JP2004043911A - High strength line pipe having excellent low temperature toughness - Google Patents

High strength line pipe having excellent low temperature toughness Download PDF

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JP2004043911A
JP2004043911A JP2002204606A JP2002204606A JP2004043911A JP 2004043911 A JP2004043911 A JP 2004043911A JP 2002204606 A JP2002204606 A JP 2002204606A JP 2002204606 A JP2002204606 A JP 2002204606A JP 2004043911 A JP2004043911 A JP 2004043911A
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Prior art keywords
toughness
strength
less
line pipe
base material
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JP2002204606A
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JP3972756B2 (en
Inventor
Shigeru Endo
遠藤 茂
Ryuji Muraoka
村岡 隆二
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JFE Steel Corp
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JFE Steel Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an X 80 class high strength line pipe in which both a base metal and a weld metal have excellent strength and toughness. <P>SOLUTION: The base metal comprises, by mass, 0.03 to 0.09% C, 0.05 to 0.30% Si, 1.6 to 2.0% Mn, ≤0.020% P, ≤0.0020% S, 0.02 to 0.05% Nb, 0.005 to 0.02% Ti and ≤0.03% Al, and the balance substantially Fe with inevitable impurities, and has a yield strength of ≥690 MPa. The weld metal part comprises 0.05 to 0.10% C, 0.05 to 0.40% Si, 1.6 to 2.0% Mn, ≤0.020% P, ≤0.005% S, ≤0.50% Cu, 0.50 to 1.50% Ni, 0.50 to 1.0% Mo, 0.05 to 0.10% V, 0.01 to 0.04% Ti and 0.015 to 0.035% O, and has a yield strength of ≥690 MPa. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、ラインパイプに関し、特に、母材と溶接金属部の両者の降伏強さが690MPa以上で、低温靭性に優れたものに関する。
【0002】
【従来の技術】
パイプラインに使用されるラインパイプは高強度化が進み、現在、米国石油協会(API)規格でX80グレードまでが実用化され、その需要は増大している。また、更に高強度のX100グレードへの要望も高まっている。
【0003】
特開昭57−35625号公報、特開平08−311548号公報は、このような高強度鋼管の製造方法に関するもので、前者は、鋼管成形後の熱処理を、後者は、高価なCuを1.0%前後添加することが開示されている。
【0004】
特許第2598357号は、主にX70グレードのラインパイプに関するものであるが、やはり、高強度、高靭性ラインパイプの製造方法に関するものである。
【0005】
特開平9−31536号公報、特開平9−41074号公報は、Bや多量のMo,Vを添加し、更に高強度のX120グレードのラインパイプの製造方法を開示している。
【0006】
特開平9−49055号公報、特開平9−314379号公報および特開平10−324950号公報は、高強度ラインパイプのシーム溶接に関し、溶接金属へのB添加や、4.0〜6.5%のNiを含有した溶接ワイヤにより低温靭性に優れた溶接金属を得る技術が提案されている。
【0007】
【発明が解決しようとする課題】
上述したように、現在、低温靭性に優れた高強度ラインパイプは高価な成分組成や、複雑な製造条件によるものとなっている。
【0008】
そこで、本発明は、鋼管に成形後、熱処理を行わず、また、高価な元素を使用しない成分組成により、安価に母材、溶接部(溶接金属を含む)の低温靭性に優れた降伏強さ690MPa以上(APIX100以上)のラインパイプを提供することを目的とする。
【0009】
【課題を解決するための手段】
本発明者等は、安価に高強度且つ低温靭性の得られる成分組成について鋭意検討を行い、母材と溶接熱影響部の低温靭性はSi,Alを低減し、溶接金属部の低温靭性はTi,Oを低減し、B無添加とした場合にそれぞれ向上することを見出した。
【0010】
本発明は以上の知見を基に更に検討を加えてなされたものであり、すなわち、本発明の低温靭性に優れた高強度ラインパイプは、質量%で、C:0.03〜0.09%、Si:0.05〜0.30%、Mn:1.6〜2.0%、P:0.020%以下、S:0.0020%以下、Nb:0.02〜0.05%、Ti:0.005〜0.02%、Al:0.03%以下、残部実質的にFe及び不可避的不純物からなる降伏強さ690MPa以上の母材と、
質量%で、C:0.05〜0.10%、Si:0.05〜0.40%、Mn:1.6〜2.0%、P:0.020%以下、S:0.005%以下、Cu:0.50%以下、Ni:0.50〜1.50%、Mo:0.50〜1.0%、V:0.05〜0.10%、Ti:0.01〜0.04%、O:0.015〜0.035%を含み、降伏強さ690MPa以上の溶接金属部とを有することを特徴とする。
【0011】
この場合に、母材部の鋼組成として、更に、Cu:0.50%以下、Ni:0.50%以下、Mo:0.30%未満の一種または二種以上を含有することが好ましい。
【0012】
さらに、母材部の鋼組成として、Cr:0.50%以下、V:0.01〜0.05%の一種または二種以上を含有することが好ましい。
【0013】
さらに、母材部の鋼組成として、Ca:0.0005〜0.0025%を含有することが好ましい。
【0014】
【発明の実施の形態】
本発明における母材、溶接金属部の成分限定理由、製造条件について詳細に説明する。
【0015】
1.母材の成分

