JP2005023288A - Specific binder and manufacturing and using processes for the same on construction site - Google Patents
Specific binder and manufacturing and using processes for the same on construction site Download PDFInfo
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本発明はバインダに関するものであるが、詳しくは特殊バインダ及び特殊バインダの施工現場におけるハンドミキサーを使用しての製法とその利用方法に関するものである。 The present invention relates to a binder. More specifically, the present invention relates to a special binder and a manufacturing method using a hand mixer at a construction site of the special binder and a method of using the same.
従来のバインダには、FRP補強バインダや高分子合成樹脂バインダがある。FRP補強バインダは、ロックウールに繊維状及び粒状のアルミニュームとガラス繊維、繊維状カーボンとを絡ませてから液状合成樹脂を飽和状態になるまで吸収させて粘度を調整して揺変を抑止することを特徴とするものであるが、これらの繊維は液状合成樹脂を吸収するものではなく、合成樹脂液に繊維状及び粒状のアルミニューム、ガラス繊維、カーボン繊維が均一に分散せず、十分な効果は得られない。また、高分子合成樹脂バインダはアクリル系・ウレタン系・エポキシ系などの合成樹脂にロックウール・繊維状及び粒状のアルミニューム・ガラス繊維・繊維状カーボンを混練してから溶剤で希釈したところに特徴を有する。これらのバインダは製造してから施工するまでの時間を数週間から数ヶ月と想定しているために、粘度維持と自然硬化を防ぐために様々な繊維質や希釈剤を混合・混練している。
このような従来技術によるバインダでは、仮にこのバインダを用いて路面などの舗装工事や壁板などの建築工事などの工法に採用されても繊維物質が固まって作業性が悪くしかも施工品質が一定せず十分な成果は得られない。この理由は、従来のバインダやFRP補強バインダ、高分子合成樹脂バインダ、セラミック樹脂剤とロックウール・繊維状及び粒状のアルミニューム・ガラス繊維・繊維状カーボン等の多品種で大量の繊維物質を混練・混合したため、溶剤の中に液むらが多く存在するからである。多くの繊維物質や希釈剤を樹脂剤やバインダに入れるのは、製造から施工までの間の粘度を維持するためである。また、バインダの補強等のために混合・混練する繊維状・粒状の物質の種類が多く、高価なものになっている。Conventional binders include FRP reinforcing binders and polymer synthetic resin binders. FRP reinforced binder suppresses fluctuations by adjusting the viscosity by absorbing liquid synthetic resin until saturated, after entanglement of fiber and granular aluminum, glass fiber, and fibrous carbon with rock wool. However, these fibers do not absorb liquid synthetic resin, and fibrous and granular aluminum, glass fiber, and carbon fiber are not evenly dispersed in the synthetic resin liquid, and sufficient effects are obtained. Cannot be obtained. Polymer synthetic resin binders are characterized by kneading rock wool, fibrous and granular aluminum, glass fiber, and fibrous carbon into acrylic, urethane, and epoxy synthetic resins and then diluting with a solvent. Have Since these binders are assumed to take several weeks to several months from production to construction, various fibers and diluents are mixed and kneaded in order to maintain viscosity and prevent spontaneous curing.
In such a conventional binder, even if this binder is used for construction methods such as pavement work on road surfaces and building work such as wallboard, the fiber material is hardened and workability is deteriorated and the work quality is kept constant. Sufficient results cannot be obtained. This is because conventional binders, FRP reinforced binders, polymer synthetic resin binders, ceramic resin agents, rock wool / fibrous and granular aluminum / glass fibers / fibrous carbon, etc.・ Because of the mixing, there is a lot of liquid unevenness in the solvent. Many fiber materials and diluents are added to the resin agent and binder in order to maintain the viscosity from manufacturing to construction. In addition, there are many types of fibrous and granular materials to be mixed and kneaded for reinforcing the binder and the like, which is expensive.
かかる従来技術によるバインダに改良を加えて、従来のバインダでは得られないバインダにするところに本発明が解決しようとする課題を有する。 There is a problem to be solved by the present invention in that the binder according to the prior art is improved to make a binder that cannot be obtained by the conventional binder.
