ja) * | 2008-10-16 | 2010-04-30 | Tosoh Corp | 高純度ピペラジン−n−カルボジチオ酸塩の製造法並びにその用途 |
JP2014088477A (ja) * | 2012-10-29 | 2014-05-15 | Tosoh Corp | 重金属処理剤及び重金属汚染物質の処理方法 |
CN109650835A (zh) * | 2018-12-26 | 2019-04-19 | 国电新能源技术研究院有限公司 | 一种高盐废水处理方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104001299B (zh) * | 2013-02-22 | 2019-06-14 | 栗田工業株式会社 | 防止重金属从粉尘溶出的稳定化处理方法 |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03231921A (ja) * | 1989-12-20 | 1991-10-15 | Miyoshi Oil & Fat Co Ltd | 金属捕集剤及び金属捕集方法 |
JPH0841017A (ja) * | 1994-07-29 | 1996-02-13 | Unitika Ltd | 低温安定性を有するジチオカルバミン酸塩水溶液およびその製造方法 |
JPH091110A (ja) * | 1995-04-17 | 1997-01-07 | Nippon Soda Co Ltd | 重金属固定剤の安定化方法 |
JPH09183763A (ja) * | 1995-12-28 | 1997-07-15 | Nippon Soda Co Ltd | ジチオカルバミン酸金属塩水溶液およびその製法 |
JPH09234450A (ja) * | 1995-12-27 | 1997-09-09 | Tosoh Corp | 飛灰中の重金属を固定化する方法 |
JP3391173B2 (ja) * | 1994-12-02 | 2003-03-31 | 東ソー株式会社 | 飛灰中の重金属の固定化方法及び重金属固定化処理剤 |
JP2003105317A (ja) * | 2001-09-28 | 2003-04-09 | Nippon Soda Co Ltd | 重金属固定剤、その製造方法及び焼却灰等の処理方法 |
JP2003105318A (ja) * | 2001-09-28 | 2003-04-09 | Nippon Soda Co Ltd | 重金属固定剤及び重金属固定剤の低温安定化方法 |
JP2003261530A (ja) * | 2002-03-06 | 2003-09-19 | Nippon Soda Co Ltd | ジチオカルバミン酸塩を含有する水溶液の製造方法 |
JP2004115639A (ja) * | 2002-09-26 | 2004-04-15 | Nippon Soda Co Ltd | 重金属固定剤及び重金属固定剤の低温安定化方法 |
JP2004352964A (ja) * | 2003-05-30 | 2004-12-16 | Kurita Water Ind Ltd | 重金属固定化剤および重金属含有物の処理方法 |
JP2005047966A (ja) * | 2003-07-30 | 2005-02-24 | Kurita Water Ind Ltd | 重金属固定化剤および重金属含有物の処理方法 |
JP2005336378A (ja) * | 2004-05-28 | 2005-12-08 | Miyoshi Oil & Fat Co Ltd | 重金属固定化処理剤組成物 |
-
2004
- 2004-05-28 JP JP2004158914A patent/JP4632346B2/ja not_active Expired - Lifetime
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03231921A (ja) * | 1989-12-20 | 1991-10-15 | Miyoshi Oil & Fat Co Ltd | 金属捕集剤及び金属捕集方法 |
JPH0841017A (ja) * | 1994-07-29 | 1996-02-13 | Unitika Ltd | 低温安定性を有するジチオカルバミン酸塩水溶液およびその製造方法 |
JP3391173B2 (ja) * | 1994-12-02 | 2003-03-31 | 東ソー株式会社 | 飛灰中の重金属の固定化方法及び重金属固定化処理剤 |
JPH091110A (ja) * | 1995-04-17 | 1997-01-07 | Nippon Soda Co Ltd | 重金属固定剤の安定化方法 |
JPH09234450A (ja) * | 1995-12-27 | 1997-09-09 | Tosoh Corp | 飛灰中の重金属を固定化する方法 |
JPH09183763A (ja) * | 1995-12-28 | 1997-07-15 | Nippon Soda Co Ltd | ジチオカルバミン酸金属塩水溶液およびその製法 |
JP2003105317A (ja) * | 2001-09-28 | 2003-04-09 | Nippon Soda Co Ltd | 重金属固定剤、その製造方法及び焼却灰等の処理方法 |
JP2003105318A (ja) * | 2001-09-28 | 2003-04-09 | Nippon Soda Co Ltd | 重金属固定剤及び重金属固定剤の低温安定化方法 |
