JP2005325187A - Cleanser composition - Google Patents
Cleanser composition Download PDFInfo
- Publication number
- JP2005325187A JP2005325187A JP2004143112A JP2004143112A JP2005325187A JP 2005325187 A JP2005325187 A JP 2005325187A JP 2004143112 A JP2004143112 A JP 2004143112A JP 2004143112 A JP2004143112 A JP 2004143112A JP 2005325187 A JP2005325187 A JP 2005325187A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- fatty acid
- salt
- general formula
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 150000003839 salts Chemical class 0.000 claims abstract description 64
- 239000002253 acid Substances 0.000 claims abstract description 46
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- -1 oxyethylene oxypropylene Chemical group 0.000 claims description 141
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 83
- 239000000194 fatty acid Substances 0.000 claims description 83
- 229930195729 fatty acid Natural products 0.000 claims description 83
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 55
- 150000004665 fatty acids Chemical class 0.000 claims description 44
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 40
- 238000004140 cleaning Methods 0.000 claims description 32
- 235000003704 aspartic acid Nutrition 0.000 claims description 19
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims description 19
- 239000002202 Polyethylene glycol Substances 0.000 claims description 12
- 229920001223 polyethylene glycol Polymers 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 10
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 9
- 239000000600 sorbitol Substances 0.000 claims description 9
- 239000004359 castor oil Substances 0.000 claims description 8
- 235000019438 castor oil Nutrition 0.000 claims description 8
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 8
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 7
- 150000005215 alkyl ethers Chemical class 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- 239000003599 detergent Substances 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 150000003973 alkyl amines Chemical class 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- 150000008378 aryl ethers Chemical class 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 11
- 210000002374 sebum Anatomy 0.000 abstract description 4
- 235000002639 sodium chloride Nutrition 0.000 description 67
- 239000003240 coconut oil Substances 0.000 description 24
- 239000011734 sodium Substances 0.000 description 24
- 229920001296 polysiloxane Polymers 0.000 description 23
- 229910052708 sodium Inorganic materials 0.000 description 23
- 235000019864 coconut oil Nutrition 0.000 description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 19
- 238000005187 foaming Methods 0.000 description 16
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 15
- 125000000217 alkyl group Chemical class 0.000 description 13
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 12
- 239000004166 Lanolin Substances 0.000 description 10
- 235000019388 lanolin Nutrition 0.000 description 10
- 229940039717 lanolin Drugs 0.000 description 10
- 239000003921 oil Substances 0.000 description 10
- 235000019198 oils Nutrition 0.000 description 10
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 9
- 229940060184 oil ingredients Drugs 0.000 description 9
- 235000010356 sorbitol Nutrition 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 125000002252 acyl group Chemical group 0.000 description 7
- 229960003237 betaine Drugs 0.000 description 7
- 239000000284 extract Substances 0.000 description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 6
- 235000001014 amino acid Nutrition 0.000 description 6
- 229940024606 amino acid Drugs 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 6
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 229920001451 polypropylene glycol Polymers 0.000 description 6
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 5
- 235000010323 ascorbic acid Nutrition 0.000 description 5
- 239000011668 ascorbic acid Substances 0.000 description 5
- 229960005070 ascorbic acid Drugs 0.000 description 5
- NZUPCNDJBJXXRF-UHFFFAOYSA-O bethanechol Chemical compound C[N+](C)(C)CC(C)OC(N)=O NZUPCNDJBJXXRF-UHFFFAOYSA-O 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 4
- 102000008186 Collagen Human genes 0.000 description 4
- 108010035532 Collagen Proteins 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 4
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 4
- CUFNKYGDVFVPHO-UHFFFAOYSA-N azulene Chemical compound C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- KVYGGMBOZFWZBQ-UHFFFAOYSA-N benzyl nicotinate Chemical compound C=1C=CN=CC=1C(=O)OCC1=CC=CC=C1 KVYGGMBOZFWZBQ-UHFFFAOYSA-N 0.000 description 4
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 4
- 229920001436 collagen Polymers 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 4
- 239000002540 palm oil Substances 0.000 description 4
- 210000002826 placenta Anatomy 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 4
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 3
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 3
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 244000280244 Luffa acutangula Species 0.000 description 3
- 235000009814 Luffa aegyptiaca Nutrition 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 3
- 229960000458 allantoin Drugs 0.000 description 3
- 150000001413 amino acids Chemical group 0.000 description 3
- 229940009098 aspartate Drugs 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 3
- 229930195712 glutamate Natural products 0.000 description 3
- 229940075507 glyceryl monostearate Drugs 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 239000003346 palm kernel oil Substances 0.000 description 3
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- 229920001282 polysaccharide Polymers 0.000 description 3
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- 150000004804 polysaccharides Chemical class 0.000 description 3
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- 239000008213 purified water Substances 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 229930182490 saponin Natural products 0.000 description 3
- 235000017709 saponins Nutrition 0.000 description 3
- 150000007949 saponins Chemical class 0.000 description 3
- 239000001488 sodium phosphate Substances 0.000 description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 description 3
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- 229930003799 tocopherol Natural products 0.000 description 3
- 239000011732 tocopherol Substances 0.000 description 3
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 2
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- IZHVBANLECCAGF-UHFFFAOYSA-N 2-hydroxy-3-(octadecanoyloxy)propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCCCCCCCCCCC IZHVBANLECCAGF-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
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- 241000283690 Bos taurus Species 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
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- 239000004471 Glycine Substances 0.000 description 2
- MPDGHEJMBKOTSU-UHFFFAOYSA-N Glycyrrhetinsaeure Natural products C12C(=O)C=C3C4CC(C)(C(O)=O)CCC4(C)CCC3(C)C1(C)CCC1C2(C)CCC(O)C1(C)C MPDGHEJMBKOTSU-UHFFFAOYSA-N 0.000 description 2
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- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 2
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- 125000005210 alkyl ammonium group Chemical group 0.000 description 2
- 235000011399 aloe vera Nutrition 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
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- 125000000637 arginyl group Chemical class N[C@@H](CCCNC(N)=N)C(=O)* 0.000 description 2
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- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
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- 229920002678 cellulose Polymers 0.000 description 2
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- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000012000 cholesterol Nutrition 0.000 description 2
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- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 description 1
- HVLUSYMLLVVXGI-USGGBSEESA-M trimethyl-[(z)-octadec-9-enyl]azanium;chloride Chemical compound [Cl-].CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)C HVLUSYMLLVVXGI-USGGBSEESA-M 0.000 description 1
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- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
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- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
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- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
本発明は洗浄剤組成物、とりわけ人体に使用する洗浄剤組成物に関する。 The present invention relates to a cleaning composition, particularly a cleaning composition for use on the human body.
従来、洗浄剤組成物には、アルキル硫酸塩、アルキルエーテル硫酸塩、高級脂肪酸塩等が使用されてきた。しかし、人体に対する刺激性の問題から、これ等に代えて、皮膚への刺激が少なく優れた洗浄力を有するN−アシルアミノ酸系界面活性剤が使用されるようになってきた。N−アシルアミノ酸系界面活性剤は皮膚刺激性の点で優れる一方、皮脂汚れに対する洗浄力、起泡力、あるいは洗浄時および洗い上がりの使用感などの点で改善が必要であった。これ等の改善を目的に数多くの提案がなされてきた。例えば特許文献1、特許文献2ではポリオキシエチレンアルキルエーテル系非イオン界面活性剤との併用が、特許文献3ではポリグリセリン脂肪酸エステル系非イオン界面活性剤との併用が、特許文献4、特許文献5では糖誘導体系非イオン界面活性剤との併用が、特許文献6、特許文献7、特許文献8にはアルカノールアミド系非イオン界面活性剤との併用が、特許文献9、特許文献10にはアミンオキシド系非イオン界面活性剤との併用が提案され、これ等の提案によりかなりの改善がなされてきた。しかし、とりわけ人体用として、起泡力、皮脂汚れ洗浄力、さっぱり感、つっぱり感をバランスよく改善する点で充分ではなく、一層の改善が望まれている。 Conventionally, alkyl sulfates, alkyl ether sulfates, higher fatty acid salts, and the like have been used in detergent compositions. However, due to the problem of irritation to the human body, instead of these, N-acylamino acid-based surfactants with less skin irritation and excellent detergency have come to be used. N-acylamino acid surfactants are excellent in terms of skin irritation, but need to be improved in terms of detergency against sebum soil, foaming power, or feeling during use and after washing. Many proposals have been made for the purpose of these improvements. For example, in Patent Document 1 and Patent Document 2, combined use with a polyoxyethylene alkyl ether-based nonionic surfactant is used, and in Patent Document 3, combined use with a polyglycerin fatty acid ester-based nonionic surfactant is described in Patent Document 4 and Patent Document. 5 is used together with a sugar derivative-based nonionic surfactant, Patent Document 6, Patent Document 7 and Patent Document 8 are used together with an alkanolamide-based nonionic surfactant, and Patent Document 9 and Patent Document 10 include Combinations with amine oxide nonionic surfactants have been proposed, and these proposals have improved considerably. However, especially for the human body, it is not sufficient in improving the foaming power, sebum dirt cleaning power, freshness, and freshness in a balanced manner, and further improvement is desired.
本発明は、泡立ち性、皮脂汚れ洗浄性に優れ、且つさっぱりした感触が得られ、洗浄後の肌のつっぱり感が少ない使用感に優れた洗浄剤組成物を提供することを目的とする。 An object of the present invention is to provide a cleaning composition that is excellent in foaming property and sebum dirt cleaning property, has a refreshing feel, and has a feeling of use that has less skin feeling after cleaning.
本発明者等は、上記目的を達成すべく鋭意研究を重ねた結果、特定のN−アシルアミノ酸系界面活性剤と非イオン系界面活性剤を併用することにより上記目的が達成されることを見いだし、本発明を完成させた。
すなわち、本発明は下記の通りである。
As a result of intensive studies to achieve the above object, the present inventors have found that the above object is achieved by using a specific N-acylamino acid surfactant and a nonionic surfactant in combination. The present invention has been completed.
That is, the present invention is as follows.