Cは、0.03%未満では、X100としての強度が得られず、一方、0.09%を超えると鋼板の母材及び溶接熱影響部の靭性を劣化させるため、0.03〜0.09%(0.03%以上、0.09%以下)とする。
【0016】
Si
Siは、脱酸のため0.05%以上必要で、一方、0.30%を超えると溶接熱影響部靭性と溶接性を劣化させるため、0.05〜0.30%とする。
【0017】
Mn
Mnは、鋼板の母材強度および靭性向上に有効で、その効果を得るため1.6%以上添加する。一方、2.0%を超えると溶接熱影響部靭性と溶接性が著しく劣化するため、1.6〜2.0%とする。
【0018】

Pは、本発明では不純物であり、母材、溶接熱影響部の靭性を確保するため生産原価を上昇させない範囲で極力低下することが望ましく、0.020%以下とする。
【0019】

X100グレードの高強度材では、MnSをCa添加によりCaS系の介在物に形態制御しても、それにより靭性が低下する場合があるため、S含有量を0.0020%以下とする。
【0020】
Nb
Nbは、スラブ加熱時と圧延時の結晶粒の成長を抑制し、ミクロ組織を微細とし、靭性を向上させる。その効果は0.02%以上で顕著となり、0.05%を超えると飽和し、溶接熱影響部(以下HAZ)の靭性を劣化させるため、0.02〜0.05%とする。
【0021】
Ti
Tiは、TiNを形成し、スラブ加熱時、HAZの粒成長を抑制し、ミクロ組織の微細化により靭性を改善する。その効果は0.005%以上で顕著で、0.02%を超えると靭性劣化が生じるため、0.005〜0.02%とする。
【0022】
Al
Alは、脱酸剤であるが、0.03%を超えるとHAZ靭性を低下させるため、0.03%以下とする。
【0023】
以上が本発明鋼の基本成分組成であり、更に特性を向上させるため、Cu,Ni,Mo,Cr,Vの一種または二種以上を添加することができる。
【0024】
Cu
Cuは、靭性と強度の向上に有効であるが、0.50%を超えると溶接性を阻害するため、0.50%以下とする。
【0025】
Ni
Niは、靭性と強度の向上に有効であるが、0.50%を超えるとその効果が飽和するため、0.50%以下とする。
【0026】
Mo
Moは、靭性と強度の向上に有効であるが、0.30%を超えるとその効果が飽和し、溶接性や耐HIC性が阻害されるため、0.30%以下とする。
【0027】
Cr
Crは、Mnと共に、低C系の鋼で強度向上に有効であるが、0.50%を超えて添加すると溶接性が劣化するため、0.50%以下とする。
【0028】