本発明は、上記の課題を解決するために開発したものであって、エポキシ系・ウレタン系等の合成樹脂剤に、少なくとも1種類のガラスファイバを施工現場においてハンドミキサーで混合したことを特徴とする特殊バインダと、更に液むらを減少させたことを特徴とする特殊バインダの提供にある。また、少なくとも1種類のガラスファイバを混合して、その粘度が100mPaS〜20,000mPaS程度のエポキシ系等の合成樹脂剤を施工現場においてハンドミキサーで膜状に被覆させて、粘度を500mPaS〜5,000mPaS程度に調整したことを特徴とする特殊バインダと更に液むらを無くしたことを特徴とする特殊バインダの製法と、少なくとも1種類のガラスファイバを混合して絡ませ、その粘度が100mPaS〜10,000mPaS程度のウレタン系等の合成樹脂剤に施工現場においてハンドミキサーで被服させて粘度を500mPaS〜5,000mPaS程度に調整したことを特徴とする特殊バインダと更に液むらを無くしたことを特徴とする特殊バインダの製法の提供にある。更に、請求項1若しくは請求項2に記載の特殊バインダに適当な硬化剤若しくは複数の硬化剤、若しくは硬化剤を使用しないで硬化時間を自由に設定してハンドミキサーで混合し、且つ砕石、砂利、砂、リサイクル石材、廃タイヤゴムチップ、溶融スラグ、焼却灰、ウッドチップ、貝殻、廃ガラスカレット等の小粒径の骨材を施工現場において平ミキサーで混合・混練してブロック状若しくは層状に成型したものを透水性・排水性・保水性を有する舗装用のブロック若しくは構造体に用いることを特徴とする特殊バインダの利用方法と、請求項1若しくは請求項2に記載の特殊バインダに適当な硬化剤若しくは複数の硬化剤、若しくは硬化剤を使用しないで硬化時間を自由に設定してハンドミキサーで混合し、且つ砕石、砂利、砂、リサイクル石材、廃タイヤゴムチップ、溶融スラグ、焼却灰、ウッドチップ、貝殻、廃ガラスカレット等の小粒径の骨材を施工現場において平ミキサーで混合・混練して路面舗装、舗装用ブロック、水路用ブロック、擁壁ブロック、建築用壁板・床板、鉄道用緩衝材・吸消音材、護岸・砂防等工事用などの用材又は吹き付け工法及び膜作用などの工法に用いることを特徴とする特殊バインダの利用方法を提供するものである。 The present invention was developed in order to solve the above-described problems, and is characterized in that at least one kind of glass fiber is mixed with a synthetic resin agent such as an epoxy-based or urethane-based material at a construction site by a hand mixer. And a special binder characterized by further reducing liquid unevenness. Further, at least one kind of glass fiber is mixed, and a synthetic resin agent such as an epoxy resin having a viscosity of about 100 mPaS to 20,000 mPaS is coated in a film shape with a hand mixer at the construction site, and the viscosity is set to 500 mPaS to 5, A special binder characterized by being adjusted to about 000 mPaS and a special binder production method characterized by eliminating liquid unevenness and at least one kind of glass fiber are mixed and entangled, and the viscosity is 100 mPaS to 10,000 mPaS. A special binder characterized in that the viscosity is adjusted to about 500 mPaS to 5,000 mPaS by applying a synthetic resin agent such as urethane to a synthetic resin agent at a construction site with a hand mixer, and a special feature characterized by eliminating liquid unevenness. It is in providing the manufacturing method of the binder. Furthermore, the curing time is freely set without using an appropriate curing agent or a plurality of curing agents, or a curing agent in the special binder according to claim 1 or 2, and the mixture is mixed with a hand mixer. , Sand, recycled stones, waste tire rubber chips, molten slag, incinerated ash, wood chips, shells, waste glass cullet, etc. A method for using a special binder, characterized in that it is used for a paving block or structure having water permeability, drainage and water retention, and suitable curing for the special binder according to claim 1 or 2. Set the curing time freely without using an agent, multiple curing agents, or curing agents, mix with a hand mixer, and crushed stone, gravel, sand, recycle Stone and waste tire rubber chips, molten slag, incinerated ash, wood chips, shells, waste glass cullet, etc. , Retaining wall blocks, building wall boards / floor boards, railway cushioning materials / absorption / sound absorbing materials, materials for construction work such as revetment and erosion control, or use of special binders characterized by spraying methods and film methods A method is provided.