1.成分(A)及び(B)を含有することを特徴とする洗浄剤組成物。
成分(A):一般式(1)で表されるN−アシルアスパラギン酸またはその塩を主成分とするN−アシルアスパラギン酸系界面活性剤
Component (A): N-acyl aspartic acid-based surfactant mainly composed of N-acyl aspartic acid represented by the general formula (1) or a salt thereof
2.さらに、小割合成分として次の一般式(2)または(3)で表されるN−アシル−ジアスパラギン酸またはその塩を含有することを特徴とする1.記載の洗浄剤組成物。
3.さらに、小割合成分として一般式(2)で表されるN−アシル−ジアスパラギン酸またはその塩と一般式(3)で表されるN−アシル−ジアスパラギン酸またはその塩との両者を含有することを特徴とする1.に記載の洗浄剤組成物。
4.一般式(2)および/または(3)におけるR2が一般式(1)におけるR1と等しいことを特徴とする2.または3.に記載の洗浄剤組成物。
3. Furthermore, N-acyl-diaspartic acid represented by the general formula (2) or a salt thereof and N-acyl-diaspartic acid represented by the general formula (3) or a salt thereof are contained as a minor component. It is characterized by the following. The cleaning composition described in 1.
4). 1. R2 in the general formula (2) and / or (3) is equal to R1 in the general formula (1) Or 3. The cleaning composition described in 1.
5.さらに、成分(C)を含有することを特徴とする1.〜4.のいずれかに記載の洗浄剤組成物。
成分(C):一般式(4)で表される高級脂肪酸またはその塩
Component (C): a higher fatty acid represented by the general formula (4) or a salt thereof
6.一般式(4)におけるR3が一般式(1)におけるR1と等しいことを特徴とする5.記載の洗浄剤組成物。
7.成分(B)の非イオン系界面活性剤が、ポリオキシアルキレンアルキルエーテル、ポリオキシエチレンポリオキシプロピレンアルキルエーテル、オキシエチレンオキシプロピレンポリマー、ポリオキシエチレンアリールエーテル、ポリオキシエチレンひまし油または硬化ひまし油エーテル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンソルビトール脂肪酸エステル、ポリエチレングリコール脂肪酸エステル、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、エチレングリコール脂肪酸エステル、プロピレングリコール脂肪酸エステル、ペンタエリスリトール脂肪酸エステル、糖誘導体、アルキルグリセリルエーテル、有機酸モノグリセリド、脂肪酸アルカノールアミド、POEアルキルアミンおよびアミンオキサイドから選ばれる1種または2種以上であることを特徴とする1.〜6.のいずれかに記載の洗浄剤組成物。
6). 4. R3 in the general formula (4) is equal to R1 in the general formula (1) The cleaning composition as described.
7). The nonionic surfactant of component (B) is polyoxyalkylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, oxyethylene oxypropylene polymer, polyoxyethylene aryl ether, polyoxyethylene castor oil or hardened castor oil ether, Oxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyethylene glycol fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, ethylene glycol fatty acid ester, propylene glycol fatty acid ester, pentaerythritol Fatty acid ester, sugar derivative, alkyl glyceryl ether, organic acid 1 glycerides, fatty acid alkanolamides, and characterized in that one or more selected from POE alkylamines and amine oxide. ~ 6. The cleaning composition according to any one of the above.
なお、本発明に言う小割合成分とは、本発明の主たる成分であるN−アシルアスパラギン酸塩よりも含有質量が少ない成分を指す。 In addition, the small ratio component said to this invention points out a component with less content mass than N-acyl aspartate which is the main component of this invention.
本発明の洗浄剤組成物は、泡立ち、洗浄力に優れ、且つさっぱりした感触が得られ、洗浄後の肌のつっぱり感がない使用感に優れた効果を有する。 The cleaning composition of the present invention has an excellent effect on the feeling of foaming, excellent cleaning power, a refreshing feel, and no feeling of firmness of the skin after cleaning.
本発明について、以下具体的に説明する。
本発明の洗浄剤組成物は、主成分として前記一般式(1)で表される成分(A)のN−アシルアスパラギン酸またはその塩を含むN−アシルアスパラギン酸系界面活性剤を含有し、好ましくは、さらに、小割合成分として一般式(2)または(3)で表されるN−アシル−ジアスパラギン酸またはその塩を含有する。更に好ましくは小割合成分が一般式(2)で表されるN−アシル−ジアスパラギン酸またはその塩と一般式(3)で表されるN−アシル−ジアスパラギン酸またはその塩の両者を含有するものである。
一般式(2)あるいは(3)におけるR2が一般式(1)におけるR1と等しいN−アシル−ジアスパラギン酸またはその塩を用いることが本発明の効果、即ち泡立ち、洗浄力に優れ、且つさっぱりした感触が得られ、洗浄後の肌のつっぱり感がないことを最大にする事が出来るのでより好ましい。そのアミノ酸部分の光学活性に関しては、L体、D体、DL体のいずれでも良い。
The present invention will be specifically described below.
The cleaning composition of the present invention contains an N-acyl aspartic acid-based surfactant containing N-acyl aspartic acid of the component (A) represented by the general formula (1) or a salt thereof as a main component, Preferably, N-acyl-diaspartic acid represented by the general formula (2) or (3) or a salt thereof is further contained as a minor component. More preferably, the minor component contains both N-acyl-diaspartic acid represented by the general formula (2) or a salt thereof and N-acyl-diaspartic acid represented by the general formula (3) or a salt thereof. To do.
Use of N-acyl-diaspartic acid or a salt thereof in which R2 in the general formula (2) or (3) is equal to R1 in the general formula (1) is excellent in the effects of the present invention, that is, foaming and detergency, and refreshing. It is more preferable because it is possible to maximize the feeling that the skin feels smooth after washing. Regarding the optical activity of the amino acid moiety, any of L-form, D-form, and DL-form may be used.
ここに、成分(A)にしめるN−アシルアスパラギン酸またはその塩の割合は、85〜100質量%、望ましくは90〜99.9質量%であり、残部はアスパラギン酸オリゴマーのN−アシル化物およびその塩である。一般式(1)で表されるN−アシルアスパラギン酸またはその塩、あるいは一般式(2)または(3)で表されるN−アシル−ジアスパラギン酸またはその塩としては、例えば、N−オクタノイルアスパラギン酸、N−デカノイルアスパラギン酸、N−ラウロイルアスパラギン酸、N−ミリストイルアスパラギン酸、N−パルミトイルアスパラギン酸、N−ステアロイルアスパラギン酸、N−イソステアロイルアスパラギン酸、N−オレオイルアスパラギン酸、N−リノレオイルアスパラギン酸、N−やし油脂肪酸アシルアスパラギン酸、N−パーム油脂肪酸アシルアスパラギン酸、N−パーム核油脂肪酸アシルアスパラギン酸等のN−アシル−アスパラギン酸の単一物あるいは混合物、これらアシル基のジアスパラギン酸の単一物あるいは混合物、そしてそれらの塩としてはナトリウム塩、カリウム塩、リチウム塩、マグネシウム塩、カルシウム塩等の金属塩;アンモニウム塩、アルキルアンモニウム塩等のアンモニウム塩;モノエタノールアミン塩、ジエタノールアミン塩、トリエタノールアミン塩、アミノメチルプロパノール塩等のアミン塩;リジン塩、アルギニン塩等の塩基性アミノ酸塩、コリン塩等の単一物あるいは混合物が挙げられる。 Here, the proportion of N-acyl aspartic acid or a salt thereof included in component (A) is 85 to 100% by mass, preferably 90 to 99.9% by mass, and the balance is an N-acylated product of an aspartic acid oligomer and its Salt. Examples of the N-acyl aspartic acid represented by the general formula (1) or a salt thereof, or the N-acyl-diaspartic acid represented by the general formula (2) or (3) include N-octa Noyl aspartic acid, N-decanoyl aspartic acid, N-lauroyl aspartic acid, N-myristoyl aspartic acid, N-palmitoyl aspartic acid, N-stearoyl aspartic acid, N-isostearoyl aspartic acid, N-oleoyl aspartic acid, N -Single or mixture of N-acyl-aspartic acid such as linoleoyl aspartic acid, N-palm oil fatty acid acylaspartic acid, N-palm oil fatty acid acylaspartic acid, N-palm kernel oil fatty acid acylaspartic acid, A single diacpartic acid of these acyl groups or Compounds and their salts include metal salts such as sodium salt, potassium salt, lithium salt, magnesium salt and calcium salt; ammonium salts such as ammonium salt and alkylammonium salt; monoethanolamine salt, diethanolamine salt and triethanolamine Examples thereof include single salts or mixtures of amine salts such as salts and aminomethylpropanol salts; basic amino acid salts such as lysine salts and arginine salts; and choline salts.
更にN−アシル−アスパラギン酸塩は塩基成分の当量を適宜調節して得られる部分的な塩であってもよく、また複数の塩基成分の組み合わせであってもよい。これらN−アシルアスパラギン酸とN−アシルアスパラギン酸塩はそれぞれ単独で用いてもまた両者を混合して用いてもよい。塩の配合に代えて、N−アシルアスパラギン酸と塩基をそれぞれに配合して配合処方の中で塩を形成することもできる。 Furthermore, the N-acyl-aspartate may be a partial salt obtained by appropriately adjusting the equivalent amount of the base component, or may be a combination of a plurality of base components. These N-acyl aspartic acid and N-acyl aspartate may be used alone or in combination. Instead of blending the salt, N-acylaspartic acid and a base can be blended with each other to form a salt in the blended recipe.