Vは、靭性、溶接性を劣化させずに、強度を向上させるのに有効で、その効果を得るため、0.01%以上添加する。一方、0.05%を超えると溶接性、靭性が著しく損なわれるため、0.01〜0.05%とする。
【0029】
Ca
Caは、硫化物系介在物の形態を制御し、HAZ靭性を改善するため、0.0005%以上添加する。一方、0.025%を超えるとその効果が飽和し、清浄度を低下させ、HAZ靭性を劣化させるため、0.0005〜0.025%とする。
【0030】
2.溶接金属部の成分

Cは、0.05%未満では、X100としての強度が得られず、一方、0.10%を超えると溶接金属部の靭性を劣化させるため、0.05〜0.10%(0.05%以上、0.10%以下)とする。
【0031】
Si
Siは、溶接金属の脱酸と作業性のため0.05%以上必要で、一方、0.40%を超えると溶接金属部の靭性と溶接性を劣化させるため、0.05〜0.40%とする。
【0032】
Mn
Mnは、溶接金属の強度および靭性向上に有効で、X80以上に必要な強度と靭性を得るため1.6%以上とする。一方、2.0%を超えると靭性と溶接性が著しく劣化するため、1.6〜2.0%とする。
【0033】
P、S
P,Sは溶接金属中では粒界に偏析し、その靭性を劣化させるため、Pは0.020%以下、Sを0.005%以下とする。
【0034】
Cu
Cuは、靭性と強度の向上に有効であるが、0.50%を超えると溶接性を阻害するため、0.50%以下とする。
【0035】
Ni
Niは、靭性と強度の向上に有効であり、その効果をえるため0.50%以上とし、一方、1.5%を超えるとその効果が飽和するため、0.50〜1.5%とする。
【0036】
Mo
Moは、靭性と強度の向上に有効であり、その効果をえるため0.50%以上とし、一方、1.0%を超えるとその効果が飽和し、溶接性が阻害されるため、0.50〜1.0%以下とする。
【0037】

Vは、靭性、溶接性を劣化させずに、強度を向上させるのに有効で、その効果を得るため、0.05%以上とする。一方、0.10%を超えると溶接性、靭性が著しく損なわれるため、0.05〜0.10%とする。
【0038】
Ti
Tiは、靭性、溶接性を劣化させずに、強度を向上させるのに有効で、その効果を得るため、0.01%以上とする。一方、0.04%を超えると溶接性、靭性が著しく損なわれるため、0.01〜0.04%とする。
【0039】

Oは靭性に影響を与え、0.015%未満、0.035%超えで靭性の劣化傾向を示すため、0.015〜0.035%とする。
【0040】
本発明において、鋼板は常法によるもので良く、特にその製造方法は規定しない。また、鋼管の成形方法も冷間であればよく、特に規定しない。
【0041】
【実施例】
表1に示す成分の鋼を用い、冷間成形シーム溶接により鋼管とし、母材の強度、靭性とシーム溶接のHAZ靭性を調査した。母材の降伏強さ(単位MPa),母材並びにHAZのー20℃でのシャルピー吸収エネルギー(単位J)も表1に示す。
【0042】
強度は降伏強さ690MPa以上、シャルピー吸収エネルギー100J以上の場合、それぞれ良好とした。表より明らかなように、本願発明鋼では優れた特性が得られ、一方、比較鋼では、母材強度が低く(K,L,N),母材あるいは溶接熱影響部の靭性が劣っていた(I〜N)。
【0043】
表1の鋼A,H,Jと種々の溶接材料を組み合わせ、鋼管を製造し、溶接金属の降伏強さと靭性を調査した。結果を表2に示す。本願発明の溶接金属(A−1,A−2,H−1,H−2)では、優れた強度、靭性が得られている。
【0044】
一方、比較例の溶接金属では、強度(A−3,H−3)、あるいは、靭性(A−3,H−4、J−1〜3)に劣っている。
【0045】
以上のように、母材、溶接金属ともに本発明範囲内の成分組成の場合に、優れた強度、靭性のラインパイプが得られている。
【0046】
【表1】