JP2003261530A (ja) * | 2002-03-06 | 2003-09-19 | Nippon Soda Co Ltd | ジチオカルバミン酸塩を含有する水溶液の製造方法 |
JP2004115639A (ja) * | 2002-09-26 | 2004-04-15 | Nippon Soda Co Ltd | 重金属固定剤及び重金属固定剤の低温安定化方法 |
JP2004352964A (ja) * | 2003-05-30 | 2004-12-16 | Kurita Water Ind Ltd | 重金属固定化剤および重金属含有物の処理方法 |
JP2005047966A (ja) * | 2003-07-30 | 2005-02-24 | Kurita Water Ind Ltd | 重金属固定化剤および重金属含有物の処理方法 |
JP2005336378A (ja) * | 2004-05-28 | 2005-12-08 | Miyoshi Oil & Fat Co Ltd | 重金属固定化処理剤組成物 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010095605A (ja) * | 2008-10-16 | 2010-04-30 | Tosoh Corp | 高純度ピペラジン−n−カルボジチオ酸塩の製造法並びにその用途 |
JP2014088477A (ja) * | 2012-10-29 | 2014-05-15 | Tosoh Corp | 重金属処理剤及び重金属汚染物質の処理方法 |
CN109650835A (zh) * | 2018-12-26 | 2019-04-19 | 国电新能源技术研究院有限公司 | 一种高盐废水处理方法 |
Also Published As
Publication number | Publication date |
---|---|
JP4632346B2 (ja) | 2011-02-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4000610B2 (ja) | 飛灰中の重金属を固定化する方法及び重金属固定化剤 | |
JP5504571B2 (ja) | 重金属処理剤および重金属汚染物質の処理方法 | |
JP4632346B2 (ja) | 廃棄物処理方法および重金属固定化処理剤組成物 | |
JP4968765B2 (ja) | 金属固定化剤 | |
JP4567650B2 (ja) | 酸性廃棄物処理剤 | |
JP2004314058A (ja) | 廃棄物処理方法 | |
JP2006095356A (ja) | 固体状廃棄物中のセレンの固定化方法 | |
JP2003181470A (ja) | 廃棄物の処理方法 | |
JP2005336378A (ja) | 重金属固定化処理剤組成物 | |
JP5160759B2 (ja) | 重金属類溶出抑制剤 | |
JPH0199679A (ja) | 土壌又は固体状廃棄物中の重金属類の固定化方法 | |
JP7046770B2 (ja) | 水銀を含むカーボン含有飛灰の処理方法 | |
JP4394915B2 (ja) | 重金属固定化処理剤及び固体状物質中の重金属固定化方法 | |
JP2005089564A (ja) | 重金属固定化処理剤及び固体状物質中の重金属固定化方法 | |
JPH091110A (ja) | 重金属固定剤の安定化方法 | |
JP4084072B2 (ja) | セメント添加剤、セメント組成物及び廃棄物処理方法 | |
JP2004008952A (ja) | 廃棄物処理剤及び廃棄物処理方法 | |
JP2006223569A (ja) | 重金属固定化剤及び重金属固定化方法 | |
JPH11116938A (ja) | 金属捕集剤組成物 | |
JP2005230604A (ja) | 排煙の処理方法 | |
JP4901622B2 (ja) | ボイラー灰処理剤 | |
JP2007209829A (ja) | 固体状廃棄物処理方法 | |
JP2003117521A (ja) | 焼却飛灰の処理方法 | |
JP5493788B2 (ja) | 重金属処理剤及び重金属汚染物質の処理方法 | |
JP2001247848A (ja) | 金属捕集剤 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070405 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20080926 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100310 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100421 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20101110 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20101112 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4632346 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20131126 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |