JP2005168305A - Raising seedling pot - Google Patents

Raising seedling pot Download PDF

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JP2005168305A
JP2005168305A JP2003408068A JP2003408068A JP2005168305A JP 2005168305 A JP2005168305 A JP 2005168305A JP 2003408068 A JP2003408068 A JP 2003408068A JP 2003408068 A JP2003408068 A JP 2003408068A JP 2005168305 A JP2005168305 A JP 2005168305A
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layer
seedling pot
acid
biodegradable resin
soil
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Toshio Ogawa
俊夫 小川
Mitsugi Baba
貢 馬場
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BABA KAGAKU KOGYO KK
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BABA KAGAKU KOGYO KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an inexpensive raising seedling pot quickly decomposed after embedded in soil so as to be lost in the soil while maintaining enough strengths when growing or distributing seedlings, or the like. <P>SOLUTION: This raising seedling pot is a double-layer type one comprising (A) a layer comprising a biodegradable resin and (B) a bran layer containing the biodegradable resin. The layer (A) is set inside and the layer (B) is set outside. It is preferable that the biodegradable resin content of the layer (B) is 20-50 mass%. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、野菜、果実、鑑賞植物、底木、植林用樹木等の苗木を育成するための育苗ポット、詳しくは埋め殺し可能な育苗ポットに関するものである。   The present invention relates to a seedling pot for growing seedlings such as vegetables, fruits, appreciation plants, bottom trees, tree-planting trees, and more particularly to a seedling pot that can be buried.

従来から野菜、果実、鑑賞植物、底木、植林用樹木等の苗木を育成させるためポリエチレン、ポリプロピレン、ポリ塩化ビニル等の合成樹脂製の育苗ポットが用いられてきた。前記育苗ポットではその中で苗木などが育成されそのままの形で流通に供され、それを購入した消費者は、育成した苗を育苗ポットから取りだし、畑やプランタン等の栽培地に移植してさらに育成を続けるのが一般的である。そして、使用済みの育苗ポットはゴミとして焼却するか又は埋め立て処分するのが一般的である。しかし、プラスチックスは燃焼時の発熱カロリーが大きく焼却炉を破損し易く、また、埋め立てても分解しない上に、単位重量当りの容積比が他の廃棄物に比べて大きく埋め立て後の地盤を弱くし、土地の再利用を困難にしている。   Conventionally, seedling pots made of synthetic resins such as polyethylene, polypropylene, and polyvinyl chloride have been used to grow seedlings such as vegetables, fruits, ornamental plants, bottom trees, and trees for planting trees. In the seedling pot, seedlings and the like are cultivated and distributed in the form as they are, and consumers who have purchased it take out the grown seedling from the seedling pot and transplant it to a cultivation area such as a field or a plantain. It is common to continue training. In general, used nursery pots are incinerated as waste or disposed of in landfills. However, plastics generate a large amount of calories when burned, and are easily damaged by incinerators. In addition, they do not decompose even when landfilled, and the volume ratio per unit weight is large compared to other wastes, making the ground after landfill weak. This makes it difficult to reuse land.

こうした問題を解決する育苗ポットとして、生分解性樹脂を用いた育苗ポットが提案されたが、いずれも苗を育成している段階で育苗ポットの分解が進行し、流通段階で育苗ポットの強度が低下し、破壊することが起きた。そこで、分解性が異なる少なくとも二種類の生分解性樹脂からなる多層構造の育苗ポットが提案(特許文献1)されたが、異なる少なくとも二種類の生分解性樹脂を積層することから層間剥離が起き易く流通段階で強度が低下する欠点があった。この欠点を解決する育苗ポットとして生分解性樹脂からなる層と該樹脂に生分解促進剤を配合した層とを積層した育苗ポットが提案された(特許文献2)。
特開平9−98671号公報 特開2002−217442号公報
As seedling pots that solve these problems, seedling pots using biodegradable resins have been proposed. It went down and destroyed. Thus, a seedling pot having a multilayer structure composed of at least two kinds of biodegradable resins having different degradability has been proposed (Patent Document 1), but delamination occurs because at least two kinds of different biodegradable resins are laminated. There was a drawback that the strength was easily reduced at the distribution stage. A seedling pot in which a layer made of a biodegradable resin and a layer in which a biodegradation accelerator is blended with the resin is laminated has been proposed as a seedling pot to solve this drawback (Patent Document 2).
JP-A-9-98671 JP 2002-217442 A

しかし、上記特許文献2に記載された育苗ポットは、高価な生分解性樹脂を大量に使用することから育苗ポットの値段が高くなり、結果的に苗木等の値段も高くなる欠点があった。   However, the seedling pot described in Patent Document 2 has a drawback in that the price of the seedling pot is increased because a large amount of expensive biodegradable resin is used, resulting in an increase in the price of seedlings and the like.