本発明の洗浄剤組成物の成分(B)である非イオン系界面活性剤としては、例えば、
POE(ポリオキシエチレン)オクチルエーテル、POEラウリルエーテル、POEミリスチルエーテル、POEセチルエーテル、POEステアリルエーテル、POEオレイルエーテル、POEイソステアリルエーテル、POEベヘニルエーテル、POEオクチル(2−エチル−ヘキシル)エーテル等のポリオキシエチレンアルキルエーテル;POE・POP(ポリオキシプロピレン)ブチルエーテル、POE・POPラウリルエーテル、POE・POPセチルエーテル等のポリオキシエチレンオキシプロピレンアルキルエーテル;
As a nonionic surfactant which is a component (B) of the cleaning composition of the present invention, for example,
POE (polyoxyethylene) octyl ether, POE lauryl ether, POE myristyl ether, POE cetyl ether, POE stearyl ether, POE oleyl ether, POE isostearyl ether, POE behenyl ether, POE octyl (2-ethyl-hexyl) ether, etc. Polyoxyethylene alkyl ether; polyoxyethyleneoxypropylene alkyl ether such as POE / POP (polyoxypropylene) butyl ether, POE / POP lauryl ether, POE / POP cetyl ether;
POE・POPグリコール(POE・POPブロックポリマー)、オキシエチレンオキシプロピレンランダムポリマー等のオキシエチレンオキシプロピレンポリマー;POEオクチルフェニルエーテル、POEノニルフェニルエーテル、POEクロロフェニルエーテル、ポリオキシエチレンナフトールエーテル等のポリオキシエチレンアリールエーテル;POE硬化ひまし油エーテル、POEひまし油エーテル;その他POEラノリンアルコールエーテル、POEフィトステロール等のエーテル系;モノステアリン酸POEグリセリル、オレイン酸POEグリセリル等のポリオキシエチレングリセリン脂肪酸エステル; Oxyethyleneoxypropylene polymers such as POE / POP glycol (POE / POP block polymer) and oxyethyleneoxypropylene random polymers; polyoxyethylene such as POE octylphenyl ether, POE nonylphenyl ether, POE chlorophenyl ether, polyoxyethylene naphthol ether Aryl ether; POE hydrogenated castor oil ether, POE castor oil ether; Other ether systems such as POE lanolin alcohol ether and POE phytosterol; Polyoxyethylene glycerin fatty acid esters such as POE glyceryl monostearate and POE glyceryl oleate;
モノラウリン酸POEソルビタン、モノステアリン酸POEソルビタン、トリステアリン酸POEソルビタン、モノイソステアリン酸POEソルビタン等のポリオキシエチレンソルビタン脂肪酸エステル;ヘキサステアリン酸POEソルビトール、テトラステアリン酸POEソルビトール、テトラオレイン酸POEソルビトール、モノラウリン酸POEソルビトール等のポリオキシエチレンソルビトール脂肪酸エステル;ポリエチレングリコールモノラウリン酸、ポリエチレングリコールモノステアリン酸、ポリエチレングリコールモノオレイン酸、ポリエチレングリコールジステアリン酸、ポリエチレングリコールジオレイン酸、ポリエチレングリコールジイソステアリン酸等のポリエチレングリコール脂肪酸エステル;その他ポリエチレングリコールラノリン脂肪酸エステル等のエーテルエステル系;モノステアリン酸グリセリル、自己乳化型モノステアリン酸グリセリル、モノヒドロキシステアリン酸グリセリル、ジステアリン酸グリセリル等のグリセリン脂肪酸エステル;モノステアリン酸ジグリセリル、モノオレイン酸ジグリセリル、ジオレイン酸ジグリセリル、モノイソステアリン酸ジグリセリル、モノステアリン酸テトラグリセリル、トリステアリン酸テトラグリセリル、ペンタステアリン酸テトラグリセリル、モノラウリン酸ヘキサグリセリル、モノミリスチン酸ヘキサグリセリル、ジステアリン酸デカグリセリル、ジイソステアリン酸デカグリセリル等のポリグリセリン脂肪酸エステル; Polyoxyethylene sorbitan fatty acid esters such as monolauric acid POE sorbitan, monostearic acid POE sorbitan, tristearic acid POE sorbitan, monoisostearic acid POE sorbitan; hexastearic acid POE sorbitol, tetrastearic acid POE sorbitol, tetraoleic acid POE sorbitol, monolaurin Polyoxyethylene sorbitol fatty acid esters such as acid POE sorbitol; polyethylene glycol fatty acid esters such as polyethylene glycol monolauric acid, polyethylene glycol monostearic acid, polyethylene glycol monooleic acid, polyethylene glycol distearic acid, polyethylene glycol dioleic acid, polyethylene glycol diisostearic acid ; Other polyethylene Glycerol fatty acid esters such as glyceryl monostearate, self-emulsifying glyceryl monostearate, glyceryl monohydroxystearate, glyceryl distearate; diglyceryl monostearate, diglyceryl monooleate, Diglyceryl dioleate, diglyceryl monoisostearate, tetraglyceryl monostearate, tetraglyceryl tristearate, tetraglyceryl pentastearate, hexaglyceryl monolaurate, hexaglyceryl monomyristate, decaglyceryl distearate, decaglyceryl diisostearate Of polyglycerol fatty acid esters;
モノラウリン酸ソルビタン、モノステアリン酸ソルビタン、モノオレイン酸ソルビタン、トリオレイン酸ソルビタン、トリステアリン酸ソルビタン、モノイソステアリン酸ソルビタン等のソルビタン脂肪酸エステル;モノラウリン酸エチレングリコール等のエチレングリコール脂肪酸エステル;モノステアリン酸プロピレングリコール、自己乳化型モノステアリン酸プロピレングリコール等のプロピレングリコール脂肪酸エステル;モノステアリン酸ペンタエリスリトール、モノオレイン酸ペンタエリスリトール等のペンタエリスリトール脂肪酸エステル;マルチトールヒドロキシ脂肪酸エーテル、アルキル化多糖、アルキル(ポリ)グルコシド、シュガーエステル等の糖誘導体;α−モノイソステアリルグリセリルエーテル等のアルキルグリセリルエーテル;アセチル−モノグリ、乳酸モノグリセリド、クエン酸モノグリセリド等の有機酸モノグリセリド;ヤシ油脂肪酸モノエタノールアミド、ラウロイルモノエタノールアミド、ミリストイルモノエタノールアミド、ラウロイルジエタノールアミド、ヤシ油脂肪酸ジエタノールアミド、ラウロイルイソプロパノールアミド、ミリストイルイソプロパノールアミド、ヤシ油脂肪酸イソプロパノールアミド、POEラウロイルモノエタノールアミド等の脂肪酸アルカノールアミド;POEラウリルアミン、POEステアリルアミン等のPOEアルキルアミン; Sorbitan fatty acid esters such as sorbitan monolaurate, sorbitan monostearate, sorbitan monooleate, sorbitan trioleate, sorbitan tristearate, sorbitan monoisostearate; ethylene glycol fatty acid esters such as ethylene glycol monolaurate; propylene glycol monostearate Propylene glycol fatty acid esters such as self-emulsifying propylene glycol monostearate; pentaerythritol fatty acid esters such as pentaerythritol monostearate and pentaerythritol monooleate; maltitol hydroxy fatty acid ethers, alkylated polysaccharides, alkyl (poly) glucosides, Sugar derivatives such as sugar esters; alkyl groups such as α-monoisostearyl glyceryl ether Seryl ether; organic acid monoglycerides such as acetyl-monoglycol, lactic acid monoglyceride, citric acid monoglyceride; coconut oil fatty acid monoethanolamide, lauroyl monoethanolamide, myristoyl monoethanolamide, lauroyl diethanolamide, coconut oil fatty acid diethanolamide, lauroyl isopropanolamide, Fatty acid alkanolamides such as myristoyl isopropanolamide, coconut oil fatty acid isopropanolamide, POE lauroyl monoethanolamide; POE alkylamines such as POE laurylamine, POE stearylamine;
ラウリルジメチルアミンオキサイド、ココジメチルアミンオキサイド、ココアミドプロピルジメチルアミンオキサイド等のアミンオキサイド等およびこれらの混合物が挙げられる。成分(B)の成分(A)に対する割合には、特に制限はなく、製品の形態や用途に応じ適宜に選ぶことができるが、一般に0.01〜20質量%の範囲で用いられる。 Examples thereof include amine oxides such as lauryldimethylamine oxide, cocodimethylamine oxide, cocoamidopropyldimethylamine oxide, and mixtures thereof. There is no restriction | limiting in particular in the ratio with respect to the component (A) of a component (B), Although it can select suitably according to the form and use of a product, Generally it is used in 0.01-20 mass%.
本発明の洗浄剤組成物に、さらに成分(C)として、一般式(4)で表される高級脂肪酸またはその塩を配合することによりさらに効果を高めることができる。なかでも、高級脂肪酸のアルキル基が、N−アシルアスパラギン酸のアシル基のアルキル部分と等しい時に本発明の効果は最大となる。高級脂肪酸の種類については特に限定するものではなく、飽和、不飽和の何れであっても良いし、直鎖状、分岐状の何れであっても良いし、水酸基、芳香族基等の置換基を有していても良い。 高級脂肪酸またはその塩の具体例としては、例えば、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、アラキジン酸、ベヘン酸、ウンデシレン酸、パルミトレイン酸、オレイン酸、リノール酸、リノレン酸、ヒドロキシステアリン酸、リシノール酸、ラノリン脂肪酸、ヤシ油脂肪酸、ひまし油脂肪酸、オリーブ油脂肪酸、パーム油脂肪酸、パーム核油脂肪酸等の高級脂肪酸の単一物あるいは混合物、そしてそれらの塩としてはナトリウム塩、カリウム塩、リチウム塩、マグネシウム塩、カルシウム塩等の金属塩;アンモニウム塩、アルキルアンモニウム塩等のアンモニウム塩;モノエタノールアミン塩、ジエタノールアミン塩、トリエタノールアミン塩、アミノメチルプロパノール塩等のアミン塩;リジン塩、アルギニン塩等の塩基性アミノ酸塩、コリン塩等の単一物あるいは混合物が挙げられる。これら高級脂肪酸と高級脂肪酸塩はそれぞれ単独で用いてもまた両者を混合して用いてもよい。塩の配合に代えて、高級脂肪酸と塩基をそれぞれに配合して配合処方の中で塩を形成することもできる。 The effect can be further enhanced by blending the detergent composition of the present invention with a higher fatty acid represented by the general formula (4) or a salt thereof as the component (C). Among them, the effect of the present invention is maximized when the alkyl group of the higher fatty acid is equal to the alkyl part of the acyl group of N-acyl aspartic acid. The type of higher fatty acid is not particularly limited, and may be saturated or unsaturated, linear or branched, and may be a substituent such as a hydroxyl group or an aromatic group. You may have. Specific examples of higher fatty acids or salts thereof include, for example, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, arachidic acid, behenic acid, undecylenic acid, palmitoleic acid, oleic acid, linol Single or mixture of higher fatty acids such as acid, linolenic acid, hydroxystearic acid, ricinoleic acid, lanolin fatty acid, coconut fatty acid, castor oil fatty acid, olive oil fatty acid, palm oil fatty acid, palm kernel oil fatty acid, and salts thereof Metal salts such as sodium salt, potassium salt, lithium salt, magnesium salt and calcium salt; ammonium salts such as ammonium salt and alkylammonium salt; monoethanolamine salt, diethanolamine salt, triethanolamine salt, aminomethylpropanol salt Amine salts; lysine salt, basic amino acid salts such as arginine salt, a single product or a mixture of such choline salts. These higher fatty acids and higher fatty acid salts may be used alone or in combination. Instead of blending the salt, a higher fatty acid and a base can be blended with each other to form a salt in the blended recipe.
