JP2005272823A5 - - Google Patents
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- JP2005272823A5 JP2005272823A5 JP2005046196A JP2005046196A JP2005272823A5 JP 2005272823 A5 JP2005272823 A5 JP 2005272823A5 JP 2005046196 A JP2005046196 A JP 2005046196A JP 2005046196 A JP2005046196 A JP 2005046196A JP 2005272823 A5 JP2005272823 A5 JP 2005272823A5
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- 125000004432 carbon atoms Chemical group C* 0.000 claims description 33
- 125000000217 alkyl group Chemical group 0.000 claims description 29
- 125000001424 substituent group Chemical group 0.000 claims description 27
- 150000001875 compounds Chemical class 0.000 claims description 23
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims description 20
- 125000003545 alkoxy group Chemical group 0.000 claims description 18
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 17
- 125000003118 aryl group Chemical group 0.000 claims description 17
- 125000003277 amino group Chemical group 0.000 claims description 12
- 125000005392 carboxamide group Chemical group NC(=O)* 0.000 claims description 12
- 125000005843 halogen group Chemical group 0.000 claims description 12
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 125000004433 nitrogen atoms Chemical group N* 0.000 claims description 10
- 125000003262 carboxylic acid ester group Chemical group [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 claims description 8
- 125000004429 atoms Chemical group 0.000 claims description 6
- 150000007942 carboxylates Chemical group 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000000304 alkynyl group Chemical group 0.000 claims description 5
- 150000001450 anions Chemical class 0.000 claims description 5
- -1 xanthene compound Chemical class 0.000 claims description 4
- 210000002706 Plastids Anatomy 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims 5
- 238000004040 coloring Methods 0.000 claims 4
- 239000000463 material Substances 0.000 claims 2
- AAAQKTZKLRYKHR-UHFFFAOYSA-N Triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- 150000001733 carboxylic acid esters Chemical group 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
Description
上記目的は、本発明にかかる色素体を提供することで達成された。即ち、本発明は、第一の色素化合物として下記一般式(1)及び(2)の少なくとも一方で示される化合物と、第二の色素化合物として下記一般式(3)で示される水不溶性トリフェニルメタン系化合物及び下記一般式(4)で示される水不溶性キサンテン系化合物の少なくとも一方を含んでいることを特徴とする色素体である。 The above object has been achieved by providing a chromophore according to the present invention. That is, the present invention provides a compound represented by at least one of the following general formulas (1) and (2) as the first dye compound and a water-insoluble triphenyl represented by the following general formula (3) as the second dye compound. it is plastid, wherein are Nde contains at least one of the methane-based compound and the water-insoluble xanthene compound represented by the following general formula (4).