こうした現状に鑑み、本発明者等は、鋭意い研究を続けた結果、育苗ポットを生分解性樹脂からなる層を内側とし、その外側に前記生分解性樹脂を配合したふすま層を形成することで、層間剥離がなく苗木等の育苗、流通時にも充分な強度が維持され、かつ土壌に埋設した時は速やかに分解し、埋め殺し可能で、しかもふすまという産業廃棄物を多く使用することから製造コストを低くでき高価な生分解性樹脂の使用を緩和できることを見出して、本発明を完成したものである。すなわち、   In view of the current situation, the present inventors have conducted intensive research, and as a result, the seedling pot has a layer made of a biodegradable resin inside, and a bran layer in which the biodegradable resin is blended is formed on the outside. Because there is no delamination, seedlings such as seedlings are maintained at sufficient strength during distribution, and when buried in the soil, they can be quickly decomposed and killed, and a lot of industrial waste such as bran is used. The present invention has been completed by finding that the production cost can be reduced and the use of expensive biodegradable resins can be eased. That is,

本発明は、苗木等の育成時や流通時に十分な強度を維持する一方、土壌に埋設後は速やかに分解し埋め殺しが可能で、かつ製品コストを低くできる育苗ポットを提供することを目的とする。   An object of the present invention is to provide a seedling pot that maintains sufficient strength during growing and distribution of seedlings, etc., and can be quickly decomposed and buried after being buried in soil, and can reduce product costs. To do.

上記目的を達成する本発明は、(A)生分解性樹脂からなる層と(B)該生分解性樹脂を含有するふすま層とからなる二層型の育苗ポットであって、前記(A)層が内側に配置され、(B)層が外側に配置されていることを特徴とする育苗ポットに係る。   The present invention for achieving the above object is a two-layer seedling pot comprising (A) a layer composed of a biodegradable resin and (B) a bran layer containing the biodegradable resin, wherein (A) The seedling pot is characterized in that the layer is disposed on the inner side and the layer (B) is disposed on the outer side.

上記生分解性樹脂としては、ポリ乳酸、乳酸単位が60モル%以上の乳酸と他のヒドロキシカルボン酸との共重合体、乳酸単位が60モル%以上の乳酸、脂肪族多価カルボン酸及び脂肪族グリコールからなる脂肪族ポリエステル共重合体などのポリ乳酸系樹脂、脂肪族ポリエステル樹脂などが挙げられる。前記ポリ乳酸としては、具体的にL−乳酸、D−乳酸、あるいはL−乳酸とD−乳酸の混合物を脱水縮合した樹脂が挙げられ、特に物性、耐熱性が要求される場合にはL体が85モル%、好ましくは95モル%のポリ乳酸がよい。前記ポリ乳酸は、乳酸の環状二量体であるラクチドを開環重合するなどの方法で製造され、その数平均分子量は20,000〜1,000,000、好ましくは50, 000〜500、000の範囲がよく、数平均分子量が20,000未満では、実用的な水分散液が得られず、また、1,000,000を超えると塗布性が悪く好ましくない。   Examples of the biodegradable resin include polylactic acid, a copolymer of lactic acid having a lactic acid unit of 60 mol% or more and other hydroxycarboxylic acid, lactic acid having a lactic acid unit of 60 mol% or more, an aliphatic polycarboxylic acid, and a fat. And polylactic acid-based resins such as aliphatic polyester copolymers composed of aliphatic glycols, and aliphatic polyester resins. Specific examples of the polylactic acid include L-lactic acid, D-lactic acid, or a resin obtained by dehydrating and condensing a mixture of L-lactic acid and D-lactic acid. Is 85 mol%, preferably 95 mol% polylactic acid. The polylactic acid is produced by ring-opening polymerization of lactide, which is a cyclic dimer of lactic acid, and the number average molecular weight thereof is 20,000 to 1,000,000, preferably 50,000 to 500,000. When the number average molecular weight is less than 20,000, a practical aqueous dispersion cannot be obtained. On the other hand, when the number average molecular weight exceeds 1,000,000, the coatability is poor, which is not preferable.