さらに、成分(C)の成分(A)と小割合成分の合計量に対する割合は特に限定されるものではないが、本発明の効果を最大に発揮するためには、成分(A)と小割合成分の合計量:成分(C)の比率は1:1000〜300:1の範囲である事が望ましく、中でも1:100〜100:1の範囲である場合に特に有効である。さらに望ましくは1:10〜10:1の範囲にある場合に最も効果が高い。 Furthermore, the ratio of the component (C) to the total amount of the component (A) and the small proportion component is not particularly limited, but in order to maximize the effect of the present invention, the proportion (A) and the small proportion are small. The ratio of the total amount of components to the component (C) is preferably in the range of 1: 1000 to 300: 1, and particularly effective in the range of 1: 100 to 100: 1. More desirably, it is most effective when it is in the range of 1:10 to 10: 1.
本発明の洗浄剤組成物には、その効果を損なわない範囲において、通常、洗浄剤あるいは化粧料として用いられる各種成分を、その目的に応じて適宜配合することができる。
これら任意成分としては、例えば、炭酸カルシウム、タルク、マイカ、カオリン、二酸化チタン、二酸化亜鉛等の粉末成分;ホホバ油、マカデミアナッツ油、アボガド油、月見草油、ミンク油、ナタネ油、ヒマシ油、ヒマワリ油、トーモロコシ油、カカオ油、ヤシ油、コメヌカ油、オリーブ油、アーモンド油、ごま油、サフラワー油、大豆油、椿油、パーシック油、ヒマシ油、ミンク油、綿実油、モクロウ、パーム油、パーム核油、卵黄油、ラノリン、スクワレン等の天然動植物油脂類;合成トリグリセライド;
In the cleaning composition of the present invention, various components that are usually used as cleaning agents or cosmetics can be appropriately blended depending on the purpose within a range that does not impair the effect.
These optional ingredients include, for example, powder components such as calcium carbonate, talc, mica, kaolin, titanium dioxide, zinc dioxide; jojoba oil, macadamia nut oil, avocado oil, evening primrose oil, mink oil, rapeseed oil, sunflower oil, sunflower oil , Corn oil, cacao oil, coconut oil, rice bran oil, olive oil, almond oil, sesame oil, safflower oil, soybean oil, coconut oil, persic oil, castor oil, mink oil, cottonseed oil, owl, palm oil, palm kernel oil, egg yolk Natural animal and vegetable oils and fats such as oil, lanolin and squalene; synthetic triglycerides;
スクワラン、流動パラフィン、ワセリン、セレシン、マイクロクリスタリンワックス、イソパラフィン等の炭化水素類;カルナバウロウ、パラフィンワックス、鯨ロウ、ミツロウ、キヤンデリラワックス、ラノリン等のワックス類;セタノール、ステアリルアルコール、ラウリルアルコール、セトステアリルアルコール、オレイルアルコール、ベヘニルアルコール、ラノリンアルコール、水添ラノリンアルコール、ヘキシルデカノール、オクチルドデカノール等の高級アルコール類;コレステリル−オクチルドデシル−ベヘニル等のコレステロールおよびその誘導体; Hydrocarbons such as squalane, liquid paraffin, petrolatum, ceresin, microcrystalline wax, isoparaffin; waxes such as carnauba wax, paraffin wax, whale wax, beeswax, candelilla wax, lanolin; cetanol, stearyl alcohol, lauryl alcohol, cetostearyl Higher alcohols such as alcohol, oleyl alcohol, behenyl alcohol, lanolin alcohol, hydrogenated lanolin alcohol, hexyl decanol, octyldodecanol; cholesterol and derivatives thereof such as cholesteryl-octyldodecyl-behenyl;
イソプロピルミリスチン酸、イソプロピルパルミチン酸、イソプロピルステアリン酸、2エチルヘキサン酸グリセロール、ブチルステアリン酸、リノール酸エチル等のエステル類;ジエチレングリコールモノプロピルエーテル、ポリオキシエチレンポリオキシプロピレンペンタエリトリトールエーテル、ポリオキシプロピレンブチルエーテル等の極性オイル;その他、メチルフェニルポリシロキサン、メチルポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、メチルシクロポリシロキサン、オクタメチルトリシロキサン、デカメチルテトラシロキサン、ポリオキシエチレン・メチルポリシロキサン共重合体、ポリオキシプロピレン・メチルポリシロキサン共重合体、ポリ(オキシエチレン・オキシプロピレン)メチルポリシロキサン共重合体、メチルハイドロジェンポリシロキサン、テトラヒドロテトラメチルシクロテトラシロキサン、ステアロキシメチルポリシロキサン、セトキシメチルポリシロキサン、メチルポリシロキサンエマルション、高重合メチルポリシロキサン、トリメチルシロキシケイ酸、架橋型メチルポリシロキサン、架橋型メチルフェニルポリシロキサン等、更にはアミノ変性シリコーン、エポキシ変性シリコーン、カルボキシル変性シリコーン、カルビノール変性シリコーン、メタクリル変性シリコーン、メルカプト変性シリコーン、フェノール変性シリコーン、片末端反応性シリコーン、異種官能基変性シリコーン、ポリエーテル変性シリコーン、メチルスチリル変性シリコーン、アルキル変性シリコーン、高級脂肪酸エステル変性シリコーン、親水性特殊変性シリコーン、高級アルコキシ変性シリコーン、高級脂肪酸含有シリコーン、フッ素変性シリコーン等の各種誘導体を含むシリコーン類;パラアミノ安息香酸およびその誘導体、ホモメチル−7N−アセチルアラントイラニレート、ブチルメトキシベンゾイルメタン、ジ−パラメトキシケイ皮酸−モノ−2−エチルヘキサン酸グリセリル、オクチルシンナメート等のパラメトキシケイ皮酸誘導体、アミルサリシレート等のサリチル酸誘導体、2,4−ジヒドロキシベンゾフェノン等のベンゾフェノン誘導体、ジメトキシベンジリデンジオキソイミダゾリンプロピオン酸エチルヘキシル、酢酸液状ラノリン、コガネバナ根抽出エキス、トリアニリノ−p−カルボエチルヘキシルオキシ−トリアジン等の紫外線吸収剤; Esters such as isopropyl myristic acid, isopropyl palmitic acid, isopropyl stearic acid, glycerol 2-ethylhexanoate, butyl stearic acid, ethyl linoleate; diethylene glycol monopropyl ether, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxypropylene butyl ether, etc. Other polar oils: methylphenyl polysiloxane, methyl polysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, methylcyclopolysiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, polyoxy Ethylene / methylpolysiloxane copolymer, polyoxypropylene / methylpolysiloxane copolymer Polymer, poly (oxyethylene / oxypropylene) methylpolysiloxane copolymer, methylhydrogenpolysiloxane, tetrahydrotetramethylcyclotetrasiloxane, stearoxymethylpolysiloxane, cetoxymethylpolysiloxane, methylpolysiloxane emulsion, highly polymerized methyl Polysiloxane, trimethylsiloxysilicic acid, cross-linked methylpolysiloxane, cross-linked methylphenyl polysiloxane, etc., amino-modified silicone, epoxy-modified silicone, carboxyl-modified silicone, carbinol-modified silicone, methacryl-modified silicone, mercapto-modified silicone, phenol Modified silicone, one-end reactive silicone, different functional group-modified silicone, polyether-modified silicone, methylstyryl-modified silicone Silicones including various derivatives such as alkyls, alkyl-modified silicones, higher fatty acid ester-modified silicones, hydrophilic specially-modified silicones, higher alkoxy-modified silicones, higher fatty acid-containing silicones, fluorine-modified silicones; paraaminobenzoic acid and its derivatives, homomethyl- 7N-acetyl allanilanilate, butyl methoxybenzoylmethane, di-paramethoxycinnamic acid-glyceryl mono-2-ethylhexanoate, paramethoxycinnamic acid derivatives such as octylcinnamate, salicylic acid derivatives such as amyl salicylate, 2 Benzophenone derivatives such as 1,4-dihydroxybenzophenone, dimethoxybenzylidene dioxoimidazoline ethylhexyl propionate, liquid lanolin acetate, extract of Coganebana root, trianilino-p-cal UV absorbers such as boethylhexyloxy-triazine;
アルブチン、コウジ酸、リン酸アスコルビン酸マグネシウムなどのアスコルビン酸およびその誘導体、グルタチオン、甘草エキス、チョウジエキス、茶抽出物、アスタキサンチン、牛胎盤エキス、トコフェロールおよびその誘導体、トラネキサム酸およびその塩、アズレン、γ−ヒドロキシ酪酸等の美白成分; Ascorbic acid and its derivatives such as arbutin, kojic acid, magnesium ascorbate phosphate, glutathione, licorice extract, clove extract, tea extract, astaxanthin, cow placenta extract, tocopherol and its derivatives, tranexamic acid and its salts, azulene, γ -Whitening ingredients such as hydroxybutyric acid;