[式中、R2-1〜R2-8は、それぞれ、水素原子、炭素数1〜8個のアルキル基、炭素数1〜8個のアルケニル基、炭素数1〜8個のアルキニル基、又はアラルキル基を示す。又、R2-1〜R2-8のうち、同じ窒素原子に結合する2個の基は、互いに結合して、窒素原子と共に5員環、6員環、又は7員環を形成してもよい。又、R2-1〜R2-8は、置換基を有していてもよく、R2-1〜R2-8及びそれらの置換基は、それぞれ同一であっても、異なっていてもよい。又、式中の芳香族環は、更に置換基を有していてもよい。X2 -は、陰イオンを示す。]
[式中、R 9 及びR 10 は、それぞれ独立に、水素原子、炭素数1〜5個のアルキル基、アリール基又は置換基としてスルホネート基を有さないアラルキル基を示し、R 11 は、水素原子、ハロゲン原子、炭素数1〜5個のアルキル基又は炭素数1〜5個のアルコキシ基を示し、R 12 及びR 13 は、それぞれ独立に、水素原子、ハロゲン原子、アルキル基、アルコキシ基、ヒドロキシル基、アミノ基、カルボキシレート基、スルホネート基、カルボン酸エステル基又はカルボキサミド基を示す。R 9 〜R 13 における、アルキル基、アルコキシ基、アラルキル基、アリール基、アミノ基、カルボン酸エステル基及びカルボキサミド基は、置換基を有してもよい。]
[式中、R 14 及びR 15 は、それぞれ独立に、水素原子、炭素数1〜5個のアルキル基、置換基としてスルホネート基を有さないアリール基又はアラルキル基を示し、R 16 は、水素原子、ハロゲン原子、炭素数1〜5個のアルキル基又は炭素数1〜5個のアルコキシ基を示し、R 17 及びR 18 は、それぞれ独立に、水素原子、ハロゲン原子、アルキル基、アルコキシ基、ヒドロキシル基、アミノ基、カルボキレート基、スルホネート基、カルボン酸エステル基又はカルボキサミド基を示す。R 14 〜R 18 における、アルキル基、アルコキシ基、アラルキル基、アリール基、アミノ基、カルボン酸エステル基及びカルボキサミド基は、置換基を有してもよい。]
[Wherein R 2-1 to R 2-8 are each a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 1 to 8 carbon atoms, an alkynyl group having 1 to 8 carbon atoms, Or an aralkyl group is shown. Two of R 2-1 to R 2-8 bonded to the same nitrogen atom are bonded to each other to form a 5-membered ring, a 6-membered ring, or a 7-membered ring together with the nitrogen atom. Also good. R 2-1 to R 2-8 may have a substituent, and R 2-1 to R 2-8 and their substituents may be the same or different. Good. Moreover, the aromatic ring in the formula may further have a substituent. X 2 − represents an anion. ]
Wherein, R 9 and R 10 each independently represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, an aralkyl group having no sulfonate group as an aryl group or a substituent, R 11 is hydrogen An atom, a halogen atom, an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms, wherein R 12 and R 13 are each independently a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, A hydroxyl group, an amino group, a carboxylate group, a sulfonate group, a carboxylic acid ester group or a carboxamide group is shown. The alkyl group, alkoxy group, aralkyl group, aryl group, amino group, carboxylate group and carboxamide group in R 9 to R 13 may have a substituent. ]
[Wherein, R 14 and R 15 each independently represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, an aryl group or an aralkyl group having no sulfonate group as a substituent, and R 16 represents a hydrogen atom. An atom, a halogen atom, an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms, wherein R 17 and R 18 are each independently a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, A hydroxyl group, an amino group, a carbochelate group, a sulfonate group, a carboxylic acid ester group or a carboxamide group is shown. The alkyl group, alkoxy group, aralkyl group, aryl group, amino group, carboxylic ester group and carboxamide group in R 14 to R 18 may have a substituent. ]