Figure 2004043911
【0047】
【表2】
Figure 2004043911
【0048】
【0049】
【発明の効果】
本発明により、母材、溶接金属ともに優れた強度、靭性の高強度ラインパイプが得られ、産業上極めて有用である。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a line pipe, and more particularly to a line pipe having a yield strength of both a base metal and a weld metal part of 690 MPa or more and excellent in low-temperature toughness.
[0002]
[Prior art]
The strength of line pipes used in pipelines has been increasing, and up to X80 grade is currently being put to practical use by American Petroleum Institute (API) standards, and the demand for them is increasing. In addition, demands for higher strength X100 grades are also increasing.
[0003]
JP-A-57-35625 and JP-A-08-31548 relate to a method of manufacturing such a high-strength steel pipe. It is disclosed to add around 0%.
[0004]
Japanese Patent No. 2598357 mainly relates to a line pipe of X70 grade, but also relates to a method of manufacturing a high-strength, high-toughness line pipe.
[0005]
Japanese Patent Application Laid-Open Nos. 9-31536 and 9-41074 disclose a method for producing a high-strength X120 grade line pipe to which B and a large amount of Mo and V are added.
[0006]
JP-A-9-49055, JP-A-9-314379 and JP-A-10-324950 relate to seam welding of high-strength line pipes, in which B is added to a weld metal and 4.0 to 6.5%. A technique for obtaining a weld metal having excellent low-temperature toughness by using a Ni-containing welding wire has been proposed.
[0007]
[Problems to be solved by the invention]
As described above, at present, a high-strength line pipe having excellent low-temperature toughness is based on an expensive component composition and complicated manufacturing conditions.
[0008]
Therefore, the present invention provides a yield strength excellent in low-temperature toughness of a base material and a welded portion (including a weld metal) at a low cost by a component composition that does not perform a heat treatment after forming into a steel pipe and does not use expensive elements. It is an object to provide a line pipe of 690 MPa or more (APIX 100 or more).
[0009]
[Means for Solving the Problems]
The present inventors have conducted intensive studies on component compositions that provide high strength and low temperature toughness at low cost. , And O, and improved when B was not added.
[0010]
The present invention has been made by further study based on the above findings, that is, the high-strength line pipe having excellent low-temperature toughness of the present invention has a C content of 0.03 to 0.09% by mass%. , Si: 0.05 to 0.30%, Mn: 1.6 to 2.0%, P: 0.020% or less, S: 0.0020% or less, Nb: 0.02 to 0.05%, A base material of Ti: 0.005 to 0.02%, Al: 0.03% or less, and a balance substantially consisting of Fe and unavoidable impurities and having a yield strength of 690 MPa or more;
In mass%, C: 0.05 to 0.10%, Si: 0.05 to 0.40%, Mn: 1.6 to 2.0%, P: 0.020% or less, S: 0.005 %, Cu: 0.50% or less, Ni: 0.50 to 1.50%, Mo: 0.50 to 1.0%, V: 0.05 to 0.10%, Ti: 0.01 to 0.04%, O: 0.015 to 0.035%, and a weld metal part having a yield strength of 690 MPa or more.
[0011]
In this case, it is preferable that the steel composition of the base material further contains one or more of Cu: 0.50% or less, Ni: 0.50% or less, and Mo: less than 0.30%.
[0012]
Further, as the steel composition of the base material portion, it is preferable to contain one or more of Cr: 0.50% or less and V: 0.01 to 0.05%.
[0013]
Furthermore, it is preferable that Ca: 0.0005 to 0.0025% is contained as a steel composition of the base material portion.
[0014]
BEST MODE FOR CARRYING OUT THE INVENTION
The reasons for limiting the components of the base metal and the weld metal part and the manufacturing conditions in the present invention will be described in detail.
[0015]
1. Base material component C
If C is less than 0.03%, the strength as X100 cannot be obtained, while if it exceeds 0.09%, the toughness of the base material of the steel sheet and the weld heat affected zone deteriorates. 09% (0.03% or more and 0.09% or less).
[0016]
Si
Si is required to be 0.05% or more for deoxidation. On the other hand, if it exceeds 0.30%, the toughness and weldability of the weld heat affected zone are deteriorated.
[0017]
Mn
Mn is effective in improving the base material strength and toughness of the steel sheet, and is added in an amount of 1.6% or more to obtain the effects. On the other hand, if it exceeds 2.0%, the toughness and weldability of the weld heat-affected zone are significantly deteriorated.
[0018]
P
P is an impurity in the present invention, and is desirably reduced as much as possible without increasing the production cost in order to secure the toughness of the base material and the weld heat affected zone, and is set to 0.020% or less.
[0019]
S
In a high-strength material of X100 grade, even if MnS is added to Ca to control the form of CaS-based inclusions, toughness may be reduced due to this, so the S content is made 0.0020% or less.
[0020]
Nb
Nb suppresses the growth of crystal grains during slab heating and rolling, refines the microstructure, and improves toughness. The effect becomes remarkable at 0.02% or more, and becomes saturated when it exceeds 0.05%, and deteriorates the toughness of a welding heat affected zone (hereinafter, HAZ).
[0021]
Ti
Ti forms TiN, suppresses HAZ grain growth during slab heating, and improves toughness by microstructural refinement. The effect is remarkable at 0.005% or more, and when it exceeds 0.02%, toughness is deteriorated.
[0022]
Al
Al is a deoxidizing agent, but if it exceeds 0.03%, the HAZ toughness is reduced.