マルチトール、ソルビトール、グリセリン、プロピレングリコール、1,3−ブチレングリコール、ポリエチレングリコール、グリコール等の多価アルコール、ピロリドンカルボン酸ソーダ、乳酸ソーダ、クエン酸ソーダなど有機酸およびその塩、ヒアルロン酸ソーダなどヒアルロン酸およびその塩、酵母および酵母抽出液の加水分解物、酵母培養液、乳酸菌培養液など醗酵代謝産物、コラーゲン、エラスチン、ケラチン、セリシン等の水溶性蛋白、コラーゲン加水分解物、カゼイン加水分解物、シルク加水分解物、ポリアスパラギン酸ナトリウム等のぺプチド類およびその塩、トレハロース、キシロビオース、マルトース、ラフィノース、メリビオース、蔗糖、ブドウ糖、植物性粘質多糖等の糖類、結晶性セルロース、非結晶性セルロース、キシラン、マンナン、ガラクタン、アラビナン、アラビノキシラン等の多糖類およびその誘導体、水溶性キチン、キトサン、ペクチン、コンドロイチン硫酸およびその塩等のグリコサミノグリカンおよびその塩、グリシン、セリン、スレオニン、アラニン、アスパラギン酸、チロシン、バリン、ロイシン、アルギニン、グルタミン、プロリン酸等のアミノ酸、アミノカルボニル反応物等の糖アミノ酸化合物、アロエ、マロニエ等の植物抽出液、トリメチルグリシン、尿素、尿酸、アンモニア、レシチン、ラノリン、スクワラン、スクワレン、グルコサミン、クレアチニン、DNA、RNA等の核酸関連物質等の保湿剤; Maltitol, sorbitol, glycerin, propylene glycol, 1,3-butylene glycol, polyhydric alcohols such as polyethylene glycol, glycol, organic acids such as pyrrolidone carboxylic acid soda, sodium lactate and sodium citrate, and salts thereof, hyaluronic acid such as sodium hyaluronate Acids and salts thereof, yeast and yeast extract hydrolysates, yeast culture fluid, fermentation metabolites such as lactic acid bacteria culture fluid, collagen, elastin, keratin, sericin and other water soluble proteins, collagen hydrolysates, casein hydrolysates, Silk hydrolyzate, peptides such as sodium polyaspartate and salts thereof, trehalose, xylobiose, maltose, raffinose, melibiose, sucrose, glucose, saccharides such as vegetable viscous polysaccharides, crystalline cellulose, amorphous cellulose Polysaccharides such as xylan, mannan, galactan, arabinan, arabinoxylan and their derivatives, glycosaminoglycans and their salts such as water-soluble chitin, chitosan, pectin, chondroitin sulfate and their salts, glycine, serine, threonine, alanine, aspartic acid , Tyrosine, valine, leucine, arginine, glutamine, amino acids such as prophosphoric acid, sugar amino acid compounds such as aminocarbonyl reactants, plant extracts such as aloe, maronier, trimethylglycine, urea, uric acid, ammonia, lecithin, lanolin, squalane Humectants such as nucleic acid related substances such as squalene, glucosamine, creatinine, DNA, RNA
カルボキシメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルトリメチルアンモニウムクロリドエーテル、エチルセルロース、ヒドロキシプロピルセルロース、メチルヒドロキシプロピルセルロース、デンプン、可溶性デンプン、カルボキシメチルデンプン、メチルデンプン、アルギン酸プロピレングリコールエステル、メチルセルロース、アラビアガム、キサンタンガム、グアーガム、ローカストビンガム、クインスシード、カラギーナン、ガラクタン、ペクチン、マンナン、デキストラン、サクシノグルカン、カードラン、ゼラチン、カゼイン、アルブミン、コラーゲン、メトキシエチレン無水マレイン酸共重合体、両性メタクリル酸エステル共重合体、ポリ塩化ジメチルメチレンピペリジニウム、ポリアクリル酸エステル共重合体、ポリ酢酸ビニル、ポリビニルアルコール、ポリビニルピロリドン、ポリビニルメチルエーテル、カルボキシビニルポリマー、ポリアクリル酸、ニトロセルロース、ポリエチレングリコール脂肪酸エステル、ジステアリン酸ポリエチレングリコール等のポリオキシエチレン脂肪酸エステル、ポリオキシエチレンジオレイン酸メチルグルコシド等のポリオキシエチレン脂肪酸エステルメチルグリコシド等の増粘剤;エチレンジアミン四酢酸およびその塩類、ヒドロキシエチレンジアミン3酢酸およびその塩類、リン酸、アスコルビン酸、コハク酸、グルコン酸、ポリリン酸塩類、メタリン酸塩類などの金属イオン封鎖剤;エタノール、プロピレングリコール、1,3ーブチレグリコール等の有機溶剤、ブチルヒドロキシトルエン、トコフェロール、フィチン酸等の酸化防止剤; Carboxymethylcellulose, hydroxyethylcellulose, hydroxypropyltrimethylammonium chloride ether, ethylcellulose, hydroxypropylcellulose, methylhydroxypropylcellulose, starch, soluble starch, carboxymethyl starch, methyl starch, propylene glycol alginate, methylcellulose, gum arabic, xanthan gum, guar gum, Locust Bingham, quince seed, carrageenan, galactan, pectin, mannan, dextran, succinoglucan, curdlan, gelatin, casein, albumin, collagen, methoxyethylene maleic anhydride copolymer, amphoteric methacrylate copolymer, polychlorinated Dimethylmethylene piperidinium, polyacrylate Ter copolymer, polyvinyl acetate, polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl methyl ether, carboxyvinyl polymer, polyacrylic acid, nitrocellulose, polyethylene glycol fatty acid ester, polyethylene glycol distearate, polyoxyethylene fatty acid ester, polyoxyethylene Thickeners such as polyoxyethylene fatty acid ester methylglycoside such as dioleic acid methyl glucoside; ethylenediaminetetraacetic acid and its salts, hydroxyethylenediamine triacetic acid and its salts, phosphoric acid, ascorbic acid, succinic acid, gluconic acid, polyphosphates , Sequestering agents such as metaphosphates; organic solvents such as ethanol, propylene glycol and 1,3-butylene glycol, butylhydroxytoluene Tocopherol, antioxidant such as phytic acid;
クエン酸、リンゴ酸、酒石酸、乳酸、アジピン酸、グルタミン酸、アスパラギン酸、マレイン酸等の有機酸;ビタミンA及びその誘導体;ビタミンB6塩酸塩、ビタミンB6トリパルミテート、ビタミンB6ジオクタノエート、ビタミンB2及びその誘導体等のビタミンB類;アスコルビン酸、アスコルビン酸硫酸エステル、アスコルビン酸リン酸エステル等のビタミンC類、αトコフェロール、βトコフェロール、γトコフェロール等のビタミンE類、ビタミンD類、ビタミンH、パントテン酸等のビタミン類; ニコチン酸アミド、ニコチン酸ベンジル、γ−オリザノール、アラントイン、グリチルリチン酸(塩)グリチルレチン酸およびその誘導体、ヒノキチオール、ムシジン、ビサボロール、ユーカリプトール、チモールイノシトール、サポニン類(キラヤサポニン、アズキサポニン、ヘチマサポニン等)トラネキサム酸、パントテルエチルエーテル、エチニルエストラジオール、セファランジン、プラセンタエキス、センブリエキス、セファランチン、ビタミンEおよびその誘導体、ガンマーオリザノールなどの血行促進剤;トウガラシチンキ、ショオウキョウチンキ、カンタリスチンキ、ニコチン酸ベンジルエステルなどの局所刺激剤、各種ビタミンやアミノ酸などの栄養剤、グリチルレチン酸、グリチルリチン酸誘導体、アラントイン、アズレン、アミノカプロン酸、ヒドロコルチゾンなどの抗炎症剤; Organic acids such as citric acid, malic acid, tartaric acid, lactic acid, adipic acid, glutamic acid, aspartic acid, maleic acid; vitamin A and its derivatives; vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 and the like Vitamin B such as derivatives; vitamin C such as ascorbic acid, ascorbic acid sulfate, ascorbic acid phosphate, vitamin E such as α-tocopherol, β-tocopherol, γ-tocopherol, vitamin D, vitamin H, pantothenic acid, etc. Vitamins of: nicotinamide, benzyl nicotinate, γ-oryzanol, allantoin, glycyrrhizic acid (salt) glycyrrhetinic acid and its derivatives, hinokitiol, mucidin, bisabolol, eucalyptol, thymol inositol, Saponins (Quillaja saponin, azoxaponin, loofah saponin, etc.) tranexamic acid, pantothel ethyl ether, ethinyl estradiol, cephalandin, placenta extract, assembly extract, cephalanthin, vitamin E and its derivatives, blood circulation promoters such as gamma oryzanol; Anti-inflammatory agents such as topical stimulants such as cinnamon tincture, cantalis tincture, benzyl nicotinate, nutrients such as various vitamins and amino acids, glycyrrhetinic acid, glycyrrhizic acid derivatives, allantoin, azulene, aminocaproic acid, hydrocortisone
酸化亜鉛、硫酸亜鉛、アラントインヒドロキシアルミニウム、塩化アルミニウム、スルホ石炭酸亜鉛、タンニン酸などの収斂剤;メントール、カンフルなどの清涼剤;抗ヒスタミン剤;トコフェロール類、BHA、BHT、没食子酸、NDGA、ユビキノンなどの酸化防止剤等の各種薬剤;サッカロマイセスなどの酵母、糸状菌、バクテリア、牛胎盤、人胎盤、人臍帯、酵母、牛コラーゲン、牛乳由来蛋白、小麦、大豆、牛血液、ブタ血液、鶏冠、カミツレ、キュウリ、コメ、シアバター、シラカバ、茶、トマト、ニンニク、ハマメリス、バラ、ヘチマ、ホップ、モモ、アンズ、レモン、キウイ、ドクダミ、トウガラシ、クララ、ギシギシ、コウホネ、セージ、ノコギリ草、ゼニアオイ、センキュウ、センブリ、タイム、トウキ、トウヒ、バーチ、スギナ、ヘチマ、マロニエ、ユキノシタ、アルニカ、ユリ、ヨモギ、シャクヤク、アロエ、アロエベラ、オウゴン、オウバク、コウカ、ベニバナ、サンシン、シコン、タイソウ、チンピ、ニンジン、ヨクイニン、ハトムギ、クチナシ、サワラ等の動植物・微生物およびその一部から有機溶媒、アルコール、多価アルコール、水、水性アルコール等で抽出または加水分解して得た天然エキス;色素; Astringents such as zinc oxide, zinc sulfate, allantoin hydroxyaluminum, aluminum chloride, zinc sulfocolate and tannic acid; refreshing agents such as menthol and camphor; antihistamines; oxidation of tocopherols, BHA, BHT, gallic acid, NDGA, ubiquinone, etc. Various drugs such as inhibitors; yeasts such as Saccharomyces, filamentous fungi, bacteria, cow placenta, human placenta, human umbilical cord, yeast, cow collagen, milk derived protein, wheat, soybean, cow blood, pig blood, chicken crown, chamomile, cucumber , Rice, shea butter, birch, tea, tomato, garlic, hamamelis, rose, loofah, hop, peach, apricot, lemon, kiwi, dokudami, capsicum, clara, scallop, kohone, sage, sawtooth grass, mallow, senkyu, assembly , Thyme, spruce, spruce, ba Chi, Sugina, Loofah, Maronie, Yukinosita, Arnica, Lily, Artemisia, Peonies, Aloe, Aloe Vera, Ogon, Oats, Pepper, Safflower, Sanshin, Shikon, Tycho, Chimpi, Carrot, Yokuinin, Barley, Gardenia, Sawara, etc. -Natural extracts obtained by extraction or hydrolysis from microorganisms and parts thereof with organic solvents, alcohols, polyhydric alcohols, water, aqueous alcohols, etc .; pigments;