本発明の実施形態は、エポキシ系・ウレタン系等の合成樹脂剤に、少なくとも1種類のガラスファイバを施工現場においてハンドミキサーで混合して絡ませて成るか、エポキシ系・ウレタン系等の合成樹脂剤に、少なくとも1種類のガラスファイバを施工現場においてハンドミキサーで混合して絡ませ、更に液むらを減少させたことを特徴とする特殊バインダであるから、従来のバインダよりも合成樹脂の分子の中に混合物を均一に分散させることが可能に成り、合成樹脂を線状や面状に構成することができ、特に膜状に作用することが可能となる。
また本発明の実施形態は、少なくとも1種類のガラスファイバを混合して絡ませ、その粘度が100mPaS〜20,000mPaS程度のエポキシ系等の合成樹脂剤を施工現場においてハンドミキサーで膜状に被覆させて、粘度を500mPaS〜5,000mPaS程度に調整したことを特徴とする特殊バインダと更に液むらを無くしたことを特徴とする特殊バインダの製法であり、且つ、少なくとも1種類のガラスファイバを混合して絡ませ、その粘度が100mPaS〜10,000mPaS程度のウレタン系等の合成樹脂剤に施工現場においてハンドミキサーで膜状に被服させて、粘度を500mPaS〜5,000mPaS程度に調整したことを特徴とする特殊バインダと更に液むらを無くしたことを特徴とする特殊バインダの製法であるから、これまでの合成樹脂で基材や骨材とを作用させた工法は勿論のこと、合成樹脂をロックウールやガラスウールなどに吸収させただけの工法より、耐蝕性・作業性・経済性・耐久性に優れており、基材や骨材の安定を高めることができる。また、セラミックや比重の軽い骨材に対しても従来と異なり、少量のガラスファイバだけで低粘度の合成樹脂を膜状に被覆させて高粘度化したことによって必要で十分な強度が得られることになった。
更に、この製法によって得られる特殊バインダは骨材表面の凹凸部分や複雑な小孔部にも完全に付着されるので、接着作用が強まり、また冬期間の現場施工時においても加熱混練の必要がないばかりか練りむらもない。また、ガラスファイバに合成樹脂を膜状に被覆させているために、合成樹脂が骨材間に留まって合成樹脂の沈下を防止することができる。
更に、本発明の実施形態は、請求項1若しくは請求項2に記載の特殊バインダに適当な1種類の硬化剤若しくは複数の硬化剤、若しくは硬化剤を使用しないで硬化時間を自由に設定して施工現場においてハンドミキサーで混合し、且つ砕石、砂利、砂、リサイクル石材、廃タイヤゴ厶チップ、溶融スラグ、焼却灰、ウッドチップ、貝殻、廃ガラスカレット等の小粒径の骨材を施工現場において平ミキサーで混合・混練してブロック状若しくは層状に成型したものを透水性・排水性・保水性を有する舗装用のブロック若しくは構造体に用いることを特徴とする特殊バインダの利用方法であり、また、請求項1若しくは請求項2に記載の特殊バインダに適当な1種類の硬化剤若しくは複数の硬化剤、若しくは硬化剤を使用しないで硬化時間を自由に設定して施工現場においてハンドミキサーで混合し、
且つ砕石、砂利、砂、リサイクル石材、廃タイヤゴムチップ、溶融スラグ、焼却灰、ウッドチップ、貝殻、廃ガラスカレット等の小粒径の骨材を施工現場において平ミキサーで混合・混練して路面舗装、舗装用ブロック、水路用ブロック、擁壁ブロック、建築用壁板・床板、鉄道用緩衝材・吸消音材、護岸・砂防等工事用などの用材又は吹き付け工法及び膜作用などの工法に用いることを特徴とする特殊バインダの利用方法であるから、土木面での路盤工事は勿論のこと舗装及び舗装用二次製品の製造並びに建築用壁板・外壁板等の製造などに利用することができる。特に、透水性・排水性・保水性舗装ブロック及び透水性・排水性・保水性を有する層状の舗装構造体においては、その骨材を特殊バインダと施工現場で混練して使用する場合には有効である。The embodiment of the present invention is made by mixing at least one kind of glass fiber with a hand mixer at a construction site, or entangled with a synthetic resin agent such as an epoxy resin or a urethane resin, or a synthetic resin agent such as an epoxy resin or a urethane resin. In addition, since it is a special binder characterized by mixing at least one glass fiber with a hand mixer at the construction site and entangled it, and further reducing the liquid unevenness, it is in the molecule of the synthetic resin than the conventional binder. It becomes possible to uniformly disperse the mixture, and the synthetic resin can be formed into a linear shape or a planar shape, and in particular, can act as a film.
