JP2003301352A - Fabric prepared by forming functional film into slit yarn and method for producing same - Google Patents

Fabric prepared by forming functional film into slit yarn and method for producing same

Info

Publication number
JP2003301352A
JP2003301352A JP2002102698A JP2002102698A JP2003301352A JP 2003301352 A JP2003301352 A JP 2003301352A JP 2002102698 A JP2002102698 A JP 2002102698A JP 2002102698 A JP2002102698 A JP 2002102698A JP 2003301352 A JP2003301352 A JP 2003301352A
Authority
JP
Japan
Prior art keywords
resin
film
fine particles
functional fine
fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2002102698A
Other languages
Japanese (ja)
Inventor
Taiji Takagi
泰治 高木
Yutaka Hayashi
豊 林
Koji Mori
幸治 森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Komatsu Seiren Co Ltd
Original Assignee
Komatsu Seiren Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Komatsu Seiren Co Ltd filed Critical Komatsu Seiren Co Ltd
Priority to JP2002102698A priority Critical patent/JP2003301352A/en
Publication of JP2003301352A publication Critical patent/JP2003301352A/en
Withdrawn legal-status Critical Current

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  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Woven Fabrics (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a fabric using yarns having excellent antistatic, antimicrobial, deodorant and thermal storage and heat insulating properties. <P>SOLUTION: The fabric uses laminated yarns formed by slenderly cutting a synthetic resin film laminate obtained by coating at least one surface of a synthetic resin film with a resin containing functional fine particles. Furthermore, the method for producing the fabric is carried out as follows. The top surface of mold release paper is coated with a resin solution containing at least one selected from a polyurethane resin, an acrylic resin, a polyester resin and a silicone resin and dried. At least one surface on the resin layer is then coated with the resin containing the functional fine particles to form a film containing the functional fine particles. The resultant synthetic resin laminated film is slenderly cut to form the laminated yarns for use. <P>COPYRIGHT: (C)2004,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明が属する技術分野】この発明は、帯電防止機能に
優れ、抗菌性、消臭性、防カビ、蓄熱保温などの各種機
能に優れた糸を使用した布帛に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fabric using a yarn which has an excellent antistatic function and various functions such as antibacterial property, deodorant property, mildew resistance, and heat retention.

【0002】[0002]

【従来の技術】近年、清潔、衛生観念の高まりととも
に、各種の抗菌性、消臭性、防カビ性を備えた商品が求
められるようになってきており、繊維布帛や衣服にも抗
菌性、消臭性、防カビ性を備えたものが求められてい
る。さらには看護や医療サイド並びにそれに準ずる施設
における衣類、シーツや敷布などの寝装材料、キュップ
や頭巾などの雑貨品においてはその傾向が顕著である。
これら抗菌性、消臭性、防カビ性を備えた繊維布帛や各
種の繊維製品には、その材料として抗菌性、消臭性、防
カビを備えた抗菌糸を使用しているものも多い。
2. Description of the Related Art In recent years, as the idea of cleanliness and hygiene has increased, products having various antibacterial properties, deodorant properties, and antifungal properties have come to be demanded. What has deodorant and antifungal properties is required. Furthermore, the tendency is remarkable in clothing in nursing and medical side and facilities equivalent thereto, bedding materials such as sheets and bed sheets, and miscellaneous goods such as cups and hoods.
Many of these fiber cloths having antibacterial properties, deodorizing properties, and antifungal properties and various fiber products use antibacterial yarns having antibacterial properties, deodorizing properties, and antifungal properties as materials thereof.

【0003】さて、このような抗菌糸としては、従来か
ら、銀や銅の金属を細長く伸ばしてなる極細金属糸や、
合成繊維などの糸の表面に銀や銅をメッキしてなるメッ
キ糸、蒸着をしてなる蒸着糸、さらには、抗菌剤、消臭
剤、防カビ剤を練りこみ又は塗布してなる抗菌剤含有糸
等が使用されている。
As such an antibacterial thread, an ultrafine metal thread formed by elongating a metal of silver or copper has been conventionally used,
Plated yarn made by plating silver or copper on the surface of synthetic fiber or the like, vapor-deposited yarn made by vapor deposition, and further an antibacterial agent made by kneading or applying an antibacterial agent, a deodorant, or an antifungal agent. Contained yarn is used.

【0004】一方で、静電気による着衣者の不快感の低
減や、静電気による電子製品の静電破壊防止の観点か
ら、各種帯電防止繊維製品が使用されており、このよう
な帯電防止繊維製品としては、従来から、炭素繊維糸を
含むものや導電性材料を使用した糸が使用されている。
On the other hand, various antistatic textile products are used from the viewpoint of reducing the discomfort of a wearer due to static electricity and preventing electrostatic breakdown of electronic products due to static electricity. As such antistatic textile products, Conventionally, a yarn containing a carbon fiber yarn or a yarn using a conductive material has been used.