香料;ラウリル硫酸ナトリウム、ラウリル硫酸カリウム、ミリスチル硫酸ナトリウム、ミリスチル硫酸カリウム、セチル硫酸ナトリウム、ステアリル硫酸ナトリウム、オレイル硫酸ナトリウム、ラウリル硫酸トリエタノールアミン等のアルキル硫酸およびその塩;ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ポリオキシエチレンセチルエーテル硫酸ナトリウム、ポリオキシエチレンオレイルエーテル硫酸ナトリウム、ポリオキシエチレンラウリルエーテル硫酸トリエタノールアミン等のアルキルエーテル硫酸およびその塩;ポリオキシエチレンオクチルフェニルエーテル硫酸ナトリウム等のアルキルアリールエーテル硫酸およびその塩;ポリオキシエチレンラウリン酸アミドエーテル硫酸ナトリウム、ポリオキシエチレンラウリン酸アミドエーテル硫酸トリエタノールアミン、ポリオキシエチレンミリスチン酸アミドエーテル硫酸ナトリウム、ポリオキシエチレンオレイン酸アミドエーテル硫酸ナトリウム、ポリオキシエチレンヤシ油脂肪酸アミドエーテル硫酸ナトリウム、オレイン酸アミドエーテル硫酸ナトリウム等のアルキルアミド硫酸およびその塩;硬化ヤシ油脂肪酸グリセリン硫酸ナトリウム等のアシルエステル硫酸およびその塩;ラウリルスルホン酸ナトリウム、ミリスチルスルホン酸ナトリウム、ヤシ油アルキルスルホン酸ナトリウム等のアルキルスルホン酸およびその塩; Perfume; Sodium lauryl sulfate, potassium lauryl sulfate, sodium myristyl sulfate, potassium myristyl sulfate, sodium cetyl sulfate, sodium stearyl sulfate, sodium oleyl sulfate, triethanolamine alkylsulfuric acid and its salts; sodium polyoxyethylene lauryl ether sulfate Alkyl ether sulfates such as sodium polyoxyethylene cetyl ether sulfate, sodium polyoxyethylene oleyl ether sulfate, polyoxyethylene lauryl ether sulfate triethanolamine and salts thereof; alkyl aryl ether sulfates such as sodium polyoxyethylene octylphenyl ether sulfate; Its salt; sodium polyoxyethylene lauric acid amide ether sulfate, polyoxyethylene laurin Amido ether sulfate triethanolamine, polyoxyethylene myristic acid amide ether sodium sulfate, polyoxyethylene oleic acid amide ether sodium sulfate, polyoxyethylene coconut oil fatty acid amide ether sodium sulfate, oleic acid amide ether sodium sulfate alkyl amide sulfuric acid and An acyl ester sulfuric acid such as hydrogenated coconut oil fatty acid sodium glyceryl sulfate and a salt thereof; an alkyl sulfonic acid such as sodium lauryl sulfonate, sodium myristyl sulfonate and sodium coconut oil alkyl sulfonate; and salts thereof;
リニアドデシルベンゼンスルホン酸ナトリウム、リニアドデシルベンゼンスルホン酸トリエタノールアミン等のアルキルベンゼンスルホン酸およびその塩;アルキルナフタレンスルホン酸およびその塩;ナフタレンスルホン酸塩のホルマリン重縮合物等のホルマリン縮合系スルホン酸およびその塩;スルホコハク酸ラウリル2ナトリウム、ジ−2−エチルヘキシルスルホコハク酸ナトリウム、ポリオキシエチレンスルホコハク酸ラウリル2ナトリウム、オレイン酸アミドスルホコハク酸2ナトリウム等のスルホコハク酸およびその塩;ドデセンスルホン酸ナトリウム、テトラデセンスルホン酸ナトリウム、ドデセンスルホン酸カリウム、デトラデセンスルホン酸カリウム等のα−オレフィンスルホン酸およびその塩; Alkylbenzene sulfonic acids and salts thereof such as sodium linear dodecyl benzene sulfonate and triethanolamine linear dodecyl benzene sulfonate; alkyl naphthalene sulfonic acids and salts thereof; formalin condensed sulfonic acids such as formalin polycondensates of naphthalene sulfonate and the like Salts: sulfosuccinic acid such as disodium lauryl sulfosuccinate, sodium di-2-ethylhexylsulfosuccinate, disodium lauryl polyoxyethylene sulfosuccinate, disodium oleamide sulfosuccinate and the like; sodium dodecene sulfonate, tetradecene sulfone Α-olefin sulfonic acids such as sodium acid, potassium dodecene sulfonate, potassium detradecene sulfonate, and salts thereof;
α−スルホラウリン酸メチルエステル、α−スルホミリスチン酸メチルエステル、α−スルホラウリン酸(EO)nメチルエステル等のα−スルホ脂肪酸エステルおよびその塩;ヤシ油脂肪酸アシル−Nメチルタウリンカリウム、ラウロイル−Nメチルタウリンナトリウム、ラウロイル−Nメチルタウリンカリウム、ラウロイル−Nメチルタウリントリエタノールアミン、ミリストイル−Nメチルタウリンナトリウム、ミリストイル−Nメチルタウリントリエタノールアミン、ヤシ油脂肪酸アシル−Nメチルタウリンナトリウム、ヤシ油脂肪酸アシル−Nメチルタウリントリエタンールアミン等のN−アシルメチル−タウリンおよびその塩;ラウロイルイセチオン酸ナトリウム、ミリストイルイセチオン酸ナトリウム、ヤシ油脂肪酸アシルイセチオン酸ナトリウム等のアシルイセチオン酸およびその塩;アルキルスルホ酢酸塩;ポリオキシエチレンラウリルエーテルリン酸ナトリウム、ポリオキシエチレンセチルエーテルリン酸ナトリウム、ポリオキシエチレンミリスチルリン酸カリウム、ポリオキシエチレンオレイルエーテルリン酸ナトリウム、ジポリオキシエチレンオレイルエーテルリン酸ナトリウム等のアルキルエーテルリン酸およびその塩; α-sulfo fatty acid esters and salts thereof such as α-sulfolauric acid methyl ester, α-sulfomyristic acid methyl ester, α-sulfolauric acid (EO) n methyl ester; coconut oil fatty acid acyl-N methyl taurine potassium, lauroyl- N-methyl taurine sodium, lauroyl-N-methyl taurine potassium, lauroyl-N-methyl taurine triethanolamine, myristoyl-N-methyl taurine sodium, myristoyl-N-methyl taurine triethanolamine, coconut oil fatty acid acyl-N-methyl taurine sodium, coconut oil fatty acid N-acylmethyl-taurine and its salts such as acyl-N-methyltaurine triethanuramine; sodium laureuylisethionate, sodium myristoyl isethionate, coconut oil fatty acid acylise Acyl isethionic acid such as sodium onate and its salts; alkyl sulfoacetates; sodium polyoxyethylene lauryl ether phosphate, sodium polyoxyethylene cetyl ether phosphate, potassium polyoxyethylene myristyl phosphate, sodium polyoxyethylene oleyl ether phosphate Alkyl ether phosphates such as dipolyoxyethylene oleyl ether sodium phosphate and salts thereof;
アルキルアリールエーテルリン酸およびその塩;ポリオキシエチレンラウリルアミドエーテルリン酸ナトリウム等の脂肪酸アミドエーテルリン酸およびその塩;ラウリルリン酸ナトリウム、ミリスチルリン酸ナトリウム、ヤシ油脂肪酸リン酸ナトリウム、ミリスチルリン酸カリウム、ラウリルリン酸トリエタノールアミン、オレイルリン酸ジエタノールアミン等のアルキルリン酸およびその塩;N−ラウロイルグルタミン酸ナトリウム、N−ミリストイルグルタミン酸ナトリウム、N−ヤシ油脂肪酸アシルグルタミン酸ナトリウム、N−ラウロイルグルタミン酸カリウム、N−ミリストイルグルタミン酸カリウム、N−ヤシ油脂肪酸アシルグルタミン酸カリウム、N−ラウロイルグルタミン酸トリエタノールアミン、N−ミリストイルグルタミン酸トリエタノールアミン、N−ヤシ油脂肪酸アシルグルタミン酸トリエタンールアミン、N−ラウロイルグリシンナトリウム、N−ミリストイルグリシントリエタノールアミン、N−ラウロイル−β−アラニンカリウム、N−ラウロイルスレオニントリエタノールアミン、N−ラウロイルサルコシンナトリウム、N−ラウロイル−N−メチル−β−アラニンナトリウム、N−ラウロイル−N−メチル−β−アラニントリエタノールアミン等のN−アシルアミノ酸およびその塩;ラウロイルイミノジ酢酸ナトリウム、ラウロイルイミノジ酢酸トリエタノールアミン、ヤシ油脂肪酸アシルイミノジ酢酸ナトリウム、ラウロイルイミノジ酢酸ジナトリウム、パーム核脂肪酸イミノジ酢酸ナトリウム等のアシルイミノジ酢酸およびその塩;ポリオキシエチレンラウリルエーテル酢酸ナトリウム、ポリオキシエチレンミリスチルエーテル酢酸カリウム、ポリオキシエチレンパルミチルエーテル酢酸トリエタノールアミン、ポリオキシエチレンステアリルエーテル酢酸ナトリウム、ポリグリセリルラウリルエーテル酢酸ナトリウム等のエーテルカルボン酸およびその塩; Alkyl aryl ether phosphates and salts thereof; fatty acid amide ether phosphates such as polyoxyethylene lauryl amide ether sodium phosphate and salts thereof; sodium lauryl phosphate, sodium myristyl phosphate, coconut oil fatty acid sodium phosphate, potassium myristyl phosphate Alkylphosphoric acids such as lauryl phosphate triethanolamine and oleyl phosphate diethanolamine and salts thereof; sodium N-lauroyl glutamate, sodium N-myristoyl glutamate, sodium N-coconut fatty acid acyl glutamate, potassium N-lauroyl glutamate, N-myristoyl Potassium glutamate, N-coconut oil fatty acid potassium acyl glutamate, N-lauroyl glutamic acid triethanolamine, N-myristoyl glutarate N-lauroyl-β-alanine potassium, N-lauroyl threonine triethanolamine, N-coconut oil triethanolamine, N-coconut oil fatty acid acyl glutamate triethanolamine, N-lauroylglycine sodium, N-myristoylglycine triethanolamine N-acyl amino acids and salts thereof such as sodium lauroyl sarcosine, N-lauroyl-N-methyl-β-alanine sodium, N-lauroyl-N-methyl-β-alanine triethanolamine; Acyl iminodiacetic acid and its salts such as triethanolamine diacetate, sodium coconut fatty acid acyliminodiacetate, disodium lauroiliminodiacetic acid, palm kernel fatty acid sodium iminodiacetic acid; polyoxy Sodium polyoxyethylene lauryl ether acetate, polyoxyethylene myristyl ether acetate, potassium acetate, polyoxyethylene palmityl ether acetate triethanolamine, polyoxyethylene stearyl ether sodium acetate, ether carboxylic acids and salts thereof such as polyglyceryl lauryl ether sodium acetate;