乳酸と共重合する他のヒドロキシカルボン酸としては、例えばグリコール酸、ジメチルグリコール酸、2−ヒドロキシ酪酸、3−ヒドロキシ酪酸、4−ヒドロキシ酪酸、2−ヒドロキシプロパン酸、3−ヒドロキシプロパン酸、2−ヒドロキシ吉草酸、3−ヒドロキシ吉草酸、4−ヒドロキシ吉草酸、5−ヒドロキシ吉草酸、2−ヒドロキシカプロン酸、3−ヒドロキシカプロン酸、4−ヒドロキシカプロン酸等が挙げられる。   Examples of other hydroxycarboxylic acids copolymerized with lactic acid include glycolic acid, dimethyl glycolic acid, 2-hydroxybutyric acid, 3-hydroxybutyric acid, 4-hydroxybutyric acid, 2-hydroxypropanoic acid, 3-hydroxypropanoic acid, 2-hydroxypropanoic acid, Examples thereof include hydroxyvaleric acid, 3-hydroxyvaleric acid, 4-hydroxyvaleric acid, 5-hydroxyvaleric acid, 2-hydroxycaproic acid, 3-hydroxycaproic acid, 4-hydroxycaproic acid and the like.

脂肪族ポリエステル共重合体を形成する脂肪族多価カルボン酸としては、例えばマロン酸、コハク酸、グルタル酸、アジピン酸、ピメリン酸、アゼライン酸及びこれらの無水物などが、また脂肪族グリコールとしては、例えばエチレングリコール、ジエチレングリコール、1,2−プロパンジオール、1,3−プロパンジオール、1,3−ブタンジオール、1,4−ブタンジオール、1,5−ペンチルジオール、1.6−ペンチルジオール、1,6−ヘキサンジオール、ネオペンチルグリコール、テトラメチレングリコールなどが挙げられる。   Examples of the aliphatic polyvalent carboxylic acid forming the aliphatic polyester copolymer include malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, azelaic acid, and anhydrides thereof. For example, ethylene glycol, diethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,5-pentyldiol, 1.6-pentyldiol, , 6-hexanediol, neopentyl glycol, tetramethylene glycol and the like.

脂肪族ポリエステル樹脂としては、ポリラクチドなどのポリ(痾−ヒドロキシカルボン酸)、ポリ−蛩−カプトラクトン、ポリエチレンサクシネート、ポリブチレンサクシネート、ポリ−竈−プロピオラクトンなどが挙げられる。前記生分解性樹脂は単独でも二種以上混合して使用してよいが、外側層を形成するふすま混合樹脂層には、前記生分解性樹脂と同じ樹脂を混合するすることを必須とする。   Examples of the aliphatic polyester resin include poly (痾 -hydroxycarboxylic acid) such as polylactide, poly- 蛩 -captolactone, polyethylene succinate, polybutylene succinate, poly- 竈 -propiolactone, and the like. The biodegradable resins may be used alone or in combination of two or more, but it is essential that the same resin as the biodegradable resin is mixed in the bran mixed resin layer forming the outer layer.

また、ふすまとは、小麦を製粉するとき得られる小麦粉以外の部分をいい、胚乳80〜85質量%、表皮12〜18質量%、胚2〜3質量%からなる産業廃棄物をいう。(B)層中の生分解樹脂の含有量は、50〜15質量%の範囲がよく、生分解性樹脂の含有量が50質量%を超えては製品の低コスト化ができず、また、15質量%未満では製品の強度が低くて好ましくない。そして、本発明の育苗ポットは、前記ふすま層中の生分解樹脂の含有量を変えることで育成期間、流通期間に合わせた生分解性期間を容易に設定できる。   Moreover, bran means parts other than the wheat flour obtained when milling wheat, and refers to industrial waste composed of 80 to 85% by mass of endosperm, 12 to 18% by mass of epidermis, and 2 to 3% by mass of embryo. (B) The content of the biodegradable resin in the layer is preferably in the range of 50 to 15% by mass, and if the content of the biodegradable resin exceeds 50% by mass, the cost of the product cannot be reduced. If it is less than 15% by mass, the strength of the product is low, which is not preferable. And the seedling pot of this invention can set easily the biodegradability period according to the growing period and the distribution period by changing content of the biodegradable resin in the bran layer.