【0005】[0005]

【発明が解決しようとする課題】しかし、これら従来か
らある極細金属糸や炭素繊維等を繊維製品に使用し、繊
維製品に抗菌性、消臭性等の各種特性を付与しようとす
る場合には、次に掲げるような問題点があった。
However, when using these conventional ultrafine metal yarns, carbon fibers, etc. in a fiber product and imparting various properties such as antibacterial property and deodorant property to the fiber product, , There were the following problems.

【0006】まず、極細金属糸やメッキ糸、蒸着糸に
は、その表面が経時変化などにより酸化して黒化するた
め、これらを繊維製品に使用すると当該繊維製品の見栄
えが悪くなったり、さらに抗菌性、消臭性、防カビ性が
低下するとの根本的な問題点があった。
First, the surface of ultrafine metal yarns, plated yarns, and vapor-deposited yarns oxidizes and blackens due to changes over time, and when these are used in textile products, the appearance of the textile products becomes worse, and There was a fundamental problem that the antibacterial property, deodorant property and antifungal property were lowered.

【0007】また、帯電防止繊維の炭素繊維糸は黒色糸
であるため、商品の見栄えの点から使用可能な商品が限
定され、特に淡色系統ではグレー化した透明性に欠ける
色のものしか得られなかった。さらに、これら複数の糸
を組合せても、抗菌性、消臭性、帯電防止性、蓄熱保温
性、商品の美観等複数の特性を備えた繊維製品を作り出
すのは困難であった。
Further, since the carbon fiber yarn of the antistatic fiber is a black yarn, the usable products are limited in terms of the appearance of the product, and especially in the light color system, only grayed products having a color lacking transparency are obtained. There wasn't. Further, even if these plural yarns are combined, it is difficult to produce a fiber product having a plurality of properties such as antibacterial property, deodorant property, antistatic property, heat retention and heat retention property, and aesthetic appearance of the product.

【0008】そこで、この発明は、帯電防止機能に優
れ、抗菌性、消臭性、防カビ、蓄熱保温など各種機能性
のある積層糸を使用した布帛を提供することを課題とす
る。
[0008] Therefore, an object of the present invention is to provide a cloth using a laminated yarn which has various functions such as an antistatic function, an antibacterial property, a deodorant property, a fungicide, and heat retention.

【0009】[0009]

【課題を解決するための手段】すなわち、この発明にか
かる積層糸を用いた布帛は、合成樹脂フィルムの少なく
とも片面に機能性微粒子を含む樹脂をコーティングさせ
て機能性微粒子含有の皮膜を成膜し、成膜した合成樹脂
フィルムとなった積層体を細長く切断して形成された積
層糸を用いた布帛を特徴とするものであって、さらに、
合成樹脂フィルム上に機能性微粒子を含む樹脂をコーテ
ィングして金属皮膜を成膜し、成膜した機能性微粒子皮
膜が内側になるように合成樹脂フィルムを貼り合わせ
し、サンドイッチ状構造となった積層体を細長く切断し
て形成された積層糸を用いた布帛を特徴とする構造とな
っている。
That is, in a fabric using the laminated yarn according to the present invention, a resin containing functional fine particles is coated on at least one side of a synthetic resin film to form a film containing the functional fine particles. Characterized by a cloth using laminated yarn formed by cutting a laminated body which has become a synthetic resin film formed into a thin film,
A synthetic resin film is coated with a resin containing functional fine particles to form a metal film, and the synthetic resin film is attached so that the formed functional fine particle film is on the inside, forming a sandwich structure. The structure is characterized by a fabric using laminated yarn formed by cutting a body into thin pieces.

【0010】また、合成樹脂フィルム上に機能性微粒子
を含む樹脂をコーティングして機能性微粒子含有皮膜が
成膜されている面とは反対側の面に、コート層が設けら
れている積層体を細長く切断して形成された積層糸を用
いた布帛を特徴とする構造となっていてよいものであ
る。
Further, a laminated body in which a coating layer is provided on the surface opposite to the surface on which a resin containing functional fine particles is coated on a synthetic resin film to form a film containing functional fine particles is formed. It may have a structure characterized by a cloth using a laminated yarn formed by cutting into thin pieces.