ヤシ油脂肪酸シルクペプチド等のアシル化ペプチド;ポリオキシエチレンラウリン酸アミドエーテルカルボン酸ナトリウム、ポリオキシエチレンミリスチン酸アミドエーテルカルボン酸ナトリウム、ポリオキシエチレンヤシ油脂肪酸アミドエーテルカルボン酸トリエタノールアミン等のアミドエーテルカルボン酸およびその塩;アシル乳酸塩;アルケニルコハク酸およびその塩等の陰イオン界面活性剤;ラウリルジメチルベタイン、ミリスチルジメチルベタイン、パルミチルジメチルベタイン、ステアリルジメチルベタイン、オレイルジメチルベタイン、ヤシ油アルキルジメチルベタイン、ラウリルメチルエチルベタイン、オクタデシルオキシメチルジメチルベタイン、ラウリルジヒドロキシエチルベタイン、ステアリルジヒドロキシエチルベタイン、ヤシ油アルキルジヒドロキシエチルベタイン、ラウリン酸アミドプロピルジメチルベタイン、ミリスチン酸アミドプロピルジメチルベタイン、ステアリン酸アミドプロピルジメチルベタイン、オレイン酸アミドプロピルジメチルベタイン、ヤシ油脂肪酸アミドプロピルジメチルベタイン等のカルボキシベタイン型;RN+H2CH2COO-(R:アルキル)で示されるラウリルグリシン、ステアリルグリシン等のグリシン型;RN+H2CH2CH2COO-(R:アルキル)で示されるラウリル−β−アラニン、ステアリル−β−アラニン等のアミノプロピオン酸型;ラウリルジメチルヒドロキシプロピルスルホベタイン、ミリスチルジメチルヒドロキシプロピリルスルホベタイン、ラウリルジメチルプロピルスルホベタイン、ヤシ油アルキルジメチルプロピルスルホベタイン、ラウリン酸アミドプロピルジメチルヒドロキシプロピルスルホベタイン等のスルホベタイン型; Acylated peptides such as coconut oil fatty acid silk peptide; amide ethers such as sodium polyoxyethylene lauric acid amide ether carboxylate, polyoxyethylene myristic acid amide ether sodium carboxylate, polyoxyethylene coconut oil fatty acid amide ether carboxylic acid triethanolamine Carboxylic acid and its salts; Acyl lactate; Anionic surfactants such as alkenyl succinic acid and its salts; Lauryl dimethyl betaine, myristyl dimethyl betaine, palmityl dimethyl betaine, stearyl dimethyl betaine, oleyl dimethyl betaine, coconut oil alkyl dimethyl betaine , Laurylmethylethylbetaine, octadecyloxymethyldimethylbetaine, lauryldihydroxyethylbetaine, stearyldihydroxyethyl Carboxybetaine types such as tine, coconut oil alkyldihydroxyethyl betaine, amidopropyl dimethyl betaine laurate, amidopropyl dimethyl betaine myristate, amidopropyl dimethyl betaine stearate, amidopropyl dimethyl betaine oleate, and coconut oil fatty acid amidopropyl dimethyl betaine; Glycine type such as laurylglycine and stearylglycine represented by RN + H 2 CH 2 COO − (R: alkyl); lauryl-β-alanine represented by RN + H 2 CH 2 CH 2 COO − (R: alkyl), Aminopropionic acid types such as stearyl-β-alanine; lauryldimethylhydroxypropylsulfobetaine, myristyldimethylhydroxypropylsulfobetaine, lauryldimethylpropylsulfobetaine, Shea oil alkyl dimethyl sulfobetaine, sulfobetaine type, such as lauric acid amide propyl dimethyl hydroxypropyl sulfobetaine;
RN+H2CH2CH2SO3 -(R:アルキル)で示されるスルホン酸型;RN+H2CH2CH2OSO3 -(R:アルキル)で示される硫酸型;ラウリルアミノプロピオン酸ナトリウム、ラウリルアミノジプロピオン酸ナトリウム、N−ラウロイル−N−ヒドロキシエチル−N´−ジカルボキシエチル−エチレンジアミン2ナトリウム、N−ラウロイル−N−ヒドロキシエチル−N´−カルボキシエチル−エチレンジアミンナトリウム、N−ラウロイル−N´−カルボキシメチル−N´−ヒドロキシエチルエチレンジアミンナトリウム、N−ヤシ脂肪酸アシル−N´−カルボキシエチル−N´−ヒドロキシエチルエチレンジアミンナトリウム、N−ラウロイル−N−ヒドロキシエチル−N´−ジカルボキシメチル−エチレンジアミン2ナトリウム、N−ラウロイル−N−ヒドロキシエチル−N´−カルボキシメチル−エチレンジアミンナトリウム、N−ヒドロキシドデシル−N−ポリオキシエチレン−N´−カルボキシエチル−N´−ポリオキシエチレンエチレンジアミンナトリウム等のアミノカルボン酸塩型;2−ラウリル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、2−ミリスチル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、2−ステアリル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、2−ヤシ油アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン等のイミダゾリン型;RN+H2CH(CH3)P(OH)O2 -(R:アルキル)で示されるリン酸型; RN + H 2 CH 2 CH 2 SO 3 -: sulfonic acid type represented by (R alkyl); RN + H 2 CH 2 CH 2 OSO 3 -:; lauryl aminopropionic acid sodium sulphate type represented by (R alkyl) , Sodium laurylaminodipropionate, N-lauroyl-N-hydroxyethyl-N′-dicarboxyethyl-ethylenediamine disodium, N-lauroyl-N-hydroxyethyl-N′-carboxyethyl-ethylenediamine sodium, N-lauroyl- N′-carboxymethyl-N′-hydroxyethylethylenediamine sodium, N-coconut fatty acid acyl-N′-carboxyethyl-N′-hydroxyethylethylenediamine sodium, N-lauroyl-N-hydroxyethyl-N′-dicarboxymethyl- Ethylenediamine 2-Natri Aminocarboxylic acids such as sodium N-lauroyl-N-hydroxyethyl-N'-carboxymethyl-ethylenediamine sodium, N-hydroxydodecyl-N-polyoxyethylene-N'-carboxyethyl-N'-polyoxyethylene ethylenediamine sodium Salt form; 2-lauryl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, 2-myristyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, 2-stearyl-N-carboxymethyl-N- Imidazoline type such as hydroxyethyl imidazolinium betaine, 2-coconut oil alkyl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaine; RN + H 2 CH (CH 3 ) P (OH) O 2 − (R: Phosphorus represented by alkyl) Acid form;
レシチン等の両性界面活性剤;ラウリルトリメチルアンモニウムクロライド、ミリスチルトリメチルアンモニウムクロライド、パルミチルトリメチルアンモニウムクロライド、ステアリルトリメチルアンモニウムクロライド、オレイルトリメチルアンモニウムクロライド、セチルトリメチルアンモニウムクロライド、ベヘニルトリメチルアンモニウムクロライド、ヤシ油アルキルトリメチルアンモニウムクロライド、牛脂アルキルトリメチルアンモニウムクロライド、ステアリルトリメチルアンモニウムブロミド、ヤシ油アルキルトリメチルアンモニウムブロミド、セチルトリメチルアンモニウムメチル硫酸等のモノアルキル第四級アンモニウム塩;ジオクチルジメチルアンモニウムクロライド、ジラウリルジメチルアンモニウムクロライド、ジステアリルジメチルアンモニウムクロライド等のジアルキル第四級アンモニウム塩;ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウムエチル硫酸、ラウロイルアミノエチルメチルジエチルアンモニウムメチル硫酸等のアシルアミノアルキル第四級アンモニウム塩;ジパルミチルポリエテノキシエチルアンモニウムクロライド、ジステアリルポリエテノキシメチルアンモニウムクロライド等のアルキルエテノキシ第四級アンモニウム塩;ラウリルイソキノリニウムクロライド等のアルキルイソキノリニウム塩; Amphoteric surfactants such as lecithin; lauryltrimethylammonium chloride, myristyltrimethylammonium chloride, palmityltrimethylammonium chloride, stearyltrimethylammonium chloride, oleyltrimethylammonium chloride, cetyltrimethylammonium chloride, behenyltrimethylammonium chloride, coconut oil alkyltrimethylammonium chloride Monoalkyl quaternary ammonium salts such as tallow alkyltrimethylammonium chloride, stearyltrimethylammonium bromide, coconut oil alkyltrimethylammonium bromide, cetyltrimethylammonium methylsulfuric acid; dioctyldimethylammonium chloride, dilauryldimethylammonium chloride Dialkyl quaternary ammonium salts such as distearyldimethylammonium chloride; Acylaminoalkyl quaternary ammonium salts such as lanolin fatty acid aminopropylethyldimethylammonium ethylsulfuric acid, lauroylaminoethylmethyldiethylammonium methylsulfuric acid; Dipalmityl polyethenoxyethyl Alkylethenoxy quaternary ammonium salts such as ammonium chloride and distearyl polyethenoxymethylammonium chloride; alkylisoquinolinium salts such as laurylisoquinolinium chloride;
ラウリルジメチルベンジルアンモニウムクロライド、ステアリルジメチルベンジルアンモニウムクロライド等のベンザルコニウム塩;ベンジルジメチル{2−[2−(p-1,1,3,3、-テトラメチルブチルフェノオキシ)エトオキシ]エチル}アンモニウムクロライド等のベンゼトニウム塩;セチルピリジニウムクロライド等のピリジニウム塩;イミダゾリニウム塩;N−ココイルアルギニンエチルエステルピロリドンカルボン酸塩、N−ラウロイルリジンエチルエチルエステル塩酸塩等のアシル塩基性アミノ酸アルキルエステル塩;ラウリルアミン塩酸塩等の第一級アミン塩;ジラウリルアミン酢酸塩等の第二級アミン塩;第三級アミン塩;脂肪酸アミドグアニジニウム塩;ラウリルトリエチレングリコールアンモニウムハイドロオキサイド等のアルキルトリアルキレングリコールアンモニウム塩等のカチオン界面活性剤;ラノリン、コレステロール、サポニン等の天然界面活性剤;アルギン酸ナトリウム、澱粉誘導体、トラガントゴム等の高分子界面活性;精製水等を配合することができる。 Benzalkonium salts such as lauryldimethylbenzylammonium chloride and stearyldimethylbenzylammonium chloride; benzyldimethyl {2- [2- (p-1,1,3,3, -tetramethylbutylphenoxy) ethoxy] ethyl} ammonium chloride Benzethonium salt such as cetylpyridinium chloride; imidazolinium salt; N-cocoyl arginine ethyl ester pyrrolidone carboxylate, acyl basic amino acid alkyl ester salt such as N-lauroyllysine ethyl ethyl ester hydrochloride; laurylamine Primary amine salt such as hydrochloride; Secondary amine salt such as dilaurylamine acetate; Tertiary amine salt; Fatty acid amidoguanidinium salt; Lauryl triethylene glycol ammonium hydroxide Cationic surfactants such as alkyltrialkylene glycol ammonium salts such as: Natural surfactants such as lanolin, cholesterol, saponin; Polymer surface activity such as sodium alginate, starch derivatives, tragacanth rubber, etc .; .