In the embodiment of the present invention, at least one kind of glass fiber is mixed and entangled, and a synthetic resin agent such as an epoxy resin having a viscosity of about 100 mPaS to 20,000 mPaS is coated in a film form with a hand mixer at a construction site. A special binder characterized in that the viscosity is adjusted to about 500 mPaS to 5,000 mPaS and a special binder characterized in that liquid unevenness is eliminated, and at least one kind of glass fiber is mixed. Specially characterized in that the viscosity is adjusted to about 500 mPaS to 5,000 mPaS by entangled and coated with a synthetic resin agent such as urethane system having a viscosity of about 100 mPaS to 10,000 mPaS in a film form with a hand mixer at the construction site. A special binder characterized by eliminating liquid binder and liquid unevenness. Because of this method, the conventional method of working with base materials and aggregates with synthetic resin, as well as the method of absorbing synthetic resin into rock wool, glass wool, etc., has better corrosion resistance and workability. -It is excellent in economy and durability, and can improve the stability of the base material and aggregate. Also, unlike conventional ceramics and aggregates with low specific gravity, the necessary and sufficient strength can be obtained by increasing the viscosity by coating a low-viscosity synthetic resin into a film with only a small amount of glass fiber. Became.
Furthermore, the special binder obtained by this manufacturing method is completely adhered to the irregularities and complex small holes on the surface of the aggregate, so that the adhesive action is strengthened, and heating and kneading is necessary even during on-site construction in the winter period. Not only there is no unevenness. Further, since the glass fiber is coated with the synthetic resin in the form of a film, the synthetic resin stays between the aggregates and can prevent the synthetic resin from sinking.
Further, in the embodiment of the present invention, the curing time can be freely set without using one kind of curing agent or a plurality of curing agents, or a curing agent suitable for the special binder according to claim 1 or claim 2. Mixing with a hand mixer at the construction site, and small-sized aggregates such as crushed stone, gravel, sand, recycled stone, waste tire gourd chips, molten slag, incinerated ash, wood chips, shells, and waste glass cullet at the construction site It is a method of using a special binder characterized in that a block or layer formed by mixing and kneading with a flat mixer is used for a paving block or structure having water permeability, drainage and water retention, and The curing time can be freely set without using one kind of curing agent or a plurality of curing agents or curing agents suitable for the special binder according to claim 1 or claim 2. Set to mix with a hand mixer at a construction site,
In addition, small particle aggregates such as crushed stone, gravel, sand, recycled stone, waste tire rubber chips, molten slag, incinerated ash, wood chips, shells, and waste glass cullet are mixed and kneaded at the construction site with a flat mixer, and then road pavement. , Pavement blocks, waterway blocks, retaining wall blocks, building wall boards / floors, railway cushioning materials / absorbing / sound absorbing materials, materials for construction such as revetments / sabos, etc. It can be used for the manufacture of pavement and secondary products for paving, as well as for the production of wallboards and exterior wallboards for construction as well as roadbed construction on civil engineering surfaces. . Especially for layered pavement structures with water permeability / drainage / water retention pavement blocks and water permeability / drainage / water retention, it is effective when the aggregate is kneaded with a special binder at the construction site. It is.