【0011】その製造方法は、離型紙上にポリウレタン
系樹脂、アクリル系樹脂、ポリエステル系樹脂、シリコ
ーン系樹脂から選ばれる少なくともひとつを含む樹脂溶
液を塗布し、乾燥した後、この樹脂層上の少なくとも片
面に機能性微粒子を含む樹脂をコーティングさせて機能
性微粒子含有の皮膜を成膜し、離型紙を剥離し、成膜し
た前記合成樹脂フィルムとなった積層体を細長く切断し
て形成された積層糸を用いることを含む布帛の製造方法
であって、さらに、離型紙上にポリウレタン系樹脂、ア
クリル系樹脂、ポリエステル系樹脂、シリコーン系樹脂
から選ばれる少なくともひとつを含む樹脂溶液を塗布
し、乾燥した後、この樹脂層上に、機能性微粒子を含む
樹脂をコーティングして機能性微粒子含有の皮膜を成膜
し、成膜した機能性微粒子含有の皮膜が内側になるよう
に前記合成樹脂フィルムを貼り合わせし、サンドイッチ
状構造となった積層体を細長く切断して形成された積層
糸を用いることを含む布帛の製造方法である。
The manufacturing method is as follows. A release paper is coated with a resin solution containing at least one selected from a polyurethane resin, an acrylic resin, a polyester resin, and a silicone resin, dried, and then at least on the resin layer. A layer formed by coating a resin containing functional fine particles on one surface to form a film containing functional fine particles, peeling the release paper, and cutting the laminated body that has become the synthetic resin film thus formed into elongated pieces. A method for producing a fabric, which comprises using a yarn, further comprising applying a resin solution containing at least one selected from a polyurethane resin, an acrylic resin, a polyester resin, and a silicone resin on a release paper and drying it. After that, a resin containing functional particles is coated on this resin layer to form a film containing functional particles, and the formed functionality is And bonding the synthetic resin film as coating of particles containing on the inside, a method for producing a fabric comprising using the laminated yarn formed by slitting the laminate in which a sandwich-like structure.

【0012】また、離型紙上にポリウレタン系樹脂、ア
クリル系樹脂、ポリエステル系樹脂、シリコーン系樹脂
から選ばれる少なくともひとつを含む樹脂溶液を塗布
し、乾燥した後、この樹脂層上に、機能性微粒子を含む
樹脂をコーティングして機能性微粒子含有の皮膜が成膜
されている面とは反対側の面に、コート層が設けられて
いる積層体を細長く切断して形成された積層糸を用いる
ことを含む布帛の製造方法であってもよい。本発明は、
書面の走査位置またはその直前(直後)を常に目視可能
とするため、書面に垂直な方向に対して傾斜した光路で
受光することを最も主要な特徴とする。
Further, a resin solution containing at least one selected from a polyurethane resin, an acrylic resin, a polyester resin and a silicone resin is applied on a release paper and dried, and then the functional fine particles are formed on the resin layer. Use a laminated yarn that is formed by cutting a laminate with a coating layer on the surface opposite to the surface on which a film containing functional particles is formed by coating a resin containing It may be a method of manufacturing a fabric including. The present invention is
Since the scanning position of the document or the immediately preceding (immediately after) position of the document is always visible, the most important feature is that light is received by an optical path inclined with respect to the direction perpendicular to the document.

【0013】[0013]

【発明の実施の形態】以下、この発明の実施の形態につ
いて、さらに詳しく説明する。この発明にかかる積層糸
の構造は、合成樹脂フィルムの少なくとも片面に機能性
微粒子を含む樹脂を付与して、機能性微粒子を成膜し、
成膜した合成樹脂フィルムとなった積層体を細長く切断
して形成された積層糸を用いた布帛という構造である。
BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be described in more detail below. The structure of the laminated yarn according to the present invention is such that a resin containing functional fine particles is applied to at least one surface of a synthetic resin film to form functional fine particles.
It is a structure using a laminated yarn formed by cutting a laminated body, which is a synthetic resin film formed, into thin pieces.

【0014】まず、合成樹脂フィルムとは、離型紙上に
ポリウレタン系樹脂、アクリル系樹脂、ポリエステル系
樹脂、シリコーン系樹脂から選ばれる少なくともひとつ
を含む樹脂溶液を3〜1000μm、好ましくは5〜3
00μmの膜厚で、ナイフオーバーロールコーター等の
公知の手段によって塗布することができる。後述のよう
に、積層体を細長く切断して形成された積層糸が細くな
ればなるほど、糸切れの問題等が顕在化し、引張り弾性
等が必要となるので、ポリウレタン系樹脂やポリエステ
ル系樹脂が好ましく使用される。次いで、乾燥は80〜
160℃の温度で行うのがよく、エアーオーブンなどの
公知の手段で行えばよい。これにより、基材としての合
成樹脂層からなるフィルム成形品が完成する。
First, the synthetic resin film means a resin solution containing at least one selected from polyurethane resin, acrylic resin, polyester resin and silicone resin on the release paper in the range of 3 to 1000 μm, preferably 5 to 3 μm.
It can be applied with a film thickness of 00 μm by a known means such as a knife over roll coater. As described below, the thinner the laminated yarn formed by cutting the laminate is, the more obvious the problem of yarn breakage becomes, and the tensile elasticity is required. Therefore, a polyurethane resin or a polyester resin is preferable. used. Then, the drying is 80 ~
The temperature is preferably 160 ° C., and known means such as an air oven may be used. As a result, a film molded product made of the synthetic resin layer as the base material is completed.