この内粉末成分との併用は、物理的な摩擦効果によって洗浄力を高めると共に、粒子表面に汚れを吸着することで有効である。また、油性成分との併用は油性成分の溶剤効果により油性の汚れを可溶化する効果があるために洗浄力の向上に適している。油性成分の中でも、シリコーン類との併用は使用後にさっぱりした感触を与える為に特に有効である。
さらに、保湿剤を併用することは過剰な脱脂による皮膚の荒れを防止することが出来、使用感の向上に寄与する。金属イオン封鎖剤、酸化防止剤との併用は長期間または過酷な使用条件下における製品の変化を防止し、良好な使用感を提供しつづける上で有効である。
The combined use with the inner powder component is effective by increasing the cleaning power by the physical friction effect and adsorbing dirt on the particle surface. Further, the combined use with the oil component is suitable for improving the detergency because it has the effect of solubilizing the oily dirt due to the solvent effect of the oil component. Among oil components, the combined use with silicones is particularly effective for giving a refreshing feel after use.
Furthermore, using a moisturizing agent together can prevent rough skin due to excessive degreasing, and contributes to an improved feeling of use. The combined use with a sequestering agent and an antioxidant is effective in preventing a change in the product under a long-term or severe use condition and providing a good feeling of use.
次に、本発明を実施例により更に詳細に説明するが、本発明の技術的範囲及びその実施態様はこれに限定されるものではない。実施例でえられた洗浄剤組成物の諸物性の測定は、以下の試験法と評価法によって行った。
<起泡力の測定>試料洗浄剤組成物を3.3gとり精製水で300gにし、ミキサーに入れ30秒間ミキサーにて撹拌し、直後の泡の高さ(mm)を起泡力とした。なお測定温度は25℃とした。また、得られた結果を次の基準により判定した。◎:起泡力が180mm以上、○:起泡力が170mm以上、180mm未満、△:起泡力が160mm以上、170mm未満、×:起泡力が160mm未満。
EXAMPLES Next, although an Example demonstrates this invention still in detail, the technical scope of this invention and its embodiment are not limited to this. Various physical properties of the cleaning composition obtained in the examples were measured by the following test methods and evaluation methods.
<Measurement of foaming power> 3.3 g of the sample detergent composition was taken up to 300 g with purified water, placed in a mixer and stirred with a mixer for 30 seconds, and the foam height (mm) immediately thereafter was defined as foaming power. The measurement temperature was 25 ° C. Moreover, the obtained result was determined according to the following criteria. ◎: Foaming force is 180 mm or more, ○: Foaming force is 170 mm or more and less than 180 mm, △: Foaming force is 160 mm or more and less than 170 mm, ×: Foaming force is less than 160 mm.
<洗浄力の測定>人工油性汚垢を木綿布に均一に付着させて作製した人工汚染布を、試料洗浄剤組成物10gを精製水で300gとして作製した洗浄液で洗浄し、結果を目視判定した。結果を洗浄力の高いものから順に◎、○、△、×で示した。
<使用感の測定>試料洗浄組成物を用いて、男女パネラー8人を対象に手洗浄試験を行い、各試験項目(さっぱり感、つっぱり感)について7段階評価し、更にその平均点から次の基準により判定した。<7段階評価>7点:非常によい、6点:良い、5点:やや良い、4点:普通、3点:やや悪い、2点:悪い、1点:非常に悪い。<判定>◎:平均点が6点以上、○:平均点が4点以上、6点未満、△:平均点が2点以上、4点未満、×:平均点が2点未満とした。
<Measurement of Detergency> An artificially contaminated cloth prepared by uniformly adhering artificial oily soil to a cotton cloth was washed with a cleaning solution prepared by using 10 g of a sample detergent composition with 300 g of purified water, and the result was visually determined. . The results are indicated by ◎, ○, Δ, × in order from the highest detergency.
<Measurement of feeling of use> Using the sample cleaning composition, a hand washing test was conducted on 8 male and female panelists, and each test item (fresh feeling, fresh feeling) was evaluated on a 7-point scale. Judged by criteria. <7-step evaluation> 7 points: very good, 6 points: good, 5 points: somewhat good, 4 points: normal, 3 points: somewhat bad, 2 points: bad, 1 point: very bad. <Determination> A: Average point is 6 points or more, B: Average point is 4 points or more, less than 6 points, Δ: Average point is 2 points or more, less than 4 points, X: Average point is less than 2 points.
[実施例1]
表1および表2に記載の配合成分を、表に記載の割合(質量%)で混合し、洗浄剤組成物を調製した。得られた洗浄剤組成物の物性を、上記、記載の方法にて測定した。結果を表の評価欄に示す。本発明の組成物は泡立ち、洗浄性および使用感において優れた結果を示した。一方、成分(A)または成分(B)を単独で用いたものは、泡立ち、洗浄力、使用感の何れかで劣った結果を示した。表中、小割合成分は、便宜上、Aの区分に記載した。
[Example 1]
The blending components described in Table 1 and Table 2 were mixed at the ratio (mass%) described in the table to prepare a cleaning composition. The physical properties of the obtained cleaning composition were measured by the method described above. The results are shown in the evaluation column of the table. The composition of the present invention showed excellent results in foaming, detergency and usability. On the other hand, those using component (A) or component (B) alone showed inferior results in any of foaming, detergency, and feeling of use. In the table, the small proportion components are shown in the category A for convenience.
[実施例2]
ラウロイルアスパラギン酸96g、ラウロイル−αジアスパラギン酸0.5gラウロイル−βジアスパラギン酸0.5g、ラウリン酸3gを混合した物を、30%水酸化ナトリウム水溶液で中和し、組成物1を作成した。下記組成によりクレンジングフォームを常法により作成し、起泡力、使用感を測定したところ、泡立ちに優れ、且つさっぱりとした感触が得られ、洗浄後のきしみ感もない優れたものであった。
(質量%)
組成物1 25.0(固形分)
ヘキサオレイン酸POE(50)ソルビトールエステル 2.0
ラウロイルジエタノールアミド 2.0
ジステアリン酸グリコール 1.0
オレス20 1.0
ベタイン 1.0
ココイルメチルタウリンNa 3.0
PEG−150 4.0
BG 10.0
精製水 バランス
[Example 2]
A mixture of 96 g of lauroyl aspartic acid, 0.5 g of lauroyl-α-diaspartic acid, 0.5 g of lauroyl-β-diaspartic acid, and 3 g of lauric acid was neutralized with a 30% aqueous sodium hydroxide solution to prepare composition 1. . A cleansing foam having the following composition was prepared by a conventional method, and the foaming power and the feeling of use were measured. As a result, the foam was excellent in foaming and a refreshing feel was obtained, and there was no squeaky feeling after washing.
(mass%)
Composition 1 25.0 (solid content)
Hexaoleic acid POE (50) sorbitol ester 2.0
Lauroyl diethanolamide 2.0
Glycol distearate 1.0
Ores 20 1.0
Betaine 1.0
Cocoyl Methyl Taurine Na 3.0
PEG-150 4.0
BG 10.0
Purified water balance
本発明の組成物は、泡立ち、洗浄性に優れ、且つ使用感にも優れており、化粧品並びに洗浄用途の分野で好適に利用できる。 The composition of the present invention is excellent in foaming, cleanability, and use feeling, and can be suitably used in the fields of cosmetics and cleaning applications.
Claims (7)
成分(A):一般式(1)で表されるN−アシルアスパラギン酸またはその塩を主成分とするN−アシルアスパラギン酸系界面活性剤
Component (A): N-acyl aspartic acid-based surfactant mainly composed of N-acyl aspartic acid represented by the general formula (1) or a salt thereof
成分(C):一般式(4)で表される高級脂肪酸またはその塩
Component (C): a higher fatty acid represented by the general formula (4) or a salt thereof
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JP2007145746A (en) * | 2005-11-25 | 2007-06-14 | Asahi Kasei Chemicals Corp | Creamy cosmetic |
JP2008150303A (en) * | 2006-12-15 | 2008-07-03 | Kao Corp | Skin cleanser |
JP2010285395A (en) * | 2009-06-12 | 2010-12-24 | Hoyu Co Ltd | Detergent composition |
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JP2006348101A (en) * | 2005-06-14 | 2006-12-28 | Asahi Kasei Chemicals Corp | Cleaning composition having improved thickening property |
JP2007145746A (en) * | 2005-11-25 | 2007-06-14 | Asahi Kasei Chemicals Corp | Creamy cosmetic |
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