上記内外層には、さらに着色を目的とする顔料、加工性を高めるための酸化防止剤、滑剤等の樹脂加工で用いる公知の添加剤を配合することができる。   In the inner and outer layers, pigments for coloring purposes, antioxidants for improving processability, and known additives used in resin processing such as lubricants can be blended.

本発明の育苗ポットの製造には、射出成形、真空成形、ラミネート成形など公知の方法が用いられるが、より好ましくは真空成形がよい。該真空成形を用いることにより層間の接着強度を高くでき層間剥離を一段と防ぐことができる。前記真空成形を実施するに当っては、所定の育苗期間、流通期間、育苗時期等の要素に適合するように(A)層の厚さ及び(B)層中の生分解樹脂の含有量を決定し、多層押出し機、単層押出し機、カレンダー装置等を用いて、2層型シートに作成し、それをストレート形成法、ドレープ成形法、 ブラグアシスト成形法、凸型エアブロー成形法、凹型エアブロー成形法を用いて、(A)層を内層に(B)層を外層となるように成形するのがよい。   For the production of the seedling pot of the present invention, known methods such as injection molding, vacuum molding and laminate molding are used, but vacuum molding is more preferable. By using the vacuum forming, the adhesive strength between layers can be increased, and delamination can be further prevented. In carrying out the vacuum forming, the thickness of the (A) layer and the content of the biodegradable resin in the (B) layer are adjusted so as to conform to factors such as a predetermined seedling raising period, distribution period, and seedling raising time. Using a multi-layer extruder, single-layer extruder, calendar device, etc., create a two-layer sheet, which is formed by straight forming method, drape forming method, brag assist forming method, convex air blow molding method, concave air blow It is preferable to use a molding method so that the (A) layer is an inner layer and the (B) layer is an outer layer.

本発明の育苗ポットは、層間の接着性が良好で層間剥離を起こすことがなく、かつ育苗期間、流通期間中は充分な強度が維持できる。その上、土壌に埋設後は速やかに生分解を起し、ポットをそのまま土壌中に埋設しても残留することがなく環境を破壊することがなく、さらに、素材としてふすまという産業廃棄物を使用することでら育苗ポットの価格を低くできる。   The seedling pot of the present invention has good adhesion between layers, does not cause delamination, and can maintain sufficient strength during the seedling period and the distribution period. In addition, biodegradation occurs promptly after being buried in the soil, and even if the pot is buried in the soil as it is, it does not remain and does not destroy the environment. In addition, bran industrial waste is used as a material. By doing so, the price of the seedling pot can be lowered.

本発明をさらに実施例に基づいて詳述するが、本発明はこれに限定されるものではない。   The present invention is further described in detail based on examples, but the present invention is not limited thereto.

ポリブチレンサクシネート(昭和高分子製、BIONOLL 、#1001 )(以下PBS という)100質量部を加圧型ニーダーに投入し、造粒して粉末マスターバッチを得た。一方、ふすま50質量部にPBS50質量部をまたふすま80質量部にPBS20質量部を混合し加圧型ニーダーに投入してふすまマスターバッチを得た。前記それぞれのマスターバッチを2層式のダイ押出し機で押出して表1に示すそれぞれの厚さの2層型シートを得た。得られた2層型シートの引張強度を測定したところ表1のとおりであった。また、その分解速度を重量減少率と強度低下率で測ったところ図1、2に示すとおりであった。さらに、前記2層型シートを用いて真空成形機で外側を生分解性樹脂含有ふすま層とする育苗ポットを製造した。得られた育苗ポットを8日間土壌中に埋設し、その後の重量変化率と破断強度の低下率とを測定したところ、図3、4のとおりであった。   100 parts by weight of polybutylene succinate (manufactured by Showa High Polymer, BIONOLL, # 1001) (hereinafter referred to as PBS) was placed in a pressure kneader and granulated to obtain a powder master batch. On the other hand, 50 parts by mass of bran and 50 parts by mass of PBS were mixed with 80 parts by mass of bran, and 20 parts by mass of PBS were mixed and put into a pressure kneader to obtain a bran master batch. The respective master batches were extruded with a two-layer die extruder to obtain two-layer sheets having the respective thicknesses shown in Table 1. When the tensile strength of the obtained two-layer sheet was measured, it was as shown in Table 1. Moreover, when the decomposition rate was measured by the weight reduction rate and the strength reduction rate, it was as shown in FIGS. Furthermore, using the two-layer type sheet, a seedling pot was produced using a vacuum forming machine with the outer side containing a biodegradable resin-containing bran layer. The obtained seedling pots were embedded in the soil for 8 days, and then the rate of change in weight and the rate of decrease in breaking strength were measured, and the results were as shown in FIGS.