【0015】この樹脂層上の少なくとも片面に機能性微
粒子を含む樹脂をコーティングさせて機能性微粒子含有
の皮膜を成膜するが、金属被膜の厚さは、3〜80μm
程度であり、製品コストの点、生産の安定性の点から、
5〜10μm程度が好ましい。機能性微粒子としては、
銀、亜鉛、銅などをセラミックやゼオライトなどにまぜ
た無機系抗菌剤、消臭剤、防カビ剤など、さらに各種の
有機系抗菌剤、消臭剤、防カビ剤など、たとえば、ピリ
チオン亜鉛錯体などを含有してもよい。帯電防止と抗菌
の併用を考慮して、しかも安全性と性能面を両立させる
意味あいにおいては、少なくとも銀を含有することが好
ましい。また、蓄熱保温のために、中空状粒子や赤外線
吸収剤や温度調節プロティン微粒子などが知られている
し、光触媒機能を持つ酸化チタンやケイ素化合物などが
挙げられるが、当該機能性微粒子をペースト状、分散さ
せた樹脂となれば、限定されるものではない。
A resin containing functional fine particles is coated on at least one surface of the resin layer to form a film containing functional fine particles. The thickness of the metal coating is 3 to 80 μm.
However, from the viewpoint of product cost and production stability,
It is preferably about 5 to 10 μm. As functional fine particles,
Inorganic antibacterial agents, deodorants, antifungal agents, etc., in which silver, zinc, copper, etc. are mixed with ceramics, zeolite, etc., as well as various organic antibacterial agents, deodorants, antifungal agents, for example, pyrithione zinc complex Etc. may be contained. It is preferable to contain at least silver in consideration of the combined use of antistatic property and antibacterial property and in the sense of achieving both safety and performance. Further, for heat storage and heat retention, hollow particles, infrared absorbents, temperature control protein fine particles, etc. are known, and examples thereof include titanium oxide and silicon compounds having a photocatalytic function. The resin is not limited as long as it is a dispersed resin.

【0016】少なくとも銅や銀をコーティングするので
あれば、抗菌性、消臭性、防カビ性はもちろんのこと、
導電性を有するので、特に合成繊維ならではの帯電防止
機能は恒常的に発揮するものであることは言うまでもな
い。
If at least copper or silver is coated, the antibacterial property, the deodorant property and the antifungal property are, of course,
Needless to say, since it has conductivity, the antistatic function, which is unique to synthetic fibers, is constantly exerted.

【0017】つぎに、合成樹脂層からなるフィルム成形
品上に機能性微粒子含有の皮膜を成膜した状態で、巻き
取り、エージングをし、離型紙を剥離する。さらに、機
能性微粒子が成膜された合成樹脂フィルムの積層体を縦
方向に幅0.1〜10ミリに切断して積層糸が完成し、
これを糸として織物、編物、不織布とする。銀、銅など
の導電性金属等をコーティングして、電磁波シールド性
を求める場合には、高密度の織物や隙間の少ない編物、
不織布に設計するべきである。
Next, in a state where a film containing functional fine particles is formed on a film molded product made of a synthetic resin layer, the film is wound and aged, and the release paper is peeled off. Furthermore, the laminated body of the synthetic resin film on which the functional fine particles are formed is cut into a width of 0.1 to 10 mm in the longitudinal direction to complete the laminated yarn,
This is used as a thread to form a woven fabric, a knitted fabric, or a nonwoven fabric. If you want to shield electromagnetic waves by coating conductive metal such as silver or copper, you can use high-density woven fabric or knitted fabric with few gaps.
It should be designed to be non-woven.