以下、図面などに従って本発明の実施について説明する。
本発明の特殊バインダは、図1〜図2に示すように少なくとも1種類のガラスファイバ2を混合して絡ませ、その粘度が100mPaS〜20,000mPaS程度のエポキシ系・ウレタン系等の合成樹脂剤1に施工現場においてハンドミキサー3で混合して被服させて、粘度を500mPaS〜5,000mPaS程度に調整して製造する事ができる。更に、液むらを減少させて製造することもできる。この特殊バインダを用いる場合は、その用途によってガラスファイバの長さや粒度を変える必要はない。つまり、ガラスファイバの粒度は1μm〜50μmで長さは1μm〜200μmとし、これらを施工現場において100mPaS〜20,000mPaS粘度の合成樹脂とをハンドミキサーで混合して膜状に被覆させる。また、粘度の調整において、粘度を500mPaS〜5,000mPaS程度にする。使用方法によって増粘剤等で粘度を調整する必要はない。
次に、図3〜図5によって特殊バインダの利用方法について説明する。
図3の4は骨材、5は路盤である。まず、本発明によって得られた特殊バインダに所定の硬化剤を混合した後で6mm〜13mm砕石を骨材4の重量に対して5wt%の特殊バインダ1を混練して30mm厚の舖装を施した。つまり、少なくとも1種類のガラスファイバ1kgにエポキシ系等のバインダ9kgを施工現場において混練して特殊バインダとした。そして、13mm以下の砕石200kgを骨材4として平ミキサーに投入し、特殊バインダを入れて5分間混練した。これを予め用意した路盤5上に敷き均し、転圧して3.5m2×30mmの図4の透水性舗装構造体を得た。
また、図4に示す平板ブロック6は、少なくとも1種類のガラスファイバ1kgにエポキシ系等のバインダ9kgを施工現場でハンドミキサーを使用して混練し、特殊バインダとした。そして、13mm以下の砕石200kgを骨材4としてミキサーに投入し、特殊バインダを入れて5分間混練、これを平板用ブロック金型に入れて成型し、300mm×300mm×50mmの透水性の平板ブロック6を得た。このようにして得た特殊バインダは、路面舗装、舗装用ブロック、水路用ブロック、擁壁ブロック、点字ブロック、建築用壁板・床板、鉄道用緩衝材・吸消音材、護岸・砂防等工事用などの用材用又は吹き付け工法及び膜作用に用いることができた。Hereinafter, embodiments of the present invention will be described with reference to the drawings.
The special binder of the present invention mixes and entangles at least one kind of glass fiber 2 as shown in FIGS. 1 to 2 and has a viscosity of about 100 mPaS to 20,000 mPaS, such as a synthetic resin agent 1 such as epoxy or urethane. It can be manufactured by adjusting the viscosity to about 500 mPaS to 5,000 mPaS by mixing with a hand mixer 3 at the construction site. Furthermore, it can also be produced with reduced liquid unevenness. When this special binder is used, it is not necessary to change the length and particle size of the glass fiber depending on the application. That is, the glass fiber has a particle size of 1 μm to 50 μm and a length of 1 μm to 200 μm, and these are mixed with a synthetic resin having a viscosity of 100 mPaS to 20,000 mPaS at a construction site and coated in a film form. Further, in adjusting the viscosity, the viscosity is set to about 500 mPaS to 5,000 mPaS. It is not necessary to adjust the viscosity with a thickener or the like depending on the method of use.
Next, a method for using a special binder will be described with reference to FIGS.
In FIG. 3, 4 is an aggregate, and 5 is a roadbed. First, after mixing a predetermined hardener with the special binder obtained by the present invention, 6 mm to 13 mm crushed stone is kneaded with 5 wt% of the special binder 1 with respect to the weight of the aggregate 4, and a 30 mm thick outfit is applied. did. That is, a special binder was prepared by kneading 9 kg of epoxy-based binder with 1 kg of at least one kind of glass fiber at the construction site. Then, 200 kg of crushed stone of 13 mm or less was put into a flat mixer as the aggregate 4, and a special binder was added and kneaded for 5 minutes. This was spread on a roadbed 5 prepared in advance and rolled to obtain a water-permeable pavement structure of FIG. 4 having a size of 3.5 m 2 × 30 mm.
In addition, the flat block 6 shown in FIG. 4 is a special binder obtained by kneading 9 kg of an epoxy-based binder with 1 kg of at least one type of glass fiber using a hand mixer at a construction site. Then, 200 kg of crushed stone of 13 mm or less is put into the mixer as aggregate 4, a special binder is added and kneaded for 5 minutes, this is placed in a flat plate block mold and molded, and a 300 mm × 300 mm × 50 mm water-permeable flat plate block 6 was obtained. Special binders obtained in this way are used for road pavement, paving blocks, waterway blocks, retaining wall blocks, braille blocks, building wall boards / floor boards, railway cushioning materials / absorbing sound absorbing materials, revetments, sabos, etc. It was possible to use for materials such as, or spraying method and film action.