上記表1には、比較例1として市販のポリエチレン製育苗ポットの強い引張り強度を示すが、本発明の育苗ポットは、育成期間、流通工程にも十分通用する強度を持ち、かつ図1、2にみるように土壌中では例えば10日埋設すれば大きな重量減少と強度低下がある。特に実施例2、4の育苗ポットにおいて顕著である。また、PBSシートの厚さによる重量変化率と破断強度の変化を図3、4に示すが、ふすまの含量の多い実施例2、4、6において特に重量変化率と破断強度の変化率が大きい。   Table 1 shows the strong tensile strength of a commercially available polyethylene seedling pot as Comparative Example 1, but the seedling pot of the present invention has sufficient strength for the growing period and distribution process, and FIGS. As seen in the figure, if buried in the soil for 10 days, for example, there will be a significant weight reduction and strength reduction. This is particularly noticeable in the seedling pots of Examples 2 and 4. 3 and 4 show changes in weight change rate and breaking strength depending on the thickness of the PBS sheet. In Examples 2, 4, and 6 having a high bran content, the change rate in weight change rate and breaking strength is particularly large. .

本発明の育苗ポットは、苗木等の育成時や流通時に十分な強度を維持するが、土壌に埋設後は速やかに分解し、環境破壊することがなく、かつ産業廃棄物を多く使用することから製品コストが低く育苗ポットの分野で有用である。   The seedling pot of the present invention maintains sufficient strength during the growth and distribution of seedlings, etc., but it quickly decomposes after being buried in the soil, does not destroy the environment, and uses a lot of industrial waste. Product cost is low and it is useful in the field of seedling pots.

8日間土壌中に埋設後の2層型シートの重量変化率を示す。The rate of weight change of a two-layer sheet after being embedded in soil for 8 days is shown. 8日間土壌中に埋設後の2層型シートの破断強度変化を示す。The change in breaking strength of a two-layer sheet after being embedded in soil for 8 days is shown. 本発明の育苗ポットを土壌に埋設後の重量減少率を示す。The weight reduction rate after embedding the seedling pot of this invention in soil is shown. 本発明の育苗ポットを土壌に埋設後の破断強度低下率を示す。The breaking strength reduction rate after embedding the seedling pot of this invention in soil is shown.

Claims (2)

(A)生分解性樹脂からなる層と(B)該生分解性樹脂を含有するふすま層とからなる二層型の育苗ポットであって、前記(A)層が内側に配置され、(B)層が外側に配置されていることを特徴とする育苗ポット。 (A) A two-layer seedling pot comprising a layer made of a biodegradable resin and (B) a bran layer containing the biodegradable resin, wherein the (A) layer is arranged on the inside, (B ) A seedling pot characterized in that the layer is arranged on the outside. (B)層中の生分解性樹脂の含有量が20〜50質量%であることを特徴とする請求項1記載の育苗ポット。

(B) Content of biodegradable resin in a layer is 20-50 mass%, The seedling pot of Claim 1 characterized by the above-mentioned.

JP2003408068A 2003-12-05 2003-12-05 Raising seedling pot Pending JP2005168305A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013116084A (en) * 2011-12-05 2013-06-13 Kyushu Institute Of Technology Breeding raising seedling pot

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013116084A (en) * 2011-12-05 2013-06-13 Kyushu Institute Of Technology Breeding raising seedling pot

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