【0018】また、合成樹脂フィルム上に機能性微粒子
をコーティングして機能性微粒子皮膜を成膜し、成膜し
た機能性微粒子皮膜が内側になるように合成樹脂フィル
ムを貼り合わせ、サンドイッチ状構造となった積層体を
細長く切断して形成された積層糸を用いた布帛を作成し
てもよいものであるが、合成樹脂フィルムにも前述の機
能性微粒子の銀、亜鉛、銅などの無機系抗菌剤、消臭
剤、防カビ剤など、さらに各種の有機系抗菌剤、消臭
剤、防カビ剤など、蓄熱保温のために、中空状粒子や赤
外線吸収剤や温度調節プロティン微粒子、光触媒機能を
持つ酸化チタンやケイ素化合物などを同時にコーティン
グすれば、機能性微粒子皮膜との併用で相乗効果も期待
できる。さらに、係る機能性微粒子をサンドイッチ構造
となる合成樹脂フィルムの片面と、もう一方の面とは、
別の機能性のある機能性微粒子をコーティングすること
で、その機能性の幅が広がり、自由設計をすることがで
きるものである。
Further, the functional fine particles are coated on the synthetic resin film to form a functional fine particle film, and the synthetic resin film is attached so that the formed functional fine particle film is on the inside to form a sandwich structure. Although it is possible to create a fabric using laminated yarn formed by cutting the resulting laminated body into thin pieces, synthetic resin films can also be made of inorganic antibacterial agents such as the above-mentioned functional fine particles of silver, zinc, copper, etc. Agents, deodorants, antifungal agents, and various organic antibacterial agents, deodorants, antifungal agents, etc., have hollow particles, infrared absorbers, temperature control protein particles, and photocatalytic functions to retain heat. If titanium oxide, silicon compound, etc. are simultaneously coated, a synergistic effect can be expected in combination with the functional fine particle film. Furthermore, one side of the synthetic resin film having such a functional fine particle as a sandwich structure and the other side are
By coating with another functional fine particle having functionality, the range of functionality is broadened and it is possible to freely design.

【0019】一方、合成樹脂フィルム上に機能性微粒子
をコーティングして3〜80μm程度の厚さの機能性微
粒子皮膜が成膜されている面とは反対側の面に、コート
層が設けられていてもよく、たとえば、粘着層を設けた
りすることも可能であり、シールを剥がして、添付する
ということも簡単である。
On the other hand, a coating layer is provided on the surface opposite to the surface on which the functional fine particles are coated on the synthetic resin film to form the functional fine particle film having a thickness of about 3 to 80 μm. Alternatively, for example, an adhesive layer may be provided, and it is easy to peel off the seal and attach it.

【0020】ここで、機能性微粒子をコーティングした
金属皮膜の側面は外部に露出しているため、酸化・塩化
するものの、隣接する繊維と互いにこすれあって、当該
酸化部分は取れてしまう。また、金属皮膜の側面以外の
部分は、合成樹脂フィルムによって保護されているた
め、酸化・塩化しない。そのため、抗菌力や消臭力が低
下したり、金属皮膜が黒化して、繊維製品の外観が悪化
するもない。さらに、積層糸が織り込まれた衣服等に静
電気が生じても機能性微粒子皮膜が、少なくとも銅や銀
など導電性金属含むので、静電気が外部に移動するた
め、静電気を帯電させない効果も発揮するものである。
Since the side surface of the metal film coated with the functional fine particles is exposed to the outside, it oxidizes and chlorides, but the adjacent fibers rub against each other and the oxidized portion is removed. Moreover, since the portions other than the side surfaces of the metal film are protected by the synthetic resin film, they do not oxidize or chloride. Therefore, the antibacterial activity and the deodorizing activity are not reduced, and the metal film is blackened, so that the appearance of the fiber product is not deteriorated. In addition, even if static electricity is generated on clothes etc. in which laminated yarn is woven, the functional fine particle film contains at least a conductive metal such as copper or silver, so that static electricity moves to the outside, so it also exhibits the effect of not charging static electricity. Is.

【0021】[0021]

【実施例】次に、この発明に係る積層糸を使用して布帛
を製造して各種試験を行い、この発明をさらに詳細に説
明する。また、以下の例に示す品質評価は、次の方法に
より行ったものである。 品質評価方法 1) 抗菌加工試験法 黄色ブドウ球菌、肺炎桿菌、大腸菌、緑膿菌、MRSA
(メチシリン耐性黄色ぶどう球菌)について、JIS
L−1902の方法に従って試験を行う。 2) 制電性試験法(帯電防止試験) 摩擦帯電圧 JIS L−1094 B法 に従って
試験を行い、帯電防止評価を行う。
EXAMPLES Next, the present invention will be described in more detail by making a fabric using the laminated yarn according to the present invention and conducting various tests. Moreover, the quality evaluation shown in the following examples is performed by the following method. Quality evaluation method 1) Antibacterial processing test method Staphylococcus aureus, Klebsiella pneumoniae, Escherichia coli, Pseudomonas aeruginosa, MRSA
(Methicillin-resistant Staphylococcus aureus)
The test is performed according to the method of L-1902. 2) Antistatic test method (antistatic test) Friction electrification voltage A test is carried out according to JIS L-1094 B method to perform antistatic evaluation.