Claims (16)
[式中、R1-1〜R1-8は、それぞれ、水素原子、炭素数1〜8個のアルキル基、炭素数1〜8個のアルケニル基、炭素数1〜8個のアルキニル基、又はアラルキル基を示す。又、R1-1〜R1-8のうち、同じ窒素原子に結合する2個の基は、互いに結合して、窒素原子と共に5員環、6員環、又は7員環を形成してもよい。又、R1-1〜R1-8は、置換基を有していてもよく、R1-1〜R1-8及びそれらの置換基は、それぞれ同一であっても、異なっていてもよい。又、式中の芳香族環は、更に置換基を有していてもよい。nは、1又は2である。X1 -は、陰イオンを示す。]
[式中、R2-1〜R2-8は、それぞれ、水素原子、炭素数1〜8個のアルキル基、炭素数1〜8個のアルケニル基、炭素数1〜8個のアルキニル基、又はアラルキル基を示す。又、R2-1〜R2-8のうち、同じ窒素原子に結合する2個の基は、互いに結合して、窒素原子と共に5員環、6員環、又は7員環を形成してもよい。又、R2-1〜R2-8は、置換基を有していてもよく、R2-1〜R2-8及びそれらの置換基は、それぞれ同一であっても、異なっていてもよい。又、式中の芳香族環は、更に置換基を有していてもよい。X2 -は、陰イオンを示す。]
[式中、R 9 及びR 10 は、それぞれ独立に、水素原子、炭素数1〜5個のアルキル基、アリール基又は置換基としてスルホネート基を有さないアラルキル基を示し、R 11 は、水素原子、ハロゲン原子、炭素数1〜5個のアルキル基又は炭素数1〜5個のアルコキシ基を示し、R 12 及びR 13 は、それぞれ独立に、水素原子、ハロゲン原子、アルキル基、アルコキシ基、ヒドロキシル基、アミノ基、カルボキシレート基、スルホネート基、カルボン酸エステル基又はカルボキサミド基を示す。R 9 〜R 13 における、アルキル基、アルコキシ基、アラルキル基、アリール基、アミノ基、カルボン酸エステル基及びカルボキサミド基は、置換基を有してもよい。]
[式中、R 14 及びR 15 は、それぞれ独立に、水素原子、炭素数1〜5個のアルキル基、置換基としてスルホネート基を有さないアリール基又はアラルキル基を示し、R 16 は、水素原子、ハロゲン原子、炭素数1〜5個のアルキル基又は炭素数1〜5個のアルコキシ基を示し、R 17 及びR 18 は、それぞれ独立に、水素原子、ハロゲン原子、アルキル基、アルコキシ基、ヒドロキシル基、アミノ基、カルボキレート基、スルホネート基、カルボン酸エステル基又はカルボキサミド基を示す。R 14 〜R 18 における、アルキル基、アルコキシ基、アラルキル基、アリール基、アミノ基、カルボン酸エステル基及びカルボキサミド基は、置換基を有してもよい。] A water-insoluble triphenylmethane-based compound represented by the following general formula (3) as the second dye compound, which contains at least one of the following general formulas (1) and (2) as the first dye compound and plastid, wherein are Nde contains at least one water-insoluble xanthene compound represented by the following general formula (4).
[Wherein R 1-1 to R 1-8 are each a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 1 to 8 carbon atoms, an alkynyl group having 1 to 8 carbon atoms, Or an aralkyl group is shown. Also, among R 1-1 to R 1-8 , two groups bonded to the same nitrogen atom are bonded to each other to form a 5-membered ring, 6-membered ring, or 7-membered ring together with the nitrogen atom. Also good. R 1-1 to R 1-8 may have a substituent, and R 1-1 to R 1-8 and their substituents may be the same or different. Good. Moreover, the aromatic ring in the formula may further have a substituent. n is 1 or 2. X 1 − represents an anion. ]
[Wherein R 2-1 to R 2-8 are each a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 1 to 8 carbon atoms, an alkynyl group having 1 to 8 carbon atoms, Or an aralkyl group is shown. Two of R 2-1 to R 2-8 bonded to the same nitrogen atom are bonded to each other to form a 5-membered ring, a 6-membered ring, or a 7-membered ring together with the nitrogen atom. Also good. R 2-1 to R 2-8 may have a substituent, and R 2-1 to R 2-8 and their substituents may be the same or different. Good. Moreover, the aromatic ring in the formula may further have a substituent. X 2 − represents an anion. ]