[0023]
The above is the basic composition of the steel of the present invention, and one or more of Cu, Ni, Mo, Cr and V can be added to further improve the properties.
[0024]
Cu
Cu is effective in improving toughness and strength, but if it exceeds 0.50%, the weldability is impaired.
[0025]
Ni
Ni is effective in improving toughness and strength, but if it exceeds 0.50%, the effect is saturated, so Ni is set to 0.50% or less.
[0026]
Mo
Mo is effective in improving toughness and strength, but if it exceeds 0.30%, its effect is saturated, and weldability and HIC resistance are impaired. Therefore, Mo is set to 0.30% or less.
[0027]
Cr
Cr, together with Mn, is a low C steel and is effective in improving the strength. However, if added in excess of 0.50%, the weldability deteriorates, so Cr is set to 0.50% or less.
[0028]
V
V is effective for improving the strength without deteriorating the toughness and weldability, and is added at 0.01% or more in order to obtain the effect. On the other hand, if it exceeds 0.05%, the weldability and toughness are significantly impaired, so the content is made 0.01 to 0.05%.
[0029]
Ca
Ca is added in an amount of 0.0005% or more to control the form of the sulfide-based inclusions and improve the HAZ toughness. On the other hand, if the content exceeds 0.025%, the effect is saturated, the cleanliness is reduced, and the HAZ toughness is deteriorated.
[0030]
2. Component C of weld metal
If C is less than 0.05%, the strength as X100 cannot be obtained. On the other hand, if it exceeds 0.10%, the toughness of the weld metal portion is deteriorated. % Or more and 0.10% or less).
[0031]
Si
Si is required to be 0.05% or more for deoxidation and workability of the weld metal. On the other hand, if it exceeds 0.40%, the toughness and weldability of the weld metal portion are deteriorated. %.
[0032]
Mn
Mn is effective for improving the strength and toughness of the weld metal, and is set to 1.6% or more to obtain the strength and toughness required for X80 or more. On the other hand, if it exceeds 2.0%, toughness and weldability are significantly deteriorated, so the content is set to 1.6 to 2.0%.
[0033]
P, S
P and S are segregated at the grain boundaries in the weld metal and deteriorate the toughness. Therefore, P is set to 0.020% or less and S is set to 0.005% or less.
[0034]
Cu
Cu is effective in improving toughness and strength, but if it exceeds 0.50%, the weldability is impaired.
[0035]
Ni
Ni is effective in improving toughness and strength, and is set to 0.50% or more in order to obtain the effect. On the other hand, if the content exceeds 1.5%, the effect is saturated. I do.
[0036]
Mo
Mo is effective in improving toughness and strength, and is set to 0.50% or more to obtain the effect. On the other hand, if it exceeds 1.0%, the effect is saturated and the weldability is impaired. 50% to 1.0% or less.
[0037]
V
V is effective for improving strength without deteriorating toughness and weldability, and is set to 0.05% or more to obtain the effect. On the other hand, if it exceeds 0.10%, the weldability and toughness are significantly impaired, so the content is made 0.05 to 0.10%.
[0038]
Ti
Ti is effective for improving the strength without deteriorating the toughness and weldability. To obtain the effect, the content of Ti is set to 0.01% or more. On the other hand, if it exceeds 0.04%, the weldability and toughness are significantly impaired, so the content is made 0.01 to 0.04%.
[0039]
O
O affects toughness, and if it is less than 0.015% and exceeds 0.035%, the toughness tends to deteriorate.
[0040]
In the present invention, the steel sheet may be formed by a conventional method, and the production method is not particularly specified. Also, the method of forming the steel pipe may be a cold one, and is not particularly limited.
[0041]
【Example】
Using steel having the components shown in Table 1, a steel pipe was formed by cold forming seam welding, and the strength, toughness, and HAZ toughness of the seam welding were investigated. Table 1 also shows the yield strength (unit MPa) of the base material, the Charpy absorbed energy (unit J) of the base material and HAZ at −20 ° C.
[0042]
The strength was determined to be good when the yield strength was 690 MPa or more and the Charpy absorbed energy was 100 J or more. As is clear from the table, excellent properties were obtained in the steel of the present invention, while in the comparative steel, the base metal strength was low (K, L, N), and the toughness of the base metal or the weld heat affected zone was poor. (I-N).
[0043]
Steel pipes were manufactured by combining steels A, H, and J in Table 1 with various welding materials, and the yield strength and toughness of the weld metal were investigated. Table 2 shows the results. In the weld metal (A-1, A-2, H-1, H-2) of the present invention, excellent strength and toughness are obtained.
[0044]
On the other hand, the weld metal of the comparative example is inferior in strength (A-3, H-3) or toughness (A-3, H-4, J-1 to 3).
[0045]
As described above, a line pipe having excellent strength and toughness is obtained when both the base metal and the weld metal have a component composition within the range of the present invention.
[0046]
[Table 1]
Figure 2004043911
[0047]
[Table 2]
Figure 2004043911
[0048]
[0049]
【The invention's effect】
According to the present invention, a high-strength line pipe having excellent strength and toughness can be obtained for both the base material and the weld metal, and is extremely useful in industry.