【0022】実施例1 コーティング用に下記の樹脂液
を調製した。 コーティング用樹脂液組成 エーテルエステル系ウレタン樹脂 KB−X 100部 (固形分30%、溶剤メチルエチルケトンおよびジメチルホルムアミド、 大日本インキ株式会社製) メチルエチルケトン 20部 ジメチルホルムアミド 10部 この樹脂液を、ナイフオーバーロールコーターを使用し
て、フルダル離型紙(EV130TPD、リンテック株
式会社製)上に、全面塗布した。離型紙上の樹脂をエア
ーオブンを用いて100℃で乾燥し、膜厚10μmの合
成樹脂フィルムを得た。
Example 1 The following resin solution was prepared for coating. Resin liquid composition for coating Ether ester type urethane resin KB-X 100 parts (solid content 30%, solvent methyl ethyl ketone and dimethylformamide, manufactured by Dainippon Ink and Chemicals, Inc.) Methyl ethyl ketone 20 parts Dimethylformamide 10 parts This resin liquid is knife over roll coater Was applied to the entire surface of a full-dull release paper (EV130TPD, manufactured by Lintec Co., Ltd.). The resin on the release paper was dried at 100 ° C. using an air oven to obtain a synthetic resin film having a film thickness of 10 μm.

【0023】つぎに、下記組成の抗菌性および/または
消臭金属を含む樹脂を調製した。 抗菌性および帯電防止性のある金属を含む樹脂組成 エーテルエステル系ウレタン樹脂 KB−X 100部 (固形分30%、溶剤メチルエチルケトンおよびジメチルホルムアミド、 大日本インキ株式会社製) メチルエチルケトン 40部 ジメチルホルムアミド 20部 銀の粉末ペースト(粒径 2μm) 30部 これを、グラビアコーターを用いて、膜厚上記の合成樹
脂フィルム上に全面塗布をし、巻き取り、70℃で20
時間エージングした後に離型紙を剥離して、150℃で
仕上げセットを行った。
Next, a resin having the following composition containing antibacterial and / or deodorant metal was prepared. Resin composition containing metal having antibacterial and antistatic properties Ether ester urethane resin KB-X 100 parts (solid content 30%, solvent methyl ethyl ketone and dimethylformamide, manufactured by Dainippon Ink and Chemicals, Inc.) Methyl ethyl ketone 40 parts Dimethylformamide 20 parts Silver 30 parts by weight of the powder paste (particle size: 2 μm) was coated on the synthetic resin film having the above film thickness using a gravure coater, and the film was wound up at 70 ° C. for 20 minutes.
After aging for a time, the release paper was peeled off, and finish setting was performed at 150 ° C.

【0024】つぎに、前記抗菌性および帯電防止性のあ
る金属を持つウレタンフィルムの積層体を縦方向に幅2
26ミクロンに切断して積層糸とし、10mm間隔で織
り込んだポリエステル混紡の織物を上記の各種試験に供
しところ、帯電圧は、520ボルトであって、抗菌性も
認められた。
Next, the urethane film laminated body having the above-mentioned antibacterial and antistatic metal is provided with a width of 2 in the longitudinal direction.
When the polyester blended fabric, which was cut into 26 microns to be a laminated yarn and woven at intervals of 10 mm, was subjected to the above-mentioned various tests, the electrification voltage was 520 V and the antibacterial property was also recognized.

【0025】比較例1 実施例1と同じ実施ではあるが、銀の粉末ペーストのみ
を使用せずに得た積層糸による布帛を同様の試験を行っ
たところ、帯電圧は、3000ボルトであって、抗菌性
は認められなかった。
COMPARATIVE EXAMPLE 1 The same test as in Example 1 was conducted, except that a fabric made of the laminated yarn obtained without using only the silver powder paste was subjected to the same test. No antibacterial property was observed.

【0026】実施例2 つぎに、実施例1の積層糸を5mm間隔で織り込んだポ
リエステル混紡の織物を使用して、上記の各種試験に供
しところ、帯電圧は、460ボルトであって、十分な抗
菌性も認められた。
Example 2 Next, the polyester blended fabric in which the laminated yarn of Example 1 was woven at 5 mm intervals was used and subjected to the above-mentioned various tests. The charged voltage was 460 V, which was sufficient. Antibacterial properties were also recognized.