Wherein, R 9 and R 10 each independently represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, an aralkyl group having no sulfonate group as an aryl group or a substituent, R 11 is hydrogen An atom, a halogen atom, an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms, wherein R 12 and R 13 are each independently a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, A hydroxyl group, an amino group, a carboxylate group, a sulfonate group, a carboxylic acid ester group or a carboxamide group is shown. The alkyl group, alkoxy group, aralkyl group, aryl group, amino group, carboxylate group and carboxamide group in R 9 to R 13 may have a substituent. ]
[Wherein, R 14 and R 15 each independently represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, an aryl group or an aralkyl group having no sulfonate group as a substituent, and R 16 represents a hydrogen atom. An atom, a halogen atom, an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms, wherein R 17 and R 18 are each independently a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, A hydroxyl group, an amino group, a carbochelate group, a sulfonate group, a carboxylic acid ester group or a carboxamide group is shown. The alkyl group, alkoxy group, aralkyl group, aryl group, amino group, carboxylic acid ester group and carboxamide group in R 14 to R 18 may have a substituent. ]
[式中、R1-1〜R1-8は、それぞれ、水素原子、炭素数1〜8個のアルキル基、炭素数1〜8個のアルケニル基、炭素数1〜8個のアルキニル基、又はアラルキル基を示す。又、R1-1〜R1-8のうち、同じ窒素原子に結合する2個の基は、互いに結合して、窒素原子と共に5員環、6員環、又は7員環を形成してもよい。又、R1-1〜R1-8は、置換基を有していてもよく、R1-1〜R1-8及びそれらの置換基は、それぞれ同一であっても、異なっていてもよい。又、式中の芳香族環は、更に置換基を有していてもよい。nは、1又は2である。X1 -は、陰イオンを示す。]
[式中、R2-1〜R2-8は、それぞれ、水素原子、炭素数1〜8個のアルキル基、炭素数1〜8個のアルケニル基、炭素数1〜8個のアルキニル基、又はアラルキル基を示す。又、R2-1〜R2-8のうち、同じ窒素原子に結合する2個の基は、互いに結合して、窒素原子と共に5員環、6員環、又は7員環を形成してもよい。又、R2-1〜R2-8は、置換基を有していてもよく、R2-1〜R2-8及びそれらの置換基は、それぞれ同一であっても、異なっていてもよい。又、式中の芳香族環は、更に置換基を有していてもよい。X2 -は、陰イオンを示す。]
[式中、R 9 及びR 10 は、それぞれ独立に、水素原子、炭素数1〜5個のアルキル基、アリール基又は置換基としてスルホネート基を有さないアラルキル基を示し、R 11 は、水素原子、ハロゲン原子、炭素数1〜5個のアルキル基又は炭素数1〜5個のアルコキシ基を示し、R 12 及びR 13 は、それぞれ独立に、水素原子、ハロゲン原子、アルキル基、アルコキシ基、ヒドロキシル基、アミノ基、カルボキシレート基、スルホネート基、カルボン酸エステル基又はカルボキサミド基を示す。R 9 〜R 13 における、アルキル基、アルコキシ基、アラルキル基、アリール基、アミノ基、カルボン酸エステル基及びカルボキサミド基は、置換基を有してもよい。]
[式中、R 14 及びR 15 は、それぞれ独立に、水素原子、炭素数1〜5個のアルキル基、置換基としてスルホネート基を有さないアリール基又はアラルキル基を示し、R 16 は、水素原子、ハロゲン原子、炭素数1〜5個のアルキル基又は炭素数1〜5個のアルコキシ基を示し、R 17 及びR 18 は、それぞれ独立に、水素原子、ハロゲン原子、アルキル基、アルコキシ基、ヒドロキシル基、アミノ基、カルボキレート基、スルホネート基、カルボン酸エステル基又はカルボキサミド基を示す。R 14 〜R 18 における、アルキル基、アルコキシ基、アラルキル基、アリール基、アミノ基、カルボン酸エステル基及びカルボキサミド基は、置換基を有してもよい。] In the ink that contain an aqueous medium and a coloring material, the coloring material, the following general formula (1) and the compound represented by at least one of (2), the following general formula as a second dye compound (3) ink, characterized in that at least one water-insoluble triphenylmethane compound and water-insoluble xanthene compound represented by the following general formula (4) indicated a plastid which are Nde free.