Claims (4)

質量%で、C:0.03〜0.09%、Si:0.05〜0.30%、Mn:1.6〜2.0%、P:0.020%以下、S:0.0020%以下、Nb:0.02〜0.05%、Ti:0.005〜0.02%、Al:0.03%以下、残部実質的にFe及び不可避的不純物からなる降伏強さ690MPa以上の母材と、
質量%で、C:0.05〜0.10%、Si:0.05〜0.40%、Mn:1.6〜2.0%、P:0.020%以下、S:0.005%以下、Cu:0.50%以下、Ni:0.50〜1.50%、Mo:0.50〜1.0%、V:0.05〜0.10%、Ti:0.01〜0.04%、O:0.015〜0.035%を含み、降伏強さ690MPa以上の溶接金属部を
有することを特徴とする低温靭性に優れた高強度ラインパイプ。
In mass%, C: 0.03 to 0.09%, Si: 0.05 to 0.30%, Mn: 1.6 to 2.0%, P: 0.020% or less, S: 0.0020 %, Nb: 0.02 to 0.05%, Ti: 0.005 to 0.02%, Al: 0.03% or less, the balance being substantially 690 MPa or more in yield strength composed of Fe and unavoidable impurities. With the base material,
In mass%, C: 0.05 to 0.10%, Si: 0.05 to 0.40%, Mn: 1.6 to 2.0%, P: 0.020% or less, S: 0.005 %, Cu: 0.50% or less, Ni: 0.50 to 1.50%, Mo: 0.50 to 1.0%, V: 0.05 to 0.10%, Ti: 0.01 to A high-strength line pipe containing 0.04%, O: 0.015 to 0.035%, and having a weld metal part having a yield strength of 690 MPa or more, and having excellent low-temperature toughness.
母材部の鋼組成として、更に、Cu:0.50%以下、Ni:0.50%以下、Mo:0.30%未満の一種または二種以上を含有することを特徴とする請求項1記載の低温靭性に優れた高強度ラインパイプ。The steel composition of the base material portion further contains one or more of Cu: 0.50% or less, Ni: 0.50% or less, and Mo: less than 0.30%. High-strength line pipe with excellent low-temperature toughness as described. 母材部の鋼組成として、更に、Cr:0.50%以下、V:0.01〜0.05%の一種または二種以上を含有することを特徴とする請求項1または2記載の低温靭性に優れた高強度ラインパイプ。The low temperature according to claim 1 or 2, wherein the base material further contains one or more of Cr: 0.50% or less and V: 0.01 to 0.05% as a steel composition. High strength line pipe with excellent toughness. 母材部の鋼組成として、更に、Ca:0.0005〜0.0025%を含有することを特徴とする請求項1乃至3の何れか一つに記載の低温靭性に優れた高強度ラインパイプ。The high-strength line pipe excellent in low-temperature toughness according to any one of claims 1 to 3, wherein the steel composition of the base material portion further contains Ca: 0.0005 to 0.0025%. .
JP2002204606A 2002-07-12 2002-07-12 High strength line pipe with excellent low temperature toughness Expired - Lifetime JP3972756B2 (en)