【0027】比較例2 実施例2と同じ実施ではあるが、銀の粉末ペーストのみ
を使用せずに得た積層糸による布帛を同様の試験を行っ
たところ、帯電圧は、3000ボルトであって、抗菌性
は認められなかった。
COMPARATIVE EXAMPLE 2 The same test as in Example 2 was conducted, except that a fabric made of the laminated yarn obtained without using only the silver powder paste was subjected to the same test. No antibacterial property was observed.

【0028】実施例3 さらに、実施例1の積層糸を2mm間隔で織り込んだポ
リアミド混紡の織物を使用して、上記の各種試験に供し
ところ、帯電圧は、380ボルトであって、十分な抗菌
性も認められた。
Example 3 Further, using the polyamide blended woven fabric in which the laminated yarn of Example 1 was woven at intervals of 2 mm, it was subjected to the above-mentioned various tests, and the electrification voltage was 380 V. The sex was also recognized.

【0029】比較例3 実施例3と同じ実施ではあるが、銀の粉末ペーストのみ
を使用せずに得た積層糸による布帛を同様の試験を行っ
たところ、帯電圧は、3000ボルトであって、抗菌性
は認められなかった。
Comparative Example 3 The same test as in Example 3 was conducted, but the same test was carried out on a fabric made of the laminated yarn obtained without using only the silver powder paste. The electrification voltage was 3000 volts. No antibacterial property was observed.

【0030】以上の結果より、明らかなように、十分な
帯電防止機能があり、抗菌性についても指定される菌に
ついては、すべてクリアーする機能を併用をしていた。
From the above results, it is clear that the bacteria having a sufficient antistatic function and clearing all antibacterial properties are used together.

【0031】[0031]

【発明の効果】上記の説明から明らかなように、この発
明にかかる積層糸は、機能性微粒子からなる皮膜を合成
樹脂フィルムに上に積層させたものを細長く切断した糸
を使用した布帛であるため、たとえば、帯電防止性があ
り、高い抗菌性を備えたものであって、各種、所望の機
能性を自由に設計できる布帛を提供するものである。
As is apparent from the above description, the laminated yarn according to the present invention is a fabric using a yarn obtained by laminating a synthetic resin film on which a film made of functional fine particles is laminated and then cutting it into elongated pieces. Therefore, for example, the present invention provides a fabric having antistatic properties and high antibacterial properties and capable of freely designing various desired functionality.

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4L036 MA04 MA05 MA15 MA34 MA39 4L048 AA16 AA21 AA26 AA27 AA46 AA47 AA52 AA56 AB28 AC13 CA05 DA01 DA13 DA22    ─────────────────────────────────────────────────── ─── Continued front page    F-term (reference) 4L036 MA04 MA05 MA15 MA34 MA39                 4L048 AA16 AA21 AA26 AA27 AA46                       AA47 AA52 AA56 AB28 AC13                       CA05 DA01 DA13 DA22