[Wherein R 1-1 to R 1-8 are each a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 1 to 8 carbon atoms, an alkynyl group having 1 to 8 carbon atoms, Or an aralkyl group is shown. Also, among R 1-1 to R 1-8 , two groups bonded to the same nitrogen atom are bonded to each other to form a 5-membered ring, 6-membered ring, or 7-membered ring together with the nitrogen atom. Also good. R 1-1 to R 1-8 may have a substituent, and R 1-1 to R 1-8 and their substituents may be the same or different. Good. Moreover, the aromatic ring in the formula may further have a substituent. n is 1 or 2. X 1 − represents an anion. ]
[Wherein R 2-1 to R 2-8 are each a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 1 to 8 carbon atoms, an alkynyl group having 1 to 8 carbon atoms, Or an aralkyl group is shown. Two of R 2-1 to R 2-8 bonded to the same nitrogen atom are bonded to each other to form a 5-membered ring, a 6-membered ring, or a 7-membered ring together with the nitrogen atom. Also good. R 2-1 to R 2-8 may have a substituent, and R 2-1 to R 2-8 and their substituents may be the same or different. Good. Moreover, the aromatic ring in the formula may further have a substituent. X 2 − represents an anion. ]
Wherein, R 9 and R 10 each independently represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, an aralkyl group having no sulfonate group as an aryl group or a substituent, R 11 is hydrogen An atom, a halogen atom, an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms, wherein R 12 and R 13 are each independently a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, A hydroxyl group, an amino group, a carboxylate group, a sulfonate group, a carboxylic acid ester group or a carboxamide group is shown. The alkyl group, alkoxy group, aralkyl group, aryl group, amino group, carboxylate group and carboxamide group in R 9 to R 13 may have a substituent. ]
[Wherein, R 14 and R 15 each independently represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, an aryl group or an aralkyl group having no sulfonate group as a substituent, and R 16 represents a hydrogen atom. An atom, a halogen atom, an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms, wherein R 17 and R 18 are each independently a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, A hydroxyl group, an amino group, a carbochelate group, a sulfonate group, a carboxylic acid ester group or a carboxamide group is shown. The alkyl group, alkoxy group, aralkyl group, aryl group, amino group, carboxylic acid ester group and carboxamide group in R 14 to R 18 may have a substituent. ]
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005046196A JP4621040B2 (en) | 2004-02-27 | 2005-02-22 | Dye body, aqueous dispersion, ink, ink tank, recording unit, recording apparatus and recording method using the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2004055256 | 2004-02-27 | ||
JP2005046196A JP4621040B2 (en) | 2004-02-27 | 2005-02-22 | Dye body, aqueous dispersion, ink, ink tank, recording unit, recording apparatus and recording method using the same |
Publications (3)
Publication Number | Publication Date |
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JP2005272823A JP2005272823A (en) | 2005-10-06 |
JP2005272823A5 true JP2005272823A5 (en) | 2008-03-13 |
JP4621040B2 JP4621040B2 (en) | 2011-01-26 |
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JP2005046196A Expired - Fee Related JP4621040B2 (en) | 2004-02-27 | 2005-02-22 | Dye body, aqueous dispersion, ink, ink tank, recording unit, recording apparatus and recording method using the same |
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JP (1) | JP4621040B2 (en) |
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EP2686738A4 (en) * | 2011-03-17 | 2014-09-17 | Canon Kk | Magenta toner |
JP6268822B2 (en) * | 2013-09-03 | 2018-01-31 | 大日本印刷株式会社 | Color material, color material dispersion, and resin composition |
JP6352213B2 (en) * | 2015-03-30 | 2018-07-04 | 富士フイルム株式会社 | Ink composition, method for producing the same, and image forming method |
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DE2460491A1 (en) * | 1974-12-20 | 1976-07-01 | Hoechst Ag | PROCESS FOR THE MANUFACTURING OF XANTHENE DYES |
JPH09255882A (en) * | 1996-03-22 | 1997-09-30 | Konica Corp | Xanthene-based pigment and ink jet recording liquid containing the same pigment |
JP2001064554A (en) * | 1999-08-31 | 2001-03-13 | Canon Inc | Ink, ink-jet recording process, recording unit, ink cartridge, and ink-jet recorder |
US6653390B1 (en) * | 2000-04-08 | 2003-11-25 | Basf Corporation | Triphenylmethane dyes for water-based compositions |
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2005
- 2005-02-22 JP JP2005046196A patent/JP4621040B2/en not_active Expired - Fee Related
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