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Cited By (7)

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WO2006098198A1 (en) 2005-03-17 2006-09-21 Sumitomo Metal Industries, Ltd. High tension steel plate, welded steel pipe and method for production thereof
WO2008078917A1 (en) * 2006-12-26 2008-07-03 Posco High strength api-x80 grade steels for spiral pipes with less strength changes and method for manufacturing the same
CN103160747A (en) * 2011-12-14 2013-06-19 鞍钢股份有限公司 Low-welding crack sensitivity off-line quenched and tempered super-thick steel plate and manufacturing method thereof
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CN108546885A (en) * 2018-07-03 2018-09-18 鞍钢股份有限公司 L555M pipeline steel with excellent low-temperature toughness and manufacturing method thereof
CN108950388A (en) * 2018-07-03 2018-12-07 鞍钢股份有限公司 L485M pipeline steel with excellent low-temperature toughness and manufacturing method thereof
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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006098198A1 (en) 2005-03-17 2006-09-21 Sumitomo Metal Industries, Ltd. High tension steel plate, welded steel pipe and method for production thereof
US8177925B2 (en) 2005-03-17 2012-05-15 Sumitomo Metal Industries, Ltd. High-tensile steel plate, welded steel pipe or tube, and methods of manufacturing thereof
WO2008078917A1 (en) * 2006-12-26 2008-07-03 Posco High strength api-x80 grade steels for spiral pipes with less strength changes and method for manufacturing the same
CN103160747A (en) * 2011-12-14 2013-06-19 鞍钢股份有限公司 Low-welding crack sensitivity off-line quenched and tempered super-thick steel plate and manufacturing method thereof
CN104789863A (en) * 2015-03-20 2015-07-22 宝山钢铁股份有限公司 X80 pipeline steel with good anti-strain aging property, pipeline pipe and manufacturing method of pipeline pipe
WO2016150116A1 (en) * 2015-03-20 2016-09-29 宝山钢铁股份有限公司 X80 pipeline steel with good strain-aging performance, pipeline tube and method for producing same
US11053563B2 (en) 2015-03-20 2021-07-06 Baoshan Iron & Steel Co., Ltd. X80 pipeline steel with good strain-aging performance, pipeline tube and method for producing same
CN108546885A (en) * 2018-07-03 2018-09-18 鞍钢股份有限公司 L555M pipeline steel with excellent low-temperature toughness and manufacturing method thereof
CN108950388A (en) * 2018-07-03 2018-12-07 鞍钢股份有限公司 L485M pipeline steel with excellent low-temperature toughness and manufacturing method thereof
CN108546885B (en) * 2018-07-03 2019-09-20 鞍钢股份有限公司 L555M pipeline steel with excellent low-temperature toughness and manufacturing method thereof
CN112575253A (en) * 2020-11-24 2021-03-30 中国石油天然气集团有限公司 X80M steel material and X80M steel pipe for longitudinal submerged arc welding and preparation method thereof

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