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 合成樹脂フィルムの少なくとも片面に機
能性微粒子を含む樹脂をコーティングさせて機能性微粒
子含有の皮膜を成膜し、成膜した合成樹脂フィルムとな
った積層体を細長く切断して形成された積層糸を用いた
布帛。
1. A synthetic resin film is formed by coating a resin containing functional fine particles on at least one surface of the synthetic resin film to form a film containing the functional fine particles, and cutting a laminated body of the formed synthetic resin film into elongated pieces. A fabric using the laminated yarn.
【請求項2】 合成樹脂フィルム上に機能性微粒子を含
む樹脂をコーティングして機能性微粒子含有の皮膜を成
膜し、成膜した機能性微粒子含有の皮膜が内側になるよ
うに合成樹脂フィルムを貼り合わせし、サンドイッチ状
構造となった積層体を細長く切断して形成された積層糸
を用いた布帛。
2. A synthetic resin film is coated with a resin containing functional fine particles to form a film containing functional fine particles, and the synthetic resin film is formed so that the formed film containing functional fine particles is on the inside. A cloth using laminated yarn formed by cutting a laminated body, which is laminated and has a sandwich structure, into thin pieces.
【請求項3】 合成樹脂フィルム上に機能性微粒子を含
む樹脂をコーティングして機能性微粒子含有の皮膜が成
膜されている面とは反対側の面に、コート層が設けられ
ている積層体を使用した請求項1または、請求項2に記
載の布帛。
3. A laminate in which a coating layer is provided on a surface opposite to a surface on which a resin containing functional fine particles is coated on a synthetic resin film to form a film containing the functional fine particles. The fabric according to claim 1 or 2, wherein the fabric is used.
【請求項4】 離型紙上にポリウレタン系樹脂、アクリ
ル系樹脂、ポリエステル系樹脂、シリコーン系樹脂から
選ばれる少なくともひとつを含む樹脂溶液を塗布し、乾
燥した後、この樹脂層上の少なくとも片面に機能性微粒
子を含む樹脂をコーティングさせて機能性微粒子含有の
皮膜を成膜し、離型紙を剥離し、成膜した前記合成樹脂
フィルムとなった積層体を細長く切断して形成された積
層糸を用いることを含む布帛の製造方法。
4. A release paper is coated with a resin solution containing at least one selected from a polyurethane resin, an acrylic resin, a polyester resin, and a silicone resin, and after drying, a function is provided on at least one surface of the resin layer. Using a laminated yarn formed by coating a resin containing functional fine particles to form a film containing functional fine particles, peeling off the release paper, and cutting the synthetic resin film-formed laminated body into elongated pieces. A method for producing a fabric, comprising:
【請求項5】 離型紙上にポリウレタン系樹脂、アクリ
ル系樹脂、ポリエステル系樹脂、シリコーン系樹脂から
選ばれる少なくともひとつを含む樹脂溶液を塗布し、乾
燥した後、この樹脂層上に、機能性微粒子を含む樹脂を
コーティングして機能性微粒子含有の皮膜を成膜し、成
膜した機能性微粒子含有の皮膜が内側になるように前記
合成樹脂フィルムを貼り合わせし、サンドイッチ状構造
となった積層体を細長く切断して形成された積層糸を用
いることを含む布帛の製造方法。
5. The release paper is coated with a resin solution containing at least one selected from a polyurethane resin, an acrylic resin, a polyester resin, and a silicone resin, dried, and then the functional fine particles are formed on the resin layer. A laminate having a sandwich structure, in which a resin containing is coated to form a film containing functional fine particles, and the synthetic resin film is attached so that the formed film containing functional fine particles is on the inside. A method for producing a fabric, which comprises using a laminated yarn formed by cutting the material into strips.
【請求項6】 離型紙上にポリウレタン系樹脂、アクリ
ル系樹脂、ポリエステル系樹脂、シリコーン系樹脂から
選ばれる少なくともひとつを含む樹脂溶液を塗布し、乾
燥した後、この樹脂層上に、機能性微粒子を含む樹脂を
コーティングして機能性微粒子含有の皮膜が成膜されて
いる面とは反対側の面に、コート層が設けられている積
層体を使用した請求項4、または、請求項5に記載の布
帛の製造方法。
6. A release paper is coated with a resin solution containing at least one selected from a polyurethane resin, an acrylic resin, a polyester resin, and a silicone resin and dried, and then the functional fine particles are formed on the resin layer. A laminated body having a coat layer provided on the surface opposite to the surface on which a film containing functional particles is formed by coating a resin containing A method for producing the described fabric.
JP2002102698A 2002-04-04 2002-04-04 Fabric prepared by forming functional film into slit yarn and method for producing same Withdrawn JP2003301352A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2002102698A JP2003301352A (en) 2002-04-04 2002-04-04 Fabric prepared by forming functional film into slit yarn and method for producing same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Publications (1)

Publication Number Publication Date
JP2003301352A true JP2003301352A (en) 2003-10-24

Family

ID=29389020

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2003301352A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009133947A1 (en) * 2008-05-02 2009-11-05 ダイヤテックス株式会社 Electromagnetic wave suppression flat yarn, electromagnetic wave suppression product using same, and methods for fabricating them
EP2116639A3 (en) * 2008-01-23 2010-05-05 Instytut Wlokien Naturalnych The method of manufacturing of bioactive technical fibre
KR101037703B1 (en) 2009-06-30 2011-05-30 코오롱글로텍주식회사 Method for manufacturing flame retarding slit fabrics and the fabrics manufactured thereby
CN112226863A (en) * 2020-08-28 2021-01-15 东莞市可可纺织材料有限公司 Preparation method of fragrance-feeling yarn and fragrance-feeling yarn

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2116639A3 (en) * 2008-01-23 2010-05-05 Instytut Wlokien Naturalnych The method of manufacturing of bioactive technical fibre
WO2009133947A1 (en) * 2008-05-02 2009-11-05 ダイヤテックス株式会社 Electromagnetic wave suppression flat yarn, electromagnetic wave suppression product using same, and methods for fabricating them
JP2009270218A (en) * 2008-05-02 2009-11-19 Diatex Co Ltd Electromagnetic wave suppression flat yarn, electromagnetic wave suppression product using same, and method for producing the same
KR101037703B1 (en) 2009-06-30 2011-05-30 코오롱글로텍주식회사 Method for manufacturing flame retarding slit fabrics and the fabrics manufactured thereby
CN112226863A (en) * 2020-08-28 2021-01-15 东莞市可可纺织材料有限公司 Preparation method of fragrance-feeling yarn and fragrance-feeling yarn

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