本発明は以上のように構成されているので、次のような効果を有する。
ア.ガラスファイバを絡ませる作用によって耐蝕性・作業性・経済性・耐久性に優れていると共に物理的にも必要で十分な強度を得た。
イ.従来の合成樹脂では製造してからの時間経過によっては、沈下を抑止することができないために、上部が弱く下部が強いという上下で強度差のある構造物を、この特殊バインダを使用すれば施工現場において製造するため、合成樹脂などの分子を線状や面状に構成し、膜状に作用させることができ、何時如何なる場所においても、上部と下部との強度が均一である構造物を作れるように成った。
ウ.道路舗装用として提供する場合には、セメントコンクリートと同等以上の強度が得られると共に、透水機能・保水機能・吸音機能を有する構造にすることが可能であり、水跳ね防止効果もある。
エ.本発明からなる特殊バインダを使用して成型された物は、透水機能・保水機能・吸音機能を有し、耐久性・耐蝕性に優れ、更に必要で十分な強度も得ることができる。
オ.歩道用として使用される場合は、廃材ウッドチップ、廃材ゴムチップ、焼却灰溶融スラグ、粉砕陶磁器、リサイクル砕石、貝殻、廃ガラスカレット、石灰石、石灰岩、珊瑚砂、珊瑚石、珊瑚岩等の基材が使用でき、リサイクル推進に役立つことができる。Since the present invention is configured as described above, it has the following effects.
A. It has excellent corrosion resistance, workability, economic efficiency, and durability due to the action of entwining the glass fiber, and it has the necessary physical strength and sufficient strength.
I. With the use of this special binder, it is possible to construct a structure with a difference in strength between the upper and lower sides, where the upper part is weak and the lower part is strong, because conventional synthetic resins cannot suppress subsidence over time. Because it is manufactured in the field, synthetic resin and other molecules can be formed into a linear or planar shape and can act as a film, making it possible to create structures where the strength of the upper and lower parts is uniform at any time and place. It was as follows.
C. When it is provided for road pavement, it can have a strength equal to or higher than that of cement concrete, and can have a structure having a water permeability function, a water retention function, and a sound absorption function, and also has a water splash prevention effect.
D. The product molded using the special binder according to the present invention has a water permeability function, a water retention function, and a sound absorption function, is excellent in durability and corrosion resistance, and can obtain a necessary and sufficient strength.
E. When used for sidewalks, base materials such as waste wood chips, waste rubber chips, incinerated ash molten slag, pulverized ceramics, recycled crushed stones, shells, waste glass cullet, limestone, limestone, cinnabar, meteorite, meteorite, etc. Can be used to help promote recycling.
1 合成樹脂 1
2 ガラスファイバ 2
3 ハンドミキサー 3
4 骨材 4
5 路盤 5
6 平板ブロック 61 Synthetic resin 1
2 Glass fiber 2
3 Hand mixer 3
4 Aggregate 4
5 Roadbed 5
6 Flat block 6
Claims (6)
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JP2003288244A JP2005023288A (en) | 2003-07-02 | 2003-07-02 | Specific binder and manufacturing and using processes for the same on construction site |
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JP2003288244A JP2005023288A (en) | 2003-07-02 | 2003-07-02 | Specific binder and manufacturing and using processes for the same on construction site |
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JP2005023288A true JP2005023288A (en) | 2005-01-27 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008544008A (en) * | 2005-06-14 | 2008-12-04 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for producing a composite of stone and synthetic resin |
KR101056806B1 (en) | 2011-04-27 | 2011-08-12 | (주)로드윈 | Soft road paving method using nature wood chip |
-
2003
- 2003-07-02 JP JP2003288244A patent/JP2005023288A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008544008A (en) * | 2005-06-14 | 2008-12-04 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for producing a composite of stone and synthetic resin |
KR101258718B1 (en) * | 2005-06-14 | 2013-04-30 | 바스프 에스이 | Process for the production of a composite of stones and a plastic |
KR101056806B1 (en) | 2011-04-27 | 2011-08-12 | (주)로드윈 | Soft road paving method using nature wood chip |
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